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    Organic Questions 1

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    SABARI SRINIVAS A
    The document contains 30 multiple choice questions about organic haloalkanes and haloarenes, their reactions, properties, uses, and related compounds. The questions cover topics like substitution reactions of alkyl halides, nucleophilic aromatic substitution of aryl halides, industrial uses of compounds like DDT and freons, and physical properties of compounds like iodoform.

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    Organic Questions 1

    Uploaded by

    SABARI SRINIVAS A
    44 views3 pages
    The document contains 30 multiple choice questions about organic haloalkanes and haloarenes, their reactions, properties, uses, and related compounds. The questions cover topics like substitution reactions of alkyl halides, nucleophilic aromatic substitution of aryl halides, industrial uses of compounds like DDT and freons, and physical properties of compounds like iodoform.

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    The document contains 30 multiple choice questions about organic haloalkanes and haloarenes, their reactions, properties, uses, and related compounds. The questions cover topics like substitution reactions of alkyl halides, nucleophilic aromatic substitution of aryl halides, industrial uses of compounds like DDT and freons, and physical properties of compounds like iodoform.

    Copyright:

    © All Rights Reserved
    Download as DOCX, PDF, TXT or read online from Scribd
    Download as docx, pdf, or txt
    44 views3 pages

    Organic Questions 1

    Uploaded by

    SABARI SRINIVAS A
    The document contains 30 multiple choice questions about organic haloalkanes and haloarenes, their reactions, properties, uses, and related compounds. The questions cover topics like substitution reactions of alkyl halides, nucleophilic aromatic substitution of aryl halides, industrial uses of compounds like DDT and freons, and physical properties of compounds like iodoform.

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    © All Rights Reserved
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    Download as docx, pdf, or txt
    of 3

    ORGANIC HALO ALKANES AND HALO ARENES

    Answer the following MCQ’S:- Marks : 30


    o
    1. Which of the following halide is 2
    (a)Isopropyl chloride (b)Isobutyl chloride
    (c)n-propyl chloride (d)n-butyl chloride
    2. Gem- dibromide is
    (a) CH 3 CH(Br)OH(Br)CH 3 (b) CH3CBr2 CH 3
    (c) CH 2 (Br)CH 2 CH 2 (d) CH 2 BrCH 2 Br
    3. Benzene hexachloride is
    (a) 1, 2, 3, 4, 5, 6-hexachlorocyclohexane
    (b) 1, 1, 1, 6, 6, 6-hexachlorocyclohexane
    (c) 1, 6-phenyl-1, 6-chlorohexane
    (d) 1, 1-phenyl-6, 6-chlorohexane
    4. What is the main product of the reaction between 2-methyl propene with HBr
    (a) 1-bromo butane (b) 1-bromo-2 methyl propane
    (c) 2-bromo butane (d) 2-bromo-2 methyl propane


    N  NBF4

     A

    5. In the above process product A is


    (a) Fluorobenzene (b) Benzene
    (c) 1, 4-difluorobenzene (d) 1, 3-difluorobenzene
    6. When ethyl alcohol (C 2 H 5 OH) reacts with thionyl chloride, in the presence of pyridine, the product
    obtained is
    (a) CH 3 CH 2 Cl  HCl (b) C 2 H 5 Cl  HCl  SO 2
    (c) CH 3 CH 2 Cl  H 2 O  SO 2 (d) CH 3 CH 2 Cl  HCl  SO 2
    7. Which of the following organic compounds will give a mixture of 1-chlorobutane and 2-chlorobutane
    on chlorination
    CH 3  CH  CH  CH 2 H
    | |

    (a) CH 3 (b) HC  C  C  CH 2
    CH 2  CH  CH  CH 2 (d) CH 2  CH  CH 2  CH 3
    (c)
    8. Decreasing order of reactivity of HX in the reaction ROH  HX  RX  H 2 O
    (a) HI  HBr  HCl  HF (b) HBr  HCl  HI  HF
    (c) HCl  HBr  HI  HF (d) HF  HBr  HCl  HI
    C6 H 5 Cl prepared by aniline with
    9.
    (a) HCl (b) Cu 2 Cl 2
    Cl 2 in presence of anhydrous AlCl3 (d) HNO 2 and then heated with Cu 2 Cl 2
    (c)
    10. Propene on treatment with HBr gives
    (a) Isopropyl bromide (b) Propyl bromide
    (c) 1, 2-dibromoethane (d) None of the above
    11. Ethylene reacts with bromine to form
    (a) Chloroethane (b) Ethylene dibromide
    (c) Cyclohexane (d) 1-bromo propane
    12. Reaction of ethyl chloride with sodium leads to
    (a) Ethane (b) Propane (c) n-butane (d) n-pentane
    13. Phosgene is the common name for
    (a) CO 2 and PH 3 (b) Phosphoryl chloride
    (c) Carbonyl chloride (d) Carbon tetrachloride
    14. Alkyl halides can be converted into Grignard reagents by
    (a) Boiling them with Mg ribbon in alcoholic solution
    (b) Warming them with magnesium powder in dry ether
    (c) Refluxing them with MgCl 2 solution
    Warming them with MgCl 2
    (d)
    15. Chlorobenzene is
    (a) Less reactive than benzyl chloride
    (b) More reactive than ethyl bromide
    (c) Nearly as reactive as methyl chloride
    (d) More reactive than isopropyl chloride
    16. The reactivities of methyl chloride, propyl chloride and chlorobenzene are in the order
    (a) Methyl chloride > propyl chloride > chlorobenzene
    (b) Propyl chloride > methyl chloride > chlorobenzene
    (c) Methyl chloride > chlorobenzene > propyl chloride
    (d) Chlorobenzene > propyl chloride > methyl chloride
    17. Reaction of t-butyl bromide with sodium methoxide produces]
    (a)Isobutane (b)Isobutylene
    (c)Sodium t-butoxide (d)t-butyl methyl ether

    C6 H 5 CH 2 Cl  KCN(aq.)  X  Y Compounds X and Y are


    18.
    (a) C6 H 6  KCl (b) C6 H 5 CH 2 CN  KCl
    (c) C6 H5 CH3  KCl (d) None of these
    CH 3  CH 2  CH 2 Br  KOH (alc.)  Product Product in above reaction is
    19.
    (a) CH 3  CH  CH 2 (b) CH 3  CH 2  CH 3
    (c) (a) and (b) both (d) None of these
    20. Ethyl chloride on heating with silver cyanide forms a compound X. The functional isomer of X is
    (c) H 3C  NH  CH 3 (d) C2 H 5 NH 2
    C 2 H5 NC (b) C 2 H5 CN
    (a)
    21. Alkyl halides react with Mg in dry ether to form
    (a) Magnesium halide (b) Grignard’s reagent
    (c) Alkene (d) Alkyne
    22. Aryl halide is less reactive than alkyl halide towards nucleophilic substitution because
    (a) Less stable carbonium ion (b) Due to large C  Cl bond energy
    2
    (c) Inductive effect (d) Resonance stabilization and sp - hybridisation of C attached to halide
    23. Which of the following are correct statements about C 2 H5 Br
    (a) It reacts with metallic Na to give ethane
    (b) It gives nitroethane on heating with aqueous ethanolic solution of AgNO 2
    C H OH
    (c) It gives 2 5 on boiling with alcoholic potash
    (d) It forms ethylacetate on heating with silver acetate
    24. In alkyl halides, Alcoholic potash is used to bring about
    (a) Dehydrogenation (b) Dehydration
    (c) Dehydrohalogenation (d) Dehalogenation
    25. Depletion of ozone layer is caused by
    (a) Freon (b) Alkane (c) Gringard reagent (d) All of these
    26. Which of the following is used in fire extinguishers
    CH 4 (b) CHCl3 (c) CH 2 Cl2 (d) CCl4
    (a)
    27. Which of the following is known as freon which is used as a refrigerant
    (a) CCl2 F2 (b) CHCl3 (c) CH 2 F2 (d) CF4
    28. Iodoform can be used as
    (a) Anaesthetic (b) Antiseptic (c) Analgesic (d) Antibiotic
    29. The commercial uses of DDT and benzene hexachloride are
    (a) DDT is a herbicide, benzene hexachloride is a fungicide
    (b) Both are insecticides
    (c) Both are herbicides
    (d) DDT is a fungicide and benzene hexachloride is a herbicide
    30. The molecular formula of DDT has
    (a) 5 chlorine atoms (b) 4 chlorine atoms
    (c) 3 chlorine atoms (d) 2 chlorine atoms

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