SAFETY DATA SHEET

DOW SILICONES CORPORATION

Product name: DOWSIL™ 3165 Fast Tack RTV Adhesive Issue Date: 02/19/2020
Sealant
Print Date: 02/20/2020
DOW SILICONES CORPORATION encourages and expects you to read and understand the entire
(M)SDS, as there is important information throughout the document. We expect you to follow the
precautions identified in this document unless your use conditions would necessitate other appropriate
methods or actions.

1. IDENTIFICATION
Product name: DOWSIL™ 3165 Fast Tack RTV Adhesive Sealant

Recommended use of the chemical and restrictions on use

Identified uses: Adhesive, binding agents

COMPANY IDENTIFICATION
DOW SILICONES CORPORATION
2200 WEST SALZBURG ROAD
MIDLAND MI 48686-0994
UNITED STATES

Customer Information Number: 800-258-2436

[email protected]

EMERGENCY TELEPHONE NUMBER

24-Hour Emergency Contact: 1 800 424 9300
Local Emergency Contact: 800-424-9300

2. HAZARDS IDENTIFICATION
Hazard classification
GHS classification in accordance with 29 CFR 1910.1200
Not a hazardous substance or mixture.

Other hazards
No data available

3. COMPOSITION/INFORMATION ON INGREDIENTS

Chemical nature: Silicone

This product is a mixture.
Component CASRN Concentration

® ™ Trademark of The Dow Chemical Company ("Dow") or an affiliated Page 1 of 13

company of Dow
Product name: DOWSIL™ 3165 Fast Tack RTV Adhesive Sealant Issue Date: 02/19/2020

Titanium(4+) 2-methylpropan-2-olate 3087-39-6 >= 1.4 - <= 2.0 %

Quartz 14808-60-7 >= 0.51 - <= 0.69 %

4. FIRST AID MEASURES

Description of first aid measures
General advice:
First Aid responders should pay attention to self-protection and use the recommended protective
clothing (chemical resistant gloves, splash protection). If potential for exposure exists refer to Section
8 for specific personal protective equipment.

Inhalation: Move person to fresh air and keep comfortable for breathing; consult a physician.

Eye contact: Flush eyes thoroughly with water for several minutes. Remove contact lenses after the
initial 1-2 minutes and continue flushing for several additional minutes. If effects occur, consult a
physician, preferably an ophthalmologist.

Ingestion: No emergency medical treatment necessary.

Most important symptoms and effects, both acute and delayed:

Aside from the information found under Description of first aid measures (above) and Indication of
immediate medical attention and special treatment needed (below), any additional important
symptoms and effects are described in Section 11: Toxicology Information.

Indication of any immediate medical attention and special treatment needed

Notes to physician: No specific antidote. Treatment of exposure should be directed at the control of
symptoms and the clinical condition of the patient.

5. FIREFIGHTING MEASURES
Extinguishing media

Suitable extinguishing media: Water spray. Alcohol-resistant foam. Carbon dioxide (CO2).
Dry chemical.

Unsuitable extinguishing media: None known..

Special hazards arising from the substance or mixture

Hazardous combustion products: Silicon oxides. Formaldehyde. Carbon oxides. Metal

oxides.

Unusual Fire and Explosion Hazards: Exposure to combustion products may be a hazard to
health..

Advice for firefighters

Fire Fighting Procedures: Use water spray to cool unopened containers.. Evacuate area..
Collect contaminated fire extinguishing water separately. This must not be discharged into

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Product name: DOWSIL™ 3165 Fast Tack RTV Adhesive Sealant Issue Date: 02/19/2020

drains.. Fire residues and contaminated fire extinguishing water must be disposed of in
accordance with local regulations..
Use extinguishing measures that are appropriate to local circumstances and the surrounding
environment. Remove undamaged containers from fire area if it is safe to do so.

Special protective equipment for firefighters: In the event of fire, wear self-contained
breathing apparatus.. Use personal protective equipment..

6. ACCIDENTAL RELEASE MEASURES

Personal precautions, protective equipment and emergency procedures: Use personal protective
equipment. Follow safe handling advice and personal protective equipment recommendations.

Environmental precautions: Discharge into the environment must be avoided. Prevent further
leakage or spillage if safe to do so. Retain and dispose of contaminated wash water. Local
authorities should be advised if significant spillages cannot be contained.

Methods and materials for containment and cleaning up: Wipe up or scrape up and contain for
salvage or disposal. Local or national regulations may apply to releases and disposal of this material,
as well as those materials and items employed in the cleanup of releases. You will need to determine
which regulations are applicable. For large spills, provide dyking or other appropriate containment to
keep material from spreading. If dyked material can be pumped, store recovered material in
appropriate container. Sections 13 and 15 of this SDS provide information regarding certain local or
national requirements.
See sections: 7, 8, 11, 12 and 13.

7. HANDLING AND STORAGE

Precautions for safe handling: Do not get on skin or clothing. Do not swallow. Avoid contact with
eyes. Take care to prevent spills, waste and minimize release to the environment. Handle in
accordance with good industrial hygiene and safety practice. CONTAINERS MAY BE HAZARDOUS
WHEN EMPTY. Since emptied containers retain product residue follow all (M)SDS and label warnings
even after container is emptied.
Use only with adequate ventilation. See Engineering measures under EXPOSURE
CONTROLS/PERSONAL PROTECTION section.

Conditions for safe storage: Keep in properly labelled containers. Store in accordance with the
particular national regulations.

Do not store with the following product types: Strong oxidizing agents.
Unsuitable materials for containers: None known.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Control parameters
If exposure limits exist, they are listed below. If no exposure limits are displayed, then no values are
applicable.

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The following substance(s), which have Occupational Exposure Limit(s) (OEL), may be formed during
handling or processing:
Methanol.
Although some of the components of this product may have exposure guidelines, no exposure would
be expected under normal handling conditions due to the physical state of the material.

Exposure controls
Engineering controls: Use local exhaust ventilation, or other engineering controls to maintain
airborne levels below exposure limit requirements or guidelines. If there are no applicable exposure
limit requirements or guidelines, general ventilation should be sufficient for most operations. Local
exhaust ventilation may be necessary for some operations.

Individual protection measures

Eye/face protection: Use safety glasses (with side shields).
Skin protection
Hand protection: Use gloves chemically resistant to this material. Examples of
preferred glove barrier materials include: Butyl rubber. Neoprene. Nitrile/butadiene
rubber ("nitrile" or "NBR"). Ethyl vinyl alcohol laminate ("EVAL"). Polyvinyl alcohol
("PVA"). Polyvinyl chloride ("PVC" or "vinyl"). Viton. Examples of acceptable glove
barrier materials include: Natural rubber ("latex"). NOTICE: The selection of a
specific glove for a particular application and duration of use in a workplace should
also take into account all relevant workplace factors such as, but not limited to: Other
chemicals which may be handled, physical requirements (cut/puncture protection,
dexterity, thermal protection), potential body reactions to glove materials, as well as
the instructions/specifications provided by the glove supplier.
Other protection: Use protective clothing chemically resistant to this material.
Selection of specific items such as face shield, boots, apron, or full body suit will
depend on the task.
Respiratory protection: Respiratory protection should be worn when there is a potential to
exceed the exposure limit requirements or guidelines. If there are no applicable exposure limit
requirements or guidelines, use an approved respirator. When respiratory protection is
required, use an approved positive-pressure self-contained breathing apparatus or positive-
pressure airline with auxiliary self-contained air supply.

9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance
Physical state paste
Color grey
Odor alcohol-like
Odor Threshold No data available
pH Not applicable
Melting point/range No data available
Freezing point No data available
Boiling point (760 mmHg) Not applicable
Flash point Not applicable
Evaporation Rate (Butyl Acetate Not applicable
= 1)
Flammability (solid, gas) Not classified as a flammability hazard

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Lower explosion limit No data available

Upper explosion limit No data available
Vapor Pressure Not applicable
Relative Vapor Density (air = 1) No data available
Relative Density (water = 1) 1.35
Water solubility No data available
Partition coefficient: n- No data available
octanol/water
Auto-ignition temperature No data available
Decomposition temperature No data available
Dynamic Viscosity Not applicable
Kinematic Viscosity Not applicable
Explosive properties Not explosive
Oxidizing properties The substance or mixture is not classified as oxidizing.
Molecular weight No data available
Particle size No data available

NOTE: The physical data presented above are typical values and should not be construed as a
specification.

10. STABILITY AND REACTIVITY

Reactivity: Not classified as a reactivity hazard.

Chemical stability: Stable under normal conditions.

Possibility of hazardous reactions: Can react with strong oxidizing agents.

Conditions to avoid: None known.

Incompatible materials: Oxidizing agents

Hazardous decomposition products:

Decomposition products can include and are not limited to: Formaldehyde. Methanol. 1-Butene.

11. TOXICOLOGICAL INFORMATION

Toxicological information appears in this section when such data is available.

Information on likely routes of exposure

Eye contact, Skin contact, Ingestion.

Acute toxicity (represents short term exposures with immediate effects - no chronic/delayed
effects known unless otherwise noted)

Acute oral toxicity

Very low toxicity if swallowed. Harmful effects not anticipated from swallowing small amounts.

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Product name: DOWSIL™ 3165 Fast Tack RTV Adhesive Sealant Issue Date: 02/19/2020

As product: Single dose oral LD50 has not been determined.

Based on information for component(s):

LD50, Rat, > 5,000 mg/kg Estimated.

Information for components:

Titanium(4+) 2-methylpropan-2-olate
LD50, Rat, 3,500 mg/kg

Quartz
Single dose oral LD50 has not been determined.

Acute dermal toxicity

Prolonged skin contact is unlikely to result in absorption of harmful amounts.

As product: The dermal LD50 has not been determined.

For this family of materials:

LD50, Rabbit, > 2,000 mg/kg Estimated.

Information for components:

Titanium(4+) 2-methylpropan-2-olate
For similar material(s): LD50, Rabbit, > 2,000 mg/kg No deaths occurred at this
concentration.

Quartz
The dermal LD50 has not been determined.

Acute inhalation toxicity

No adverse effects are anticipated from inhalation. Vapor from heated material may cause
respiratory irritation.

As product: The LC50 has not been determined.

Information for components:

Titanium(4+) 2-methylpropan-2-olate
For similar material(s): LC50, Rat, 4 Hour, vapour, > 20 mg/l Estimated.

Quartz
The LC50 has not been determined.

Skin corrosion/irritation
Based on information for component(s):
Brief contact may cause skin irritation with local redness.

Information for components:

Titanium(4+) 2-methylpropan-2-olate
For similar material(s):
Brief contact may cause slight skin irritation with local redness.
May cause drying and flaking of the skin.

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Product name: DOWSIL™ 3165 Fast Tack RTV Adhesive Sealant Issue Date: 02/19/2020

Quartz
May cause skin irritation due to mechanical abrasion.
May cause drying and flaking of the skin.

Serious eye damage/eye irritation

Based on information for component(s):
May cause slight eye irritation.

Information for components:

Titanium(4+) 2-methylpropan-2-olate
For similar material(s):
May cause eye irritation.
May cause corneal injury.

Quartz
Solid or dust may cause irritation or corneal injury due to mechanical action.

Sensitization
For skin sensitization:
No relevant data found.

For respiratory sensitization:

No relevant data found.

Information for components:

Titanium(4+) 2-methylpropan-2-olate
For skin sensitization:
For similar material(s):
Did not cause allergic skin reactions when tested in guinea pigs.

For respiratory sensitization:

No relevant data found.

Quartz
For skin sensitization:
No relevant data found.

For respiratory sensitization:

No relevant data found.

Specific Target Organ Systemic Toxicity (Single Exposure)

Evaluation of available data suggests that this material is not an STOT-SE toxicant.

Information for components:

Titanium(4+) 2-methylpropan-2-olate
Available data are inadequate to determine single exposure specific target organ toxicity.

Quartz
Evaluation of available data suggests that this material is not an STOT-SE toxicant.

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Aspiration Hazard
Based on available information, aspiration hazard could not be determined.

Information for components:

Titanium(4+) 2-methylpropan-2-olate
Based on available information, aspiration hazard could not be determined.

Quartz
Based on physical properties, not likely to be an aspiration hazard.

Chronic toxicity (represents longer term exposures with repeated dose resulting in
chronic/delayed effects - no immediate effects known unless otherwise noted)

Specific Target Organ Systemic Toxicity (Repeated Exposure)

Contains a component(s) that is/are not expected to be bioavailable due to the physical state of the
material under normal handling and processing conditions.

Information for components:

Titanium(4+) 2-methylpropan-2-olate
No relevant data found.

Quartz
In humans, effects have been reported on the following organs:
Kidney.
Repeated excessive exposure to crystalline silica may cause silicosis, a progressive and
disabling disease of the lungs.
Due to the physical state of the material, this component is not expected to be bioavailable
under normal handling and processing conditions.

Carcinogenicity
Based on information for component(s): Did not cause cancer in long-term animal studies which used
routes of exposure considered relevant to industrial handling. Positive results have been reported in
other studies using routes of exposure not relevant to industrial handling.

Contains a component(s) that is/are not expected to be bioavailable due to the physical state of the
material under normal handling and processing conditions.

Information for components:

Titanium(4+) 2-methylpropan-2-olate
No relevant data found.

Quartz
Has caused cancer in humans. Has caused cancer in laboratory animals. Due to the physical
state of the material, this component is not expected to be bioavailable under normal handling
and processing conditions.

Teratogenicity
Contains component(s) which did not cause birth defects or any other fetal effects in lab animals.

Information for components:

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Titanium(4+) 2-methylpropan-2-olate
No relevant data found.

Quartz
For similar material(s): Did not cause birth defects or any other fetal effects in laboratory
animals.

Reproductive toxicity
Contains component(s) which did not interfere with reproduction in animal studies. Contains
component(s) which did not interfere with fertility in animal studies.

Information for components:

Titanium(4+) 2-methylpropan-2-olate
No relevant data found.

Quartz
No relevant data found.

Mutagenicity
Contains a component(s) which were negative in in vitro genetic toxicity studies.

Information for components:

Titanium(4+) 2-methylpropan-2-olate
No relevant data found.

Quartz
In vitro genetic toxicity studies were negative in some cases and positive in other cases.

12. ECOLOGICAL INFORMATION

Ecotoxicological information appears in this section when such data is available.

Toxicity

Titanium(4+) 2-methylpropan-2-olate
Acute toxicity to fish
No relevant data found.

Quartz
Acute toxicity to fish
Not expected to be acutely toxic to aquatic organisms.

Persistence and degradability

Titanium(4+) 2-methylpropan-2-olate
Biodegradability: No relevant data found.

Quartz
Biodegradability: Biodegradation is not applicable.

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Bioaccumulative potential

Titanium(4+) 2-methylpropan-2-olate
Bioaccumulation: No relevant data found.

Quartz
Bioaccumulation: Partitioning from water to n-octanol is not applicable.

Mobility in soil

Titanium(4+) 2-methylpropan-2-olate
No relevant data found.

Quartz
No relevant data found.

13. DISPOSAL CONSIDERATIONS

Disposal methods: DO NOT DUMP INTO ANY SEWERS, ON THE GROUND, OR INTO ANY BODY
OF WATER. All disposal practices must be in compliance with all Federal, State/Provincial and local
laws and regulations. Regulations may vary in different locations. Waste characterizations and
compliance with applicable laws are the responsibility solely of the waste generator. AS YOUR
SUPPLIER, WE HAVE NO CONTROL OVER THE MANAGEMENT PRACTICES OR
MANUFACTURING PROCESSES OF PARTIES HANDLING OR USING THIS MATERIAL. THE
INFORMATION PRESENTED HERE PERTAINS ONLY TO THE PRODUCT AS SHIPPED IN ITS
INTENDED CONDITION AS DESCRIBED IN MSDS SECTION: Composition Information. FOR
UNUSED & UNCONTAMINATED PRODUCT, the preferred options include sending to a licensed,
permitted: Incinerator or other thermal destruction device. For additional information, refer to:
Handling & Storage Information, MSDS Section 7 Stability & Reactivity Information, MSDS Section10
Regulatory Information, MSDS Section 15

Treatment and disposal methods of used packaging: Empty containers should be recycled or
otherwise disposed of by an approved waste management facility. Waste characterizations and
compliance with applicable laws are the responsibility solely of the waste generator. Do not re-use
containers for any purpose.

14. TRANSPORT INFORMATION

DOT
Not regulated for transport

Classification for SEA transport (IMO-IMDG):

Not regulated for transport
Transport in bulk Consult IMO regulations before transporting ocean bulk
according to Annex I or II
of MARPOL 73/78 and the
IBC or IGC Code

Classification for AIR transport (IATA/ICAO):

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Product name: DOWSIL™ 3165 Fast Tack RTV Adhesive Sealant Issue Date: 02/19/2020

Not regulated for transport

This information is not intended to convey all specific regulatory or operational

requirements/information relating to this product. Transportation classifications may vary by container
volume and may be influenced by regional or country variations in regulations. Additional
transportation system information can be obtained through an authorized sales or customer service
representative. It is the responsibility of the transporting organization to follow all applicable laws,
regulations and rules relating to the transportation of the material.

15. REGULATORY INFORMATION

Superfund Amendments and Reauthorization Act of 1986 Title III (Emergency Planning and
Community Right-to-Know Act of 1986) Sections 311 and 312
No SARA Hazards

Superfund Amendments and Reauthorization Act of 1986 Title III (Emergency Planning and
Community Right-to-Know Act of 1986) Section 313
This material does not contain any chemical components with known CAS numbers that exceed the
threshold (De Minimis) reporting levels established by SARA Title III, Section 313.

Pennsylvania Right To Know

The following chemicals are listed because of the additional requirements of Pennsylvania law:

Components CASRN
Dimethyl siloxane, trimethoxysilyl-terminated Not available

Calcium carbonate treated with stearic acid Not available

Siloxanes and silicones, dimethyl 63148-62-9
Amorphous fumed silica 112945-52-5

California Prop. 65
WARNING: This product can expose you to chemicals including Methanol, which is/are known to the
State of California to cause birth defects or other reproductive harm. For more information go to
www.P65Warnings.ca.gov.

United States TSCA Inventory (TSCA)

All components of this product are in compliance with the inventory listing requirements of the U.S.
Toxic Substances Control Act (TSCA) Chemical Substance Inventory.

16. OTHER INFORMATION

Hazard Rating System

NFPA
Health Flammability Instability
1 1 0

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HMIS
Physical
Health Flammability
Hazard
1/ 1 0

Revision
Identification Number: 3111440 / A713 / Issue Date: 02/19/2020 / Version: 8.0
Most recent revision(s) are noted by the bold, double bars in left-hand margin throughout this
document.

Full text of other abbreviations

AICS - Australian Inventory of Chemical Substances; ASTM - American Society for the Testing of
Materials; bw - Body weight; CERCLA - Comprehensive Environmental Response, Compensation,
and Liability Act; CMR - Carcinogen, Mutagen or Reproductive Toxicant; DIN - Standard of the
German Institute for Standardisation; DOT - Department of Transportation; DSL - Domestic
Substances List (Canada); ECx - Concentration associated with x% response; EHS - Extremely
Hazardous Substance; ELx - Loading rate associated with x% response; EmS - Emergency Schedule;
ENCS - Existing and New Chemical Substances (Japan); ErCx - Concentration associated with x%
growth rate response; ERG - Emergency Response Guide; GHS - Globally Harmonized System; GLP
- Good Laboratory Practice; HMIS - Hazardous Materials Identification System; IARC - International
Agency for Research on Cancer; IATA - International Air Transport Association; IBC - International
Code for the Construction and Equipment of Ships carrying Dangerous Chemicals in Bulk; IC50 - Half
maximal inhibitory concentration; ICAO - International Civil Aviation Organization; IECSC - Inventory of
Existing Chemical Substances in China; IMDG - International Maritime Dangerous Goods; IMO -
International Maritime Organization; ISHL - Industrial Safety and Health Law (Japan); ISO -
International Organisation for Standardization; KECI - Korea Existing Chemicals Inventory; LC50 -
Lethal Concentration to 50 % of a test population; LD50 - Lethal Dose to 50% of a test population
(Median Lethal Dose); MARPOL - International Convention for the Prevention of Pollution from Ships;
MSHA - Mine Safety and Health Administration; n.o.s. - Not Otherwise Specified; NFPA - National Fire
Protection Association; NO(A)EC - No Observed (Adverse) Effect Concentration; NO(A)EL - No
Observed (Adverse) Effect Level; NOELR - No Observable Effect Loading Rate; NTP - National
Toxicology Program; NZIoC - New Zealand Inventory of Chemicals; OECD - Organization for
Economic Co-operation and Development; OPPTS - Office of Chemical Safety and Pollution
Prevention; PBT - Persistent, Bioaccumulative and Toxic substance; PICCS - Philippines Inventory of
Chemicals and Chemical Substances; (Q)SAR - (Quantitative) Structure Activity Relationship; RCRA -
Resource Conservation and Recovery Act; REACH - Regulation (EC) No 1907/2006 of the European
Parliament and of the Council concerning the Registration, Evaluation, Authorisation and Restriction of
Chemicals; RQ - Reportable Quantity; SADT - Self-Accelerating Decomposition Temperature; SARA -
Superfund Amendments and Reauthorization Act; SDS - Safety Data Sheet; TCSI - Taiwan Chemical
Substance Inventory; TSCA - Toxic Substances Control Act (United States); UN - United Nations;
UNRTDG - United Nations Recommendations on the Transport of Dangerous Goods; vPvB - Very
Persistent and Very Bioaccumulative

Information Source and References

This SDS is prepared by Product Regulatory Services and Hazard Communications Groups from
information supplied by internal references within our company.

DOW SILICONES CORPORATION urges each customer or recipient of this (M)SDS to study it
carefully and consult appropriate expertise, as necessary or appropriate, to become aware of and
understand the data contained in this (M)SDS and any hazards associated with the product. The
information herein is provided in good faith and believed to be accurate as of the effective date shown
above. However, no warranty, express or implied, is given. Regulatory requirements are subject to
change and may differ between various locations. It is the buyer's/user's responsibility to ensure that

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Product name: DOWSIL™ 3165 Fast Tack RTV Adhesive Sealant Issue Date: 02/19/2020

his activities comply with all federal, state, provincial or local laws. The information presented here
pertains only to the product as shipped. Since conditions for use of the product are not under the
control of the manufacturer, it is the buyer's/user's duty to determine the conditions necessary for the
safe use of this product. Due to the proliferation of sources for information such as manufacturer-
specific (M)SDSs, we are not and cannot be responsible for (M)SDSs obtained from any source other
than ourselves. If you have obtained an (M)SDS from another source or if you are not sure that the
(M)SDS you have is current, please contact us for the most current version.
US

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