Components Mfr M.W Masss density v.f.

r mass fr
kmol/hr kg/kgmol kg/hr kg/m3 m3/hr
TDA 21.62 122.17 2641.14 1521 1.736451 0.137456
O2 19.81 32 633.87 46.575 13.60975 0.032989
CO 386.11 28 10811.08 67.135 161.0349 0.562651
TFE 41.53 100.05 4155.40 1325 3.136149 0.216263
H2o 15.79 18 284.22 1000 0.284223 0.014792
TDC 1.93 356 687.77 1100 0.625248 0.035794
TDI 0.01 174.2 1.04 1210 0.000857 5.39E-05
sum 486.80 19214.52 180.4276 1

ra
Cao 0.058354

Mole fractionof TDA 0.04441

ConversionRate
(X)Inverse
law (ra)
of rate law (1/-ra)
0 0.01680607 59.50232
0.1 0.01519293 65.82009
0.2 0.01356534 73.71729
0.3 0.0119231 83.87083
0.4 0.010266 97.40889
0.5 0.0082205 121.6471
0.6 0.00690645 144.7921
0.7 0.00520358 192.1753
0.8 0.00348503 286.9417
0.82 0.00313942 318.5305

Levenspiel Plot
900000.00
800000.00
700000.00
600000.00
Axis Title

500000.00
400000.00
300000.00
200000.00
100000.00
0.00
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9

Conversion (X)
 Axis T
400000.00
300000.00
200000.00
100000.00
0.00
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9

Conversion (X)

Simpson's 5 point rule

Fao 2641.14
0.2 94.3532858
Simpson's 2 point rule
0.02 4.036481
98.38977
weight of catalyst 259861.4 density of catalyst 8746
Volume of Catalyst 29.71203 97.48041
volume of reactor = Vr=
Vol. of catalyst = Vr × (1-e)
e = void fraction = Vg× ρ
Vg range 0.1 to 1 cm3/g pellet
Vg = 0.32 cm3/gm
ρ = 0.87 g/cm3
e 0.279872
Vr 41.25937 m3

PRESSURE DROP

Φ = bed void fraction 0.32

DP = 0.04 cm
ρf= feed density 0.589 g/cm3
G = mass velocity 0.09347502 g/cm2 Sec
m = viscosity of feed 0.011 g/cm. Sec
gc 980.67 cm/sec2
L = length of reactor 809 cm
Putting values in above eq. gives
ΔP/L 2.36872476
ΔP 1916.29833 gm/cm2 42.55505
1.85495497 atm
k 337475 350
SPACE TIME

density Space time = Volume of reactor /Volumetric flow rate

kg/m3
209.0699 liq 7769.57 Space time 0.228676 hr
1.536478 gas 11444.95 13.72053 min
37.7736
286.549
14.79208
39.37386
0.065272 MFR IN g/sec 5337.368
589.1601

6.0142523

X 1/ra Fao/ra
0 59.5023249 157154.13
0.1 65.82008515 173840.24
0.2 73.71728546 194697.87
0.3 83.87082871 221514.82
0.4 97.40888639 257270.77
0.5 121.6471325 321287.43
0.6 144.7920882 382416.56
0.7 192.1752901 507562.36
0.8 286.9416938 757853.95
0.82 318.5304951 841284.48

X Fao/ra
0 157154.13
0.1 173840.24
0.2 194697.87
0.3 221514.82 Levenspiel Plot
0.4 257270.77 350
Inverse of rate law (1/-ra)

0.5 321287.43
300
0.6 382416.56
250
0.7 507562.36
0.8 757853.95 200

0.82 841284.48 150

100

50

0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9
 Inverse of rate la
200

150

100

50

0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9

Conversion (X)

8.205734E-05

0.0254 0.0762 dia=3inch

lentgh= 20f
number of tubes 115.3659444

kg/m3
0.08 0.04

431.0595065

2PIRH
dia 2.697 269.7 vol 685108.1
length 8.09 809 2PIR2
RAD 134.85 114198.8
799306.9

crossectional area 57099.40065

r /Volumetric flow rate

Plot

0.5 0.6 0.7 0.8 0.9

 0.5 0.6 0.7 0.8 0.9

on (X)
 0.01 TDI
1162.38 TFE Components Mfr M.W Masss density v.f.r
1.89 H2O kmol/hr kg/kgmol kg/hr kg/m3 m3/hr
2901.81 CO TDA 3.99 122.17 487.05 1521 0.320219
145.24 O2 O2 4.54 32 145.24 46.575 3.118399
487.05 TDA CO 103.64 28 2901.81 67.135 43.22357
681.72 TDC TFE 11.62 100.05 1162.38 1325 0.877267
5380.11 H2o 0.11 18 1.89 1000 0.001894
TDC 1.91 356 681.72 1100 0.619741
TDI 0.00 174.2 0.01 1210 9.67E-06
sum 125.80 5380.11 48.1611

ra
Cao 0.0416415

Mole fractionof TDA 0.0316906

Conversion Rate
(X) Inverse
law (ra)of rate law (1/-ra)
0 0.01199275 83.383693
0.1 0.01082779 92.354939
0.2 0.0096554 103.569
0.3 0.00847551 117.98707
0.4 0.00728804 137.21117
0.5 0.00590284 169.40987
0.6 0.00489008 204.49551
0.7 0.00367945 271.77985
0.8 0.00246094 406.34854
0.82 0.00221629 451.20476

Levenspiel Plot
500
Inverse of rate law (1/-ra)

450
400
350
300
250
200
150
100
50
0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9

Conversion X
 150

Inverse
100
50
0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9

Conversion X

Simpson's 5 point rule

Fao 487.05
0.2 133.094172
Simpson's 2 point rule
0.02 5.717022
138.81119
weight of catalyst 67608.328 density of catalyst
Volume of Catalyst 7.7301999 25.361548
volume of reactor = Vr=
Vol. of catalyst = Vr × (1-e)
e = void fraction = Vg× ρ
Vg range 0.1 to 1 cm3/g pellet
Vg = 0.32 cm3/gm
ρ = 0.87 g/cm3
e 0.279872
Vr 10.73448 m3

PRESSURE DROP

Φ = bed void fraction 0.32

DP = 0.04 cm
ρf= feed density 0.60116499 g/cm3
G = mass velocity 0.06923918 g/cm2 Sec
m = viscosity of feed 0.011 g/cm. Sec
gc 980.67 cm/sec2
L = length of reactor 497.32988 cm
Putting values in above eq. gives
ΔP/L 1.71648167
ΔP 853.657623 gm/cm2
0.82633086 atm
 k 337474.9 350
SPACE TIME

mass fr density Space time = Volume of reactor /Volumetric flow ra

kg/m3
0.090528 137.6937 liq 2333.05 Space time 0.2228869
0.026996 1.257322 gas 3047.05 13.373216
0.53936 36.20994
0.216051 286.2679
0.000352 0.352042
0.12671 139.3815
2.18E-06 0.002632 MFR IN g/sec 1494.474
1 601.165

1.6053701

X 1/ra Fao/ra
0 83.3836933 40612.23
0.1 92.35493892 44981.697
0.2 103.568996 50443.53
0.3 117.9870693 57465.888
0.4 137.2111671 66829.031
0.5 169.4098693 82511.487
0.6 204.4955092 99600.033
0.7 271.7798514 132371
0.8 406.3485358 197913
0.82 451.204764 219760.37

X Fao/ra
0 40612.23
0.1 44981.70
0.2 50443.53
0.3 57465.89 Levenspiel Plot
0.4 66829.03
250000.00
0.5 82511.49
0.6 99600.03 200000.00
0.7 132371.03
0.8 197913.04 150000.00
Fao/-ra

0.82 219760.37
100000.00

50000.00

0.00
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8
 150000.00

Fao/-ra
100000.00

50000.00

0.00
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8

Conversion X

8.205734E-05

dia=3inch
lentgh= 20f
number of tubes 40.38463099

8746 kg/m3
0.08 0.04

112.19448
0.589

3PI/4 2.3561945

4.555855

2PIRH
dia 1.6577663 165.7766265 vol 258879.4
length 4.9732988 497.3298795 2PIR2
RAD 0.8288831 82.88831325 43146.567
302026

crossectional area 21584.22585

43.583669
of reactor /Volumetric flow rate

hr
min

Plot

.4 0.5 0.6 0.7 0.8 0.9

.4 0.5 0.6 0.7 0.8 0.9

sion X
 0.01 TDI
1162.38 TFE
1.89 H2O
2901.81 CO
145.24 O2
487.05 TDA
681.72 TDC
5380.11
Component
density kg/m3
TDA 1214
O2 1.331
CO 1.165
TDI 1210
H2O 992
TDC 1100
TFE 1325
SUM