Chapter 12: Carbon & Its Compounds (A) Carbon
Chapter 12: Carbon & Its Compounds (A) Carbon
Chapter 12: Carbon & Its Compounds (A) Carbon
(A) Carbon
1. Mention the properties of carbon.
Carbon is a non-metal
It is the first member of group 14 of periodic table.
Its valency is four.
4. Will carbon as an atom interact with other atoms to form ionic or covalent bonds?
Carbon as an atom interacts with other atoms to from covalent bonds.
5. What is allotropy?
Allotropy is the property of elements which have same chemical properties but different
physical properties.
6. Name the allotropic forms of carbon
Crystalline carbon – Diamond & graphite
Amorphous carbon
7. Why is diamond hard whereas graphite soft even through both are crystalline forms
of carbon?
The reason for difference is because of arrangement of carbon atoms.
8. Mention the uses of graphite.
a) Graphite is used as lead in pencils.
b) It is used as a pigment.
c) It is used as a moulding material in glass manufacture.
d) It is used as electrode in batteries, electroplating and electroforming.
e) It is used in brushes of electric motors
f) It is used as a neutron moderator in nuclear reactors.
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11. What are the two properties of carbon which lead to the formation of a large
number of carbon compounds?
Catenation and isomerism
15. Write the electronic configuration of carbon atom when it is in ground state.
The electronic configuration of carbon atom in ground state is 1s2, 2s2, 2p2
22. Why do first three alkanes methane, ethane and propane have no isomers?
Methane (CH 4), ethane (C 2H 6 ) and propane (C 3 H 8 ) have no scope for branching of C –
C chain hence they do not exhibit isomerism.
n-butane Iso-butane
27. Organic compounds are formed under some vital force. True or false. Explain.
Organic compounds are not formed under vital force is false because earlier they thought
that organic compounds could not be prepared in the laboratory. In 1828 Friedrich Wohler
prepared urea, a typical product of animal metabolism by heating an aqueous solution of
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29. Why are Calcium Carbide (CaC 2 ), Carbon monoxide (CO), Carbon dioxide (CO 2),
Hydrogen cyanide (HCN) and calcium carbonate (CaCO 3) classified as inorganic
compounds through they contain carbon?
These compounds contain only one or two carbon atoms per formula unit and contain no
carbon-carbon (C-C) bonds or carbon-hydrogen bonds. Hence they are classified as
inorganic compounds.
33. Name three typical organic compounds commonly present in our food.
Starch, sugar, citric acid, cooking oil etc.
(B) Hydrocarbons
35. What are hydrocarbons?
Hydrocarbons are the simplest binary organic compounds containing carbon and
hydrogen.
36. Why are hydrocarbons currently the main source of world’s electrical energy and
heat source?
The energy produced when burnt often this energy is used directly as heat as in home
heaters which use either oil or natural gas.
47. Write the molecular formulae of the third and fifth member of homologous series of
carbon compounds represented by the general formula C n H 2n+2
Third member n = 3, C 3 H 2x3+2 = C 3 H 8
Fifth member n = 5, C 5 H 2x5+2 = C 5 H 12
CH 4 + 2O 2 CO 2 + H 2 O
c) Methane gas burns with yellow flame or methane undergoes incomplete combustion.
It forms carbon monoxide and water.
2CH 4 + 3O 2 2CO + 4H 2 O
d) A mixture of methane and chlorine is exposed to ultraviolet light (sunlight).
Organic product chloromethane is formed
UV
CH 4 + Cl 2 CH 3 Cl + HCl
56. Write about the combustibility of methane.
a) Complete combustion:
During complete combustion methane burns in air or oxygen with a non-luminous flame,
forming carbon dioxide and water.
CH 4 + 2O 2 CO 2 + H 2 O
b) Incomplete combustion:
During incomplete combustion, methane gas burns with yellow flame, carbon particles are
seen.
Methane + Oxygen Carbon monoxide + Water
2CH 4 + 3O 2 2CO + 4H 2 O
57. Complete and balance the following equation:
a) CH 4 + O 2
UV
b) CH4 + Cl 2
60. Name the product obtained when methane and chlorine is exposed to ultraviolet
light (sunlight).
When a mixture of methane and chlorine is exposed to ultraviolet light, chloromethane is
formed.
UV
CH 4 + Cl 2 CH 3 Cl + HCl
68. Give the names and structural formulae of next two higher homologues of methane.
Alkynes are unsaturated hydrocarbons that contain one triple bond between carbon
atoms.
The name of these hydrocarbons end with ‘yne’.
Their general formula is C n H 2n-2 .
Ex: Ethyne, Propyne etc.
76. Give the general name of the class of compounds having the general formula
C n H 2n-2 . Write the first member of this homologous series.
Alkynes. The first member is Ethyne.
78. Select the hydrocarbons which are members of the same homologous series.
C 5 H 10 , C 3 H 8 , C 6 H 10 , C 4 H 10 , C 7 H 12 , C 8 H 16
Alkanes: C 3H 8 and C 4H 10, Alkenes: C 5 H 10 and C 8 H 16 , Alkynes: C6 H 10 and C 7H 12
79. Classify the following into saturated and unsaturated hydrocarbons – Benzene,
cyclopropane, alkene and alkane, methane, ethene, Propyne, butene
Saturated: Alkane, cyclopropane, methane
Unsaturated: Benzene, alkene, ethene, Propyne, butene
80. Classify the following compounds containing double bond and triple bond –
Ethyne, benzene, Butyne, pentene
Double bond: Benzene, pentene
Triple bond: Ethyne, Butyne
81. Give reason: Alkanes undergo only substitution reactions but alkenes and alkynes
undergo both substitution and addition reactions.
Alkenes and alkynes have double and triple bonds, which on breaking can add hydrogen
atoms to satisfy the valency.
84. Give reason: Alkenes and Cycloalkanes have same general formula.
Alkenes and Cycloalkanes have same general formula because they have double bond
between carbon atoms.
86. Even though alkenes and Cycloalkanes have the same general formula, they are
different. How?
Alkenes are unsaturated where as Cycloalkanes are saturated.
89. Cyclohexane does not belong to aromatic class even though it has a ring structure.
How do you justify this?
Cyclohexane is a saturated hydrocarbon in which the carbon atoms are joined by single
covalent bonds to form a ring where as in aromatic hydrocarbons have alternate single
and double bonds. Hence Cyclohexane is does not belong to aromatic class.
or or
91. Write the structure of Toluene.
or
OR
93. Mention the uses of Benzene
a) Benzene is used as solvent for oils, fats, resins, rubber, sulphur, iodine etc.
b) It is used in the manufacture of dyes, drugs, perfumes, explosives etc.
c) It in used in preparation of gammexane, an insecticide.
d) It is used for dry cleaning.
94. Mention the uses of Toluene
a) Toluene is used as a solvent for oils, fats, paints, lacquers, resins etc.
b) It is used in the manufacture of TriNitroToluene (TNT) an explosive.
95. Mention the used of Naphthalene
a) Naphthalene is used as an insecticide in the form of moth balls.
b) It is used in the synthesis of dyes.
(C) Functional Groups
97. On the basics of functional groups present, how are organic compounds
classified?
Alkyl / Aryl radical (Less reactive part) and Functional group ( Active part)
99. Even though NaOH & KOH contains –OH group. It is not included in the group of
organic substances. Why?
NaOH and KOH are strong bases which are ionic compound that contain OH ions.
Alcohols are covalent compounds, even though they have on or more hydroxyl ( -OH )
functional group, they do not behave like bases. The – OH group attached to a carbon
atom is a covalent bond.
105. Write the molecular formula of first five members of carboxylic acid.
Name of carboxylic acid Molecular Formula
1. Methanoic acid HCOOH
2. Ethanoic acid CH 3 COOH
3. Propanoic acid C 2 H 5 COOH
4. Butananoic acidu C 3 H 7 COOH
113. Give one example each of the compounds having the following functional groups:
a) Aldehyde group – Methanal
b) Alcohol group – Methanol
c) Carboxylic acid group - Methanoic acid
Amino acids is a molecule that contains both amino (– NH 2 ) and carboxylic acid (–
COOH) functional groups.
115. Name the simplest and the smallest amino acid found in protein.
Glycine, Its formula is H 2 N – CH 2 – COOH
117. Write the structure of glycerol or Write the structural formula of the compound
having 3 – OH group.
118. Write the structural formula of the compound having one – COOH group.
122. Even though Methyl alcohol (CH3 OH) and Ethyl alcohol (C 2 H5 OH) contains –OH
group. They are not called hydroxides but alcohols. Why?
OR
NaOH is not called as sodium alcohol. Why?
OR
CH 3 OH is not called Methyl hydroxide but Methyl alcohol. Why?
In Methyl alcohol and Ethyl alcohol, hydroxyl group is just a group of atoms –OH which is
covalently bonded to a carbon atom. In hydroxides –OH is a hydroxyl ion which is formed
by ionic bond. Hence methyl alcohol and ethyl alcohol are not called as hydroxides.
Fats are solids at room temperature and have more shelf life as they are chemically
inactive. Hence it is easy to transport,
134. Give reason: Hydrogenated Oils are often used in frying and pastries.
Hydrogenated oils have a higher melting point. Hence it is used for frying and pastries.
Saponification value helps the manufacturer of soap to prepare soap which does not
contain excess of potassium hydroxide.
1. Methane CH 4
2. Ethane C2H6
3. Propane C3H8
4. Butane C 4 H 10
5. Pentane C 5 H 12
6. Ethene C2H4
7. Propene C3H6
8. Butene C4H8
9. Pentene C 5 H 10
16. Cyclopentane C 5 H 10
17. Cyclohexane C 6 H 12
19. Toluene C6 H5 CH 3
20. Naphthalene C 10 H 8
21 Glycerol C3H8 O3
13. The person who suggested that organic compounds are derived from organisms is
Berzelius.
14. The first organic compound which was synthesized from inorganic compound was urea.
15. The person who synthesized urea from ammonium cyanate was Friedrich Wohler.
16. Friedrich Wohler prepared the organic compound urea.
17. The unique properties of carbon atom are catenation, tetravalency and isomerism.
18. The study of compounds and reactions involving carbon is called Organic chemistry.
19. An example of an organic compound present in our food is starch.
20. Simplest binary organic compounds containing carbon and hydrogen only are called
hydrocarbons.
21. Compounds of carbon with hydrogen alone are called hydrocarbons.
22. IUPAC stands for International Union of Pure and Applied Chemistry.
23. An example of a hydrocarbon in gaseous form is methane/ propane.
24. An example of a hydrocarbon in liquid form is hexane/benzene.
25. An example of a hydrocarbon in solid form is wax/naphthalene/asphalt.
26. An example of a hydrocarbon which is a polymer is polyethylene.
27. Hydrocarbons have a characteristic odour only in vapour state.
28. The main source of the world’s electric energy and heat source is hydrocarbons.
29. The two principal sources of hydrocarbons are petroleum and coal.
30. Aliphatic hydrocarbons are mainly obtained from petroleum.
31. Aromatic hydrocarbons are mainly obtained from coal.
32. Saturated hydrocarbons are referred to as paraffins.
33. The general formula of alkanes is C n H 2n+2
34. Hydrocarbons having the general formula C n H 2n+2 are called alkanes.
35. Alkenes are referred to as olefins.
36. The first member of the alkanes or saturated hydrocarbon is methane.
37. Carbon compounds have usually low melting points and boiling points.
38. Two adjacent homologues differ by 1 carbon atom and 2 hydrogen atoms.
39. The unsaturated hydrocarbons having double bond between carbon atom are alkene.
40. The general formula of alkene is C n H 2n .
41. The hydrocarbon having the general formula C n H 2n is alkene.
42. The first member of the alkene hydrocarbon group is Ethene.
43. The unsaturated hydrocarbons having one triple bond between carbon atoms are
alkynes.
44. The general formula of alkynes is C n H2n-2
45. The first member of the alkyne series is Ethyne.
46. In homologous series one member differs from the preceding member by a CH 2 group.
47. The derivatives of a series of hydrocarbons whose simplest member is benzene is
Aromatic hydrocarbons.
48. Benzene ring was proposed by Kekule.
49. The active part of an organic compound is the functional group.
50. The less reactive part of an organic compound is the alkyl/aryl part.
51. Compounds containing – OH group as functional group are called alcohols.
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