Page 1/8

Safety data sheet

according to 1907/2006/EC, Article 31
Printing date 25.04.2018 Version number 1 Revision: 25.04.2018

SECTION 1: Identification of the substance/mixture and of the company/

undertaking
1.1 Product identifier
Trade name Kiesoton
Article number: KIESON-0000
1.2 Relevant identified uses of the substance or mixture and uses advised against
No further relevant information available.
Application of the substance / the mixture
Solvents
Industrial / commercial use
1.3 Details of the supplier of the safety data sheet
Manufacturer/Supplier:
Kiesewetter GmbH...und die Chemie stimmt
Maybachstr. 8b
51381 Leverkusen
Tel.: +49 (0) 2171 9128055
Fax: +49 (0) 2171 9128054
Web: www.kieserol.de
Email: [email protected]
Informing department: General Manager
1.4 Emergency telephone number:
Medical Emergency information in case of poisoning:
Poison Information Center Mainz - 24h - Phone: +49 (0) 6131 19240 (advisory service in German or
Englisch language)

SECTION 2: Hazards identification

2.1 Classification of the substance or mixture
Classification according to Regulation (EC) No 1272/2008
The product is not classified according to the CLP regulation.
2.2 Label elements
Labelling according to Regulation (EC) No 1272/2008 Void
Hazard pictograms Void
Signal word Void
Hazard statements Void
Additional information:
EUH210 Safety data sheet available on request.
2.3 Other hazards
Results of PBT and vPvB assessment
PBT: Not applicable.
vPvB: Not applicable.

SECTION 3: Composition/information on ingredients

3.2 Mixtures
Description: Solvent mixture.
(Contd. on page 2)
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Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 25.04.2018 Version number 1 Revision: 25.04.2018

Trade name Kiesoton

(Contd. of page 1)
Dangerous components:
CAS: 108-65-6 2-methoxy-1-methylethyl acetate Flam. Liq. 3, H226 10-25%
EINECS: 203-603-9
Reg.nr.: 01-2119475791-29
Additional information For the wording of the listed hazard phrases refer to section 16.

SECTION 4: First aid measures

4.1 Description of first aid measures
General advice: Change contaminated clothing
After inhalation
Supply fresh air. If required, provide artificial respiration. Keep patient warm. Consult doctor if symptoms
persist.
In case of unconsciousness bring patient into stable side position for transport.
After skin contact
Rinse with warm water.
If skin irritation continues, consult a doctor.
After eye contact
Rinse opened eye for 15 minutes under running water.
In case of persistent symptoms consult doctor.
After swallowing
Rinse out mouth and then drink plenty of water.
Seek medical treatment.
4.2 Most important symptoms and effects, both acute and delayed
No further relevant information available.
Information for doctor
Symptomatic treatment (decontamination, vital functions), no specific antidote known.
4.3 Indication of any immediate medical attention and special treatment needed
No further relevant information available.

SECTION 5: Firefighting measures

5.1 Extinguishing media
Suitable extinguishing agents
CO2, extinguishing powder or water jet. Fight larger fires with water jet or alcohol-resistant foam.
For safety reasons unsuitable extinguishing agents Water with a full water jet.
5.2 Special hazards arising from the substance or mixture
Carbon monoxide may be evolved if incomplete combustion occurs. Not classified as flammable but will
burn.
Can be released in case of fire:
organic decomposition products
5.3 Advice for firefighters
Protective equipment:
See section 8.
Wear full protective suit with self-contained breathing apparatus.
Additional information
Dispose of fire debris and contaminated fire fighting water in accordance with official regulations.
(Contd. on page 3)
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Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 25.04.2018 Version number 1 Revision: 25.04.2018

Trade name Kiesoton

(Contd. of page 2)
Endangered containers in the surrounding area should be cooled with a water-hose.

SECTION 6: Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures
Wear protective equipment and keep unprotected persons away.
Ensure adequate ventilation
6.2 Environmental precautions:
Do not allow to enter drainage system, surface or ground water.
If large amounts are released, the authorities must be informed.
6.3 Methods and material for containment and cleaning up:
Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).
Contaminated material has to be disposed as waste (see item 13).
6.4 Reference to other sections
See Section 7 for information on safe handling
See Section 8 for information on personal protection equipment.
See Section 13 for information on disposal.
Danger of burning is possible

SECTION 7: Handling and storage

7.1 Precautions for safe handling
The usual good standards of industrial hygiene should be maintained.
Information about protection against explosions and fires:
Keep ignition sources away - Do not smoke.
Protect against electrostatic sparks.
Pay attention to general rules of internal fire prevention.
7.2 Conditions for safe storage, including any incompatibilities
Storage Keep containers tightly closed. Store in cool, dry conditions.
Requirements to be met by storerooms and containers:
Suitable material for containers and conduit: steel or stainless steel.
Information about storage in one common storage facility:
Pay attention to regulations / technical guidelines on mixed storage of flammable liquids.
Further information about storage conditions: Protect from heat and direct sunlight.
7.3 Specific end use(s) No further relevant information available.

SECTION 8: Exposure controls/personal protection

Additional information about design of technical systems: No further data; see item 7.
8.1 Control parameters
Components with critical values that require monitoring at the workplace:
CAS: 108-65-6 2-methoxy-1-methylethyl acetate (10-25%)
WEL Short-term value: 548 mg/m³, 100 ppm
Long-term value: 274 mg/m³, 50 ppm
Sk
(Contd. on page 4)
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Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 25.04.2018 Version number 1 Revision: 25.04.2018

Trade name Kiesoton

(Contd. of page 3)
Additional information: The lists that were valid during the compilation were used as basis.
8.2 Exposure controls
Personal protective equipment
General protective and hygienic measures
The usual precautionary measures should be adhered to in handling the chemicals.
Keep away from food, beverages and fodder.
Wash hands during breaks and at the end of the work.
Avoid contact with the eyes and skin.
Gases, fumes and aerosols should not be inhaled.
Breathing equipment:
Not necessary if room is well-ventilated.
Use breathing protection only when aerosol or mist is formed.
Recommended filter device for short term use: Filter A
Protection of hands:
The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.
Selection of the glove material on consideration of the penetration times, rates of diffusion and the
degradation
Material of gloves
Butylrubber, BR, recommended thickness of the material: ≥0.7 mm, penetration time: ≥480 min.
Nitrile rubber, NBR, recommended thickness of the material: ≥0.4 mm, penetration time: ≥480 min.
The selection of the suitable gloves does not only depend on the material, but also on further marks of
quality and varies from manufacturer to manufacturer. As the product is a preparation of several
substances, the resistance of the glove material can not be calculated in advance and has therefore to be
checked prior to the application.
Penetration time of glove material
Note information regarding permeation rate, penetration times and the degradation supplied by the
manufacturer of gloves just as workplace-specific conditions.
Eye protection: Safety glasses
Body protection:
Standard proctective clothing. Chemical resistant safety-shoes or boots. If skin contact is possible, wear
inpenetrable protective clothing against this solvent.

SECTION 9: Physical and chemical properties

9.1 Information on basic physical and chemical properties
General Information
Appearance:
Form: Fluid
Colour: Colourless
Smell: Characteristic
Odour threshold: Not determined.
pH-value: not applicable
Change in condition
Melting point/freezing point: Not determined
Initial boiling point and boiling range: > 140 °C
Flash point: ca. 67-68 °C
(Contd. on page 5)
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Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 25.04.2018 Version number 1 Revision: 25.04.2018

Trade name Kiesoton

(Contd. of page 4)

Inflammability (solid, gaseous) Not applicable.

Ignition temperature: 315 °C
Decomposition temperature: Not determined.
Self-inflammability: Product is not selfigniting.
Explosive properties: Product is not potentially explosive
Critical values for explosion:
Lower: 1.5 Vol %
Upper: 12.7 Vol %
Vapour pressure: Not determined.
Density at 20 °C 1.038 g/cm³
Relative density Not determined.
Vapour density Not determined.
Evaporation rate Not determined.
Solubility in / Miscibility with
Water: Not miscible or difficult to mix
Partition coefficient: n-octanol/water: Not determined.
Viscosity:
dynamic: Not determined.
kinematic: Not determined.
9.2 Other information No further relevant information available.

SECTION 10: Stability and reactivity

10.1 Reactivity No further relevant information available.
10.2 Chemical stability
Thermal decomposition / conditions to be avoided:
To avoid thermal decomposition do not overheat.
To avoid: warmth, flames, sparks
10.3 Possibility of hazardous reactions
Reacts with strong oxidizing agents
Can form explosive mixtures in air if heated above flash point and/or when sprayed or atomised
10.4 Conditions to avoid No further relevant information available.
10.5 Incompatible materials:
strong oxidizing agents
alkalies
Acids
10.6 Hazardous decomposition products:
Thermal decomposition can produce a variety of compounds, the precise nature of which will depend on
the decomposition conditions.
(Contd. on page 6)
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Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 25.04.2018 Version number 1 Revision: 25.04.2018

Trade name Kiesoton

(Contd. of page 5)
Additional information:
Incomplete combustion will generate smoke, carbon dioxide and hazardous gases, which will include
carbon monoxide.

SECTION 11: Toxicological information

11.1 Information on toxicological effects
Acute toxicity Based on available data, the classification criteria are not met.
Primary irritant effect:
Skin corrosion/irritation Based on available data, the classification criteria are not met.
Serious eye damage/irritation Based on available data, the classification criteria are not met.
Respiratory or skin sensitisation Based on available data, the classification criteria are not met.
CMR effects (carcinogenity, mutagenicity and toxicity for reproduction)
Germ cell mutagenicity Based on available data, the classification criteria are not met.
Carcinogenicity Based on available data, the classification criteria are not met.
Reproductive toxicity Based on available data, the classification criteria are not met.
STOT-single exposure Based on available data, the classification criteria are not met.
STOT-repeated exposure Based on available data, the classification criteria are not met.
Aspiration hazard Based on available data, the classification criteria are not met.

SECTION 12: Ecological information

12.1 Toxicity
Aquatic toxicity: No further relevant information available.
12.2 Persistence and degradability The product is readily biodegradable.
12.3 Bioaccumulative potential No bioaccumulation
12.4 Mobility in soil No further relevant information available.
Additional ecological information:
General notes:
Do not allow to enter drainage system, surface or ground water
Water hazard class 1 (Self-assessment): slightly hazardous for water.
12.5 Results of PBT and vPvB assessment
PBT: Not applicable.
vPvB: Not applicable.
12.6 Other adverse effects No further relevant information available.

SECTION 13: Disposal considerations

13.1 Waste treatment methods
Recommendation
A used product should be recycled or used in other contexts, otherwise be handed over to an appropriate
disposal site.
Waste disposal key number:
Since 01/01/99 the waste code numbers have not only been product-related but are also essentially
application-related. The valid waste code number of the application can be obtained from the European
waste catalogue.
(Contd. on page 7)
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Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 25.04.2018 Version number 1 Revision: 25.04.2018

Trade name Kiesoton

(Contd. of page 6)

Uncleaned packagings: Disposal must be made according to official regulations.

Recommendation:
After complete emptying and cleaning, send to be reconditioned or recycled.
Rented packaging: After optimal emptying, close immediately and return to the supplier without cleaning.
Care should be taken that no other materials get into the packaging.
Other containers: After complete emptying and cleaning, send to be reconditioned or recycled.

SECTION 14: Transport information

14.1 UN-Number
ADR, IMDG, IATA Void
14.2 UN proper shipping name
ADR, IMDG, IATA Void
14.3 Transport hazard class(es)
ADR, IMDG, IATA
Class Void
14.4 Packing group
ADR, IMDG, IATA Void
14.6 Special precautions for user Not applicable.
14.7 Transport in bulk according to Annex II
of Marpol and the IBC Code Not applicable.
Transport/Additional information: Not dangerous according to the above specifications.
UN "Model Regulation": Void

SECTION 15: Regulatory information

15.1 Safety, health and environmental regulations/legislation specific for the substance
or mixture
TSCA (Toxic Substances Control Act)
All ingredients are listed.
Canadian Domestic Substances List (DSL)
All ingredients are listed.
Philippines Inventory of Chemicals and Chemical Substances
All ingredients are listed.
Chinese Chemical Inventory of Existing Chemical Substances
All ingredients are listed.
Australian Inventory of Chemical Substances
All ingredients are listed.
(Contd. on page 8)
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Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 25.04.2018 Version number 1 Revision: 25.04.2018

Trade name Kiesoton

(Contd. of page 7)
Korean Existing Chemical Inventory
CAS: 623-84-7 1,2-propandiol diacetate KE-29272
CAS: 108-65-6 2-methoxy-1-methylethyl acetate KE-23315
New Zealand Inventory of Chemicals
All ingredients are listed.
Existing Chemical Substances (Japan)
CAS: 623-84-7 1,2-propandiol diacetate 2-665
CAS: 108-65-6 2-methoxy-1-methylethyl acetate 2-3144

Directive 2012/18/EU
Named dangerous substances - ANNEX I None of the ingredients is listed.
REGULATION (EC) No 1907/2006 ANNEX XVII Conditions of restriction: 40
National regulations
Technical instructions (air):
Class Share in %
NK 50-100
Water hazard class: Water hazard class 1 (Self-assessment): slightly hazardous for water.
15.2 Chemical safety assessment: A Chemical Safety Assessment has not been carried out.

SECTION 16: Other information

These data are based on our present knowledge. However, they shall not constitute a guarantee for any
specific product features and shall not establish a legally valid contractual relationship.
Relevant phrases
H226 Flammable liquid and vapour.
Department issuing data specification sheet: see item 1: Informing department
Abbreviations and acronyms:
RID: Règlement international concernant le transport des marchandises dangereuses par chemin de fer (Regulations Concerning
the International Transport of Dangerous Goods by Rail)
ICAO: International Civil Aviation Organisation
LEV: Local Exhaust Ventilation
RPE: Respiratory Protective Equipment
RCR: Risk Characterisation Ratio (RCR= PEC/PNEC and RCR= Estimated Exposition/DNEL)
ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement concerning the
International Carriage of Dangerous Goods by Road)
IMDG: International Maritime Code for Dangerous Goods
IATA: International Air Transport Association
GHS: Globally Harmonized System of Classification and Labelling of Chemicals
CLP: Classification, Labelling and Packaging (Regulation (EC) No. 1272/2008)
EINECS: European Inventory of Existing Commercial Chemical Substances
ELINCS: European List of Notified Chemical Substances
CAS: Chemical Abstracts Service (division of the American Chemical Society)
vPvB: very Persistent and very Bioaccumulative
Flam. Liq. 3: Flammable liquids – Category 3
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