Astm G152 - 13
Astm G152 - 13
Astm G152 - 13
More specific information about methods for determining the ISO 4892-1 Plastics—Methods of Exposure to Laboratory
change in properties after exposure and reporting these results Light Sources, Part 1, General Guidance4
is described in Practice D5870. ISO 4892-4 Plastics—Methods of Exposure to Laboratory
1.4 The values stated in SI units are to be regarded as the Light Sources, Part 4, Open-Flame Carbon Arc Lamp4
standard.
3. Terminology
1.5 This standard does not purport to address all of the
safety concerns, if any, associated with its use. It is the 3.1 Definitions—The definitions given in Terminology G113
responsibility of the user of this standard to establish appro- are applicable to this practice.
priate safety and health practices and determine the applica- 3.1.1 As used in this practice, the term sunlight is identical
bility of regulatory limitations prior to use. to the terms daylight and solar irradiance, global as they are
1.5.1 Should any ozone be generated from the operation of defined in Terminology G113.
the light source, it shall be carried away from the test
specimens and operating personnel by an exhaust system.
2
For referenced ASTM standards, visit the ASTM website, www.astm.org, or
contact ASTM Customer Service at [email protected]. For Annual Book of ASTM
1
This practice is under the jurisdiction of ASTM Committee G03 on Weathering Standards volume information, refer to the standard’s Document Summary page on
and Durability and is the direct responsibility of Subcommittee G03.03 onSimulated the ASTM website.
3
and Controlled Exposure Tests. The last approved version of this historical standard is referenced on
Current edition approved July 1, 2013. Published July 2013. Originally approved www.astm.org.
4
in 1997. Last previous edition approved in 2006 as G152 – 06. DOI: 10.1520/ Available from American National Standards Institute (ANSI), 25 W. 43rd St.,
G0152-13. 4th Floor, New York, NY 10036, http://www.ansi.org.
6.1 Laboratory Light Source—Open flame carbon arc light affect filter transmission.
sources typically use three or four pairs of carbon rods, which 6.1.3.4 Differences in the composition of the metallic salts
contain a mixture of rare-earth metal salts and have a metal used in he carbon rods can affect the spectral power distribu-
coating such as copper on the surface. An electric current is tion.
passed between the carbon rods which burn and give off 6.1.4 Spectral Irradiance:
ultraviolet, visible, and infrared radiation. The carbon rod pairs 6.1.4.1 Spectral Irradiance of Open Flame Carbon Arc with
are burned in sequence, with one pair burning at any one time. Daylight Filters—Daylight filters are used to reduce the short
Use carbon rods recommended by the device manufacturer. wavelength UV irradiance of the open flame carbon arc in an
--```,``,,,,``,`,````,`,,`,,,,,,-`-`,,`,,`,`,,`---
291–300 0% 0%
percentage of the total irradiance from 250 to 400 nm. The manufacturer is
301–320 2.1 % 0.1–1.5 %
responsible for determining conformance to Table 3. Annex A1 states how to
321–340 8.1 % 9.4–14.8 %
determine relative spectral irradiance.
341–360 13.2 % 23.2–23.5 % B
The data in Table 3 are based on the rectangular integration of 24 spectral power
361–380 27.3 % 29.6–32.5 %
distributions for open flame carbon-arcs with various lots of carbon rods and
381–400 49.3 % 30.9–34.5 %
extended UV filters of various lots and ages. The spectral power distribution data
is for filters within the aging recommendations of the device manufacturer. The
Ultraviolet and Visible Wavelength Region Irradiance as a Percentage of Total
minimum and maximum data are at least the three sigma limits from the mean for
Irradiance from 300 to 800 nmC
all measurements.
Irradiance as a Percentage of Total Irradiance from 300 to 800 nmC C
For any individual spectral power distribution, the calculated percentage for the
bandpasses in Table 1 will sum to 100 %. Test results can be expected to differ
Open Flame Carbon Arc Estimated Window Glass
between exposures using open flame carbon arc devices in which the spectral
Bandpass (nm) with Window Glass FiltersE Filtered SunlightD
power distributions differ by as much as that allowed by the tolerances typical for
300–400 22.7–34.1 % 9.0–11.1 %
daylight filters. Contact the manufacturer of the carbon-arc devices for specific
401–700 51.1–67.3 % 71.3–73.1 %
spectral power distribution data for the open flame carbon-arc and filters used.
*Data from 701 to 800 nm is not shown D
The ASTM benchmark solar radiation data is defined in ASTM G177 and is for
atmospheric conditions and altitude chosen to maximize the short wavelength UV
A fraction of solar UV. This data is provided for comparison purposes only.
Carbon Arc Data—This data are for a typical spectral power distribution for an
E
open flame carbons arc with window glass filters. Not enough spectral data is Previous versions of this standard used solar radiation data from Table 4 of CIE
available for meaningful analysis to develop a specification. Subcommittee G03.03 Publication Number 85. See Appendix X2 for more information comparing the solar
is working to collect sufficient data in order to develop a specification. radiation data used in the standard with that for CIE 85 Table 4.
B F
Sunlight Data—The sunlight data is for global irradiance on a horizontal surface For the benchmark solar spectrum, the UV irradiance (290-400 nm) is 9.8% and
with an air mass of 1.2, column ozone 0.294 atm cm, 30 % relative humidity, the visible irradiance (400-800 nm) is 90.2% expressed as a percentage of the
altitude 2100 m (atmospheric pressure of 787.8 mb), and an aerosol represented total irradiance from 290 to 800 nm. The percentages of UV and visible irradiances
by an optical thickness of 0.081 at 300 nm and 0.62 at 400 nm. The range is on samples exposed in filtered open flame carbon arc devices may vary due to the
determined by multiplying solar irradiance by the upper and lower limits for number and reflectance properties of specimens being exposed. This is based on
transmission of single strength window glass samples used for studies conducted measurements in xenon-arc devices but similar measurements have not been
by Subcommittee G03.02.6 made in open flame carbon-arc devices.
C
Sunlight Data—The sunlight data is from Table 4 of CIE Publication No. 85,
global solar irradiance on a horizontal surface with an air mass of 1.0, column
ozone of 0.34 atm cm, 1.42 cm precipitable water vapor, and an aerosol
represented by an optical thickness of 0.1 at 500 nm.
7
12.1 accelerated; accelerated weathering; carbon arc; dura-
Fischer, R. M., “Results of Round-Robin Studies of Light- and Water-Exposure
Standard Practices,” Symposium on Accelerated and Outdoor Durability Testing of
bility; exposure; laboratory weathering; light; lightfastness;
Organic Materials, ASTM STP 1202, Warren K. Ketola and Douglas Grossman, nonmetallic materials; open flame carbon arc; sunshine carbon
Editors, ASTM, 1993. arc; temperature; ultraviolet; weathering
--```,``,,,,``,`,````,`,,`,,,,,,-`-`,,`,,`,`,,`---
A1.1 Conformance to the spectral power distribution tables determining conformance to the relative spectral irradiance
is a design parameter for an open flame carbon-arc with the requirements for an open flame carbon-arc with extended UV
different filters provided. Manufacturers of equipment claiming filters, measurement from 250 nm to 400 nm is required. The
conformance to this standard shall determine conformance to total irradiance in each wavelength bandpass is then summed
the spectral power distribution tables for all carbon-arc/filter and divided by the specified total UV irradiance according to
combinations provided, and provide information on mainte- Eq A1.1. Use of this equation requires that each spectral
nance procedures to minimize any spectral changes that may interval must be the same (for example, 2 nm) throughout the
occur during normal use. spectral region used.
A1.2 The spectral power distribution data for this standard λ i 5B
A1.1 is used to determine the relative spectral irradiance using IR 5 λ i 5400 3 100 (A1.1)
rectangular integration. Other integration techniques can be (
λ i 5C
E λi
used to evaluate spectral power distribution data, but may give
different results. When comparing spectral power distribution where:
data to the spectral power distribution requirements of this IR = relative irradiance in percent,
standard, use the rectangular integration technique. E = irradiance at wavelength λi (irradiance steps must be
equal for all bandpasses),
A1.3 To determine whether a specific filter for an open A = lower wavelength of wavelength bandpass,
flame carbon-arc device meets the requirements of Table 1, B = upper wavelength of wavelength bandpass,
Table 2, or Table 3, measure the spectral power distribution C = lower wavelength of total UV bandpass used for calcu-
from 250 nm to 400 nm. Typically, this is done at 2 nm lating relative spectral irradiance (290 nm for daylight
increments. If the manufacturer’s spectral measurement equip- filters, 300 nm for window glass filters, or 250 nm for
ment cannot measure wavelengths as low as 250 nm, the extended UV filters), and
lowest measurement wavelength must be reported. The lowest λi = wavelength at which irradiance was measured.
wavelength measured shall be no greater than 270 nm. For
APPENDIXES
(Nonmandatory Information)
X1.1 Any exposure conditions may be used, as long as the for the parameters in Table X1.1. If the actual operating
exact conditions are detailed in the report. Following are some conditions do not agree with the machine settings after the
representative exposure conditions. These are not preferred equipment has stabilized, discontinue the test and correct the
necessarily and no recommendation is implied. These condi- cause of the disagreement before continuing.
tions are provided for reference only (see Table X1.1).
X1.3 For conversion of test cycles, see Table X1.3.
X1.2 Unless otherwise specified, operate the apparatus to
maintain the operational fluctuations specified in Table X1.2
NOTE 1—Historical convention has established Cycle 1a as a very commonly used exposure cycle. Other cycles may give a better simulation of the
effects of outdoor exposure. Cycle 2 has been used for exterior textiles. Cycle 3, 4, and 5 have been used for exterior coatings and stains. Cycle 6 has
been used for lightfastness of indoor materials. The operational fluctuation values given for the set point temperatures are those that have been historically
used for these exposures and may be above the maximum operational fluctuation given in Practice G151.
NOTE 2—More complex cycles may be programmed in conjunction with dark periods that allow high relative humidities and the formation of
condensate at elevated chamber temperatures. Condensation may be produced on the face of the specimens by spraying the rear side of them to cool them
below the dewpoint.
NOTE 3—For special tests, high operating temperatures may be desirable, but this will increase the tendency for thermal degradation to adversely
influence the test results.
NOTE 4—Surface temperature of specimens is an essential test quantity. Generally, degradation processes accelerate with increasing temperature. The
specimen temperature recommended for the accelerated test depends on the material to be tested and on the aging criterion under consideration.
NOTE 5—The relative humidity of the air as measured in the test chamber is not necessarily equivalent to the relative humidity of the air very close
to the specimen surface. This is because test specimens having varying colors and thicknesses may be expected to vary in temperature.
--```,``,,,,``,`,````,`,,`,,,,,,-`-`,,`,,`,`,,`---
G23– Method 3 — continuous expo- G152, Table X1.1, cycle 6 uses the
sure to light with no water spray same conditions but requires use of
window glass filters
X2. COMPARISON OF BENCHMARK SOLAR UV SPECTRUM WITH THE CIE 85 TABLE 4 SOLAR UV SPECTRUM
X2.1 This standard uses a benchmark solar spectrum based Radiation provides the program and documentation for calcu-
on atmospheric conditions that provide for a very high level of lating solar spectral irradiance.
solar ultraviolet radiation. This benchmark solar spectrum is
published in ASTM G177, Standard Tables for Reference Solar X2.2 Previous versions of this standard used CIE 85 Table 4
11
Ultraviolet Spectral Distributions: Hemispherical on 37 degree as the benchmark solar spectra. Table X2.1 compares the
Tilted Surface. The solar spectrum is calculated using the basic atmospheric conditions used for the benchmark solar
SMARTS2 solar radiation model.8,9,10 ASTM Adjunct spectrum and the CIE 85 Table 4 solar spectrum.
ADJG0173, SMARTS2 Solar Radiation Model for Spectral X2.3 Table X2.2 compares irradiance (calculated using
rectangular integration) and relative irradiance for the bench-
8
Gueymard, C., “Parameterized Transmittance Model for Direct Beam and mark solar spectra and the CIE 85 Table 4 solar spectrum, in
Circumsolar Spectral Irradiance,” Solar Energy, Vol 71, No. 5, 2001, pp. 325-346. the bandpasses used in this standard.
9
Gueymard, C. A., Myers, D., and Emery, K., “Proposed Reference Irradiance
Spectra for Solar Energy Systems Testing,” Solar Energy, Vol 73, No 6, 2002, pp.
443-467.
10 11
Myers, D. R., Emery, K., and Gueymard, C., “Revising and Validating Spectral CIE-Publication Number 85: Recommendations for the Integrated Irradiance
Irradiance Reference Standards for Photovoltaic Performance Evaluation,” Proceed- and the Spectral Distribution of Simulated Solar Radiation for Testing Purposes, 1st
ings of Solar 2002 – Sunrise on the Reliable Energy Economy, Reno, NV, June Edition, 1989 (Available from American National Standards Institute, 11 W. 42nd
15-20, 2002. St., 13th Floor, New York, NY 10036).
--```,``,,,,``,`,````,`,,`,,,,,,-`-`,,`,,`,`,,`---
SUMMARY OF CHANGES
Subcommittee G03.03 has identified the location of selected changes to this standard since the last issue
(G152 – 06) that may impact the use of this standard. This section may also include descriptions of the changes
or reasons for the changes, or both.
(1) Harmonized text and format in paragraphs 5.2, 5.2.1, and (4) Introduced text and table clarifying the use of operational
Appendix Appendix X1, as well as format in Table X1.1. fluctuations.
(2) Deleted operational fluctuations listed in Table X1.1 that
were the same as those listed in Table X1.2.
(3) Changed allowable operational fluctuation for humidity
control from 6 5% to 6 10%, harmonized with other industry
standards
This standard is subject to revision at any time by the responsible technical committee and must be reviewed every five years and
if not revised, either reapproved or withdrawn. Your comments are invited either for revision of this standard or for additional standards
and should be addressed to ASTM International Headquarters. Your comments will receive careful consideration at a meeting of the
responsible technical committee, which you may attend. If you feel that your comments have not received a fair hearing you should
make your views known to the ASTM Committee on Standards, at the address shown below.
This standard is copyrighted by ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959,
United States. Individual reprints (single or multiple copies) of this standard may be obtained by contacting ASTM at the above
address or at 610-832-9585 (phone), 610-832-9555 (fax), or [email protected] (e-mail); or through the ASTM website
(www.astm.org). Permission rights to photocopy the standard may also be secured from the ASTM website (www.astm.org/
COPYRIGHT/).
--```,``,,,,``,`,````,`,,`,,,,,,-`-`,,`,,`,`,,`---