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Safety Data Sheet

acc. to OSHA HCS (HazCom 2012)
Printing date 06/16/2017 Reviewed on 06/16/2017

1 Identification
· Product identifier
· Trade name: Calcio-H No.1
· Catalogue number:
00511031, (4)511030BT, (4)511031BT, 00511030BT, 00511031BT, (4)517761-1BT, (4)517762-1BT, 00511039, 00511039BT
· Application of the substance / the mixture: Reagent for water analysis
· Manufacturer/Supplier:
Tintometer Inc.
6456 Parkland Drive
Sarasota, FL 34243
USA
phone: (941) 756-6410
fax: (941) 727-9654
www.lovibond.us
Made in Germany
®
· Emergency telephone number: Chemtrec : (US & Canada) 800-424-9300 (International) +1 (703) 527-3887

2 Hazard(s) identification
· Classification of the substance or mixture The product is not classified as hazardous.
· Label elements
· GHS label elements none
· Hazard pictograms none
· Signal word none
· Hazard statements none
· Other hazards No further relevant information available.

3 Composition/information on ingredients
· Chemical characterization: Mixtures
· Description: mixture of organic compounds
· Composition and Information on Ingredients: none

4 First-aid measures
· Description of first aid measures
· General information: Immediately remove any clothing soiled by the product.
· After inhalation: Supply fresh air.
· After skin contact: Immediately wash with water and soap and rinse thoroughly.
· After eye contact:
Rinse opened eye for several minutes (at least 15 min) under running water. If symptoms persist, consult a doctor.
· After swallowing:
Rinse out mouth and then drink 1-2 glasses of water.
If symptoms persist consult doctor.
· Most important symptoms and effects, both acute and delayed
after swallowing of large amounts:
thirst
sickness
vomiting
· Indication of any immediate medical attention and special treatment needed: No further relevant information available.
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(Contd. on page 2)

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Safety Data Sheet
acc. to OSHA HCS (HazCom 2012)
Printing date 06/16/2017 Reviewed on 06/16/2017

Trade name: Calcio-H No.1

(Contd. of page 1)

5 Fire-fighting measures
· Extinguishing media
· Suitable extinguishing agents: Water, Carbon dioxide (CO₂), Foam, Fire-extinguishing powder
· Special hazards arising from the substance or mixture
Can burn in fire.
Formation of toxic gases is possible during heating or in case of fire.
In case of fire, the following can be released:
nitrous gases
Sulfur oxides (SOx)
Nitrogen oxides (NOx)
Carbon monoxide (CO) and carbon dioxide (CO2)
· Advice for firefighters
· Protective equipment:
Wear self-contained respiratory protective device.
Wear fully protective suit.
· Additional information
Collect contaminated fire fighting water separately. It must not enter the sewage system.
Dispose of fire debris and contaminated fire fighting water in accordance with official regulations.
Ambient fire may liberate hazardous vapours.

6 Accidental release measures

· Personal precautions, protective equipment and emergency procedures
· Advice for non-emergency personnel: No special measures required.
· Advice for emergency responders: Protective equipment: see section 8
· Environmental precautions: Do not allow product to reach sewage system or any water course.
· Methods and material for containment and cleaning up:
Ensure adequate ventilation.
Pick up mechanically.
Dispose contaminated material as waste according to item 13.
· Reference to other sections
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information.

7 Handling and storage

· Handling:
· Precautions for safe handling
· Advice on safe handling: No special precautions are necessary if used correctly.
· Hygiene measures:
The usual precautionary measures for handling chemicals should be followed.
Wash hands before breaks and at the end of work.
Do not eat, drink or smoke when using this product.
· Conditions for safe storage, including any incompatibilities
· Storage:
· Requirements to be met by storerooms and receptacles: Store in a cool location.
· Information about storage in one common storage facility: Not required.
· Further information about storage conditions:
Protect from heat and direct sunlight.
Protect from exposure to the light.
Store in dry conditions.
Protect from humidity and water.
· Recommended storage temperature: 20 °C +/- 5 °C (approx. 68°F)
· Specific end use(s) No further relevant information available.
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(Contd. on page 3)

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Safety Data Sheet
acc. to OSHA HCS (HazCom 2012)
Printing date 06/16/2017 Reviewed on 06/16/2017

Trade name: Calcio-H No.1

(Contd. of page 2)

8 Exposure controls/personal protection

· Control parameters
· Components with limit values that require monitoring at the workplace:
The product does not contain any relevant quantities of materials with critical values that have to be monitored at the workplace.
· Additional information: The lists that were valid during the creation were used as basis.
· Engineering measures:
Technical measures and appropriate working operations should be given priority over the use of personal protective equipment.
See item 7.
· Personal protective equipment:
· Breathing equipment: Use respiratory protective device against the effects of fumes/dust/aerosol.
· Recommended filter device for short term use: Filter P1
· Protection of hands:
Preventive skin protection by use of skin-protecting agents is recommended.
After use of gloves apply skin-cleaning agents and skin cosmetics.
· Material of gloves
Nitrile rubber, NBR
Recommended thickness of the material: ≥ 0.11 mm
· Penetration time of glove material
Value for the permeation: Level ≤ 1 (10 min)
The exact break through time has to be found out by the manufacturer of the protective gloves and has to be observed.
· Eye protection:
Safety glasses
use against the effects of fumes / dust
· Body protection: Protective work clothing
· Limitation and supervision of exposure into the environment:
Do not allow product to reach sewage system or any water course.

9 Physical and chemical properties

· Information on basic physical and chemical properties
· Appearance:
Form / Physical state: Solid
Color: Pink
· Odor: Odorless
· Odor threshold: Not applicable.
· pH-value (8.7 g/l) at 20 °C (68 °F): 4.3
· Melting point/freezing point: Not determined.
· Initial boiling point and boiling range: Not determined.
· Flash point: Not determined.
· Flammability (solid, gas): Not determined.
· Decomposition temperature: Not determined.
· Auto-ignition temperature: Product is not self-igniting.
· Danger of explosion: As the product is supplied it is not capable of dust explosion; however enrichment with
fine dust causes risk of dust explosion.
· Flammability or explosive limits:
Lower: Not determined.
Upper: Not determined.
· Oxidizing properties: none
· Vapor Pressure: Not applicable.
· Density: Not determined.
· Relative density: Not determined.
· Vapor density: Not applicable.
· Evaporation rate: Not applicable.
(Contd. on page 4)
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Safety Data Sheet
acc. to OSHA HCS (HazCom 2012)
Printing date 06/16/2017 Reviewed on 06/16/2017

Trade name: Calcio-H No.1

(Contd. of page 3)

· Solubility(ies)
Water: Soluble.
· Partition coefficient (n-octanol/water): Not applicable.
· Viscosity: Not applicable.
· Solvent content:
Organic solvents: 0.0 %
Solids content: 100.0 %
· Other information No further relevant information available.

10 Stability and reactivity

· Reactivity Risk of dust explosion.
· Chemical stability Stable at ambient temperature (room temperature).
· Possibility of hazardous reactions
Reacts with oxidizing agents.
--> Forms heat.
· Conditions to avoid Strong heating (decomposition)
· Incompatible materials: No further relevant information available.
· Hazardous decomposition products: see section 5

11 Toxicological information
· Information on toxicological effects
· Acute toxicity: Based on available data, the classification criteria are not met.
· Primary irritant effect:
· on the skin: Based on available data, the classification criteria are not met.
· on the eye: Based on available data, the classification criteria are not met.
· Sensitization: Based on available data, the classification criteria are not met.
· Carcinogenic categories
· IARC (International Agency for Research on Cancer)
CAS: 139-05-9 sodium cyclamate 3
· NTP (National Toxicology Program)
None of the ingredients is listed.
· OSHA-Ca (Occupational Safety & Health Administration)
None of the ingredients is listed.
· Other information: see section 8 / 15
· Synergistic Products: None
· CMR effects (carcinogenity, mutagenicity and toxicity for reproduction): The following statements refer to the mixture:
· Germ cell mutagenicity Based on available data, the classification criteria are not met.
· Carcinogenicity Based on available data, the classification criteria are not met.
· Reproductive toxicity Based on available data, the classification criteria are not met.
· STOT (specific target organ toxicity) -single exposure Based on available data, the classification criteria are not met.
· STOT (specific target organ toxicity) -repeated exposure Based on available data, the classification criteria are not met.
· Aspiration hazard Based on available data, the classification criteria are not met.
· Additional toxicological information:
When used and handled according to specifications, the product does not have any harmful effects according to our experience
and the information provided to us.

12 Ecological information
· Toxicity
· Aquatic toxicity: No further relevant information available.
(Contd. on page 5)
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Safety Data Sheet
acc. to OSHA HCS (HazCom 2012)
Printing date 06/16/2017 Reviewed on 06/16/2017

Trade name: Calcio-H No.1

(Contd. of page 4)
· Persistence and degradability No further relevant information available.
· Bioaccumulative potential No further relevant information available.
· Mobility in soil No further relevant information available.
· Other adverse effects Avoid transfer into the environment.

13 Disposal considerations
· Waste treatment methods
· Recommendation:
Must not be disposed of together with household garbage. Do not allow product to reach sewage system.
Disposal must be made according to official regulations.
· Uncleaned packagings:
· Recommendation: Disposal must be made according to official regulations.
· Recommended cleansing agent: Water, if necessary with cleansing agents.

14 Transport information
· UN-Number
· DOT, IMDG, IATA none
· UN proper shipping name
· DOT, IMDG, IATA none
· Transport hazard class(es)
· DOT, IMDG, IATA
· Class none
· Packing group
· DOT, IMDG, IATA none
· Environmental hazards: Not applicable.
· Special precautions for user Not applicable.
· Transport in bulk according to Annex II of MARPOL73/78
and the IBC Code Not applicable.
· Transport/Additional information: Not dangerous according to the above specifications.

15 Regulatory information
· Safety, health and environmental regulations/legislation specific for the substance or mixture
· Sara
· Section 355 (Extremely hazardous substances):
None of the ingredients is listed.
· Section 313 (Specific toxic chemical listings):
None of the ingredients is listed.
· TSCA (Toxic Substances Control Act):
All ingredients are listed.
· Proposition 65
· Chemicals known to cause cancer:
None of the ingredients is listed.
· Chemicals known to cause reproductive toxicity for females:
None of the ingredients is listed.
· Chemicals known to cause reproductive toxicity for males:
None of the ingredients is listed.
· Chemicals known to cause developmental toxicity:
CAS: 3051-09-0 Murexid
(Contd. on page 6)
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Safety Data Sheet
acc. to OSHA HCS (HazCom 2012)
Printing date 06/16/2017 Reviewed on 06/16/2017

Trade name: Calcio-H No.1

(Contd. of page 5)
· New Jersey Right-to-Know List:
None of the ingredients is listed.
· New Jersey Special Hazardous Substance List:
None of the ingredients is listed.
· Pennsylvania Right-to-Know List:
None of the ingredients is listed.
· Pennsylvania Special Hazardous Substance List:
None of the ingredients is listed.
· EPA (Environmental Protection Agency)
None of the ingredients is listed.
· NIOSH-Ca (National Institute for Occupational Safety and Health)
None of the ingredients is listed.
· Information about limitation of use: Not required.
· Chemical safety assessment: A Chemical Safety Assessment has not been carried out.

16 Other information
This information is based on our present knowledge. However, this shall not constitute a guarantee for any specific product
features and shall not establish a legally valid contractual relationship.
· Date of preparation / last revision 06/16/2017 / 4
· Abbreviations and acronyms:
STOT: specific target organ toxicity
SE: single exposure
RE: repeated exposure
EC50: half maximal effective concentration
IC50: hallf maximal inhibitory concentration
NOEL or NOEC: No Observed Effect Level or Concentration
ACGIH® - American Conference of Governmental Industrial Hygienists
•A1 - Confirmed human carcinogen
•A2 - Suspected human carcinogen
•A3 - Confirmed animal carcinogen with unknown relevance to humans
•A4 - Not classifiable as a human carcinogen
•A5 - Not suspected as a human carcinogen
IARC - International Agency for Research on Cancer
•Group 1 - Carcinogenic to humans
•Group 2A - Probably carcinogenic to humans
•Group 2B - Possibly carcinogenic to humans
•Group 3 - Not classifiable as to carcinogenicity to humans
•Group 4 - Probably not carcinogenic to humans
NTP - National Toxicology Program, U.S. Department of Health and Human Services
•Group K - Known to be Human Carcinogens
•Group R - Reasonably Anticipated to be Human Carcinogens
ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement concerning the International Carriage of Dangerous Goods
by Road)
RID: Règlement international concernant le transport des marchandises dangereuses par chemin de fer (Regulations Concerning the International Transport of
Dangerous Goods by Rail)
IMDG: International Maritime Code for Dangerous Goods
DOT: US Department of Transportation
IATA: International Air Transport Association
EINECS: European Inventory of Existing Commercial Chemical Substances
ELINCS: European List of Notified Chemical Substances
CAS: Chemical Abstracts Service (division of the American Chemical Society)
NIOSH: National Institute for Occupational Safety
OSHA: Occupational Safety & Health
TLV: Threshold Limit Value
PEL: Permissible Exposure Limit
REL: Recommended Exposure Limit

· Sources Data arise from safety data sheets, reference works and literature.
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