Modern Steelmaking Processes: Topics To Discuss
Modern Steelmaking Processes: Topics To Discuss
Modern Steelmaking Processes: Topics To Discuss
Topics to discuss…
1. Basic oxygen process
2. Design of converter
3. Feed materials
4. Material balance
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Basic Oxygen Process
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The BOF vessel itself consists of
• the vessel shell, made of a bottom,
a cylindrical centre shell (barrel), and
a top cone;
• reinforcing components to the cone,
such as a lip ring and top ring;
• auxiliary removable bottoms for
bottom reline access, or for
individual bottom reline of bottom-
blown vessels;
• and a tap hole.
ℎ𝑏
= 0.328 𝑇 −0.0148
𝑑𝑏
𝑑𝑏 = 0.704 𝑇 −0.386 𝑚
Nomenclature of the bath dimensions of a converter
ℎ𝑤 ≈ 3.5 x ℎ𝑏
For a 150-ton converter capacity,
hb = 1.48 m; db = 4.87 m; hw = 5.2 m; 𝑉 = 460 m3/min at STP 𝑉 = 3.07 𝑚3 /𝑚𝑖𝑛. 𝑡𝑜𝑛
Total height of converter = 6.7 m (excluding bottom refractory thickness) T = capacity of Converter in ton
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• the attack of molten metal and slag is severe if the liquid iron
contains more silicon and manganese content and/or if steels
with low carbon steels in BOF vessel are to be produced
Safety lining
• burned pitch impregnated magnesite refractories
• typical thickness is 20 cm (45 cm on the bottom)
Working lining
• thickness varied on type of operation and wear rate
• normally lasts 300-1000 heats
• higher wear areas require greater thickness or higher quality materials
Vessel Part Type of Lining Thickness of Lining, mm Materials required for lining
fire brick 1 x 75 a 50/60 ton converter :
magnesite brick 2 x 65
Bottom
magnesite brick 1 x 250 Dolomite brick
tarred dolomite brick 1 x 350 = (3821 nos.) x (31.2 kg/pc)
total thickness 805 = 121.4 ton
magnesite brick 1 x 125 Ramming mass = 9.0 ton
Side wall
tarred dolomite brick 1 x 350
total thickness 835 Magnesite lining = 57.9 ton
magnesite brick 1 x 125 Waste during laying = 6.0 ton
Nose tarred dolomite mass 1 x 190 max
tarred dolomite brick 1 x 350 Total weight refractory = 194.3 ton
total thickness 665 max. (475 min.)
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Multi-hole lances
• large volume of oxygen (typically 60 m3/ton at 109 m3/hr) can be blown with the
restricted total blowing time of 15-20 minutes.
• causes the total jet energy gets dispersed along the diameter of the vessel rather
than in the vertical direction
• this results more liquid metal to be exposed to oxygen, faster slag-metal reaction
and higher productivity
Lance life
• determined by the life of the nozzles.
• failures of the lance due to faulty cooling, manufacturing defects, and
differential expansion between copper tip and steel tube.
• the usual life of a lance does not exceed a few hundred heats.
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Feed Material
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Basis: 1000 kg hot metal hot metal steel/ slag exit gas
steel scrap
0.8% Si CaO 54% 85% CO
Let, 0.2% P 0.1% C FeO 18% 15% CO2
a = mass of steel 0.25% Mn MnO 2.5%
4% C CaO/SiO2 = 3.5
b = mass of slag
Mn balance: Fe balance:
Mn in hot metal = Mn in slag Fe in hot metal + Fe in scrap = Fe in steel + Fe in slag
1000 x (0.0025) = b x 0.025 1000 x 0.9475 + (1000 x 0.15) x 0.999
b = 100 kg = a x 0.999 + (100 x 0.18) x (56/72)
a = 1084.45 kg
C balance:
C in hot metal + C in scrap = C in steel + C in gas
1000 x 0.04 + (1000x0.15) x 0.001 = 1084.45 x 0.001 + C in gas
C in gas = 39.06 kg
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C + O2 = CO2
C + O = CO
C in CO2 = 39.06 x 0.15 = 5.86 kg CO2 produced = (22.4 m3/12 kg) x 5.86 kg = 10.94 m3
C in CO = 39.06 – 5.86 = 33.20 kg CO produced = (22.4 m3/12 kg) x 33.2 kg = 61.97 m3
Oxygen requirement
Mn + 1/2 O2 = MnO
For CO2: 10.94 m3 Fe + 1/2 O2 = FeO
For CO: (61.97 m3) x 0.5 = 30.98 m3 2P + 5/2 O2 = P2O5
For MnO: (1000 x 0.0025) x (22.4/2)/55 = 0.5 m3 Si + O2 = SiO2
For FeO: (100 x 0.18) x (22.4/2)/56 = 0.04 m3
For P2O5: (1000 x 0.002) x (5x22.4/2)/(2x31) = 1.81 m3
For SiO2: (1000 x 0.008) x (22.4/28) = 6.4 m3
Total oxygen requirement = 50.67 m3 at STP
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Required:
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Basis: 20,000 kg pig iron
O supplied per minute = (580 m3) x (1.293 kg/m3) x (0.232 kg O / kg air) = 173.99 kg
In basic Bessemer process, three periods of blow can be identified. During the first
period, Si and Mn are oxidised. During the second period, all carbon is oxidised. In the
third period, P is oxidised.
In all of these periods, Fe is oxidiesd to form FeO. For the ease of calculation, its is
assumed that Fe is oxidised at a uniform rate throughout these periods.
Time for 1st period (without Fe) = (338.57+64) kg / 173.99 kg/min = 2.31 min
Time for 2nd period (without Fe) = (640+640) kg / 173.99 kg/min = 7.36 min
Time for 3rd period (without Fe) = 619.35 kg / 173.99 kg/min = 3.56 min
Total time for 1st period = 2.31 + 1.84 x 2.31 / (2.31+7.36+3.56) = 2.63 min
Total time for 2nd period = 7.36 + 1.84 x 7.36 / (2.31+7.36+3.56) = 8.38 min
Total time for 3rd period = 3.56 + 1.84 x 3.56 / (2.31+7.36+3.56) = 4.06 min
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SiO2 in slag = 340 + 338.57 = 678.57 kg Slag analysis:
MnO in slag = 220+64 = 284 kg
P2O5 in slag = 480+619.35 = 1099.35 kg SiO2 = 678.67 kg = 14.22%
FeO in slag = 720+320 = 1040 kg MnO = 284 kg = 5.95%
P2O5 = 1099.35 kg = 23.04%
Total slag without CaO = 3101.92 kg, FeO = 1040 kg = 21.79%
which is (100-35) or 65% of the total slag CaO = 1670.26 kg = 35.00%
Total = 4772.18 kg = 100%
Total slag formed = 3101.92 kg / 0.65 = 4772.18 kg
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