D Block Elements 04-06-2020

BASARA GNANASARASWATHI CAMPUS
Sec: SC-60 D-Block elements Date: 04–06-2020

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SINGLE ANSWER TYPE
1. Which of the following has highest ionic radii?
A) Cr3 B) Mn3 C) Fe3 D) Co3
2. Which of the following element has maximum density?

A) Hg B) Au C) Os D) Pb
3. The highest oxidation state achieved by a transition metal is given by
A) ns electrons B) (n – 1)d electrons
C) (n + 1)d electrons D) ns + (n – 1)d electrons
4. Which one of the following characteristics of transition metals is associated with their
catalytic activity?
A) Paramagnetic behaviour B) colour of hydrated ions
C) Variable oxidation states D) high enthalpy of atomisation
5. In the dichromate dianion
A) 4 Cr  O bonds are equivalent B) 6 Cr  O bonds are equivalent
C) All Cr  O bonds are equivalent D) All Cr  O bonds are non – equivalent
6. What is the general electronic configuration for 2nd row transition series
A) [Ne]3d110 ,4s 2 B) [Ar]3d110 , 4s12 C) [Kr]4d110 , 5s12 D) [Xe]5d110 , 5s12
7. Which ion has maximum magnetic moment

A) V 3 B) Mn3 C) Fe3 D) Cu2
8. Which of the following statement is not true about Mohr's salt?
A) It decolourises KMnO4
B) It is a primary standard
C) It is a double salt
D) Oxidation state of iron is +3 in this salt
9. In the first transition series, the highest B.P. and M.P. is of

A) Cr B) V C) Ni D) Fe
10. The placement of Zn, Cd and Hg along with 'd' block elements is not proper because
A) Their 'd ' orbitals are completely filled
B) Their 'd ' orbitals are empty
C) They do not form complex compounds
D) They do not form coloured compounds
11. Which of the following pair of ions may exhibit same colour

A) Cr3+ and Fe2+ B) Ti3+ and V2+ C) Fe3+ and Mn2+ D) Cu and Ni2+
12. When an acidified solution of ferrous ammonium sulphate it treated with potassium
permanganate solution, the ion which is oxidised is

A) MnO4 B) NH4 C) Fe D) SO24
13. CrO42- (yellow) changes to Cr2O72- (orange) in pH  x and vice-versa in pH  y .
Hence, x and y are:
A) 6,8 B) 6,5 C) 8,6 D) 7,7
14. CrO3 dissolves in aqueous NaOH to give:

A) Cr2O72 - B) CrO4 2 C) Cr(OH)3 D) Cr(OH)2
 
15. The product of I with MnO4 in alkaline medium is:
A) I2 B) IO C) IO3  D) IO4 
16. On heating KMnO4, one among the following is not formed:
A) K2MnO4 B) O2 C) MnO2 D) MnO
17. Which represents correct comparison of the stability of oxometallic anions?
2 3
A) MnO 4  Mn 2  B) Cr  Cr C) CrO24  Cr 3  D) All of these
18. Potassium dichromate in alkaline solution, with 30% H2O2 produces :
A) K3CrO8 B) CrO(O2)2 C) CrO3 D) K2CrO4
19. KMnO4 on treatment with conc. H2SO4 forms a compound (X) which decomposes explosively
on heating forming (Y). The (X) and (Y) are respectively :
A) Mn2O7 , MnO2 B) Mn2O7 , Mn2O3
C) MnSO4 , Mn2O3 D) Mn2O3 , MnO2
20. Which of the following is true for the species having 3d4 configuration?
A) Cr2+ is reducing in nature B) Mn3+ is oxidising in nature.
C) Both (A) and (B) D) Need electrode potential data
21. One of the products formed due to the reaction between KMnO4 and HCl is
A) Red liquid, CrO2Cl2 B) black powder, MnO2
C) Greenish yellow gas, Cl2 D) Colourless liquid, HClO4
MULTIPLE CORRECT OPTION TYPE
1
22. Transition elements with 4s configuration are:
A) Cr B) Zn C) Ni D) Cu
23. Which of the following statements is/are not true in regard to transition elements?
A) They readily form complex compounds

B) They show variable valency
C) All their ions are colourless
D) Their ions contain partially filled d -electron levels
24. Which of the following statements are correct?
A) An acidified solution of K 2Cr2O7 liberates iodine from iodides
B) In acidic solution dichromate ions are converted to chromate ions
C) Ammonium dichromate on heating undergoes exothermic decomposition to give
Cr2O3
D) Potassium dichromate is used as a titrant for Fe2 ions
25. Which of the following oxides are not acidic in nature
A) Mn2O3 B) Mn3O4 C) MnO2 D) Mn2O7
26. When CO2 is passed into aqueous:
A) Na 2CrO4 solution, its yellow colour changes to orange
B) K2MnO4 solution, its disproportionates to KMnO4 and MnO2
C) Na 2Cr2O7 solution, its orange colour changes to green
D) KMnO4 solution, its pink colour changes to green
27. I
Pyrolusite is MnO2 used to prepare KMnO4 . Steps are, MnO2   MnO24 
II
MnO4 .
Steps I and II are respectively:
A) fuse with KOH/air and electrolytic oxidation
B) fuse with KOH KNO3 and electrolytic oxidation
C) fuse with conc. HNO3 air and electrolytic oxidation
D) dissolve in H2O and oxidation
28. Potassium manganate  K2MnO4  is formed when:
A) cuprous oxide reacts with alkaline KMnO4 solution
B) manganese dioxide is fused with K2CO3 in presence of KNO3
C) formaldehyde reacts with potassium permanganate in presence of concentrated
potassium hydroxide solution
D) potassium permanganate is heated with potassium hydroxide
29. Select the correct statement(s) with respect to oxides and oxoanions of transition
metals.
A) Among oxides of chromium, CrO is basic, Cr2O3 is amphoteric and CrO3 is
acidic.
B) No higher oxides of iron above Fe2O3 are found.
C)Ti, V, Cr and Mn form oxides MO and their correct increasing order of
acidic character is MnO < CrO < VO < TiO
D) Vanadium (v) oxide does not react with acids but reacts with alkali only.
30. Potassium manganate (K2MnO4) is formed when :
A) Potassium permanganate reacts with formaldehyde in acidic medium.
B) Manganese dioxide is fused with potassium hydroxide in air.
C) Manganese hydroxide reacts with K2O2 in alkaline medium.
D) Potassium permanganate is heated at 750K.
A) Interstitial compounds have high melting points, higher than those of pure metals.
B) Permanganate titrations in presence of hydrochloric acid are unsatisfactory.
C) KMnO4 does not act as an oxidising agent in strong alkaline medium.
D) KMnO4 on heating in a current of H2 gives MnO.
A) Acidic dichromate solutions on treatment with H2O2 gives deep blue CrO  O2 2 in presence
of ether layer
B) A deep red liquid, CrO2Cl2 is formed by the reaction of chromium(III) oxide with HCl in
presence of conc. H2SO4 .
C)  NH4 2 Cr2O7 on heating yields green chromium(III) oxide and nitrogen gas.
D) K 2Cr2O7 on heating with charcoal produces K2CO3.
A) Mercurous ion exists as Hg 
B) Mercurous ion is diamagnetic and exists as dimer Hg 22
C) Mercurous ion is colourless
D) There is a covalent bond between two Hg  ions in Hg 22
KEY
1. A 2. C 3. D 4. C 5. B 6. C 7. C
8. D 9. A 10. A 11. A 12. C 13. A 14. B
15. C 16. C 17. D 18. A 19. A 20. C 21. C
22. A 23. CD 24. ACD 25. ABC 26. AB 27. AB 28. ABCD
29. ABD 30. BCD 31. ABD 32. ACD 33. BCD

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BASARA GNANASARASWATHI CAMPUS

Sec: SC-60 D-Block elements Date: 04–06-2020

2. Which of the following element has maximum density?

A) [Ne]3d110 ,4s 2 B) [Ar]3d110 , 4s12 C) [Kr]4d110 , 5s12 D) [Xe]5d110 , 5s12

7. Which ion has maximum magnetic moment

9. In the first transition series, the highest B.P. and M.P. is of

14. CrO3 dissolves in aqueous NaOH to give:

A) They readily form complex compounds

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