Modern Atomic Theory

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Modern Atomic Theory: Models

In 1913, Neils Bohr, a student of Rutherford's,


developed a new model of the atom. He proposed
that electrons are arranged in concentric circular
orbits around the nucleus. This model is patterned
on the solar system and is known as the planetary
model. The Bohr model can be summarized by the
following four principles:

1. Electrons occupy only certain orbits around


the nucleus. Those orbits are stable and are
called "stationary" orbits.
2. Each orbit has an energy associated
with it. The orbit nearest the nucleus has
an energy of E1, the next orbit E2, etc.
Bohr model
3. Energy is absorbed when an electron
jumps from a lower orbit to a higher one and energy is emitted when an
electron falls from a higher orbit to a lower orbit.
4. The energy and frequency of light emitted or absorbed can be calculated
by using the difference between the two orbital energies.

In 1926 Erwin Schrödinger, an Austrian physicist, took the


Bohr atom model one step further. Schrödinger used
mathematical equations to describe the likelihood of
finding an electron in a certain position. This atomic model
is known as the quantum mechanical model of the atom.
Unlike the Bohr model, the quantum mechanical model
does not define the exact path of an electron, but rather,
predicts the odds of the location of the electron. This
model can be portrayed as a nucleus surrounded by an
electron cloud. Where the cloud is most dense, the
probability of finding the electron is greatest, and
conversely, the electron is less likely to be in a less dense Quantum mechanical model
area of the cloud. Thus, this model introduced the concept
of sub-energy levels.

Until 1932, the atom was believed to be composed of a positively charged nucleus
surrounded by negatively charged electrons. In 1932, James Chadwick bombarded
beryllium atoms with alpha particles. An unknown radiation was produced. Chadwick
interpreted this radiation as being composed of particles with a neutral electrical charge
and the approximate mass of a proton. This particle became known as the neutron.
With the discovery of the neutron, an adequate model of the atom became available to
chemists.
Since 1932, through continued experimentation, many additional particles have been
discovered in the atom. Also, new elements have been created by bombarding existing
nuclei with various subatomic particles. The atomic theory has been further enhanced
by the concept that protons and neutrons are made of even smaller units called quarks.
The quarks themselves are in turn made of vibrating strings of energy. The theory of the
composition of the atom continues to be an ongoing and exciting adventure.

Modern Atomic Theory: Models

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