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Appendix 1
PROPERTY TABLES AND CHARTS (SI UNITS)

Table A–1 Molar mass, gas constant, and Table A–20 Ideal-gas properties of carbon dioxide,
critical-point properties CO2
Table A–2 Ideal-gas specific heats of various Table A–21 Ideal-gas properties of carbon
common gases monoxide, CO
Table A–3 Properties of common liquids, solids, Table A–22 Ideal-gas properties of hydrogen, H2
and foods Table A–23 Ideal-gas properties of water vapor, H2O
Table A–4 Saturated water—Temperature table Table A–24 Ideal-gas properties of monatomic
Table A–5 Saturated water—Pressure table oxygen, O
Table A–6 Superheated water Table A–25 Ideal-gas properties of hydroxyl, OH
Table A–7 Compressed liquid water Table A–26 Enthalpy of formation, Gibbs function
Table A–8 Saturated ice–water vapor of formation, and absolute entropy at
25°C, 1 atm
Figure A–9 T-s diagram for water
Table A–27 Properties of some common fuels and
Figure A–10 Mollier diagram for water
hydrocarbons
Table A–11 Saturated refrigerant-134a—
Table A–28 Natural logarithms of the equilibrium
Temperature table
constant Kp
Table A–12 Saturated refrigerant-134a—
Figure A–29 Generalized enthalpy departure chart
Pressure table
Figure A–30 Generalized entropy departure chart
Table A–13 Superheated refrigerant-134a
Figure A–31 Psychrometric chart at 1 atm total
Figure A–14 P-h diagram for refrigerant-134a
pressure
Figure A–15 Nelson–Obert generalized
Table A–32 One-dimensional isentropic
compressibility chart
compressible-flow functions
Table A–16 Properties of the atmosphere at high for an ideal gas with k  1.4
altitude
Table A–33 One-dimensional normal-shock
Table A–17 Ideal-gas properties of air functions for an ideal gas with k  1.4
Table A–18 Ideal-gas properties of nitrogen, N2 Table A–34 Rayleigh flow functions for an ideal
Table A–19 Ideal-gas properties of oxygen, O2 gas with k  1.4

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TABLE A–17
Ideal-gas properties of air
T h u s° T h u s°
K kJ/kg Pr kJ/kg vr kJ/kg · K K kJ/kg Pr kJ/kg vr kJ/kg · K
200 199.97 0.3363 142.56 1707.0 1.29559 580 586.04 14.38 419.55 115.7 2.37348
210 209.97 0.3987 149.69 1512.0 1.34444 590 596.52 15.31 427.15 110.6 2.39140
220 219.97 0.4690 156.82 1346.0 1.39105 600 607.02 16.28 434.78 105.8 2.40902
230 230.02 0.5477 164.00 1205.0 1.43557 610 617.53 17.30 442.42 101.2 2.42644
240 240.02 0.6355 171.13 1084.0 1.47824 620 628.07 18.36 450.09 96.92 2.44356
250 250.05 0.7329 178.28 979.0 1.51917 630 638.63 19.84 457.78 92.84 2.46048
260 260.09 0.8405 185.45 887.8 1.55848 640 649.22 20.64 465.50 88.99 2.47716
270 270.11 0.9590 192.60 808.0 1.59634 650 659.84 21.86 473.25 85.34 2.49364
280 280.13 1.0889 199.75 738.0 1.63279 660 670.47 23.13 481.01 81.89 2.50985
285 285.14 1.1584 203.33 706.1 1.65055 670 681.14 24.46 488.81 78.61 2.52589
290 290.16 1.2311 206.91 676.1 1.66802 680 691.82 25.85 496.62 75.50 2.54175
295 295.17 1.3068 210.49 647.9 1.68515 690 702.52 27.29 504.45 72.56 2.55731
298 298.18 1.3543 212.64 631.9 1.69528 700 713.27 28.80 512.33 69.76 2.57277
300 300.19 1.3860 214.07 621.2 1.70203 710 724.04 30.38 520.23 67.07 2.58810
305 305.22 1.4686 217.67 596.0 1.71865 720 734.82 32.02 528.14 64.53 2.60319
310 310.24 1.5546 221.25 572.3 1.73498 730 745.62 33.72 536.07 62.13 2.61803
315 315.27 1.6442 224.85 549.8 1.75106 740 756.44 35.50 544.02 59.82 2.63280
320 320.29 1.7375 228.42 528.6 1.76690 750 767.29 37.35 551.99 57.63 2.64737
325 325.31 1.8345 232.02 508.4 1.78249 760 778.18 39.27 560.01 55.54 2.66176
330 330.34 1.9352 235.61 489.4 1.79783 780 800.03 43.35 576.12 51.64 2.69013
340 340.42 2.149 242.82 454.1 1.82790 800 821.95 47.75 592.30 48.08 2.71787
350 350.49 2.379 250.02 422.2 1.85708 820 843.98 52.59 608.59 44.84 2.74504
360 360.58 2.626 257.24 393.4 1.88543 840 866.08 57.60 624.95 41.85 2.77170
370 370.67 2.892 264.46 367.2 1.91313 860 888.27 63.09 641.40 39.12 2.79783
380 380.77 3.176 271.69 343.4 1.94001 880 910.56 68.98 657.95 36.61 2.82344
390 390.88 3.481 278.93 321.5 1.96633 900 932.93 75.29 674.58 34.31 2.84856
400 400.98 3.806 286.16 301.6 1.99194 920 955.38 82.05 691.28 32.18 2.87324
410 411.12 4.153 293.43 283.3 2.01699 940 977.92 89.28 708.08 30.22 2.89748
420 421.26 4.522 300.69 266.6 2.04142 960 1000.55 97.00 725.02 28.40 2.92128
430 431.43 4.915 307.99 251.1 2.06533 980 1023.25 105.2 741.98 26.73 2.94468
440 441.61 5.332 315.30 236.8 2.08870 1000 1046.04 114.0 758.94 25.17 2.96770
450 451.80 5.775 322.62 223.6 2.11161 1020 1068.89 123.4 776.10 23.72 2.99034
460 462.02 6.245 329.97 211.4 2.13407 1040 1091.85 133.3 793.36 23.29 3.01260
470 472.24 6.742 337.32 200.1 2.15604 1060 1114.86 143.9 810.62 21.14 3.03449
480 482.49 7.268 344.70 189.5 2.17760 1080 1137.89 155.2 827.88 19.98 3.05608
490 492.74 7.824 352.08 179.7 2.19876 1100 1161.07 167.1 845.33 18.896 3.07732
500 503.02 8.411 359.49 170.6 2.21952 1120 1184.28 179.7 862.79 17.886 3.09825
510 513.32 9.031 366.92 162.1 2.23993 1140 1207.57 193.1 880.35 16.946 3.11883
520 523.63 9.684 374.36 154.1 2.25997 1160 1230.92 207.2 897.91 16.064 3.13916
530 533.98 10.37 381.84 146.7 2.27967 1180 1254.34 222.2 915.57 15.241 3.15916
540 544.35 11.10 389.34 139.7 2.29906 1200 1277.79 238.0 933.33 14.470 3.17888
550 555.74 11.86 396.86 133.1 2.31809 1220 1301.31 254.7 951.09 13.747 3.19834
560 565.17 12.66 404.42 127.0 2.33685 1240 1324.93 272.3 968.95 13.069 3.21751
570 575.59 13.50 411.97 121.2 2.35531
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Appendix 1 | 937

TABLE A–17
Ideal-gas properties of air (Concluded)
T h u s° T h u s°
K kJ/kg Pr kJ/kg vr kJ/kg · K K kJ/kg Pr kJ/kg vr kJ/kg · K
1260 1348.55 290.8 986.90 12.435 3.23638 1600 1757.57 791.2 1298.30 5.804 3.52364
1280 1372.24 310.4 1004.76 11.835 3.25510 1620 1782.00 834.1 1316.96 5.574 3.53879
1300 1395.97 330.9 1022.82 11.275 3.27345 1640 1806.46 878.9 1335.72 5.355 3.55381
1320 1419.76 352.5 1040.88 10.747 3.29160 1660 1830.96 925.6 1354.48 5.147 3.56867
1340 1443.60 375.3 1058.94 10.247 3.30959 1680 1855.50 974.2 1373.24 4.949 3.58335
1360 1467.49 399.1 1077.10 9.780 3.32724 1700 1880.1 1025 1392.7 4.761 3.5979
1380 1491.44 424.2 1095.26 9.337 3.34474 1750 1941.6 1161 1439.8 4.328 3.6336
1400 1515.42 450.5 1113.52 8.919 3.36200 1800 2003.3 1310 1487.2 3.994 3.6684
1420 1539.44 478.0 1131.77 8.526 3.37901 1850 2065.3 1475 1534.9 3.601 3.7023
1440 1563.51 506.9 1150.13 8.153 3.39586 1900 2127.4 1655 1582.6 3.295 3.7354
1460 1587.63 537.1 1168.49 7.801 3.41247 1950 2189.7 1852 1630.6 3.022 3.7677
1480 1611.79 568.8 1186.95 7.468 3.42892 2000 2252.1 2068 1678.7 2.776 3.7994
1500 1635.97 601.9 1205.41 7.152 3.44516 2050 2314.6 2303 1726.8 2.555 3.8303
1520 1660.23 636.5 1223.87 6.854 3.46120 2100 2377.7 2559 1775.3 2.356 3.8605
1540 1684.51 672.8 1242.43 6.569 3.47712 2150 2440.3 2837 1823.8 2.175 3.8901
1560 1708.82 710.5 1260.99 6.301 3.49276 2200 2503.2 3138 1872.4 2.012 3.9191
1580 1733.17 750.0 1279.65 6.046 3.50829 2250 2566.4 3464 1921.3 1.864 3.9474

Note: The properties Pr (relative pressure) and vr (relative specific volume) are dimensionless quantities used in the analysis of isentropic processes, and
should not be confused with the properties pressure and specific volume.
Source: Kenneth Wark, Thermodynamics, 4th ed. (New York: McGraw-Hill, 1983), pp. 785–86, table A–5. Originally published in J. H. Keenan and
J. Kaye, Gas Tables (New York: John Wiley & Sons, 1948).
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938 | Thermodynamics

TABLE A–18
Ideal-gas properties of nitrogen, N2
_ _ _ _ _ _
T h u s° T h u s°
K kJ/kmol kJ/kmol kJ/kmol · K K kJ/kmol kJ/kmol kJ/kmol · K
0 0 0 0 600 17,563 12,574 212.066
220 6,391 4,562 182.639 610 17,864 12,792 212.564
230 6,683 4,770 183.938 620 18,166 13,011 213.055
240 6,975 4,979 185.180 630 18,468 13,230 213.541
250 7,266 5,188 186.370 640 18,772 13,450 214.018
260 7,558 5,396 187.514 650 19,075 13,671 214.489
270 7,849 5,604 188.614 660 19,380 13,892 214.954
280 8,141 5,813 189.673 670 19,685 14,114 215.413
290 8,432 6,021 190.695 680 19,991 14,337 215.866
298 8,669 6,190 191.502 690 20,297 14,560 216.314
300 8,723 6,229 191.682 700 20,604 14,784 216.756
310 9,014 6,437 192.638 710 20,912 15,008 217.192
320 9,306 6,645 193.562 720 21,220 15,234 217.624
330 9,597 6,853 194.459 730 21,529 15,460 218.059
340 9,888 7,061 195.328 740 21,839 15,686 218.472
350 10,180 7,270 196.173 750 22,149 15,913 218.889
360 10,471 7,478 196.995 760 22,460 16,141 219.301
370 10,763 7,687 197.794 770 22,772 16,370 219.709
380 11,055 7,895 198.572 780 23,085 16,599 220.113
390 11,347 8,104 199.331 790 23,398 16,830 220.512
400 11,640 8,314 200.071 800 23,714 17,061 220.907
410 11,932 8,523 200.794 810 24,027 17,292 221.298
420 12,225 8,733 201.499 820 24,342 17,524 221.684
430 12,518 8,943 202.189 830 24,658 17,757 222.067
440 12,811 9,153 202.863 840 24,974 17,990 222.447
450 13,105 9,363 203.523 850 25,292 18,224 222.822
460 13,399 9,574 204.170 860 25,610 18,459 223.194
470 13,693 9,786 204.803 870 25,928 18,695 223.562
480 13,988 9,997 205.424 880 26,248 18,931 223.927
490 14,285 10,210 206.033 890 26,568 19,168 224.288
500 14,581 10,423 206.630 900 26,890 19,407 224.647
510 14,876 10,635 207.216 910 27,210 19,644 225.002
520 15,172 10,848 207.792 920 27,532 19,883 225.353
530 15,469 11,062 208.358 930 27,854 20,122 225.701
540 15,766 11,277 208.914 940 28,178 20,362 226.047
550 16,064 11,492 209.461 950 28,501 20,603 226.389
560 16,363 11,707 209.999 960 28,826 20,844 226.728
570 16,662 11,923 210.528 970 29,151 21,086 227.064
580 16,962 12,139 211.049 980 29,476 21,328 227.398
590 17,262 12,356 211.562 990 29,803 21,571 227.728
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Appendix 1 | 939

TABLE A–18
Ideal-gas properties of nitrogen, N2 (Concluded)
_ _ _ _ _ _
T h u s° T h u s°
K kJ/kmol kJ/kmol kJ/kmol · K K kJ/kmol kJ/kmol kJ/kmol · K
1000 30,129 21,815 228.057 1760 56,227 41,594 247.396
1020 30,784 22,304 228.706 1780 56,938 42,139 247.798
1040 31,442 22,795 229.344 1800 57,651 42,685 248.195
1060 32,101 23,288 229.973 1820 58,363 43,231 248.589
1080 32,762 23,782 230.591 1840 59,075 43,777 248.979
1100 33,426 24,280 231.199 1860 59,790 44,324 249.365
1120 34,092 24,780 231.799 1880 60,504 44,873 249.748
1140 34,760 25,282 232.391 1900 61,220 45,423 250.128
1160 35,430 25,786 232.973 1920 61,936 45,973 250.502
1180 36,104 26,291 233.549 1940 62,654 46,524 250.874
1200 36,777 26,799 234.115 1960 63,381 47,075 251.242
1220 37,452 27,308 234.673 1980 64,090 47,627 251.607
1240 38,129 27,819 235.223 2000 64,810 48,181 251.969
1260 38,807 28,331 235.766 2050 66,612 49,567 252.858
1280 39,488 28,845 236.302 2100 68,417 50,957 253.726
1300 40,170 29,361 236.831 2150 70,226 52,351 254.578
1320 40,853 29,378 237.353 2200 72,040 53,749 255.412
1340 41,539 30,398 237.867 2250 73,856 55,149 256.227
1360 42,227 30,919 238.376 2300 75,676 56,553 257.027
1380 42,915 31,441 238.878 2350 77,496 57,958 257.810
1400 43,605 31,964 239.375 2400 79,320 59,366 258.580
1420 44,295 32,489 239.865 2450 81,149 60,779 259.332
1440 44,988 33,014 240.350 2500 82,981 62,195 260.073
1460 45,682 33,543 240.827 2550 84,814 63,613 260.799
1480 46,377 34,071 241.301 2600 86,650 65,033 261.512
1500 47,073 34,601 241.768 2650 88,488 66,455 262.213
1520 47,771 35,133 242.228 2700 90,328 67,880 262.902
1540 48,470 35,665 242.685 2750 92,171 69,306 263.577
1560 49,168 36,197 243.137 2800 94,014 70,734 264.241
1580 49,869 36,732 243.585 2850 95,859 72,163 264.895
1600 50,571 37,268 244.028 2900 97,705 73,593 265.538
1620 51,275 37,806 244.464 2950 99,556 75,028 266.170
1640 51,980 38,344 244.896 3000 101,407 76,464 266.793
1660 52,686 38,884 245.324 3050 103,260 77,902 267.404
1680 53,393 39,424 245.747 3100 105,115 79,341 268.007
1700 54,099 39,965 246.166 3150 106,972 80,782 268.601
1720 54,807 40,507 246.580 3200 108,830 82,224 269.186
1740 55,516 41,049 246.990 3250 110,690 83,668 269.763

Source: Tables A–18 through A–25 are adapted from Kenneth Wark, Thermodynamics, 4th ed. (New York: McGraw-Hill, 1983), pp. 787–98. Originally
published in JANAF, Thermochemical Tables, NSRDS-NBS-37, 1971.
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940 | Thermodynamics

TABLE A–19
Ideal-gas properties of oxygen, O2
_ _ _ _ _ _
T h u s° T h u s°
K kJ/kmol kJ/kmol kJ/kmol · K K kJ/kmol kJ/kmol kJ/kmol · K
0 0 0 0 600 17,929 12,940 226.346
220 6,404 4,575 196.171 610 18,250 13,178 226.877
230 6,694 4,782 197.461 620 18,572 13,417 227.400
240 6,984 4,989 198.696 630 18,895 13,657 227.918
250 7,275 5,197 199.885 640 19,219 13,898 228.429
260 7,566 5,405 201.027 650 19,544 14,140 228.932
270 7,858 5,613 202.128 660 19,870 14,383 229.430
280 8,150 5,822 203.191 670 20,197 14,626 229.920
290 8,443 6,032 204.218 680 20,524 14,871 230.405
298 8,682 6,203 205.033 690 20,854 15,116 230.885
300 8,736 6,242 205.213 700 21,184 15,364 231.358
310 9,030 6,453 206.177 710 21,514 15,611 231.827
320 9,325 6,664 207.112 720 21,845 15,859 232.291
330 9,620 6,877 208.020 730 22,177 16,107 232.748
340 9,916 7,090 208.904 740 22,510 16,357 233.201
350 10,213 7,303 209.765 750 22,844 16,607 233.649
360 10,511 7,518 210.604 760 23,178 16,859 234.091
370 10,809 7,733 211.423 770 23,513 17,111 234.528
380 11,109 7,949 212.222 780 23,850 17,364 234.960
390 11,409 8,166 213.002 790 24,186 17,618 235.387
400 11,711 8,384 213.765 800 24,523 17,872 235.810
410 12,012 8,603 214.510 810 24,861 18,126 236.230
420 12,314 8,822 215.241 820 25,199 18,382 236.644
430 12,618 9,043 215.955 830 25,537 18,637 237.055
440 12,923 9,264 216.656 840 25,877 18,893 237.462
450 13,228 9,487 217.342 850 26,218 19,150 237.864
460 13,525 9,710 218.016 860 26,559 19,408 238.264
470 13,842 9,935 218.676 870 26,899 19,666 238.660
480 14,151 10,160 219.326 880 27,242 19,925 239.051
490 14,460 10,386 219.963 890 27,584 20,185 239.439
500 14,770 10,614 220.589 900 27,928 20,445 239.823
510 15,082 10,842 221.206 910 28,272 20,706 240.203
520 15,395 11,071 221.812 920 28,616 20,967 240.580
530 15,708 11,301 222.409 930 28,960 21,228 240.953
540 16,022 11,533 222.997 940 29,306 21,491 241.323
550 16,338 11,765 223.576 950 29,652 21,754 241.689
560 16,654 11,998 224.146 960 29,999 22,017 242.052
570 16,971 12,232 224.708 970 30,345 22,280 242.411
580 17,290 12,467 225.262 980 30,692 22,544 242.768
590 17,609 12,703 225.808 990 31,041 22,809 242.120
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Appendix 1 | 941

TABLE A–19
Ideal-gas properties of oxygen, O2 (Concluded )
_ _ _ _ _ _
T h u s° T h u s°
K kJ/kmol kJ/kmol kJ/kmol · K K kJ/kmol kJ/kmol kJ/kmol · K
1000 31,389 23,075 243.471 1760 58,880 44,247 263.861
1020 32,088 23,607 244.164 1780 59,624 44,825 264.283
1040 32,789 24,142 244.844 1800 60,371 45,405 264.701
1060 33,490 24,677 245.513 1820 61,118 45,986 265.113
1080 34,194 25,214 246.171 1840 61,866 46,568 265.521
1100 34,899 25,753 246.818 1860 62,616 47,151 265.925
1120 35,606 26,294 247.454 1880 63,365 47,734 266.326
1140 36,314 26,836 248.081 1900 64,116 48,319 266.722
1160 37,023 27,379 248.698 1920 64,868 48,904 267.115
1180 37,734 27,923 249.307 1940 65,620 49,490 267.505
1200 38,447 28,469 249.906 1960 66,374 50,078 267.891
1220 39,162 29,018 250.497 1980 67,127 50,665 268.275
1240 39,877 29,568 251.079 2000 67,881 51,253 268.655
1260 40,594 30,118 251.653 2050 69,772 52,727 269.588
1280 41,312 30,670 252.219 2100 71,668 54,208 270.504
1300 42,033 31,224 252.776 2150 73,573 55,697 271.399
1320 42,753 31,778 253.325 2200 75,484 57,192 272.278
1340 43,475 32,334 253.868 2250 77,397 58,690 273.136
1360 44,198 32,891 254.404 2300 79,316 60,193 273.891
1380 44,923 33,449 254.932 2350 81,243 61,704 274.809
1400 45,648 34,008 255.454 2400 83,174 63,219 275.625
1420 46,374 34,567 255.968 2450 85,112 64,742 276.424
1440 47,102 35,129 256.475 2500 87,057 66,271 277.207
1460 47,831 35,692 256.978 2550 89,004 67,802 277.979
1480 48,561 36,256 257.474 2600 90,956 69,339 278.738
1500 49,292 36,821 257.965 2650 92,916 70,883 279.485
1520 50,024 37,387 258.450 2700 94,881 72,433 280.219
1540 50,756 37,952 258.928 2750 96,852 73,987 280.942
1560 51,490 38,520 259.402 2800 98,826 75,546 281.654
1580 52,224 39,088 259.870 2850 100,808 77,112 282.357
1600 52,961 39,658 260.333 2900 102,793 78,682 283.048
1620 53,696 40,227 260.791 2950 104,785 80,258 283.728
1640 54,434 40,799 261.242 3000 106,780 81,837 284.399
1660 55,172 41,370 261.690 3050 108,778 83,419 285.060
1680 55,912 41,944 262.132 3100 110,784 85,009 285.713
1700 56,652 42,517 262.571 3150 112,795 86,601 286.355
1720 57,394 43,093 263.005 3200 114,809 88,203 286.989
1740 58,136 43,669 263.435 3250 116,827 89,804 287.614
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942 | Thermodynamics

TABLE A–20
Ideal-gas properties of carbon dioxide, CO2
_ _ _ _ _ _
T h u s° T h u s°
K kJ/kmol kJ/kmol kJ/kmol · K K kJ/kmol kJ/kmol kJ/kmol · K
0 0 0 0 600 22,280 17,291 243.199
220 6,601 4,772 202.966 610 22,754 17,683 243.983
230 6,938 5,026 204.464 620 23,231 18,076 244.758
240 7,280 5,285 205.920 630 23,709 18,471 245.524
250 7,627 5,548 207.337 640 24,190 18,869 246.282
260 7,979 5,817 208.717 650 24,674 19,270 247.032
270 8,335 6,091 210.062 660 25,160 19,672 247.773
280 8,697 6,369 211.376 670 25,648 20,078 248.507
290 9,063 6,651 212.660 680 26,138 20,484 249.233
298 9,364 6,885 213.685 690 26,631 20,894 249.952
300 9,431 6,939 213.915 700 27,125 21,305 250.663
310 9,807 7,230 215.146 710 27,622 21,719 251.368
320 10,186 7,526 216.351 720 28,121 22,134 252.065
330 10,570 7,826 217.534 730 28,622 22,522 252.755
340 10,959 8,131 218.694 740 29,124 22,972 253.439
350 11,351 8,439 219.831 750 29,629 23,393 254.117
360 11,748 8,752 220.948 760 30,135 23,817 254.787
370 12,148 9,068 222.044 770 30,644 24,242 255.452
380 12,552 9,392 223.122 780 31,154 24,669 256.110
390 12,960 9,718 224.182 790 31,665 25,097 256.762
400 13,372 10,046 225.225 800 32,179 25,527 257.408
410 13,787 10,378 226.250 810 32,694 25,959 258.048
420 14,206 10,714 227.258 820 33,212 26,394 258.682
430 14,628 11,053 228.252 830 33,730 26,829 259.311
440 15,054 11,393 229.230 840 34,251 27,267 259.934
450 15,483 11,742 230.194 850 34,773 27,706 260.551
460 15,916 12,091 231.144 860 35,296 28,125 261.164
470 16,351 12,444 232.080 870 35,821 28,588 261.770
480 16,791 12,800 233.004 880 36,347 29,031 262.371
490 17,232 13,158 233.916 890 36,876 29,476 262.968
500 17,678 13,521 234.814 900 37,405 29,922 263.559
510 18,126 13,885 235.700 910 37,935 30,369 264.146
520 18,576 14,253 236.575 920 38,467 30,818 264.728
530 19,029 14,622 237.439 930 39,000 31,268 265.304
540 19,485 14,996 238.292 940 39,535 31,719 265.877
550 19,945 15,372 239.135 950 40,070 32,171 266.444
560 20,407 15,751 239.962 960 40,607 32,625 267.007
570 20,870 16,131 240.789 970 41,145 33,081 267.566
580 21,337 16,515 241.602 980 41,685 33,537 268.119
590 21,807 16,902 242.405 990 42,226 33,995 268.670
cen84959_ch18-ap01.qxd 8/11/06 1:21 PM Page 943

Appendix 1 | 943

TABLE A–20
Ideal-gas properties of carbon dioxide, CO2 (Concluded)
_ _ _ _ _ _
T h u s° T h u s°
K kJ/kmol kJ/kmol kJ/kmol · K K kJ/kmol kJ/kmol kJ/kmol · K
1000 42,769 34,455 269.215 1760 86,420 71,787 301.543
1020 43,859 35,378 270.293 1780 87,612 72,812 302.217
1040 44,953 36,306 271.354 1800 88,806 73,840 302.884
1060 46,051 37,238 272.400 1820 90,000 74,868 303.544
1080 47,153 38,174 273.430 1840 91,196 75,897 304.198
1100 48,258 39,112 274.445 1860 92,394 76,929 304.845
1120 49,369 40,057 275.444 1880 93,593 77,962 305.487
1140 50,484 41,006 276.430 1900 94,793 78,996 306.122
1160 51,602 41,957 277.403 1920 95,995 80,031 306.751
1180 52,724 42,913 278.361 1940 97,197 81,067 307.374
1200 53,848 43,871 297.307 1960 98,401 82,105 307.992
1220 54,977 44,834 280.238 1980 99,606 83,144 308.604
1240 56,108 45,799 281.158 2000 100,804 84,185 309.210
1260 57,244 46,768 282.066 2050 103,835 86,791 310.701
1280 58,381 47,739 282.962 2100 106,864 89,404 312.160
1300 59,522 48,713 283.847 2150 109,898 92,023 313.589
1320 60,666 49,691 284.722 2200 112,939 94,648 314.988
1340 61,813 50,672 285.586 2250 115,984 97,277 316.356
1360 62,963 51,656 286.439 2300 119,035 99,912 317.695
1380 64,116 52,643 287.283 2350 122,091 102,552 319.011
1400 65,271 53,631 288.106 2400 125,152 105,197 320.302
1420 66,427 54,621 288.934 2450 128,219 107,849 321.566
1440 67,586 55,614 289.743 2500 131,290 110,504 322.808
1460 68,748 56,609 290.542 2550 134,368 113,166 324.026
1480 66,911 57,606 291.333 2600 137,449 115,832 325.222
1500 71,078 58,606 292.114 2650 140,533 118,500 326.396
1520 72,246 59,609 292.888 2700 143,620 121,172 327.549
1540 73,417 60,613 292.654 2750 146,713 123,849 328.684
1560 74,590 61,620 294.411 2800 149,808 126,528 329.800
1580 76,767 62,630 295.161 2850 152,908 129,212 330.896
1600 76,944 63,741 295.901 2900 156,009 131,898 331.975
1620 78,123 64,653 296.632 2950 159,117 134,589 333.037
1640 79,303 65,668 297.356 3000 162,226 137,283 334.084
1660 80,486 66,592 298.072 3050 165,341 139,982 335.114
1680 81,670 67,702 298.781 3100 168,456 142,681 336.126
1700 82,856 68,721 299.482 3150 171,576 145,385 337.124
1720 84,043 69,742 300.177 3200 174,695 148,089 338.109
1740 85,231 70,764 300.863 3250 177,822 150,801 339.069
cen84959_ch18-ap01.qxd 8/11/06 1:21 PM Page 944

944 | Thermodynamics

TABLE A – 21
Ideal-gas properties of carbon monoxide, CO
_ _ _ _ _ _
T h u s° T h u s°
K kJ/kmol kJ/kmol kJ/kmol · K K kJ/kmol kJ/kmol kJ/kmol · K
0 0 0 0 600 17,611 12,622 218.204
220 6,391 4,562 188.683 610 17,915 12,843 218.708
230 6,683 4,771 189.980 620 18,221 13,066 219.205
240 6,975 4,979 191.221 630 18,527 13,289 219.695
250 7,266 5,188 192.411 640 18,833 13,512 220.179
260 7,558 5,396 193.554 650 19,141 13,736 220.656
270 7,849 5,604 194.654 660 19,449 13,962 221.127
280 8,140 5,812 195.713 670 19,758 14,187 221.592
290 8,432 6,020 196.735 680 20,068 14,414 222.052
298 8,669 6,190 197.543 690 20,378 14,641 222.505
300 8,723 6,229 197.723 700 20,690 14,870 222.953
310 9,014 6,437 198.678 710 21,002 15,099 223.396
320 9,306 6,645 199.603 720 21,315 15,328 223.833
330 9,597 6,854 200.500 730 21,628 15,558 224.265
340 9,889 7,062 201.371 740 21,943 15,789 224.692
350 10,181 7,271 202.217 750 22,258 16,022 225.115
360 10,473 7,480 203.040 760 22,573 16,255 225.533
370 10,765 7,689 203.842 770 22,890 16,488 225.947
380 11,058 7,899 204.622 780 23,208 16,723 226.357
390 11,351 8,108 205.383 790 23,526 16,957 226.762
400 11,644 8,319 206.125 800 23,844 17,193 227.162
410 11,938 8,529 206.850 810 24,164 17,429 227.559
420 12,232 8,740 207.549 820 24,483 17,665 227.952
430 12,526 8,951 208.252 830 24,803 17,902 228.339
440 12,821 9,163 208.929 840 25,124 18,140 228.724
450 13,116 9,375 209.593 850 25,446 18,379 229.106
460 13,412 9,587 210.243 860 25,768 18,617 229.482
470 13,708 9,800 210.880 870 26,091 18,858 229.856
480 14,005 10,014 211.504 880 26,415 19,099 230.227
490 14,302 10,228 212.117 890 26,740 19,341 230.593
500 14,600 10,443 212.719 900 27,066 19,583 230.957
510 14,898 10,658 213.310 910 27,392 19,826 231.317
520 15,197 10,874 213.890 920 27,719 20,070 231.674
530 15,497 11,090 214.460 930 28,046 20,314 232.028
540 15,797 11,307 215.020 940 28,375 20,559 232.379
550 16,097 11,524 215.572 950 28,703 20,805 232.727
560 16,399 11,743 216.115 960 29,033 21,051 233.072
570 16,701 11,961 216.649 970 29,362 21,298 233.413
580 17,003 12,181 217.175 980 29,693 21,545 233.752
590 17,307 12,401 217.693 990 30,024 21,793 234.088
cen84959_ch18-ap01.qxd 8/11/06 1:21 PM Page 945

Appendix 1 | 945

TABLE A–21
Ideal-gas properties of carbon monoxide, CO (Concluded)
_ _ _ _ _ _
T h u s° T h u s°
K kJ/kmol kJ/kmol kJ/kmol · K K kJ/kmol kJ/kmol kJ/kmol · K
1000 30,355 22,041 234.421 1760 56,756 42,123 253.991
1020 31,020 22,540 235.079 1780 57,473 42,673 254.398
1040 31,688 23,041 235.728 1800 58,191 43,225 254.797
1060 32,357 23,544 236.364 1820 58,910 43,778 255.194
1080 33,029 24,049 236.992 1840 59,629 44,331 255.587
1100 33,702 24,557 237.609 1860 60,351 44,886 255.976
1120 34,377 25,065 238.217 1880 61,072 45,441 256.361
1140 35,054 25,575 238.817 1900 61,794 45,997 256.743
1160 35,733 26,088 239.407 1920 62,516 46,552 257.122
1180 36,406 26,602 239.989 1940 63,238 47,108 257.497
1200 37,095 27,118 240.663 1960 63,961 47,665 257.868
1220 37,780 27,637 241.128 1980 64,684 48,221 258.236
1240 38,466 28,426 241.686 2000 65,408 48,780 258.600
1260 39,154 28,678 242.236 2050 67,224 50,179 259.494
1280 39,844 29,201 242.780 2100 69,044 51,584 260.370
1300 40,534 29,725 243.316 2150 70,864 52,988 261.226
1320 41,226 30,251 243.844 2200 72,688 54,396 262.065
1340 41,919 30,778 244.366 2250 74,516 55,809 262.887
1360 42,613 31,306 244.880 2300 76,345 57,222 263.692
1380 43,309 31,836 245.388 2350 78,178 58,640 264.480
1400 44,007 32,367 245.889 2400 80,015 60,060 265.253
1420 44,707 32,900 246.385 2450 81,852 61,482 266.012
1440 45,408 33,434 246.876 2500 83,692 62,906 266.755
1460 46,110 33,971 247.360 2550 85,537 64,335 267.485
1480 46,813 34,508 247.839 2600 87,383 65,766 268.202
1500 47,517 35,046 248.312 2650 89,230 67,197 268.905
1520 48,222 35,584 248.778 2700 91,077 68,628 269.596
1540 48,928 36,124 249.240 2750 92,930 70,066 270.285
1560 49,635 36,665 249.695 2800 94,784 71,504 270.943
1580 50,344 37,207 250.147 2850 96,639 72,945 271.602
1600 51,053 37,750 250.592 2900 98,495 74,383 272.249
1620 51,763 38,293 251.033 2950 100,352 75,825 272.884
1640 52,472 38,837 251.470 3000 102,210 77,267 273.508
1660 53,184 39,382 251.901 3050 104,073 78,715 274.123
1680 53,895 39,927 252.329 3100 105,939 80,164 274.730
1700 54,609 40,474 252.751 3150 107,802 81,612 275.326
1720 55,323 41,023 253.169 3200 109,667 83,061 275.914
1740 56,039 41,572 253.582 3250 111,534 84,513 276.494
cen84959_ch18-ap01.qxd 8/11/06 1:21 PM Page 946

946 | Thermodynamics

TABLE A–22
Ideal-gas properties of hydrogen, H2
_ _ _ _ _ _
T h u s° T h u s°
K kJ/kmol kJ/kmol kJ/kmol · K K kJ/kmol kJ/kmol kJ/kmol · K
0 0 0 0 1440 42,808 30,835 177.410
260 7,370 5,209 126.636 1480 44,091 31,786 178.291
270 7,657 5,412 127.719 1520 45,384 32,746 179.153
280 7,945 5,617 128.765 1560 46,683 33,713 179.995
290 8,233 5,822 129.775 1600 47,990 34,687 180.820
298 8,468 5,989 130.574 1640 49,303 35,668 181.632
300 8,522 6,027 130.754 1680 50,622 36,654 182.428
320 9,100 6,440 132.621 1720 51,947 37,646 183.208
340 9,680 6,853 134.378 1760 53,279 38,645 183.973
360 10,262 7,268 136.039 1800 54,618 39,652 184.724
380 10,843 7,684 137.612 1840 55,962 40,663 185.463
400 11,426 8,100 139.106 1880 57,311 41,680 186.190
420 12,010 8,518 140.529 1920 58,668 42,705 186.904
440 12,594 8,936 141.888 1960 60,031 43,735 187.607
460 13,179 9,355 143.187 2000 61,400 44,771 188.297
480 13,764 9,773 144.432 2050 63,119 46,074 189.148
500 14,350 10,193 145.628 2100 64,847 47,386 189.979
520 14,935 10,611 146.775 2150 66,584 48,708 190.796
560 16,107 11,451 148.945 2200 68,328 50,037 191.598
600 17,280 12,291 150.968 2250 70,080 51,373 192.385
640 18,453 13,133 152.863 2300 71,839 52,716 193.159
680 19,630 13,976 154.645 2350 73,608 54,069 193.921
720 20,807 14,821 156.328 2400 75,383 55,429 194.669
760 21,988 15,669 157.923 2450 77,168 56,798 195.403
800 23,171 16,520 159.440 2500 78,960 58,175 196.125
840 24,359 17,375 160.891 2550 80,755 59,554 196.837
880 25,551 18,235 162.277 2600 82,558 60,941 197.539
920 26,747 19,098 163.607 2650 84,368 62,335 198.229
960 27,948 19,966 164.884 2700 86,186 63,737 198.907
1000 29,154 20,839 166.114 2750 88,008 65,144 199.575
1040 30,364 21,717 167.300 2800 89,838 66,558 200.234
1080 31,580 22,601 168.449 2850 91,671 67,976 200.885
1120 32,802 23,490 169.560 2900 93,512 69,401 201.527
1160 34,028 24,384 170.636 2950 95,358 70,831 202.157
1200 35,262 25,284 171.682 3000 97,211 72,268 202.778
1240 36,502 26,192 172.698 3050 99,065 73,707 203.391
1280 37,749 27,106 173.687 3100 100,926 75,152 203.995
1320 39,002 28,027 174.652 3150 102,793 76,604 204.592
1360 40,263 28,955 175.593 3200 104,667 78,061 205.181
1400 41,530 29,889 176.510 3250 106,545 79,523 205.765
cen84959_ch18-ap01.qxd 8/11/06 1:21 PM Page 947

Appendix 1 | 947

TABLE A–23
Ideal-gas properties of water vapor, H2O
_ _ _ _ _ _
T h u s° T h u s°
K kJ/kmol kJ/kmol kJ/kmol · K K kJ/kmol kJ/kmol kJ/kmol · K
0 0 0 0 600 20,402 15,413 212.920
220 7,295 5,466 178.576 610 20,765 15,693 213.529
230 7,628 5,715 180.054 620 21,130 15,975 214.122
240 7,961 5,965 181.471 630 21,495 16,257 214.707
250 8,294 6,215 182.831 640 21,862 16,541 215.285
260 8,627 6,466 184.139 650 22,230 16,826 215.856
270 8,961 6,716 185.399 660 22,600 17,112 216.419
280 9,296 6,968 186.616 670 22,970 17,399 216.976
290 9,631 7,219 187.791 680 23,342 17,688 217.527
298 9,904 7,425 188.720 690 23,714 17,978 218.071
300 9,966 7,472 188.928 700 24,088 18,268 218.610
310 10,302 7,725 190.030 710 24,464 18,561 219.142
320 10,639 7,978 191.098 720 24,840 18,854 219.668
330 10,976 8,232 192.136 730 25,218 19,148 220.189
340 11,314 8,487 193.144 740 25,597 19,444 220.707
350 11,652 8,742 194.125 750 25,977 19,741 221.215
360 11,992 8,998 195.081 760 26,358 20,039 221.720
370 12,331 9,255 196.012 770 26,741 20,339 222.221
380 12,672 9,513 196.920 780 27,125 20,639 222.717
390 13,014 9,771 197.807 790 27,510 20,941 223.207
400 13,356 10,030 198.673 800 27,896 21,245 223.693
410 13,699 10,290 199.521 810 28,284 21,549 224.174
420 14,043 10,551 200.350 820 28,672 21,855 224.651
430 14,388 10,813 201.160 830 29,062 22,162 225.123
440 14,734 11,075 201.955 840 29,454 22,470 225.592
450 15,080 11,339 202.734 850 29,846 22,779 226.057
460 15,428 11,603 203.497 860 30,240 23,090 226.517
470 15,777 11,869 204.247 870 30,635 23,402 226.973
480 16,126 12,135 204.982 880 31,032 23,715 227.426
490 16,477 12,403 205.705 890 31,429 24,029 227.875
500 16,828 12,671 206.413 900 31,828 24,345 228.321
510 17,181 12,940 207.112 910 32,228 24,662 228.763
520 17,534 13,211 207.799 920 32,629 24,980 229.202
530 17,889 13,482 208.475 930 33,032 25,300 229.637
540 18,245 13,755 209.139 940 33,436 25,621 230.070
550 18,601 14,028 209.795 950 33,841 25,943 230.499
560 18,959 14,303 210.440 960 34,247 26,265 230.924
570 19,318 14,579 211.075 970 34,653 26,588 231.347
580 19,678 14,856 211.702 980 35,061 26,913 231.767
590 20,039 15,134 212.320 990 35,472 27,240 232.184
cen84959_ch18-ap01.qxd 8/11/06 1:21 PM Page 948

948 | Thermodynamics

TABLE A–23
Ideal-gas properties of water vapor, H2O (Concluded )
_ _ _ _ _ _
T h u s° T h u s°
K kJ/kmol kJ/kmol kJ/kmol · K K kJ/kmol kJ/kmol kJ/kmol · K
1000 35,882 27,568 232.597 1760 70,535 55,902 258.151
1020 36,709 28,228 233.415 1780 71,523 56,723 258.708
1040 37,542 28,895 234.223 1800 72,513 57,547 259.262
1060 38,380 29,567 235.020 1820 73,507 58,375 259.811
1080 39,223 30,243 235.806 1840 74,506 59,207 260.357
1100 40,071 30,925 236.584 1860 75,506 60,042 260.898
1120 40,923 31,611 237.352 1880 76,511 60,880 261.436
1140 41,780 32,301 238.110 1900 77,517 61,720 261.969
1160 42,642 32,997 238.859 1920 78,527 62,564 262.497
1180 43,509 33,698 239.600 1940 79,540 63,411 263.022
1200 44,380 34,403 240.333 1960 80,555 64,259 263.542
1220 45,256 35,112 241.057 1980 81,573 65,111 264.059
1240 46,137 35,827 241.773 2000 82,593 65,965 264.571
1260 47,022 36,546 242.482 2050 85,156 68,111 265.838
1280 47,912 37,270 243.183 2100 87,735 70,275 267.081
1300 48,807 38,000 243.877 2150 90,330 72,454 268.301
1320 49,707 38,732 244.564 2200 92,940 74,649 269.500
1340 50,612 39,470 245.243 2250 95,562 76,855 270.679
1360 51,521 40,213 245.915 2300 98,199 79,076 271.839
1380 52,434 40,960 246.582 2350 100,846 81,308 272.978
1400 53,351 41,711 247.241 2400 103,508 83,553 274.098
1420 54,273 42,466 247.895 2450 106,183 85,811 275.201
1440 55,198 43,226 248.543 2500 108,868 88,082 276.286
1460 56,128 43,989 249.185 2550 111,565 90,364 277.354
1480 57,062 44,756 249.820 2600 114,273 92,656 278.407
1500 57,999 45,528 250.450 2650 116,991 94,958 279.441
1520 58,942 46,304 251.074 2700 119,717 97,269 280.462
1540 59,888 47,084 251.693 2750 122,453 99,588 281.464
1560 60,838 47,868 252.305 2800 125,198 101,917 282.453
1580 61,792 48,655 252.912 2850 127,952 104,256 283.429
1600 62,748 49,445 253.513 2900 130,717 106,605 284.390
1620 63,709 50,240 254.111 2950 133,486 108,959 285.338
1640 64,675 51,039 254.703 3000 136,264 111,321 286.273
1660 65,643 51,841 255.290 3050 139,051 113,692 287.194
1680 66,614 52,646 255.873 3100 141,846 116,072 288.102
1700 67,589 53,455 256.450 3150 144,648 118,458 288.999
1720 68,567 54,267 257.022 3200 147,457 120,851 289.884
1740 69,550 55,083 257.589 3250 150,272 123,250 290.756
cen84959_ch18-ap01.qxd 8/11/06 1:21 PM Page 949

Appendix 1 | 949

TABLE A–24
Ideal-gas properties of monatomic oxygen, O
_ _ _ _ _ _
T h u s° T h u s°
K kJ/kmol kJ/kmol kJ/kmol · K K kJ/kmol kJ/kmol kJ/kmol · K
0 0 0 0 2400 50,894 30,940 204.932
298 6,852 4,373 160.944 2450 51,936 31,566 205.362
300 6,892 4,398 161.079 2500 52,979 32,193 205.783
500 11,197 7,040 172.088 2550 54,021 32,820 206.196
1000 21,713 13,398 186.678 2600 55,064 33,447 206.601
1500 32,150 19,679 195.143 2650 56,108 34,075 206.999
1600 34,234 20,931 196.488 2700 57,152 34,703 207.389
1700 36,317 22,183 197.751 2750 58,196 35,332 207.772
1800 38,400 23,434 198.941 2800 59,241 35,961 208.148
1900 40,482 24,685 200.067 2850 60,286 36,590 208.518
2000 42,564 25,935 201.135 2900 61,332 37,220 208.882
2050 43,605 26,560 201.649 2950 62,378 37,851 209.240
2100 44,646 27,186 202.151 3000 63,425 38,482 209.592
2150 45,687 27,811 202.641 3100 65,520 39,746 210.279
2200 46,728 28,436 203.119 3200 67,619 41,013 210.945
2250 47,769 29,062 203.588 3300 69,720 42,283 211.592
2300 48,811 29,688 204.045 3400 71,824 43,556 212.220
2350 49,852 30,314 204.493 3500 73,932 44,832 212.831

TABLE A–25
Ideal-gas properties of hydroxyl, OH
_ _ _ _ _ _
T h u s° T h u s°
K kJ/kmol kJ/kmol kJ/kmol · K K kJ/kmol kJ/kmol kJ/kmol · K
0 0 0 0 2400 77,015 57,061 248.628
298 9,188 6,709 183.594 2450 78,801 58,431 249.364
300 9,244 6,749 183.779 2500 80,592 59,806 250.088
500 15,181 11,024 198.955 2550 82,388 61,186 250.799
1000 30,123 21,809 219.624 2600 84,189 62,572 251.499
1500 46,046 33,575 232.506 2650 85,995 63,962 252.187
1600 49,358 36,055 234.642 2700 87,806 65,358 252.864
1700 52,706 38,571 236.672 2750 89,622 66,757 253.530
1800 56,089 41,123 238.606 2800 91,442 68,162 254.186
1900 59,505 43,708 240.453 2850 93,266 69,570 254.832
2000 62,952 46,323 242.221 2900 95,095 70,983 255.468
2050 64,687 47,642 243.077 2950 96,927 72,400 256.094
2100 66,428 48,968 243.917 3000 98,763 73,820 256.712
2150 68,177 50,301 244.740 3100 102,447 76,673 257.919
2200 69,932 51,641 245.547 3200 106,145 79,539 259.093
2250 71,694 52,987 246.338 3300 109,855 82,418 260.235
2300 73,462 54,339 247.116 3400 113,578 85,309 261.347
2350 75,236 55,697 247.879 3500 117,312 88,212 262.429
cen84959_ch18-ap01.qxd 8/11/06 1:21 PM Page 950

950 | Thermodynamics

TABLE A–26
Enthalpy of formation, Gibbs function of formation, and absolute entropy at
25°C, 1 atm
_ _ _
hf° gf° s°
Substance Formula kJ/kmol kJ/kmol kJ/kmol · K

Carbon C(s) 0 0 5.74

Hydrogen H2(g) 0 0 130.68
Nitrogen N2(g) 0 0 191.61
Oxygen O2(g) 0 0 205.04
Carbon monoxide CO(g) 110,530 137,150 197.65
Carbon dioxide CO2(g) 393,520 394,360 213.80
Water vapor H2O(g) 241,820 228,590 188.83
Water H2O() 285,830 237,180 69.92
Hydrogen peroxide H2O2(g) 136,310 105,600 232.63
Ammonia NH3(g) 46,190 16,590 192.33
Methane CH4(g) 74,850 50,790 186.16
Acetylene C2H2(g) +226,730 +209,170 200.85
Ethylene C2H4(g) +52,280 +68,120 219.83
Ethane C2H6(g) 84,680 32,890 229.49
Propylene C3H6(g) +20,410 +62,720 266.94
Propane C3H8(g) 103,850 23,490 269.91
n-Butane C4H10(g) 126,150 15,710 310.12
n-Octane C8H18(g) 208,450 +16,530 466.73
n-Octane C8H18() 249,950 +6,610 360.79
n-Dodecane C12H26(g) 291,010 +50,150 622.83
Benzene C6H6(g) +82,930 +129,660 269.20
Methyl alcohol CH3OH(g) 200,670 162,000 239.70
Methyl alcohol CH3OH() 238,660 166,360 126.80
Ethyl alcohol C2H5OH(g) 235,310 168,570 282.59
Ethyl alcohol C2H5OH() 277,690 174,890 160.70
Oxygen O(g) +249,190 +231,770 161.06
Hydrogen H(g) +218,000 +203,290 114.72
Nitrogen N(g) +472,650 +455,510 153.30
Hydroxyl OH(g) +39,460 +34,280 183.70

Source: From JANAF, Thermochemical Tables (Midland, MI: Dow Chemical Co., 1971); Selected
Values of Chemical Thermodynamic Properties, NBS Technical Note 270-3, 1968; and API
Research Project 44 (Carnegie Press, 1953).
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Appendix 1 | 951

TABLE A–27
Properties of some common fuels and hydrocarbons
Higher Lower
Molar Enthalpy of Specific heating heating
mass, Density,1 vaporization,2 heat,1 cp value,3 value,3
Fuel (phase) Formula kg/kmol kg/L kJ/kg kJ/kg · K kJ/kg kJ/kg
Carbon (s) C 12.011 2 — 0.708 32,800 32,800
Hydrogen (g) H2 2.016 — — 14.4 141,800 120,000
Carbon monoxide (g) CO 28.013 — — 1.05 10,100 10,100
Methane (g) CH4 16.043 — 509 2.20 55,530 50,050
Methanol () CH4O 32.042 0.790 1168 2.53 22,660 19,920
Acetylene (g) C2H2 26.038 — — 1.69 49,970 48,280
Ethane (g) C2H6 30.070 — 172 1.75 51,900 47,520
Ethanol () C2H6O 46.069 0.790 919 2.44 29,670 26,810
Propane () C3H8 44.097 0.500 335 2.77 50,330 46,340
Butane () C4H10 58.123 0.579 362 2.42 49,150 45,370
1-Pentene () C5H10 70.134 0.641 363 2.20 47,760 44,630
Isopentane () C5H12 72.150 0.626 — 2.32 48,570 44,910
Benzene () C6H6 78.114 0.877 433 1.72 41,800 40,100
Hexene () C6H12 84.161 0.673 392 1.84 47,500 44,400
Hexane () C6H14 86.177 0.660 366 2.27 48,310 44,740
Toluene () C7H8 92.141 0.867 412 1.71 42,400 40,500
Heptane () C7H16 100.204 0.684 365 2.24 48,100 44,600
Octane () C8H18 114.231 0.703 363 2.23 47,890 44,430
Decane () C10H22 142.285 0.730 361 2.21 47,640 44,240
Gasoline () CnH1.87n 100–110 0.72–0.78 350 2.4 47,300 44,000
Light diesel () CnH1.8n 170 0.78–0.84 270 2.2 46,100 43,200
Heavy diesel () CnH1.7n 200 0.82–0.88 230 1.9 45,500 42,800
Natural gas (g) CnH3.8nN0.1n 18 — — 2 50,000 45,000
1At 1 atm and 20°C.
2At 25°C for liquid fuels, and 1 atm and normal boiling temperature for gaseous fuels.
3At 25°C. Multiply by molar mass to obtain heating values in kJ/kmol.
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952 | Thermodynamics

TABLE A–28
Natural logarithms of the equilibrium constant Kp
PCnC PDnD
The equilibrium constant Kp for the reaction nA A + nB B ∆ nC C + nD D is defined as Kp ≡
PAnA PBnB
Temp.,
K H2 ∆ 2H O2 ∆ 2O N2 ∆ 2N H2O ∆ H2 + 1/2O2 H2O ∆ 1/2H2 + OH CO2 ∆ CO + 1/2O2 1/ N
2 2 + 1/2O2 ∆ NO

298 164.005 186.975 367.480 92.208 106.208 103.762 35.052

500 92.827 105.630 213.372 52.691 60.281 57.616 20.295
1000 39.803 45.150 99.127 23.163 26.034 23.529 9.388
1200 30.874 35.005 80.011 18.182 20.283 17.871 7.569
1400 24.463 27.742 66.329 14.609 16.099 13.842 6.270
1600 19.637 22.285 56.055 11.921 13.066 10.830 5.294
1800 15.866 18.030 48.051 9.826 10.657 8.497 4.536
2000 12.840 14.622 41.645 8.145 8.728 6.635 3.931
2200 10.353 11.827 36.391 6.768 7.148 5.120 3.433
2400 8.276 9.497 32.011 5.619 5.832 3.860 3.019
2600 6.517 7.521 28.304 4.648 4.719 2.801 2.671
2800 5.002 5.826 25.117 3.812 3.763 1.894 2.372
3000 3.685 4.357 22.359 3.086 2.937 1.111 2.114
3200 2.534 3.072 19.937 2.451 2.212 0.429 1.888
3400 1.516 1.935 17.800 1.891 1.576 0.169 1.690
3600 0.609 0.926 15.898 1.392 1.088 0.701 1.513
3800 0.202 0.019 14.199 0.945 0.501 1.176 1.356
4000 0.934 0.796 12.660 0.542 0.044 1.599 1.216
4500 2.486 2.513 9.414 0.312 0.920 2.490 0.921
5000 3.725 3.895 6.807 0.996 1.689 3.197 0.686
5500 4.743 5.023 4.666 1.560 2.318 3.771 0.497
6000 5.590 5.963 2.865 2.032 2.843 4.245 0.341

Source: Gordon J. Van Wylen and Richard E. Sonntag, Fundamentals of Classical Thermodynamics, English/SI Version, 3rd ed. (New York: John Wiley &
Sons, 1986), p. 723, table A.14. Based on thermodynamic data given in JANAF, Thermochemical Tables (Midland, MI: Thermal Research Laboratory, The
Dow Chemical Company, 1971).