TARGET: JEE (Main + Advanced) 2020 Course: VIKAAS (JA) NO. B1

DPPs BOOKLET-2 VIKAAS (JA) | CHEMISTRY
P-CH EM ISTRY
TARGET : JEE (Main + Advanced) 2020


EST INFORM AT IO
DPP
DAILY PRACTICE PROBLEMS
Course : VIKAAS(JA) NO. B1

1. Course of the week as per plan :
2. Course covered till previous week :
3. Target of the current week :
4. DPP Syllabus :
DPP No. # B1 (JEE-MAIN)
Total Marks : 54 Max. Time : 36 min.
Single choice Objective ('–1' negative marking) Q.1 to Q.18 (3 marks, 2 min.) [54, 36]
ANSWER KEY
1. (B) 2. (B) 3. (C) 4. (C) 5. (B) 6. (A) 7. (A)
8. (C) 9. (C) 10. (D) 11. (B) 12. (A) 13. (D) 14. (C)
15. (C) 16. (A) 17. (D) 18. (C)
1. S1 : Photoelectric effect can be explained on the basis of wave nature of electromagnetic radiations. -
S2 : An orbital represented by n = 2,  = 1 is dumb-bell shaped.
S3 : dxy orbital has zero probability of finding electrons along X-axis and Y-axis.
S1 : izdk'koS|qr izHkko dks oS|qrpqEcdh; fofdj.kksa dh rjax izd`fr ds vk/kkj ij le>k;k tk ldrk gSA
S2 : n = 2,  = 1 }kjk fu:fir d{kd dh vkd`fr MEcsy (dumb-bell) gksrh gSA
S3 : X-v{k rFkk Y-v{k ij dxy d{kd esa bysDVªkWuksa ds ik;s tkus dh izkf;drk 'kwU; gksrh gSA
(A) FTF (B*) FTT (C) TFT (D) TFF
Sol. S1 : Photoelectric effect can be explained on the basis of particle nature of electromagnetic radiations.
S2 : n = 2,  = 1  2p-orbital  dumb-bell shaped.
S3 : dxy orbital has its lobes directed at an angle of 45º from X-axis and Y-axis. So, it has zero
probability of finding electrons along X-axis and Y-axis.
gy- S1 : izdk'koS|qr izHkko dks oS|qrpqEcdh; fofdj.kksa dh d.k izd`fr ds vk/kkj ij le>k;k tk ldrk gSA
S2 : n = 2,  = 1  2p-d{kd  vkd`fr = MEcsy (dumb-bell)
S3 : dxy d{kd dh ikfy;k¡ X-v{k rFkk Y-v{k ls 45º dks.k ij gksrh gSaA blfy,] X-v{k rFkk Y-v{k ij dxy d{kd esa
bysDVªkWuksa ds ik;s tkus dh izkf;drk 'kwU; gksrh gSA
2. For which of the following orbitals, the probability of finding the electrons along both X-axis and Y-axis
is non-zero.
fuEufyf[kr d{kdksa esa ls fdl d{kd ds fy, X–v{k rFkk Y-v{k nksuksa ds vuqfn'k bySDVªkWuksa ds ik;s tkus dh
izkf;drk (probability) v'kwU; gksrh gSA
(A) dxy (B*) dx2  y2 (C) pz (D) dzx
Sol. dx2 – y 2 orbital has its 4 lobes directed along X-axis and Y-axis.
dx 2 – y 2 d{kd] 4 ikyh;k¡ j[krk gS tks dh X-v{k rFkk Y-v{k ds vuqfn'k foU;kflr gksrs gSA
3. Which of the following sets of quantum numbers can be correct for an electron in 4f-orbital :
4f-d{kd ds ,d bysDVªkWu ds fy, pkjksa DokaVe la[;kvksa dk dkSulk lewg lgh gks ldrk gS %
1
(A) n = 4,  = 3, m = –2, s = 0 (B) n = 4,  = 3, m = +4, s = –
2
1 1
(C*) n = 4,  = 3, m = +1, s = + (D) n = 4,  = 2, m = –1, s = +
2 2
Sol. For n = 4,   4, for  = 3, m  4 n = 4 ds fy,,   4, for  = 3, m  4
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PAGE NO.-1
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4. If electronic configuration of B is written as 1s3 2s2. Which principle is violated during filling electrons?
(A) Aufbau principle
(B) Hund's maximum multiplicity rule
(C*) Pauli's exclusion principle
(D) Hund's maximum multiplicity rule and Pauli's exclusion principle
;fn B dk bySDVªkWfud foU;kl 1s3 2s2 fy[kk tk;s rks fuEu esa ls dkSuls fl)kUr dk mYya?ku bysDVªku Hkjus ds
nkSjku gqvk gS ?
(A) vkWQckÅ fl)kUr
(B) gq.M dh vf/kdre cgqdrk dk fu;e
(C*) ikÅyh dk viorZu fu;e
(D) gq.M dh vf/kdre cgqdrk dk fu;e vkSj ikÅyh dk viorZu fu;e
5. In the electronic configuration of Mn (Z = 25) :

(A) the number of electrons having n +  = 4 are 5.
(B*) the number of electrons having m = 0 are 13.
(C) the magnetic moment is 1.73 BM
(D) Mn belongs to IIIrd period and d-Block in Modern periodic table.
Mn (Z = 25) ds bysDVªkWfud foU;kl esa %
(A) n +  = 4 okys bysDVªkWuksa dh la[;k 5 gSA
(B*) tks bysDVªkWu m = 0 j[krs gSa] mudh la[;k 13 gSA
(C) pØ.k pqEcdh; vk?kw.kZ 1.73 BM gSA
(D) Mn, vk/kqfud vkorZ lkj.kh ds r`rh; vkorZ rFkk d-CykWd ls lEcfU/kr gSA
Sol. Mn - 1s2 2s2 2p6 3s2 3p6 3d5 4s2
m = 0 for all s-electron and two-p electron and one d-electron hence total = 13.
lHkh s-bysDVªkWu vkSj nks p-bysDVªkWu vkSj ,d d-bysDVªkWu ds fy;s m = 0 gS blfy, budh la[;k 13 gSA
6. Rearrange the following (I to IV) in the order of increasing masses:
I. 0.5 mole of O3
II. 0.5 g atom of oxygen
III. 3.011 × 1023 molecules of O2
IV. 5.6 litre of CO2 at STP
fuEu nzO;eku ds vkjksgh Øe esa (I ls IV dks) O;ofLFkr dhft, %
I. O3 ds 0.5 eksy
II. vkWDlhtu ds 0.5 xzke ijek.kq
III. O2 dk 3.011 × 1023 v.kq
IV. STP ij CO2 ds 5.6 yhVj
(A*) II < IV < III < I (B) II < I < IV < III (C) IV < II < III < I (D) I < II < III < IV
Sol. I. 0.5 mole O3 = 24 g O3 ; II. 0.5 g atom of oxygen = 8 g
3.011  1023 5.6
III. × 32 = 16 g O2 ; IV. × 44 g CO2 = 11 g CO2
6.022  10 23
22.4
gy- I. 0.5 eksy O3 = 24 g O3 ; II. vkWDlhtu dk 0.5 xzke ijek.kq = 8 g
3.011  1023 5.6
III. × 32 = 16 g O2 ; IV. × 44 g CO2 = 11 g CO2
6.022  10 23
22.4
7. If a sample of Ferric sulphate Fe2(SO4)3 contains 7.2 moles of O-atoms, then the number of S-atoms in
the given sample are :
;fn QSfjd lYQsV Fe2(SO4)3 dk ,d çkn'kZ 7.2 eksy O-ijek.kq j[krk gS] rks fn;s x;s çkn'kZ esa S-ijek.kqvksa dh
la[;k fuEu gS %
(A*) 1.8 NA (B) 0.9 NA (C) 3.6 NA (D) 3.1 NA
Sol. In Fe2(SO4)3 :
Moles of O– atoms : Moles of S– atoms = 12 : 3
3
Moles of S– atoms =  7.2 = 1.8
12
No. of S– atoms = 1.8 NA
PAGE NO.-2
gy- Fe2(SO4)3 esa
O– ijek.kqvksa ds eksy : S– ijek.kqvksa ds eksy = 12 : 3
3
S– ijek.kqvksa ds eksy =  7.2 = 1.8
12
S– ijek.kqvksa dh la[;k = 1.8 NA
8. A gas XH2 has molar mass 34 g/mol. What is the molar mass of XO3 (nearly) ?
(A) 64 g/mol (B) 82 g/mol (C*) 80 g/mol (D) cannot be found
XH2 xSl dk eksyj nzO;eku 34 g/mol gSA XO3 dk eksyj nzO;eku fdruk gksxk (yxHkx) ?
(A) 64 g/mol (B) 82 g/mol (C*) 80 g/mol (D) Kkr ugha fd;k tk ldrk gSA
Sol. 34 = MX + 2  MX = 32 g/mol
 MXO3 = 32 + 3 × 16 = 32 + 48 = 80 g/mol.
9. The respective ratio of weight of oxygen in samples of pure CuO and Cu 2O, if both samples contain the
same mass of copper, is :
(A) 1 : 2 (B) 1 : 1 (C*) 2 : 1 (D) none of these
'kq) CuO o Cu2O ds çkn'kZ esa vkWDlhtu ds Hkkj dk vuqikr D;k gksxk] ;fn nksuksa çkn'kZ] dkWij ds leku nzO;eku
;qDr gksa%
(A) 1 : 2 (B) 1 : 1 (C*) 2 : 1 (D) buesa ls dksbZ ugha
10 Find the relative density of SO3 gas with respect to methane:
feFksu ds lkis{k] SO3 dk vkisf{kd ?kuRo Kkr dhft, %
(A) 8 (B) 3.5 (C) 2.5 (D*) 5
MSO3 80
Sol. R.D. = = = 5..
MCH4 16
11 The density of air at STP is 0.0013 g mL–1. Its vapour density is :

(A) 0.01456 (B*) 14.56 (C) 1.456 (D) Data insufficient
STP ij ok;q dk ?kuRo 0.0013 g mL–1 gSA ok;q dk ok"i ?kuRo fuEu gksxk %
(A) 0.01456 (B*) 14.56 (C) 1.456 (D) vi;kZIr vk¡dM+s
Sol. –1
Molar mass of air at STP = 0.0013 g mL × 22400 mL = 29.12 g
so V.D. = 29.12 / 2 = 14.56
gy % STP ij ok;q dk eksyj nzO;eku = 0.0013 g mL–1 × 22400 mL = 29.12
vr % V.D. = 29.12 / 2 = 14.56
12 The atomic mass of a metal is 27 u. If its valency is 3, the vapour density of the volatile metal chloride
will be:
,d /kkrq dk ijek.kq Hkkj 27 u gS rFkk la;kstdrk 3 gSA bl /kkrq ds ok"i'khy DyksjkbM dk ok"i ?kuRo fuEu gksxk %
(A*) 66.75 (B) 321 (C) 267 (D) 80.25
Sol. Element must be Al
MAlCl3 133.5
Hence, volatile chloride will be AlCl3 so V.D. = = = 66.75
2 2
gy % Al rRo gksuk pkfg,
MAlCl3 133.5
AlCl3 ok"i'khy DyksjkbM gksuk pkfg, bflfy, V.D. = = = 66.75
2 2
13 Analysis of chlorophyll shows that it contains 2.64 percent magnesium. How many atoms of magnesium
does 1.00 g of chlorophyll contains?
DyksjksfQy dk fo'kys"k.k ;g n'kkZrk gS fd blesa 2.64 izfr'kr eSXuhf'k;e gksrk gSA DyksjksfQy ds 1.00 xzke esa
eSXuhf'k;e ds fdrus ijek.kq gksxs\
(A) 6.62  1023 (B) 6.62  1021 (C) 6.62  1024 (D*) 6.62  1020
2.64
Sol. Mass of Mg = 1  
100
PAGE NO.-3
2.64
Atoms of Mg = 100 NA = 11 10–4 NA= 6.62 1020
24
2.64
Sol. Mg dk nzO;eku = 1  
100
2.64
Mg ds ijek.kq = 100 NA = 11 10–4 NA= 6.62 1020
24
14 What mass percentage of oxygen is present in the compound CaCO 3 . 3Ca3(PO4)2?
;kSfxd CaCO3 . 3Ca3(PO4)2 esa vkWDlhtu dk æO;eku izfr'kr D;k gS \
(A) 23.3% (B) 45.36% (C*) 41.94% (D) 17.08%
16  27
Sol. % of O (O dk %)= × 100 = 41.94%
(100  3  310)
15 Compound have 1.15% sodium. What is the minimum molar weight (g/mol) of the compound?
;kSfxd esa 1.15% lksfM;e j[krk gSA ;kSfxd dk U;wure eksyj Hkkj (g/mol) D;k gksxk \
(A) 4200 (B) 3750 (C*) 2000 (D) 3000
16 0.1 mole of a carbohydrate with empirical formula CH2O contains 1 g of hydrogen. What can be its
molecular formula ?
ewykuqikrh lw=k CH2O ds lkFk ,d 0.1 eksy dkcksZgkbMªsV] 1 xzke gkbMªkstu;qDr gSA bldk v.kqlw=k D;k gks ldrk gS \
(A*) C5H10O5 (B) C6H12O6 (C) C3H6O3 (D) C4H10O4
Sol. 0.1 mole of carbohydrate with E.F. CH2O contains 1 g of hydrogen.
 1 mole of carbohydrate will contain hydrogen
= 10 g = 10 g atoms
In CH2O, g atomic ratio of C : H : O = 1 : 2 : 1.
 With 10 g atoms of H, g atoms of C combined = 5 and g atoms of O combined = 5. Hence,
actual formula (molecular formula) will be C5H10O5.
gy- eqykuqikrh lw=k CH2O ds lkFk 0.1 eksy dkcksZgkbMªsV] 1 g gkbMªkstu ;qDr gksaA
1 eksy dkcksg
Z kbMªsV 10 xzke gkbMªkstu = 10 xzke ijek.kq gkbMªkstu ;qDr gS
CH2O esa, C : H : O dk xzke ijek.oh; vuqikr = 1 : 2 : 1.
 H ds 10 xzke ijek.kq ds lkFk la;ksftr C ds xzke ijek.kq = 5 o O ds la;ksftr xzke ijek.kq = 5 vr% okLrfod
lw=k ¼v.kqlw=k½ C5H10O5 gSA
17. A compound contain equal masses of the elements X, Y and Z. If the atomic weights of X, Y and Z are
10, 20 and 30 respectively. The minimum molecular mass of compound is :
,d ;kSfxd] rRo X, Y o Z dk cjkcj nzO;eku j[krk gSA ;fn X, Y o Z dk ijek.kq Hkkj Øe'k% 10, 20 o 30 gS rc
;kSfxd dk U;wure v.kqHkkj D;k gksxk \
(A) 80 (B) 360 (C) 200 (D*) 180
Sol. X Y Z
W W W
W W W
10 20 30
W W W
30 30 30
3 1.5 1
6 3 2
Empirical formula (ewykuqikrh lw=k) X6Y3Z2
Minimum molecular mass of compound = 1[(10 × 6) + (3 × 20) + (2 × 30)] = 180 Ans.
;kSfxd dk U;wure v.kqHkkj = 1[(10 × 6) + (3 × 20) + (2 × 30)] = 180 Ans.
18. A gaseous organic compound has a density of 2.5 kg/m 3 at 2 atm and at 273ºC. The molecular formula
of the compound can be :
,d xSlh; dkcZfud ;kSfxd dk ?kuRo] 2 atm rFkk 273ºC rki ij 2.5 kg/m3 gSA ;kSfxd dk v.kqlw=k D;k gks ldrk
gS %
(A) C3H4O2 (B) C4H4 (C*) C3H4O (D) C4H10
PAGE NO.-4
PM 2  Mgas
Sol. d=  2.5 =  Mgas = 56
RT 0.082  546
 Options (C) is correct. ( (C) fodYi lgh gaSA½
P-CH EM ISTRY


EST INFORM AT IO
DPP

1. Course of the week as per plan : 2. Course covered till previous week :
3. Target of the current week : 4. DPP Syllabus :
DPP No. # B2 (JEE-ADVANCED)
Multiple choice objective ('–1' negative marking) Q.7 to Q.9 (4 marks, 2 min.) [12, 06]
Comprehension ('–1' negative marking) Q.10 to Q.11 (3 marks, 2 min.) [06, 04]
Integer type Questions ('–1' negative marking) Q.12 to Q.15 (4 marks, 3 min.) [16, 12]
Match the column (no negative marking) Q.16 (8 marks 6 min.) [08, 06]
ANSWER KEY
1. (A) 2. (A) 3. (A) 4. (A) 5. (D) 6. (B) 7. (ABC)
8. (AC) 9. (ABD) 10. (a) 2 (b) 4 (c) 3 (d) 2 (e) 3 (f) 2 (g) 6
11. (a) 5 (b) 3 (c) 2 (d) 5 (e) 7 (f) 4 (g) 3 12. 1 13. 5 14. 10
15. 24 16. (A)  p, s ; (B)  q, r ; (C)  p, s (D)  q, r
1. The density of water at 4°C is 1 × 103 kg m–3. Assuming no empty space to be present between water
molecules, the volume occupied by one molecule of water is approximately:
4°C ij ty dk ?kuRo 1 × 103 kg m–3 gSA ty ds v.kqvksa ds e/; dksbZ fjDr LFkku ugha ekurs gq,] ty ds ,d v.kq
}kjk ?ksjk x;k yxHkx vk;ru fuEu gS %
(A*) 3 × 10–23 mL (B) 6 × 10–23 mL (C) 3 × 10–22 mL (D) 6 × 10–22 mL
Sol. 1 × 103 kg/m3 = 1 g/mL. [Since, 1m3 = 106 cm3 = 106 mL].
= 1 g/cc
6.022 × 1023 H2O molecule weigh —————18 g
18
1 H2O molecule weigh ————— g = 3 × 10–23 g
6.022  1023
mass 3  10 –23 g
d= , So, volume = = 3 × 10–23 mL.
volume 1(g / mL)
gy % 1 × 103 kg/m3 = 1 g/mL. [Since, 1m3 = 106 cm3 = 106 mL].

= 1 g/cc
6.022 × 1023 H2O dk Hkkj —————18 g
18
1 H2O dk Hkkj ————— g = 3 × 10–23 g
6.022  1023
mass 3  10 –23 g
d= , blfy, vk;ru = = 3 × 10–23 mL.
volume 1(g / mL)
2. A sample of a compound contains 9.75 g Zn, 9 × 1022 atoms of Cr and 0.6 gram-atoms of O. What is
empirical formula of compound ? (Atomic Mass Zn = 65)
(A*) ZnCrO4 (B) ZnCr2O4 (C) Zn2CrO4 (D) None of these
PAGE NO.-5
,d ;kSfxd ds ,d uewus esa 9.75 xzke Zn, 9 × 1022 Cr ds ijek.kq rFkk O ds 0.6 xzke&ijek.kq gSaA ;kSfxd dk
ewykuqikrh lw=k Kkr djksA (ijek.oh; nzO;eku Zn = 65)
(A*) ZnCrO4 (B) ZnCr2O4 (C) Zn2CrO4 (D) buesa ls dksbZ ugha
9.81 9  1022
Sol. Mole of Zn = = 0.15 Mole of Cr = = 0.15 Mole of O = 0.6
65 6.023  1023
0.15 0.15 0.6
So, Simple ratio Zn = =1 Cr = =1 O= =4
0.15 0.15 0.15
So, ZnCrO4.
9.81 9  1022
Sol. Zn ds eksy = Cr ds eksy = O ds eksy = 0.6
65 6.023  1023
0.15 0.15 0.6
blfy, ljy vuqikr Zn = =1 Cr = =1 O= =4
0.15 0.15 0.15
blfy, ZnCrO4.
3. Assuming 100% yield of the reaction, how many moles of NaHCO 3 will produce 448 mL of CO2 gas at

STP according to the reaction: NaHCO3  Na2CO3 + CO2 + H2O (unbalanced)
vfHkfØ;k dh yfC/k 100% ekurs gq,] fuEu vfHkfØ;k ds vuqlkj STP ij NaHCO3 ds fdrus eksy ls 448 mL CO2

xSl mRikfnr gksxh % NaHCO3  Na2CO3 + CO2 + H2O (vlUrqfyr)
(A*) 0.04 (B) 0.4 (C) 4 (D) 40

Sol. 2NaHCO3  Na2CO3 + CO2 + H2O
448
Mole (eksy)
22400
2 × 0.02 = 0.02
= 0.04 mole
4. When Dinitrogen pentaoxide (N2O5, a white solid) is heated, it decomposes into nitrogen dioxide and
oxygen. If a sample of N2O5 produces 1.6 g O2, then how many grams of NO2 are formed?

N2O5(s)   NO2(g) + O2(g) (not balanced)
tc ukbVªkstu isUVkvkWDlkbM (N2O5), tks fd ,d lQsn Bksl gS] dks xeZ djrs gSa] rks ;g ukbVªkstu MkbvkWDlkbM
vkSj vkWDlhtu esa fo?kfVr gks tkrk gSA ;fn N2O5 ds uewus ls 1.6 xzke O2 dk mRiknu gksrk gS] rks fdrus xzke NO2
cusxh \

N2O5(s)   NO2(g) + O2(g) (vlarqfyr)
(A*) 9.2 g (B) 4.6 g (C) 2.3 g (D) 18.4 g
 1
Sol. N2O5(s)   2NO2(s) + O2 (Balanced reaction)
2
Mole of O2 Mole of NO2
=
1/ 2 2
1.6
× 2 × 2 = Mole of NO2 = 0.2
32
wt of NO2 = 0.2 × 46 = 9.2 g.
 1
gy % N2O5(s)   2NO2(s) + O2 (lUrqfyr vfHkfØ;k)
2
Mole of O2 Mole of NO2 1.6
=  × 2 × 2 = NO2 ds eksy = 0.2
1/ 2 2 32
NO2 dk Hkkj = 0.2 × 46 = 9.2 g.
PAGE NO.-6
5. Determine the empirical formula of Kevlar, used in making bullet proof vests, is 70.6% C, 4.2% H,
11.8% N and 13.4% O by mass.
dSYokj] tks cqysV izwQ osLVl~ (Bullet proof vests) cukus esa iz;qDr fd;k tkrk gSa] dk eqykuqikrh lw=k Kkr dhft,
rFkk blesa 70.6% C, 4.2% H, 11.8% N o 13.4% O ¼æO;eku izfr'kr½ gSaA
(A) C7H5NO2 (B) C7H5N2O (C) C7H9NO (D*) C7H5NO
6. 1 mole of an organic compound containing C, H and O on complete combustion produces 134.4 L of
CO2 gas at STP and 108 g H2O. Then, the molecular formula of organic compound could be:
,d dkcZfud ;kSfxd dk 1 eksy] tks C, H rFkk O j[krk gS] iw.kZ :i ls ngu ij STP ij 134.4 L CO2 o 108 g
H2O mRikfnr djrk gSA rc dkcZfud ;kSfxd dk v.kqlw=k fuEu gks ldrk gS %
(A) C6H6O6 (B*) C6H12O6 (C) C6H6O (D) C8H12O2
 y z y
Sol. CxHyOz +  x    O2 xCO2 + H2O
 4 2 2
134.4 108
1 mole
22.4 18
= 6 mole = 6 mole
From stoichiometry, x = 6 and y = 12
So, formula of organic compound = C6H12Oz.
However, the value of z cannot be predicted. So, possible formulae is C 6H12O6.
 y z y
Sol. CxHyOz +  x    O2 xCO2 + H2O
 4 2 2
134.4 108
1 eksy
22.4 18
= 6 eksy = 6 eksy
jllehdj.kferh ls, x = 6 rFkk y = 12
blfy,] dkcZfud ;kSfxd dk lw=k = C6H12Oz.
;|fi] z dk eku ugha crk;k tk ldrk gS] blfy, laHkkfor lw=k C6H12O6 gSA
7.* According to Bohr atomic model, the angular momentum of electron can have the value(s):
cksj ijek.kq izfr:i ds vuqlkj bysDVªkWu ds dks.kh; laosx ds eku gks ldrs gSA
h h h h
(A*) 0.5 (B*) (C*) (D) 2.5
  0.5  2 
8.* For a reaction :

aA + bB  cC + dD
If initially 'x' moles of 'A' are taken with 'y' moles of 'B', which of the following is/are correct :
a x a x
(A*) If = , then no reactant is left over (B) If > , then 'B' is limiting reagent
b y b y
a x x a
(C*) If < , then 'B' is limiting reagent (D) If > , then 'A' is limiting reagent.
b y y b
,d vfHkfØ;k aA + bB cC + dD ds fy, ;fn çkjEHk esa 'A' ds x eksy, 'B' ds y eksy ds lkFk fy;s tkrs gSa] rc
fuEu esa ls dkSulk lgh gS %
a x a x
(A*) ;fn = gks] rc dksbZ vfHkdeZd ugha cpsxkA (B) ;fn > ] rc 'B' lhekUr vfHkdeZd gksxkA
b y b y
a x x a
(C*) ;fn < ] rc 'B' lhekUr vfHkdeZd gksxkA (D) ;fn > ] rc 'A' lhekUr vfHkdeZd gksxkA
b y y b
9.* In a gaseous reaction of type :
xA(g) + yB(g)  pC(g) + qD(g)
where x, y, p and q are stoichiometric coefficients. Which of the following statements is/are correct :
(A*) At STP, x litre of A combine with y litre of B to give C and D
(B*) x mole of A combine with y mole of B to give C and D
(C) x g of A combine with y g of B to give C and D.
(D*) x molecules of A combine with y molecules of B to give C and D.
PAGE NO.-7
,d fuEu izdkj dh xSlh; vfHkfØ;k %
xA(g) + yB(g)  pC(g) + qD(g)
esa x, y, p rFkk q jllehdj.kferh; xq.kkad gSaA rc fuEu esa ls dkSulk@dkSuls dFku lgh gS@gSa :
(A*) STP ij A ds x yhVj] B ds y yhVj ds lkFk fØ;k djds C rFkk D nsrs gaSA
(B*) A ds x eksy] B ds y eksy ds lkFk fØ;k djds C rFkk D nsrs gSaA
(C) A ds x xzke, B ds y xzke ds lkFk fØ;k djds C rFkk D nsrs gSaA
(D*) A ds x v.kq] B ds y v.kqvksa ds lkFk fØ;k djds C rFkk D nsrs gSaA
Sol. According to stoichiometry of reaction option A, B and D are correct.
vfHkfØ;k dh jllfedj.kferh; ds vuqlkj fodYi A, B rFkk D lgh gSA
Comprehension vuqPNsn %&
Significant Figures
When we measure a physical quantity, generally the measured value does not come out to be
accurate. it may contain some error. When the measured value is expressed as a number, some digits
which it contains are known reliably plus the first digit which is unreliable.
for example, let us measure the length of a glass plate using a scale. Let this length lie somewehre
between 2.6 cm and 2.7 cm, and finally we write the length as 2.63 cm. Here digits 2 and 6 are reliable,
but digit 3 is unreliable. Now the reliable digits and first unreliable digit are known as significant figures
or significant digits. thus, the measurement 2.63 cm contains three significant figures.
These signifificant figures are desired when the observations of any experiment have to be recorded
and then to be used in calculations.
lkFkZd vad :
tc ge ,d HkkSfrd jkf'k dk ekiu djrs gS] lkekU;r% ekik x;k eku ;FkkFkZ ugh gksrk gSA blesa dqN =kqfV gks ldrh
gS tc ekis x;s eku dks vadksa esa fy[krs gS] dqN vad fo'oluh; rjhds ls izkIr ugh gksrs gS rFkk ftldk izFke vad
vfo'oluh; gksrk gSA
mnkgj.k ds fy, ekukfd iSekus ds mi;ksx ls dkap dh ifV~Vdk dh yEckbZ ekih tkrh gSA ekukfd yEckbZ 2.6 cm o
2.7 cm ds e/; fLFkr gS rFkk ge vfUre :i ls yEckbZ 2.63 cm. fy[k nsrs gSA ;gka vad 2 rFkk 6 fo'oluh; gS
ysfdu vad 3 vfo'oluh; gSA vc fo'oluh; vad rFkk izFke vfo'olhu; vad lkFkZd vad dgykrk gSA vr% 2.63
cm ds ekiu esa rhu lkFkZd vad gSA bu lkFkZd vadks dh vko';drk gksrh gSA tc fdlh iz;ksx esa ikB~;kad fy[kk
tkrk gS rFkk budk x.kuk esa mi;ksx fd;k tkrk gSA
Rules for Counting Significant figures : lkFkZd vad dh x.kuk ds fy, fu;e %
For a Number Greater than 1 1 ls cMh la[;k ds fy,
Rule 1. All non-zero digits are significant. There may be decimal point in between and the location of decimal
does not matter. Example :
(a) 2357 has four significant figures (b) 312 has three significant figures
(c) 325.23 has five significant figures (d) 23.523 has five significant figures.
fu;e 1. lHkh v'kwU; vad lkFkZd vad gksrs gSA muds e/; n'keyo gks ldrk gS rFkk n'keyo dh fLFkfr egRoiw.kZ ugh gSA
mnkgj.k %
(a) 2357 pkj lkFkZd vad gSA (b) 312 rhu lkFkZd vad gSA
(c) 325.23 ikap lkFkZd vad gSA (d) 23.523 ikap lkFkZd vad gSA
Rule 2. All zeros between two non-zero digits are significant. Location of decimal does not matter. Example
(a) 2307 has four significant figures (b) 320.03 has five significant figures
(c) 32.003 has five significant figures.
fu;e 2. nks v'kwU; vadks ds e/; vkus okys lHkh 'kwU; vad lkFkZd vad gksrs gSA n'keyo dh fLFkfr egRoiw.kZ ugh gSA mnkgj.k
(a) 2307 pkj lkFkZd vad gSA (b) 320.03 ikap lkFkZd vad gSA
(c) 32.003 ikap lkFkZd vad gSA
Rule 3. If the number is without decimal part, then the terminal of trailing zeros are not significant. Example :
(a) 23500 has three significant figures (b) 53000 has two significant figures
fu;e 3. ;fn la[;k fcuk n'keyo ds gS] rc la[;k ds lhekUr vfUre 'kwU; lkFkZd vad ugh gSA mnkgj.k
(a) 23500 rhu lkFkZd vad gSA (b) 53000 nks lkFkZd vad gSA
Rule 4. Trailing zeros in the decimal part are significant. Example :
(a) 3.700 has four significant figures (b) 2.50 has three significant figures
PAGE NO.-8
fu;e 4. n'keyo Hkkx esa lhekUr vfUre 'kwU; lkFkZd vad gksrs gSA mnkgj.k
(a) 3.700 pkj lkFkZd vad gSA (b) 2.50 rhu lkFkZd vad gSA
For a Number less than 1 1 ls NksVh la[;k ds fy,
Any zero to the right of a non-zero digit is significant , All zeros between decimal point and first non-
zero digit are not significant. Example :
v'kwU; vad ds nka;h vksj dksbZ Hkh 'kwU; lkFkZd vad gSA n'keyo fcUnq rFkk izFke v'kwU; vad ds e/; ds lHkh 'kwU;
lkFkZd vad ugh gSA mnkgj.k
(a) 0.0074 has two significant figures (a) 0.0074 nks lkFkZd vad gSA
(b) 0.00704 has three significant figures. (b) 0.00704 rhu lkFkZd vad gSA
(c) 0.007040 has four significant figures (c) 0.007040 pkj lkFkZd vad gSA
(d) 0.07040 has four significant figures (d) 0.07040 pkj lkFkZd vad gSA
Rule 5. There are certain measurement, which are exact i.e.
Number of apples are = 12 (exactly) = 12.000000........... 

This type of measurement is infinitely accurate so, it has  S.F.
* Numbers of students in class = 125 (exact)
* Speed of light in the vacuum = 299,792,458 m/s (exact)
fu;e 5.
;gka dqN fu'fpr ekiu fn;k gS tks fd iw.kZ gS vFkkZr~
lsoks dh la[;k = 12 (Bhd exact) = 12.000000........... 

bl rjg ds ekiu esa vuUr ;FkkZFkrk gksrh gSA vr% blesa  lkFkZd vad gksrs gSA
* d{kk esa fo|kfFkZ;ksa dh la[;k = 125 (Bhd exact)
* fuokZr esa izdk'k dh pky = 299,792,458 m/s (Bhd exact)
10. Write the number of significant figures in the following :

fuEu la[;ksa ds lkFkZd vad fyf[k;s %
(a) 0.053 (b) 50.00 (c) 0.0500 (d) 5.7 × 106
(e) 5.70 × 106 (f) 2400 (g) 0.0305090
Ans. (a) 2 (b) 4 (c) 3 (d) 2
(e) 3 (f) 2 (g) 6
11. Count total number of S.F. in

lkFkZd vadksa dh x.kuk dhft;sA
(a) 3.0800 (b) 0.00418 (c) 3500 (d) 300.00
(e) 5.003020 (f) 6.020 × 1023 (g) 1.60 × 10–19
Ans. (a) 5 (b) 3 (c) 2 (d) 5
(e) 7 (f) 4 (g) 3
Sol. (a) S.F. = Five , as trailing zeros after decimal place are significant.
(b) S.F. = Three, as leading zeros are not significant.
(c) S.F. = Two, the trailing zeros are not significant.
(d) S.F. = Five, trailing zeros after decimal point are significant.
(e) S.F. = Seven, the trailing zeros after decimal place are significant.
(f) S.F. = Four ; 6, 0, 2, 0 ; remaining 23 zeros are not significant.
(g) S.F. = Three ; 1, 6, 0 ; remaining 19 zeros are not significant.
12. A compound of Mg contains 6% Mg by mass. Minimum molar mass of the compound is n × 10 2 g/mol,
Caffeine has a molecular weight of 194. It contains about 30% by mass of nitrogen. The number of
atoms of nitrogen in one molecule of it is m. Give value of m/n
PAGE NO.-9
Mg dk ,d ;kSf xd Hkkj ls 6% Mg j[krk gSA ;fn ;kSf xd dk U;wu re eks yj nz O ;eku n × 10 2 g/mol gSA
dSQhu dk v.kqHkkj 194 gSA blesa Hkkj ds vuqlkj yxHkx 30% ukbVªkstu gSA blds ,d v.kq esa ukbVªkstu ds
ijek.kqvksa dh la[;k m gSA m/n dk eku nhft,A
Ans. 1
Sol. Let the molar mass of compound be 'M' ¼ekuk fd ;kSfxd dk eksyj nzO;eku 'M' gS)
M 6
Hence ¼blfy,½ = 24
100
M = 400 g /mole ¼eksy½
13. An oxide of Osmium (symbol Os) is pale yellow solid. If 2.794 g of the compound contains 2.09 g of
osmium, what is its empirical formula ? (At. wt. of Os = 190) Report your answer as (x+y) if the
empirical formula is OsxOy.
vksfLe;e (Os) dk ,d vkWDlkbM gYdk ihyk Bksl gSA ;fn 2.794 xzke ;kSfxd esa 2.09 xzke vksfLe;e mifLFkr gS] rks
bldk ewykuqikrh lw=k D;k gksxk \ (Os dk ijek.kq Hkkj = 190) viuk mRrj (x+y) ds :i esa nsa] ;fn ewykuqikrh lw=k
OsxOy gSA
Ans. 5
Sol. wt. of compound = 2.794 g
wt. of osmium = 2.09 g
wt. of oxygen = 2.794 – 2.09 = 0.704 g
2.09 0.704
Mole of osmium = = 0.011 and mole of oxygen = = 0.044
190 16
0.011
So relative mole of osmium = =1
0.011
0.044
& relative mole of oxygen = =4
0.011
so, empirical formula = OsO4 .
gy % ;kSfxd dk Hkkj = 2.794 g
Os dk Hkkj = 2.09 g
vkWDlhtu dk Hkkj = 2.794 – 2.09 = 0.704 g
2.09 0.704
Os ds eksy = = 0.011 vkSj vkWDlhtu ds eksy = = 0.044
190 16
0.011
Os ds vkisf{kd eksy = =1
0.011
0.044
rFkk vkWDlhtu ds vkisf{kd eksy = =4
0.011
blfy, ewykuqikrh lw=k = OsO4 .
14. The hydrated salt Na2CO3.xH2O undergoes 63% loss in mass on heating and becomes
anhydrous.Calculate the value of x.
futZy yo.k Na2CO3.xH2O esa xeZ djus ij 63% ál gksrk gSa rFkk vuknzZ gks tkrk gSaA x dk eku Kkr djksA
Ans. 10
Sol. Na2CO3 . xH2O (s)  Na2CO3 (s) + xH2O (g).
Let 100 g of Na2CO3 . xH2O be present
100
 mole of H2O formed ;
106  18x
100
63 = (18)
106  18x
6678 + 1134 x = 1800 x
666 x = 6678
x  10
gy- Na2CO3 . xH2O (s) Na2CO3 (s) + xH2O (g).
100
ekuk Na2CO3 . xH2O ds 100 g mifLFkr gSa
106  18x
 H2O ds eksy curs gSa ;
PAGE NO.-10
100
63 = (18)
106  18x
6678 + 1134 x = 1800 x
666 x = 6678  x  10
15. 1 g sample of alkaline earth metal react completely with 4.08 g H2SO4 and yield an ionic product MSO4.
Then find out the atomic mass of Alkaline earth metal (M)?
,d {kkjh; e`nk /kkrq dk 1 xzke çkn'kZ 4.08 xzke H2SO4 ds lkFk iw.kZr% vfHkd`r gksrk gS rFkk ,d vk;fud mRikn
MSO4 cukrk gS rc {kkjh; e`nk /kkrq M dk ijek.kq nzO;eku crkb;sa \
Ans. 24
Sol. M + H2SO4  MSO4 + H2
mole of M Mole of H2SO4
=
1 1
1 4.08 98
=  a= = 24.01
a 98 4.08
This is atomic weight of M (M dk ijek.kq nzO;eku) = 24.
16. Match the column
Column I LrEHk I Column II LrEHk II
(A) Velocity(osx) (p) <
(B) Ionisation power (vk;uu {kerk) (q)  > 
(C) Penetrating power (Hksnu {kerk) (r)  < 
(D) mass (nzO;eku) (s)  > 

Ans. (A)  p, s ; (B)  q, r ; (C)  p, s (D)  q, r
P-CH EM ISTRY


EST INFORM AT IO
DPP

ChemINFO : 4 Questions ('–1' negative marking) Q.17 to Q.20 (4 marks, 2 min.) [16, 08]
ANSWER KEY
1. (C) 2. (C) 3. (B) 4. (B) 5. (B) 6. (C) 7. (A)
8. (A) 9. (B) 10. (A) 11. (B) 12. (B) 13. (B) 14. (B)
15. (D) 16. (C) 17. (D) 18. (B) 19. (A) 20. (D)
1. Photoelectron emission is observed for three different metals A, B and C. The kinetic energy of the
fastest photoelectrons versus frequency of incident radiations  is plotted for each metal. Which of the
following graph shows the phenomenon most correctly :
rhu fofHkUu /kkrqvksa A, B rFkk C ds fy, QksVksbysDVªkWu mRltZu izsf{kr fd;k x;k gSA izR;sd /kkrq ds fy, vf/kdre
xfr okys QksVksbysDVªkWuksa dh xfrt ÅtkZ ,oe~ vkifrr fofdj.kksa dh vko`fÙk  ds e/; xzkQ [khapk x;k gSA fuEu esa ls
dkSulk xzkQ izØe dks lgh ls n'kkZrk gS %
PAGE NO.-11
(A) (B) (C*) (D)
Sol. K.E. of photoelectrons increases with increase in frequency of incident radiation. The graph for three
metals A, B and C will be parallel to each other. K.E. = h – 
 QksVksbySDVªkWuksa dh xfrt ÅtkZ vkifrr fofdj.kksa dh vko`fÙk c<+kus ij c<+rh gSA vr% /kkrq A, B rFkk C ds vkjs[k
lekukUrj gksxsaA K.E. = h – 
2. Which particle must have been produced in the following processes respectively:
(I) 7N14 + 2He4  8O17 + .... (II) 79Au198  80Hg198 + ....
(III) 12Mg24 + 2He4  14Si27 + .... (IV) 11Na23  10Ne23 + ....
(A) Proton, Positron, Neutron, -particle (B) Positron, -particle, Neutron, Proton
(C*) Proton, -particle, Neutron, Positron (D) Positron, Neutron, -particle, Proton
fuEufyf[kr çØeksa esa Øe'k% dkSuls d.k mRikfnr gksus pkfg, %
(I) 7N14 + 2He4  8O17 + .... (II) 79Au198  80Hg198 + ....
(III) 12Mg24 + 2He4  14Si27 + .... (IV) 11Na23  10Ne23 + ....
(A) çksVkWu, ikWthVªkWu, U;wVªkWu, -d.k (B) ikWthVªkWu, -d.k, U;wVªkWu, çksVkWu
(C*) çksVkWu, -d.k, U;wVªkWu, ikWthVªkWu (D) ikWthVªkWu, U;wVªkWu, -d.k, çksVkWu
Sol. (I) 7N14 + 2He4  8O17 + 1H1 (II) 79Au198  80Hg198 + –1e0
(III) 12Mg24 + 2He4  14Si27 + 0n1 (IV) 11Na23  10Ne23 + +1e0
3. Compounds of boron with hydrogen are called boranes. One of these boranes has the empirical
formula BH3 and a molecular weight of 28 amu. What is its atomicity :
cksjkWu rFkk gkbMªkstu ls feydj cus ;kSfxd cksjsUk dgykrs gSaA buesa ls ,d cksjsu dk ewykuqikrh lw=k BH3 gS vkSj
bldk vkf.od nzO;eku 28 amu gSA bldh ijek.kqdrk D;k gksxh %
(A) 12 (B*) 8 (C) 6 (D) 4
Sol. Molecular mass = n (empirical mass)
v.kqHkkj ¾ n ¼ewykuqikrh Hkkj½
28
n= =2
14
Molecular formula = n (empirical formula) = 2 (BH3) = B2H6.
v.kql=k ¾ n (ewykuqikrh lw=k½ = 2 (BH3) = B2H6.
4. Given the numbers : 161cm, 0.161cm, 0.0161 cm. The number of significant figures for the three
numbers are
(A) 3, 4 and 5 respectively (B*) 3, 3 and 3 respectively
(C) 3, 3 and 4 respectively (D) 3, 4 and 4 respectively
nh xbZ rhuksa la[;kvksa 161 cm, 0.161 cm, 0.0161 cm ds fy;s lkFkZd vad Øe'k% gS &
(A) Øe'k% 3, 4 o 5 (B) Øe'k% 3, 3 o 3 (C) Øe'k% 3, 3 o 4 (D) Øe'k% 3, 4 o 4
5. A semiconductor YBa2Cu3O7 is prepared by a reaction involving Y2O3, BaO2 and Cu2O. The mole ratio
in which these compounds should combine, is :
,d v)Zpkyd YBa2Cu3O7 dks Y2O3, BaO2 rFkk Cu2O ls lEcfU/kr ,d vfHkfØ;k }kjk cuk;k tkrk gSA eksy
vuqikr ftlesa] bu ;kSfxdksa dks la;ksftr fd;k tkrk gS] fuEu gS%
(A) 1 : 2 : 4 (B*) 1 : 4 : 3 (C) 1 : 2 : 3 (D) 1 : 3 : 4
Sol. Y2O3  4BaO2  3Cu2O 
 2YBa2Cu3O7
Mole ratio  1 : 4 : 3.
eksy vuqikr  1 : 4 : 3.
6. Butane, C4H10, burns with the oxygen in air to give carbon dioxide and water.
What is the amount (in moles) of carbon dioxide produced from 0.15 mole C 4H10 ?
C4H10(g) + O2(g) CO2(g) + H2O(g) (not balanced)
(A) 0.0375 (B) 0.15 (C*) 0.6 (D) None of these
PAGE NO.-12
C;wVsu (C4H10) ok;q dh mifLFkfr esa vkWDlhtu ds lkFk tydj dkcZu MkbZvkWDlkbM vkSj ty cukrk gSA C4H10 ds
0.15 eksy ls dkcZuMkbZvkWDlkbM dh fdruh ek=kk ¼eksy esa½ dk mRiknu gksxk %
13
C4H10(g) + O2(g) CO2(g) + H2O(g) (vlarqfyr)
2
(A) 0.0375 (B) 0.15 (C*) 0.6 (D) buesa ls dksbZ ugh
Sol. On balancing the reaction,
C4H10 + 13 O2  4CO2 + 5H2O
2
Mole of C4H10 Mole of CO2
=
1 4 1
Hence mole of CO2 = 4 × mole of C4H10 = 4 × 0.15 = 0.60
gy % vfHkfØ;k dks lUrqfyr djus ij
13
C4H10 + O2  4CO2 + 5H2O
2
Mole of C4H10 Mole of CO2
=
1 4 1
blfy, CO2 ds eksy = 4 × C4H10 ds eksy = 4 × 0.15 = 0.60
7. When oxygen gas is passed through Siemen's ozoniser, it completely gets converted into ozone gas.
The volume of ozone gas produced at STP, if initally 96 g of oxygen gas was taken, is :
tc lkbeu vkst+ksukblj esa ls vkWDlhtu xSl dks izokfgr fd;k tkrk gS] rks ;g iw.kZ :i ls vkst+ks u xSl esa ifjofrZr
gks tkrh gSA STP ij mRikfnr vkst+ksu xSl dk vk;ru D;k gksxk] ;fn izkjEHk esa 96 xzke vkWDlhtu xSl dks fy;k
x;k gks %
(A*) 44.8 L (B) 89.6 L (C) 67.2 L (D) 22.4 L
Sol. 3O2  2O3
96
Mole = =3 mole = 2
32
 Volume of O3 gas at STP = 2 × 22.4 = 44.8 L
gy 3 O2  2 O3
96
eksy = =3 eksy = 2
32
 STP ij O3 xSl dk vk;ru = 2 × 22.4 = 44.8 L
8. Zinc and hydrochloric acid react according to the reaction :
Zn(s) + 2HCl(aq.) ZnCl2(aq.) + H2(g)
If 0.3 mole of Zn are added to hydrochloric acid containing 0.52 mole HCl, how many moles of H 2 are
produced:
ftad vkSj gkbMªksDyksfjd vEy dh fØ;k fuEu vfHkfØ;k ds vuqlkj gksrh gS %
Zn(s) + 2HCl(aq.) ZnCl2(aq.) + H2(g)
;fn 0.52 eksy HCl ;qDr gkbMªksDyksfjd vEy esa Zn ds 0.3 eksy dks feyk fn;k tk;s] rks H2 ds fdrus eksy cusaxs %
(A*) 0.26 (B) 0.52 (C) 0.14 (D) 0.3
Mole of HCl 0.52
Sol. LR  HCl, so Mole of H2 = = = 0.26
2 2
HCl ds eksy 0.52
LR  HCl, blfy, H2 ds eksy = = = 0.26
2 2
9. If a solution containing 0.5 mole of BaCl2 is mixed with another solution containing 0.1 mole of Na 3PO4,
the maximum number of mole of Ba3(PO4)2 that can be formed is :
(A) 0.166 (B*) 0.05 (C) 0.6 (D) 0.1
;fn BaCl2 ds 0.5 eksy ;qDr ,d foy;u dks Na3PO4 ds 0.1 eksy ;qDr ,d vU; foy;u ds lkFk fefJr fd;k
x;k] rks cuus okys Ba3(PO4)2 ds vf/kdre eksyksa dh la[;k fuEu gS :
(A) 0.166 (B*) 0.05 (C) 0.6 (D) 0.1
Sol. 3BaCl2 + 2Na3PO4  Ba3(PO4)2 + 6 NaCl
mole 0.5 0.1
PAGE NO.-13
0.5 0.1
(L.R is Na3PO4)
3 2
Now from mole– mole analysis vc eksy&eksy fo'ys"k.k ls
mole of Na3PO4 mole of Ba3 PO4 2
=
2 1
0.1
= = mole of Ba3(PO4)2 Ba3(PO4)2 ds eksy
2
 mole of Ba3(PO4)2 = 0.05 mol. Ba3(PO4)2 ds eksy = 0.05 mol.
10. If the percentage yield of given reaction is 30%, how many total moles of the gases will be produced, if
8 moles of NaNO3 are taken initially :

NaNO3 (s)  Na2O(s) + N2 (g) + O2(g) (unbalanced)
(A*) 4.2 mole (B) 2.4 mole (C) 4.8 mole (D) 2.1 mole
;fn uhps nh xbZ vfHkfØ;k dh izfr'kr yfC/k 30% gks] rks xSl ds dqy fdrus eksy mRikfnr gksaxs] ;fn 8 eksy
NaNO3 izkjEHk esa fy, tkrs gksa %

NaNO3 (s)  Na2O(s) + N2 (g) + O2(g) (vlUrqfyr)
(A*) 4.2 eksy (B) 2.4 eksy (C) 4.8 eksy (D) 2.1 eksy

Sol. 4NaNO3 (s)  2Na2O(s) + 2N2 (g) + 5O2(g)
Mole 8
30  8  7
× 
 4 
So, total gas moles produced = = 4.2 mole
100

gy 4NaNO3 (s)  2Na2O(s) + 2N2 (g) + 5O2(g)
eksy 8
30  8  7
blfy,] xSl ds dqy mRikfnr eksy = ×  = 4.2 eksy
100  4 
11. From the following reaction sequence :
Cl2 + 2KOH  KCl + KClO + H2O
3KClO  2KCl + KClO3
4KClO3  3KClO4 + KCl
Calculate the mass of chlorine needed to produce 138.5 g of KClO 4 :
(A) 142 g (B*) 284 g (C) 432 g (D) None of these
fuEu vfHkfØ;k Øe ls %
Cl2 + 2KOH  KCl + KClO + H2O
3KClO  2KCl + KClO3
4KClO3  3KClO4 + KCl
KClO4 ds 138.5 xzke ds mRiknu ds fy;s vko';d Dyksjhu ds nzO;eku dh x.kuk djks %
(A) 142 xzke (B*) 284 xzke (C) 432 xzke (D) buesa ls dksbZ ugha
Mole of KClO4 Mole of KClO3
Sol. =
3 4
138.5 4
Mole of KClO3 = 4 =
138.5 / 3 3
4
Mole of KClO = ×3=4
3
Mole of KClO = Mole of Cl2 = 4
Mass of Cl2 = 4 × 71 = 284 g.
PAGE NO.-14
KClO4 ds eksy KClO3 ds eksy
Sol. =
3 4
138.5 4
KClO3 ds eksy = 4 =
138.5 / 3 3
4
KClO ds eksy = ×3=4
3
KClO ds eksy= Cl2 ds eksy = 4
Cl2 Hkkj = 4 × 71 = 284 g.
12. 3L of N2 gas are mixed with 6L of H2 gas to form NH3 gas. What volume of NH3 gas can be produced if
all volumes are measured under same temperature and pressure conditions:
3L, N2 xSl dks 6L, H2 xSl ds lkFk] NH3 fuekZ.k ds fy, fefJr fd;k x;kA ;fn lHkh vk;ru leku rki o nkc ij
fy;s x;s gSa] rks NH3 dk fdruk vk;ru çkIr gksxk %
(A) 6L (B*) 4L (C) 9L (D) 2L
Sol. N2 (g) + 3H2 (g)  2NH3 (g)
Vol. 3 6 ( V  n)
62
L.R. = 4 L.
3
13. Calculate the volume in litre of 0.1 M solution of HCl which contains 0.365 g HCl?
0.1 M HCl foy;u dk vk;ru ¼yhVj esa½ Kkr djks] ftlesa HCl dk nzO;eku 0.365 g gS \
(A) 10–2 L (B*) 0.1 L (C) 1 L (D) 10 L
No.of moles 0.365 / 36.5
Sol. Volume = = = 0.1
Molarity 0.1
14. What volume of a 0.8 M solution contains 100 millimoles of the solute?
,d 0.8 M foy;u] tks foys; ds 100 feyheksy ;qDr gS] dk vk;ru D;k gS \
(A) 80 mL (B*) 125 mL (C) 125 L (D) 80 L
nsolute
Sol. M=
Vsolution
0.8 100  10 3
=
1000 vol. of solution
vol. of solution = 125 ml
(Here nsolute = mole of solute, Vsolution = vol. of solution).
15. Calculate the molarity when :

(a) 4.9 g H2SO4 acid dissolved in water to result 500 mL solution.
(b) 2 gram-molecules of KOH dissolved in water to result 500 mL solution.
(A) (a) 0.1 M (b) 0.07 M (B) (a) 0.4 M (b) 4 M
(C) (a) 0.4 M (b) 0.07 M (D*) (a) 0.1 M (b) 4 M
eksyjrk dh x.kuk djks tc %
(a) 4.9 xzke H2SO4 vEy] ty esa foys; gksdj 500 mL ifj.kkeh foy;u cuk;sA
(b) KOH ds 2 xzke&v.kq] ty esa foys; gksdj 500 mL ifj.kkeh foy;u cuk;saA
(A) (a) 0.1 M (b) 0.07 M (B) (a) 0.4 M (b) 4 M
(C) (a) 0.4 M (b) 0.07 M (D*) (a) 0.1 M (b) 4 M
4.9
Sol. (a) M = 98 = 0.1 M
500
1000
2 mole
(b) M = × 1000 = 4 M.
500
16. Find the mass of solute and solvent in 100mL,1 M NaOH solution having density 1.5 g/mL.
(A) 40 g, 110 g (B) 4 g, 150 g (C*) 4 g, 146 g (D) 40 g, 150 g
PAGE NO.-15
1 M NaOH ds 100 mL foy;u dk ?kuRo 1.5 g/mL gSA blesa foys; vkSj foyk;d dk nzO;eku crkvksA
(A) 40 xzke, 110 xzke (B) 4 xzke, 150 xzke (C*) 4 xzke, 146 xzke (D) 40 xzke, 150 xzke
Sol. Mole of NaOH = molarity × volume () = 1 × 0.1 = 0.1
mass of NaOH = 0.1 × 40 = 4 g
mass of solution = volume × density = 100 × 1.5 = 150 g
Hence : mass of solvent = 150 – 4 = 146 g.
NaOH ds eksy = eksyjrk × vk;ru () = 1 × 0.1 = 0.1
NaOH dk nzO;eku = 0.1 × 40 = 4 g
foy;u dk nzO;eku = vk;ru × ?kuRo = 100 × 1.5 = 150 g
vr% : foyk;d dk nzO;eku = 150 – 4 = 146 g.
ChemINFO Estimation of Sulphur

Daily Self-Study Dosage for mastering Chemistry Elemental analysis of Sulphur
Estimation of Sulphur : Sulphur is estimated by Carius method.
Principle : When an organic compound containing sulphur is heated with fuming nitric acid, sulphur is oxidised
to sulphuric acid. This is precipitated as barium sulphate by adding barium chloride solution. From the amount
of barium sulphate, percentage of sulphur can be calculated.
Calculations : Mass of organic compound = W g
Mass of barium sulphate = W1g
BaSO4  S
233 g 32 g
233 g of barium sulphate contains sulphur = 32 g
32
W 1g of barium sulphate contains sulphur =  W1g
233
32 W1
Percentage of sulphur =   100
233 W
ChemINFO Estimation of Sulphur

Daily Self-Study Dosage for mastering Chemistry Elemental analysis of Sulphur
lYQj dk fu/kkZj.k % lYQj dk fu/kkZj.k dSfj;l fof/k }kjk fd;k tk ldrk gSA
fl)kUr % tc lYQj ;qDr ,d dkcZfud ;kSfxdks dks l/kqe ukbfVªd vEy ds lkFk xeZ fd;k tkrk gS rks lYQj] lYQ;wfjd
vEy esa vkWDlhd`r gks tkrk gSA blesa csfj;e DyksjkbM foy;u feykus ij csfj;e lYQsV ds :i esa vo{ksfir gks tkrk gSA
csfj;e lYQsV dh ek=kk ls lYQj dh izfr'krrk dh x.kuk dh tk ldrh gSA
x.kuk % dkcZfud inkFkZ dk nzO;eku = W xzke
csfj;e lYQsV dk nzO;eku = W1xzke
BaSO4  S
233 xzke 32 xzke
233 xzke csfj;e lYQsV dk nzO;eku = 32 xzke
32
W 1 xzke csfj;e lYQsV dk nzO;eku =  W1 xzke
233
32 W1
lYQj dh izfr'krrk =   100
233 W
Memorize this theory as soon as you get the DPP. Revise it regularly and master this concept by practice.
17. Percentage of sulphur in organic compound can be determined by this method :
(A) Liebig's method (B) Duma's method (C) Kjeldahl's method (D*) Carius method
dkcZfud ;kSfxd esa lYQj dh izfr'krrk dk fu/kkZj.k fuEu fof/k }kjk fd;k tkrk gS &
(A) fyfcax fof/k (B) M~;wek fof/k (C) tsYMky fof/k (D*) dSfj;l fof/k
PAGE NO.-16
18. In carius method for the estimation of sulphur, the formula used is
16 Massof bariumsulphate
(A) Percentage of S =   100
233 Massof organic compound
32 Massof bariumsulphate
(B*) Percentage of S =   100
233 Massof organic compound
32 Mass of organic compound
(C) Percentage of S =   100
233 Mass of barium sulphate
233 Massof organic sulphate
(D) Percentage of S =   100
32 Massof bariumcompound
lYQj ds fu/kkZj.k ds fy, dSfj;l fof/k esa mi;ksxh lw=k gS &
(A) lYQj dh izfr'krrk = 16  csfj;e lYQsV dk nzO;eku  100
233 dkcZfud ; kSfxd dk nzO; eku
32 csfj;e lYQsV dk nzO;eku
(B*) lYQj dh izfr'krrk =   100
(C) lYQj dh izfr'krrk =   100
(D) lYQj dh izfr'krrk =   100
19. 0.2595 g of an organic compound in a qualitative analysis yielded 0.35 of the barium sulphate. The
percentage of sulphur in the substance is :
(A*) 18.52 (B) 26.52% (C) 17.5 (D) 32.2
csfj;e lYQsV ds 0.35 ls xq.kkRed fo'kys"k.k esa ,d dkcZfud ;kSfxd 0.2595 xzke izkIr gksrk gSA rks inkFkZ esa lYQj
dh izfr'krrk gksxh &
(A*) 18.52 (B) 26.52% (C) 17.5 (D) 32.2
32 wt. of BaSO4 32 0.35
Sol. % of S    100    100 = 18.52%
233 wt. of organic compound 233 0.2595
20. On heating 0.32 of an organic compound with concentrated nitric acid and barium chloride, 0.932 g
barium sulphate was obtained. Calculate the percentage of sulphur in the given compound.
(A) 10 % (B) 20 % (C) 30 % (D*) 40 %
0.32 xzke dkcZfud ;kSfxd dks lkUnz ukbfVªd vEy vkSj csfj;e DyksjkbM ds lkFk xeZ djus ij 0.932 xzke csfj;e
lYQsV izkIr gqvkA fn;s x;s ;kSfxd esa lYQj dh izfr'krrk gS %
(A) 10 % (B) 20 % (C) 30 % (D*) 40 %
Sol. Mass of organic compound, W = 0.32 g
Mass of barium sulphate, W1 = 0.932 g
BaSO4  S
233g 32g
32 W 32 0.932
Percentage of sulphur = × 1 × 100 =   100 = 40%
233 W 233 0.32
Sol. dkcZfud ;kSfxd dk nzO;eku W = 0.32 xzke
csfj;e lYQsV dk nzO;eku W1 = 0.932 xzke
BaSO4  S
233 xzke 32 xzke
32 W 32 0.932
lYQj dh izfr'krrk = × 1 × 100 =   100 = 40%
233 W 233 0.32
PAGE NO.-17
P-CH EM ISTRY


EST INFORM AT IO
DPP

4. DPP Syllabus :
Comprehension ('–1' negative marking) Q.8 to Q.10 and Q.11 (a) & (b) (3 marks, 2 min.) [15, 10]
Single Integer type Questions ('–1' negative marking) Q.12 to Q.15 (4 marks 3 min.) [16, 12]
ANSWER KEY
1. (C) 2. (D) 3. (C) 4. (A) 5. (ABC) 6. (ABC) 7. (ACD)
8. (D) 9. (A) 10. (C) 11(a). (a) 0.059 (b) 0.058 (c) 5.1 × 106 (d) 5.0 × 106
11(b). (i) 0.0393 kg (ii) 4.08 x 108sec (iii) 5.24 m (iv) 4.74 × 10–6 kg 12. 5 13. 4
14. 3 15. 21
1. Light of wavelength  falls on metal having work function hc/0. Photoelectric effect will take place only if :
dk;Z Qyu hc/0 okyh /kkrq ij  rjax-nS/;Z dk izdk'k vkifrr gksrk gSA izdk'k fo|qr izHkko dsoy rc mRiUu gksxk] tc %
(A)   0 (B)   20 (C*)   0 (D)   0/2
Sol. For photoelectric effect to take place, Elight  W 
hc hc
  or   0 .
 0
gy % izdk'k oS|qrh; izHkko ?kfVr gksrk gS] Elight  W  
hc hc
  or   0 .
 0
2. The orbital angular momentum of an electron corresponding to n = 4 and m = –3 is :
n = 4 rFkk m = –3 ls lEcfU/kr bysDVªkWu dk d{kh; dks.kh; laosx D;k gS :
h 6h 3h
(A) 0 (B) (C) (D*)
2 2 
Sol. n = 4, m = – 3
 only possible value of  is 3.
2 3h 3h
 Orbital angular momentum = (  1) = = .
2 
gy- n = 4, m = – 3
  dk dsoy lEHkkfor eku 3 gSA
2 3h 3h
 d{kh; dks.kh; laosx = (  1) = =
2 
3. Manganese achieves its maximum oxidation state in which of these compounds:
eSaXuht] fuEu esa ls fdl ;kSfxd esa viuh vf/kdre vkWDlhdj.k voLFkk dks izkIr djrk gS %
(A) MnO2 (B) Mn3O4 (C*) KMnO4 (D) K2MnO4
( 7) (  6) ( 4) 8/3
Sol. KMnO4 > K 2MnO4 > MnO2 > Mn3O 4
PAGE NO.-18
4. The oxidation number of sulphur in S8, S2F2, H2S and H2SO4 respectively are :
(A*) 0, +1, –2 and 6 (B) +2, 0, +2 and 6 (C) 0, +1, +2 and 4 (D) –2, 0, +2 and 6
S8, S2F2, H2S o H2SO4 es lYQj dh vkWDlhdj.k la[;k Øe'k% fuEu gSaA
(A*) 0, +1, –2 rFkk 6 (B) +2, 0, +2 rFkk 6 (C) 0, +1, +2 rFkk 4 (D) –2, 0, +2 rFkk 6
5.* For a mixture of 100 mL of 0.3 M CaCl2 solution and 400 mL of 0.1 M HCl solution, select the correct
options:
(A*) Total concentration of cations = 0.14 M (B*) [Cl–] = 0.2 M
(C*) Moles of Ca2+ in mixture = 0.03 (D) None of these
0.3 M CaCl2 foy;u ds 100 mL rFkk 0.1 M HCl foy;u dk 400 mL ds feJ.k ds fy, fuEu esa ls lgh fodYi
dk p;u dhft, %
(A*) /kuk;uksa dh dqy lkUnzrk = 0.14 M (B*) [Cl–] = 0.2 M
(C*) feJ.k esa Ca2+ ds eksy = 0.03 (D*) buesa ls dksbZ ugha
M V  M2 V2 0.2  100  0.1  400 0.6
Sol. Molarity of cation = 1 1 = = = 0.12 M
V1  V2 500 5
3(0.2)100  0.1  400 0.6  0.4
Molarity of Cl— = = = 0.2 M.
500 5
6.* Which statement(s) is/are correct :
(A*) Oxidation number of oxygen is –2 in most of its compounds.
(B*) Oxidation number of oxygen is +2 in Oxygen difluoride.
1
(C*) Oxidation number of oxygen is – in superoxides.
2
(D) Oxidation number of oxygen is +1 in peroxides.
fuEu esa ls dkSulk@dkSuls dFku lgh gS@gSa %
(A*) vkWDlhtu ds vf/kdrj ;kSfxdksa esa vkWDlhtu dh vkWDlhdj.k la[;k –2 gksrh gSA
(B*) vkWDlhtu Mkb¶yksjkbM esa vkWDlhtu dh vkWDlhdj.k la[;k +2 gksrh gSA
(C*) lqijvkWDlkbM esa vkWDlhtu dh vkWDlhdj.k la[;k – 1 gksrh gSA
2
(D) ijvkWDlkbMksa esa vkWDlhtu dh vkWDlhdj.k la[;k +1 gksrh gSA
Sol. Oxidation number of oxygen is (–1) in peroxide.
7.* Identify the incorrect statement(s) :

(A*) Halogens always have –1 oxidation state in their compounds.
(B) Oxidation number can be zero, negative, positive, integer or fractional.
(C*) In OF2, the oxidation number of F is +1.
(D*) Hydrogen always has + 1 oxidation number in its compounds.
fuEu esa ls dkSulk@dkSuls dFku lgh ugh gS@gSa %
(A*) vius ;kSfxdksa esa gSykstu] lnSo –1 vkWDlhdj.k voLFkk izkIr djrs gSaA
(B) vkWDlhdj.k vad 'kwU;] _.kkRed] /kukRed] iwa.kkZd vFkok fHkUuked la[;k gks ldrk gSA
(C*) OF2 esa ¶yksjhu dk vkWDlhdj.k vad +1 gSA
(D*) vius ;kSfxdksa esa gkbMªkstu lnSo +1 vkWDlhdj.k voLFkk izkIr djrk gSA
Comprehension # 1
Read the following passage carefully and answer the questions (8 to 10).
Iodine is an important substance needed by the body of a human being. We consume it in the form of
salt, which has very-very small % content of iodine. Iodine has various industrial applications also. The
following process has been used to obtain iodine from oil-field brines in California :
NaI + AgNO3  AgI + NaNO3 ; 2 AgI + Fe  FeI2 + 2Ag
2 FeI2 + 3Cl2  2FeCl3 + 22
PAGE NO.-19
vuqPNsn # 1
fuEufyf[kr vuqPNsn dks /;kuiwoZd if<+, rFkk (8 ls 10) ç'uksa ds mÙkj nhft,A
vk;ksMhu ekuo 'kjhj ds fy, vko';d ,d egRoiw.kZ inkFkZ gSA bls ge yo.k ds :i esa xzg.k djrs gSa] ftlesa
vk;ksMhu vo;o cgqr de çfr'kr ek=kk esa mifLFkr gksrk gSA vk;ksMhu ds dbZ vkS|ksfxd vuqç;ksx Hkh gSaA
dsfyQkWfuZ;k eas vkW;y-QhYM czkbu ls vk;ksMhu çkIr djus ds fy, fuEu çØe dke esa ysrs gaS %
NaI + AgNO3  AgI + NaNO3 ; 2 AgI + Fe  FeI2 + 2Ag
2 FeI2 + 3Cl2  2FeCl3 + 22
8. If 381 kg of iodine is produced per hour, then mass of AgNO3 required per hour will be :
;fn vk;ksMhu dk mRiknu 381 kg çfr ?kUVk gksrk gS] rks çfr ?k.Vs vko';d AgNO3 dk nzO;eku fdruk gksxk %
(A) 170 kg (B) 340 kg (C) 255 kg (D*) 510 kg
381  10 3
3  10 3
Sol. Moles of 2 produced = =
254 2
3
for this much moles of 2, moles of AgNO3 required = × 2 × 103
2
 mass of AgNO3 required = 3 × 170 × 103 = 510 kg
381  10 3 3  103
gy mRikfnr 2 ds eksy = =
254 2
3
2 ds bl eksy ds fy, AgNO3 ds vko';d eksy = × 2 × 103
2
 AgNO3 dk vko';d Hkkj = 3 × 170 × 103 = 510 kg.
9. If 324 g of Ag is recovered in pure form, then minimum amount of Na required will be:
(A*) 450 g (B) 150 g (C) 300 g (D) 600 g
;fn Ag ds 324 xzke dks 'kq) :i esa iqu% izkIr fd;k tkrk gS] rc Na dh vko';d U;wure ek=kk D;k gksxh %
(A) 450 xzke (B) 150 xzke (C) 300 xzke (D) 600 xzke
324
Sol. Moles of Ag recovered = =3
108
Hence moles of Na required to produce this Ag = 3
 mass of Na = 3 × 150 = 450 g
324
gy Ag ds izkIr eksy = =3
108
;g bl Ag dks mRikfnr djus ds Na ds eksy fy, vko';d eksy = 3
 Na dk nzO;eku = 3 × 150 = 450 g.
10. If above reaction is carried out by taking 150 kg of Na and 85 kg of AgNO3, then number of moles of
iodine formed is :
;fn Na ds 150 kg rFkk AgNO3 ds 85 kg dks ysdj mijksDr vfHkfØ;k djkbZ tkrh gS] rks cuus okys vk;ksMhu ds
eksyksa dh la[;k fuEu gS %
(A) 0.5 (B) 500 (C*) 250 (D) 0.25
150
Sol. moles of Na = × 103 = 103
150
85
moles of AgNO3 = × 103 = 5 × 102
170
clearly AgNO3 is limiting reagent
moles of AgNO3 5  102
 moles of 2 formed = = = 250
2 2
PAGE NO.-20
150
gy Na ds eksy = × 103 = 103
150
85
AgNO3 ds eksy = × 103 = 5 × 102
170
Li"Vr;k AgNO3 lhekar vfHkdeZd gSA
AgNO3 ds eksy 5  102
 cus gq, 2 eksy = = = 250
2 2
Comprehension # 2
Rules for Rounding off the uncertain Digits :
When we do calculations using measured values, the result may contain more than one uncertain
digits, which should be rounded off. The following rules are used for rounding off :
If the digit to be dropped is less than 5, then the preceding digit remains unchanged. Example :
(a) 6.32 after rounding off becomes 6.3
(b) 5.934 after rounding off becomes 5.93
If the digit to be dropped is more than 5, then the preceding digit is increased by one. Example :
(a) If it is only 5 or 5 followed by zero, then the preceding digit is raised by one if it is odd and left
unchanged if it is even. Example :
(i) 4.750 after rounding off becomes 4.8
(ii) 4.75 after rounding off becomes 4.8
(iii) 4.650 after rounding off becomes 4.6
(iv) 4.65 after rounding off becomes 4.6
(b) If 5 is further followed by a non-zero digit, the preceding digit is raised by one. Example :
(i) 15.352 after rounding off becomes 15.4
(ii) 9.853 after rounding off becomes 9.9
vuqPNsn # 2
vfuf'pr vad dks iw.kkZafdr djus ds fu;e (Rules for Rounding off the uncertain Digits)
tc ge x.kuk esa ekfir eku dk mi;ksx djrs gSa] ifj.kke esa ,d ls vf/kd vfuf'pr vad gks ldrk gS] ftls
iw.kkZafdr djuk pkfg,A iw.kkZafdr djus ds fy, fuEu fu;e mi;ksx esa ysrs gSa :
ftl la[;k dks iw.kk±fdr djuk gS ;fn og 5 ls de gS rks mlls igys okyk vad vifjofrZr jgrk gSA mnkgj.k :
(a) 6.32 dks iw.kk±fdr djus ds ckn 6.3 gks tkrk gSA
(b) 5.934 dks iw.kk±fdr djus ds ckn 5.93 gks tkrk gSA
ftl la[;k dks iw.kk±fdr djuk gS ;fn og 5 ls vf/kd gS rks igys okyk vad ,d ls c<+ tkrk gSA mnkgj.k :
(a) ;fn ;g dsoy 5 ;k 5 ds vkxs 'kwU; gS] rc igys okyk vad ,d ls c<+sxk ;fn ;g fo"ke gS rFkk ;g
vifjofrZr jgsxk ;fn ;g le gSA mnkgj.k :
(i) 4.750 dks iw.kk±fdr djus ds ckn 4.8 gks tkrk gSA
(ii) 4.75 dks iw.kk±fdr djus ds ckn 4.8 gks tkrk gSA
(iii) 4.650 dks iw.kk±fdr djus ds ckn 4.6 gks tkrk gSA
(iv) 4.65 dks iw.kk±fdr djus ds ckn 4.6 gks tkrk gSA
(b) ;fn 5 ds vkxs dh la[;k v'kwU; vad gS rks igys okyk vad ,d ls c<+ tkrk gSA mnkgj.k :
(i) 15.352 dks iw.kk±fdr djus ds ckn 15.4 gks tkrk gSA
(ii) 9.853 dks iw.kk±fdr djus ds ckn 9.9 gks tkrk gSA
Now answer the following questions :
vc fuEu iz'uksa ds mÙkj nhft,A
11(a). Round off to two significant figures :
nks lkFkZd vadksa rd iw.kk±fdr dhft,A
(a) 0.05857 (b) 0.05837 (c) 5.07 × 106 (d) 5.01 × 106
Ans. (a) 0.059 (b) 0.058 (c) 5.1 × 106 (d) 5.0 × 106
11(b). Round off the following numbers within three significant figures -
(i) 0.03927 kg (ii) 4.085 × 108 sec (iii) 5.2354 m (iv) 4.735 × 10–6 kg
fuEu la[;kvksa dks rhu lkFkZd vadksa eas iw.kkZfdr dhft,A
(i) 0.03927 kg (ii) 4.085 × 108 sec (iii) 5.2354 m (iv) 4.735 × 10–6 kg
Ans. (i) 0.0393 kg (ii) 4.08 × 108 sec (iii) 5.24 m (iv) 4.74 × 10–6 kg
Sol. (i) 0.0393 kg (ii) 4.08 × 108 sec (iii) 5.24 m (iv) 4.74 × 10–6 kg
PAGE NO.-21
12. 120 g Mg is burnt in air to give a mixture of MgO and Mg3N2. The mixture is now dissolved in HCl to
form MgCl2 and NH4Cl. If 107 g NH4Cl is produced, then determine the moles of MgCl2 formed:
120 xzke Mg ok;q esa tydj MgO rFkk Mg3N2 dk ,d feJ.k nsrk gSA tc feJ.k dks HCl esa ?kksyk tkrk gS] rks
MgCl2 rFkk NH4Cl mRikfnr gksrs gSaA ;fn 107 xzke NH4Cl curk gS] rks çkIr MgCl2 ds eksyksa dh x.kuk djks %
Ans. 5
Sol. Apply POAC on Mg
Mg  MgCl2
5 moles x moles
1×5=x×1  x = 5 moles
gy- Mg ij POAC yxkus ij
Mg  MgCl2
5 eksy x eksy
1×5=x×1  x = 5 eksy
13. A 5 g mixture of SO2 and O2 gases is reacted to form SO3 gas. What should be the mass ratio of SO 2
and O2 gases in mixture to obtain maximum amount of SO3 gas :
SO2 rFkk O2 dk 5 xzke feJ.k fØ;kdj SO3 cukrs gSA feJ.k esa SO2 rFkk O2 dk nzO;eku dk vuqikr D;k gks fd
vf/kdre SO3 xSl izkIr gksA
Ans. 4
Sol. For maximum amount of product, the reactants should be present in their stoichiometric ratio.
2SO2 (g) + O2 (g)  2SO3 (g)
mass x 5–x
x 5–x
mole
64 32
 x
 
64
So, =2:1
 – x
5
 
32 
Therefore, x = 4
mSO2 : mO2 = 4 : 1.
14. An impure sample of cuprite (Cu2O) contains 66.6% Copper by mass. Find the ratio of % of pure Cu2O
66.6  143
to % of impurity by mass in the sample. Take = 37.5.
254
D;wizkbV (Cu2O) dk ,d v'kq) izkn'kZ] æO;eku ls 66.6% dkWij j[krk gSA izkn'kZ esa 'kq) Cu2O ds nzO;eku
66.6  143
% o v'kfq) ds nzO;eku % dk vuqikr Kkr dhft;sA = 37.5 fyft,A
254
Ans. 3
66.6  143
Sol. % of pure Cu2O ('kq) Cu2O dk %) = = 75%
2  63.5
75
% of impurity (v'kqf) dk %) = 25% So, ratio (vr%, vuqikr) = =3
25
1
okLrfod Ca(NO3)2 dk izfr'kr fo[k.Mu = 200 × 100 = 10%
1
20
15. An isotope of chromium, on bombardment with neutron, undergoes a nuclear reaction yielding element
X as shown below. Then find the atomic number of element X :
24 Cr 0 n  20 n   1 H  X
52 1 1 1
Øksfe;e ds ,d leLFkkfud (isotope) dks U;wVªkWuksa dh ckSNkj (bombardment) djus ij uhps fn[kkbZ x;h ukfHkdh;
vfHkfØ;k (nuclear reaction) gksrh gS ftleas rRo X izkIr gksrk gSA rc rRo X dk ijek.kq Øekad Kkr dhft;sA
52
24 Cr 10 n  210 n   11 H  X
Ans. 21
PAGE NO.-22
Sol. 52 + 1 = 2 + 4 + 1 + A  46 = A
24 = 2 + 1 + Z  Z = 21
So it is Sc (blfy, ;g Sc gS)
P-CH EM ISTRY


EST INFORM AT IO
DPP

4. DPP Syllabus :
ANSWER KEY
1. (D) 2. (C) 3. (D) 4. (A) 5. (C) 6. (C) 7. (D)
8. (A) 9. (C) 10. (B) 11. (B) 12. (A) 13. (B) 14. (B)
15. (C) 16. (B) 17. (A) 18. (B) 19. (B)
1. According to Bohr model,the ratio of area covered by second orbit of H atom and first orbit of He + ion is:
cksj izk:i ds vuqlkj] H ijek.kq dh f}rh; d{kk o He+ vk;u dh izFke d{kk }kjk ?ksjs gq, {ks=kQy dk vuqikr fuEu gS%
(A) 1 : 1 (B) 16 : 1 (C) 8 : 1 (D*) 64 : 1
1
2. S1 : For an electron, the given set of quantum numbers is not possible : n = 4, = 1, m = 0, s = +
2
S2 : The total number of orbitals in a subshell is 2 + 1, where  = Azimuthal quantum number.
1
S1 : ,d bysDVªkWu ds fy, DokaVe la[;k dk fn;k x;k lsV n = 4, = 1, m = 0, s = + laHko ugha gSA
2
S2 : ,d midks'k esa d{kdksa dh dqy la[;k 2 + 1 gksrh gS] tgk¡  = f}xa'kh DokaVe la[;k gSA
(A) T T (B) T F (C*) F T (D) F F
1
Sol. S1 : For an electron, the given set of quantum numbers is possible : n = 4, = 1, m = 0, s = +
2
1
,d bySDVªkWu ds fy, DokaVe la[;k dk fn;k x;k lsV n = 4, = 1, m = 0, s = + laHko gSA
2
3. If for any electron in an orbital, a parameter ‘P’ is defined as :

P = n –  + m, where n, , m are the quantum numbers of that orbital.Then, what can be the maximum
value of P for an unpaired electron of 24Cr3+ ion ?
;fn ,d d{kd esa fdlh bysDVªkWu ds fy,] ,d izkpy ‘P’ fuEu izdkj ls ifjHkkf"kr djrs gSa %
P = n– + m, tgka n, , m bl d{kd dh DokaVe la[;k,¡ gSaA rc 24Cr3+ vk;u ds ,d v;qfXer bysDVªkWu ds fy,
P dk vf/kdre eku D;k gks ldrk gS?
(A) 4 (B) 5 (C) 2 (D*) 3
Sol. Cr3+ = 1s2 2s2 2p6 3s2 3p6 3d3
n=3 ; =2 ; m = 2 (maximum possible value) (vf/kdre laHko eku)
n–  + m = 3.
PAGE NO.-23
4. Potassium manganate is a dark green, crystalline substance whose composition is 39.6% K, 27.9% Mn
and 32.5% O by mass. What is its empirical formula: (Atomic mass of Mn = 55 u)
iksVsf'k;e eSaXusV xgjs gjs jax dk fØLVyh; inkFkZ gS] ftldk nzO;eku laxBu 39.6% K, 27.9% Mn vkSj 32.5% O
gSA bldk ewykuqikrh lw=k D;k gS % (Atomic mass of Mn = 55 u)
(A*) K2MnO4 (B) KMnO4 (C) KMnO3 (D) K2MnO2
39.6 27.9 32.5
Sol. For K Mn  O
39.08 54.93 16
 1.01  0.50  2.03
so, simple ratio ¼blfy, ljy vuqikr½
K2 Mn  1 O4
Hence K2MnO4.
5. In the reaction 4A + 2B + 3C  A4 B2 C3 what will be the number of moles of product formed. Starting
from 2 moles of A, 1.2 moles of B & 1.44 moles of C :
vfHkfØ;k 4A + 2B + 3C  A4 B2 C3 esa] mRikn ds eksyksa dh la[;k D;k gksxh] ;fn ;g vfHkfØ;k A ds 2 eksy, B
ds 1.2 eksy rFkk C ds 1.44 eksy ls izkjEHk dh tkrh gS %
(A) 0.5 (B) 0.6 (C*) 0.48 (D) 4.64
Sol. 4A + 2B + 3C  A4B2C3
Initial mole 2 1.2 1.44 0
final mole 0 0.48
C is limiting reagent.
 moles of A4B2C3 is 0.48.
gy % 4A + 2B + 3C  A4B2C3
izkjfEHkd eksy 2 1.2 1.44 0
vfUre eksy 0 0.48
C lhekUrdkjh vfHkdeZd gSA
 A4B2C3 ds eksy 0.48 gSA
6. An alloy of iron and carbon is treated with sulphuric acid, in which only iron reacts :
2Fe(s) + 3H2SO4(aq)  Fe2 (SO4)3(aq) + 3H2(g)
If a sample of alloy weighing 140 g gave 6 g of hydrogen, what is the percentage of iron in the alloy ?
(A) 40% (B) 60% (C*) 80% (D) 30%
yksgs vkSj dkcZu dh ,d feJ /kkrq dks lY¶;wfjd vEy ls mipkfjr fd;k tkrk gS] ftlesa ls dsoy yksgk fØ;k djrk gS%
2Fe(s) + 3H2SO4(aq)  Fe2 (SO4)3(aq) + 3H2(g)
;fn feJ /kkrq ds ,d uewus] ftldk nzO;eku 140 xzke gS] ds }kjk gkbMªkstu ds 6 xzke izkIr gksrs gaS] rks feJ /kkrq esa
yksgs dk izfr'kr D;k gS \
(A) 40% (B) 60% (C*) 80% (D) 30%
Sol. 2Fe(s) + 3H2SO4(aq) Fe2 (SO4)3(aq) + 3H2(g)
6
Mole of H2 = = 3 mol
2
3
Mole of Fe = × 2 = 2
3
Mass of Fe = 2 × 56 = 112 g.
112
Percentage of Fe in the alloy = × 100 = 80%.
140
Sol. 2Fe(s) + 3H2SO4(aq)  Fe2 (SO4)3(aq) + 3H2(g)
7. Oxidation number of underlined elements in N2O5, SO32–, NH+4 are :
N2O5, SO32–, NH4+ esa uhps vafdr fd;s x;s rRoksa ds vkWDlhdj.k vad fuEu gSa %
(A) +5, +2, –3 (B) +6, –2, +3 (C) +6, +2, –3 (D*) +5, +4, –3
( 5) ( 4) (–3)
Sol. N2O5 > SO32– > NH4
8. What volume of water is required to make 0.2 M solution from 16 mL of a 0.5 M solution?
,d 0.5 M foy;u ds 16 mL ls 0.2 M foy;u cukus ds fy;s ty ds fdrus vk;ru dh vko';drk iM+sxh \
(A*) 24 mL (B) 40 mL (C) 6.4 mL (D) 20 mL
PAGE NO.-24
Sol. M1V1 = M2V2
0.5 × 16 = 0.2 × V2
V2 = 40 ml
Volume of water = 40 – 16 = 24 mL ty dk vk;ru = 40 – 16 = 24 mL
9. K2Cr2O7 + C2O4 + H2SO4 K2SO4 + CO2 + Cr2(SO4)3 + H2O
2–
In above reaction, identify the elements which do not undergo change in their oxidation state:
(A) K, C & O (B) S, H, O & Cr (C*) K, O, S & H (D) Cr & C
K2Cr2O7 + C2O42– + H2SO4 K2SO4 + CO2 + Cr2(SO4)3 + H2O
mijksDr vfHkfØ;k esa mu rRoksa dks igpkfu;s] ftudh vkWDlhdj.k voLFkk esa dksbZ ifjorZu ugha gqvk %
(A) K, C o O (B) S, H, O o Cr (C*) K, O, S o H (D) Cr o C
10. A, B and C elements have the oxidation number of +6, –2 and –1 repectively. The possible molecular
formula when these atoms combine can be :
rRo A, B ,oa C Øe'k% + 6, –2 ,oa–1 vkWDlhdj.k voLFkk,¡ j[krs gSaA bu rRoksa ls cuus okys ;kSfxd dk v.kqlw=k D;k
gks ldrk gS %
(A) A2BC (B*) AB2C2 (C) ABC2 (D) AB2C
Sol. In AB2C2 only sum of charges on the atoms A, B, C comes out zero according to its oxidation number.
11. Calculate the amount of 75% pure NaI required to prepare 5 litre of 0.5 M solution.
(A) 281.25 g (B*) 500 g (C) 923.33 g (D) 519.375 g
0.5 M foy;u ds 5 yhVj cukus ds fy, 75% 'kq) NaI dh fdruh ek=kk vko';d gS\
(A) 281.25 xzke (B*) 500 xzke (C) 923.33 xzke (D) 519.375 xzke
12. 5 g of K2SO4 was dissolved in water to prepare 250 mL of solution. What volume of this solution should
be used so that 2.33 g of BaSO4 may be precipitated from BaCI2 solution.
K2SO4 + BaCl2  BaSO4 + 2KCl
(A*) 87 mL (B) 174 mL (C) 8.7 mL (D) 17.4 mL
ty esa K2SO4 ds 5 xzke ?kksys tkrs gSa rFkk 250 mL foy;u cuk;k tkrk gSA bl foy;u dk fdruk vk;ru dke esa
ysuk pkfg, rkfd BaCl2 foy;u ls BaSO4 dss 2.33 xzke dks vo{ksfir fd;k tk ldsA
K2SO4 + BaCl2  BaSO4 + 2KCl
(A*) 87 mL (B) 174 mL (C) 8.7 mL (D) 17.4 mL
Sol. K2SO4 + BaCl2 BaSO4 + 2 KCl
2.33 1
mole of BaSO4 = =
233 100
1
mole of K2SO4 used =
100
5 /174 20
molarity of K2SO4 solution = =
1/ 4 174
Lets volume of K2SO4 solution is V.
1 1 174
= M  V  V =  = 0.087 litre = 87 ml
100 100 20
gy % K2SO4 + BaCl2 BaSO4 + 2 KCl
2.33 1
BaSO4 ds eksy = =
233 100
1
K2SO4 ds vfHkd`r eksy =
100
5 /174 20
K2SO4 foy;u dh eksyjrk = =
1/ 4 174
ekuk fd K2SO4 dk vk;ru V gSA
1 1 174
= M  V V =  = 0.087 yhVj = 87 ml
100 100 20
PAGE NO.-25
13. Concentrated HNO3 is 63% HNO3 by mass and has a density of 1.4 g/mL. How many millilitres of this
solution are required to prepare 250 mL of a 1.20 M HNO3 solution?
lkfUnzr HNO3 nzO;eku dk 63% HNO3 o bldk ?kuRo 1.4 g/mL gSA 1.20 M HNO3 foy;u dk 250 mL cukus ds
fy, bl foy;u ds fdrus feyh yhVj vko';d gSA
(A) 18.0 (B*) 21.42 (C) 20.0 (D) 14.21
Sol. m-moles of HNO3 required = 250 × 1.2 = 300
100
100 g solution contain 1 mole HNO3 mL solution contain 1 mole HNO3
1.4
1000
molarity of HNO3 solution = × 1.40 = 14 14 × V = 300 or V = 21.42 mL.
100
gy- vko';d HNO3 ds feyh eksYl = 250 × 1.2 = 300
100
100 g foy;u 1 eksy HNO3 j[krk gS mL foy;u 1 eksy HNO3 j[krk gS
1.4
1000
HNO3 foy;u dh eksyjrk = × 1.40 = 14  14 × V = 300 vFkok V = 21.42 mL.
100
14. What volume of 0.25 M HNO3 (nitric acid) solution reacts with 50 mL of 0.15 M Na 2CO3 (sodium
carbonate) solution in the following reaction :
2HNO3(aq) + Na2CO3(aq)2NaNO3(aq) + H2O() + CO2(g)
fuEu vfHkfØ;k esa 0.25 M HNO3 (ukbfVªd vEy) foy;u dk fdruk vk;ru] 0.15 M Na2CO3 (lksfM;e dkcksZusV)
foy;u ds 50 mL ls fØ;k djrk gS % net
2HNO3(aq) + Na2CO3(aq)  2NaNO3(aq) + H2O() + CO2(g)
(A) 30 mL (B*) 60 mL (C) 120 mL (D) 100 mL
15. Composition of a sample is Fe0.93 O1.00 . If Fe is present in +2 & +3 oxidation state in this sample then %
of Fe present in +3 oxidation state
,d uewus dk laxBu Fe0.93 O1.00 gSA ;fn bl uewus esa Fe, + 2 rFkk +3 vkDlhdj.k voLFkk esa mifLFkr gSA rc+ +3
vkDlhdj.k voLFkk esa Fe dk % gksxkA
(A) 85% (B) 30% (C*) 15% (D) 60%
Sol. Fe0.93 O1.00
From charge balance Where X is mole of Fe(III)
3x + (0.93 – x) 2 = 2
3x + 1.86 – 2x = 2
0.14
x = 0.14 % of Fe3+ =  100 = 15%
0.93
Sol. Fe0.93 O1.00
vkos'k larqyu ls
tgk¡ X , Fe(III) ds eksy gSa
3x + (0.93 – x) 2 = 2
3x + 1.86 – 2x = 2
x = 0.14
0.14
Fe3+ dk % =  100 = 15%
0.93
ChemINFO Duma's Method
Daily Self-Study Dosage for mastering Chemistry Elemental Analysis of Nitrogen by duma’s method
Duma's method : This method can be applied in case of all nitrogeneous compounds :
Principle : A nitrogenous compound of formula CxHyNz when strongly heated with cupric oxide, in the
atmosphere of CO2. Nitrogen is set free along with the formational carbon dioxides of nitrogen may be oxidised
into oxides of nitrogen. When the gaseous mixutre is passed over a roll of heated bright copper gauze, the
oxides of nitrogen are reduced again into nitrogen.
y z
CxHyNz + CuO (Excess) xCO2 + H2O + N2 + (Cu)
2 2
Oxides of nitrogen + Cu N2 + CuO
PAGE NO.-26
The resultant mixture is collected over KOH solution in a nitrometer.All the gases except nitrogen are absorbed.
The volume of nitrogen collected over KOH solution is measured.
Observations :
(i) Mass of the organic substance taken = W g (ii) Volume of moist nitrogen in nitrometer = v mL
(iii) Room temperature = t°C = (t + 273) K (iv) Atmospheric tension at room temperature = P 1mm
 Pressure of dry nitrogen = (p – p1) mm
(p  p1)  v 273
Calculation : Volume of N2 at NTP (by gas equation) =   V mL
(t  273) 760
28
Percentage of Nitrogen : V mL of N2 at NTP =  v g (22400 mL of N2 weight at NTP = 28 g)
22400
28 V
 Percentage of nitrogen in the given compound =   100 (Reff: Disha publication)
22400 W
ChemINFO Duma's Method

Daily Self-Study Dosage for mastering Chemistry Elemental Analysis of Nitrogen by duma’s method
M~;wek fof/k % ;g fof/k lHkh ukbVªkstu;qDr ;kSfxdksa ds fy, iz;qDr dh tk ldrh gSA
fl)kUr% CxHyNz lw=k ds ,d ukbVªkstu ;qDr ;kSfxd CO2 ds okrkoj.k esa D;qfizd vkWDlkbM ds lkFk izcy :i ls xeZ djrs
gS] rks ukbVªkstu dkcZu MkbZvkWDlkbM¼CO2½ ds lkFk eq¶r voLFkk esa gksrh gS] ftlesa ukbVªkstu vius vkWDlkbM esa vkWDlhd`r
gks tkrh gS] tc xSlh; feJ.k dks xeZ pedhys dkWij xSt ¼tkyh½ ls izokfgr fd;k tkrk gS rc ukbVªkstu vkWDlkbM iqu%
ukbVªkstu esa vipf;r gks tkrs gSA
y z
CxHyNz + CuO (vkf/kD;)  xCO2 + H2O + N2 + (Cu)
2 2
ukbVªkstu vkWDlkbM + Cu  N2 + CuO
ifj.kkeh feJ.k dks ukbVªksehVj ls KOH foy;u ij ,df=kr dj ysrs gSA lHkh xSls ukbVªkstu ds vfrfjDr vo'kksf"kr gks tkrh
gSA KOH foy;u ij ,df=kr ukbVªkstu dk vk;ru eki ysrs gSA
izs{k.k %
(i) dkcZfud inkFkZ dk nzO;eku ysrs gS = W g (ii) ukbVªksehVj esa v)Z ukbVªkstu dk vk;ru eki ysrs gS = v mL
(iii) dejs dk rki = t°C = (t + 273) K (iv) dejs ds rki ij ok;qe.Myh; ruko = P1 mm
 'kq"d ukbVªkstu dk nkc = (p – p1) mm
(p  p1)  v 273
x.uk % NTP ij N2 dk vk;ru ¼xSl lehdj.k }kjk½ =   V mL
(t  273) 760
28
ukbVªkstu dh izfr'kr % NTP ij N2 dk V mL =  v g (NTP ij 22400 mL dk N2 Hkkj = 28 g)
22400
28 V
 fn;s x;s ;kSfxd esa ukbVªkstu izfr'krrk =   100
22400 W
16. Nitrogen is estimated in organic compound by :

(A) Carius method (B*) Duma's method (C) Lassaigne's method (D) None of these
dkcZfud ;kSfxd esa ukbVªkstu dh x.kuk fuEu esa fdlds }kjk dh tk ldrh gS%
(A) dsfjvl fof/k (B*) M~;wek fof/k (C) ySlkusa fof/k (D) buesa ls dksbZ ugha
17. In Duma's method for the estimation of nitrogen in an organic compound, nitrogen is determined in the
form of:
(A*) Gaseous nitrogen (B) Sodium cyanide
(C) Ammonium sulphate (D) Gaseous ammonia
dkcZfud ;kSfxd esa ukbVªkstu dh x.kuk gsrq M~;wek fof/k esa] ukbVªkstu fdl :i esa izkIr dh tkrh gS%
(A*) xSlh; ukbVªkstu (B) lksfM;e lk;ukbM (C) veksfu;e lYQsV (D) xSlh; veksfu;k
PAGE NO.-27
18. 0.25 g of the organic compound on analysis by Duma's method gave 32 ml of nitrogen gas at STP, the
percentage of nitrogen in the compound is :
M~;wek fof/k }kjk 0.25 xzke dkcZfud ;kSfxd ds v/;;u ij 32 ml ukbVªkstu xSl STP ij izkIr gqbZ] ;kSfxd esa
ukbVªkstu dh izfr'kr ek=kk gS %
(A) 8% (B*) 16% (C) 20% (D) 25
28 V 28 32
Sol. Percentage of nitrogen =   100 =   100  16%
22400 W 22400 0.25
28 V 28 32
Sol. ukbVªkstu dh izfr'kr ek=kk =   100 =   100  16%
22400 W 22400 0.25
19. 0.45 g of an organic compound on analysis by Duma's method gave 44 ml of nitrogen gas at STP
percentage of nitrogen in the compound is :
(A) 6% (B*) 12% (C) 18% (D) 25%
M~;wek fof/k }kjk 0.45 xzke dkcZfud ;kSfxd ds v/;;u ij 44 ml ukbVªkstu xSl STP ij izkIr gqbZ] ;kSfxd esa
ukbVªkstu dh izfr'kr ek=kk gS%
(A) 6% (B*) 12% (C) 18% (D) 25%
28 V 28 44
Sol. Percentage of nitrogen =   100 =   100  12%
22400 W 22400 0.45
28 V 28 44
Sol. ukbVªkstu dh izfr'kr ek=kk =   100 =   100  12%
22400 W 22400 0.45
P-CH EM ISTRY


EST INFORM AT IO
DPP

Comprehension ('–1' negative marking) Q.10 (a) & (b) to Q.13 (3 marks, 2 min.) [12, 08]
Match the column (no negative marking) Q.14 (8 marks, 6 min.) [08, 06]
ANSWER KEY
1. (D) 2. (B) 3. (B) 4. (B) 5. (C) 6. (C) 7. (ABC)
8. (BCD) 9. (ABD) 10 (a). (a) 953 (b) 954 (c) 953.3 (d) 953.4
10 (b). (a) 7 (b) 6 (c) 6.6 (d) 6.4 11. (A) 12. (B) 13. (D)
14. (A - p, q, r) ; (B - q, r) ; (C - q, r) ; (D - p, s) 15. (C) 16. (D)
1. Which of the following compounds have sulphur atom in its maximum oxidation state :
X = H2SO4 ; Y = H2SO5 ; Z = H2S2O8
(A) Z only (B) X only (C) Y only (D*) X, Y and Z
fuEu esa ls fdl@fdu ;kSfxd¼dksa½ esa lYQj ijek.kq] viuh vf/kdre vkWDlhdj.k voLFkk esa gS %
X = H2SO4 ; Y = H2SO5 ; Z = H2S2O8
(A) dsoy Z (B)dsoy X (C) dsoy Y (D*) X, Y vkSj Z
Sol. In all these three compounds
H2SO4, H2SO5, H2S2O8, ‘S’ is in +6 state which is it’s maximum oxidation state.
bu rhuks ;kSfxdksa H2SO4, H2SO5, H2S2O8, esa ‘S’, +6 voLFkk esa gS tks bldh vf/kdre vkWDlhdj.k voLFkk gSA
PAGE NO.-28
2. Fe shows an oxidation state of +1 in :
fuEu esa Fe ,d vkWDlhdj.k voLFkk +1 n'kkZrk gSA
(A) Fe(CO)5 (B*) [Fe(H2O)5(NO+)]SO4
(C) Fe4[Fe(CN)6]3 (D) [FeCl4]–
Sol. Let oxidation state is x ;
(x + 5 × 0 + 1) – 2 = 0  x = +1
gy. ekuk vkWDlhdj.k voLFkk x gSA
(x + 5 × 0 + 1) – 2 = 0  x = +1
3. 0.8 mole of a mixture of CO and CO2 requires exactly 40 gram of NaOH in solution for complete
conversion of all the CO2 into Na2CO3, if the mixture (0.8 mole) is completely oxidised to CO 2, find
further required moles of NaOH
CO o CO2 ds 0.8 eksy feJ.k ds fy, Bhd 40 xzke NaOH vko';d gSa ftlls lHkh CO2 dk Na2CO3 esa iw.kZ :i
ls ifjorZu gks lds] ;fn feJ.k (0.8 eksy) iw.kZ :i ls CO2 esa vkWDlhd`r gks jgk gksa] NaOH ds vksj vko';d eksy
Kkr dhft,\
(A) 0.2 (B*) 0.6 (C) 1 (D) 1.5
Sol. CO2 + 2NaOH  Na2CO3 + H2O
nNaOH = 1 ;  CO2 present in mixture = 0.5 and Co present = 0.3 mole
when more CO2 produced = 0.3, more NaOH required = 0.3 × 2 = 0.6 mole
Sol. CO2 + 2NaOH  Na2CO3 + H2O
nNaOH = 1 ;  feJ.k eas mifLFkr CO2 = 0.5 rFkk feJ.k esa Co = 0.3 eksy gSa
tc vksj CO2 mRikfnr = 0.3 eksy gksrk gSa rks vksj NaOH vko';d 0.3 × 2 = 0.6 eksy vksj vko';d gSaA
4. The molar ratio of Fe2+ to Fe3+ in a mixture of ferrous sulphate and ferric sulphate having equal number
of sulphate ions from both components of mixture is :
(A) 1 : 2 (B*) 3 : 2 (C) 2 : 3 (D) 3 : 1
QSjl lYQsV rFkk Qsfjd lYQsV ds ,d feJ.k] ftlesa feJ.k ds nksuksa ?kVdksa esa lYQsV vk;u dh leku la[;k gks]
esa Fe2+ rFkk Fe3+ dk eksyj vuqikr fuEu gksxk %
(A) 1 : 2 (B*) 3 : 2 (C) 2 : 3 (D) 3 : 1
Sol. For equal number of sulphate ion in both ferrous and ferric sulphate, we have
Qsjl rFkk Qsfjd lYQsV nksuksa esa lYQsV vk;u dh la[;k leku gksus ds fy,
Fe 2  1 Fe 2  3
=  = .
Fe 3  2/3 Fe 3  2
5. In which of the following compounds, nitrogen has an oxidation state of –1?
fuEu esa ls fdl ;kSfxd esa ukbVªkstu] –1 vkWDlhdj.k voLFkk j[krk gS \
(A) N2O (B) NO2– (C*) NH2OH (D) N2H4
Sol. NH2OH
x + 3(+1) + 1(–2) = 0
x = –1
6. A solution containing 0.1 mole of a metal chloride MCl x requires 500 mL of 0.8 M AgNO3 solution for
complete precipitation. The value of x is :
,d /kkrq DyksjkbM MClx ds 0.1 eksy ;qDr ,d foy;u ds iw.kZ :i ls vo{ksi.k ds fy, 0.8 M AgNO3 foy;u ds
500 mL vko';d gaSA x dk eku fuEu gS %
(A) 1 (B) 2 (C*) 4 (D) 3
Sol. MClx + AgNO3  AgCl + MNO3
500
POAC on Ag  × 0.8 = 1 × mole of AgCl  mole of AgCl = 0.4 ...........(A)
1000
POAC on Cl
 0.1 × x = 1 × mole of AgCl = 0.4..............(A)
 mole of AgCl = 0.1 x ....................(B)
put eq (B) in eq (A)
0.1 x = 0.4
x=4
gy % MClx + AgNO3  AgCl + MNO3
PAGE NO.-29
Ag ij POAC
500
× 0.8 = 1 × AgCl ds eksy  AgCl ds eksy = 0.4 ...........(A)
1000
Cl ij POAC
0.1 × x = 1 × AgCl ds eksy = 0.4..............(A)  AgCl ds eksy = 0.1 x ....................(B)
leh- (A) esa (B) dks j[kus ij
0.1 x = 0.4
x=4
7.* The following transitions occur when sodium atoms are sprayed into hot flame. The various steps are
numbered.
I II III IV V
3s 
 3p   4d  4s  3p  3s
Which of these steps result in emission of photon ?
(A*) III (B*) V (C*) IV (D)a I
tc lksfM;e ijek.kqvksa dks xeZ Tokyk esa j[krs gSa] rc fuEu laØe.k gksrs gSaA fofHkUu inksa dks ukekafdr fd;k gqvk gSA
I II III IV V
3s 
 3p 
 4d  4s  3p  3s
fuEu esa ls dkSuls inksa ds ifj.kkeLo:i QksVkWu dk mRltZu gksrk gS \
(A*) III (B*) V (C*) IV (D)a I
8.* Dichromate ion in acidic medium oxidizes stannous ion as :

xSn2+ + yCr2O72– + zH+  aSn4+ + bCr3+ + cH2O
(A) the value of x : y is 1 : 3 (B*) the value of x + y + z is 18
(C*) a : b is 3 : 2 (D*) the value of z – c is 7
vEyh; ek/;e esa MkbØksesV vk;u fuEu izdkj ls LVSul vk;u dks vkWDlhd`r djrk gSA
xSn2+ + yCr2O72– + zH+  aSn4+ + bCr3+ + cH2O
(A) x : y dk eku 1 : 3 gS (B*) x + y + z dk eku 18 gS
(C*) a : b dk vuqikr 3 : 2 gS (D*) z – c dk eku 7 gS
Sol. 3Sn + 14H + Cr2O7  3Sn + 2Cr + 7H2O
2+ + 2– 4+ 3+
9.* Identify the correct options for the following reaction

A + B  AnBm
(A*) n mol A react with m mol B
 1  1
(B*)   moles of A react with   moles of B
 m  n
 n
(C) If m mol A is limiting then   moles of AnBm is formed
 m
(D*) (n + m) mol mixture of A & B can produce maximum of 1 mol of AnBm
fuEu vfHkfØ;k ls lEcfU/kr lgh fodYiksa dk p;u dhft,A
A + B  AnBm
(A*) A ds n eksy B ds m eksy ls vfHkfØ;k djrs gSaA
 1  1
(B*) A ds   eksy B ds   eksy ls vfHkfØ;k djrs gSaA
m n
ds m eksy lhekar gSa rc AnBm ds   eksy mRikfnr gksxsaA

n
(C) ;fn A
 m
(D*) A rFkk B dk (n + m) eksy feJ.k vf/kdre 1 eksy AnBm mRikfnr dj ldrk gSA
Sol. nA + mB  AnBm
mol A molB mol AnBm
= =
n m 1
PAGE NO.-30
Comprehension # 1
Significant Figures in Calculations:-
When we do calculation using measured values, the result cannot be more accurate than any of the
measured values. The result must possess the accuracy level as that of original measurements. So to
have proper accuracy in the final result, we need to follow some rules during different arithmetical
operations.
(A). Addition and subtraction : The number of decimal places in the final result of any of these operations
has to be equal to the smallest number of decimal places in any of the terms involved in calculations.
Example:
a. Sum of 2.29 and 62.7 is 64.99. After rounding off to one place of decimal it will become 65.0.
b. Subtraction of 62.7 from 82.29 gives 19.59. After rounding off to one place of decimal, it will become 19.6.
Note: During the subtraction of quantities of nearly equal magnitude, accuracy is almost destroyed,
e.g., 3.28 – 3.23 = 0.05. Result 0.05 has only one significant figure whereas original measurements
have three significant figures each.
So it is advised that the difference should be measured directly instead of measuring the quantities first
and then finding their difference.
(B). Multiplication and division : In these operations, the number of significant figures in the result is the
same as the smallest number of significant figures in any of the factors. Example :
a. 1.3 × 1.2 = 1.56. After rounding off to two significant figures, it becomes. 1.6.
3500
b. = 465.42. As 3500 has minimum number of significant figures. i.e. two, the quotient must have
7.52
two significant figures. So 465.42 = 470 (after rounding off)
c. If we divide 3500 m by 7.52, 3500 m has four significant figures, then final result should be 465
(after rounding off to three significant figures).
vuqPNsn # 1
x.kuk esa lkFkZd vad :-
tc ge ekiu ekuksa dk x.kuk esa mi;ksx djrs gSa] fdlh Hkh ekiu ekuksa ls ifj.kke vf/kd ;FkkFkZ izkIr ugha dj ldrs
gSaA ifj.kke dh ;FkkFkZrk dk Lrj ewy ekiuksa ds cgqr lehi gksrk gSA vr% vfUre ifj.kke esa mfpr ;FkkFkZrk j[kus ds
fy,] gesa fofHkUu vadxf.krh; lafØ;kvksa ds nkSjku dqN fu;eksa dk vuqlj.k djus dh vko';drk gSA
(A). ;ksxQy ,oa O;odyu (Addition and Substraction) : vafre ifj.kke esa n'keyo vad dk LFkku bl lafØ;k dh
x.kuk esa lfEefyr lHkh inksa esa ls U;wure n'keyo vad LFkku ds in ds cjkcj gksrk gSA mnkgj.kkFkZ :
a. 2.29 rFkk 62.7 dk tksM+ 64.99 gSA n'keyo ds ,d LFkku rd iw.kkZadu djus ds i'pkr~ ;g 65.0 gks tkrk gSA.
b.82.29 esa ls 62.7 ?kVkus ij 19.59 vkrk gSA n'keyo ds ,d LFkku rd iw.kk±du ds i'pkr~ ;g 19.6 gks tkrk gSA
Note: yxHkx leku ifjek.k dh jkf'k;ksa ds O;odyu ds nkSjku] ;FkkFkZrk yxHkx [kRe gks tkrh gS] mnkgj.kkFkZ
3.28–3.23 = 0.05 gSA ifj.kke 0.05 dsoy ,d lkFkZd vad j[krk gSA tcfd ewy ekiu esa izR;sd rhu lkFkZd vad j[krs gSaA
vr% varj Kkr djus ds fy, ;g lykg nh tkuh pkfg, fd jkf'k;ksa ds igys ekiu rFkk fQj varj Kkr djus dh
txg lhèks gh varj Kkr djuk pkfg,A
(B). xq.kuQy o HkkxQy : bl lafØ;k esa ifj.kke esa lkFkZd vadksa dh la[;k x.kuk esa lfEefyr xq.kd (factors) esa ls
lcls de lkFkZd vad dh la[;k ds leku gksrh gSA mnkgj.kkFkZ :
a. 1.3 × 1.2 = 1.56. nks lkFkZd vadksa rd iw.kk±fdr djus ij ;g 1.6 gks tkrk gSA
3500
b. = 465.42. tSlk fd 3500 U;wure lkFkZd vad j[krk gS] vFkkZr~ nksA HkkxQy nks lkFkZd vad j[krk gSA
7.52
vr% 465.42 = 470 (iw.kk±fdr djus ds i'pkr~)
c. ;fn ge 3500 m dks 7.52 ls Hkkx nsaxs rks, 3500 m nks lkFkZad vad j[krk gS] rc vafre ifj.kke 465 gksuk pkfg,
(rhu lkFkZd vadksa rd iw.kk±fdr djus ds i'pkr~).
Now answer the following question (Q.10) :
vc fuEu iz'u (Q.10) dk mÙkj nhft,&
10(a). With due regard to significant figures, add the following
(a) 953 and 0.324 (b) 953 and 0.625 (c) 953.0 and 0.324 (d) 953.0 and 0.374
lkFkZd vadksa ds lanHkZ esa fuEu dks tksMsa %
(a) 953 rFkk 0.324 (b) 953 rFkk 0.625 (c) 953.0 rFkk 0.324 (d) 953.0 rFkk 0.374
Sol. (a) 953 (b) 954 (c) 953.3 (d) 953.4
PAGE NO.-31
10(b). With due regard to significant figures, subtract
lkFkZd vadksa ds lanHkZ esa fuEu dks ?kVk;sa %
(a) 0.35 from 7 (b) 0.65 from 7 (c) 0.35 from 7.0 (d) 0.65 from 7.0
(a) 7 esa ls 0.35 (b) 7 esa ls 0.65 (c) 7.0 esa ls 0.35 (d) 7.0 esa ls 0.65
Sol. (a) 7 (b) 6 (c) 6.6 (d) 6.4
Comprehension # 2
Molarity(mol/L) Molality(mol/Kg) Density (g/mL) Gram molecular mass of solute
Solution-1 a – d1 P
Solution-2 – b d2 Q
Solution-3 1 – 1.060 60
Now answer the following questions :
vuqPNsn # 2
eksyjrk (mol/L) eksyyrk (mol/Kg) ?kuRo (g/mL) foys; dk xzke vkf.od nzO;eku
foy;u-1 a – d1 P
foy;u-2 – b d2 Q
foy;u-3 1 – 1.060 60
vc fuEu ç'uksa ds mÙkj nhft, %
11. What is molality of solution-1 :
foy;u&1 dh eksyyrk D;k gksxh :
(A*)
1000  a (B)
1000 d1
(C)
a
(D) None of these buesa ls dksbZ ugha
1000  d1  aP 1000 a  P 1000 d1  aP
Sol. For solution 1  'a' moles of solute are present in 1000 ml of solution.
wt. of solution = 1000 × d1 g
wt. of solute = aP g
 a  1000 
So, Molality =  
1000  d1  aP 
gy % foy;u 1 ds fy, 1000 ml foy;u esa foy; ds 'a' eksy mifLFkr gSa
foy;u dk Hkkj = 1000 × d1 g
foys; dk Hkkj = aP g
 a  1000 
blfy, eksyjrk =  
1000  d1  aP 
12. What is the molarity of solution-2 :
foy;u&2 dh eksyjrk D;k gksxh :
b  d2 b  1000  d2 1000  bQ
(A) (B*) (C) (D) None of these buesa ls dksbZ ugha
1000  bQ 1000  bQ 1000  bd2
Sol. For solution 2  'b' moles of solute are present in 1000 g of solvent.
wt. of solution = 1000 + bQ
1000  bQ b  1000 b  1000  d2
vol. of solution =  Molality = =
d2 1000  bQ 1000  bQ
d2
gy % foy;u 2 ds fy, 1000g foyk;d esa foys; ds 'b' eksy mifLFkr gSa
foy;u dk Hkkj = 1000 + bQ
b  1000 b  1000 b  1000  d2
foy;u dk vk;ru =  eksYkyrk = =
1000  bQ 1000  bQ 1000  bQ
d2 d2
PAGE NO.-32
13. Which of the follownig statements is/are true :
(I) For solution-3, molarity and molality are equal.
(II) Mole fraction and molality of solution are independent of temperature.
(III) If same mass of an impure solute is dissolved instead of pure solute, then molarity of solution with
respect to solute compound will be equal in two cases .
(A) I, II & III (B) Only II (C) II & III (D*) I & II
fuEu esa ls dkSulk@dkSuls dFku lR; gSa %
(I) foy;u&3 ds fy;s eksyjrk rFkk eksyyrk leku gSA
(II) foy;u dk eksy izHkkt vkSj eksyyrk rki ls Lora=k jgrs gSaA
(III) ;fn ,d v'kq) foys; ds leku nzO;eku dks 'kq) foys; ds LFkku ij ?kksysa] rks nksuksa fLFkfr;ksa esa foys; ;kSfxd ds
lanHkZ esa foy;u dh eksyjrk leku gksxhA
(A) I, II rFkk III (B) dsoy II (C) II rFkk III (D*) I rFkk II
M
Sol. m= M2  Mw of Solute ¼foy; dk v.kqHkkj½
MM2
d
1000
14. Match the following :
Column I Column II
(A) 1 M glucose solution (p) 1 mole solute per litre of solution
(B) 3 M urea solution (q) 180 g solute per litre of solution
(C) 3 M CH3COOH solution (r) % w/v = 18%
(D) 1 M H2SO4 solution (s) % w/v = 9.8%
fuEu dks lqesfyr dhft, %
LrEHk I LrEHk II
(A) 1 M Xywdksl foy;u (p) 1 eksy foys; izfr yhVj foy;u
(B) 3 M ;wfj;k foy;u (q) 180 g foys; izfr yhVj foy;u
(C) 3 M CH3COOH foy;u (r) % w/v = 18%
(D) 1 M H2SO4 foy;u (s) % w/v = 9.8%
Ans. (A - p, q, r) ; (B - q, r) ; (C - q, r) ; (D - p, s)
Sol. (A) 1 M glucose solution  1mole of solute/L
 180 g solute/L
      (180 g/1000)× 100 = 18% (w/v)
(B) 3 M urea solution (NH2CoNH2)  3 mole of solute/L
      (60 × 3)g of solute/L
 (180 g/1000)× 100 = 18% (w/v)
(C) 3 M CH3COOH solution  3 mole of solute/L
 (3 × 60)g of solute/L
 (180 g/1000)× 100 = 18% (w/v)
(D) 1 M H2SO4 solution  1 mole of solute/L
 98g of solute/L
98
  100 = 9.8 % (w/v)
1000
gy % (A) 1 M Xywdksl foy;u  1eksy foys; /L
 180 g foys;/L
      (180 g/1000)× 100 = 18% (w/v)
(B) 3 M ;wfj;k foy;u (NH2CoNH2)  3 eksy foys;/L
      (60 × 3)g foys;/L
 (180 g/1000)× 100 = 18% (w/v)
PAGE NO.-33
(C) 3 M CH3COOH foy;u  3 eksy foys;/L
 (3 × 60)g foys;/L
 (180 g/1000)× 100 = 18% (w/v)
(D) 1 M H2SO4 foy;u  1 eksy foys;/L
98
 98g foys;/L   100 = 9.8 % (w/v)
1000
ChemINFO Estimation of Phosphorus

Daily Self-Study Dosage for mastering Chemistry Estimation of Phosphorous
First method :
A known mass of compound is heated with fuming HNO 3 which converts phosphorous to H3PO4
(phosphoric acid). It is precipitated as ammonium phospho molybdate [(NH 4)3.PO4.12 MoO3] by adding
NH3 and ammonium molybdate [(NH4)2 MoO2]. It is filtered, dried, and weighed. (molar mass of
ammonium phospho molybdate = 1877 gram)
Atomic mass of P Mass of ammonium phospho molybdate
Percentage of P = × ×100
Molecular mass of ammonium phospho molybdate Mass of compound
Second Method :
A known mass of compound is heated with fuming HNO3 which converts phosphorous to H3PO4.
Magnesia mixture (MgCl2 + NH4Cl) is then added, which gives the precipitate of magnesium ammonium
phosphate (MgNH4.PO4) which on heating gives magnesium pyrophosphate (Mg 2P2O7), which is
weighed.
2 × Atomic mass of P mass of Mg 2P2O 7
Percentage of P = × × 100
Molecular mass of Mg2P2O7 mass of compound
15. In the quantitative estimation of phosphorous by using magnesia mixture, the formula used is where
(w = mass of Mg2 P2 O7 W = mass of compound)
62 w  100 31 W  100
(A) Pecentage of P   (B) Pecentage of P  
222 W 222 w
62 W  100 31 w  100
(C*) Pecentage of P   (D) Pecentage of P  
222 w 222 W
Where w is the mass of Mg2P2O7 and W is the mass of the compound.
16. In the quantitative estimation of phosphorous by using ammonium molybdate, the formula used is
where w = mass of ammonium phospho molybdate.
W = Mass of compound) :
62 w  100 62 W  100
(A) Percentage of P   (B) Percentage of P  
1877 W 1877 w
31 w  100 31 W  100
(C) Percentage of P   (D*) Percentage of P  
1877 W 1877 w
where w is the mass of ammonium phospho molybdate and W is the mass of the compound.
ChemINFO Estimation of Phosphorus

Daily Self-Study Dosage for mastering Chemistry QkWLQksjl dk xq.kkRed vkadyu
izFke fof/k :
tc ,d vKkr nzO;eku okys ;kSfxd dks la/kwez HNO3 ds lkFk xeZ djrs gS rks QkWLQksjl H3PO4 esa ifjofrZr gks tkrk
gSA blesa NH3 rFkk veksfu;e eksfyCMsV [(NH4)2 MoO2] feykus ij veksfu;e QkWLQkseksfyCMsV [(NH4)3 .PO4.12
MoO3] dk vo{ksi izkIr gksrk gSA bl vo{ksi dks Nku dj] /kks dj lq[kk ysrs gS rFkk blds Hkkj dh rkSyus ds ckn
x.kuk dh tkrh gSA
P dk ijek.kq Hkkj veksfu;e QkWLQks eksfyCMsV dk v.kqHkkj
P dk izfr'kr = × × 100
veksfu;e QkWLQks eksfyCMsV dk v.kqHkkj ;kSfxd dk Hkkj
PAGE NO.-34
f}rh; fof/k :
tc ,d vKkr nzO;eku okysa ;kSfxd dks la/kwez HNO3 ds lkFk xeZ djrs gS rks QkWLQksjl H3PO4 esa ifjofrZr gks tkrk
gSA blds ckn blesa eSXuhf'k;k (MgCl2 + NH4Cl) dk feJ.k feyk;k tkrk gSA ftlds ifj.kkeLo:i eSaXuhf'k;e
veksfu;e QkWLQsV (MgNH4.PO4) dk vo{ksi izkIr gksrk gS tks xeZ djus ij eSaXuhf'k;e ik;jksQkWLQsV (Mg2P2O7)
nsrk gS] ftlds Hkkj dh rkSyus ds ckn x.kuk dh tkrh gSA
2  P dk ijek.kq Hkkj Mg2P2O7 dk Hkkj
P dk çfr'kr =   100
Mg2P2O7 dk v.kq Hkkj ;kSfxd dk Hkkj
15. eSXuhf'k;k feJ.k feykdj QkWLQksjl ds xq.kkRed vkadyu esa fuEu esa ls fdl lw=k dk mi;ksx djrs gS :
62 w  100 31 W  100
(A) P dk izfr'kr =  (B) P dk izfr'kr = 
222 W 222 w
62 W  100 31 w  100
(C*) P dk izfr'kr =  (D) P dk izfr'kr = 
222 w 222 W
tgkW w = Mg2P2O7 dk Hkkj gS rFkk W ;kSfxd dk Hkkj gSaA
16. veksfu;e eksfyCMsV feykdj QkWLQksjl ds xq.kkRed vkadyu esa fuEu esa ls fdl lw=k dk mi;ksx djrs gS :
62 w  100 62 W  100
(A) P dk izfr'kr =  (B) P dk izfr'kr = 
1877 W 1877 w
31 w  100 31 W  100
(C) P dk izfr'kr =  (D*) P dk izfr'kr = 
1877 W 1877 w
tgk¡ w = veksfu;e QkWLQkseksfyCMsV dk Hkkj gS rFkk W ;kSfxd dk Hkkj gSA
P-CH EM ISTRY


EST INFORM AT IO
DPP

Multiple choice objective ('–1' negative marking) Q.6 (4 marks, 2 min.) [04, 02]
Single Integer type Questions ('–1' negative marking) Q.07 to Q.11 (4 marks 3 min.) [20, 15]
Matching List Type (Only One options correct) ('–1' negative marking) Q.12 (3 marks, 2 min.) [03, 02]
1. (A) 2. (A) 3. (D) 4. (A) 5. (B) 6. (BC) 7. 5
8. 7 9. 5 10. 76 11. 6 12. (D)
1. Which series of subshells is arranged in the order of increasing energy for multi-electron atoms?
cgqbysDVªkWu ijek.kq ds fy, c<+rh ÅtkZ ds Øe esa dkSulh midks'k Js.kh dks O;ofLFkr fd;k x;k gSA
(A*) 6s, 4f, 5d, 6p (B) 4f, 6s, 5d, 6p (C) 5d, 4f, 6s, 6p (D) 4f, 5d, 6s, 6p
Sol. Use (n+l) rule.
gy- (n+l) fu;e dk mi;ksxA
2. If the uncertainty in velocity and position is same, then the uncertainty in momentum will be:
;fn osx rFkk fLFkfr esa vfuf'prrk leku gS] rks laosx esa vfuf'prrk gksxhA
hm h h 1 h
(A*) (B) m (C) (D)
4 4 4 m m 4
PAGE NO.-35
h h
Sol. x = ; x p =
4 m 4
h h mh
; p = ; p =
4 m 4 4
3. 10 moles of CO2 do not contain :
(A) 120 g of C (B) 20 gram-atoms of O
(C) 30 NA atoms (D*) 160 g of O
CO2 ds 10 eksy ugh j[krs gSA
(A) C ds 120 xzke dks (B) O ds 20 xzke&ijek.kqvksa dks
(C) 30 NA ijek.kqvksa dks (D*) O ds 160 xzke dks
4. Maximum number of electrons in a subshell with  = 3 and n = 4 is :

,d midks'k esa] ftlds fy;s  = 3 rFkk n = 4 gS] bysDVªkWuksa dh vf/kdre la[;k gS %
(A*) 14 (B) 16 (C) 10 (D) 12
Sol. (n = 4,  = 3)  4f subshell
So, total No. of electron in subshell = 2 (2  + 1) = 2 (2 × 3 + 1) = 14 electron.
gy- (n = 4,  = 3)  4f midks'k
vr%] midks'k esa bysDVªkWuksa dh dqy la[;k = 2 (2  + 1) = 2 (2 × 3 + 1) = 14 bysDVªkWu
5. Photoelectric emission is observed from a surface for frequencies 1 and 2 of the incident radiation
(1 >2). If the maximum kinetic energies of the photoelectrons in the two cases are in the ration 1: k
then the threshold frequency 0 is given by
,d lrg ij 1 rFkk 2 vko`fr dh fofdj.k (1 >2) Mkyus ij QksVks bysDVªkWfud izHkko izkIr gkskr gSA ;fn nks
ifjLFkfr;ksa esa QksVks bysDVªkWuks dh vf/kdre xfrt ÅtkZ dk vuqikr 1: k gS rc nsgyh vko`fr 0 fdlds }kjk nh tk
ldrh gSA
2  1 k1  2 k2  1 2  1
(A) (B*) (C) (D)
k 1 k 1 k 1 k
Sol. h1 = h0 + KE1 , KE1 = h(1 – 0)
h2 = h0 + KE2 , KE2 = h(2 – 0)
KE1 1   0
= = 1
KE2 k 2  0
2 – 0 = k1 – k0
k  2
0= 1
k 1
6.* Which is/are correct graph(s) ?
fuEu esa ls dkSulk@dkSuls vkjs[k lgh gSA 
(A) (B*) (C*) (D)
Intensity of light
at same frequency
7. The potential difference applied on the metal surface to reduce the velocity of photoelectron to zero is
known as Stopping Potential. When a beam of photons of wavelength 40 nm was incident on a surface
of a particular pure metal, some emitted photoelectrons had stopping potential equal to 18.6 V, some
had 12 V and rest had lower values. Calculate the threshold wavelength (0) of the metal (in Å)
assuming that at least one photoelectron is ejected with maximum possible kinetic energy.
(hc = 12400eVÅ) Report your answer after dividing by 200.
/kkrq dh lrg ls mRlftZr bysDVªkWu dh xfrt ÅtkZ] 'kwU; djus ds fy;s vko';d foHko dks fujksèkh foHko (Stopping
Potential) dgrs gSaA rjax&nS/;Z 40 nm ds QksVkWuksa dks ;fn ,d 'kq) /kkrq dh lrg ij vkifrr fd;k tkrk gS] rks
PAGE NO.-36
/kkrq ls mRlftZr dqN izdkf'k; bysDVªkWuksa dk fujksèkh foHko (stopping potential) 18.6 V ds cjkcj] dqN dk 12 V
rFkk 'ks"k dk 12 V ls de ik;k tkrk gSA èkkrq dh nsgyh rjax&nS/;Z (0) (Å esa) Kkr dhft,A ¼;g ekusa fd mRlftZr
izdkf'k; bysDVªkWuksa esa de ls de ,d izdkf'k; bysDVªkWu] vf/kdre laHko xfrt ÅtkZ j[krk gS½ (hc = 12400 eVÅ)
viuk mÙkj 200 ls foHkkftr dj ds nsaA
Ans. 5
Sol. The maximum KE of potoelectron is corresponding to maximum stopping = 18.6 eV
Eincident = W + KEmax
12400
eV = W + 18.6 eV
400
W = 12.4 eV
12400
 0 = Å = 1000 Å
12.4
8. When the valve connecting (A) and (B) is opened, V = 10 L V = 30 L

the gases mix. The mixture is then sparked and P1 = 5 atm
50% of N2 reacts to give NO(g). If final temperature N2(g) O2(g) P2 = 3 atm
TA = TB = 300K
of the vessels is two times initial temperature, find P1 P2
final pressure in the vessel. (Give answer in atm)
(A)
(B)
tc (A) o (B) dks tksM+us okys okYo dks [kqyk j[kk tkrk gS V = 10 L V = 30 L
P1 = 5 atm
rks xSl fefJr gksrh gSA feJ.k esa fQj LikdZ (sparked)
N2(g) O2(g) P2 = 3 atm
fd;k tkrk gS o 50% N2 fØ;k dj] NO(g) nsrk gSA ;fn P1 P2
TA = TB = 300K
ik=kksa esa vfUre rkieku] izkjafHkd rkieku dk nqxquk gks] rks
ik=k esa vfUre nkc Kkr dhft, (atm esa mÙkj nhft,) (A)
(B)
Ans. 7
Sol. On opening the valve.
okWYo dks [kqyk djus ij
140
Pf × (10 + 30) = 5 × 10 + 3 × 30 =
40
7
Pf = atm
2
Consider reaction
vfHkfØ;k dk voyksdu djus ij
N2 (g) + O2 (g)   2NO (g)
t=0 a b 0 (moles) ¼eksy½
a a a
finally vUrr % a  b 2  (moles) ¼eksy½
2 2 2
total initial moles = a + b
dqy izkjafHkd eksy = a + b
a a
total final moles = a  + b  + a
2 2
a a
dqy vfUre eksy = a  + b  + a = a + b
2 2
So initial moles = final moles
blfy, izkjafHkd eksy = vfUre eksy
 We are simply doubling the temperature after reaction.
ge vfHkfØ;k ds i'pkr rkieku dks nqxquk djrs gSA
 On doubling the temperature at constant volume and moles, pressure doubles.
fu;r vk;ru ij rkieku dks nqxquk djus ij eksy o nkc nqxqus gks tkrs gSA
PAGE NO.-37
7
So Finally pressure = 2  atm = 7 atm
2
7
blfy, vfUre nkc = 2  atm = 7 atm
2
9. The stopcock, connecting the two bulbs of volume 8 litre and 10 litre containing an ideal gas at 6.25 atm
and 4 atm respectively, is opened. What is the final gas pressure, if the temperature remains same?
nks cYc] ftudk vk;ru 8 yhVj vkSj 10 yhVj gS rFkk ftuesa Øe'k% 6.25 atm rFkk 4 atm ij ,d vkn'kZ xSl gS]
LVkWidkWd }kjk tqMs+ gSaA ;fn rki fu;r jgs] rks LVkWidkWd [kksyus ds ckn vfUre nkc dh x.kuk djksA
Ans. 5
Sol. After the opening of the stop cock the pressure of the each bulb will remain same.
10 x 4
At the beginning, the no. of moles of gas in A =
RT
6.25 x 8
At the beginning, the no. of moles of gas in B =
RT
90
 total no. of mole at the beginning =
RT
Total no. of mole of gas before opening the stop cock

90
= total no. of moles of gas after opening stop cock =
RT
 pressure after the opening of the stop cock
90 RT 90
P= x = = 5 atm
RT Vtotal 10  8
10. Two glass bulbs of equal volume are filled with an ideal gas at 500 K and pressure of 76 cm of Hg and
are connected by a narrow tube. One of the bulb is then placed in a water bath maintained at 700 K and
the other bulb is maintained at 500 K. What is the new value of the pressure (in cm of Hg) inside the
6
bulbs? The volume of the connecting tube is negligible. Report your answer after multiplying by .
7
,d ladjh uyh }kjk] leku vk;ru ds nks dk¡p ds cYc] ftuesa Hg ds 76 cm nkc rFkk 500 K ij ,d vkn'kZ xSl
Hkjh gS] dks la;ksftr fd;k tkrk gSA buesa ls ,d cYc dks 700 K ij LFkkfir ty ds Vc esa j[kk tkrk gS rFkk nwljs
cYc dks 500 K ij dk;e j[kk tkrk gSA cYcksa ds vUnj nkc dk u;k eku (Hg ds cm esa) D;k gS\ la;ksftr djus
6
okyh uyh dk vk;ru ux.; gSA viuk mÙkj ls xq.kk djus ds i'pkr~ nhft,A
7
Ans. 76
11. If oxidation number per atom of phosphorous is x on reactant side and that of silicon is y on product
side, find 2x – y.
Ca3(PO4)2 + SiO2 + C  CaSiO3 + P4 + CO
;fn vfHkdkjd dh rjQ QkLQksjl dh izfr ijek.kq vkWDlhdj.k la[;k x gS rFkk mRikn dh rjQ flfydkWu dh izfr
ijek.kq vkWDlhdj.k la[;k y gS rc 2x–y Kkr djsA
Ca3(PO4)2 + SiO2 + C  CaSiO3 + P4 + CO
Ans. 6
Sol. Oxidation number of P in Ca3(PO4)2 = + 5 = x
Oxidation number of Si in CaSiO3 = + 4 = y
2x – y = 6.
Sol. Ca3(PO4)2 esa P dh vkWDlhdj.k la[;k = + 5 = x
CaSiO3 esa Si dh vkWDlhdj.k la[;k = + 4 = y
2x – y = 6.
PAGE NO.-38
12. Match the following :
Column  Column 
(A) Binding energy of 5th excited state of Li2+ sample (p) 10.2 V
(B) st excitation potential of H-atom (q) 3.4 eV
(C) 2nd excitation potential of He+ ion (r) 13.6 eV
(D) I.E. of H-atom (s) 48.4 V
LrEHk  LrEHk 
(A) Li++ uewus dh 5th mÙksftr voLFkk dh cU/ku ÅtkZ (p) 10.2 V
(B) H-ijek.kq dk st mÙkstu foHko (q) 3.4 eV
(C) He+ dk 2nd mÙkstu foHko (r) 13.6 eV
(D) H-ijek.kq dh vk;uu ÅtkZ (s) 48.4 V
(A) [A  r] ; [B  p] ; [C  s] ; [D  q] (B) [A  s] ; [B  p] ; [C  q] ; [D  r]
(C) [A  q] ; [B  r] ; [C  s] ; [D  p] (D*) [A  q] ; [B  p] ; [C  s] ; [D  r].
Sol. (A) Transition n  6 to n For Li2+ sample
(B) Transition n  1 to n 2 For H-atom sample
(C) Transition n  1 to n 3 For He+ sample
(D) Transition n  1 to n For H-atom sample
gy % (A) laØe.k n  6 to n Li2+ ds fy,
(B) laØe.k n  1 to n 2 H-ijek.kq ds fy,
(C) laØe.k n  1 to n 3 He+ ds fy,
(D) laØe.k n  1 to n H-ijek.kq ds fy,
P-CH EM ISTRY

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EST INFORM AT IO
DPP

ANSWER KEY
1. (A) 2. (B) 3. (A) 4. (B) 5. (A) 6. (A) 7. (A)
8. (C) 9. (B) 10. (B) 11. (C) 12. (D) 13. (D) 14. (A)
15. (A) 16. (A)
1. Equal masses of Sulphur dioxide and Oxygen gases are mixed in an empty container at 25°C. The
fraction of the total pressure exerted by sulphur dioxide is : (Assume no chemical reaction)
,d [kkyh ik=k esa lYQj MkbvkWDlkbM vkSj vkWDlhtu xSlksa dks 25°C ij leku ek=kk esa feykrs gSaA SO2 ds }kjk
Mkyk x;k nkc] dqy nkc dk fdruk Hkkx gS % ¼dksbZ jklk;fud vfHkfØ;k u ekusa½
(A*) 1/3 (B) 1/2 (C) 2/3 (D) 1/5
Sol. Let the mass of SO2 and oxygen be m g. Mole fraction of SO2, XSO2
m
64 m 32 1
= =  = Let the total pressure be P.
m m 32 3m 3

64 32
PAGE NO.-39
1 1
 Partial pressure of SO2, PSO2 = P × XSO2 = P. P×
3 3
2. At constant volume and temperature conditions, the rates of diffusion r A and rB of gases A and B having
densities A and B are related by the expression :
fu;r rki rFkk nkc dh ifjfLFkfr;ksa ij] xSl A rFkk B dh folj.k dh nj rA rFkk rB gS rFkk ftldk ?kuRo A rFkk
B gS] buds eè; lEcUèk fuEu gksxkA
(A) rA = rB (A /B) (B*) rA = rB (B /A)½ (C) rA = rB (B /A) (D) rA = rB (A /B)½
3. The ratio of rates of diffusion of SO2, O2 and CH4 under identical conditions is :
leku ifjfLFkfr;ksa esa SO2, O2 vkSj CH4 ds folj.k (diffusion) dh njksa dk vuqikr fuEu gS
(A*) 1 : 2 :2 (B) 1 : 2 : 4 (C) 2 : 2:1 (D) 1 : 2 : 2
4. The molecular weight of a gas, which diffuse through a porous plug at 1/6th of the speed of hydrogen
under identical conditions, is :
leku ifjfLFkfr;ksa ds vUrZxr] gkbMªkstu ds 1/6th osx ls ,d laj/kzh Iyx esa ls folfjr xSl dk vkf.od nzO;eku
fuEu gS %
(A) 12 u (B*) 72 u (C) 36 u (D) 24 u
1 2
Sol. = (Where X is molecular weight of gas) (;gk¡ X xSl dk v.kqHkkj gS)
6 x
1 2
=
36 x
x = 72
5. Molecular weight of a gas that diffuses twice as rapidly as the gas with molecular weight 64 is :
(assume identical conditions)
,d xSl] tks vkf.od nzO;eku 64 okyh xSl ls nks xquk rhoz xfr ls folfjr gksrh gS] ml xSl dk vkf.od nzO;eku
fuEu gS% ¼leku ifjfLFkfr;k¡ ekusa½
(A*) 16 (B) 8 (C) 256 (D) 32
Sol. M1  64 ; r2  2r1
2
r  1
M2  M1  1   64   16
 2
r 4
6. The ratio of the rate of diffusion of a given element to that of helium is 1.414. The molecular weight of
the element is: (assume same temperature and pressure)
,d fn;s x;s rRo ,oa ghfy;e ds folj.k dh nj dk vuqikr 1.414 gSA ml rRo dk vkf.od nzO;eku fuEu gS %
¼leku rki ,oa nkc ekusa½
(A*) 2 (B) 4 (C) 8 (D) 16
rg MHe r 2He 4 4
Sol.   Mg  MHe . 2   2
rHe Mg r g (1.4)2 1.96
Note :1.4  2 
 
7. 5 mL of He gas diffuses out in 1 second from a hole. Find the volume of SO 2 that will diffuse out from
the same hole under identical conditions in 2 seconds.
,d fNnz ls 1 lsd.M esa He xSl dk 5 mL folfjr fd;k tkrk gSA SO2 dk og vk;ru Kkr dhft,] tks 2 lsd.M esa
leku ifjfLFkfr;ksa ds vUrxZr leku fNnz ls folfjr fd;k tkrk gks A
(A*) 2.5 mL (B) 1.25 mL (C) 1.77 mL (D) 5 mL
5mL
Sol. Rate of diffusion of He = = 5ml/s = rHe (say)
15
1 1
rSO2 = rHe × = 5ml/s ×
4 4
PAGE NO.-40
5
Volume of SO2 diffused in 2.0 seconds = × 2 ml = 2.5 ml Ans.
4
8. The rate of effusion of helium gas at a pressure of 1000 torr is 10 torr min –1. What will be the rate of
effusion of hydrogen gas at a pressure of 2000 torr at the same temperature?
1000 torr ds ,d nkc ij ghfy;e xSl ds fulj.k dh nj 10 torr min–1 gSaA leku rkieku ij 2000 torr ds nkc
ij gkbMªkstu xSl ds fulj.k dh nj D;k gksxh \
(A) 20 torr min–1 (B) 40 torr min–1 (C*) 20 2 torr min–1 (D) 10 torr min–1
9. A bottle of dry NH3 & a bottle of dry HCl connected through a long tube are opened simultaneously
under identical conditions at both ends. The white ammonium chloride ring first formed will be:
,d yEch ufydk }kjk ,d 'kq"d NH3 dh cksry rFkk ,d 'kq"d HCl dh cksry dks tksM+k tkrk gS rFkk nksuksa cksryksa
dks leku ifjfLFkfr;ksa esa ,d lkFk [kksyk tkrk gS] rks 'osr veksfu;e DyksjkbM oy;] izFke ckj fuEu ij cusxk %
(A) at the centre of the tube (B*) near the HCl bottle
(C) near the NH3 bottle (D) throughout the length of tube
(A) V~;wc ds dsUnz ij (B*) HCl cksry ds fudV
(C) NH3 cksry ds fudV (D) V~;wc dh lEiw.kZ yEckbZ ij
10. At room temperature, A2 gas (vapour density = 40) and B2 gas are allowed to diffuse through identical
pinholes from opposite ends of a glass tube of 1m length and of uniform cross-section. The two gases
first meet at a distance of 60 cm from the A2 end. The molecular mass of B2 gas is :
dejs ds rki ij] A2 xSl (ok"i ?kuRo = 40) dks rFkk B2 xSl dks ,d leku vuqizLFk dkV ¼cross-section½ rFkk 1m
yEckbZ okyh dk¡p dh ufydk ds foijhr fljksa ij fLFkr nks le:ih lw{e fNnzksa }kjk folfjr fd;k tkrk gSA nksuksa
xSlas] izFke ckj A2 fljs ls 60 cm dh nwjh ij feyrh gSaA rc B2 xSl dk vkf.od nzO;eku fuEu gS :
(A) 90 u (B*) 180 u (C) 45 u (D) 35.5 u
rA 2 VDB2
Sol. =
rB2 VDA 2
60 / t VD1
=
40 / t 40
VD1 = 90
M1 = 180 u
11. A mixture containing 2 moles of He and 1 mole of CH 4 is taken in a closed container and made to
effuse through a small orifice of container. Then, which is the correct effused volume percentage of He
and CH4 initially, respectively :
,d can ik=k esa 2 eksy He rFkk 1 eksy CH4 ;qDr ,d feJ.k fy;k tkrk gS rFkk bls ,d lw{e fNnz ls folfjr fd;k
tkrk gSA rc fuEu esa ls dkSu] Øe'k% He rFkk CH4 ds izkjfEHkd folfjr vk;ruksa dh lgh izfr'krrk n'kkZrk gS %
(A) 40%, 60% (B) 20%, 80% (C*) 80%, 20% (D) 60%, 40%
Sol. Rate of diffusion of He = r1
rate of diffusion of CH4 = r2
r1 n M2 2 16 4
= 1 = =
r2 n 2 M1 1 4 1
4
Diffused mole of He =  100 = 80%
5
1
Diffused mole of CH4 =  100 = 20%
5
He ds folj.k dh xfr = r1
CH4 ds folj.k dh xfr = r2
r1 n M2 2 16 4
= 1 = =
r2 n2 M1 1 4 1
PAGE NO.-41
4
He ds folfjr eksy =  100 = 80%
5
1
CH4 ds folfjr eksy =  100 = 20%
5
12. At same temperature and pressure, which of the following gases will have same average translational
kinetic energy per mole as N2O :
(A) He (B) H2S (C) CO2 (D*) All of these
leku rki o nkc ij fuEu esa dkSulh xSl¼lsa½] N2O ds leku çfr eksy vkSlr LFkkukUrj.k xfrt ÅtkZ j[kasxh %
(A) He (B) H2S (C) CO2 (D*) mijksDr lHkh
13. At what temperature, will hydrogen molecules have the same average translational kinetic energy as
nitrogen molecules have, at 35°C?
fdl rki ij gkbMªkstu v.kqvksa dh vkSlr LFkkukUrj.k xfrt ÅtkZ] ukbVªkstu v.kqvksa dh 35°C ij vkSlr LFkkukUrj.k
xfrt ÅtkZ ds cjkcj gksxh %
 28  35   2  35   2  28 
(A)   °C (B) 
 28 
(C) 
 35 
°C °C (D*) 35 °C
 2 
14. Average translational K.E. of one mole of helium gas at 273 K in calories is :
273 K ij ,d eksy ghfy;e xSl dh vkSlr LFkkukUrj.k xfrt ÅtkZ] dSyksjh esa fuEu gS %
(A*) 819 (B) 81.9 (C) 3412.5 (D) 34.125
15. A sample of gas contains N1 molecules and the average translational kinetic energy at – 123°C is E1
ergs. Another sample of gas at 27°C has average translational kinetic energy as 2E 1 ergs. Assuming
gases to be ideal, the number of gas molecule in the second sample will be
xSl dk ,d uewuk N1 v.kq ;qDr gS rFkk – 123°C ij vkSlr LFkkukarj.k xfrt ÅtkZ E1 vxZ gSA 27°C ij xSl ds
,d vU; uewus dh vkSlr LFkkukarj.k xfrt ÅtkZ 2E1 vxZ gSA vkn'kZ xSl ekurs gq,] f}rh; uewus esa xSl v.kq dh
la[;k fuEu gksxh%
N1
(A*) N1 (B) (C) 2N1 (D) 4N1
4
16. If average kinetic energy of the molecules in 5 L of He at 2 atm is E, then average kinetic energy of the
same number of molecules in 15 L of Ne at 3 atm in terms of E is .......... :
;fn 5 L He esa 2 atm nkc ij] v.kqvksa dh vkSlr~ xfrt ÅtkZ E gS] rks E ds inksa esa] 3 atm ij 15 L Ne esa leku
v.kqvksa dh la[;k dh vkSlr~ xfrt ÅtkZ .......... gSA
(A*) 4.5 E (B) E (C) 0.9 E (D) 22.5 E
P-CH EM ISTRY


EST INFORM AT IO
DPP

Match the column (no negative marking) Q.12 (8 marks 6 min.) [08, 06]
PAGE NO.-42
ANSWER KEY
1. (D) 2. (A) 3. (B) 4. (D) 5. (C) 6. (AC) 7. (BCD)
8. (CD) 9. 6 10. 8 11. 60 12. (A) – q, r ; (B) – s ; (C) – p ; (D) – q
13. (C) 14. (B) 15. (D) 16. (D)
1. Equal amount (mass) of methane and ethane have their total translational kinetic energy in the ratio
3 : 1 then their temperatures are in the ratio.
leku ek=kk ¼nzO;eku½ ds esFksu rFkk ,sFksu ds fy, dqy LFkkukUrfjr xfrt ÅtkZ dk vuqikr 3 : 1 gS rc muds
rkiekuksa dk vuqikr fuEu gS&
(A) 5 : 8 (B) 45 : 8 (C) 15 : 8 (D*) 8 : 5
3 M
Sol. E1 =  RT1
2 16
3 M E1 30 T1 T1 8 3 30 T1
E2 =  RT2       .
2 30 E2 16 T2 T2 5 1 16 T2
2. At a definite temperature (T), the distribution of velocities is given by the

curve. The curve that indicates that the velocities corresponding to points
A, B and C are :
(A) most probable, average and root mean square
(B) average, root mean square and most probable
(C) root mean square, average and most probable
(D) most probable, root mean square and average
,d fuf'pr rkieku ij] osx ds forj.k dks oØ }kjk fn;k x;k gS rks oØ esa
fcUnq A, B rFkk C ds lUnHkZ esa osx gS %
(A*) lokZf/kd lEHkkfor] vkSlr rFkk oxZ ek/; ewy
(B) vkSlr] oxZ ek/; ewy rFkk lokZf/kd lEHkkfor
(C) oxZ ek/; ewy] vkSlr rFkk lokZf/kd lEHkkfor
(D) lokZf/kd lEHkkfor] oxZ ek/; ewy rFkk vkSlr
3. The graphs representing distribution of molecular speeds at 300

K for gases Cl2 and N2 are as shown below (Atomic mass N =
14, Cl = 35.5)
(A)  graph is for N2 and  is for Cl2   
(B*)  graph is for N2 and  is for Cl2
(C) either graph can be taken for N2 or Cl2
(D) information is not sufficient
300 K rkieku ij xSl Cl2 ,oa N2 ds fy, v.kqvksa dh xfr ds forj.k dks
fuEu xzkQ esa çnf'kZr fd;k x;k gS& (v.kqHkkj N = 14 , Cl = 35.5)
(A)  xzkQ N2 dk o  xzkQ Cl2 dk gSA
(B*)  xzkQ N2 dk o  xzkQ dk Cl2 dk gSA
(C) dksbZ Hkh xzkQ Cl2 o N2 dk gks ldrk gSA
(D) lwpuk i;kZIr ugha gSA
Sol. Mol. wt. of Cl2 is more than molecular weight of N2.
gy- Cl2 dk v.kqHkkj] N2 ds v.kqHkkj ls vf/kd gSA
4. The root mean square velocity of an ideal gas at constant pressure varies with density (d) as:
fu;r nkc ij ,d vkn'kZ xSl ds fy, oxZ ek/; ewy (vrms) osx] ?kuRo (d) ds lkFk fuEu izdkj ls ifjofrZr gksrk gS %
(A) d2 (B) d (C) d (D*) 1 d
3RT
Sol. Urms = using ideal gas equation,
M
PAGE NO.-43
w RT RV P
PV = nRT = RT;   where d is the density of the gas
M M w d
3P 1
 Urms = at constant pressure, Urms 
d d
3RT
Urms = vkn'kZ xSl lehdj.k dk mi;ksx dj
M
w RT RV P
PV = nRT = RT;   ;gk¡ d xSl dk ?kuRo gSA
M M w d
3P 1
 Urms = fu;r nkc ij , Urms 
d d
5. In Haber process, 30 litres of dihydrogen and 30 litres of dinitrogen were taken for reaction which
yielded only 50% of the expected product. What will be the composition of gaseous mixture under the
given condition in the end ?
(A) 20 litres ammonia, 25 litres dinitrogen, 15 litres dihydrogen
(B) 20 litres ammonia, 20 litres dinitrogen, 20 litres dihydrogen
(C*) 10 litres ammonia, 25 litres dinitrogen, 15 litres dihydrogen
(D) 20 litres ammonia, 10 litres dinitrogen, 30 litres dihydrogen
gscj fof/k esa f}gkbMªkstu ds 30 yhVj vkSj f}ukbVªkstu ds 30 yhVj vfHkfØ;k ds fy, fy;s x;s] ftlesa vuqekfur
mRikn dh dsoy 50% dh yfC/k gksrh gSA Åij nh xbZ ifjfLFkfr ds vuq:i xSlh; feJ.k dk laxBu D;k gksxk\
(A) 20 yhVj veksfu;k, 25 yhVj f}ukbVªkstu, 15 yhVj f}gkbMªkstu
(B) 20 yhVj veksfu;k, 20 yhVj f}ukbVªkstu, 20 yhVj f}gkbMªkstu
(C*) 10 yhVj veksfu;k, 25 yhVj f}ukbVªkstu, 15 yhVj f}gkbMªkstu
(D) 20 yhVj veksfu;k, 10 yhVj f}ukbVªkstu, 30 yhVj f}gkbMªkstu
6.* An equimolar mixture of CO and O2 is exploded to produce CO2. Which of the following is/are correct ?
(A*) The initial vapour density of the mixture is 15.
(B) The average molar mass of final mixture is less than that of initial mixture.
(C*) CO is limiting reagent.
(D) Mole % of CO2 in the final mixture is 50%.
CO o O2 dk ,d leeksyj feJ.k] foLQksfVr gksdj CO2 nsrk gSA fuEu esa ls dkSulk@dkSuls lgh gS@gSa\
(A*) feJ.k dk izkjfEHkd ok"i ?kuRo 15 gSA
(B) vfUre feJ.k dk vkSlr eksyj nzO;eku izkjfEHkd feJ.k ds vkSlr nzO;eku ls de gksrk gSA
(C*) CO lhekUr vfHkdeZd gSA
(D) vfUre feJ.k esa CO2 dk eksy izfr'kr 50% gSA
Sol. L.R.
2CO + O2  2CO2
1 1
CO is L.R. (CO L.R. gSA)
M 1  28  1  32 60
V.D. of mixture (feJ.k dk V.D.) = mix = = = 15.
2 (1  1)  2 22
As number of moles are decreasing Mav of mixture increases.
(pwafd eksyksa dh la[;k de gksrh gS] rks feJ.k dk Mav esa o`f) gksrh gSA)
moles of CO2 produced (mRikfnr CO2 ds eksy) = 1
1 1
moles of O2 left ('ks"k cps CO2 ds eksy) = 1– =
2 2
1
mole % of CO2 (CO2 dk eksy %) = × 100 = 66.6 %
1  0.5
PAGE NO.-44
7.* Which of the following are examples of disproportionation reactions?
buesa ls dkSuls folekuqikrh vfHkfØ;k,sa (disproportionation reactions) gSa\
(A) Ag(NH3)2+ + 2H+  Ag+ + 2NH4+
(B*) Cl2 + OH– ClO– + Cl– + H2O
(C*) Cu2O + 2H+ Cu + Cu+2 + H2O
dil. with H O
(D*) 2HCuCl2 
2
Cu + Cu2+ + 4Cl– + 2H+
8.* The time taken for effusion of 32 mL of oxygen gas will be the same as the time taken for effusion of
which gas sample under identical conditions: (Take 2 = 1.4, 3 = 1.7)
32 mL vkWDlhtu xSl ds fulj.k esa fy;k x;k le;] leku ifjfLFkfr;ksa esa fuEu esa ls dkSuls xSl çkn'kZ ds fulj.k
esa fy, x;s le; ds leku gksxk % (yhft,% 2 = 1.4, 3 = 1.7)
(A) 64 mL H2 (B) 50 mL N2 (C*) 44.8 mL CH4 (D*) 22.4 mL SO2
9. Let the total number of orbitals in ath shell be 16 and value of azimuthal quantum number for the
unpaired electron in vanadium atom (Z = 23) be 'b', then find the sum (a + b).
ekuk fd ath dks'k esa d{kdksa dh dqy la[;k 16 gS rFkk osusfM;e ijek.kq (Z = 23) esa v;qfXer bysDVªkWu ds fy,
f}xa'kh DokaVe la[;k dk eku 'b' gS rc (a + b) ds ;ksx dk eku Kkr dhft,A
Ans. 6
Sol. Total number of orbitals in ath shell = a2 = 16
 a = 4.
value of  for unpaired electron in V atom = 2. ( 3d orbital)
 b=2
 (a + b) = 4 + 2 = 6.
gy. a dks'k esa d{kdksa dh dqy la[;k = a2 = 16
th
 a = 4.
V ijek.kq esa] v;qfXer bysDVªkWu ds fy,  dk eku = 2. ( 3d d{kd)
 b=2
 (a + b) = 4 + 2 = 6.
10. 100 mL of sulphuric acid solution (sp. gr. = 1.84) contains 98% by weight of pure acid. Calculate the
volume of 0.46 M NaOH solution (in L) required to just neutralize the above acid solution.
100 mL lY¶;wfjd vEy foy;u (fof'k"V ?kuRo = 1.84), nzO;eku ls 98% 'kq) vEy j[krk gSA 0.46 M NaOH
foy;u ds ml vk;ru dh x.kuk (L esa) djks] tks mijksDr vEy ds foy;u dks mnklhu djus ds fy;s vko';d gSA
Ans. 8
Sol. For neutralisation
¼mnklhfudj.k ds fy,½
2 × m moles of H2SO4¼ds fefyeksy½ = m moles of NaOH ¼ds fefyeksy½
98
2× × 1.84 × 10 × 100 = 0.46 × V
98
V = 8000 mL = 8 L.
11. The given reaction is an important step in Ostwald’s method for manufacturing of HNO 3. If we start with
6.8 g of NH3 and 40 g of O2, then what mass % of excess reagent will be left behind?
NH3 + O2  NO + H2O
HNO3 ds fuekZ.k ds fy, vksLVokWYM fof/k esa uhps nh xbZ vfHkfØ;k ,d egRoiw.kZ in gSA ;fn ge vfHkfØ;k] 6.8 g
NH3 o 40 g O2 ls izkjEHk djrs gksa] rks vkf/kD; esa fy;s x;s vfHkdeZd dk fdruk % 'ks"k jg tk;sxk \
NH3 + O2  NO + H2O
Ans. 60
Sol. 4NH3 + 5O2  4NO + 6H2O
6.8 40
Mole 17 32
= 0.4 = 1.25
mole 0.4 1.25
st. coeff. 4 5
= 0.1 = 0.25
PAGE NO.-45
0.4  5
(LR) Moles reacted = = 0.5
4
So, Moles left = 0.75
(mO2 )left 0.75  32
 % of excess reagent left = × 100 = × 100 = 60
(mO2 )initial 40
Sol. 4NH3 + 5O2 4NO + 6H2O
eksy 6.8
17
40
32
= 0.4 = 1.25
eksy 0.4 1.25
= 0.1 = 0.25
jllehdj.kferh 4 5
xq.kkad
0.4  5
(LR) vfHkd`r eksy = = 0.5
4
blfy,] 'ks"k cps eksy = 0.75
(mO2 )'ks"k 0.75  32
 vkf/kD; esa cps vfHkdeZd dk % = × 100 = × 100 = 60
(mO2 )izkjEHk 40

Column  Column 
(A) 50 mL of 3M HCl solution + 150 mL of 1M FeCl3 solution (p) 4.17 m
(B) An aqueous solution of NaCl with mole fraction of NaCl as 0.1 (q) [Cl–] = 3 M
(C) 20% (w/w) propanol (C3H7OH) solution (r) [H+] = 0.75 M
(D) 10.95% (w/v) HCl solution (s) 6.1 m
LrEHk  LrEHk 
(A) 3M HCl foy;u ds 50 mL + 1M FeCl3 ds 150 mL (p) 4.17 m
(B) NaCl ds ,d tyh; foy;u ftlesa NaCl dk eksy fHkUu 0.1 gS (q) [Cl–] = 3 M
(C) 20% (w/w) izksisukWy (C3H7OH) dk foy;u (r) [H+] = 0.75 M
(D) 10.95% (w/v) HCl foy;u (s) 6.1 m
Ans. (A) – q, r ; (B) – s ; (C) – p ; (D) – q
50  3  150  1  3 600 0.1
Sol. (A) [Cl–] = = =3M (B) molality =  1000 = 6.17 m
200 200 0.9  18
10.95
10  1000 36.5
(C) Molality = = 1.85 m. (D) Molarity of HCl = × 1000 = 3 M
60  90 100
50  3  150  1  3 600 0.1
Sol. (A) [Cl–] = = =3M (B) eksyyrk =  1000 = 6.17 m
200 200 0.9  18
10 10.95
(C) eksyyrk = 60  1000 = 1.85 m (D) HCl dh eksyjrk = 36.5 × 1000 = 3 M
90 100
ChemINFO Estimation Of Halogens

Daily Self-Study Dosage for mastering Chemistry Elemental analysis of Halogen
Estimation of Halogens : The estimation of halogens (Cl, Br or I) in organic compounds is usually
done by Carius method.
Principle : The method is based on the fact that when an organic compound containing halogen (Cl,
Br or I) is heated in a sealed tube with fuming nitric acid in presence of silver nitrate, silver halide is
formed. From the mass of silver halide formed, the precentage of the halogen can be calculated.
Calculations : Mass of the organic substance = W g
Mass of the silver halide = W1g
PAGE NO.-46
35.5 W1
(a) Chlorine : Percentage of chlorine =   100
143.5 W
W 1 is mass of silver chloride
W is mass of organic substance
80 W1
(b) Bromine : Percentage of bromine =   100
188 W
W 1 is mass of silver bromide
127 W1
(c) Iodine : Percentage of iodine =   100
235 W
W 1 is mass of silver Iodide
ChemINFO gSykstu dk fu/kkZj.k

Daily Self-Study Dosage for mastering Chemistry Elemental analysis of Halogen
gSykstu dk fu/kkZj.k % dkcZfud ;kSfxdksa esa gSykstu (Cl, Br ;k I) ds fu/kkZj.k ds fy, lkekU;r% dsfj;l fof/k dk
mi;ksx fd;k tkrk gSA
fl)kUr % ;g fof/k bl rF; ij vk/kkfjr gS fd tc gSykstu (Cl, Br ;k I) dks ;qDr dkcZfud ;kSfxdksa dks flYoj
ukbVªsV dh mifLFkfr esa l?kwe ukbVªhd vEy ds lkFk cU/k ij[kuyh esa xeZ fd;k tkrk gS rks flYoj gSykbM dk
fuekZ.k gksrk gSA fufeZr flYoj gSykbM ds nzO;eku ls gSykstu dh izfr'krrk dh x.kuk dh tk ldrh gSA
x.kuk % dkcZfud inkFkZ dk nzO;eku = W xzke
flYoj gSykbM dk nzO;eku = W1 xzke
35.5 W1
(a) Dyksjhu % Dyksjhu dh izfr'krrk =   100
143.5 W
dkcZfud inkFkZ dk nzO;eku = W xzke
flYoj DyksjkbM dk nzO;eku = W1 xzke
80 W1
(b) czksehu % czksehu dh izfr'krrk =   100
188 W
flYoj czksekbM dk nzO;eku = W1 xzke
127 W1
(c) vk;ksMhu % vk;ksMhu dh izfr'krrk =   100
235 W
flYoj vk;ksMkbM dk nzO;eku = W 1 xzke
13. In carius method for estimation of chlorine, the formula used is :

80 massof AgCl
(A) Percentage of Cl =   100
188 Massof organic subs tance
127 massof AgCl

(B) Percentage of Cl =   100
235 Massof organic subs tance
35.5 massof AgCl

(C*) Percentage of Cl =   100
143.5 Massof organic compound
35.5 massof organic compound

(D) Percentage of Cl =   100
143.5 Massof AgCl
PAGE NO.-47
Dyksjhu ds fu/kkZj.k ds fy, dSfj;l fof/k esa mi;ksxh lw=k gS &
AgCl dk nzO;eku
(A) Cl dh izfr'krrk = 80 × ×100
188 dkcZfud inkFkZ dk nzO;eku
127 AgCl dk nzO;eku
(B) Cl dh izfr'krrk = × ×100
235 dkcZfud ;kSfxd dk nzO;eku
35.5 AgCl dk nzO;eku
(C*) Cl dh izfr'krrk = × ×100
143.5 dkcZfud ;kSfxd dk nzO;eku
(D) Cl dh izfr'krrk =
35.5 dkcZfud ;kfSxd dk nzO;eku
× ×100
143.5 AgCl dk nzO;eku
14. 0.5264 g silver bromide is obtained from 0.5124 g of an organic compound. The percentage of bromine
in the compound is :
,d dkcZfud ;kSfxd ds 0.5124 xzke ls 0.5264 xzke flYoj czksekbM izkIr gksrk gS rks ;kSfxd esa czksehu dh izfr'krrk gS %
(A) 23.71 % (B*) 43.71 % (C) 35.2 % (D) 53.6 %
Mass of silver bromide, W 1 = 0.5264 g
80 W1 80 0.5264
Percentage of bromine =   100 =  × 100 = 43.71%
188 W 188 0.5124
flYoj czksekbM dk nzO;eku W1 = 0.5264 xzke
80 W1 80 0.5264
czksehu dh izfr'krrk =   100 =  × 100 = 43.71%
188 W 188 0.5124
15. 0.156 g of an organic compound of heating with fuming HNO 3 and AgNO3 gives 0.235g of AgI. The
percentage of iodine in the compound.
0.156 xzke ,d dkcZfud ;kSfxd dks l/kwwe HNO3 vkSj AgNO3 ds lkFk xeZ djrs gS rks 0.235 xzke AgI izkIr gksrk gS]
rks ;kSfxd esa czksehu dh izfr'krrk gS %
(A) 52.1 % (B) 63.2 % (C) 71.3 % (D*) 81.4 %
Mass of AgI, W 1 = 0.235
127 W1 127 0.235
Percentage of iodine =   100 =   100 = 81.41
235 W 235 0.156
AgI dk nzO;eku W 1 = 0.235
127 W1 127 0.235
vk;ksMhu dh izfr'krrk =   100 =   100 = 81.41
235 W 235 0.156
16. 0.1171 g of an organic compound on heating with conc. HNO 3 and silver nitrate in Carius furnace gave
0.42 g of AgCl. The percentage of chlorine in the compound is
dSfj;l Hkêh esa 0.1171 xzke dkcZfud ;kSfxd dks lkUnz HNO3 vkSj flYoj ukbVªsV ds lkFk xeZ djrs gS rks 0.42 xzke
AgCl izkIr gksrk gSA bl ;kSfxd esa Dyksjhu dh izfr'krrk gS %
(A) 38.2 % (B) 54.3 % (C) 71.4 % (D*) 88.8 %
Mass of AgCl, W 1 = 0.42 g
35.5 W1 35.5 0.42
Percentage of chlorine =   100 =   100  88.80%
143.5 W 143.5 0.1170
AgCI dk nzO;eku W 1 = 0.42 xzke
35.5 W1 35.5 0.42
Dyksjhu dh izfr'krrk =   100 =   100  88.80%
143.5 W 143.5 0.1170
PAGE NO.-48
P-CH EM ISTRY


EST INFORM AT IO
DPP

1. Two vessels, A and B, contain the same gas. If the pressure, volume and absolute temperature of the
gas in A are two times as compared with those of gas in B, and if mass of the gas in B is x g, the mass
of the gas in A will be :
(A) 4x g (B) x/2 g (C*) 2x g (D) x g
nks ik=k A rFkk B leku xSl j[krs gaSA ;fn ik=k A esa] ik=k B dh vis{kk nkc] vk;ru o ije xSl rki nqxqus gSa rFkk
;fn ik=k B esa xSl dk nzO;eku x g gS] rks ik=k A esa xSl dk nzO;eku fuEu gksxk %
(A) 4x xzke (B) x/2 xzke (C*) 2x xzke (D) x xzke
2. A gas mixture contains 50% helium and 50% methane by volume. What is the percent by weight of
methane in the mixture ?
,d xSl feJ.k 50% ghfy;e o 50% esFksu ¼vk;ru ls½ j[krk gSA feJ.k esa esFksu dk izfr'kr ¼nzO;eku ls½ D;k gS \
(A) 88.89% (B) 20% (C) 71.43% (D*) 80%
Sol. Equal volumes contain equal number of moles.
Hence, molar ratio of He : CH4 = 1 : 1
 Ratio by weight = 4 : 16 = 1 : 4
4
 CH4 present by weight =  100 = 80%
5
leku vk;ru eksyksa dh leku la[;k j[krk gSA
vr% He : CH4 dk eksy vuqikr = 1 : 1
 vuqikr ¼Hkkj dk½ = 4 : 16 = 1 : 4
4
 mifLFkr CH4 (Hkkj dk) izfr'kr =  100 = 80%
5
3. A mixture of He and SO2 at one bar pressure contains 20% by weight of He. Partial pressure of He will
be :
(A) 0.2 bar (B) 0.4 bar (C) 0.6 bar (D*) 0.8 bar
1 ckj nkc ij ghfy;e vkSj lYQj MkbZvkWDlkbM dk feJ.k] ghfy;e ds nzO;eku ls 20% ;qDr gSA rc ghfy;e dk
vkaf'kd nkc D;k gksxk %
(A) 0.2 ckj (B) 0.4 ckj (C) 0.6 ckj (D*) 0.8 ckj
Sol. Weight of He = 20 g in 100 g mixture ; Weight of SO2 = 80 g
20 80 5
 Moles of He = =5;  Moles of SO2 = =
4 64 4
5 25
 Total moles = 5 + =
4 4
5
 '
PHe = PT x mole fraction of He = 1 x = 0.8 bar
25 / 4
Sol. He dk nzO;eku = 20 g (100 g feJ.k esa½ ; SO2 dk nzO;eku = 80 g
 He ds eksy = = 5 ;  SO2 ds eksy = =
PAGE NO.-49
 dqy eksy = 5 + =
5
 '
PHe = PT x He dk eksy fHkUu = 1 x = 0.8 ckj
25 / 4
4. The density of gas A is twice that of a gas B at the same temperature. The molecular weight of gas B is
thrice that of A.The ratio of the pressure exerted on A and B will be :
leku rki ij xSl A dk ?kuRo] xSl B ds ?kuRo dk nks xquk gSA xSl B dk vkf.od nzO;eku] A ls rhu xquk gSA A
vkSj B }kjk yxk, x, nkc dk vuqikr fuEu gS %
(A*) 6 : 1 (B) 3 : 2 (C) 2 : 3 (D) 1 : 6
5. A 4.0 dm3 flask containing N2 at 4.0 bar was connected to a 6.0 dm 3 flask containing helium at 6.0 bar,
and the gases were allowed to mix isothermally. Then the total pressure of the resulting mixture will be :
6.0 bar ij N2 ;qDr 4.0 dm3 ¶ykLd dks 6.0 bar ij ghfy;e ;qDr 6.0 dm3 ¶ykLd ls tksM+k tkrk gS rFkk xSlksa
dks lerkih; :i ls fefJr fd;k tkrk gSA rc ifj.kkeh feJ.k dk dqy nkc fuEu gksxk%
(A) 4.8 bar (B*) 5.2 bar (C) 5.6 bar (D) 5.4 bar
Sol. At constant temperature,
P1 V1 + P2 V2 = P3 (V1 + V2)
(4.0 bar) (4.0 dm 3) + (6.0 bar) (6.0 dm3) = P3 (4.0 + 6.0 dm3)
16  36 52
or P3 = = = 5.2 bar.
10 10
gy- fu;r rki ij]

P1 V1 + P2 V2 = P3 (V1 + V2)
(4.0 bar) (4.0 dm 3) + (6.0 bar) (6.0 dm3) = P3 (4.0 + 6.0 dm3)
16  36 52
or P3 = = = 5.2 bar.
10 10
6. What volume of oxygen gas (O2) measured at 0°C and 1 atm is needed to burn completely 1 L of
propane gas (C3H8) measured under the same conditions?
leku ifjfLFkfr;ksa ds vUrxZr 1 L çksisu xSl (C3H8) dks iw.kZ :i ls tykus ds fy, 0ºC o 1 atm ij vkWDlhtu xSl
(O2) dk vk;ru D;k gksuk pkfg, \
(A) 7 L (B) 6 L (C*) 5 L (D) 10 L
Sol. C3H8 + 5O2  3CO2 + 4H2O
1L 5L
7. Two inflated ballons I and II (thin skin) having volume 600 mL and 1500
mL at 300 K are taken as shown in diagram. If maximum volume of
inner and outer balloons are 800 mL and 1800 mL respectively then find
the balloon which will burst first on gradual heating.
(A) inner balloon
(B) outer balloon
(C) both simultaneously
(D) unpredictable
7. 300 K ij nks Qqys gq, xqCckjs (iryh ijr) I rFkk II ftudk vk;ru 600 mL rFkk
1500 mL gS] ysrs gSA tSlk fd fp=k esa n'kkZ;k x;k gSA ;fn vkUrfjd rFkk cká
xqCckjs dk vf/kdre vk;ru Øe'k% 800 mL vkSj 1800 mL gS rks crkb;s] Øfed
xeZ djus ij dkSulk xqCckjk igys QVrk gS %
(A) vkUrfjd xqCckjk
(B*) cká xqCckjk
(C) nksuks ,d lkFk
(D) vu~vuqekfur
PAGE NO.-50
Sol. Case I—Suppose inner balloon burst first
voLFkk I—ekuk vkUrfjd xqCckjk igys QVrk gS&
600 8000
=  T2 = 400 K
300 T2
Case II—Suppose outer balloon burst first
voLFkk II—ekuk cká xqCckjk igys QVrk gS&
1500 1800
= ; T2 = 360 K
300 T2
8. If an ideal gas is allowed to expand at constant tempeature then-

(A) the kinetic energy of the gas molecules decreases
(B) the kinetic energy of the gas molecules increases
(C*) the kinetic energy of the gas molecules remains the same
(D) None
;fn ,d vkn'kZ xSl fuf'pr rki ij foLrkfjr gksrh gS rc &
(A) xSl ds v.kqvksa dh xfrt ÅtkZ de gksrh gSA (B) xSl ds v.kqvksa dh xfrt ÅtkZ c<+rh gSA
(C*) xSl ds v.kqvksa dh xfrt ÅtkZ leku jgrh gSA (D) buesa ls dksbZ ughaaA
9. 3 g of carbon and 5 g of oxygen react with each other completely. Which of the following options is true
regarding composition of final mixture :
3 xzke dkcZu rFkk 5 xzke vkWDlhtu iw.kZ:i ls fØ;k djrs gSA vfUre feJ.k ds fuekZ.k ds lUnHkZ esa fuEu esa ls dkSulk
fodYi lgh gS%
(A) nCO2 = 0.15625 ; nC = 0.09375 (B) nCO = 0.0625 ; nCO2 = 0.1875
(C) nCO = 0.25 ; nO2 = 0.03125 (D*) nCO= 0.1875 ; nCO2 = 0.0625
1  
Sol. C + O2 CO
2
3 5
Initial mole 0
12 32
5 3 1 3
final mole 0 – ( )
32 12 2 12
1  
CO + O2 CO2
2
1 1
Initial mole 0
4 32
1 1 1
final mole – 0
4 16 16
3
=
16
3 /16 3
xCO = = = 0.75
3 /16  1/16 4
1  
gy % C + O2 CO
2
3 5
izkjfEHkd eksy 0
12 32
5 3 1 3
vfUre eksy 0 – ( )
32 12 2 12
CO + O2 CO2
1 1
izkjfEHkd eksy 0
4 32
1 1 1
vfUre eksy – 0
4 16 16
PAGE NO.-51
3
=
16
3 /16 3
xCO = = = 0.75
3 /16  1/16 4
10. Consider three one-litre flasks labeled A, B and C filled with the gases NO, NO 2 and N2O, respectively,
each at STP, In which flask do the molecules have the highest average kinetic energy?
(A) Flask C (B) Flask B (C) Flask A (D*) All are the same
A, B rFkk C yscy yxs gq, ,d yhVj ds rhu ¶ykLdksa esa Øe'k% NO, NO2 rFkk N2O xSlksa dks Hkjk tkrk gSA çR;sd
STP ij dkSuls ¶ykLd esa v.kqvksa dh vkSlr xfrt ÅtkZ vf/kd gksxh\
(A) ¶ykLd C (B) ¶ykLd B (C) ¶ykLd A (D*) lHkh esa leku
11. If a gas expands at constant temperature, it indicates that :

(A) kinetic energy of molecules decreases.
(B) pressure of the gas increases.
(C*) kinetic energy of molecules remains the same.
(D) number of the molecules of gas increases.
;fn dksbZ xSl fLFkj rki ij izlkfjr gksrh gS] rks ;g n'kkZrk gS fd %
(A) v.kqvksa dh xfrt ÅtkZ ?kVrh gSA (B) xSl dk nkc c<+ tkrk gSA
(C*) v.kqvksa dh xfrt ÅtkZ vifjofrZr jgrh gSA (D) xSl ds v.kqvksa dh la[;k c<+ tkrh gSA
3
Sol. KE = RT (for one mole of a gas)
2
As, the kinetic energy of a gaseous molecule depends only on temperature, thus at constant
temperature, the kinetic energy of the molecule remains the same.
3
Sol. KE = RT (xSl ds 1 eksy ds fy,)
2
,d xSlh; v.kq dh xfrt ÅtkZ dsoy rkieku ij fuHkZj djrh gS] vr% fu;r rkieku ij v.kq dh xfrt ÅtkZ leku
jgrh gSA
12. Express the average kinetic energy per mole of a monoatomic gas of molar mass M, at temperature T
K in terms of the mean speed of the molecules ( c ) :
,d ,dy&ijek.oh; xSl] ftldk eksyj nzO;eku M gS] dh çfr eksy vkSlr xfrt ÅtkZ dks T K rki ij v.kqvksa ds
ekè; osx ( c ) ds in esa fuEu lw=k ls O;Dr djsaxs %
8M 3M  2M   3 M 
( c )2 ( c )2 (C)  ( c )2 ( c )2
  
(D*) 
 16 
(A) (B)
3 16
13. The correct relationship between average translational kinetic energy per mole (KE) and most probable
speed (vmp) for an ideal gas is : (M is molar mass of gas)
,d vkn'kZ xSl ds fy, vkSlr LFkkukUrj.k xfrt ÅtkZ izfreksy (K.E.) rFkk vf/kdre izkf;drk xfr (vmp) ds e/;
lgh lacaèk fuEu gS % (M, xSl dk eksyj nzO;eku gS)
16KE 2KE 2KE 4KE
(A) vmp = (B) vmp = (C) vmp = (D*) vmp =
3M M 3M 3M
3 3M
Sol. KE = RT = (Vmp)2
2 4
14. Consider three electron jumps described below for the hydrogen atom.
x: n = 3 to n=1
y: n = 4 to n=2
z: n = 5 to n=3
The photon emitted in which transition will have smallest wave number :
(A*) z (B) y (C) x (D) All have same value
PAGE NO.-52
gkbMªkstu ijek.kq ds fy, rhu bysDVªkWu laØe.kksa dk o.kZu fuEu gS %
x: n = 3 ls n=1
y: n = 4 ls n=2
z: n = 5 ls n=3
tc QksVkWu mRlftZr gksrk gS] rks fdl laØe.k dh rjax la[;k lcls de gksxh \
(A*) z (B) y (C) x (D) lHkh dk eku leku gksxkA
Sol. x: n = 3 to n = 1 (12.09 eV)
y: n = 4 to n = 2 (2.55 eV)
z: n = 5 to n = 3 (0.967 eV)
Smallest wave number  minimum energy n = 5 to n = 3 (0.967 eV)
U;wure rjax la[;k  U;wure ÅtkZ n = 5 ls n = 3 (0.967 eV).
15. In the electronic configuration of Mn (Z = 25) :
(A) the number of electrons having n +  = 4 are 5
(B*) the number of electrons having m = 0 are 13.
(C) the magnetic moment is 1.73 BM
(D) Mn belongs to IIIrd period and d-Block in Modern periodic table.
Mn (Z = 25) ds bysDVªkWfud foU;kl esa %
(A) n +  = 4 okys bysDVªkWuksa dh la[;k 5 gSA
(B*) tks bysDVªkWu m = 0 j[krs gSa] mudh la[;k 13 gSA
(C) pØ.k pqEcdh; vk?kw.kZ 1.73 BM gSA
(D) Mn, vk/kqfud vkorZ lkj.kh ds r`rh; vkorZ rFkk d-CykWd ls lEcfU/kr gSA
Sol. Mn - 1s2 2s2 2p6 3s2 3p6 3d5 4s2
m = 0 for all s-electron and two-p electron and one d-electron hence total = 13.
lHkh s-bysDVªkWu vkSj nks p-bysDVªkWu vkSj ,d d-bysDVªkWu ds fy;s m = 0 gS blfy, budh la[;k 13 gSA
= 3.0 g mixture feJ.k
16. If rate of diffusion of A is 5 times that of B, what will be the density ratio of A and B :
(A*) 1/25 (B) 1/5 (C) 25 (D) 4
;fn A dh folj.k dh nj B ls 5 xq.kk gS] rks A rFkk B ds ?kuRo dk vuqikr gksxk :
(A*) 1/25 (B) 1/5 (C) 25 (D) 4
17. On increasing temperature of a particular gaseous sample, the fraction of toal gas molecules which
have speed equal to most probable speed will :
(A) increase (B*) decrease
(C) remains constant (D) nothing can be said with certainty
,d fuf'pr xSlh; çkn'kZ ds rkieku esa o`f) djus ij] dqy xSl v.kqvksa dk izHkkt] tks lcls izkf;d osx j[krk gS]
mlesa %
(A) o`f) gksxh (B*) deh gksxh
(C) og fu;r jgsxk (D) fuf'pr :i ls dqN ugha dgk tk ldrk
18. The mean transitional kinetic energy per unit volume, E and the pressure, P of a perfect gas are related
as:
,d xSl dh ek/; laØe.k ÅtkZ izfr bdkbZ vk;ru E vkSj nkc P esa mfpr lEcU/k gS&
(A) P = E/2 (B*) P = 2E/3 (C) P = E 3 /2 (D) P = 3E/2
19. Calculate the temperature at which the root mean square speed of sulphur dioxide molecules is the
same as that of oxygen gas molecules at 300 K :
og rki Kkr dhft;ss] tc SO2 xSl ds v.kqvksa dk oxZ ek/; ewy osx] vkWDlhtu xSl ds v.kqvksa ds 300 K ij oxZ
ek/; ewy osx ds cjkcj gksxk %
(A) 150 K (B*) 600 K (C) 300 K (D) 1200 K
PAGE NO.-53
20. A sample of air is saturated with benzene (vapour pressure = 100 mm of Hg at 298 K) at 298 K and
partial pressure of air is 650 mm of Hg. If it is isothermally compressed to half of its initial volume, the
final pressure of the system is :
(A) 1500 torr (B) 425 torr (C*) 1400 torr (D) 1200 torr
298 K ij ok;q dk ,d uewuk] csathu (298 K ij ok"i nkc = Hg dk 100 mm) ds lkFk lar`Ir gS rFkk ok;q dk
vkaf'kd nkc] Hg dk 650 mm gSA ;fn ;g] vius izkjafHkd vk;ru ds vk/ks rd lerkih; :i ls laihfMr fd;k
tkrk gS] rks fudk; dk vfUre nkc fuEu gS %
(A) 1500 VkWj (B) 425 VkWj (C*) 1400 VkWj (D) 1200 VkWj
Sol. On compressing Pf (air) = 650 × 2 mm of Hg
= 1300 mm of Hg
so PT = (1300 + 100) = 1400 mm of Hg
gy. laaihfM+r djus ij] Pf (ok;q) = Hg ds 650 × 2 mm
= Hg ds 1300 mm
blfy, PT = (1300 + 100) = Hg ds 1400 mm
P-CH EM ISTRY


EST INFORM AT IO
DPP

1. 224 mL of CO2 at N.T.P. is passed through 100 mL of 0.2 M solution of NaOH. What is the weight of
Na2CO3 formed ? 2NaOH + CO2  Na2CO3 + H2O
N.T.P. ij CO2 ds 224 mL dks NaOH ds 0.2 M foy;u ds 100 mL eas ls çokfgr fd;k tkrk gSA cuk;s x;s
Na2CO3 dk nzO;eku D;k gS\ 2NaOH + CO2  Na2CO3 + H2O
(A*) 1.06 g (B) 0.53 g (C) 2.12 g (D) 10.6 g
Sol. molar mass of Na2CO3 = 46 + 60 = 106
2 NaOH + CO2  Na2CO3 + H2O
0.2  100 224
initial mole
1000 22400
final mole 0.02 mole 0.01 mole 0.01 mole
Weight of Na2CO3 formed = 0.01 × 106 = 1.06 gram
gy- Na2CO3 dk vkf.od nzO;eku = 46 + 60 = 106
2 NaOH + CO2  Na2CO3 + H2O
0.2  100 224
izkjfEHkd eksy
1000 22400
vfUre eksy 0.02 eksy 0.01 eksy 0.01 eksy
cuk;s x, Na2CO3 dk Hkkj = 0.01 × 106 = 1.06 xzke
PAGE NO.-54
2. A graph between compressibility factor (Z) & pressure is drawn for three
gases at the same temperature then correct order of boyles temperature (Tb)
of X, Y and Z is.
[Assume that Vander Waal's constant 'b' is nearly same for all three gases.]
(A*) Tb(x) < Tb(y) < Tb(z) (B) Tb(x) = Tb(y) = Tb(z)
(C) Tb(x) > Tb(y) > Tb(z) (D) can not be predicted
rhu xSlksa ds fy;s leku rki ij lEihM~;rk xq.kkad (Z) rFkk nkc ds chp xzkQ cuk;k
tkrk gSA rc xSl X,Y rFkk Z ds fy, ckW;y rki (Tb) dk lgh Øe gSA
[;g ekus dh ok.Mj okWy fLFkjkad 'b' rhuksa xSlksa ds fy;s yxHkx leku gSA]
(A*) Tb(x) < Tb(y) < Tb(z) (B) Tb(x) = Tb(y) = Tb(z)
(C) Tb(x) > Tb(y) > Tb(z) (D) vuqeku ugha yxk;k tk ldrk gSA
3.  For the following two isotherms drawn at two different temperature T 1
and T2. Which of the following statement is true? (number of moles are
constant)
(A*) T2 > T1 (B) T1 > T2 (C) T1 = T2
(D) T1 =2 T2 (E) Cannot be predicted
nks fHkUu rkiekuksa T1 rFkk T2 ij nks lerkih dks fuEu izdkj ls [khapk tkrk gSA
fuEu esa ls dkSulk dFku lR; gSA (eksyksa dh la[;k fu;r jgrh gSa)
(A*) T2 > T1 (B) T1 > T2 (C) T1 = T2
(D) T1 =2 T2 (E) dgk ugha tk ldrk
Sol. const = K
log P + log V = log K
 y + x = K1 as T K1 
Hence intercept on co-ordinate axes will increase  T2 > T1
PV = fu;r = K
log P + log V = log K
 y + x = K1 as T K1 
vr% funsZ'kh v{kksa ij vUr% [k.M esa o‘f) gksxhA
4. For the four gases A, B, E and D, the value of the excluded volume per mole is same. If the order of the
critical temperature is TB > TD > TA > TE, then the order of their liquefaction pressure at a temperature T
(T < TE) will be :
pkj xSl A, B, E rFkk D ds vioftZr vk;ru ¼excluded volume½ dk izfr eksy eku] leku gSA ;fn Økafrd rki
dk Øe Øe'k% TB > TD > TA > TE gS] rc rki T (T < TE) ij nzohdj.k nkc dk Øe D;k gksxk %
(A) PA < PB < PE < PD (B*) PB < PD < PA < PE (C) PE < PA < PD < PB (D) PD < PE < PA < PB
5. Gases deviate from the ideal gas behavior because their molecules:
(A) Possess negligible volume (B*) Have forces of attraction between them
(C) Are polyatomic (D) Are not attracted to one another
xSl vkn'kZ O;ogkj ls fopfyr gksrh gS D;ksafd muds v.kq
(A) ux.; vk;ru j[krs gSa (B*) vkil esa vkd"kZ.k dk cy j[krs gSA
(C) cgqijek.oh; gksrs gSa (D) ,d nwljs dh rjQ vkdf"kZr ugha gksrs gSA
6. The compressibility factor for an ideal gas is :

,d vkn'kZ xSl ds fy, laihfM;rk xq.kkad fuEu gS %
(A) 0 (B*) 1 (C) 3/8 (D) 
Sol. For ideal gas, compressibility actor (Z) = 1.
gy- vkn'kZ xSl ds fy,] laihfM;rk xq.kkad (Z) = 1 gSA
PAGE NO.-55
7. A real gas most closely approaches the behaviour of an ideal gas at :
(A) low pressure & low temperature (B) high pressure & high temperature
(C*) low pressure & high temperature (D) high pressure & low temperature
,d okLrfod xSl] ,d vkn'kZ xSl ds O;ogkj ds lcls utnhd] fuEu esa ls fdu ifjfLFkfr;ksa esa igq¡prh gS %
(A) fuEu nkc rFkk fuEu rki (B) mPp nkc rFkk mPp rki
(C*) fuEu nkc rFkk mPp rki (D) mPp nkc rFkk fuEu rki
Sol. A real gas behaves idealy under conditions of low pressure and high temperature .
fuEu nkc rFkk mPp rki ij ,d okLrfod xSl] vkn'kZ xSl dh rjg O;ogkj djrh gSA
8. Which of the following is correct order of temperature shown in the

following Z Vs P graph for the same gas:
,d gh xSl ds fy, Z rFkk P ds e/; n'kkZ;s x;s fuEu oØ esa rki dk lgh
Øe fuEu esa ls dkSulk gS %
(A) T1 < T2 < T3 < T4
(B*) T4 < T3 < T2 < T1
(C) T1 < T3 < T2 < T4
(D) T4 < T2 < T3 < T1
9. Z vs P graph is plotted for 1 mole of three different gases X, Y and Z at temperature T 1.
rkieku T1 ij rhu fofHkUu xSlksa X, Y rFkk Z izR;sd ds 1 eksy ds fy,] Z dk P ds lkis{k vkjs[k fuEu gS %
X T1
Z
Y
Z
P
Then, which of the following graph is incorrect if the above plot is made for 1 mole of each gas at T 2
temperature (T2 < T1) :
rc buesa ls dkSulk vkjs[k xyr gS] ;fn izR;sd xSl ds 1 eksy ds fy, T2 rki (T2 < T1) ij mijksDr vkjs[k cuk;k
tkrk gks%
X X
Z Z Z X Z
X Y Y Y
Y Z
Z Z
Z
(A) (B*) (C) (D)
P P P P
10. One litre gas at 400 K and 300 atm pressure is compressed to a pressure of 600 atm and 200 K. The
compressibility factor is changed from 1.2 to 1.6 respectively. Calculate the final volume of the gas.
,d yhVj xSl tks 400 K rFkk 300 atm nkc ls laihfMr djds xSl dk nkc 600 atm rFkk rki 200 K dj fn;k
tkrk gSA bl vfHkfØ;k esa laihfM;rk xq.kkad 1.2 ls 1.6 gks tkrk gS rks xSl dk vfUre vk;ru Kkr djksA
2 1 4
(A) 2 litre (B) litre (C*) litre (D) litre
3 3 3
PV
Sol. Z1 = 1 1
RT1
P2 V2
Z2 =
RT2
Z1 P1 T V
= × 2 × 1
Z 2 P2 T1 V2
PAGE NO.-56
1
V2 = litre
3
11. The compressibility of a gas is less than unity at S.T.P. Therefore :

(A) Vm > 22.4 litres (B*) Vm < 22.4 litres (C) Vm = 22.4 litres (D) Vm = 44.8 litres
,d xSl dh laihfM+;rk xq.kkad S.T.P. ij ,d ls de gS blfy;s&
(A) Vm > 22.4 litres (B*) Vm < 22.4 litres (C) Vm = 22.4 litres (D) Vm = 44.8 litres
12. Compressibility factor (Z) for N2 at – 23°C and 820 atm pressure is 1.9. Find the number of moles of N 2
gas required to fill a gas cylinder of 95 L capacity under the given conditions.
(A*) 2000 (B) 200 (C) 2 × 104 (D) Cannot be determined
N2 dk laihfM+;rk xq.kkad (Z) –23°C rFkk 820 atm ij 1.9 gSA nh xbZ voLFkk esa 95 L {kerk ds ,d flys.Mj esa
Hkjus ds fy, vko';d eksy gksxh&
(A*) 2000 (B) 200 (C) 2 × 104 (D) fu/kkZj.k ugh dj ldrs gSa
PV PV
Sol. Z=  n=
nRT ZRT
13. Which of the following graph is correct for real gases other than hydrogen and helium?
(A) (B) (C*) (D)
gkbMªkstu o ghfy;e ds vykok] okLrfod xSlkssa ds fy, lkekU;r% fuEu esa ls dkSulk vkjs[k lgh gS \
(A) (B) (C*) (D)
14. Which of the following graph is commonly correct for hydrogen gas?
(A*) (B) (C) (D)
gkbMªkstu xSl ds fy,] lkekU;r% dkSulk vkjs[k lgh gS \
(A*) (B) (C) (D)
15. For a real gas Z is greater than one and curve B represents ideal gas D
behaviour. Then the curve for the real gas is :
okLrfod xSl ds fy, Z dk eku ,d ls vf/kd gksrk gSA rFkk oØ B vkn'kZ xSl P
O;ogkj dks iznf'kZr djrk gSA okLrfod xSl ds fy, oØ gSA B

A
(A) A C
(B) B V
(C) C
(D) D
PAGE NO.-57
16. In the graph shown, which of the statements is correct. A
W
(A) for A, B, C & D the compressibility factor is > 1 B

(B) for A, B, C & D the value of z is less than one PV
Ideal
(C*) for A, B, z is greater than one & C, D, z is less than one gas
C
(D) for A, B, z is less than one & C, D, z is greater than one D
P
xzkQ esa n'kkZ;s vuqlkj fuEu es ls dkSulk dFku lgh gSA A

(A) A, B, C o D ds fy, laihfM;rk xq.kkd >1 B
(B) A, B, C o D ds fy, laihfM;rk xq.kkd ,d ls de gksrk gSA PV
Ideal
(C*) A, B ds fy, z dk eku ,d ls vf/kd o C, D ds fy, z dk eku ,d ls de gas
C
gksrk gSA D
(D) A, B ds fy, z dk eku ,d ls de o C, D ds fy, z dk eku ,d ls vf/kd P
gksrk gSA
pV
17. Consider the equation Z = . Which of the following statements is correct?
RT
(A) When Z > 1, real gases are easier to compress than the ideal gas.
(B) When Z = 1, real gases get compressed easily as compared to ideal gas.
(C*) When Z > 1, real gases are difficult to compress as compared to ideal gas.
(D) When Z = 1, real gases are difficult to compress as compared to ideal gas.
pV
fuEu lehdj.k Z = ds vuqlkj fuEu esa ls dkSulk dFku lgh gS \
RT
(A) tc Z > 1 gS rc okLrfod xSl, vkn'kZ xSl dh rqyuk es vklkuh ls lEihfMr gks tkrh gSA
(B) tc Z = 1 gS rc okLrfod xSl, vklkuh ls lEihfMr gks tkrh gSA
(C*) tc Z < 1 gS rc okLrfod xSl dks lEihfMr djuk dfBu gSA
(D) tc Z = 1 gS rc okLrfod xSl dks lEihfMr djuk dfBu gSA
18. Compressibility factor for He behaving as real gas generally is :
lkekU;r% ,d okLrfod xSl ds leku O;ogkj djus okyh He ds fy;s laihfM+;rk xq.kkad gS&
 a   Pb  RTV
(B)  1 (C*)  1 
 RTV  
(A) 1 (D)
 RT  (1  a)
Sol. PV = Pb + RT
PV Pb
=1+
RT RT
19. The density of Nitrogen gas is maximum at :

(A) STP (B) 273 K and 0.5 atm (C*) 546 K and 4 atm (D) 546 K and 1 atm
fdl fLFkfr esa ukbVªkstu xSl dk ?kuRo vf/kdre gksxk %
(A) STP (B) 273 K rFkk 0.5 atm (C*) 546 K rFkk 4 atm (D) 546 K rFkk 1 atm
20. The rms velocity of hydrogen is 7 times the rms velocity of nitrogen. If T is the temperature of the
gas, then
gkbMªkstu dk rms osx] ukbVªkstu ds rms osx ls 7 xquk gSA ;fn xSl dk rkieku T gS] rks %
(A) T(H2 )  T(N2 ) (B) T(H2 )  T(N2 ) (C*) T(H2 )  T(N2 ) (D) T(H2 )  7 T(N2 )
3RTH2 3RTN2 3RT
Sol. Given that : = 7 (because Urms = )
2 28 M
3RTH2 3  RTN2
So =7×  TN2 = 2TH2 or TN2 > TH2
2 28
PAGE NO.-58
3RTH2 3RTN2 3RT

gy. fn;k x;k gSA fd : = 7 (D;ksafd Urms = )
2 28 M
3RTH2 3  RTN2
blfy, =7×  TN2 = 2TH2 ;k TN2 > TH2
2 28
P - C H E M I S T RY


EST INFORM AT IO
DPP

4. DPP Syllabus :
Comprehension ('–1' negative marking) Q.10 to Q.12 (3 marks, 2 min.) [09, 06]
Match the column (no negative marking) Q.20 (8 marks, 6 min.) [08, 06]
ANSWER KEY
1. A vessel has nitrogen gas and water vapours in equilibrium with liquid water at a total pressure of 1
atm. The partial pressure of water vapours is 0.3 atm. The volume of this vessel is reduced to one-third
of the original volume, at the same temperature, then total pressure of the system is :(Neglect volume
occupied by liquid water)
,d ik=k esa ukbVªkstu xSl vkSj ikuh dh ok"i] lkE; ij nzfor ikuh ds lkFk dqy nkc 1 atm ij mifLFkr gSaA ikuh
dh ok"i dk vkaf'kd nkc 0.3 atm gSA bl ik=k ds vk;ru dks] blds ewy vk;ru ls leku rki ij ,d-frgkbZ rd
de dj nsrs gSaA rc fudk; dk dqy nkc D;k gksxk % (nzo ikuh }kjk ?ksjk x;k vk;ru ux.; ekusa
(A) 3 atm (B) 1 atm (C) 0.53 atm (D*) 2.4 atm
2. Given the value of their van der Waals’ constant ‘a’ arrange the following gases in the order of their
expected liquification pressure at a temperature T. T is below the critical point of all the gases.
Gas CH4 Kr N2 Cl2
‘a’ 2.283 2.439 1.408 6.579
(atmL2.mol-1)
rki T ij fuEufyf[kr xSlksa ds fy, ok.Mjoky fu;rkad a dk eku fuEu izdkj ls fn;k x;k gSA bu xSlksa dks buds
visf{kr nzfor nkc ds Øe esa O;ofLFkr djksA T ;gka ij lHkh xSlksa ds fy, ØkfUrd fcUnq ls de gSA
xSl CH4 Kr N2 Cl2
‘a’ 2.283 2.439 1.408 6.579
(atmL2.mol-1)
(A) CH4 < Kr < N2 < Cl2 (B) N2 < CH4 < Kr < Cl2 (C*) Cl2 < Kr < CH4 < N2 (D) Cl2 < N2 < Kr < CH4
PAGE NO.-59
3. The variation of compressibility factor ‘Z’ with pressure at different
temperatures T1, T2 and T3 is given as follows. Match the temperature in
Column I with the Column II values.
Column I Column II
(a) T1 1. 500 K
(b) T2 2. 1000 K
(c) T3 3. 200 K
(A*) a  3, b  1, c  2 (B) a  1, b  2, c  3
(C) a  2, b  3, c  1 (D) Information is in sufficient
lEihM~;rk xq.kkad ¼ ‘Z’½ dk fofHké rkiekuksa T1, T2 ,oa T3 ij nkc ds lkFk dk

ifjorZu fuEu xzkQ ds vuqlkj gksrk gSA
LrEHk-I ds rkiekuksa dk LrEHk-II ds ekuksa ds lkFk lgh lEcU/k dkSulk gksxkA
LrEHk-I LrEHk-II
(a) T1 1. 500 K
(b) T2 2. 1000 K
(c) T3 3. 200 K
(A*) a  3, b  1, c  2 (B) a  1, b  2, c  3
(C) a  2, b  3, c  1 (D) lwpuk vi;kZIr gSA
4. Plot at Boyle’s temperature for a real gas will be :
ckW;y rki ij ,d okLrfod xSl dk vkjs[k] fuEu izdkj dk gksxk %
(A) (B) (C*) (D)
Sol. At Boyle's temperature, for low pressure regions, Z = 1. However, for high pressure regions, Z > 1.
ckW;y rki ij, fuEu nkc okys {ks=k esa, Z = 1. tcfd mPp nkc okys {ks=k esa , Z > 1.
5.* The curves in the Fig. represents two different Maxwell Boltmann velocity
distributions for the same gas sample under two different conditions, A and
B. Which of the following statements about conditions A and B is/are false?
(A) The temperature for B is greater than for A.
(B*) The average kinetic energy for A is greater than for B.
(C*) The intermolecular attractive forces are greater for A than for B.
(D*) A and B correspond to the same temperature but different volumes.
leku xSl uewus dh nks fHkUUk A o B ds fy, leku nks fHkUu esDlosy&oksYVeku osx
forj.k dk vkjs[k fp=k esa iznf'kZr gSA fuEu es ls dkSu lk dFku fLFkrh A vkSj B ds
fy, lgh gS&
(A) B ds fy, rkieku A dh vis{kk vf/kd gSA
(B*) A ds fy, vkSlr xfrt ÅtkZ B vis{kk vf/kd gSA
(C*) A ds fy, B dh vis{kk vUrjkf.o vkd"kZ.k cy vf/kd gSA
(D*) A vkSj B ds laxr rkieku leku gS ysfdu vk;ru fHkUu gSA
6.* Which of the following statements is/are correct about Boyle temperature (T B):
(A) Temperature at which 1st virial cofficient of Vander waal equation becomes Zero.
(B*) Temperature at which 2nd virial cofficient of Vander waal equation becomes Zero.
a
(C*) According to Vander waal's equation, value of T B = .
Rb
(D*) TB of a gas depends upon the nature of gas.
fuEu esa ls dkSulk@dkSuls dFku] ckW;y rki (TB) ds lanHkZ esa lR; gS@gSa %
(A) rki] ftl ij ok.Mj okWy lehdj.k dk izFke fofj;y xq.kkad 'kwU; gksrk gSA
PAGE NO.-60
(B*) rki] ftl ij ok.Mj okWy lehdj.k dk f}rh; fofj;y xq.kkad 'kwU; gksrk gSA
a
(C*) ok.Mj okWy lehdj.k ds vuqlkj] TB dk eku gksrk gSA
Rb
(D*) xSl dk TB, xSl dh izd`fr ij fuHkZj djrk gSA
7.* The given plot represents the P-V plot of a gas at different temperatures. Then
which of the following statements are true.
(A) vapour liquid equilibrium can exist at T 5
(B*) vapour liquid equilibrium can exist at T 1
(C*) vapour liquid equilibrium can exist at T 2
(D) vapour liquid equilibrium can exist at T 4
mijksDr vkjs[k ,d xSl ds fy, fofHkUu rki ij P-V vkjs[k dks fu:fir djrk gSA rks
fuEu esa ls dkSulk/dkSuls dFku lgh gSA
(A) T5 Ikj ok"i nzo lkE; vfLRkRo es gks ldrk gSA
(B*) T1 Ikj ok"i nzo lkE; vfLRkRo es gks ldrk gSA
(C*) T2 Ikj ok"i nzo lkE; vfLRkRo es gks ldrk gSA
(D) T4 Ikj ok"i nzo lkE; vfLRkRo es gks ldrk gS
Sol. Clearly from the sketch at temperature T 4 & T5 liquefaction of gas is not possible at any pressures
because T4 and T5 is greater than TC .
But in case of T1 and T2 liquefaction can take place hence there can be liquid vapour equilibrium
B
8.* One way of writing the equation of state PV = RT[A + + .......]. which is true for constant A & B in
V
equation. When compare to Vander Waal's equation.
b a
(A) expression for B is a – (B*) expression for B is b –
RT RT
(C*) unit of B is cm3 and it is temperature dependent (D*) constant A must be 1
B
PV = RT[A + + .......] voLFkk lehdj.k dks fy[kus dk ,d rjhdk gS lehdj.k esa fu;rkad A & B ds fy;s
V
dkSulk lgh gS
b a
(A) B ds fy;s O;atd a – (B*) B ds fy;s O;atd b –
RT RT
(C*) B dh bZdkbZ cm3 vkSj ;g rki ij fuHkZj djrh gSZ (D*) fu;rkad A , 1 gh gksuk pkfg;s
PV V a
9.* The Vander waal's equation of state for a non-ideal gas can be rearranged to give = 
RT V  b VRT
for 1 mole of gas. The constants a & b are positive numbers . When applied to H 2 at 80K, the equation
gives the curve as shown in the figure. Which one of the following statements is(are) correct:
PV V a
,d vukn'kZ ¼okLrfod½ xSl ds ,d eksy ds fy, okUMjokWYl~ lehdj.k dks iquZO;ofLFkr dj = 
RT V  b VRT
nh tk ldrh gSA fu;rkad a rFkk b /kukRed la[;k,¡ gaSA tc 80K ij H2 ds fy, lehdj.k dk iz;ksx djrs gSa] rks
lehdj.k vkd`fr esa n'kkZ, vuqlkj oØ nsrh gSA fuEu esa ls dkSulk@dkSuls oDrO; lgh gS@gSa %
1.0
PV
RT
40 60 80
0
P, atm
(A) At 40 atm, the two terms V/(V  b) & a/VRT are equal.
(B) At 80 atm, the two terms V/(V  b) & a/VRT are equal.
PAGE NO.-61
(C*) At a pressure greater than 80 atm, the term V/(V  b) is greater than a/VRT.
a
(D*) At 60 atm, the term V/(V  b) is smaller than 1  .
VRT
(A) 40 atm ij nksuksa in V/(V  b) rFkk a/VRT cjkcj gksaxsA
(B) 80 atm ij nksuksa in V/(V  b) rFkk a/VRT cjkcj gkasxAs
(C*) tc nkc 80 atm ls Åij gksxk] rc in V/(V  b), a/VRT ls vf/kd gksxkA
a
(D*) 60 atm ij in V/(V  b), 1  ls NksVk gksxkA
VRT
PV
Sol. Clearly, from the graph at 80 K = = 1 and at 60K, Z < 1
RT
PV
Sol. Li"Vr% 80 K ij xzkQ ls K = = 1 rFkk 60K ij Z < 1.
RT
Comprehension #
Vanderwaal equation for real gas is given as :
 an2 
 P   (V–nb) = nRT
 V2 
PVm
Where ‘a’ and ‘b’ are constant for pressure and volume correction. If factor Z =
RT
is to be calculated, where Vm is molar volume.
vuqPNsn #
okLrfod xSl ds fy, okUMjokYl lehdj.k fuEu nh xbZ
 an2 
 P  2  (V–nb) = nRT
 V 
PVm
;gkW ‘a’ rFkk ‘b’ xSl rFkk vk;ru la'kks/ku (correction) ds fy, fu;arkd gSA ;fn dkjd Z dh] Z =
RT
}kjk x.kuk dh tkrh gSA ;gkW Vm eksyj vk;ru gSA
10. For a real gas with very large value of molar volume, which of the following equation can most suitably
be applied:
vR;f/kd eksyj vk;ru okyh ,d okLrfod xSl ds fy, fuEu esa ls dkSulh lehdj.k] lokZf/kd mi;qDr :i ls
iz;qDr dh tk ldrh gS %
a Pb a
(A) Z = 1 – (B*) PVm = RT (C) Z = 1 + (D) PVm – RT =
VmRT RT Vm
Sol. For very large value of molar volume (Vm)
a
and b can be neglected, so gas behaves as Ideal
Vm
 PVm = RT
vR;f/kd eksyj vk;ru (Vm) ds fy,
a
rFkk b dks ux.; ekuk tk ldrk gS vr% xSl vkn'kZ O;ogkj djrh gSA
Vm
 PVm = RT
11. Which of following graph is correct for a sample of 1 mol of real gas at a fixed very high pressure.
fuEu esa ls dkSulk xzkQ mPp nkc ij okLrfod xSl ds 1 eksy uewus ds fy;s lgh gSA
PAGE NO.-62
(A*) (B) (C) (D)
Pb
Sol. Z=1+ (High pressure region) mPPk nkc {kS=k  y = C + mx
RT
12. Which of the following statement is correct.

(A) When Z > 1, real gases are easier to compress than ideal gas
(B) When Z = 1, real gases get compressed easily
(C*) When Z > 1, real gases are difficult to compress
(D) Ideal gases easier to compress than real gases.
fuEu esa ls dkSuls dFku lgh gSA
(A) tc Z > 1 gksxk] rc okLrfod xSl dk vkn'kZ xSl dh rqyuk esa lEihMu vklku gksxkA
(B) tc Z = 1, okLrfod xSl vklkuh ls lEihfM+r gksxhA
(C*) tc Z > 1 gksxk] rc okLrfod xSl dk lEihM+u dfBu gksxkA
(D) vkn'kZ xSl dk lEihM+u okLrfod xSl dh rqyuk esa ljy gksrk gSA
13. If the value of Avogadro number is 6.023 × 1023 mol–1 and the value of Boltzmann constant is
1.380 × 10–23 J K–1, then the number of significant digits in the calculated value of the universal gas
constant is
;fn vkoksxknzks la[;k dk eku 6.023 × 1023 mol–1 gS rFkk cksYV~Wleku fLFkjkad dk eku 1.380 × 10–23 J K–1 gS] rc
ifjdfyr lkoZf=kd xSl fLFkjkad (universal gas constant) esa lkFkZd vadksa (significant digits) dh la[;k gS %
Ans. 4
R
Sol. K=  R = k.NA
NA
= 6.023 × 1023 × 1.380 × 10–23 J.mol–1.k–1
There are 4 significant figures in each term. (;gkW izR;sd in esa 4 lkFkZd vad gSA)
Hence, these be 4 significant figure in R. (vr% R esa pkj lkFkZd vad gksxsA)
14. Determine the total number of electrons with clockwise spin and n +  + m = 3 in Ar (Z = 18) atom.
Ar (Z = 18) ijek.kq esa n +  + m = 3 rFkk nf{k.kkorZ pØ.k j[kus okys bysDVªkWuksa dh dqy la[;k ifjdfyr dhft,A
Ans. 3
Sol. n +  + m = 3
3 0 0 3s  1 e– with clockwise spin
2 1 0 2px  1 e– with clockwise spin
3 1 –1 3px  1 e– with clockwise spin
 Total number of electrons = 1 + 1 + 1 = 3
gy n +  + m = 3
3 0 0 3s  1 e– nf{k.kkorZ pØ.k ds lkFk
2 1 0 2px  1 e– nf{k.kkorZ pØ.k ds lkFk
3 1 –1 3px  1 e– nf{k.kkorZ pØ.k ds lkFk
 bysDVªkWuksa dh dqy la[;k = 1 + 1 + 1 = 3
15. A bottle of 1 litre capacity is labelled as 1 molar Al 2(SO4)3(aq). If the bottle is half filled and density of
solution is 1.342 g/mL, then what will be molality of Al3+(aq) in this solution.
1 yhVj {kerk okys ,d ik=k dks 1 eksyj Al2(SO4)3(aq) fy[k dj ukekafdr fd;k x;k gSA ;fn ;g ik=k vk/kk Hkjk gS
rFkk foy;u dk ?kuRo 1.342 g/mL gS] rks bl foy;u esa Al3+(aq) vk;uksa dh eksyyrk D;k gksxh %
Ans. 2
PAGE NO.-63
1
Sol. m= =1
(1000  1.342  342)
1000
As each mole of Al2(SO4)3 gives two mole of Al3+ ion
Al2(SO4)3 dk izR;sd eksy Al3+ ds nks eksy nsrk gS
mAl3 = 2 × 1 = 2 m.
16. Let Z be the compressibility factor for a real gas at critical conditions and Vander W aal constant 'b' is
RT 
dependent as b =  C  , then find the product (Z × m).
mP  C
ekuk dh] Øakfrd ifjfLFkfr ij] ,d okLrfod xSl ds fy,] lEihM~;rk xq.kkad Z gS rFkk ok.Mjoky fu;rkad 'b', fuEu
R  TC 
çdkj ls fuHkZj djrk gS] b = , rc (Z × m) dk xq.kuQy Kkr dhft;s \
m  PC 
Ans. 3
PC VC 3
Sol. For a real gas at critical point, Z = =
RTC 8
R  TC 
Also, b =
8  PC 
 m=8
3
 Product (Z × m) = × 8 = 3.
8
PC VC 3
gy- Økafrd fcUnq ij ,d okLrfod xSl ds fy,] Z = =
RTC 8
RT 
rFkk, b =  C 
8  PC 
 m=8
3
 (Z × m) dk xq.kuQy = ×8=3
8
17. A certain quantity of an ideal gas occupied 128 mL when collected over water at 15°C and 754 mm
pressure. It occupies 118.3 mL in dry state at NTP. Find the vapour pressure of water (in mm) at 15°C.
tc ,d vkn'kZ xSl dh fuf'pr ek=kk dks 15ºC rki rFkk 754 mm nkc ij ty ds Åij ,df=kr fd;k tkrk gSa] rc
bl xSl ds }kjk ?ksjk x;k vk;ru 128 mL gSA NTP ij 'kq"d voLFkk esa bl xSl ds }kjk ?ksjk x;k vk;ru 118.3
mL gSA rc 15ºC rki ij ty ds ok"i nkc dh x.kuk ¼mm esa½ dhft,A
Ans. 13
Sol. For gas,
P1V1 P2 V2
=
T1 T2
760  118.3 P2  128
=  P2 = 741 mm of Hg
273 288
Ptotal = P2, gas + V.P.  V.P. = 754 – 741 = 13 mm of Hg
gy % xSl ds fy,]
P1V1 P2 V2
=
T1 T2
760  118.3 P2  128
=  P2 xSl= Hg dk 741 mm
273 288
Ptotal = P2, gas + V.P.  V.P. = 754 – 741 = Hg dk 13 mm.
PAGE NO.-64
18. A certain organic compound contains carbon, hydrogen, oxygen and nitrogen. Weight % of carbon in
the compound is 20. The weight ratio N : H : O = 7 : 1 : 4. What is the least possible molecular mass of
the compound ?
,d dkcZfud ;kSfxd esa dkcZu] gkbMªkstu] vkWDlhtu rFkk ukbVªkstu gSA ;kSfxd esa dkcZu dk nzO;eku % 20 gSA N :
H : O = 7 : 1 : 4 nzO;eku vuqikr eas gSA ;kSfxd dk U;wure lEHko vkf.od nzO;eku D;k gS \
Ans. 60
19. Dihydrogen gas was collected over water in a 20 L vessel at 27ºC at a total pressure of one
atmosphere. On analysis, it was found that the quantity of H 2 collected was 0.775 mole. If this vessel is
now connected with another 10 L evacuated vessel, find the final pressure (in Torr) when equilibrium is
1
established. Take R = Latm/K/mole
12
Report your answer after dividing it by 10 and rounding it off to the nearest whole number. [G.T.S. ]
1 ok;qe.Myh; dqy nkc ij 27ºC ij ,d 20 yhVj ds ik=k esa ikuh ds Åij MkbZgkbMªkstu xSl ,df=kr dh xbZA
v/;;u djus ij ik;k x;k fd H2 dh ,df=kr ek=kk 0.775 eksy gSA ;fn bl ik=k dks ,d vU; 10 yhVj ds
1
fuokZfrr ik=k ls tksM fn;k tkrk gS] rks lkE; vkus ij vfUre nkc ¼VkWj esa½ Kkr dhft,A \R = Latm/K/mole
12
yhft,A viuk mRrj 10 ls Hkkx nsdj fudVre iw.kk±d ds :i esa nhft,A
Ans. 51

Column I Column II
For a gas, repulsive tendency Effects of ‘a’ and ‘b’ compensate each
(A) (p)
dominates other.
At TB = – 3°C for a gas in high There is no difference between physical
(B) (q)
pressure region properties in liquid and gas state.
(C) At TC (r) Z>1
For He gas at 0°C in all pressure
(D) (s) TC = 80 K
region
fuEu dks lqesfyr dhft,&

LrEHk I LrEHk II
'a' vkSj 'b' dk izHkko ,d nwljs dks le;ksftr
(A) ,d xSl ds fy;s izfrd"khZ izo`fÙk izHkkoh gS (p)
djrk gSA
TB = – 3 °C ij ,d xSl ds fy;s] mPp ;gk¡ nzo vkSj xSl voLFkk esa HkkSfrdh; xq.k/keks±
(B) (q)
nkc {ks=k esa esa dksbZ vUrj ugha gSA
(C) TC ij (r) Z>1
(D) 0°C ij He xSl ds fy;s lHkh nkc {ks=k esa (s) TC = 80 K
Ans. [A – r] ; [B – r, s] ; [C – q] ; [D – r]
PAGE NO.-65

TARGET: JEE (Main + Advanced) 2020 Course: VIKAAS (JA) NO. B1

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DPPs BOOKLET-2 VIKAAS (JA) | CHEMISTRY

TARGET : JEE (Main + Advanced) 2020

Course : VIKAAS(JA) NO. B1

5. In the electronic configuration of Mn (Z = 25) :

11 The density of air at STP is 0.0013 g mL–1. Its vapour density is :

TARGET : JEE (Main + Advanced) 2020

Course : VIKAAS(JA) NO. B2

gy % 1 × 103 kg/m3 = 1 g/mL. [Since, 1m3 = 106 cm3 = 106 mL].

8.* For a reaction :

Number of apples are = 12 (exactly) = 12.000000........... 

lsoks dh la[;k = 12 (Bhd exact) = 12.000000........... 

10. Write the number of significant figures in the following :

11. Count total number of S.F. in

Ans. (A)  p, s ; (B)  q, r ; (C)  p, s (D)  q, r

TARGET : JEE (Main + Advanced) 2020

Course : VIKAAS(JA) NO. B3

(A) (B) (C*) (D)

15. Calculate the molarity when :

ChemINFO Estimation of Sulphur

ChemINFO Estimation of Sulphur

TARGET : JEE (Main + Advanced) 2020

Course : VIKAAS(JA) NO. B4

7.* Identify the incorrect statement(s) :

TARGET : JEE (Main + Advanced) 2020

Course : VIKAAS(JA) NO. B5

3. If for any electron in an orbital, a parameter ‘P’ is defined as :

ChemINFO Duma's Method

16. Nitrogen is estimated in organic compound by :

TARGET : JEE (Main + Advanced) 2020

Course : VIKAAS(JA) NO. B6

8.* Dichromate ion in acidic medium oxidizes stannous ion as :

9.* Identify the correct options for the following reaction

ds m eksy lhekar gSa rc AnBm ds   eksy mRikfnr gksxsaA

ChemINFO Estimation of Phosphorus

ChemINFO Estimation of Phosphorus

TARGET : JEE (Main + Advanced) 2020

Course : VIKAAS(JA) NO. B7

4. Maximum number of electrons in a subshell with  = 3 and n = 4 is :

(A) (B*) (C*) (D)

8. When the valve connecting (A) and (B) is opened, V = 10 L V = 30 L

Total no. of mole of gas before opening the stop cock

TARGET : JEE (Main + Advanced) 2020

Course : VIKAAS(JA) NO. B8

TARGET : JEE (Main + Advanced) 2020

Course : VIKAAS(JA) NO. B9

2. At a definite temperature (T), the distribution of velocities is given by the

3. The graphs representing distribution of molecular speeds at 300

12. Match the following :

ChemINFO Estimation Of Halogens

ChemINFO gSykstu dk fu/kkZj.k

13. In carius method for estimation of chlorine, the formula used is :

127 massof AgCl

35.5 massof AgCl

35.5 massof organic compound

TARGET : JEE (Main + Advanced) 2020

Course : VIKAAS(JA) NO. B10

gy- fu;r rki ij]

8. If an ideal gas is allowed to expand at constant tempeature then-

11. If a gas expands at constant temperature, it indicates that :

(A) (B) (C) (D)