TC) O.

U
9f. CH NH2 (0.12 mole, pK, =3.3) is added to 0.08 moles of HCl and the solution is diluted to
one litre, resulting pH of solution is

(a) 10.7 (b) 3.6 (c) 10.4 (d) 11.3

 A 11 solution contains 0.2 M NH OH and 0.2 M NH,CI. If 1.0 ml. of 0.001 M HCl
HCI isis ar
what will be the [OH J of the resulting solution (K, =2x 10) added tot
(a) 2 10 (b) 5x 10-10 (c) 2x 10s (d) None of these
95. 0.1 M formic acid solution is titrated against 0.1 M NaOH solution. What would be
difference in pH between 1/5 and 4/5 stages of neutralization of acid1?
uld be the
(a) 2 log 3/4 (b) 2 log 1/5 (c) log 1/3 (d) 2 log 4
96. In tne neutralization process of H PO and NaOH, the number of buffers formed will be
(a) 3 (b) 1 (c) 2 (d) 4
97. A buffer solution is made up of acetic acid [pK, = 5] having conc. = 1.5 M and sodium acetate

having conc. - 0.15 M. What is the number of OH ions present in 1 litre solution?
(a) 100 N (b) 10 NA (c) 10 NA (d) 10 NA
98. The pH of a solution of 0.10 M CH,COOH increases when which of the following substancesis
added?

(a) NaHSO (b) HClO4 (c) KNO3 (d) KCOD

99. H ion concentration of water does not change by adding:
(a) CHCOONa (b) NaN03 (c) NaCN (d) Na,C0,
100. pK of NH is 9.26. Hence, effective range for NH,OH - NHCI buffer is about pH

(a) 8.26 to 10.26 (b) 4.74 to 5.74 (c) 3.74 to 5.74 (d) 8.26 to 9.26
101. 1.0L solution is prepared by mixing 61 g benzoic acid (pka =4.2) with 72 g of sodium
benzoate and then 300 ml 1.0 M HBr solution was added. The pH of final solution1s
(a) 3.6 (b) 3.8 (c) 4.2 (d) 4.8
102. The pH of a solution containing 0.4 M HCO, and 0.2 M CO is
[K (H,CO,) = 4 < 10; K, (HCO) = 4 x 10 ]

(a) 10.4 (b) 10.1 (c) 6.1 (d) 10.7

193. The pH of the resultant solution of 20 ml. of0.1 MH,PO, and 20 ml. of 0.1 MNa,PO, B

(a) pk + log 2 (d) pk +p

(b) pK (C) pka, (d) 2
 When100 100 mL of 0.1 M NaCN solution is titrated with 0.1 M HCI solution the variation of pH
with rolume of HCl added will be
of solution

pH pH

(a) (b)
Volume of HCI added Volume of HCI added

pH pH

(d)

Volume of HCI added Volume of HCI added

best indicator for the detection of end point in titration of a weak acid and a strong base
106.The
is
(a) Methyl orange (3.1 to 4.4) (b) Methyl red (4.2 to 6.3)
(d) Phenolphthalein (8.2 to 10)
Bromothymol blue (6 to 7.6)
titration of 20 mlL of 0.02 M CH COOH with
Select the best indicator from the given table for
0.02 M NaOH. Given pk, (CH COOH) 4.74 =

Indicator pH range

Bromothymol blue 6.0-7.6

(D
9.3-10.5
(ID Thymolphthalein
11.4-13
(IID Malachite green
7.4-9.0
(V M-Cresol purple
(d) V
Sa) 1 (b) II
(c) III
10.thymol
Bromo blue is an indicator with a K, value of 6
x 1 0 . What % of this indicator is in its

basic form at a pH of 5? (d) 60

a) 40 (b) 85.7
(c) 14.3
109.An acid-base indicator has Kyin -3.0 10. The acid form of the indicator is red and the
basic form is blue. The change in [H"] required to change the indicator from 75% red to 75%
blue is :
(a) 8x 10 M (b) 9 10 M (c) 1 10 M (d) 3x10 M
 114. When equal volumes of the following solutions are mixed, the precipitation of AgCl1
(Ksp=1.8x10-10) will occur with
(a) 10 M (Ag) and 104 M (CIa) (b) 10-5M (Ag*) and 105 M(CI")
(c) 10 M (Ag*) and 10 M (CI) (d) 10-10 M (Ag*) and 10-l0 M (CI")
115. Choose the correct set of
True/False for following statements:
() Silver chloride is more soluble in very concentrated sodium
chloride solution than in pure
water.
(ii) The pH of a buffer solution does
base.
not change on addition of small amount of an acid ora

(iii) Addition of NH4Cl does not affect the

pH of a solution of NHOH
(iv) Degree of hydrolysis of ammonium acetate
does not depend upon the concentration of
ammonium acetate solution.
(vA mixture of acetic acid and sodium acetate
(a) TTFTT can act as buffer solution.
(b) FTTTF (c) TFTFT
116. A 1 litre solution containing NH Cl and NH OH has (d) FFTTT
mol/litre. Which of the following hydroxide ion concentration of 10
to 1 litre solution of hydroxides could be precipitated when the solution is addeu
0.1 M metal ions?
D Ba(OH)2 (Ksp =5x 10-3)
(1) Ni(OH), (K5, =1.6 10"l6) x
CI) Mn(OH)2 (K5o =2x
10-1 (TV) Fe(OH), (K,, =8 10-l6) x
(a) I, II, IV (b) IV
(c)II and IV (d) II, III, IV
 dree gWen

(a) pk, and pk, + pk a, (b)KC and pKa 2+pK,

(C) pk and P t2 pKa, (d) pkand pK,
113. In which of rthe following is the
solution of AgCl unsaturated?
cases
(a) [Ag"1[CI]< Ksp (b) [Ag*][CI]>
K, (c) [Ag"][CI]=K5» (d) Ag"1[C1 [Ag 1C]sK
1 4. When equal volurnes of the
following solutions are mixed, the precipitation of Agc
(Ksp =1.8 x
10) will occur with
(a) 10M (Ag*) and 10 M (Cl) (b) 10 M (Ag*) and 10 M (CI)
(c) 10 M (Ag*) and 10- M (Cl) (d) 10-
M (Ag*) and 10- M
115. Choose the correct set of
(CI)
True/False for following statements:
) Silver chloride is more soluble in very concentrated sodium
chloride solution than in pure
water. ure
ii) The pH of a buffer solution does not change on addition of small
amount of an acid or a
base.
(ii) Addition of NH CI does not affect the pH of a solution of
NHOH
(iv) Degree of hydrolysis of ammonium acetate does
not depend upon the
ammonium acetate solution. concentration of
(v) A mixture of acetic acid and sodium acetate can act as buffer
(a) TTFTT
solution.
(b) FTTTF (c) TFTFT (d) FFTTT
16. A 1 litre solution containing NH CI and NH OH has hydroxide ion concentration of
10
mol/litre. Which of the following hydroxides could be precipitated when the solution is added
to 1 litre solution of 0.1 M metal ions?
(D Ba(OH)2 (Ks, =5x 10 3) (11) Ni(OH), (Kg, =1.6 x 1070)
(II) Mn(OH), (K5, =2x 10-1s) (IV) Fe(OH)2 (K5, = 8 x 10-lb)
(a) I, II, IV (b) IV (c) II and IV (d) II, I, V
117. 150 mL of 0.0008 M ammonium sulphate is mixed with 50 mL of 0.04 M calcium nitrate. The
ionic produet of CaSo will be: (K, =2.4x 10
for CasO)

(a)<Ksp (b)> Ksp (c)K sp (d) None of these

118. In a saturated solution of AgCI, NaCl is added gradually. The concentration of Ag" is plotted
against the concentration of Cl. The graph appears as

(a) [Agl b) Ag1 (c) Agt (d) Ag1

[C CI [C [CH
. Ks, AgCl is 1x 1070. Its solubility in O.1M KNO, will be:
0f
(a) 10 moles/litre (b) >10 moles/litre (c) < 10 moles/litre (d) None of these
120. 50 ml. of a solution containing 10 mole of Agt is mixed with 50 ml of a 0.1 M HCl solution.
How much Ag" remains in solution? (Ksn of AgCl =1.0x
-10

(a) 2.5x 10 (b) 2.5 x 10-/ (c) 2.5 x 10- (d) 2.5 x 10-10
 (d) None of these
a The solubility of electrolytes MX , MX2 and MX is 1x 10 moles per litre. Hence their
respective solubility products are
(a) 10, 4 x 10,27 x 10-12 (b) 10-,4x 10 ,32 x 1012
(c) 10,8 108,32 x 10-12
x
(d) None of these
125. Asaturated solution of Ca,(PO )2 has [Ca* ]=2x10-5 M and [PO]=1.6 10 M of
x
Ksp
Ca,(PO 4)2 is :

(a) 3.2 x 10-13 (b) 3.2 x 10-34 (c) 2.048 x 10-33 (d) None of these
126. Which of the following is most soluble in water?
Va)Ba (PO4)2 (K, =6x 10-39) (6) ZnS (Kg, =
7 x 10l6)
(c)Fe(OH)3 (K5, =6x 10-) (d)Ag3PO 4) (K5 =1.8 10-18) x

127. Silver ions are added to a solution with Br"]=[CI]=[C0]=[AsO]=0.1M. Which

compound will precipitate with lowest [Ag* ]?
(a) AgBr (Kn 5 x 103) =
(6) AgCl (Ksp =1.8 x 10-10)
(c) Ag2CO (K =8.1x 10 (d) Ag 3AsO, (K5, 1x 10-22) =
146. At 25°C, Ks, for PbBr, is equal to 8 x 10.If the salt is 80% dissociated, what is the solubility
P
of PbBr2 in mol/litre?
1/3 1/3 1/3 10-3 /2
10-4 10-5 104
(a) (b) (c) (d)
1.6x 1.65| 1.6x 1.6 0.8 x0.8 1.6x1.6
147. What is the molar solubility of Mn(OH) 2(Ksp 4.5 x 10") in a buffer solution containing
=

equal amounts of NH4 and NH3 (K, =1.8 x 10-)?

(b) 1.38 x 104 (c) 1.38 x 103 (d) 7.3x 10
a) 3.0 x 104
Find of NH4Cl required to prevent Mg(OH), from precipitating in a litre of solution
148 moles
which contains 0.02 mole of NH3 and 0.001 mole ofMg2
ions.

Given K, (NH3) 10*; Ks, [Mg(OH),]

= =10-11.
(a) 10 4 (b) 2x 10-3 (c) 0.02 (d) 0.1
a f NH
64. The degree of dissociation of water at 25°C
1.9x10% and density is 1.0 g cm The equilibrium
constant for water is:
(a) 1.0x 10-14 (b) 2.0 10-14
x

Mc) 2.0 x10-16 (d) 1.0x 10-3

56 Which one is more acidic in aqueous solution?
(a) NiCl2 (b) FeCl3
(c) AICI13 (d) BeC12
bas rranged in the order ot
 (c) SiO2 +NaOH(aq) (d) ZnO+ NaOH(aq)
The correct acidic strength orderis: (IIT 2001)
(a) HCIO<HCIO2 < HCIO <HCIO4
(b) HCIO4 <HCI03 <HCI02 <HCIO
(c) HCI0< HCIO4 <HCIO3 < HCI0,
(d) HCIO4 <HCI02 <HCI03 <HCIO
64. For a sparingly soluble salt A,B,, the relationship of its

solubility product Ls with its solubility (S) is : (IIT 2001)

(a) Ls =Stg.pP.q (b) Ls =sPri.p'.qP
p+q
(c) Ls =SP pP q (d) Ls =S PA (pq)
65 The coreot ordor nfooidio aten +1h i0 TUT 9009
 (d) 8x10
The specIcs present in solution when CO, is dissolved in

water (IT 2006)

Ja) CO2. HCO3. HCOj.CO;
(b) HCO3.co
(C) Co,HCO
(d) CO2, H2CO3
71. 2.5 mL ofweak monoacidicbase (K}, = 1x 10 at

25°C) is titrated with HCI in water at 25°C. The

concentration ofH* at equivalence point is: (IIT 2008)

(a) 3.7 x10-1 M (b) 3.2 x10 M
(c) 3.2 x10 M (d)2.7x10M
72. Solubility product Ks, of salt of type MX. MX 2 and
M3X at temperature T are 4.0 x10-3, 3.2 x10-l4 and
2.7x10 respectively. Solubilities of these salts in mol
dmat temperature T are in the order: (IIT 2008)
(a) MX > MX2 > M3 X (b) M3X < MX2 > MX
(c) MX2 > M3X> MX (d) MX> M3 > MX2
3. The dissociation constant of a substituted benzoic acid at
25°C is 1.0 x10*. The pH of a 0.01M solution of its
sodium salt is: (IIT 2009
(a) 10 (b) 8
(c) 12 (d) 6
A . How many litres of water must be added to I litre of an
aqueous solution of HCI with a pH of I to create an
aqueous solution with pH of2? JEE (Main) 2013]
(a) 2.0 L (b) 9.0 L
(c) 0.1 L (d) 0.9 L
75. The Ksp of Ag 2CrO4 is 1.1x107 at 298 K. The
solubility (in mol/L) of Ag2CrO4 in a 0.1 MAgNOD3
solutionis: JEE (Advanced) 1 20131
(a) 1.1x10-1 (b)1.Ix10-10
(c) 1.1x10-12 (d) 1.1x109
6.The initial rate of hydrolysis of methyl acetate (1M) by a
weak acid (HA, IM) is 1/100"" of that of
(HX, IM), at 25°C. The Ka of H A is:
a
strong acid

JEE (Advanced) II 2013]

(a) 1x10 (b) 1x10
(c) 1x10 (d) Ix10-3
 6. Calculate the [OH] of [NH2 C2H4NH3] and
[H3N-C2H4
(aq.); if
NH3]4* in 0.15 M ethylene diamine

NH2C2H4 NH2 +H20 NH2C2 H4 NH +OH;

Ki =8.5 x10
NH2C2H4NH+H20=[NH3C2H4NHNH312*
1
+OH;sK2 =2.7 x10 8
 Calculate | H Jand [C
HCI,CO)
0.01 M HCI and 001 M
in solution that is a
in
(HCI,COOH is 5 x10-2 CHCICOOH. K, for
A solution contains 0.09 M
CHCI,COOH and 0IM
CHCOOH. The pH of this
solution is
1. If K, for acetic
acid is 10 .calculate K, for
CHCI,COOH.
5. What is [H Jfor a solution in which
0) pH =3
(i) pH 4.75?=

6. The pH of 0.05 M aqueous solution of

12.0. Calculate K. diethyl amine is

(Roorkee 1993)
27. The Kw for 2H20 H30" +OH changes from
1014 at 25°C to 9.62 x10 at 60°C. What is of
water at 60°C? What pH
happens to its neutrality?
28. lonic product of water
(Kw)=1x107 at 25° C. What
are dissociation constant of water
and autoprotonation
constant of water?
29. Will the pH of water be same at 4° Cand 25°
C? Explain.
IIT 2003|
The pH of pure water at 25°C and 35°C are 7 and 6
respectively. Calculate the heat of formation of water
from H and OH.
1. A solution of HCl has a pH=5.If one mL of it is diluted
to 1 litre, what will be pH of resulting solution?
32. 2.0
g of diborane (B,H6) reacts with water to produce
10
100mL solution. If Ka for H;BO is 7.3 x 10
calculate pH of solution.
T00 mL of HCI gas at 25°C and 740 mm pressure were

GSsolved in one litre of water. Caleulate the pti of

solution. Given, V.P. of H,O at 25°C is 23.7 mm

n a the concentrations of " , HCO3 and CO In a

carbonic acid if the pBl of solution s

.0 M solution of
4.18. K= 4.45x10,K2 =4.69 x 10
5