Astm D6161 - 1998
Astm D6161 - 1998
Astm D6161 - 1998
Standard Terminology
Used for Crossflow Microfiltration, Ultrafiltration,
Nanofiltration and Reverse Osmosis Membrane Processes1
This standard is issued under the fixed designation D 6161; the number immediately following the designation indicates the year of
original adoption or, in the case of revision, the year of last revision. A number in parentheses indicates the year of last reapproval. A
superscript epsilon (e) indicates an editorial change since the last revision or reapproval.
membrane separation processes. used to remove tastes, odor, chlorine, chloramines, and some
organics from water. A family of carbonaceous substances
2. Referenced Documents manufactured by processes that develop adsorptive proper-
2.1 ASTM Standards: ties.
D 1129 Terminology Relating to Water2 adsorption—the holding of a substance onto the surface of a
D 2035 Practice for Coagulation-Flocculation Jar Test of solid by chemical surface forces, without forming new
Water3 chemical bonds.
aerobic bacteria—bacteria that require oxygen for growth.
3. Significance and Use See bacteria, aerobes.
3.1 The need to understand the relationships found in aggregate—granular material such as sand, gravel, crushed
membrane unit processes for water treatment increases with the stone.
continuing demand for these separation systems. Defining the air scour—distributing air over the entire filter area at the
terms common to crossflow microfiltration, ultrafiltration, bottom of a filter media flowing upward to improve the
nanofiltration and reverse osmosis processes assist the manu- effectiveness of backwashing or to permit the use of lower
facturer, consultant and end-user in eliminating inter-process backwash water flow rate, or both.
terminology confusion. algae—any of a group of chiefly aquatic mono cellular plants
with chlorophyll often masked by a brown or red pigment.
4. Terminology alkalinity—the quantitative capacity of aqueous media to react
4.1 Definitions: with hydrogen ions. “M” alkalinity is that which will react
with acid as the pH of the sample is reduced to the
absorption—the holding of a substance within a solid by methylorange endpoint of about 4.5. “P” alkalinity is that
cohesive or capillary forces. which reacts with acid as the pH of the sample is reduced to
accumulator—a pulsation dampener installed on the suction the phenolphthalein end point of 8.3.“ M” is the total
and/or discharge lines of pumps, generally plunger type, to alkalinity which is the sum of hydroxide plus carbonate plus
minimize pressure surges and provide uniformity of flow. bicarbonate contents, “P” includes all the hydroxyl and half
accuracy—the closeness of agreement between an observed the carbonate content.
value and an accepted reference value. Where an accepted alum—aluminum sulfate, AL2(SO 4)3XH2O (X 5 14-18), a
reference value is not available, a measure of the degree of coagulant.
conformity of a value generated by a specific procedure to ambient temperature—the temperature of the surroundings,
the assumed or accepted true value, and includes both typically 20°– 25°C.
precision and bias. amorphous—non crystalline, devoid of regular cohesive
acetylation—substitution of an acetyl radical for an active structure.
hydrogen. Specifically, formation of cellulose acetate from anaerobic bacteria—bacteria that do not use oxygen. Oxygen
cellulose. is toxic to them. See bacteria, anaerobes.
amphoteric—capable of acting as an acid or a base.
1
This terminology is under the jurisdiction of ASTM Committee D-19 on Water angstrom (A)—a unit of length equaling 10−10 metres, 10−4µ
and is the direct responsibility of Subcommittee D19.08 on Membranes and Ion metres, 10 −8 centimetres and 3.937 3 10−9 in. The symbol
Exchange Materials.
Current edition approved March 10, 1998. Published December 1998. Originally
is Å, A or A.U. .
published as D 6161 – 97. Last previous edition D 6161–97. anion—negatively charged ion.
2
Annual Book of ASTM Standards, Vol 11.01.
3
Annual Book of ASTM Standards, Vol 11.02.
precipitation of sparingly soluble inorganic salts. For densities less than unity.
anti-telescoping device—a plastic or metal device attached to *60°F/60°F
the ends of a spiral wound cartridge to prevent movement of bed depth—the depth of the filter medium or ion exchange
the cartridge leaves in the feed flow direction, due to high resin in a vessel.
feed flows. bed expansion—the depth increase of filter medium or ion
AOC—assimilable organic carbon. exchange resin that occurs during backwashing.
aquifer—a water-bearing geological formation that provides a binders—in reference to cartridge filters, chemicals used to
ground water reservoir. hold, or 8bind’, short fibers together in a filter.
aramid—a fully aromatic polyamide. biocide—a substance that kills all living organisms.
array—an arrangement of devices connected to common feed, biological deposits—the debris left by organisms as a result of
product and reject headers; that is, a 2:1 array. their life processes.
asymmetric membrane—membrane which has a change in biomass—any material which is or was a living organism or
pore structure with depth. See anisotropic membranes. excreted from a micro-organism.
ATD—see anti-telescoping device.
biostat—a substance that inhibits biological growth.
atomic weight—the relative mass of an atom based on a scale
binding—in surface filtration, a build-up of particulates on the
in which a specific carbon atom (carbon 12) is assigned a
filter, restricting fluid flow through the filter at normal
mass value of 12.
pressures.
ATP—adenosine triphosphate.
block—a grouping of devices in a single unit having common
autopsy—the dissection of a membrane module or element to
control. See array, bank, train.
investigate causes of unsatisfactory performance.
availability—the on-stream time or rated operating capacity of BOD (biochemical oxygen demand)—the amount of dis-
a water treatment system. solved oxygen utilized by natural agencies in water in
a-value—membrane water permeability coefficient. The coef- stabilizing organic matter at specified test conditions.
ficient is defined as the amount of water produced per unit body feed—the continuous addition of filter medium (for
area of membrane when net driving pressure (NDP) is unity, example, diatomaceous earth) to sustain the efficacy of the
a unit of measurement is m3/hr/m2/kPa. filter.
AWWA—American Water Works Association. BOO—build, own, operate.
AWWARF—American Water Works Association Research BOOT—build, own, operate and transfer.
Foundation. boundary layer—a thin layer at the membrane surface where
backwash—reverse the flow of water with/without air either water velocities deviate significantly less than those in the
across or through a medium or membrane designed to bulk flow.
remove the collected foreign material from the bed or brackish water—water with an approximate concentration of
membranes. total dissolved solids ranging from 1000 to 10 000 mg/L. See
--`-`-`,,`,,`,`,,`---
bacteria—any of a class of microscopic single-celled organ- high brackish water, sea water.
isms reproducing by fission or by spores. Characterized by breakpoint chlorination—the point at which the water chlo-
round, rod-like spiral or filamentous bodies, often aggre- rine demand is satisfied and any further chlorine is the
gated into colonies or mobile by means of flagella. Widely chlorine residual, the “free” chlorine species.
dispersed in soil, water, organic matter, and the bodies of break tank—a storage device used for hydraulic isolation and
plants and animals. Either autotrophic (self-sustaining, self- surge protection.
generative), saprophytic (derives nutrition from non-living brine—the concentrate (reject) stream from a crossflow mem-
organic material already present in the environment), or brane device performing desalination. Portion of the feed
parasitic (deriving nutrition from another living organism). stream which does not pass through the membrane.
Often symbiotic (advantageous) in man, but sometimes brine (concentrate) seal—a rubber lip seal on the outside of a
pathogenic. spiral wound cartridge which prevents feed by-pass between
by multiplying concentration in mg/L of the ion by the as chlorine of polyphosphate, into a feed water supply.
equivalent weight of calcium carbonate (50) and dividing by chloramine—a combination of chlorine and ammonia in water
the equivalent weight of the ion. (See Table 1). which has bactericidal qualities for a longer time than does
carbonate hardness—the hardness in a water caused by free chlorine.
carbonates and bicarbonates of calcium and magnesium. The chlorine—chemical used for its qualities as a bleaching or
amount of hardness equivalent to the alkalinity formed and oxidizing agent and disinfectant in water purification.
deposited when water is boiled. In boilers, carbonate hard- chlorine demand—the amount of chlorine used up by reacting
ness is readily removed by blowdown. with oxidizable substances in water before chlorine residual
calcium hypochlorite—Ca (HCIO)2, a disinfection agent. can be measured.
cartridge—see spiral-wound cartridge. chlorine, residual—the amount of available chlorine present
catalyst—a substance whose presence initiates or changes the in water at any specified time.
rate of a chemical reaction, but does not itself enter into the chlorine, free available—the chlorine (Cl 2), hypochlorite ions
reaction. (OCl–), hypochlorous acid (HOCl) or the combination
cathode—negative electrode. thereof present in water.
cation—positively charged ion. chlorine, total available—the sum of free available chlorine
cation exchange material—a material capable of the revers- plus chloramines present in water.
ible exchange of positively charged ions. CIP—cleaning-in-place.
cationic polyelectrolyte—a polymer containing positively citric acid—C3H4(OH)(CO 2H)3, membrane cleaning chemi-
charged groups used for coagulation/flocculation, usually cal.
dimethyl - aminoethyl methacrylate or dimethyl-aminoethyl clarifier—a tank in which precipitate settles and supernatant
acrylate. See polyelectrolyte. overflows, a liquid-solids separation unit using gravity to
TABLE 1 Conversion FactorsA,B
mg/l mg/l Clark or Grain per French German EPM Atomic
as Ion as CaCO3 English Degree US Gallon Degree Degree MEQ/L Weight
Ca++ 2.495 0.175 0.0583 0.250 0.140 0.0499 40.08
Mg++ 4.112 0.288 0.0583 0.411 0.231 0.0823 24.32
Na+ 2.175 0.152 0.0583 0.218 0.122 0.0435 22.99
K+ 1.279 0.089 0.0583 0.128 0.072 0.0256 39.10
Sr++ 1.141 0.080 0.0583 0.114 0.064 0.0288 87.63
Ba++ 0.728 0.051 0.0583 0.073 0.041 0.0146 137.36
Fe++ 1.791 0.125 0.0583 0.179 0.101 0.0358 55.85
HCO3– 0.819 0.057 0.0583 0.082 0.046 0.0164 61.02
SO4– 1.041 0.073 0.0583 0.104 0.058 0.0208 96.07
Cl– 1.410 0.098 0.0583 0.141 0.079 0.0282 35.46
F– 2.632 0.184 0.0583 0.263 0.148 0.0526 19.00
NO3– 0.806 0.056 0.0583 0.081 0.045 0.0161 62.00
CO3– – 1.666 0.117 0.0583 0.167 0.094 0.0323 60.01
PO4– – – 1.579 0.110 0.0583 0.158 0.089 0.0316 94.98
A
To convert from mg/l as ion to any other unit multiply by factor.
B
To convert to mg/l as ion from any other unit divide by factor.
soluble compounds in water. reverse osmosis (RO)—the separation process where one
precoat—the initial coating of the septum in a diatomaceous component of a solution is removed from another compo-
earth filter to provide initial straining medium. nent by flowing the feed stream under pressure across a
pressure filtration—filtration performed in an enclosed pres- semipermeable membrane. RO removes ions based on elec-
surized filter vessel. tro chemical forces, colloids, and organics down to 150
pressure vessel—the vessel containing one or more individual molecular weight. May also be called hyperfiltration.
membrane elements and designed to withstand safely the RO train—one of two or more complete RO installations,
--`-`-`,,`,,`,`,,`---
the ratio of product (CP ) and feed (CF) salt concentrations material to the mass (density) of an equal volume of water at
expressed as percent. the same specified temperature.
salt rejection, SR—(100 - salt passage) expressed as percent: specific flux—flux divided by net pressure driving force.
S D
spiral wound cartridge—a crossflow membrane element
CP
SR 5 100 1–CF design consisting of a product tube, flat membrane leaves,
feed channel spacers, anti-telescoping devices, and brine
. (concentrate) seal.
sanitization—reduction in the number of bacterial contami- spiral wound membrane—a flat sheet membrane with one or
nants to safe levels. See disinfection. more feed channel spacers and barrier layers, all of which
saturation—the point at which a solution contains enough of are rolled into a spiral configuration.
a dissolved solid, liquid, or gas so that no more will dissolve stage—a sequestial arrangement of pressure vessels, usually
into the solution at a given temperature and pressure. reject staged such as 2:1 array, sometimes permeate staged
SBS—sodium bisulfite, NaHSO3. as in double pass RO.
scale inhibitor—a chemical which inhibits the growth of staging—see brine staging and product staging.
micro-crystals (inhibits precipitation of sparingly soluble standard test conditions—the parameters under which a
salts). See antiscalant. membrane manufacturer tests devices for flow and salt
scaling—the build-up of precipitated salts on a surface, such as rejection.
membranes, pipes, tanks, or boiler condensate tubes. sterilization—destruction or removal of all viable organisms.
SDI—silt density index—an index calculated from the rate of Stiff & Davis stability index, S&DSI—an index calculated
plugging of 0.45 µm membrane filter. It is an indication of from total dissolved solids, calcium concentration, total
the amount of particulate matter in water, sometimes called alkalinity, pH and solution temperature that shows the
fouling index. tendency of a water solution to precipitate or dissolve
S&DSI—Stiff and Davis saturation index, measure of CaCO3 calcium carbonate. S&DSI is used primarily for seawater
solubility in seawater or highly saline water. See LSI. RO applications.
SDWA—Safe Drinking Water Act of the United States, speci- STP—sodium triphosphate - Na5P 3O10, a cleaning agent.
fying required purity levels of municipal potable water. STPP—sodium tripolyphosphate. See STP.
sea water—water with an approximate concentration of total supersaturation—a state in which the inorganic salt (s) are in
dissolved solids ranging from 30 000 to 60 000 mg/L. See solution at a level higher than the respective solubility
brackish water, high brackish water. product.
sedimentation—the precipitation or settling of insoluble ma- suspended solids (SS)—solid organic and inorganic particles
terials from a suspension, either by gravity or artificially. For that are held in suspension in a liquid.
example, centrifuge, pressure. SWRO—seawater reverse osmosis.
semipermeable membrane—a membrane which preferen- symmetric membrane—membrane and bulk polymer have
tially allows the passage of specific compounds while equivalent characteristic (isotropic).
rejecting others. TBC—total bacteria count, the total number of viable micro-
SHMP—sodium hexametaphosphate. (NaHMP) organisms present in the sample, excluding anaerobic organ-
Siemens—a measure of electrical conductance in water, isms.
equivalent to a mho. See Mho, Ohm. TCC—total colony count.
slime—biological deposits of gelatinous or filamentous matter. TDS—total dissolved solids, usually expressed as mg/L or
sludge—a water-formed sedimentary deposit. ppm (parts per million).
sludge blanket—suspended bed of solids in a solids contact or telescoping—the movement of the outer layers of a spiral
sludge blanket clarifier. wound cartridge in the direction of the feed flow caused by
SMBS—sodium metabisulfite, Na2S 2O5. excessive pressure drop through the feed channel spacer.
softening—see membrane softening. temperature correction factor (TCF)—defines the effect of
softener—water treatment equipment that uses a sodium based temperature on permeate flow relative to a base temperature
thin film composite (TFC)—see composite membrane. but will retain non-ionic solutes based primarily on physical
threshold treatment—the process of stopping precipitation at size, not chemical potential.
the start of occurrence; usually does not stop the formation
ultra pure water—water generally used in semiconductor
of nuclei but does inhibit growth. See antiscalant.
THM—trihalomethanes; a group of low molecular weight industry having specifications (chemical, physical and bio-
molecules which can result from chlorination of organics logical) for extremely low contaminant levels.
typically found in surface water. USEPA—U.S. Environmental Protection Agency.
THMP—trihalomethane precursors; organic molecules found ultraviolet (UV) radiation—wave lengths between 200 to 300
in water which have the potential of reacting with chlorine to nm. These wave lengths have a strong germicidal effect. The
form THMs. maximum effect is at 253.7 nm.
thrust collar—a plastic cylinder placed between the last spiral viable—ability to live or grow. For example, bacteria, plants.
wound cartridge and vessel end plate to support the last
VOC (viable organism count)—a measure of biological
cartridge in a pressure vessel against telescoping.
activity (living or growing) in water.
TOC—total organic carbon, a measure of the level of organic
constituents in water. VOC (volatile organic compound)—an organic compound
TOCl—total organic chlorine. with a vapor pressure higher than water.
TOX—total organic halides. WQA—water quality association.
TOXFP—total organic halide formation potential. water softener—a vessel having a cation resin in the sodium
train—a grouping of devices. See array, bank, block. form that removes cations such as calcium and magnesium
transmembrane pressure—the net driving force across the from water and releases another ion such as sodium. The
membrane. The hydraulic pressure differential from the feed resin is usually regenerated. See softener.
side to permeate side less the osmotic pressure differential on Y—conversion, recovery.
each side.
zeolite—any of various natural or synthetic hydrated alumi-
TRC—total residual chlorine.
num silicates used as ion exchange substrates in water
trisodium phosphate (TSP)—Na3PO 412H2O, a cleaning
softening.
agent.
TSS—total suspended solids. Concentration of undissolved zero discharge—a condition whereby a facility discharges no
solids in a liquid, usually expressed in mg/L or ppm. process effluent.
TTHM—total trihalomethane. zeta potential—colloidal stability measured in millivolts.
turbidity—a suspension of fine particles that scatters or High negative value (–10 to –30 mv) results in particulate
absorbs light rays. stability.
turbidity, jackson candle (JTU)—an empirical measure of
turbidity in special apparatus, based on the measurement of 5. Summary
the depth of a column of water sample that is just sufficient
5.1 This terminology is common to membrane separation
to extinguish the image of a burning standard candle
processes but independent of the source of manufacture.
observed vertically through the sample.
turbidity, nephelometric (NTU)—an empirical measure of
6. Keywords
turbidity based on a measurement of the light-scattering
characteristics (tyndall effect) of the particulate matter in the 6.1 crossflow; membranes; microfiltration; nanofiltration;
sample. reverse osmosis; terminology; ultrafiltration
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