Thermal Expansion
Thermal Expansion
Thermal Expansion
expansion
o changes in volume compared to original
volume (ΔV/V ) called volumetric
0
expansion or cubical expansion
For most materials, over small temperature
ranges, these fractional changes…
o are directly proportional to temperature
change (ΔT) and
o have the same sign (i.e., materials usually
expand when heated and contract when
cooled)
o are larger for liquids than solids
A coefficient of thermal expansion…
o is the ratio of the fractional change in size
of a material to its change in temperature
o is represented by the symbol α (alpha) for
solids and β (beta) for liquids
o uses the SI unit inverse kelvin (K or 1/K) or
−1
Solids…
o tend to retain their shape when not
constrained and so are best described by a
linear coefficient of thermal
expansion, α (alpha).
o have an areal expansion that is very nearly
twice their linear expansion, 2α (since two
perpendicular linear measurements describe
an area)
o have a volumetric expansion that is very
nearly three times their linear
expansion, 3α(since three perpendicular linear
measurements describe a volume)
Liquids…
o tend to take on the shape of their container
and so are best described by a volumetric
coefficient of thermal expansion, β (beta).
Gases…
o have a thermal expansion that is best
described using the ideal gas law
described laterin this book.
equation solids
Δℓ = ℓ αΔT linear expansion
0
Δ A 2αΔ
= areal (or superficial) expansion
A 0T
Δ V 3αΔ
= volumetric (or cubical) expansion
V 0T
equation liquids
Δ V
= βΔT volumetric (or cubical) expansion
V 0
equation gases
P ideal gas law (We are not going to
= nRT
V use this)
Equations of thermal expansion