ULTRAZOL 8219H

PRODUCT DISTRIBUTED BY / PRODUIT DISTRIBUÉ PAR

Brenntag Canada Inc. WHMIS Number: 00067349

43 Jutland Road. Index: HCI6489/09B
Toronto, Ontario Effective Date: 2009 May 27
M8Z 2G6 Date of Revision: 2009 May 27
(416) 259-8231 Website: http://www.brenntag.ca
_______________________________________________________________________________________________

EMERGENCY TELEPHONE NUMBERS / EN CAS D'URGENCE

Toronto, ON (416) 226-6117 Montréal, QC (514) 861-1211 Winnipeg, MB (204) 943-8827

Edmonton, AB (780) 424-1754 Calgary, AB (403) 263-8660 Vancouver, BC (604) 685-5036
_______________________________________________________________________________________________

This document consists of an English and French MSDS.

Le présent document comprend une fiche signalétique en anglais et en français.

WHMIS Classification / Symbol: B-2: Flammable Liquid; D-2A: Very Toxic (Carcinogen).
Classification / symbole SIMDUT : B-2 : Liquide inflammable ; D-2A : Très toxique (cancérogène).

READ THE ENTIRE MSDS FOR THE COMPLETE HAZARD EVALUATION OF THIS PRODUCT.

LIRE LA FICHE SIGNALÉTIQUE EN ENTIER POUR UNE ÉVALUATION COMPLÈTE DES DANGERS QUE
REPRÉSENTE CE PRODUIT
LUBRIZOL® 8219H

Material Safety Data Sheet

LUBRIZOL® 8219H

Prepared according to 29CFR 1910.1200.

1 Chemical Product and Company Identification

The Lubrizol Corporation

29400 Lakeland Boulevard
Wickliffe, Ohio 44092
Tel: (440) 943-4200

Product Trade Name LUBRIZOL® 8219H

CAS Number Not applicable for mixtures.
Synonyms None.
Generic Chemical Name Mixture.
Product Type Gasoline additive.
Preparation/Revision Date 27 May 2009
Transportation Emergency FOR TRANSPORT EMERGENCY call CHEMTREC: (+1) 703-527-3887 (outside the
Phone No. U.S.), 1-800-424-9300 (in the U.S.)
MSDS No. 17208533-1221915-4021930-102103

2 Hazards Identification

Appearance Clear liquid.

Odor Aromatic hydrocarbon
Principal Hazards Danger.

Flammable liquid. may create a flash fire hazard.

Harmful if inhaled.

Causes respiratory tract irritation.

May be harmful if absorbed through skin.

May cause eye irritation.

May cause skin irritation.

Contains components which may cause cancer.

May cause chronic health effects.

Target Organs: Blood Central nervous system Heart Kidney Liver

See Section 11 for complete health hazard information.

3 Composition/Information on Ingredients

Hazardous Ingredients
Comp CAS No. Percentage (by wt.) Carcinogen
Xylene 1330-20-7 37.9% N/E

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Ethylbenzene 100-41-4 9.5% IARC Suspect Carcinogen

Petroleum naphtha 64742-94-5 From 1 to 4.9 percent N/E
Polyether amine Confidential. From 1 to 4.9 percent N/E
Naphthalene 91-20-3 0.5% IARC Suspect Carcinogen NTP Carcinogen

(N/E) - None established

4 First Aid Measures

Eyes Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy
to do. Continue rinsing. If eye irritation persists, get medical attention.
Skin Wash with soap and water for 20 minutes or until chemical is removed. Immediately remove
contaminated clothing. Get medical attention if irritation develops. Launder contaminated
clothing before reuse.
Inhalation Remove exposed person to fresh air. If breathing is labored, administer oxygen. If breathing
has stopped, apply artificial respiration. Call a poison center or doctor if you feel unwell.
Oral DO NOT INDUCE VOMITING. Get immediate medical attention. Never give anything by
mouth to a person who is losing consciousness, unconscious or convulsing. Call a poison
center or doctor if exposed or you feel unwell.
Additional Information If exposed or concerned: Get medical attention.

5 Fire Fighting Measures

Flash Point 32 °C, 89.6 °F PMCC (Typical)

Extinguishing Media CO2, dry chemical, or foam. Water can be used to cool and protect exposed material.
Firefighting Procedures Recommend wearing self-contained breathing apparatus. Water may cause splattering.
Unusual Fire & Explosion Toxic fumes, gases or vapors may evolve on burning. Vapors may be heavier than air and
Hazards may travel along the ground to a distant ignition source and flash back. Container may
rupture on heating.

6 Accidental Release Measures

Spill Procedures May form explosive mixtures with air. Immediately evacuate all personnel from danger area.
Personal Protective Equipment must be worn, see Personal Protection Section for PPE
recommendations. Eliminate all sources of heat, sparks pilot lights, static electricity and open
flames. Ventilate spill area. Prevent entry into sewers and waterways, dispose of in
accordance with all federal, state and local environmental regulation. Pick up free liquid for
recycle and/or disposal if can be accomplished safely with explosion proof equipment.
Residual liquid can be absorbed on inert material. Check under Transportation and Labeling
(DOT/CERCLA) and Other Regulatory Information Section (SARA) for hazardous
substances to determine regulatory reporting requirements for spills.

7 Handling and Storage

Pumping Temperature Not determined.

Maximum Handling
Not determined.
Temperature
Handling Procedures Keep away from ignition sources such as heat, sparks and open flame. No smoking. Keep
containers closed when not in use. Do not discharge into drains or the environment, dispose
to an authorized waste collection point. Use appropriate containment to avoid environmental
contamination. Avoid breathing dust, fume, gas, mist, vapors or spray. Ground / bond
container and receiving equipment. Use explosion-proof equipment. Use only non-sparking
tools. Wash thoroughly after handling. Empty containers retain material residue. Do not cut,

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LUBRIZOL® 8219H

weld, braze, solder, drill, grind or expose containers to heat, flame, spark or other sources of
ignition.
Maximum Storage
Not determined.
Temperature
Storage Procedures Do not store near potential sources of ignition. Isolated outside storage is preferred. Inside
storage area should be in a flammable liquids cabinet or storage area. Store in a cool, dry,
well-ventilated area. Keep container tightly closed.
Loading Temperature Not determined.

8 Exposure Controls/Personal Protection

Exposure Limits
Exposure Guidelines
OSHA ACGIH Other
Comp TWA STEL TWA STEL TWA STEL
Xylene 100 ppm N/E 100 ppm 150 ppm N/E N/E
Ethylbenzene 100 ppm N/E 100 ppm 125 ppm N/E N/E
Petroleum
N/E N/E N/E N/E 100 ppm (l) N/E
naphtha
Naphthalene 10 ppm N/E 10 ppm (s) 15 ppm N/E N/E

(s) - Skin exposure

(p) - Proposed limit
(c) - Ceiling exposure
(l) - Recommended exposure limit
(u) - Supplier recommended exposure limit
(N/E) - None established
Other Exposure Limits None known.
Engineering Controls Use material in well ventilated area only. Additional ventilation or exhaust may be required
to maintain air concentrations below recommended exposure limits. Use explosion proof
equipment.
Gloves Procedures Viton. Teflon. Polyvinyl alcohol. Note: polyvinyl alcohol gloves are water soluble and
should not be used when there is potential for water contact.
Eye Protection Safety glasses. If potential for splash or mist exists, wear chemical goggles or faceshield.
Respiratory Protection Use NIOSH/MSHA approved full face respirator with a combination organic vapor and high
efficiency filter cartridge if the recommended exposure limit is exceeded. Use self-contained
breathing apparatus for entry into confined space, for other poorly ventilated areas and for
large spill clean-up sites. Consult with an industrial hygienist to determine the appropriate
respiratory protection for your specific use of this material. A respiratory protection program
compliant with all applicable regulations must be followed whenever workplace conditions
require the use of a respirator.
Clothing Recommendation Gloves, coveralls, apron, boots as necessary to minimize contact. Wear either a chemical
protective suit or apron when potential for contact with material exists. Do not wear rings,
watches or similar apparel that could entrap the material and cause a skin reaction. Launder
contaminated clothing before reuse.

9 Physical and Chemical Properties

Flash Point 32 °C, 89.6 °F PMCC (Typical)

Upper Flammable Limit Not determined.
Lower Flammable Limit Not determined.
Autoignition Point Not determined.
Explosion Data
Material does not have explosive properties in the liquid state, but vapors may form

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LUBRIZOL® 8219H

explosive mixtures with air.

Vapor Pressure 0.02503 psi (Calc) (0 °C)
0.03367 psi (Calc) (4 °C)
0.0886 psi (Calc) (20 °C)
0.23811 psi (Calc) (38 °C)
1.46259 psi (Calc) (77 °C)
pH Not determined.
Specific Gravity 0.9 (15.6 °C)
Bulk Density Not determined.
Water Solubility Insoluble.
Percent Solid Not determined.
Percent Volatile Not determined.
Volatile Organic Compound Not determined.
Vapor Density Not determined.
Evaporation Rate Not determined.
Odor Aromatic hydrocarbon
Appearance Clear liquid.
Viscosity 23 Centistokes (0 °C)
10 Centistokes (25 °C)
7 Centistokes (40 °C)
Odor Threshold Not determined.
Boiling Point Not determined.
Pour Point Temperature < -40 °C, < -40 °F
Melting / Freezing Point Not determined.

The above data are typical values and do not constitute a specification. Vapor pressure
data are calculated unless otherwise noted.

10 Stability and Reactivity

Stability Material is normally stable at moderately elevated temperatures and pressures.

Decomposition Temperature Not determined.
Incompatibility Strong oxidizing agents.
Polymerization Will not occur.
Thermal Decomposition Smoke, carbon monoxide, carbon dioxide, aldehydes and other products of incomplete
combustion. Nitrogen oxides.
Conditions to Avoid Not determined.

11 Toxicological Information

-- ACUTE EXPOSURE --
Eye Irritation Weak to moderate eye irritant. Does not meet EU R36 criteria. Based on data from similar
materials.
Skin Irritation May cause mild skin irritation. Does not meet Canadian D2B or EU R38 criteria. Based on
data from similar materials. Prolonged or repeated skin contact as from clothing wet with
material may cause dermatitis. Symptoms may include redness, edema, drying, and cracking
of the skin.
Respiratory Irritation Nose, throat and lung irritant. Based on data from components or similar materials. Exposure
to a high concentration of vapor or mist is irritating to the respiratory tract.
Dermal Toxicity
The LD50 in rabbits is > 2000 mg/Kg. Based on data from components or similar materials.

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LUBRIZOL® 8219H

Components of this material may be absorbed through the skin.

Inhalation Toxicity The LC50 (1 hr.) in rats for vapors of this material is > 200 mg/l. Based on data from
components or similar materials. High concentrations may cause headaches, dizziness,
fatigue, nausea, vomiting, drowsiness, stupor, other central nervous system effects leading to
visual impairment, respiratory failure, unconsciousness and death.
Oral Toxicity The LD50 in rats is 2000 – 5000 mg/Kg. Based on data from components or similar
materials. The oral LD50 (rat) of xylene is 3.5 g/kg.
Dermal Sensitization No data available to indicate product or components may be a skin sensitizer.
Inhalation Sensitization No data available to indicate product or components may be respiratory sensitizers.

-- CHRONIC EXPOSURE --
Chronic Toxicity Repeated overexposure to petroleum naphtha can cause nervous system damage. Xylene has
been found to cause cardiac, liver and kidney effects, anemia and eye damage in laboratory
animals. Prolonged and repeated inhalation of hydrocarbon solvents such as xylene can cause
chronic neurological disturbances. Chronic exposure to xylene has been shown to cause
hearing loss in experimental animals and is synergistically enhanced when xylene is
combined with n-hexane.
Carcinogenicity A two-year National Toxicology Program (NTP) study found an increased incidence of
tumors of the nose in rats exposed to naphthalene by inhalation. In mice similarly exposed,
increased incidences of alveolar/bronchiolar adenomas were observed. Naphthalene has been
classified by the International Agency for Research on Cancer (IARC) as a possible human
carcinogen (Group 2B) on the basis of sufficient evidence of carcinogenicity in experimental
animals but inadequate evidence in exposed humans. A National Toxicology Program (NTP)
study found an increased incidence of renal tubule neoplasms in male and female rats
exposed to ethylbenzene by inhalation for two years. In male and female mice similarly
exposed, increased incidences of alveolar/bronchiolar neoplasms, and hepatocellular
neoplasms, respectively, were observed. Ethylbenzene has been classified by IARC as a
possible human carcinogen (Group 2B) on the basis of sufficient evidence of carcinogenicity
in experimental animals but inadequate evidence in exposed humans.
Mutagenicity No data available to indicate product or any components present at greater than 0.1% are
mutagenic or genotoxic.
Reproductive Toxicity No data available to indicate either product or components present at greater than 0.1% that
may cause reproductive toxicity.
Teratogenicity Xylene is fetotoxic in rats and rabbits in the absence of maternal toxicity. Prolonged and
repeated exposure of pregnant animals to toluene by inhalation has been reported to cause
adverse fetal developmental effects.

-- ADDITIONAL INFORMATION --
Other No other health hazards known.

12 Ecological Information

-- ENVIRONMENTAL TOXICITY --
Freshwater Fish Toxicity The acute LC50 is 1 - 10 mg/L based on component data.
Freshwater Invertebrates
The acute EC50 is 1 - 10 mg/L based on component data.
Toxicity
Algal Inhibition The acute EC50 is 1 - 10 mg/L based on component data.
Saltwater Fish Toxicity Not determined.
Saltwater Invertebrates
Not determined.
Toxicity
Bacteria Toxicity Not determined.
Miscellaneous Toxicity Not determined.

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LUBRIZOL® 8219H

-- ENVIRONMENTAL FATE --
Biodegradation At least 25% of the components in this product show moderate biodegradation based on
OECD 302-type test data.
Bioaccumulation 1 - 10% of the components potentially bioconcentrate, based on octanol/water coefficients.
Soil Mobility Not determined.

13 Disposal Considerations

Waste Disposal This material, if discarded, is a hazardous waste under RCRA Regulation 40 CFR 261.
Material, if discarded, is expected to be hazardous waste under RCRA due to ignitability
(D001). 0.005% Benzene, CAS no. 71-43-2, D018. Treatment, storage, transportation, and
disposal must be in accordance with applicable Federal, State/Provincial, and Local
regulations.

14 Transport Information

ICAO/IATA I UN1993 Flammable liquid, n.o.s. (Petroleum naphtha, Xylene), Class 3, PG III
ICAO/IATA II UN1993 Flammable liquid, n.o.s. (Petroleum naphtha, Xylene), Class 3, PG III
IMDG UN1993 Flammable liquid, n.o.s. (Petroleum naphtha, Xylene), Class 3, PG III
IMDG EMS Fire F-E
IMDG EMS Spill S-E
IMDG MFAG *Subsection 4.2
MARPOL Annex II Not determined.
USCG Compatibility Not determined.
U.S. DOT Bulk UN1993 Flammable liquid, n.o.s. (Petroleum naphtha, Xylene) Class 3, PG III, RQ
(Naphthalene, Xylene)
U.S. DOT Non-Bulk UN1993 Flammable liquid, n.o.s. (Petroleum naphtha, Xylene) Class 3, PG III
DOT NAERG 128
TDG Bulk UN1993 Flammable liquid, n.o.s. (Petroleum naphtha, Xylene), Class 3, PG III
TDG Non-Bulk UN1993 Flammable liquid, n.o.s. (Petroleum naphtha, Xylene), Class 3, PG III
Mexico UN1993 Flammable liquid, n.o.s. (Petroleum naphtha, Xylene), Class 3, PG III
Mexico Non-Bulk UN1993 Flammable liquid, n.o.s. (Petroleum naphtha, Xylene), Class 3, PG III
Bulk Quantity 85000 liters, 22457 gal.
Non-Bulk Quantity 207.8 liters, 55 gal.

Review classification requirements before shipping materials at elevated temperatures.

15 Regulatory Information

-- Global Chemical Inventories --

USA All components of this material are on the US TSCA Inventory or are exempt.

Section 8d (Benzene, ethyl-).Section 4a (Naphthalene).Section 4a (p-xylene).May be subject

Other TSCA Reg.
to export notification under TSCA Section 12(b).
EU All components are in compliance with the EC Seventh amendment Directive 92 /32/EEC.
Japan This product requires notification in Japan.
Australia A component(s) of this product has been notified and assessed under the Industrial
Chemicals (Notification and Assessment) Act, 1989. This product may be imported only by
Lubrizol Australia.

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LUBRIZOL® 8219H

New Zealand May require notification before sale under New Zealand regulations.
Canada All components are in compliance with the Canadian Environmental Protection Act and are
present on the Domestic Substances List. Naphthalene and 1,2,4-Trimethylbenzene are
components of Petroleum naphtha. Ethylbenzene is a component of Xylene.
Switzerland All components are in compliance with the Environmentally Hazardous Substances
Ordinance in Switzerland.
Korea All components are in compliance in Korea.
Philippines All components are in compliance with the Philippines Toxic Substances and Hazardous and
Nuclear Wastes Control Act of 1990 (R.A. 6969).
China All components of this product are listed on the Inventory of Existing Chemical Substances
in China.

-- Other U.S. Federal Regulations --

SARA Ext. Haz. Subst. This product does not contain greater than 1.0% of any chemical substance on the SARA
Extremely Hazardous Substances list.
SARA Section 313 37.9% Xylene (mixed isomers), CAS no. 1330-20-7; 9.5% Ethylbenzene, CAS no. 100-41-4;
0.5% Naphthalene, CAS no. 91-20-3
SARA 311 Classifications Acute Hazard Yes
Chronic Hazard Yes
Fire Hazard Yes
Reactivity Hazard No
CERCLA Hazardous
Substances Transit Reportable Quantities
Reportable Reportable
Component Units Units
Quantity RQ Quantity RQ
Xylene 1409 gal. 5331 liters
Naphthalene 2810 gal. 10634 liters

FDA Approval Not applicable.

-- State Regulations --
Cal. Prop. 65 This product contains the following chemical(s) known to the state of California to cause
cancer and/or birth defects: 0.005% Benzene, CAS no. 71-43-2 0.379% Toluene, CAS no.
108-88-3 0.475% Naphthalene, CAS no. 91-20-3 9.5% Ethylbenzene, CAS no. 100-41-4

-- Product Registrations --
U.S. Fuel Registration This fuel additive is registered in the United States.
U.S. Dept of Agriculture This product has not been filed with the USDA to support H2 approvals.
NSF Nonfood Compounds
This product has not been filed with the NSF to support H1 or H2 approvals.
Registration
Finnish Registration
Not Registered
Number
Swedish Registration
Not Registered
Number
Norwegian Registration
Not Registered
Number
Danish Registration
Not Registered
Number
Swiss Registration Number Not Registered
Italian Registration Number Not Registered
Korean Registration
This product is registered in Korea with the Ministry of the Environment.
Number

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LUBRIZOL® 8219H

-- Other / International --
TDG Regulated Limit. None known.

16 Other Information

US NFPA Codes Health Fire Reactivity Special

2 3 0 N/E
(N/E) - None established

HMIS Codes Health Fire Reactivity

2* 3 0
Precautionary Labels Danger.

Flammable liquid. may create a flash fire hazard.

Harmful if inhaled.

Causes respiratory tract irritation.

May be harmful if absorbed through skin.

May cause eye irritation.

May cause skin irritation.

Contains components which may cause cancer.

May cause chronic health effects.

Revision Indicators Section: 2 Principal hazards. Changed: 31 March 2009

Section: 3 Hazardous ingredients. Changed: 13 April 2009
Section: 4 Inhalation first aid. Changed: 29 March 2009
Section: 4 Oral first aid. Changed: 24 September 2008
Section: 4 Skin first aid. Changed: 29 March 2009
Section: 7 Handling procedures. Changed: 29 March 2009
Section: 8 Clothing recommendations. Changed: 29 March 2009
Section: 8 Hazardous ingredients. Changed: 13 April 2009
Section: 9 Odor threshold. Changed: 1 April 2009
Section: 9 Percent volatile. Changed: 27 October 2008
Section: 9 Vapor pressure. Changed: 6 February 2009
Section: 10 Thermal decomposition. Changed: 30 January 2009
Section: 11 Chronic toxicity. Changed: 24 September 2008
Section: 11 Inhalation toxicity. Changed: 27 May 2009
Section: 11 Teratogenicity. Changed: 27 October 2008
Section: 13 Waste disposal. Changed: 27 May 2009
Section: 15 Canada. Changed: 3 February 2009
Section: 15 Cercla hazardous substances. Changed: 30 January 2009
Section: 16 Principal hazards. Changed: 31 March 2009

As the conditions or methods of use are beyond our control, we do not assume any responsibility and expressly disclaim
any liability for any use of this product. Information contained herein is believed to be true and accurate but all
statements or suggestions are made without warranty, expressed or implied, regarding accuracy of the information, the
hazards connected with the use of the material or the results to be obtained from the use thereof. Compliance with all
applicable federal, state, and local regulations remains the responsibility of the user.

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