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    Exp5 Determination of Heat of Solution F

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    Jim
    This experiment aims to determine the heat of solution of benzoic acid by measuring its solubility at different temperatures, plotting ln(Cs) vs 1/T, and calculating the heat of solution from the slope of the line based on Van't Hoff's equation; solubility depends on factors like temperature, pressure, and the nature of the solute and solvent; and the chemical reactions can be exothermic, releasing heat, or endothermic, absorbing heat during the reaction.

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    Exp5 Determination of Heat of Solution F

    Uploaded by

    Jim
    82 views8 pages
    This experiment aims to determine the heat of solution of benzoic acid by measuring its solubility at different temperatures, plotting ln(Cs) vs 1/T, and calculating the heat of solution from the slope of the line based on Van't Hoff's equation; solubility depends on factors like temperature, pressure, and the nature of the solute and solvent; and the chemical reactions can be exothermic, releasing heat, or endothermic, absorbing heat during the reaction.

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    This experiment aims to determine the heat of solution of benzoic acid by measuring its solubility at different temperatures, plotting ln(Cs) vs 1/T, and calculating the heat of solution from the slope of the line based on Van't Hoff's equation; solubility depends on factors like temperature, pressure, and the nature of the solute and solvent; and the chemical reactions can be exothermic, releasing heat, or endothermic, absorbing heat during the reaction.

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
    82 views8 pages

    Exp5 Determination of Heat of Solution F

    Uploaded by

    Jim
    This experiment aims to determine the heat of solution of benzoic acid by measuring its solubility at different temperatures, plotting ln(Cs) vs 1/T, and calculating the heat of solution from the slope of the line based on Van't Hoff's equation; solubility depends on factors like temperature, pressure, and the nature of the solute and solvent; and the chemical reactions can be exothermic, releasing heat, or endothermic, absorbing heat during the reaction.

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
    of 8

    Exp5: Determination of Heat of

    Solution From Solubility


    Theory
    When a sufficiently large amount of solute is in contact with the
    limited amount of solvent, dissolving of the solute starts taking
    place. After a certain period of time, the reverse process,
    precipitation, starts to occur. When dissolving and precipitation of
    the solute take place at equal rate (equilibrium has been
    established), the solution is said to be saturated. After this point
    the concentration of the solute in the solution remaining
    unchanged. The concentration of the saturated solution is defined
    as the solubility of the solute in the given solvent. Solubility is
    generally a function of temperature.
    Theory
    Heat of Solution:- is the amount of heat that absorbed
    when one mole of the solid is dissolved in a solution that is
    already practically saturated.
    Solubility:- involves to measure the concentration of the solute in the
    saturated solution.
    At equilibrium:

    The chemical reactions are two kinds


    1-Exothermic
    2-Endothermix
    * The solubility depends on the temperature, pressure and nature of the solute & solvent.

    ** The solubility of solute (benzoic acid) can be determined as a function of


    temperature. A plot of lnCs versus 1/T should give straight line with the slop being
    equal to heat of solution.
    Vant Hoff equation
    ∆𝑮 = ∆𝑯 − 𝑻∆𝑺

    ∆𝑮 = −𝑹𝑻 𝒍𝒏 𝑲𝒔

    −𝑹𝑻 𝒍𝒏 𝑲𝒔 = ∆𝑯 − 𝑻∆𝑺

    ∆𝑯 𝑻∆𝑺
    𝒍𝒏 𝑲𝒔 = −
    −𝑹𝑻 −𝑹𝑻

    ∆𝑯 ∆𝑺
    𝒍𝒏 𝑲𝒔 𝒐𝒓 𝒍𝒏𝑪𝑺 = − +
    𝑹𝑻 𝑹
    𝒎𝒐𝒍𝒆
    𝑾𝒉𝒆𝒓𝒆 𝑲𝒔 𝒐𝒓 𝑪𝑺 = 𝑺𝒐𝒍𝒖𝒃𝒊𝒍𝒊𝒕𝒚 𝒐𝒇 𝒔𝒐𝒍𝒗𝒆𝒏𝒕
    𝑲𝒈
    𝑻 = 𝑻𝒆𝒎𝒑𝒆𝒓𝒂𝒕𝒖𝒓𝒆 °𝑭
    𝑱
    ∆𝑯 = 𝑯𝒆𝒂𝒕 𝒐𝒇 𝒔𝒐𝒍𝒖𝒕𝒊𝒐𝒏
    𝒎𝒐𝒍𝒆
    Procedure
    1- Weight 1 gm of benzoic acid and add it to approximately 250ml of distilled water
    that has been heated up to 60°C in a beaker. Caution, above 70°C benzoic acid may
    be decompose.

    2- Use the pipette to transfer 10 ml from the filtrate to the conical flask, and titrate
    with the standard (0.1N) NaOH solution, using phenol phthalein as the indicator.

    3- Repeat step 2 at different temperature (30)°C.


    Calculation

    1- Complete the table below:


    T°C TK 1/TK Vml Cs lnCs
    NaOH

    2-Draw the plot between lnCs versus 1/T.

    3- Calculate the heat of solution from the plot.


    Discussion
    Q1/ What is the factors that affected on the solubility?
    Q2/ What is the Goal of the experiment?
    Q3/ What the differences between exothermic and endothermic
    reaction?

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