Chemicals Handling: OGDCL Oil & Gas Field
Chemicals Handling: OGDCL Oil & Gas Field
Chemicals Handling: OGDCL Oil & Gas Field
Chemicals handling
Prepared By
Reviewed By
Approved By:
Date:
Issue Status:
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TABLE OF CONTENTS
1.0 PURPOSE......................................................................................................................
2.0 SCOPE...........................................................................................................................
3.0 SPECIFIC ABBREVIATIONS / DEFINITIONS..............................................................
4.0 AFFECTS.......................................................................................................................
ROLES AND RESPONSIBILITIES................................................................................
5.1 OGDCL OGDCL/Utilities Construction Manager.................................................
5.2 CONTRACTOR Construction Manager................................................................
5.3 CONTRACTOR HSSE Manager.............................................................................
5.4 CONTRACTOR Supervisors and Vendors...........................................................
6.0 HAZARDOUS CHEMICALS REQUIRING CONTROL..................................................
6.1 General....................................................................................................................
6.2 Hydrocarbons.........................................................................................................
6.3 Flammable liquefied or pressurized gases
6.4 Corrosives...............................................................................................................
6.5 Chemical asphyxiants............................................................................................
6.6 Irritant gases and vapours....................................................................................
6.7 Systemic toxic chemicals......................................................................................
6.8 Carcinogens and suspect carcinogens...............................................................
6.9 Infectious substances............................................................................................
6.10 Asbestos.................................................................................................................
6.11 Tributyltin (TBT)......................................................................................................
7.0 MATERIAL SAFETY DATA SHEETS (MSDS).............................................................
7.1 Inventory of hazardous materials.........................................................................
7.2 MSDS Master File/Listing......................................................................................
7.3 Material Safety Data Sheets (MSDSs) content....................................................
9.0 PACKAGING AND LABELLING...................................................................................
9.1 General....................................................................................................................
9.2 Warning signs
9.3 Packaging for transport to/from Worksite...........................................................
10.0 STORAGE AREAS........................................................................................................
10.1 General....................................................................................................................
10.2 Segregation of incompatible materials
10.3 Separation distances.............................................................................................
11.0 USE.................................................................................................................................
11.1 Transport.................................................................................................................
11.2 Handling and use....................................................................................................
11.3 Personal protective equipment (PPE)..................................................................
12.0 SPILLS AND WASTE DISPOSAL.................................................................................
12.1 Spills........................................................................................................................
12.2 Disposal of hazardous chemicals........................................................................
13.0 INFORMATION AND TRAINING...................................................................................
14.0 WORKSITE INSPECTIONS...........................................................................................
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1.0 PURPOSE
The purpose of this procedure is to ensure the safe handling, use and disposal of all
chemicals
It is CONTRACTOR responsibility to ensure that all chemicals produced, imported, or used.
The components of this Hazard Communication Program include:
2.0 SCOPE
This document addressed the HSE requirements for the storage and use of all chemicals
during the operation on OGDCL site. These include:
Paint, thinners;
Refractory material, concrete grouts, sealants and curing materials, fireproofing material,
etc;
Maintain a log of all chemicals (storage locations, quantities, etc) at the Jobsite; and
Monitoring and close out any control actions, training, and workplace monitoring and worker
health surveillance identified in the risk assessments.
5.1 General
The categories in this section outline the general characteristics of the chemicals that may
be used on the OGDCL gas field. CONTRACTOR shall obtain and review the MSDSs of
all chemicals.
5.2 Hydrocarbons
These substances exist in both liquid and gaseous form. They are in the work place in the
forms of fuels, lubricants, and fuel gases. They are also found in many other chemicals
such as solvents, thinners and paints. There are classified are:
Flammable: lighter forms of hydrocarbons have flash points below 37.8 degrees Celsius;
and
Combustible: Flash points above 37.8 degrees Celsius and below 61 degrees Celsius.
Inhalation of hydrocarbon vapours may cause headaches, dizziness, or in extreme cases,
suffocation. Skin and/or eye contact with the liquid can cause irritation. Chronic inhalation
studies with light hydrocarbon components have shown kidney damage and kidney cancer
in laboratory animals.
5.9 Asbestos
Asbestos is known carcinogen and has been linked to lung cancer.
Chemical identification
The first section helps identify the chemical by name, trade names, and the chemical
manufacturer
Hazardous ingredients
This section lists what is in the chemical mixture that can be harmful. It also lists the
concentration of the chemical ingredient and the exposure limit to which one can safely be
exposed.
Physical data
This section describes the chemical’s appearance, colour, and other physical
characteristics such as boiling point, volatility, and vapour pressure.
Reactivity data
This section describes if the chemical reacts with other chemicals, water, or certain
conditions such as temperature. Incompatibility information lists the materials, such as
water, that cause the chemical to burn, explode, or release dangerous gases. Instability
describes environmental conditions, such as heat, that cause a dangerous reaction.
Special protection
This is a listing of any personal protective equipment needed to work safely with the
chemical. If protective equipment is needed, this section may list the specific types that are
recommended.
Special precautions
This section lists other special precautions to follow. This section may also list other health
and safety information not included in any other section.
6.1 General
Each container of chemicals at the Worksite shall be labelled, tagged, or marked with the
identity of hazardous chemical contained therein, and shall show hazard warnings
appropriate for employee protection. The hazard warning label shall be as described in
section 9.2 of this document, which uses words, pictures and symbols in order to convey
the hazard of the chemical(s) in the container.
Labels shall be legible, in English (plus other languages, as required), and prominently
displayed.
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The word, term, or phrase that is used to identify the hazardous chemical(s) on the label
shall also be used on the associated MSDS.
Signs, placards, process sheets, batch tickets, operating procedures, or other such written
materials may be used in lieu of affixing labels to individual stationary process containers.
However, the alternative method shall identify the applicable containers and shall convey
the required hazardous chemicals identification and hazard warning. The written materials
should be readily accessible to the employees through their employers.
Each of the three coloured areas in the NFPA fire diamond has a box in which the degree
of hazard can be written. The degree of hazard is given by these numbers:
Number Degree of Hazard
4 Extreme
3 Serious
2 Moderate
1 Slight
0 Minimal
Health (blue)
4 On very short exposure could cause death or major residual
Extreme
injury even though prompt medical treatment is given.
A known or suspected human carcinogen, mutagen or
Highly toxic material
teratogen.
3 Serious May cause serious temporary or residual injury on short term
exposure even though prompt medical attention is given.
Toxic material A known or suspected small animal carcinogen, mutagen or
teratogen.
2 Moderate
Intense or continued exposure could cause temporary
incapacitation or possible residual injury unless prompt medical
Moderately toxic treatment is given
material
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1 Slight May cause irritation but only minor residual injury even without
treatment.
Slightly toxic Recognized innocuous material when used with responsible
material care
0 Minimal No chemical is without some degree of toxicity.
Flammability (red)
4 Extreme
Flash point below 73 F (22.8 C)
Extremely
flammable
3 Serious Vaporizes readily and can be ignited under almost all ambient
conditions.
Flammable May form explosive mixtures with or burn rapidly in air.
May burn rapidly due to self-contained oxygen.
May ignite spontaneously in air
Flash point at or 22.8 C but less than 37.8 C
2 Moderate Must be moderately heated or exposed to relatively high temperatures
for ignition to occur.
Combustible Solids which readily give off flammable vapours.
Flash point at or above 37.8 C but less than 93.4 C
1 Slight Must be preheated for ignition to occur.
Will burn in air when exposed at 815.5 C for 5 minutes.
Slightly
Flash point at or above 93.4 C
combustible
0 Minimal Will not burn
Will not exhibit a flash point
Will not burn in air when exposed at 815.5 C for 5 minutes.
Reactivity (Yellow)
4 Extreme Can explode or decompose violently at normal temperature and
pressure
Can undergo a violent self-accelerating exothermic reaction with
common materials or by itself
May be sensitive to mechanical or local thermal shock at normal
temperature and pressure
3 Serious Can detonate or explode but requires a strong initiating force or confined
heating before initiation
Readily promotes oxidation with combustible materials and may cause
fires
Is sensitive to thermal or mechanical shock at elevated temperatures.
May react explosively with water without requiring heat or confinement
2 Moderate Normally unstable and readily undergoes violent change but does not
detonate.
May undergo chemical change with rapid release of energy at normal
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temperature and pressure.
May react violently with water
Forms potentially explosive mixtures with water
1 Slight Normally stable material which can become unstable at high temperature
and pressure
0 Minimal Normally stable material which is not reactive with water
Special (White)
Water Reactive
Ox
Oxidizing Agent
Radioactive
Poison
Notes:
1. The text on the categories labels and the secondary hazard labels can be written on one
line;
2. On the categories labels and the secondary hazard labels there should be a border with the
same colour as that of the symbol. The border is (5) mm long if the label is (100 mm x
100mm). The labels should be square placed at angle 45 like a diamond; and
3. The categories labels can be used as secondary hazard labels provided that the lower
angle of the category label is to be removed. Category (6) labels only are to be affixed on
the containers and packages containing hazardous materials falling within categories (6.1a)
and (6.1b).
General requirements
Hazardous materials should be packed in a good quality packing and capped and sealed
properly to avoid any spill or leak during loading / unloading and transport. This is
applicable to new and re-used packing materials. No significant amount of any hazardous
material shall be attached outside the packing (e.g. as a sample).
The coating of the packing in direct contact with the hazardous substance shall be resistant
to the chemical or any other effects of the chemical so as to avoid interaction and corrosion
and consequently result in leak or spill or reaction. The packing should not be made of
plastic or a material that may be affected by heat or chemical reaction with the contents of
the substance or cold. The choice of packing material should take consideration of the
nature of the substance packed.
The exterior body of the packing and the interior coating or surface should be resistant to
vibrations. The corks or caps are to be tightly fixed by air vacuum means. It is to be
designed in a way that makes it easy to inspect/ check the packing.
Labels
The type, quality and specification of labels to be affixed to packages shall be:
The labels shall be a good adhesive type that cannot be easily removed and the data
written on the labels cannot be erased in the ordinary shipping conditions;
The handling and danger warning labels affixed on the packages of hazardous materials
shall comply with Section 8.3 of this document. The dimensions of the danger warning
labels should be at least (100 x 100) mm. The symbol is to be placed in the upper part of
the label whereas the text is in the bottom with the category number except the labels in
U.N. Categories 1.4, 1.5 and 1.6;
The text indicating the hazardous nature of the material should be in English. This is
applicable also in relation to the handling labels. The label may contain brief information
about the manufacturer, but this should be in the margin in small font;
Labels shall be
o Affixed on the package properly so as to be clearly seen
o If the label cannot be stuck on the surface of the package it shall be tightly tied to it
o Secondary hazard/ danger labels when used, may be affixed beside the major
danger / hazard labels
o At least two labels showing the right direction (this side up) shall be affixed on
opposite sides of the packing
o other labels may be attached if the labels do not contradict the requirements of this
procedure
o All packages shall be marked with the UN identification number followed by the UN
unique number
7.1 General
All bulk quantities of hazardous materials (including fuel and paint) shall be stored in the
laydown areas of the Worksite,
CONTRACTOR shall only store hazardous chemicals in areas approved by OGDCL:,
which meet the storage requirements of the respective Material Safety Data Sheet.
Chemical storage will be in secure areas (e.g. fence, locked doors, etc).
Liquid and solid hazardous materials storage areas shall have impermeable floors with
secondary containment that is minimum 110% of the largest tank volume.
A spill kit (adsorbent pads, gloves, container for waste, etc) shall be kept in all hazardous
chemical storage areas.
UN 1.1 1.2 2.2 2.3 3.1 4.1 4.2 4.3 5.1 5.2 6.1 8
Category
1.1 C C C C C C C C C C C
1.2 C C B B C B C C B B
2.2 C C A A B A A B A A
2.3 C C C C C C C C C C C
3.1 C B A C B B B C C B A
4.1 C B A C C B B C C B A
4.2 C C B C C B B C C B A
4.3 C B A C C B B C C B B
5.1 C C A C C C C C B B B
5.2 C C B C C C C C B B B
6.1 C B A C C B B B B C A
8 C B A C C A A B B B A
For separating two categories of hazardous materials use the alphabetical letter at the
intersection of the vertical line representing the first category with the horizontal line
representing the other category
A: the distance for separation is to be at least (3) meters away from the other categories
C: they should not be stored in the same room and the distance for separation is to be at
least (10) meters
Hazardous materials should be stored away from fabrication shops and Worksite to the
maximum extent practicable.
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If hazardous materials are stored in industrial installations, the distance of separation
should be at least 3 meters away from the production of non-flammable materials, and it
should be at least 10 meters away from any source of hazard.
8.0 USE
8.1 Transport
Transportation of hazardous substances at the Worksite will be carried out in compliance
with the transportation requirements of the respective Material Safety Data Sheet. In
certain circumstances an escort for the transportation of some chemicals may be
necessary. In all cases the chemical being transported will be clearly identified by signs
attached to the transport vehicle.
CONTRACTOR shall ensure that their suppliers/vendors include the related MSDSs in the
shipping and delivery documentation for all hazardous materials transported to the
Worksite.
9.1 Spills
. CONTRACTOR shall also: ..
Install additional monitoring wells after clean up of the spill to establish the effectiveness of
the clean up work
Immediate Actions
If spilled materials are flammable, eliminate sources of ignition from near the spill area.
If it can be performed safely, stop the source of the spill and contain the spill within as small
an area as possible.
If the spill is small or minor (i.e., less than or equal to 820litres), and is NOT in an
environmentally sensitive area:
The spill will be immediately cleaned-up by Jobsite personnel and properly disposed.
CONTRACTOR will notify the OGDCL HSE Manager as soon as possible of the location
and action taken.
The OGDCL HSSE Manager will notify the Managers and complete an Environmental
Incident Report.
For large spills (i.e., greater than to 820 litres OR spills impact environmentally sensitive
areas (e.g., buffer areas, water courses):
CONTRACTOR shall immediately contact the OGDCL HSE Manager, the OGDCL Manager
and, if injuries are involved, the Worksite Medical Facilities;
The OGDCL HSSE Manager will implement the Emergency Response / Emergency
Evacuation Procedure. The OGDCL Manager (or designee) will secure the area and
establish perimeter control at a safe distance from the spill.
Scene management will be the responsibility of the Construction Manager (or designee)
and supported by the OGDCL HSE Manager until offsite emergency management
personnel assume control (if necessary).
If an immediate threat to human health or the environment DOES NOT EXIST, the OGDCL
HSE Manager will arrange for a safe cleanup of the spill.
Small or minor spills, less than or equal to 820 litres should be cleaned-up immediately by
Worksite personnel and properly disposed.
Large or major spills, greater than to 820 litres, outside of contained areas should be diked
with absorbent clay or soil to prevent liquid from reaching drainages, buffer areas, storm
sewers, or other bodies of water. Spill cleanup wastes must be placed in proper waste
containers and properly labeled.
Diesel fuel and gasoline cleanup wastes will be disposed of as hazardous wastes.
Diesel fuel and gasoline cleanup wastes that contain free-flowing liquid will be drained to
remove as much of the free-flowing product as possible. The free product removed from
the waste must either be recycled or, if not recyclable, disposed of as a hazardous waste.
Small or minor spills, less than to 820 litres, should be cleaned-up immediately by Jobsite
personnel and properly disposed.
Large or major spills, greater than to 820 litres, will be diked with absorbent, clay or soil to
prevent liquid from reaching storm sewers, bodies of water or other protected area.
Cleanup wastes must be placed in proper waste containers and properly labeled.
Hydraulic/lube oil cleanup wastes, where the soil and/or rags are saturated, must be
disposed of as hazardous wastes.
Soil and rags that are not saturated may be disposed of with the non-hazardous solid
waste.
Hydraulic/lube oil cleanup wastes that do contain free-flowing liquid will be drained to
remove as much of the free-flowing product as possible. The free product removed from
the waste must either be recycled or, if not recyclable, disposed of as a hazardous waste.
Refer to MSDS (available from the HSE Manager) for special hazards associated with any
spilled chemicals, especially for reactivity with other materials in the spilled area.
Small or minor spills within contained areas should be neutralized (if appropriate). Free
product that cannot be re-used must be handled and disposed of as hazardous waste, if
product characteristics warrant.
Spills of acids, caustics, or other dangerous chemicals outside of contained areas should be
diked with absorbent, clay or soil to prevent liquid from reaching storm sewers or bodies of
water. Trained offsite contractor personnel should perform the cleanup of large amounts of
free liquid.
Spill cleanup wastes must be placed in hazardous waste containers and transferred to the
Waste Management Area for disposal as a hazardous waste.
Methods and observations that may be used to detect and identify hazardous chemicals
such as odour, visual presence, etc.