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    Tarea - Balance Redox: 2-Cri + Naoh + CL Naio + Na Cro + Nacl + H O Solución

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    Raul Cobian
    The document describes several redox reactions involving manganese, potassium, aluminum, iodine, and sulfuric acid. 1. Aluminum iodide reacts with sulfuric acid to produce iodine and aluminum sulfate, providing electrons. Potassium permanganate then reacts with these electrons to reduce manganese from the +7 to the +2 oxidation state, producing potassium sulfate. 2. A larger reaction combines these processes, with additional aluminum iodide, sulfuric acid, and potassium permanganate producing more iodine, manganese sulfate, aluminum sulfate, potassium sulfate, and water. 3. A reaction is described between chromium iodide, sodium hydroxide

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    Tarea - Balance Redox: 2-Cri + Naoh + CL Naio + Na Cro + Nacl + H O Solución

    Uploaded by

    Raul Cobian
    36 views2 pages
    The document describes several redox reactions involving manganese, potassium, aluminum, iodine, and sulfuric acid. 1. Aluminum iodide reacts with sulfuric acid to produce iodine and aluminum sulfate, providing electrons. Potassium permanganate then reacts with these electrons to reduce manganese from the +7 to the +2 oxidation state, producing potassium sulfate. 2. A larger reaction combines these processes, with additional aluminum iodide, sulfuric acid, and potassium permanganate producing more iodine, manganese sulfate, aluminum sulfate, potassium sulfate, and water. 3. A reaction is described between chromium iodide, sodium hydroxide

    Original Description:

    tarea de química ciclo 1

    Original Title

    TAREA - REDOX (3)

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    The document describes several redox reactions involving manganese, potassium, aluminum, iodine, and sulfuric acid. 1. Aluminum iodide reacts with sulfuric acid to produce iodine and aluminum sulfate, providing electrons. Potassium permanganate then reacts with these electrons to reduce manganese from the +7 to the +2 oxidation state, producing potassium sulfate. 2. A larger reaction combines these processes, with additional aluminum iodide, sulfuric acid, and potassium permanganate producing more iodine, manganese sulfate, aluminum sulfate, potassium sulfate, and water. 3. A reaction is described between chromium iodide, sodium hydroxide

    Copyright:

    © All Rights Reserved
    Download as DOCX, PDF, TXT or read online from Scribd
    Download as docx, pdf, or txt
    36 views2 pages

    Tarea - Balance Redox: 2-Cri + Naoh + CL Naio + Na Cro + Nacl + H O Solución

    Uploaded by

    Raul Cobian
    The document describes several redox reactions involving manganese, potassium, aluminum, iodine, and sulfuric acid. 1. Aluminum iodide reacts with sulfuric acid to produce iodine and aluminum sulfate, providing electrons. Potassium permanganate then reacts with these electrons to reduce manganese from the +7 to the +2 oxidation state, producing potassium sulfate. 2. A larger reaction combines these processes, with additional aluminum iodide, sulfuric acid, and potassium permanganate producing more iodine, manganese sulfate, aluminum sulfate, potassium sulfate, and water. 3. A reaction is described between chromium iodide, sodium hydroxide

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    © All Rights Reserved
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    TAREA – BALANCE REDOX

    1- K+1 Mn+7 O-24 + Al+3 I-13 + H+12 S+ 6O-24 → Mn+2 S+6 O-24 + K+12 S+6 O-2 4 + Al+3 2 (S+6 O-2 4)3 + I0
     + H
    2
    +1
    2 o

    0
    2Al+3I-13 → 3I 2 + 6e-

    K+1 Mn+7 O-2 4 + 5e- → Mn+2 S+6 O-2 4

    2Al+ 3I-1 3 + 3H2 SO4 → 3I0 2 + Al2(SO4)3 + 6e-

    2K+1 Mn+7 O-2 4 + 3H2SO4 + 10e- → 2Mn+2 S+6 O-2 4 + K2SO4

    2Al+3I-1 3 + 3H2SO4 → 3I0 2 + Al2(SO4)3 + 6e- + 6H+

    2K+1Mn+7O-2 4 + 3H2SO4 + 10e- + 10H+ → 2Mn+2 S+6 O-2 4 + K2SO4

    2Al+3I-1 3 + 3H2SO4 → 3I0 2 + Al2(SO4)3 + 6e- + 6H+

    2K+1 Mn+7O-2 4 + 3H2SO4 + 10e- + 10H+ → 2Mn+2 S+6O-2 4 + K2SO4 + 8H2O

    10Al+3 I-1 3 + 15H2SO4 → 15I0 2 + 5Al2(SO4)3 + 30e- + 30H+

    6K+1 Mn+7O-24 + 9H2SO4 + 30e- + 30H+ → 6Mn+2S+6O-2 4 + 3K2SO4 + 24H2O

    10AlI  + 6KMnO  + 24H SO  + 30e  + 30H  → 15I  + 6MnSO  + 5Al (SO )  +


    3 4 2 4
    - +
    2 4 2 4 3

    3K SO  + 30e  + 24H O + 30H


    2 4
    -
    2
    +

    10AlI  + 6KMnO  + 24H SO  → 15I  + 6MnSO  + 5Al (SO )  + 3K SO  + 24H O


    3 4 2 4 2 4 2 4 3 2 4 2

    2-CrI3 + NaOH + Cl2 NaIO4 + Na2CrO4 + NaCl + H2O

    SOLUCIÓN:

    I.Cr I 3 +5 NaOH → 3 NaI O 4 + N a2 Cr O4


    Cr I 3 +5 NaOH +11 H 2 O →3 NaI O 4 + N a2 Cr O4
    Cr I 3 +5 NaOH +11 H 2 O →3 NaI O 4 + N a2 Cr O 4 + 27 H + ¿¿
    −¿ x2 ¿

    Cr I 3 +5 NaOH +11 H 2 O →3 NaI O4 + N a2 Cr O 4 + 27 H + ¿+27 e ¿


    −¿¿

    2 Cr I 3+10 NaOH +22 H 2 O → 6 NaI O 4 +2 N a 2 Cr O 4+ 54 H +¿+54 e ¿

    II. C l 2 +2 NaOH → 2 NaCl


    C l 2 +2 NaOH → 2 NaCl+ 2 H 2 O
    C l 2 +2 NaOH + 2 H +¿ →2 NaCl+2 H O ¿ 2

    −¿→2 NaCl +2 H 2 O x 27¿

    C l 2 +2 NaOH + 2 H +¿+2 e ¿
    −¿→54 NaCl +54 H 2 O ¿

    27 C l 2 +54 NaOH +54 H +¿+54 e ¿

    III. Ec.1 + Ec.2

    2 Cr I 2+27 C l 2+64 NaOH → 6 NaI O 4 +54 NaCl+2 N a2 Cr O 4 +32 H 2 O

    5) NaOH + I2 = NaI + NaIO3 + H2O

    Solución:

    1. NaOH + I2 → NaI + NaIO3 + H2O


    2. Na+1O-2H+1 + I02 → Na+1I-1 + Na+1I+5O-23 + H+12O-2
     O: I02 → 2Na+1I+5O-23 + 10e-
    R: I02 + 2e- → 2Na+1I-1
     O: I02 → 2Na+1I+5O-23 + 10e-
    R: I02 + 2e- → 2Na+1I-1
    3. *) O: I02 + 2NaOH → 2Na+1I+5O-23 + 10e
    R: I02 + 2NaOH + 2e- → 2Na+1I-1

    *) O: I02 + 2NaOH → 2Na+1I+5O-23 + 10e- + 10H+


    R: I02 + 2NaOH + 2e- + 2H+ → 2Na+1I-
    *) O: I02 + 2NaOH + 4H2O → 2Na+1I+5O-23 + 10e- + 10H+
    R: I02 + 2NaOH + 2e- + 2H+ → 2Na+1I-1 + 2H2O
    4. *) (O: I02 + 2NaOH + 4H2O → 2Na+1I+5O-23 + 10e- + 10H+ )1
    (R: I02 + 2NaOH + 2e- + 2H+ → 2Na+1I-1 + 2H2O)5
    *) O: I02 + 2NaOH + 4H2O → 2Na+1I+5O-23 + 10e- + 10H+
    R: 5I02 + 10NaOH + 10e- + 10H+ → 10Na+1I-1 + 10H2O
    5. 6I02 + 12NaOH + 4H2O + 10e- + 10H+ → 2Na+1I+5O-23 + 10Na+1I-1 +
    10e- + 10H2O + 10H+
    6. 3I02 + 6NaOH → Na+1I+5O-23 + 5Na+1I-1 + 3H2O
    7. 6NaOH + 3I2 → 5NaI + NaIO3 + 3H2O

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