Identifying Redox Reactions

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Identifying Redox Reactions

The first step in balancing any redox reaction is determining whether or not it is even
an oxidation-reduction reaction. This requires that one and typically more species
changing oxidation states during the reaction. To maintain charge neutrality in the
sample, the redox reaction will entail both a reduction component and an oxidation
components. These are often separated into independent two hypothetical half-
reactions to aid in understanding the reaction. This requires identifying which element
is oxidized and which element is reduced. For example, consider this reaction:

Cu(s)+2Ag+(aq)→Cu2+(aq)+2Ag(s)

The first step in determining whether the reaction is a redox reaction is to split the
equation into two hypothetical half-reactions. Let's start with the half-reaction involving
the copper atoms:

Cu(s)→Cu2+(aq)

The oxidation state of copper on the left side is 0 because it is an element on its own.
The oxidation state of copper on the right hand side of the equation is +2. The copper
in this half-reaction is oxidized as the oxidation states increases from 0 in CuCu to +2
in Cu2+Cu2+. Now consider the silver atoms

2Ag+(aq)→2Ag(s)

In this half-reaction, the oxidation state of silver on the left side is a +1. The oxidation
state of silver on the right is 0 because it is an pure element. Because the oxidation
state of silver decreases from +1 to 0, this is the reduction half-reaction.

Consequently, this reaction is a redox reaction as both reduction and oxidation half-
reactions occur (via the transfer of electrons, that are not explicitly shown in equations
2). Once confirmed, it often necessary to balance the reaction (the reaction in equation
1 is balanced already though), which can be accomplished in two ways because the
reaction could take place in neutral, acidic or basic conditions.

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