SUCCESS POINT SCIENCE ACADEMY

Chemistry
Time : 1.30 hr XII - A Div Marks : 120

Some Basic Concept In Chemistry

1) Carbon and oxygen combine to form two oxides,

A) 5.57 × 1022 B) 0.62 × 1023
carbon monoxide and carbon dioxide in which the
ratio of the weights of carbon and oxygen is
respectively 12 : 16 and 12 : 32. These figures C) 5.0 × 1022 D) 6.2 × 1029
illustrate the
8) The number of significant figures in (0.04)2 +(0.25)2
is :
A) Law of multiple proportions
A) one B) two C) three D) four
B) Law of reciprocal proportions
9) gaseous mixture contains oxygen and nitrogen in
C) Law of conservation of mass the ratio of 1:4 by weight. Therefore, the ratio of
their number of molecules is
D) Law of constant proportions
A) 1:4 B) 1:8 C) 7:32 D) 3:16
2) From the following masses, the one which is
expressed nearest to the milligram is 10) Calculate to the correct number of significant
figures : 4.26-(15.635/5.0)
A) 16 g B) 16.4 g
A) 1.13 B) 1.2 C) 1.1 D) 1.133
C) 16.428 g D) 16.4284 g 11) The law of multiple proportions is illustrated by the
3) A sample of pure carbon dioxide, irrespective of its two compounds
source contains 27.27% carbon and 72.73%
oxygen. The data support A) Sodium chloride and sodium bromide

A) Law of constant composition B) Ordinary water and heavy water

B) Law of conservation of mass C) Caustic soda and caustic potash

C) Law of reciprocal proportions D) Sulphur dioxide and sulphur trioxide

12) The percentage of Se in peroxidase anhydrous

D) Law of multiple proportions enzyme is 0.5% by weight (atomic wt. = 78.4). Then
4) A sample of calcium carbonate (CaCO3 ) has the minimum molecular weight of peroxidase
following percentage composition : Ca= 40% ; C = anhydrous enzyme is
12% ; O = 48% If the law of constant proportions is
true, then the weight of calcium in 4 g of a sample A) 15.68 × 104 B) 1.568 × 103
of calcium carbonate obtained from another source
will be C) 15.68 D) 3.136 × 104

13) What is the molality of pure water?

A) 0.016 g B) 0.16 g

A) 1 B) 18
C) 1.6 g D) 16 g

5) 12g of Mg (at. mass 24) will react completely with C) 55.5 D) None of these
acid to give
14) The simplest formula of a compound containing
32.5% K, 0.839% H, 26.7% S and 39.9% O is
A) One mole of H2

A) KHSO4 B) KHSO3
B) 1/2 mole of H2

C) K2 SO4 .2H2 O D) KHSO2

C) 2/3 mole of O2
15) One litre of a gas at S.T.P. weighs 1.16 g. It can
D) Both 1/2 mol of H2 and 1/2 mol of O2 possibly b e :

6) How many times is a kg heavier than a mg ?

A) C2 H2 B) CO C) O2 D) CH4

A) 103 B) 105 C) 106 D) 109 16) Which has maximum number of atoms

7) The number of silver atoms present in a 90% pure

silver wire weighing 10 g is :
 A) 24 gms of C(12) B) 56 gms of Fe(56) A) 12 g of carbon combines with 32 g of oxygen
to form 44 g of CO2
C) 27 gms of Al(27) D) 108 gms of Ag(108)
B) When 12 g of carbon is heated in a vacuum
17) Given that the abundances of isotopes 54 Fe , 56 Fe there is no change in mass
and 57 Fe are 5%, 90% and 5% respectively, the
atomic mass of Fe is
C) A sample of air increases in volume when
heated at constant pressure but its mass
A) 55.85 B) 55.95 C) 55.75 D) 56.05. remains unaltered
18) The number of O3 molecules in 16 g of ozone is
approximately. D) The weight of a piece of platinum is the same
before and after heating in air
A) 2 × 1023 B) 3 × 1023 25) The distance of the sun from the earth is 93,000,000
miles. The number of significant figures is:
C) 4 × 1023 D) 6 × 1023
A) eight B) seven
19) Number of moles in 65.6 µ g of carbon is

C) two D) between 2 and 8.

A) 5.47 × 10−12 B) 5.47 × 10−6
26) What volume of Hydrogen gas, at 273 K and 1 atm
C) 5.47 × 10−8 D) 5.47 × 10−9 pressure will be consumed in obtaining 21.6 g of
elemental boron (atomic mass = 10.8) from the
20) An alloy of metals A and B contains atoms in the reduction of boron trichloride by Hydrogen
ratio of 2 : 5 and weighs 36 g. The percentage of
metal A in the sample is 22.22% (by mass). If
A) 22.4 L B) 89.6 L
atomic mass of A is 40, the atomic mass of metal B
is :
C) 67.2 L D) 44.8 L
A) 138 a.m.u B) 56 a.m.u 27) The volume occupied by 4.4 g of CO2 at STP is

C) 112 a.m.u. D) 72 a.m.u. A) 22.4 L B) 2.24 L

21) Volume of a gas at STP is 1.12 × 10−7 cc. Calculate
the number of molecules in it C) 0.224 L D) 0.1 L

28) Volume occupied by one molecule of water

A) 3.01 × 1020 B) 3.01 × 1012 (density=1g cm−3 ) is

C) 3.01 × 1023 D) 3.01 × 1024 A) 6.023 × 10−23 cm3 B) 3.0 × 10−23 cm3
22) The number of molecules in 100ml of 0.02N H2 SO4
is C) 5.5 × 10−23 cm3 D) 9.0 × 10−23 cm3

29) The total number of electrons present in 3.2 g of

A) 6.02 × 1022 B) 6.02 × 1021 methane :

C) 6.02 × 1020 D) 6.02 × 1018 A) 2 × 10 × 6.022 × 1022

23) 100 ml O2 and H2 kept at same temperature and
pressure. What is true about their number of B) 10 × 6.022 × 1023
molecules
C) 10 × 6.022 × 1022
A) NO2 > NH2
D) 6.022 × 1023
B) NO2 < NH2
30) Avogadro number 6.02 × 1023 of carbon atoms are
present in
C) NO2 = NH2
A) 12 grams of 12 CO2
D) NO2 + NH2 = 1 mole

24) Which of the following is the best example of law of B) 22.4 litre 12 CO2 at room temperature
conservation of mass
C) 44 grams of 12 CO2

D) 12 moles of 12 CO2
 Answer Sheet
Chemistry : Some Basic Concept In Chemistry
Total Questions : 30 Total Marks : 120

1 A 2 C 3 A 4 C 5 B 6 C 7 C 8 B 9 C 10 B 11 D 12 A
13 C 14 B 15 A 16 A 17 A 18 A 19 B 20 B 21 B 22 C 23 C 24 A
25 C 26 C 27 B 28 B 29 A 30 C
 Solution Sheet
Chemistry : Some Basic Concept In Chemistry
Total Questions : 30 Total Marks : 120

22.22
5) Mg+2 ≡ H2 20) Mass of A in alloy = = × 36 = 8.0g
12gm 1 100
n= = mole of H2 Mass of metal B = 36 − 8.0 = 28.0 g
24gm 2 No. of atoms of A in the sample
6) 1 kg = 103 g = 103 × 103 mg = 106 mg 6.0 × 1023 × 8
=
40
7) Amount of pure silver in 10 g wire Atoms of B in the sample
90 6.0 × 1023 × 8 5
= 10 × = 9g = ×
100 40 2
108 g of Ag contain atoms = 6 × 1023 Now mass of metal B = 28 g
9 g of Ag contain atoms 6.0 × 1023 × 8 × 5
atoms of metal B = 28 g
6 × 1023 40 × 2
= × 9 = 5 × 1022 23
6.0 × 10 atoms of metal B
108
28 × 40 × 2
8) (0.04)2 + (0.25)2 = 0.0016 + 0.0625 = × 6.0 × 1023 = 56
6.0 × 1023 × 8 × 5
= 2 × 10 - 3 + 62 × 10 - 3 Mass of 1 mole atoms = 56 g
(upto correct significant figures) ∴ Atomic mass of metal B = 56 a.m.u.
= 64 × 10 - 3
Number of significant figures = 2 21) ∵ 22400 cc of gas at STP has 6 × 1023 molecules
∴ 1.12 ×10−7 of gas at STP has
1 4
9) Molar ratio of O2 : N2 = : = 7 : 32 6 × 1023 × 1.12 × 10−7
32 28 = 0.03 × 1014 = 3 × 1012 .
22400
12) 0.5% by wt. means 0.5 g of Se is present in 100 g of
enzyme.
Since at least one atom of Se must be present in 22) Nomality = Molarity × Valency factor
the enzyme 0.02 = M × 2
and at. wt. of Se is 78.4, therefore, 1 gram atom of no.of moles
Molarity =
Se i.e. Volume in litre
n
78.4 g will be present in enzyme 0.01= = n=0.001
100 0.1
= × 78.4 = 1.568 × 104 g 1 mole H2 SO4 contains 6.023 × 1023 molecules
0.5 So, 0.001 mole contains 6.023 × 1020 molecules.
∴ Minimum molecular wt. of enzyme
= 15.68 × 104 23) This is Avogadro"s hypothesis. According to this,
14) Formula of compound = KHSO3 equal volume of all
gases contain equal no. of molecules under similar
15) 1 L of gas weighs = 1.16 g condition of
22.4 L of gas weigh = 1.16 × 22.4 = 26 temperature and pressure.
Molecular weight of gas = 26
It can be possibly C2 H2 25) The last zeros are not significant unless the
uncertainty is mentioned.
16) 12 g. of Carbon= 6.023 × 1023
6.023 × 1023 26) BCl3 + 3[H] → B + 3HCl
24 g. of Carbon= × 24 3 21.6
12 BCl3 + H2 → B + 3HCl; B = = 2mole
23
= 6.023 × 10 . 2 10.8
3
But 56gm, 27gm. and 108gm of Fe, Al and Ag B ≡ H2
2
respectively contains 3
same no. (Avogadros number) of atoms 1mole ≡ mole ; 2 mole – 3 mole
2
textbf V = 3 × 22.4 = 67.2L.
17) Atomic mass of Fe
5 × 54 + 90 × 56 + 5 × 57 27) 44g CO2 occupies 22.4L at STP
=
100 22.4
270 + 5040 + 285 4.4g CO2 occupies = × 4.4= 2.24L.
= 44
100
=55.85 28) 1000g of H2 O =1000 cm3

18) 48 g of O3 contain molecules =6.02 × 1023

16 g of O3 contain molecules
6.02 × 1023
= × 16 = 2 × 1023
48