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    At RT P VBVVB: Calculate Z, GR, HR and SR For Co2 at 325 K and 60 Bar Using R-K Eos. Answer

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    Rachita Prakash Saraf
    1) The Redlich-Kwong equation of state is used to calculate Z, GR, HR, and SR for CO2 at 325 K and 60 bar. 2) Values for the gas constants like critical temperature and pressure are obtained from literature. 3) Parameters like beta, q, Z, I are calculated by inserting the values in the respective equations. 4) GR is calculated to be -667.4 J/mol, HR is calculated to be -2302.1 J/mol, and SR is calculated to be -5.03 J/(mol∙K).

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    At RT P VBVVB: Calculate Z, GR, HR and SR For Co2 at 325 K and 60 Bar Using R-K Eos. Answer

    Uploaded by

    Rachita Prakash Saraf
    371 views2 pages
    1) The Redlich-Kwong equation of state is used to calculate Z, GR, HR, and SR for CO2 at 325 K and 60 bar. 2) Values for the gas constants like critical temperature and pressure are obtained from literature. 3) Parameters like beta, q, Z, I are calculated by inserting the values in the respective equations. 4) GR is calculated to be -667.4 J/mol, HR is calculated to be -2302.1 J/mol, and SR is calculated to be -5.03 J/(mol∙K).

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    q41063965

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    1) The Redlich-Kwong equation of state is used to calculate Z, GR, HR, and SR for CO2 at 325 K and 60 bar. 2) Values for the gas constants like critical temperature and pressure are obtained from literature. 3) Parameters like beta, q, Z, I are calculated by inserting the values in the respective equations. 4) GR is calculated to be -667.4 J/mol, HR is calculated to be -2302.1 J/mol, and SR is calculated to be -5.03 J/(mol∙K).

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    © All Rights Reserved
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    Download as docx, pdf, or txt
    371 views2 pages

    At RT P VBVVB: Calculate Z, GR, HR and SR For Co2 at 325 K and 60 Bar Using R-K Eos. Answer

    Uploaded by

    Rachita Prakash Saraf
    1) The Redlich-Kwong equation of state is used to calculate Z, GR, HR, and SR for CO2 at 325 K and 60 bar. 2) Values for the gas constants like critical temperature and pressure are obtained from literature. 3) Parameters like beta, q, Z, I are calculated by inserting the values in the respective equations. 4) GR is calculated to be -667.4 J/mol, HR is calculated to be -2302.1 J/mol, and SR is calculated to be -5.03 J/(mol∙K).

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    © All Rights Reserved
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    https://www.chegg.

    com/homework-help/questions-and-answers/-q41063965

    Calculate Z, GR, HR and SR for CO2 at 325 K and 60 bar using R-K EoS.

    Answer:

    The R-K equation of state is given as:

    RT a T 
    P 
    V  b V  V  b
    …… (1)

    Here, P is the pressure of the gas, V is the volume of the gas, T is the temperature of the gas, b
    and a(T) are the parameters, and R is the universal gas constant.

    b and a  T 
    The value of are given as:

    RTc
    b  0.08664 ...... (2)
    Pc
    R 2Tc2
    a  T   0.42748 ...... (3)
    Tr1 2 Pc

    Here, Tc and Pc are critical temperature and pressure of the gas respectively and Tr is reduced
    temperature.

    Given data:

    T  325 K
    P  60 bar

    R  0.08314  bar  L   mol  K 


    Take the value of R as

    From table of properties for pure substance, Tc and Pc for CO2 are:

    Tc  304.2 K
    Pc  73.83 bar

    Calculate the value of reduced temperature as:

    T
    Tr 
    Tc
    325 K

    304.2 K
     1.068

    b and a  T 
    Now, calculate the value of using equations (2) and (3) respectively as:

    RTc
    b  0.08664
    Pc
      bar  L   304.2 K
     0.08314  
      mol  K  
     0.08664
     73.83 bar 
     0.0297 L mol
    R 2Tc2
    a  T   0.42748 1 2
    Tr Pc
    2
      bar  L   304.2 K 2
     0.08314   
      mol  K  
     0.42748
     1.068  73.83 bar 
    12

     3.584  bar  L2   mol 


    2

    Now, calculate the value of  and q as:

    bP
    
    RT
     L 
     0.0297   60 bar 
      mol 
      bar  L   325 K
     0.08314  
      mol  K  
     0.066
    aT 
    q
    bRT

    3.584
     bar  L  2


     mol  2
     L   bar  L   325 K
     0.0297   0.08314  
     mol    mol  K  
     4.466

    Calculate the value of Z as:

     Z  
    Z  1    q   
    ZZ  
     Z  0.066 
    Z  1  0.066   4.466   0.066   
     Z  Z  0.066  
    Z  0.729
    Now, Calculate the value of I as:

    1  Z   
    I ln 
        Z   
    For RK equation of states,
      1 and   0
    1   0.729    1  0.066  
    I ln  
    1  0   0.729    0   0.066  
    I  0.0867

    G R is calculated as:

    GR
     Z  1  ln  Z     qI
    RT
    GR
      0.729   1  ln  0.729  0.066    4.466   0.0867 
      bar  L  
     0.08314   325 K 
      mol  K  
      bar  L   325 K 0.247
    G R   0.08314   
      mol  K  
    G R  6.674
     bar  L 
     mol 
    G R  667.4 J/mol

    dq
    To calculate H and S , value of dTr is required. It is calculated as:
    R R

    dq

    d
    dTr dTr

    4.934Tr3 2 
     3
     4.934    Tr5 2
     2
     3
     4.934     1.068 
    5 2

     2
     6.279

    R
    Now, calculate H as:

    HR  dq 
     Z  1  Tr  I
    RT  dTr 
    HR
     0.729  1   1.068   6.279   0.0867 
      bar  L  
     0.08314   325 K 
      mol  K  
      bar  L   325 K 0.852
    H R   0.08314   
      mol  K  
    H R  23.021
     bar  L 
     mol 
    H R  2302.1 J/mol

    R
    Now, calculate S as:

    SR  dq 
     ln  Z      q  Tr I
    R  dTr 
    SR
     ln  0.729  0.066    4.466   1.068   6.279    0.0867 
      bar  L  
     0.08314 
      mol  K  
      bar  L  
    S R   0.08314   0.6052 
      mol  K  

    S R  0.0503
     bar  L 
     mol  K 
    S R  5.03 J/  mol  K 

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