[Adsorption / desorption isotherm]

File Name HC MeOH 15.DAT

Date of measurement 3/12/2012
Time of measurement 12:44:17
COMMENT1 HC MeOH 15
COMMENT2
COMMENT3
COMMENT4
Serial number 256
Version

Sample weight 0.1563 [g] Saturated vapor pressure

Standard volume 8.97 [cm3] Adsorption cross section area
Dead volume 12.624 [cm3] File name of walladsorption
Equilibrium time 100 [sec] all adsorption correction value 1
Adsorptive N2 all adsorption correction value 2
Apparatus temperature 0 [C] Number of adsorption data
Adsorption temperature 77 [K] Number of desorption data

No pi /kPa pe /kPa pe2 /kPa p0 /kPa p/p0

ADS
1 0 0.0040591 0 98.041 4.1402E-05
2 0 0.020295 0 97.972 0.00020715
3 0 0.052768 0 97.956 0.00053869
4 0 0.6495 0 97.948 0.0066306
5 0 3.2026 0 97.891 0.032716
6 0 4.7207 0 97.924 0.048208
7 0 7.0465 0 97.863 0.072004
8 0 9.5591 0 97.891 0.09765
9 0 12.068 0 97.839 0.1233
10 0 14.564 0 97.806 0.1489
11 0 17.012 0 97.83 0.1739
12 0 19.471 0 97.774 0.1991
13 0 21.891 0 97.701 0.2241
14 0 24.326 0 97.713 0.249
15 0 26.778 0 97.721 0.274
16 0 29.25 0 97.677 0.2995
17 0 34.007 0 97.636 0.3483
18 0 39.133 0 97.592 0.401
19 0 43.956 0 97.596 0.4504
20 0 48.644 0 97.567 0.4986
21 0 53.287 0 97.551 0.5462
22 0 58.414 0 97.555 0.5988
23 0 63.443 0 97.482 0.6508
24 0 67.429 0 97.442 0.692
 25 0 68.03 0 97.413 0.6984
26 0 71.667 0 97.397 0.7358
27 0 72.815 0 97.393 0.7476
28 0 75.799 0 97.357 0.7786
29 0 77.723 0 97.332 0.7985
30 0 79.858 0 97.328 0.8205
31 0 82.988 0 97.3 0.8529
32 0 85.155 0 97.3 0.8752
33 0 88.216 0 97.28 0.9068
34 0 90.497 0 97.256 0.9305
35 0 92.372 0 97.247 0.9499
36 0 94.848 0 97.215 0.9757
37 0 96.208 0 97.203 0.9898
38 0 96.642 0 97.215 0.9941
DES
1 0 95.01 0 97.223 0.9772
2 0 92.498 0 97.219 0.9514
3 0 87.615 0 97.207 0.9013
4 0 84.891 0 97.195 0.8734
5 0 82.038 0 97.219 0.8438
6 0 79.663 0 97.211 0.8195
7 0 77.354 0 97.219 0.7957
8 0 75.539 0 97.219 0.777
9 0 72.787 0 97.215 0.7487
10 0 71.066 0 97.243 0.7308
11 0 67.027 0 97.247 0.6892
12 0 63.248 0 97.243 0.6504
13 0 59.632 0 97.26 0.6131
14 0 58.491 0 97.235 0.6015
15 0 53.77 0 97.243 0.5529
16 0 48.794 0 97.256 0.5017
17 0 43.736 0 97.243 0.4498
18 0 39.044 0 97.268 0.4014
19 0 34.088 0 97.231 0.3506
20 0 29.103 0 97.251 0.2993
21 0 26.757 0 97.231 0.2752
22 0 24.322 0 97.235 0.2501
23 0 21.85 0 97.235 0.2247
24 0 19.378 0 97.239 0.1993
25 0 16.89 0 97.215 0.1737
26 0 14.426 0 97.211 0.1484
27 0 11.938 0 97.227 0.1228
28 0 9.5226 0 97.243 0.097926

Adsorption / desorption isotherm

240
g-1
 Adsorption / desorption isotherm

240
Va/cm3(STP) g-1

160

80

0
0 0.5 1
p/p0

ADS DES
 Saturated vapor pressure 97.435 [kPa]
Adsorption cross section area 0.162 [nm2]
File name of walladsorption
adsorption correction value 1
adsorption correction value 2
Number of adsorption data 38
Number of desorption data 28

Va/cm3(STP) g-1

0.4834
7.0499
13.809
19.893
23.166
24.303
25.797
27.267
28.714
30.127
31.557
33.016
34.536
36.1
37.711
39.366
42.608
46.121
49.524
53.148
57.146
62.433
68.722
75.281
76.381
84.248
87.087
95.831
102.24
111.28
125.83
134.8
146.43
153.89
159.45
165.33
168.01
168.73

167.63
165.52
157.36
149.85
142.01
134.96
127.69
120.21
107.42
99.752
85.577
76.126
68.779
66.915
60.465
55.455
50.985
47.461
43.931
40.427
38.8
37.125
35.484
33.879
32.35
30.86
29.4
27.95
[BET plot]
File Name HC MeOH 15.DAT
Date of measurement 3/12/2012
Time of measurement 12:44:17
COMMENT1 HC MeOH 15
COMMENT2
COMMENT3
COMMENT4
Serial number 256
Version

Sample weight 0.1563 [g] Saturated vapor pressure

Standard volume 8.97 [cm3] Adsorption cross section area
Dead volume 12.624 [cm3] File name of walladsorption
Equilibrium time 100 [sec] all adsorption correction value 1
Adsorptive N2 all adsorption correction value 2
Apparatus temperature 0 [C] Number of adsorption data
Adsorption temperature 77 [K] Number of desorption data

Starting point 6
End point 16
Slore 0.034719
Intercept 0.00055275
Correlation coefficient 0.9997
Vm 28.351 [cm3(STP) g-1]
as,BET 123.4 [m2 g-1] 0.04876431599
C 63.812 63.8120749707
Total pore volume (p/p0=0.990) 0.2598 [cm3 g-1]
Average pore diameter 8.4208 [nm]

No p/p0 p/Va(p0-p)
1 4.1402E-05 8.5648E-05
2 0.00020715 2.939E-05
3 0.00053869 3.9031E-05
4 0.0066306 0.00033554
5 0.032716 0.00146
6 0.048208 0.0020841
7 0.072004 0.0030077
8 0.09765 0.0039688
9 0.1233 0.0049001
10 0.1489 0.0058074
11 0.1739 0.0066704
12 0.1991 0.0075316
13 0.2241 0.0083612
14 0.249 0.0091821
15 0.274 0.010009
 16 0.2995 0.010859
17 0.3483 0.012544
18 0.401 0.014514
19 0.4504 0.016547
20 0.4986 0.018708

BET-Plot

0.15
p/Va(p0-p)

0.1

0.05

0
0 0.25 0.5
p/p0
 Saturated vapor pressure 97.435 [kPa]
Adsorption cross section area 0.162 [nm2]
File name of walladsorption
adsorption correction value 1
adsorption correction value 2
Number of adsorption data 38
Number of desorption data 28

123.474173946
123.32685
 ADS DES
No
p/p0 Va/cm3(STP) g-1 p/p0 Va/cm3(STP) g-1
V vs P/Po
1 0 0 0.989 84.27
2 0.01 5 0.91 79.66 Adsorption
3 0.05 10 0.825 78.25 120
4 0.07 13 0.75 77.01
5 0.107 16.98 0.717 75.98 100
6 0.141 18.13 0.677 72.62
0.167 19 80
7 0.66 70.81

V
8 0.223 19.4 0.637 66.01 60
9 0.244 19.8 0.625 64.36
10 0.268 19.99 0.588 55.67 40
11 0.322 20.2 0.573 51.4
12 0.404 21.2 0.542 44.3 20
13 0.47 25 0.49 35.05
14 0.555 35.5 0.458 30.33 0
0 0.2 0.4 0.6
15 0.637 50.28 0.417 25.8 P/Po
16 0.667 55.86 0.4 22.09
17 0.694 61.49 0.325 21.5 p/p0
18 0.724 65.67 0.27 20.5 7 0.05
19 0.756 70.65 0.24 20 8 0.07
20 0.781 74.76 0.22 19.5 9 0.107
21 0.825 78.07 10 0.141
22 0.883 79.38 11 0.167
23 0.939 79.84 12 0.223
24 0.971 81.43 13 0.244
25 0.99 84.14 14 0.268
26 0.999 87.35
27 1 91.84
28 1 96.35

BET Linear Region (P/Va(Po-P

0.02
P/Va(Po-P)

0.018
0.016 f(x) = 0.061090741215972 x + 0.001192
R² = 0.980231653578762
0.014
0.012
0.01
0.008
0.006
0.004
0.002
0
0 0.05 0.1 0.15 0.2 0.25
P/Po
Vm 28.6532951289
a 124.790728612 m2/g
 V vs P/Po
Adsorption Desorption

.2 0.4 0.6 0.8 1 1.2

P/Po

Va/cm3(STP) g-1 p/Va(p0-p)

10 0.00526315789
13 0.00578990902
16.98 0.00705658591
18.13 0.00905374263
19 0.01055158906
19.4 0.01479388077
19.8 0.01630057186
19.99 0.01831516851

Linear Region (P/Va(Po-P) vs P/Po)

(x) = 0.061090741215972 x + 0.001192420537684

² = 0.980231653578762

p/Va(p0-p)
Linear (p/Va(p0-p))

0.1 0.15 0.2 0.25 0.3

P/Po