Multi 3430
Multi 3430
Multi 3430
Multi 3430
pH
ba75865e04 02/2010
Multi 3430
Accuracy when The use of advanced technology and the high quality standard of our instru-
going to press ments are the result of a continuous development. This may result in differ-
ences between this operating manual and your meter. Also, we cannot
guarantee that there are absolutely no errors in this manual. Therefore, we
are sure you will understand that we cannot accept any legal claims resulting
from the data, figures or descriptions.
2 ba75865e04 02/2010
Multi 3430 Contents
1 Overview . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 7
1.1 Keypad . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 8
1.2 Display . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 9
1.3 Socket field . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 11
1.4 Automatic sensor recognition . . . . . . . . . . . . . . . . . . . . . 12
1.5 IDS sensors. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 12
2 Safety . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 15
2.1 Authorized use . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 16
2.2 General safety instructions . . . . . . . . . . . . . . . . . . . . . . . 16
3 Commissioning . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 19
3.1 Scope of delivery. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 19
3.2 Power supply. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 19
3.3 Initial commissioning . . . . . . . . . . . . . . . . . . . . . . . . . . . . 19
3.3.1 Inserting the rechargeable batteries. . . . . . . . . . 19
3.3.2 Connecting the power pack / charging the
batteries ............................ 20
3.3.3 Switching on the meter. . . . . . . . . . . . . . . . . . . . 21
3.3.4 Setting the date and time . . . . . . . . . . . . . . . . . 21
4 Operation . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 23
4.1 Switching on the meter . . . . . . . . . . . . . . . . . . . . . . . . . . 23
4.2 General operating principles . . . . . . . . . . . . . . . . . . . . . . 24
4.2.1 Operating modes . . . . . . . . . . . . . . . . . . . . . . . . 24
4.2.2 Display of several sensors in the measuring mode
25
4.2.3 Navigation . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 26
4.2.4 Example 1 on navigation: Setting the language. 28
4.2.5 Example 2 on navigation: Setting the date and
time . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 30
4.3 Sensor-independent settings . . . . . . . . . . . . . . . . . . . . . 32
4.3.1 System . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 32
4.3.2 Data storage. . . . . . . . . . . . . . . . . . . . . . . . . . . . 34
4.3.3 Automatic Stability control . . . . . . . . . . . . . . . . . 34
4.4 Sensor info . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 34
4.5 Channel display. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 35
4.6 pH value . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 36
4.6.1 General information . . . . . . . . . . . . . . . . . . . . . . 36
4.6.2 Measuring the pH value . . . . . . . . . . . . . . . . . . . 37
ba75865de01 02/2010 3
Contents Multi 3430
6 What to do if... . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 87
4 ba75865de01 02/2010
Multi 3430 Contents
7 Technical data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 91
7.1 General data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 91
7.2 Measuring ranges, resolution, accuracy . . . . . . . . . . . . . 92
8 Lists . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 93
ba75865de01 02/2010 5
Contents Multi 3430
6 ba75865de01 02/2010
Multi 3430 Overview
1 Overview
The compact, digital precision meter Multi 3430 enables you to carry
out pH measurements, ORP measurements, conductivity measure-
ments and dissolved oxygen (D.O.) measurements quickly and reliably.
The Multi 3430 provides the maximum degree of operating comfort,
reliability and measuring certainty for all applications.
The Multi 3430 supports you in your work with the following functions:
z proven calibration procedures
z automatic stability control (AR),
z automatic sensor recognition,
z CMC (continuous measurement control)
z QSC (sensor quality control).
pH
1 Keypad
2 Display
3 Socket field
ba75865e04 02/2010 7
Overview Multi 3430
The two USB interfaces (USB-A and USB-B) enable you to:
z Transmit data to
– a USB memory device
– a PC
z Update the meter firmware.
1.1 Keypad
F1 F2
CAL AR
MENU
ENTER
Multi 3430
AR
<AR> Freezes the measured value (HOLD function)
Switches the AutoRead measurement on or off
8 ba75865e04 02/2010
Multi 3430 Overview
1.2 Display
3 4
5
7
1
22.09.2009 08:00
Info 8
1 Status information
2 Measured value (with unit)
3 Measured parameter
4 Continuous measurement control (CMC function)
5 Channel display:
Plug position of the sensor
6 Sensor symbol (calibration evaluation, calibration interval)
7 Measured temperature (with unit)
8 Softkeys and date + time
ba75865e04 02/2010 9
Overview Multi 3430
10 ba75865e04 02/2010
Multi 3430 Overview
5 1 2 3 4
Connectors:
1 Digital sensors
(pH, ORP, conductivity, D.O.)
2 Power pack
3 USB-A (Host) interface
4 USB B (Device) interface
5 Service interface
CAUTION
Only connect sensors to the meter that cannot return any voltages
or currents that are not allowed (> SELV and > current circuit with
current limiting).
WTW IDS sensors meet these requirements.
ba75865e04 02/2010 11
Overview Multi 3430
In digital IDS sensors, sensor data are stored that clearly identify the
sensor.
The sensor data are automatically taken over by the meter.
Note
Information on available IDS sensors is given on the Internet and in
the WTW catalog, "Laboratory and field instrumentation".
12 ba75865e04 02/2010
Multi 3430 Overview
Sensor data from IDS IDS sensors transmit the following sensor data to the meter:
sensors z SENSOR ID
– Sensor name
– Sensor series number
z Calibration data
– Calibration date
– Calibration characteristics
– Calibration interval
– Selected buffer set (IDS pH sensors only)
– Cell constant (IDS conductivity sensors only)
– Calibration history of the last 10 calibrations
z Measurement settings (IDS conductivity sensors only)
– The set measured parameter
– The set reference temperature
– The set temperature coefficient
– The set TDS factor
The calibration data are updated in the IDS sensor after each calibra-
tion procedure. A message is displayed while the data are being
updated in the sensor.
Note
In the measured value display, you can display the sensor name and
series number of the selected sensor with the [Info] softkey. You can
then display all further sensor data stored in the sensor with the [Plus]
softkey.
ba75865e04 02/2010 13
Overview Multi 3430
14 ba75865e04 02/2010
Multi 3430 Safety
2 Safety
This operating manual contains basic instructions that you must follow
during the commissioning, operation and maintenance of the meter.
Consequently, all responsible personnel must read this operating man-
ual before working with the meter.
The operating manual must always be available within the
vicinity of the meter.
Target group The meter was developed for work in the field and in the laboratory.
Thus, we assume that, as a result of their professional training and
experience, the operators will know the necessary safety precautions
to take when handling chemicals.
Safety instructions Safety instructions in this operating manual are indicated by the warn-
ing symbol (triangle) in the left column. The signal word (e.g. "Caution")
indicates the level of danger:
WARNING
indicates instructions that must be followed precisely in order to
avoid possibly great dangers to personnel.
CAUTION
indicates instructions that must be followed precisely in order to
avoid the possibility of slight injuries or damage to the meter or
the environment.
Further notes
Note
indicates notes that draw your attention to special features.
Note
indicates cross-references to other documents, e.g. operating manu-
als.
ba75865e04 02/2010 15
Safety Multi 3430
Function and The smooth functioning and operational safety of the meter can only be
operational safety guaranteed if the generally applicable safety measures and the specific
safety instructions in this operating manual are followed during opera-
tion.
The smooth functioning and operational safety of the meter can only be
guaranteed under the environmental conditions that are specified in
chapter 7 TECHNICAL DATA.
CAUTION
The meter is only allowed to be opened by authorized personnel.
16 ba75865e04 02/2010
Multi 3430 Safety
Safe operation If safe operation is no longer possible, the meter must be taken out of
service and secured against inadvertent operation!
Safe operation is no longer possible if the meter:
z has been damaged in transport
z has been stored under adverse conditions for a lengthy period of
time
z is visibly damaged
z no longer operates as described in this manual.
If you are in any doubt, please contact the supplier of the meter.
Obligations of the The purchaser of this meter must ensure that the following laws and
purchaser guidelines are observed when using dangerous substances:
z EEC directives for protective labor legislation
z National protective labor legislation
z Safety regulations
z Safety datasheets of the chemical manufacturers.
CAUTION
In addition to the safety instructions mentioned here, also follow
the safety instructions of the sensors used.
The operating manuals of the sensors are available on the sup-
plied CD and on the Internet under www.WTW.com.
ba75865e04 02/2010 17
Safety Multi 3430
18 ba75865e04 02/2010
Multi 3430 Commissioning
3 Commissioning
3.1 Scope of delivery
z Meter Multi 3430
z 4 NiMH rechargeable batteries 1.2 V Mignon type AA
z USB cable (A plug on mini B plug)
z Power pack
z Short instructions
z Detailed operating manual (4 languages)
z CD-ROM
ba75865e04 02/2010 19
Commissioning Multi 3430
CAUTION
Make sure that the poles of the rechargeable batteries are posi-
tioned correctly.
The ± signs on the batteries must correspond to the ± signs in the
battery compartment.
4 Close the battery compartment (2) and tighten the screws (1).
CAUTION
The line voltage at the operating site must lie within the input volt-
age range of the original power pack (see section 7.1).
CAUTION
Use original power packs only (see section 7.1).
CAUTION
The batteries in the battery compartment are automatically
charged when the power pack is connected.
Make sure that only NiMH rechargeable batteries are in the battery
compartment. The charging process is optimized for NiMH re-
chargeable batteries. Other battery types can cause damage dur-
ing the charging process.
20 ba75865e04 02/2010
Multi 3430 Commissioning
1 Connect the plug of the power pack to the socket for the power
pack on the Multi 3430.
2 Connect the original power pack to an easily accessible power
outlet.
Note
Charge the batteries completely prior to putting the meter into operation
for the first time. The charging process takes approx. 10 hours. The
symbol is displayed if the batteries are nearly discharged.
Note
The meter has an energy saving feature to avoid unnecessary power
consumption during battery operation.
The energy saving feature switches off the meter during battery opera-
tion if no key is pressed during the adjusted interval. (How to set the
switch-off interval, see section 4.3).
The switch-off interval of the energy saving feature is not active when
the meter is supplied with power via the power pack or the USB-B
cable.
ba75865e04 02/2010 21
Commissioning Multi 3430
22 ba75865e04 02/2010
Multi 3430 Operation
4 Operation
4.1 Switching on the meter
Switching on Press the <On/Off> key.
The meter performs a self-test.
The display shows the manufacturer's logo while the self-test is being
performed.
If a sensor is connected the measured value display appears.
Automatic switch-off The instrument has an automatic switchoff function in order to save the
batteries (see section 4.3.1). The automatic switchoff switches off the
measuring instrument if no key is pressed for an adjustable period.
Display illumination The meter automatically switches the display illumination to energy
saving mode if no key is pressed for 20 seconds.
After a further 60 seconds, the meter switches off the display illumina-
tion completely.
The illumination is switched on with the next keystroke again.
You can also generally switch on the display illumination (see section
4.3.1).
ba75865e04 02/2010 23
Operation Multi 3430
Operating elements, An overview of the operating elements and the display is given in sec-
display tion 1.1 and section 1.2.
Operating modes, An overview of the operating modes and navigation of the Multi 3430 is
navigation given in section 4.2.1 and section 4.2.3.
24 ba75865e04 02/2010
Multi 3430 Operation
With the softkey you can very easily switch between the two display
types. The suitable softkey is displayed depending on the operating sit-
uation.
ba75865e04 02/2010 25
Operation Multi 3430
4.2.3 Navigation
Menus and dialogs The menus for settings and dialogs in procedures contain further sub-
menus. The selection is made with the <S><T> keys. The current
selection is displayed with a frame.
z Submenus
The name of the submenu is displayed at the upper edge of the
frame. Submenus are opened by confirming with <MENU/ENTER>.
Example:
System
General
Interface
Clock function
Service information
Reset
22.09.2009 08:00
z Settings
Settings are indicated by a colon. The current setting is displayed on
the right-hand side. The setting mode is opened with <MENU/
ENTER>. Subsequently, the setting can be changed with <S><T>
and <MENU/ENTER>. Example:
26 ba75865e04 02/2010
Multi 3430 Operation
General
Language: Deutsch
Acoustic signal: Off
Volume 9
Illumination: On
Brightness: 12
Switchoff time: 1h
Temperature unit °C
Stability control On
22.09.2009 08:00
z Functions
Functions are designated by the name of the function. They are
immediately carried out by confirming with <MENU/ENTER>. Exam-
ple: Display the Calibration record function.
pH
Calibration record
Calibration data storage
Buffer: TEC
Single-point calibration: Yes
Calibration interval: 7d
Unit for slope: mV/pH
22.09.2009 08:00
pH
Calibration record:
Calibration data storage
Buffer: TEC
Single-point calibration: Yes
Calibration interval: 7d
Unit for slope: mV/pH
22.09.2009 08:00
Note
The principles of navigation are explained in the two following sections
by reference of examples:
z Setting the language (section 4.2.4)
z Setting the date and time (see section 4.2.5).
ba75865e04 02/2010 27
Operation Multi 3430
22.09.2009 08:00
28 ba75865e04 02/2010
Multi 3430 Operation
System
General
Interface
Clock function
Service information
Reset
22.09.2009 08:00
General
Language: Deutsch
Acoustic signal: Off
Illumination: On
Kontrast: 50 %
Switchoff time: 1h
22.09.2009 08:00
General
Language: Deutsch
Acoustic signal: Off
Illumination: On
Brightness: 50 %
Switchoff time: 1h
22.09.2009 08:00
ba75865e04 02/2010 29
Operation Multi 3430
The measuring instrument has a clock with a date function. The date
and time are indicated in the status line of the measured value display.
When storing measured values and calibrating, the current date and
time are automatically stored as well.
The correct setting of the date and time and date format is important for
the following functions and displays:
z Current date and time
z Calibration date
z Identification of stored measured values.
Note
After a fall of the supply voltage (empty batteries), the date and time are
reset to 01.08.2009 00, 00:00 hours.
Setting the date, time The date format can be switched from the display of day, month, year
and date format (dd.mm.yy) to the display of month, day, year (mm/dd/yy or mm.dd.yy).
30 ba75865e04 02/2010
Multi 3430 Operation
Clock function
Date format: dd.mm.yy
Date: 30.09.2009
Time: 14:53:40
22.09.2009 08:00
3 Select and confirm the Time menu with <S><T> and <MENU/
ENTER>.
The hours are highlighted.
4 Change and confirm the setting with <S><T> and <MENU/
ENTER>.
The minutes are highlighted.
5 Change and confirm the setting with <S><T> and <MENU/
ENTER>.
The seconds are highlighted.
6 Change and confirm the setting with <S><T> and <MENU/
ENTER>.
The time is set.
7 If necessary, set the Date and Date format. The setting is made
similarly to that of the time.
8 If necessary, select and set the Date with <S><T> and
<MENU/ENTER>.
9 To make further settings, switch to the next higher menu level
with <ESC>.
or
Switch to the measured value display with <MODE>.
The instrument is in the measuring operating mode.
ba75865e04 02/2010 31
Operation Multi 3430
4.3.1 System
Settings To open the Storage & config menu, press the <MENU/ENTER > key _
in the measured value display. After completing the settings, switch to
the measured value display with <MODE>.
Default settings are printed in bold.
32 ba75865e04 02/2010
Multi 3430 Operation
ba75865e04 02/2010 33
Operation Multi 3430
This menu contains all functions to display, edit and erase stored mea-
sured values.
Note
Detailed information on the storage functions of the Multi 3430 is given
in section 4.8.
You can activate or switch off the automatic Stability control function
(see section 4.6.3).
34 ba75865e04 02/2010
Multi 3430 Operation
SenTix 940
B092500013
More 30.09.2009 08:00
SenTix 940
B092500013
Man. temperature: 25°C
pH resolution 0.001
mV resolution 0.1
Buffer TEC
Calibration interval 7d
Unit for slope mV/pH
QSC:
30.09.2009 08:00
Channel display
Display of the plug position
for the respective parameter
The red bar indicates for
each connected sensor to
which plug position of the
meter it is connected.
ba75865e04 02/2010 35
Operation Multi 3430
4.6 pH value
Note
The sensor connection and the USB-B (device) interface are galvani-
cally isolated. This facilitates interference-free measurements also in
the following cases:
z Measurement in grounded test samples
z Measurement with several sensors connected to one Multi 3430 in
one test sample
Preparatory activities Perform the following preparatory activities when you want to measure:
36 ba75865e04 02/2010
Multi 3430 Operation
Stability control The stability control function (AutoRead) continually checks the stability
(AutoRead ) of the measurement signal. The stability has a considerable impact on
the reproducibility of measured values. The display of the measured
parameter flashes until a stable measured value is available.
You can start the Stability control manually at any time, irrespective of
the setting for automatic Stability control (see page 34) in the Measure-
ment menu.
ba75865e04 02/2010 37
Operation Multi 3430
Note
You can prematurely terminate the Stability control function manually
with <MENU/ENTER> at any time. If the Stability control function is pre-
maturely terminated, the current measurement data are output to the
interface without the AutoRead info.
Criteria for a stable The Stability control function checks whether the measured values are
measured value stable within the monitored time interval.
38 ba75865e04 02/2010
Multi 3430 Operation
Settings The settings are made in the menu for calibration and measurement
settings of the pH/ORP measurement. To open the settings, display the
required measured parameter in the measured value display and press
the <MENU/ENTER> key. After completing the settings, switch to the
measured value display with <MODE>.
Default settings are printed in bold.
ba75865e04 02/2010 39
Operation Multi 3430
40 ba75865e04 02/2010
Multi 3430 Operation
4.6.4 pH calibration
Why calibrate? During the operation of a pH sensor, the slope and asymmetry of the
sensor change with time. As a result, an inexact measured value is dis-
played. Calibration determines the current values of the zero point and
slope of the pH sensor and stores them in the measuring instrument.
Thus, you should calibrate at regular intervals.
Buffer sets for You can use the buffer sets quoted in the table for an automatic calibra-
calibration tion. The pH values are valid for the specified temperature values. The
temperature dependence of the pH values is taken into consideration
during the calibration.
ba75865e04 02/2010 41
Operation Multi 3430
42 ba75865e04 02/2010
Multi 3430 Operation
Note
The buffers are selected in the menu, pH / <MENU/ENTER> / Calibra-
tion / Buffer (see page 39).
ba75865e04 02/2010 43
Operation Multi 3430
Calibration points Calibration can be performed using one to five buffer solutions in any
order (single-point to five-point calibration). The meter determines the
following values and calculates the calibration line as follows:
Note
You can display the slope in the units, mV/pH or % (see page 39).
Stability control The calibration procedure automatically activates the stability control
function. The current measurement with stability control can be termi-
nated at any time (accepting the current value).
Calibration record The new calibration values are displayed when a calibration procedure
is completed.
Display calibration data You can have the data of the last calibration displayed (see page 53).
and output to interface Subsequently, you can transmit the displayed calibration data to the
interface, e. g. to a PC, with the <PRT> key.
Note
The calibration record is automatically transmitted to the interface after
calibrating.
44 ba75865e04 02/2010
Multi 3430 Operation
Sample record
31.07.2009 15:55
Multi 3430
Ser. no. 09250023
CALIBRATIONpH
31.07.2009 16:13:33
SenTix 940
Ser. no. B092500013
AutoCal TEC
Buffer 1 4.01
Buffer 2 7.00
Buffer 3 10.01
Voltage 1 184.0 mV 24.0 °C
Voltage 2 3.0 mV 24.0 °C
Voltage 3 -177.0 mV 24.0 °C
Slope -60.2 mV/pH
Asymmetry 4.0 mV
Sensor +++
etc...
Calibration evaluation After calibrating, the meter automatically evaluates the calibration. The
zero point and slope are evaluated separately. The worse evaluation of
both is taken into account. The evaluation appears on the display and
in the calibration record.
Note
For pH IDS sensors you can optionally enable a more finely graded cal-
ibration evaluation (QSC) (see section 4.6.10).
ba75865e04 02/2010 45
Operation Multi 3430
Preparatory activities Perform the following preparatory activities when you want to calibrate:
After the specified calibration interval has expired the sensor symbol or
the QSC color scale flashes. It is still possible to measure.
Note
To ensure the high measuring accuracy of the measuring system, cal-
ibrate after the calibration interval has expired.
Setting the calibration The calibration interval is set to 7 days (d7) in the factory.
interval You can change the interval (1 ... 999 days):
46 ba75865e04 02/2010
Multi 3430 Operation
Make sure that in the sensor menu, Buffer menu, the buffer set is cor-
rectly selected (see page 39).
Use any one to five buffer solutions of the selected buffer set in ascend-
ing or descending order.
Note
If single-point calibration was set in the menu, the calibration procedure
is automatically finished with the measurement of buffer solution 1 and
the calibration record is displayed.
30.09.2009 08:00
ba75865e04 02/2010 47
Operation Multi 3430
30.09.2009 08:00
30.09.2009 08:00
Note
For single-point calibration, the instrument uses the Nernst slope
(-59.2 mV/pH at 25 °C) and determines the zero point of the IDS pH
sensor.
48 ba75865e04 02/2010
Multi 3430 Operation
30.09.2009 08:00
30.09.2009 08:00
ba75865e04 02/2010 49
Operation Multi 3430
30.09.2009 08:00
Note
Calibration is automatically completed after the last buffer of a buffer
set has been measured. Then the calibration record is displayed.
Note
The calibration line is determined by linear regression.
50 ba75865e04 02/2010
Multi 3430 Operation
Single-point calibration Use any buffer solution for this rapid method.
The calibration will be the more exact the nearer the pH value of the
buffer solution is to that of the test sample.
To carry out this procedure, ConCal has to be set as the buffer set (se
section 4.6.3) in the Buffer menu of the sensor menu.
Note
If single-point calibration was set in the menu, the calibration procedure
is automatically finished with the measurement of buffer solution 1 and
the calibration record is displayed.
30.09.2009 08:00
ba75865e04 02/2010 51
Operation Multi 3430
30.09.2009 08:00
30.09.2009 08:00
Note
For single-point calibration, the instrument uses the Nernst slope
(-59.2 mV/pH at 25 °C) and determines the zero point of the IDS pH
sensor.
52 ba75865e04 02/2010
Multi 3430 Operation
30.09.2009 08:00
13 Take over the calibration value for the slope with <MENU/
ENTER>.
The calibration is completed as a two-point calibration.
The calibration record is displayed.
The calibration data can be displayed and then output to the interface.
Displaying the The calibration record of the last calibration is to be found under the
calibration record menu item, Calibration / Calibration record. To open it in the measured
_
value display, press the <CAL > key.
ba75865e04 02/2010 53
Operation Multi 3430
Sample printout
31.07.2009 16:55
Multi 3430
Ser. no. 09250023
CALIBRATIONpH
SenTix 940
Ser. no. B092500013
31.07.2009 16:13:33
AutoCal TEC
Buffer 1 4.01
Buffer 2 7.00
Buffer 3 10.01
Voltage 1 184.0 mV 24.0 °C
Voltage 2 3.0 mV 24.0 °C
Voltage 3 -177.0 mV 24.0 °C
Slope -60.2 mV/pH
Asymmetry 4.0 mV
Sensor +++
etc...
54 ba75865e04 02/2010
Multi 3430 Operation
1
2
3
4
The limits of the calibrated range are determined by the buffers used
for calibration:
ba75865e04 02/2010 55
Operation Multi 3430
General information The QSC function (Quality Sensor Control) is a new sensor evaluation
on the QSC function for digital IDS sensors. It evaluates the condition of an IDS pH sensor
individually and with a very fine grading.
On the display, the QSC color scale (from green to yellow) indicates the
current sensor evaluation by means of a pointer.
The finely graded sensor evaluation of the QSC function promptly calls
your attention to changes of the sensor.
Thus you can do what is necessary to restore the optimum measuring
quality (e.g. clean, calibrate or replace the sensor).
Low tolerances for zero point Greater tolerances for zero point
and slope when using QSC buf- and slope when using commer-
fer solutions cial buffer sets
56 ba75865e04 02/2010
Multi 3430 Operation
QSC calibration The QSC function is enabled by once carrying out an additional three-
point calibration with special QSC buffer solutions. It covers the mea-
suring range of the sensor from pH 2 to pH 11. The QSC initial calibra-
tion determines the actual condition of the sensor and stores it as a
reference in the sensor.
To meet the high requirements of a QSC initial calibration, the QSC ini-
tial calibration should optimally be carried out with the initial commis-
sioning of the sensor.
Carry out the normal calibrations for your special measuring range with
your usual standard solutions as previously done.
Note
As soon as the QSC function was enabled for an IDS sensor, it is not
possible to return to the sensor evaluation with the sensor symbol for
this sensor.
22.09.2009 08:00
Note
Carry out the QSC initial calibration very carefully. It determines the ref-
erence value for the sensor. This reference value cannot be overwritten
or reset.
As soon as the QSC function was enabled, it is not possible to return to
the sensor evaluation with the sensor symbol.
ba75865e04 02/2010 57
Operation Multi 3430
You can carry out QSC control calibrations at greater intervals than
normal calibrations.
A QSC control calibration can, e.g. be useful if the sensor evaluation
noticeably changed (after some normal calibrations).
58 ba75865e04 02/2010
Multi 3430 Operation
Note
The sensor connection and the USB-B (device) interface are galvani-
cally isolated. This facilitates interference-free measurements also in
the following cases:
z Measurement in grounded test samples
z Measurement with several sensors connected to one Multi 3430 in
one test sample
Preparatory activities Perform the following preparatory activities when you want to measure:
Note
IDS ORP sensors are not calibrated. However, you can check IDS
ORP sensors using a test solution.
ba75865e04 02/2010 59
Operation Multi 3430
Stability control The stability control function (AutoRead) continually checks the stability
(AutoRead ) of the measurement signal. The stability has a considerable impact on
the reproducibility of measured values. The display of the measured
parameter flashes until a stable measured value is available.
You can start the Stability control manually at any time, irrespective of
the setting for automatic Stability control (see page 34) in the System
menu.
Note
You can prematurely terminate the Stability control function manually
with <MENU/ENTER> at any time. If the Stability control function is pre-
maturely terminated, the current measurement data are not output to
the interface.
Criteria for a stable The Stability control function checks whether the measured values are
measured value stable within the monitored time interval.
60 ba75865e04 02/2010
Multi 3430 Operation
Settings The settings are made in the menu for measuring settings of the ORP
measurement. To open the settings, display the required measured
parameter in the measured value display and press the <MENU/
ENTER> key. After completing the settings, switch to the measured
value display with <MODE>.
Default settings are printed in bold.
ba75865e04 02/2010 61
Operation Multi 3430
Dear customer:
To carry out D.O. measurements with the Multi 3430, the digital D.O.
sensor FDO 925 is required.
The D.O. sensor FDO 925 is not yet available at present. Therefore, the
D.O. measuring function is not implemented in the current meter soft-
ware (firmware) of the Multi 3430 and not described in the operating
manual at hand.
After you have carried out the software update, all functions for D.O.
measurement will be available at your Multi 3430.
62 ba75865e04 02/2010
Multi 3430 Operation
4.9 Conductivity
Temperature IDS sensors measure the temperature with a temperature sensor inte-
measurement grated in the IDS sensor.
Preparatory activities Perform the following preparatory activities when you want to measure:
4.9.2 Measuring
ba75865e04 02/2010 63
Operation Multi 3430
Selecting the You can switch between the following displays with <M>:
displayed z Conductivity [μS/cm] / [mS/cm]
measured parameter
z Resistivity [Ω·cm] / [kΩ·cm] / [MΩ·cm]
z Salinity SaL [ ]
z Total dissolved solids TDS [mg/l] / [g/l]
The factor to calculate the total dissolved solids is set to 1.00 in the fac-
tory. You can adjust this factor to meet your requirements in the range
of 0.40 to 1.00. The factor is set in the Measurement menu for the
parameter, TDS.
Freezing the measured With the HOLD function, you can freeze the current measured value.
value (HOLD function) The displayed measured value stops changing until you switch the
HOLD function off.
Note
If the HOLD function is active, you can, e.g. start a manual measure-
ment with stability control.
Stability control The stability control function (AutoRead) continually checks the stability
(AutoRead ) of the measurement signal. The stability has a considerable impact on
the reproducibility of measured values. The display of the measured
parameter flashes until a stable measured value is available.
You can start the Stability control manually at any time, irrespective of
the setting for automatic Stability control (see page 34) in the Measure-
ment menu.
64 ba75865e04 02/2010
Multi 3430 Operation
Note
You can prematurely terminate the Stability control function manually
with <MENU/ENTER> at any time. If the Stability control function is pre-
maturely terminated, the current measurement data are not output to
the interface.
Criteria for a stable The Stability control function checks whether the measured values are
measured value stable within the monitored time interval.
ba75865e04 02/2010 65
Operation Multi 3430
Note
The reference temperature and temperature compensation are set in
the Measurement menu for the parameter, conductivity (see section
4.9.4).
Application tips Select the following temperature compensations given in the table
according to the respective test sample:
66 ba75865e04 02/2010
Multi 3430 Operation
Overview The following settings are possible for IDS conductivity sensors:
z Calibration record (display)
z Calibration interval
z Reference temperature
z Temperature compensation
z TDS factor
z Unit of the temperature
z Automatic Stability control
Settings The settings are made in the Measurement menu for the measured
parameter, conductivity. To open the settings, display the required
measured parameter in the measured value display and press the
<MENU/ENTER> key. After completing the settings, switch to the mea-
sured value display with <MODE>.
The possible settings are individually displayed for each sensor. Below
the setting menu is displayed for two IDS sensors (TetraCon 925,
LR325/01).
Default settings are printed in bold.
ba75865e04 02/2010 67
Operation Multi 3430
68 ba75865e04 02/2010
Multi 3430 Operation
ba75865e04 02/2010 69
Operation Multi 3430
Why determine the cell Aging slightly changes the cell constant, e. g. due to coatings. As a
constant? result, an inexact measured value is displayed. The original character-
istics of the cell can often be restored by cleaning the cell. Calibration
determines the current value of the cell constant and stores this value
in the meter.
Thus, you should calibrate at regular intervals (we recommend: every
6 months).
Procedure You can determine the actual cell constant of the IDS conductivity sen-
sor cell by calibrating with the control standard in the following range:
z 0.450 ... 0.500 cm-1
(e.g. TetraCon 925, nominal cell constant 0.475)
The cell constant is determined in the control standard, 0.01 mol/l KCl.
In the delivery condition, the calibrated cell constant of the IDS sensor
is set to 0.475 cm-1 (conductivity measuring cell, TetraCon 925).
Display calibration data You can have the data of the last calibration displayed (see section
and output to interface 4.9.6). Subsequently, you can transmit the displayed calibration data to
the interface, e. g. to a printer or PC, with the <PRT> key.
Note
The calibration record is automatically transmitted to the interface after
calibrating.
Sample record:
31.07.2009 16:55:12
Multi 3430
Ser. no. 09250023
CALIBRATION Cond
TetraCon 925
Ser. no. 09250033
31.07.2009 16:13:33
Calibration evaluation After the calibration, the meter automatically evaluates the current sta-
tus of the calibration. The evaluation appears on the display and in the
calibration record.
70 ba75865e04 02/2010
Multi 3430 Operation
Determining the cell For this calibration procedure, the Measuring cell setting must be set to
constant cal in the Measurement menu. Proceed as follows to determine the cell
constant:
30.09.2009 08:00
ba75865e04 02/2010 71
Operation Multi 3430
The calibration data can be displayed and then output to the interface.
Displaying the The calibration record of the last calibration is to be found under the
calibration record menu item, Calibration / Calibration record. To open it in the measured
_
value display, press the <CAL > key.
72 ba75865e04 02/2010
Multi 3430 Operation
Storage locations The Multi 3430 meter has two measurement data memories. The mea-
sured values recorded either manually or automatic are stored sepa-
rately in individual measurement data memories.
ba75865e04 02/2010 73
Operation Multi 3430
ID number: 1
Continue
22.09.2009 08:00
If the storage is full When all memory locations are occupied, it is not possible to continue
storing. Then you can e.g. transmit the stored data to a PC or a USB
flash drive (see section 4.10.3) and subsequently erase the storage
(see section 4.10.4).
74 ba75865e04 02/2010
Multi 3430 Operation
Configuring the
automatic storage
1 Press the <STO > key. _
The menu for automatic storage appears.
function
Automatic data storage
ID number 1 Adjusted entire storage
Interval 30 s duration
Duration 180 min
Continue
Max. available storage
0d03h00min duration
0 1d17h33min
22.09.2009 08:00
Graphical display of the
storage usage
Settings You can configure the automatic storage function with the following set-
tings:
ba75865e04 02/2010 75
Operation Multi 3430
Starting the automatic To start the automatic storage function, select Continue with <S><T>
storage function and confirm with <MENU/ENTER>. The meter switches to the mea-
sured value display.
30.09.2009 08:00
Note
If the automatic storage function is activated, only the following keys
_
are active: <MODE>, <STO > and <On/Off>. The other keys and the
automatic switch-off function are deactivated.
Terminating the Proceed as follows to switch off the automatic storage function before
automatic storage the adjusted storage duration has expired:
function prematurely
1 Press the <STO > key. _
The following window appears.
Warning
Yes
No
22.09.2009 08:00
76 ba75865e04 02/2010
Multi 3430 Operation
Editing the data storage The storage is edited in the menu, Storage & config / Data storage. To
_
open the Storage & config menu, press the <MENU/ENTER > key in
the measured value display.
Note
The settings are explained here using the manual storage as an exam-
ple. The same settings and functions are available for the automatic
storage.
ba75865e04 02/2010 77
Operation Multi 3430
22.09.2009 08:00
Sample printout
31.07.2009 09:56:20
Multi 3430
Ser. no. 09250023
SenTix 940
Ser. no. B092500013
ID number 2
pH 6.012 24.8 °C, AR, Sensor: +++
________________________________________
31.07.2009 10:56:20
Multi 3430
Ser. no. 09250023
SenTix 940
Ser. no. B092500013
ID number 2
pH 6.012 24.8 °C, AR, Sensor: +++
________________________________________
etc...
Quitting the display To quit the display of stored measurement datasets, you have the fol-
lowing options:
z Switch directly to the measured value display with <MODE>.
z Quit the display and move to the next higher menu level with
<ESC>.
78 ba75865e04 02/2010
Multi 3430 Operation
Via the USB-B interface (USB Device) you can transmit data to a PC or
printer and update the meter software.
Installation of the USB System requirements of the PC for installation of the USB driver:
driver on the PC
z PC with at least one free USB connection and CD-ROM drive
z Windows 2000, XP, Vista.
ba75865e04 02/2010 79
Operation Multi 3430
Connect the USB-A interface (USB Host) of the Multi 3430 to a USB
flash drive.
80 ba75865e04 02/2010
Multi 3430 Operation
Via the USB-B interface you can transmit data to a PC. Via the USB-A
interface you can transmit data to a USB memory device. The following
table shows which data are transmitted to the interface in which way:
Note
The following rule applies: With the exception of the menus, shortly
pressing the <PRT> key generally outputs the display contents to the
interface (displayed measured values, measuring datasets, calibration
records).
ba75865e04 02/2010 81
Operation Multi 3430
4.12 Reset
You can reset (initialize) all sensor settings and sensor-independent
settings separately from each other.
Note
The calibration data are reset to the default settings together with the
measuring parameters. Recalibrate after performing a reset.
The sensor settings are reset under the Reset menu item in the menu
for calibration and measurement settings. To open the settings, display
the required measured parameter in the measured value display and
press the <MENU/ENTER> key.
82 ba75865e04 02/2010
Multi 3430 Operation
ORP The following settings for ORP measurements are reset to the default
settings with the Reset function:
The sensor settings are reset under the Reset menu item in the menu
for calibration and measurement settings. To open the settings, display
the required measured parameter in the measured value display and
press the <MENU/ENTER> key.
Conductivity The following settings for conductivity measurements are reset to the
default settings with the Reset function:
The sensor settings are reset under the Reset menu item in the menu
for calibration and measurement settings. To open the settings, display
the required measured parameter in the measured value display and
press the <MENU/ENTER> key.
ba75865e04 02/2010 83
Operation Multi 3430
The system settings are reset in the menu, Storage & config / System
/ Reset. To open the Storage & config menu, press the <MENU/
_
ENTER > key in the measured value display.
84 ba75865e04 02/2010
Multi 3430 Maintenance, cleaning, disposal
Note
See the relevant operating manuals of the IDS sensors for instructions
on maintenance.
CAUTION
Make sure that the poles of the rechargeable batteries are posi-
tioned correctly.
The ± signs on the batteries must correspond to the ± signs in the
battery compartment.
ba75865e04 02/2010 85
Maintenance, cleaning, disposal Multi 3430
5 Close the battery compartment (2) and tighten the screws (1).
5.2 Cleaning
Occasionally wipe the outside of the measuring instrument with a
damp, lint-free cloth. Disinfect the housing with isopropanol as
required.
CAUTION
The housing is made of synthetic material (ABS). Thus, avoid con-
tact with acetone or similar detergents that contain solvents. Re-
move any splashes immediately.
5.3 Packing
This meter is sent out in a protective transport packing.
We recommend: Keep the packing material. The original packing pro-
tects the meter against damage during transport.
5.4 Disposal
Note
This meter contains rechargeable batteries. Batteries that have been
removed must only be disposed of at a recycling facility set up for this
purpose or via the retail outlet.
It is illegal to dispose of the batteries in household refuse.
86 ba75865e04 02/2010
Multi 3430 What to do if...
6 What to do if...
6.1 General information
Cause Remedy
– Batteries almost empty – Charge the batteries (see
section 3.3.2 CONNECTING
Display THE POWER PACK / CHARGING
THE BATTERIES)
– Replace the batteries (see
section 5.1 MAINTENANCE)
ba75865e04 02/2010 87
What to do if... Multi 3430
6.2 pH
Error message
OFL, UFL Cause Remedy
IDS pH sensor:
– Measured value outside the – Use suitable IDS pH sensor
measuring range
– Air bubble in front of the dia- – Remove air bubble
phragm
– Air in the diaphragm – Extract air or moisten dia-
phragm
– Cable broken – Exchange IDS pH sensor
– Gel electrolyte dried out – Exchange IDS pH sensor
88 ba75865e04 02/2010
Multi 3430 What to do if...
Test sample:
– pH value not stable – Measure with air excluded if
necessary
– Temperature not stable – Adjust temperature if neces-
sary
ba75865e04 02/2010 89
What to do if... Multi 3430
6.3 Conductivity
Error message,
OFL Cause Remedy
– Measured value outside the – Use suitable IDS conductiv-
measuring range ity sensor
90 ba75865e04 02/2010
Multi 3430 Technical data
7 Technical data
7.1 General data
ba75865e04 02/2010 91
Technical data Multi 3430
92 ba75865e04 02/2010
Multi 3430 Lists
8 Lists
This chapter provides additional information and orientation aids.
Specialist terms The glossary briefly explains the meaning of the specialist terms. How-
ever, terms that should already be familiar to the target group are not
described here.
Index The index will help you to find the topics that you are looking for.
Glossary
Adjusting To manipulate a measuring system so that the relevant value (e. g. the
displayed value) differs as little as possible from the correct value or
a value that is regarded as correct, or that the difference remains with-
in the tolerance.
Asymmetry see zero point
AutoRange Name of the automatic selection of the measuring range.
Calibration Comparing the value from a measuring system (e. g. the displayed
value) to the correct value or a value that is regarded as correct. Of-
ten, this expression is also used when the measuring system is adjust-
ed at the same time (see adjusting).
Electromotive force of The electromotive force U of the combination electrode is the measur-
an electrode able electromotive force of an electrode in a solution. It equals the
sum of all the galvanic voltages of the combination electrode. Its de-
pendency on the pH results in the electrode function, which is charac-
terized by the parameters, slope and zero point.
Junction The junction is a porous body in the housing wall of reference elec-
trodes or electrolyte bridges. It arranges the electrical contact be-
tween two solutions and makes the electrolyte exchange more
difficult. The expression, junction, is also used for ground or junction-
less transitions.
Measured parameter The measured parameter is the physical dimension determined by
measuring, e. g. pH, conductivity or D.O. concentration.
Measured value The measured value is the special value of a measured parameter to
be determined. It is given as a combination of the numerical value and
unit (e. g. 3 m; 0.5 s; 5.2 A; 373.15 K).
ba75865e04 02/2010 93
Lists Multi 3430
94 ba75865e04 02/2010
Multi 3430 Index
Authorized use . . . . . . . . . . . . . . . . . . . . . . 16 M
Automatic switch-off . . . . . . . . . . . . . . . . . . 23 Measured value display . . . . . . . . . . . . . . . 26
AutoRead . . . . . . . . . . . . . . . . . . . . . . . . . . 64 Measurement accuracy . . . . . . . . . . . . . . . 46
ORP . . . . . . . . . . . . . . . . . . . . . . . . . . . 60 Measurement data storage
pH . . . . . . . . . . . . . . . . . . . . . . . . . . . . 37 Edit . . . . . . . . . . . . . . . . . . . . . . . . . . . . 77
Erase . . . . . . . . . . . . . . . . . . . . . . . . . . 77
B Storage locations . . . . . . . . . . . . . . . . . 73
Battery compartment . . . . . . . . . . . . . . 19, 85 Measurement dataset . . . . . . . . . . . . . . . . 73
Measuring . . . . . . . . . . . . . . . . . . . . . . . . . 63
C ORP voltage . . . . . . . . . . . . . . . . . . . . 59
Calibration . . . . . . . . . . . . . . . . . . . . . . . . . 70 pH . . . . . . . . . . . . . . . . . . . . . . . . . . . . 37
pH . . . . . . . . . . . . . . . . . . . . . . . . . . . . 41 Menu for calibration and measurement settings
Calibration evaluation . . . . . . . . . . . . . . . . 70 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 67
pH . . . . . . . . . . . . . . . . . . . . . . . . . . . . 45 pH/ORP . . . . . . . . . . . . . . . . . . . . . 39, 61
Calibration interval . . . . . . . . . . . . . . . . . . . 46 Menus (navigation) . . . . . . . . . . . . . . . . . . 26
Calibration points Messages . . . . . . . . . . . . . . . . . . . . . . . . . 27
pH . . . . . . . . . . . . . . . . . . . . . . . . . . . . 44
calibration records . . . . . . . . . . . . . . . . 53, 72 O
Cell constant . . . . . . . . . . . . . . . . . . . . . . . 70 Operational safety . . . . . . . . . . . . . . . . . . . 16
Connect the power pack . . . . . . . . . . . . . . 20
Connecting a PC . . . . . . . . . . . . . . . . . 79, 80 P
pH buffer sets . . . . . . . . . . . . . . . . . . . . . . 41
D Precautions . . . . . . . . . . . . . . . . . . . . . . . . 15
Dataset . . . . . . . . . . . . . . . . . . . . . . . . . . . . 73 Print . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 81
Date and time . . . . . . . . . . . . . . . . . . . . . . . 30
Default settings R
Measured parameter . . . . . . . . . . . . . . 82 Reset . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 82
System settings . . . . . . . . . . . . . . . . . . 84 RS232 interface . . . . . . . . . . . . . . . . . . . . . 80
Display . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 9
S
E Safety . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 15
Energy saving feature . . . . . . . . . . . . . . . . 21 Scope of delivery . . . . . . . . . . . . . . . . . . . . 19
Setting the date . . . . . . . . . . . . . . . . . . . . . 21
F Setting the time . . . . . . . . . . . . . . . . . . . . . 21
Firmware update . . . . . . . . . . . . . . . . . . . . 97 Single-point calibration
pH . . . . . . . . . . . . . . . . . . . . . . 48, 51, 52
I Slope
Initial commissioning . . . . . . . . . . . . . . 19, 21 pH . . . . . . . . . . . . . . . . . . . . . . . . . . . . 41
Initialize . . . . . . . . . . . . . . . . . . . . . . . . . . . 82 Socket field . . . . . . . . . . . . . . . . . . . . . . . . 11
Interval for calibration . . . . . . . . . . . . . . . . . 46 Stability control
automatic . . . . . . . . . . . . . . . . . . . . . . . 34
Storage interval . . . . . . . . . . . . . . . . . . . . . 75
K Storing in memory . . . . . . . . . . . . . . . . . . . 62
Keys . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 8 Automatic . . . . . . . . . . . . . . . . . . . . . . . 75
Manual . . . . . . . . . . . . . . . . . . . . . . . . . 74
ba75865e04 02/2010 95
Index Multi 3430
T
Temperature compensation . . . . . . . . . . . 66
Temperature measurement . . . . . . . . . . . . 63
pH . . . . . . . . . . . . . . . . . . . . . . . . . . . . 36
Three-point calibration
pH . . . . . . . . . . . . . . . . . . . . . . . . . . . . 49
Transmitting data . . . . . . . . . . . . . . . . . . . 79
Transmitting measured values . . . . . . . . . 79
Two-point calibration
pH . . . . . . . . . . . . . . . . . . . . . . 48, 51, 53
Z
Zero point of pH combination electrode . . 41
96 ba75865e04 02/2010
Multi 3430 Appendix: Firmware update
For the update via the USB-B interface, the following is required:
z a free USB interface (virtual COM port) on the PC
z the driver for the USB interface (on the enclosed CD-ROM)
z the USB cable (included in the scope of delivery of the Multi 3430).
Program installation
1 Install the downloaded firmware update on a PC.
Program start
2 In the windows start menu, open the update folder and start the
firmware update program.
Firmware update
3 Using the USB interface cable, connect the Multi 3430 to a
USB interface (virtual COM port) of the PC.
4 Switch on the Multi 3430.
5 In the firmware update program, start the update process with
OK.
6 Follow the instructions of the firmware update program.
During the programming process, a corresponding message
and a progress bar (in %) are displayed.
The programming process takes up to 30 minutes. A termina-
tory message is displayed after a successful programming pro-
cess. The firmware update is completed.
7 Disconnect the Multi 3430 from the PC.
The Multi 3430 is ready for operation again.
After switching the meter off and on you can check whether the meter
has taken over the new software version (see page 87).
ba75865e04 02/2010 97
Appendix: Firmware update Multi 3430
98 ba75865e04 02/2010
Wissenschaftlich-Technische Werkstätten GmbH
Dr.-Karl-Slevogt-Straße 1
D-82362 Weilheim
Germany