METALS

TABLE No. 1

PEAK WIDTH IS DIFFERENCE IN TEMPERATURE BETWEEN PEAK ONSET AND END POINT.
TOTAL CHANGE IN WEIGHT IS THE DIFFERENCE IN WEIGHT AT ONSET AND END POINT.
CHANGE IN TEMPERATURE PER WEIGHT IN PERCENT IS THE RATIO OF TOTAL CHANGE IN WEIG
RATE OF CHANGE IN WEIGHT g/s IS THE RATIO OF TOTAL CHANGE IN WEIGHT AND PEAK WIDT
RATE OF CHANGE IN WEIGHT BETWEEN CONTROL AND TREATED POWDERS IS 100*( R TREAT

ALUMINUM ANTIMONY
PEAK ONSET C CONTROL 533.00 468.00
PEAK C CONTROL 577.70 601.11
PEAK END PT. C CONTROL 625.70 618.34
PEAK WIDTH C CONTROL 92.70 150.34
%CHANGE IN WEIGHT AT
ONSET CONTROL 100.36 101.39
%CHANGE IN WEIGHT AT
END PT. CONTROL 101.78 42.32
TOTAL CHANGE IN
WEIGHT % CONTROL 1.43 -59.07
%CHANGE IN WEIGHT/
PEAK WIDTH (%/C) CONTROL 0.02 -0.39
PEAK ONSET C TREATED 538.49 508.75
PEAK C TREATED 585.46 561.98
PEAK END PT. C TREATED 629.29 579.20
PEAK WIDTH C TREATED 90.80 70.45
%CHANGE IN WEIGHT AT
ONSET TREATED 98.13 98.29
%CHANGE IN WEIGHT AT
END PT. TREATED 99.01 87.05
TOTAL CHANGE IN
WEIGHT % TREATED 0.88 -11.24
%CHANGE IN WEIGHT/
PEAK WIDTH (%/C) TREATED 0.01 -0.16

ALUMINUM ANTIMONY
PEAK WIDTH C CONTROL 92.70 150.34
PEAK WIDTH C TREATED 90.80 70.45
TOTAL CHANGE IN
WEIGHT % CONTROL 1.43 -59.07
TOTAL CHANGE IN
WEIGHT % TREATED 0.88 -11.24

ALUMINUM ANTIMONY
%CHANGE IN WEIGHT/
PEAK WIDTH (%/C) CONTROL 0.02 -0.39
%CHANGE IN WEIGHT/
PEAK WIDTH (%/C) TREATED 0.01 -0.16
 ALUMINUM ANTIMONY
%CHANGE IN WEIGHT/
PEAK WIDTH (RATE OF
WEIGHT) CHANGE)
(g/sec) CONTROL 3.39E-07 -6.94E-06
%CHANGE IN WEIGHT/
PEAK WIDTH (RATE OF
WEIGHT) CHANGE)
(g/sec) TREATED 1.63E-07 -4.38E-06

ALUMINUM ANTIMONY

RATE OF WEIGHT CHANGE

BETWEEN CONTROL AND
TREATED POWDERS (%) -51.88 -36.98

ALUMINUM ANTIMONY
PEAK C CONTROL 577.70 601.11
PEAK C TREATED 585.46 561.98
% CHANGE IN PEAK
TEMPERATURE 1.34 -6.51

TABLES 2 & 3 DSC- TGA

PERCENT CHANGE IN ΔH (LATENT HEAT OF MELTING) IS 100*(ΔH TREATED-ΔH CONTROL)/ ΔH C
PERCENT CHANGE IN T (MELTING POINT) IS 100*(T TREATED-T CONTROL)/ T CONTROL
PERCENT CHANGE IN MASS AT PEAH TEMPERATURE IS 100*(M TREATED-M CONTROL)/ M CON

CHANGE IN DSC- TGA CHARACTERISTICS OF TREATED POWDERS

PARAMETER ALUMINIUM ANTIMONY COPPER

0
MELTING POINT C 660.4 630.7 1084.88
OBSERVED PEAK
POSITION 0C 663.12 629.03 421.6
PERCENT CHANGE IN
MELTING POINT 0.41 -0.26
LATENT HEAT OF MELTING
J/g -397 -163.17 -205
OBSERVED ΔH J/g -326.9 -144.45 389.11

PERCENT CHANGE IN
LATENT HEAT OF MELTING -17.66 -11.47
CHANGE IN MASS AT PEAK
POSITION (%) -2.18 -9.72 -2.73

PARAMETER ALUMINIUM ANTIMONY COPPER

PERCENT CHANGE IN
MELTING POINT 0.41 -0.26

PERCENT CHANGE IN
LATENT HEAT OF MELTING -17.66 -11.47
CHANGE IN MASS AT PEAK
POSITION (%) -2.18 -9.72 -2.73

PARAMETER STRONTIUM MAGNESIUM BRASS

0
MELTING POINT C 768 650
OBSERVED PEAK
POSITION 0C 484.58 648.51 1083.99
PERCENT CHANGE IN
MELTING POINT -0.23
LATENT HEAT OF MELTING
J/g -104.7 -360.377
OBSERVED ΔH J/g -208.67 -139.87 -1517.04

PERCENT CHANGE IN
LATENT HEAT OF MELTING -61.19
CHANGE IN MASS AT PEAK
POSITION (%) -7.40 481.89 3.13

PARAMETER STRONTIUM MAGNESIUM BRASS

OBSERVED PEAK
POSITION 0C 484.58 648.51 1083.99
OBSERVED ΔH J/g -208.67 -139.87 -1517.04
CHANGE IN MASS AT PEAK
POSITION (%) -7.40 -2.69 3.13

TABLE 4 TGA AND SDTA

Testing done at Sophisticated Analytical Instrument Facility (SAIF) - Nagpur, Maharashtra - India
HEATING RANGE AND HEATING RATE: Room temperature to 400 º Celsius @ 5 º Celsius / minute.

Medium: Atmospheric Air

PERCENT CHANGE IN ΔH (LATENT HEAT OF MELTING) IS 100*(ΔH TREATED-ΔH CONTROL)/ ΔH C

PERCENT CHANGE IN T (MELTING POINT) IS 100*(T TREATED-T CONTROL)/ T CONTROL
PERCENT CHANGE IN MASS AT PEAH TEMPERATURE IS 100*(M TREATED-M CONTROL)/ M CON

K- CONVERSION
ELEMENT TREATMENT FROM SDTA soC FACTOR TO DSC
BISMUTH CONTROL 238.99 6.60
TREATED 1 201.26 6.60
TREATED 2 131.19 6.60
TREATED 3 101.26 6.60
TREATED 4 141.19 6.60
CADMIUM CONTROL 52.90 7.30
TREATED 1 75.27 7.30
TREATED 2 64.30 7.30
TREATED 3 101.26 7.30
TREATED 4 99.54 7.30
INDIUM CONTROL 18.13 5.45
TREATED 1 16.69 5.45
TREATED 2
TREATED 3
TREATED 4 11.64 5.45
LEAD CONTROL 25.56 7.40
TREATED 1 37.70 7.40
TREATED 2 25.62 7.40
TREATED 3 35.18 7.40
TREATED 4 60.07 7.40

DATA FOR CHARTS

BISMUTH CADMIUM

CONTROL 0.12 0.31

TREATED 1 -0.87 -0.89
PERCENT CHANGE IN
TREATED 2 0.15 -6.76
MASS
PERCENT CHANGE IN
MASS
TREATED 3 -9.99 -5.57
TREATED 4 0.38 0.24
CONTROL
TREATED 1 -5.59 -4.59
PERCENT CHANGE IN ΔH TREATED 2 -36.29 -38.34
TREATED 3 -44.81 -19.82
TREATED 4 -1.80 6.28

ELEMENT/ K- CONVERSION
TREATMENT FROM SDTA soC FACTOR TO DSC
LITHIUM GRANULES CONTROL 224.87 5.64
EXOTHERMIC TREATED 1 1653.85 5.64
EXOTHERMIC TREATED 2 1069.59 5.64
TREATED 3 98.64 5.64
EXOTHERMIC TREATED 4 739.19 5.64
SELENIUM CONTROL 102.66 5.97
TREATED 1 132.13 5.97
TREATED 2 40.38 5.97
TREATED 3 58.08 5.97
TREATED 4 216.56 5.97
TIN CONTROL 100.63 6.13
TREATED 1 112.49 6.13
TREATED 2 179.53 6.13
TREATED 3 136.51 6.13
TREATED 4 246.92 6.13

DATA FOR CHARTS

LITHIUM
GRANULES SELENIUM

CONTROL 0.94 -7.01

TREATED 1 1.10 -9.05
PERCENT CHANGE IN
TREATED 2 5.85 -3.80
MASS
TREATED 3 2.16 -6.81
TREATED 4 4.07 0.34
CONTROL
TREATED 1 23.56 6.76
PERCENT CHANGE IN ΔH TREATED 2 151.26 -18.43
TREATED 3 -69.25 -23.07
TREATED 4 150.58 12.16
 LEAD TIN

CONTROL -3.94 -5.78

TREATED 1 -1.11 -2.98
PERCENT CHANGE IN
TREATED 2 -7.23 -2.23
MASS
TREATED 3 -5.45 -4.06
TREATED 4 -0.23 0.38
CONTROL
TREATED 1 1.88 4.56
PERCENT CHANGE IN ΔH TREATED 2 -43.07 -31.17
TREATED 3 -40.78 -29.33
TREATED 4 7.17 12.88
 DTA-DTG

LE No. 1

EAK ONSET AND END POINT.

AT ONSET AND END POINT.
E RATIO OF TOTAL CHANGE IN WEIGHT AND PEAK WIDTH
HANGE IN WEIGHT AND PEAK WIDTH IN SECONDS
ATED POWDERS IS 100*( R TREATED- R CONTROL)/ R CONTROL

STRONTIUM TELLURIUM ZINC

272.35 391.33 350.63
358.46 511.88 579.20
385.07 605.00 651.21
112.72 213.67 300.58

100.16 100.88 98.86

109.20 122.23 114.44

9.04 21.35 15.58

0.08 0.10 0.05

375.68 453.96 364.72
488.40 652.78 538.49
516.58 688.78 585.46
140.90 234.82 220.74

95.22 97.92 97.83

81.85 14.16 106.45

-13.37 -83.76 8.62

-0.09 -0.36 0.04

STRONTIUM TELLURIUM ZINC

112.72 213.67 300.58
140.90 234.82 220.74

9.04 21.35 15.58

-13.37 -83.76 8.62

STRONTIUM TELLURIUM ZINC

0.08 0.10 0.05

-0.09 -0.36 0.04

STRONTIUM TELLURIUM ZINC

1.51E-06 2.82E-06 1.54E-06

-3.00E-06 -8.45E-06 6.68E-07

STRONTIUM TELLURIUM ZINC

-298.90 -399.63 -56.63

STRONTIUM TELLURIUM ZINC

358.46 511.88 579.20
488.40 652.78 538.49

36.25 27.53 -7.03

 *(ΔH TREATED-ΔH CONTROL)/ ΔH CONTROL
D-T CONTROL)/ T CONTROL
*(M TREATED-M CONTROL)/ M CONTROL

GOLD SILVER
1064.43 961.9

1048.93 887.28

-1.46 -7.76

-62.762 -104.2
-48.51 -116.14

-22.71 11.46

-0.89 -0.41

GOLD SILVER
-1.46 -7.76

-22.71 11.46

-0.89 -0.41

BRONZE

396.94

119.72

2.03

BRONZE

396.94
 119.72

2.03

A AND SDTA
AIF) - Nagpur, Maharashtra - India
00 º Celsius @ 5 º Celsius / minute.

*(ΔH TREATED-ΔH CONTROL)/ ΔH CONTROL

D-T CONTROL)/ T CONTROL
*(M TREATED-M CONTROL)/ M CONTROL

MASS OF SAMPLE mo LATENT HEAT OF MASS OF SAMPLE AT

mg FUSION ΔH J/g MELTING POINT oC MELTING POINT m
34.73 45.39 273.01 34.77
30.98 42.85 272.07 30.71
29.92 28.92 271.77 29.97
26.67 25.05 272.16 24.00
20.89 44.57 272.51 20.97
8.65 44.64 321.04 8.68
12.90 42.60 320.69 12.79
17.05 27.53 321.08 15.90
20.65 35.80 321.01 19.50
15.31 47.45 321.12 15.35
3.683 26.84 155.94 3.35
3.32 27.45 156.11 3.21

2.47 25.65 156.23 2.55

10.29 18.39 325.71 9.88
14.89 18.73 325.98 14.73
18.11 10.47 324.99 16.80
23.90 10.89 326.17 22.60
22.55 19.70 327.04 22.50

INDIUM LEAD

-9.04 -3.94
-3.32 -1.11
-7.23
 -5.45
3.07 -0.23

2.28 1.88
-43.07
-40.78
-4.42 7.17

MASS OF SAMPLE mo LATENT HEAT OF MASS OF SAMPLE AT

mg FUSION ΔH J/g MELTING POINT oC MELTING POINT m
4.67 271.62 186.34 4.71
27.77 335.60 305.42 28.08
8.83 682.46 349.56 9.35
6.66 83.52 182.49 6.80
6.12 680.62 328.06 6.37
9.49 64.61 220.92 8.82
11.44 68.98 220.82 10.40
4.57 52.70 220.50 4.40
6.98 49.71 220.99 6.50
17.84 72.47 221.99 17.90
13.14 46.92 232.91 12.38
14.05 49.06 232.66 13.63
34.06 32.29 234.04 33.30
25.22 33.16 232.87 24.20
28.56 52.96 232.86 28.67

TIN

-5.78
-2.98
-2.23
-4.06
0.38

4.56
-31.17
-29.33
12.88
 PERCENT
PERCENT CHANGE IN CHANGE IN
MASS ΔH
0.12
-0.87 -5.59
0.15 -36.29
-9.99 -44.81
0.38 -1.80
0.31
-0.89 -4.59
-6.76 -38.34
-5.57 -19.82
0.24 6.28
-9.04
-3.32 2.28

3.07 -4.42
-3.94
-1.11 1.88
-7.23 -43.07
-5.45 -40.78
-0.23 7.17
 PERCENT
PERCENT CHANGE IN CHANGE IN
MASS ΔH
0.94
1.10 23.56
5.85 151.26
2.16 -69.25
4.07 150.58
-7.01
-9.05 6.76
-3.80 -18.43
-6.81 -23.07
0.34 12.16
-5.78
-2.98 4.56
-2.23 -31.17
-4.06 -29.33
0.38 12.88