CPE615-Lecture 8 Industrial Hygiene

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Faculty of Chemical Engineering

Universiti Teknologi MARA

Industrial Hygiene

Process Safety - CPE615


Introduction
• Industrial hygiene: a science devoted to the
identification, evaluation, and control of occupational
conditions that cause sickness and injury.

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• Typical activities involving industrial hygiene:
• monitoring toxic airborne vapour concentration,
• reducing toxic airborne vapours through the use of
ventilation,
• selecting proper PPE to prevent worker exposure,
• developing procedures for the handling of hazardous
materials,
• monitoring and reducing noise, heat, radiation, etc.
Introduction

• Three phases in any industrial hygiene project:


▪ Identification: determination of the presence or possibility
of workplace exposure.

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▪ Evaluation: determination of the magnitude of the exposure.
▪ Control: application of appropriate technology to reduce
workplace exposures to acceptable levels.
• Toxic chemicals can be handled safely when principles
of industrial hygiene are appropriately applied.
Identification
• During the
identification step,
the potential
hazards and

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methods of contact
are identified and
recorded.
Data required for hazard
identification

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Safety Data Sheets (SDS)
• One of the most important references used during an
industrial hygiene study involving toxic chemicals is the SDS.
• SDS lists the physical properties of substance that may be
required to determine the potential hazards of the substance.
It also can be used to develop a strategy for proper control

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and handling of the chemicals.
• SDS available from:
• The chemical manufacturer
• A commercial source
• A private library developed by the chemical plant
SDS
example

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Source:
https://www.chaffey.edu
/environmental_health_
safety/MSDS.shtml
Evaluation

• The evaluation phase determines the extent and


degree of employee exposure to toxicants and
physical hazards in the workplace environment.

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• A direct method for determining worker exposures is
by continuously monitoring the air concentrations of
toxicants on-line in a work environment.
• Continuous monitoring is not the usual situation
because most facilities do not have the necessary
equipment available.
Evaluation
• The more usual case is for intermittent samples to be
obtained, representing worker exposures at fixed
points in time.

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• If we assume that the concentration Ci is fixed (or
averaged) over the period of time Ti, the TWA
concentration is computed by:

C1T1 + C2T2 + .... + CnTn


TWA = ………………….(1.1)
8 hr
Evaluation
• If more than one chemical is present in the workplace,
we assume that the effects of the toxicants are
additive.
• The combined exposures from multiple toxicants with

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different TLV-TWA is determined from the equation:
n


Ci
………………….(1.2)
i =1
(TLV − TWA )i
Where,
n is the total number of toxicants
Ci is the concentration of chemical i with respect to the other toxicants
(TLV-TWA)i is the TLV-TWA for chemical species i.
Evaluation
• If the sum in equation 1.2 exceeds 1, then the workers
are overexposed.
• The mixture TLV-TWA can be computed from

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n

C
i =1
i
(TLV − TWA )mix = n
………………….(1.3)

Ci
i =1
(TLV − TWA) i

• If the sum of the concentrations of the toxicants in the


mixture exceeds this amount, then the workers are
overexposed.
Example 1
Air contains 5 ppm of diethylamine (TLV-TWA of 10
ppm), 20 ppm of cyclohexanol (TLV-TWA of 50 ppm)
and 10 ppm of propylene oxide (TLV-TWA of 20 ppm).

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What is the mixture TLV-TWA and has this level been
exceeded?
Answer:
Use eq 1.3, (TLV-TWA)mix = 25 ppm
The total mixture concentration = 35 ppm EXCEED
OR
Use eq 1.2, you get 1.40 which is bigger than 1.
So, exceed TLV-TWA
Example 2
Determine the 8-hr TWA worker exposure if the worker
is exposed to Turpentine vapours as follows:
Duration of exposure (hr) Measured concentration

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2 110
2 330
4 90

Answer:
Use eq 1.1, TWA = 155 ppm
Because TLV-TWA of turpentine is 100 ppm, the
worker is overexposed.
Example 3
Determine whether the following noise level is
permissible with no additional control features:
Noise Level (dBA) Duration (hr) Maximum Allowed (hr)

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85 3.6 No limit
95 3.0 4
110 0.5 0.5

Answer:
Use eq 1.2, the sum = 1.75 Exceed 1.0
Employees in this environment are required
to wear ear protection
Example 4
Determine the TLV for a uniform mixture of dusts
containing the following particles:
Type of dust Concentration TLV (mppcf)

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(wt%)
Nonasbestiform talc 70 20
Quartz 30 2.7

Answer:

Use eq 1.3, TLV of mixture = 6.8 mppcf


Control
• After potential health hazards are identified and
evaluated, the appropriate control techniques must
be developed and installed.

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• This requires the application of appropriate
technology for reducing workplace exposures.
• The two major control techniques:
▪ Environmental Control
▪ Personal Protection
Control
• Environmental Control
▪ Enclosures
▪ Ventilations
▪ Wet Methods (to minimise contamination with dusts)

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▪ Good Housekeeping
• Personal Protection (last line of defense)
▪ Safety glasses
▪ Face shields
▪ Aprons
▪ Space suits
▪ Ear plugs

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