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AITS-FT-I (Paper-1)-PCM(Sol)-JEE(Advanced)/15
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ANSWERS, HINTS & SOLUTIONS
FULL TEST– I
(PAPER-1)
ALL INDIA TEST SERIES
Q. No. PHYSICS CHEMISTRY MATHEMATICS

1. B B A
2. D B B
3. D A C
4. C C A
5. A, D A, B, D A, C
6. B, D A, B, C A, B, C, D
7. A, C B, D A, C, D
8. B, C, D B, C, D A, B, C, D
9. B C A
10. D D C
11. B A B
(A)  (q) (A  s, t) (A)  (s)
(B)  (p, q, s, t) (B  p, q, r, t) (B)  (q)
1.
(C)  (p, q, s, t) (C  p, s) (C)  (s)
(D)  (r, s) (D  q, s, t) (D)  (p, r, t)
(A)  (t) (A  q) (A)  (p)
(B)  (q, s) (B  p, t) (B)  (q)
2.
(C)  (p, q, r) (C  p, q) (C)  (p)
(D)  (t) (D  s) (D)  (r)
1. 1 4 3
2. 1 7 4
3. 2 3 3
4. 8 5 5
5. 2 2 4
6. 3 1 3
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Physics PART – I
SECTION – A
    
dp ˆ  50kˆ N
3. Fnet   15iˆ  20tjˆ  50kˆ = Freal  Fpseudo and Freal  mg(k)
dt
dT
4. Q = KA
dx
x T
Q
A 
dx = K 0 (1  T)dT
0

0
T
Q  T2 
x = K0  T  
A  2 0

by solving
Q  T2 
x  K 0  T  
A  2 
Q  (300)2 
So, x0  K0  300  
A  2 
So, at x = 2x0 temperature T  425 K
A2
5. m = V  =  A1  A 2  A1A 2  H
F
m
H  mg
 A1  A 2  A1A 2  FB
 
A1
A2  H 
P1 = 1gH1
P2 = 2gH2  P1 > P2
F = mg  FB = mg  PA1
F1 = mg  A1P1,
F2 = mg  A1P2
2GMm GM2
6. U 
d2  y 2 2d
2GMm 2Gm2
 
d2  y2 2d
 2 1
= 2Gm2   
 d2  y2 d 
 
1
= U  mv 2
2
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h E E P v 
7. v = f =      Particle 
p h P 2m  2 
a x  b t )2
8. y  5e –(
09-11. h = 160 m
2h 2  160
t10    4 2 sec
g 10
Velocity of system after collision in vertical direction, v 10 = 30 m/s;
Velocity of system after collision in horizontal direction, v 20  ¼  40 = 10 m/s
v120  900 + 2  10  80  v10  50 m/s
50  30
t 20  = 2 sec
10
t10  4 sec
SECTION - B
2. Shape of sting at t = 0 is given by. y
 0 if   x  vt  L
h(L  x  vt) / L if vt  L  x  vt

y(x,t)  
h(L  x  vt) / L if vt  x  vt  L
 0 if vt  L  x   x
O
y
x
O ((vt  L), 0) (vt, 0) ((vt + L), 0)
SECTION – C

2. 10gsin = 5g sin 
2

10 sin = 5 (2 sin /2 cos /2)
2
cos /2 = 1
4. y1 = A sin 1t Ar
y2 = A sin 2t cycle
2A0
 (   1 )   ( 2  1 ) 
yr = 2A cos  2 t  sin t A0
2 2 1s
1/6 s
1/3 s
1/4 s
3/4 s
2/3 s
  
5/6s
Resultant amplitude Ar = 2A|cos()t/2|

t  1
()   t = s
2 2 4
t  1
( )   t = s
2 3 6
In one cycle of intensity of 1/2s, the detector remain idle for
 1 1 1
2    s  sec
4 6 6
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 1 1
 In ½ sec cycle, active time is    = 1/3 sec
 2 6
1/ 3 
 In 12 sec interval, active time is 12  = 8 sec
(1/ 2)
(2C)V 2
6. V1   V
3C 3
1 4 2 2CV 2
U1  C V 
2 9 9
V
V2 =
3
1 V2 V 2 CV 2
U2  (2C) C 
2 9 9 9
CV 2
Initial total energy =
3
1
Final total energy = (2C)V 2  CV 2
2
2 4
Charge flow through the battery  2CV  CV  CV
3 3
4
 Wbattery  CV 2
3
4CV 2 2CV 2 2
 Heat dissipated    CV 2
3 3 3
Chemistry PART – II
SECTION – A
1. H3C CH2 H3C CH 2 O

CH3 CH2 Cl N C N  
N C OH  CO
CaCN 2   H3 O 
2


H3C CH2 H3C CH 2
H3C CH2 CH3

N i 2CH3I
H  
 
 H3C CH2 N CH 2 CH3 OH

ii Moist Ag O
2
H3C CH 2 CH3
(A)
(B)
H
H2C CH2  H3C CH2 N CH3  H2O
(C)
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2. O
CH3 CH3 O O
H2 C C CH3
O
H2 C C C CH2 CH2 C OH
O

Anhydride AlCl
 
3
(minor) O
O C CH2 CH2 C OH
 i  Zn  Hg /HCl
(major)
 ii  SOCl2 / 
 i  Zn  Hg / HCl
 i SOCl2 / 
Cl
CH3
O
Cl
Anhyd. AlCl3 /   CS2 
O
CH3
Anhyd. AlCl3 /   CS2 

CH3
O
(minor) O
(major)
3. N2O C8H7OCl
287 m
Molar weight of C8H7OCl = 8  12 + 7  1 + 16 + 35.5
= 154.5 g
Molar weight of N2O = 2  14 + 16 = 44 g
According to Graham’s Law of diffusion
rN2O MC8H7OCl 154.5
   3.5  1.87 : 1
rC8H7 OCl MN2O 44
1.87 th
dN2O   287 = 187 row from N2O side.
2.87
1.0 th
dC8H7OCl   287 = 100 row from weeping gas side.
2.87
Therefore, the spectator from the side of N2O in the 187th. Row will be laughing and weeping
simultaneously. Alternatively, the spectator from the side of weeping gas in 100th row will laugh
and weep.
4. The given orbital diagram has two radial nodes, i.e. n    1  2
 The orbital, in which electron is present is 3s.
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Cl Cl
5. (A) H2C CH Cl  H3C CH C Cl

Cl Cl
These occurs decrease in electron density and hence the ionization potential increases.
N
(B) Basic strength  electron density over one N-atom has lesser electron density over
N
one N-atom than in

N
1
(C) Heat of combustion 
Stability
stability  No. of  –H
and if no. of –H of same stability  ease of hyperconjugation.
(D) Conjugate acid of weaker base is stronger acid. Basic strength
NH2 NH2 NH2
CH3
 
CH3
6. B. pt. of CCl4 < that of SiCl4. The vapour must always be richer in more volatile component.
Hence, the upper curve represents the composition of the vapour and the lower curve represents
the composition of the solution at corresponding B. pt.
8. The correct basic order for (a) option
CH3O > CH3NH > CH3CH2
(-ve) charge on most (-ve) charge on least
electronegative atom electronegative atom
and it can also explain by its conjugate rest all option are correct.
Solution for the Q. No. 9 to 11.
M – PbCO3
P – Pb(NO3)2
B – PbO
C – CO2
D – NO2
E – O2
F – CaCO3
G – Ca(HCO3)2
Q – PbSO4
R – NaNO3
SECTION –C
1. O O O O
14 14 14 14
N O N O N OH N O
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2. ZB  4  2  2
ZA  4
ZC2  1
 A 4B 2Z 1
x+y+z=7
o
3. r2 = 5.49 A 2
o
2r = 83.05 A
o
then r = 13.22 A
0.529  n2
 r
Z
0.529  n2
 13.22 =
Z
n=5
Number of maximum lines possible = 3
CH3 COOH  NaOH  CH3 COONa  H2O

4. Int. No. of mole 106 V 10 6 V 0 0
6
at t  t sec 0 0 10 V
6
10 V
CH3COONa   2V
= 5  10–7< 10-6.
Kw  C
OH  
  Ka
104  107  5
=
1.9  105
= 2.63  10–8 < 10–6
so pOH = –log (2.63  10–8 + 10–7)
pH = 7
pH
 5
1.42
5. Mn2  MnO2  2e 
4e   O2  2H2O
1 Eq of Mn+2 = 1 Eq of O2
(n = 2) (n = 4)
½ mole of Mn+2 = 1 Eq. of O2
2 mole of Mn+2 = 4 Eq. of O2
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6. 

2C  s   O2  g   Keq  103
 2CO  g 
CO2  g  

 C  s   O2  g  Keq  10

2


C  s   CO2  g  
 2CO  g  Keq  101  X


C  s   O2  g  
 2C  s   CO2  g Keq  1/ x  10
1


2CO  g   O2  g   1
 2CO2  g  Keq  10  Y
Hence X : Y = 1 : 1
Mathematics PART – III
SECTION – A
1. Let z1, z2 be the two roots with |z1| = 1
c c 1
 z 1z 2 =  z2  1
a a z1
 z1z1  z2 z2  1
b
 z1  z 2   and |b| = |a|
a
 |z1 + z2|2 = 1
 1 1
 (z1 + z2)  z1  z2   1   z1  z2     1
 z1 z2 
 (z1 + z2)2 = z1z2  b2 = ac
2. For x  [0, 1], f(x)  f(1) ( f(x) is decreasing)

f 'x f ' 1
 2  2
f x  1 f x  1
1 1
f ' x  dx
  f 2  x   1 dx  f ' 1  f 2  x   1
0 0
1
1 dx
 tan1 f  x   f ' 1  2
0 f x 1
0
1
dx tan1 f 1
 
 f 2  x   1 f ' 1
0
tan1 f 1 f 1

 tan–1  <    > 0  
f ' 1 f ' 1
1
dx f 1
  f 2  x   1  f ' 1
0
3.  P(x) = 0 has n real roots

 x P(x) = 0 has n + 1 real roots
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d

dx
 xP  x   0
 x P(x) + P(x) = 0 has n real roots
 x(x P(x) + P(x)) = 0 has n + 1 real roots
d 2

dx
 
x P '  x   xP  x   0 has n real roots
i.e. x2 P(x) + 3x P(x) + P(x) = 0 has n real roots  (I) is true

Let one of the roots of P(x) = 0 is , and one root of Q(x) = 0 is  as given,   
 P(x) Q(x) + P(x) Q(x) = 0
d

dx
P  x  Q'  x    0
Consider f(x) = P(x) Q(x)
f() = 0, f() = 0
d
Hence, by Rolles theorem
dx
P  x  Q'  x    0 has at least one real root lying between  and 
4. Case-I:
a a
If a  [0, 1], the curves intersect at  ,  and (a, a). The bounded region is contained in the
3 3
 1  1
triangle with vertices (0, 0),  , 0  and (1, 1) with area =
2  4
1
Hence, area can not exceed
4
Case-II:
a a a 
If a  [1, 3]. In this case the bounded region is a quadrilateral with four vertices  ,  ,  , 0  ,
3 3 2 
a2 4a 1 a a 1  4  a  a
 3 , 3  and (1, 1). In this case area bounded = 1  2  3  2  2  3  2  2 
    
2
1  a  2 1
=  
3 6 3
Case-III: If a  [3, 4]. This case is symmetric with case-I
2 (2, 0) (2, 0)
a  1 1 a  a 
 , 0  , 0  , 0
2  2  2 
5. Multiplying the first DE by gh, the second by fh and the third by fg, and adding the equations
gives
2
(fgh) = 6(fgh) + 6
Let f(x) g(x) h(x) = k(x)
2
We have k(x) = 6(k(x)) + 6
Integrating and using k(0) = 1 gives
 
k(x) = tan  6x  
 4
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f ' x  1
Now 1st DE   2k  x  
f x k  x
f ' x    
  2 tan  6x    cot  6x  
f x  4   4 
Integrating and using f(0) = 1 gives option A and C
6. By reflection property of ellipse PAF2 = QAF1 P H1

 H1 is reflection of F1  QAH1 = QAF1 A
Now PH2 = PF2, PH1 = PF1 H2 B Q
and F2H1 = F2A + AF1 = 2a
and F1H2 = F1B + BH2 = F1B + F2B = 2a F2 F1
Hence, PF2H1 and PF1H2 are congruent as all three
sides are equal
This leads to all the options
7. Let f(x) = a(x – 1)(x – 1)

 f(x) f(x + 1) = a2(x – 1)(x – 1 + 1)(x – 1)(x – 1 + 1)
= a2(x2 + x – 1x – 1x + 11 – 1)(x2 + x – 1x – 1x + 11 – 1)
 f(x) f(x + 1) = a2[(x2 – (1 + 1 – 1) x + 11) – 1]  [(x2 – (1 + 1 – 1) x + 11) – 1]
Hence, g(x) = a2(x – 1)(x – 1) and h(x) = x2 – (1 + 1 – 1) + 11
8. Consider h(x) = x(1 + ln x), h: [1, )  [1, )

Clearly h(x) to increasing function in its domain
 f() denotes the solution of x(1 + ln x) = 
 f: [1, )  [1, ), f is inverse function of h(x)
As lim h       lim f     
 
1 1 1
f '     f '    
h'  x  x  f 2  ln x xf 2  ln  f    
 
f    ln  f    ln  ln 
Now consider L  lim  lim = lim
  

f    1  ln  f       1  ln  f    
1/  f  2  ln f   
By L’Hospitals Rule L  lim  lim  lim
 f '    f     f '     1  ln f   
 2 
 ln f   1 
 L  lim 
   1
  1 
 ln f     1 
 
9. (I) holds true obviously

  
 
For (II): A B  C   a1, a2 b1  c 1, b2  c 2 
= 2a1(b1 + c1) + a2(b2 + c2) + a1(b2 + c2) + a2(b1 + c1)
= (2a1b1 + a2b2 + a1b2 + a2b1) + (2a1c1 + a2c2 + a1c2 + a2c1)
   
= A B  A C
Similarly it can be checked that (III) also holds true
 
10. A  B  a1b1  a2b2  2 a2b1  2 a1b2
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   a  b1   a2  b2  3
 A B   1     a2  b1    a1  b2     a1  a2    b1  b2  
 2   2  2
  3  
 A B 
2
A B 
   
11. A  B  a1b1  a2b2  a3b3  B  A
Hence, (I) holds true
  
 
A B  C  a1  b1  c1   a2  b2  c 2   a3  b3  c 3   a1b1  a2b2  a3b3    a1c1  a2c 2  a3c 3 
 a1b1  a2b2  a3b3  a1c1  a2c 2  a3 c 3
 (II) Don’t hold true
Similarly (III) can be checked
SECTION – B
3
1. Normal y + tx = at + 2at P(t1)
 at3 + (2a – h)t – k = 0
N(h, k)
 t1 + t2 + t3 = 0  t3 = –(t1 + t2) ….. (1)
A
2a  h
 t1t2 + t2t3 + t3t1 = ….. (2)
a
k Q(t2) R(t3)
Also, t1t 2 t 3  ..... (3) (–a, 0)
a B
O
 ABC is equilateral
So, G  H  O C
a a 
G    t1t 2  t 2 t 3  t 3 t1 ,  t1  t 2  t 2  t 3  t 3  t1  
3 3 
a 
G    t1t 2  t 2 t 3  t 3 t1 , 0  ..... (4)
 3 
 a 
H   a,  t1  t 2  t 3  t1t 2 t 3   ..... (5)
 3 
Comparing (4) and (5), t1t2t3 = 0 and from (3), k = 0
2a  h a
From equation (2), we get   a
a 3
2a – h = –3a
h = 5a
 O  circumcentre of ABC = (–a, 0)
Image of O will lie on circle
 N  (5a, 0)
 One of the intersection point lie on vertex ( k = 0)
So, t2 = 0
 at3 + (2a – 5a)t = 0
 t3 – 3t = 0  t(t2 – 3) = 0
t = 0,  3
 
 Intersection points  P  3a, 2a 3 , Q  (0, 0), R  3a,  2a 3  
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2. (A) (f(x))2 + [f(x)]2 = h(x) h(x)

h(x) = 2f(x) f(x) + 2f(x) f(x)
= 2f(x) (f(x) + f(x))
= 2f(x) {–x g(x) f(x)}
2 O
= –2x(f(x)) g(x)
So, h(x) < 0 of x > 0 and h(x) > 0 for x < 0
Then, x = 0 is a maxima
(B) f 2(x) + f(x) = g(x)
2f(x) f(x) + f(x) = g(x) and g(x) = f(x) {2f(x) + 1}
So, g(x)  0 as g(x) is increasing and for f(x)  0
2f(x) + 1  0
1
Hence, f  x   
2
x 
2 G(x)
(C) Let G  x     f  t  dt  ….. (1) O
 0 
x
G'  x 
G'  x   2f  x   f  t  dt and  g x
0
2
and G(0) = 0 = g(0)
Also, g(x) is non-increasing
Hence, g(x)  0 x  (–, 0), g(x)  0 x  [0, )
i.e., G(x)  0 for x  0, G(x)  0 for x  0 and G(0) = 0
But G(x) (from equation (1))  0
Hence, G(x) = 0 x  R
x
 f  t  dt  0 xR
0
i.e., f(x) = 0 x  R
Hence, f(1) = 0
x
(D) f  x   x 2   e t f  x  t  dt ….. (1)
0
x
f  x   x 2  e x  et f  x  x  t  dt
0
x
f  x   x 2  e x  et f  t  dt
0
x
f '  x   2x  e x e x f  x    e  x  et f f  t  dt
0
x
f '  x   2x  f  x    e   f  t  dt = 2x + f(x) + x2 – f(x)
 x t
0
2
f(x) = 2x + x
2 x3
f(x) = x +  c and from equation (1) f(0) = 0
3
Hence, c = 0
x3
i.e., f(x) = x 2 
3
1 2 k 2
f  1  1   ,  k=2
3 3 3 3
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13
SECTION – C
 /2
1. Let f  r    xr sin xdx
0
 /2  /2
x r 1  /2 xr 1
Now,  xr cos xdx  cos x 0   sin xdx
0
r 1 0
r 1
 /2
f  r  1
  xr cos xdx 
0  r  1
r C f r  r  1
So, we have lim L
r  f  r  1
r 1

 /2  
2
Now, consider f  r    xr dx   
0
r 1
2x  
Also as sin x 

x  0, 2 
 
r 1

 /2
2  
2
f  r    xr 1dx   
0
 r 2
r 1
r 2 r
  r  f r  
r2  r 1
r 1
2
r   f r 
f r   2  r  1 2
Hence, lim  lim  =
r  f  r  1 r  r  2
 r 
2
r  1   f  r  1

f r  2
Now, lim r C  r  1  L  lim r C  r  1  L
r  f  r  1 r  
2
For positive L we should have C = –1 and L =

 
2. Let x + y =  and x – y =   x  and y 
2 2
f  f  
Given equation  f() – f() = (2 – 2)   2   2
 
f x
Hence,  x 2  k (k is some real constant)
x
f(x) = x3 + kx
f(1) = –2  k = –3, f(x) = x3 – 3x
f(x) = 3(x – 1)(x + 1) on the interval x    3, 3  extreme value are –2 and 2
3. The given equation can be re-written as quadratic in y

y2 + (8x – 2x2)y + (3x2 + 6x) = 0
Its discriminant to equal to
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14
= (64x2 – 32x3 + 4x4) – 4(3x2 + 6x) = 4x(x3 – 8x2 + 13x – 6)

= 4x(x – 6)(x – 1)2
For solutions in integers this discriminant should by perfect square this happens if and only if
2 2
z = x(x – 6) = (x – 3) – 9
2 2
9 = (x – 3) – z = (x + z – 3)(x – z – 3) for name integer z
Checking all factorisations 9 = (–9)  (–1) = (–3)  (–3) = (–1)  (–9) = 9  1 = 3  3 = 1  9
This gives all possible pairs (x, y) as (x, y) = (–2, 0), (–2, 24), (0, 0), (8, 4), (8, 60), (6, 12)
Therefore exactly three pairs of natural number (x, y) are possible

4. As no multiple of  nor any odd multiple of satisfies the equation we can multiply both sides by
4
sin x cos 2x, which gives
sin 8x cos 5x = 2 sin 4x cos 4x cos 5x = 4 sin 2x cos 2x cos 4x sin 5x
= (sin x sin 2x)(8 cos x cos 4x cos 5x) = sin x cos 2x
 sin 13x + sin 3x = sin 3x – sin x
 sin 13x = sin (–x)
n
 13x = n + (–1) (–x)
 5 7 11  2 3  4 5 6
Which gives 10 solutions , , , , , , , , ,
12 12 12 12 7 7 7 7 7 7
5. Let Hi  the event of getting a head on ith coin

H  getting odd number of heads on throwing n coins once
Coin Number: 1 2 3 4 …….. m ….. n
1 1 1 1 1 1
P(Hi) ….. ….. (1)
3 5 7 9  2m  1  2n  1
2 4 6 8 2m 2n
 
P Hi
3 5 7 9
……..
 2m  1
…..
 2n  1
….. (2)
Now, P(H) = sum of series which has each term consisting of product of an odd number of terms
from (1) and even number of terms from (2) such that total number of factors in each term is n
 2 1  4 1  6 1   2n 1  1
Consider the product        .....     2n  1
 3 3  5 5  7 7   2n  1 2n  1 
1
 
LHS = P H  P H 
2n  1
Also, P H  P H  1
n
 P H  
2n  1
  = 1,  = 2,  = 1,  +  +  = 4
6. (, ) and (, ) will lie on some line y = –x + 

Solving line and parabola – (–x + ) = ax – bx2 (, )
 bx2 – (1 + a)x +  = 0 ….. (1)
2
Again, y = a( – y) – b( – y)
2 2
 by + y(1 + a – 2b) + (b – a) = 0 ….. (2) (, )
Both (1) and (2) has same roots which are  and 
1 a
Hence, 1 + a – 2b = –(1 + a)   
b
Now, for ,  to exist disc of (1) > 0
 (1 + a)2 – 4b > 0
 (a – 3)(a + 1) > 0
 a  (–, –1)  (3, )
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ANSWERS, HINTS & SOLUTIONS

Q. No. PHYSICS CHEMISTRY MATHEMATICS

Resultant amplitude Ar = 2A|cos()t/2|

1. H3C CH2 H3C CH 2 O

H3C CH2 CH3

Anhyd. AlCl3 /   CS2 

5. (A) H2C CH Cl  H3C CH C Cl

one N-atom than in

CH3 COOH  NaOH  CH3 COONa  H2O

5. Mn2  MnO2  2e 

Mathematics PART – III

2. For x  [0, 1], f(x)  f(1) ( f(x) is decreasing)

tan1 f 1 f 1

3.  P(x) = 0 has n real roots

i.e. x2 P(x) + 3x P(x) + P(x) = 0 has n real roots  (I) is true

6. By reflection property of ellipse PAF2 = QAF1 P H1

7. Let f(x) = a(x – 1)(x – 1)

8. Consider h(x) = x(1 + ln x), h: [1, )  [1, )

9. (I) holds true obviously

2. (A) (f(x))2 + [f(x)]2 = h(x) h(x)

3. The given equation can be re-written as quadratic in y

= (64x2 – 32x3 + 4x4) – 4(3x2 + 6x) = 4x(x3 – 8x2 + 13x – 6)

5. Let Hi  the event of getting a head on ith coin

6. (, ) and (, ) will lie on some line y = –x + 

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