Caliche (Calcrete, Duricrust)
Caliche (Calcrete, Duricrust)
Caliche (Calcrete, Duricrust)
A soil that is mineralogically an impure limestone. Such soils are also known as duricrust, kunkar, nari,
kafkalla, Omdurman lime, croute, and race. Many soil profiles in semiarid climates (that is, those
characterized by a rainfall of 4–20 in. or 10–50 cm per year) contain concentrations of calcium
carbonate (CaCO3). This calcium carbonate is not an original feature of the soils but has been added
during soil formation either by direct precipitation in soil pores or by replacement of preexisting
material. Fossil analogs of caliche, which are widely reported in ancient sedimentary sequences, are
referred to as calcrete or cornstone. See also Limestone; Soil.
The principal control on the formation of caliche is a hydrologic regime in which there is sufficient
moisture to introduce calcium carbonate in solution to the soil but not enough to leach it through the
system. As a result, calcium carbonate precipitates in the soil during periods of evaporation, and it will
slowly increase in amount as long as the hydrologic setting remains stable. The source of the carbonate
may be from the dissolution of adjacent limestones, from the hydrolysis of plagioclase and other
silicates, or from carbonate loess.
Within the climatic constraints noted above, most caliche forms in river floodplains and near the surface
of alluvial fans. In addition, caliche deposits may form within exposed marine and lacustrine limestones
during periods of sea-level fall or lake desiccation. Caliche may also form at inert pediment (eroded
rock) surfaces; in the geological record such surfaces will be seen as unconformities. In this context it is
interesting that the first unconformity ever recognized as such, by James Hutton in 1787 on the Isle of
Arran, western Scotland, is characterized by a development of caliche. See also Unconformity.
The mineralogy of the host soil or rock in which a caliche develops may vary considerably; it is not
essential for there to be any preexisting carbonate grains within the regolith. The most favorable
medium is a clay-rich soil of limited permeability. Low permeability provides the residence time in the
soil pores necessary for calcite to precipitate. See also Calcite; Regolith.