ZA Polymers LLDPE Overview

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SASOL CHEMICALS

Hexene linear low density polyethylene (hLLDPE)


product overview - film, moulding and extrusion
Hexene linear Low Density Polyethylene (hLLDPE) Product overview

SASOL AT A GLANCE
Sasol is an international integrated chemicals and energy company that leverages technologies and the expertise of
our 30 400 people working in 36 countries. We develop and commercialise technologies, and build and operate
world-scale facilities to produce a range of high-value product streams, including liquid fuels, chemicals and low-
carbon electricity.

SASOL CHEMICALS
Sasol Chemicals is a producer and marketer of a range of commodity chemicals based on the Fischer Tropsch (FT)
and natural gas value chains including chemical feedstocks of ethane, ethylene, propylene and ammonia. Final
products include polymers, explosives, fertilisers, mining reagents (caustic soda, sodium cyanide), and a range of
alcohols, ketones, acrylate monomers, and other oxygenated solvents.
Final products marketed through the Polymers division include low density polyethylene (LDPE), hexene linear low
density polyethylene (hLLDPE), polypropylene (PP), and polyvinyl chloride (PVC) as well as propylene and ethylene
monomers. Through this product portfolio we offer polymer solutions for a broad range of applications and
industries.
Our polymers are marketed throughout Sub-Saharan Africa, Europe, Americas and Asia and we are active in over 75
countries globally.
Our Polymer Technology Services Centre in Johannesburg provides expertise and technical service support to
external customers and also undertakes polymer-related applications research and development applicable to the
Polymers division.

POLYETHYLENE OVERVIEW
Polyethylene grades are characterised primarily on the basis of their density. Low density polyethylene (LDPE) is the
oldest form of polyethylene and is produced under high pressure conditions which promote the formation of a high
degree of both long and short chain branching within the polymer structure. These characteristics give rise to resins
which are soft, tough and flexible, as well as being easy to process.
Hexene linear low density polyethylene (hLLDPE) comprises a more linear structure with limited short chain
branching produced through the co-polymerisation of ethylene with short chain alpha-olefins such as butene or
hexene. Sasol uses 1-hexene as a co-monomer, which provides a tougher hLLDPE product. The hLLDPE resins exhibit
improved mechanical properties over LDPE, such as higher tensile strength, higher impact, and increased puncture
resistance. In film conversion, the use of hLLDPE can deliver lower gauge (thickness) films than LDPE, however
these films are not as easy to process.
Both LDPE and hLLDPE are predominantly used in flexible blown film extrusion applications where the relative
benefits of each polymer can be combined to produce optimum film performance properties. The inherent
toughness and mechanical property benefits of hLLDPE also allow this polymer to be widely used in rotational
moulding applications such as water and chemical tanks, storage bins and road barriers, as well as a range of rigid
applications. Injection moulding applications for LDPE include the production of closures and lids.

SASOL POLYETHYLENE PRODUCT AND SERVICE OFFERING


! High quality products manufactured to world class standards.
! Sales and technical support provided by an experienced and qualified team.
! A customer focused organisation with a track record of commitment to meeting the requirements of all
customers.
! An established production technology platform providing a sustainable base to support the growth aspirations of
our business and that of our customers.

Sales enquiries Technical support


Phone: +27 (0)10 344 5000 Phone: +27 (0)11 458 0700
email: [email protected] Fax: +27 (0)11 458 0734 www.sasol.com
hLLDPE grade range - film
Grade name MFI Nominal Additive Features Applications
(g/10min)1 density package
(g/cm3)2

Hexene copolymer
HF2308E 0.8 0.923 Antioxidant Excellent mechanical Heavy duty film (>75 µm)
Low antiblock properties Blending into HDPE or LDPE
Excellent puncture
resistance
High impact strength

HF2110 1.0 0.921 Antioxidant Outstanding mechanical Blown stretch film


properties Blending into LDPE
Good heat sealing range

HF2910T 1.0 0.929 Antioxidant Outstanding mechanical General packaging thin film
High antiblock properties (10 to 30 µm)
High slip Good heat sealing range Blending into LDPE
Excellent drawdown Not recommended for
Good stiffness lamination film

HF2020 2.0 0.920 Antioxidant Medium strength LLDPE Cast stretch film (mono and
Good heat sealing range co-extruded)
1
190C; 2.16 kg
2
Density measured according to ASTM D1505 without annealing
Notes:
1. Surface properties of grades containing slip and antiblock additives will be dependent on film thickness.
2. For further details refer to the relevant Product Data Sheet.

hLLDPE grade range - moulding and extrusion


Grade name MFI Nominal Features Applications
(g/10min)1 density
(g/cm3)2

Injection moulding - Hexene copolymer

HM2420 20 0.924 High gloss Injection moulded containers


Good low temperature
performance

HR3950 5 0.939 Good ESCR Injection moulded containers


Medium rigidity
Medium flow
Good low temperature
performance

Masterbatch extrusion - Hexene copolymer

HM2420 20 0.924 High flow Base for colour and additive


concentrates
hLLDPE grade range - moulding and extrusion
Grade name MFI Nominal Features Applications
(g/10min)1 density
(g/cm3)2

Rotational moulding - Hexene copolymer

HR3935 3.5 0.939 Good heat stability Rotomoulded rigid parts for
High rigidity indoor use
Good ESCR
Excellent impact strength

HR3935U 3.5 0.939 UV stabilised Rotomoulded rigid parts for


Good heat stability outdoor use
High rigidity
Good ESCR
Excellent impact strength

HR3950 5 0.939 High rigidity Rotomoulded rigid parts for


Good ESCR indoor use

HR3950U 5 0.939 UV stabilised Rotomoulded rigid parts for


High rigidity outdoor use
Good ESCR
1
190C; 2.16 kg
2
Density measured according to ASTM D1505 without annealing

Grade name MFI Nominal Features Applications


(g/10min)1 density
(g/cm3)2

Pipe / profile extrusion - Hexene copolymer

HF2110 1 0.921 Medium rigidity General purpose low pressure


Good burst strength pipe
Good ESCR

HF2020 2 0.920 Good burst strength General purpose low pressure


Good ESCR pipe

Notes:
1. All grades contain antioxidant
2. For further details refer to the relevant Product Data Sheet.

Sales enquiries Technical support


Phone: +27 (0)10 344 5000 Phone: +27 (0)11 458 0700
email: [email protected] Fax: +27 (0)11 458 0734 www.sasol.com

DISCLAIMER
This publication contains information provided in good faith and is indicative, based on Sasol's current knowledge on the subject. No guarantee or warranty is intended or implied.
We reserve the right to make changes as a result of technological progress or development. Any information, including suggestions for use of products, should not preclude
experimental testing and verification, to ensure the suitability of a product for each specific application. Users must also abide by local and international laws and obtain all
necessary permits when required to do so. Prior to handling a hazardous product, consult it's safety data sheet. In case of questions or queries, please contact Sasol through our
customer service channels. All products purchased or supplied by Sasol Chemicals are subject to the terms and conditions set out in the contract, order confirmation and/or bill of
lading.

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