National Senior Certificate: Grade 12
National Senior Certificate: Grade 12
National Senior Certificate: Grade 12
SENIOR CERTIFICATE
GRADE 12
SEPTEMBER 2019
MARKS: 150
TIME: 3 hours
2. This question paper consists of EIGHT questions. Answer ALL the questions in
the ANSWER BOOK.
6. Number the answers correctly according to the numbering system used in this
question paper.
9. Round off your final numerical answers to a minimum of TWO decimal places.
Four options are provided as possible answers to the following questions. Each
question has only ONE correct answer. Write only the letter (A – D) next to the question
number (1.1 – 1.10) in the ANSWER BOOK.
Cℓ
I
H3C – CH – CH2 – CH – CH2OH
I
CH3
A 4-chloro-1-methyl pentan-1-ol
B 2-chloro-4-methyl pentan-2-ol
C 4-chloro-2-methyl pentan-1-ol
D 2-methyl-4-chloro butan-2-ol (2)
1.2 Each of the reactions below represenst a cracking reaction of C15H32. During
which reaction are two different alkenes produced?
A Ethane
B Ethene
C Propene
D Poly-ethene (2)
1.4 Which ONE of the following combinations of values for activation energy (Ea)
and heat of reaction (∆H) is possible for a reaction?
A 100 -50
B 100 +100
C 50 +50
D 50 +100 (2)
Which ONE of the following changes will have no influence on the rate of this
reaction?
1.6 The reaction which is represented by the balanced equation below, has
reached equilibrium in a closed container.
How will the equilibrium be influenced if first the volume of the container is
decreased and then the temperature is increased?
A x
B x2
1
C
x
1
D (2)
x2
T2
Reaction Rate
T1
Time
Which ONE of the following combinations regarding the forward reaction and
the Kc value is correct?
A NH3 ; NH+4
B NH3 ; H2O
C H2O ; NH+4
D NH3 ; OH- (2)
1.10 During a certain neutralisation reaction, 1 mole of base is used up for every
2 moles of acid. Which ONE of the following pairs can possibly be the base
and the acid?
CH3CH2C(CH3)CH3
I
Br
2.1.3 Write down the IUPAC name of the MAJOR ORGANIC PRODUCT
which forms when this compound undergoes an elimination
reaction. (2)
2.2.4 Give the IUPAC names of the organic acid and alcohol which react
to form propyl butanoate. (2)
2.3 Use MOLECULAR FORMULAE and write the balanced equation for the
complete combustion of C4H10. (3)
[19]
Compounds A to E, indicated in the table below, are used during two investigations to
determine the factors which influence boiling point.
3.2.2 Write down the independent variable for this investigation. (1)
3.2.3 Write down one control variable for this investigation. (1)
3.2.4 Explain fully why the boiling points increase from compound A to
compound C. (3)
3.4 Consider investigation II. Refer to the type of Van Der Waals forces in each
of the compounds and explain why the boiling point of compound D is higher
than that of compound E. (3)
[17]
In the flow diagram below, prop-1-ene is used as a starting compound for the
preparation of other organic compounds. P to T represent chemical reactions.
P
Prop-1-ene Alcohol
Q
R T
S
Alkane Halo-alkane
+ Cℓ2
4.1.1 P (1)
4.1.2 S (1)
4.1.3 Q (1)
4.1.4 T (1)
4.4 During reaction T, the halo-alkane reacts in the presence of a base to form the
alcohol in QUESTION 4.2.2. Write down the:
5.1 A reaction takes place in a test tube and the test tube becomes cold. (1)
5.1.1 In terms of energy change, name the type of reaction which occurs. (1)
5.2.1 Give a reason why the mass of the beaker and its contents
DECREASES. (1)
5.2.2 Use the values in the table and calculate the average rate of the
reaction in g∙s-1 for the total duration of the reaction. (3)
Study the graph below which shows decrease in mass against time.
6
Decrease in mass (g)
0 30 60 90 120 150
Time (s)
5.2.3 Give a reason for the shape of the graph from 105 s to 120 s. (1)
5.2.4 Give a reason why the rate of the reaction INCREASES from 0 s
to 30 s. (1)
5.2.5 Give a reason why the rate of the reaction DECREASES from
45 s to 105 s. (1)
5.2.6 Use the collision theory to explain the answer to QUESTION 5.2.5. (2)
5.2.7 Calculate the mass of copper used during this reaction. (4)
5.2.8 Except for adding a catalyst, name THREE other changes which
can be made n order to INCREASE the rate of this reaction. (3)
5.3 Another learner adds 100 cm3 HCℓ of concentration 0,25 mol∙dm-3 to an
excess of Na2S2O3(aq) and 0,24 g of sulphur is deposited. The equation for
the reaction is:
6.2 Use Le Chatelier’s principle and explain how an increase in pressure will
influence the amount of ozone at equilibrium. (3)
6.5 Explain how the addition of a suitable catalyst will influence the amount of
oxygen at equilibrium. (2)
Ozone (O3) reacts with nitrogen oxide (NO) as indicated in the reaction below.
Note that O3, NO and O2 are all colourless gases while NO2 is a brown gas.
The colour of the gas mixture is light brown.
6.6 A mixture of the four gases is prepared in a 2 dm3 sealed container with the
following initial concentrations:
Use the information given and calculate the value of the equilibrium constant (7)
at 1500 K.
6.7 A number of changes are made to the equilibrium mixture and the mixture is
allowed to reach a new equilibrium after each change.
'A learner wants to determine the percentage ethanoic acid (CH3COOH) in vinegar. The
following apparatus is used:
Retort stand Q
Ehrlenmeyer flask
A 3,1 - 4,4
B 6,0 - 7,6
C 8,3 - 10,0
Which ONE of the indicators (A,B or C) above is most suited to indicate the
exact endpoint of this titration?
(2)
Give a reason for the answer
25 cm3 of this solution is neutralised by 28,5 cm3 of a 0,11 mol∙dm-3 sodium hydroxide
(NaOH) solution.
7.5 Calculate the number of moles of sodium hydroxide which are used to
neutralise 25 cm3 of acid. (2)
Concentrated sulphuric acid (H2SO4) is added to pure water at 25 °C. The pH of the
solution is 1,6.
8.2 Ammonium chloride crystals (NH4Cℓ) are dissolved in water and undergo
hydrolysis.
m N
n= n=
M NA
n m V
c= or/of c= n=
V MV Vm
c a v a na
= pH = -log[H3O+]
c b v b nb
or/of
E θcell = E reduction
θ
− E θoxidation / E θsel = E reduksie
θ
− E θoksidasie
or/of
Eθcell = Eθoxidising agent − Ereducing
θ
E θ = E θoksideermi ddel − E reduseermi
agent / sel
θ
ddel
1 2 13 14 15 16 17 18
3 4 5 6 7 8 9 10 11 12
(I) (II) (III) (IV) (V) (VI) (VII) (VIII)
1 Atomic number 2
KEY/SLEUTEL
2,1
H He
1 29 4
Electronegativity Symbol
1,9
3 4 Cu 5 6 7 8 9 10
1,0
1,5
2,0
2,5
3,0
3,5
4,0
Li Be 63,5 B C N O F Ne
7 9 11 12 14 16 19 20
11 12 Approximate relative atomic mass 13 14 15 16 17 18
0,9
1,2
1,5
1,8
2,1
2,5
3,0
Na Mg Aℓ Si P S Cℓ Ar
23 24 Benaderde relatiewe atoommassa 27 28 31 32 35,5 40
19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36
0,8
1,0
1,3
1,5
1,6
1,6
1,5
1,8
1,8
1,8
1,9
1,6
1,6
1,8
2,0
2,4
2,8
K Ca Sc Ti V Cr Mn Fe Co Ni Cu Zn Ga Ge As Se Br Kr
39 40 45 48 51 52 55 56 59 59 63,5 65 70 73 75 79 80 84
37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54
0,8
1,0
1,2
1,4
1,8
1,9
2,2
2,2
2,2
1,9
1,7
1,7
1,8
1,9
2,1
2,5
Rb Sr Y Zr Nb Mo Tc Ru Rh Pd Ag Cd In Sn Sb Te I Xe
86 88 89 91 92 96 101 103 106 108 112 115 119 122 128 127 131
55 56 57 72 73 74 75 76 77 78 79 80 81 82 83 84 85 86
0,7
0,9
1,6
1,8
1,8
1,9
2,0
2,5
Cs Ba La Hf Ta W Re Os Ir Pt Au Hg Tℓ Pb Bi Po At Rn
133 137 139 179 181 184 186 190 192 195 197 201 204 207 209
87 88 89
0,7
0,9
Fr Ra Ac
226 58 59 60 61 62 63 64 65 66 67 68 69 70 71
Ce Pr Nd Pm Sm Eu Gd Tb Dy Ho Er Tm Yb Lu
140 141 144 150 152 157 159 163 165 167 169 173 175
Na+ + e− ⇌ Na − 2,71
Mg2+ + 2e− ⇌ Mg − 2,36
Aℓ3+ + 3e− ⇌ Aℓ − 1,66
Mn2+ + 2e− ⇌ Mn − 1,18
Cr2+ + 2e− ⇌ Cr − 0,91
2H2O + 2e− ⇌ H2(g) + 2OH− − 0,83
Zn2+ + 2e− ⇌ Zn − 0,76
Cr3+ + 3e− ⇌ Cr − 0,74
Fe2+ + 2e− ⇌ Fe − 0,44
Cr3+ + e− ⇌ Cr2+ − 0,41
Cd2+ + 2e− ⇌ Cd − 0,40
Co2+ + 2e− ⇌ Co − 0,28
Ni2+ + 2e− ⇌ Ni − 0,27
Sn2+ + 2e− ⇌ Sn − 0,14
Pb2+ + 2e− ⇌ Pb − 0,13
Fe3+ + 3e− ⇌ Fe − 0,06
2H+ + 2e− ⇌ H2(g) 0,00
S + 2H+ + 2e− ⇌ H2S(g) + 0,14
Sn4+ + 2e− ⇌ Sn2+ + 0,15
Cu2+ + e− ⇌ Cu+ + 0,16
2−
SO 4 + 4H+ + 2e− ⇌ SO2(g) + 2H2O + 0,17
Cu2+ + 2e− ⇌ Cu + 0,34
2H2O + O2 + 4e− ⇌ 4OH− + 0,40
SO2 + 4H+ + 4e− ⇌ S + 2H2O + 0,45
Cu+ + e− ⇌ Cu + 0,52
I2 + 2e− ⇌ 2I− + 0,54
O2(g) + 2H+ + 2e− ⇌ H2O2 + 0,68
Fe3+ + e− ⇌ Fe2+ + 0,77
−
NO 3 + 2H+ + e− ⇌ NO2(g) + H2O + 0,80
Ag+ + e− Ag ⇌ + 0,80
−
2+
Hg + 2e Hg(ℓ)
⇌ + 0,85
− + −
NO 3 + 4H + 3e ⇌ NO(g) + 2H2O + 0,96
− −
Br2(ℓ) + 2e ⇌ 2Br + 1,07
Pt2+ + 2 e− ⇌ Pt + 1,20
MnO2 + 4H+ + 2e− ⇌ Mn2+ + 2H2O + 1,23
O2(g) + 4H+ + 4e− ⇌ 2H2O + 1,23
2−
Cr2O 7 + 14H+ + 6e− ⇌ 2Cr3+ + 7H2O + 1,33
Cℓ2(g) + 2e− ⇌ 2Cℓ− + 1,36
−
MnO 4 + 8H+ + 5e− ⇌ Mn2+ + 4H2O + 1,51
H2O2 + 2H+ +2 e− ⇌ 2H2O +1,77
Co3+ + e− ⇌ Co2+ + 1,81
F2(g) + 2e− ⇌ 2F− + 2,87