Multi 3430

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Operating manual

Multi 3430

pH

Digital pH / dissolved oxygen /


conductivity meter
for 3 digital IDS sensors

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Multi 3430

Accuracy when The use of advanced technology and the high quality standard of our instru-
going to press ments are the result of a continuous development. This may result in differ-
ences between this operating manual and your meter. Also, we cannot
guarantee that there are absolutely no errors in this manual. Therefore, we
are sure you will understand that we cannot accept any legal claims resulting
from the data, figures or descriptions.

Copyright © Weilheim 2010, WTW GmbH


Reproduction in whole - or even in part - is prohibited without the express writ-
ten permission of WTW GmbH, Weilheim.
Printed in Germany.

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Multi 3430 Contents

Multi 3430 - Contents

1 Overview . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 7
1.1 Keypad . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 8
1.2 Display . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 9
1.3 Socket field . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 11
1.4 Automatic sensor recognition . . . . . . . . . . . . . . . . . . . . . 12
1.5 IDS sensors. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 12

2 Safety . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 15
2.1 Authorized use . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 16
2.2 General safety instructions . . . . . . . . . . . . . . . . . . . . . . . 16

3 Commissioning . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 19
3.1 Scope of delivery. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 19
3.2 Power supply. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 19
3.3 Initial commissioning . . . . . . . . . . . . . . . . . . . . . . . . . . . . 19
3.3.1 Inserting the rechargeable batteries. . . . . . . . . . 19
3.3.2 Connecting the power pack / charging the
batteries ............................ 20
3.3.3 Switching on the meter. . . . . . . . . . . . . . . . . . . . 21
3.3.4 Setting the date and time . . . . . . . . . . . . . . . . . 21

4 Operation . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 23
4.1 Switching on the meter . . . . . . . . . . . . . . . . . . . . . . . . . . 23
4.2 General operating principles . . . . . . . . . . . . . . . . . . . . . . 24
4.2.1 Operating modes . . . . . . . . . . . . . . . . . . . . . . . . 24
4.2.2 Display of several sensors in the measuring mode
25
4.2.3 Navigation . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 26
4.2.4 Example 1 on navigation: Setting the language. 28
4.2.5 Example 2 on navigation: Setting the date and
time . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 30
4.3 Sensor-independent settings . . . . . . . . . . . . . . . . . . . . . 32
4.3.1 System . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 32
4.3.2 Data storage. . . . . . . . . . . . . . . . . . . . . . . . . . . . 34
4.3.3 Automatic Stability control . . . . . . . . . . . . . . . . . 34
4.4 Sensor info . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 34
4.5 Channel display. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 35
4.6 pH value . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 36
4.6.1 General information . . . . . . . . . . . . . . . . . . . . . . 36
4.6.2 Measuring the pH value . . . . . . . . . . . . . . . . . . . 37

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Contents Multi 3430

4.6.3 Settings for pH measurements . . . . . . . . . . . . . . 39


4.6.4 pH calibration . . . . . . . . . . . . . . . . . . . . . . . . . . . 41
4.6.5 Calibration interval . . . . . . . . . . . . . . . . . . . . . . . 46
4.6.6 Carrying out an automatic calibration (AutoCal) . 47
4.6.7 Carrying out a manual calibration (ConCal) . . . . 51
4.6.8 Displaying calibration records . . . . . . . . . . . . . . . 53
4.6.9 Continuous measurement control (CMC
function) ............................. 55
4.6.10 QSC function (sensor quality control) . . . . . . . . . 56
4.7 ORP voltage . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 59
4.7.1 General information . . . . . . . . . . . . . . . . . . . . . . 59
4.7.2 Measuring the ORP . . . . . . . . . . . . . . . . . . . . . . 59
4.7.3 Settings for ORP measurements . . . . . . . . . . . . 61
4.8 Dissolved oxygen. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 62
4.9 Conductivity . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 63
4.9.1 General information . . . . . . . . . . . . . . . . . . . . . . 63
4.9.2 Measuring . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 63
4.9.3 Temperature compensation . . . . . . . . . . . . . . . . 66
4.9.4 Settings for IDS conductivity sensors . . . . . . . . . 67
4.9.5 Determining the cell constant
(calibration in control standard) . . . . . . . . . . . . . 70
4.9.6 Displaying calibration records . . . . . . . . . . . . . . . 72
4.10 Data storage . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 73
4.10.1 Manual storage . . . . . . . . . . . . . . . . . . . . . . . . . . 74
4.10.2 Automatic storage at intervals ............ 75
4.10.3 Editing the measurement data storage. . . . . . . . 77
4.10.4 Erasing the measurement data storage . . . . . . . 78
4.11 Transmitting data (USB interfaces) . . . . . . . . . . . . . . . . . 79
4.11.1 Outputting current measurement data . . . . . . . . 79
4.11.2 Transmitting data (to a PC). . . . . . . . . . . . . . . . . 79
4.11.3 Connecting the PC / USB-B interface (USB
Device) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 79
4.11.4 Connecting the USB memory device / USB-A
interface (USB Host) ................... 80
4.11.5 Options for data transmission . . . . . . . . . . . . . . . 81
4.12 Reset . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 82
4.12.1 Resetting the measurement settings . . . . . . . . . 82
4.12.2 Resetting the system settings . . . . . . . . . . . . . . . 84

5 Maintenance, cleaning, disposal . . . . . . . . . . . . . . . . . 85


5.1 Maintenance . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 85
5.1.1 Replacing the rechargeable batteries . . . . . . . . . 85
5.2 Cleaning. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 86
5.3 Packing . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 86
5.4 Disposal . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 86

6 What to do if... . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 87

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Multi 3430 Contents

6.1 General information. . . . . . . . . . . . . . . . . . . . . . . . . . . . . 87


6.2 pH . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 88
6.3 Conductivity. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 90

7 Technical data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 91
7.1 General data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 91
7.2 Measuring ranges, resolution, accuracy . . . . . . . . . . . . . 92

8 Lists . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 93

9 Appendix: Firmware update. . . . . . . . . . . . . . . . . . . . . 97

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Contents Multi 3430

6 ba75865de01 02/2010
Multi 3430 Overview

1 Overview
The compact, digital precision meter Multi 3430 enables you to carry
out pH measurements, ORP measurements, conductivity measure-
ments and dissolved oxygen (D.O.) measurements quickly and reliably.
The Multi 3430 provides the maximum degree of operating comfort,
reliability and measuring certainty for all applications.

The Multi 3430 supports you in your work with the following functions:
z proven calibration procedures
z automatic stability control (AR),
z automatic sensor recognition,
z CMC (continuous measurement control)
z QSC (sensor quality control).

pH

1 Keypad
2 Display
3 Socket field

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Overview Multi 3430

The two USB interfaces (USB-A and USB-B) enable you to:
z Transmit data to
– a USB memory device
– a PC
z Update the meter firmware.

1.1 Keypad

F1 F2

CAL AR

PRT STO RCL ESC

MENU
ENTER

Multi 3430

In this operating manual, keys are indicated by brackets <..> .


The key symbol (e.g. <MENU/ENTER>) generally indicates a short
keystroke (under 2 sec) in this operating manual. A long keystroke
(approx. 2 sec) is indicated by the underscore behind the key symbol
(e.g. <MENU/ENTER >). _
F1 <F1>: Softkeys providing situation dependent functions, e.g.:
<F2>: <F1>/[Info]: View information on a sensor
F2

<On/Off>: Switches the meter on or off

<MODE>: Selects the measured parameter

<CAL>: Calls up the calibration procedure


CAL
<CAL >:_ Displays the calibration data

AR
<AR> Freezes the measured value (HOLD function)
Switches the AutoRead measurement on or off

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Multi 3430 Overview

<STO>: Saves a measured value manually


_
<STO >: Opens the menu for the automatic save function
<RCL>: Displays the manually stored measured values
<RCL_>: Displays the automatically stored measured values

<S><T>: Menu control, navigation


<W><X>:

<MENU/ENTER>: Opens the menu for measurement settings / Confirms


MENU
ENTER
<MENU/ENTER >:_ entries
Opens the menu for system settings
<PRT> Outputs stored data to the interface
PRT
_
<PRT > Outputs displayed data to the interface in intervals

1.2 Display

3 4
5

7
1
22.09.2009 08:00
Info 8
1 Status information
2 Measured value (with unit)
3 Measured parameter
4 Continuous measurement control (CMC function)
5 Channel display:
Plug position of the sensor
6 Sensor symbol (calibration evaluation, calibration interval)
7 Measured temperature (with unit)
8 Softkeys and date + time

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Overview Multi 3430

Function display AutoCal Calibration with automatic buffer recognition, e.g.


indicators e.g. TEC with the buffer set: Technical buffers
ConCal Calibration with any buffers
Error An error occurred during calibration
AR Stability control (AutoRead) is active
HOLD Measured value is frozen (<AR> key)
Batteries are almost empty
Mains operation with charging function
The batteries are automatically charged in the back-
ground.
Mains operation

Data are automatially output to the USB-B interface


at intervals
Data are output to the USB-A interface (USB flash
drive)
Power supply via the USB-B interface
Batteries are not being charged

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Multi 3430 Overview

1.3 Socket field

5 1 2 3 4

Connectors:
1 Digital sensors
(pH, ORP, conductivity, D.O.)
2 Power pack
3 USB-A (Host) interface
4 USB B (Device) interface
5 Service interface

CAUTION
Only connect sensors to the meter that cannot return any voltages
or currents that are not allowed (> SELV and > current circuit with
current limiting).
WTW IDS sensors meet these requirements.

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Overview Multi 3430

1.4 Automatic sensor recognition


The automatic sensor recognition for IDS sensors allows
z to operate an IDS sensor at different meters without recalibration
z to operate different IDS sensors at one meter without recalibration
z to assign measurement data to an IDS sensor
– Measurement datasets are always stored and output with the
sensor name and sensor series number.
z to assign calibration data to an IDS sensor
– Calibration data and calibration history are always stored and
output with the sensor name and sensor series number.
z to activate the correct cell constant for conductivity sensors auto-
matically
z to hide menus automatically that do not concern this sensor

To be able to use the automatic sensor recognition, a meter that sup-


ports the automatic sensor recognition (e.g. Multi 3430) and a digital
IDS sensor are required.

In digital IDS sensors, sensor data are stored that clearly identify the
sensor.
The sensor data are automatically taken over by the meter.

1.5 IDS sensors


IDS sensors
z support the automatic sensor recognition
z show only the settings relevant to the specific sensor in the setting
menu
z process signals in the sensor digitally so that precise and interfer-
ence-free measurements are enabled even with long cables
z facilitate to assign a sensor to a measured parameter with differently
colored couplings
z have quick-lock couplings with which to fix the sensors to the meter.

Note
Information on available IDS sensors is given on the Internet and in
the WTW catalog, "Laboratory and field instrumentation".

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Multi 3430 Overview

Sensor data from IDS IDS sensors transmit the following sensor data to the meter:
sensors z SENSOR ID
– Sensor name
– Sensor series number
z Calibration data
– Calibration date
– Calibration characteristics
– Calibration interval
– Selected buffer set (IDS pH sensors only)
– Cell constant (IDS conductivity sensors only)
– Calibration history of the last 10 calibrations
z Measurement settings (IDS conductivity sensors only)
– The set measured parameter
– The set reference temperature
– The set temperature coefficient
– The set TDS factor

The calibration data are updated in the IDS sensor after each calibra-
tion procedure. A message is displayed while the data are being
updated in the sensor.

Note
In the measured value display, you can display the sensor name and
series number of the selected sensor with the [Info] softkey. You can
then display all further sensor data stored in the sensor with the [Plus]
softkey.

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Overview Multi 3430

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Multi 3430 Safety

2 Safety
This operating manual contains basic instructions that you must follow
during the commissioning, operation and maintenance of the meter.
Consequently, all responsible personnel must read this operating man-
ual before working with the meter.
The operating manual must always be available within the
vicinity of the meter.

Target group The meter was developed for work in the field and in the laboratory.
Thus, we assume that, as a result of their professional training and
experience, the operators will know the necessary safety precautions
to take when handling chemicals.

Safety instructions Safety instructions in this operating manual are indicated by the warn-
ing symbol (triangle) in the left column. The signal word (e.g. "Caution")
indicates the level of danger:

WARNING
indicates instructions that must be followed precisely in order to
avoid possibly great dangers to personnel.

CAUTION
indicates instructions that must be followed precisely in order to
avoid the possibility of slight injuries or damage to the meter or
the environment.

Further notes
Note
indicates notes that draw your attention to special features.

Note
indicates cross-references to other documents, e.g. operating manu-
als.

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Safety Multi 3430

2.1 Authorized use


The authorized use of the meter consists exclusively of the measure-
ment of the pH, ORP, conductivity and dissolved oxygen in a field and
laboratory environment.
The technical specifications as given in chapter 7 TECHNICAL DATA must
be observed. Only the operation and running of the meter according to
the instructions given in this operating manual is authorized.
Any other use is considered unauthorized.

2.2 General safety instructions


This meter is constructed and tested in compliance with the IEC 1010
safety regulations for electronic measuring instruments.
It left the factory in a safe and secure technical condition.

Function and The smooth functioning and operational safety of the meter can only be
operational safety guaranteed if the generally applicable safety measures and the specific
safety instructions in this operating manual are followed during opera-
tion.

The smooth functioning and operational safety of the meter can only be
guaranteed under the environmental conditions that are specified in
chapter 7 TECHNICAL DATA.

If the meter was transported from a cold environment to a warm envi-


ronment, the formation of condensate can lead to the faulty functioning
of the meter. In this event, wait until the temperature of the meter
reaches room temperature before putting the meter back into opera-
tion.

CAUTION
The meter is only allowed to be opened by authorized personnel.

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Multi 3430 Safety

Safe operation If safe operation is no longer possible, the meter must be taken out of
service and secured against inadvertent operation!
Safe operation is no longer possible if the meter:
z has been damaged in transport
z has been stored under adverse conditions for a lengthy period of
time
z is visibly damaged
z no longer operates as described in this manual.

If you are in any doubt, please contact the supplier of the meter.

Obligations of the The purchaser of this meter must ensure that the following laws and
purchaser guidelines are observed when using dangerous substances:
z EEC directives for protective labor legislation
z National protective labor legislation
z Safety regulations
z Safety datasheets of the chemical manufacturers.

CAUTION
In addition to the safety instructions mentioned here, also follow
the safety instructions of the sensors used.
The operating manuals of the sensors are available on the sup-
plied CD and on the Internet under www.WTW.com.

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Safety Multi 3430

18 ba75865e04 02/2010
Multi 3430 Commissioning

3 Commissioning
3.1 Scope of delivery
z Meter Multi 3430
z 4 NiMH rechargeable batteries 1.2 V Mignon type AA
z USB cable (A plug on mini B plug)
z Power pack
z Short instructions
z Detailed operating manual (4 languages)
z CD-ROM

3.2 Power supply


The Multi 3430 is supplied with power in the following ways:
z Battery operation with NiMh rechargeable batteries
z Mains operation with the supplied power pack.
The NiMh rechargeable batteries are automatically charged while
the power pack is connected.
z USB operation via a connected USB-B cable.
The inserted NiMh rechargeable batteries are not charged

3.3 Initial commissioning


Perform the following activities:
z Insert the rechargeable batteries and charge them
z Connect the power pack (mains operation / battery charging)
z Switch on the meter
z Set the date and time

3.3.1 Inserting the rechargeable batteries

1 Unscrew the two screws (1) on the underside of the meter.


2 Open the battery compartment (2) on the underside of the
meter.

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Commissioning Multi 3430

3 Place four rechargeable batteries (type Mignon AA) in the bat-


tery compartment.

CAUTION
Make sure that the poles of the rechargeable batteries are posi-
tioned correctly.
The ± signs on the batteries must correspond to the ± signs in the
battery compartment.

4 Close the battery compartment (2) and tighten the screws (1).

3.3.2 Connecting the power pack / charging the batteries

CAUTION
The line voltage at the operating site must lie within the input volt-
age range of the original power pack (see section 7.1).

CAUTION
Use original power packs only (see section 7.1).

CAUTION
The batteries in the battery compartment are automatically
charged when the power pack is connected.
Make sure that only NiMH rechargeable batteries are in the battery
compartment. The charging process is optimized for NiMH re-
chargeable batteries. Other battery types can cause damage dur-
ing the charging process.

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Multi 3430 Commissioning

1 Connect the plug of the power pack to the socket for the power
pack on the Multi 3430.
2 Connect the original power pack to an easily accessible power
outlet.

With mains operation, one of the following symbols is displayed:

: Mains operation with charging function


The batteries are automatically charged in the background.
: Mains operation

Note
Charge the batteries completely prior to putting the meter into operation
for the first time. The charging process takes approx. 10 hours. The
symbol is displayed if the batteries are nearly discharged.

3.3.3 Switching on the meter

1 Press the <On/Off> key.


The meter performs a self-test.
The display shows the manufacturer's logo while the self-test
is being performed.
2 Connect the sensor.
The meter switches to the measuring mode (measured value
display).

Note
The meter has an energy saving feature to avoid unnecessary power
consumption during battery operation.
The energy saving feature switches off the meter during battery opera-
tion if no key is pressed during the adjusted interval. (How to set the
switch-off interval, see section 4.3).
The switch-off interval of the energy saving feature is not active when
the meter is supplied with power via the power pack or the USB-B
cable.

3.3.4 Setting the date and time

3 See section 4.2.5

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Commissioning Multi 3430

22 ba75865e04 02/2010
Multi 3430 Operation

4 Operation
4.1 Switching on the meter
Switching on Press the <On/Off> key.
The meter performs a self-test.
The display shows the manufacturer's logo while the self-test is being
performed.
If a sensor is connected the measured value display appears.

Info 30.09.2009 08:00

Switching off Press the <On/Off> key.

Automatic switch-off The instrument has an automatic switchoff function in order to save the
batteries (see section 4.3.1). The automatic switchoff switches off the
measuring instrument if no key is pressed for an adjustable period.

The automatic switchoff is not active


z if the power pack is connected
z if a USB-B cable is connected
z if the Autom. Speichern function is active, or with automatic data
transmission

Display illumination The meter automatically switches the display illumination to energy
saving mode if no key is pressed for 20 seconds.
After a further 60 seconds, the meter switches off the display illumina-
tion completely.
The illumination is switched on with the next keystroke again.

You can also generally switch on the display illumination (see section
4.3.1).

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Operation Multi 3430

4.2 General operating principles


This section contains basic information on the operation of the
Multi 3430.

Operating elements, An overview of the operating elements and the display is given in sec-
display tion 1.1 and section 1.2.

Operating modes, An overview of the operating modes and navigation of the Multi 3430 is
navigation given in section 4.2.1 and section 4.2.3.

4.2.1 Operating modes

The meter has the following operating modes:


z Measuring
The measurement data of the connected sensors is shown in the
measured value display
z Calibration
The course of a calibration with calibration information, functions
and settings is displayed
z Storage in memory
The meter stores measuring data automatically or manually
z Data transmission
The meter transmits measuring data and calibration records to a
USB-B interface automatically or manually.
z Setting
The system menu or a sensor menu with submenus, settings and
functions is displayed

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Multi 3430 Operation

4.2.2 Display of several sensors in the measuring mode

The measured values of the connected sensors can be displayed in the


following ways:
z Clear display of all connected sensors
z Detailed display of one sensor
(e.g. incl. CMC feature with pH sensors)

With the softkey you can very easily switch between the two display
types. The suitable softkey is displayed depending on the operating sit-
uation.

Info 30.09.2009 08:00 Info 30.09.2009 08:00

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Operation Multi 3430

4.2.3 Navigation

Measured value display In the measured value display, you can


z use <S><T> to select one of several connected sensors. The
selected sensor is displayed with a colored background.
The following actions / menus refer to the selected sensor
z open the menu for calibration and measurement settings with
<MENU/ENTER> (short keystroke)
z open the Storage & config menu with the sensor-independent set-
_
tings by pressing <MENU/ENTER > (long keystroke, approx. 2 s).
z change the display in the selected measuring window (e. g. pH <−>
mV) by pressing <MODE>.

Menus and dialogs The menus for settings and dialogs in procedures contain further sub-
menus. The selection is made with the <S><T> keys. The current
selection is displayed with a frame.
z Submenus
The name of the submenu is displayed at the upper edge of the
frame. Submenus are opened by confirming with <MENU/ENTER>.
Example:

System
General
Interface
Clock function
Service information
Reset

22.09.2009 08:00

z Settings
Settings are indicated by a colon. The current setting is displayed on
the right-hand side. The setting mode is opened with <MENU/
ENTER>. Subsequently, the setting can be changed with <S><T>
and <MENU/ENTER>. Example:

26 ba75865e04 02/2010
Multi 3430 Operation

General
Language: Deutsch
Acoustic signal: Off
Volume 9
Illumination: On
Brightness: 12
Switchoff time: 1h
Temperature unit °C
Stability control On

22.09.2009 08:00

z Functions
Functions are designated by the name of the function. They are
immediately carried out by confirming with <MENU/ENTER>. Exam-
ple: Display the Calibration record function.

pH
Calibration record
Calibration data storage
Buffer: TEC
Single-point calibration: Yes
Calibration interval: 7d
Unit for slope: mV/pH

[i] 2.00 4.01 7.00 10.01

22.09.2009 08:00

Messages Information is marked by the [i] symbol. They cannot be selected.


Example:

pH
Calibration record:
Calibration data storage
Buffer: TEC
Single-point calibration: Yes
Calibration interval: 7d
Unit for slope: mV/pH

[i] 2.00 4.01 7.00 10.01

22.09.2009 08:00

Note
The principles of navigation are explained in the two following sections
by reference of examples:
z Setting the language (section 4.2.4)
z Setting the date and time (see section 4.2.5).

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Operation Multi 3430

4.2.4 Example 1 on navigation: Setting the language

1 Press the <On/Off> key.


The measured value display appears.
The instrument is in the measuring mode.

Info 30.09.2009 08:00

2 Open the Storage & config menu with <MENU/ENTER _>.


The instrument is in the setting mode.

Storage & config


System
Data storage

22.09.2009 08:00

3 Select the System submenu with <S><T>.


The current selection is displayed with a frame.
4 Open the System submenu with <MENU/ENTER>.

28 ba75865e04 02/2010
Multi 3430 Operation

System
General
Interface
Clock function
Service information
Reset

22.09.2009 08:00

5 Select the General submenu with <S><T>.


The current selection is displayed with a frame.
6 Open the General submenu with <MENU/ENTER>.

General
Language: Deutsch
Acoustic signal: Off
Illumination: On
Kontrast: 50 %
Switchoff time: 1h

22.09.2009 08:00

7 Open the setting mode for the Language with <MENU/


ENTER>.

General
Language: Deutsch
Acoustic signal: Off
Illumination: On
Brightness: 50 %
Switchoff time: 1h

22.09.2009 08:00

ba75865e04 02/2010 29
Operation Multi 3430

8 Select the required language with <S><T>.


9 Confirm the setting with <MENU/ENTER>.
The meter switches to the measuring mode.
The selected language is active.

4.2.5 Example 2 on navigation: Setting the date and time

The measuring instrument has a clock with a date function. The date
and time are indicated in the status line of the measured value display.
When storing measured values and calibrating, the current date and
time are automatically stored as well.

The correct setting of the date and time and date format is important for
the following functions and displays:
z Current date and time
z Calibration date
z Identification of stored measured values.

Therefore, check the time at regular intervals.

Note
After a fall of the supply voltage (empty batteries), the date and time are
reset to 01.08.2009 00, 00:00 hours.

Setting the date, time The date format can be switched from the display of day, month, year
and date format (dd.mm.yy) to the display of month, day, year (mm/dd/yy or mm.dd.yy).

1 In the measured value display:


Open the Storage & config menu with <MENU/ENTER _>.
The instrument is in the setting operating mode.
2 Select and confirm the System / Clock function menu with
<S><T> and <MENU/ENTER>.
The setting menu for the date and time opens up.

30 ba75865e04 02/2010
Multi 3430 Operation

Clock function
Date format: dd.mm.yy
Date: 30.09.2009
Time: 14:53:40

22.09.2009 08:00

3 Select and confirm the Time menu with <S><T> and <MENU/
ENTER>.
The hours are highlighted.
4 Change and confirm the setting with <S><T> and <MENU/
ENTER>.
The minutes are highlighted.
5 Change and confirm the setting with <S><T> and <MENU/
ENTER>.
The seconds are highlighted.
6 Change and confirm the setting with <S><T> and <MENU/
ENTER>.
The time is set.
7 If necessary, set the Date and Date format. The setting is made
similarly to that of the time.
8 If necessary, select and set the Date with <S><T> and
<MENU/ENTER>.
9 To make further settings, switch to the next higher menu level
with <ESC>.
or
Switch to the measured value display with <MODE>.
The instrument is in the measuring operating mode.

ba75865e04 02/2010 31
Operation Multi 3430

4.3 Sensor-independent settings


The Storage & config menu includes the following settings:
z System (see section 4.3.1).
z Data storage (see section 4.3.2)

4.3.1 System

Overview The following sensor-independent meter characteristics can be


adjusted in the Storage & config/System menu:
z Menu language
z Beep on keystroke
z Loudness of the beep
z Illumination
z Brightness
z Interval of the automatic switchoff
z Data interface
z Clock and date function
z Reset of all sensor-independent system settings to the default con-
dition

Settings To open the Storage & config menu, press the <MENU/ENTER > key _
in the measured value display. After completing the settings, switch to
the measured value display with <MODE>.
Default settings are printed in bold.

Menu item Setting Description


System / General / Language Deutsch Selects the menu language
English
(further)
System / General / Acoustic signal Beep 1 Selects/switches off the beep
Beep 2 on keystroke
Off
System / General / Volume 0 ... 5 ... 10 Changes the loudness of the
signal tone
System / General / Illumination Auto Switches the display illumina-
On tion on/off
System / General / Brightness 0 ... 10 ... 22 Changes the display bright-
ness
System / General / Switchoff time 10 min ... 1h ... 24 h Adjusts the switch-off time

32 ba75865e04 02/2010
Multi 3430 Operation

Menu item Setting Description


System / General / Temperature °C Temperature unit,
unit °F degrees Celsius or degrees
Fahrenheit.
All temperatures are displayed
with the selected unit.
System / General / Stability control On Switches on or off the auto-
Off matic stability control during
measurement (see section
4.3.3)
System / Interface / USB Host On Switches on or off the USB
Off Host interface.
You can switch off the power
supply of the USB Host inter-
face to extend the operating
time of the batteries.
The USB Host interface has to
be switched on in order to
transfer data to a USB memory
device.
System / Interface / Baud rate 1200, 2400, 4800, Baud rate of the USB Device
9600, 19200 interface
System / Interface / Output format ASCII Output format for data trans-
CSV mission
For details, see section 4.11
System / Interface / Decimal sepa- Dot (xx.x) Decimal separator
rator Comma (xx,x)
System / Interface / Output header Output of a header for Output
format: CSV
System /Clock function Date format Settings of time and date.
Date For details, see section 4.2.5
Time
System /Service information Hardware version and software
version of the meter are dis-
played.
System /Reset - Resets the system settings to
the default values.
For details, see section 4.12.2

ba75865e04 02/2010 33
Operation Multi 3430

4.3.2 Data storage

This menu contains all functions to display, edit and erase stored mea-
sured values.

Note
Detailed information on the storage functions of the Multi 3430 is given
in section 4.8.

4.3.3 Automatic Stability control

The automatic Stability control (AutoRead) function continuously


checks the stability of the measurement signal. The stability has a con-
siderable impact on the reproducibility of measured values.

You can activate or switch off the automatic Stability control function
(see section 4.6.3).

The measured parameter flashes on the display


z as soon as the measured value is outside the stability range
z when you switch over between the measured parameters with
<MODE>.
z when the automatic Stability control is switched off.

4.4 Sensor info


You can display the current sensor data and sensor settings of a con-
nected sensor at any time. The sensor data are available in the mea-
sured value display with the [Info] softkey.

Info 30.09.2009 08:00

1 In the measured value display:


Display the sensor data (sensor name, series number) with
[Info].

34 ba75865e04 02/2010
Multi 3430 Operation

SenTix 940
B092500013
More 30.09.2009 08:00

2 Display further sensor data (settings) with [More].

SenTix 940
B092500013
Man. temperature: 25°C
pH resolution 0.001
mV resolution 0.1
Buffer TEC
Calibration interval 7d
Unit for slope mV/pH
QSC:

30.09.2009 08:00

4.5 Channel display


The Multi 3430 manages the connected sensors and displays which
sensor is plugged to which connection.

Channel display
Display of the plug position
for the respective parameter
The red bar indicates for
each connected sensor to
which plug position of the
meter it is connected.

Info 30.09.2009 08:00

ba75865e04 02/2010 35
Operation Multi 3430

4.6 pH value

4.6.1 General information

You can measure the following variables:


z pH value [ ]
z Sensor voltage [mV]

Note
The sensor connection and the USB-B (device) interface are galvani-
cally isolated. This facilitates interference-free measurements also in
the following cases:
z Measurement in grounded test samples
z Measurement with several sensors connected to one Multi 3430 in
one test sample

Temperature For reproducible pH measurements, it is essential to measure the tem-


measurement perature of the test sample.
IDS sensors measure the temperature with a temperature sensor inte-
grated in the IDS sensor.

Preparatory activities Perform the following preparatory activities when you want to measure:

1 Connect the IDS pH sensor to the meter.


The pH measuring window is displayed.
2 If necessary, select the measured parameter with <MODE>.
3 If necessary, calibrate or check the IDS pH sensor.

36 ba75865e04 02/2010
Multi 3430 Operation

4.6.2 Measuring the pH value

1 Perform the preparatory activities according to section 4.6.1.


2 Immerse the IDS pH sensor in the test sample.

Info 30.09.2009 08:00

3 Select the pH or mV display with <MODE>.

Stability control The stability control function (AutoRead) continually checks the stability
(AutoRead ) of the measurement signal. The stability has a considerable impact on
the reproducibility of measured values. The display of the measured
parameter flashes until a stable measured value is available.
You can start the Stability control manually at any time, irrespective of
the setting for automatic Stability control (see page 34) in the Measure-
ment menu.

1 Freeze the measured value with <AR>.


The [HOLD] status indicator is displayed.
2 Using <MENU/ENTER>, activate the Stability control function
manually.
The [AR] status indicator appears while the measured value is
assessed as not stable. A progress bar is displayed and the
display of the measured parameter flashes.
The [HOLD][AR] status indicator appears as soon as a stable
measured value is recognized. The progress bar disappears
and the display of the measured parameter stops flashing.
The current measurement data is output to the interface. Mea-
surement data meeting the stability control criterion is marked
by AR.

ba75865e04 02/2010 37
Operation Multi 3430

Note
You can prematurely terminate the Stability control function manually
with <MENU/ENTER> at any time. If the Stability control function is pre-
maturely terminated, the current measurement data are output to the
interface without the AutoRead info.

3 Release the frozen measured value again with <AR> or


<MODE>.
The [AR] status display disappears. The display switches back
to the previous indication.

Criteria for a stable The Stability control function checks whether the measured values are
measured value stable within the monitored time interval.

Measured Time interval Stability in the time interval


parameter
pH value 15 seconds Δ pH: Better than 0.01

Temperature 15 seconds Δ T (° C): Better than 0.02

The minimum duration until a measured value is assessed as stable is


the monitored time interval. The actual duration is mostly longer.

38 ba75865e04 02/2010
Multi 3430 Operation

4.6.3 Settings for pH measurements

Overview The following settings are possible for pH measurements:


z Resolution
z Calibration interval
z Buffers for calibration
z Automatic stability control
z Unit for slope
z Calibration record (display)

Settings The settings are made in the menu for calibration and measurement
settings of the pH/ORP measurement. To open the settings, display the
required measured parameter in the measured value display and press
the <MENU/ENTER> key. After completing the settings, switch to the
measured value display with <MODE>.
Default settings are printed in bold.

Menu item Possible set- Description


ting
Calibration /Calibra- - Displays the calibration
tion record record of the last calibration.
Calibration /Buffer TEC Buffer sets to be used for pH
NIST/DIN calibration.
ConCal For further buffers and
... details, see section 4.6.4.
Calibration /Single- Yes Quick calibration with 1 buf-
point calibration No fer
Calibration /Calibra- 1 ... 7 ... 999 d Calibration interval for the
tion interval IDS pH sensor (in days).
The meter reminds you to
calibrate regularly by the
flashing sensor symbol in
the measuring window.
Calibration /Unit for mV/pH Unit of the slope.
slope % The % display refers to the
Nernst slope of
-59.2 mV/pH (100 x deter-
mined slope/Nernst slope).
Calibration /Calibra- Displays the last calibration
tion data storage records (max. 10)
Man. temperature -25 ... +25 ... Entry of the manually deter-
+130 °C mined temperature.

ba75865e04 02/2010 39
Operation Multi 3430

Menu item Possible set- Description


ting
pH resolution 0.001 Resolution of the pH display
0.01
0.1
mV resolution 0.1 Resolution of the mV dis-
1 play

Reset - Resets all sensor settings to


the delivery condition (see
section 4.12.1).
QSC /First calibra- Starts the initial calibration
tion with QSC buffers.
This menu item is only avail-
able as long as no initial cal-
ibration was carried out with
the connected IDS sensor.
QSC /Record of first Displays the calibration
calibration record of the QSC initial cal-
ibration.
QSC /Control cali- Starts the control calibration
bration with QSC buffers.
This menu item is only avail-
able if an initial calibration
was carried out with the con-
nected IDS sensor.

40 ba75865e04 02/2010
Multi 3430 Operation

4.6.4 pH calibration

Why calibrate? During the operation of a pH sensor, the slope and asymmetry of the
sensor change with time. As a result, an inexact measured value is dis-
played. Calibration determines the current values of the zero point and
slope of the pH sensor and stores them in the measuring instrument.
Thus, you should calibrate at regular intervals.

When do you have to z When the calibration interval has expired


calibrate?

Buffer sets for You can use the buffer sets quoted in the table for an automatic calibra-
calibration tion. The pH values are valid for the specified temperature values. The
temperature dependence of the pH values is taken into consideration
during the calibration.

No. Buffer set * pH values at


1 ConCal Any Any
2 NIST/DIN 1.679 25 °C
DIN buffers according to DIN 19266 4.006
and NIST Traceable Buffers 6.865
9.180
12.454
3 TEC 2.000 25 °C
WTW Technical buffers 4.010
7.000
10.011
4 Merck 1* 4.000 20°C
7.000
9.000
5 Merck 2 * 1.000 20°C
6.000
8.000
13.000
6 Merck 3 * 4.660 20°C
6.880
9.220
7 Merck 4 * 2.000 20°C
4.000
7.000
10.000
8 Merck 5 * 4.010 25 °C
7.000
10.000

ba75865e04 02/2010 41
Operation Multi 3430

No. Buffer set * pH values at


9 DIN 19267 1.090 25 °C
4.650
6.790
9.230
10 Mettler Toledo US * 1.679 25 °C
4.003
7.002
10.013
11 Mettler Toledo EU * 1.995 25 °C
4.005
7.002
9.208
12 Fisher 1* 2.007 25 °C
4.002
7.004
10.002
13 Fluka BS * 4.006 25 °C
6.984
8.957
14 Radiometer * 1.678 25 °C
4.005
7.000
9.180
15 Baker * 4.006 25 °C
6.991
10.008
16 Metrohm * 3.996 25 °C
7.003
8.999
17 Beckman * 4.005 25 °C
7.005
10.013
18 Hamilton DC * 4.005 25 °C
7.002
10.013
19 Precisa * 3.996 25 °C
7.003
8.999

42 ba75865e04 02/2010
Multi 3430 Operation

No. Buffer set * pH values at


20 Reagecon TEC * 2.000 25 °C
4.010
7.000
10.000
21 Reagecon 20 * 2.000 20°C
4.000
7.000
10.000
13.000
22 Reagecon 25 * 2.000 25 °C
4.000
7.000
10.000
13.000
23 Riedel-de Haen * 2.000 20°C
4.000
7.000
10.000

* Brand names or trade names are trademarks of their respective owners


protected by law.

Note
The buffers are selected in the menu, pH / <MENU/ENTER> / Calibra-
tion / Buffer (see page 39).

ba75865e04 02/2010 43
Operation Multi 3430

Calibration points Calibration can be performed using one to five buffer solutions in any
order (single-point to five-point calibration). The meter determines the
following values and calculates the calibration line as follows:

Determined values Displayed calibration data


1-point Asy z Zero point = Asy
z Slope = Nernst slope
(-59.2 mV/pH at 25 °C)
2-point Asy z Zero point = Asy
Slp. z Slope = Slp.
3-point to Asy z Zero point = Asy
5-point Slp. z Slope = Slp.
The calibration line is calculated
by linear regression.

Note
You can display the slope in the units, mV/pH or % (see page 39).

Stability control The calibration procedure automatically activates the stability control
function. The current measurement with stability control can be termi-
nated at any time (accepting the current value).

Calibration record The new calibration values are displayed when a calibration procedure
is completed.

Display calibration data You can have the data of the last calibration displayed (see page 53).
and output to interface Subsequently, you can transmit the displayed calibration data to the
interface, e. g. to a PC, with the <PRT> key.

Note
The calibration record is automatically transmitted to the interface after
calibrating.

44 ba75865e04 02/2010
Multi 3430 Operation

Sample record
31.07.2009 15:55
Multi 3430
Ser. no. 09250023

CALIBRATIONpH
31.07.2009 16:13:33
SenTix 940
Ser. no. B092500013
AutoCal TEC
Buffer 1 4.01
Buffer 2 7.00
Buffer 3 10.01
Voltage 1 184.0 mV 24.0 °C
Voltage 2 3.0 mV 24.0 °C
Voltage 3 -177.0 mV 24.0 °C
Slope -60.2 mV/pH
Asymmetry 4.0 mV
Sensor +++

etc...

Calibration evaluation After calibrating, the meter automatically evaluates the calibration. The
zero point and slope are evaluated separately. The worse evaluation of
both is taken into account. The evaluation appears on the display and
in the calibration record.

Display Calibration Zero point Slope


record [mV] [mV/pH]
+++ -15 ... +15 -60.5 ... -58

++ -20 ... +20 -58 ... -57

+ -25 ... +25 -61 ... -60.5


or
-57 ... -56
- -30 ... +30 -62 ... -61
or
-56 ... -50
Clean the IDS sensor according to the
sensor operating manual
< -30 or ... -62 or
Error Error
> 30 ... -50
Eliminate the error according to
chapter 6 WHAT TO DO IF...

Note
For pH IDS sensors you can optionally enable a more finely graded cal-
ibration evaluation (QSC) (see section 4.6.10).

ba75865e04 02/2010 45
Operation Multi 3430

Preparatory activities Perform the following preparatory activities when you want to calibrate:

1 Connect the IDS pH sensor to the meter.


The pH measuring window is displayed.
2 Keep the buffer solutions ready.

4.6.5 Calibration interval

The calibration evaluation is displayed as a sensor symbol.


After the QSC function has been enabled the sensor symbol is
replaced by the QSC color scale (see section 4.6.10).

After the specified calibration interval has expired the sensor symbol or
the QSC color scale flashes. It is still possible to measure.

Note
To ensure the high measuring accuracy of the measuring system, cal-
ibrate after the calibration interval has expired.

Setting the calibration The calibration interval is set to 7 days (d7) in the factory.
interval You can change the interval (1 ... 999 days):

1 Open the menu for measurement settings with <MENU/


ENTER>.
2 In the Calibration / Calibration interval menu, set the calibration
interval with <S><T>.
3 Confirm the setting with <MENU/ENTER>.
4 Quit the menu with <MODE>.

46 ba75865e04 02/2010
Multi 3430 Operation

4.6.6 Carrying out an automatic calibration (AutoCal)

Make sure that in the sensor menu, Buffer menu, the buffer set is cor-
rectly selected (see page 39).

Use any one to five buffer solutions of the selected buffer set in ascend-
ing or descending order.

Below, calibration with Technical buffers (TEC) is described. When


other buffer sets are used, other nominal buffer values are displayed.
Apart from that, the procedure is identical.

Note
If single-point calibration was set in the menu, the calibration procedure
is automatically finished with the measurement of buffer solution 1 and
the calibration record is displayed.

1 In the measured value display, select the measured parameter


pH or mV with <MODE>.
2 Start the calibration with <CAL>.
The calibration display appears.

30.09.2009 08:00

3 Immerse the IDS pH sensor in buffer solution 1.


4 Start the measurement with <MENU/ENTER>.
The measured value is checked for stability (stability control).
The [AR] status indicator is displayed. The measured parame-
ter flashes.

ba75865e04 02/2010 47
Operation Multi 3430

30.09.2009 08:00

5 Wait for the end of the measurement with stability control or


accept the calibration value with <MENU/ENTER>.
The calibration display for the next buffer appears.

30.09.2009 08:00

6 If necessary, finish the calibration procedure as a single-point


calibration with <MODE>.
The calibration record is displayed.

Note
For single-point calibration, the instrument uses the Nernst slope
(-59.2 mV/pH at 25 °C) and determines the zero point of the IDS pH
sensor.

Continuing with two-


7 Thoroughly rinse the IDS sensor with distilled water.
point calibration
(Buffer: TEC) 8 Immerse the IDS pH sensor in buffer solution 2.
9 Start the measurement with <MENU/ENTER>.
The measured value is checked for stability (stability control).
The [AR] status indicator is displayed. The measured parame-
ter flashes.

48 ba75865e04 02/2010
Multi 3430 Operation

30.09.2009 08:00

10 Wait for the measurement with stability control to be completed


or terminate the stability control and take over the calibration
value with <MENU/ENTER>.
The calibration display for the next buffer appears.

30.09.2009 08:00

11 Finish the calibration procedure as a two-point calibration with


<MODE>.
The calibration record is displayed.

Continuing with three-


12 Thoroughly rinse the IDS pH sensor with distilled water.
point to five-point
calibration 13 Immerse the IDS pH sensor in buffer solution 3.
(Buffer TEC)
14 Start the measurement with <MENU/ENTER>.
The measured value is checked for stability (stability control).
The [AR] status indicator is displayed. The measured parame-
ter flashes.

ba75865e04 02/2010 49
Operation Multi 3430

30.09.2009 08:00

15 Use <MODE> to finish the calibration.


The calibration record is displayed.
or
Switch to calibration with the next buffer with <MENU/
ENTER>.

Note
Calibration is automatically completed after the last buffer of a buffer
set has been measured. Then the calibration record is displayed.

Note
The calibration line is determined by linear regression.

50 ba75865e04 02/2010
Multi 3430 Operation

4.6.7 Carrying out a manual calibration (ConCal)

Single-point calibration Use any buffer solution for this rapid method.
The calibration will be the more exact the nearer the pH value of the
buffer solution is to that of the test sample.

Two-point calibration Use two buffer solutions for this procedure:


z first buffer solution: pH 7.0 ± 0.5
z any other buffer solution

To carry out this procedure, ConCal has to be set as the buffer set (se
section 4.6.3) in the Buffer menu of the sensor menu.
Note
If single-point calibration was set in the menu, the calibration procedure
is automatically finished with the measurement of buffer solution 1 and
the calibration record is displayed.

1 In the measured value display, select the measured parameter


pH or mV with <MODE>.
2 Start the calibration with <CAL>.
The calibration display appears.

30.09.2009 08:00

3 Thoroughly rinse the IDS pH sensor with distilled water.


4 Immerse the IDS pH sensor in buffer solution 1.
5 Start the measurement with <MENU/ENTER>.
The measured value is checked for stability (stability control).
The measured parameter flashes.

ba75865e04 02/2010 51
Operation Multi 3430

30.09.2009 08:00

6 Wait for the measurement with stability control to be com-


pleted.
Set the nominal buffer value for the measured temperature with
<S><T>.
7 Take over the calibration value for the asymmetry with <MENU/
ENTER>.
The calibration display for the next buffer appears.

30.09.2009 08:00

8 If necessary, finish the calibration procedure as a single-point


calibration with <MODE>.
The calibration record is displayed.

Note
For single-point calibration, the instrument uses the Nernst slope
(-59.2 mV/pH at 25 °C) and determines the zero point of the IDS pH
sensor.

52 ba75865e04 02/2010
Multi 3430 Operation

Continuing with two-


9 Thoroughly rinse the IDS pH sensor with distilled water.
point calibration
10 Immerse the IDS pH sensor in buffer solution 2.
11 Start the measurement with <MENU/ENTER>.
The measured value is checked for stability (stability control).
The measured parameter flashes.
12 Wait for the measurement with stability control to be com-
pleted.
Set the nominal buffer value for the measured temperature with
<S><T>.

30.09.2009 08:00

13 Take over the calibration value for the slope with <MENU/
ENTER>.
The calibration is completed as a two-point calibration.
The calibration record is displayed.

4.6.8 Displaying calibration records

The calibration data can be displayed and then output to the interface.
Displaying the The calibration record of the last calibration is to be found under the
calibration record menu item, Calibration / Calibration record. To open it in the measured
_
value display, press the <CAL > key.

The calibration records of the last 10 calibrations are to be found in the


menu, Calibration / Calibration data storage. To open the Calibration
menu, press the <MENU/ENTER> key in the measured value display.

ba75865e04 02/2010 53
Operation Multi 3430

Menu item Setting/func- Description


tion
Calibration / - Displays the calibration
Calibration data stor- records.
age
Further options:
z Scroll through the cali-
bration records with
<W><X>.
z Output the displayed
calibration record to the
interface with <PRT>.
z Output all calibration
records to the interface
with <PRT >._
z Quit the display with
<ESC> or <MENU/
ENTER>.
z Switch directly to the
measured value display
with <MODE>.

Sample printout
31.07.2009 16:55
Multi 3430
Ser. no. 09250023

CALIBRATIONpH
SenTix 940
Ser. no. B092500013
31.07.2009 16:13:33
AutoCal TEC
Buffer 1 4.01
Buffer 2 7.00
Buffer 3 10.01
Voltage 1 184.0 mV 24.0 °C
Voltage 2 3.0 mV 24.0 °C
Voltage 3 -177.0 mV 24.0 °C
Slope -60.2 mV/pH
Asymmetry 4.0 mV
Sensor +++

etc...

54 ba75865e04 02/2010
Multi 3430 Operation

4.6.9 Continuous measurement control (CMC function)

The Continuous Measurement Control (CMC function) facilitates to


evaluate the current measured value instantly and definitely.
After each successful calibration the scale of the pH measuring range
is displayed in the measured value display. Here you can very clearly
see whether or not the current measured value is in the calibrated part
of the measuring range.
The following information is displayed:

1
2

3
4

Info 30.09.2009 08:00

1 Measuring range for which a valid calibration is available (back-


ground color). Measured values in this range are suitable for
documentation.
2 Measuring range for which no valid calibration is available (light
gray). Measured values in this range are not suitable for docu-
mentation. Calibrate the meter with buffers covering this mea-
suring range.
If the current measured value is not in the calibrated range, the
color of this range changes to dark gray.
If a measured value is outside the measuring range pH 0 - 14,
overflow arrows are displayed at the left or right edge of the mea-
suring range.
3 Currently measured pH value (needle)
4 Marking lines for all nominal buffer values used with the last valid
calibration

The limits of the calibrated range are determined by the buffers used
for calibration:

Lower limit: Buffer with lowest pH value - 2 pH units


Upper limit: Buffer with highest pH value + 2 pH units

ba75865e04 02/2010 55
Operation Multi 3430

4.6.10 QSC function (sensor quality control)

General information The QSC function (Quality Sensor Control) is a new sensor evaluation
on the QSC function for digital IDS sensors. It evaluates the condition of an IDS pH sensor
individually and with a very fine grading.

On the display, the QSC color scale (from green to yellow) indicates the
current sensor evaluation by means of a pointer.

QSC color scale

The double arrow on


the color scale indi-
cates the current sen-
sor evaluation.
Info 22.09.2009 08:00

The sensor evaluation is documented as a percentage (1 - 100) in the


printout.

The finely graded sensor evaluation of the QSC function promptly calls
your attention to changes of the sensor.
Thus you can do what is necessary to restore the optimum measuring
quality (e.g. clean, calibrate or replace the sensor).

Sensor evaluation With QSC function Without QSC function (sensor


with / without symbol)
QSC function
Very fine grading of the sensor Rough grading of the sensor
evaluation (100 grades) evaluation (4 grades)

The reference value is individu- A theoretical reference value is


ally determined for each sensor used for all sensors
during the QSC initial calibra-
tion.

Low tolerances for zero point Greater tolerances for zero point
and slope when using QSC buf- and slope when using commer-
fer solutions cial buffer sets

Additional QSC calibration No additional calibration required


required (with special QSC buf-
fer set)

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Multi 3430 Operation

QSC calibration The QSC function is enabled by once carrying out an additional three-
point calibration with special QSC buffer solutions. It covers the mea-
suring range of the sensor from pH 2 to pH 11. The QSC initial calibra-
tion determines the actual condition of the sensor and stores it as a
reference in the sensor.
To meet the high requirements of a QSC initial calibration, the QSC ini-
tial calibration should optimally be carried out with the initial commis-
sioning of the sensor.

Carry out the normal calibrations for your special measuring range with
your usual standard solutions as previously done.

Note
As soon as the QSC function was enabled for an IDS sensor, it is not
possible to return to the sensor evaluation with the sensor symbol for
this sensor.

Carrying out a QSC


1 Open the menu for measurement settings with <MENU/
initial calibration
ENTER>.
2 In the QSC menu, select First calibration with <S><T>.
The calibration display appears. AutoCal QSC-Kit is displayed
as the buffer.
Exclusively use the QSC-Kit for the QSC calibration. If you use
other buffers, you will have no valid QSC calibration.

22.09.2009 08:00

3 Calibration with the buffers of the QSC-Kit is done like a normal


three-point calibration.
Follow the user guide.

Note
Carry out the QSC initial calibration very carefully. It determines the ref-
erence value for the sensor. This reference value cannot be overwritten
or reset.
As soon as the QSC function was enabled, it is not possible to return to
the sensor evaluation with the sensor symbol.

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Operation Multi 3430

4 As soon as the three-point calibration has been successfully


carried out you can decide whether to accept or discard the cal-
ibration as the QSC initial calibration.

The QSC initial calibration is completed. The sensor is calibrated. If you


want to calibrate with special buffers for your measurements, you can
subsequently carry out a normal calibration with your buffers. The ref-
erence values determined with the QSC calibration are also used for
the evaluation of normal calibrations. In the measured value display,
the color scale of the QSC function is always displayed. A double arrow
on the color scale indicates the current sensor evaluation.

QSC color scale

The double arrow on


the color scale indi-
cates the current sen-
sor evaluation.
Info 22.09.2009 08:00

You can carry out QSC control calibrations at greater intervals than
normal calibrations.
A QSC control calibration can, e.g. be useful if the sensor evaluation
noticeably changed (after some normal calibrations).

Carrying out a QSC


1 Open the menu for measurement settings with <MENU/
control calibration
ENTER>.
2 In the QSC menu, select Control calibration with <S><T>.
The calibration display appears. AutoCal QSC-Kit is displayed
as the buffer.
Exclusively use the QSC-Kit for the QSC calibration. If you use
other buffers, you will have no valid QSC control calibration.
3 Follow the user guide.
The calibration is carried out like a normal three-point calibra-
tion. As soon as the three-point calibration has been success-
fully carried out you can decide whether to accept or discard the
calibration as the QSC control calibration.

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4.7 ORP voltage

4.7.1 General information

You can measure the following variables:


z ORP [mV]

Note
The sensor connection and the USB-B (device) interface are galvani-
cally isolated. This facilitates interference-free measurements also in
the following cases:
z Measurement in grounded test samples
z Measurement with several sensors connected to one Multi 3430 in
one test sample

Preparatory activities Perform the following preparatory activities when you want to measure:

1 Connect the IDS ORP sensor to the meter.


The ORP measuring window is displayed.
2 Check the meter with the IDS ORP sensor.

4.7.2 Measuring the ORP

Note
IDS ORP sensors are not calibrated. However, you can check IDS
ORP sensors using a test solution.

1 Perform the preparatory activities according to section 4.6.1.


2 Immerse the IDS ORP sensor in the test sample.

Info 30.09.2009 08:00

ba75865e04 02/2010 59
Operation Multi 3430

3 Select the mV display with <MODE>.

Stability control The stability control function (AutoRead) continually checks the stability
(AutoRead ) of the measurement signal. The stability has a considerable impact on
the reproducibility of measured values. The display of the measured
parameter flashes until a stable measured value is available.
You can start the Stability control manually at any time, irrespective of
the setting for automatic Stability control (see page 34) in the System
menu.

1 Freeze the measured value with <AR>.


The [HOLD] status indicator is displayed.
2 Using <MENU/ENTER>, activate the Stability control function
manually.
The [AR] status indicator appears while the measured value is
assessed as not stable. A progress bar is displayed and the
display of the measured parameter flashes.
The [HOLD][AR] status indicator appears as soon as a stable
measured value is recognized. The progress bar disappears
and the display of the measured parameter stops flashing.
The current measurement data is output to the interface. Mea-
surement data meeting the stability control criterion is marked
by AR.

Note
You can prematurely terminate the Stability control function manually
with <MENU/ENTER> at any time. If the Stability control function is pre-
maturely terminated, the current measurement data are not output to
the interface.

3 Release the frozen measured value again with <AR> or


<MODE>.
The [AR] status display disappears. The display switches back
to the previous indication.

Criteria for a stable The Stability control function checks whether the measured values are
measured value stable within the monitored time interval.

Measured Time interval Stability in the time


parameter interval
ORP voltage 15 seconds Δ mV: Better than 0.3

The minimum duration until a measured value is assessed as stable is


the monitored time interval. The actual duration is mostly longer.

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4.7.3 Settings for ORP measurements

Overview The following settings are possible for ORP measurements:


z Resolution
z Automatic stability control

Settings The settings are made in the menu for measuring settings of the ORP
measurement. To open the settings, display the required measured
parameter in the measured value display and press the <MENU/
ENTER> key. After completing the settings, switch to the measured
value display with <MODE>.
Default settings are printed in bold.

Menu item Possible set- Description


ting
mV resolution 0.1 Resolution of the mV dis-
1 play
Reset - Resets all sensor settings to
the delivery condition (see
section 4.12.1).

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Operation Multi 3430

4.8 Dissolved oxygen

Dear customer:

To carry out D.O. measurements with the Multi 3430, the digital D.O.
sensor FDO 925 is required.

The D.O. sensor FDO 925 is not yet available at present. Therefore, the
D.O. measuring function is not implemented in the current meter soft-
ware (firmware) of the Multi 3430 and not described in the operating
manual at hand.

As soon as the FDO 925 digital D.O. sensor is available, a firmware


update and the enhanced operating manual will be provided in the
Internet under www.wtw.com.

After you have carried out the software update, all functions for D.O.
measurement will be available at your Multi 3430.

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4.9 Conductivity

4.9.1 General information

You can measure the following variables:


z Conductivity
z Specific resistance
z Salinity
z Total dissolved solids (TDS)

Temperature IDS sensors measure the temperature with a temperature sensor inte-
measurement grated in the IDS sensor.
Preparatory activities Perform the following preparatory activities when you want to measure:

1 Connect an IDS conductivity sensor to the meter.


The conductivity measuring window is displayed.
The Measuring cell and cell constant for the connected IDS
conductivity sensor are automatically taken over.

4.9.2 Measuring

You can carry out conductivity measurements as follows:

1 Perform the preparatory activities according to section 4.9.1.


2 Immerse the IDS conductivity sensor in the test sample.

Info 30.09.2009 08:00

ba75865e04 02/2010 63
Operation Multi 3430

Selecting the You can switch between the following displays with <M>:
displayed z Conductivity [μS/cm] / [mS/cm]
measured parameter
z Resistivity [Ω·cm] / [kΩ·cm] / [MΩ·cm]
z Salinity SaL [ ]
z Total dissolved solids TDS [mg/l] / [g/l]

The factor to calculate the total dissolved solids is set to 1.00 in the fac-
tory. You can adjust this factor to meet your requirements in the range
of 0.40 to 1.00. The factor is set in the Measurement menu for the
parameter, TDS.

Freezing the measured With the HOLD function, you can freeze the current measured value.
value (HOLD function) The displayed measured value stops changing until you switch the
HOLD function off.

1 Freeze the measured value with <AR>.


The [HOLD] status indicator is displayed.

Note
If the HOLD function is active, you can, e.g. start a manual measure-
ment with stability control.

2 Release the frozen measured value again with <AR>.


The HOLD function is switched off.
The [HOLD] status display disappears.

Stability control The stability control function (AutoRead) continually checks the stability
(AutoRead ) of the measurement signal. The stability has a considerable impact on
the reproducibility of measured values. The display of the measured
parameter flashes until a stable measured value is available.
You can start the Stability control manually at any time, irrespective of
the setting for automatic Stability control (see page 34) in the Measure-
ment menu.

1 Freeze the measured value with <AR>.


The [HOLD] status indicator is displayed.

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2 Using <MENU/ENTER>, activate the Stability control function


manually.
The [AR] status indicator appears while the measured value is
assessed as not stable. A progress bar is displayed and the
display of the measured parameter flashes.
The [HOLD][AR] status indicator appears as soon as a stable
measured value is recognized. The progress bar disappears
and the display of the measured parameter stops flashing.
The current measurement data is output to the interface. Mea-
surement data meeting the stability control criterion is marked
by AR.

Note
You can prematurely terminate the Stability control function manually
with <MENU/ENTER> at any time. If the Stability control function is pre-
maturely terminated, the current measurement data are not output to
the interface.

3 Using <MENU/ENTER>, start a further measurement with Sta-


bility control.
or
Release the frozen measured value again with <AR>.
The display switches to the measured value display.
The [AR][HOLD] status display disappears.

Criteria for a stable The Stability control function checks whether the measured values are
measured value stable within the monitored time interval.

Measured Time interval Stability in the time interval


parameter
Conductivity ϰ 10 seconds Δ ϰ: better than
0.5% of measured value
Temperature 10 seconds Δ T (° C): Better than 0.02

The minimum duration until a measured value is assessed as stable is


the monitored time interval. The actual duration is mostly longer.

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Operation Multi 3430

4.9.3 Temperature compensation

The calculation of the temperature compensation is based on the pre-


set reference temperature, 20 °C or 25 °C. It appears on the display as
Tr20 or Tr25.

You can select one of the following temperature compensation meth-


ods:
z Nonlinear temperature compensation (nLF) according to EN 27
888
z Linear temperature compensation (lin) with adjustable coeffi-
cients of 0.000 ... 3.000 %/K
z No temperature compensation (off)

Note
The reference temperature and temperature compensation are set in
the Measurement menu for the parameter, conductivity (see section
4.9.4).

Application tips Select the following temperature compensations given in the table
according to the respective test sample:

Test sample Temperature compensation Display


indica-
tor
Natural water nLF nLF
(ground water, surface according to EN 27 888
water, drinking water)
Ultrapure water nLF nLF
according to EN 27 888
Other aqueous solu- lin Set linear lin
tions temperature coefficient
0.001 ... 3.000 %/K
Salinity (seawater) Automatic nLF according to Sal, nLF
IOT

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4.9.4 Settings for IDS conductivity sensors

Overview The following settings are possible for IDS conductivity sensors:
z Calibration record (display)
z Calibration interval
z Reference temperature
z Temperature compensation
z TDS factor
z Unit of the temperature
z Automatic Stability control

Settings The settings are made in the Measurement menu for the measured
parameter, conductivity. To open the settings, display the required
measured parameter in the measured value display and press the
<MENU/ENTER> key. After completing the settings, switch to the mea-
sured value display with <MODE>.
The possible settings are individually displayed for each sensor. Below
the setting menu is displayed for two IDS sensors (TetraCon 925,
LR325/01).
Default settings are printed in bold.

Setting menu of Menu item Possible Description


TetraCon 925 setting
Calibration /Cali- - Displays the calibration record of
bration record the last calibration.
Calibration /Cali- 1 ... 150 ... Calibration interval for the IDS con-
bration interval 999 d ductivity sensor (in days).
The meter reminds you to calibrate
regularly by the flashing sensor
symbol in the measuring window.
Measurement / Measuring cell used
Measuring cell /
Type cal Measuring cells whose cell con-
stant is determined by calibration
in the KCL control standard solu-
tion.
Calibration range:
0.450 to 0.500 cm-1
The currently valid cell constant is
displayed in the status line.
man Freely adjustable cell constant in
the range 0.450 ... 0.500 cm-1.

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Operation Multi 3430

Menu item Possible Description


setting
Measurement / 0.450 ... Display and setting option of the
Measuring cell / 0.475 ... cell constant.
Man. cell const. 0.500 cm-1
Measurement / nLF Procedure for temperature com-
Temp. comp. lin pensation (see section 4.9.3).
(TC) / Method Off
This setting is only available for the
measured parameters, ӕ and ρ.
Measurement / 0.000 ... Coefficient of the linear tempera-
Temp. comp. 2.000 ... ture compensation.
(TC) / 3.000 %/K
Linear coeff. This setting is only available when
the linear temperature compensa-
tion is set.
Measurement / 20 °C Reference temperature
Temp. comp. 25 °C
(TC) / This setting is only available for the
Reference temp. measured parameters, ӕ and ρ.
Measurement / 0.40 ... Factor for TDS value
TDS factor 1.00
Reset - Resets all sensor settings to the
delivery condition (see section
4.12.1).

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Setting menu of Menu item Possible set- Description


LR325/01 ting
Measurement / 0.090 ... ... Display and setting option of
Measuring cell / 0.100 ... the cell constant.
Cell constant 0.110 cm-1
Measurement / nLF Procedure for temperature
Temp. comp. (TC) / lin compensation (see section
Method Off 4.9.3).

This setting is only available


for the measured parame-
ters, ӕ and ρ.
Measurement / 0.000 ... Coefficient of the linear tem-
Temp. comp. (TC) / 2.000 ... perature compensation.
Linear coeff. 3.000 %/K
This setting is only available
when the linear temperature
compensation is set.
Measurement / 20 °C Reference temperature
Temp. comp. (TC) / 25 °C
Reference temp. This setting is only available
for the measured parame-
ters, ӕ and ρ.
Measurement /TDS 0.40 ... 1.00 Factor for TDS value
factor
Reset - Resets all sensor settings to
the delivery condition (see
section 4.12.1).

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Operation Multi 3430

4.9.5 Determining the cell constant


(calibration in control standard)

Why determine the cell Aging slightly changes the cell constant, e. g. due to coatings. As a
constant? result, an inexact measured value is displayed. The original character-
istics of the cell can often be restored by cleaning the cell. Calibration
determines the current value of the cell constant and stores this value
in the meter.
Thus, you should calibrate at regular intervals (we recommend: every
6 months).

Procedure You can determine the actual cell constant of the IDS conductivity sen-
sor cell by calibrating with the control standard in the following range:
z 0.450 ... 0.500 cm-1
(e.g. TetraCon 925, nominal cell constant 0.475)
The cell constant is determined in the control standard, 0.01 mol/l KCl.

In the delivery condition, the calibrated cell constant of the IDS sensor
is set to 0.475 cm-1 (conductivity measuring cell, TetraCon 925).

Stability control In calibration, the Stability control function (AutoRead) is automatically


(AutoRead) activated.

Display calibration data You can have the data of the last calibration displayed (see section
and output to interface 4.9.6). Subsequently, you can transmit the displayed calibration data to
the interface, e. g. to a printer or PC, with the <PRT> key.

Note
The calibration record is automatically transmitted to the interface after
calibrating.

Sample record:
31.07.2009 16:55:12
Multi 3430
Ser. no. 09250023

CALIBRATION Cond
TetraCon 925
Ser. no. 09250033
31.07.2009 16:13:33

Cell constant 0.476 1/cm 25.0 °C


Sensor +++

Calibration evaluation After the calibration, the meter automatically evaluates the current sta-
tus of the calibration. The evaluation appears on the display and in the
calibration record.

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Multi 3430 Operation

Display Calibration Cell constant [cm-1]


record
+++ Within the range
0.450 ... 0.500 cm-1

Outside the range


Error Error
0.450 ... 0.500 cm-1
Eliminate the error according to
chapter 6 WHAT TO DO IF...

Determining the cell For this calibration procedure, the Measuring cell setting must be set to
constant cal in the Measurement menu. Proceed as follows to determine the cell
constant:

1 Connect an IDS conductivity sensor to the meter.


2 In the measured value display, select the conductivity parame-
ter with <M>.
3 Start the calibration with <CAL>.
The cell constant that was calibrated last is displayed.

30.09.2009 08:00

4 Immerse the IDS conductivity sensor in the control standard


solution, 0.01 mol/l KCI.
5 Start the measurement with <MENU/ENTER>.
The measured value is checked for stability (stability control).
The [AR] status indicator is displayed. The measured parame-
ter flashes.

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Operation Multi 3430

6 Wait for the end of the measurement with stability control or


accept the calibration value with <MENU/ENTER>.
The calibration record is displayed and output to the interface.
7 Switch to the measured value display with <MENU/ENTER>.

4.9.6 Displaying calibration records

The calibration data can be displayed and then output to the interface.
Displaying the The calibration record of the last calibration is to be found under the
calibration record menu item, Calibration / Calibration record. To open it in the measured
_
value display, press the <CAL > key.

The calibration records of the last 10 calibrations are to be found in the


menu, Calibration / Calibration data storage. To open the Calibration
menu, press the <MENU/ENTER> key in the measured value display.

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Multi 3430 Operation

4.10 Data storage


You can transmit measured values (datasets) to the data storage:
z Manual storage (see section 4.10.1)
z Automatic storage at intervals (see section 4.10.2)

Each storage process transmits the current dataset to the interface at


the same time.

Measurement dataset A complete dataset consists of:


z Date/time
z Meter name, series number
z Sensor name, series number
z ID number
z Measured value of the connected sensor
z Measured temperature value of the connected sensor
z AutoRead info: AR appears with the measured value if the Auto-
Read criterion was met while storing (stable measured value). Oth-
erwise, the AR display is missing.
z Calibration evaluation:
- 4 levels (+++, ++, +, -, or no evaluation) or
- QSC (percentage)

Storage locations The Multi 3430 meter has two measurement data memories. The mea-
sured values recorded either manually or automatic are stored sepa-
rately in individual measurement data memories.

Storage Maximum number of datasets


Manual data storage 200
Automatic data storage 5000

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Operation Multi 3430

4.10.1 Manual storage

You can transmit a measurement dataset to the data storage as fol-


lows. The dataset is at the same time output to the interface:

1 Press the <STO> key shortly.


The menu for manual storage appears.

Manual data storage 4 From 200


30.09.2009 11:24:16
pH 7.000 24.8 °C AR +++

ID number: 1
Continue

22.09.2009 08:00

2 If necessary, change and confirm the ID number (1 ... 10000)


with <S><T> and <MENU/ENTER>.
The dataset is stored. The meter switches to the measured
value display.

If the storage is full When all memory locations are occupied, it is not possible to continue
storing. Then you can e.g. transmit the stored data to a PC or a USB
flash drive (see section 4.10.3) and subsequently erase the storage
(see section 4.10.4).

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Multi 3430 Operation

4.10.2 Automatic storage at intervals

The storage interval (Interval) determines the time interval between


automatic storage processes. Each storage process transmits the cur-
rent dataset to the interface at the same time.

Configuring the
automatic storage
1 Press the <STO > key. _
The menu for automatic storage appears.
function
Automatic data storage
ID number 1 Adjusted entire storage
Interval 30 s duration
Duration 180 min
Continue
Max. available storage
0d03h00min duration
0 1d17h33min

22.09.2009 08:00
Graphical display of the
storage usage

Settings You can configure the automatic storage function with the following set-
tings:

Menu item Possible Description


setting
ID number 1 ... 10000 ID number for the dataset series.
Interval 1 s, 5 s, 10 s, Storage interval.
30 s, 1 min,
5 min, The lower limit of the storage
10 min, interval can be restricted by the
15 min, number of free storage locations.
30 min, The upper limit is restricted by the
60 min storage duration.
Duration 1 min ... x min Storage duration.
Specifies after which time the
automatic storage should be ter-
minated.

The lower limit of the storage


duration is restricted by the stor-
age interval.
The upper limit is restricted by the
number of free storage locations.

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Operation Multi 3430

Starting the automatic To start the automatic storage function, select Continue with <S><T>
storage function and confirm with <MENU/ENTER>. The meter switches to the mea-
sured value display.

Remaining storage duration

Graphical display of the


storage duration
0d03h00min

30.09.2009 08:00

The active automatic storage function can be recognized by the prog-


ress bar in the status line. The progress bar indicates the remaining
storage duration.

Note
If the automatic storage function is activated, only the following keys
_
are active: <MODE>, <STO > and <On/Off>. The other keys and the
automatic switch-off function are deactivated.

Terminating the Proceed as follows to switch off the automatic storage function before
automatic storage the adjusted storage duration has expired:
function prematurely
1 Press the <STO > key. _
The following window appears.

Warning

Stop automatic storage?

Yes
No

22.09.2009 08:00

2 Using <S><T>, select Yes and confirm with <MENU/


ENTER>.
The meter switches to the measured value display.
The automatic storage function is terminated.

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Multi 3430 Operation

4.10.3 Editing the measurement data storage

The contents of the manual or automatic measurement data storage


can be shown on the display.
Each of the measurement data storages has a function to erase the
entire contents.

Editing the data storage The storage is edited in the menu, Storage & config / Data storage. To
_
open the Storage & config menu, press the <MENU/ENTER > key in
the measured value display.

Open the manual or automatic storage directly with the <RCL> or


_
<RCL > key.

Note
The settings are explained here using the manual storage as an exam-
ple. The same settings and functions are available for the automatic
storage.

Settings Menu item Setting/ Description


function
Data storage / - Displays all measurement
Manual data storage / datasets page by page.
Display
Further options:
z Scroll through the datasets
with <W><X>.
z Output the displayed data-
set to the interface with
<PRT>.
z Quit the display with
<ESC>.
Data storage / - Outputs all stored measure-
Manual data storage / ment data to a connected USB
Copy to USB flash flash drive.
drive
Data storage / - Outputs all stored measure-
Manual data storage / ment data to the interface.
Output to RS232/USB
Data storage / - Erases the entire manual mea-
Manual data storage / surement data storage.
Erase
Note:
All calibration data remains
stored when this action is per-
formed.

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Operation Multi 3430

Display presentation Manual data storage (200) 3 of 64


of a dataset 30.09.2009 11:24:16 ID number: 1

SenTix 940 B20234008565


pH 7.000 24.8 °C AR Sensor: +++

22.09.2009 08:00

Sample printout
31.07.2009 09:56:20
Multi 3430
Ser. no. 09250023

SenTix 940
Ser. no. B092500013
ID number 2
pH 6.012 24.8 °C, AR, Sensor: +++
________________________________________

31.07.2009 10:56:20
Multi 3430
Ser. no. 09250023

SenTix 940
Ser. no. B092500013
ID number 2
pH 6.012 24.8 °C, AR, Sensor: +++
________________________________________

etc...

Quitting the display To quit the display of stored measurement datasets, you have the fol-
lowing options:
z Switch directly to the measured value display with <MODE>.
z Quit the display and move to the next higher menu level with
<ESC>.

4.10.4 Erasing the measurement data storage

How to erase the measurement data memory is described in section


4.10.3 EDITING THE MEASUREMENT DATA STORAGE.

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4.11 Transmitting data (USB interfaces)

4.11.1 Outputting current measurement data

1 Output the current measurement data to the USB-B interface


with <PRT>.

4.11.2 Transmitting data (to a PC)

The meter has the following interfaces:


z USB-B interface (USB Device)
e.g. to connect a PC
z USB-A interface (USB Host),
e.g. to connect a USB flash drive

Via the USB-B interface (USB Device) you can transmit data to a PC or
printer and update the meter software.

Via the USB-A interface (USB Host) it is possible to transfer data to an


external USB memory device.

4.11.3 Connecting the PC / USB-B interface (USB Device)

Connect the Multi 3430 to the PC via the USB-B interface.

Installation of the USB System requirements of the PC for installation of the USB driver:
driver on the PC
z PC with at least one free USB connection and CD-ROM drive
z Windows 2000, XP, Vista.

1 Insert the supplied installation CD in the CD drive of your PC.


2 Install the driver from the CD.
Follow the Windows installation instructions as necessary.
3 Connect the Multi 3430 to the PC via the USB-B interface.
The meter is listed as a virtual COM interface among the con-
nections in the Windows instrument manager.

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Operation Multi 3430

4 Set the same transmission data at the connected instrument


(PC):
z Baud rate: to be selected in the range 1200 ... 19200
z Handshake: RTS/CTS
z Set at the PC only:
– Parity: none
– Data bits: 8
– Stop bits: 1

4.11.4 Connecting the USB memory device / USB-A


interface (USB Host)

Connect the USB-A interface (USB Host) of the Multi 3430 to a USB
flash drive.

1 Connect the USB printer or a USB memory device to the USB


Host interface.

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4.11.5 Options for data transmission

Via the USB-B interface you can transmit data to a PC. Via the USB-A
interface you can transmit data to a USB memory device. The following
table shows which data are transmitted to the interface in which way:

Data Control Operation / description


Current Manual z With <PRT>.
measured values z Simultaneously with every
of all connected manual storage process
sensors (see section 4.10.1).
Automatic, at z With <PRT >._
intervals Then you can set the trans-
mission interval.
z Simultaneously with every
automatic storage process
(see section 4.10.2).
Stored measured Manual z Displayed dataset with
values <PRT> after calling up from
the storage.
z All datasets with the Output
to RS232/USB function.
For details, see section 4.10.3.
Calibration Manual z Displayed calibration record
records with <PRT>.
z All calibration records with
<PRT >._
For details, see section 4.11.
Automatic z At the end of a calibration
procedure.

Note
The following rule applies: With the exception of the menus, shortly
pressing the <PRT> key generally outputs the display contents to the
interface (displayed measured values, measuring datasets, calibration
records).

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Operation Multi 3430

4.12 Reset
You can reset (initialize) all sensor settings and sensor-independent
settings separately from each other.

4.12.1 Resetting the measurement settings

Note
The calibration data are reset to the default settings together with the
measuring parameters. Recalibrate after performing a reset.

pH The following settings for pH measurements are reset to the default


settings with the Reset function:

Setting Default settings


Buffer AutoCalTEC
Cal. interval 7d
Unit for slope mV/pH
Measured parameter pH
pH resolution 0.001
mV resolution 0.1
Asymmetry 0 mV
Slope -59.2 mV
Man. temperature 25 °C
Single-point calibration Off
Stability control On

The sensor settings are reset under the Reset menu item in the menu
for calibration and measurement settings. To open the settings, display
the required measured parameter in the measured value display and
press the <MENU/ENTER> key.

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Multi 3430 Operation

ORP The following settings for ORP measurements are reset to the default
settings with the Reset function:

Setting Default settings


mV resolution 0.1
Man. temperature 25 °C
Stability control On

The sensor settings are reset under the Reset menu item in the menu
for calibration and measurement settings. To open the settings, display
the required measured parameter in the measured value display and
press the <MENU/ENTER> key.

Conductivity The following settings for conductivity measurements are reset to the
default settings with the Reset function:

Setting Default settings


Cal. interval 150 d
Measured parameter ӕ
Cell constant (c) Depending on the connected
measuring cell:
0.475 cm-1 (calibrated)
0.475 cm-1 (set up)
0.100 cm-1
Temperature compensation nLF
Reference temperature 25 °C
Temperature coefficient (TC) of 2.000 %/K
the linear temperature compen-
sation
TDS factor 1.00
Stability control On

The sensor settings are reset under the Reset menu item in the menu
for calibration and measurement settings. To open the settings, display
the required measured parameter in the measured value display and
press the <MENU/ENTER> key.

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Operation Multi 3430

4.12.2 Resetting the system settings

The following system settings can be reset to the default condition:

Setting Default settings


Language English
Acoustic signal On
Volume 6
Baud rate 4800 Baud
Output format ASCII
Decimal separator .
Brightness 15
Illumination Auto
Switchoff time 1h
Temperature unit °C
USB Host On

The system settings are reset in the menu, Storage & config / System
/ Reset. To open the Storage & config menu, press the <MENU/
_
ENTER > key in the measured value display.

84 ba75865e04 02/2010
Multi 3430 Maintenance, cleaning, disposal

5 Maintenance, cleaning, disposal


5.1 Maintenance
The only maintenance activity required is replacing the batteries.

Note
See the relevant operating manuals of the IDS sensors for instructions
on maintenance.

5.1.1 Replacing the rechargeable batteries

1 Unscrew the two screws (1) on the underside of the meter.


2 Open the battery compartment (2) on the underside of the
meter.

3 Remove the four rechargeable batteries from the battery com-


partment.
4 Place four new rechargeable batteries (type Mignon AA) in the
battery compartment.

CAUTION
Make sure that the poles of the rechargeable batteries are posi-
tioned correctly.
The ± signs on the batteries must correspond to the ± signs in the
battery compartment.

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Maintenance, cleaning, disposal Multi 3430

5 Close the battery compartment (2) and tighten the screws (1).

5.2 Cleaning
Occasionally wipe the outside of the measuring instrument with a
damp, lint-free cloth. Disinfect the housing with isopropanol as
required.

CAUTION
The housing is made of synthetic material (ABS). Thus, avoid con-
tact with acetone or similar detergents that contain solvents. Re-
move any splashes immediately.

5.3 Packing
This meter is sent out in a protective transport packing.
We recommend: Keep the packing material. The original packing pro-
tects the meter against damage during transport.

5.4 Disposal
Note
This meter contains rechargeable batteries. Batteries that have been
removed must only be disposed of at a recycling facility set up for this
purpose or via the retail outlet.
It is illegal to dispose of the batteries in household refuse.

86 ba75865e04 02/2010
Multi 3430 What to do if...

6 What to do if...
6.1 General information

Sensor symbol flashes Cause Remedy


– Calibration interval expired – Recalibrate the measuring
system

Cause Remedy
– Batteries almost empty – Charge the batteries (see
section 3.3.2 CONNECTING
Display THE POWER PACK / CHARGING
THE BATTERIES)
– Replace the batteries (see
section 5.1 MAINTENANCE)

Meter does not react to Cause Remedy


keystroke
– Operating condition undefined – Processor reset:
or EMC load unallowed Press the <MENU/ENTER>
and <On/Off> key simulta-
neously

You want to know which Cause Remedy


software
version is in the meter – E. g., a question by the service – Switch on the meter.
department Open the menu, <MENU/
_
ENTER > / Enregis. &
config. / Système / Service
information. The instrument
data is displayed.

ba75865e04 02/2010 87
What to do if... Multi 3430

6.2 pH
Error message
OFL, UFL Cause Remedy
IDS pH sensor:
– Measured value outside the – Use suitable IDS pH sensor
measuring range
– Air bubble in front of the dia- – Remove air bubble
phragm
– Air in the diaphragm – Extract air or moisten dia-
phragm
– Cable broken – Exchange IDS pH sensor
– Gel electrolyte dried out – Exchange IDS pH sensor

Error message, Cause Remedy


Error
IDS pH sensor:
– The values determined for zero – Recalibrate
point and slope of the IDS pH
sensor are outside the allowed
limits.
– Junction contaminated – Clean the junction
– IDS pH sensor broken – Exchange IDS pH sensor
– Buffer solutions:
– The used buffer solutions are not – Select different buffer set
suitable for the selected buffer or
set – Use different buffer solu-
tions
– Buffer solutions too old – Use only once.
Note the shelf life
– Buffer solutions depleted – Change solutions

88 ba75865e04 02/2010
Multi 3430 What to do if...

No stable measured Cause Remedy


value
IDS pH sensor:
– Junction contaminated – Clean the junction
– Membrane contaminated – Clean membrane

Test sample:
– pH value not stable – Measure with air excluded if
necessary
– Temperature not stable – Adjust temperature if neces-
sary

IDS pH sensor + test sample:


– Conductivity too low – Use suitable IDS pH sensor
– Temperature too high – Use suitable IDS pH sensor
– Organic liquids – Use suitable IDS pH sensor

Obviously incorrect Cause Remedy


measured values
IDS pH sensor:
– IDS pH sensor unsuitable – Use suitable IDS sensor
– Temperature difference – Adjust temperature of buffer
between buffer and test sample or sample solutions
too great
– Measurement procedure not – Follow special procedure
suitable

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What to do if... Multi 3430

6.3 Conductivity
Error message,
OFL Cause Remedy
– Measured value outside the – Use suitable IDS conductiv-
measuring range ity sensor

Error message, Cause Remedy


Error
– IDS conductivity sensor contam- – Clean and if necessary,
inated exchange IDS conductivity
sensor
– Calibration solution not suitable – Check calibration solutions

90 ba75865e04 02/2010
Multi 3430 Technical data

7 Technical data
7.1 General data

Dimensions Approx. 180 x 80 x 55 mm


Weight Approx. 0.4 kg
Mechanical structure Type of protection IP 67
Electrical safety Protective class III
Test certificates CE

Ambient Storage - 25 °C ... + 65 °C


conditions Operation -10 °C ... + 55 °C
Climatic class 2

Power Rechargeable batter- 4 x 1.2 V NiMH rechargeable batteries,


supply ies type AA
Operational life Approx. 150 h #

Power pack Input: 100 ... 240 V ~ / 50 ... 60 Hz / 270 mA


Output: 9 V = / 1.1 A
Connection max. overvoltage category II
Primary plugs contained in the scope of
delivery: Euro, US, UK and Australian.

USB interface (device) Type USB 1.1


USB-B (Device), PC
Baud rate adjustable:
1200, 2400, 4800, 9600, 19200 Baud
Data bits 8
Stop bits 2
Parity None
Handshake RTS/CTS
Cable length max. 3 m

USB interface (host) Type USB 2.0


USB-A (host), USB device

# The operational life is shorter if, e.g.


- several sensors are operated
- the maximum display illumination is set

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Technical data Multi 3430

Applicable directives EMC EC directive 2004/108/EC


and standards EN 61326-1
EN 61000-3-2
EN 61000-3-3
FCC Class A
Meter safety EC directive 2006/95/EC
EN 61010-1
Climatic class VDI/VDE 3540
IP protection class EN 60529

FCC Class A Equipment Statement


Note: This equipment has been tested and found to comply with
the limits for a Class A digital device, pursuant to Part 15 of the
FCC Rules. These limits are designed to provide reasonable
protection against harmful interference when the equipment is
operated in a commercial environment. This equipment
generates, uses, and can radiate radio frequency energy and, if
not installed and used in accordance with the instruction manual,
may cause harmful interference to radio communications.
Operation of this equipment in a residential area is likely to cause
harmful interference in which case the user will be required to
correct the interference at his own expense.
Changes or modifications not expressly approved by the
manufacturer could void the user‘s authority to operate the
equipment.

7.2 Measuring ranges, resolution, accuracy


Note
These data are given in the documentation of your sensor.

92 ba75865e04 02/2010
Multi 3430 Lists

8 Lists
This chapter provides additional information and orientation aids.

Specialist terms The glossary briefly explains the meaning of the specialist terms. How-
ever, terms that should already be familiar to the target group are not
described here.

Index The index will help you to find the topics that you are looking for.

Glossary

Adjusting To manipulate a measuring system so that the relevant value (e. g. the
displayed value) differs as little as possible from the correct value or
a value that is regarded as correct, or that the difference remains with-
in the tolerance.
Asymmetry see zero point
AutoRange Name of the automatic selection of the measuring range.
Calibration Comparing the value from a measuring system (e. g. the displayed
value) to the correct value or a value that is regarded as correct. Of-
ten, this expression is also used when the measuring system is adjust-
ed at the same time (see adjusting).
Electromotive force of The electromotive force U of the combination electrode is the measur-
an electrode able electromotive force of an electrode in a solution. It equals the
sum of all the galvanic voltages of the combination electrode. Its de-
pendency on the pH results in the electrode function, which is charac-
terized by the parameters, slope and zero point.
Junction The junction is a porous body in the housing wall of reference elec-
trodes or electrolyte bridges. It arranges the electrical contact be-
tween two solutions and makes the electrolyte exchange more
difficult. The expression, junction, is also used for ground or junction-
less transitions.
Measured parameter The measured parameter is the physical dimension determined by
measuring, e. g. pH, conductivity or D.O. concentration.
Measured value The measured value is the special value of a measured parameter to
be determined. It is given as a combination of the numerical value and
unit (e. g. 3 m; 0.5 s; 5.2 A; 373.15 K).

ba75865e04 02/2010 93
Lists Multi 3430

ORP voltage The ORP is caused by oxidizing or reducing substances dissolved in


water if these substances become effective on an electrode surface
(e. g. a gold or platinum surface).
pH value The pH value is a measure of the acidic or basic effect of an aqueous
solution. It corresponds to the negative decadic logarithm of the molal
hydrogen ions activity divided by the unit of the molality. The practical
pH value is the value of a pH measurement.
Potentiometry Name of a measuring technique. The signal (depending on the mea-
sured parameter) of the electrode is the electrical potential. The elec-
trical current remains constant.
Reset Restoring the original condition of all settings of a measuring system.
Resolution Smallest difference between two measured values that can be dis-
played by a meter.
Slope The slope of a linear calibration function.
Stability control Function to control the measured value stability.
(AutoRead )
Standard solution The standard solution is a solution where the measured value is
known. It is used to calibrate a measuring system.
Test sample Designation of the test sample ready to be measured. Normally, a test
sample is made by processing the original sample. The test sample
and original sample are identical if the test sample was not processed.
Zero point The zero point of a pH combination electrode is the pH value at which
the electromotive force of the pH combination electrode at a specified
temperature is zero. Normally, this is at 25 °C.

94 ba75865e04 02/2010
Multi 3430 Index

Authorized use . . . . . . . . . . . . . . . . . . . . . . 16 M
Automatic switch-off . . . . . . . . . . . . . . . . . . 23 Measured value display . . . . . . . . . . . . . . . 26
AutoRead . . . . . . . . . . . . . . . . . . . . . . . . . . 64 Measurement accuracy . . . . . . . . . . . . . . . 46
ORP . . . . . . . . . . . . . . . . . . . . . . . . . . . 60 Measurement data storage
pH . . . . . . . . . . . . . . . . . . . . . . . . . . . . 37 Edit . . . . . . . . . . . . . . . . . . . . . . . . . . . . 77
Erase . . . . . . . . . . . . . . . . . . . . . . . . . . 77
B Storage locations . . . . . . . . . . . . . . . . . 73
Battery compartment . . . . . . . . . . . . . . 19, 85 Measurement dataset . . . . . . . . . . . . . . . . 73
Measuring . . . . . . . . . . . . . . . . . . . . . . . . . 63
C ORP voltage . . . . . . . . . . . . . . . . . . . . 59
Calibration . . . . . . . . . . . . . . . . . . . . . . . . . 70 pH . . . . . . . . . . . . . . . . . . . . . . . . . . . . 37
pH . . . . . . . . . . . . . . . . . . . . . . . . . . . . 41 Menu for calibration and measurement settings
Calibration evaluation . . . . . . . . . . . . . . . . 70 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 67
pH . . . . . . . . . . . . . . . . . . . . . . . . . . . . 45 pH/ORP . . . . . . . . . . . . . . . . . . . . . 39, 61
Calibration interval . . . . . . . . . . . . . . . . . . . 46 Menus (navigation) . . . . . . . . . . . . . . . . . . 26
Calibration points Messages . . . . . . . . . . . . . . . . . . . . . . . . . 27
pH . . . . . . . . . . . . . . . . . . . . . . . . . . . . 44
calibration records . . . . . . . . . . . . . . . . 53, 72 O
Cell constant . . . . . . . . . . . . . . . . . . . . . . . 70 Operational safety . . . . . . . . . . . . . . . . . . . 16
Connect the power pack . . . . . . . . . . . . . . 20
Connecting a PC . . . . . . . . . . . . . . . . . 79, 80 P
pH buffer sets . . . . . . . . . . . . . . . . . . . . . . 41
D Precautions . . . . . . . . . . . . . . . . . . . . . . . . 15
Dataset . . . . . . . . . . . . . . . . . . . . . . . . . . . . 73 Print . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 81
Date and time . . . . . . . . . . . . . . . . . . . . . . . 30
Default settings R
Measured parameter . . . . . . . . . . . . . . 82 Reset . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 82
System settings . . . . . . . . . . . . . . . . . . 84 RS232 interface . . . . . . . . . . . . . . . . . . . . . 80
Display . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 9
S
E Safety . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 15
Energy saving feature . . . . . . . . . . . . . . . . 21 Scope of delivery . . . . . . . . . . . . . . . . . . . . 19
Setting the date . . . . . . . . . . . . . . . . . . . . . 21
F Setting the time . . . . . . . . . . . . . . . . . . . . . 21
Firmware update . . . . . . . . . . . . . . . . . . . . 97 Single-point calibration
pH . . . . . . . . . . . . . . . . . . . . . . 48, 51, 52
I Slope
Initial commissioning . . . . . . . . . . . . . . 19, 21 pH . . . . . . . . . . . . . . . . . . . . . . . . . . . . 41
Initialize . . . . . . . . . . . . . . . . . . . . . . . . . . . 82 Socket field . . . . . . . . . . . . . . . . . . . . . . . . 11
Interval for calibration . . . . . . . . . . . . . . . . . 46 Stability control
automatic . . . . . . . . . . . . . . . . . . . . . . . 34
Storage interval . . . . . . . . . . . . . . . . . . . . . 75
K Storing in memory . . . . . . . . . . . . . . . . . . . 62
Keys . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 8 Automatic . . . . . . . . . . . . . . . . . . . . . . . 75
Manual . . . . . . . . . . . . . . . . . . . . . . . . . 74

ba75865e04 02/2010 95
Index Multi 3430

T
Temperature compensation . . . . . . . . . . . 66
Temperature measurement . . . . . . . . . . . . 63
pH . . . . . . . . . . . . . . . . . . . . . . . . . . . . 36
Three-point calibration
pH . . . . . . . . . . . . . . . . . . . . . . . . . . . . 49
Transmitting data . . . . . . . . . . . . . . . . . . . 79
Transmitting measured values . . . . . . . . . 79
Two-point calibration
pH . . . . . . . . . . . . . . . . . . . . . . 48, 51, 53

Z
Zero point of pH combination electrode . . 41

96 ba75865e04 02/2010
Multi 3430 Appendix: Firmware update

9 Appendix: Firmware update


General information Available firmware updates are provided on the Internet.
With the "Firmware Update " program and a PC you can update the
firmware of the Multi 3430 to the newest version.
For the update you have to connect the meter to a PC.

For the update via the USB-B interface, the following is required:
z a free USB interface (virtual COM port) on the PC
z the driver for the USB interface (on the enclosed CD-ROM)
z the USB cable (included in the scope of delivery of the Multi 3430).

Program installation
1 Install the downloaded firmware update on a PC.

An update folder is created in the Windows start menu.


If an update folder already exists for the meter (or meter type),
the new data is displayed there.

Program start
2 In the windows start menu, open the update folder and start the
firmware update program.

Firmware update
3 Using the USB interface cable, connect the Multi 3430 to a
USB interface (virtual COM port) of the PC.
4 Switch on the Multi 3430.
5 In the firmware update program, start the update process with
OK.
6 Follow the instructions of the firmware update program.
During the programming process, a corresponding message
and a progress bar (in %) are displayed.
The programming process takes up to 30 minutes. A termina-
tory message is displayed after a successful programming pro-
cess. The firmware update is completed.
7 Disconnect the Multi 3430 from the PC.
The Multi 3430 is ready for operation again.

After switching the meter off and on you can check whether the meter
has taken over the new software version (see page 87).

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Appendix: Firmware update Multi 3430

98 ba75865e04 02/2010
Wissenschaftlich-Technische Werkstätten GmbH

Dr.-Karl-Slevogt-Straße 1
D-82362 Weilheim

Germany

Tel: +49 (0) 881 183-0


+49 (0) 881 183-100
Fax: +49 (0) 881 183-420
E-Mail: [email protected]
Internet: http://www.WTW.com

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