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    δ (perfluoroheptane) =12.0 (cal/cc) : Chapter 9 Assignment (Answers are in parenthesis)

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    The document contains 6 multiple choice questions about solutions, phase equilibria, and thermodynamics. The questions cover topics like liquid-liquid miscibility gaps, solubility, activity coefficients, melting point depression, and vapor pressure calculations using virial coefficients. The answers provided are: No, 0.35 and 0.7, 2.83, 3.8x108, 1250K, 1600 bar.

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    δ (perfluoroheptane) =12.0 (cal/cc) : Chapter 9 Assignment (Answers are in parenthesis)

    Uploaded by

    Protim's go
    115 views1 page
    The document contains 6 multiple choice questions about solutions, phase equilibria, and thermodynamics. The questions cover topics like liquid-liquid miscibility gaps, solubility, activity coefficients, melting point depression, and vapor pressure calculations using virial coefficients. The answers provided are: No, 0.35 and 0.7, 2.83, 3.8x108, 1250K, 1600 bar.

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    Ch 9 Assignment

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    The document contains 6 multiple choice questions about solutions, phase equilibria, and thermodynamics. The questions cover topics like liquid-liquid miscibility gaps, solubility, activity coefficients, melting point depression, and vapor pressure calculations using virial coefficients. The answers provided are: No, 0.35 and 0.7, 2.83, 3.8x108, 1250K, 1600 bar.

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
    115 views1 page

    δ (perfluoroheptane) =12.0 (cal/cc) : Chapter 9 Assignment (Answers are in parenthesis)

    Uploaded by

    Protim's go
    The document contains 6 multiple choice questions about solutions, phase equilibria, and thermodynamics. The questions cover topics like liquid-liquid miscibility gaps, solubility, activity coefficients, melting point depression, and vapor pressure calculations using virial coefficients. The answers provided are: No, 0.35 and 0.7, 2.83, 3.8x108, 1250K, 1600 bar.

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    of 1

    Chapter 9 Assignment

    (Answers are in parenthesis)

    1. The liquids, perfluoro-n-heptane and benzene are only partially miscible at


    temperatures below their UCST of 113.4oC. At 100oC one liquid phase is
    approximately 0.48 mole fraction benzene, and the other 0.94 mole fraction
    benzene. The liquid molar volume of perfluoro-n-heptane and benzene at 25oC
    are 226 cc/mole and 89cc/mole, respectively. Check if above data is consistent
    with Regular Solution behaviour with δ(benzene)=9.2(cal/cc)1/2;
    δ(perfluoroheptane)=12.0(cal/cc) [No]
    1/2

    2. In a binary mixture of B and C, at const. T and P,


    G /=
    E
    RT xB xC [2.0 + 0.2( xB − xC ) − 0.8( xB − xC ) 2 ] Determine the composition limits of
    essential stability of the mixture. [x B = 0.35, 0.7]

    3. A solute ‘A’ dissolves to partition into two fully immiscible liquids ‘B’ and ‘C’.
    Phase I contains only ‘A’ and ‘B’ and is equimolar, while phase II contains
    95mole % ‘C’. The liquid phase coefficient model is of the form: G E / RT = β xi x j . If
    β = 1 for phase I, compute that for phase II. [2.83]

    4. The solubility (mole fraction) of a substance A (solid) in water is 3.37 x10−10 at


    25C. The melting point of the solid is 178.1C, and its heat of fusion 15.1kJ/mole.
    Estimate the acitivity coefficient of A in water. What does the value suggest in
    terms of interaction of the two? [ 3.8x108 ]

    5. A liquid solution at 4000K and 1 atm, contains 5mol% of ‘1’ and 95mol% of ‘2’.
    The mixture is cooled isobarically. By how much does the temperature drop
    before just the first solid particle appears? Assume that both the phases form ideal
    solution. The melting point and fusion enthalpies (constant) are:
    = =
    Tm1 353.4 K ; Tm 2 278.7 K ; ∆H fus ,1 ( J / mol ) =∆ 9843 [1250K]
    19008; H fus ,2 ( J / mol ) =

    6. A pure solid (1) exists in equilibrium with a mixture of its vapour and a gas (2) at
    4000K. The vapour mixture contains 0.1 mol% of the solute (1) and forms an ideal
    solution. Calculate the pressure of the system. The molar volume of solid at 4000K
    1600
    is 200.0 cm3/mol. Data: log10 P sub (bar=
    ) 2.0 − 0 The second virial coefficients
    T( K)
    at 4000K=
    are: B11 –565,
    = =
    B22 –400, B12 –350cm3 / mole.

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