Safety Data Sheet

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1. Product identifier
Mixture identification:
Trade name: Ink Pack， Magenta， T7733

1.2. Relevant identified uses of the substance or mixture and uses advised against
Recommended use:
Ink for inkjet printing
1.3. Details of the supplier of the safety data sheet
Company:
EPSON EUROPE B.V.
Azie building, Atlas ArenA, Hoogoorddreef 5,1101 BA Amsterdam
Zuidoost The Netherlands
Phone number: +31-20-314-5000
Competent person responsible for the safety data sheet:
[email protected]
Date: 21/10/2016
Revision: 1.0
1.4. Emergency telephone number
Phone number: +31-20-314-5000
Giftnotruf Berlin; +48 (0) 30 30686 790

SECTION 2: Hazards identification

2.1. Classification of the substance or mixture
EC regulation criteria 1272/2008 (CLP)
The product is not classified as dangerous according to Regulation EC 1272/2008
(CLP).
Adverse physicochemical, human health and environmental effects:
No other hazards
2.2. Label elements
The product is not classified as dangerous according to Regulation EC 1272/2008 (CLP).
Hazard pictograms:
None
Hazard statements:
None
Precautionary statements:
None
Special Provisions:
EUH210 Safety data sheet available on request.
EUH208 Contains 2,4,7,9-tetramethyldec-5-yne-4,7-diol. May produce an allergic
reaction.
EUH208 Contains 1,2-benzisothiazol-3(2H)-one; 1,2-benzisothiazolin-3-one. May
produce an allergic reaction.
Special provisions according to Annex XVII of REACH and subsequent amendments:
None
2.3. Other hazards
vPvB Substances: None - PBT Substances: None
Other Hazards:
No other hazards

SECTION 3: Composition/information on ingredients

3.1. Substances
No

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3.2. Mixtures
Hazardous components within the meaning of the CLP regulation and related classification:

Qty Name Ident. Number Classification

65% ~ Water CAS: 7732-18-5 The product is not classified as
80% EC: 231-791-2 dangerous according to
Regulation EC 1272/2008 (CLP).
15% ~ Glycerol CAS: 56-81-5 The product is not classified as
20% EC: 200-289-5 dangerous according to
Regulation EC 1272/2008 (CLP).
0.25% ~ Triethanol amine CAS: 102-71-6 The product is not classified as
0.5% EC: 203-049-8 dangerous according to
Regulation EC 1272/2008 (CLP).
0.1% ~ 2,4,7,9-tetramethyldec- CAS: 126-86-3 3.3/1 Eye Dam. 1 H318
0.25% 5-yne-4,7-diol EC: 204-809-1
3.4.2/1B Skin Sens. 1B H317
4.1/C3 Aquatic Chronic 3 H412
< 0.05% 1,2-benzisothiazol-3(2 Index 613-088-00-6 3.1/4/Oral Acute Tox. 4 H302
H)-one; number:
1,2-benzisothiazolin-3- CAS: 2634-33-5 3.2/2 Skin Irrit. 2 H315
one EC: 220-120-9 3.3/1 Eye Dam. 1 H318
3.4.2/1-1A-1B Skin Sens.
1,1A,1B H317
4.1/A1 Aquatic Acute 1 H400

SECTION 4: First aid measures

4.1. Description of first aid measures
In case of skin contact:
Wash with plenty of water and soap.
In case of eyes contact:
In case of contact with eyes, rinse immediately with plenty of water and seek medical
advice.
In case of Ingestion:
Do not under any circumstances induce vomiting. OBTAIN A MEDICAL EXAMINATION
IMMEDIATELY.
In case of Inhalation:
Remove casualty to fresh air and keep warm and at rest.
4.2. Most important symptoms and effects, both acute and delayed
None
4.3. Indication of any immediate medical attention and special treatment needed
Treatment:
None

SECTION 5: Firefighting measures

5.1. Extinguishing media
Suitable extinguishing media:
Water.
Carbon dioxide (CO2).
Extinguishing media which must not be used for safety reasons:
None in particular.
5.2. Special hazards arising from the substance or mixture
Do not inhale explosion and combustion gases.

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Burning produces heavy smoke.

5.3. Advice for firefighters
Use suitable breathing apparatus .
Collect contaminated fire extinguishing water separately. This must not be discharged into
drains.
Move undamaged containers from immediate hazard area if it can be done safely.

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures
Wear personal protection equipment.
Remove persons to safety.
See protective measures under point 7 and 8.
6.2. Environmental precautions
Do not allow to enter into soil/subsoil. Do not allow to enter into surface water or drains.
Retain contaminated washing water and dispose it.
In case of gas escape or of entry into waterways, soil or drains, inform the responsible
authorities.
Suitable material for taking up: absorbing material, organic, sand
6.3. Methods and material for containment and cleaning up
Wash with plenty of water.
6.4. Reference to other sections
See also section 8 and 13

SECTION 7: Handling and storage

7.1. Precautions for safe handling
Avoid contact with skin and eyes, inhalation of vapours and mists.
Do not eat or drink while working.
See also section 8 for recommended protective equipment.
7.2. Conditions for safe storage, including any incompatibilities
Keep away from food, drink and feed.
Incompatible materials:
None in particular.
Instructions as regards storage premises:
Adequately ventilated premises.
7.3. Specific end use(s)
None in particular

SECTION 8: Exposure controls/personal protection

8.1. Control parameters
Glycerol - CAS: 56-81-5
- OEL Type: OSHA - LTE: 5 mg/m3 - Notes: PEL, as mist, respirable fraction
- OEL Type: OSHA - LTE: 15 mg/m3 - Notes: PEL, as mist, total dust
DNEL Exposure Limit Values
No data available
PNEC Exposure Limit Values
2,4,7,9-tetramethyldec-5-yne-4,7-diol - CAS: 126-86-3
Target: Fresh Water - Value: 0.04 mg/l
Target: Marine water - Value: 0.004 mg/l
Target: Freshwater sediments - Value: 0.32 mg/kg
Target: Marine water sediments - Value: 0.032 mg/kg
8.2. Exposure controls
Eye protection:
Not needed for normal use. Anyway, operate according good working practices.
Protection for skin:

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No special precaution must be adopted for normal use.

Protection for hands:
Not needed for normal use.
Respiratory protection:
Not needed for normal use.
Thermal Hazards:
None
Environmental exposure controls:
None
Appropriate engineering controls:
None

SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties
Appearance and colour: Magenta Liquid
Odour: Slightly
Odour threshold: No data available
pH: 7.4 ~ 8.1 at 20 °C
Melting point / freezing point: No data available
Initial boiling point and boiling range: No data available
Solid/gas flammability: No data available
Upper/lower flammability or explosive limits: No data available
Vapour density: No data available
Flash point: Does not flash until 93 °C / 199 ° F
(closed cup method, ASTM D 3278)
Evaporation rate: No data available
Vapour pressure: No data available
Relative density: 1.056 at 20 °C
Solubility in water: Complete
Solubility in oil: No data available
Partition coefficient (n-octanol/water): No data available
Auto-ignition temperature: No data available
Decomposition temperature: No data available
Viscosity: < 5 mPa·s at 20 °C
Explosive properties: No data available
Oxidizing properties: No data available
9.2. Other information
Miscibility: No data available
Fat Solubility: No data available
Conductivity: No data available

SECTION 10: Stability and reactivity

10.1. Reactivity
Stable under normal conditions
10.2. Chemical stability
Stable under normal conditions
10.3. Possibility of hazardous reactions
None
10.4. Conditions to avoid
Stable under normal conditions.
10.5. Incompatible materials
None in particular.
10.6. Hazardous decomposition products
None.

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SECTION 11: Toxicological information

11.1. Information on toxicological effects
Toxicological information of the mixture:
Ink
e) germ cell mutagenicity:
Test: Mutagenesis - Species: Salmonella Typhimurium and Escherichia coli
Negative
Toxicological information of the main substances found in the mixture:
Glycerol - CAS: 56-81-5
a) acute toxicity:
Test: LD50 - Route: Oral - Species: Guinea pig = 7750 mg/kg - Source: Journal
of Industrial Hygiene and Toxicology. Vol. 23, Pg. 259, 1941
Test: LDLo - Route: Oral - Species: Human = 1428 mg/kg - Source: "Toxicology
of Drugs and Chemicals," Deichmann, W.B., New York, Academic Press, Inc.,
1969Vol. -, Pg. 288, 1969. - Notes: BEHAVIORAL: HEADACHE
GASTROINTESTINAL: NAUSEA OR VOMITING
Triethanol amine - CAS: 102-71-6
a) acute toxicity:
Test: LD50 - Route: Oral - Species: Guinea pig = 2200 mg/kg - Source:
"Toxicometric Parameters of Industrial Toxic Chemicals Under Single Exposure,"
Izmerov, N.F., et al., Moscow, Centre of International Projects, GKNT, 1982Vol. -,
Pg. 114, 1982.
Test: LD50 - Route: Oral - Species: Mouse = 5846 mg/kg - Source: Science
Reports of the Research Institutes, Tohoku University, Series C: Medicine. Vol.
36(1-4), Pg. 10, 1989. - Notes: GASTROINTESTINAL: "HYPERMOTILITY,
DIARRHEA" KIDNEY, URETER, AND BLADDER: OTHER CHANGES
BEHAVIORAL: CONVULSIONS OR EFFECT ON SEIZURE THRESHOLD
2,4,7,9-tetramethyldec-5-yne-4,7-diol - CAS: 126-86-3
a) acute toxicity:
Test: LD50 - Route: Dermal - Species: Rat > 2000 mg/kg - Notes: OECD TG
No.402
b) skin corrosion/irritation:
Test: Skin Irritant - Species: Rabbit Mild irritant - Notes: OECD TG No.404
c) serious eye damage/irritation:
Test: Eye Irritant - Species: Rabbit Highly irritating - Notes: EPA OTS 798.4500
d) respiratory or skin sensitisation:
Test: Skin Sensitisation - Route: LLNA - Species: Mouse Sensitiser - Notes:
OECD TG No.429
e) germ cell mutagenicity:
Test: Mutagenesis - Species: Salmonella Typhimurium Negative - Notes: OECD
TG No.471

If not differently specified, the information required in Regulation (EU) 2015/830 listed below
must be considered as 'No data available':
a) acute toxicity;
b) skin corrosion/irritation;
c) serious eye damage/irritation;
d) respiratory or skin sensitisation;
e) germ cell mutagenicity;
f) carcinogenicity;
g) reproductive toxicity;
h) STOT-single exposure;
i) STOT-repeated exposure;

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j) aspiration hazard.

SECTION 12: Ecological information

12.1. Toxicity
Adopt good working practices, so that the product is not released into the environment.
2,4,7,9-tetramethyldec-5-yne-4,7-diol - CAS: 126-86-3
a) Aquatic acute toxicity:
Endpoint: LC50 - Species: Fish = 36 mg/l - Duration h: 96 - Notes: OECD TG No.203
Endpoint: EC50 - Species: Daphnia = 88 mg/l - Duration h: 48 - Notes: OECD TG
No.202
Endpoint: EC50 - Species: Algae = 15 mg/l - Duration h: 72 - Notes: OECD TG No.201
c) Bacteria toxicity:
Endpoint: EC50 - Species: activated sludge = mg/l - Notes: OECD TG No.209
12.2. Persistence and degradability
No data available
12.3. Bioaccumulative potential
No data available
12.4. Mobility in soil
No data available
12.5. Results of PBT and vPvB assessment
vPvB Substances: None - PBT Substances: None
12.6. Other adverse effects
None

SECTION 13: Disposal considerations

13.1. Waste treatment methods
Recover if possible. In so doing, comply with the local and national regulations currently in
force.

SECTION 14: Transport information

14.1. UN number
Not classified as dangerous in the meaning of transport regulations.
14.2. UN proper shipping name
No data available
14.3. Transport hazard class(es)
No data available
14.4. Packing group
No data available
14.5. Environmental hazards
No data available
14.6. Special precautions for user
No data available
14.7. Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code
No data available

SECTION 15: Regulatory information

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
Dir. 98/24/EC (Risks related to chemical agents at work)
Dir. 2000/39/EC (Occupational exposure limit values)
Regulation (EC) n. 1907/2006 (REACH)
Regulation (EC) n. 1272/2008 (CLP)
Regulation (EC) n. 790/2009 (ATP 1 CLP) and (EU) n. 758/2013
Regulation (EU) 2015/830

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Regulation (EU) n. 286/2011 (ATP 2 CLP)

Regulation (EU) n. 618/2012 (ATP 3 CLP)
Regulation (EU) n. 487/2013 (ATP 4 CLP)
Regulation (EU) n. 944/2013 (ATP 5 CLP)
Regulation (EU) n. 605/2014 (ATP 6 CLP)
Restrictions related to the product or the substances contained according to Annex XVII
Regulation (EC) 1907/2006 (REACH) and subsequent modifications:
Restrictions related to the product:
No restriction.
Restrictions related to the substances contained:
No restriction.
Where applicable, refer to the following regulatory provisions :
Directive 2003/105/CE ('Activities linked to risks of serious accidents') and subsequent
amendments.
Regulation (EC) nr 648/2004 (detergents).
1999/13/EC (VOC directive)

Provisions related to directives 82/501/EC(Seveso), 96/82/EC(Seveso II):

No data available
15.2. Chemical safety assessment
No

SECTION 16: Other information

Full text of phrases referred to in Section 3:
H318 Causes serious eye damage.
H317 May cause an allergic skin reaction.
H412 Harmful to aquatic life with long lasting effects.
H302 Harmful if swallowed.
H315 Causes skin irritation.
H400 Very toxic to aquatic life.

Hazard class and Code Description

hazard category
Acute Tox. 4 3.1/4/Oral Acute toxicity (oral), Category 4
Skin Irrit. 2 3.2/2 Skin irritation, Category 2
Eye Dam. 1 3.3/1 Serious eye damage, Category 1
Skin Sens. 1,1A,1B 3.4.2/1-1A-1B Skin Sensitisation, Category 1,1A,1B
Skin Sens. 1B 3.4.2/1B Skin Sensitisation, Category 1B
Aquatic Acute 1 4.1/A1 Acute aquatic hazard, category 1
Aquatic Chronic 3 4.1/C3 Chronic (long term) aquatic hazard, category 3

This document was prepared by a competent person who has received appropriate training.
Main bibliographic sources:
ECDIN - Environmental Chemicals Data and Information Network - Joint Research Centre,
Commission of the European Communities
SAX's DANGEROUS PROPERTIES OF INDUSTRIAL MATERIALS - Eight Edition - Van
Nostrand Reinold
CCNL - Appendix 1
Insert further consulted bibliography
The information contained herein is based on our state of knowledge at the above-specified date. It
refers solely to the product indicated and constitutes no guarantee of particular quality.
It is the duty of the user to ensure that this information is appropriate and complete with respect to
the specific use intended.
This Safety Data Sheet cancels and replaces any preceding release.

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ADR: European Agreement concerning the International Carriage of

Dangerous Goods by Road.
CAS: Chemical Abstracts Service (division of the American Chemical
Society).
CLP: Classification, Labeling, Packaging.
DNEL: Derived No Effect Level.
EINECS: European Inventory of Existing Commercial Chemical Substances.
GefStoffVO: Ordinance on Hazardous Substances, Germany.
GHS: Globally Harmonized System of Classification and Labeling of
Chemicals.
IATA: International Air Transport Association.
IATA-DGR: Dangerous Goods Regulation by the "International Air Transport
Association" (IATA).
ICAO: International Civil Aviation Organization.
ICAO-TI: Technical Instructions by the "International Civil Aviation Organization"
(ICAO).
IMDG: International Maritime Code for Dangerous Goods.
INCI: International Nomenclature of Cosmetic Ingredients.
KSt: Explosion coefficient.
LC50: Lethal concentration, for 50 percent of test population.
LD50: Lethal dose, for 50 percent of test population.
LTE: Long-term exposure.
PNEC: Predicted No Effect Concentration.
RID: Regulation Concerning the International Transport of Dangerous Goods
by Rail.
STE: Short-term exposure.
STEL: Short Term Exposure limit.
STOT: Specific Target Organ Toxicity.
TLV: Threshold Limiting Value.
TWATLV: Threshold Limit Value for the Time Weighted Average 8 hour day.
(ACGIH Standard).
WGK: German Water Hazard Class.

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