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    D - and F-Block - Eklavya (Q)

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    Dhruv Kuchhal
    This document contains 15 multiple choice questions regarding d-block elements and their compounds. It also includes comprehension questions and subjective answer type questions related to identifying compounds and outlining reaction mechanisms. Key topics covered include properties of transition metals and their salts, oxidation states, tests of ions, preparation of compounds, and disproportionation reactions.

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    © All Rights Reserved
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    D - and F-Block - Eklavya (Q)

    Uploaded by

    Dhruv Kuchhal
    52 views10 pages
    This document contains 15 multiple choice questions regarding d-block elements and their compounds. It also includes comprehension questions and subjective answer type questions related to identifying compounds and outlining reaction mechanisms. Key topics covered include properties of transition metals and their salts, oxidation states, tests of ions, preparation of compounds, and disproportionation reactions.

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    d- and f-block_Eklavya(Q)

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    This document contains 15 multiple choice questions regarding d-block elements and their compounds. It also includes comprehension questions and subjective answer type questions related to identifying compounds and outlining reaction mechanisms. Key topics covered include properties of transition metals and their salts, oxidation states, tests of ions, preparation of compounds, and disproportionation reactions.

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
    52 views10 pages

    D - and F-Block - Eklavya (Q)

    Uploaded by

    Dhruv Kuchhal
    This document contains 15 multiple choice questions regarding d-block elements and their compounds. It also includes comprehension questions and subjective answer type questions related to identifying compounds and outlining reaction mechanisms. Key topics covered include properties of transition metals and their salts, oxidation states, tests of ions, preparation of compounds, and disproportionation reactions.

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
    of 10

    CHEMISTRY (D- and F-BLOCK ELEMENTS)

    SINGLE CHOICE QUESTIONS


    Question 1: When excess of sodium thiosulphate is added to dil. AgNO3 solution a soluble
    compound X is formed. However, when dil. Na2S2O3 solution is added to conc. AgNO3 solution,
    a white ppt. turning yellow and finally black ppt. of Y is obtained. Which is the correct pair:
    Options:
    (a) X is Ag2S and Y is Na3[Ag(S2O3)2]
    (b) X is Na3[Ag(S2O3)2] and Y is Ag2S
    (c) X is Ag2S2O3 and Y is Ag2S
    (d) X is Ag2S2O3 and Y is Na3[Ag(S2O3)2]

    compound (𝑈) + conc..H2 SO4


    Question 2: (𝑇) → (𝑉) Red gas
    NaOH+AgNO3 NH3 soln.
    → (𝑊) Red ppt. → (𝑋)
    T is an Orange crystalline compound which when burnt imparts violet color.
    dil. HCl
    (W) Red ppt. → (Y) white ppt.
    NaOH𝛥
    (U) → (Z) gas (gives white fumes with HCl) sublimes on heating
    Identify (T) to (Z).
    Options:
    (a) T = KMnO4, U = HCl, V = Cl2, W = HgI2, X = Hg(NH2)NO3, Y = Hg2Cl2, Z = N2
    (b) T= K2Cr2O7, U= NH4Cl, V= CrO2Cl2, W= Ag2CrO4, X = [Ag (NH3)2]+, Y= AgCl, Z = NH3
    (c) T = K2CrO4, U = KCl, V = CrO2Cl2, W = HgI2, X = Na2CrO4, Y = BaCO3, Z = NH4Cl
    (d) T = K2MnO4, U = NaCl, V = CrO3, W = AgNO2, X = (NH4)2CrO4, Y = CaCO3, Z = SO2

    Question 3: Which of the following is not a consequence of the Lanthanoid contraction?


    Options:
    (a) 5d series elements have a higher IE1 than 3d or 4d series
    (b) Zr and Hf have a comparable size
    (c) Zr and Hf occurs together in the earth crust in their minerals
    (d) High density of the sixth period elements

    Question 4: Copper sulphate is prepared by blowing a current of air through copper scrap and
    dilute H2SO4. Dilute HNO3 is also added:

    Options:

    (a) to oxidise copper to Cu2+ which then form CuSO4 with dilute H2SO4

    (b) to oxidise Fe2+ to iron (III) sulphate, which remains in solution after crystallisation of CuSO4

    (c) to speed up the ionisation of H2SO4 to give SO42– ions

    (d) which combines with H2SO4 to give a very strong oxidising mixture and oxidises Cu to Cu2+

    Question 5: Metal-metal bonding is more frequent in 4d or 5d series than in 3d series due to:

    Options:

    (a) their greater enthalpies of atomisation

    (b) the large size of the orbitals which participates in the metal-metal bond formation

    (c) their ability to involve both ns and (n – 1) d electrons in the bond formation

    (d) the comparable size of 4d and 5d series elements

    Question 6: The maximum and minimum m.p. Of 1st transition and 2nd transition series
    respectively are obtained with:
    Options:
    (a) Cr and Zn
    (b) Cr and Cd
    (c) Cr and Hg
    (d) Mo and Cd
    Question 7: A metal M which is not affected by strong acids like conc. HNO3, conc. H2SO4 and
    conc. Solution of alkalies like NaOH, KOH forms MCl3, which finds use for toning in
    photography? The metal M is:

    Options:

    (a) Ag

    (b) Hg

    (c) Au

    (d) Cu

    Question 8: When aqueous sodium hydroxide is added to an aqueous solution of chromium (III)
    ions, a green blue precipitate is first formed which re-dissolves to give a green solution. This
    green colour is due to:

    Options:

    (a) [Cr(H2O)6]3+

    (b) CrO42–

    (c) [Cr(OH)4]–

    (d) [Cr(OH)3(H2O)3]

    Question 9: Copper is very slowly oxidised on the surface in moist air, giving a green coating of
    verdigris, it is:

    Options:

    (a) Cu2O

    (b) CuCO3
    (c) Cu(CH3COO)2.Cu(OH)2

    (d) CuSO4

    Question 10:

    Which of the following statement is true for the compounds [X], [Y] and [Z]?

    Options:

    (a) In all three compounds, the chromium is in +6 oxidation state

    (b) [Z] is a deep blue-violet coloured compound which decomposes rapidly in aqueous solution
    into Cr+3 and dioxygen

    (c) Saturated solution of [Y] gives bright orange compound, chromic anhydride, with
    concentrated H2SO4

    (d) All of these

    Question 11: CuCN reacts with FeCl3 to give


    Options:
    (a) CuCl2
    (b) Cu(CN)2
    (c) (CN)2
    (d) All of these

    Question 12: Which of the following statements is correct?


    Options:
    (a) In Mohr’s salt, (NH4)2SO4 enables hydrated FeSO4 to be used as a better primary standard
    during titration than green vitriol
    (b) AgOH when added to an aqueous solution of K2Cr2O7 gives precipitate of Ag2Cr2O7
    (c) Oxidising action of bleaching powder is more in hot water than in cold water
    (d) A warm aqueous solution of chlorine is less acidic than in cold aqueous solution

    Question 13:
    Statement-1: Both PbCrO4 and BaCrO4 are yellow precipitates, they can be distinguished by
    KOH.
    Statement-2: PbCrO4 is soluble in KOH, while BaCrO4 is insoluble in KOH.
    Options:
    (a) Statement1 is True, Statement2 is True; Statement2 is a correct explanation for Statement1
    (b) Statement1 is True, Statement2 is Tue; Statement2 is NOT a correct explanation for
    Statement1
    (c) Statement - 1 is True, Statement - 2 is False
    (d) Statement - 1 is False, statement - 2 is True

    Question 14:
    Statement-1: AgCl, Cu2Cl2, Hg2Cl2 and PbCl2 do not respond chromyl chloride test
    satisfactorily.
    Statement-2: They either decompose or get oxidized during warming with K2Cr2O7 and Conc.
    H2SO4.
    Options:
    (a) Statement1 is True, Statement2 is True; Statement2 is a correct explanation for Statement1
    (b) Statement1 is True, Statement2 is Tue; Statement2 is NOT a correct explanation for
    Statement1
    (c) Statement - 1 is True, Statement - 2 is False
    (d) Statement - 1 is False, statement - 2 is True
    Question 15: Match the following

    Options:

    (a) A ⟶ R; B ⟶ P, Q, R, S; C ⟶ P, R; D ⟶ Q

    (b) A ⟶ P; B ⟶ R, S; C ⟶ Q, R; D ⟶ P, S

    (c) A ⟶ Q; B ⟶ P, R, S; C ⟶ P, S; D ⟶ R, S

    (d) A ⟶ S; B ⟶ Q, R; C ⟶ R, S; D ⟶ P, Q

    Question 16: Match the inorganic compounds in column A with the product(s) obtained on
    strong heating given in column B Match the following:

    Column I Column II

    (A) Pb(NO3)2 (p) N2

    (B) NH4NO2 (q) O2

    (C) (NH4)2Cr2O7 (r) NO2

    (D) AgNO3 (s) H2O

    (t) Metal oxide

    Options:
    (a) A-q, r, s; B-p; C-p, s, t; D-t, r.
    (b) A-q, r, t; B-p, q, s; C-p, s; D-s, t.
    (c) A-q, r, t; B-p, s; C-p, s, t; D-q, r.
    (d) A-r, t, s; B-p, q, s; C-p, s, t; D-q, r.
    MULTIPLE CHOICE QUESTIONS
    Question 17: Which statements about corrosive sublimate (HgCl2) are correct?

    Options:

    (a) It sublimes on heating

    (b) It oxidises stannous chloride

    (c) It is highly poisonous

    (d) It is prepared by heating mercury in chlorine

    Question 18: The species that undergoes disproportionation in an alkaline medium are:

    Options:

    (a) Cl2

    (b) MnO42–

    (c) NO2

    (d) ClO4–

    Question 19: Which of the following statements regarding d-block elements are true?

    Options:

    (a) the colour of anhydrous CuSO4 is blue

    (b) “splitting of silver” can be prevented by covering the surface of molten silver with charcoal

    (c) Iodine liberated in a reaction can be estimated by titration against a standard thiosulphate
    solution

    (d) Lanthanum is first element of third transition series.


    COMPREHENSION # 1 (FOR Q. 20 TO Q. 22)
    𝛥 High Temp.
    Light green (Compound ‘A’) → White Residue (B) → C+D+E

    (i) ‘D’ and ‘E’ are two acidic gas.

    (ii) ‘D’ is passed through HgCl2 solution to give yellow ppt.

    (iii) ‘E’ is passed through water first and then H2S is passed, white turbidity is obtained.

    (iv) A is water soluble and addition of HgCl2 in it, yellow ppt is obtained but white ppt does not
    turn into grey on addition of excess solution of ‘A’.

    Question 20: ‘D’ and ‘E’ are respectively.

    Options:

    (a) SO2 and SO3

    (b) SO3 and SO2

    (c) SO2 and CO2

    (d) CO2 and CO

    Question 21: Yellow ppt in the above observation is:


    Options:
    (a) Mercuric oxide
    (b) Basic mercury (II) sulphite
    (c) Basic mercury (II) sulphate
    (d) Mercuric iodide
    Question 22: ‘C’ is soluble in:

    Options:

    (a) dil. HCl

    (b) dil. H2SO4

    (c) conc. CH3COOH

    (d) Boiled conc. HCl

    SUBJECTIVE ANSWER TYPE


    Question 23: What is the coordination entity formed when excess of aqueous KCN is added to
    an aqueous solution of copper sulphate? Why is it that no precipitate of copper sulphide is
    obtained when H2S(g) is passed through this solution?

    Question 24: Why is K2Cr2O7 generally preferred over Na2Cr2O7 in volumetric analysis
    although both are oxidising agents?

    Question 25: K2PtCl6 is well known compound whereas corresponding Ni compound is not
    known. Explain.

    Question 26: Suggest a series of reactions, using common chemicals, by which each of the
    following synthesis can be performed:
    (a) Fe(OH)3 from FeS
    (b) BaCrO4 from BaCO3 and K2Cr2O7
    (c) CrCl3 from (NH4)2Cr2O7
    (d) MnCO3 from MnO2

    Question 27: A white amorphous powder (A) on heating yields a colourless, non-combustible
    gas (B) and a solid (C). The later compound assumes a yellow colour on heating and changes to
    white on cooling. (C) dissolves in dilute acid and the resulting solution gives a white ppt. on
    adding K4[Fe(CN)6] solution. (A) dissolves in dilute HCl with evolution of gas, which is
    identical in all respect to (B). The gas (B) turns lime water milky, but the milkiness disappears
    with the continuous passage of gas. The solution obtained by treating (A) with dil. HCl gives a
    white precipitate (D) on the addition of excess NH4OH and passing H2S. Same solution
    (obtained by treatment of (A) with dil. HCl) gives a white precipitate (E) on the addition of
    NaOH solution, but dissolves on further addition of the base. Identify (A) to (E).

    Question 28: A compound (A) is greenish crystalline salt which gave the following results:
    (i) Addition of BaCl2 solution to solution of (A) results in the formation of a white ppt. (B),
    which is insoluble in dil. HCl.
    (ii) On heating (A), water vapors and two oxides of sulphur, (C) and (D) are liberated leaving
    a red brown residue (E).
    (iii) (E) dissolves in warm conc. HCl to give a yellow solution (F).
    (iv) With H2S, the solution (F) yields a pale-yellow ppt. (G), which when filtered, leaves a
    greenish filtrate (H).
    (v) Solution (F) on treatment with thiocyanate ions gives blood red coloured compound (I).
    Identify the substances from (A) to (I)

    Question 29: A white substance (A) reacts with dilute H2SO4 to produce a colourless suffocating
    gas (B) and a colourless solution (C). The reaction of gas (B) with potassium iodate and starch
    solution produces a blue colour solution. Aqueous solution of (A) gives a white precipitate with
    BaCl2 solution which is soluble in dilute HCl. Addition of aqueous NH3 or NaOH to (C)
    produces first a precipitate which dissolves in excess of the respective reagent to produce a clear
    solution. Similarly, addition of excess of potassium ferrocyanide to (C) produces a precipitate
    (D) which also dissolves in aqueous NaOH giving a clear solution. Identify (A), (B), (C) and (D).
    Write the equations of the reactions involved.

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