Thermal Expansion

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 Thermal expansion refers to a fractional

change in size of a material in response to a


change in temperature.
 This includes…
o changes in length compared to original
length (Δℓ/ℓ ) called linear expansion
0

o changes in area compared to original area


(ΔA/A ) called areal expansion or superficial
0

expansion
o changes in volume compared to original
volume (ΔV/V ) called volumetric
0

expansion or cubical expansion
 For most materials, over small temperature
ranges, these fractional changes…
o are directly proportional to temperature
change (ΔT) and
o have the same sign (i.e., materials usually
expand when heated and contract when
cooled)
o are larger for liquids than solids
 A coefficient of thermal expansion…
o is the ratio of the fractional change in size
of a material to its change in temperature
o is represented by the symbol α (alpha) for
solids and β (beta) for liquids
o uses the SI unit inverse kelvin (K  or 1/K) or
−1

the equivalent acceptable non SI unitinverse


degree Celsius (℃  or 1/℃).
−1

 Solids…
o tend to retain their shape when not
constrained and so are best described by a
linear coefficient of thermal
expansion, α (alpha).
o have an areal expansion that is very nearly
twice their linear expansion, 2α (since two
perpendicular linear measurements describe
an area)
o have a volumetric expansion that is very
nearly three times their linear
expansion, 3α(since three perpendicular linear
measurements describe a volume)
 Liquids…
o tend to take on the shape of their container
and so are best described by a volumetric
coefficient of thermal expansion, β (beta).
 Gases…
o have a thermal expansion that is best
described using the ideal gas law
described laterin this book.
equation solids
Δℓ  =  ℓ αΔT linear expansion
0

Δ A 2αΔ
 =  areal (or superficial) expansion
A 0T
Δ V 3αΔ
 =  volumetric (or cubical) expansion
V 0T
equation liquids
Δ V
 =  βΔT volumetric (or cubical) expansion
V 0

equation gases
P ideal gas law (We are not going to
 =  nRT
V use this)
Equations of thermal expansion

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