Material Safety Data Sheet Printing Date: 27.7.

2016
Revision Date:25.7.2016

MATERIAL SAFETY DATA SHEET

1- CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

MANUFACTURER UZ KİMYA KİMYEVİ MADDE PAZARLAMA

ADDRESS and PHONE NUMBERS 129/26 Sk. No:8 4.Sanayi Sitesi Bornova /İZMİR
IN CASE OF EMERGENCY Number:0 232 375 92 22
PRODUCT NAME Zinc Phosphate/Zinc strontium phosphate/Activated
zinc phosphate Pigment
PRODUCT CODE ZP-46/ZSP-44/ZP-30
CHEMICAL CLASS Inorganic Zinc compound
CHEMICAL FORMULA Zn3(PO4)22H2O
EMERGENCY E-MAIL ADDRESS [email protected]
TYPE OF USE : ANTI-CORROSIVE PIGMENT

1.2 Relevant identified uses of the substance or mixture and uses advised against
Identified uses: Use in the manufacture of anti-corrosive coatings.
Uses advised against: This MSDS only applies to the uses identified above

2-HAZARDS IDENTIFICATION

2.1 Classification of the substance or mixture

This material is a substance

Classification according to Regulation (EC) 1272/2008 (EU ‘CLP’ regulation) and GHS
Acute aquatic toxicity (category 1)
Chronic aquatic toxicity (category 1)

Classification according to EU Directive 67/548/EEC

R 50/53
Very toxic to aquatic organisms, may cause long-term harm in the aquatic environment
2.2 Label elements
Labelling according to Regulation (EC) 1272/2008 (EU ‘CLP’ regulation)
Pictogram, signal code(s): GHS09, Wng

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Signal word(s) Warning

Hazard statement(s)
H410 Very toxic to aquatic life with long term effects
Precautionary statements(s)
P273 Avoid release to the aquatic environment
P391 Collect spillage
P501 Dispose of contents/containers as hazardous waste in accordance
with applicable legislation (state the applicable legislation)

2.3 Other hazards

None

3-COMPOSITION AND INFORMATION ON INGREDIENTS

This material is a substance.

Material Name: trizinc bis(orthophosphate)
Index No: 030-011-00-6
EC No: 231-944-3
CAS No: 7779-90-0

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4-FIRST AID

4.1 Description of first aid measures

General advice:
Remove from source of exposure.
This material is not classified as hazardous to health but exposure of first aiders should be
minimised, particularly inhalation of dust or fumes
Inhalation :
Move person to fresh air. If person experiences irritation or difficulty breathing seek medical
advice
Ingestion :
Wash out mouth with water. Make affected person drink plenty of water. Seek medical
advice
Skin contact :
Wash area with water and soap then rinse thoroughly with water.
Eye contact :
Wash out with plenty of water. After initial flushing, remove any contact lenses and continue
flushing. See medical advice in the event irritation or other complaints.

4.2 Most important symptoms and effects, both acute and delayed
No specific effects and/or symptoms have been reported or are known.

4.3 Indication of any immediate medical attention and special treatment needed
None

5-FIRE FIGHTING MEASURES

5.1 Extinguishing media

This material is not combustible. Use extinguishing media based on surrounding materials.

5.2 Special hazards arising from the substances or mixture

Phosphorus oxides and zinc oxides may be formed in a fire situation

5.3 Advice for fire fighters

Use self-contained breathing apparatus.
Prevent fire-fighting water from entering watercourses, drains or the sewage system
(environmental pollutant).

6-ACCIDENTAL RELEASE MEASURES

6.1 Personal precautions, protective equipment and emergency procedures

This material is not classified as hazardous to health but exposure should be minimised,
particularly inhalation of dust.

Evacuate personnel from area of spillage.

Avoid breathing dust. If entry is necessary into an area of significant airborne dust, wear a
particle dust mask: P3, P2 or P1.
Minimise time exposed to dust until a proper evaluation of risk can be undertaken.
Do not undertake actions that will create airborne dust.

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6.2 Environmental precautions

Do not allow to enter sewage system.
Do not allow to enter surface water drains
Do not allow to enter streams, rivers or other waterways
Inform relevant authorities if the material does enter the above systems.
Prevent soil contact.
Remove spilled material from ground and soil as quickly as possible to minimise
environmental contamination

6.3 Methods and material for containment and cleaning up

Take up mechanically while minimise dust generation.
Collect spilled material in sealable containers.
Re-use/recycling of spilled material is highly recommended.
All contaminated materials from the cleaning-up operation must be disposed of as hazardous
waste.
Do not wash residues from spillage to drain with water

6.4 Reference to any other sections

See section 13 for disposal information

7-HANDLING AND STORAGE

7.1 Precautions for safe handling:

Powder may be irritating to the skin or eyes by mechanical action. Dust may be irritating to
the respiratory system. Minimise dust generation and exposure to dust. See section 8 for
details of personal protective equipment
Clear up spillages immediately. Granules / pellets may present a slip hazard.

Follow good hygiene practices: do not eat, drink or smoke in the workplace. Wash hands after
use.
Remove contaminated clothing before entering eating areas.
Follow good hygiene practices: do not eat, drink or smoke in the workplace. Wash hands after
use.
Remove contaminated clothing before entering eating areas.
7.2 Conditions for safe storage, including any incompatibilities
Keep in a dry place
Keep only in the original packaging or other sealable containers.
Keep away from acids and bases.

7.3 specific end use(s)

None identified

8-EXPOSURE CONTROLS AND PERSONAL PROTECTION

8.1 Control parameters

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The minimum level of control that should be undertaken is to comply with the UK
occupational exposure limit for nuisance dust:

Workplace Exposure Limit: Inhalable nuisance dust 10 mg/m3 LTEL (8hr TWA)
Respirable nuisance dust 4 mg/m3 LTEL (8hr TWA)
Exposure should not exceed these levels

8.2 Exposure controls

Appropriate engineering controls
If the occupational exposure limit is likely to be exceeded use ventilation (natural or forced)
or extraction to reduce exposure to below the limit.

Personal protective equipment

This material does not have hazardous chemical properties that require the use of specific
personal protective equipment.
Normal occupational hygiene practices should be followed to minimise skin contact with the
material.
This includes the use of gloves and long sleeved clothing to prevent irritation by mechanical
action.
In the event of eye irritation due to mechanical action wear CEN approved box goggles.
If occupational exposure limits are exceeded use CEN approved dust masks with a filter type
P1, P2 or P3. Dust masks must be used properly to be effective. Follow manufacturers
instructions and also obtain specialist advice to select the correct filter type.

9-PHYSICAL AND CHEMICAL PROPERTIES

FORM Powder SOLUBILITY IN Insoluble

WATER
MELTING POINT 140°C COLOUR White
BOILING POINT N/E ODOR Odorless
FREEZING POINT N/E MOLECULAR 422,11
WEIGHT
BULK DENSITY 300kg/m3 EVAPORATION N/E
15 % DENSITY
SPECIFIC 3,30,1 EVAPORATION N/E
GRAVITY RATE
OTHER DATA pH 7,00,1

10-STABILITY AND REACTIVITY

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10.1 Reactivity
Not reactive to materials commonly used in the transportation, handling and storage of
industrial materials.

10.2 Chemical stability

Stable at room temperature and temperatures up to 90°C .

10.3 Possibility of hazardous reactions

None

10.4 Conditions to avoid

Keep away from acids and bases.

10.5 Incompatible materials

Acids and bases

10.6 Hazardous decomposition products

Phosphorus oxides and zinc oxides may be formed in a fire situation.

11-TOXICOLOGICAL INFORMATION

11.1 Information on toxicological effects

Acute toxicity Oral: LD 50 (rat): > 5000 mg / kg
Skin corrosion/irritation Not irritating (rabbit).
Serious eye damage/ eye irritation Not irritating (rabbit).
Respiratory or skin sensitisation Not sensitising.
Germ cell mutagenicity no data available.
Carcinogenicity no evidence of carcinogenicity.
Reproductive toxicity no evidence of reproductive toxicity.
Specific target organ toxicity
– Single exposure no data available.
Specific target organ toxicity
– Repeated exposure no data available.
Aspiration hazard no data available.

Not classified as having any of these hazards according to the harmonised classification given
in
REGULATION (EC) No 1272/2008 and the first ATP.

12-ECOLOGICAL INFORMATION

12.1 Toxicity
Acute toxicity for fish (Oncorhynchus mykiss) LC(50) (96h) 0.14-0.26 mg Zn2+/L
Acute toxicity for ctustacea (Daphnia magna) EC(50) (48h) 0.04 – 0.86 mg Zn2+/L
Acute toxicity for algae (Selenastrum capriocornutum) EC(50) (72h) 0.136 – 0.150 mg
Zn2+/L

12.2 Persistence and biodegradability

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Data not available.

12.3 Bioaccumulative potential

Data not available.

12.4 Mobility in soil

Data not available.

12.5 Results of PBT and vPvB assessment

Data not available.

12.6 Other adverse effects

Very toxic to aquatic life.

13-DISPOSAL INFORMATION

13.1 Waste treatment methods

Product
Dispose of as hazardous waste
European waste code will depend upon the use of the material and cannot be specified here.

Packaging
Clean, uncontaminated packaging can be recycled.
Packaging contaminated with the product must be disposed of as hazardous waste.

14-TRANSPORT INFORMATION

14.1 UN number
3077

14.2 UN proper shipping name

ADR/RID: Environmentally hazardous substance, solid, n.o.s. (TRIZINC BIS
ORTHOPHOSPHATE)
ADNR: Environmentally hazardous substance, solid, n.o.s. (TRIZINC BIS
ORTHOPHOSPHATE)
IMDG: Environmentally hazardous substance, solid, n.o.s. (TRIZINC BIS
ORTHOPHOSPHATE)
IATA Environmentally hazardous substance, solid, n.o.s. (TRIZINC BIS
ORTHOPHOSPHATE)

14.3 Transport hazard class(s)

ADR/RID: 9 ADNR: 9 IMDG: 9 + MP IATA: 9

14.4 Packing group

ADR/RID: 111 ADNR: 111 IMDG 111 IATA 111

14.5 Environmental hazards

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ADR/RID: yes ADNR: yes IMDG: Marine pollutant, Yes IATA: yes

14.6 Special precautions for user

None identified

15-REGULATIONS

This Safety Data Sheet has been prepared in accordance with the requirements of regulation
(EC) No 1907/2006 as amended by regulation (EU) No 453/2010.

The Workplace exposure Limit given in section 8 has been taken from the UK HSE
document:
EH40/2005 Workplace exposure limits as amended.

Relevant regulations:
Regulation (EC) 1272/2008 (EU ‘CLP’ regulation)
Regulation (EC) 790/2009 First Adaptation to Technical Progress (ATP) for CLP regulation
EU Directive 67/548/EEC (‘Dangerous Substances Directive’)
Regulation (EC) No 1907/2006 (‘REACH’)
Regulation (EU) No 453/2010.

15.1 Safety, health and environmental regulations/legislation specific for the substance
or mixture
None identified

15.2 Chemical safety assessment

Chemical Safety Assessment has been undertaken as part of the REACH registration
submission document for this material but this information has not yet been made public.

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16-OTHER INFORMATION

Employers should use this information only as a supplement to other information gathered by
them, and should make independent judgement of suitability of this information to ensure
proper use and protect the health and safety of employees. This information is furnished
without warranty, and any use of the product not in conformance with this Material Safety
Data Sheet, or in combination with any other product or process, is the responsibility of the
user.

ANNEX

The following exposure scenarios have been considered in the compilation of this SDS:

1) Use as a component in the production of coatings, paints, enamels or varnishes.

The substance may be converted to these products directly or it may be converted into an
intermediate that is further processed to produce the product.
These are industrial processes in which the following activities may take place:
• Removal of the substance from the packaging / supply container
• Transfer to a storage vessel and storage
• Transfer to a mixing vessel and mixing with other components (solid or liquid)
• Pellitising, sintering or pressing followed by direct use or transfer to a container for
transport or supply (packaging).
Subsequent operations may include:
• High temperature processing including pressing, sintering, grinding, fritting or casting
• Low temperature processing including pressing and pellitising
• Transfer to a container for transport or supply (packaging).

2) Use of a dispersion, paste or paint containing this substance.

This is an industrial or professional process in which the following activities may take place:
• Reception/unpacking/opening of the container of material
• Application by spraying, coating or embedding.
• Disposal of waste / residual material

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