N67F CM-ZN-2 - 5001.110.016 - Norm

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Surface finishing; Coatings of zinc and zinc alloys; Requirements, tests

Titel/ Title: and types
SG-Norm/ SG-standard: 4497037031
Ersatz für Bosch Norm/ Replaces Bosch-Norm: N67F CM-ZN-2
Ausgabe/ Edition: 13/05/2011
Sprache/ Language: English
Originalsprache/ original language English
Normungsorganisation/ Standardization organization: SEG organization
Bearbeiter/ Our reference: SG/EMP
Ersetzt Ausgabe/ replaces edition:
Änderungsinformation/ Change information
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Warning note | 2012-01-26 | 0-1
Edition date of warning note 2012-01-26
Warning note
Bosch-Norm to be corrected
Document number (edition) N67F CM-ZN-2 (2011-05-13)
Part number 4 497 037 031
Title Coatings of zinc and zinc alloys; requirements, tests and types
Language en
Correction
Section 3.6.1:
With increasing strength the endangerment through hydrogen decreases.
Corrected section:
With increasing strength, the risk posed by hydrogen increases.
Section 3.6.2.4, table 1 “Heat treatment to reduce the internal stress” says:
Corrected section:
© Robert Bosch GmbH. All rights reserved, also regarding any disposal, exploitation, reproduction, editing, distribution, as well as in the event of applications for industrial
property rights.
ikp2nh 2019-12-05 SIENO 4497037031
Warning note | 2012-01-26 | 0-2
Section 4.2, table 5
Corrected table:
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Edition date of warning note 2011-07-06
Warning note
Handling and purpose of the warning note:
> Bosch GlobalNet > Topics > Standards at Bosch > FAQs about standards > Warning note
Bosch-Norm to be corrected
Document number (edition) N67F CM-ZN-2 (2011-05-13)
Part number 4 497 037 031
Title Coatings of zinc and zinc alloys; requirements, tests and types
Language en
Correction
In the chapter 3.6.3.1, headline “heat treatment”, table 2 says:
Corrected table:
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ikp2nh 2019-12-05 SIENO 4497037031
4 497 037 031 2011-05-13
Bosch-Norm N67F CM-ZN-2
Coatings of zinc and zinc alloys

Requirements, tests and types
Series: N67F Surface finishing

Technical responsibility: jrt2st CR/PJ-COR (400)
Standardization organization: C/CTI (497) Replaces edition: 2010-09-22

Created by: etc1si C/CTI2 (497)
Document language: en
Original language: de
Change: Editorial revision
Change information: AEN 4497R23527 (document for internal use at Bosch)
Translation Responsibility
Release date Source language Target language Translated by Unit code BWN
2011-05-13 de en etc1si C/CTI2 497
In case of doubt the original language edition of this Bosch-Norm applies.

The comma is used as decimal marker.
Printed versions and copies of NormMaster documents are not subject to

the NormMaster update service. Up-to-dateness is not guaranteed.
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© Robert Bosch GmbH. All rights reserved, also regarding any disposal, exploitation, reproduction, editing, distribution, as well as in the event of
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2019-12-05 for industrial
SIENOproperty rights. 4497037031
Bosch-Norm | 4497037031 | N67F CM-ZN-2 | 2011-05-13 |2
Area of validity, binding force, freedom to disclose

Valid for Bosch Group
Binding for No central agreement
Binding due to No central agreement
Recommended for Bosch Group
Disclosure Restricted in accordance with RB/GF 108
This Bosch-Norm has to be observed by suppliers if it is part of the contract for delivery.
1 Scope
This Bosch-Norm specifies requirements, tests and types of coatings of zinc and zinc alloys.
Note: For the structure of the Bosch designation for coatings of zinc and zinc alloys see N67F CM-ZN.
2 External standards
The Bosch designations used in this Bosch-Norm for coatings of zinc and zinc alloys are based on:
f DIN 50979 (2008-07)
Metallic coatings - Electroplated coatings of zinc and zinc alloys on iron or steel with supplementary
Cr(VI)-free treatment
f DIN EN ISO 10683 (2001-02)
Fasteners - Non-electrolytically applied zinc flake coatings
3 Requirements and testing

3.1 Corrosion
3.1.1 Corrosion resistance
Depending on coating system and test method, minimum duration of artificial ageing is defined, i.e. up to
which test duration no corrosion products of the base material (Ri0, without red rust) or the coat (K0,
without white rust) are permissible.
The requirements on the minimum resistivity refer to the „coated condition“ and also to the condition after
exposure to heat at 120 °C/24 h before corrosion test. Exposure to heat is not required for the coating
system of zinc with transparent passivation (thinfilm passivation) without sealing. Determination in
accordance with DIN 50979 (2008-07).
f Treatments not agreed in the order (e.g. treatment with wax or grease) intended to improve the
resistance in the corrosion tests are not permissible.
f Before the corrosion test, avoid any effects (e.g. through sorting, transport, assembly or aggressive
media) that would impair the corrosion-protective properties of the coats. Evaluating or limiting the
degree of damage does not make part of this Bosch-Norm.
The achievable corrosion resistance of coatings does not depend only on system and quality of the
coating but also on the parts to be coated (material, geometry). If the parts are such that it is difficult to
achieve an optimal coating quality (for example due to material defects or complex parts geometry), an
agreement on reduced corrosion resistance values may be necessary.
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3.1.2 Salt spray testing (NSS test)

The coating quality is mostly tested with the NSS test in accordance with DIN EN ISO 9227 (2006-10).
Evaluate the significant surfaces of the tested part (see DIN EN 1403 (1998-10)). If the drawing does not
specify significant coated surfaces, the entire part surface has to be considered the significant surface.
Additional test conditions and evaluations may be agreed for supplementary assessment, e.g. for
thermally, mechanically or chemically damaged coatings or for the inspection of edges or other weak
points.
The corrosion of coatings of zinc and zinc alloys is evaluated in accordance with Bosch-Norm N42AP 015.
3.2 Appearance
The significant surface of the electroplated part shall be free from clearly visible bubbles, pores,
roughnesses, cracks or spots.
3.3 Coating thickness
The surface finishing methods in accordance with this Bosch-Norm specify the minimum coating thickness
(xmin) of the coatings of zinc and zinc alloys, and apply to the essential surfaces. If no essential surface is
defined on the drawing, the entire part surface is considered the essential surface.
The coating thickness of passivations and sealings remain unconsidered.
The indicated coating thickness of zinc flake coatings refer to the entire coating system consisting of the
zinc flake coating and the non-metallic top coat.
If measuring points are agreed, the minimum coat thickness applies to these measuring points. All
measuring points have to be defined in the parts drawing and all significant surfaces have to be coated.
Definition of significant surface, reference area and measuring area see DIN EN 1403 (1998-10).
Maximum coating thickness values (xmax) may be indicated part-specific if they are required for further
partial machining of the part. For example fits and crimped areas.
In order to assure the dimensional stability of coated threads, the thread diameters in uncoated condition
have to be adapted to the intended coat structure. Before coating, internal diameters have to be
manufactured respectively larger and the external diameter respectively smaller (see DIN EN ISO 4042
(2001-01)).
3.4 Adhesion of coating
The test specimens are stored during 30 minutes at 210 °C to 230 °C and then immediately quenched in
water with a temperature of 15 °C to 25 °C. Spalling and blistering of the coat is not permissible (thermal
shock test based on DIN EN ISO 2819 (1995-01)).
Note: If suitable, additional testing on adhesive strength by bending or grinding of the parts is
recommended.
3.5 Absence of Cr(VI)
The applied coating has to be Cr(VI)-free in accordance with DIN EN 15205 (2007-02).
Because it is difficult to identify Cr(VI) in zinc flake coatings they have to be free from chromium
compounds.
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3.6 Avoidance of hydrogen induced, delayed ductility-dip cracks and fractures when
coating high-strength steel parts
3.6.1 Restricting the strenght values
The decisive material parameters are tensile strength and ductility. With increasing strength the
endangerment through hydrogen decreases. The Bosch-Norm specifies the following limit values:
f parts where the tensile strength is Rm < 1000 MPa are uncritical, the process conditions for coating are
not specified,
f all steel parts where the tensile strength is Rm 1000 MPa are considered high-strength parts, the
process conditions for coating (see 3.6.3) must be observed,
f parts where the tensile strength is 2000 MPa must not be coated in accordance with this Bosch-
Norm.
For classification of the strength, the upper tolerance of the material specification applies.
3.6.2 Requirements on parts to be coated
3.6.2.1 Heat treatment and structural condition
Quench-hardening and tempering of parts
After hardening, the structure shall have at least 90 % martensite. Tempering of the parts shall be
performed at 360 °C.
Exceptions for partially hardened screws are specified by the Bosch-Norms N38A SR5 and N38A SR6
and/or for case hardened screws by Bosch-Norm N38A SR10. ...
By applying inductive tempering, threaded parts with hardnesses > 540 HV (over the entire cross section)
shall reach in the thread zone hardness values < 540 HV.
Case hardening or surface hardening of parts

Case hardened or surface hardened parts shall be annealed after hardening at 210 °C to 230 °C (see
Table 1).
Compared to case hardening with common annealing at 180 °C, the higher annealing temperatures
specified in the table produce a reduced surface hardening (hardness drop).
When electroplating case hardened parts, observe the following requirements:
f If the surface hardness is < 600 HV, treatment by electroplating is permissible without any restriction
(see Table 2).
f If possible, avoid electroplating of parts with a surface hardness > 600 HV. Otherwise, decision on the
part-specific suitability for electroplating is required. For this, decisive influence variables are: parts
cross section, core hardness, notch factor, case depth (= Eht) and the mechanical load of the parts.
The respective parts require an individual release through the development department.
Edge oxidation
Edge oxidation acts like notching with high stress concentration factors (Dk > 5). State-of-the art measures
are to be taken in order to keep the edge oxidation as minimum as possible.
Note: Heat treatments without vacuum can achieve an edge oxidation of 15 m for case hardened parts
and 5 m for quench-hardened and tempered parts.
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3.6.2.2 Coverings
Heat treatments can produce or burn-in coverings. Their defective coat structure impair a subsequent
metal deposition. Therefore the coverings have to be removed. This can be done to a limited extent
through pretreatment before the coating process, e.g. through pickling, derusting or shot peening. Where
such a pretreatment is not successful, special measures during or before the heat treatment are required,
for example:
f quench-hardening and tempering under inert gas or vacuum
f cleaning of the parts before hardening or tempering
f use of precoppered steel wire for springs
3.6.2.3 Shape
For punched parts, overlappings with cavity formation on the shearing surfaces are inadmissible because
pickling acid or electrolytes may be retained due to capillary action and embedded during electroplating.
This may lead to hydrogen formation. Because cracks, laminations and the like have the same effect,
electroplated parts may have only minimum surface defects.
Under mechanical load, notches on parts cause stress concentrations and enhance hydrogen induced
ductility-dip cracks and fractures. The stress concentration degree is usually determined through the
stress concentration factor Dk. For details on the coaction of stress concentration factor, part strength and
restrictions to load see Bosch-Norm N67F CM-ZN-1.
3.6.2.4 Heat treatment for reduction of internal stress
Case hardening or surface hardening, plastic forming or machining such as grinding of parts produce high
internal stresses. These may produce cracks even already during pickling or electroplating. Such parts
require heat treatment before pickling or electrolytical treatment in accordance with Table 2.
Table 1 Heat treatment to reduce the internal stress

Parts Temperature in °C 1) Holding time in h
f case hardened or surface hardened
210 bis 230
f hardened and ground
f work-hardened and/or plastically deformed
f tension and torsion springs of:
f 5 151 1.. ... 240
f 5 151 2.. ... 240
f 5 151 3.. ... 240
f shot-blasted springs of:
1
f unalloyed steel 220
f alloyed steel 240
f other springs 320 2), 3)
f threads rolled after heat treatment, shot-peened parts and
220
surface-rolled parts
f other parts of:
f unlegiertem Stahl 220 to50 2)
f lalloyed steel 420 2)
1) Select for the heat treatment the highest possible temperature and observe that the temperature of the preceding heat
treatment must not be exceeded.
2) Select for parts transformed by austempering a temperature that is by 40 °C below the transforming temperature.
3) Detailed values see Bosch-Norm N15F 10.1
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3.6.3 Process conditions for coating

In the following, the minimum requirements are specified in order to perform the coating process of high-
strength steel parts in accordance with this Bosch-Norm. Additional restrictions require part-specific
determinations.
3.6.3.1 Electrolytically deposited coatings of zinc and zinc alloys
Mechanical pretreatment
Mechanical pretreatment is performed mainly through shot peening or vibratory finishing. These treatment
methods allow to remove coverings without hydrogen absorption. These methods are applied
predominantly if
f shape and surface of the parts to be treated are not damaged through effects of shot peening and
abrasive agents
f chemically degreasing, derusting or pickling does not produce appropriate results.
Electrolytical degreasing and/or derusting
These treatment methods are performed usually in strong alkaline solutions with anodic and/or cathodic
polarity or with anodic/cathodic change of pole. During the cathodic treatment the parts absorb hydrogen.
Only anodic polarity is permissible.
Pickling
Steel parts react when pickled with acids (or acid solutions) by dissoluting the metal oxides and the metal.
During the metal dissolution atomic hydrogen develops. The absorption of hydrogen by the part can be
significantly influenced with inhibitors. However, inhibition against metal removal does not necessarily
mean an effective inhibition against hydrogen absorption.
Observe the following conditions when pickling:
f pickling is only permissible in inhibited pickling solution
f the positive effect of the inhibitor used to reduce the hydrogen absorption shall be certified. Suitable
methods are for example:
f pickling tests with highly-critical test parts through bracing test
f permeation test
Here a test method is concerned for the determination of the hydrogen occurring and diffusing in
chemical-electroplating processes.
f the permissible pickling duration is limited to 5 minutes
Coating
Deposited coatings of zinc and zinc alloys have to be permeable for absorbed hydrogen. Thickness and
structure of the coating have to be selected so that absorbed hydrogen can escape through the coat
during the subsequent heat treatment. The coating structure depends mainly on the electrolytes used and
the coating parameters.
Observe the following conditions when coating:
f For coatings of high-strength steel parts with a tensile strength higher than 1450 MPa it has to be
certified that the electrolytes used for the coating are permeable for hydrogen during the subsequent
heat treatment. Suitable methods are for example:
f testing the coating on highly critical sample parts with heat treatment and bracing test
f permeation test
f The coating thickness over the entire sample surface must average out at maximum 16 m.
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Heat treatment
Heat treatment is required in order to reduce the hydrogen absorbed during a pickling and/or electrolytical
treatment to an uncritical degree.
Observe the following conditions for heat treatment:
f duration between pickling and/or electrolytical treatment and beginning of heat treatment:
4h
f heat treatment conditions in accordance with Table 2.
After heat treatment, the zinc or zinc alloys deposits must not show any bubbles or spangles.
Table 2 Heat treatment after electrolytical deposition of zinc or zinc alloys

Hardness and/or tensile strength Rm of the parts Heat treatment conditions 1)
minimum holding time
hardness Rm parts temperature 2)
at parts temperature
HV HRC in MPa in °C in h
310 to 90 31 to 39,8 1000 to 1250 6
391 to 450 39,9 to 45,3 1251 to 1450 12
220 ± 10
451 to 490 45,4 to 48,4 1451 to 1600 20
491 to 600 48,5 to 55,2 1601 to 2000 24
ase hardened and annealed at 360 °C 360 °C 220 ± 10 24
case hardened and annealed at 220 °C ± 10 °C 220 ± 10 24 3)
1)
Perform heat treatment in the air-circulation furnace.
2)
If the parts temperature varies after heating up, then the lower temperature value applies. With higher temperatures the
coatings run the risk of damage.
3)
f Each part requires an individual release through the product development department (see section 3.6.2.1 (Case
hardening or surface hardening of parts)).
f The heat treatment duration is considered a guideline value. Depending on parts, a deviating value may be defined.
f Hardness drop due to heat treatment.
Secondary treatment
Secondary treatments are chemically produced conversion coatings, sealings and lubricating coatings.
Observe the following conditions for secondary treatment:
f High-strength steel parts are subject to secondary treatment after heat treatment. Exceptions from this
sequence are permissible if requirements and properties of the respective type (see section 4) are met.
f The heat-treated zinc or zinc alloy coating must not be subject to any other cathodic treatment, e.g.
secondary zinc-plating.
Rework
Rework means removing and reapplying the coating of zinc or zinc alloy.
Observe the following conditions for rework:
f brittled batches must not be reworked, batches are considered brittled if:
f cracks or precracks occurred during bracing test
f the treatment was not performed in accordance with this section
f only one-time rework is permissible
f when removing coatings of zinc or zinc alloy, the process conditions in accordance with this section
apply
f for heat treatment after coating the 1,5-fold duration of time in accordance with Table 2 applies
f identify reworked batches accordingly
f perform the bracing test in accordance with the Bosch-Norm N42AP 926 before and after rework
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3.6.3.2 Zinc flakes

It is the essential characteristic of mechanical zinc-plating and coating with zinc flakes that during
pretreatment and formation of the coating no hydrogen develops. Therefore, heat treatment is not required
to reduce absorbed hydrogen to an uncritical degree .
Observe the following conditions for coating:
f pretreatment preferably through mechanical and currentless degreasing
f pickling not permissible
f for electrolytical degreasing or derusting only anodic polarity is permissible
Rework only permissible if no hydrogen can develop when removing or reapplying the coatings.
3.6.4 Quality assurance measures
3.6.4.1 Supplier selection
High-strength, highly-stressed parts may only be coated by professional suppliers. Suppliers must take
preventive quality and process assuring measures to avoid hydrogen induced, delayed ductility-dip cracks
and fractures.
3.6.4.2 Preventive process assurance
Results of random sampling can describe the "risk of embrittlement" of production batches only in an
insufficient way. Therefore preventive measures for process assurance have to be taken. These
measures shall assure that all quality-related process parameters in accordance with section 3.6.3 are
observed and documented.
3.6.4.3 Bracing test
The bracing test is used to detect serious process deficiencies, e.g. to detect if the heat treatment after
coating had not been performed.
The following conditions have to be observed for bracing test:
f All tested parts must pass the bracing test according to Bosch-Norm N42AP 926 without cuts and/or
fractures.
f The test extent and documentation has to be agreed with the responsible quality assurance
department, in particular with R and D parts.
Cuts and/or fractures occur in critical cases only in a few parts of a production batch (ppm range). In
practical application, the extent of random sampling for bracing test may be reduced so that a reliable
statement about an existing "brittled" batch can be made.
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4 Requirements to process parameters and types

The Bosch part number and the Bosch designation of the surface finishing method can be determined
with the qualities Table 4ff in this Bosch-Norm as follows:
f known requirements on the corrosion resistance
f known requirement on the color one
f known parts strength
Selection based on the technical information of Bosch-Norm N67F CM-ZN-1:
f type of coating
f coating thickness
f type of passivation
f application of sealing and/or top coat
f production method (barrel, rack and dip-spinning method)
f process parameters (see section 4.1)
4.1 Process parameters
Table 3 Indicators of the process parameters Table 4 ff
Indicator Process parameters

L none specified values
Coating of high-strength steel parts in accordance with section 3.6
H
(e.g. heat treatment)
Note: Further requirements, properties and process parameters may be agreed in the manufacturing
documents.
CAUTION!
Use the Bosch part number from Table 4 ff for new applications.
It is not recommended to use the obsolete document number (e.g. N67F 821 69) and/or the document
part number (e.g. 4 497 011 699) in new or updated documents.
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Bosch-Norm | 4497037031 | N67F CM-ZN-2 | 2011-05-13 | 10
4.2 Types of zinc coatings

Table 4 Types of electrodeposited coatings with zinc
Note: The table lists only methods with unlimited applicability.
base material: ferrous material, e.g. steel or gray cast iron
passivation: transparent (thinfilm passivation)
Corrosion Tensile
Coat
Bosch part resistance Production Process strength of
Bosch designation thickness Color tone Sealing
number method parameter material
K 0 [h] Ri 0 [h] [m]
[MPa]
5 001 100 000 CM-Fe-Zn-5-An-T0-L-B barrel L < 1000
8 48
5 001 100 001 CM-Fe-Zn-5-An-T0-H-B treatment H 1000
5
5 001 100 002 CM-Fe-Zn-5-An-T0-L-R rack L < 1000
16 72
5 001 100 003 CM-Fe-Zn-5-An-T0-H-R treatment H 1000
8 72 colorless
through
8 no
5 001 100 006 CM-Fe-Zn-8-An-T0-L-R iridescent by L < 1000
rack
16 96 color
8 96
12
5 001 100 010 CM-Fe-Zn-12-An-T0-L-R rack L < 1000
16 120
Standard parts
5 001 100 002 CM-Fe-Zn-5-An-T0-L-R
colorless L < 1000
5 001 100 000 CM-Fe-Zn-5-An-T0-L-B 48 barrel
8 and/or through
and/or 5 and/or rack no
5 001 100 003 CM-Fe-Zn-5-An-T0-H-R 16 iridescent by
72 treatment
color H 1000
5 001 100 001 CM-Fe-Zn-5-An-T0-H-B
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contd. Table 4
passivation: iridescent passivated (thickfilm passivation)
Corrosion Tensile
Coat
K 0 [h] Ri 0 [h] [m]
[MPa]
5 001 100 012 CM-Fe-Zn-5-Cn-T0-L-B barrel L < 1000
72 144
5 001 100 013 CM-Fe-Zn-5-Cn-T0-H-B treatment H 1000
5
5 001 100 014 CM-Fe-Zn-5-Cn-T0-L-R rack L < 1000
120 192
5 001 100 015 CM-Fe-Zn-5-Cn-T0-H-R treatment H 1000
72 216
iridescent by
8 no
5 001 100 018 CM-Fe-Zn-8-Cn-T0-L-R color L < 1000
rack
120 264
72 288
12
120 336
passivation: iridescent passivation (thinfilm passivation or thickfilm passivation is not specified)
120 192
5
168 264 colorless
through
yes
5 001 100 028 CM-Fe-Zn-8-Cn-T2-L-B iridescent by L < 1000
barrel
120 264 color
8
168 360
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contd. Table 4
passivation: iridescent passivation
Corrosion Tensile
Coat
K 0 [h] Ri 0 [h] [m]
[MPa]
120 360 colorless
through
12 yes
5 001 100 034 CM-Fe-Zn-12-Cn-T2-L-R iridescent by L < 1000
rack
168 480 color
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4.3 Types of zinc nickel coatings

Table 5 Types of electrodeposited coatings with zinc nickel (with a mass content of 12% to 16% nickel)
Corrosion Tensile
Coat
K 0 [h] Ri 0 [h] [m]
[MPa]
5 001 110 000 CM-Fe-ZnNi-5-Cn-T0-L-B barrel L < 1000
120 480
5 001 110 001 CM-Fe-ZnNi-5-Cn-T0-H-B treatment H 1000
5
5 001 110 002 CM-Fe-ZnNi-5-Cn-T0-L-R rack L < 1000
192 600
5 001 110 003 CM-Fe-ZnNi-5-Cn-T0-H-R treatment H 1000
120 720
iridescent by
8 no
5 001 110 006 CM-Fe-ZnNi-8-Cn-T0-L-R color L < 1000
rack
192 720
120 720
12
192 720
168 600
5
360 720 colorless
through
yes
5 001 110 016 CM-Fe-ZnNi-8-Cn-T2-L-B iridescent by barrel L < 1000
168 720 color
8
360 720
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contd. Table 5
Corrosion Tensile
Coat
K 0 [h] Ri 0 [h] [m]
[MPa]
168 720 colorless
through
12 yes
5 001 110 022 CM-Fe-ZnNi-12-Cn-T2-L-R iridescent by L < 1000
rack
360 720 color
passivation: black passivating
5 001 110 024 CM-Fe-ZnNi-5-Fn-T0-L-B barrel L < 1000
48 480
5 001 110 025 CM-Fe-ZnNi-5-Fn-T0-H-B treatment H 1000
5
5 001 110 026 CM-Fe-ZnNi-5-Fn-T0-L-R rack L < 1000
72 600
5 001 110 027 CM-Fe-ZnNi-5-Fn-T0-H-R treatment H 1000
48 720
8
5 001 110 030 CM-Fe-ZnNi-8-Fn-T0-L-R black L no < 1000
rack
72 720
48 720
12
72 720
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contd. Table 5
passivation: iridescent passivation
Corrosion Tensile
Coat
K 0 [h] Ri 0 [h] [m]
[MPa]
168 480
5
240 600
168 720
8 black yes
240 720
168 720
12
240 720
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4.4 Types of zinc iron coatings

Table 6 Types of electrodeposited coatings with zinc iron (with a mass content of 0,3% to 1,0% iron)
passivation: black passivating
Corrosion Tensile
Coat
K 0 [h] Ri 0 [h] [m]
[MPa]
5 001 120 000 CM-Fe-ZnFe-5-Fn-T2-L-B barrel L < 1000
120 192
5 001 120 001 CM-Fe-ZnFe-5-Fn-T2-H-B treatment H 1000
5
5 001 120 002 CM-Fe-ZnFe-5-Fn-T2-L-R rack L < 1000
168 264
5 001 120 003 CM-Fe-ZnFe-5-Fn-T2-H-R treatment H 1000
120 264
8 black yes
168 360
120 360
12
168 480
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4.5 Types of zinc flake coatings

Table 7 Types of zinc flake coatings
passivation: none
Corrosion Tensile
Coat nicht-
Bosch part resistance Color Production Process strength of
Bosch designation thickness metallische
number tone method parameter material
K 0 [h] Ri 0 [h] [m] Deckschicht
[MPa]
5 001 130 000 CM-Fe-flZn-8-Sc-T0-L-D L < 1000
480 no
5 001 130 001 CM-Fe-flZn-8-Sc-T0-H-D silver- H 1000
- 8
5 001 130 002 CM-Fe-flZn-8-Sc-T2-L-D colored L < 1000
dip-spinning
720
5 001 130 003 CM-Fe-flZn-8-Sc-T2-H-D method H 1000
yes
5 001 130 004 CM-Fe-flZn-10-Bk-T2-L-D L < 1000
120 480 10 black
5 001 130 005 CM-Fe-flZn-10-Bk-T2-H-D H 1000
Note: In case of zinc flake coatings the coating thickness refers to the entire coating system consisting of the zinc flake coating and the non-metallic
top coat.
applications for
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5 Normative references
The following documents are applicable in addition to this Bosch-Norm. With dated references solely the
edition referred to applies. With undated references the last edition of the indicated document applies
(including all revisions). Intentionally cited historical standards are additionally identified as „Type H“.
No. Document number (edition date) Title Type 1)

Metallic coatings - Electroplated coatings of
1 DIN 50979 (2008-07) zinc and zinc alloys on iron or steel with Z
supplementary Cr(VI)-free treatment
Corrosion protection of metals -
2 DIN EN 1403 (1998-10) Electrodeposited coatings - Method of Z
specifying general requirements
Determination of hexavalent chromium in
3 DIN EN 15205 (2007-02) corrosion protection layers - Qualitative Z
analysis
Metallic coatings on metallic substrates -
Electrodeposited and chemically deposited
4 DIN EN ISO 2819 (1995-01) Z
coatings - Review of methods available for
testing adhesion
5 DIN EN ISO 4042 (2001-01) Fasteners - Electroplated coatings Z
Fasteners - Non-electrolytically applied zinc
6 DIN EN ISO 10683 (2001-02) Z
flake coatings
Spring calculation and design; Tempering
7 N15F 10.1 temperatures for springs of spring wire; Z
Approximate values
8 N38A SR5 Screws with partial inductive hardening M
9 N38A SR6 Screws with partial case hardening M
10 N38A SR10 Thread-forming screws M
Definition of corrosion and rusting degree on
11 N42AP 015 M
zinc-coated ferrous materials
12 N42AP 926 Bracing test M
Coatings of zinc and zinc alloys; Technical
13 N67F CM-ZN-1 Z
information
Coatings of zinc and zinc alloys; Overview on
14 N67F CM-ZN-3 Z
methods
1)
Type: M = Document to be supplied; Z = Cited document; H = Historical document
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Surface finishing; Coatings of zinc and zinc alloys; Requirements, tests

SG-Norm/ SG-standard: 4497037031

Ersatz für Bosch Norm/ Replaces Bosch-Norm: N67F CM-ZN-2

Ausgabe/ Edition: 13/05/2011

Sprache/ Language: English

Originalsprache/ original language English

Normungsorganisation/ Standardization organization: SEG organization

Bearbeiter/ Our reference: SG/EMP

Ersetzt Ausgabe/ replaces edition:

Änderungsinformation/ Change information

© SEG Automotive Germany GmbH | Robert-Bosch-Straße 2 | 71701 Schwieberdingen | GERMANY

ikp2nh 2019-12-05 SIENO 4497037031

Edition date of warning note 2012-01-26

Section 4.2, table 5

Coatings of zinc and zinc alloys

Series: N67F Surface finishing

Standardization organization: C/CTI (497) Replaces edition: 2010-09-22

Change information: AEN 4497R23527 (document for internal use at Bosch)

In case of doubt the original language edition of this Bosch-Norm applies.

Printed versions and copies of NormMaster documents are not subject to

Area of validity, binding force, freedom to disclose

3 Requirements and testing

3.1.2 Salt spray testing (NSS test)

Case hardening or surface hardening of parts

Table 1 Heat treatment to reduce the internal stress

3.6.3 Process conditions for coating

Table 2 Heat treatment after electrolytical deposition of zinc or zinc alloys

3.6.3.2 Zinc flakes

4 Requirements to process parameters and types

Indicator Process parameters

4.2 Types of zinc coatings

ikp2nh 2019-12-05 SIENO 4497037031

4.3 Types of zinc nickel coatings

ikp2nh 2019-12-05 SIENO 4497037031

ikp2nh 2019-12-05 SIENO 4497037031

4.4 Types of zinc iron coatings

4.5 Types of zinc flake coatings

No. Document number (edition date) Title Type 1)

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