757-2016B Appendix G-Material Safety Data Sheets PDF

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Appendix G

860198-0230(1.0)

Location Product Name Manufacturer Name Manufacturer Part #

39023 - 39583 TPO - Sem Products Inc. 39153


Body Shop Direct Bumper Coaters

39091-LV; 39104-LV Sem Products Inc.


Body Shop Flexible Bumper Coater

3M Dynatron Putty- 3M General Office LB-K100-0587-6


Body Shop
Cote 592, 592T, 593
3M Panel Bonding 3M 08115
Body Shop
Adhesive PN 08115
3M Scotch-Weld Epoxy 3M
Body Shop Adhesive DP-100 Clear

Body Shop 470 Featherspray Sluyter Company Ltd.


Body Shop 476 Spray Adhesive Sluyter Company Ltd.
Acrysol Body Solvent Lawson Products Inc P60170
Body Shop
16 Oz NW
Body Shop Air Tool Oil CRC Industries 74095
Air Tool Oil Kleen-Flo Tumbler 4168
Body Shop
Industries Ltd.
Allegro 70% IPA Allegro Industries 1001, 1001-05, 1001-10
Body Shop
Hygienic Wipe
Bactine Original First Bayer Healthcare LLC -
Body Shop Consumer Care
Aid Liquid
BD7-77 Plus Penetrant Barnes Group Inc. BD1108
Body Shop

Bio-Rust J. Walter Company Ltd. 53-G 245


Body Shop
Bon Ami Power Foam Diversey Inc.
Body Shop
Glass Cleaner
Correction pen (Multi- Pentel Co. Ltd ZL31-W, ZLC31-W,
Body Shop ZL33-W
Purpose)
Body Shop Cream Hardener ITW Evercoat 100340
Crown 8034 General Aervoe Industries Inc
Body Shop Purpose Silicone
Lubricant
Depend (R) Activator Henkel Loctite 21088
Body Shop 7387 Aerosol Corporation

Dupli-Color Enamel Sherwin Williams DA1600


Body Shop Paint, Gloss Black
(OSHA)
Dupli-Color Enamel Sherwin Williams DA1670
Body Shop Paint, Gloss White
(OSHA White)
Dupli-Color Engine Sherwin Williams DE1615
Body Shop Enamel with Ceramic,
Aluminum
Dupli-Color Lacquer Sherwin Williams DAL1607
Body Shop
Paint, Flat Black
Dupli-Color Primer Sherwin Williams DAP1692
Body Shop Surfacer, Gray Hot Rod

Eco-Care Engine Kleen-Flo Tumbler 022


Body Shop Industries Ltd.
Degreaser
Envy Foaming Diversey Lever
Body Shop
Disinfectant Cleaner
ETP Gold Cutting Fluid Lawson Products Inc P91010
Body Shop

European Auto Coat Transtar Autobody 1273


Body Shop
Technologies
Everglass quart Illinois Tool Works Inc. 100632
Body Shop
Extend(R) Rust Henkel Corp 37557
Body Shop
Treatment
Film Forming Lubricant Balmar, LLC 101G
Body Shop

Glance Foaming Glass Johnson Diversey 04553


Body Shop & Multi-Surface
Cleaner
Body Shop Glass Cleaner Sprayway 1000000075
Body Shop Graffiti wipes Total Solutions 1447
HHS 5000 500ml Würth Canada Limitée 893-1063
Body Shop
High Build Undercoat Würth Canada Limitée 890.9072
Body Shop 550G. Paintable -
890.9072
Johnsens Brake Parts Technical Chemical 2420
Body Shop Company
Cleaner
Kopr-Kote Thermal Jet Lube of Canada Ltd.
Body Shop
Grade
Krylon Industrial Quik- Sherwin Williams 03702
Mark Solvent-Based
Inverted Marking Paint
Body Shop
(Fluorescent), Orange

Loctite 242 Henkel Loctite Canada 135355


Body Shop Inc.
Threadlocker
Body Shop LPS 1 (Aerosol) LPS Laboratories Inc. C30116
Marvel Air Tool Oil Marvel Oil Company 50093
Body Shop
Inc.
Body Shop Metal Glaze ITW Evercoat 100416
Moovit (Aerosol) Lloyds Laboratories Inc. 11008
Body Shop
Mopar Multi-Purpose Chrysler LLC.
Body Shop
Lube
Never-Seez Regular Bostik Findley Inc. V048740
Body Shop
Grade Cmpd.
One Step Hand Belvedere International
Body Shop Sanitizer Incorporated

PF 7770-3 Truck Line Pro-Form Products Ltd.


Body Shop Pliogrip Urethane
Adhesive Part A
Pyro-Chem ABC Tyco Fire Protection 2001-2-012 ANa
Body Shop
Products
QD Electronic Cleaner CRC Industries 75012
Body Shop
(Aerosol)
Reflex 700 A Langeman 872-1025
Body Shop
Manufacturing Ltd.
Body Shop Rustex Primer Grey Cloverdale Paint Inc. 71024
Body Shop Sika Cleaner-205 Sika Canada Inc.
Body Shop Sikaflex 252 Sika Corporation 604270
Body Shop Sikaflex-222 UV Sika Canada Inc.
Stokolan intensive Deb
Body Shop
repair
TECHNOMELT KS 250 Henkel AG & Co.
Body Shop COOL known as Dorus
KS 250 cool
TEROSON SI 9160 CL Henkel Corporation 475372
known as SILATECH
Body Shop
SILICONE SEALANT IND

Valve Action Paint LA-CO Industries Inc.- 96800


Body Shop Markal Company
Marker
Way Oil Vistac 68, 220 Chevron Texaco Global 232511
Body Shop Lubricants
WD-40 Bulk Liquid WD 40 Products
Body Shop
Canada Ltd.
Windex Original Glass Diversey Inc. 350000014153
Body Shop Cleaner with Ammonia-
D
Inventory List by Status - All Products with Document Type
Location Product Name Manufacturer Name Manufacturer Part # Item Status Document Type
Transit Dept (8050) > Cat Cement Chemtool Inc. Carterpillar Deactivated
421 Osborne (8080)
Transit Dept (8050) > G.b.p. Reducer Sherwin-Williams R7K981 Deactivated
421 Osborne (8080) Activator Automotive Finishes
Transit Dept (8050) > Goldex Institutional RW Packaging Ltd. Deactivated
421 Osborne (8080) Bleach
Transit Dept (8050) > Kopr-Kote Thermal Jet Lube of Canada Ltd. Deactivated
421 Osborne (8080) Grade
Transit Dept (8050) > Percept Concentrated Johnson Diversey/ The 4337041 Deactivated
421 Osborne (8080) General Virucide Butcher Company
Disinfectant Cleaner
(cAN)
Transit Dept (8050) > PERCEPT RTUWIPES JohnsonDiversey - Deactivated
421 Osborne (8080) Canada, Inc.
Transit Dept (8050) > Shopworks Bioclean Rochester Midland Ltd. Deactivated
421 Osborne (8080)
Transit Dept (8050) > 39023 - 39583 TPO - Sem Products Inc. 39153 Matched English Canada
421 Osborne (8080) > Direct Bumper Coaters WHMIS
Body Shop
Transit Dept (8050) > 39091-LV; 39104-LV Sem Products Inc. Matched English Canada
421 Osborne (8080) > Flexible Bumper Coater WHMIS
Body Shop
Transit Dept (8050) > 39143 Trim Black Sem Products Inc. 39143 Matched English Canada
421 Osborne (8080) > WHMIS
Body Shop
Transit Dept (8050) > 3M Dynatron Putty-Cote 3M General Office LB-K100-0587-6 Matched English Canada
421 Osborne (8080) > 592, 592T, 593 WHMIS
Body Shop
Transit Dept (8050) > 3M Panel Bonding 3M 08115 Matched English Canada
421 Osborne (8080) > Adhesive PN 08115 WHMIS
Body Shop
Transit Dept (8050) > 3M Scotch-Weld Epoxy 3M Matched English Canada
421 Osborne (8080) > Adhesive DP-100 Clear WHMIS
Body Shop
Transit Dept (8050) > 470 Featherspray Sluyter Company Ltd. Matched English Canada
421 Osborne (8080) > WHMIS
Body Shop
Transit Dept (8050) > 476 Spray Adhesive Sluyter Company Ltd. Matched English Canada
421 Osborne (8080) > WHMIS
Body Shop
Transit Dept (8050) > Abrasive Sanding Discs KWH Mirka Matched English Canada
421 Osborne (8080) > WHMIS
Body Shop
Transit Dept (8050) > Accel Tb Wipes Virox Technologies Matched English Canada
421 Osborne (8080) > WHMIS
Body Shop
Transit Dept (8050) > ACDelco Penetrating Shrader Canada Ltd. 992955 Matched English Canada
421 Osborne (8080) > Fluid, 290 g WHMIS
Body Shop
Transit Dept (8050) > Acrysol Body Solvent Lawson Products Inc P60170 Matched English Canada
421 Osborne (8080) > 16 Oz NW WHMIS
Body Shop
Transit Dept (8050) > Air Tool Oil CRC Industries 74095 Matched English Canada
421 Osborne (8080) > WHMIS
Body Shop
Transit Dept (8050) > Air Tool Oil Kleen-Flo Tumbler 4168 Matched English Canada
421 Osborne (8080) > Industries Ltd. WHMIS
Body Shop
Transit Dept (8050) > Allegro 70% IPA Allegro Industries 1001, 1001-05, 1001-10 Matched English Canada
421 Osborne (8080) > Hygienic Wipe WHMIS
Body Shop
Transit Dept (8050) > BD7-77 Plus Penetrant Barnes Group Inc. BD1108 Matched English Canada
421 Osborne (8080) > WHMIS
Body Shop
Transit Dept (8050) > Bio-Rust J. Walter Company Ltd. 53-G 245 Matched English Canada
421 Osborne (8080) > WHMIS
Body Shop
Transit Dept (8050) > Bon Ami Power Foam Diversey Inc. Matched English Canada
421 Osborne (8080) > Glass Cleaner WHMIS
Body Shop
Transit Dept (8050) > Coated Abrasives Flap Jet Equipment & Tools Matched English Canada
421 Osborne (8080) > Discs (Aluminum Oxide, Ltd WHMIS
Body Shop Zirconia, Ceramic
Grains, Surface
Conditioning Disc, And
Semiflex Discs)
Transit Dept (8050) > Coated Finished Flap Saint-Gobain Matched English Canada
421 Osborne (8080) > Discs Abrasives, Inc. WHMIS
Body Shop
Transit Dept (8050) > Correction pen (Multi- Pentel Co. Ltd ZL31-W, ZLC31-W, Matched English Canada
421 Osborne (8080) > Purpose) ZL33-W WHMIS
Body Shop
Transit Dept (8050) > Cream Hardener ITW Evercoat 100340 Matched English Canada
421 Osborne (8080) > WHMIS
Body Shop
Transit Dept (8050) > Crown 8034 General Aervoe Industries Inc Matched English Canada
421 Osborne (8080) > Purpose Silicone WHMIS
Body Shop Lubricant
Transit Dept (8050) > Depend (R) Activator Henkel Loctite 21088 Matched English Canada
421 Osborne (8080) > 7387 Aerosol Corporation WHMIS
Body Shop
Transit Dept (8050) > Dupli-Color Enamel Sherwin Williams DA1600 Matched English Canada
421 Osborne (8080) > Paint, Gloss Black WHMIS
Body Shop (OSHA)
Transit Dept (8050) > Dupli-Color Enamel Sherwin Williams DA1670 Matched English Canada
421 Osborne (8080) > Paint, Gloss White WHMIS
Body Shop (OSHA White)
Transit Dept (8050) > Dupli-Color Engine Sherwin Williams DE1615 Matched English Canada
421 Osborne (8080) > Enamel with Ceramic, WHMIS
Body Shop Aluminum
Transit Dept (8050) > Dupli-Color Lacquer Sherwin Williams DAL1607 Matched English Canada
421 Osborne (8080) > Paint, Flat Black WHMIS
Body Shop
Transit Dept (8050) > Dupli-Color Primer Sherwin Williams DAP1692 Matched English Canada
421 Osborne (8080) > Surfacer, Gray Hot Rod WHMIS
Body Shop
Transit Dept (8050) > Eco-Care Engine Kleen-Flo Tumbler 022 Matched English Canada
421 Osborne (8080) > Degreaser Industries Ltd. WHMIS
Body Shop
Transit Dept (8050) > Envy Foaming Diversey Lever Matched English Canada
421 Osborne (8080) > Disinfectant Cleaner WHMIS
Body Shop
Transit Dept (8050) > ETP Gold Cutting Fluid Lawson Products Inc P91010 Matched English Canada
421 Osborne (8080) > WHMIS
Body Shop
Transit Dept (8050) > European Auto Coat Transtar Autobody 1273 Matched English Canada
421 Osborne (8080) > Technologies WHMIS
Body Shop
Transit Dept (8050) > Everglass quart Illinois Tool Works Inc. 100632 Matched English Canada
421 Osborne (8080) > WHMIS
Body Shop
Transit Dept (8050) > Extend(R) Rust Henkel Corp 37557 Matched English Canada
421 Osborne (8080) > Treatment WHMIS
Body Shop
Transit Dept (8050) > Film Forming Lubricant Balmar, LLC 101G Matched English Canada
421 Osborne (8080) > WHMIS
Body Shop
Transit Dept (8050) > Flap Disc, Type 29 and Osborn AB-03 Matched English Canada
421 Osborne (8080) > 27 WHMIS
Body Shop
Transit Dept (8050) > Floor-Dry, Solid-a-Sorb, EP Minerals, LLC Matched English Canada
421 Osborne (8080) > MP Grades WHMIS
Body Shop
Transit Dept (8050) > Glance Foaming Glass Johnson Diversey 04553 Matched English Canada
421 Osborne (8080) > & Multi-Surface Cleaner WHMIS
Body Shop
Transit Dept (8050) > Glass Cleaner Sprayway 1000000075 Matched English Canada
421 Osborne (8080) > WHMIS
Body Shop
Transit Dept (8050) > Graffiti wipes Total Solutions 1447 Matched English Canada
421 Osborne (8080) > WHMIS
Body Shop
Transit Dept (8050) > Grinding discs / cutting- Klingspor Abrasives Inc. Matched English Canada
421 Osborne (8080) > off wheels group O WHMIS
Body Shop
Transit Dept (8050) > Grinding discs, cutting- Klingspor Abrasives Inc. Matched English Canada
421 Osborne (8080) > off wheels group KP WHMIS
Body Shop
Transit Dept (8050) > HHS 5000 500ml Würth Canada Limitée 893-1063 Matched English Canada
421 Osborne (8080) > WHMIS
Body Shop
Transit Dept (8050) > High Build Undercoat Würth Canada Limitée 890.9072 Matched English Canada
421 Osborne (8080) > 550G. Paintable - WHMIS
Body Shop 890.9072
Transit Dept (8050) > HI-LITER Markers Avery Product Matched English Canada
421 Osborne (8080) > (Yellow, Light Green, Corporation WHMIS
Body Shop Light Blue, Pink)
Transit Dept (8050) > HP Grinding, HP XX, J. Walter Company Ltd. Matched English Canada
421 Osborne (8080) > Allsteel XX, Stainless, WHMIS
Body Shop ALU, Concrete,
Pipefitter, Xcavator,
Ripcut, Chopcut,
Chopcut ALU, Portacut,
Zip, Zip Stainless,
Zipcut, Zip ALU,
Railcut, HP Cup Wheel,
Flexcut, Flexcut
Milscale
Transit Dept (8050) > Johnsens Brake Parts Technical Chemical 2420 Matched English Canada
421 Osborne (8080) > Cleaner Company WHMIS
Body Shop
Transit Dept (8050) > Kitty Hair Fibre Glass-Evercoat 100857 Matched English Canada
421 Osborne (8080) > Co. Inc. WHMIS
Body Shop
Transit Dept (8050) > Kopr-Kote Thermal Jet Lube of Canada Ltd. Matched English Canada
421 Osborne (8080) > Grade WHMIS
Body Shop
Transit Dept (8050) > Krylon Industrial Quik- Sherwin Williams 03702 Matched English Canada
421 Osborne (8080) > Mark Solvent-Based WHMIS
Body Shop Inverted Marking Paint
(Fluorescent), Orange
Transit Dept (8050) > Loctite 242 Henkel Loctite Canada 135355 Matched English Canada
421 Osborne (8080) > Threadlocker Inc. WHMIS
Body Shop
Transit Dept (8050) > LPS 1 (Aerosol) LPS Laboratories Inc. C30116 Matched English Canada
421 Osborne (8080) > WHMIS
Body Shop
Transit Dept (8050) > Marvel Air Tool Oil Marvel Oil Company 50093 Matched English Canada
421 Osborne (8080) > Inc. WHMIS
Body Shop
Transit Dept (8050) > Metal Glaze ITW Evercoat 100416 Matched English Canada
421 Osborne (8080) > WHMIS
Body Shop
Transit Dept (8050) > Moovit (Aerosol) Lloyds Laboratories Inc. 11008 Matched English Canada
421 Osborne (8080) > WHMIS
Body Shop
Transit Dept (8050) > Mopar Multi-Purpose Chrysler LLC. Matched English Canada
421 Osborne (8080) > Lube WHMIS
Body Shop
Transit Dept (8050) > Never-Seez Regular Bostik Findley Inc. V048740 Matched English Canada
421 Osborne (8080) > Grade Cmpd. WHMIS
Body Shop
Transit Dept (8050) > One Step Hand Belvedere International Matched English Canada
421 Osborne (8080) > Sanitizer Incorporated WHMIS
Body Shop
Transit Dept (8050) > PF 7770-3 Truck Line Pro-Form Products Ltd. Matched English Canada
421 Osborne (8080) > Pliogrip Urethane WHMIS
Body Shop Adhesive Part A
Transit Dept (8050) > Pyro-Chem ABC Tyco Fire Protection 2001-2-012 ANa Matched English Canada
421 Osborne (8080) > Products WHMIS
Body Shop
Transit Dept (8050) > QD Electronic Cleaner CRC Industries 75012 Matched English Canada
421 Osborne (8080) > (Aerosol) WHMIS
Body Shop
Transit Dept (8050) > Reflex 700 A Langeman 872-1025 Matched English Canada
421 Osborne (8080) > Manufacturing Ltd. WHMIS
Body Shop
Transit Dept (8050) > Reflex 700 B Langeman 983-1030 Matched English Canada
421 Osborne (8080) > Manufacturing Ltd. WHMIS
Body Shop
Transit Dept (8050) > Reinforced Resinoid Osborn Matched English Canada
421 Osborne (8080) > Bonded Abrasive WHMIS
Body Shop Wheel
Transit Dept (8050) > Rost Off Wurth USA 08902 Matched English Canada
421 Osborne (8080) > WHMIS
Body Shop
Transit Dept (8050) > Rustex Primer Grey Cloverdale Paint Inc. 71024 Matched English Canada
421 Osborne (8080) > WHMIS
Body Shop
Transit Dept (8050) > Sika Cleaner-205 Sika Canada Inc. Matched English Canada
421 Osborne (8080) > WHMIS
Body Shop
Transit Dept (8050) > Sikaflex 252 Sika Corporation 604270 Matched English Canada
421 Osborne (8080) > WHMIS
Body Shop
Transit Dept (8050) > Sikaflex-222 UV Sika Canada Inc. Matched English Canada
421 Osborne (8080) > WHMIS
Body Shop
Transit Dept (8050) > Small Diameter Osborn Matched English Canada
421 Osborne (8080) > Abrasive Wheels WHMIS
Body Shop
Transit Dept (8050) > Stokolan intensive Deb Matched English Canada
421 Osborne (8080) > repair WHMIS
Body Shop
Transit Dept (8050) > Super Duster 134 and MG Chemicals Ltd. 402A-140G Matched English Canada
421 Osborne (8080) > Super Duster 134 Plus WHMIS
Body Shop
Transit Dept (8050) > TECHNOMELT KS 250 Henkel AG & Co. Matched English Canada
421 Osborne (8080) > COOL known as Dorus WHMIS
Body Shop KS 250 cool
Transit Dept (8050) > TEROSON SI 9160 CL Henkel Corporation 475372 Matched English Canada
421 Osborne (8080) > known as SILATECH WHMIS
Body Shop SILICONE SEALANT
IND
Transit Dept (8050) > Travabon Stockhausen Inc. Matched English Canada
421 Osborne (8080) > WHMIS
Body Shop
Transit Dept (8050) > Uvex Clear Lens Honeywell Safety S468 Matched English Canada
421 Osborne (8080) > Cleaning Towelette Products WHMIS
Body Shop
Transit Dept (8050) > Valve Action Paint LA-CO Industries Inc.- 96800 Matched English Canada
421 Osborne (8080) > Marker Markal Company WHMIS
Body Shop
Transit Dept (8050) > Vitrified Abrasive Saint Gobain North 66253109044 Matched English Canada
421 Osborne (8080) > Product America WHMIS
Body Shop
Transit Dept (8050) > Way Oil Vistac 68, 220 Chevron Texaco Global 232511 Matched English Canada
421 Osborne (8080) > Lubricants WHMIS
Body Shop
Transit Dept (8050) > WD-40 Bulk Liquid WD 40 Products Matched English Canada
421 Osborne (8080) > Canada Ltd. WHMIS
Body Shop
Transit Dept (8050) > Windex Original Glass Diversey Inc. 350000014153 Matched English Canada
421 Osborne (8080) > Cleaner with Ammonia- WHMIS
Body Shop D
Transit Dept (8050) > 41 Cut-Off Wheel Tyrolit North America 384142 In Progress English Canada
421 Osborne (8080) > Inc. WHMIS
Body Shop
Transit Dept (8050) > Bactine Original First Bayer Healthcare LLC - In Progress English Canada
421 Osborne (8080) > Aid Liquid Consumer Care WHMIS
Body Shop
Transit Dept (8050) > Crown General Purpose Aervoe Industries Inc Deactivated
421 Osborne (8080) > Silicone Lubricant - Bulk
Body Shop
Transit Dept (8050) > 11111-BT503 Wasp K-G Packaging - Spray Matched English Canada
421 Osborne (8080) > and Hornet Killer Pak WHMIS
Building Painters Shop

Transit Dept (8050) > 14 OZ MRO MRO Solutions L.L.C. 1000009047 Matched English Canada
421 Osborne (8080) > SOLUTIONS HD WHMIS
Building Painters Shop DGRSR LB 12PK

Transit Dept (8050) > 3M Booth Coating 3M Canada Inc. 60-9801-0920-5 Matched English Canada
421 Osborne (8080) > WHMIS
Building Painters Shop

Transit Dept (8050) > 603-604 Sico Expert Sico Production 603404 Matched English Canada
421 Osborne (8080) > WHMIS
Building Painters Shop

Transit Dept (8050) > 71-054 BREEZE EXT. General Paint Corp. Matched English Canada
421 Osborne (8080) > S/G-CLEAR BASE WHMIS
Building Painters Shop

Transit Dept (8050) > 883-401 Sico Expert Sico Industries Inc. Matched English Canada
421 Osborne (8080) > WHMIS
Building Painters Shop

Transit Dept (8050) > 883-403 Sico Expert Sico Industries Inc. Matched English Canada
421 Osborne (8080) > WHMIS
Building Painters Shop
Transit Dept (8050) > Acrylic Lacquer Thinner The Martin-Senour Co. 3092 Matched English Canada
421 Osborne (8080) > Fast Evaporating WHMIS
Building Painters Shop

Transit Dept (8050) > Air Tool Oil CRC Industries 74095 Matched English Canada
421 Osborne (8080) > WHMIS
Building Painters Shop

Transit Dept (8050) > Air Tool Oil Kleen-Flo Tumbler 4168 Matched English Canada
421 Osborne (8080) > Industries Ltd. WHMIS
Building Painters Shop

Transit Dept (8050) > Aquapon WB PPG Industries 98-101 Matched English Canada
421 Osborne (8080) > Component B Architectural Finishes WHMIS
Building Painters Shop

Transit Dept (8050) > Armour Etch Armour Products 15-0150 Matched English Canada
421 Osborne (8080) > WHMIS
Building Painters Shop

Transit Dept (8050) > BEYE 2X3.7L 123 Rust-Oleum Z02012 Matched English Canada
421 Osborne (8080) > Primer WHMIS
Building Painters Shop

Transit Dept (8050) > Boiled Linseed Oil Recochem Inc. 13-404EXP Matched English Canada
421 Osborne (8080) > WHMIS
Building Painters Shop

Transit Dept (8050) > CertainTeed Finishing CertainTeed Gypsum Matched English Canada
421 Osborne (8080) > Products and Ready- WHMIS
Building Painters Shop Mix Compounds

Transit Dept (8050) > Clovaguard Hb Cloverdale Paint Inc. 83150A Matched English Canada
421 Osborne (8080) > Polyamide Epoxy WHMIS
Building Painters Shop

Transit Dept (8050) > Colorant S Red Oxide PPG Architect Coatings Matched English Canada
421 Osborne (8080) > 837770 WHMIS
Building Painters Shop
Transit Dept (8050) > Colorant Y Yellow PPG Architect Coatings Matched English Canada
421 Osborne (8080) > Ochre 837930 WHMIS
Building Painters Shop

Transit Dept (8050) > Conv. Epocy Primer PPG Automotive F3997 Matched English Canada
421 Osborne (8080) > Black Refinish WHMIS
Building Painters Shop

Transit Dept (8050) > Conventional Epoxy PPG Automotive F3996 Matched English Canada
421 Osborne (8080) > Primer Hardener Refinish WHMIS
Building Painters Shop

Transit Dept (8050) > Corrostop Bright Red PPG Architect Coatings Matched English Canada
421 Osborne (8080) > 635720 WHMIS
Building Painters Shop

Transit Dept (8050) > Corrostop Burnt Orange PPG Industries, Inc. 00400801 Matched English Canada
421 Osborne (8080) > 635590 WHMIS
Building Painters Shop

Transit Dept (8050) > Corrostop Gloss Black PPG Architect Coatings Matched English Canada
421 Osborne (8080) > 635180 WHMIS
Building Painters Shop

Transit Dept (8050) > Corrostop Gloss Ultwh AkzoNobel Canada Inc. 635110 Matched English Canada
421 Osborne (8080) > 635110 WHMIS
Building Painters Shop

Transit Dept (8050) > Corrostop Nbase PPG Architect Coatings Matched English Canada
421 Osborne (8080) > 635503 WHMIS
Building Painters Shop

Transit Dept (8050) > Corrostop Real Blue PPG Architect Coatings Matched English Canada
421 Osborne (8080) > 635350 WHMIS
Building Painters Shop

Transit Dept (8050) > Covercoat Semi-Gloss Cloverdale Paint Inc. 02124 Matched English Canada
421 Osborne (8080) > Latex Clear Base WHMIS
Building Painters Shop Weatherone
Transit Dept (8050) > D-15 Insect Repellent Quixtar Canada 602643 Matched English Canada
421 Osborne (8080) > Corporation WHMIS
Building Painters Shop

Transit Dept (8050) > Dettol Antiseptic Reckitt & Benckiser 930666 Matched English Canada
421 Osborne (8080) > Disinfectant (Liquid) - WHMIS
Building Painters Shop Canadian

Transit Dept (8050) > Devflex Acrylic Semi- PPG Architectural 4216L Matched English Canada
421 Osborne (8080) > Gloss Coatings WHMIS
Building Painters Shop

Transit Dept (8050) > Dimension 2K Acrylic Sherwin Williams DS693 Matched English Canada
421 Osborne (8080) > Urethane Sealer (Part WHMIS
Building Painters Shop A) Gray

Transit Dept (8050) > Dimension Reducer, Sherwin-Williams DR633 Matched English Canada
421 Osborne (8080) > Medium WHMIS
Building Painters Shop

Transit Dept (8050) > Dlx K&B Eggshell White PPG Architect Coatings Matched English Canada
421 Osborne (8080) > 18010 WHMIS
Building Painters Shop

Transit Dept (8050) > EP589 Gray Epoxy BASF Canada Inc. 30089473 Matched English Canada
421 Osborne (8080) > Primer WHMIS
Building Painters Shop

Transit Dept (8050) > Epoxy Primer Catalyst PPG Coatings and DP402LF Matched English Canada
421 Osborne (8080) > Resins WHMIS
Building Painters Shop

Transit Dept (8050) > Floor Urethane Natwh PPG Architect Coatings Matched English Canada
421 Osborne (8080) > 261501 WHMIS
Building Painters Shop

Transit Dept (8050) > G156, XF Metal Polish Meguiar's Matched English Canada
421 Osborne (8080) > Paste WHMIS
Building Painters Shop
Transit Dept (8050) > General Paint Industrial General Paint Corp 16-054 Matched English Canada
421 Osborne (8080) > Urethane Self-Prime WHMIS
Building Painters Shop Coating - Gloss interior
and exterior, Clear
Base
Transit Dept (8050) > Gld Ultra Sgl ClBase PPG Architect Coatings Matched English Canada
421 Osborne (8080) > 94806 WHMIS
Building Painters Shop

Transit Dept (8050) > HHS Lube 500ml Würth Canada Limitée 08931065 Matched English Canada
421 Osborne (8080) > WHMIS
Building Painters Shop

Transit Dept (8050) > Hi-Glo Synthetic Sherwin-Williams WS59 Matched English Canada
421 Osborne (8080) > Enamel System, Fast WHMIS
Building Painters Shop Reducer

Transit Dept (8050) > Hi-Hide Eggshell Int Cloverdale Paint Inc. 03243 Matched English Canada
421 Osborne (8080) > Acrylic Latex White WHMIS
Building Painters Shop

Transit Dept (8050) > IC LSPR 12PK White Rust Oleum 020066112684 Matched English Canada
421 Osborne (8080) > Marking Corporation WHMIS
Building Painters Shop

Transit Dept (8050) > Interior Semi-Gloss Cloverdale Paint Inc. 01123 Matched English Canada
421 Osborne (8080) > Acrylic Latex White WHMIS
Building Painters Shop Base-Premium Classic

Transit Dept (8050) > KRYLON ColorMaster Krylon Products Group 51511 Matched English Canada
421 Osborne (8080) > with Covermax WHMIS
Building Painters Shop Technology, Silver

Transit Dept (8050) > Krylon High Strength Sherwin Williams 9090 Matched English Canada
421 Osborne (8080) > Spray Adhesive WHMIS
Building Painters Shop
Transit Dept (8050) > Krylon INdustrial Quik- Sherwin-Williams 03901 Matched English Canada
421 Osborne (8080) > Mark Water-Based WHMIS
Building Painters Shop Inverted Marking Paint
(APWA) Brilliant White

Transit Dept (8050) > LePage Polyfilla Big Henkel Loctite Canada 1256104 Matched English Canada
421 Osborne (8080) > Inc. WHMIS
Building Painters Shop

Transit Dept (8050) > LIMCO LB Bases & BASF Corporation Matched English Canada
421 Osborne (8080) > Colors without Lead WHMIS
Building Painters Shop

Transit Dept (8050) > Manus Impact Beads Potters Industries Inc. Matched English Canada
421 Osborne (8080) > WHMIS
Building Painters Shop

Transit Dept (8050) > New Rapid Tap Relton Corporation Matched English Canada
421 Osborne (8080) > WHMIS
Building Painters Shop

Transit Dept (8050) > NON SANDING PPG Industries, Inc. DP50LF Matched English Canada
421 Osborne (8080) > EPOXY PRIMER WHMIS
Building Painters Shop LIGHT GRAY (LEAD
FREE)
Transit Dept (8050) > Olympic Wood PPG Coatings and 79304 Matched English Canada
421 Osborne (8080) > Protector Sc Navajo Resins WHMIS
Building Painters Shop Red

Transit Dept (8050) > Para Premium Eggshell General Paint Ltd 9090 Matched English Canada
421 Osborne (8080) > Latex Interior Wall WHMIS
Building Painters Shop Paint, White

Transit Dept (8050) > Product 567 Bulk Henkel Australia Pty Ltd Matched English Canada
421 Osborne (8080) > WHMIS
Building Painters Shop
Transit Dept (8050) > Promar 400 Interior Sherwin Williams B21W4451 Matched English Canada
421 Osborne (8080) > Latex Gloss Enamel WHMIS
Building Painters Shop Extra White

Transit Dept (8050) > Regal Aquaglo Benjamin Moore & Co. 333, n333 Matched English Canada
421 Osborne (8080) > WHMIS
Building Painters Shop

Transit Dept (8050) > Rohper LSPR 6Pk Flat Rust Oleum V2182838 Matched English Canada
421 Osborne (8080) > Gray Primer Corporation WHMIS
Building Painters Shop

Transit Dept (8050) > Rohper Lspr 6Pk Gloss Rust Oleum V2116838 Matched English Canada
421 Osborne (8080) > High Tmp Aluminum Corporation WHMIS
Building Painters Shop

Transit Dept (8050) > Select Semigloss Akzo Nobel / Sico Matched English Canada
421 Osborne (8080) > Natwh 677500 WHMIS
Building Painters Shop

Transit Dept (8050) > Sikaflex-252 Sika Canada Inc. Matched English Canada
421 Osborne (8080) > WHMIS
Building Painters Shop

Transit Dept (8050) > Spec 200 Interior Semi Benjamin Moore & Co. 034 Matched English Canada
421 Osborne (8080) > Gloss WHMIS
Building Painters Shop

Transit Dept (8050) > Speckle Stone Metallic K-G Spray-Pak Inc. 00002865 Matched English Canada
421 Osborne (8080) > Series WHMIS
Building Painters Shop

Transit Dept (8050) > Stokolan Classsic Deb-Stoko USA LLC Matched English Canada
421 Osborne (8080) > WHMIS
Building Painters Shop

Transit Dept (8050) > Super Acrylic II Cloverdale Paint Inc. 43057 Matched English Canada
421 Osborne (8080) > Eggshell Clear Base WHMIS
Building Painters Shop
Transit Dept (8050) > Super Acrylic II Cloverdale Paint Inc. 43054 Matched English Canada
421 Osborne (8080) > Eggshell Deep Base WHMIS
Building Painters Shop

Transit Dept (8050) > Super Acrylic II Semi- Cloverdale Paint Inc. 44057 Matched English Canada
421 Osborne (8080) > Gloss Clear Base WHMIS
Building Painters Shop

Transit Dept (8050) > Super Acrylic II Semi- Cloverdale Paint Inc. 44054 Matched English Canada
421 Osborne (8080) > Gloss Deep Base WHMIS
Building Painters Shop

Transit Dept (8050) > Thinner - Fast PPG Automotive F3320 Matched English Canada
421 Osborne (8080) > Refinish / WHMIS
Building Painters Shop NexaAutoColor

Transit Dept (8050) > TNT S/G Deeptone PPG Industries 27-210 Matched English Canada
421 Osborne (8080) > Base WHMIS
Building Painters Shop

Transit Dept (8050) > TSP General Purpose Dap Inc. 070798630017 Matched English Canada
421 Osborne (8080) > Cleaner WHMIS
Building Painters Shop

Transit Dept (8050) > Turpentine Recochem Inc. Matched English Canada
421 Osborne (8080) > WHMIS
Building Painters Shop

Transit Dept (8050) > Ultra Low Voc Ecologic Cloverdale Paint Inc. 70694 Matched English Canada
421 Osborne (8080) > WB Gloss Level 2 WHMIS
Building Painters Shop Eggshell Neutral Base

Transit Dept (8050) > Ultra Low VOC Ecologic Cloverdale Paint Inc. 70651 Matched English Canada
421 Osborne (8080) > WB Gloss Level 3 Pearl WHMIS
Building Painters Shop Deep Base

Transit Dept (8050) > Ultra Low VOC Ecologic Cloverdale Paint Inc. 70653 Matched English Canada
421 Osborne (8080) > WB Gloss Level 3 Pearl WHMIS
Building Painters Shop White Base
Transit Dept (8050) > Ultra Low VOC Ecologic Cloverdale Paint Inc. 70621 Matched English Canada
421 Osborne (8080) > WB Gloss Level 5 Semi WHMIS
Building Painters Shop Gloss Deep Base

Transit Dept (8050) > Ultra Low Voc Ecologic Cloverdale Paint Inc. 70624 Matched English Canada
421 Osborne (8080) > WB Gloss Level 5 Semi WHMIS
Building Painters Shop Gloss Neutral Base

Transit Dept (8050) > Ultra Low Voc Ecologic Cloverdale Paint Inc. 70623 Matched English Canada
421 Osborne (8080) > WB Gloss Level 5 Semi WHMIS
Building Painters Shop Gloss White Base

Transit Dept (8050) > Ultra Low Voc Ecologic Cloverdale Paint Inc. 70601 Matched English Canada
421 Osborne (8080) > WB Gloss Level 6 WHMIS
Building Painters Shop Gloss Deep Base

Transit Dept (8050) > VHT FlameProof VHT Products Co. SP104 Matched English Canada
421 Osborne (8080) > Coating 1300-2000F WHMIS
Building Painters Shop (704-1093C) - Serosol,
Flat Gray
Transit Dept (8050) > W/R Epoxy Topcoat PPG Industries 98-56 Matched English Canada
421 Osborne (8080) > Midtone Base Architectural Finishes WHMIS
Building Painters Shop

Transit Dept (8050) > WD-40 Bulk Liquid WD 40 Products Matched English Canada
421 Osborne (8080) > Canada Ltd. WHMIS
Building Painters Shop

Transit Dept (8050) > WDCARE QT 6PK Rust-Oleum 66941 Matched English Canada
421 Osborne (8080) > WATCO Dark Satin Fin Corporation WHMIS
Building Painters Shop Wax

Transit Dept (8050) > Windex Original Glass Diversey Inc. 350000014153 Matched English Canada
421 Osborne (8080) > Cleaner with Ammonia- WHMIS
Building Painters Shop D

Transit Dept (8050) > Zep Spirit II Ready-To- Zep Manufacturing 0679 Matched English Canada
421 Osborne (8080) > Use Detergent Company of Canada WHMIS
Building Painters Shop Disinfectant
Transit Dept (8050) > Loctite 754 Extended Henkel Australia Pty Ltd In Progress English Canada
421 Osborne (8080) > Rust Treatment WHMIS
Building Painters Shop

Transit Dept (8050) > 03405-2100 38-2100-2 K-G Packaging - Spray Matched English Canada
421 Osborne (8080) > Quick Start Starting Pak WHMIS
Carpentry Shop Fluid 311G
Transit Dept (8050) > AcrylPro Ceramic Tile Custom Building Matched English Canada
421 Osborne (8080) > Adhesive Products Inc. WHMIS
Carpentry Shop
Transit Dept (8050) > Black Knight Certified Labs, Div. of 0638 Matched English Canada
421 Osborne (8080) > NCH Corp. WHMIS
Carpentry Shop
Transit Dept (8050) > Concrete Bonding Quikrete Companies 9902 Matched English Canada
421 Osborne (8080) > Adhesive WHMIS
Carpentry Shop
Transit Dept (8050) > Crown 8034 General Aervoe Industries Inc Matched English Canada
421 Osborne (8080) > Purpose Silicone WHMIS
Carpentry Shop Lubricant
Transit Dept (8050) > Debba Industrial Deb USA, Inc 42131 Matched English Canada
421 Osborne (8080) > Protective Cream WHMIS
Carpentry Shop
Transit Dept (8050) > Dupli-Color Automotive Sherwin-Williams BG600 Matched English Canada
421 Osborne (8080) > Finish, Super Black WHMIS
Carpentry Shop
Transit Dept (8050) > Dupli-Color Enamel Sherwin Williams DA1600 Matched English Canada
421 Osborne (8080) > Paint, Gloss Black WHMIS
Carpentry Shop (OSHA)
Transit Dept (8050) > DUPLI-COLOR Dupli-Color Products DAP1692 Matched English Canada
421 Osborne (8080) > Sandable Primer, Gray WHMIS
Carpentry Shop Hot Rod
Transit Dept (8050) > Dynaflex 230 - Colors Dap Canada Inc. 070798740822 Matched English Canada
421 Osborne (8080) > WHMIS
Carpentry Shop
Transit Dept (8050) > Elmer's Carpenter's Elmer's Products, Inc. E9010 Matched English Canada
421 Osborne (8080) > Wood Filler-MAX WHMIS
Carpentry Shop
Transit Dept (8050) > Facto Hd40 Swish Maintenance Ltd. 5840 Matched English Canada
421 Osborne (8080) > WHMIS
Carpentry Shop
Transit Dept (8050) > Fast dry enamel PEINTURES J.C.96 PJC-103-M-S Matched English Canada
421 Osborne (8080) > metallic color satin WHMIS
Carpentry Shop gloss in aerosol
Transit Dept (8050) > Gojo Natural Orange GOJO Industries, Inc. 0956-04 Matched English Canada
421 Osborne (8080) > Pumice Hand Cleaner WHMIS
Carpentry Shop
Transit Dept (8050) > Goo Gone Liquid Goo Gone 2098C, 2088C, 2065C, Matched English Canada
421 Osborne (8080) > 2050C WHMIS
Carpentry Shop
Transit Dept (8050) > GSI Amine STONHARD, DIVISION 72203/A Matched English Canada
421 Osborne (8080) > OF STONCOR WHMIS
Carpentry Shop GROUP, INC

Transit Dept (8050) > Henry 203 Roll Roofing Henry Company Matched English Canada
421 Osborne (8080) > Adhesive WHMIS
Carpentry Shop
Transit Dept (8050) > Homax Grout and Homax Products 9540 Matched English Canada
421 Osborne (8080) > Stone Sealer, WHMIS
Carpentry Shop Waterbased Aerosol
Transit Dept (8050) > Industrial Choice Rust Oleum 239007 Matched English Canada
421 Osborne (8080) > Aerosol - Solvent Based Corporation WHMIS
Carpentry Shop Inverted Marking Paint

Transit Dept (8050) > Johnsens Brake Parts Technical Chemical 2420 Matched English Canada
421 Osborne (8080) > Cleaner Company WHMIS
Carpentry Shop
Transit Dept (8050) > Lps Noflash Electro LPS Laboratories Inc. 04016 Matched English Canada
421 Osborne (8080) > Contact Cleaner WHMIS
Carpentry Shop
Transit Dept (8050) > Meadow-Patch T1 W. R. Meadows Inc 8211000 Matched English Canada
421 Osborne (8080) > WHMIS
Carpentry Shop
Transit Dept (8050) > Minwax Stainable Sherwin Williams 4285- Matched English Canada
421 Osborne (8080) > Wood Filler WHMIS
Carpentry Shop
Transit Dept (8050) > Miracle Lumber Lock ITW TACC International Matched English Canada
421 Osborne (8080) > Adhesive Corp. WHMIS
Carpentry Shop
Transit Dept (8050) > Moovit (Aerosol) Lloyds Laboratories Inc. 11008 Matched English Canada
421 Osborne (8080) > WHMIS
Carpentry Shop
Transit Dept (8050) > New Rapid Tap Relton Corporation Matched English Canada
421 Osborne (8080) > WHMIS
Carpentry Shop
Transit Dept (8050) > OMNI-PAK THE SHERWIN- DV6, DV12, DV16 Matched English Canada
421 Osborne (8080) > MasterBlend EZ WILLIAMS COMPANY WHMIS
Carpentry Shop TOUCH (DV Cans)
Transit Dept (8050) > Pennzoil GT SOPUS Products Matched English Canada
421 Osborne (8080) > Performance Racing WHMIS
Carpentry Shop Motor Oil SAE 25W-50

Transit Dept (8050) > PolyBlend Sanded Custom Building Matched English Canada
421 Osborne (8080) > Grout Products Inc. WHMIS
Carpentry Shop
Transit Dept (8050) > Portland Cement Based Quikrete Companies Matched English Canada
421 Osborne (8080) > Concrete Products WHMIS
Carpentry Shop
Transit Dept (8050) > Powerhold 5500 Cove Powerhold Matched English Canada
421 Osborne (8080) > Base Adhesive WHMIS
Carpentry Shop
Transit Dept (8050) > Roof Cement Gibson Homans Co 182470 Matched English Canada
421 Osborne (8080) > WHMIS
Carpentry Shop
Transit Dept (8050) > Seal Cure /18 (VOC) W. R. Meadows of 3582-000 Matched English Canada
421 Osborne (8080) > Canada WHMIS
Carpentry Shop
Transit Dept (8050) > Severe Weather Henry Company Matched English Canada
421 Osborne (8080) > Superior Roof Repair WHMIS
Carpentry Shop
Transit Dept (8050) > Sikaflex 252 Sika Corporation 604270 Matched English Canada
421 Osborne (8080) > WHMIS
Carpentry Shop
Transit Dept (8050) > Sikaflex Self-Leveling Sika Canada AQ 191 A Matched English Canada
421 Osborne (8080) > Sealant WHMIS
Carpentry Shop
Transit Dept (8050) > SikaGrout 212 Sika Canada Inc. Matched English Canada
421 Osborne (8080) > WHMIS
Carpentry Shop
Transit Dept (8050) > SpeedSet Fortified Thin- Custom Building 010186302805 Matched English Canada
421 Osborne (8080) > Set Mortar (Gray / Products Inc. WHMIS
Carpentry Shop White)
Transit Dept (8050) > Stanley Chalks Stanley Works Matched English Canada
421 Osborne (8080) > WHMIS
Carpentry Shop
Transit Dept (8050) > Straitline Marking Chalk Irwin Industrial Tool 77007 Matched English Canada
421 Osborne (8080) > Blue Company Pty Ltd WHMIS
Carpentry Shop
Transit Dept (8050) > Structo-Lite Basecoat USG Corporation Matched English Canada
421 Osborne (8080) > Plaster WHMIS
Carpentry Shop
Transit Dept (8050) > Super Lube 11 OZ Dri- Synco Chemical 11016 Matched English Canada
421 Osborne (8080) > Film Lubricant with Corporation WHMIS
Carpentry Shop Syncolon PTFE
Transit Dept (8050) > Sure-Steptm W.R. Meadows of 3050-340 Matched English Canada
421 Osborne (8080) > Western Canada WHMIS
Carpentry Shop
Transit Dept (8050) > Synko Dust Control CGC Inc (A USG Matched English Canada
421 Osborne (8080) > Drywall Compound Company) WHMIS
Carpentry Shop
Transit Dept (8050) > Synko Lite Joint CGC Inc (A USG Matched English Canada
421 Osborne (8080) > Company) WHMIS
Carpentry Shop
Transit Dept (8050) > Tandus Centiva C-36E Tandus Centiva Matched English Canada
421 Osborne (8080) > Floor Primer WHMIS
Carpentry Shop
Transit Dept (8050) > The Wave Urinal Fresh Products Inc. RWDS10xx, WDS10xx, Matched English Canada
421 Osborne (8080) > Deodorizer WDS100xx WHMIS
Carpentry Shop
Transit Dept (8050) > Ultrabond Eco 575 Mapei Corporation Matched English Canada
421 Osborne (8080) > WHMIS
Carpentry Shop
Transit Dept (8050) > Ultramarine Blue Nubiola UMB/US01 Matched English Canada
421 Osborne (8080) > WHMIS
Carpentry Shop
Transit Dept (8050) > Zep Spirit II Ready-To- Zep Manufacturing 0679 Matched English Canada
421 Osborne (8080) > Use Detergent Company of Canada WHMIS
Carpentry Shop Disinfectant
Transit Dept (8050) > 101Eu Film Forming Oil Center Research Matched English Canada
421 Osborne (8080) > Lubricant Inc. WHMIS
Machine Shop
Transit Dept (8050) > 34A Valve Grinding Permatex Canada 80036 Matched English Canada
421 Osborne (8080) > Compound 1.5oz WHMIS
Machine Shop
Transit Dept (8050) > 39143 Trim Black Sem Products Inc. 39143 Matched English Canada
421 Osborne (8080) > WHMIS
Machine Shop
Transit Dept (8050) > 3D Aviation Form-A- Permatex USA 80017 Matched English Canada
421 Osborne (8080) > Gasket #3 Sealant 1PT WHMIS
Machine Shop
Transit Dept (8050) > 3M Super Foam Fast 3M Canada Inc. 62-4950-4935-5 Matched English Canada
421 Osborne (8080) > Spray Adhesive 74, WHMIS
Machine Shop Clear
Transit Dept (8050) > 404 Quick Set Instant Henkel Loctite Canada 135465 Matched English Canada
421 Osborne (8080) > Adhesive Inc. WHMIS
Machine Shop
Transit Dept (8050) > A9 Aluminum Cutting Relton Corporation Matched English Canada
421 Osborne (8080) > Fluid WHMIS
Machine Shop
Transit Dept (8050) > AeroShell Oil W 15W- Shell Canada Products 001A9612 Matched English Canada
421 Osborne (8080) > 50 Ltd. WHMIS
Machine Shop
Transit Dept (8050) > Air Tool Oil Kleen-Flo Tumbler 4168 Matched English Canada
421 Osborne (8080) > Industries Ltd. WHMIS
Machine Shop
Transit Dept (8050) > Alcohol Free Towelettes Allegro Industries 3001 Matched English Canada
421 Osborne (8080) > WHMIS
Machine Shop
Transit Dept (8050) > Aromx 60 Swish Maintenance Ltd. 8960 Matched English Canada
421 Osborne (8080) > WHMIS
Machine Shop
Transit Dept (8050) > BD1077 Heavy Load American Jetway 0718-63 Matched English Canada
421 Osborne (8080) > Red Grease WHMIS
Machine Shop
Transit Dept (8050) > BD7-77 Plus Penetrant Barnes Group Inc. BD1108 Matched English Canada
421 Osborne (8080) > WHMIS
Machine Shop
Transit Dept (8050) > Biowash 2000 Prairie West Industrial Matched English Canada
421 Osborne (8080) > Ltd. WHMIS
Machine Shop
Transit Dept (8050) > Blue Steel Ink Aerosol DoALL Cutting Fluids F02378 Matched English Canada
421 Osborne (8080) > WHMIS
Machine Shop
Transit Dept (8050) > Bon Ami Power Foam Diversey Inc. Matched English Canada
421 Osborne (8080) > Glass Cleaner WHMIS
Machine Shop
Transit Dept (8050) > Brake & Parts Cleaner Würth Canada Limitée Matched English Canada
421 Osborne (8080) > 408gr - 890.9107 WHMIS
Machine Shop
Transit Dept (8050) > CB 100 J. Walter Company Ltd. 53-G 167 Matched English Canada
421 Osborne (8080) > WHMIS
Machine Shop
Transit Dept (8050) > Compressor Oil 460 Esso Petroleum Matched English Canada
421 Osborne (8080) > Canada WHMIS
Machine Shop
Transit Dept (8050) > Crankcase Oil ISO 68 Cat Pumps Matched English Canada
421 Osborne (8080) > Special Formula WHMIS
Machine Shop Premium Grade
Transit Dept (8050) > Crown 8034 General Aervoe Industries Inc Matched English Canada
421 Osborne (8080) > Purpose Silicone WHMIS
Machine Shop Lubricant
Transit Dept (8050) > Cut+Cool Cutting and Würth Canada Limitée 893.050012 Matched English Canada
421 Osborne (8080) > Drilling Oil Eco 5L WHMIS
Machine Shop
Transit Dept (8050) > D-15* Insect Repellent Amway Corporation Matched English Canada
421 Osborne (8080) > WHMIS
Machine Shop
Transit Dept (8050) > DEVCON Titanium ITW Polymers 10760 Matched English Canada
421 Osborne (8080) > Putty Adhesives WHMIS
Machine Shop
Transit Dept (8050) > Dow Corning 4 Dow Corning Matched English Canada
421 Osborne (8080) > Electrical Insulating Corporation / Styron WHMIS
Machine Shop Compound LLC
Transit Dept (8050) > Dry All Origination Matched English Canada
421 Osborne (8080) > WHMIS
Machine Shop
Transit Dept (8050) > Dupli-Color Acrylic Dupli-Color Products DAL1607 Matched English Canada
421 Osborne (8080) > Lacquer Aerosol Paint, WHMIS
Machine Shop Flat Black
Transit Dept (8050) > Dupli-Color Enamel Sherwin Williams DA1600 Matched English Canada
421 Osborne (8080) > Paint, Gloss Black WHMIS
Machine Shop (OSHA)
Transit Dept (8050) > Dupli-Color Enamel Sherwin Williams DA1670 Matched English Canada
421 Osborne (8080) > Paint, Gloss White WHMIS
Machine Shop (OSHA White)
Transit Dept (8050) > Dupli-Color Engine Sherwin Williams DE1605 Matched English Canada
421 Osborne (8080) > Enamel With Ceramic, WHMIS
Machine Shop Ford Red
Transit Dept (8050) > Dupli-Color Primer Sherwin Williams DAP1699 Matched English Canada
421 Osborne (8080) > Sealer, Gray WHMIS
Machine Shop
Transit Dept (8050) > Dykem Transparent ITW Pro Brands 80000 Matched English Canada
421 Osborne (8080) > Stain Aerosol - Steel WHMIS
Machine Shop Blue and Steel Red
Transit Dept (8050) > Envy Foaming Diversey Lever Matched English Canada
421 Osborne (8080) > Disinfectant Cleaner WHMIS
Machine Shop
Transit Dept (8050) > Extend(R) Rust Henkel Corp 37557 Matched English Canada
421 Osborne (8080) > Treatment WHMIS
Machine Shop
Transit Dept (8050) > Fluid Film Aerosol (AS) Eureka Chemical Matched English Canada
421 Osborne (8080) > Company WHMIS
Machine Shop
Transit Dept (8050) > Glance Foaming Glass Johnson Diversey 04553 Matched English Canada
421 Osborne (8080) > & Multi-Surface Cleaner WHMIS
Machine Shop
Transit Dept (8050) > Gojo Original Formula GOJO Industries, Inc. Matched English Canada
421 Osborne (8080) > Hand Cleaner WHMIS
Machine Shop
Transit Dept (8050) > HHS 5000 500ml Würth Canada Limitée 893-1063 Matched English Canada
421 Osborne (8080) > WHMIS
Machine Shop
Transit Dept (8050) > High Build Undercoat Würth Canada Limitée 890.9072 Matched English Canada
421 Osborne (8080) > 550G. Paintable - WHMIS
Machine Shop 890.9072
Transit Dept (8050) > Hydrex Mv 22, 36, 60 Petro-Canada 490-110 Matched English Canada
421 Osborne (8080) > WHMIS
Machine Shop
Transit Dept (8050) > Johnsens Brake Parts Technical Chemical 2420 Matched English Canada
421 Osborne (8080) > Cleaner Company WHMIS
Machine Shop
Transit Dept (8050) > Kolor Kut Water Finding Kolor Kut Products Matched English Canada
421 Osborne (8080) > Paste Company WHMIS
Machine Shop
Transit Dept (8050) > Kopr-Kote Thermal Jet Lube of Canada Ltd. Matched English Canada
421 Osborne (8080) > Grade WHMIS
Machine Shop
Transit Dept (8050) > Lemon Kleen Prairie West Industrial Matched English Canada
421 Osborne (8080) > Ltd. WHMIS
Machine Shop
Transit Dept (8050) > Loctite 222Ms Henkel Loctite Canada 135334 Matched English Canada
421 Osborne (8080) > Threadlocker Inc. WHMIS
Machine Shop
Transit Dept (8050) > Loctite 242 Henkel Loctite Canada 135355 Matched English Canada
421 Osborne (8080) > Threadlocker Inc. WHMIS
Machine Shop
Transit Dept (8050) > Loctite 262 Henkel Loctite Canada 26221 Matched English Canada
421 Osborne (8080) > Threadlocker High Inc. WHMIS
Machine Shop Strength
Transit Dept (8050) > Loctite 515 Gasket Henkel Loctite Canada 51531 Matched English Canada
421 Osborne (8080) > Eliminator Flange Inc. WHMIS
Machine Shop Sealant Part No. 51531

Transit Dept (8050) > Loctite 518 Henkel Limited 153476 Matched English Canada
421 Osborne (8080) > WHMIS
Machine Shop
Transit Dept (8050) > Loctite 567 PST Pipe Henkel Loctite Canada 56747 Matched English Canada
421 Osborne (8080) > Sealant with PTFE Inc. WHMIS
Machine Shop Thread Sealant Part
No. 56747
Transit Dept (8050) > Loctite 609 Retaining Henkel Loctite Canada 135512 Matched English Canada
421 Osborne (8080) > Compound Press Fit Inc. WHMIS
Machine Shop
Transit Dept (8050) > Loctite 620 Retaining Henkel Loctite Canada 135514 Matched English Canada
421 Osborne (8080) > Compound Slip Fit Inc. WHMIS
Machine Shop
Transit Dept (8050) > Loctite 680 Retaining Henkel Loctite Canada 68035 Matched English Canada
421 Osborne (8080) > Compound Slip Fit Inc. WHMIS
Machine Shop
Transit Dept (8050) > Loctite 754 Extend Henkel Corporation 234981 Matched English Canada
421 Osborne (8080) > WHMIS
Machine Shop
Transit Dept (8050) > Loctite MR 5414 Black Henkel Loctite Canada 234930 Matched English Canada
421 Osborne (8080) > Contact Adhesive Inc. WHMIS
Machine Shop Known As Loctite Black
Contact Adhesiv

Transit Dept (8050) > Loctite SF 7070 known Henkel Limited Matched English Canada
421 Osborne (8080) > as Loctite 7070 WHMIS
Machine Shop
Transit Dept (8050) > Loctite SI 587 known as Henkel Loctite Canada 234590 Matched English Canada
421 Osborne (8080) > Loctite 587 300ml EN Inc. WHMIS
Machine Shop
Transit Dept (8050) > loctite SI 5900 Instant Henkel Corporation 40479 Matched English Canada
421 Osborne (8080) > Gasket Known As WHMIS
Machine Shop Instant Gasket 190ml
AE
Transit Dept (8050) > Loctite Sil CB GRS 280 Henkel Corporation 232872 Matched English Canada
421 Osborne (8080) > GR known as Loctite WHMIS
Machine Shop 39401 280 Grit-> End
MSDS/Lable Name

Transit Dept (8050) > Loctite Silver Grade Henkel Loctite Canada 76759 Matched English Canada
421 Osborne (8080) > Anti-Seize Inc. WHMIS
Machine Shop
Transit Dept (8050) > LPS 1 (Aerosol) LPS Laboratories Inc. C30116 Matched English Canada
421 Osborne (8080) > WHMIS
Machine Shop
Transit Dept (8050) > LPS 3 Premier Rust LPS Laboratories Inc. 00316 Matched English Canada
421 Osborne (8080) > Inhibitor Aerosol WHMIS
Machine Shop
Transit Dept (8050) > LPS F-104 (Aerosol) ITW Pro Brands 04920 Matched English Canada
421 Osborne (8080) > WHMIS
Machine Shop
Transit Dept (8050) > LPS NoFlash NU ITW Pro Brands C04015 Matched English Canada
421 Osborne (8080) > WHMIS
Machine Shop
Transit Dept (8050) > LPS Tapmatic TriCut LPS Laboratories Inc. 05316 Matched English Canada
421 Osborne (8080) > WHMIS
Machine Shop
Transit Dept (8050) > Lubriplate 105 Lubriplate Lubricants Matched English Canada
421 Osborne (8080) > Co WHMIS
Machine Shop
Transit Dept (8050) > Magic Non Alcohol Braco Manufacturing / ST100BN Matched English Canada
421 Osborne (8080) > Hygenic Cleansing Fluid Magic Safety Products WHMIS
Machine Shop
Transit Dept (8050) > Manus Impact Beads Potters Industries Inc. Matched English Canada
421 Osborne (8080) > WHMIS
Machine Shop
Transit Dept (8050) > Masters 770 Yellow GF Thompson Co. Ltd. Matched English Canada
421 Osborne (8080) > Low Voc Cement for WHMIS
Machine Shop Plastic Pipe
Transit Dept (8050) > Masters Metallic GF Thompson Co. Ltd. Matched English Canada
421 Osborne (8080) > Compound WHMIS
Machine Shop
Transit Dept (8050) > MOBIL VACTRA OIL Imperial Oil Products 8303 Matched English Canada
421 Osborne (8080) > NO. 2 (FEBIS K 68) Division WHMIS
Machine Shop
Transit Dept (8050) > Moovit (Aerosol) Lloyds Laboratories Inc. 11008 Matched English Canada
421 Osborne (8080) > WHMIS
Machine Shop
Transit Dept (8050) > Never-Seez Regular Bostik Findley Inc. Matched English Canada
421 Osborne (8080) > Grade Cmpd. WHMIS
Machine Shop
Transit Dept (8050) > New Rapid Tap Relton Corporation Matched English Canada
421 Osborne (8080) > WHMIS
Machine Shop
Transit Dept (8050) > Nuflex 302 High Nuco Inc. Matched English Canada
421 Osborne (8080) > Temperature Gasket WHMIS
Machine Shop Making Silicone Sealant
Transit Dept (8050) > Oatey Candian PVC Oatey Co. 31505 Matched English Canada
421 Osborne (8080) > Medium Clear or Grey WHMIS
Machine Shop Cement
Transit Dept (8050) > Omni J. Walter Company Ltd. 53-X 003 Matched English Canada
421 Osborne (8080) > WHMIS
Machine Shop
Transit Dept (8050) > One Step Hand Belvedere International Matched English Canada
421 Osborne (8080) > Sanitizer Incorporated WHMIS
Machine Shop
Transit Dept (8050) > Opti-Mizer Interlube International Matched English Canada
421 Osborne (8080) > Inc. WHMIS
Machine Shop
Transit Dept (8050) > Osborn Blue Layout Osborn International M5715 Matched English Canada
421 Osborne (8080) > Fluid 76214 WHMIS
Machine Shop
Transit Dept (8050) > Personal Respirator Allegro Industries 1001, 1001-05, 1001-10 Matched English Canada
421 Osborne (8080) > Cleaning Pad WHMIS
Machine Shop
Transit Dept (8050) > Petrosol 3139 Sunoco Inc, A Division 101803 Matched English Canada
421 Osborne (8080) > of Suncor Energy WHMIS
Machine Shop
Transit Dept (8050) > PF 500 Non-Paintable Pro-Form Products Ltd. PF 500 Matched English Canada
421 Osborne (8080) > Rubberized Undercoat WHMIS
Machine Shop
Transit Dept (8050) > PowerFist Air Tool Oil Nemco Resources 5059 Matched English Canada
421 Osborne (8080) > WHMIS
Machine Shop
Transit Dept (8050) > Propane Worthington Cylinder Matched English Canada
421 Osborne (8080) > Corporation WHMIS
Machine Shop
Transit Dept (8050) > Protective Cream 311 West Penetone Inc. Matched English Canada
421 Osborne (8080) > WHMIS
Machine Shop
Transit Dept (8050) > Pyro-Chem ABC Tyco Fire Protection 2001-2-012 ANa Matched English Canada
421 Osborne (8080) > Products WHMIS
Machine Shop
Transit Dept (8050) > QD Electronic Cleaner CRC Industries 75012 Matched English Canada
421 Osborne (8080) > (Aerosol) WHMIS
Machine Shop
Transit Dept (8050) > Resinoid Bonded United Abrasives, Inc. Matched English Canada
421 Osborne (8080) > Abrasives WHMIS
Machine Shop
Transit Dept (8050) > Respiratory Fluid with Braco Manufacturing / CN30DNA Matched English Canada
421 Osborne (8080) > Alcohol Magic Safety Products WHMIS
Machine Shop
Transit Dept (8050) > Rubber Care Stick Wurth Australia Pty Ltd. 0893 012 8 Matched English Canada
421 Osborne (8080) > WHMIS
Machine Shop
Transit Dept (8050) > Safety Wash Cleaner MG Chemicals Ltd. 4050-1L Matched English Canada
421 Osborne (8080) > Degreaser WHMIS
Machine Shop
Transit Dept (8050) > Shell Gadus S4 Shell Canada Products 001E0213 Matched English Canada
421 Osborne (8080) > V600AC 1.5 Ltd. WHMIS
Machine Shop
Transit Dept (8050) > Shell Spirax S6 ATF Shell Oil Products 001D8305 Matched English Canada
421 Osborne (8080) > A295 WHMIS
Machine Shop
Transit Dept (8050) > Sikaflex-252 Sika Canada Inc. Matched English Canada
421 Osborne (8080) > WHMIS
Machine Shop
Transit Dept (8050) > Smoke Screen Aerosol Zep Manufacturing 0187 Matched English Canada
421 Osborne (8080) > Company of Canada WHMIS
Machine Shop
Transit Dept (8050) > Speclt Sspr 6Pk Farm Rust Oleum 7449830 Matched English Canada
421 Osborne (8080) > Yellow (Caterpillar Corporation WHMIS
Machine Shop
Transit Dept (8050) > Sterling Wunrub 83 Johnson Diversey 2050020 Matched English Canada
421 Osborne (8080) > WHMIS
Machine Shop
Transit Dept (8050) > Stokolan Classsic Deb-Stoko USA LLC Matched English Canada
421 Osborne (8080) > WHMIS
Machine Shop
Transit Dept (8050) > Stokolan intensive Deb Matched English Canada
421 Osborne (8080) > repair WHMIS
Machine Shop
Transit Dept (8050) > STP Oil Treatment The Armor All / STP Matched English Canada
421 Osborne (8080) > Products Company WHMIS
Machine Shop
Transit Dept (8050) > Super Duster 134 and MG Chemicals Ltd. 402A-140G Matched English Canada
421 Osborne (8080) > Super Duster 134 Plus WHMIS
Machine Shop
Transit Dept (8050) > Super Lube Multi- Synco Chemical Matched English Canada
421 Osborne (8080) > Purpose Synthetic Corporation WHMIS
Machine Shop Grease with Syncolon
(PTFE)
Transit Dept (8050) > Syngard FS 75W90 Martin Lubricants 571209 Matched English Canada
421 Osborne (8080) > Limited Slip Blend WHMIS
Machine Shop
Transit Dept (8050) > Ten Minute Rad Flush Kleen-Flo Tumbler 708 Matched English Canada
421 Osborne (8080) > Industries Ltd. WHMIS
Machine Shop
Transit Dept (8050) > TEROSON SI 9160 CL Henkel Corporation 475372 Matched English Canada
421 Osborne (8080) > known as SILATECH WHMIS
Machine Shop SILICONE SEALANT
IND
Transit Dept (8050) > Travabon Stockhausen Inc. Matched English Canada
421 Osborne (8080) > WHMIS
Machine Shop
Transit Dept (8050) > Trim Black PPG Coatings and SXA9000 Matched English Canada
421 Osborne (8080) > Resins WHMIS
Machine Shop
Transit Dept (8050) > Trim Tap NC Master Chemical Matched English Canada
421 Osborne (8080) > Corporation WHMIS
Machine Shop
Transit Dept (8050) > Ultra Coolant Ingersoll Rand 38459582 Matched English Canada
421 Osborne (8080) > WHMIS
Machine Shop
Transit Dept (8050) > Uno S V J. Walter Company Ltd. 53-G 053 Matched English Canada
421 Osborne (8080) > WHMIS
Machine Shop
Transit Dept (8050) > Uvex Clear Lens Honeywell Safety S461 Matched English Canada
421 Osborne (8080) > Cleaner Products WHMIS
Machine Shop
Transit Dept (8050) > Victory Blue Victory Blue, Llc Matched English Canada
421 Osborne (8080) > WHMIS
Machine Shop
Transit Dept (8050) > Voltesso 35 Exxonmobil Canada 201580103030 Matched English Canada
421 Osborne (8080) > WHMIS
Machine Shop
Transit Dept (8050) > WD-40 Bulk Liquid WD 40 Products Matched English Canada
421 Osborne (8080) > Canada Ltd. WHMIS
Machine Shop
Transit Dept (8050) > Weld-On P-68 Low IPS Corp. Matched English Canada
421 Osborne (8080) > VOC Primer for PVC WHMIS
Machine Shop and CPVC Plastic Pipe

Transit Dept (8050) > White Petroleum Jelly Jedmon Products Matched English Canada
421 Osborne (8080) > USP Limited WHMIS
Machine Shop
Transit Dept (8050) > Windex Original Glass Diversey Inc. 350000014153 Matched English Canada
421 Osborne (8080) > Cleaner with Ammonia- WHMIS
Machine Shop D
Transit Dept (8050) > Windex Powerized Johnson Diversey 90129 Matched English Canada
421 Osborne (8080) > Foaming Glass Cleaner WHMIS
Machine Shop (Aerosol)
Transit Dept (8050) > Xk2 Zep Manufacturing 6745 Matched English Canada
421 Osborne (8080) > Company of Canada WHMIS
Machine Shop
Transit Dept (8050) > Zep Spirit II Ready-To- Zep Manufacturing 0679 Matched English Canada
421 Osborne (8080) > Use Detergent Company of Canada WHMIS
Machine Shop Disinfectant
Transit Dept (8050) > ZL-W01 Pentel of America Ltd Matched English Canada
421 Osborne (8080) > WHMIS
Machine Shop
Transit Dept (8050) > 104000 Mulco Supra Akzo Nobel Matched English Canada
421 Osborne (8080) > Expert WHMIS
Stores - Transit
(CWIN90)
Transit Dept (8050) > 2.1 EPOXY PRIMER PPG Industries DP90LV Matched English Canada
421 Osborne (8080) > BLACK WHMIS
Stores - Transit
(CWIN90)
Transit Dept (8050) > 2.1 EPOXY PRIMER PPG Industries DP50LV Matched English Canada
421 Osborne (8080) > GRAY WHMIS
Stores - Transit
(CWIN90)
Transit Dept (8050) > 2.1 Epoxy Primer White PPG Automotive DP48LV Matched English Canada
421 Osborne (8080) > Refinish WHMIS
Stores - Transit
(CWIN90)
Transit Dept (8050) > 2319S Lacquer DuPont Chemicals 2319S Matched English Canada
421 Osborne (8080) > Thinners and Cleaning WHMIS
Stores - Transit Solvents
(CWIN90)
Transit Dept (8050) > 245 Core SN63Pb37 Litton Kester Solder Matched English Canada
421 Osborne (8080) > WHMIS
Stores - Transit
(CWIN90)
Transit Dept (8050) > 247; 5/95; 30/70 ASTM The Canada Metal Matched English Canada
421 Osborne (8080) > 30 A, B, C; 40/60 ASTM Company WHMIS
Stores - Transit 40 A, B; 50/50 ASTM A,
(CWIN90) B;
Transit Dept (8050) > 2-6 Casting Alloy, 15/85 The Canada Metal Matched English Canada
421 Osborne (8080) > ASTM 15B, 20/80 Company WHMIS
Stores - Transit ASTM 20 B, 25/75
(CWIN90) ASTM 30 A B, 30/70,
34/66, 35/65, 45/55
ASTM A B, Pirellie, "E"
Alloy
Transit Dept (8050) > 39101; 39104 Flexible Sem Products Inc. 39101 Matched English Canada
421 Osborne (8080) > Bumper Coater WHMIS
Stores - Transit
(CWIN90)
Transit Dept (8050) > 39103 Flexible Bumper Sem Products Inc. 39103 Matched English Canada
421 Osborne (8080) > Coater WHMIS
Stores - Transit
(CWIN90)
Transit Dept (8050) > 3-in-one Multi-purpose WD-40 Company Matched English Canada
421 Osborne (8080) > Oil WHMIS
Stores - Transit
(CWIN90)
Transit Dept (8050) > 3M Bondo Red Cream 3M General Office LB-K100-0415-4 Matched English Canada
421 Osborne (8080) > Hardener 307, 913, WHMIS
Stores - Transit 913M, 913C, 913ES,
(CWIN90) 928, 928C, 9307,
7653079, 810505D,
510506D, 810507D
Transit Dept (8050) > 3M Brand Contact 3M Canada Inc. CS-0406-1444-1 Matched English Canada
421 Osborne (8080) > Adhesive 10 WHMIS
Stores - Transit Neutral/Brushable (EC-
(CWIN90) 2166) (Inactive)
Transit Dept (8050) > 3M Brand Ten Bond 3M Canada Inc. CS-0406-2181-8 Matched English Canada
421 Osborne (8080) > Contact Cement WHMIS
Stores - Transit
(CWIN90)
Transit Dept (8050) > 3M Dynatron Blue 3M General Office LB-K100-0514-3 Matched English Canada
421 Osborne (8080) > Cream Hardener 4B, 8, WHMIS
Stores - Transit 309, 30753, 9307G
(CWIN90)
Transit Dept (8050) > 3M Dynatron Fiberglass 3M General Office 70-0080-0039-7 Matched English Canada
421 Osborne (8080) > Resin, P.N. 692, 694 WHMIS
Stores - Transit
(CWIN90)
Transit Dept (8050) > 3M Dynatron Putty-Cote 3M General Office LB-K100-0587-6 Matched English Canada
421 Osborne (8080) > 592, 592T, 593 WHMIS
Stores - Transit
(CWIN90)
Transit Dept (8050) > 3M Perfect-It Foam 3M Canada Inc. 38109 Matched English Canada
421 Osborne (8080) > Polishing Pad Glaze - WHMIS
Stores - Transit Light PN 38109, 39109,
(CWIN90) 39109S, 39819

Transit Dept (8050) > 3M Scotch-Grip High 3M Canada Inc. 62-1357-2630-5 Matched English Canada
421 Osborne (8080) > Performance Contact WHMIS
Stores - Transit Adhesive 1357
(CWIN90)
Transit Dept (8050) > 3M Super Duty Rubbing 3M Canada Inc. 5954 Matched English Canada
421 Osborne (8080) > Compound PN 5954 WHMIS
Stores - Transit 5955 5956 39004
(CWIN90)
Transit Dept (8050) > 404 Quick Set Instant Henkel Loctite Canada 135465 Matched English Canada
421 Osborne (8080) > Adhesive Inc. WHMIS
Stores - Transit
(CWIN90)
Transit Dept (8050) > 44 Core Litton Kester Solder Matched English Canada
421 Osborne (8080) > SN96.5AG3.0CU0.5 WHMIS
Stores - Transit
(CWIN90)
Transit Dept (8050) > 44 Resin Litton Kester Solder 44 Matched English Canada
421 Osborne (8080) > WHMIS
Stores - Transit
(CWIN90)
Transit Dept (8050) > 470 Featherspray Sluyter Company Ltd. Matched English Canada
421 Osborne (8080) > WHMIS
Stores - Transit
(CWIN90)
Transit Dept (8050) > 476 Spray Adhesive Sluyter Company Ltd. Matched English Canada
421 Osborne (8080) > WHMIS
Stores - Transit
(CWIN90)
Transit Dept (8050) > 567 Thread Sealant Pst Henkel Loctite Canada 234460 Matched English Canada
421 Osborne (8080) > Pipe Sealant with Ptfe Inc. WHMIS
Stores - Transit
(CWIN90)
Transit Dept (8050) > 660 Quick Metal Henkel Loctite Canada 135527 Matched English Canada
421 Osborne (8080) > Retaining Compound Inc. WHMIS
Stores - Transit
(CWIN90)
Transit Dept (8050) > 68034 - Crown Silicone Aervoe Industries 85-68034-3 (80646X) Matched English Canada
421 Osborne (8080) > Lubricant Canada WHMIS
Stores - Transit
(CWIN90)
Transit Dept (8050) > 70% Isopropyl Alcohol Canadian Custom Matched English Canada
421 Osborne (8080) > Packaging WHMIS
Stores - Transit
(CWIN90)
Transit Dept (8050) > 7007 & 7011 Stamp Ink TCI Stamps Matched English Canada
421 Osborne (8080) > WHMIS
Stores - Transit
(CWIN90)
Transit Dept (8050) > A-125 (Liquid) Ecolab Ltd Matched English Canada
421 Osborne (8080) > WHMIS
Stores - Transit
(CWIN90)
Transit Dept (8050) > Accel Tb Wipes Virox Technologies Matched English Canada
421 Osborne (8080) > WHMIS
Stores - Transit
(CWIN90)
Transit Dept (8050) > Acrysol Body Solvent Lawson Products Inc P60170 Matched English Canada
421 Osborne (8080) > 16 Oz NW WHMIS
Stores - Transit
(CWIN90)
Transit Dept (8050) > Adora Lotion Hand Avmor Ltd. 1213 Matched English Canada
421 Osborne (8080) > Soap WHMIS
Stores - Transit
(CWIN90)
Transit Dept (8050) > Aervoe Survey Marking Aervoe Industries Inc. Matched English Canada
421 Osborne (8080) > Paint - Aerosol WHMIS
Stores - Transit (English)
(CWIN90)
Transit Dept (8050) > Air 1 Diesel Exhaust Recochem Inc. 55-124AIRH52 Matched English Canada
421 Osborne (8080) > Fluid WHMIS
Stores - Transit
(CWIN90)
Transit Dept (8050) > Air Tool Oil Kleen-Flo Tumbler 4168 Matched English Canada
421 Osborne (8080) > Industries Ltd. WHMIS
Stores - Transit
(CWIN90)
Transit Dept (8050) > Ajax Cleanser Colgate Palmolive Matched English Canada
421 Osborne (8080) > Canada WHMIS
Stores - Transit
(CWIN90)
Transit Dept (8050) > Aqua-Prep Low Voc Sherwin-Williams SC155 Matched English Canada
421 Osborne (8080) > Surface Cleaner Automotive Finishes WHMIS
Stores - Transit
(CWIN90)
Transit Dept (8050) > Arcair Air Carbon Arc Tweco/ArcairProducts 21-xx3-003 Matched English Canada
421 Osborne (8080) > Electrodes, Tweco Heat Inc. WHMIS
Stores - Transit Shrink Carbon
(CWIN90)
Transit Dept (8050) > Arctec 222 (AC-DC) Arctec Alloys Ltd. Matched English Canada
421 Osborne (8080) > WHMIS
Stores - Transit
(CWIN90)
Transit Dept (8050) > Armour Shield B Cloverdale Paint Inc. 83ARMB Matched English Canada
421 Osborne (8080) > Component WHMIS
Stores - Transit
(CWIN90)
Transit Dept (8050) > Aromx 60 Swish Maintenance Ltd. 8960 Matched English Canada
421 Osborne (8080) > WHMIS
Stores - Transit
(CWIN90)
Transit Dept (8050) > Autorf Sspr 6Pk Farm Rust Oleum 249275 Matched English Canada
421 Osborne (8080) > Yellow (John Deere) Corporation WHMIS
Stores - Transit (249275)
(CWIN90)
Transit Dept (8050) > AW 4715 Rockguard Pro-Form Products Ltd. Matched English Canada
421 Osborne (8080) > Black WHMIS
Stores - Transit
(CWIN90)
Transit Dept (8050) > BD1077 Red Grease Barnes Group Inc. A-6010 0718-63 Matched English Canada
421 Osborne (8080) > WHMIS
Stores - Transit
(CWIN90)
Transit Dept (8050) > BD1107 7-77 American Jetway 0718-28 Matched English Canada
421 Osborne (8080) > LUBRICANT-20 OZ WHMIS
Stores - Transit
(CWIN90)
Transit Dept (8050) > Bio-Circle L J. Walter Company Ltd. Matched English Canada
421 Osborne (8080) > WHMIS
Stores - Transit
(CWIN90)
Transit Dept (8050) > Biowash 2000 Prairie West Industrial Matched English Canada
421 Osborne (8080) > Ltd. WHMIS
Stores - Transit
(CWIN90)
Transit Dept (8050) > Black Semi Gloss PPG Automotive DU9645 Matched English Canada
421 Osborne (8080) > Durethane Refinish WHMIS
Stores - Transit
(CWIN90)
Transit Dept (8050) > Black Sure Foot Davis Frost, Inc. LX-00097 Matched English Canada
421 Osborne (8080) > WHMIS
Stores - Transit
(CWIN90)
Transit Dept (8050) > Bleach 5.0% -7.9% Lavo Inc Matched English Canada
421 Osborne (8080) > WHMIS
Stores - Transit
(CWIN90)
Transit Dept (8050) > Blue Marvel 2000 Zep Manufacturing G244 Matched English Canada
421 Osborne (8080) > Company of Canada WHMIS
Stores - Transit
(CWIN90)
Transit Dept (8050) > Brake & Parts Cleaner Würth Canada Limitée Matched English Canada
421 Osborne (8080) > 408gr - 890.9107 WHMIS
Stores - Transit
(CWIN90)
Transit Dept (8050) > Brake Cleaner Refilo Würth Canada Limitée 890108720 Matched English Canada
421 Osborne (8080) > 20L WHMIS
Stores - Transit
(CWIN90)
Transit Dept (8050) > Brake Lining - AF / 557 Fras-Le S.A. Matched English Canada
421 Osborne (8080) > WHMIS
Stores - Transit
(CWIN90)
Transit Dept (8050) > Butcher's Percept RTU Virox Technologies Matched English Canada
421 Osborne (8080) > Wipes WHMIS
Stores - Transit
(CWIN90)
Transit Dept (8050) > Calclean-Canada Nu-Calgon Wholesalers 4820 Matched English Canada
421 Osborne (8080) > Inc. WHMIS
Stores - Transit
(CWIN90)
Transit Dept (8050) > Canadian Hi- Technical Chemical 2416F Matched English Canada
421 Osborne (8080) > Performance Brake Company WHMIS
Stores - Transit Parts Cleaner
(CWIN90)
Transit Dept (8050) > Carbon Steel Welding National Standard Matched English Canada
421 Osborne (8080) > Wire Company WHMIS
Stores - Transit
(CWIN90)
Transit Dept (8050) > Castrol Transynd Castrol Canada Inc. 455936-US03 US65 Matched English Canada
421 Osborne (8080) > WHMIS
Stores - Transit
(CWIN90)
Transit Dept (8050) > CC640 Series Hewlett Packard Co. Matched English Canada
421 Osborne (8080) > WHMIS
Stores - Transit
(CWIN90)
Transit Dept (8050) > Cdg Wheel Spray - Würth Canada Limitée 893.1056 Matched English Canada
421 Osborne (8080) > 893.1056 500Ml WHMIS
Stores - Transit
(CWIN90)
Transit Dept (8050) > Centari R Acrylic Dupont Performance Matched English Canada
421 Osborne (8080) > Enamel Tints and Coatings WHMIS
Stores - Transit Miscellaneous Factory
(CWIN90) Packaged Colors

Transit Dept (8050) > Circuitworks Conductive ITW Chemtronics Inc. CW2400 Matched English Canada
421 Osborne (8080) > Epoxy - Part A WHMIS
Stores - Transit (Adhesive)
(CWIN90)
Transit Dept (8050) > Circuitworks Conductive ITW Chemtronics Inc. CW2400 Matched English Canada
421 Osborne (8080) > Epoxy - Part B WHMIS
Stores - Transit (Hardener)
(CWIN90)
Transit Dept (8050) > Circuitworks Rubber ITW Chemtronics Inc. CW2605 (Part B) Matched English Canada
421 Osborne (8080) > Keypad Repair Kit - Part WHMIS
Stores - Transit B (Curing Agent)
(CWIN90)
Transit Dept (8050) > Cleaner 33 Sluyter Company Ltd. Matched English Canada
421 Osborne (8080) > WHMIS
Stores - Transit
(CWIN90)
Transit Dept (8050) > ClovaGuard HB Cloverdale Paint Inc. 83150B Matched English Canada
421 Osborne (8080) > Polyamide Activa WHMIS
Stores - Transit
(CWIN90)
Transit Dept (8050) > Clovaguard Hb Cloverdale Paint Inc. 83150A Matched English Canada
421 Osborne (8080) > Polyamide Epoxy WHMIS
Stores - Transit
(CWIN90)
Transit Dept (8050) > CMT 22A Brake Pro Ltd Matched English Canada
421 Osborne (8080) > WHMIS
Stores - Transit
(CWIN90)
Transit Dept (8050) > CMT 22A1 Brake Pro Ltd Matched English Canada
421 Osborne (8080) > WHMIS
Stores - Transit
(CWIN90)
Transit Dept (8050) > Compressor Oil- Solest thermo king 985-887-2200 Matched English Canada
421 Osborne (8080) > 35 WHMIS
Stores - Transit
(CWIN90)
Transit Dept (8050) > Concept Mixing Bases PPG Automotive DMC-1 (0808-T0) Matched English Canada
421 Osborne (8080) > Refinish WHMIS
Stores - Transit
(CWIN90)
Transit Dept (8050) > Contact OL Spray A. Würth GmbH & Co. Matched English Canada
421 Osborne (8080) > 200ml - 893.60 KG WHMIS
Stores - Transit
(CWIN90)
Transit Dept (8050) > Continuum Aec3139 GE Betz CANADA Matched English Canada
421 Osborne (8080) > WHMIS
Stores - Transit
(CWIN90)
Transit Dept (8050) > Conv. Epocy Primer PPG Automotive F3997 Matched English Canada
421 Osborne (8080) > Black Refinish WHMIS
Stores - Transit
(CWIN90)
Transit Dept (8050) > Conventional Epoxy PPG Automotive F3995 Matched English Canada
421 Osborne (8080) > Primer Refinish WHMIS
Stores - Transit
(CWIN90)
Transit Dept (8050) > Conventional Epoxy PPG Automotive F3996 Matched English Canada
421 Osborne (8080) > Primer Hardener Refinish WHMIS
Stores - Transit
(CWIN90)
Transit Dept (8050) > Corashield Antichip PPG Automotive P7972 Matched English Canada
421 Osborne (8080) > Coating Refinish WHMIS
Stores - Transit
(CWIN90)
Transit Dept (8050) > Correction Fluid Dixon Ticonderoga Matched English Canada
421 Osborne (8080) > Company WHMIS
Stores - Transit
(CWIN90)
Transit Dept (8050) > Correction pen (Multi- Pentel Co. Ltd ZL31-W, ZLC31-W, Matched English Canada
421 Osborne (8080) > Purpose) ZL33-W WHMIS
Stores - Transit
(CWIN90)
Transit Dept (8050) > Corrshield MD4102 Ge Betz Matched English Canada
421 Osborne (8080) > WHMIS
Stores - Transit
(CWIN90)
Transit Dept (8050) > Cream Hardener ITW Evercoat 100340 Matched English Canada
421 Osborne (8080) > WHMIS
Stores - Transit
(CWIN90)
Transit Dept (8050) > Crown 8034 General Aervoe Industries Inc Matched English Canada
421 Osborne (8080) > Purpose Silicone WHMIS
Stores - Transit Lubricant
(CWIN90)
Transit Dept (8050) > Cupran Special Evonik Stockhausen Inc SK-127B Matched English Canada
421 Osborne (8080) > WHMIS
Stores - Transit
(CWIN90)
Transit Dept (8050) > Dap 73473 Silicone Dow Corning Matched English Canada
421 Osborne (8080) > Sealant Clear CDN Corporation / Styron WHMIS
Stores - Transit LLC
(CWIN90)
Transit Dept (8050) > Dar Fast Reducer PPG Automotive DTR601 Matched English Canada
421 Osborne (8080) > Refinish WHMIS
Stores - Transit
(CWIN90)
Transit Dept (8050) > DAR Reducer PPG Automotive DTR602WC Matched English Canada
421 Osborne (8080) > Refinish WHMIS
Stores - Transit
(CWIN90)
Transit Dept (8050) > Darina XL EP 2 Shell Canada Products 504-554 Matched English Canada
421 Osborne (8080) > Ltd. WHMIS
Stores - Transit
(CWIN90)
Transit Dept (8050) > Deb Azure Foam Wash Deb Canada AZU1L-CAN, AZU2LT- Matched English Canada
421 Osborne (8080) > CAN WHMIS
Stores - Transit
(CWIN90)
Transit Dept (8050) > Debonaire Foaming DEB Canada Inc.& SBS SF 032A Matched English Canada
421 Osborne (8080) > Skin Cleanser (Pink). Products WHMIS
Stores - Transit (Unscented)
(CWIN90)
Transit Dept (8050) > Depend (R) Activator Henkel Loctite 21088 Matched English Canada
421 Osborne (8080) > 7387 Aerosol Corporation WHMIS
Stores - Transit
(CWIN90)
Transit Dept (8050) > Depend Activator 7075 Henkel Loctite Canada 22671 Matched English Canada
421 Osborne (8080) > Inc. WHMIS
Stores - Transit
(CWIN90)
Transit Dept (8050) > Dettol Antiseptic Reckitt & Benckiser 930666 Matched English Canada
421 Osborne (8080) > Disinfectant (Liquid) - WHMIS
Stores - Transit Canadian
(CWIN90)
Transit Dept (8050) > Diamond Glacier Tiger Calcium Services Matched English Canada
421 Osborne (8080) > Supreme Inc. WHMIS
Stores - Transit
(CWIN90)
Transit Dept (8050) > Di-Electric Grease CRC Industries 03082 Matched English Canada
421 Osborne (8080) > (Aerosol) WHMIS
Stores - Transit
(CWIN90)
Transit Dept (8050) > Diesel Exhaust Fluid Brenntag Canada Inc. 00070093 Matched English Canada
421 Osborne (8080) > WHMIS
Stores - Transit
(CWIN90)
Transit Dept (8050) > Diesel Exhaust Fluid 32 Cummins Filtration / CC2584 Matched English Canada
421 Osborne (8080) > Fleetguard Inc. WHMIS
Stores - Transit
(CWIN90)
Transit Dept (8050) > Dimension 4.6 Voc Sherwin-Williams DS691 Matched English Canada
421 Osborne (8080) > Sealer, Gray Automotive Finishes WHMIS
Stores - Transit
(CWIN90)
Transit Dept (8050) > Door Latch Grease and Ford Canada 178365 Matched English Canada
421 Osborne (8080) > Silicone Brake Caliper WHMIS
Stores - Transit Grease and Dielectric
(CWIN90) Compound
Transit Dept (8050) > Dow Brake Fluid 310 DOW CIG North Matched English Canada
421 Osborne (8080) > America WHMIS
Stores - Transit
(CWIN90)
Transit Dept (8050) > Dow Corning 4 Dow Corning Matched English Canada
421 Osborne (8080) > Electrical Insulating Corporation / Styron WHMIS
Stores - Transit Compound LLC
(CWIN90)
Transit Dept (8050) > Dow Corning 732 Multi- Dow Corning Matched English Canada
421 Osborne (8080) > Purpose Sealant, Corporation / Styron WHMIS
Stores - Transit Aluminum LLC
(CWIN90)
Transit Dept (8050) > Dow Corning 732 Multi- Dow Corning Matched English Canada
421 Osborne (8080) > Purpose Sealant, Black Corporation / Styron WHMIS
Stores - Transit LLC
(CWIN90)
Transit Dept (8050) > Dupli-Color Enamel Sherwin Williams DA1600 Matched English Canada
421 Osborne (8080) > Paint, Gloss Black WHMIS
Stores - Transit (OSHA)
(CWIN90)
Transit Dept (8050) > Dupli-Color Enamel Sherwin Williams DA1670 Matched English Canada
421 Osborne (8080) > Paint, Gloss White WHMIS
Stores - Transit (OSHA White)
(CWIN90)
Transit Dept (8050) > Dupli-Color Enamel Sherwin Williams DA1630 Matched English Canada
421 Osborne (8080) > Paint, Leaf Green WHMIS
Stores - Transit
(CWIN90)
Transit Dept (8050) > Dupli-Color Enamel Sherwin Williams DA1612 Matched English Canada
421 Osborne (8080) > Paint, Machinery Gray WHMIS
Stores - Transit
(CWIN90)
Transit Dept (8050) > Dupli-Color Enamel Sherwin Williams DA1620 Matched English Canada
421 Osborne (8080) > Paint, Royal Blue WHMIS
Stores - Transit
(CWIN90)
Transit Dept (8050) > Dupli-Color Engine Sherwin Williams DE1605 Matched English Canada
421 Osborne (8080) > Enamel With Ceramic, WHMIS
Stores - Transit Ford Red
(CWIN90)
Transit Dept (8050) > Dupli-Color Lacquer Sherwin Williams DAL1607 Matched English Canada
421 Osborne (8080) > Paint, Flat Black WHMIS
Stores - Transit
(CWIN90)
Transit Dept (8050) > Dupli-Color Lacquer Sherwin Williams DAL1677 Matched English Canada
421 Osborne (8080) > Paint, Gloss Black WHMIS
Stores - Transit
(CWIN90)
Transit Dept (8050) > Dupli-Color Primer Sherwin Williams DAP1699 Matched English Canada
421 Osborne (8080) > Sealer, Gray WHMIS
Stores - Transit
(CWIN90)
Transit Dept (8050) > Dupli-Color Primer Sherwin Williams DAP1692 Matched English Canada
421 Osborne (8080) > Surfacer, Gray Hot Rod WHMIS
Stores - Transit
(CWIN90)
Transit Dept (8050) > Duron Single Grade Petro-Canada 420-054 Matched English Canada
421 Osborne (8080) > Oils Sae Viscosity WHMIS
Stores - Transit Grades 10W, 20, 30,
(CWIN90) 40, 50
Transit Dept (8050) > Duster ITW Chemtronics Inc. ES1617C Matched English Canada
421 Osborne (8080) > WHMIS
Stores - Transit
(CWIN90)
Transit Dept (8050) > Enamel 1-Gl 2Pk 7400 Rust Oleum 7448402 Matched English Canada
421 Osborne (8080) > Yel (Old Caterpllr) Corporation WHMIS
Stores - Transit
(CWIN90)
Transit Dept (8050) > Envirowest Gunwash Univar Canada Ltd. Matched English Canada
421 Osborne (8080) > WHMIS
Stores - Transit
(CWIN90)
Transit Dept (8050) > EPOXY HARDENER PPG Industries DP401LV Matched English Canada
421 Osborne (8080) > WHMIS
Stores - Transit
(CWIN90)
Transit Dept (8050) > Epoxy Primer Catalyst PPG Automotive DP401LF Matched English Canada
421 Osborne (8080) > Refinish WHMIS
Stores - Transit
(CWIN90)
Transit Dept (8050) > Epoxy Primer Gray PPG Automotive F3993 Matched English Canada
421 Osborne (8080) > Refinish WHMIS
Stores - Transit
(CWIN90)
Transit Dept (8050) > Epoxy Primer White PPG Automotive DP48LF Matched English Canada
421 Osborne (8080) > (Non Chrome) Refinish WHMIS
Stores - Transit
(CWIN90)
Transit Dept (8050) > Etching Filler Sherwin-Williams E2G980 Matched English Canada
421 Osborne (8080) > Automotive Finishes WHMIS
Stores - Transit
(CWIN90)
Transit Dept (8050) > European Auto Coat Transtar Autobody 1273 Matched English Canada
421 Osborne (8080) > Technologies WHMIS
Stores - Transit
(CWIN90)
Transit Dept (8050) > Everglass Fibre Glass-Evercoat 100622 Matched English Canada
421 Osborne (8080) > Co. Inc. WHMIS
Stores - Transit
(CWIN90)
Transit Dept (8050) > Exempt Solvent PPG Automotive F3385 Matched English Canada
421 Osborne (8080) > Refinish WHMIS
Stores - Transit
(CWIN90)
Transit Dept (8050) > Exempt Solvent - PPG Automotive F3390 Matched English Canada
421 Osborne (8080) > Medium Refinish WHMIS
Stores - Transit
(CWIN90)
Transit Dept (8050) > Extend Rust Treatment Henkel Loctite Canada 234981 Matched English Canada
421 Osborne (8080) > Inc. WHMIS
Stores - Transit
(CWIN90)
Transit Dept (8050) > Extra Oil Heavy Duty Prairie West Industrial 14808-60-7 Matched English Canada
421 Osborne (8080) > Floor Sweeping Ltd WHMIS
Stores - Transit Compound
(CWIN90)
Transit Dept (8050) > Extra Slow Activator PPG Automotive ESX540 Matched English Canada
421 Osborne (8080) > Refinish WHMIS
Stores - Transit
(CWIN90)
Transit Dept (8050) > eyesaline Fendall, Inc. Matched English Canada
421 Osborne (8080) > WHMIS
Stores - Transit
(CWIN90)
Transit Dept (8050) > F-900 Torque Seal Organic Products Matched English Canada
421 Osborne (8080) > Company WHMIS
Stores - Transit
(CWIN90)
Transit Dept (8050) > Fast Compliant Thinner PPG Automotive D8764 Matched English Canada
421 Osborne (8080) > Refinish WHMIS
Stores - Transit
(CWIN90)
Transit Dept (8050) > Fast Dry Additive PPG Automotive F3400 Matched English Canada
421 Osborne (8080) > Refinish WHMIS
Stores - Transit
(CWIN90)
Transit Dept (8050) > Fast Dry Surfacer PPG Automotive F3975 Matched English Canada
421 Osborne (8080) > Refinish WHMIS
Stores - Transit
(CWIN90)
Transit Dept (8050) > Fast Reducer PPG Automotive F3311 Matched English Canada
421 Osborne (8080) > Refinish WHMIS
Stores - Transit
(CWIN90)
Transit Dept (8050) > Film Forming Lubricant Balmar, LLC 101G 380 Matched English Canada
421 Osborne (8080) > 380 WHMIS
Stores - Transit
(CWIN90)
Transit Dept (8050) > Fire Extinguisher ABC Pyro Chem, Inc. Matched English Canada
421 Osborne (8080) > Multipurpose Dry WHMIS
Stores - Transit Chemical
(CWIN90)
Transit Dept (8050) > Fluid Film Aerosol (AS) Eureka Chemical Matched English Canada
421 Osborne (8080) > Company WHMIS
Stores - Transit
(CWIN90)
Transit Dept (8050) > Foam San Zep Manufacturing 0880 Matched English Canada
421 Osborne (8080) > Company of Canada WHMIS
Stores - Transit
(CWIN90)
Transit Dept (8050) > Form-a-Thread 4.8ml Henkel Loctite Canada 28654_390222 Matched English Canada
421 Osborne (8080) > Syr Act Inc. WHMIS
Stores - Transit
(CWIN90)
Transit Dept (8050) > Gasket Eliminator 518 Henkel Loctite Canada 51831 Matched English Canada
421 Osborne (8080) > Sealant Inc. WHMIS
Stores - Transit
(CWIN90)
Transit Dept (8050) > Gasoline, Unleaded Petro-Canada Matched English Canada
421 Osborne (8080) > WHMIS
Stores - Transit
(CWIN90)
Transit Dept (8050) > Gear, Chain & Cable Henkel Loctite 81251 Matched English Canada
421 Osborne (8080) > Lubricant Corporation WHMIS
Stores - Transit
(CWIN90)
Transit Dept (8050) > Glance Foaming Glass Johnson Diversey 04553 Matched English Canada
421 Osborne (8080) > & Multi-Surface Cleaner WHMIS
Stores - Transit
(CWIN90)
Transit Dept (8050) > Glass Impact Beads Potters Industries Inc. Matched English Canada
421 Osborne (8080) > WHMIS
Stores - Transit
(CWIN90)
Transit Dept (8050) > Gojo Original Formula GOJO Industries, Inc. Matched English Canada
421 Osborne (8080) > Hand Cleaner WHMIS
Stores - Transit
(CWIN90)
Transit Dept (8050) > Goldex Institutional RW Packaging Ltd. Matched English Canada
421 Osborne (8080) > Bleach WHMIS
Stores - Transit
(CWIN90)
Transit Dept (8050) > Graffiti Wipes Share Corporation Matched English Canada
421 Osborne (8080) > Canada Chemical Ltd. WHMIS
Stores - Transit
(CWIN90)
Transit Dept (8050) > Granular Absorbent Oil-Dri Corporation of Matched English Canada
421 Osborne (8080) > America WHMIS
Stores - Transit
(CWIN90)
Transit Dept (8050) > Green Link Bowl Zep Manufacturing P848 Matched English Canada
421 Osborne (8080) > Cleaner Company of Canada WHMIS
Stores - Transit
(CWIN90)
Transit Dept (8050) > Heat Shield Auto-Chem Inc. 4680 / 4681 Matched English Canada
421 Osborne (8080) > WHMIS
Stores - Transit
(CWIN90)
Transit Dept (8050) > Heavy Duty Diesel Nemco Resources 0701 Matched English Canada
421 Osborne (8080) > Antifreeze (SCA) Pure WHMIS
Stores - Transit
(CWIN90)
Transit Dept (8050) > HHS Lube 500ml Würth Canada Limitée 08931065 Matched English Canada
421 Osborne (8080) > WHMIS
Stores - Transit
(CWIN90)
Transit Dept (8050) > HHS Red Lube 500Ml Würth Canada Limitée 089310651 Matched English Canada
421 Osborne (8080) > WHMIS
Stores - Transit
(CWIN90)
Transit Dept (8050) > High Build Undercoat Würth Canada Limitée 890.9072 Matched English Canada
421 Osborne (8080) > 550G. Paintable - WHMIS
Stores - Transit 890.9072
(CWIN90)
Transit Dept (8050) > High Solids Hardener - PPG Automotive F3260 Matched English Canada
421 Osborne (8080) > Fast Refinish WHMIS
Stores - Transit
(CWIN90)
Transit Dept (8050) > HP Color LaserJet Hewlett Packard Matched English Canada
421 Osborne (8080) > CB381A Cyan Print Company WHMIS
Stores - Transit Cartridge
(CWIN90)
Transit Dept (8050) > Hp Color Laserjet Hewlett Packard Matched English Canada
421 Osborne (8080) > Cb382A Yellow Print Company WHMIS
Stores - Transit Cartridge
(CWIN90)
Transit Dept (8050) > Hp Color Laserjet Hewlett Packard Matched English Canada
421 Osborne (8080) > Cb383A Magenta Print Company WHMIS
Stores - Transit Cartridge
(CWIN90)
Transit Dept (8050) > HP Color Laserjet Hewlett Packard Matched English Canada
421 Osborne (8080) > CB384A Imaging Drum Company WHMIS
Stores - Transit Cartridge
(CWIN90)
Transit Dept (8050) > HP Color LaserJet Hewlett Packard Matched English Canada
421 Osborne (8080) > CB385A Imaging Drum Company WHMIS
Stores - Transit Cartridge
(CWIN90)
Transit Dept (8050) > HP Color LaserJet Hewlett Packard Matched English Canada
421 Osborne (8080) > CB386A Imaging Drum Company WHMIS
Stores - Transit Cartridge
(CWIN90)
Transit Dept (8050) > HP Color LaserJet Hewlett Packard Matched English Canada
421 Osborne (8080) > CB387A Imaging Drum Company WHMIS
Stores - Transit Cartridge
(CWIN90)
Transit Dept (8050) > Hp Color Laserjet Hewlett Packard Matched English Canada
421 Osborne (8080) > Cb390A Black Print Company WHMIS
Stores - Transit Cartridge
(CWIN90)
Transit Dept (8050) > HP LaserJet 92291A-X Hewlett Packard Matched English Canada
421 Osborne (8080) > Print Cartridge Company WHMIS
Stores - Transit
(CWIN90)
Transit Dept (8050) > Hs Polyurethane Clear PPG Automotive DCU2001 (0808) Matched English Canada
421 Osborne (8080) > Refinish WHMIS
Stores - Transit
(CWIN90)
Transit Dept (8050) > Hydrex Aw 22, 32, 46, Petro-Canada 490-138 Matched English Canada
421 Osborne (8080) > 68, 80, 100 WHMIS
Stores - Transit
(CWIN90)
Transit Dept (8050) > HYDREX TM MV Petro Canada Matched English Canada
421 Osborne (8080) > ARCTIC 15 Lubricants WHMIS
Stores - Transit
(CWIN90)
Transit Dept (8050) > Hydrogen Peroxide RW Packaging Ltd. Matched English Canada
421 Osborne (8080) > Solution - 10 Volume WHMIS
Stores - Transit 3%
(CWIN90)
Transit Dept (8050) > Ice Fighter Plus Zep Manufacturing 5813 Matched English Canada
421 Osborne (8080) > Company of Canada WHMIS
Stores - Transit
(CWIN90)
Transit Dept (8050) > International Compound Irmco Matched English Canada
421 Osborne (8080) > #2 WHMIS
Stores - Transit
(CWIN90)
Transit Dept (8050) > Jet Clean F.S. EX JT Zep Manufacturing P241 Matched English Canada
421 Osborne (8080) > #1 Company of Canada WHMIS
Stores - Transit
(CWIN90)
Transit Dept (8050) > Johnsen's Canadian Hi- Technical Chemical Matched English Canada
421 Osborne (8080) > Performance Brake Company WHMIS
Stores - Transit Parts Cleaner 14 OZ
(CWIN90)
Transit Dept (8050) > Kem-Transport Sherwin-Williams R4K183 Matched English Canada
421 Osborne (8080) > Synthetic Enamel Automotive Finishes WHMIS
Stores - Transit Reducer, Fast
(CWIN90)
Transit Dept (8050) > Kem-Transport Zinc Sherwin-Williams E2Y36 Matched English Canada
421 Osborne (8080) > Chromate Primer Automotive Finishes WHMIS
Stores - Transit
(CWIN90)
Transit Dept (8050) > Kitty Hair Fibre Glass-Evercoat 100857 Matched English Canada
421 Osborne (8080) > Co. Inc. WHMIS
Stores - Transit
(CWIN90)
Transit Dept (8050) > Klarifiant Johnson Diversey Matched English Canada
421 Osborne (8080) > WHMIS
Stores - Transit
(CWIN90)
Transit Dept (8050) > Kolor Kut Water Finding Kolor Kut Products Matched English Canada
421 Osborne (8080) > Paste Company WHMIS
Stores - Transit
(CWIN90)
Transit Dept (8050) > Kopr-Kote Thermal Jet Lube of Canada Ltd. Matched English Canada
421 Osborne (8080) > Grade WHMIS
Stores - Transit
(CWIN90)
Transit Dept (8050) > Krylon High Heat & Sherwin Williams 1402 Matched English Canada
421 Osborne (8080) > Radiator Paint, WHMIS
Stores - Transit Aluminum
(CWIN90)
Transit Dept (8050) > Laura Line Sanitizing J. R. Phoenix Skin Care Matched English Canada
421 Osborne (8080) > Gel Prod./Laura Line Skin WHMIS
Stores - Transit Care
(CWIN90)
Transit Dept (8050) > Lavo-6 Bleach Lavo Matched English Canada
421 Osborne (8080) > WHMIS
Stores - Transit
(CWIN90)
Transit Dept (8050) > Lead Acid Battery NorthStar Battery Co. Matched English Canada
421 Osborne (8080) > LLC WHMIS
Stores - Transit
(CWIN90)
Transit Dept (8050) > Leak Seeker #14-755 31 Incorporated Matched English Canada
421 Osborne (8080) > WHMIS
Stores - Transit
(CWIN90)
Transit Dept (8050) > Lemon Kleen Prairie West Industrial Matched English Canada
421 Osborne (8080) > Ltd. WHMIS
Stores - Transit
(CWIN90)
Transit Dept (8050) > Lepage LCP 506 Henkel Consumer Matched English Canada
421 Osborne (8080) > Contact Cement Adhesives WHMIS
Stores - Transit Premium Grade
(CWIN90)
Transit Dept (8050) > Liberty No Scrub Swish Maintenance Ltd. 4007 Matched English Canada
421 Osborne (8080) > Stripper WHMIS
Stores - Transit
(CWIN90)
Transit Dept (8050) > Lift-Away Johnson Diversey 2405205 Matched English Canada
421 Osborne (8080) > WHMIS
Stores - Transit
(CWIN90)
Transit Dept (8050) > Liquid Hardener US Chemical & Plastic 765-3032 Matched English Canada
421 Osborne (8080) > (93510) Cie WHMIS
Stores - Transit
(CWIN90)
Transit Dept (8050) > Liquid Paper Correction NewellRubbermaid Matched English Canada
421 Osborne (8080) > Fluid - Pen and Ink WHMIS
Stores - Transit
(CWIN90)
Transit Dept (8050) > Lite Weight Fibre Glass-Evercoat 100156 Matched English Canada
421 Osborne (8080) > Co. Inc. WHMIS
Stores - Transit
(CWIN90)
Transit Dept (8050) > Loctite 222Ms Henkel Loctite Canada 22221 Matched English Canada
421 Osborne (8080) > Threadlocker Low Inc. WHMIS
Stores - Transit Strength
(CWIN90)
Transit Dept (8050) > Loctite 242 Henkel Loctite Canada 135355 Matched English Canada
421 Osborne (8080) > Threadlocker Inc. WHMIS
Stores - Transit
(CWIN90)
Transit Dept (8050) > Loctite 262 Henkel Loctite Canada 26231 Matched English Canada
421 Osborne (8080) > Threadlocker Inc. WHMIS
Stores - Transit
(CWIN90)
Transit Dept (8050) > Loctite 290 Henkel Loctite Canada 29031 Matched English Canada
421 Osborne (8080) > Threadlocker Inc. WHMIS
Stores - Transit
(CWIN90)
Transit Dept (8050) > Loctite 567 PST Pipe Henkel Loctite Canada 56747 Matched English Canada
421 Osborne (8080) > Sealant with PTFE Inc. WHMIS
Stores - Transit Thread Sealant Part
(CWIN90) No. 56747
Transit Dept (8050) > Loctite 587 Blue High Henkel Loctite 58775 Matched English Canada
421 Osborne (8080) > Performance RTV Corporation WHMIS
Stores - Transit Silicone Gasket Maker
(CWIN90)
Transit Dept (8050) > Loctite 609 Retaining Henkel Loctite Canada 135512 Matched English Canada
421 Osborne (8080) > Compound Press Fit Inc. WHMIS
Stores - Transit
(CWIN90)
Transit Dept (8050) > Loctite 680 Retaining Henkel Loctite Canada 68035 Matched English Canada
421 Osborne (8080) > Compound Slip Fit Inc. WHMIS
Stores - Transit
(CWIN90)
Transit Dept (8050) > Loctite 7649 Primer Henkel Loctite Canada 209715 Matched English Canada
421 Osborne (8080) > Inc. WHMIS
Stores - Transit
(CWIN90)
Transit Dept (8050) > Loctite Fixmaster Pox Henkel Loctite Canada 702092 Matched English Canada
421 Osborne (8080) > Pak Inc. WHMIS
Stores - Transit
(CWIN90)
Transit Dept (8050) > Loctite Instant Gasket Henkel Loctite IDH No. 270636 Matched English Canada
421 Osborne (8080) > Corporation WHMIS
Stores - Transit
(CWIN90)
Transit Dept (8050) > Loctite Silver Grade Henkel Loctite Canada Matched English Canada
421 Osborne (8080) > Anti-Seize Inc. WHMIS
Stores - Transit
(CWIN90)
Transit Dept (8050) > Low Voc Hardener PPG Automotive DFX11 Matched English Canada
421 Osborne (8080) > Refinish WHMIS
Stores - Transit
(CWIN90)
Transit Dept (8050) > LPS 1 Premium LPS Laboratories Inc. 00105 Matched English Canada
421 Osborne (8080) > Lubricant WHMIS
Stores - Transit
(CWIN90)
Transit Dept (8050) > LPS 3 Premier Rust LPS Laboratories Inc. 00316 Matched English Canada
421 Osborne (8080) > Inhibitor Aerosol WHMIS
Stores - Transit
(CWIN90)
Transit Dept (8050) > Lps F-104° LPS Laboratories Inc. 04905 Matched English Canada
421 Osborne (8080) > Solvent/Degreaser WHMIS
Stores - Transit
(CWIN90)
Transit Dept (8050) > Lps Noflash Nu Electro LPS Laboratories Inc. 04015 Matched English Canada
421 Osborne (8080) > Contact Cleaner WHMIS
Stores - Transit
(CWIN90)
Transit Dept (8050) > LPS Precision Clean LPS Laboratories Inc. 02701 Matched English Canada
421 Osborne (8080) > Concentrate WHMIS
Stores - Transit
(CWIN90)
Transit Dept (8050) > Lubriplate 105 Lubriplate Lubricants Matched English Canada
421 Osborne (8080) > Co WHMIS
Stores - Transit
(CWIN90)
Transit Dept (8050) > Marvelube EP 9F Esso Petroleum 8370 Matched English Canada
421 Osborne (8080) > Canada WHMIS
Stores - Transit
(CWIN90)
Transit Dept (8050) > Masters Metallic GF Thompson Co. Ltd. Matched English Canada
421 Osborne (8080) > Compound WHMIS
Stores - Transit
(CWIN90)
Transit Dept (8050) > Maximum 5W30, Petro-Canada 410-335 Matched English Canada
421 Osborne (8080) > 10W30, 10W40 WHMIS
Stores - Transit
(CWIN90)
Transit Dept (8050) > Mc30Bl Marrin - Lotion Marrin Brothers Limited Matched English Canada
421 Osborne (8080) > Hand Soap WHMIS
Stores - Transit
(CWIN90)
Transit Dept (8050) > Medium Solids PPG Automotive F3270 Matched English Canada
421 Osborne (8080) > Hardener Refinish WHMIS
Stores - Transit
(CWIN90)
Transit Dept (8050) > Mercon SP Automatic Ford Canada 175325 Matched English Canada
421 Osborne (8080) > Transmission Fluid WHMIS
Stores - Transit
(CWIN90)
Transit Dept (8050) > Micromist Fresh Scent Zep Manufacturing 0243 Matched English Canada
421 Osborne (8080) > Company of Canada WHMIS
Stores - Transit
(CWIN90)
Transit Dept (8050) > Mighty Kleen Prairie West Industrial Matched English Canada
421 Osborne (8080) > Ltd. WHMIS
Stores - Transit
(CWIN90)
Transit Dept (8050) > Mineral Spirits Univar Canada Ltd Matched English Canada
421 Osborne (8080) > WHMIS
Stores - Transit
(CWIN90)
Transit Dept (8050) > Miracle Disinfectant Swish Maintenance Ltd. Matched English Canada
421 Osborne (8080) > Spray ‘N Wipe WHMIS
Stores - Transit
(CWIN90)
Transit Dept (8050) > MOBIL DELVAC Imperial Oil Products 20026 Matched English Canada
421 Osborne (8080) > SYNTHETIC ATF Division WHMIS
Stores - Transit
(CWIN90)
Transit Dept (8050) > MOBIL VACTRA OIL Imperial Oil Products 8303 Matched English Canada
421 Osborne (8080) > NO. 2 (FEBIS K 68) Division WHMIS
Stores - Transit
(CWIN90)
Transit Dept (8050) > Molykote 33 Extreme Dow Corning Matched English Canada
421 Osborne (8080) > Low Temp. Bearing Corporation WHMIS
Stores - Transit Grease, Medium
(CWIN90)
Transit Dept (8050) > Moovit (Aerosol) Lloyds Laboratories Inc. 11008 Matched English Canada
421 Osborne (8080) > WHMIS
Stores - Transit
(CWIN90)
Transit Dept (8050) > Nemco Diesel SCA Nemco Resources Matched English Canada
421 Osborne (8080) > Antifreeze WHMIS
Stores - Transit
(CWIN90)
Transit Dept (8050) > Nemco Methanol Nemco Resources Matched English Canada
421 Osborne (8080) > WHMIS
Stores - Transit
(CWIN90)
Transit Dept (8050) > Nemco Rad Antifreeze Nemco Resources Matched English Canada
421 Osborne (8080) > & Summer Coolant WHMIS
Stores - Transit Nemco Universal
(CWIN90) Antifreeze
Transit Dept (8050) > Nemco Windshield Nemco Resources Matched English Canada
421 Osborne (8080) > Washer Fluid WHMIS
Stores - Transit
(CWIN90)
Transit Dept (8050) > Never-Seez Heavy Bostik Findley Inc. V682040 Matched English Canada
421 Osborne (8080) > Metal Free Product WHMIS
Stores - Transit Series
(CWIN90)
Transit Dept (8050) > Never-Seez Regular Bostik Findley Inc. V048740 Matched English Canada
421 Osborne (8080) > Grade Cmpd. WHMIS
Stores - Transit
(CWIN90)
Transit Dept (8050) > Nev-SZ Reg NSA16 Bostik Findley Inc. 45987 Matched English Canada
421 Osborne (8080) > 12.5oz Aero WHMIS
Stores - Transit
(CWIN90)
Transit Dept (8050) > Nitrogen Dioxide 0.001- Air Liquide 10058036, 10058034, Matched English Canada
421 Osborne (8080) > 0.022%, Carbon 10058171, 10058172, WHMIS
Stores - Transit Monoxide 0.0005-1.0%, 10150597,
(CWIN90) Methane 0.0-2.5%,
Oxygen 0.0-23.5%

Transit Dept (8050) > Non-Fluorescent Colors Aervoe Industries Inc 201 Matched English Canada
421 Osborne (8080) > 201 Red WHMIS
Stores - Transit
(CWIN90)
Transit Dept (8050) > One Shot Intake Kent Automotive Matched English Canada
421 Osborne (8080) > System Cleaner WHMIS
Stores - Transit
(CWIN90)
Transit Dept (8050) > One Step Hand Belvedere International Matched English Canada
421 Osborne (8080) > Sanitizer Incorporated WHMIS
Stores - Transit
(CWIN90)
Transit Dept (8050) > Oxivir Plus Disinfectant Diversey/Sealed Air 100859586 Matched English Canada
421 Osborne (8080) > Cleaner Concentrate WHMIS
Stores - Transit (Can)
(CWIN90)
Transit Dept (8050) > Oxivir Plus Disinfectant Diversey, Inc. Matched English Canada
421 Osborne (8080) > Cleaner Concentrate WHMIS
Stores - Transit (CAN) (1:40 Dilution)
(CWIN90)
Transit Dept (8050) > P-388 (BN-3) Fricciones Tecnicas y Matched English Canada
421 Osborne (8080) > Maquinados S.A. de C. WHMIS
Stores - Transit V.
(CWIN90)
Transit Dept (8050) > P-397 (B N6) Fricciones Tecnicas y Matched English Canada
421 Osborne (8080) > Maquinados S.A. de C. WHMIS
Stores - Transit V.
(CWIN90)
Transit Dept (8050) > P-417 (BN-4) Fricciones Tecnicas y Matched English Canada
421 Osborne (8080) > Maquinados S.A. de C. WHMIS
Stores - Transit V.
(CWIN90)
Transit Dept (8050) > Paradichlorobenzene Recochem Inc. 21-128 Matched English Canada
421 Osborne (8080) > WHMIS
Stores - Transit
(CWIN90)
Transit Dept (8050) > Pc Quick Grid Rear Permatex Canada 81532 Matched English Canada
421 Osborne (8080) > Defrost 1.4Ml WHMIS
Stores - Transit
(CWIN90)
Transit Dept (8050) > Peak Global Lifetime Old World Industries Matched English Canada
421 Osborne (8080) > Concentrate Antifreeze LLC WHMIS
Stores - Transit & Coolant
(CWIN90)
Transit Dept (8050) > PEAK LONG LIFE Old World Industries Matched English Canada
421 Osborne (8080) > CONCENTRATE LLC WHMIS
Stores - Transit ANTIFREEZE &
(CWIN90) COOLANT
Transit Dept (8050) > Pelletized Radiator Stop Rislone Matched English Canada
421 Osborne (8080) > Leak WHMIS
Stores - Transit
(CWIN90)
Transit Dept (8050) > PENCOOL 200055 The Penray 200055 Matched English Canada
421 Osborne (8080) > Companies, Inc. WHMIS
Stores - Transit (Canada)
(CWIN90)
Transit Dept (8050) > Personal Safety Allegro Industries 1001 Matched English Canada
421 Osborne (8080) > Equipment Cleaning WHMIS
Stores - Transit Pads
(CWIN90)
Transit Dept (8050) > Petro-Canada Atf D3M Petro-Canada Matched English Canada
421 Osborne (8080) > WHMIS
Stores - Transit
(CWIN90)
Transit Dept (8050) > Petrosol 3139 Petro-Canada S3139 Matched English Canada
421 Osborne (8080) > WHMIS
Stores - Transit
(CWIN90)
Transit Dept (8050) > Pf 206 Brush Able Pro-Form Products Ltd. Matched English Canada
421 Osborne (8080) > Rubber Based Seam WHMIS
Stores - Transit Sealer (Off-White)
(CWIN90)
Transit Dept (8050) > PF 500 Non-Paintable Pro-Form Products Ltd. PF 500 Matched English Canada
421 Osborne (8080) > Rubberized Undercoat WHMIS
Stores - Transit
(CWIN90)
Transit Dept (8050) > PF 532 Pro Guard Pro-Form Products Ltd. PF 532 Matched English Canada
421 Osborne (8080) > Rubberized Gravlguard WHMIS
Stores - Transit
(CWIN90)
Transit Dept (8050) > PF 701 Non-Paintable Pro-Form Products Ltd. PF 701 Matched English Canada
421 Osborne (8080) > Rubberized Undercoat WHMIS
Stores - Transit
(CWIN90)
Transit Dept (8050) > Pigmented Chrome PPG Automotive F3960 Matched English Canada
421 Osborne (8080) > Etch Primer Refinish WHMIS
Stores - Transit
(CWIN90)
Transit Dept (8050) > Pigmented Chrome PPG Automotive F3961 Matched English Canada
421 Osborne (8080) > Etch Primer Harden Refinish WHMIS
Stores - Transit
(CWIN90)
Transit Dept (8050) > Plastic Adhesion Sherwin-Williams UPO-7226A Matched English Canada
421 Osborne (8080) > Promoter (Aerosol), Automotive Finishes WHMIS
Stores - Transit Clear
(CWIN90)
Transit Dept (8050) > PolarZone RV Nemco Resources 0680 Matched English Canada
421 Osborne (8080) > Antifreeze WHMIS
Stores - Transit
(CWIN90)
Transit Dept (8050) > Power Cool 3149 Old World Industries Matched English Canada
421 Osborne (8080) > Antifreeze & Coolant LLC WHMIS
Stores - Transit (Silicate Free)
(CWIN90)
Transit Dept (8050) > pr88 – The Wash-off Ursula Rath GmbH Matched English Canada
421 Osborne (8080) > Hand Protection WHMIS
Stores - Transit
(CWIN90)
Transit Dept (8050) > Prairie Extract Prairie West Industrial Matched English Canada
421 Osborne (8080) > Ltd. WHMIS
Stores - Transit
(CWIN90)
Transit Dept (8050) > Prairie West Industrial Prairie West Industrial Matched English Canada
421 Osborne (8080) > Ltd. Heavy Duty Floor Ltd. WHMIS
Stores - Transit Sweeping Compound
(CWIN90)
Transit Dept (8050) > Precision Xl 3 Moly Petro-Canada 650-137 Matched English Canada
421 Osborne (8080) > Ep1, Ep2 WHMIS
Stores - Transit
(CWIN90)
Transit Dept (8050) > Precision Xl Emb Petro-Canada 650-134 Matched English Canada
421 Osborne (8080) > WHMIS
Stores - Transit
(CWIN90)
Transit Dept (8050) > Precision Xl Ep00 Petro-Canada 650-131 Matched English Canada
421 Osborne (8080) > WHMIS
Stores - Transit
(CWIN90)
Transit Dept (8050) > Precision Xl Ep1, Ep2 Petro-Canada 650-132 Matched English Canada
421 Osborne (8080) > WHMIS
Stores - Transit
(CWIN90)
Transit Dept (8050) > Preptech Epoxy Cloverdale Paint Inc. 83020B Matched English Canada
421 Osborne (8080) > Penetrating Sealer WHMIS
Stores - Transit Activator
(CWIN90)
Transit Dept (8050) > Prestone Command Prestone R & D AFC10000/F Matched English Canada
421 Osborne (8080) > Heavy Duty Laboratory WHMIS
Stores - Transit Antifreeze/Coolant
(CWIN90)
Transit Dept (8050) > Propane Bernz-O-matic Matched English Canada
421 Osborne (8080) > WHMIS
Stores - Transit
(CWIN90)
Transit Dept (8050) > Protective Cream 311 West Penetone Inc. Matched English Canada
421 Osborne (8080) > WHMIS
Stores - Transit
(CWIN90)
Transit Dept (8050) > Qd Contact Cleaner CRC Industries 72130 Matched English Canada
421 Osborne (8080) > (Aerosol) WHMIS
Stores - Transit
(CWIN90)
Transit Dept (8050) > Quick Grid TM Repair Permatex Canada 15067 Matched English Canada
421 Osborne (8080) > Kit .05FO CG WHMIS
Stores - Transit
(CWIN90)
Transit Dept (8050) > Radiator Stop Leak and Bar’s Products C16 / R6 Matched English Canada
421 Osborne (8080) > Conditioner WHMIS
Stores - Transit
(CWIN90)
Transit Dept (8050) > Reducer PPG Automotive DT860 Matched English Canada
421 Osborne (8080) > Refinish WHMIS
Stores - Transit
(CWIN90)
Transit Dept (8050) > Reducer - Medium Refinish Products F3321 Matched English Canada
421 Osborne (8080) > WHMIS
Stores - Transit
(CWIN90)
Transit Dept (8050) > Refrigerant R-134a Ford Canada 132532 Matched English Canada
421 Osborne (8080) > WHMIS
Stores - Transit
(CWIN90)
Transit Dept (8050) > Replenisher Black Xerox Corporation 006R01046, Matched English Canada
421 Osborne (8080) > 006R01047, WHMIS
Stores - Transit 006R01186,
(CWIN90) 006R01146, 006R01
Transit Dept (8050) > Resinoid Bonded United Abrasives, Inc. Matched English Canada
421 Osborne (8080) > Abrasives WHMIS
Stores - Transit
(CWIN90)
Transit Dept (8050) > Ridgid Nuclear Thread Ridge Tool Company 41565 Matched English Canada
421 Osborne (8080) > Cutting Oil WHMIS
Stores - Transit
(CWIN90)
Transit Dept (8050) > Rohper Lspr 6Pk Gloss Rust Oleum V2116838 Matched English Canada
421 Osborne (8080) > High Tmp Aluminum Corporation WHMIS
Stores - Transit
(CWIN90)
Transit Dept (8050) > Rost Off 300ml Würth Canada Limitée 890.2 Matched English Canada
421 Osborne (8080) > WHMIS
Stores - Transit
(CWIN90)
Transit Dept (8050) > Rost Off Ice - 893.240 A. Würth GmbH & Co. 893.240 Matched English Canada
421 Osborne (8080) > KG WHMIS
Stores - Transit
(CWIN90)
Transit Dept (8050) > Sbs 33 Waterless Skin Deb USA, Inc Matched English Canada
421 Osborne (8080) > Cleanser with Patented WHMIS
Stores - Transit Scrubbers
(CWIN90)
Transit Dept (8050) > SC-200 Spartan Chemical Co., 2200 Matched English Canada
421 Osborne (8080) > Inc. WHMIS
Stores - Transit
(CWIN90)
Transit Dept (8050) > Set 45 BASF Corporation 30368387 Matched English Canada
421 Osborne (8080) > WHMIS
Stores - Transit
(CWIN90)
Transit Dept (8050) > Shell Bronze Gasoline Shell Canada Products Matched English Canada
421 Osborne (8080) > Ltd. WHMIS
Stores - Transit
(CWIN90)
Transit Dept (8050) > Sika Cleaner-205 Sika Canada Inc. Matched English Canada
421 Osborne (8080) > WHMIS
Stores - Transit
(CWIN90)
Transit Dept (8050) > Sikaflex-221 Sika Canada Inc. Matched English Canada
421 Osborne (8080) > WHMIS
Stores - Transit
(CWIN90)
Transit Dept (8050) > Sikaflex-222 UV Sika Canada Inc. Matched English Canada
421 Osborne (8080) > WHMIS
Stores - Transit
(CWIN90)
Transit Dept (8050) > Sikaflex-252 Sika Canada Inc. Matched English Canada
421 Osborne (8080) > WHMIS
Stores - Transit
(CWIN90)
Transit Dept (8050) > Silicone Conformal MG Chemicals Ltd. 422-55 Matched English Canada
421 Osborne (8080) > Coating WHMIS
Stores - Transit
(CWIN90)
Transit Dept (8050) > Single Stage High PPG Industries FDGH-1 Matched English Canada
421 Osborne (8080) > Solids Polyurethane WHMIS
Stores - Transit Enamel
(CWIN90)
Transit Dept (8050) > Single Stage High PPG Industries FDGH-3 Matched English Canada
421 Osborne (8080) > Solids Polyurethane WHMIS
Stores - Transit Enamel
(CWIN90)
Transit Dept (8050) > Single Stage Hs PPG Automotive FDGH-1 (0808) Matched English Canada
421 Osborne (8080) > Polyurethane Enamel Refinish WHMIS
Stores - Transit
(CWIN90)
Transit Dept (8050) > Single Stage HS PPG Automotive FDGH-3 (0808-T0) Matched English Canada
421 Osborne (8080) > Polyurethane Enamel Refinish WHMIS
Stores - Transit
(CWIN90)
Transit Dept (8050) > Slow Activator PPG Automotive ESX520 Matched English Canada
421 Osborne (8080) > Refinish WHMIS
Stores - Transit
(CWIN90)
Transit Dept (8050) > Sodium Bicarbonate, Brenntag Canada Inc. Matched English Canada
421 Osborne (8080) > Solid WHMIS
Stores - Transit
(CWIN90)
Transit Dept (8050) > Solder paste CMC no. Canada Metal (Pacific) Matched English Canada
421 Osborne (8080) > 50 or no. 504 Ltd. WHMIS
Stores - Transit
(CWIN90)
Transit Dept (8050) > SOS State Industrial Matched English Canada
421 Osborne (8080) > Products WHMIS
Stores - Transit
(CWIN90)
Transit Dept (8050) > SP-30 Kester, Inc. Matched English Canada
421 Osborne (8080) > WHMIS
Stores - Transit
(CWIN90)
Transit Dept (8050) > SpeedBonder 325 Henkel Loctite Canada 32530 Matched English Canada
421 Osborne (8080) > Structural Adhesive Inc. WHMIS
Stores - Transit
(CWIN90)
Transit Dept (8050) > Stephanie Janes Heavy ABT Products Inc Matched English Canada
421 Osborne (8080) > Duty Floor Sweeping WHMIS
Stores - Transit Compound
(CWIN90)
Transit Dept (8050) > Sterling Wunrub 83 Johnson Diversey 2050020 Matched English Canada
421 Osborne (8080) > WHMIS
Stores - Transit
(CWIN90)
Transit Dept (8050) > Stick-Kut - Lubricating Relton Corporation Matched English Canada
421 Osborne (8080) > Stick Wax WHMIS
Stores - Transit
(CWIN90)
Transit Dept (8050) > Stokolan Classsic Deb-Stoko USA LLC Matched English Canada
421 Osborne (8080) > WHMIS
Stores - Transit
(CWIN90)
Transit Dept (8050) > STP Oil Treatment The Armor All / STP Matched English Canada
421 Osborne (8080) > Products Company WHMIS
Stores - Transit
(CWIN90)
Transit Dept (8050) > Stream Johnson Diversey Matched English Canada
421 Osborne (8080) > Canada WHMIS
Stores - Transit
(CWIN90)
Transit Dept (8050) > Suds Prairie West Industrial Matched English Canada
421 Osborne (8080) > Ltd. WHMIS
Stores - Transit
(CWIN90)
Transit Dept (8050) > Super Cold 134 MG Chemicals Ltd. 403A-285G Matched English Canada
421 Osborne (8080) > WHMIS
Stores - Transit
(CWIN90)
Transit Dept (8050) > Super Duster 134 and MG Chemicals Ltd. 402A-140G Matched English Canada
421 Osborne (8080) > Super Duster 134 Plus WHMIS
Stores - Transit
(CWIN90)
Transit Dept (8050) > Superior Lithium Kokam Co., Ltd. SLPB Matched English Canada
421 Osborne (8080) > Polymer Battery WHMIS
Stores - Transit
(CWIN90)
Transit Dept (8050) > Supreme 5W-20, 5W- Petro-Canada 410-341 Matched English Canada
421 Osborne (8080) > 30, 10W-30, 10W-40, WHMIS
Stores - Transit 20W-50 Motor Oil
(CWIN90)
Transit Dept (8050) > Swish Clean & Green Swish Maintenance Ltd. 65319 Matched English Canada
421 Osborne (8080) > Toilet Bowl Cleaner WHMIS
Stores - Transit
(CWIN90)
Transit Dept (8050) > Swish Clean-It Lotion Swish Maintenance Ltd. 8027 Matched English Canada
421 Osborne (8080) > Soap WHMIS
Stores - Transit
(CWIN90)
Transit Dept (8050) > Synthite ER-41Air John C. Dolph Matched English Canada
421 Osborne (8080) > Drying Varnish Company WHMIS
Stores - Transit
(CWIN90)
Transit Dept (8050) > Tech-Chek Concentrate Tech International Matched English Canada
421 Osborne (8080) > WHMIS
Stores - Transit
(CWIN90)
Transit Dept (8050) > TECTYL 518 DAUBERT CHEMICAL Matched English Canada
421 Osborne (8080) > COMPANY WHMIS
Stores - Transit
(CWIN90)
Transit Dept (8050) > Tellus 46 Shell Canada Products 407-163 Matched English Canada
421 Osborne (8080) > Ltd. WHMIS
Stores - Transit
(CWIN90)
Transit Dept (8050) > TERJ KF#3 Dubois Chemicals, Inc 3600043, 3600170 Matched English Canada
421 Osborne (8080) > WHMIS
Stores - Transit
(CWIN90)
Transit Dept (8050) > Thinner - Slow PPG Automotive F3340 Matched English Canada
421 Osborne (8080) > Refinish WHMIS
Stores - Transit
(CWIN90)
Transit Dept (8050) > Thinner Lacquer 94 Brenntag Canada Inc. Matched English Canada
421 Osborne (8080) > ABS (0629) WHMIS
Stores - Transit
(CWIN90)
Transit Dept (8050) > Travabon Stockhausen Inc. Matched English Canada
421 Osborne (8080) > WHMIS
Stores - Transit
(CWIN90)
Transit Dept (8050) > Traxon 80W-90, 85W- Petro-Canada 470-501 Matched English Canada
421 Osborne (8080) > 140 WHMIS
Stores - Transit
(CWIN90)
Transit Dept (8050) > Tun-O-Wash Cleaner ITW Chemtronics Inc. ES2400C Matched English Canada
421 Osborne (8080) > (Formerly CFC Free WHMIS
Stores - Transit Tun-O-Wash)
(CWIN90)
Transit Dept (8050) > ULS Diesel B5 Shell Canada Products Matched English Canada
421 Osborne (8080) > Ltd. WHMIS
Stores - Transit
(CWIN90)
Transit Dept (8050) > ULS Diesel B5 Dye Shell Canada Products Matched English Canada
421 Osborne (8080) > Ltd. WHMIS
Stores - Transit
(CWIN90)
Transit Dept (8050) > Ultra Coolant Ingersoll Rand 38459582 Matched English Canada
421 Osborne (8080) > WHMIS
Stores - Transit
(CWIN90)
Transit Dept (8050) > Used OIL GFL environmental Matched English Canada
421 Osborne (8080) > west corporation WHMIS
Stores - Transit
(CWIN90)
Transit Dept (8050) > Very Slow Activator PPG Automotive ESX530 Matched English Canada
421 Osborne (8080) > Refinish WHMIS
Stores - Transit
(CWIN90)
Transit Dept (8050) > WATER BASED RUST CORROSION C1800WB CAVITY Matched English Canada
421 Osborne (8080) > INHIBITOR CONTROL COATINGS WAX CLEAR WHMIS
Stores - Transit LTD.
(CWIN90)
Transit Dept (8050) > Wave Urinal Deodorizer Fresh Products Inc. Matched English Canada
421 Osborne (8080) > WHMIS
Stores - Transit
(CWIN90)
Transit Dept (8050) > WD-40 Bulk Liquid WD 40 Products Matched English Canada
421 Osborne (8080) > Canada Ltd. WHMIS
Stores - Transit
(CWIN90)
Transit Dept (8050) > Weller WB1 2Oz. - Apex Tool Group Matched English Canada
421 Osborne (8080) > Butane Fuel WHMIS
Stores - Transit
(CWIN90)
Transit Dept (8050) > Windex Powerized Johnson Diversey 90122 Matched English Canada
421 Osborne (8080) > Glass Cleaner (RTU) WHMIS
Stores - Transit
(CWIN90)
Transit Dept (8050) > WorkCentre 6400 Xerox Corporation Matched English Canada
421 Osborne (8080) > Toner WHMIS
Stores - Transit
(CWIN90)
Transit Dept (8050) > Workcentre Xerox Corporation 6R1509 Matched English Canada
421 Osborne (8080) > 7525/7530/7535/7545/7 WHMIS
Stores - Transit 556 Toner
(CWIN90)
Transit Dept (8050) > Wynn’s Heavy Duty Wynn's A4701 Matched English Canada
421 Osborne (8080) > Universal Cooling WHMIS
Stores - Transit System Flush
(CWIN90)
Transit Dept (8050) > XALT Superior Lithium Dow Kokam LLC 4343 Matched English Canada
421 Osborne (8080) > Polymer Battery WHMIS
Stores - Transit
(CWIN90)
Transit Dept (8050) > Xk2 Zep Manufacturing 6745 Matched English Canada
421 Osborne (8080) > Company of Canada WHMIS
Stores - Transit
(CWIN90)
Transit Dept (8050) > Yukon Gold Tiger Calcium Services Matched English Canada
421 Osborne (8080) > Inc. WHMIS
Stores - Transit
(CWIN90)
Transit Dept (8050) > Zep Smoke Screen Zep Manufacturing 0187 Matched English Canada
421 Osborne (8080) > Company WHMIS
Stores - Transit
(CWIN90)
Transit Dept (8050) > Zep Spirit II Ready-To- Zep Manufacturing 0679 Matched English Canada
421 Osborne (8080) > Use Detergent Company of Canada WHMIS
Stores - Transit Disinfectant
(CWIN90)
Transit Dept (8050) > Lithium Ion Secondary Mitsubishi Heavy P140 In Progress English Canada
421 Osborne (8080) > Battery Industries Ltd. WHMIS
Stores - Transit
(CWIN90)
Transit Dept (8050) > Aircraft Paint Stripper US Chemical & Plastic 495-1 Deactivated
421 Osborne (8080) > Cie
Stores - Transit
(CWIN90)
Transit Dept (8050) > Argon (Gas/Liquid) Air Liquide Canada Inc Deactivated
421 Osborne (8080) >
Stores - Transit
(CWIN90)
Transit Dept (8050) > Blueshield 6/ Blueshield Air Liquide Canada Inc Deactivated
421 Osborne (8080) > 7/ Blueshield 8/
Stores - Transit Blueshield 21/ Aflux
(CWIN90)
Transit Dept (8050) > Cat Cement Chemtool Inc. Carterpillar Deactivated
421 Osborne (8080) >
Stores - Transit
(CWIN90)
Transit Dept (8050) > DuPont SUVA 134a DuPont-Mitsui 130000000349 Deactivated
421 Osborne (8080) > Refrigerant Fluorochemicals Co.
Stores - Transit Ltd.
(CWIN90)
Transit Dept (8050) > Envirotac 2 Enviromental Products Deactivated
421 Osborne (8080) > & Applications
Stores - Transit
(CWIN90)
Transit Dept (8050) > Freylube Prema Freylube Division SL-078 Deactivated
421 Osborne (8080) >
Stores - Transit
(CWIN90)
Transit Dept (8050) > G.b.p. Reducer Sherwin-Williams R7K981 Deactivated
421 Osborne (8080) > Activator Automotive Finishes
Stores - Transit
(CWIN90)
Transit Dept (8050) > Kubota Premium UDT Shell Canada Products Deactivated
421 Osborne (8080) > Ltd.
Stores - Transit
(CWIN90)
Transit Dept (8050) > KUBOTA SAE 10W-30 Ashland KU10205 Deactivated
421 Osborne (8080) > ENGINE OIL
Stores - Transit
(CWIN90)
Transit Dept (8050) > Lubriplate No. 105 Fiske Brothers Refining 21421 Deactivated
421 Osborne (8080) > Co./ Lubriplate
Stores - Transit
(CWIN90)
Transit Dept (8050) > Shopworks Bioclean Rochester Midland Ltd. Deactivated
421 Osborne (8080) >
Stores - Transit
(CWIN90)
Transit Dept (8050) > Stokolan Stockhausen Inc. Deactivated
421 Osborne (8080) >
Stores - Transit
(CWIN90)
Transit Dept (8050) > SUVA 134a (Auto) Dupont 811972 Deactivated
421 Osborne (8080) >
Stores - Transit
(CWIN90)
Transit Dept (8050) > SUVA 134a refrigerant E.I. du Pont Canada 130000000349 Deactivated
421 Osborne (8080) > Company
Stores - Transit
(CWIN90)
Transit Dept (8050) > Terj Kf#3 Johnson Diversey Deactivated
421 Osborne (8080) > Canada
Stores - Transit
(CWIN90)
Transit Dept (8050) > Zep Spirit Ii Ready-To- Zep Manufacturing Deactivated
421 Osborne (8080) > Use Detergent Company
Stores - Transit Disinfectant
(CWIN90)
Transit Dept (8050) > Acrysol Body Solvent Lawson Products Inc P60170 Matched English Canada
421 Osborne (8080) > 16 Oz NW WHMIS
Washrack (CWIN91)
Transit Dept (8050) > Air Brake Antifreeze Nemco Resources 0780 Matched English Canada
421 Osborne (8080) > WHMIS
Washrack (CWIN91)
Transit Dept (8050) > Ajax Cleansing Powder- Colgate-Palmolive 200000017779 Matched English Canada
421 Osborne (8080) > Regular Company WHMIS
Washrack (CWIN91)
Transit Dept (8050) > Aromx 60 Swish Maintenance Ltd. 8960 Matched English Canada
421 Osborne (8080) > WHMIS
Washrack (CWIN91)
Transit Dept (8050) > Autorf Sspr 6Pk Farm Rust Oleum 249275 Matched English Canada
421 Osborne (8080) > Yellow (John Deere) Corporation WHMIS
Washrack (CWIN91) (249275)
Transit Dept (8050) > BD7-77 Plus Penetrant Barnes Group Inc. BD1108 Matched English Canada
421 Osborne (8080) > WHMIS
Washrack (CWIN91)
Transit Dept (8050) > Bio-Circle L J. Walter Company Ltd. Matched English Canada
421 Osborne (8080) > WHMIS
Washrack (CWIN91)
Transit Dept (8050) > Blue Marvel 2000 Zep Manufacturing G244 Matched English Canada
421 Osborne (8080) > Company of Canada WHMIS
Washrack (CWIN91)
Transit Dept (8050) > Catchmaster Brand Atlantic Paste & Glue Matched English Canada
421 Osborne (8080) > Products (Insect and Co. Inc WHMIS
Washrack (CWIN91) Rodent Glue Traps and
Monitors)
Transit Dept (8050) > Citra Solve Aerosol Share Corporation Matched English Canada
421 Osborne (8080) > Canada Chemical Ltd. WHMIS
Washrack (CWIN91)
Transit Dept (8050) > Classique Gentle Lotion Avmor Ltd. 1213 Matched English Canada
421 Osborne (8080) > Unitip WHMIS
Washrack (CWIN91)
Transit Dept (8050) > D&E (All) Irving Blending & Matched English Canada
421 Osborne (8080) > Packaging WHMIS
Washrack (CWIN91)
Transit Dept (8050) > D-15 Insect Repellent Quixtar Canada 602643 Matched English Canada
421 Osborne (8080) > Corporation WHMIS
Washrack (CWIN91)
Transit Dept (8050) > Diesel Exhaust Fluid Brenntag Canada Inc. 00070093 Matched English Canada
421 Osborne (8080) > WHMIS
Washrack (CWIN91)
Transit Dept (8050) > Diesel Fuel Petro-Canada W104 Matched English Canada
421 Osborne (8080) > WHMIS
Washrack (CWIN91)
Transit Dept (8050) > Dry All Origination Matched English Canada
421 Osborne (8080) > WHMIS
Washrack (CWIN91)
Transit Dept (8050) > Dupli-Color Acrylic Dupli-Color Products DA1670 Matched English Canada
421 Osborne (8080) > Enamel Aerosol Pain, WHMIS
Washrack (CWIN91) Gloss White (OSHA
White)
Transit Dept (8050) > Dupli-Color Acrylic Dupli-Color Products DAL1607 Matched English Canada
421 Osborne (8080) > Lacquer Aerosol Paint, WHMIS
Washrack (CWIN91) Flat Black
Transit Dept (8050) > duron E 15W-40 Petro Canada Matched English Canada
421 Osborne (8080) > WHMIS
Washrack (CWIN91)
Transit Dept (8050) > Extra Oil Heavy Duty Prairie West Industrial 14808-60-7 Matched English Canada
421 Osborne (8080) > Floor Sweeping Ltd WHMIS
Washrack (CWIN91) Compound
Transit Dept (8050) > Floor-Dry, Solid-a-Sorb, EP Minerals, LLC Matched English Canada
421 Osborne (8080) > MP Grades WHMIS
Washrack (CWIN91)
Transit Dept (8050) > Fluid Film Aerosol (AS) Eureka Chemical Matched English Canada
421 Osborne (8080) > Company WHMIS
Washrack (CWIN91)
Transit Dept (8050) > Gasoline, Unleaded Petro-Canada Matched English Canada
421 Osborne (8080) > WHMIS
Washrack (CWIN91)
Transit Dept (8050) > Glance Foaming Glass Diversey Lever Matched English Canada
421 Osborne (8080) > & Multi-Surface Cleaner WHMIS
Washrack (CWIN91)
Transit Dept (8050) > Graffiti & Spray Paint ITW Dymon 07816 Matched English Canada
421 Osborne (8080) > Remover WHMIS
Washrack (CWIN91)
Transit Dept (8050) > Graffiti wipes Total Solutions 1447 Matched English Canada
421 Osborne (8080) > WHMIS
Washrack (CWIN91)
Transit Dept (8050) > Green Link Bowl Zep Manufacturing P848 Matched English Canada
421 Osborne (8080) > Cleaner Company of Canada WHMIS
Washrack (CWIN91)
Transit Dept (8050) > Hi-Liter Markers Avery Dennison Matched English Canada
421 Osborne (8080) > Stationery WHMIS
Washrack (CWIN91)
Transit Dept (8050) > Jet Clean Simoniz USA, Inc. J0395 Matched English Canada
421 Osborne (8080) > WHMIS
Washrack (CWIN91)
Transit Dept (8050) > Jet Clean F.S. EX JT Zep Manufacturing P241 Matched English Canada
421 Osborne (8080) > #1 Company of Canada WHMIS
Washrack (CWIN91)
Transit Dept (8050) > Johnsens Brake Parts Technical Chemical 2420 Matched English Canada
421 Osborne (8080) > Cleaner Company WHMIS
Washrack (CWIN91)
Transit Dept (8050) > Kolor Kut Modified Kolor Kut Products Matched English Canada
421 Osborne (8080) > Water Finding Paste (M- Company WHMIS
Washrack (CWIN91) 3)
Transit Dept (8050) > KRYLON Industrial Sherwin Williams 03621 Matched English Canada
421 Osborne (8080) > QUIK-MARK Solvent- WHMIS
Washrack (CWIN91) Based Inverted Marking
Paint (APWA), Blue

Transit Dept (8050) > Lavo-6 Bleach Lavo Matched English Canada
421 Osborne (8080) > WHMIS
Washrack (CWIN91)
Transit Dept (8050) > Lock De-Icer w/ Teflon K-G Spray-Pak INC 03405-1132, 38-1132-2 Matched English Canada
421 Osborne (8080) > WHMIS
Washrack (CWIN91)
Transit Dept (8050) > Lps Noflash Nu Electro LPS Laboratories Inc. 04015 Matched English Canada
421 Osborne (8080) > Contact Cleaner WHMIS
Washrack (CWIN91)
Transit Dept (8050) > Maxforce Roach Killer Bayer Crop Science Inc Matched English Canada
421 Osborne (8080) > Bait Gel Syringe WHMIS
Washrack (CWIN91)
Transit Dept (8050) > Mercon SP Automatic Ford Canada 175325 Matched English Canada
421 Osborne (8080) > Transmission Fluid WHMIS
Washrack (CWIN91)
Transit Dept (8050) > Moovit (Aerosol) Lloyds Laboratories Inc. 11008 Matched English Canada
421 Osborne (8080) > WHMIS
Washrack (CWIN91)
Transit Dept (8050) > Og 73 Share Corporation Matched English Canada
421 Osborne (8080) > Canada Chemical Ltd. WHMIS
Washrack (CWIN91)
Transit Dept (8050) > Prairie Extract Prairie West Industrial Matched English Canada
421 Osborne (8080) > Ltd. WHMIS
Washrack (CWIN91)
Transit Dept (8050) > Pyro-Chem ABC Tyco Fire Protection 2001-2-012 ANa Matched English Canada
421 Osborne (8080) > Products WHMIS
Washrack (CWIN91)
Transit Dept (8050) > Qd Contact Cleaner CRC Industries 72130 Matched English Canada
421 Osborne (8080) > (Aerosol) WHMIS
Washrack (CWIN91)
Transit Dept (8050) > Quato 44 Swish Maintenance Ltd. 9807 Matched English Canada
421 Osborne (8080) > WHMIS
Washrack (CWIN91)
Transit Dept (8050) > Red Devil Degreaser ECP Incorporated Matched English Canada
421 Osborne (8080) > WHMIS
Washrack (CWIN91)
Transit Dept (8050) > Reducer PPG Automotive DT860 Matched English Canada
421 Osborne (8080) > Refinish WHMIS
Washrack (CWIN91)
Transit Dept (8050) > SC 400 J. Walter Inc. 53-G 513 Matched English Canada
421 Osborne (8080) > WHMIS
Washrack (CWIN91)
Transit Dept (8050) > Sharpie Pen Sanford, L.P. 071408 Matched English Canada
421 Osborne (8080) > WHMIS
Washrack (CWIN91)
Transit Dept (8050) > Smoke Screen Aerosol Zep Manufacturing 0187 Matched English Canada
421 Osborne (8080) > Company of Canada WHMIS
Washrack (CWIN91)
Transit Dept (8050) > Stokolan Classic Cream Deb USA, Inc. 33869-US, 33886-US, Matched English Canada
421 Osborne (8080) > PN10087250-US WHMIS
Washrack (CWIN91)
Transit Dept (8050) > STP08001 , STP08002 Kleinmann GmbH 775488 (model 16982) Matched English Canada
421 Osborne (8080) > , STP15101 Screen WHMIS
Washrack (CWIN91) Cleaning Wipes, Tub

Transit Dept (8050) > Super Duster 134 and MG Chemicals Ltd. 402A-140G Matched English Canada
421 Osborne (8080) > Super Duster 134 Plus WHMIS
Washrack (CWIN91)
Transit Dept (8050) > Super Lube 11 OZ Dri- Synco Chemical 11016 Matched English Canada
421 Osborne (8080) > Film Lubricant with Corporation WHMIS
Washrack (CWIN91) Syncolon PTFE
Transit Dept (8050) > Trapper Rat Glue, Bell Laboratories Inc. Matched English Canada
421 Osborne (8080) > Mouse Glue WHMIS
Washrack (CWIN91)
Transit Dept (8050) > Travabon Stockhausen Inc. Matched English Canada
421 Osborne (8080) > WHMIS
Washrack (CWIN91)
Transit Dept (8050) > Trisodium Phosphate Cleartech Industries Inc Matched English Canada
421 Osborne (8080) > WHMIS
Washrack (CWIN91)
Transit Dept (8050) > TSP General Purpose Dap Inc. 070798630017 Matched English Canada
421 Osborne (8080) > Cleaner WHMIS
Washrack (CWIN91)
Transit Dept (8050) > Uvex Clear Lens Honeywell Safety S461 Matched English Canada
421 Osborne (8080) > Cleaner Products WHMIS
Washrack (CWIN91)
Transit Dept (8050) > Uvex Clear Lens Honeywell Safety S468 Matched English Canada
421 Osborne (8080) > Cleaning Towelette Products WHMIS
Washrack (CWIN91)
Transit Dept (8050) > Vanish Snow & Ice HLF Diversified Inc. Matched English Canada
421 Osborne (8080) > Melter WHMIS
Washrack (CWIN91)
Page 1 of 5
Sika Canada Inc. MATERIAL SAFETY DATA SHEET

SECTION I: PRODUCT INFORMATION

® ®
PRODUCT: Sika Aktivator-205 (Old Sika Cleaner-205) REVISION DATE: November 20, 2014

USAGE: CLEANING SOLUTION

MANUFACTURER/SUPPLIER: SIKA CANADA INC.


601, avenue Delmar
Pointe Claire, QC
H9R 4A9

EMERGENCY TELEPHONE NUMBER: CANUTEC (collect) (613) 996-6666

TDG CLASSIFICATION: Isopropanol Solution WHMIS Classification: B2, D2B


UN NUMBER: 1219 Class: 3
Packaging Group: II

SECTION II: HAZARDOUS INGREDIENTS

LD50 (mg/kg) LC50


Hazardous ingredients % T.L.V. # CAS
(route, species) (species, route)

ACGIH 3
ISOPROPYL 66 100mg/m /4h
60-100 400 ppm (TWA) 67-63-0 5 045 (oral, rat)
ALCOHOL (rat)
500 ppm (STEL)

SECTION III: PHYSICAL CHARACTERISTICS

Physical State: Liquid (isopropanol) Boiling Point: 82°C (isopropanol)


Appearance and Odor: Clear and colorless liquid, rubbing Freezing Point: Not Established
alcohol odor Density: 0.8 g/ml
Odor Threshold: Not Established Water Solubility: Miscible in water (isopropanol)
Evaporation Rate: 2.83 (isopropanol) pH: No information found (isopropanol)
Vapor Density: 2,1 (isopropanol) % volatile: 100 (isopropanol)
Vapor Pressure: 44 @ 25°C (isopropanol) Water/Oil Distribution: Not Established
Page 2 of 5
Sika Canada Inc. MATERIAL SAFETY DATA SHEET

® ®
PRODUCT: Sika Aktivator-205 (Old Sika Cleaner-205)

SECTION IV: FIRE AND EXPLOSION HAZARDS

Flammability: Yes TDG inflammability Class: 3 (isopropanol)


Flammable upper limits (% vol.): 12.7 (isopropanol)
If Yes, under what conditions: Flame, spark Flammable lower limits (% vol.): 2.0 (isopropanol)
Flash Point (method used): 12°C (isopropanol)
Auto-ignition temperature: 399ºC (isopropanol)
Extinguishing methods: Foam, dry chemical Dangerous Combustion Products: CO (isopropanol)
products, CO2, water for
large flames.
Protect from mechanical impact: No

Special Methods: Firefighters must wear Protect from static discharge: No


complete protective
clothing with NIOSH
respiratory equipment.

SECTION V: REACTIVITY DATA

Chemical stability: Yes Dangerous decomposition products: CO.

If not, under what conditions:

Incompatibility with other material: Yes Polymerization Risks: No

If Yes, which ones: Acid, strong


oxidizer, amine,
aluminum at high
temperature.

Incompatibility with pure Isopropanol:


strong oxidizers, acetaldehyde, acids, chlorine, ethylene
oxide, hydrogen-palladium combination, hydrogen
peroxide-sulfuric acid combination, potassium tert-
butoxide, hypochlorous acid, isocyanates, nitroform,
phosgene, aluminum, oleum and perchloric acid.
Page 3 of 5
Sika Canada Inc. MATERIAL SAFETY DATA SHEET

® ®
PRODUCT: Sika Aktivator-205 (Old Sika Cleaner-205)

SECTION VI: TOXIC PROPERTIES

ROUTE OF ENTRY / CONTACT

Eyes: Irritating, splashes cause severe irritation, Carcinogenicity: Not established


possible corneal burns and eye damage.

Toxic effects
Skin: Irritating. Contact may result in dermatitis. on reproduction: Not established
May cause skimming of skin’s fat.

Teratogenicity: Not established


Inhalation: Vapor or mist from this product may
cause irritation.
Mutagenicity: Not established

Ingestion: May cause nausea, vomiting, fainting,


diarrhea, lung damage, gastro-intestinal Product with synergistic
system disorder, constipation. The single effects: Not established
lethal dose for a human adult = 250 ml

Over exposure may cause breathing difficulties,


headaches, nausea, vomiting, lack of coordination,
fainting. May aggravate respiratory, skin, eye, and lung
problems.

Aggravation of pre-existing condition, skin disorder,


impaired liver kidney, or pulmonary function may be more
susceptible to the effects of this agent.

An acute or chronic exposure will increase the toxic effects mentioned in this section and may aggravate respiratory
problems.
Page 4 of 5
Sika Canada Inc. MATERIAL SAFETY DATA SHEET

® ®
PRODUCT: Sika Aktivator-205 (Old Sika Cleaner-205)

SECTION VII: PREVENTIVE MEASURES

PERSONAL PROTECTIVE EQUIPMENT OTHERS

Gloves: Use chemical resistant gloves. Ventilation: Sufficient ventilation required.

Respiratory equipment: NIOSH approved mask with Procedure in case


organic vapor cartridge. of leaks: Absorb with sand or other
absorbent material.
Eyes: Full-face mask and goggles
Handling and
Shoes: Leather Equipment methods: Avoid skin, eye and clothing
contact
Clothing: Rubber Apron and lab coat
Warehouse
Other: Eye wash station, shower Requirements: Keep all containers closed in a
cool, dry and well ventilated area.
Keep away from heat and open
flame.

Special Shipping
Instructions: See TDG class

Waste Disposal: Dispose of sand and rinse water


according to municipal, provincial
or federal laws for disposal of
chemicals.
Page 5 of 5
Sika Canada Inc. MATERIAL SAFETY DATA SHEET

® ®
PRODUCT: Sika Aktivator-205 (Old Sika Cleaner-205)

SECTION VIII: FIRST AID

Skin : Remove contaminated clothing and shoes.


Wash immediately with plenty of water.
Wash clothing before re-wearing.
Consult a physician if required.

Eyes : Rinse eyes immediately with plenty of water for several minutes, while holding
eyelids wide open, to ensure a proper wash.
See a physician if required.

Inhalation : In the case of overexposure, evacuate to fresh air.


Consult a physician if required.

Ingestion : Drink plenty of water. Do not induce vomiting.


Do not give anything by mouth to an unconscious person.
See a physician immediately.

SECTION IX: PREPARATION INFORMATION

Prepared By: R & D of Sika Canada Inc.


Telephone #: (514) 697-2610
Fax #: (514) 694-2792

Notice To Reader

The information contained in this Material Safety Data Sheet applies only to the actual Sika Canada product identified and described herein. This
information is not intended to address, nor does it address the use or application of the identified Sika product in combination with any other material,
product or process. All of the information set forth herein is based on technical data regarding the identified product that Sika believes to be reliable
as of the date hereof. Prior to each use of any Sika product, the user must always read and follow the warnings and instructions on the product's
current Product Data Sheet, product label and Material Safety Data Sheet for each Sika product, which are available at web site and/or telephone
number listed in Section IX of this MSDS.

SIKA MAKES NO WARRANTIES EXPRESS OR IMPLIED AND ASSUMES NO LIABILITY ARISING FROM THIS INFORMATION OR ITS USE.
SIKA SHALL NOT BE LIABLE UNDER ANY LEGAL THEORY FOR SPECIAL OR CONSEQUENTIAL DAMAGES AND SHALL NOT BE
RESPONSIBLE FOR THE USE OF THIS PRODUCT IN A MANNER TO INFRINGE ON ANY PATENT OR ANY OTHER INTELLECTUAL
PROPERTY RIGHTS HELD BY OTHERS.

All sales of Sika products are subject to its current terms and conditions of sale available at www.sika.ca or 514-697-2610.

AQ 191 A
Date: 2012/02/01
App: S.G.
Page 1 of 5
Sika Canada Inc. MATERIAL SAFETY DATA SHEET

SECTION I: PRODUCT INFORMATION

® th
PRODUCT: Sikaflex -252 REVISION DATE: February 24 , 2015

USAGE: ONE COMPONENT URETHANE BASED ADHESIVE / SEALANT

SUPPLIER: SIKA CANADA INC.


601, avenue Delmar
Pointe Claire, QC
H9R 4A9

EMERGENCY TELEPHONE NUMBER: CANUTEC (collect) (613) 996-6666

TDG CLASSIFICATION: Not Regulated WHMIS Classification: B3, D2A


UN NUMBER: Not Established Class: Not Applicable
Packaging Group: Not Applicable

SECTION II: HAZARDOUS INGREDIENTS

LD50 (mg/kg) LC50


Hazardous ingredients % T.L.V. # CAS
(route, species) (species, route)

ACGIH
XYLENE 1-5 100ppm (TWA) 1330-20-7 4300 (oral, rat) 6350ppmh/4H
150ppm (STEL)

POLYOL AND
ISOCYANATE 30-60 Not Established Not Available Not Established Not Established
PREPOLYMER

AMORPHOUS SILICA 5-10 Not Available 7631-86-9 Not Available Not Available

METHYLENE ACGIH
3
369mg/m /4H
BIS PHENYL 0,1-1,0 101-68-8 31 600 (oral, rat)
ISOCYANATE 0,005 ppm (rat)

SECTION III: PHYSICAL CHARACTERISTICS

Physical State: Paste Boiling Point: Not Established


Appearance and Odor: Various color, odorless Freezing Point: Not Established
Density: 1,21 g/ml
Odor Threshold: Not Established Water Solubility: Not Established
Evaporation Rate: Not Established pH: Not Established
Vapor Density: Not Established % volatile: Not Established
Vapor Pressure: Not Established Water/Oil Distribution: Not Established
Page 2 of 5
Sika Canada Inc. MATERIAL SAFETY DATA SHEET

®
PRODUCT: Sikaflex -252

SECTION IV: FIRE AND EXPLOSION HAZARDS

Flammability: No TDG inflammability Class: Not Regulated


Flammable upper limits (% vol.): Not Established
If Yes, under what conditions: Flammable lower limits (% vol.): Not Established
Flash Point (method used): > 80°C (TCC)
Extinguishing methods: Foam, dry chemical Auto-ignition temperature: Not Established
products, CO2, water for Dangerous Combustion Products: Carbon oxides,
large flames. Nitrogen oxide.

Special Methods: Firefighters must wear


complete protective Protect from mechanical impact: No
clothing with respiratory
equipment and they must Protect from static discharge: No
protect any exposed skin.
Heated isocyanates react
strongly with water.

SECTION V: REACTIVITY DATA

Chemical stability: Yes Dangerous decomposition products: Carbon oxides,


Nitrogen oxide,
If not, under what conditions:

Incompatibility with other material: Yes Polymerization Risks: No

If Yes, which ones: Acid, strong


oxidizer, amine.
Page 3 of 5
Sika Canada Inc. MATERIAL SAFETY DATA SHEET

®
PRODUCT: Sikaflex -252

SECTION VI: TOXIC PROPERTIES

ROUTE OF ENTRY / CONTACT

Eyes: Irritating. Carcinogenicity: Not Established

Skin: Irritating. Contact may result in dermatitis, Toxic effects


allergic reactions, and sensitization. on reproduction: Not Established

Inhalation: Vapor or mist from this product may Teratogenicity: Xylene is classified as a
cause irritation. development toxicant
(Embryo toxin)

Ingestion: May cause nausea, vomiting, fainting,


diarrhea, lung damage, G.I. system Mutagenicity: Not Established
disorder, constipation, ulcers.

Product with synergistic


effects: Not Established

Over exposure may cause breathing difficulties,


sensitization, headaches, nausea, vomiting. May
aggravate respiratory, skin, eye, lung problems and
allergies.

If the product is applied according to the manufacturer,


none of these symptoms should be encountered.

A person who is sensitized to isocyanate may have a


reaction with a level of isocyanate well below the T.L.V.

Xylene is a central nervous system depressor and in rare


cases, may cause a sensitization of the heart muscle
causing arrhythmia.

An acute or chronic exposure will increase the toxic effects mentioned in this section and may aggravate respiratory
problems. An over exposure may cause death.
Page 4 of 5
Sika Canada Inc. MATERIAL SAFETY DATA SHEET

®
PRODUCT: Sikaflex -252

SECTION VII: PREVENTIVE MEASURES

PERSONAL PROTECTIVE EQUIPMENT OTHERS

Gloves: Use chemical resistant gloves. Ventilation: Sufficient ventilation required

Respiratory equipment: Use a NIOSH approved respirator Procedure in case


if the TLV is exceeded. of leaks: Absorb with sand or other
absorbent material.
Eyes: Full face mask or safety glasses
Handling and Equipment
Shoes: Leather methods: Avoid skin, eye and clothing
contact
Clothing: Rubber Apron
Warehouse
Other: Eye wash station, shower Requirements: Keep all containers closed in a
cool, dry and well ventilated area.
Keep away from heat and open
flame.

Special Shipping
Instructions: See TDG class

Waste Disposal: Dispose of sand and rinse water


according to municipal, provincial
or federal laws for disposal of
chemical.
Page 5 of 5
Sika Canada Inc. MATERIAL SAFETY DATA SHEET

®
PRODUCT: Sikaflex -252

SECTION VIII: FIRST AID

Skin : Remove contaminated clothing and shoes.


Wash immediately with plenty of water.
Wash clothing before re-wearing.
Consult a physician if required.

Eyes : Rinse eyes immediately with plenty of water for several minutes, while holding
eyelids wide open, to ensure a proper wash.
See a physician immediately.

Inhalation : In the case of overexposure, evacuate to fresh air.


Consult a physician if required.

Ingestion : Drink plenty of water. Do not induce vomiting.


Do not give anything by mouth to an unconscious person.
See a physician immediately.

SECTION IX: PREPARATION INFORMATION

Prepared By: R & D of Sika Canada Inc.


Telephone #: (514) 697-2610
Fax #: (514) 694-2792

Notice To Reader

The information contained in this Material Safety Data Sheet applies only to the actual Sika Canada product identified and described herein. This
information is not intended to address, nor does it address the use or application of the identified Sika product in combination with any other material,
product or process. All of the information set forth herein is based on technical data regarding the identified product that Sika believes to be reliable
as of the date hereof. Prior to each use of any Sika product, the user must always read and follow the warnings and instructions on the product's
current Product Data Sheet, product label and Material Safety Data Sheet for each Sika product, which are available at web site and/or telephone
number listed in Section IX of this MSDS.

SIKA MAKES NO WARRANTIES EXPRESS OR IMPLIED AND ASSUMES NO LIABILITY ARISING FROM THIS INFORMATION OR ITS USE.
SIKA SHALL NOT BE LIABLE UNDER ANY LEGAL THEORY FOR SPECIAL OR CONSEQUENTIAL DAMAGES AND SHALL NOT BE
RESPONSIBLE FOR THE USE OF THIS PRODUCT IN A MANNER TO INFRINGE ON ANY PATENT OR ANY OTHER INTELLECTUAL
PROPERTY RIGHTS HELD BY OTHERS.

All sales of Sika products are subject to its current terms and conditions of sale available at www.sika.ca or 514-697-2610.

AQ 191 A
Date: 2012/02/01
App: S.G.
Revision date: 18/0612015 Revision: 1
1.

SAFETY DATA SHEET


Stokolan® intensive repair

SECTION 1 Identification of the substance!mbcture and of the oornpany/undertaldng


1
1.1. Product identifier
Product name Stokolan® intensive repair

Product number 99036413,99036414,99036415,99036416,99042843,9903641 7,9903641 89903641 9990364


20

Internal identification M 961

1.2. Relevant identified uses of the substance or mixture and uses advised against
Identified uses Hand Cream

1.3. Details of the supplier of the safety data sheet


Supplier Deb Ltd
Denby Hall Way
Denby
Derbyshire
DE5 8JZ
Main Tel. 01773 855100
Technical Tel 01773 855105
[email protected]

1.4. Emergency telephone number


Emergency telephone National Poisons Information Service (UK) 0844 8920111

[SECTION 2 Hazards identification

2.1. Classification of the substance or mixture


Classification
Physical hazards Not Classified

Health hazards Not Classified


Environmental hazards Not Classified

Classification (67!5481EEC or
I 9991451EC)

2.2. Label elements


Hazard statements NC Not Classified

2.3. Other hazards


This product does not contain any substances classified as PBT or vPvB.

[SECTION 3 Composiboniinformabon on ingredients ‘

3.2. Mixtures

116
Revision date: 18/06/2015 Revision: I

Stokolan® intensive repair

INCI AQUA (WATER)


VITIS VINIFERA SEED OIL
CAPRYLIC/CAPRIC TRIGLYCERIDE
DICAPRYLY ETHER
POLYGLYCERYL-4 DI ISOSTEARATE/POLYHYDROXYSTEARATE/SEBACATE
ISOPRPYL PALMITATE
UREA
SORBITOL
ZINC SULFATE
GINKGO BILOBA LEAF EXTRACT
ALLANTOIN
TOCOPHEROL
CERA ALBA
GLYCERIN
CHOLESTEROL
CERAMIDE NP
CERAMIDE NS
CERAMIDEEOS
CERAMIDE EOP
CERAMIDE AP
CAPROOYL PHYTOSPHINGOSINE
CAPROOYL SPHINGOSINE
HYDROGENATED CASTOR OIL
CERA MICROCRISTALLINA/PARAFFIN
CETYL ALCOHOL
BEHENIC ACID
CETEARETH-25
PHENOXYETHANOL
BENZOIC ACID
DEHYDROACETIC ACID
ETHYLHEXYLGLYCERIN
TRISODIUM DICARBOXYMETHYL ALANINATE
ALCOHOL
PROPYLENE GLYCOL
ASCORBYL PALMITATE
ASCORBIC ACID
CITRIC ACID
LACTIC ACID
PARFUM (FRAGRANCE)

SECTION 4 First aid measures

4.1. Desciiption of first aid measures


Inhalation Not relevant. Unlikely route of exposure as the product does not contain volatile substances.

Ingestion Rinse mouth thoroughly with water. Get medical attention if any discomfort continues.

Skin contact Not relevant.

Eye contact Remove any contact lenses and open eyelids wide apart. Continue to rinse for at least 15
minutes. Continue to rinse for at least 15 minutes. Get medical attention promptly if symptoms
occur after washing.

4.2. Most important symptoms and effects, both acute and delayed
Inhalation No specific symptoms known.

Ingestion No specific symptoms known.

2/6
Revision date: 1810612015 Revision: I

Stokolan® intensive repair

Skin contact Does not decompose when used and stored as recommended.

Eye contact May cause temporary eye irritation.

4.3. Indication of any immediate medical attention and special treatment needed
Notes for the doctor No specific recommendations.

SECTION 5 Firefighting measures

5.1. Extinguishing media


Suitable extinguishing media The product is not flammable. Use fire-extinguishing media suitable for the surrounding fire.

5.2. Special hazards arising from the substance or mixture


Hazardous combustion No known hazardous decomposition products.
products

5.3. Advice for firefighters


Protective actions during No specific firefighting precautions known.
firefighting

SECTION 6: Accidental release measures


6.1. Personal precautions, protective equipment and emergency procedures
Personal precautions Avoid contact with eyes.

6.2. Environmental precautions


Environmental precautions Not considered to be a significant hazard due to the small quantities used.

6.3. Methods and material for containment and deaning up


Methods for deaning up Flush away spillage with plenty of water. Avoid contamination of ponds or watercourses with
washing down water. Absorb spillage with non-combustible, absorbent material. Do not
discharge into drains or watercourses or onto the ground.

6.4. Reference to other sections


Reference to other sections For waste disposal, see Section 13.

SECTION 7 Handling and storage

7.1. Precautions for safe handling


Usage precautions Avoid contact with eyes.

7.2. Conditions for safe storage, induding any incompatibilities


Storage precautions Store in closed original container at temperatures between 0°C and 30°C.

7.3. Specific end use(s)


Specific end use(s) The identified uses for this product are detailed in Section 1.2.

SECTION 8: Exposure Controls!personal protection ;

I
8.1. Control parameters
Ingredient comments No exposure limits known for ingredient(s).

8.2. Exposure controls


Appropriate engineering Not relevant.
controls

3/6
Revision date: 1810612015 Revision: 1

Stokolan® intensive repair

Eyelface protection Not relevant. C


Hygiene measures Not relevant.
Respiratory protection No specific recommendations.

[SECTION 9 Physical and Chemical Propecties

9.1. Information on basic physical and chemical properties


Appearance Liquid

9.2. Other information


[SECTION 10: StabilIty and reactivity

10.1. Reactivity
Reactivity There are no known reactivity hazards associated with this product.

10.2. Chemical stability


Stability Stable at normal ambient temperatures.

10.3. Possibility of hazardous reactions


Possibility of hazardous None known.
reactions

10.4. Conditions to avoid


Conditions to avoid There are no known conditions that are likely to result in a hazardous situation.

10.5. Incompatible materials


Materials to avoid No specific material or group of materials is likely to react with the product to produce a
hazardous situation.
C
10.6. Hazardous decomposition products
Hazardous decomposition Does not decompose when used and stored as recommended.
products

[SECTION 11 ToxicologIcal Information

11.1. Information on toxicological effects

Inhalation No specific health hazards known.

Ingestion May cause discomfort if swallowed.

Skin contact Skin irritation should not occur when used as recommended.

Eye contact May cause temporary eye irritation.

SECTiON 12: Ecological Information

Ecotoxicity Not regarded as dangerous for the environment.

12.1. Toxicity
12.2. Persistence and degradability
Persistence and degradability The surfactant(s) contained in this product complies(comply) with the biodegradability criteria
as laid down in Regulation (EC) No. 648/2004 on detergents. Data to support this assertion
are held at the disposal of the competent authorities of the Member States and will be made
available to them at their direct request, or at the request of a detergent manufacturer. C
4/6
Revision date: 18/06/2015 Revision: 1

Stokolan® intensive repair

12.3. Bioaccumulative potential


Bioaccumulative potential No data available on bioaccumulation.

12.4. Mobility in soil


Mobility The product is soluble in water.

12.5. Results of PBT and vPvB assessment


Results of PBT and vPvB This product does not contain any substances classified as PBT or vPvB.
assessment

12.6. Other adverse effects


Other adverse effects None known.

SECTION 13 Disposal considerations

13.1. Waste treatment methods


General information When handling waste, the safety precautions applying to handling of the product should be
considered.

Disposal methods Dispose of waste to licensed waste disposal site in accordance with the requirements of the
local Waste Disposal Authority.

[ SECTION 14: Transport information


Road transport notes Not classified.

Rail transport notes Not classified.

Sea transport notes Not classified.

Air transport notes Not classified.

14.1. UN number
Not applicable.

14.2. UN proper shipping name


Not applicable.

14.3. Transport hazard class(es)


Not applicable.

14.4. Packing group


Not applicable.

14.5. Environmental hazards


Environmentally hazardous substance/marine pollutant
No.

14.6. Special precautions for user


Not applicable.

14.7. Transport in bulk according to Annex II of MARPOL73I78 and the IBC Code
Transport in bulk according to Not applicable.
Annex II of MARPOL 73178
and the IBC Code

5/6
Revision date: 18/06/2015 Revision: I

Stokolan® intensive repair

SECTION 15: Regulatory Infomiation

15.1. Safety, health and environmental regulationsllegislation specific for the substance or mixture
EU legislation This is a cosmetic product regulated by Regulation EC no 1223/2009 (as amended) and is
thus exempt from the Safety Data Sheet requirements of Regulation EC no 453/2010. It is
also exempt from exempt from the classification and labelling rules of the Classification,
Labelling and Packaging Regulation (EC) No 127212008.

Water hazard classification WGK 1

15.2. Chemical safety assessment


No chemical safety assessment has been carried out.

SECTiON 16: Other information

Revision comments Revision of information NOTE: Lines within the margin indicate significant changes from the
previous revision.

Revision date 18/06/2015

Revision 1

SOS number 21025

This information relates only to the specific material designated and may not be valid for such material used in combination
with any other materials or in any process. Such information is, to the best of the company’s knowledge and belief, accurate
and reliable as of the date indicated. However, no warranty guarantee or representation is made to its accuracy, reliability or
completeness. It is the user’s responsibility to satisfy himself as to the suitability of such information for his own particular use.

6/6
Safety Data Sheet according to (EC) No 190712006
Page 1 of5

sdsno. 364025
V002.2
TECHNOMELT KS 250 COOL known as Dorus KS 250 cool Revision: 06.06.2012
printing date: 07.03.2014

SECTION 1: Identification of the substance/mixture and of the compaiiy/uñdertaldn2


1.1. Product identifier
TECHNOMELT KS 250 COOL known as Dorus KS 250 cool
1.2. Relevant identified uses of the substance or mixture and uses advised against
Intended use:
Wood adhesives

1.3. Details of the supplier of the safety data sheet


Henkel AG & Co. KGaA
Henkelstr. 67
40589 Düsseldorf

Germany

Phone: +49(049)211 7970


Fax-no.: +49(049)211 798 4008

[email protected]

1.4. Emergency telephone number


24 Hours Emergency Tel: +44 (0)1442 278497

SECTION
2.1. Classification of the substance or mixture

Classification (CLP):
No data available.

Classification (DPD):
No classification required.

2.2. Label elements

Label elements (CLP):


No data available.
Label elements (DPD):
The product is not subject to classification according to the calculation methods of the ‘General Classification Guideline for
Preparatiom of the EC’ as issued in the last version.

2.3. Other hazards


None if used properly.
MSDS-No.: 364025 TECHNOMELT KS 250 COOL known as Dorus KS 250 cool Page 2 of 5
V002.2

SECTION 3CowposIdbn11nformatIon on Ined1*


General chemical description:
I C
Hotmelt adhesive
Base substances of preparation:
Ethylene-vinyl acetate copolymer

Declaration of the ingredients according to CLP (EC) No 1272/2008:

No data available.

Declaration of ingredients according to DPD (EC) No 1999/45:

Contains no dangerous substances exceeding the limits of the EU-Regulation

I SECTION 4 First aid measures I


4.1. Description of first aid measures

Inhalation:
Move to fresh air, consult doctor if complaint persists.

Skin contact:
Molten product. After skin contact cool down immediately with cold water. Do not remove adherent product. Seek medical
advice.

Eye contact:
After contact with the hot melt: cool with water, seek medical attention.

Ingestion:
Rinse mouth, drink 1-2 glasses of water, do not induce vomiting, consult a doctor.

4.2. Most important symptoms and effects, both acute and delayed
C
No data available.

4.3. Indication of any immediate medical attention and special treatment needed
See section: Description of first aid measures

I SECTION 5;Ffreftgbtlngmeasures

5.1. Extinguishing media


Suitable extinguishing media:
All common extinguishing agents are suitable.

Extinguishing media which must not be used for safety reasons:


High pressure waterjet

5.2. Special hazards arising from the substance or mixture


In case of fire toxic gases can be released.
5.3. Advice for firefighters
Wear self-contained breathing appanstus.
Wear protective equipment.

I SECTION 6: Accidental release measures I


6.1. Personal precautions, protective equipment and emergency procedures
Wear protective equipment.
MSDS-No.: 364025 TECHNOMELT KS 250 COOL known as Dorus KS 250 cool Page 3 of 5
V002.2

6.2. Environmental precautions


Do not empty into drains / surface water / ground water.

6.3. Methods and material for containment and cleaning up


Allow to solidifS’.
Remove mechanically.
Dispose of contaminated material as waste according to Chapter 13.

6.4. Reference to other sections


See advice in chapter 8

SEc’fldN1:
7.1. Precautions for safe handling
Hygiene measures:
Do not eat, drink or smoke while working.
Wash hands before work breaks and after finishing work.

7.2. Conditions for safe storage, including any incompatibilities


Ensure good ventilation/extraction.
Store in sealed original container.

7.3. Specific end use(s)


Wood adhesives

8.1. Control parameters


None
8.2. Exposure controls:

Engineering controls:
Ensure good ventilatiom’extraction.

Respiratory protection:
Suitable breathing mask when there is inadequate ventilation.

Hand protection:
Wear refractive gloves while working with the hot melt.

Eye protection:
Protective goggles

Skin protection:
Wear protective equipment.

Advices to personal protection equipment:


Use only personal protection that’s CE-labelled according to the regulation no. 819 of 19 August 1994.

I SECTION 9: PhysIcal and chemiprapediá


9.1. Information on basic physical and chemical properties
Appearance solid material
granulate
amber
Odor aromatic

pH No data available / Not applicable


Initial boiling point No data available / Not applicable
Flash point No data available / Not applicable
Decomposition temperature No data available / Not applicable
MSDS-No.: 364025 TECHNOMELT KS 250 COOL known as Dorus KS 250 cool Page 4 of 5
V002.2

Vapour pressure No data available / Not applicable


Density I,16g/crn3
(20 °C (68 °F))
Bulk density No data available / Not applicable
Viscosity 13.000 18.000 rnPa.s
-

(Brookfield; Instrument: RVT; 200 °C (392


°F); speed of rotation: 10 mm-I; Spindle No:
27)
Viscosity (kinematic) No data available / Not applicable
Explosive properties No data available / Not applicable
Solubility (qualitative) Insoluble
(20 C (68 CF); Solvent: Water)
Solidification temperature No data available / Not applicable
Melting point No data available / Not applicable
Flammability No data available / Not applicable
Auto-ignition temperature No data available / Not applicable
Explosive limits No data available / Not applicable
Partition coefficient: n-octanollwater No data available / Not applicable
Evaporation rate No data available / Not applicable
Vapor density No data available / Not applicable
Oxidising properties No data available / Not applicable

9.2. Other information

Softening point/range 97 - 105 °C (206.6-221 °F)

SEc .ON 1O $tabiLfty and reactivity


10.1. Reactivity
None if used for intended purpose.

10.2. Chemical stability


Stable under recommended storage conditions.

10.3. Possibility of hazardous reactions


See section reactivity

10.4. Conditions to avoid


None if used for intended purpose.

10.5. Incompatible materials


None if used properly.

10.6. Hazardous decomposition products


At higher temperatures acetic acid may be released.

SECTtON11:
11.1. Information on toxicological effects

General toxicological information:


To the best of our know ledge no hannful effects are to be expected if the product is handled and used properly.

I
General ecological information:
Do not empty into drains, soil or bodies of water.

I I
13.1. Waste treatment methods

(___
MSDS-No.: 364025 TECE-INOMELT KS 250 COOL known as Dorus KS 250 cool Page 5 of 5
V002.2

Product disposal:
The valid EEC waste code numbers are not product-related but are largely source-related. These can be requested from the
manufacturer.

In consultation with the responsible local authority, must be subjected to special treatment.

I SECflONI4:Transportlnfonnàtion
General information:
Not hazardous according to RID, ADR, ADNR, IMDG, IATA-DGR.

SECTION 15: ReuIatoryhzfornat1on

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
VOC content 0%
(VOCV 814.018 VOC regulation
CH)

I 16: Other.informatioñ

Further information:
This information is based on our current level of knowledge and relates to the product in the state in which it is delivered. It is
intended to describe our products from the point of view of safety requirements and is not intended to guarantee any
particular properties.
C

C /
Material Safety Data Sheet

Revision Number: 005.3 Issue date: 03/17/2016

1. PRODUCT AND COMPANY IDENTIFICATION


Product name: TEROSON SI 9160 CL known as IDH number: 475372
SILATECH® SILICONE SEALANT IND
Product type: Silicone Item number: 32389
Region: Canada
Company address: Contact information:
Henkel Corporation Telephone: 905.814.6511
2515 Meadowpine Boulevard MEDICAL EMERGENCY Phone: Poison Control Center
Mississauga, Ontario L5N 6C3 1-877-671-4608 (toll free) or 1-303-592-1711
TRANSPORT EMERGENCY Phone: CHEMTREC
1-800-424-9300 (toll free) or 1-703-527-3887
Internet: www.henkelna.com

2. HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
Physical state: Paste WHMIS hazard class: D.2.B
Color: Translucent
Odor: Acetic acid
WARNING: PROLONGED OR REPEATED CONTACT WITH UNCURED SEALANT MAY
CAUSE EYE, SKIN AND RESPIRATORY TRACT IRRITATION.
REPEATED OR PROLONGED CONTACT MAY CAUSE ALLERGIC SKIN
REACTION.

Relevant routes of exposure: Skin, Inhalation, Eyes

Potential Health Effects

Inhalation: Acetic acid produced during cure may irritate eyes, nose and throat. When heated to
temperatures exceeding 300° F (150° C) in the presence of air, silicones may form
formaldehyde vapors. Formaldehyde is a potential cancer hazard and a known skin and
respiratory sensitizer. Vapors irritate the eyes, nose and throat. Safe handling conditions may
be maintained by keeping formaldehyde vapor concentrations below the OSHA permissible
limit.
Skin contact: Prolonged or repeated contact with uncured sealant may cause skin irritation.
Eye contact: Vapors may irritate eyes. Contact with eyes will cause irritation.
Ingestion: Not expected under normal conditions of use. Not expected to be harmful by ingestion.

Existing conditions aggravated by Eye, skin, and respiratory disorders.


exposure:

This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR
1910.1200).

See Section 11 for additional toxicological information.

3. COMPOSITION / INFORMATION ON INGREDIENTS


Hazardous components CAS NUMBER %
Silicone Resin Proprietary 60 - 100
Distillates (petroleum), hydrotreated middle 64742-46-7 10 - 30
Silicon dioxide 7631-86-9 10 - 30
Triacetoxyethylsilane 17689-77-9 1-5
Methylsilanetriyl triacetate 4253-34-3 1-5

IDH number: 475372 Product name: TEROSON SI 9160 CL known as SILATECH® SILICONE SEALANT IND

Page 1 of 5
Acetic acid 64-19-7 1-5

Exposure to moisture during cure will release 1-5% acetic acid.

4. FIRST AID MEASURES


Inhalation: Move to fresh air. If breathing is difficult, give oxygen. If not breathing, give
artificial respiration. If symptoms develop and persist, get medical attention.

Skin contact: Wipe off paste with paper towel or cloth. Wash with soap and water. If
symptoms develop and persist, get medical attention.

Eye contact: Rinse thoroughly with plenty of water, also under the eyelids. If eye irritation
persists, consult a specialist.

Ingestion: Do not induce vomiting. If a person feels unwell or symptoms of skin irritation
appear, consult a physician.

5. FIRE FIGHTING MEASURES


Flash point: > 93 °C (> 199.4 °F)

Autoignition temperature: Not available.

Flammable/Explosive limits - lower: 4 % Upper/lower explosion limit

Flammable/Explosive limits - upper: 19.9 % Upper/lower explosion limit

Extinguishing media: Foam, dry chemical or carbon dioxide.

Special firefighting procedures: None

Unusual fire or explosion hazards: None

Hazardous combustion products: Formaldehyde. Silica mist. Acrid smoke and fumes.

6. ACCIDENTAL RELEASE MEASURES


Use personal protection recommended in Section 8, isolate the hazard area and deny entry to unnecessary and unprotected
personnel.

Environmental precautions: Do not allow product to enter sewer or waterways.

Clean-up methods: Scrape up as much material as possible. Spilled material will solidify. Store in
a partly filled, closed container until disposal. Maintain good ventilation for
large spills.

7. HANDLING AND STORAGE


Handling: Avoid contact with eyes, skin and clothing. Do not handle contact lenses until
all sealant has been removed from hands. Residual sealant may transfer to
lenses and cause eye irritation.

Storage: Store in a dry area below 90° F. Keep container closed.

For information on product shelf life contact Henkel Canada Customer Service at 800-263-5043.

8. EXPOSURE CONTROLS / PERSONAL PROTECTION


Employers should complete an assessment of all workplaces to determine the need for, and selection of, proper exposure
controls and protective equipment for each task performed.

IDH number: 475372 Product name: TEROSON SI 9160 CL known as SILATECH® SILICONE SEALANT IND
Page 2 of 5
Hazardous components ACGIH TLV OSHA PEL AIHA WEEL OTHER
Silicone Resin None None None None
5 mg/m3 TWA
Distillates (petroleum), hydrotreated middle 5 mg/m3 PEL Mist. None None
Inhalable fraction.
20 MPPCF TWA 3 mg/m3 TWA
Silicon dioxide 6 mg/m3 TWA None
0.8 mg/m3 TWA Respirable fraction.
Triacetoxyethylsilane None None None None
Methylsilanetriyl triacetate None None None None
15 ppm STEL 10 ppm (25
Acetic acid None None
10 ppm TWA mg/m3) PEL

Engineering controls: Ensure adequate ventilation, especially in confined areas. Use local ventilation
if general ventilation is insufficient to maintain vapor concentration below
established exposure limits.

Respiratory protection: Use NIOSH approved respirator if there is potential to exceed exposure
limit(s).

Eye/face protection: Safety goggles or safety glasses with side shields. Full face protection should
be used if the potential for splashing or spraying of product exists.

Skin protection: Chemical resistant, impermeable gloves. Nitrile gloves. Butyl rubber gloves.

9. PHYSICAL AND CHEMICAL PROPERTIES


Physical state: Paste
Color: Translucent
Odor: Acetic acid
Odor threshold: Not available.
pH: Not available.
Vapor pressure: < 10 mm hg (20 °C (68°F))
Boiling point/range: Not available.
Melting point/ range: Not available.
Specific gravity: 1.01 at 20 °C (68°F)
Vapor density: Heavier than air.
Flash point: > 93 °C (> 199.4 °F)
Flammable/Explosive limits - lower: 4%
Flammable/Explosive limits - upper: 19.9 %
Autoignition temperature: Not available.
Evaporation rate: Not available.
Solubility in water: Not determined
Partition coefficient (n-octanol/water): Not available.
VOC content: 3.0 %; 30 g/l
Viscosity: Not available.

10. STABILITY AND REACTIVITY


Stability: Stable

Sensitivity to Mechanical Impact: Not available.

Sensitivity to static discharge: Not available.


Hazardous reactions: Will not occur.

Hazardous decomposition Acetic acid is liberated slowly upon contact with moisture. Formaldehyde.
products:

Incompatible materials: Acids. Bases. Oxidizing agents. Water.

Conditions to avoid: Prolonged heating at temperatures above 150 °C. Exposure to moisture.

IDH number: 475372 Product name: TEROSON SI 9160 CL known as SILATECH® SILICONE SEALANT IND
Page 3 of 5
11. TOXICOLOGICAL INFORMATION

Toxicologically synergistic products: Not available.

Refer to the following for Irritancy of Product, Sensitization to Product, Carcinogenicity, Reproductive Toxicity, Teratogenicity,
and Mutagenicity.

OSHA Carcinogen
Hazardous components NTP Carcinogen IARC Carcinogen (Specifically ACGIH Carcinogen
Regulated)
Silicone Resin No No No No
Distillates (petroleum), hydrotreated
No No No Group A4
middle
Silicon dioxide No No No No
Triacetoxyethylsilane No No No No
Methylsilanetriyl triacetate No No No No
Acetic acid No No No No

Hazardous components LD50s and LC50s Health Effects/Target Organs


Silicone Resin None No Target Organs
Distillates (petroleum), hydrotreated
None Irritant
middle
Silicon dioxide Oral LD50 (RAT) = > 22,500 mg/kg Nuisance dust
Triacetoxyethylsilane None No Target Organs
Methylsilanetriyl triacetate None Irritant, Allergen
Oral LD50 (RABBIT) = 1,200 mg/kg
Oral LD50 (RAT) = 3.53 g/kg
Allergen, Corrosive, Eyes, Gastrointestinal,
Acetic acid Oral LD50 (RAT) = 3.31 g/kg
Immune system, Irritant, Kidney
Dermal LD50 (RABBIT) = 1,060 mg/kg
Inhalation LC50 (RAT, 4 h) = 11.4 mg/l

12. ECOLOGICAL INFORMATION


Ecological information: Not available.

13. DISPOSAL CONSIDERATIONS


Information provided is for unused product only.

Recommended cleaning agents: Follow all local, state, federal and provincial regulations for disposal. Cured
rubber can be incinerated or landfilled following EPA and local regulations.

Hazardous waste number: Not available.

14. TRANSPORT INFORMATION

Canada Transportation of Dangerous Goods - Ground


Proper shipping name: Not regulated
Hazard class or division: None
Identification number: None
Packing group: None

International Air Transportation (ICAO/IATA)


Proper shipping name: Not regulated
Hazard class or division: None
Identification number: None
Packing group: None

IDH number: 475372 Product name: TEROSON SI 9160 CL known as SILATECH® SILICONE SEALANT IND
Page 4 of 5
Water Transportation (IMO/IMDG)
Proper shipping name: Not regulated
Hazard class or division: None
Identification number: None
Packing group: None

15. REGULATORY INFORMATION


Canada Regulatory Information

CEPA DSL/NDSL Status: All components are listed on or are exempt from listing on the Canadian Domestic
Substances List.

United States Regulatory Information

TSCA 8 (b) Inventory Status: All components are listed or are exempt from listing on the Toxic Substances Control Act
Inventory.

16. OTHER INFORMATION


This material safety data sheet contains changes from the previous version in sections: Reviewed MSDS. Reissued with
new date.

This product has been classified in accordance with the hazard criteria of the Controlled Products Regulation (CPR), and
the MSDS contains all the information required by the CPR.

Prepared by: Timothy Pratt, Regulatory Affairs Specialist

DISCLAIMER: The data contained herein are furnished for information only and are believed to be reliable. However, Henkel Corporation and
its affiliates (“Henkel”) does not assume responsibility for any results obtained by persons over whose methods Henkel has no control. It is the
user’s responsibility to determine the suitability of Henkel’s products or any production methods mentioned herein for a particular purpose, and
to adopt such precautions as may be advisable for the protection of property and persons against any hazards that may be involved in the
handling and use of any Henkel’s products. In light of the foregoing, Henkel specifically disclaims all warranties, express or implied, including
warranties of merchantability and fitness for a particular purpose, arising from sale or use of Henkel’s products. Henkel further disclaims any
liability for consequential or incidental damages of any kind, including lost profits.

IDH number: 475372 Product name: TEROSON SI 9160 CL known as SILATECH® SILICONE SEALANT IND
Page 5 of 5
Safety Data Sheet

SECTION 1 PRODUCT AND COMPANY IDENTIFICATION

Way Oil Vistac 68, 220


Product Use: Industrial Oil
Product Number(s): 232511, 232512
Company Identification
Chevron Products Company
a division of Chevron U.S.A. Inc.
6001 Bollinger Canyon Rd.
San Ramon, CA 94583
United States of America
www.chevronlubricants.com

Transportation Emergency Response


CHEMTREC: (800) 424-9300 or (703) 527-3887
Health Emergency
Chevron Emergency Information Center: Located in the USA. International collect calls accepted. (800)
231-0623 or (510) 231-0623
Product Information
email : [email protected]
Product Information: 1 (800) 582-3835, [email protected]

SECTION 2 HAZARDS IDENTIFICATION

CLASSIFICATION: Not classified as hazardous according to 29 CFR 1910.1200 (2012).

SECTION 3 COMPOSITION/ INFORMATION ON INGREDIENTS

COMPONENTS CAS NUMBER AMOUNT


Highly refined mineral oil (C15 - C50) Mixture 70 - 99 %wt/wt
Distillates, hydrotreated middle 64742-46-7 70 - 99 %wt/wt

SECTION 4 FIRST AID MEASURES

Description of first aid measures


Eye: No specific first aid measures are required. As a precaution, remove contact lenses, if worn, and
flush eyes with water.

_____________________________________________________________________

Revision Number: 5 1 of 7 Way Oil Vistac 68, 220


Revision Date: JUNE 03, 2014 SDS : 7459
Skin: No specific first aid measures are required. As a precaution, remove clothing and shoes if
contaminated. To remove the material from skin, use soap and water. Discard contaminated clothing and
shoes or thoroughly clean before reuse.
Ingestion: No specific first aid measures are required. Do not induce vomiting. As a precaution, get
medical advice.
Inhalation: No specific first aid measures are required. If exposed to excessive levels of material in the air,
move the exposed person to fresh air. Get medical attention if coughing or respiratory discomfort occurs.

Most important symptoms and effects, both acute and delayed


IMMEDIATE SYMPTOMS AND HEALTH EFFECTS
Eye: Not expected to cause prolonged or significant eye irritation.
Skin: Contact with the skin is not expected to cause prolonged or significant irritation. Contact with the skin
is not expected to cause an allergic skin response. Not expected to be harmful to internal organs if
absorbed through the skin.
Ingestion: Not expected to be harmful if swallowed.
Inhalation: Not expected to be harmful if inhaled. Contains a petroleum-based mineral oil. May cause
respiratory irritation or other pulmonary effects following prolonged or repeated inhalation of oil mist at
airborne levels above the recommended mineral oil mist exposure limit. Symptoms of respiratory irritation
may include coughing and difficulty breathing.

DELAYED OR OTHER SYMPTOMS AND HEALTH EFFECTS: Not classified.

Indication of any immediate medical attention and special treatment needed


Not applicable.

SECTION 5 FIRE FIGHTING MEASURES

EXTINGUISHING MEDIA: Use water fog, foam, dry chemical or carbon dioxide (CO2) to extinguish flames.

PROTECTION OF FIRE FIGHTERS:


Fire Fighting Instructions: This material will burn although it is not easily ignited. See Section 7 for proper
handling and storage. For fires involving this material, do not enter any enclosed or confined fire space
without proper protective equipment, including self-contained breathing apparatus.
Combustion Products: Highly dependent on combustion conditions. A complex mixture of airborne
solids, liquids, and gases including carbon monoxide, carbon dioxide, and unidentified organic compounds
will be evolved when this material undergoes combustion.

SECTION 6 ACCIDENTAL RELEASE MEASURES

Protective Measures: Eliminate all sources of ignition in vicinity of spilled material.


Spill Management: Stop the source of the release if you can do it without risk. Contain release to prevent
further contamination of soil, surface water or groundwater. Clean up spill as soon as possible, observing
precautions in Exposure Controls/Personal Protection. Use appropriate techniques such as applying
non-combustible absorbent materials or pumping. Where feasible and appropriate, remove contaminated
soil. Place contaminated materials in disposable containers and dispose of in a manner consistent with
applicable regulations.
Reporting: Report spills to local authorities as appropriate or required.

SECTION 7 HANDLING AND STORAGE

Precautionary Measures: Do not get in eyes, on skin, or on clothing. Wash thoroughly after handling.
General Handling Information: Avoid contaminating soil or releasing this material into sewage and
drainage systems and bodies of water.
Static Hazard: Electrostatic charge may accumulate and create a hazardous condition when handling this
_____________________________________________________________________

Revision Number: 5 2 of 7 Way Oil Vistac 68, 220


Revision Date: JUNE 03, 2014 SDS : 7459
material. To minimize this hazard, bonding and grounding may be necessary but may not, by themselves,
be sufficient. Review all operations which have the potential of generating and accumulating an electrostatic
charge and/or a flammable atmosphere (including tank and container filling, splash filling, tank cleaning,
sampling, gauging, switch loading, filtering, mixing, agitation, and vacuum truck operations) and use
appropriate mitigating procedures. For more information, refer to OSHA Standard 29 CFR 1910.106,
'Flammable and Combustible Liquids', National Fire Protection Association (NFPA 77, 'Recommended
Practice on Static Electricity', and/or the American Petroleum Institute (API) Recommended Practice 2003,
'Protection Against Ignitions Arising Out of Static, Lightning, and Stray Currents'.
Container Warnings: Container is not designed to contain pressure. Do not use pressure to empty
container or it may rupture with explosive force. Empty containers retain product residue (solid, liquid,
and/or vapor) and can be dangerous. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose
such containers to heat, flame, sparks, static electricity, or other sources of ignition. They may explode and
cause injury or death. Empty containers should be completely drained, properly closed, and promptly
returned to a drum reconditioner or disposed of properly.

SECTION 8 EXPOSURE CONTROLS/PERSONAL PROTECTION

GENERAL CONSIDERATIONS:
Consider the potential hazards of this material (see Section 3), applicable exposure limits, job activities, and
other substances in the work place when designing engineering controls and selecting personal protective
equipment. If engineering controls or work practices are not adequate to prevent exposure to harmful
levels of this material, the personal protective equipment listed below is recommended. The user should
read and understand all instructions and limitations supplied with the equipment since protection is usually
provided for a limited time or under certain circumstances.

ENGINEERING CONTROLS:
Use in a well-ventilated area.

PERSONAL PROTECTIVE EQUIPMENT


Eye/Face Protection: No special eye protection is normally required. Where splashing is possible, wear
safety glasses with side shields as a good safety practice.
Skin Protection: No special protective clothing is normally required. Where splashing is possible, select
protective clothing depending on operations conducted, physical requirements and other substances in the
workplace. Suggested materials for protective gloves include: 4H (PE/EVAL), Nitrile Rubber, Silver Shield,
Viton.
Respiratory Protection: No respiratory protection is normally required.
If user operations generate an oil mist, determine if airborne concentrations are below the occupational
exposure limit for mineral oil mist. If not, wear an approved respirator that provides adequate protection
from the measured concentrations of this material. For air-purifying respirators use a particulate cartridge.
Use a positive pressure air-supplying respirator in circumstances where air-purifying respirators may not
provide adequate protection.

Occupational Exposure Limits:

Component Agency TWA STEL Ceiling Notation


Highly refined mineral oil (C15 - ACGIH 5 mg/m3 10 mg/m3 -- --
C50)
Highly refined mineral oil (C15 - OSHA Z-1 5 mg/m3 -- -- --
C50)
Consult local authorities for appropriate values.

SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES

Attention: the data below are typical values and do not constitute a specification.

_____________________________________________________________________

Revision Number: 5 3 of 7 Way Oil Vistac 68, 220


Revision Date: JUNE 03, 2014 SDS : 7459
Color: Brown
Physical State: Liquid
Odor: Petroleum odor
Odor Threshold: No data available
pH: Not Applicable
Vapor Pressure: <0.01 mmHg @ 37.8 °C (100 °F)
Vapor Density (Air = 1): >1
Initial Boiling Point: 315°C (599°F)
Solubility: Soluble in hydrocarbons; insoluble in water
Freezing Point: Not Applicable
Specific Gravity: 0.9117 @ 15.6°C (60.1°F) / 15.6°C (60.1°F) Minimum
Density: Not Applicable
Viscosity: 61.2 mm2/s @ 40°C (104°F) Minimum
Evaporation Rate: No data available
Decomposition temperature: No Data Available
Octanol/Water Partition Coefficient: No data available

FLAMMABLE PROPERTIES:
Flammability (solid, gas): No Data Available
Flashpoint: (Cleveland Open Cup) 170 °C (338 °F) (Min)
Autoignition: No data available
Flammability (Explosive) Limits (% by volume in air): Lower: Not Applicable Upper: Not Applicable

SECTION 10 STABILITY AND REACTIVITY

Reactivity: This material is not expected to react.


Chemical Stability: This material is considered stable under normal ambient and anticipated storage and
handling conditions of temperature and pressure.
Incompatibility With Other Materials: May react with strong acids or strong oxidizing agents, such as
chlorates, nitrates, peroxides, etc.
Hazardous Decomposition Products: None known (None expected)
Hazardous Polymerization: Hazardous polymerization will not occur.

SECTION 11 TOXICOLOGICAL INFORMATION

Information on toxicological effects


Serious Eye Damage/Irritation: The eye irritation hazard is based on evaluation of data for product
components.
Skin Corrosion/Irritation: The skin irritation hazard is based on evaluation of data for product
components.
Skin Sensitization: The skin sensitization hazard is based on evaluation of data for product components.
Acute Dermal Toxicity: The acute dermal toxicity hazard is based on evaluation of data for product
components.
Acute Oral Toxicity: The acute oral toxicity hazard is based on evaluation of data for product components.

Acute Inhalation Toxicity: The acute inhalation toxicity hazard is based on evaluation of data for product
components.

Acute Toxicity Estimate: Not Determined

_____________________________________________________________________

Revision Number: 5 4 of 7 Way Oil Vistac 68, 220


Revision Date: JUNE 03, 2014 SDS : 7459
Germ Cell Mutagenicity: The hazard evaluation is based on data for components or a similar material.
Carcinogenicity: The hazard evaluation is based on data for components or a similar material.
Reproductive Toxicity: The hazard evaluation is based on data for components or a similar material.

Specific Target Organ Toxicity - Single Exposure: The hazard evaluation is based on data for
components or a similar material.
Specific Target Organ Toxicity - Repeated Exposure: The hazard evaluation is based on data for
components or a similar material.

ADDITIONAL TOXICOLOGY INFORMATION:


This product contains petroleum base oils which may be refined by various processes including severe
solvent extraction, severe hydrocracking, or severe hydrotreating. None of the oils requires a cancer
warning under the OSHA Hazard Communication Standard (29 CFR 1910.1200). These oils have not been
listed in the National Toxicology Program (NTP) Annual Report nor have they been classified by the
International Agency for Research on Cancer (IARC) as; carcinogenic to humans (Group 1), probably
carcinogenic to humans (Group 2A), or possibly carcinogenic to humans (Group 2B). These oils have not
been classified by the American Conference of Governmental Industrial Hygienists (ACGIH) as: confirmed
human carcinogen (A1), suspected human carcinogen (A2), or confirmed animal carcinogen with unknown
relevance to humans (A3).

SECTION 12 ECOLOGICAL INFORMATION

ECOTOXICITY
This material is not expected to be harmful to aquatic organisms. The ecotoxicity hazard is based on an
evaluation of data for the components or a similar material. The product has not been tested. The
statement has been derived from the properties of the individual components.

MOBILITY
No data available.

PERSISTENCE AND DEGRADABILITY


This material is not expected to be readily biodegradable. The biodegradability of this material is based on
an evaluation of data for the components or a similar material.The product has not been tested. The
statement has been derived from the properties of the individual components.

POTENTIAL TO BIOACCUMULATE
Bioconcentration Factor: No data available.
Octanol/Water Partition Coefficient: No data available

SECTION 13 DISPOSAL CONSIDERATIONS

Use material for its intended purpose or recycle if possible. Oil collection services are available for used oil
recycling or disposal. Place contaminated materials in containers and dispose of in a manner consistent
with applicable regulations. Contact your sales representative or local environmental or health authorities
for approved disposal or recycling methods.

SECTION 14 TRANSPORT INFORMATION

The description shown may not apply to all shipping situations. Consult 49CFR, or appropriate Dangerous
Goods Regulations, for additional description requirements (e.g., technical name) and mode-specific or
quantity-specific shipping requirements.

_____________________________________________________________________

Revision Number: 5 5 of 7 Way Oil Vistac 68, 220


Revision Date: JUNE 03, 2014 SDS : 7459
DOT Shipping Description: NOT REGULATED AS A HAZARDOUS MATERIAL UNDER 49 CFR

IMO/IMDG Shipping Description: NOT REGULATED AS DANGEROUS GOODS FOR TRANSPORT


UNDER THE IMDG CODE

ICAO/IATA Shipping Description: NOT REGULATED AS DANGEROUS GOODS FOR TRANSPORT


UNDER ICAO

Transport in bulk according to Annex II of MARPOL 73/78 and the IBC code:
Not applicable

SECTION 15 REGULATORY INFORMATION

EPCRA 311/312 CATEGORIES: 1. Immediate (Acute) Health Effects: NO


2. Delayed (Chronic) Health Effects: NO
3. Fire Hazard: NO
4. Sudden Release of Pressure Hazard: NO
5. Reactivity Hazard: NO

REGULATORY LISTS SEARCHED:


01-1=IARC Group 1 03=EPCRA 313
01-2A=IARC Group 2A 04=CA Proposition 65
01-2B=IARC Group 2B 05=MA RTK
02=NTP Carcinogen 06=NJ RTK
07=PA RTK

No components of this material were found on the regulatory lists above.

CHEMICAL INVENTORIES:
All components comply with the following chemical inventory requirements: AICS (Australia), DSL
(Canada), IECSC (China), KECI (Korea), PICCS (Philippines), TSCA (United States).

One or more components does not comply with the following chemical inventory requirements: ENCS
(Japan).

NEW JERSEY RTK CLASSIFICATION:


Under the New Jersey Right-to-Know Act L. 1983 Chapter 315 N.J.S.A. 34:5A-1 et. seq., the product is to
be identified as follows: PETROLEUM OIL (Lubricating oil)

SECTION 16 OTHER INFORMATION

NFPA RATINGS: Health: 0 Flammability: 1 Reactivity: 0

HMIS RATINGS: Health: 1 Flammability: 1 Reactivity: 0


(0-Least, 1-Slight, 2-Moderate, 3-High, 4-Extreme, PPE:- Personal Protection Equipment Index
recommendation, *- Chronic Effect Indicator). These values are obtained using the guidelines or published
evaluations prepared by the National Fire Protection Association (NFPA) or the National Paint and Coating
Association (for HMIS ratings).

LABEL RECOMMENDATION:
Label Category : INDUSTRIAL OIL 1 - IND1

_____________________________________________________________________

Revision Number: 5 6 of 7 Way Oil Vistac 68, 220


Revision Date: JUNE 03, 2014 SDS : 7459
REVISION STATEMENT: This revision updates the following sections of this Safety Data Sheet: 1-16
Revision Date: JUNE 03, 2014

ABBREVIATIONS THAT MAY HAVE BEEN USED IN THIS DOCUMENT:


TLV - Threshold Limit Value TWA - Time Weighted Average
STEL - Short-term Exposure Limit PEL - Permissible Exposure Limit
GHS - Globally Harmonized System CAS - Chemical Abstract Service Number
ACGIH - American Conference of Governmental IMO/IMDG - International Maritime Dangerous Goods
Industrial Hygienists Code
API - American Petroleum Institute SDS - Safety Data Sheet
HMIS - Hazardous Materials Information System NFPA - National Fire Protection Association (USA)
DOT - Department of Transportation (USA) NTP - National Toxicology Program (USA)
IARC - International Agency for Research on OSHA - Occupational Safety and Health Administration
Cancer
NCEL - New Chemical Exposure Limit EPA - Environmental Protection Agency
SCBA - Self-Contained Breathing Apparatus

Prepared according to the 29 CFR 1910.1200 (2012) by Chevron Energy Technology Company, 6001
Bollinger Canyon Road San Ramon, CA 94583.

The above information is based on the data of which we are aware and is believed to be correct
as of the date hereof. Since this information may be applied under conditions beyond our
control and with which we may be unfamiliar and since data made available subsequent to the
date hereof may suggest modifications of the information, we do not assume any responsibility
for the results of its use. This information is furnished upon condition that the person receiving
it shall make his own determination of the suitability of the material for his particular purpose.

_____________________________________________________________________

Revision Number: 5 7 of 7 Way Oil Vistac 68, 220


Revision Date: JUNE 03, 2014 SDS : 7459
WD-40

MATERIAL SAFETY DATA SHEET


SECTION 1 PRODUCT AND COMPANY IDENTIFICATION

MANUFACTURER/SUPPLIER: US Office:
WD-40 Products [Canada] Ltd. WD-40 Company
P.O. Box 220 1061 Cudahy Place
Toronto, Ontario M9C 4V3 San Diego, CA 92110

Information Phone #: (416) 622-9881 Information Phone #: (619) 275-1400


Emergency Phone # 24 hr: Emergency Phone # 24 hr:
Canutec: (613) 996-6666 Chemtrec: (800) 424-9300
Designated for use only in the event of chemical Designated for use only in the event of chemical
emergencies involving a spill, leak, fire exposure or emergencies involving a spill, leak, fire exposure or
accident involving chemicals accident involving chemicals.

PRODUCT NAME: WD-40 Bulk Liquid


PRODUCT USE: Cleaner, lubricant.
MSDS DATE OF PREPARATION: March 27, 2014

SECTION 2 HAZARDS IDENTIFICATION

DANGER! Harmful or fatal if swallowed. Combustible Liquid. Avoid eye contact. Use with adequate ventilation.
Keep away from heat, sparks and all other sources of ignition.

POTENTIAL HEALTH EFFECTS:


PRIMARY ROUTES OF ENTRY: Inhalation, skin and eye contact.
ACUTE EFFECTS:
INGESTION: This product has low oral toxicity. Swallowing may cause irritation, nausea, vomiting and diarrhea.
This product is an aspiration hazard. If swallowed, can enter the lungs and may cause chemical pneumonitis.
EYES: Contact may be mildly irritating to eyes. May cause redness and tearing.
SKIN: Prolonged and/or repeated contact may produce mild irritation and defatting with possible dermatitis.
INHALATION: High concentrations may cause nasal and respiratory irritation and central nervous system effects
such as headache, dizziness and nausea. May aggravate existing respiratory conditions such as asthma. Intentional
abuse may be harmful or fatal.
CHRONIC EFFECTS: None expected.

SECTION 3 COMPOSITION INFORMATION ON INGREDIENTS

Ingredient CAS Number Percent


Aliphatic Petroleum Distillates 64742-47-8 50-70%
64742-88-7
Petroleum Base Oil 64742-58-1 30-35%
64742-53-6
64742-56-9
64742-65-0
Non-Hazardous Ingredients Proprietary <10%

Page 1 of 4
WD-40 Bulk Liquid
03/27/14

SECTION 4 FIRST AID MEASURES

For Medical Emergencies Call 1-888-324-7596 (24 hours/day)


INGESTION: Aspiration Hazard. DO NOT induce vomiting. Call physician, poison control center or the WD-40
Safety Hotline at 1-888-324-7596 immediately.
EYE CONTACT: Flush thoroughly with water. Get medical attention if irritation persists.
SKIN CONTACT: Wash with soap and water. If irritation develops and persists, get medical attention.
INHALATION: If irritation is experienced, move to fresh air. Get medical attention if irritation or other symptoms
develop and persist.

SECTION 5 FIRE FIGHTING MEASURES

EXTINGUISHING MEDIA: Use water fog, dry chemical, carbon dioxide or foam. Do not use water jet or flooding
amounts of water. Burning product will float on the surface and spread fire.
SPECIAL FIRE FIGHTING PROCEDURES: Firefighters should always wear positive pressure self-contained
breathing apparatus and full protective clothing. Cool fire-exposed containers with water.
UNUSUAL FIRE/EXPLOSION HAZARDS: Combustible liquid and vapor. Vapors are heavier than air and may
travel along surfaces to remote ignition sources and flash back.

SECTION 6 ACCIDENTAL RELEASE MEASURES

SPILL RESPONSE: Wear appropriate protective clothing (see Section 8). Eliminate all sources of ignition and
ventilate area. Contain and collect liquid with an inert absorbent and place in a container for disposal. Clean spill
area thoroughly. Report spills to authorities as required.

SECTION 7 HANDLING AND STORAGE

HANDLING: Avoid contact with eyes. Avoid prolonged contact with skin. Avoid breathing vapors or aerosols. Use
with adequate ventilation. Keep away from heat, sparks and open flames. Wash thoroughly with soap and water
after handling. Keep containers closed when not in use. Keep out of the reach of children.

STORAGE: Store away from heat, flames and incompatible materials.

SECTION 8 EXPOSURE CONTROLE/PERSONAL PROTECTION

OCCUPATIONAL EXPOSURE LIMITS:


Aliphatic Petroleum Distillates 1200 mg/m3 TWA Manufacturer Recommended
Petroleum Base Oil 5 mg/m3 TWA ACGIH TLV
10 mg/m3 STEL ACGIH TLV
Non-Hazardous Ingredients None Established

The Following Controls are Recommended for Normal Consumer Use of this Product
Engineering Controls: Use in a well-ventilated area.
Personal Protection:
Eye Protection: Avoid eye contact. Safety glasses or goggles recommended.
Skin Protection: Avoid prolonged skin contact. Chemical resistant gloves recommended for operations where skin
contact is likely.
Respiratory Protection: None needed for normal use with adequate ventilation.

For Bulk Processing or Workplace Use the Following Controls are Recommended
Engineering Controls: Use adequate general and local exhaust ventilation to maintain exposure levels below that
occupational exposure limits.
Personal Protection:
Eye Protection: Safety goggles recommended where eye contact is possible.
Skin Protection: Wear chemical resistant gloves.

Page 2 of 4
WD-40 Bulk Liquid
03/27/14

Respiratory Protection: None required if ventilation is adequate. If the occupational exposure limits are exceeded,
wear a NIOSH approved respirator. Respirator selection and use should be based on contaminant type, form and
concentration. Follow applicable regulations and good Industrial Hygiene practice.
Work/Hygiene Practices: Wash with soap and water after handling.

SECTION 9 PHYSICAL DATA

APPEARANCE AND ODOR: Light amber liquid with a mild odor.

Freezing Point: Not Applicable Odor Threshold: Not Determined


Boiling Point: 361 - 369F (183 - 187°C) Specific Gravity: 0.78 – 0.82 @ 60F
Solubility in Water: Insoluble pH: Not Applicable
Vapor Pressure: 1 psi @38C (100F) ASTM Vapor Density: Greater than 1
D323
Percent Volatile: 70-75% VOC: 533 grams/liter (65%)
Coefficient of Water/Oil Not Determined Kinematic Viscosity: 2.79-2.96cSt @ 100F
Distribution:
Flash Point: 122F (49°C) Tag Open Cup Flammable Limits: LEL: 0.6% UEL: 8.0%
(Solvent Portion)
Pour Point: -63C (-81.4F ) ASTM D-97 Explosion Impact: None

SECTION 10 STABILITY AND REACTIVITY

STABILITY: Stable
INCOMPATIBILITY: Strong oxidizing agents. Avoid heat and open flames.
HAZARDOUS DECOMPOSITION PRODUCTS: Carbon monoxide, carbon dioxide.

SECTION 11 TOXICOLOGICAL INFORMATION

The oral toxicity of this product is estimated to be greater than 5,000 mg/kg based on an assessment of the
ingredients. This product is not classified as toxic by established criteria. It is an aspiration hazard.

None of the components of this product is listed as a carcinogen or suspected carcinogen or is considered a
reproductive hazard.

SECTION 12 ECOLOGICAL INFORMATION

No data is currently available.

SECTION 13 DISPOSAL CONSIDERATIONS

WASTE DISPOSAL METHOD: If this product becomes a waste, it would be expected to meet the criteria of a
hazardous waste based on flammability. However, it is the responsibility of the generator to determine at the time of
disposal the proper classification and method of disposal. Dispose in accordance with federal, state, and local
regulations.

SECTION 14 TRANSPORT INFORMATION

U.S. DOT Hazard Classification: Excepted from Hazmat (49CFR 173.150 (F)) in non-bulk packagings. Bulk
Packagings: Combustible Liquid, n.o.s. (contains Petroleum Distillates), NA1993, PG III

Canadian TDG Classification: Not regulated as a dangerous good when packages in a small means of containment
(See 1.33 Class 3, Flammable Liquids: General Exemption).

IMDG Code Hazard Classification: UN1268, Petroleum Distillates, n.o.s. 3, PG III.

Page 3 of 4
WD-40 Bulk Liquid
03/27/14

SECTION 15 REGULATORY INFORMATION

U.S. FEDERAL REGULATIONS:

CERCLA 103 Reportable Quantity: This product is not subject to CERCLA reporting requirements, however, oil spills
are reportable to the National Response Center under the Clean Water Act and many states have more stringent release
reporting requirements. Report spills as required under federal, state and local regulations.

SARA TITLE III:


Hazard Category For Section 311/312: Acute Health, Fire Hazard
Section 313 Toxic Chemicals: This product contains the following chemicals subject to SARA Title III Section 313
Reporting requirements: None
Section 302 Extremely Hazardous Substances (TPQ): None

EPA Toxic Substances Control Act (TSCA) Status: All of the components of this product are listed on the TSCA
inventory.

CANADIAN REGULATIONS:

Canadian Environmental Protection Act: All of the ingredients are listed on the Canadian Domestic Substances List
or exempt from notification

Canadian WHMIS Classification: Class B-3 (Combustible Liquid).


This MSDS has been prepared according to the criteria of the Controlled Products Regulation (CPR) and the MSDS
contains all of the information required by the CPR.

SECTION 16 OTHER INFORMATION

HMIS Hazard Rating: Health – 1 (slight hazard), Fire Hazard – 2 (moderate hazard), Physical Hazard – 0
(minimal hazard)

Revision Date: 03/27/14 Supersedes: 03/10/13

Prepared By: Industrial Health & Safety Consultants, Inc. 1-203-929-3473

This MSDS complies with OSHA guidelines set by 29 CFR 1910.1200 and the Canadian WHMIS regulations. The
foregoing information has been compiled from sources believed to be accurate but is not warranted to be. Recipients
are advised to confirm in advance of need that data is correct. Standards change without notice. It is the
responsibility of the recipient to insure that their personnel have been notified of any changes which may affect
them. The data provided on this MSDS are not meant to be used as specifications, only as guideline information as
to the safe use of this product. User should refer to applicable laws before use.

N/D = Not Determined N/E = Not Established N/A = Not Applicable

1071200/ No.0084302

Page 4 of 4
Safety Data Sheet

according to Hazard Communication Standard; 29 CFR 1910.1200 

WINDEX® CLENER ORIGINAL WITH AMMONIA-D®


Version 1.2 Print Date 03/24/2016

Revision Date 03/14/2016 SDS Number 350000014153

1. PRODUCT AND COMPANY IDENTIFICATION

Product information
Product name : WINDEX® CLENER ORIGINAL WITH AMMONIA-D®

Recommended use : Hard Surface Cleaner

Manufacturer, importer, : S.C. Johnson & Son, Inc.


supplier 1525 Howe Street
Racine WI 53403-2236

Telephone : +18005585252
Emergency telephone : 24 Hour Medical Emergency Phone: (866)231-5406
number 24 Hour International Emergency Phone: (703)527-3887
24 Hour Transport Emergency Phone: (800)424-9300

2. HAZARDS IDENTIFICATION
Classification of the substance or mixture

Globally Harmonized System (GHS) Classification


This product does not meet the criteria for classification in any hazard class according to regulation
OSHA 29 CFR 1910.1200.

Labelling

Precautionary statements
Other hazards : None identified

3. COMPOSITION/INFORMATION ON INGREDIENTS

This product does not contain hazardous chemicals at or above a reportable level as defined by OSHA
29 CFR 1910.1200

For additional information on product ingredients, see www.whatsinsidescjohnson.com.

4. FIRST AID MEASURES

Eye contact : No special requirements


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WINDEX® CLENER ORIGINAL WITH AMMONIA-D®


Version 1.2 Print Date 03/24/2016

Revision Date 03/14/2016 SDS Number 350000014153

Skin contact : No special requirements

Inhalation : No special requirements.

Ingestion : No special requirements

5. FIREFIGHTING MEASURES

Suitable extinguishing : Use water spray, alcohol-resistant foam, dry chemical or


media carbon dioxide.

Specific hazards during : Container may melt and leak in heat of fire.
firefighting

Further information : Fight fire with normal precautions from a reasonable distance.
Standard procedure for chemical fires. Wear full protective
clothing and positive pressure self-contained breathing
apparatus.

6. ACCIDENTAL RELEASE MEASURES

Personal precautions : Wash thoroughly after handling.

Environmental : Outside of normal use, avoid release to the environment.


precautions

Methods and materials : Dike large spills.


for containment and Clean residue from spill site.
cleaning up

7. HANDLING AND STORAGE

Handling
Precautions for safe : Avoid contact with skin, eyes and clothing.
handling For personal protection see section 8.
KEEP OUT OF REACH OF CHILDREN AND PETS.

Advice on protection : Normal measures for preventive fire protection.

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WINDEX® CLENER ORIGINAL WITH AMMONIA-D®


Version 1.2 Print Date 03/24/2016

Revision Date 03/14/2016 SDS Number 350000014153

against fire and explosion

Storage
Requirements for storage : Keep container closed when not in use.
areas and containers
Other data : Stable under normal conditions.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Occupational Exposure Limits


ACGIH or OSHA exposure limits have not been established for this product or reportable ingredients
unless noted in the table above.

Personal protective equipment


Respiratory protection : No special requirements.

Hand protection : No special requirements.

Eye protection : No special requirements.

Skin and body protection : No special requirements.

Hygiene measures : Handle in accordance with good industrial hygiene and safety
practice. Wash thoroughly after handling.

9. PHYSICAL AND CHEMICAL PROPERTIES

Form : liquid

Color : blue

Odor : floral

Odour Threshold : Test not applicable for this product type

pH : 10.7
at (25 C)

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WINDEX® CLENER ORIGINAL WITH AMMONIA-D®


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Revision Date 03/14/2016 SDS Number 350000014153

Melting point/freezing point : 0C

Initial boiling point and : 100 C


boiling range

Flash point : does not flash

Evaporation rate : Test not applicable for this product type

Flammability (solid, gas) : Does not sustain combustion.

Upper/lower flammability or : Test not applicable for this product type


explosive limits

Vapour pressure : Calculated31.7 hPa

Vapour density : Test not applicable for this product type

Relative density : 1.00 g/cm3 at 25 C

Solubility(ies) : soluble

Partition coefficient: n- : Test not applicable for this product type


octanol/water

Auto-ignition temperature : Test not applicable for this product type

Decomposition temperature : Heating can release hazardous gases.

Viscosity, dynamic : similar to water

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WINDEX® CLENER ORIGINAL WITH AMMONIA-D®


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Viscosity, kinematic : similar to water

Oxidizing properties : Test not applicable for this product type

Volatile Organic : 0.2 % - additional exemptions may apply


Compounds *as defined by US Federal and State Consumer Product
Total VOC (wt. %)* Regulations

Other information : None identified :

10. STABILITY AND REACTIVITY

Possibility of hazardous : If accidental mixing occurs and toxic gas is formed, exit area
reactions immediately. Do not return until well ventilated.

Conditions to avoid : Direct sources of heat.

Incompatible materials : Do not mix with bleach or any other household cleaners.
Strong bases

Hazardous decomposition : Thermal decomposition can lead to release of irritating gases


products and vapours.

11. TOXICOLOGICAL INFORMATION

Emergency Overview : This product does not meet the criteria for classification in any
hazard class according to regulation OSHA 29 CFR
1910.1200.

Acute oral toxicity : LD50 > 5000 mg/kg

Acute inhalation toxicity : LC50 > 10 mg/L

Acute dermal toxicity : LD50 > 5000 mg/kg


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WINDEX® CLENER ORIGINAL WITH AMMONIA-D®


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Revision Date 03/14/2016 SDS Number 350000014153

GHS Properties Classification Routes of entry


Acute toxicity No classification proposed Oral

Acute toxicity No classification proposed Dermal

Acute toxicity No classification proposed Inhalation - Dust and Mist

Acute toxicity No classification proposed Inhalation - Vapour

Acute toxicity No classification proposed Inhalation - Gas

Skin corrosion/irritation No classification proposed -

Serious eye No classification proposed -


damage/eye irritation
Skin sensitisation No classification proposed -

Respiratory No classification proposed -


sensitisation
Germ cell mutagenicity No classification proposed -

Carcinogenicity No classification proposed -

Reproductive toxicity No classification proposed -

Specific target organ No classification proposed -


toxicity - single
exposure
Specific target organ No classification proposed -
toxicity - repeated
exposure
Aspiration hazard No classification proposed -

Aggravated Medical : None known.


Condition

12. ECOLOGICAL INFORMATION

Product : The product itself has not been tested.


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WINDEX® CLENER ORIGINAL WITH AMMONIA-D®


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Revision Date 03/14/2016 SDS Number 350000014153

Toxicity
The ingredients in this formula have been reviewed and no adverse impact to the environment is
expected when used according to label directions.

No environmental data required.

Other adverse effects : None known.

13. DISPOSAL CONSIDERATIONS

Consumer may discard empty container in trash, or recycle


where facilities exist.

14. TRANSPORT INFORMATION

Please refer to the Bill of Lading/receiving documents for up-to-date shipping information.

Land transport
Not classified as dangerous in the meaning of transport regulations.

Sea transport
Not classified as dangerous in the meaning of transport regulations.

Air transport
Not classified as dangerous in the meaning of transport regulations.

15. REGULATORY INFORMATION

Notification status : All ingredients of this product are listed or are excluded from
listing on the U.S. Toxic Substances Control Act (TSCA)
Chemical Substance Inventory.

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WINDEX® CLENER ORIGINAL WITH AMMONIA-D®


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Revision Date 03/14/2016 SDS Number 350000014153

Notification status : All ingredients of this product comply with the New Substances
Notification requirements under the Canadian Environmental
Protection Act (CEPA).

California Prop. 65 : This product does not contain any chemicals known to State of
California to cause cancer, birth defects, or any other
reproductive harm.

16. OTHER INFORMATION


HMIS Ratings
Health 1

Flammability 0

Reactivity 0

NFPA Ratings
Health 1

Fire 0

Reactivity 0

Special -

This information is being provided in accordance with the Occupational Safety and Health Administration
(OSHA) regulation (29 CFR 1910.1200). The information supplied is designed for workplaces where
product use and frequency of exposure exceeds that established for the labeled consumer use.

Further information

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WINDEX® CLENER ORIGINAL WITH AMMONIA-D®


Version 1.2 Print Date 03/24/2016

Revision Date 03/14/2016 SDS Number 350000014153

This document has been prepared using data from sources considered to be technically reliable. It does
not constitute a warranty, expressed or implied, as to the accuracy of the information contained herein.
Actual conditions of use are beyond the seller's control. User is responsible to evaluate all available
information when using product for any particular use and to comply with all Federal, State, Provincial
and Local laws and regulations.

Prepared by SC Johnson Global Safety Assessment &


Regulatory Affairs (GSARA)

9/9
f

AICLANDS 7,
GRAINGER
LUiiiLil i Reference: 384142

FcDERAnON EUR(WEENNE DES


AIRICANTS DE PRODUITSABRASWS GLI Revision: 08.01.2014
Printing date: 18.06.2015
Page 1 of 5

Voluntary product information based on the format of a safety data sheet


for organic bonded abrasives

1. identification of Product and Company

1.1 Product Identifier: 384142


41 CUT-OFF WHEEL,REINF.
11 5X1 2X22,23
TA6OP-BFXA
special marking acc. to customer needs

1.2 Use of the product

Organic bonded abrasives used for grinding/cutting of different materials

1.3 Company identification:

Company: TYROLIT Schleifmittelwerke Swarovski KG


Address: Swarovskistrasse 33 Phone: + +43 5242 606 2572
A-6130 Schwaz Fax: + +43 5242 606 12572
E-mail: [email protected]
1.4 Emergency telephone number:,

Environmental Department + +43 664 8292 740

2. Hazards Identification

2.1. Classification

Not applicable.
Abrasives are articles and not dangerous substances or mixtures according to directive 1999/45/EC or Regulation
(EC) N° 1272/2008.
See also section 8 and 16.

2.2. Label elements


Abrasives are articles and not dangerous substances or mixtures and therefore no labelling is required according
to directive 1999/45/EC or Regulation (EC) N° 1272/2008.

2.3. Other hazards

Not known.

3. Compositionllnformation on Ingredients
The product contains ingredients which are classified according to 67/548/EEC or Regulation (EC) Nr. 1 272/2008
or for which a community occupational exposure limit value exists:

Substance EC-N’ CAS-N’ Concentrat Classification acc. to Regulation Classification acc.


ion (%) (EC) N’ 127212008 (CLP) to
Hazard classesl Hazard
hazard categories statements
Potassium- 262-153-1 60304-36-1 <15 Eye lint. 2 H319 Xn; R22
Aluminium- Acute Tox. 4 H332 Xi; R36/37/38
p

Reference: 384142
Revision: 08.01.2014
EtERAi1ON EuROPENNE OE Printing date: 18.06.2015
TA5ICANtS DE POOUITS ?8RA
Page 2 of 5

Fluoride Lact. H362


STOT RE 1 H372
Aquatic_chronic_3 H412

(For the full text of the H-phrases and the R-phrases see section 1 6)

The wheel was produced without addition of fillers containing chlorine (Cl), sulfur (S04), iron (Fe), copper(Cu)
and zinc (Zn).
Suitable for stainless steel conditioning.

4. First Aid Measures

See also section 8 and 16

4.1. Description of first aid measures

Inhalation: not possible, due to the form of the product


Eye contact: not possible, due to the form of the product
Skin contact: no harmful effects known
Ingestion: not likely, due to the form of the product
If necessary contact physician
Note to physician: Not available.

4.2. Most important symptoms and effects, both acute and delayed
Not known.

4.3. Indication of any immediate medical attention and special treatment needed

Not relevant. Treat symptomatically.

5. Fire Fighting Measures


5.1. Extinguishing media
Extinguishing media: water, foam, sand, powder or C02 as appropriate for surrounding materials.

5.2. Special hazards arising from the product


Toxic fumes may occur. Use respiratory protective equipment.

5.3. Advice for fire fighters

Extinguishing materials should be selected according to the surrounding area.

6. Accidental release measures


Not applicable.

7. Handling and Storage

Follow instructions of grinding machine manufacturers and the relevant national regulations. In addition, observe
the safety recommendations of the manufacturer.

eij
A3CXLANDS
GRJUNGER.
1ITILILLitnatLi Reference: 384142

cERArioou:PlprnNE Oit 5
FARIcANtsoEPRooLJirsAi3RAs4Fs
Page 3 of 5

8. Exposure Controls I Personal Protection

8.1. Control parameters

Before grinding it is recommended to perform a risk assessment and to use personal


protection equipment
accordingly.
Occupational exposure limit values andlor biological limit values
Keep exposure to the following components under surveillance.
(Observe also the regional official regulations)

Limit valu, type Substance 00N CASN


Occupational Omit value Peak limit source, remark
lcountr, of origin)

Long term Short term


.
mgIm mum’ (ppm) mg!m’ mi/rn’ (ppm)
MAK (A) Fluoride 262-153-I 60304-36- 2,5 12.5 GKV

Note: Hazardous dust of workpiece material may be generated during grinding and/or sanding
National regulations for dust exposure limit values have to be taken into consideration. operations.

8.2. Exposure controls


8.2.1 Individual protection measures
-

8.2.1.1. Respiratory Use


protection: respiratory
depends
protective equipment (type and on specific application
being
material ground)

8.2.1 .2. Hand protection: Wear protective gloves (type depends on specific application and
ground) being material

8.2.1.3. Eye protection: Wear protective goggles or face shield (type depends on specific application
material being ground) and
8.2.1.4. Hearing protection: Use hearing protection
(type depends on specific application and material being ground)
8.2.1.5. Body protection: Use protective clothing
(type depends on specific application and material being ground)

9. Physical and Chemical Properties


9.1 Physical state: solid
9.2 Colour: various

9.3 Solubility in water: not applicable

10. Stability and Reactivity

10.1. Reactivity
Abrasives are stable when handled or stored correctly.

10.2. Chemical stability


Abrasives are stable when handled or stored correctly.

10.3. Possibility of hazardous reactions


No dangerous reactions known.

10.4. Conditions to avoid


No decomposition in normal use.

10.5. Incompatible materials


No dangerous reactions known.

10.6. Hazardous decomposition products

At temperatures exceeding 250’ C hazardous or toxic decomposition products may be generated.


ACXLAHDS
— QRA1NGER
:ju}áLLrJ LL Reference: 3841 42
1” E Revision: 08.01 .2014
FECERATION ELJROPESNNE Printing date: 18.06.2015
FAffeCANTS OE PROOUIT AERSWS Page 4 of 5

1 1. Toxicological Information

No toxicological effects if inhaled or swallowed or with eye or skin contact are known.
See also section 8.

12. Ecological Information

12.1. Toxicity
No effects known.
1 2.2. Persistence and degradability
No biodegradable potentials known.
12.3. Bioaccumulative potential
No potentials known
12.4. Mobility in soil
No potentials known.
12.5. Results of PBT and vPvB assessment
Not relevant.
12.6. Other adverse effects
No effects known.

13. Disposal Considerations

13.1. Product
Follow national and regional regulations.

Due to the ingredients and properties disposal as hazardous waste (2000/532/EC) (EWC - Nr. 120120)

13.2. Packing
Follow national and regional regulations.

14. Transport Information

The product is not covered by international regulation on the transport of dangerous goods.

15. Regulatory Information


15.1. Safety, health and environmental regulationsllegislation specific for the product
No specific labelling requirements under respective EC directives.

1 5.2. Chemical safety assessment


Not relevant.

16. Other Information

Changes to the previous versions


See sections 1 to 16.
Literature and data sources

Directive (1999/45/EC), amended by Regulation (EC) N’. 1907/2006.


Directive (67/548/EWG), amended by Directive 2009/2/EC.
REACH Regulation (EC) Nr. 1907/2006, amended by Regulation (EC) N’ 552/2009..
Regulation (EC) N’ 1272/2008, amended by Regulation (EC) N’ 790/2009.
Directive 2000/39/EG, amended by Directive 2009/161 /EC.
Directive 75/324/EWG amended by Regulation (EC) N’ 219/2009.
Transport regulations according to ADR, RID und IATA..

Hazard statements referred to in section 2 and 3


According to Regulation (EC) N’ 127212008:
CKLANLS
GRAINGER.__________
Reference: 384142
1’! p - - .
Revision: 08.01.2014
DERATlONLJpOPeNNEDEs Printing date: 18.06.2015
FA5RiCANTSOE0OUiTS8RSS
Page 5 of 5

H31 9 Causes serious eye irritation.


H332 Harmful if inhaled.
H362 May cause harm to breast-fed children.
H372 Causes damage to organs through prolonged or repeated exposure.
H412 Harmful to aquatic life with long lasting effects.

According to Directive 67154 8/EWC:

R20 Harmful by inhalation


R36 Irritating to eyes
R48/23 Toxic: danger of serious damage to health by prolonged exposure through inhalation
R52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic
environment
R64 May cause harm to breast-fed babies

The above information is based on our current standard of knowledge and does not constitute any warranty
conditions of the product. The information does not form part of any contractual agreement. It remains of
users responsibility to adhere existing laws and regulations. the

Issued by: Environmental Department


TYROLIT Schleifmittelwerke Swarovski KG

Contact: DI Antje Schwemberger


[email protected]
Tel: + +43 5242 606 2572
a
4’
r?.
I 3M’’ Dynatron Putty-Cote 592, 593 03/12/15

Safety Data Sheet


Copyright,20 I 5,3M Company.
All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is allowed
provided that: (l)the information is copied in full with no changes unless prior written agreement is obtained from 3M, and (2) neither
the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon.

Document Group: 24-2410-9 Version Number: 2.00


Issue Date: 03/12/15 Supercedes Date: 07/20/09

Product identifier
3MTM Dynatron Putty-Cote 592, 593

ID Number(s):

70-0080-0354-6, 70-0080-0355-3

Recommended use
Automotive, Autobody repair.

Supplier’s details

MANUFACTURER: 3M
DIVISION: Automotive Aftermarket

ADDRESS: 3M Center, St. Paul, MN 55 144-1000, USA


Telephone: 1-888-3M HELPS (1-888-364-3577)

Emergency telephone number


1-800-364-3577 or (651) 737-6501 (24 hours)

This product is a kit or a multipart product which consists of multiple, independently packaged components. A Safety Data
Sheet (SDS), Article Information Sheet (AIS), or Article Information Letter (AlL) for each of these components is included.
Please do not separate the component documents from this cover page. The document numbers for components of this
product are:

26-9510-4, 24-2371-3

DISCLAIMER: The information in this Safety Data Sheet (SDS) is believed to be correct as of the date issued. 3M MAKES NO
WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF
MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF
TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable for user’s method of
use or application. Given the variety of factors that can affect the use and application of a 3M product, some of which are uniquely
within the user’s knowledge and control, it is essential that the user evaluate the 3M product to determine whether it is fit for a
particular purpose and suitable for user’s method of use or application.

3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer may
have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness or accuracy.
In addition, information obtained from a database may not be as current as the information in the SDS available directly from 3M

Pagelof 2
-C’

3MTM Dynatron Putty-Cote 592, 593 03/12/15 I Q


3M USA SDSs are available at www.3M.com

Page2of 2
I 3M” Blue Cream Hardener 03/07/14

3M
Safety Data Sheet
Copyright,2014,3M Company.
All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is
allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is obtained from
3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon.

Document Group: 26-9510-4 Version Number: 9.01


Issue Date: 03/07/14 Supercedes Date: 02/19/14

I SECTION 1: Identification
1.1. Product identifier
3MT Blue Cream Hardener

Product Identification Numbers


LB-Kl 00-0788-3, LB-K100-0801-2, 41-0003-6567-0, 41-0003-6575-3, 41-0003-6576-1, 41-0003-6577-9, 41-0003-6578-7,
41-0003-6610-8, 41-0003-6613-2, 41-0003-6614-0, 60-4550-4563-7, 60-4550-4689-0, 70-0080-0038-5, 70-0080-0373-6, 70-
0080-0377-7, 70-0080-0380-1, 70-0080-0382-7, 70-0080-0386-8, 70-0080-03 89-2, 70-0080-0609-3

1.2. Recommended use and restrictions on use

Recommended use
Automotive, Hardener for Body Fillers

1.3. Supplier’s details


MANUFACTURER: 3M
DIVISION: Automotive Aftermarket

ADDRESS: 3M Center, St. Paul, MN 55 144-1000, USA


Telephone: 1-888-3M HELPS (1-888-364-3577)

1.4. Emergency telephone number


1-800-364-3577 or (651) 737-6501 (24 hours)

I SECTION 2: Hazard identification


The label elements below were prepared in accordance with OSHA Hazard Communication Standard, 29 CFR 1910.1200.
This information may be different from the actual product label information for labels regulated by other agencies.

2.1. Hazard classification


Organic Peroxide: Type E.
Serious Eye Damage/Irritation: Category 2A.
Skin Sensitizer: Category 1.

2.2. Label elements


Signal word
Warning

Symbols

Page 1 of 11
I 3MTM Blue Cream Hardener 03/07/14 I C
Flame Exclamation mark

Pictograms

Hazard Statements
Heating may cause a fire.

Causes serious eye irritation.


May cause an allergic skin reaction.

Precautionary Statements
General:
Keep out of reach of children.

Prevention:
Keep away from heat/sparks/open flames/hot surfaces. No smoking.
-

Keep away from clothing and other combustible materials.


Keep only in original container.
Avoid breathing dust/fume/gas/mist/vapors/spray.
Wear protective gloves and eye/face protection.
Wash thoroughly after handling.
Contaminated work clothing must not be allowed out of the workplace.
C
Response:
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
If eye irritation persists: Get medical advice/attention.
IF ON SKIN: Wash with plenty of soap and water.
If skin irritation or rash occurs: Get medical advice/attention.
Wash contaminated clothing before reuse.

Storage:
Protect from sunlight.
Store at temperatures not exceeding 32C/90F. Keep cool.
Store away from other materials.

Disposal:
Dispose of contents/container in accordance with applicable local/regional/national/international regulations.

Notes to Physician:
Not applicable

2.3. Hazards not otherwise classified


None.

8% of the mixture consists of ingredients of unknown acute dermal toxicity.


15% of the mixture consists of ingredients of unknown acute inhalation toxicity.

I SECTION 3: Composition/information on ingredients


C
Page 2 of 11
I 3M1M Blue Cream Hardener 03/07/14 I

Ingredient C.A.S. No. % by Wt


Benzoyl Peroxide 94-36-0 30 60 Trade Secret *
-

Water 7732-18-5 10- 30 Trade Secret *


Benzoic Acid, C9-1 1-Branched Alkyl Esters 131298-44-7 10- 30 Trade Secret *
Zinc Stearate 557-05-1 5 10 Trade Secret *
-

Calcium Sulfate 777 8-1 8-9 3 7 Trade Secret *


-

Oxirane, Polymer with Methyloxirane, Monobutyl Ether 9038-95-3 1 5 Trade Secret *


-

Ferric Ferrocyanide 14038-43-8 < 1 Trade Secret *


Ferric Ammonium Ferrocyanide 25869-00-5 < I Trade Secret *

*The specific chemical identity andJor exact percentage (concentration) of this composition has been withheld as a trade
secret.

I SECTION 4: First aid measures


4.1. Description of first aid measures

Inhalation:
Remove person to fresh air. If you feel unwell, get medical attention.

Skin Contact:
Immediately wash with soap and water. Remove contaminated clothing and wash before reuse. If signs/symptoms develop,
get medical attention.

Eye Contact:
Immediately flush with large amounts of water. Remove contact lenses if easy to do. Continue rinsing. Get medical
attention.

If Swallowed:
Rinse mouth. If you feel unwell, get medical attention.

4.2. Most important symptoms and effects, both acute and delayed
See Section 11.1. Information on toxicological effects.

4.3. Indication of any immediate medical attention and special treatment required
Not applicable

I SECTION 5: Fire-fighting measures


5.1. Suitable extinguishing media
In case of fire: Use a fire fighting agent suitable for ordinary combustible material such as water or foam to extinguish.

5.2. Special hazards arising from the substance or mixture


Closed containers exposed to heat from fire may build pressure and explode. Part of the oxygen for combustion is supplied
by the peroxide itself.

Hazardous Decomposition or By-Products


Substance Condition
Carbon monoxide During Combustion
Carbon dioxide During Combustion
Toxic Vapor, Gas, Particulate During Combustion

5.3. Special protective actions for fire-fighters

Page 3 of 11
I 3M’ Blue Cream Hardener 03/07/14

No unusual fire or explosion hazards are anticipated.

I SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures


Evacuate area. Keep away from heat/sparks/open flames/hot surfaces. No smoking. Use only non-sparking tools.
-

Ventilate the area with fresh air. Refer to other sections of this SDS for information regarding physical and health hazards,
respiratory protection, ventilation, and personal protective equipment.

6.2. Environmental precautions


Avoid release to the environment. For larger spills, cover drains and build dikes to prevent entry into sewer systems or
bodies of water.

6.3. Methods and material for containment and cleaning up


Collect as much of the spilled material as possible using non-sparking tools. Place in a closed container approved for
transportation by appropriate authorities. Clean up residue. Seal the container. Dispose of collected material as soon as
possible.

I SECTION 7: Handling and storage


7.1. Precautions for safe handling
Avoid breathing of dust created by cutting, sanding, grinding or machining. Keep out of reach of children. Keep away from
heat/sparks/open flames/hot surfaces. No smoking. Avoid breathing dust/fume/gas/mist/vapors/spray. Do not get in eyes,
-

on skin, or on clothing. Do not eat, drink or smoke when using this product. Wash thoroughly after handling.
Contaminated work clothing should not be allowed out of the workplace. Avoid release to the environment. Wash
contaminated clothing before reuse.

7.2. Conditions for safe storage including any incompatibilities


C’
Protect from sunlight. Store at temperatures not exceeding 32C/90F. Keep cool. Keep only in original container. Store
away from other materials. Keep/store away from clothing and other combustible materials.

I SECTION 8: Exposure controls/personal protection

8.1. Control parameters

Occupational exposure limits

Ingredient C.A.S. No. Agency Limit type Additional Comments


Zinc Stearate 557-05-I US Dept of TWA(as total dust):l5
Labor OSHA
- mg/m3;TWA(respirable
fraction):5 mg/m3
Calcium Sulfate 7778-18-9 Amer Conf of TWA(inhalable fraction):l0
Gov. Indust. rng/m3
1-lyg.
Calcium Sulfate 7778-18-9 US Dept of TWA(as total dust):15
Labor OSHA
- mg/m3;TWA(respirable
fraction):5 mg/m3
Benzoyl Peroxide 94-36-0 Amer Conf of TWA:5 mg/m3
Gov. Indust.
Hyg.
Benzoyl Peroxide 94-36-0 US Dept of TWA:5 mg/m3
Labor OSHA
-

Amer ConfofGov. Indust. Hyg. : American Conference of Governmental Industrial Hygienists


American Indust. Hygiene Assoc American Industrial Hygiene Association
Chemical Manufacturer Rec Guid : Chemical Manufacturer’s Recommended Guidelines
C
Page 4 of 11
I 3M
’ Blue Cream Hardener
1 03/07/14

US Dept of Labor OSHA : United States Department of Labor Occupational Safety and Health Administration
- -

TWA: Time-Weighted-Average
STEL: Short Term Exposure Limit
CElL: Ceiling

8.2. Exposure controls

8.2.1. Engineering controls


Use general dilution ventilation andlor local exhaust ventilation to control airborne exposures to below relevant Exposure
Limits and/or control dust/fume/gas/mist/vapors/spray. If ventilation is not adequate, use respiratory protection equipment.

8.2.2. Personal protective equipment (PPE)

Eye/face protection

Wear eye/face protection. Select and use eye/face protection to prevent contact based on the results of an exposure
assessment. The following eye/face protection(s) are recommended:
Indirect Vented Goggles

Skin/hand protection
Select and use gloves and/or protective clothing approved to relevant local standards to prevent skin contact based on the
results of an exposure assessment. Selection should be based on use factors such as exposure levels, concentration of the
substance or mixture, frequency and duration, physical challenges such as temperature extremes, and other use conditions.
Consult with your glove and/or protective clothing manufacturer for selection of appropriate compatible gloves/protective
clothing. Wear protective gloves.
Gloves made from the following material(s) are recommended: Nitrile Rubber

If this product is used in a manner that presents a higher potential for exposure (eg. spraying, high splash potential etc.), then
use of protective coveralls may be necessary. Select and use body protection to prevent contact based on the results of an
exposure assessment. The following protective clothing material(s) are recommended: Apron Nitrile —

Respiratory protection

Wear respiratory protection if ventilation is inadequate to prevent overexposure. An exposure assessment may be needed to
decide if a respirator is required. If a respirator is needed, use respirators as part of a full respiratory protection program.
Based on the results of the exposure assessment, select from the following respirator type(s) to reduce inhalation exposure:
Half facepiece or full facepiece air-purifying respirator suitable for organic vapors and particulates

For questions about suitability for a specific application, consult with your respirator manufacturer.

I SECTION 9: Physical and chemical properties


9.1. Information on basic physical and chemical properties
General Physical Form: Solid
Specific Physical Form: Paste
Odor, Color, Grade: Blue paste with slight ester odor
Odor threshold No Data Available
pH No Data Available
Melting point No Data A t’ailable
Boiling Point Not Applicable
Flash Point Ill °C [Test Method: Estimated]
Evaporation rate No Data Available
Flammability (solid, gas) Organic Peroxide: Type E.
Flammable Limits(LEL) Not Applicable
Flammable Limits(UEL) Not Applicable
Vapor Pressure No Data Available

Page 5 of 11
I 3M’ Blue Cream Hardener 03/07/14

Vapor Density No Data Available

Density 1.2 g/ml


Specific Gravity 1.2 [RefStd. WATER=1] [Details: @25 C]

Solubility in Water Negligible


Solubility- non-water No Data A vailable

Partition coefficient: n-octanoll water No Data Available


Autoignition temperature 410°C [Test Method: Estimated]
Decomposition temperature No Data Available
Viscosity 70,000 centipoise 150,000 centipoise
-

Hazardous Air Pollutants 2.0 % weight [Test Method: Calculated]


Volatile Organic Compounds 0 % weight [Test Method: calculated per CARB title 2]
Volatile Organic Compounds 0 gIl [Test Method: calculated SCAQMD rule 443.1]
VOC Less 1120 & Exempt Solvents 0 g/l [Test Method: calculated SCAQMD rule 443.1]

I SECTION 10: Stability and reactivity


10.1. Reactivity
This material may be reactive with certain agents under certain conditions see the remaining headings in this section.
-

10.2. Chemical stability


Stable.
C
10.3. Possibility of hazardous reactions
Hazardous polymerization will not occur.

10.4. Conditions to avoid


None known.

10.5. Incompatible materials


Accelerators

10.6. Hazardous decomposition products


Substance Condition
None known.

Refer to section 5.2 for hazardous decomposition products during combustion.

I SECTION 11: Toxicological information


The information below may not be consistent with the material classification in Section 2 if specific ingredient
classifications are mandated by a competent authority. In addition, toxicological data on ingredients may not be
reflected in the material classification and/or the signs and symptoms of exposure, because an ingredient may be
present below the threshold for labeling, an ingredient may not be available for exposure, or the data may not be
relevant to the material as a whole.

11.1. Information on Toxicological effects

Signs and Symptoms of Exposure

Page 6 of 11
I 3M’ Blue Cream Hardener 03/07114

Based on test data and/or information on the components, this material may produce the following health effects:

Inhalation:
May be harmful if inhaled. Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge,
headache, hoarseness, and nose and throat pain.

Dust from cutting, grinding, sanding or machining may cause irritation of the respiratory system. Signs/symptoms may
include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain.

Skin Contact:
Maybe harmful in contact with skin.
Contact with the skin during product use is not expected to result in significant irritation. Allergic Skin Reaction (non-photo
induced): Signs/symptoms may include redness, swelling, blistering, and itching.

Eye Contact:
Severe Eye Irritation: Signs/symptoms may include significant redness, swelling, pain, tearing, cloudy appearance of the
cornea, and impaired vision.

Dust created by cutting, grinding, sanding, or machining may cause eye irritation. Signs/symptoms may include redness,
swelling, pain, tearing, and blurred or hazy vision.

Ingestion:
Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhea.

Toxicological Data
If a component is disclosed in section 3 but does not appear in a table below, either no data are available for that endpoint or
the data are not sufficient for classification.

S.cute Toxicity
Name Route Species Value
Overall product Dermal No data available; calculated ATE 4,386 mg/kg
Overall product Inhalation- No data available; calculated ATE 10.5 mg/I
DustlMist(4
hr)
Overall product Ingestion No data available; calculated ATE> 5,000 mg/kg
Benzoyl Peroxide Dermal LD5O estimated to be 2,000 5,000 mg/kg
-

Benzoyl Peroxide Inhalation- Rat L.C50 > 24.3 mg/I


Dust/Mist
(4 hours)
Benzoyl Peroxide Ingestion Rat LD5O> 5,000 mg/kg
Benzoic Acid, C9-l I-Branched Alkyl Esters Dermal Rabbit LD5O> 2,000 mg/kg
Benzoic Acid, C9-I I-Branched Alkyl Esters Inhalation- Rat LC5O 2 mg/I
Dust/Mist
(4 hours)
Benzoic Acid, C9-l I-Branched AIkyl Esters Ingestion Rat LD5O> 5,000 mg/Icg
Zinc Stearste Dermal Rabbit LD5O> 2,000 mg/kg
Zinc Stearate Ingestion Rat LD5O> 5,000 mg/kg
Calcium Sulfate Ingestion Rat LD5O> 5,000 mg/kg
Oxirane, Polymer with Methyloxirane, Monobutyl Ether Dermal Rabbit LD5O> 16,960 mg/kg
Oxirane, Polymer with Methyloxirane, Monobutyl Ether Inhalation- Rat LC5O> 5 mg/i
Dust/Mist
(4 hours)
Oxirane, Polymer with Methyloxirane, Monobutyl Ether Ingestion Rat LD5O 4,240 mg/kg
Ferric Ammonium Ferrocyanide Ingestion Rat LD5O> 5,1 10 mg/kg
Ferric Ferrocyanide Ingestion Rat LD5O> 8,000 mg/kg
ATE = acute toxicity estimate

Skin Corrosion/Irritation
Name I Species Value

Page 7 of 11
I 3M” Blue Cream Hardener 03/07/14 I

Benzoyl Peroxide Rabbit Minimal irritation


Oxirane, Polymer with Methyloxirane, Monobutyl Ether Rabbit Minimal irritation

Serious Eye Damage/Irritation

Name Species Value


Benzoyl Peroxide Rabbit Severe irritant
Oxirane, Polymer with Methyloxirane, Monobutyl Ether Rabbit No significant irritation

Skin Sensitization

Name Species Value


Benzoyl Peroxide Human Sensitizing
and
animal

Respiratory Sensitization

Name Species Value

Germ Cell Mutagenicity

Name Route Value

Benzoyl Peroxide In Vitro Not mutagenic


Benzoyl Peroxide In vivo Not mutagenic

Carcinogenicity

Name Route Species Value


benzoyl Peroxide Ingestion Multiple Not carcinogenic
animal
apecies
Benzoyl Peroxide

Oxirane, Polymer with Methyloxirane, Monobutyl Ether


Dermal

Ingestion
Mouse

Rat
Some positive data exist, but the data are not
sufficient for classification
Not carcinogenic
C
Reproductive Toxicity

Reproductive and/or Developmental Effects


Name Route Value Species Test Result Exposure
Duration
Benzoyl Peroxide Ingestion Not toxic to female reproduction Rat NOAEL premating &
1,000 during
mg/lcg/day gestation
Benzoyl Peroxide Ingestion Some positive male reproductive data Rat NOAEL 500 premating &
exist, but the data are not aufficient for mg/kg/day during
classification gestation
Benzoyl Peroxide Ingestion Some positive developmental data exist, Rat NOAEL 500 premating &
but the data are not sufficient for mg/kg/day during
classification gestation
Oxirane, Polymer with Methyloxirane, Ingestion Not toxic to female reproduction Rat NOAEL 90 days
Monobutyl Ether 3,770
mg/kg/day
Oxirane, Polymer with Methyloxirane, Ingestion Not toxic to male reproduction Rat NOAEL 90 days
Monobutyl Ether 3,770
mg/kg/day
Oxirane, Polymer with Methyloxirane, Inhalation Some positive male reproductive data Rat NOAEL 1 2 weeks
Monobutyl Ether exist, but the data are not sufficient for mg/I
classification

Target Organ(s)

Specific Target Organ Toxicity - single exposure

Name Route Target Organ(s) Value Species Test Result Exposure


Duration
Oxirane, Polymer with Ingestion nervous system Some positive data exist, but the Rat NOAEL Not
Methyloxirane,_Monobutyl data_are_not_sufficient_for available

C
Page 8 of 11
I 3M Blue Cream Hardener 03/07/14

Ether I I I classification I I I
Specific Target Organ Toxicity - repeated exposure
Name Route Target Organ(s) Value Species Test Result Exposure
Duration
Oxirane, Polymer with Inhalation endocrine system I Some positive data exist, but the Rat NOAEL 1 2 weeks
Methyloxirane, Monobutyl hematopoietic data are not sufficient for mg/I
Ether system I liver I classification
nervous_system
Oxirane, Polymer with Inhalation kidney and/or Some positive data exist, but the Rat NOAEL .005 2 weeks
Methyloxirane, Monobutyl bladder data are not sufficient for mg/I
Ether classification
Oxirane, Polymer with Inhalation respiratory system Some positive data exist, but the Rat LOAEL .001 2 weeks
Methyloxirane, Monobutyl data are not sufficient for mg/I
Ether classification
Oxirane, Polymer with Inhalation heart All data are negative Rat NOAEL .5 2 weeks
Methyloxirsne, Monobutyl mg/I
Ether
Oxirane, Polymer with Ingestion liver I kidney and/or Some positive data exist, but the Rat NOAEL 145 90 days
Methyloxirane, Monobutyl bladder data are not sufficient for mg/kg/day
Ether classification
Oxirane, Polymer with Ingestion hematopoietic All data are negative Rat NOAEL 500 2 years
Methyloxirane, Monobulyl system mg/kg/day
Ether
Oxirane, Polymer with Ingestion heart I endocrine All data are negative Rat NOAEL 90 days
Methyloxirane, Monobutyl system I respiratory 3,770
Ether system mg/kg/day

Aspiration Hazard
Name Value

Please contact the address or phone number listed on the first page of the SDS for additional toxicological information
on this material and/or its components.

I SECTION 12 Ecological information


j
Ecotoxicological information

Please contact the address or phone number listed on the first page of the SDS for additional ecotoxicological information on this material
and/or its components.
Chemical fate information

Please contact the address or phone number listed on the first page of the SDS for additional chemical fate information on this material
and/or its components.

I SECTION 13: Disposal considerations 1


13.1. Disposal methods
Dispose of contents! container in accordance with the local/regional/national/international regulations.

Dispose of waste product in a permitted industrial waste facility. As a disposal alternative, incinerate uncured product in a
permitted waste incineration facility. Proper destruction may require the use of additional fuel during incineration processes.
Empty drums/barrels/containers used for transporting and handling hazardous chemicals (chemical
substances/mixtures/preparations classified as Hazardous as per applicable regulations) shall be considered, stored, treated &
disposed of as hazardous wastes unless otherwise defined by applicable waste regulations. Consult with the respective
regulating authorities to determine the available treatment and disposal facilities.

I SECTION 14 Transport Information

Page 9 of 11
I 3MTM Blue Cream Hardener 03/07/14

IFor Transport Information, please visit http://3M.comlTransportinfo or call 1-800-364-3577 or 651-737-6501. I


I SECTION 15 Regulatory information I
15.1. US Federal Regulations
Contact 3M for more information.

311/312 Hazard Categories:

Fire Hazard No
- Pressure Hazard No - Reactivity Hazard No
- Immediate Hazard Yes
- Delayed Hazard No
-

Section 313 Toxic Chemicals subject to the reporting requirements of that section and 40 CFR part 372 (EPCRA):

Ingredient C.A.S. No % by Wt
Zinc Stearate (ZINC COMPOUNDS) 557-05-1 5- 10
Benzoyl Peroxide 94-36-0 30 60
-

15.2. State Regulations


Contact 3M for more information.

15.3. Chemical Inventories


The components of this product are in compliance with the chemical notification requirements of TSCA.
(
Contact 3M for more information.

15.4. International Regulations


Contact 3M for more information.

This SDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200. I
I SECTION 16: Other information
NFPA Hazard Classification
Health: 2 Flammability: 2 Instability: 0 Special Hazards: Oxidizer

National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address
the hazards that are presented by short-term, acute exposure to a material under conditions of fire, spill, or similar
emergencies. Hazard ratings are primarily based on the inherent physical and toxic properties of the material but also include
the toxic properties of combustion or decomposition products that are known to be generated in significant quantities.

Document Group: 26-9510-4 Version Number: 9.01


Issue Date: 03/07/14 Supercedes Date: 02/19/14

DISCLAIMER: The information in this Safety Data Sheet (SDS) is believed to be correct as of the date issued. 3M MAKES
NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY
OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR
USAGE OF TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable
for users method of use or application. Given the variety of factors that can affect the use and application of a 3M product,
some of which are uniquely within the user’s knowledge and control, it is essential that the user evaluate the 3M product to

Page 10 of 11
3MTM Blue Cream Hardener 03/07/ 14

determine whether it is fit for a particular purpose and suitable for user’s method of use or application.

3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer
may have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness
or accuracy. In addition, information obtained from a database may not be as current as the information in the SDS available
directly from 3M

3M USA SDSs are available at www.3M.com

Page 11 of 11
I 3M DYNATRON® PUTTY-COTE 592, 592T, 593 12/15/15 I

3M
Safety Data Sheet
Copyright,201 5,3M Company.
All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is
allowed provided that: (I) the information is copied in full with no changes unless prior written agreement is obtained from
3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon.

Document Group: 24-2371-3 Version Number: 6.02


Issue Date: 12/15/15 Supercedes Date: 05/26/15

I SECTION 1: Identification
1.1. Product identifier
3MTM DYNATRON® PUTTY-COTE 592, 592T, 593

Product Identification Numbers


LB-K1 00-0587-6, LB-Kl 00-0587-7, LB-K1 08-2014-3, 41-3701-1520-0

1.2. Recommended use and restrictions on use

Recommended use
Automotive, Autobody repair.

1.3. Supplier’s details


MANUFACTURER: 3M
DIVISION: Automotive Aftermarket
ADDRESS: 3M Center, St. Paul, MN 55 144-1000, USA
Telephone: 1-888-3M HELPS (1 -888-364-3577)

1.4. Emergency telephone number


1-800-364-3577 or (651) 737-6501 (24 hours)

I SECTION 2: Hazard identification


The label elements below were prepared in accordance with OSHA Hazard Communication Standard, 29 CFR 19 10.1200.
This information may be different from the actual product label information for labels regulated by other agencies.

2.1. Hazard classification


Flammable Liquid: Category 3.
Serious Eye Damage/Irritation: Category 1.
Skin Sensitizer: Category 18.
Carcinogenicity: Category IA.
Specific Target Organ Toxicity (single exposure): Category I.
Specific Target Organ Toxicity (repeated exposure): Category 1.

2.2. Label elements


Signal word
Danger

C
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I 3M’ DYNATRON® PtJTTY-COTE 592, 592T, 593 12/15/15

Symbols
Flame I Corrosion Exclamation mark I Health Hazard

Hazard Statements
Flammable liquid and vapor.

Causes serious eye damage.


May cause an allergic skin reaction.
May cause cancer.

Causes damage to organs:


liver
sensory organs

Causes damage to organs through prolonged or repeated exposure:


respiratory system I
sensory organs

May cause damage to organs through prolonged or repeated exposure:


liver

Precautionary Statements
General:
Keep out of reach of children.

Prevention:
Obtain special instructions before use.
Do not handle until all safety precautions have been read and understood.
Keep away from heat/sparks/open flames/hot surfaces. No smoking.
-

Ground/bond container and receiving equipment.


Use only non-sparking tools.
Take precautionary measures against static discharge.
Keep container tightly closed.
Use explosion-proof electrical/ventilating/lighting equipment.
Do not breathe dust/fume/gas/mist/vapors/spray.
Wear protective gloves and eye/face protection.
Do not eat, drink or smoke when using this product.
Wash thoroughly after handling.
Contaminated work clothing must not be allowed out of the workplace.

Response:
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
Immediately call a POISON CENTER or doctor/physician.
IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower.
IF ON SK[N: Wash with plenty of soap and water.
If skin irritation or rash occurs: Get medical advice/attention.
Wash contaminated clothing before reuse.
Get medical advice/attention if you feel unwell.

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I 3M DYNATRON® PUTTY-COTE 592, 592T, 593 12115/15 •.10
In case of fire: Use a fire fighting agent suitable for flammable liquids such as dry chemical or carbon dioxide to
extinguish.

Storage:
Store in a well-ventilated place. Keep cool.
Store locked up.

Disposal:
Dispose of contents/container in accordance with applicable local/regional/national/international regulations.

2.3. Hazards not otherwise classified


None.

36% of the mixture consists of ingredients of unknown acute oral toxicity.


41% of the mixture consists of ingredients of unknown acute dermal toxicity.
49% of the mixture consists of ingredients of unknown acute inhalation toxicity.

SECTION 3 Composition/information on ingredients


Ingredient C.A.S. No. % by Wt
Proprietary Polyester Resin Trade Secret* 15 40 Trade Secret
-
*

Poly[oxy(methyl-l,2-ethanediyl)], .alpha.-hydro- 25322-69-4 10 - 30 Trade Secret *

omega. -hydroxy
Styrene Monomer 100-42-5 10 30 Trade Secret *
-

Defoamer Trade Secret* 1 0 30 Trade Secret *

0
-

2,4,7,9-Tetramethyl-5-Decyne-4,7-Diol 126-86-3 5 10 Trade Secret *


-

Limestone 13 17-65-3 3 7 Trade Secret *


-

Polyester Polymer Trade Secret* 3 7 Trade Secret *


Talc 14807-96-6 1 5 Trade Secret *
-

Titanium Dioxide 13463-67-7 - 5 Trade Secret *


Fatty Acid Amide Trade Secret* 1 5 Trade Secret *
-

Thickening Agent Trade Secret* < 3 Trade Secret *


Quartz Silica 14808-60-7 < 0.5 Trade Secret *

*The specific chemical identity andlor exact percentage (concentration) of this composition has been withheld as a trade
secret.

I SECTION 4 First aid measures


4.1. Description of first aid measures

Inhalation:
Remove person to fresh air. If you feel unwell, get medical attention.

Skin Contact:
Immediately wash with soap and water. Remove contaminated clothing and wash before reuse. If signs/symptoms develop,
get medical attention.

Eye Contact:
Immediately flush with large amounts of water for at least 15 minutes. Remove contact lenses if easy to do. Continue
rinsing. Immediately get medical attention.

If Swallowed:
Rinse mouth, If you feel unwell, get medical attention.

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I 3M IJYNATRON® PU TTY-COTE 592, 592T, 593 12/1 5115

4.2. Most important symptoms and effects, both acute and delayed
See Section 11.1. Information on toxicological effects.

4.3. Indication of any immediate medical attention and special treatment required
Not applicable

SECTION 5: Fire-fighting measures


5.1. Suitable extinguishing media
In case of fire: Use a fire fighting agent suitable for flammable liquids such as dry chemical or carbon dioxide to extinguish.

5.2. Special hazards arising from the substance or mixture


Closed containers exposed to heat from fire may build pressure and explode.

5.3. Special protective actions for fire-fighters


Water may not effectively extinguish tire; however, it should be used to keep fire-exposed containers and surfaces cool and
prevent explosive rupture.

SECTION 6: Accidental release measures


6.1. Personal precautions, protective equipment and emergency procedures
Evacuate area. Keep away from heat/sparks/open flames/hot surfaces. No smoking. Use only non-sparking tools. Ventilate
-

the area with fresh air. For large spill, or spills in confined spaces, provide mechanical ventilation to disperse or exhaust
vapors, in accordance with good industrial hygiene practice. Warning! A motor could be an ignition source and could cause
flammable gases or vapors in the spill area to burn or explode. Refer to other Sections of this SDS for information regarding
physical and health hazards, respiratory protection, ventilation, and personal protective equipment.

6.2. Environmental precautions


Avoid release to the environment. For larger spills, cover drains and build dikes to prevent entry into sewer systems or bodies
of water.

6.3. Methods and material for containment and cleaning up


Contain spill. Cover spill area with a fire-extinguishing foam. An appropriate aqueous film forming foam (AFFF) is
recommended. Working from around the edges of the spill inward, cover with bentonite, vermiculite, or commercially
available inorganic absorbent material. Mix in sufficient absorbent until it appears dry. Remember, adding an absorbent
material does not remove a physical, health, or environmental hazard. Collect as much of the spilled material as possible
using non-sparking tools. Place in a metal container approved for transportation by appropriate authorities. Clean up residue
with an appropriate solvent selected by a qualified and authorized person. Ventilate the area with fresh air. Read and follow
safety precautions on the solvent label and SDS. Seal the container. Dispose of collected material as soon as possible.

SECTION 7: Handling and storage


7.1. Precautions for safe handling
Keep out of reach of children. Do not handle until all safety precautions have been read and understood. Keep away from
heat/sparks/open flames/hot surfaces. No smoking. Use only non-sparking tools. Take precautionary measures against
-

static discharge. Do not breathe dust/fume/gas/mist/vapors/spray. Do not get in eyes, on skin, or on clothing. Do not eat,
drink or smoke when using this product. Wash thoroughly after handling. Contaminated work clothing should not be
allowed out of the workplace. Avoid release to the environment. Wash contaminated clothing before reuse. Avoid contact
with oxidizing agents (eg. chlorine, chromic acid etc.) Wear low static or properly grounded shoes. Use personal protective
equipment (gloves, respirators, etc.) as required. To minimize the risk of ignition, determine applicable electrical
classifications for the process using this product and select specific local exhaust ventilation equipment to avoid flammable
vapor accumulation. Ground/bond container and receiving equipment if there is potential for static electricity accumulation
during transfer. Vapors may travel long distances along the ground or floor to an ignition source and flash back.

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I 3MTM DYNATRON® PUTTY-COTE 592, 592T, 593 12/15/15

7.2. Conditions for safe storage including any incompatibilities


Store in a well-ventilated place. Keep cool. Keep container tightly closed to prevent loss of stabilizing materials. Protect
from sunlight. Store away from heat. Store away from acids. Store away from strong bases. Store away from oxidizing
agents. Store away from areas where product may come into contact with food or pharmaceuticals. Store in a dry place.

I SECTION 8: Exposure controls/personal protection


8.1. Control parameters

Occupational exposure limits


If a component is disclosed in section 3 but does not appear in the table below, an occupational exposure limit is not available
for the component.
Ingredient C.A.S. No. Agency Limit type Additional Comments
Styrene Monomer 100-42-5 ACGIH TWA:20 ppm;STEL:40 ppm A4: Not class, as human
carcin
Styrene Monomer 100-42-5 OSHA TWA: 100 ppm;CEIL:200 ppm
Limestone 1317-65-3 OSHA TWA(as total dust): 15
mg/m3 ;TWA(respirable
fraction):5 mg/m3
Titanium Dioxide 13463-67-7 ACGIH TWA:l0 mg/m3 A4: Not class, as human
carcin
Titanium Dioxide 13463-67-7 CMRG TWA(as respirable dust):5
mg/m3
Titanium Dioxide 13463-67-7 OSHA TWA(as total dust):15 mg/m3
Talc 14807-96-6 OSHA TWA concentration(as total
dust):0.3 mg/m3;TWA
concentration(respirable):0. I
mg/m3(2.4 millions of
C
particles/cu. ft.);TWA:20
millions of particles/cu. ft.
Talc 14807-96-6 ACGIH TWA(respirable fraction):2 A4: Not class, as human
rng/rn3 carcin
Talc 14807-96-6 CMRG TWA(as respirable dust):0.5
mg/m3
Quartz Silica 14808-60-7 ACGIH TWA(respirable A2: Suspected human
fraction):0.025 mg/m3 carcin.
Quartz Silica 14808-60-7 OSHA TWA concentration(as total
dust):0.3 mg/m3;TWA
concentration(respirable):0. 1
rng/m3(2.4 millions of
particles/cu. ft.)
Poly[oxy(methyl-1,2- 25322-69-4 AIHA TWA(as aerosol):lO mg/m3
ethanediyl)], .alpha.-hydro
.omega.-hydroxy
ACGIH : American Conference of Governmental Industrial Hygienists
AIHA : American Industrial Hygiene Association
CMRG : Chemical Manufacturer’s Recommended Guidelines
OSHA: United States Department of Labor Occupational Safety and Health Administration
-

TWA: Time-Weighted-Average
STEL: Short Term Exposure Limit
CElL: Ceiling

8.2. Exposure controls

8.2.1. Engineering controls


Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below relevant Exposure
C
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I 3M’ DYNATRON® PUTTY-COTE 592, 592T, 593 12/15/15

Limits andlor control dustlfume/gas/mistlvapors/spray. If ventilation is not adequate, use respiratory protection equipment.
Use explosion-proof ventilation equipment. Provide appropriate local exhaust ventilation for cutting, grinding, sanding or
machining.

8.2.2. Personal protective equipment (PPE)

Eye/face protection

Select and use eye/face protection to prevent contact based on the results of an exposure assessment. The following eye/face
protection(s) are recommended:
Full Face Shield
Indirect Vented Goggles

Skin/hand protection
Select and use gloves and/or protective clothing approved to relevant local standards to prevent skin contact based on the
results of an exposure assessment. Selection should be based on use factors such as exposure levels, concentration of the
substance or mixture, frequency and duration, physical challenges such as temperature extremes, and other use conditions.
Consult with your glove and/or protective clothing manufacturer for selection of appropriate compatible gloves/protective
clothing. Note: Nitrile gloves may be worn over polymer laminate gloves to improve dexterity.
Gloves made from the following material(s) are recommended: Polymer laminate

If this product is used in a manner that presents a higher potential for exposure (eg. spraying, high splash potential etc.), then
use of protective coveralls may be necessary. Select and use body protection to prevent contact based on the results of an
exposure assessment. The following protective clothing material(s) are recommended: Apron polymer laminate
-

Respiratory protection

An exposure assessment may be needed to decide if a respirator is required. If a respirator is needed, use respirators as part of
a full respiratory protection program. Based on the results of the exposure assessment, select from the following respirator
type(s) to reduce inhalation exposure:
Half facepiece or full facepiece air-purifying respirator suitable for organic vapors and particulates

For questions about suitability for a specific application, consult with your respirator manufacturer.

I SECTION 9: Physical and chemical properties


9.1. Information on basic physical and chemical properties
General Physical Form: Liquid
Specific Physical Form: Paste
Odor, Color, Grade: Solvent odor White Paste
Odor threshold No Data Available
pH No Data Available
1’4elting point No Data Available
Boiling Point 293 °F
Flash Point 90 °F [Test Method: Closed Cup]
Flash Point 32 °C [Test Method: SETAFLASH]
Evaporation rate No Data Available
Flammability (solid, gas) Not Applicable
Flammable Limits(LEL) No Data A vailable
Flammable Limits(UEL) A/a Data Available
Vapor Pressure No Data Available
Vapor Density 3.6 [RefStd: AIR=l]
Density 2.75 g/ml
Specific Gravity 2.75 [RefStd: WATER=l]
Solubility In Water No Data Available

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I 3M DYNATRON® PUTTY-COTE 592. 592T. 593 12/15/15

Solubility- non-water No Data Available


Partition coefficient: n-octanol/ water No Data Available
Autoignition temperature No Data Available
Decomposition temperature No Data Available
Viscosity 352,000 476,000 centipoise
-

Hazardous Air Pollutants 0.55 lb HAPS/Ib solids [Test Method: Calculated]


Volatile Organic Compounds 15.1 % weight [Test Method. calculated per CARE title 2]
Volatile Organic Compounds 414 g/l [Test Method: calculated SCAQMD rule 443.1]
Percent volatile 13.2 % weight
Percent volatile 15.2 % volume
VOC Less H20 & Exempt Solvents 415 g/l [Test Method: calculated SCAQMD rule 443.1]

I SECTION 10: Stability and reactivity


10.1. Reactivity
This material may be reactive with certain agents under certain conditions see the remaining headings in this section.
-

10.2. Chemical stability


Stable. Stable under normal conditions. May become unstable at elevated temperatures and/or pressure.

10.3. Possibility of hazardous reactions


Hazardous polymerization will not occur.

10.4. Conditions to avoid


Heat
Sparks and/or flames
C
10.5. Incompatible materials
Strong oxidizing agents
Strong acids
Alkali and alkaline earth metals
Strong oxidizing agents
Strong bases

10.6. Hazardous decomposition products


Substance Condition
Hydrocarbons Not Specified
Carbon monoxide Not Specified
Carbon dioxide Not Specified

I SECTION 11: Toxicological information


The information below may not be consistent with the material classification in Section 2 if specific ingredient
classifications are mandated by a competent authority. In addition, toxicological data on ingredients may not be
reflected in the material classification and/or the signs and symptoms of exposure, because an ingredient may be
present below the threshold for labeling, an ingredient may not be available for exposure, or the data may not be
relevant to the material as a whole.

11.1. Information on Toxicological effects

Signs and Symptoms of Exposure

Based on test data and/or information on the components, this material may produce the following health effects:
c
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[3Mm1 DYNATRON® PUTTY-COTE 592, 592T, 593 12115/15

Inhalation:
May be harmful if inhaled.
Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose
and throat pain.

May cause additional health effects (see below).

Skin Contact:
Mild Skin Irritation: Signs/symptoms may include localized redness, swelling, itching, and dryness. Allergic Skin Reaction
(non-photo induced): Signs/symptoms may include redness, swelling, blistering, and itching.

Eye Contact:
Corrosive (Eye Bums): Signs/symptoms may include cloudy appearance of the cornea, chemical burns, severe pain, tearing,
ulcerations, significantly impaired vision or complete loss of vision.

Ingestion:
May be harmful if swallowed.
Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhea.

May cause additional health effects (see below).

Additional Health Effects:

Single exposure may cause target organ effects:


Auditory Effects: Signs/symptoms may include hearing impairment, balance dysfunction and ringing in the ears.

Liver Effects: Signs/symptoms may include loss of appetite, weight loss, fatigue, weakness, abdominal tenderness and
jaundice.

Prolonged or repeated exposure may cause target organ effects:


Pneumoconiosis: Sign/symptoms may include persistent cough, breathlessness, chest pain, increased amounts of sputum, and
changes in lung function tests.

Ocular Effects: Signs/symptoms may include blurred or significantly impaired vision.

Auditory Effects: Signs/symptoms may include hearing impairment, balance dysfunction and ringing in the ears.

Liver Effects: Signs/symptoms may include loss of appetite, weight loss, fatigue, weakness, abdominal tenderness and
jaundice.

Carcinogenicity:
Contains a chemical or chemicals which can cause cancer.

Ingredient CAS No. Class Description Regulation


SILICA, CRYS AIRRESP 14808-60.7 Known human carcinogen National Toxicology Program Carcinogens
Quartz Silica 14808-60-7 Grp. I: Carcinogenic to humans International Agency for Research on Cancer
Styrene Monomer 100-42-5 Grp. 2B: Possible human care. International Agency for Research on Cancer
Styrene Monomer 100-42-5 Anticipated human carcinogen National Toxicology Program Carcinogens
Titanium Dioxide 13463-67-7 Grp. 2B: Possible human care. International Agency for Research on Cancer

Toxicological Data
If a component is disclosed in section 3 but does not appear in a table below, either no data are available for that endpoint or
the data are not sufficient for classification.

Acute Toxicity
I Name I Route I Species I Value

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I 3MTM DYNATRON® PUTTY-COTE 592, 592T, 593 12/15/15

Overall product Dermal No data available; calculated ATE> 5,000 mg/kg


Overall product Inhalation- No data available; calculated ATE 20 50 mg/I
-

Vapor(4 hr)
Overall product Ingestion No data available; calculated ATE 2,000 5,000
-

mg/kg
Styrene Monomer Dermal Rat LD5O> 2,000 mg/kg
Styrene Monomer Inhalation- Rat LC5O 8.3 mg/I
Vapor (4
hours)
Styrene Monomer Ingestion Rat LD5O 5,000 mg/kg
PoIy[oxy(methyl-I,2-ethanediyl)], .alpha.-hydro-.omega.- Dermal Rabbit LD5O> 10,000 mg/kg
hydroxy
Poly[oxy(methyl-I,2-ethanediyl)], .alpha.-hydro-.omega.- Ingestion Rat LD5O> 2,000 mg/kg
hydroxy
2,4,7,9-Tetramethyl-5-Decyne-4,7-Diol Dermal Rat LD5O > 2,000 mg/kg
2,4,7,9-Tetramethyl-5-Decyne-4,7-Diol Ingestion Rat LD5O> 500 mg/kg
Limestone Dermal Rat LD5O> 2,000 mg/lcg
Limestone Inhalation- Rat LC5O 3 mg/I
Dust/Mist
(4 hours)
Limestone Ingestion Rat LD5O 6,450 mg/kg
Polyester Polymer Ingestion LD5O estimated to be 2,000 5,000 mg/kg
-

Titanium Dioxide Dermal Rabbit LD5O> 10,000 mg/kg


Titanium Dioxide Inhalation- Rat LC5O > 6.82 mg/I
Dust/Mist
(4 hours)
Titanium Dioxide Ingestion Rat LD5O> 10,000 mg/kg
Talc Dermal LD5O estimated to be> 5,000 mg/kg
Talc Ingestion LD5O estimated to be> 5,000 mg/kg
Thickening Agent Dermal LD5O estimated to be> 5,000 mg/kg
Thickening Agent Inhalation-
Dust/Mist
(4 hours)
Rat LC5O> 12.6 mg/I
C,’
Thickening Agent Ingestion Rat LD5O> 5,000 mg/kg
Quartz Silica Dermal LD5O estimated lobe> 5,000 mg/kg
Quartz Silica Ingestion LD5O estimated to be> 5,000 mg/kg
ATE = acute toxicity estimate

Skin Corrosion/Irritation
Name Species Value

Styrene Monomer official Mild irritant


classifica
lion
Poly[oxy(methyl-l,2-ethanediyl)1, .alpha.-hydro-.omega.-hydroxy- Rabbit No significant irritation
2,4,7,9-Tetramethyl-5-Decyne-4,7-Diol Rabbit No significant irritation
Limestone Rabbit No significant irritation
Titanium Dioxide Rabbit No significant irritation
Talc Rabbit No significant irritation
Thickening Agent Rat No significant irritation
Quartz Silica Professio No significant irritation
nal
judgeme
nt

Serious Eye Damage/Irritation


Name Species Value

Styrene Monomer official Moderate irritant


classifies
tion
Poly[oxy(methyl-1,2-ethanediyl)], .alpha.-hydro-.omega.-hydroxy- Rabbit No significant irritation

C
2,4,7,9-Tetramelhyl-5-Decyne-4,7-Diol Rabbit Corrosive

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Limestone Rabbit No significant irritation


Titanium Dioxide Rabbit No significant irritation
Talc Rabbit No significant irritation
Thickening Agent Rabbit No significant irritation

Skin Sensittzation
Name Species Value
Styrene Monomer Guinea Not sensitizing
pig
2,4,7,9-Tetramethyl-5-Decyne-4,7-Diol Mouse Sensitizing
Titanium Dioxide Human Not sensitizing
and
animal

Respiratory Sensitization
Name Species Value

Talc Human Not sensitizing

Germ Cell Mutagenicity


Name Route Value

Styrene Monomer In Vitro Some positive data exist, but the data are not
sufficient for classification
Styrene Monomer In vivo Some positive data exist, but the data are not
sufficient for classification
Titanium Dioxide In Vitro Not mutagenic
Titanium Dioxide In vivo Not mutagenic
Talc In Vitro Not mutagenic
Talc In vivo Not mutagenic
Quartz Silica In Vitro Some poaitive data exist, but the data are not
sufficient for classification
Quartz Silica In vivo Some positive data exist, but the data are not
sufficient for classification

Carcinogenicity
Name Route Species Value
Styrene Monomer Ingestion Mouse Carcinogenic
Styrene Monomer Inhalation Human Carcinogenic
and
animal
Titanium Dioxide Ingestion Multiple Not carcinogenic
animal
species
Titanium Dioxide Inhalation Rat Carcinogenic
Talc Inhalation Rat Some positive data exist, but the data are not
sufficient for classification
Quartz Silica Inhalation Human Carcinogenic
and
animal

Reproductive Toxicity

Reproductive and/or Developmental Effects


Name Route Value Species Test Result Exposure
Duration
Styrene Monomer Ingestion Not toxic to female reproduction Rat NOAEL 21 3 generation
mg/kg/day
Styrene Monomer Inhalation Not toxic to female reproduction Rat NOAEL 2.1 2 generation
mg/I
Styrene Monomer Inhalation Not toxic to male reproduction Rat NOAEL 2.1 2 generation
mg/I
Styrene Monomer Ingestion Some positive male reproductive data Rat NOAEL 400 60 days

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exist, but the data are not sufficient for mg/kg/day


classification
Styrene Monomer Ingestion Some positive developmental data exist, Rat NOAEL 400 during
but the data are not sufficient for mg/kg/day gestation
classification
Styrene Monomer Inhalation Some positive developmental data exist, Multiple NOAEL 2.1 during
but the data are not sufficient for animal mg/I gestation
classification species
Limestone Ingestion Not toxic to development Rat NOAEL 625 premating &
mg/kg/day during
gestation
Talc Ingestion Not toxic to development Rat NOAEL 1,600 during
mg/kg organogenesi

Target Organ(s)

Specific Target Organ Toxicity - single exposure


Name Route Target Organ(s) Value Species Test Result Exposure
Duration
Styrene Monomer Inhalation auditory system Causes damage to organs Multiple LOAEL 4.3 not available
animal mg/I
species
Styrene Monomer Inhalation liver Causes damage to organs Mouse LOAEL 2.1 not available
mg/I
Styrene Monomer Inhalation central nervous May cause drowsiness or Human NOAEL Not occupational
system depression dizziness available exposure
Styrene Monomer Inhalation respiratory irritation Some positive data exist, but the Human NOAEL Not
data are not sufficient for and available
classification animal
Styrene Monomer

Styrene Monomer
Inhalation

Inhalation
endocrine system

kidney and/or
bladder
All data are negative

All data are negative


Rat

Multiple
animal
NOAEL Not
available
NOAEL 2.1
mg/I
not available

not available
C:
species
Limestone Inhalation respiratory system All data are negative Rat NOAEL 90 minutes
0.812 mg/I

Specific Target Organ Toxicity - repeated exposure


Name Route Target Organ(s) Value Species Test Result Exposure
Duration
Styrene Monomer Inhalation eyes Causes damage to organs through Human NOAEL Not occupational
prolonged or repeated exposure available exposure
Styrene Monomer Inhalation auditory system May cause damage to organs Multiple NOAEL 1.3 not available
though prolonged or repeated animal mg/I
exposure species
Styrene Monomer Inhalation liver May cause damage to organs Mouse LOAEL 0.85 13 weeks
though prolonged or repeated mg/I
exposure
Styrene Monomer Inhalation nervous system Some positive data exist, but the Multiple LOAEL 1.1 not available
data are not sufficient for animal mg/I
classification species
Styrene Monomer Inhalation hematopoietic Some positive data exist, but the Rat NOAEL 0.85 7 days
system data are not sufficient for mg/I
classification
Styrene Monomer Inhalation endocrine system Some positive data exist, but the Rat NOAEL 0.6 10 days
data are not sufficient for mg/I
classification
Styrene Monomer Inhalation respiratory system Some positive data exist, but the Multiple LOAEL 0.09 not available
data are not sufficient for animal mg/I
classification species
Styrene Monomer Inhalation heart bone, teeth, All data are negative Multiple NOAEL 4.3 2 years
nails, and/or hair I animal mg/I
muscles I kidney species
and/or bladder
Styrene Monomer Ingestion nervous system Some positive data exist, but the Rat LOAEL 500 8 weeks

C.
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data are not sufficient for mg/kg/day


classification
Styrene Monomer Ingestion immune system Some positive data exist, but the Multiple NOAEL Not not available
data are not sufficient for animal available
classification species
Styrene Monomer Ingestion liver kidney and/or Some positive data exist, but the Rat NOAEL 677 6 months
bladder data are not sufficient for mg/kg/day
classification
Styrene Monomer Ingestion hematopoietic Some positive data exist, but the Dog NOAEL 600 470 days
system data are not sufficient for mg/kg/day
classification
Styrene Monomer Ingestion heart respiratory All data are negative Rat NOAEL 35 105 weeks
system mg/kg/day
Limestone Inhalation respiratory system Some positive data exist, but the Human NOAEL Not occupational
data are not sufficient for available exposure
classification
Titanium Dioxide Inhalation respiratory system Some positive data exist, but the Rat LOAEL 0.01 2 years
data are not sufficient for mg/I
classification
Titanium Dioxide Inhalation pulmonary fibrosis All data are negative Human NOAEL Not occupational
available exposure
Talc Inhalation pneumoconiosis Causes damage to organs through Human NOAEL Not occupational
prolonged or repeated exposure available exposure
Talc Inhalation pulmonary fibrosis I Some positive data exist, but the Rat NOAEL 18 113 weeks
respiratory system data are not sufficient for mg/m3
classification
Quartz Silica Inhalation silicosis Causes damage to organs through Human NOAEL Not occupational
prolonged or repeated exposure available exposure

Aspiration Hazard
For the componentlcomponents, either no data are currently available or the data are not sufficient for classification.

Please contact the address or phone number listed on the first page of the SDS for additional toxicological information
on this material and/or its components.

I SECTION 12: Ecological information


Ecotoxicological information

Please contact the address or phone number listed on the first page of the SDS for additional ecotoxicological information on this material
and/or its components.
Chemical fate information

Please contact the address or phone number listed on the first page of the SDS for additional chemical fate information on this material
and/or its components.

I SECTION 13: Disposal considerations


13.1. Disposal methods
Dispose of contents! container in accordance with the local/regional/national/international regulations.

Dispose of completely cured (or polymerized) material in a permitted industrial waste facility. As a disposal alternative,
incinerate uncured product in a permitted waste incineration facility. Empty drums/barrels/containers used for transporting
and handling hazardous chemicals (chemical substances/mixtures/preparations classified as Hazardous as per applicable
regulations) shall be considered, stored, treated & disposed of as hazardous wastes unless otherwise defined by applicable
waste regulations. Consult with the respective regulating authorities to determine the available treatment and disposal
facilities.

SECTION 14: Transport Information

Page 12 of 14
I 3M DYNATRON® PUTTY-COTE 592, 592T, 593 12/15/15

For Transport Information, please visit http://3M.com/Transportinfo or call 1-800-364-3577 or 651-737-6501, I

I SECTION 15: Regulatory information


15.1. US Federal Regulations
Contact manufacturer for more information
311/312 Hazard Categories:

Fire Hazard Yes


- Pressure Hazard No
- Reactivity Hazard No - Immediate Hazard Yes- Delayed Hazard Yes
-

Section 313 Toxic Chemicals subject to the reporting requirements of that section and 40 CFR part 372 (EPCRA):

Ingredient C.A.S. No % by Wt
Styrene Monomer 100-42-5 Trade Secret 10- 30

15.2. State Regulations


Contact manufacturer for more information
California Proposition 65

Ingredient C.A.S. No. Classification


SILICA, CRYSTALLINE (AIRBORNE None Carcinogen
PARTICLES OF RESPIRABLE SIZE)
Titanium Dioxide 13463-67-7 Carcinogen

WARNING: This product contains a chemical known to the State of California to cause cancer.

15.3. Chemical Inventories


The components of this product are in compliance with the chemical notification requirements of TSCA.

Contact manufacturer for more information

15.4. International Regulations


Contact manufacturer for more information

This SDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200. I

I SECTION 16: Other information


NFPA Hazard Classification
Health: 3 Flammability: 3 Instability: I Special Hazards: None

National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address
the hazards that are presented by short-term, acute exposure to a material under conditions of fire, spill, or similar
emergencies. Hazard ratings are primarily based on the inherent physical and toxic properties of the material but also include
the toxic properties of combustion or decomposition products that are known to be generated in significant quantities.

HMIS Hazard Classification


Health: *3 Flammability: 3 Physical Hazard: 1 Personal Protection: X See PPE section.
-

Hazardous Material Identification System (HMIS® IV) hazard ratings are designed to inform employees of chemical hazards
in the workplace. These ratings are based on the inherent properties of the material under expected conditions of normal use

Page 13 of 14
3N1 DYNATRO® PUTTY-COTE 592, 592T, 593 12115/15

and are not intended for use in emergency situations. HMIS® IV ratings are to be used with a fully implemented HMIS® IV
program. HMIS® is a registered mark of the American Coatings Association (ACA).

Document Group: 24-2371-3 Version Number: 6.02


Issue Date: 12/15/15 Supercedes Date: 05/26/15

DISCLAIMER: The information in this Safety Data Sheet (SDS) is believed to be correct as of the date issued. 3M MAKES
NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY
OF MERCHANTABILITY OR FIThESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR
USAGE OF TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable
for user’s method of use or application. Given the variety of factors that can affect the use and application of a 3M product,
some of which are uniquely within the user’s knowledge and control, it is essential that the user evaluate the 3M product to
determine whether it is fit for a particular purpose and suitable for user’s method of use or application.

3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer
may have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness
or accuracy. In addition, information obtained from a database may not be as current as the information in the SDS available
directly from 3M

3M USA SDSs are available at www.3M.com

Page 14 of 14
0 0
I 3M’ Panel Bonding Adhesive PN 08115 09/24/15

3M
Safety Data Sheet
Copyright,201 5,3M Company.
All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is allowed
provided that: (1) the information is copied in full with no changes unless prior written agreement is obtained from 3M, and (2) neither
the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon.

Document Group: 07-1664-7 Version Number: 12.10


Issue Date: 09/24/15 Supercedes Date: 11/24/14

Product identifier
3MTM Panel Bonding Adhesive PN 08115

ID Number(s):

41-0003-6745-2, 41-0003-8009-1, 41-0003-8082-8, 41-9103-0505-5, 60-9800-3093-0, 60-9800-3246-4, 60-9800-4425-3, FS-9100-


3423-0, FS-9 100-3424-8, FS-9 100-3425-5, FS-9 100-5376-8

Recommended use
Automotive, Adhesive

Supplier’s details

MANUFACTURER: 3M
DIVISION: Automotive Aftermarket

ADDRESS: 3M Center, St. Paul, MN 55 144-1000, USA


Telephone: 1-888-3M HELPS (1-888-364-3577)

Emergency telephone number


1-800-364-3577 or (651) 737-6501 (24 hours)

This product is a kit or a multipart product which consists of multiple, independently packaged components. A Safety Data
Sheet (SDS), Article Information Sheet (AIS), or Article Information Letter (ALL) for each of these components is included.
Please do not separate the component documents from this cover page. The document numbers for components of this
product are:

09-3599-9, 32-4327-6

DISCLAIMER: The information in this Safety Data Sheet (SDS) is believed to be correct as of the date issued. 3M MAKES NO
WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF
MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF
TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable for user’s method of
use or application. Given the variety of factors that can affect the use and application of a 3M product, some of which are uniquely
within the user’s knowledge and control, it is essential that the user evaluate the 3M product to detennine whether it is fit for a
particular purpose and suitable for user’s method of use or application.

3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer may
have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness or accuracy.
In addition, information obtained from a database may not be as current as the information in the SDS available directly from 3M

Pagelof 2
‘1

I 3M Panel Bonding Adhesive PN 08115 09/24/15 I

3M USA SDSs are available at www.3M.com

C-,
Page2of 2
I 3MTM Panel Bonding (90 Minutes) Adhesive Part A (Accelerator) PN 08115, 38315, 58115 09/24/15 I

3M
Safety Data Sheet
Copyright,20 1 5,3M Company.
All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is
allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is obtained from
3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon.

Document Group: 09-3599-9 Version Number: 14.10


Issue Date: 09/24/15 Supercedes Date: 09/11/15

I SECTION 1: Identification
1.1. Product identifier
3MTM Panel Bonding (90 Minutes) Adhesive Part A (Accelerator) PN 08115, 38315, 58115

Product Identification Numbers


LB-K 100-0010-6

1.2. Recommended use and restrictions on use

Recommended use
Automotive, Use with Part B, MSDS 32-4327-6

1.3. Supplier’s details


MANUFACTURER: 3M
DIVISION: Automotive Aftermarket
ADDRESS: 3M Center, St. Paul, MN 55 144-1000, USA
Telephone: 1-888-3M HELPS (1-888-364-3577)

1.4. Emergency telephone number


1-800-364-3577 or (651) 737-6501 (24 hours)

I SECTION 2: Hazard identification


The label elements below were prepared in accordance with OSHA Hazard Communication Standard, 29 CFR 1910.1200.
This information may be different from the actual product label information for labels regulated by other agencies.

2.1. Hazard classification


Serious Eye Damage/Irritation: Category 1.
Skin Corrosion/Irritation: Category lB.
Skin Sensitizer: Category lB.
Reproductive Toxicity: Category I B.

2.2. Label elements


Signal word
Danger

Symbols
Corrosion Exclamation mark Health Hazard

Page 1 of 13
I 3MTM Panel Bonding (90 Minutes) Adhesive Part A (Accelerator) PN 08115, 38315, 58115 09/24/15 I

Pictograms

Hazard Statements
Causes severe skin burns and eye damage.
May cause an allergic skin reaction.
May damage fertility or the unborn child.

Precautionary Statements
General:
Keep out of reach of children.

Prevention:
Obtain special instructions before use.
Do not handle until all safety precautions have been read and understood.
Do not breathe dust/fume/gas/mist/vapors/spray.
Wear protective gloves, protective clothing, and eye/face protection.
Wash thoroughly after handling.
Contaminated work clothing must not be allowed out of the workplace.

Response:
IF INHALED: Remove person to fresh air and keep comfortable for breathing.
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower.
IF ON SKIN: Wash with plenty of soap and water.
Immediately call a POISON CENTER or doctor/physician.
If skin irritation or rash occurs: Get medical advice/attention.
Wash contaminated clothing before reuse.
IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.

Storage:
Store locked up.

Disposal:
Dispose of contents/container in accordance with applicable local/regional/national/international regulations.

2.3. Hazards not otherwise classified


May cause chemical gastrointestinal burns. Persons previously sensitized to amines may develop a cross-sensitization
reaction to certain other arnines.

36% of the mixture consists of ingredients of unknown acute oral toxicity.


37% of the mixture consists of ingredients of unknown acute dermal toxicity.

I SECTION 3: Composition/information on ingredients


Ingredient C.A.S. No. % by Wt
Polymeric Diamide 6891 1-25-1 15 40 Trade Secret *
-

Fused Silica 60676-86-0 10 30 Trade Secret *


-

Butadiene Aciylonitrile Copolymer 68683-29-4 9 30 Trade Secret *


C
-

Page 2 of 13
3MTh Panel Bonding (90 Minutes) Adhesive Part A(Accelerator) PN 08115,38315, 58115 09/24/15 -

Bis(3-Aminopropyl) Ether of Diethylene Glycol 4246-51-9 7 13 Trade Secret *


-

Tris(2,4,6-Dimethylaminomonomethyl)Phenol 90-72-2 5 10 Trade Secret *


-

Amine Epoxy Curing Agent 288-32-4 1 5 Trade Secret *


-

Dimethyl Siloxane, Reaction Product with Silica 67762-90-7 1 5 Trade Secret *


-

Inorganic Salt NJTSRN 04499600-63 17


- Trade Secret* I 5 Trade Secret *
-

Bis[(Dimethylamino)Methyl]Phenol 71074-89-0 0.1 1.5 Trade Secret


-
*

N-Aminoethylpiperazine 140-31-8 0.1 1.5 Trade Secret


-
*

Toluene 108-88-3 < 0.5 Trade Secret *

NJTS or NJTSRN: New Jersey Trade Secret Registry Number.

*The specific chemical identity andlor exact percentage (concentration) of this composition has been withheld as a trade
secret.

I SECTION 4: First aid measures


4.1. Description of first aid measures

Inhalation:
Remove person to fresh air. If you feel unwell, get medical attention.

Skin Contact:
Immediately flush with large amounts of water for at least 15 minutes. Remove contaminated clothing. Get immediate
medical attention. Wash clothing before reuse.

Eye Contact:
Immediately flush with large amounts of water for at least 15 minutes. Remove contact lenses if easy to do. Continue
rinsing. Immediately get medical attention.

If Swallowed:
Rinse mouth. Do not induce vomiting. Get immediate medical attention.

4.2. Most important symptoms and effects, both acute and delayed
See Section 11 .1. Information on toxicological effects.

4.3. Indication of any immediate medical attention and special treatment required
Not applicable

I SECTION 5: Fire-fighting measures


5.1. Suitable extinguishing media
In case of fire: Use a fire fighting agent suitable for ordinary combustible material such as water or foam to extinguish.

5.2. Special hazards arising from the substance or mixture


None inherent in this product.

Hazardous Decomposition or By-Products


Substance Condition
Carbon monoxide During Combustion
Carbon dioxide During Combustion

5.3. Special protective actions for fire-fighters


No special protective actions for fire-fighters are anticipated.

Page 3 of 13
I 3M’ Panel Bonding (90 Minutes) Adhesive Part A (Accelerator) PN 08115, 38315, 58115 09/24/15

I SECTION 6: Accidental release measures


6.1. Personal precautions, protective equipment and emergency procedures
Evacuate area. Ventilate the area with fresh air. For large spill, or spills in confined spaces, provide mechanical ventilation
to disperse or exhaust vapors, in accordance with good industrial hygiene practice. Refer to other sections of this SDS for
information regarding physical and health hazards, respiratory protection, ventilation, and personal protective equipment.

6.2. Environmental precautions


Avoid release to the environment. For larger spills, cover drains and build dikes to prevent entry into sewer systems or bodies
of water.

6.3. Methods and material for containment and cleaning up


Contain spill. Working from around the edges of the spill inward, cover with bentonite, vermiculite, or commercially
available inorganic absorbent material. Mix in sufficient absorbent until it appears dry. Remember, adding an absorbent
material does not remove a physical, health, or environmental hazard. Collect as much of the spilled material as possible.
Place in a closed container approved for transportation by appropriate authorities. Clean up residue with an appropriate
solvent selected by a qualified and authorized person. Ventilate the area with fresh air. Read and follow safety precautions on
the solvent label and SDS. Seal the container. Dispose of collected material as soon as possible.

I SECTION 7: Handling and storage


7.1. Precautions for safe handling
Do not use in a confined area with minimal air exchange. Keep out of reach of children. Do not handle until all safety
precautions have been read and understood. Do not breathe dust/fume/gas/mist/vapors/spray. Do not get in eyes, on skin, or
on clothing. Do not eat, drink or smoke when using this product. Wash thoroughly after handling. Contaminated work
clothing should not be allowed out of the workplace. Wash contaminated clothing before reuse. Avoid contact with
oxidizing agents (eg. chlorine, chromic acid etc.) Use personal protective equipment (gloves, respirators, etc.) as required.
C
7.2. Conditions for safe storage including any incompatibilities
Store away from acids. Store away from oxidizing agents.

I SECTION 8: Exposure controls/personal protection


8.1. Control parameters

Occupational exposure limits


If a component is disclosed in section 3 but does not appear in the table below, an occupational exposure limit is not available
for the component.
Ingredient C.A.S. No. Agency Limit type Additional Comments
Toluene 108-88-3 ACGIH TWA:20 ppm A4: Not class, as human
carcin
Toluene 108-88-3 CMRG STEL:75 ppm Skin Notation
Toluene 108-88-3 OSHA TWA:200 ppm;CEIL:300 ppm
SILICA, AMORPHOUS 60676-86-0 OSHA TWA concentration:0.8
rng/m3;TWA:20 millions of
particles/cu. ft.
Dimethyl Siloxane, Reaction 67762-90-7 CMRG CEIL:5 mg/m3
Product with Silica
SILICA, AMORPHOUS 67762-90-7 OSHA TWA concentration:0.8
mg/m3;TWA:20 millions of
particles/cu. ft.
Tris(2,4,6- 90-72-2 CMRG TWA:5 ppm
Dimethylaminomonomethyl)Phen
C
Page 4 of 13
I 3M
’ Panel Bonding (90 Minutes)
5 Adhesive Part A (Accelerator) PN 08115, 38315, 58115 09/24/15

Lol I I I I I
ACGIH : American Conference of Governmental Industrial Hygienists
AIHA: American Industrial Hygiene Association
CMRG: Chemical Manufactureis Recommended Guidelines
OSHA: United States Department of Labor Occupational Safety and Health Administration
TWA: Time-Weighted-Average
STEL: Short Term Exposure Limit
CElL: Ceiling

8.2. Exposure controls

8.2.1. Engineering controls


Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below relevant Exposure
Limits and/or control dustlfume/gas/mistJvapors/spray. If ventilation is not adequate, use respiratory protection equipment.

8.2.2. Personal protective equipment (PPE)

Eye/face protection

Select and use eye/face protection to prevent contact based on the results of an exposure assessment. The following eye/face
protection(s) are recommended:
Full Face Shield
Indirect Vented Goggles

Skin/hand protection
Select and use gloves and/or protective clothing approved to relevant local standards to prevent skin contact based on the
results of an exposure assessment. Selection should be based on use factors such as exposure levels, concentration of the
substance or mixture, frequency and duration, physical challenges such as temperature extremes, and other use conditions.
Consult with your glove and/or protective clothing manufacturer for selection of appropriate compatible gloves/protective
clothing. Note: Nitrile gloves may be worn over polymer laminate gloves to improve dexterity.
Gloves made from the following material(s) are recommended: Polymer laminate

If this product is used in a manner that presents a higher potential for exposure (eg. spraying, high splash potential etc.), then
use of protective coveralls may be necessary. Select and use body protection to prevent contact based on the results of an
exposure assessment. The following protective clothing material(s) are recommended: Apron polymer laminate
-

Respiratory protection

An exposure assessment may be needed to decide if a respirator is required. If a respirator is needed, use respirators as part of
a full respiratory protection program. Based on the results of the exposure assessment, select from the following respirator
type(s) to reduce inhalation exposure:
Half facepiece or full facepiece air-purifying respirator suitable for organic vapors and particulates

For questions about suitability for a specific application, consult with your respirator manufacturer.

I SECTION 9 Physical and chemical properties


9.1. Information on basic physical and chemical properties
General Physical Form: Liquid
Specific Physical Form: Viscous liquid
Odor, Color, Grade: Tan liquid, slight amine odor.
Odor threshold No Data Available
pH Not Applicable
Melting point Not Applicable
Boiling Point >1 10°C
Flash Point 110°C [Test Method: Closed Cup]
Evaporation rate <=1 [RefStd: BUOACI]

Page 5 of 13
I 3M’ Panel Bonding (90 Minutes) Adhesive Part A (Accelerator) PN 08115, 38315, 58115 09/24/15 I

Flammability (solid, gas) Not Applicable


Flammable Limits(LEL) No Data Available
Flammable Limits(UEL) No Data Available
Vapor Pressure <=200 mmHg [@ 20°C]
Vapor Density No Data Available
Density 1.2 g/ml
Specific Gravity 1.2 [RefStd: WATER= 1]
Solubility In Water No Data Available
Solubility- non-water No Data Available
Partition coefficient: n-octanol/ water No Data Available
Autoignition temperature No Data Available
Decomposition temperature No Data Available
Viscosity 100,000-225,000 centipoise [Test Method: Brookfield]
Hazardous Air Pollutants 0.01 lb HAPS/Ib solids [Test Method: Calculated]
Volatile Organic Compounds 4 gIl [Test Method: calculated SCAQMD rule 443.1]
Volatile Organic Compounds 0.4 % weight [Test Method: calculated per CARB title 2]
Percent volatile 0.4 % weight
VOC Less H20 & Exempt Solvents 4 g/l [Test Method: calculated SCAQMD rule 443.1]

I SECTION 10: Stability and reactivitv


10.1. Reactivity
This material is considered to be non reactive under normal use conditions.

10.2. Chemical stability


Stable.

10.3. Possibility of hazardous reactions


0
Hazardous polymerization will not occur.

10.4. Conditions to avoid


None known.

10.5. Incompatible materials


Strong oxidizing agents

10.6. Hazardous decomposition products


Substance Condition
None known.

Refer to section 5.2 for hazardous decomposition products during combustion.

I SECTION 11: Toxicological information


The information below may not be consistent with the material classification in Section 2 if specific ingredient
classifications are mandated by a competent authority. In addition, toxicological data on ingredients may not be
reflected in the material classification and/or the signs and symptoms of exposure, because an ingredient may be
present below the threshold for labeling, an ingredient may not be available for exposure, or the data may not be
relevant to the material as a whole.

11.1. Information on Toxicological effects

Signs and Symptoms of Exposure


C
Page 6 of 13
I_3MTM Panel Bonding (9nutes) Adhesive Part A(Accelerator) P_15, 38315, 58115 09/24115

Based on test data and/or information on the components, this material may produce the following health effects:

Inhalation:
Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose
and throat pain.

May cause additional health effects (see below).

Skin Contact:
May be harmful in contact with skin.
Corrosive (Skin Burns): Signs/symptoms may include localized redness, swelling, itching, intense pain, blistering,
ulceration, and tissue destruction.

Allergic Skin Reaction (non-photo induced): Signs/symptoms may include redness, swelling, blistering, and itching.

Eye Contact:
Corrosive (Eye Bums): Signs/symptoms may include cloudy appearance of the cornea, chemical burns, severe pain, tearing,
ulcerations, significantly impaired vision or complete loss of vision.

Ingestion:
May be harmful if swallowed.
Gastrointestinal Corrosion: Signs/symptoms may include severe mouth, throat and abdominal pain; nausea; vomiting; and
diarrhea; blood in the feces and/or vomitus may also be seen.

May cause additional health effects (see below).

Additional Health Effects:

Reproductive/Developmental Toxicity:
Contains a chemical or chemicals which can cause birth defects or other reproductive harm.

Toxicological Data
If a component is disclosed in section 3 but does not appear in a table below, either no data are available for that endpoint or
the data are not sufficient for classification.

Acute Toxicity
Name Route Species Value
Overall product Dermal No data available; calculated ATE 2,000- 5,000
mg/kg
Overall product Ingestion No data available; calculated ATE 2,000 - 5,000
mg/kg
Fused Silica Dermal Rabbit LDSO> 5,000 mg/kg
Fused Silica Inhalation- Rat LC5O > 0.69 1 mg/I
Dust/Mist
(4 hours)
Fused Silica Ingestion Rat LD5O> 5,110 mg/kg
Butadiene Acrylonitrile Copolymer Demial Rabbit LD5O> 3,000 mg/kg
Butadiene Acrylonitrile Copolymer Ingestion Rat LD5O> 15,300 mg/kg
Bis(3-Aminopropyl) Ether of Diethylene Glycol Dermal Rabbit LD5O 2,500 mg/kg
Bis(3-Aminopropyl) Ether of Diethylene Glycol Ingestion Rat LD5O 3,160 mg/kg
Tris(2,4,6-Dimethylaminomonomethyl)Phenol Dermal Rat LD5O 1,280 mg/kg
Tria(2,4,6-Dimethylaminomonomethyl)Phenol Ingestion Rat LD5O 1,000 mg/kg
Dimethyl SiloxAne, Reaction Product with Silica Dermal Rabbit LD5O> 5,000 mg/kg
Dimethyl Siloxane, Reaction Product with Silica Inhalation- Rat LC5O >0.691 mg/I
Dust/Mist
(4 hours)
Dhnethyl Siloxane, Reaction Product with Silica Ingestion Rat LD5O >5,110 mg/kg
Amine Epoxy Curing Agent Dermal LD5O estimated to be 200- 1,000 mg/kg

Page 7 of 13
3MTM Panel Bonding (90 Minutes) Adhesive Part A (Accelerator) PN 08115, 38315, 58115 09/24/15 i

Amine Epoxy Curing Agent Ingestion Rat LD50 970 mg/kg


Inorganic Salt NJTSRN 04499600-6317
- Dermal Rat LD5O estimated to be> 5,000 mg/lcg
Inorganic Salt NJTSRN 04499600-63 17
- Ingestion Rat LD5O 9,285 mg/kg
Bis[(Dimethylamino)Methyl]Phenol Ingestion LD5O estimated to be 300- 2,000 mg/kg
N-Aminoethylpiperazine Dermal Rabbit LD5O 865 mg/kg
N-Aminoethylpiperazine Ingestion Rat LD5O 1,470 mg/kg
Toluene Dermal Rat LD5O 12,000 mg/kg
Toluene Inhalation- Rat LC5O 30 mg/I
Vapor (4
hours)
Toluene Ingestion Rat LD5O 5,550 mg/kg
ATE = acute toxicity estimate

Skin Corrosion/Irritation

Name Species Value

Overall product Rabbit Corrosive


Polymeric Diamide Rabbit Irritant
Fused Silica Rabbit No significant irritation
Bis(3-Aminopropyl) Ether of Diethylene Glycol Rabbit Corrosive
Tris(2,4,6-Dimethylsminomonomethyl)Phenol Rabbit Corrosive
Dimethyl Siloxane, Reaction Product with Silica Rabbit No significant irritation
Bis[(Dimethylamino)Methyl]Phenol similar Corrosive
compoun
da
N-Aminoethylpiperazine Rabbit Corrosive
Toluene Rabbit Irritant

Serious Eye Damage/Irritation


Name

Overall product
Species

similar
Value

Corrosive
C
health
hazards
Polymeric Diamide similar Corrosive
health
hazards
Fused Silica Rabbit No significant irritation
Bis(3-Asninopropyl) Ether of Diethylene Glycol similar Corrosive
health
hazards
Tris(2,4,6-Dimethylaminomonomethyl)Phenol Rabbit Corrosive
Dimethyl Siloxane, Reaction Product with Silica Rabbit No significant irritation
Bis[(Dimethylamino)MethyllPhenol similar Corrosive
compoun
ds
N-Aminoethylpiperazine Rabbit Corrosive
Toluene Rabbit Moderate irritant

Skin Sensitization
Name Species Value
Overall product Guinea Sensitizing
pig
Polymeric Diamide Guinea Sensitizing
pig
Fused Silica Human Not sensitizing
and
animal
Butadiene Acrylonitrile Copolymer Guinea Some positive data exist, but the data are not
pig sufficient for classification
Tris(2,4,6-Dimethylaminomonomethyl)Phenol Guinea Some positive data exist, but the data are not
pig sufficient for classification
Dimethyl Siloxane, Reaction Product with Silica Human Not sensitizing
and

Page 8 of 13
I 3M Panel Bonding (90 Minutes) Adhesive Part A (Accelerator) PN 08115. 38315. 58115 09/24/15

animal
N-Aminoethylpiperazine Guinea Senaitizing
pig
Toluene Guinea Not sensitizing
pig

Respiratory Sensitization

For the component/components, either no data are currently available or the data are not sufficient for classification.

Germ Cell Mutagenicity


Name Route Value

Fused Silica In Vitro Not mutagenic


Tris(2,4,6-Dimethylaminomonomethyl)Phenol In Vitro Not mutagenic
Dimethyl Siloxane, Reaction Product with Silica In Vitro Not mutagenic
N-Aminoethylpiperazine In vivo Not mutagenic
N-Aminoethylpiperazine In Vitro Some positive data exist, but the data are not
sufficient for classification
Toluene In Vitro Not mutagenic
Toluene In vivo Not mutagenic

Carcinogenicity
Name Route Species Value
Fused Silica Not Mouse Some positive data exist, but the data are not
Specified sufficient for classification
Dimethyl Siloxane, Reaction Product with Silica Not Mouse Some positive data exist, but the data are not
Specified sufficient for classification
Toluene Dermal Mouse Some positive data exist, but the data are not
sufficient for classification
Toluene Ingestion Rat Some positive data exist, but the data are not
sufficient for classification
Toluene Inhalation Mouse Some positive data exist, but the data are not
sufficient for classification

Reproductive Toxicity

Reproductive and/or Developmental Effects


Name Route Value Species Test Result Exposure
Duration
Fused Silica Ingestion Not toxic to female reproduction Rat NOAEL 509 1 generation
mg/kg/day
Fused Silica Inhalation Not toxic to male reproduction Rat NOAEL 497 1 generation
mg/kg/day
Fused Silica Ingestion Not toxic to development Rat NOAEL 1,350 during
mg/kg/day organogenesi

Dimethyl Siloxane, Reaction Product with Ingestion Not toxic to female reproduction Rat NOAEL 509 1 generation
Silica mg/kg/day
Dimethyl Siloxane, Reaction Product with Ingestion Not toxic to male reproduction Rat NOAEL 497 1 generation
Silica mg/kg/day
Dimethyl Siloxane, Reaction Product with Ingestion Not toxic to development Rat NOAEL 1,350 during
Silica mg/kg/dsy organogenesi

N-Aminoethylpiperazine Ingestion Not toxic to female reproduction Rat NOAEL 598 prernating &
mg/kg/day during
gestation
N-Aminoethylpiperazine Ingestion Not toxic to male reproduction Rat NOAEL 409 32 days
mg/kg/day
N-Aminoethylpiperazine Ingestion Not toxic to development Rat NOAEL 899 premating &
mg/kg/day during
gestation
Toluene Inhalation Some positive female reproductive data Human NOAEL Not occupational
exist, but the data are not sufficient for available exposure
classification

Page 9 of 13
I 3M Panel Bonding (90 Minutes) Adhesive Part A (Accelerator) PN 08115,38315,58115 09/24/15 i

Toluene Inhalation Some positive male reproductive data Rat NOAEL 2.3 1 generation
exist, but the data are not sufficient for mg/I
classification
Toluene Ingestion Toxic to development Rat LOAEL 520 during
mg/kg/day gestation
Toluene Inhalation Toxic to development Human NOAEL Not poisoning
available and/or abuse

Target Organ(s)

Specific Target Organ Toxicity - single exposure


Name Route Target Organ(s) Value Species Test Result Exposure
Duration
Bis(3-Aminopropyl) Ether Inhalation respiratory irritation Some positive data exist, but the NOAEL Not
of Diethylene Glycol data are not sufficient for available
classification
Tris(2,4,6- Inhalation respiratory irritation Some positive data exist, but the NOAEL Not
Dimethylaminomonomethy data are not sufficient for available
l)Phenol classification
N-Aminoethylpiperazine Inhalation respiratory irritation Some positive data exist, but the NOAEL Not
data are not sufficient for available
classification
Toluene Inhalation central nervous May cause drowsiness or Human NOAEL Not
system depression dizziness available
Toluene Inhalation respiratory irritation Some positive data exist, but the Human NOAEL Not
data are not sufficient for available
classification
Toluene Inhalation immune system Some positive data exist, but the Mouse NOAEL 3 hours
data are not sufficient for 0.004 mg/I
classification
Toluene Ingestion central nervous May cause drowsiness or Human NOAEL Not poisoning
system depression dizziness available and/or abuse

Specific Target Organ Toxicity - repeated exposure


Name Route Target Organ(s) Value Species Test Result Exposure
Duration
Fused Silica Inhalation respiratory system I All data are negative Human NOAEL Not occupational
silicosis available exposure
Tris(2,4,6- Dermal skin I liver I nervous Some positive data exist, but the Rat NOAEL 125 28 days
Dimethylaminomonomethy system data are not sufficient for mg/kg/day
l)Phenol classification
Tris(2,4,6- Dermsl auditory system I All data are negative Rat NOAEL 125 28 days
Dimethylaminomonomethy hematopoietic mg/kg/day
1)Phenol system I eyes
Dimethyl Siloxane, Inhalation respiratory system I All data are negative Human NOAEL Not occupational
Reaction Product with silicosis available exposure
Silica
N-Aminoethylpiperazine Ingestion heart I endocrine All data are negative Rat NOAEL 598 28 days
system I mg/kg/day
hematopoietic
system liver
nervous System I
kidney and/or
bladder
Toluene Inhalation auditory system Causes damage to organs through Human NOAEL Not poisoning
nervous system I prolonged or repeated exposure available and/or abuse
eyes I olfactory
system
Toluene Inhalation respiratory system Some positive data exist, but the Rat LOAEL 2.3 15 months
data are not sufficient for mg/I
classification
Toluene Inhalation heart I liver I kidney Some positive data exist, but the Rat NOAEL 11.3 15 weeks
and/or bladder data are not sufficient for mg/I
classification
Toluene Inhalation endocrine system Some positive data exist, but the Rat NOAEL 1.1 4 weeks
data are not sufficient for mg/I
classification

Page 10 of 13
I 3MTh! Panel Bondine (90 Minutesi Adhesive Part A (AcceIerator PN 08115. 38315. 58115 09/24/15

Toluene Inhalation immune system Some positive data exist, but the Mouse NOAEL Not 20 days
data are not sufficient for available
classification
Toluene Inhalation bone, teeth, nails, Some positive data exist, but the Mouse NOAEL 1.1 8 weeks
and/or hair data are not sufficient for mg/I
classification
Toluene Inhalation hematopoietic Some positive data exist, but the Human NOAEL Not occupational
system I vascular data are not sufficient for available exposure
system classification
Toluene Ingestion nervous system Some positive data exist, but the Rat NOAEL 625 13 weeks
data are not sufficient for mg/kg/day
classification
Toluene Ingestion heart Some positive data exist, but the Rat NOAEL 13 weeks
data are not sufficient for 2,500
classification mg/kg/day
Toluene Ingestion liver I kidney and/or Some positive data exist, but the Multiple NOAEL 13 weeks
bladder data are not sufficient for animal 2,500
classification species mg/kg/day
Toluene Ingestion hematopoietic Some positive data exist, but the Mouse NOAEL 600 14 days
system data are not sufficient for mg/kg/day
classification
Toluene Ingestion endocrine system Some positive data exist, but the Mouse NOAEL 105 28 days
data are not sufficient for mg/kg/day
classification
Toluene Ingestion immune system Some positive data exist, but the Mouse NOAEL 105 4 weeks
dala are not sufficient for mg/kg/day
classification

Aspiration Hazard
Name Value
Toluene Aspiration hazard

Please contact the address or phone number listed on the first page of the SDS for additional toxicological information
on this material and/or its components.

I SECTION 12 Ecological information

Ecotoxicological information

Please contact the address or phone number listed on the first page of the SDS for additional ecotoxicological information on this material
and/or its components.
Chemical fate information

Please contact the address or phone number listed on the first page of the SDS for additional chemical fate information on this material
and/or its components,

I SECTION 13: Disposal considerations

13.1. Disposal methods


Dispose of contents! container in accordance with the local/regional/national/international regulations.

Dispose of completely cured (or polymerized) material in a permitted industrial waste facility. As a disposal alternative,
incinerate uncured product in a permitted waste incineration facility. Proper destruction may require the use of additional fuel
during incineration processes. Empty drums/barrels/containers used for transporting and handling hazardous chemicals
(chemical substances/mixtures/preparations classified as [-lazardous as per applicable regulations) shall be considered, stored,
treated & disposed of as hazardous wastes unless otherwise defined by applicable waste regulations. Consult with the
respective regulating authorities to determine the available treatment and disposal facilities.

SECTION 14: Transport Information

Page 11 of 13
I 3MTM Panel Bonding (90 Minutes) Adhesive Part A (Accelerator) PN 08115, 38315, 58115 09/24/15

For Transport Information, please visit http://3M.com/Transportinfo or call 1-800-364-3577 or 651-737-6501. j

I SECTION 15: Reu1atory information 1


15.1. US Federal Regulations
Contact 3M for more information.

311/312 Hazard Categories:

Fire Hazard No
- Pressure Hazard No
- Reactivity Hazard No - Immediate Hazard Yes - Delayed Hazard Yes
-

Section 313 Toxic Chemicals subject to the reporting requirements of that section and 40 CFR part 372 (EPCRA):

Ingredient C.A.S. No % by Wt
Inorganic Salt NJTSRN 04499600-63 17
- Trade Secret 1 5
-

(NITRATE COMPOUNDS (WATER


DISSOCIABLE; REPORTABLE ONLY WHEN
IN AQUEOUS SOLUTION))

15.2. State Regulations


Contact 3M for more information.

California Proposition 65

Enredient
Benzene
Benzene
C.A.S. No.
71-43-2
71-43-2
Classification
Male reproductive toxin
Carcinogen
0
Benzene 71-43-2 Developmental Toxin
Toluene 108-88-3 Female reproductive toxin
Toluene 108-88-3 Developmental Toxin

WARNING: This product contains a chemical known to the State of California to cause birth defects or other reproductive
harm.
WARNING: This product contains a chemical known to the State of California to cause cancer.

15.3. Chemical Inventories


The components of this product are in compliance with the chemical notification requirements of TSCA.

Contact 3M for more information.

15.4. International Regulations


Contact 3M for more information.

I This SDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200. I
I SECTION 16: Other information
NFPA Hazard Classification
Health: 3 Flammability: I Instability: 0 Special Hazards: None

National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address
the hazards that are presented by short-term, acute exposure to a material under conditions of fire, spill, or similar

Page 12 of 13
I 3MTM Panel Bonding (90 Minutes) Adhesive Part A (Accelerator) PN 08115, 38315, 58115 09/24/15 I

emergencies. Hazard ratings are primarily based on the inherent physical and toxic properties of the material but also include
the toxic properties of combustion or decomposition products that are known to be generated in significant quantities.

Document Group: 09-3599-9 Version Number: 14.10


Issue Date: 09/24/15 Supercedes Date: 09/11/15

DISCLAIMER: The information in this Safety Data Sheet (SDS) is believed to be correct as of the date issued. 3M MAKES
NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY
OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR
USAGE OF TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable
for user’s method of use or application. Given the variety of factors that can affect the use and application of a 3M product,
some of which are uniquely within the user’s knowledge and control, it is essential that the user evaluate the 3M product to
determine whether it is fit for a particular purpose and suitable for use?s method of use or application.

3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer
may have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness
or accuracy. In addition, information obtained from a database may not be as current as the information in the SDS available
directly from 3M

3M USA SDSs are available at www.3M.com

Page 13 of 13
I 3M Panel Bonding Adhesive Part B PNs 08115, 38315, 58115 09/23/15 I

3M
Safety Data Sheet
Copyright,201 5,3M Company.
All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is
allowed provided that: (I) the information is copied in full with no changes unless prior written agreement is obtained from
3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon.

Document Group: 32-4327-6 Version Number: 1.01


Issue Date: 09/23/15 Supercedes Date: 11/24/14

I SECTION 1: Identification
1.1. Product identifier
3MTM Panel Bonding Adhesive Part B PNs 08115, 38315, 58115

1.2. Recommended use and restrictions on use

Recommended use
Automotive, Structural Panel Bonding Adhesive

1.3. Supplier’s details


MANUFACTURER: 3M
DIVISION: Automotive Aftermarket
ADDRESS: 3M Center, St. Paul, MN 55 144-1000, USA
Telephone: 1-888-3M HELPS (1-888-364-3577)

1.4. Emergency telephone number


1-800-364-3577 or (651) 737-6501 (24 hours)

I SECTION 2: Hazard identification


The label elements below were prepared in accordance with OSHA Hazard Communication Standard, 29 CFR 1910.1200.
This infoniiation may be different from the actual product label information for labels regulated by other agencies.

2.1. Hazard classification


Serious Eye Damage/Irritation: Category 2A.
Skin Sensitizer: Category 1.
Carcinogenicity: Category 2.

2.2. Label elements


Signal word
Warning

Symbols
Exclamation mark Health Hazard

Pictograms

C
Page 1 of 13
I 3M Panel Bonding Adhesive Part B PNs 08115, 38315, 58115 09/23/15

Hazard Statements
Causes serious eye irritation.
May cause an allergic skin reaction.
Suspected of causing cancer.

Precautionary Statements
General:
Keep out of reach of children.

Prevention:
Obtain special instructions before use.
Do not handle until all safety precautions have been read and understood.
Avoid breathing dust/fume/gas/mist/vapors/spray.
Wear protective gloves and eye/face protection.
Wash thoroughly after handling.
Contaminated work clothing must not be allowed out of the workplace.

Response:
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
If eye irritation persists: Get medical advice/attention.
IF ON SKIN: Wash with plenty of soap and water.
If skin irritation or rash occurs: Get medical advice/attention.
Wash contaminated clothing before reuse.
IF exposed or concerned: Get medical advice/attention.

Storage:
Store locked up.

Disposal:
Dispose of contents/container in accordance with applicable local/regional/national/international regulations.

2.3. Hazards not otherwise classified


None.

34% of the mixture consists of ingredients of unknown acute inhalation toxicity.

I SECTION 3: Composition/information on ingredients


Ingredient C.A.S. No. % by Wt
4,4-Isopropylidenediphenol-Epichiorohydrin Polymer 25068-38-6 30 60 Trade Secret *
-

Oxide Glass Chemicals 65997-17-3 10- 30 Trade Secret *


Fused Silica 60676-86-0 7 13 Trade Secret *
-

l,4-Bis[(2,3-Epoxypropoxy)MethyljCyclohexane 14228-73-0 7 13 Trade Secret *


-

Acrylate Polymer Trade Secret* 5 10 Trade Secret *


-

Silica 7631 -8 6-9 1 5 Trade Secret *


-

3-(Trimethoxysilyl)propyl Glycidyl Ether 2530-83-8 0.5 1.5 Trade Secret *


-

Dimethyl Siloxane, Reaction Product With Silica 67762-90-7 0.5 1.5 Trade Secret *
-

Carbon Black 1333-86-4 < 0.5 Trade Secret *

Page 2 of 13
I 3M Panel Bonding Adhesive Part B PNs 08115, 38315, 58115 09/23/15

lEpichiorohydrin *
1106-89-8 1<0.02 Trade Secret

*The specific chemical identity and/or exact percentage (concentration) of this composition has been withheld as a trade
secret.

I SECTION 4: First aid measures


4.1. Description of first aid measures

Inhalation:
Remove person to fresh air. If you feel unwell, get medical attention.

Skin Contact:
Immediately wash with soap and water. Remove contaminated clothing and wash before reuse. If signs/symptoms develop,
get medical attention.

Eye Contact:
Immediately flush with large amounts of water. Remove contact lenses if easy to do. Continue rinsing. Get medical
attention.

If Swallowed:
Rinse mouth. If you feel unwell, get medical attention.

4.2. Most important symptoms and effects, both acute and delayed
See Section 11.1. Information on toxicological effects.

4.3. Indication of any immediate medical attention and special treatment required
Not applicable

I SECTION 5: Fire-fighting measures


5.1. Suitable extinguishing media
In case of fire: Use a fire fighting agent suitable for ordinary combustible material such as water or foam to extinguish.

5.2. Special hazards arising from the substance or mixture


None inherent in this product.

5.3. Special protective actions for fire-fighters


No special protective actions for fire-fighters are anticipated.

I SECTION 6: Accidental release measures


6.1. Personal precautions, protective equipment and emergency procedures
Evacuate area. Ventilate the area with fresh air. For large spill, or spills in confined spaces, provide mechanical ventilation
to disperse or exhaust vapors, in accordance with good industrial hygiene practice. Refer to other sections of this SDS for
information regarding physical and health hazards, respiratory protection, ventilation, and personal protective equipment.

6.2. Environmental precautions


Avoid release to the environment. For larger spills, cover drains and build dikes to prevent entry into sewer systems or bodies
of water.

6.3. Methods and material for containment and cleaning up


Contain spill. Working from around the edges of the spill inward, cover with bentonite, vermiculite, or commercially
available inorganic absorbent material. Mix in sufficient absorbent until it appears dry. Remember, adding an absorbent

Page 3 of 13
3M’ Panel Bonding Adhes lye Part B PNs 08115, 38315, 58115 09/23/15

material does not remove a physical, health, or environmental hazard. Collect as much of the spilled material as possible.
Place in a closed container approved for transportation by appropriate authorities. Clean up residue with an appropriate
solvent selected by a qualified and authorized person. Ventilate the area with fresh air. Read and follow safety precautions on
the solvent label and SDS. Seal the container. Dispose of collected material as soon as possible.

I SECTION 7: Handling and storage


7.1. Precautions for safe handling
Keep out of reach of children. Do not handle until all safety precautions have been read and understood. Avoid breathing
dust/fume/gas/mist/vapors/spray. Do not get in eyes, on skin, or on clothing. Do not eat, drink or smoke when using this
product. Wash thoroughly after handling. Contaminated work clothing should not be allowed out of the workplace. Avoid
release to the environment. Wash contaminated clothing before reuse. Avoid contact with oxidizing agents (eg. chlorine,
chromic acid etc.) Use personal protective equipment (gloves, respirators, etc.) as required.

7.2. Conditions for safe storage including any incompatibilities


Store away from acids. Store away from strong bases. Store away from oxidizing agents. Store away from amines.

I SECTION 8: Exposure controls/personal protection


8.1. Control parameters

Occupational exposure limits


If a component is disclosed in section 3 but does not appear in the table below, an occupational exposure limit is not available
for the component.
Ingredient C.A.S. No. Agency Limit type Additional Comments
Epichlorohydrin 106-89-8 ACGIH TWA:0.5 ppm A3: Confirmed animal
carcin., Skin Notation
Epichlorohydrin 106-89-8 OSHA TWA:19 mg/m3(5 ppm) Skin Notation
Carbon Black 1333-86-4 ACGIH TWA(inhalable fraction):3 A3: Confirmed animal
mg/m3 carcin.
Carbon Black 1333-86-4 CMRG TWA:0.5 mg/m3
Carbon Black 1333-86-4 OSHA TWA:3.5 mg/m3
3-(Trimethoxysilyl)propyl 2530-83-8 CMRG TWA:5 ppm
Glycidyl Ether
SILICA, AMORPHOUS 60676-86-0 OSHA TWA concentration:0.8
mg/m3;TWA:20 millions of
particles/cu. ft.
Oxide Glass Chemicals 65997-17-3 Manufacturer TWA(as dust):lO mg/m3
determined
Dimethyl Siloxane, Reaction 67762-90-7 CMRG CEIL:5 mg/m3
Product With Silica
SILICA, AMORPHOUS 67762-90-7 OSHA TWA concentration:0.8
mg/rn3;TWA:20 millions of
particles/cu. ft.
Silica 763 1-86-9 CMRG TWA(as respirable dust):3
mg/m3
SILICA, AMORPHOUS 763 1-86-9 OSHA TWA concentration:0.8
mg/m3;TWA:20 millions of
particles/cu. ft.
ACGIH: American Conference of Governmental Industrial Hygienists
AIHA : American Industrial Hygiene Association
CMRG: Chemical Manufacture?s Recommended Guidelines
OSHA: United States Department of Labor Occupational Safety and Health Administration
-

TWA: Time-Weighted-Average
STEL: Short Term Exposure Limit

Page 4 of 13
I 3M’ Panel Bonding Adhesive Part B PNs 08115,38315, 58115 09/23/15

CElL: Ceiling

8.2. Exposure controls

8.2.1. Engineering controls


Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below relevant Exposure
Limits and/or control dust/fume/gas/mist/vapors/spray. If ventilation is not adequate, use respiratory protection equipment.

8.2.2. Personal protective equipment (PPE)

Eye/face protection

Select and use eye/face protection to prevent contact based on the results of an exposure assessment. The following eye/face
protection(s) are recommended:
Indirect Vented Goggles

Skin/hand protection
Select and use gloves and/or protective clothing approved to relevant local standards to prevent skin contact based on the
results of an exposure assessment. Selection should be based on use factors such as exposure levels, concentration of the
substance or mixture, frequency and duration, physical challenges such as temperature extremes, and other use conditions.
Consult with your glove and/or protective clothing manufacturer for selection of appropriate compatible gloves/protective
clothing. Note: Nitrile gloves may be worn over polymer laminate gloves to improve dexterity.
Gloves made from the following material(s) are recommended: Polymer laminate

If this product is used in a manner that presents a higher potential for exposure (eg. spraying, high splash potential etc.), then
use of protective coveralls may be necessary. Select and use body protection to prevent contact based on the results of an
exposure assessment. The following protective clothing material(s) are recommended: Apron polymer laminate
-

Respiratory protection

An exposure assessment may be needed to decide if a respirator is required. If a respirator is needed, use respirators as part of
a full respiratory protection program. Based on the results of the exposure assessment, select from the following respirator
type(s) to reduce inhalation exposure:
Half facepiece or full facepiece air-purifying respirator suitable for organic vapors and particulates

For questions about suitability for a specific application, consult with your respirator manufacturer.

I SECTION 9: Physical and chemical properties


9.1. Information on basic physical and chemical properties
General Physical Form: Liquid
Odor, Color, Grade: Black, Viscous Liquid.
Odor threshold No Data A vailable
pH No Data Available
Melting point No Data Available
Boiling Point > 95 °F
Flash Point > 220 °F [Test Method: Closed Cup]
Evaporation rate <= I Units not avail, or not appl. [RefStd: BUOAC=lj
Flammability (solid, gas) Not Applicable
Flammable Limits(LEL) No Data A vailable
Flammable Limits(UEL) No Data A vailable
Vapor Pressure < 27 psia
Vapor Pressure No Data Available
Vapor Density No Data Available
Density 10.014 lb/gal
Specific Gravity 1.2 [RefStd: WATER=l]

Page 5 of 13
I 3M’ Panel Bonding Adhesive Part B PNs 08115, 38315, 58115 09/23/15

Solubility in Water Negligible


Solubility- non-water No Data Available
Partition coefficient: n-octanoll water No Data Available
Autoignition temperature No Data Available
Decomposition temperature No Data Available
Viscosity 100,000 centipoise -225,000 centipoise [Test Method:
Brookfield]
Hazardous Air Pollutants 0.00162 lb RAPS/gal
Volatile Organic Compounds 15 g/l [Test Method: calculated SCAQMD rule 443.1]
Volatile Organic Compounds 1.6 % weight [Test Method: calculated per CARB title 2]
Percent volatile 1.6% weight
VOC Less 1120 & Exempt Solvents 15 g/l [Test Method: calculated SCAQMD rule 443.1]

I SECTION 10: Stability and reactivity


10.1. Reactivity
This material may be reactive with certain agents under certain conditions see the remaining headings in this section.
-

10.2. Chemical stability


Stable.

10.3. Possibility of hazardous reactions


Hazardous polymerization will not occur.

10.4. Conditions to avoid


Sparks and/or flames

10.5. Incompatible materials


Amines
Strong acids
Strong bases
Strong oxidizing agents

10.6. Hazardous decomposition products


Substance Condition
Aldehydes Not Specified
Carbon monoxide Not Specified
Carbon dioxide Not Specified

I SECTION 11: Toxicological information


The information below may not be consistent with the material classification in Section 2 if specific ingredient
classifications are mandated by a competent authority. In addition, toxicological data on ingredients may not be
reflected in the material classification and/or the signs and symptoms of exposure, because an ingredient may be
present below the threshold for labeling, an ingredient may not be available for exposure, or the data may not be
relevant to the material as a whole.

11.1. Information on Toxicological effects

Signs and Symptoms of Exposure

Based on test data andlor information on the components, this material may produce the following health effects:

Page 6 of 13
4

I 3M’ Panel Bonding Adhesive Part B PNs 08115, 38315, 58115 09/23/15

Inhalation:
Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose
and throat pain.

May cause additional health effects (see below).

Skin Contact:
Mild Skin Irritation: Signs/symptoms may include localized redness, swelling, itching, and dryness. Allergic Skin Reaction
(non-photo induced): Signs/symptoms may include redness, swelling, blistering, and itching.

Eye Contact:
Severe Eye Irritation: Signs/symptoms may include significant redness, swelling, pain, tearing, cloudy appearance of the
cornea, and impaired vision.

Ingestion:
Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhea.

Additional Health Effects:

Carcinogenicity:
Contains a chemical or chemicals which can cause cancer.

Ineredient CAS No. Class Description Reeulation


Generic: GLASS FILAMENTS 65997-1 7-3 Anticipated human carcinogen National Toxicology Program Carcinogens
Carbon Black 1333-86-4 Grp. 2B: Possible human care. International Agency for Research on Cancer
Epichlorohydrin 106.89-8 Grp. 2A: Probable human care. International Agency for Research on Cancer
Epichlorohydrin 1 06-89-8 Anticipated human carcinogen National Toxicology Program Carcinogens

Toxicological Data
If a component is disclosed in section 3 but does not appear in a table below, either no data are available for that endpoint or
the data are not sufficient for classification.

Acute Toxicity
Name Route Species Value
Overall product Dermal No data available; calculated ATE> 5,000 mg/kg
Overall product Inhalation- No data available; calculated ATE> 12.5 mg/I
DustlMist(4
hr)
Overall product Ingestion No data available; calculated ATE> 5,000 mg/kg
4,4’-Tsopropylidenediphenol-Epichlorohydrin Polymer Dermal Rat LD5O> 1,600 mg/kg
4,4-Isopropylidenediphenol-Epichlorohydrin Polymer Ingestion Rat LD5O> 1,000 mg/kg
Oxide Glass Chemicals Dermal LD5O estimated to be> 5,000 mg/kg
Oxide Glass Chemicals Ingestion LD5O estimated to be 2,000- 5,000 mg/kg
l,4-Bis[(2,3-Epoxypropoxy)MethyllCyclohexane Dermal Rabbit LD5O 2,500 mg/kg
Fused Silica Dermal Rabbit LD5O> 5,000 mg/kg
1,4-Bis[(2,3-Epoxypropoxy)Methyl]Cyclohexane Ingestion Rat LD5O 2,450 mg/kg
Fused Silica Inhalation- Rat LC5O > 0.691 mg/I
Dust/Mist
(4 hours)
Fused Silica Ingestion Rat LD5O >5,110 mg/kg
Acrylate Polymer Dermal Rabbit LD5O> 5,000 mg/kg
Acrylate Polymer Ingestion Rat LD5O> 5,000 mg/kg
Silica Dermal Rabbit LD5O> 5,000 mg/kg
Silica Inhalation- Rat LC5O > 0.691 mg/I
Dust/Mist
(4 hours)
Silica Ingestion Rat LD5O> 5,110 mg/kg
3-(Trimethoxysilyl)propyl Glycidyl Ether Dermsl Rabbit LD5O 4,000 mg/kg
3-(Trimethoxysilyl)propyl Glycidyl Ether Inhalation- Rat LC5O> 5.3 mg/I
Dust/Mist

Page 7 of 13
I 3M”’ Panel Bonding Adhesive Part B PNsO8I15,38315, 58115 09/23/15

(4 hours)

3-(Trimethoxysilyl)propyl Glycidyl Ether Ingestion Rat LD5O 7,010 mg/kg

Dimethyl Siloxane, Reaction Product With Silica Dermal Rabbit LD50> 5,000 mg/kg

Dimethyl Siloxane, Reaction Product With Silica Inhalation- Rat LC5O > 0.691 mg/I

Dust/Mist

(4 hours)

Dimethyl Siloxane, Reaction Product With Silica Ingestion Rat LD5O> 5,110 mg/kg
Carbon Black Dermal Rabbit LD50> 3,000 mg/kg
Carbon Black Ingestion Rat LD5O> 8,000 mg/kg

Epichiorohydrin Dermal Rabbit LD5O 755 mg/kg

Epichiorohydrin Inhalation- Rat LC5O 1.7 mg/I

Vapor (4
hours)

Epichlorohydrin Ingestion Rat LD5O 260 mg/kg


ATE = acute toxicity estimate

Skin Corrosion/Irritation

Name Species Value

4,4’-Isopropylidenediphenol-Epichlorohydrin Polymer Rabbit Mild irritant

Oxide Glass Chemicals Professio No significant irritation


nal
judgeme
nt
I ,4-Bia[(2,3-Epoxypropoxy)MethyllCyclohexane Professio Mild irritant
nal

judgeme

nt

Fused Silica Rabbit No significant irritation


Acrylate Polymer Profeaaio Minimal irritation
nal
judgeme
nt

Silica Rabbit No significant irritation


3-(Trimethoxysilyl)propyl Glycidyl Ether Rabbit Mild irritant
Dimethyl Siloxane, Reaction Product With Silica Rabbit No significant irritation
Carbon Black Rabbit No significant irritation
Epichlorohydrin Human Corrosive
and
animal

Serious Eye Damage/Irritation


Name Species Value

4,4’-Isopropylidenediphenol-Epichlorohydrin Polymer Rabbit Moderate irritant

Oxide Glass Chemicals Professio No significant irritation

nal

judgeme

nt

I ,4-Bis[(2,3-Epoxypropoxy)Methyl}Cyclohexane Profesaio Mild irritant


nal
judgeme
nt
Fused Silica Rabbit No significant irritation
Aciylate Polymer Professio Mild irritant
nal
judgeme
nt
Silica Rabbit No significant irritation
3-(Trimethoxysilyl)propyl Glycidyl Ether Rabbit Corrosive
Dimethyl Siloxane, Reaction Product With Silica Rabbit No significant irritation
Carbon Black Rabbit No significant irritation
Epichlorohydrin Rabbit Corrosive

Skin Sensitization

Page 8 of 13
I 3MTM Panel Bonding Adhesive Part B PNs 08115, 38315, 58115 09/23/15

Name Species Value


4,4’-Isopropylidenediphenol-Epichlorohydrin Polymer Human Sensitizing
and
animal
l,4-Bis[(2,3-Epoxypropoxy)Methyl)Cyclohexsne similar Sensitizing
compoun
ds
Fused Silica Human Not sensitizing
and
animal
Silica Human Not sensitizing
and
animal
3-(Trimethoxysilyl)propyl Glycidyl Ether Guinea Some positive data exist, but the data are not
pig sufficient for clsssification
Dimethyl Siloxane, Reaction Product With Silica Human Not sensitizing
and
animal
Epichlorohydrin Human Sensitizing
and
animal

Respiratory Sensitization
Name Species Value

4,4’-Isopropylidenediphenol-Epichlorohydrin Polymer Human Some positive data exist, but the data are not
sufficient for classification

Germ Cell Mutagenicity


Name Route Value

4,4’-Isopropylidenediphenol-Epichlorohydrin Polymer In vivo Not mutagenic


4,4’-Isopropylidenediphenol-Epichlorohydrin Polymer In Vitro Some positive data exist, but the data are not
sufficient for classification
Oxide Glass Chemicals In Vitro Some positive dsta exist, but the data are not
sufficient for classification
Fused Silica In Vitro Not mutsgenic
Silica In Vitro Not mutagenic
3-(Trimethoxysilyl)propyl Glycidyl Ether In vivo Not mutsgenic
3-(Trimethoxysilyl)propyl Glycidyl Ether In Vitro Some positive data exist, but the data are not
sufficient for classification
Dimethyl Siloxane, Reaction Product With Silica In Vitro Not mutagenic
Carbon Black In Vitro Not mutagenic
Carbon Black In vivo Some positive data exist, but the data are ot
sufficient for classification
Epichlorohydrin In Vitro Some positive data exist, but the data are not
sufficient for classification
Epichlorohydrin In vivo Mutagenic

Carcinogenicity
Name Route Species Value
4,4’-Isopropylidenediphenol-Epichlorohyds-in Polymer Dermsl Mouse Some positive data exist, but the data are not
sufficient for classification
Oxide Glass Chemicals Inhalation Multiple Some positive data exist, but the data are not
animsi sufficient for classification
species
Fused Silica Not Mouse Some positive data exist, but the data are not
Specified sufficient for classification
Silica Not Mouse Some positive data exist, but the data are not
Specified sufficient for classification
3-(Trimethoxysilyl)propyl Glycidyl Ether Dermal Mouse Not carcinogenic
Dimethyl Siloxane, Reaction Product With Silica Not Mouse Some positive data exist, but the data are not
Specified sufficient for classification
Carbon Black Dermsl Mouse Not carcinogenic
Carbon Black Ingestion Mouse Not carcinogenic
C.,
Page 9 of 13
I 3M Panel Bonding Adhesive Part B PNs 08115, 38315, 58115 09/23/15

Carbon Black Inhalation Rat Carcinogenic


Epichlorohydrin Dermal Mouse Not carcinogenic
Epichiorohydrin Ingestion Rat Carcinogenic
Epichlorohydrin Inhalation Rat Carcinogenic

Reproductive Toxicity

Reproductive and/or Developmental Effects


Name Route Value Species Test Result Exposure
Duration
4,4’-lsopropylidenediphenol- Ingestion Not toxic to female reproduction Rat NOAEL 750 2 generation
Epichlorohydrin Polymer mg/kg/day
4,4’-Isopropylidenediphenol- Ingestion Not toxic to male reproduction Rat NOAEL 750 2 generation
Epichlorohydrin Polymer mg/kg/day
4,4’-lsopropylidenediphenol- Dermal Not toxic to development Rabbit NOAEL 300 during
Epichlorohydrin Polymer mg/kg/day organogenesi

4,4-Isopropytidenediphenol- Ingestion Not toxic to development Rat NOAEL 750 2 generation


Epichlorohydrin Polymer mg/kg/day
Fused Silica Ingestion Not toxic to female reproduction Rat NOAEL 509 1 generation
mg/kg/day
Fused Silica Inhalation Not toxic to male reproduction Rat NOAEL 497 1 generation
mg/kg/day
Fused Silica Ingestion Not toxic to development Rat NOAEL 1,350 during
mg/kg/day organogeneai

Silica Ingestion Not toxic to female reproduction Rat NOAEL 509 1 generation
mg/kg/day
Silica Ingestion Not toxic to male reproduction Rat NOAEL 497 1 generation
mg/kg/day
Silica Ingestion Not toxic to development Rat NOAEL 1,350 during
mg/kg/day organogenesi

3-(Trimethoxyailyl)propyl Glycidyl Ether Ingestion Not toxic to female reproduction Rat NOAEL 1,000 1 generation
mg/kg/day
3-(Trimethoxyailyl)propyl Glycidyl Ether Ingestion Not toxic to male reproduction Rat NOAEL 1,000 1 generation
mg/kg/day
3-(Trimethoxyailyl)propyl Glycidyl Ether Ingestion Some positive developmental data exist, Rat NOAEL 3,000 during
but the data are not sufficient for mg/kg/day organogenesi
classification a
Dimethyl Siloxane, Reaction Product With Ingestion Not toxic to female reproduction Rat NOAEL 509 1 generation
Silica mg/kg/day
Dimeihyl Siloxane, Reaction Product With Ingestion Not toxic to male reproduction Rat NOAEL 497 1 generation
Silica mg/kg/day
Dimethyl Siloxane, Reaction Product With Ingestion Not toxic to development Rat NOAEL 1,350 during
Silica mg/kg/day organogeneai

Epichlorohydrin Inhalation Not toxic to female reproduction Rat NOAEL 0.2 10 weeks
mg/I
Epichlorohydrin Inhalation Not toxic to development Multiple NOAEL 0.09 during
animal mg/I organogeneai
species a
Epichlorohydrin Ingestion Some positive developmental data exist, Multiple NOAEL 160 during
but the data are not sufficient for animal mg/kg/day gestation
classification species
Epichlorohydrin Ingestion Toxic to male reproduction Rat LOAEL 6.25 23 days
mg/kg/day
Epichtorohydrin Inhalation Toxic to male reproduction Rat NOAEL 0.02 10 weeks
mg/I

Target Organ(s)

Specific Target Organ Toxicity - single exposure


Name Route Target Organ(s) Value Species Test Result Exposure
Duration

Page 10 of 13
I 3MTM Panel Bonding Adhesive Part B PNs 08115, 38315, 58115 09/23/15 I C
I ,4-Bis[(2,3- Inhalation respiratory irritation Some positive data exist, but the NOAEL Not
Epoxypropoxy)MethyljCyc data are not sufficient for available
lohexane classification
Epichlorohydrin Inhalation respiratory irritation May cause respiratory irritation Human NOAEL not occupational
___________________ available exposure
Epichlorohydrin Inhalation liver Some positive data exist, but the Human NOAEL not occupational
data are not sufficient for available exposure
classification

Specific Target Organ Toxicity repeated exposure


-

Name Route Target Organ(s) Value Species Test Result Exposure


Duration

4,4’- Dermal liver Some positive data exist, but the Rat NOAEL 2 years
Isopropylidenediphenol- data are not sufficient for 1,000
Epichlorohydrin Polymer classification mg/kg/day
4,4’- Dermal nervous system All data are negative Rat NOAEL 13 weeks
Isopropylidenediphenol- 1,000
Epichlorohydrin Polymer mg/kg/day
4,4’- Ingestion auditory system I All data are negative Rat NOAEL 28 days
Isopropylidenediphenol- heart I endocrine 1,000
Epichlorohydrin Polymer system mg/kg/day
hematopoietic
system I liver I eyes I
kidney and/or
bladder
Oxide Glass Chemicals Inhalation respiratory system Some positive data exist, but the Human NOAEL not occupational
data are not sufficient for available exposure
classification
Fused Silica Inhalation respiratory system I All data are negative Human NOAEL Not occupational
silicosis available exposure
Silica Inhalation respiratory system I All data are negative Human NOAEL Not occupational
silicosis available exposure
3-(Trimelhoxysilyl)propyl Ingestion heart I endocrine All data are negative Rat NOAEL 28 days
Glycidyl Ether system I bone, teeth, 1,000
nails, and/or hair I mg/kg/day
hematopoietic
system I liver I
immune system I
nervous system I
kidney and/or
bladder I respiratory
system
Dimethyl Siloxane, Inhalation respiratory system I All data are negative Human NOAEL Not occupational
Reaction Product With silicosis available exposure
Silica
Carbon Black Inhalation pneumoconiosis Some positive data exist, but the Human NOAEL Not occupational
data are not sufficient for available exposure
classification
Epichiorohydrin Inhslation liver Causes damage to organs through Rat NOAEL 0.21 19 days
prolonged or repeated exposure mg/I
Epichlorohydrin Inhalation kidney and/or May cause damage to organs Rat NOAEL 0.04 136 weeks
bladder though prolonged or repeated mg/I
exposure
Epichlorohydrin Inhalation endocrine system Some positive data exist, but the Rat NOAEL 4 weeks
data are not sufficient for 0.377 mg/I
classification
Epichlorohydrin Inhalation immune system Some positive data exist, but the Rat LOAEL 4 weeks
data are not sufficient for 0.21 1 mg/I
classification
Epichlorohydrin Inhalation heart Some positive data exist, but the Rat NOAEL 0.02 98 days
data are not sufficient for mg/I
classification
Epichlorohydrin Inhalation nervous system Some positive data exist, but the Rat NOAEL 98 days
data are not sufficient for 0.002 mg/I
classification
Epichlorohydrin Inhalation respiratory system Some positive data exist, but the Multiple NOAEL 0.02 13 weeks
data are not sufficient for animal mg/I
classification species
C
Page 11 of 13
I 3lI’ Panel Bonding Adhesive Part B PNs 08115, 38315, 58115 09/23/15 I

Epichlorohydrin Inhalation blood All data are negative Rat NOAEL 90 days
0.189 mg/I
Epichiorohydrin Ingestion heart blood Some positive data exist, but the Rat NOAEL 80 12 weeks
data are not sufficient for mg/kg/day
classification
Epichlorohydrin Ingestion liver Some positive data exist, but the Rat NOAEL 25 90 days
data are not sufficient for mg/kg/day
classification

Aspiration Hazard
For the component/components, either no data are currently available or the data are not sufficient for classification.

Please contact the address or phone number listed on the first page of the SDS for additional toxicological information
on this material and/or its components.

I SECTION 12: Ecological information

Ecotoxicological information
Please contact the address or phone number listed on the first page of the SDS for additional ecotoxicological infonnation on this material
and/or its components.
Chemical fate information
Please contact the address or phone number listed on the first page of the SDS for additional chemical fate information on this material
and/or its components.

I SECTION 13: Disposal considerations

13.1. Disposal methods


Dispose of contents! container in accordance with the local/regional/national/international regulations.

Dispose of waste product in a permitted industrial waste facility. As a disposal alternative, incinerate in a permitted waste
incineration facility. Proper destruction may require the use of additional fuel during incineration processes. Empty
drums/barrels/containers used for transporting and handling hazardous chemicals (chemical substances/mixtures/preparations
classified as Hazardous as per applicable regulations) shall be considered, stored, treated & disposed of as hazardous wastes
unless otherwise defined by applicable waste regulations. Consult with the respective regulating authorities to determine the
available treatment and disposal facilities.

I SECTION 14: Transport Information


For Transport tnformation, please visit http://3Mcom/Transportinfo or call 1-800-364-3577 or 651-737-6501.

I SECTION 15 Regulatory information

15.1. US Federal Regulations


Contact 3M for more information.

311/312 Hazard Categories:

Fire Hazard No- Pressure Hazard No - Reactivity Hazard No - Immediate Hazard Yes - Delayed Hazard - Yes

15.2. State Regulations


Contact 3M for more information.

Page 12 of 13
3M’’ Panel Bonding Adhesive Part B PNs 08115, 38315, 58115 09/23/15 j

California Proposition 65

lnredient C.A.S. No. Classification


Epic hlorohydrin 106-89-8 Male reproductive toxin
Epichlorohydrin 106-89-8 Carcinogen
Carbon Black 1333-86-4 Carcinogen

WARNING: This product contains a chemical known to the State of California to cause birth defects or other reproductive
harm.
WARNING: This product contains a chemical known to the State of California to cause cancer.

15.3. Chemical Inventories


The components of this product are in compliance with the chemical notification requirements of TSCA.

Contact 3M for more information.

15.4. International Regulations


Contact 3M for more information.

I This SDS has beenjçpared to meet theU.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200.

I SECTION 16 Other information I


NFPA Hazard Classification
Health: 2 Flammability: 1 Instability: 0 Special Hazards: None

National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address
0
the hazards that are presented by short-term, acute exposure to a material under conditions of fire, spill, or similar
emergencies. Hazard ratings are primarily based on the inherent physical and toxic properties of the material but also include
the toxic properties of combustion or decomposition products that are known to be generated in significant quantities.

Document Group: 32-4327-6 Version Number: 1.01


Issue Date: 09/23/15 Supercedes Date: 11/24/14

DISCLAIMER: The information in this Safety Data Sheet (SDS) is believed to be correct as of the date issued. 3M MAKES
NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY
OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR
USAGE OF TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable
for user’s method of use or application. Given the variety of factors that can affect the use and application of a 3M product,
some of which are uniquely within the user’s knowledge and control, it is essential that the user evaluate the 3M product to
determine whether it is fit for a particular purpose and suitable for user’s method of use or application.

3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer
may have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness
or accuracy. In addition, information obtained from a database may not be as current as the information in the SDS available
directly from 3M

3M USA SDSs are available at www.3M.com

C
Page 13 of 13
3M™ Scotch-Weld™ Epoxy Adhesive DP100, Clear 04/16/15

Safety Data Sheet


Copyright,2015,3M Company.
All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is allowed
provided that: (1) the information is copied in full with no changes unless prior written agreement is obtained from 3M, and (2) neither
the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon.

Document Group: 11-3180-4 Version Number: 14.00


Issue Date: 04/16/15 Supercedes Date: 04/23/10

Product identifier
3M™ Scotch-Weld™ Epoxy Adhesive DP100, Clear

ID Number(s):

62-3575-1430-6, 62-3575-1435-5, 62-3575-3530-1, 62-3575-3830-5

Recommended use
Structural adhesive

Supplier's details

MANUFACTURER: 3M
DIVISION: Industrial Adhesives and Tapes Division

ADDRESS: 3M Center, St. Paul, MN 55144-1000, USA


Telephone: 1-888-3M HELPS (1-888-364-3577)

Emergency telephone number


1-800-364-3577 or (651) 737-6501 (24 hours)

This product is a kit or a multipart product which consists of multiple, independently packaged components. A Safety Data
Sheet (SDS), Article Information Sheet (AIS), or Article Information Letter (AIL) for each of these components is included.
Please do not separate the component documents from this cover page. The document numbers for components of this
product are:

10-3337-2, 10-3341-4

DISCLAIMER: The information in this Safety Data Sheet (SDS) is believed to be correct as of the date issued. 3M MAKES NO
WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF
MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF
TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable for user's method of
use or application. Given the variety of factors that can affect the use and application of a 3M product, some of which are uniquely
within the user's knowledge and control, it is essential that the user evaluate the 3M product to determine whether it is fit for a
particular purpose and suitable for user's method of use or application.

3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer may
have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness or accuracy.
In addition, information obtained from a database may not be as current as the information in the SDS available directly from 3M

________________________________________________________________________________________________________
Page 1 of 2
3M™ Scotch-Weld™ Epoxy Adhesive DP100, Clear 04/16/15

3M USA SDSs are available at www.3M.com

________________________________________________________________________________________________________
Page 2 of 2
3M™ Scotch-Weld™ Epoxy Adhesive DP100 Clear, Part A 04/16/15

Safety Data Sheet


Copyright,2015,3M Company.
All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is
allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is obtained from
3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon.

Document Group: 10-3341-4 Version Number: 22.00


Issue Date: 04/16/15 Supercedes Date: 01/06/10

SECTION 1: Identification
1.1. Product identifier
3M™ Scotch-Weld™ Epoxy Adhesive DP100 Clear, Part A

1.2. Recommended use and restrictions on use

Recommended use
Accelerator for 2 part epoxy adhesive, Structural adhesive

1.3. Supplier’s details


MANUFACTURER: 3M
DIVISION: Industrial Adhesives and Tapes Division
ADDRESS: 3M Center, St. Paul, MN 55144-1000, USA
Telephone: 1-888-3M HELPS (1-888-364-3577)

1.4. Emergency telephone number


1-800-364-3577 or (651) 737-6501 (24 hours)

SECTION 2: Hazard identification


2.1. Hazard classification
Serious Eye Damage/Irritation: Category 2A.
Skin Corrosion/Irritation: Category 2.

2.2. Label elements


Signal word
Warning

Symbols
Exclamation mark |

Pictograms

Hazard Statements

__________________________________________________________________________________________
Page 1 of 9
3M™ Scotch-Weld™ Epoxy Adhesive DP100 Clear, Part A 04/16/15

Causes serious eye irritation.


Causes skin irritation.

Precautionary Statements

Prevention:
Wear protective gloves and eye/face protection.
Wash thoroughly after handling.

Response:
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
If eye irritation persists: Get medical advice/attention.
IF ON SKIN: Wash with plenty of soap and water.
If skin irritation occurs: Get medical advice/attention.
Take off contaminated clothing and wash it before reuse.

2.3. Hazards not otherwise classified


None.

SECTION 3: Composition/information on ingredients


Ingredient C.A.S. No. % by Wt
Mercaptan Polymer (NJTS Reg. No. 04499600-6776) Trade Secret* 80 - 95 Trade Secret *
2,4,6-tris((Dimethylamino)methyl)phenol 90-72-2 5 - 15 Trade Secret *
bis((Dimethylamino)methyl)phenol 71074-89-0 0.1 - 1.5 Trade Secret *

NJTS or NJTSRN: New Jersey Trade Secret Registry Number.

*The specific chemical identity and/or exact percentage (concentration) of this composition has been withheld as a trade
secret.

SECTION 4: First aid measures


4.1. Description of first aid measures

Inhalation:
Remove person to fresh air. If you feel unwell, get medical attention.

Skin Contact:
Immediately wash with soap and water. Remove contaminated clothing and wash before reuse. If signs/symptoms develop,
get medical attention.

Eye Contact:
Immediately flush with large amounts of water. Remove contact lenses if easy to do. Continue rinsing. Get medical
attention.

If Swallowed:
Rinse mouth. If you feel unwell, get medical attention.

4.2. Most important symptoms and effects, both acute and delayed
See Section 11.1. Information on toxicological effects.

4.3. Indication of any immediate medical attention and special treatment required

__________________________________________________________________________________________
Page 2 of 9
3M™ Scotch-Weld™ Epoxy Adhesive DP100 Clear, Part A 04/16/15

Not applicable

SECTION 5: Fire-fighting measures


5.1. Suitable extinguishing media
In case of fire: Use a fire fighting agent suitable for ordinary combustible material such as water or foam to extinguish.

5.2. Special hazards arising from the substance or mixture


None inherent in this product.

Hazardous Decomposition or By-Products


Substance Condition
Carbon monoxide During Combustion
Carbon dioxide During Combustion
Hydrogen Sulfide During Combustion
Oxides of Nitrogen During Combustion
Oxides of Sulfur During Combustion

5.3. Special protective actions for fire-fighters


No special protective actions for fire-fighters are anticipated.

SECTION 6: Accidental release measures


6.1. Personal precautions, protective equipment and emergency procedures
Evacuate area. Ventilate the area with fresh air. For large spill, or spills in confined spaces, provide mechanical ventilation
to disperse or exhaust vapors, in accordance with good industrial hygiene practice. Warning! A motor could be an ignition
source and could cause flammable gases or vapors in the spill area to burn or explode. Refer to other sections of this SDS for
information regarding physical and health hazards, respiratory protection, ventilation, and personal protective equipment.

6.2. Environmental precautions


Avoid release to the environment.

6.3. Methods and material for containment and cleaning up


Contain spill. Working from around the edges of the spill inward, cover with bentonite, vermiculite, or commercially
available inorganic absorbent material. Mix in sufficient absorbent until it appears dry. Remember, adding an absorbent
material does not remove a physical, health, or environmental hazard. Collect as much of the spilled material as possible.
Place in a closed container approved for transportation by appropriate authorities. Clean up residue with an appropriate
solvent selected by a qualified and authorized person. Ventilate the area with fresh air. Read and follow safety precautions on
the solvent label and SDS. Seal the container. Dispose of collected material as soon as possible.

SECTION 7: Handling and storage


7.1. Precautions for safe handling
Avoid breathing dust/fume/gas/mist/vapors/spray. Do not get in eyes, on skin, or on clothing. Do not eat, drink or smoke
when using this product. Wash thoroughly after handling. Avoid contact with oxidizing agents (eg. chlorine, chromic acid
etc.)

7.2. Conditions for safe storage including any incompatibilities


Store away from oxidizing agents.

SECTION 8: Exposure controls/personal protection


8.1. Control parameters

__________________________________________________________________________________________
Page 3 of 9
3M™ Scotch-Weld™ Epoxy Adhesive DP100 Clear, Part A 04/16/15

Occupational exposure limits


If a component is disclosed in section 3 but does not appear in the table below, an occupational exposure limit is not available
for the component.
Ingredient C.A.S. No. Agency Limit type Additional Comments
2,4,6- 90-72-2 CMRG TWA:5 ppm
tris((Dimethylamino)methyl)phen
ol
ACGIH : American Conference of Governmental Industrial Hygienists
AIHA : American Industrial Hygiene Association
CMRG : Chemical Manufacturer's Recommended Guidelines
OSHA : United States Department of Labor - Occupational Safety and Health Administration
TWA: Time-Weighted-Average
STEL: Short Term Exposure Limit
CEIL: Ceiling

8.2. Exposure controls

8.2.1. Engineering controls


Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below relevant Exposure
Limits and/or control dust/fume/gas/mist/vapors/spray. If ventilation is not adequate, use respiratory protection equipment.

8.2.2. Personal protective equipment (PPE)

Eye/face protection

Select and use eye/face protection to prevent contact based on the results of an exposure assessment. The following eye/face
protection(s) are recommended:
Indirect Vented Goggles

Skin/hand protection
Select and use gloves and/or protective clothing approved to relevant local standards to prevent skin contact based on the
results of an exposure assessment. Selection should be based on use factors such as exposure levels, concentration of the
substance or mixture, frequency and duration, physical challenges such as temperature extremes, and other use conditions.
Consult with your glove and/or protective clothing manufacturer for selection of appropriate compatible gloves/protective
clothing.
Gloves made from the following material(s) are recommended: Butyl Rubber
Neoprene
Nitrile Rubber

Respiratory protection

An exposure assessment may be needed to decide if a respirator is required. If a respirator is needed, use respirators as part of
a full respiratory protection program. Based on the results of the exposure assessment, select from the following respirator
type(s) to reduce inhalation exposure:
Half facepiece or full facepiece air-purifying respirator suitable for organic vapors and particulates

For questions about suitability for a specific application, consult with your respirator manufacturer.

SECTION 9: Physical and chemical properties


9.1. Information on basic physical and chemical properties
General Physical Form: Liquid
Specific Physical Form: Viscous
Odor, Color, Grade: dark amber, strong mercaptan odor
Odor threshold No Data Available
pH Not Applicable

__________________________________________________________________________________________
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3M™ Scotch-Weld™ Epoxy Adhesive DP100 Clear, Part A 04/16/15

Melting point Not Applicable


Boiling Point >=257 ºC
Flash Point 257 ºC [Test Method: Closed Cup]
Evaporation rate Not Applicable
Flammability (solid, gas) Not Applicable
Flammable Limits(LEL) Not Applicable
Flammable Limits(UEL) Not Applicable
Vapor Pressure Negligible
Vapor Density Not Applicable
Density 1.15 g/ml
Specific Gravity 1.15 [Ref Std: WATER=1]
Solubility in Water Negligible
Solubility- non-water No Data Available
Partition coefficient: n-octanol/ water No Data Available
Autoignition temperature No Data Available
Decomposition temperature No Data Available
Viscosity 8,000 - 15,000 centipoise [@ 73 ºF ]
Hazardous Air Pollutants 0 % weight [Test Method: Calculated]
VOC Less H2O & Exempt Solvents 0 g/l [Test Method: calculated SCAQMD rule 443.1] [Details:
when used as intended with Part B]
VOC Less H2O & Exempt Solvents 0 g/l [Test Method: calculated SCAQMD rule 443.1] [Details: as
supplied]
VOC Less H2O & Exempt Solvents 0 % [Test Method: calculated SCAQMD rule 443.1] [Details:
when used as intended with Part B]

SECTION 10: Stability and reactivity


10.1. Reactivity
This material may be reactive with certain agents under certain conditions - see the remaining headings in this section.

10.2. Chemical stability


Stable.

10.3. Possibility of hazardous reactions


Hazardous polymerization will not occur.

10.4. Conditions to avoid


Heat is generated during cure. Do not cure a mass larger than 50 grams in a confined space to prevent a premature exothermic
reaction with production of intense heat and smoke.

10.5. Incompatible materials


Strong oxidizing agents

10.6. Hazardous decomposition products


Substance Condition
None known.

Refer to section 5.2 for hazardous decomposition products during combustion.

SECTION 11: Toxicological information


The information below may not be consistent with the material classification in Section 2 if specific ingredient
classifications are mandated by a competent authority. In addition, toxicological data on ingredients may not be

__________________________________________________________________________________________
Page 5 of 9
3M™ Scotch-Weld™ Epoxy Adhesive DP100 Clear, Part A 04/16/15

reflected in the material classification and/or the signs and symptoms of exposure, because an ingredient may be
present below the threshold for labeling, an ingredient may not be available for exposure, or the data may not be
relevant to the material as a whole.

11.1. Information on Toxicological effects

Signs and Symptoms of Exposure

Based on test data and/or information on the components, this material may produce the following health effects:

Inhalation:
Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose
and throat pain.

Skin Contact:
Skin Irritation: Signs/symptoms may include localized redness, swelling, itching, dryness, cracking, blistering, and pain.

Eye Contact:
Severe Eye Irritation: Signs/symptoms may include significant redness, swelling, pain, tearing, cloudy appearance of the
cornea, and impaired vision.

Ingestion:
May be harmful if swallowed.
Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhea.

Toxicological Data
If a component is disclosed in section 3 but does not appear in a table below, either no data are available for that endpoint or
the data are not sufficient for classification.

Acute Toxicity
Name Route Species Value
Overall product Ingestion No data available; calculated ATE 2,000 - 5,000
mg/kg
Mercaptan Polymer (NJTS Reg. No. 04499600-6776) Dermal Rabbit LD50 > 10,200 mg/kg
Mercaptan Polymer (NJTS Reg. No. 04499600-6776) Ingestion Rat LD50 2,600 mg/kg
2,4,6-tris((Dimethylamino)methyl)phenol Dermal Rat LD50 1,280 mg/kg
2,4,6-tris((Dimethylamino)methyl)phenol Ingestion Rat LD50 1,000 mg/kg
bis((Dimethylamino)methyl)phenol Ingestion LD50 estimated to be 300 - 2,000 mg/kg
ATE = acute toxicity estimate

Skin Corrosion/Irritation
Name Species Value

Overall product In vitro Irritant


data
2,4,6-tris((Dimethylamino)methyl)phenol Rabbit Corrosive
bis((Dimethylamino)methyl)phenol similar Corrosive
compoun
ds

Serious Eye Damage/Irritation


Name Species Value

Overall product In vitro Severe irritant


data
2,4,6-tris((Dimethylamino)methyl)phenol Rabbit Corrosive
bis((Dimethylamino)methyl)phenol similar Corrosive
compoun
ds

__________________________________________________________________________________________
Page 6 of 9
3M™ Scotch-Weld™ Epoxy Adhesive DP100 Clear, Part A 04/16/15

Skin Sensitization
Name Species Value
2,4,6-tris((Dimethylamino)methyl)phenol Guinea Some positive data exist, but the data are not
pig sufficient for classification

Respiratory Sensitization
For the component/components, either no data are currently available or the data are not sufficient for classification.

Germ Cell Mutagenicity


Name Route Value

2,4,6-tris((Dimethylamino)methyl)phenol In Vitro Not mutagenic

Carcinogenicity
For the component/components, either no data are currently available or the data are not sufficient for classification.

Reproductive Toxicity

Reproductive and/or Developmental Effects


For the component/components, either no data are currently available or the data are not sufficient for classification.

Target Organ(s)

Specific Target Organ Toxicity - single exposure


Name Route Target Organ(s) Value Species Test Result Exposure
Duration
2,4,6- Inhalation respiratory irritation Some positive data exist, but the NOAEL Not
tris((Dimethylamino)methy data are not sufficient for available
l)phenol classification

Specific Target Organ Toxicity - repeated exposure


Name Route Target Organ(s) Value Species Test Result Exposure
Duration
2,4,6- Dermal skin | liver | nervous Some positive data exist, but the Rat NOAEL 125 28 days
tris((Dimethylamino)meth system data are not sufficient for mg/kg/day
yl)phenol classification
2,4,6- Dermal auditory system | All data are negative Rat NOAEL 125 28 days
tris((Dimethylamino)meth hematopoietic mg/kg/day
yl)phenol system | eyes

Aspiration Hazard
For the component/components, either no data are currently available or the data are not sufficient for classification.

Please contact the address or phone number listed on the first page of the SDS for additional toxicological information
on this material and/or its components.

SECTION 12: Ecological information


Ecotoxicological information
Please contact the address or phone number listed on the first page of the SDS for additional ecotoxicological information on this material
and/or its components.
Chemical fate information
Please contact the address or phone number listed on the first page of the SDS for additional chemical fate information on this material
and/or its components.

__________________________________________________________________________________________
Page 7 of 9
3M™ Scotch-Weld™ Epoxy Adhesive DP100 Clear, Part A 04/16/15

SECTION 13: Disposal considerations


13.1. Disposal methods
Dispose of contents/ container in accordance with the local/regional/national/international regulations.

Dispose of completely cured (or polymerized) material in a permitted industrial waste facility. As a disposal alternative,
incinerate uncured product in a permitted waste incineration facility. Proper destruction may require the use of additional fuel
during incineration processes. If no other disposal options are available, waste product that has been completely cured or
polymerized may be placed in a landfill properly designed for industrial waste. Empty drums/barrels/containers used for
transporting and handling hazardous chemicals (chemical substances/mixtures/preparations classified as Hazardous as per
applicable regulations) shall be considered, stored, treated & disposed of as hazardous wastes unless otherwise defined by
applicable waste regulations. Consult with the respective regulating authorities to determine the available treatment and
disposal facilities.

EPA Hazardous Waste Number (RCRA): Not regulated

SECTION 14: Transport Information

For Transport Information, please visit http://3M.com/Transportinfo or call 1-800-364-3577 or 651-737-6501.

SECTION 15: Regulatory information

15.1. US Federal Regulations


Contact 3M for more information.

311/312 Hazard Categories:

Fire Hazard - No Pressure Hazard - No Reactivity Hazard - No Immediate Hazard - Yes Delayed Hazard - No

15.2. State Regulations


Contact 3M for more information.

15.3. Chemical Inventories


The components of this product are in compliance with the chemical notification requirements of TSCA.

Contact 3M for more information.

15.4. International Regulations


Contact 3M for more information.

This SDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200.

SECTION 16: Other information


NFPA Hazard Classification
Health: 2 Flammability: 1 Instability: 1 Special Hazards: None

National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address
the hazards that are presented by short-term, acute exposure to a material under conditions of fire, spill, or similar
emergencies. Hazard ratings are primarily based on the inherent physical and toxic properties of the material but also include

__________________________________________________________________________________________
Page 8 of 9
3M™ Scotch-Weld™ Epoxy Adhesive DP100 Clear, Part A 04/16/15

the toxic properties of combustion or decomposition products that are known to be generated in significant quantities.

Document Group: 10-3341-4 Version Number: 22.00


Issue Date: 04/16/15 Supercedes Date: 01/06/10

DISCLAIMER: The information in this Safety Data Sheet (SDS) is believed to be correct as of the date issued. 3M MAKES
NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY
OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR
USAGE OF TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable
for user's method of use or application. Given the variety of factors that can affect the use and application of a 3M product,
some of which are uniquely within the user's knowledge and control, it is essential that the user evaluate the 3M product to
determine whether it is fit for a particular purpose and suitable for user's method of use or application.

3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer
may have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness
or accuracy. In addition, information obtained from a database may not be as current as the information in the SDS available
directly from 3M

3M USA SDSs are available at www.3M.com

__________________________________________________________________________________________
Page 9 of 9
3M™ Scotch-Weld™ Epoxy Adhesive DP100 Clear, Part B 04/16/15

Safety Data Sheet


Copyright,2015,3M Company.
All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is
allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is obtained from
3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon.

Document Group: 10-3337-2 Version Number: 16.00


Issue Date: 04/16/15 Supercedes Date: 06/16/05

SECTION 1: Identification
1.1. Product identifier
3M™ Scotch-Weld™ Epoxy Adhesive DP100 Clear, Part B

Product Identification Numbers


DP-100

1.2. Recommended use and restrictions on use

Recommended use
Structural adhesive

1.3. Supplier’s details


MANUFACTURER: 3M
DIVISION: Industrial Adhesives and Tapes Division
ADDRESS: 3M Center, St. Paul, MN 55144-1000, USA
Telephone: 1-888-3M HELPS (1-888-364-3577)

1.4. Emergency telephone number


1-800-364-3577 or (651) 737-6501 (24 hours)

SECTION 2: Hazard identification


2.1. Hazard classification
Serious Eye Damage/Irritation: Category 2B.
Skin Sensitizer: Category 1.

2.2. Label elements


Signal word
Warning

Symbols
Exclamation mark |

Pictograms

__________________________________________________________________________________________
Page 1 of 9
3M™ Scotch-Weld™ Epoxy Adhesive DP100 Clear, Part B 04/16/15

Hazard Statements
Causes eye irritation.
May cause an allergic skin reaction.

Precautionary Statements

Prevention:
Avoid breathing dust/fume/gas/mist/vapors/spray.
Wear protective gloves.
Wash thoroughly after handling.
Contaminated work clothing must not be allowed out of the workplace.

Response:
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
If eye irritation persists: Get medical advice/attention.
IF ON SKIN: Wash with plenty of soap and water.
If skin irritation or rash occurs: Get medical advice/attention.
Wash contaminated clothing before reuse.

Disposal:
Dispose of contents/container in accordance with applicable local/regional/national/international regulations.

2.3. Hazards not otherwise classified


None.

SECTION 3: Composition/information on ingredients


Ingredient C.A.S. No. % by Wt
Epoxy Resin 25068-38-6 100

SECTION 4: First aid measures


4.1. Description of first aid measures

Inhalation:
Remove person to fresh air. If you feel unwell, get medical attention.

Skin Contact:
Immediately wash with soap and water. Remove contaminated clothing and wash before reuse. If signs/symptoms develop,
get medical attention.

Eye Contact:
Flush with large amounts of water. Remove contact lenses if easy to do. Continue rinsing. If signs/symptoms persist, get
medical attention.

If Swallowed:
Rinse mouth. If you feel unwell, get medical attention.

__________________________________________________________________________________________
Page 2 of 9
3M™ Scotch-Weld™ Epoxy Adhesive DP100 Clear, Part B 04/16/15

4.2. Most important symptoms and effects, both acute and delayed
See Section 11.1. Information on toxicological effects.

4.3. Indication of any immediate medical attention and special treatment required
Not applicable

SECTION 5: Fire-fighting measures


5.1. Suitable extinguishing media
In case of fire: Use a fire fighting agent suitable for ordinary combustible material such as water or foam to extinguish.

5.2. Special hazards arising from the substance or mixture


None inherent in this product.

Hazardous Decomposition or By-Products


Substance Condition
Aldehydes During Combustion
Carbon monoxide During Combustion
Carbon dioxide During Combustion
Ketones During Combustion

5.3. Special protective actions for fire-fighters


No special protective actions for fire-fighters are anticipated.

SECTION 6: Accidental release measures


6.1. Personal precautions, protective equipment and emergency procedures
Evacuate area. Ventilate the area with fresh air. For large spill, or spills in confined spaces, provide mechanical ventilation
to disperse or exhaust vapors, in accordance with good industrial hygiene practice. Warning! A motor could be an ignition
source and could cause flammable gases or vapors in the spill area to burn or explode. Refer to other sections of this SDS for
information regarding physical and health hazards, respiratory protection, ventilation, and personal protective equipment.

6.2. Environmental precautions


Avoid release to the environment. For larger spills, cover drains and build dikes to prevent entry into sewer systems or
bodies of water.

6.3. Methods and material for containment and cleaning up


Contain spill. Working from around the edges of the spill inward, cover with bentonite, vermiculite, or commercially
available inorganic absorbent material. Mix in sufficient absorbent until it appears dry. Remember, adding an absorbent
material does not remove a physical, health, or environmental hazard. Collect as much of the spilled material as possible.
Place in a closed container approved for transportation by appropriate authorities. Clean up residue with an appropriate
solvent selected by a qualified and authorized person. Ventilate the area with fresh air. Read and follow safety precautions on
the solvent label and SDS. Seal the container. Dispose of collected material as soon as possible.

SECTION 7: Handling and storage


7.1. Precautions for safe handling
Avoid breathing dust/fume/gas/mist/vapors/spray. Do not get in eyes, on skin, or on clothing. Do not eat, drink or smoke
when using this product. Wash thoroughly after handling. Contaminated work clothing should not be allowed out of the
workplace. Avoid release to the environment. Wash contaminated clothing before reuse. Avoid contact with oxidizing
agents (eg. chlorine, chromic acid etc.)

__________________________________________________________________________________________
Page 3 of 9
3M™ Scotch-Weld™ Epoxy Adhesive DP100 Clear, Part B 04/16/15

7.2. Conditions for safe storage including any incompatibilities


Store away from heat. Store away from acids. Store away from oxidizing agents.

SECTION 8: Exposure controls/personal protection


8.1. Control parameters

Occupational exposure limits


No occupational exposure limit values exist for any of the components listed in Section 3 of this SDS.

8.2. Exposure controls

8.2.1. Engineering controls


No engineering controls required.

8.2.2. Personal protective equipment (PPE)

Eye/face protection

Select and use eye/face protection to prevent contact based on the results of an exposure assessment. The following eye/face
protection(s) are recommended:
Indirect Vented Goggles

Skin/hand protection
Select and use gloves and/or protective clothing approved to relevant local standards to prevent skin contact based on the
results of an exposure assessment. Selection should be based on use factors such as exposure levels, concentration of the
substance or mixture, frequency and duration, physical challenges such as temperature extremes, and other use conditions.
Consult with your glove and/or protective clothing manufacturer for selection of appropriate compatible gloves/protective
clothing. Note: Nitrile gloves may be worn over polymer laminate gloves to improve dexterity.
Gloves made from the following material(s) are recommended: Polymer laminate

Respiratory protection
None required.

SECTION 9: Physical and chemical properties


9.1. Information on basic physical and chemical properties
General Physical Form: Liquid
Specific Physical Form: Viscous
Odor, Color, Grade: light straw colored, epoxy odor
Odor threshold No Data Available
pH Not Applicable
Melting point Not Applicable
Boiling Point >=249 ºC
Flash Point 249 ºC [Test Method: Pensky-Martens Closed Cup]
Evaporation rate Not Applicable
Flammability (solid, gas) Not Applicable
Flammable Limits(LEL) Not Applicable
Flammable Limits(UEL) Not Applicable
Vapor Pressure <=0.03 mmHg [@ 70 ºC]
Vapor Density Not Applicable
Density 1.17 g/ml
Specific Gravity 1.17
Solubility in Water Nil

__________________________________________________________________________________________
Page 4 of 9
3M™ Scotch-Weld™ Epoxy Adhesive DP100 Clear, Part B 04/16/15

Solubility- non-water No Data Available


Partition coefficient: n-octanol/ water No Data Available
Autoignition temperature No Data Available
Decomposition temperature No Data Available
Viscosity 10,000 - 30,000 centipoise [@ 73.4 ºF ] [Details: MITS data]
Hazardous Air Pollutants 0 % weight [Test Method: Calculated]
VOC Less H2O & Exempt Solvents 0 g/l [Test Method: calculated SCAQMD rule 443.1] [Details:
when used as intended with Part A]
VOC Less H2O & Exempt Solvents 0 g/l [Test Method: calculated SCAQMD rule 443.1] [Details: as
supplied]
VOC Less H2O & Exempt Solvents 0 % [Test Method: calculated SCAQMD rule 443.1] [Details:
when used as intended with Part A]

SECTION 10: Stability and reactivity


10.1. Reactivity
This material may be reactive with certain agents under certain conditions - see the remaining headings in this section.

10.2. Chemical stability


Stable.

10.3. Possibility of hazardous reactions


Hazardous polymerization will not occur.

10.4. Conditions to avoid


Heat is generated during cure. Do not cure a mass larger than 50 grams in a confined space to prevent a premature exothermic
reaction with production of intense heat and smoke.
Heat

10.5. Incompatible materials


Strong acids
Strong oxidizing agents

10.6. Hazardous decomposition products


Substance Condition
None known.

Refer to section 5.2 for hazardous decomposition products during combustion.

SECTION 11: Toxicological information


The information below may not be consistent with the material classification in Section 2 if specific ingredient
classifications are mandated by a competent authority. In addition, toxicological data on ingredients may not be
reflected in the material classification and/or the signs and symptoms of exposure, because an ingredient may be
present below the threshold for labeling, an ingredient may not be available for exposure, or the data may not be
relevant to the material as a whole.

11.1. Information on Toxicological effects

Signs and Symptoms of Exposure

Based on test data and/or information on the components, this material may produce the following health effects:

__________________________________________________________________________________________
Page 5 of 9
3M™ Scotch-Weld™ Epoxy Adhesive DP100 Clear, Part B 04/16/15

Inhalation:
No health effects are expected.

Skin Contact:
Mild Skin Irritation: Signs/symptoms may include localized redness, swelling, itching, and dryness. Allergic Skin Reaction
(non-photo induced): Signs/symptoms may include redness, swelling, blistering, and itching.

Eye Contact:
Moderate Eye Irritation: Signs/symptoms may include redness, swelling, pain, tearing, and blurred or hazy vision.

Ingestion:
Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhea.

Toxicological Data
If a component is disclosed in section 3 but does not appear in a table below, either no data are available for that endpoint or
the data are not sufficient for classification.

Acute Toxicity
Name Route Species Value
Epoxy Resin Dermal Rat LD50 > 1,600 mg/kg
Epoxy Resin Ingestion Rat LD50 > 1,000 mg/kg
ATE = acute toxicity estimate

Skin Corrosion/Irritation
Name Species Value

Epoxy Resin Rabbit Mild irritant

Serious Eye Damage/Irritation


Name Species Value

Epoxy Resin Rabbit Moderate irritant

Skin Sensitization
Name Species Value
Epoxy Resin Human Sensitizing
and
animal

Respiratory Sensitization
Name Species Value

Epoxy Resin Human Some positive data exist, but the data are not
sufficient for classification

Germ Cell Mutagenicity


Name Route Value

Epoxy Resin In vivo Not mutagenic


Epoxy Resin In Vitro Some positive data exist, but the data are not
sufficient for classification

Carcinogenicity
Name Route Species Value
Epoxy Resin Dermal Mouse Some positive data exist, but the data are not
sufficient for classification

Reproductive Toxicity

__________________________________________________________________________________________
Page 6 of 9
3M™ Scotch-Weld™ Epoxy Adhesive DP100 Clear, Part B 04/16/15

Reproductive and/or Developmental Effects


Name Route Value Species Test Result Exposure
Duration
Epoxy Resin Ingestion Not toxic to female reproduction Rat NOAEL 750 2 generation
mg/kg/day
Epoxy Resin Ingestion Not toxic to male reproduction Rat NOAEL 750 2 generation
mg/kg/day
Epoxy Resin Dermal Not toxic to development Rabbit NOAEL 300 during
mg/kg/day organogenesi
s
Epoxy Resin Ingestion Not toxic to development Rat NOAEL 750 2 generation
mg/kg/day

Target Organ(s)

Specific Target Organ Toxicity - single exposure


For the component/components, either no data are currently available or the data are not sufficient for classification.

Specific Target Organ Toxicity - repeated exposure


Name Route Target Organ(s) Value Species Test Result Exposure
Duration
Epoxy Resin Dermal liver Some positive data exist, but the Rat NOAEL 2 years
data are not sufficient for 1,000
classification mg/kg/day
Epoxy Resin Dermal nervous system All data are negative Rat NOAEL 13 weeks
1,000
mg/kg/day
Epoxy Resin Ingestion auditory system | All data are negative Rat NOAEL 28 days
heart | endocrine 1,000
system | mg/kg/day
hematopoietic
system | liver | eyes
| kidney and/or
bladder

Aspiration Hazard
For the component/components, either no data are currently available or the data are not sufficient for classification.

Please contact the address or phone number listed on the first page of the SDS for additional toxicological information
on this material and/or its components.

SECTION 12: Ecological information


Ecotoxicological information
Please contact the address or phone number listed on the first page of the SDS for additional ecotoxicological information on this material
and/or its components.
Chemical fate information
Please contact the address or phone number listed on the first page of the SDS for additional chemical fate information on this material
and/or its components.

SECTION 13: Disposal considerations


13.1. Disposal methods
Dispose of contents/ container in accordance with the local/regional/national/international regulations.

Dispose of completely cured (or polymerized) material in a permitted industrial waste facility. As a disposal alternative,
incinerate uncured product in a permitted waste incineration facility. Proper destruction may require the use of additional fuel

__________________________________________________________________________________________
Page 7 of 9
3M™ Scotch-Weld™ Epoxy Adhesive DP100 Clear, Part B 04/16/15

during incineration processes. Combustion products will include halogen acid (HCl/HF/HBr). Facility must be capable of
handling halogenated materials. If no other disposal options are available, waste product that has been completely cured or
polymerized may be placed in a landfill properly designed for industrial waste. Empty drums/barrels/containers used for
transporting and handling hazardous chemicals (chemical substances/mixtures/preparations classified as Hazardous as per
applicable regulations) shall be considered, stored, treated & disposed of as hazardous wastes unless otherwise defined by
applicable waste regulations. Consult with the respective regulating authorities to determine the available treatment and
disposal facilities.

EPA Hazardous Waste Number (RCRA): Not regulated

SECTION 14: Transport Information

For Transport Information, please visit http://3M.com/Transportinfo or call 1-800-364-3577 or 651-737-6501.

SECTION 15: Regulatory information

15.1. US Federal Regulations


Contact 3M for more information.

311/312 Hazard Categories:

Fire Hazard - No Pressure Hazard - No Reactivity Hazard - No Immediate Hazard - Yes Delayed Hazard - No

15.2. State Regulations


Contact 3M for more information.

15.3. Chemical Inventories


The components of this product are in compliance with the chemical notification requirements of TSCA.

Contact 3M for more information.

15.4. International Regulations


Contact 3M for more information.

This SDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200.

SECTION 16: Other information


NFPA Hazard Classification
Health: 2 Flammability: 1 Instability: 1 Special Hazards: None

National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address
the hazards that are presented by short-term, acute exposure to a material under conditions of fire, spill, or similar
emergencies. Hazard ratings are primarily based on the inherent physical and toxic properties of the material but also include
the toxic properties of combustion or decomposition products that are known to be generated in significant quantities.

Document Group: 10-3337-2 Version Number: 16.00


Issue Date: 04/16/15 Supercedes Date: 06/16/05

DISCLAIMER: The information in this Safety Data Sheet (SDS) is believed to be correct as of the date issued. 3M MAKES

__________________________________________________________________________________________
Page 8 of 9
3M™ Scotch-Weld™ Epoxy Adhesive DP100 Clear, Part B 04/16/15

NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY
OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR
USAGE OF TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable
for user's method of use or application. Given the variety of factors that can affect the use and application of a 3M product,
some of which are uniquely within the user's knowledge and control, it is essential that the user evaluate the 3M product to
determine whether it is fit for a particular purpose and suitable for user's method of use or application.

3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer
may have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness
or accuracy. In addition, information obtained from a database may not be as current as the information in the SDS available
directly from 3M

3M USA SDSs are available at www.3M.com

__________________________________________________________________________________________
Page 9 of 9
MATERIAL SAFETY DATA SHEET
470 FEATHERSPRAY
Page : 1

SLUYTER COMPANY LTD.


375 Steelcase Road East
Markham, Ontario L3R 1G3 Canada
Tel (905) 475-6011 Fax (905) 475-3119

SECTION 01: CHEMICAL PRODUCT AND COMPANY IDENTIFICATION


MANUFACTURER-----------------------SLUYTER COMPANY LTD.
375 Steelcase Road East
Markham, Ontario L3R 1G3 Canada
Tel (905) 475-6011
PRODUCT NAME-----------------------470 FEATHERSPRAY.
PRODUCT USES-----------------------Foam adhesive.
CHEMICAL FAMILY--------------------Solvent based adhesive (Pressurized).

SECTION 02: COMPOSITION / INFORMATION ON INGREDIENTS


INGREDIENTS / % CAS / TLV LD/50, ROUTE, SPECIES LC/50, ROUTE, SPECIES
ACETONE
10 - 30 67-64-1 9750 mg/kg 16000 ppm 4 hours
750 ppm Oral (Rat) Inhalation (Rat)
CYCLOHEXANE
10 - 30 110-82-7 12705 mg/kg 50 ppm 1 hour
300 ppm Oral (Rat) Inhalation (Rat)
HEXANE
30 - 60 110-54-3 28710 mg/kg 120000 mg/m3
50 ppm Oral (Rat) Inhalation MUS
ISOBUTANE
10 - 30 75-28-5 Not Indicated Not indicated
800 ppm
PROPANE
10 - 30 74-98-6 Not indicated Not Indicated
1000 ppm

SECTION 03: HAZARDS IDENTIFICATION


ROUTE OF ENTRY:--------------------
SKIN CONTACT-----------------Can cause moderate skin irritation,
defatting and dermatitis.
SKIN ABSORPTION--------------Not available.
INHALATION CHRONIC-----------Breathing of high vapour concentrations
could cause dizziness, headache or even
unconsciousness. May be anesthetic which
could result in other central nervous system effects.
INGESTION--------------------Can cause gastro-intestinal irritation,
nausea, vomiting and diarrhea. Small
amounts of liquid aspirated into
respiratory system could cause severe
health effects (e.g. Bronchopneumonia or Pulmonary Edema).
EYE CONTACT------------------Contains materials that are moderately
irritating to the eyes.
EFFECTS OF ACUTE EXPOSURE----------Refer to "ROUTE ENTRY" section.
EFFECTS OF CHRONIC EXPOSURE--------Prolonged or repeated exposure to N-Hexane
may damage peripheral nerve tissue of the
arms and legs, which may result in
muscular weakness or loss of sensation in
the extremities. Prolonged or repeated skin
contact may cause drying or cracking of the skin.

Ref: 0000201E Preparation Date : May.07.2015

EMERGENCY - CALL CANUTEC (613) 996-6666 (Collect)


MATERIAL SAFETY DATA SHEET
470 FEATHERSPRAY
Page : 2

SECTION 04: FIRST AID MEASURES


EYE CONTACT------------------------Check for and remove any contact lenses.
Immediately flush with water for a minimum
of 20 minutes and get medical attention.
SKIN CONTACT-----------------------Remove contaminated clothing. Wash
affected area with water and soap. Seek
medical attention if irritation occurs or persists.
INHALATION-------------------------Remove patient to fresh air. If not
breathing, trained personnel should
administer artificial respiration. Get
medical attention.
INGESTION--------------------------Do NOT induce vomiting. Get immediate
medical attention.
ADDITIONAL INFORMATION-------------Contact your local poison control centre.

SECTION 05: FIRE FIGHTING MEASURES


FLAMMABILITY-----------------------Flammable.
UNDER WHAT CONDITIONS--------------Flammable aerosol. A dangerous fire hazard
when exposed to heat, flames or
sparks. CAUTION: CONTENTS UNDER PRESSURE.
Temperatures above 50°C may cause container to explode.
SPECIAL PROCEDURES-----------------A self-contained breathing apparatus is
required for fire fighting personnel. Use
water spray to cool fire exposed surfaces
and to protect personnel.
FLASH POINT (METHOD)--------------- -18°C TAG Closed Cup. Flame projection > 45 cm.
AUTO IGNITION TEMPERATURE----------Not available.
UPPER FLAMMABLE LIMIT (% VOL)------7.00.
LOWER FLAMMABLE LIMIT (% VOL)------0.60.
EXTINGUISHING MEDIA----------------Alcohol foam, CO2 or dry chemical.
HAZARDOUS COMBUSTION PRODUCTS------Oxides of Carbon (CO and CO2). Toxic fumes.
SENSITIVITY TO MECHANICAL----------Not available.
IMPACT
SENSITIVITY TO STATIC--------------Not available.
DISCHARGE

SECTION 06: ACCIDENTAL RELEASE MEASURES


LEAK/SPILL-------------------------Ventilate. Remove all sources of ignition,
open flames, sparks and heaters. Wear
protective gear (See SECTION 8).Small
spills can be wiped. Large spills must be
collected for disposal. Use a
non-combustible absorbent inorganic
material. Clean thoroughly with solvent
based cleaner. Prevent run-off into drains,
sewers and other waterways.

SECTION 07: HANDLING AND STORAGE


HANDLING PROCEDURES----------------Avoid skin and eye contact. Avoid breathing
vapours. Use adequate ventilation. Keep away
from heat, sparks and open flame.
STORAGE NEEDS----------------------Store in a cool area, away from all
sources of heat and ignition. Store in a
dry, well ventilated area. Do NOT store

Ref: 0000201E Preparation Date : May.07.2015

EMERGENCY - CALL CANUTEC (613) 996-6666 (Collect)


MATERIAL SAFETY DATA SHEET
470 FEATHERSPRAY
Page : 3
above 49°C.

SECTION 08: EXPOSURE CONTROLS / PERSONAL PROTECTION


PROTECTIVE EQUIPMENT:--------------
EYE/TYPE---------------------Safety glasses.
RESPIRATORY/TYPE-------------If used indoors on a continuous basis or
if the TLV is exceeded, the use of a
cartridge type respirator (NIOSH/MSHA
approved) is recommended.
GLOVES/ TYPE-----------------Not applicable.
CLOTHING/TYPE----------------Wear adequate protective clothing.
FOOTWEAR/TYPE----------------Safety boots as specified in workplace regulations.
OTHER/TYPE-------------------Eye bath and safety shower.
VENTILATION REQUIREMENTS-----------Natural or mechanical (Explosion Proof)
ventilation to keep vapour levels well below the TLV.

SECTION 09: PHYSICAL AND CHEMICAL PROPERTIES


PHYSICAL STATE---------------------Aerosol Can.
ODOUR------------------------------Petroleum Solvent Odour.
SPECIFIC GRAVITY-------------------0.75 - 0.85 (Liquid Contents).
ODOUR THRESHOLD (ppm)--------------Not available.
VAPOUR PRESSURE--------------------90 psig @ 20°C.
VAPOUR DENSITY (AIR=1)------------- > 1.00.
EVAPORATION RATE-------------------Not available.
BOILING POINT (deg C)--------------56°C.
pH---------------------------------Not applicable.
SOLUBILITY IN WATER (% W/W)--------Negligible.
COEFFICIENT OF WATER\OIL-----------Not available.
DISTRIBUTION
FREEZING POINT--------------------- < 0°C.
MELTING POINT (deg C)--------------Not applicable.
MOLECULAR WEIGHT-------------------Not applicable.

SECTION 10: STABILITY AND REACTIVITY


INCOMPATIBILITY--------------------Strong acids and strong bases. Oxidizing agents.
REACTIVITY CONDITIONS--------------Excessive heat, sparks and open flame.
HAZARDOUS PRODUCTS OF--------------Oxides of Carbon (CO and C02). Toxic
DECOMPOSITION fumes. Smoke.

SECTION 11: TOXICOLOGICAL INFORMATION


EXPOSURE LIMIT OF MATERIAL---------See "HAZARDOUS INGREDIENTS" in SECTION 2.
IRRITANCY OF MATERIAL--------------Moderate.
SENSITIZING CAPABILITY OF----------Not available.
MATERIAL
CARCINOGENICITY OF MATERIAL--------No information is available and no adverse
carcinogenic effects are anticipated.
TERATOGENICITY---------------------No information is available and no adverse
teratogenicity effects are anticipated.
MUTAGENICITY-----------------------No information is available and no adverse
mutagenicity effects are anticipated.
REPRODUCTIVE EFFECTS---------------No information is available and no adverse
reproductive effects are anticipated.
SYNERGISTIC MATERIALS--------------Not available.

SECTION 12: ECOLOGICAL INFORMATION


Ref: 0000201E Preparation Date : May.07.2015

EMERGENCY - CALL CANUTEC (613) 996-6666 (Collect)


MATERIAL SAFETY DATA SHEET
470 FEATHERSPRAY
Page : 4

ENVIRONMENTAL----------------------Not available. Can be dangerous if allowed


to enter drinking water intakes. Product
has an unaesthetic appearance and can be a
nuisance. Do not contaminate domestic or
irrigation water supplies, lakes, streams,
ponds and rivers.
BIODEGRADABILITY-------------------Not available. The solvent portion of this
product is biodegradable and vaporizes rapidly.

SECTION 13: DISPOSAL CONSIDERATIONS


WASTE DISPOSAL---------------------Contents under pressure. Do NOT puncture,
incinerate or expose to heat, even when
empty. Spilled material and water rinses
are classified as chemical waste. To be
disposed of in accordance with current
Local, Provincial and Federal regulations.

SECTION 14: TRANSPORT INFORMATION


T.D.G. CLASSIFICATION-------------- SHIPPING NAME – Aerosols
WHMIS – Consumer Commodity
PACKAGING GROUP- Not Applicable
UN NUMBER - 1950
If the shipment exceeds 500 kg in weight - shipped as
CONSUMER COMMODITY - AEROSOLS FLAMMABLE CLASS 2.1.

SECTION 15: REGULATORY INFORMATION


CPR COMPLIANCE---------------------This product has been classified in
accordance with the hazard criteria of the
CPR and the MSDS contains all the
information required by the CPR.
WHMIS CLASSIFICATION---------------Class A Class B Div.5 Flammable. Aerosol
Class D Div.2 Subdiv.B.

SECTION 16: OTHER INFORMATION


IMPORTANT:-------------------------The information on this Material Safety
Data Sheet is furnished without warranty,
expressed or implied. All the information
appearing herein is based upon data
obtained from manufacturers and/or
recognized technical sources. While the
information is believed to be accurate, we
make no representations for the accuracy or sufficiency.

Ref: 0000201E Preparation Date : May.07.2015

EMERGENCY - CALL CANUTEC (613) 996-6666 (Collect)


MATERIAL SAFETY DATA SHEET
476 SPRAY ADHESIVE
Page : 1

SLUYTER COMPANY LTD.


375 Steelcase Road East
Markham, Ontario L3R 1G3 Canada
Tel (905) 475-6011 Fax (905) 475-3119

SECTION 01: CHEMICAL PRODUCT AND COMPANY IDENTIFICATION


MANUFACTURER-----------------------SLUYTER COMPANY LTD.
375 Steelcase Road East
Markham, Ontario L3R 1G3 Canada
Tel (905) 475-6011
PRODUCT NAME-----------------------476 SPRAY ADHESIVE
PRODUCT USES-----------------------Foam adhesive.
CHEMICAL FAMILY--------------------Solvent based adhesive (Pressurized).

SECTION 02: COMPOSITION / INFORMATION ON INGREDIENTS


INGREDIENTS / % CAS / TLV LD/50, ROUTE, SPECIES LC/50, ROUTE, SPECIES
ACETONE
10 - 30 67-64-1 9750 mg/kg 16000 ppm 4 hours
750 ppm Oral (Rat) Inhalation (Rat)
CYCLOHEXANE
10 - 30 110-82-7 12705 mg/kg 50 ppm 1 hour
300 ppm Oral (Rat) Inhalation (Rat)
HEXANE
30 - 60 110-54-3 28710 mg/kg 120000 mg/m3
50 ppm Oral (Rat) Inhalation MUS
ISOBUTANE
10 - 30 75-28-5 Not Indicated Not indicated
800 ppm
PROPANE
10 - 30 74-98-6 Not indicated Not Indicated
1000 ppm

SECTION 03: HAZARDS IDENTIFICATION


ROUTE OF ENTRY:--------------------
SKIN CONTACT-----------------Can cause moderate skin irritation,
defatting and dermatitis.
SKIN ABSORPTION--------------Not available.
INHALATION CHRONIC-----------Breathing of high vapour concentrations
could cause dizziness, headache or even
unconsciousness. May be anesthetic which
could result in other central nervous system effects.
INGESTION--------------------Can cause gastro-intestinal irritation,
nausea, vomiting and diarrhea. Small
amounts of liquid aspirated into
respiratory system could cause severe
health effects (e.g. Bronchopneumonia or Pulmonary Edema).
EYE CONTACT------------------Contains materials that are moderately
irritating to the eyes.
EFFECTS OF ACUTE EXPOSURE----------Refer to "ROUTE ENTRY" section.
EFFECTS OF CHRONIC EXPOSURE--------Prolonged or repeated exposure to N-Hexane
may damage peripheral nerve tissue of the
arms and legs, which may result in
muscular weakness or loss of sensation in
the extremities. Prolonged or repeated skin
contact may cause drying or cracking of the skin.

Ref: 0000202E Preparation Date : May.07.2015

EMERGENCY - CALL CANUTEC (613) 996-6666 (Collect)


MATERIAL SAFETY DATA SHEET
476 SPRAY ADHESIVE
Page : 2

SECTION 04: FIRST AID MEASURES


EYE CONTACT------------------------Check for and remove any contact lenses.
Immediately flush with water for a minimum
of 20 minutes and get medical attention.
SKIN CONTACT-----------------------Remove contaminated clothing. Wash
affected area with water and soap. Seek
medical attention if irritation occurs or persists.
INHALATION-------------------------Remove patient to fresh air. If not
breathing, trained personnel should
administer artificial respiration. Get
medical attention.
INGESTION--------------------------Do NOT induce vomiting. Get immediate
medical attention.
ADDITIONAL INFORMATION-------------Contact your local poison control centre.

SECTION 05: FIRE FIGHTING MEASURES


FLAMMABILITY-----------------------Flammable.
UNDER WHAT CONDITIONS--------------Flammable aerosol. A dangerous fire hazard
when exposed to heat, flames or
sparks. CAUTION: CONTENTS UNDER PRESSURE.
Temperatures above 50°C may cause container to explode.
SPECIAL PROCEDURES-----------------A self-contained breathing apparatus is
required for fire fighting personnel. Use
water spray to cool fire exposed surfaces
and to protect personnel.
FLASH POINT (METHOD)--------------- -18°C TAG Closed Cup. Flame projection > 45 cm.
AUTO IGNITION TEMPERATURE----------Not available.
UPPER FLAMMABLE LIMIT (% VOL)------7.00.
LOWER FLAMMABLE LIMIT (% VOL)------0.60.
EXTINGUISHING MEDIA----------------Alcohol foam, CO2 or dry chemical.
HAZARDOUS COMBUSTION PRODUCTS------Oxides of Carbon (CO and CO2). Toxic fumes.
SENSITIVITY TO MECHANICAL----------Not available.
IMPACT
SENSITIVITY TO STATIC--------------Not available.
DISCHARGE

SECTION 06: ACCIDENTAL RELEASE MEASURES


LEAK/SPILL-------------------------Ventilate. Remove all sources of ignition,
open flames, sparks and heaters. Wear
protective gear (See SECTION 8).Small
spills can be wiped. Large spills must be
collected for disposal. Use a
non-combustible absorbent inorganic
material. Clean thoroughly with solvent
based cleaner. Prevent run-off into drains,
sewers and other waterways.

SECTION 07: HANDLING AND STORAGE


HANDLING PROCEDURES----------------Avoid skin and eye contact. Avoid breathing
vapours. Use adequate ventilation. Keep away
from heat, sparks and open flame.
STORAGE NEEDS----------------------Store in a cool area, away from all
sources of heat and ignition. Store in a
dry, well ventilated area. Do NOT store

Ref: 0000202E Preparation Date : May.07.2015

EMERGENCY - CALL CANUTEC (613) 996-6666 (Collect)


MATERIAL SAFETY DATA SHEET
476 SPRAY ADHESIVE
Page : 3
above 49°C.

SECTION 08: EXPOSURE CONTROLS / PERSONAL PROTECTION


PROTECTIVE EQUIPMENT:--------------
EYE/TYPE---------------------Safety glasses.
RESPIRATORY/TYPE-------------If used indoors on a continuous basis or
if the TLV is exceeded, the use of a
cartridge type respirator (NIOSH/MSHA
approved) is recommended.
GLOVES/ TYPE-----------------Not applicable.
CLOTHING/TYPE----------------Wear adequate protective clothing.
FOOTWEAR/TYPE----------------Safety boots as specified in workplace regulations.
OTHER/TYPE-------------------Eye bath and safety shower.
VENTILATION REQUIREMENTS-----------Natural or mechanical (Explosion Proof)
ventilation to keep vapour levels well below the TLV.

SECTION 09: PHYSICAL AND CHEMICAL PROPERTIES


PHYSICAL STATE---------------------Aerosol Can.
ODOUR------------------------------Petroleum Solvent Odour.
SPECIFIC GRAVITY-------------------0.75 - 0.85 (Liquid Contents).
ODOUR THRESHOLD (ppm)--------------Not available.
VAPOUR PRESSURE--------------------90 psig @ 20°C.
VAPOUR DENSITY (AIR=1)------------- > 1.00.
EVAPORATION RATE-------------------Not available.
BOILING POINT (deg C)--------------56°C.
pH---------------------------------Not applicable.
SOLUBILITY IN WATER (% W/W)--------Negligible.
COEFFICIENT OF WATER\OIL-----------Not available.
DISTRIBUTION
FREEZING POINT--------------------- < 0°C.
MELTING POINT (deg C)--------------Not applicable.
MOLECULAR WEIGHT-------------------Not applicable.

SECTION 10: STABILITY AND REACTIVITY


INCOMPATIBILITY--------------------Strong acids and strong bases. Oxidizing agents.
REACTIVITY CONDITIONS--------------Excessive heat, sparks and open flame.
HAZARDOUS PRODUCTS OF--------------Oxides of Carbon (CO and C02). Toxic
DECOMPOSITION fumes. Smoke.

SECTION 11: TOXICOLOGICAL INFORMATION


EXPOSURE LIMIT OF MATERIAL---------See "HAZARDOUS INGREDIENTS" in SECTION 2.
IRRITANCY OF MATERIAL--------------Moderate.
SENSITIZING CAPABILITY OF----------Not available.
MATERIAL
CARCINOGENICITY OF MATERIAL--------No information is available and no adverse
carcinogenic effects are anticipated.
TERATOGENICITY---------------------No information is available and no adverse
teratogenicity effects are anticipated.
MUTAGENICITY-----------------------No information is available and no adverse
mutagenicity effects are anticipated.
REPRODUCTIVE EFFECTS---------------No information is available and no adverse
reproductive effects are anticipated.
SYNERGISTIC MATERIALS--------------Not available.

SECTION 12: ECOLOGICAL INFORMATION


Ref: 0000202E Preparation Date : May.07.2015

EMERGENCY - CALL CANUTEC (613) 996-6666 (Collect)


MATERIAL SAFETY DATA SHEET
476 SPRAY ADHESIVE
Page : 4

ENVIRONMENTAL----------------------Not available. Can be dangerous if allowed


to enter drinking water intakes. Product
has an unaesthetic appearance and can be a
nuisance. Do not contaminate domestic or
irrigation water supplies, lakes, streams,
ponds and rivers.
BIODEGRADABILITY-------------------Not available. The solvent portion of this
product is biodegradable and vaporizes rapidly.

SECTION 13: DISPOSAL CONSIDERATIONS


WASTE DISPOSAL---------------------Contents under pressure. Do NOT puncture,
incinerate or expose to heat, even when
empty. Spilled material and water rinses
are classified as chemical waste. To be
disposed of in accordance with current
Local, Provincial and Federal regulations.

SECTION 14: TRANSPORT INFORMATION


T.D.G. CLASSIFICATION-------------- SHIPPING NAME – Aerosols
WHMIS – Consumer Commodity
PACKAGING GROUP- Not Applicable
UN NUMBER - 1950
If the shipment exceeds 500 kg in weight - shipped as
CONSUMER COMMODITY - AEROSOLS FLAMMABLE CLASS 2.1.

SECTION 15: REGULATORY INFORMATION


CPR COMPLIANCE---------------------This product has been classified in
accordance with the hazard criteria of the
CPR and the MSDS contains all the
information required by the CPR.
WHMIS CLASSIFICATION---------------Class A Class B Div.5 Flammable. Aerosol
Class D Div.2 Subdiv.B.

SECTION 16: OTHER INFORMATION


IMPORTANT:-------------------------The information on this Material Safety
Data Sheet is furnished without warranty,
expressed or implied. All the information
appearing herein is based upon data
obtained from manufacturers and/or
recognized technical sources. While the
information is believed to be accurate, we
make no representations for the accuracy or sufficiency.

Ref: 0000202E Preparation Date : May.07.2015

EMERGENCY - CALL CANUTEC (613) 996-6666 (Collect)


Page 1/13
Safety Data Sheet
ace. to OSHA HCS
Printing date 02/22/2016

I Identification
Product identifier
Trade name: 39023 39583 TPO-Direct Bumper Coaters
-

Article number:
39153, 39253, 39263, 39273, 39163, 39173, 39183, 39193, 39283, 39293, 39413, 39423, 39443, 39583, 39023,
39073, 39083, 39103
Application of the substance/the mixture Coating
Details of the supplier of the safety data sheet
Manufacturer/Supplier:
SEM Products Inc.
1685 Overview Drive
Rock Hill, SC 29730
803 207 8225
Information department:
[email protected] : SEM Products,Inc. 1685 Overview Dr. Rock Hill, SC 29730 : phone 1-800-83 1-
1122, M- TH 7am 4pm EDT
-

Emergency telephone nuniber: CHEMTREC 1-800-424-9300

*
2 Hazard(s) identification
• Classification of the substance or mixture

GHSO2 GHSO4 Flame, Gas cylinder



Flam. Aerosol 1 H222 Extremely Jlammable aerosol. -

GHSO4 Gas cylinder

Press. Gas H280 Contains gas under pressure; may explode f heated.

GHSO8 Health hazard

Carc. 2 H351 Suspected ofcausing cancer.


Repr. 2 H361 Suspected ofdamagingfertility or the unborn child.
STOTRE 2 H3 73 May cause damage to organs through prolonged or repeated exposure.
Asp. Tox. 1 H304 May befatal ifswallowed and enters airways.

GHSO7

Skin Irrit. 2 ff315 causes skin irritation.


STOT SE 3 H336 May cause drowsiness or dizziness.
Label elements
GHS label elements The product is classfled and labeled according to the Globally Harmonized System (GHS,.
(Contd. on page 2)
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Trade name: 39023 39583 TPO-Direct Bumper C’oaters


-

(Contd. of page 1)
• Hazard pictograms

GHSO2 GHSO4 GHSO7 GHSO8

• Signal word Danger


• Hazard-determining components of labeling:
toluene
cyclohexane
2, 6-dimethylheptan-4-one
Carbon black
• Hazard statements
H222 Extremely flammable aerosol.
H280 Contains gas under pressure; may explode f heated.
H315 Causes skin irritation.
H351 Suspected ofcausing cancer.
1-1361 Suspected of damagingfertility or the unborn child.
H336 May cause drowsiness or dizziness.
H3 73 May cause damage to organs through prolonged or repeated exposure.
H304 May be fatal fswallowed and enters airways.
Precautionary statements
P210 Keep awayfrom heat/sparks/open flames/hot surfaces. No smoking.
P251 Do not pierce or burn, even after use.
P260 Do not breathe dust/fume/gas/mist/vapors/spray.
P211 Do not spray on an open flame or other ignition source.
P280 Wear protective gloves.
P264 Wash thoroughly after handling.
P271 Use only outdoors or in a well-ventilated area.
P201 Obtain special instructions before use.
P202 Do not handle until all safety precautions have been read and understood.
P301 +P310 IF SWALLOWED: Immediately call a POISON CENTER/ doctor.
P321 Specflc treatment (see on this label).
P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P312 Call a POISON CENTER/doctor fyou feel unwell.
P308+P313 IF exposed or concerned: Get medical advice/attention.
P332+P313 Ifskin irritation occurs: Get medical advice/attention.
P314 Get medical advice/attention fyou feel unwell.
P331 Do NOT induce vomiting.
P302+P352 IF ON SKIN: Wash with plenty ofwater.
P362+P364 Take offcontaminated clothing and wash it before reuse.
P405 Store locked up.
P410+P403 Protectfrom sunlight. Store in a well-ventilated place.
P410+P412 Protectfrom sunlight. Do not expose to temperatures exceeding 50°C/122°F.
P403+P233 Store in a well-ventilated place. Keep container tightly closed.
P501 Dispose of contents/container in accordance with local/regional/national/international regulations.
(Contd. on page 3)
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• Trade name: 39023 39583 TPO-Direct Bumper Coaters


-

(Contd. of page 2)
Classification system:
• NFPA ratings (scale 0-4)
Health = I
Fire 4
Reactivity = 3
• HMJS-ratings (scale 0-4)
HEALTH Health = *1
FIRE ci Fire 4
L REACTIVIT Reactivity = 3
Other hazards
Results ofPBT and vPvB assessment
• PBT: Not applicable.
• vPvB: Not applicable.

3 Composition/information on ingredients

Chemical characterization: Mixtures


Description:
Mixture: consisting of thefollowing components.
Weight percentages
Dangerous components:
115-10-6 dimethyl ether 40 60%
-

108-88-3 toluene 13 30%


-

110-19-0 isobutyl acetate 13 30%


-

110-82-7 cyclohexane 1.5-5%


108-83-8 2, 6-dimethylheptan-4-one 1-1.5%
NJ TSRN: 8009285004 Polyester Plasticizer 1-1.5%
13 33-86-4 Carbon black <-1%
13463-67-7 titanium dioxide <1 %

4 First-aid measures

Description offirst aid nieasures


General information: Immediately remove any clothing soiled by the product.
After inhalation: In case ofunconsciousness place patient stably in side position for transportation.
After skin contact: Immediately wash with water and soap and rinse thoroughly.
After eye contact: Rinse opened eye for several minutes under running water.
After swallowing: Ifsymptoms persist consult doctor.
Information for doctor:
Most important symptoms and effects, both acute and delayed No further relevant information available.
Indication of any immediate medical attention and special treatment needed
No further relevant information available.

(Contd. on page 4)
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Safety Data Sheet
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Trade name: 39023 39583 TPO-Direct Bumper Coaters


-

(Contd. of page 3)

*
5 Fire-fighting measures

• Extinguishing media
• Suitable extinguishing agents:
C02, extinguishingpowder or water spray. Fight largerfires with water spray or alcohol resistantfoam.
Special hazards arisingfrom the substance or mixture
During heating or in case offire poisonous gases are produced.
• Adviceforfirefighters
Protective equipment: Mouth respiratory protective device.

*
6 Accidental release measures
• Personal precautions, protective equipment and emergency procedures
Mount respiratory protective device.
Wear protective equipment. Keep unprotected persons away.
Environmental precautions: Do not allow to enter sewers/surface or ground water.
Methods and materialfor containment and cleaning up:
Dispose contaminated material as waste according to item 13.
Ensure adequate ventilation.
• Reference to other sections
See Section 7for information on safe handling.
See Section 8for information on personal protection equipment.
See Section 13 for disposal information.

*
7 Handling and storage 0
• Handling:
Precautions for safe handling
No special measures required.
Ensure good ventilation/exhaustion at the workplace.
Open and handle receptacle with care.
Information aboutprotection against explosions andfires:
Do not spray on a nakedflame or any incandescent material.
Keep ignition sources away Do not smoke.
-

Keep respiratory protective device available.


Pressurized container: protect from sunlight and do not expose to temperatures exceeding 50 °C, i.e. electric
lights. Do not pierce or burn, even after use.
• Conditions for safe storage, including any incompatibilities
Storage:
Requirements to be met by storerooms and receptacles:
Observe official regulations on storing packagings with pressurized containers.
Information about storage in one common storage facility: Not required.
Further information about storage conditions: Keep receptacle tightly sealed.
Specific end use(s) Noflirther relevant information available.

*
8 Exposure controls/personal protection
Additional information about design of technical systems: Noflirther data; see item 7.
(Conid. on page 5)

0
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Trade name: 39023 39583 TPO-Direct Bumper Coaters


-

(Contd. of page 4)

Control parameters
• Components with limit values that require monitoring at the workplace:
115-10-6 dimethyl ether
WEEL Long-term value. 1000 ppm
108-88-3 toluene
PEL Long-term value: 200 ppm
Ceiling limit value: 300; 500* ppm
*l0rninpeakper 8-hr shfl
REL Short-term value: 560 mg/m, 150 ppm
3
Long-term value: 375 mg/rn
, 100 ppm
3
TLV Long-term value: 75 ing/m, 20 ppm
3
BEI
110-19-0 isobutyl acetate
PEL Long-term value: 700 mg/rn, 150 ppm
3
REL Long-term value: 700 mg/m , 150 ppm
3
TL V Short-term value: NIC- 712 ing/m
, NJC-150 ppm
3
Long-term value: (713) NIC-238 mg/rn
, (150) NJC-50 ppm
3
110-82-7 cyclohexane
PEL Long-term value: 1 050 mg/rn
, 300 ppm
3
REL Long-term value: 1050 mg/rn, 300 ppm
3
TL V Long-term value: 344 mg/rn
, 100 ppm
3
108-83-8 2,6-dimethylheptan-4-one
PEL Long-term value: 290 mg/rn, 50 ppm
3
REL Long-term value: 150 mg/in, 25 ppm
3
TL V Long-term value: 145 mg/rn
, 25 ppm
3
Ingredients with biological limit values:
108-88-3 toluene
BEI 0.02 mg/L
Medium: blood
Time: prior to last shift of workweek
Parameter: Toluene

0.03 mg/L
Medium: urine
Time: end ofshift
Parameter: Toluene

0.3 rng/g creatinine


Medium: urine
Time: end ofshfl
Parameter: o-Cresol with hydrolysis (background)
Additional information: The lists that were valid during the creation were used as basis.
Exposure controls
Personal protective equipment:
General protective and hygienic measures:
Keep awayfrornfoodstiffs, beverages andfeed.
(Contd. on page 6)
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Trade nanse: 39023 39583 TPO-Direct Bumper Coaters


-

(Contd. of pageS)
Immediately remove all soiled and contaminated clothing.
Wash hands before breaks and at the end ofwork.
Store protective clothing separately.
Avoid contact with the skin.
Avoid contact wit!, the eyes and skin.
Breathing equipin cut:
In case of brief exposure or low pollution use respiratoryfilter device. In case of intensive or longer exposure use
respiratoty protective device that is independent ofcirculating air.
Protection of hands:
Due to missing tests no recommendation to the glove material can be given for the product/ the preparation/ the
chemical mixture.
Selection of the glove material on consideration of the penetration times, rates of dUflision and the degradation

Protective gloves

The glove material has to be impermeable and resistant to the product/the substance/ the preparation.
• Material ofgloves
The selection of the suitable gloves does not only depend on the material, but also on further marks ofquality and
varies from manufacturer to ,nanufacturer. As the product is a preparation ofseveral substances, the resistance
of the glove material can not be calculated in advance and has therefore to be checked prior to the application.
• Penetration time ofglove material
The exact break trough time has to be found out by the manufacturer of the protective gloves and has to be
observed.
• Eye protection:
Safety glasses
C
Tightly sealed goggles

*
9 Physical and chemical properties
• Information on basic physical and chemical properties
• General Information
Appearance:
Form: Aerosol
Color: According to product specification
• Odor: Characteristic
• Odor threshold: Not determined.
pH-value: Not determined.
Change in condition
Melting point/Meltiiig range: Undetermined.
Boiling point/Boiling range: -24 °C
Flash point: -42 °C
• Flaniniabiity (solid, gaseous): Not applicable.
Ignition temperature: 235 °C
(Contd. on page 7)
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• Trade name: 39023 39583 TPO-Direct Bumper Coaters


-

(Contd. of page 6)
Decomposition temperature: Not determined.
Auto igniting: Product is not seijigniting.
• Danger of explosion: hi use, inayforniflamniable/explosive vapour-air mixture.
Explosion limits:
Lower: 1.2 Vol %
Upper: 18.6 Vol %
Vapor pressure at 20 °C: 5200 hPa
• Density at 20 °C: 0. 78383 g/cm
3
• Relative density Not determined.
• Vapor density Not determined.
• Evaporation rate Not applicable.
Solubility in I Miscibility with
Water: Not miscible or df/Icult to mix.
Partition coefficient (n-octanol/water): Not determined.
Viscosity:
Dynamic: Not determined.
Kinematic: Not determined.
Solvent content:
Organic solvents: 89.8 %
VOC content: 89.8 %
704.1 g/l / 5.88 lb/gl
Solids content: 9.6%
Other information No further relevant information available.

*
10 Stability and reactivity
Reactivity No further relevant information available.
• Chemical stability
• Thermal decomposition /conditions to be avoided: No decomposition f used according to specflcations.
• Possibility ofhazardous reactions No dangerous reactions known.
Conditions to avoid Noflirther relevant information available.
Incompatible materials: Noflirther relevant information available.
• Hazardous decomposition products: No dangerous decomposition products known.

*
11 Toxicological information
. Information on toxicological effects
Acute toxicity:
LD/LC5O values that are relevantfor classification:
108-88-3 toluene
Oral LD5O 5000 mg/kg (rat)
Dermal LD5O 12124 mg/kg (rabbit)
(Contd. on page 8)
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Trade name: 39023 39583 TPO-Direct Bumper Coaters


-

(Contd. of page 7)
F Inhalative LCS0/4 h 5320 mg/i (mouse)
110-82-7 cyclohexane
Oral LD5O 12705 mg/kg (rat)
• Primary irritant effect:
on the skin: Irritant to skin and mucous membranes.
on the eye: No irritating effect.
• Sensitization: No sensitizing effects known.
• Additional toxicological information:
The product shows thefollowing dangers according to internally approved calculation methods for preparations:
Irritant
• Carcinogenic categories
JARC (International Agencyfor Research on Cancer)
108-88-3 toluene 3
1333-86-4 Carbon black
13463-67-7 titanium dioxide
1330-20-7 xylene 3
67-63-0 propan-2-ol 3
100-41-4 ethyibenzene 2B
763 1-86-9 silicon dioxide, chemically prepared 3
14807-96-6 Talc 2B
NTP (National Toxicology Program) —

None ofthe ingredients is listed.


• OSHA-Ca (Occupational Safety & Health Administration)
68911-87-5 ALKYL QUA TERNARYAMMONIUM MONTMORILLONITE

*
12 Ecological information
• Toxicity
Aquatic toxicity: Noforther relevant information available.
• Persistence and degradability Noflirther relevant information available.
• Behavior in environmental systems:
Bioaccumulative potential No further relevant information available.
Mobility in soil No further relevant information available.
Additional ecological information:
General notes:
Water hazard class 3 (Self-assessment): extremely hazardousfor water
Water hazard class 2 (Self-assessment): hazardous for water
Do not allow product to reach ground water, water course or sewage system.
Danger to drinking water f even small quantities leak into the ground.
Results of PBT and vPvB assessment
• PBT: Not applicable.
• vPvB: Not applicable.
• Other adverse effects Nofiwther relevant information available.

(Contd. on page 9)

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-

(Conid. of page 8)

13 Disposal considerations
• Waste treatment methods
• Recommendation:
Must not be disposed oftogether with household garbage. Do not allow product to reach sewage system.
• Un cleanedpackagings:
• Recommendation: Disposal must be made according to official regulations.

*
14 Transport information
• UN-Number
• DOT, ADR, IMDG, IA TA UN1950
• UNproper shipping name
• DOT, IATA Aerosols,flammable
ADR 1950 Aerosols
IMDG AEROSOLS
• Transport hazard class(es.)
• DOT

• Class 2.1
• Label 2.1
• ADR

4
Class
Label
2 5F Gases
2.1 V

• IMDG, JATA

4
Class
Label
2.1
2.1
Packing group
• DOT, ADR, IMDG, IATA Void
• Environmental hazards:
Marine pollutant: No
Special precautionsfor user Warning: Gases
(Contd. on page 10)
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r
Trade name: 39023 39583 TPO-Direct Bumper Coaters
-

c
(Contd. of page 9)

EMS Number: F-D,S-U


. Stowage ‘ode SW] Protectedfrom sources of heat.
SW22 For AEROSOLS with a maximum capacity of 1 litre:
Category A. For AEROSOLS i’ith a capacity above 1 litre:
Category B. For W4STE AEROSOLS: Category C, Clear of living
quarters.
Segregation Code SG69 For AEROSOLS with a maximum capacity of I litre:
Segregation as for class 9. Stow “separatedfrom” class 1 exceptfor
division 1.4. For AEROSOLS with a capacity above I litre:
Segregation as for the appropriate subdivision of class 2. For
WASTE AEROSOLS: Segregation as for the appropriate subdivision
ofclass 2.
Transport in bulk according to Annex II of
MARPOL 73/78 and the IBC Code Not applicable.
. Transport/Additional information:
DOT
. Quantity limitations On passenger aircraft/rail: 75 kg
On cargo aircraft only: 150 kg
ADR
Excepted quantities (EQ) Code: EQ
Not permitted as Excepted Quantity
IMDG
Limited quantities (LQ) 1L
Excepted quantities (EQ) Code: E0
Not permitted as Excepted Quantity C
UN “Model Regulation “: UN 1950 AEROSOLS, 2.1

*
15 Regulatory information
• Safety, health and environmental regulations/legislation specific for the substance or mixture
• Sara
• Section 355 (extremely hazardous substances):
None ofthe ingredient is listed.
Section 313 (SpecjfIc toxic chemical listings):
108-88-3 toluene
110-82-7 cyclohexane
7429-90-5 aluminium
ACR YLIC RESIN
1330-20-7 xylene
78-93-3 butanone
67-63-0 propan-2-ol
100-41-4 ethylbenzene
67-56-1 methanol
1480 7-96-6 Talc
(Contd. on page 1]
USA —
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-

(Contd. of page 10)


TSCA (Toxic Substances Control Act):
115-10-6 dimethyl ether
108-88-3 toluene
110-19-0 isobutyl acetate
110-82-7 cyclohexane
108-83-8 2, 6-dimethylheptan-4-one
1333-86-4 Carbon black
7429-90-5 aluminium
19549-80-5 4, 6-dimethylheptan-2-one
64742-88-7 Solvent naphtha (petroleum), medium aliph.
13463-67-7 titanium dioxide
512 74-00-1 YELLOW IRON OXIDE
1330-20-7 xylene
78-93-3 butanone
67-63-0 propan-2-ol
1332-3 7-2 Iron oxide
Proposition 65
(‘hemicals known to cause cancer:
1333-86-4 Jarbon black
13463-67-7 titanium dioxide
1330-20-7 xylene
100-41-4 ethylbenzene
25068-38-6 bisphenolAchloro)oxirane polymer
Chemicals known to cause reproductive toxicityforfemnales:
108-88-3 toluene
• Chemicals known to cause reproductive toxicity for males:
None ofthe ingredients is listed.
Chemicals known to cause developmental toxicity:
108-88-3 toluene
67-56-1 methanol
Can cerogenity categories
EPA (Environmental Protection Agency)
108-88-3 toluene II
110-82-7 cyclohexane T
1330-20-7 xvlene
78-93-3 butanone T
100-41-4 ethylbenzene D
TL V (Threshold Limit Value established by ACGIFI) —

108-88-3 toluene A4
1333-86-4 Carbon black
7429-90-5 aluminium A4
13463-67-7 titanium dioxide A4
(Contd. on page 12)
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-

(Contd. of nape lfl


1330-20-7 xylene A4
67-63-0 propan-2-ol A4
100-41-4 ethylbenzene A3
14807-96-6 Talc A4
• NIOSH-Ca (National Institutefor Occupational Safety and Health)
1333-86-4 Carbon black
13463-67-7 titanium dioxide
67-56-1 methanol
• GHS label elements The product is classfled and labeled according to the Globally Harmonized System (GHS).
• Hazard pictograms

GHSO2 GHSO4 GHSO7 GHSO8

• Signal word Danger


• Hazard-determining components of labeling:
toluene
cyclohexane
2, 6-dimethylheptan-4-one
Carbon black
• Hazard statements
H222 Extremelyflammable aerosol.
H280 Contains gas under pressure; may explode f heated.
H315 Causes skin irritation.
H351 Suspected of causing cancer.
H361 Suspected of damagingfertility or the unborn child.
H336 May cause drowsiness or dizziness.
H3 73 May cause damage to organs through prolonged or repeated exposure.
H304 May be fatal f swallowed and enters airways.
Precautionary statements
P210 Keep awayfrom heat/sparks/open flam es/hot surfaces. No smoking.
P251 Do not pierce or burn, even after use.
P260 Do not breathe dust/fume/gas/mist/vapors/spray.
P211 Do not spray on an open flame or other ignition source.
P280 Wear protective gloves.
P264 Wash thoroughly after handling.
P271 Use only outdoors or in a well-ventilated area.
P201 Obtain special instructions before use.
P202 Do not handle until all safety precautions have been read and understood.
P301 +P310 IF SWALLOWED: Immediately call a POISON CENTER! doctor.
P321 Specc treatment (see on this label).
P304+P340 IF INHALED: Remove person to fresh air and keep comfortablefor breathing.
P312 Call a POISON CENTER/doctor fyou feel unwell.
P308+P313 IF exposed or concerned: Get medical advice/attention.
P332+P313 If sldn irritation occurs: Get medical advice/attention.
P314 Get medical advice/attention fyou feel unwell.
P331 Do NOT induce vomiting.
P302+P352 IF ON SKIN: Wash with plenty ofwater.
(Contd. on page 13)

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(Contd. of page 12)


P362+P364 Take off contaminated clothing and wash it before reuse.
P405 Store locked up.
P410±P403 Protectfrom sunlight. Store in a well-ventilated place.
P410+P412 Protectfrom sunlight. Do not expose to temperatures exceeding 50°c/i 22 °F.
P403+P233 Store in a well-ventilatedplace. Keep container tightly closed.
P501 Dispose of contents/container in accordance with local/regional/national/international regulations.
Chemical safety assessment: A Chemical Safety Assessment has not been carried out.

16 Other information
This information is based on our present knowledge. However, this shall not constitute a guarantee for any
specflc productfeatures and shall not establish a legally valid contractual relationship.
• Department issuing SDS: Environment protection department.
• contact: Steve Gayer ([email protected])
• Date ofpreparation /last revision 02/22/2016/8
• Abbreviations and acronyms:
RID: Reglement international concernant le transport des inarchandises dangereuses par chemin defer (Regulations Concerning the
International Transport ofDangerous Goods by Rail)
IC’AO: International Civil Aviation Organisation
ADR: Accord europten sur le transport des ,narchandises dangereuses par Route (European Agreement concerning the International
Carriage ofDangerous Goods by Road)
IMDG: International Maritime Code for Dangerous Goods
DOT.’ US Department of Transportation
IA TA: International Air Transport Association
ACGIH: American Conference of Governmental Industrial Hygienists
EINECS: European Inventory ofExisting Commercial Chemical Substances
ELINCS: European List ofNot(fied Chemical Substances
CAS: Che,nicalAbstracts Sen’ice (division of the American Chemical Society)
NFPA: National Fire Protection Association (USA)
HMIS: Hazardous Materials Identification Syste,n (USA)
VOC: Volatile Organic Compounds (USA, EU)
LC5O: Lethal concentration, 50 percent
LD5O: Lethal dose, 50 percent
PBT: Persistent, Bioaccumulative and Toxic
vPvB: very Persistent and very Bioaccumulative
NIOS!-I: National Institute for Occupational Safety
OSHA: Occupational Safety & Health
TLV: Threshold Limit Value
PEL: Permissible Exposure Limit
REL: Recommended Exposure Limit
BE!: Biological Exposure Limit
Fla,n, Aerosol 1: Flammable aerosols, Hazard Category 1
Press. Gas: Gases under pressure: Compressed gas
Skin frrit. 2: Skin corrosion/irritation, Hazard Category 2
Carc. 2: Carcinogenicity, Hazard Category 2
Repr. 2: Reproductive toxicity, Hazard Category 2
STOTSE 3: Spec ific target organ toxicity Single exposure, Hazard Category 3
-

STOT RE 2: Spec (fic target organ toxicity Repeated exposure, Hazard Category 2
-

Asp. Tox. 1: Aspiration hazard. Hazard Categomy 1


• *
Data compared to the previous version altered.
4

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1 Identification
· Product identifier
· Trade name: 39101-LV; 39104-LV Flexible Bumper Coater
· Article number: 39101-LV, 39104-LV
· Relevant identified uses of the substance or mixture and uses advised against
No further relevant information available.
· Application of the substance / the mixture Coating
· Details of the supplier of the safety data sheet
· Manufacturer/Supplier:
SEM Products Inc.
1685 Overview Drive
Rock Hill, SC 29730
803 207 8225
· Information department:
[email protected] : SEM Products,Inc. 1685 Overview Dr. Rock Hill, SC 29730 : phone 1-800-831-
1122, M - TH 7am - 4pm EDT
· Emergency telephone number: CHEMTREC 1-800-424-9300

* 2 Hazard(s) identification
· Classification of the substance or mixture

GHS02 Flame

Flam. Liq. 2 H225 Highly flammable liquid and vapor.

GHS08 Health hazard

Carc. 2 H351 Suspected of causing cancer.


Repr. 2 H361 Suspected of damaging fertility or the unborn child.
STOT RE 2 H373 May cause damage to organs through prolonged or repeated exposure.

GHS07

Skin Irrit. 2 H315 Causes skin irritation.


Eye Irrit. 2A H319 Causes serious eye irritation.
STOT SE 3 H335-H336 May cause respiratory irritation. May cause drowsiness or dizziness.
· Label elements
· GHS label elements The product is classified and labeled according to the Globally Harmonized System (GHS).
· Hazard pictograms

GHS02 GHS07 GHS08

· Signal word Danger


(Contd. on page 2)
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(Contd. of page 1)

· Hazard-determining components of labeling:


acetone
toluene
Carbon black
4-chloro-alpha,alpha,alpha-trifluorotoluene
· Hazard statements
H225 Highly flammable liquid and vapor.
H315 Causes skin irritation.
H319 Causes serious eye irritation.
H351 Suspected of causing cancer.
H361 Suspected of damaging fertility or the unborn child.
H335-H336 May cause respiratory irritation. May cause drowsiness or dizziness.
H373 May cause damage to organs through prolonged or repeated exposure.
· Precautionary statements
P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking.
P241 Use explosion-proof electrical/ventilating/lighting/equipment.
P260 Do not breathe dust/fume/gas/mist/vapors/spray.
P280 Wear protective gloves / eye protection / face protection.
P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin
with water/shower.
P305+P351+P338 If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present
and easy to do. Continue rinsing.
P321 Specific treatment (see on this label).
P405 Store locked up.
P501 Dispose of contents/container in accordance with local/regional/national/international
regulations.
· Hazard description:
· WHMIS-symbols:
B2 - Flammable liquid
D2A - Very toxic material causing other toxic effects

· Classification system:
· NFPA ratings (scale 0 - 4)
Health = 1
3 Fire = 3
1 0 Reactivity = 0
· HMIS-ratings (scale 0 - 4)
HEALTH *1 Health = *1
FIRE 3 Fire = 3
REACTIVITY 0 Reactivity = 0
· Other hazards
· Results of PBT and vPvB assessment
· PBT: Not applicable.
(Contd. on page 3)
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(Contd. of page 2)
· vPvB: Not applicable.

* 3 Composition/information on ingredients
· Chemical characterization: Mixtures
· Description:
Mixture: consisting of the following components.
Weight percentages
· Dangerous components:
67-64-1 acetone 15-40%
98-56-6 4-chloro-alpha,alpha,alpha-trifluorotoluene 10-30%
108-88-3 toluene 3-7%
37244-96-5 NEPHELINE SYENITE 1-5%
NJ TSRN: 8009285004 Polyester Plasticizer 1-5%
1333-86-4 Carbon black 1-5%
108-65-6 2-methoxy-1-methylethyl acetate 1-5%
2807-30-9 2-(propyloxy)ethanol 1-5%
67-56-1 methanol ≤ 1%

4 First-aid measures
· Description of first aid measures
· After inhalation: In case of unconsciousness place patient stably in side position for transportation.
· After skin contact: Immediately wash with water and soap and rinse thoroughly.
· After eye contact:
Rinse opened eye for several minutes under running water. If symptoms persist, consult a doctor.
· After swallowing: If symptoms persist consult doctor.
· Information for doctor:
· Most important symptoms and effects, both acute and delayed No further relevant information available.
· Indication of any immediate medical attention and special treatment needed
No further relevant information available.

5 Fire-fighting measures
· Extinguishing media
· Suitable extinguishing agents: CO2, sand, extinguishing powder. Do not use water.
· For safety reasons unsuitable extinguishing agents: Water with full jet
· Special hazards arising from the substance or mixture No further relevant information available.
· Advice for firefighters
· Protective equipment: No special measures required.

6 Accidental release measures


· Personal precautions, protective equipment and emergency procedures
Wear protective equipment. Keep unprotected persons away.
· Environmental precautions: Do not allow to enter sewers/ surface or ground water.
(Contd. on page 4)
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(Contd. of page 3)
· Methods and material for containment and cleaning up:
Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).
Dispose contaminated material as waste according to item 13.
Ensure adequate ventilation.
Do not flush with water or aqueous cleansing agents
· Reference to other sections
See Section 7 for information on safe handling.
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information.

7 Handling and storage


· Handling:
· Precautions for safe handling
No special measures required.
Ensure good ventilation/exhaustion at the workplace.
Prevent formation of aerosols.
· Information about protection against explosions and fires:
Keep ignition sources away - Do not smoke.
Protect against electrostatic charges.
· Conditions for safe storage, including any incompatibilities
· Storage:
· Requirements to be met by storerooms and receptacles: Store in a cool location.
· Information about storage in one common storage facility: Not required.
· Further information about storage conditions:
Keep receptacle tightly sealed.
Store in cool, dry conditions in well sealed receptacles.
· Specific end use(s) No further relevant information available.

* 8 Exposure controls/personal protection


· Additional information about design of technical systems: No further data; see item 7.
· Control parameters
· Components with limit values that require monitoring at the workplace:
67-64-1 acetone
EL Short-term value: 500 ppm
Long-term value: 250 ppm
EV Short-term value: 750 ppm
Long-term value: 500 ppm
108-88-3 toluene
EL Long-term value: 20 ppm
R
EV Long-term value: 20 ppm
1333-86-4 Carbon black
EL Long-term value: 3 mg/m³
IARC 2B
EV Long-term value: 3.5 mg/m³
(Contd. on page 5)
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(Contd. of page 4)
108-65-6 2-methoxy-1-methylethyl acetate
EL Short-term value: 75 ppm
Long-term value: 50 ppm
EV Long-term value: 270 mg/m³, 50 ppm
2807-30-9 2-(propyloxy)ethanol
EV Long-term value: 110 mg/m³, 25 ppm
Skin
67-56-1 methanol
EL Short-term value: 250 ppm
Long-term value: 200 ppm
Skin
EV Short-term value: 325 mg/m³, 250 ppm
Long-term value: 260 mg/m³, 200 ppm
Skin
· Additional information: The lists that were valid during the creation were used as basis.
· Exposure controls
· Personal protective equipment:
· General protective and hygienic measures:
Keep away from foodstuffs, beverages and feed.
Immediately remove all soiled and contaminated clothing.
Wash hands before breaks and at the end of work.
Avoid contact with the eyes and skin.
· Breathing equipment:
In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer exposure use
respiratory protective device that is independent of circulating air.
· Protection of hands:
Due to missing tests no recommendation to the glove material can be given for the product/ the preparation/ the
chemical mixture.
Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation

Protective gloves

The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.
· Material of gloves
The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and
varies from manufacturer to manufacturer. As the product is a preparation of several substances, the resistance
of the glove material can not be calculated in advance and has therefore to be checked prior to the application.
· Penetration time of glove material
The exact break trough time has to be found out by the manufacturer of the protective gloves and has to be
observed.
(Contd. on page 6)
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(Contd. of page 5)
· Eye protection:

Tightly sealed goggles

* 9 Physical and chemical properties


· Information on basic physical and chemical properties
· General Information
· Appearance:
Form: Liquid
Color: According to product specification
· Odor: Characteristic
· Odour threshold: Not determined.
· pH-value: Not determined.
· Change in condition
Melting point/Melting range: Undetermined.
Boiling point/Boiling range: 40 °C
· Flash point: -18 °C
· Flammability (solid, gaseous): Not applicable.
· Ignition temperature: 465 °C
· Decomposition temperature: Not determined.
· Auto igniting: Product is not selfigniting.
· Danger of explosion: In use, may form flammable/explosive vapour-air mixture.
· Explosion limits:
Lower: 2.6 Vol %
Upper: 13.0 Vol %
· Vapor pressure at 20 °C: 233 hPa
· Density at 20 °C: 1.02 g/cm³
· Relative density Not determined.
· Vapour density Not determined.
· Evaporation rate Not determined.
· Solubility in / Miscibility with
Water: Not miscible or difficult to mix.
· Partition coefficient (n-octanol/water): Not determined.
· Viscosity:
Dynamic: Not determined.
Kinematic: Not determined.
· Solvent content:
Organic solvents: 74.8 %
(Contd. on page 7)
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(Contd. of page 6)

VOC content: 10.4 %


299.1 g/l / 2.50 lb/gl
Solids content: 25.3 %
· Other information No further relevant information available.

10 Stability and reactivity


· Reactivity
· Chemical stability
· Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications.
· Possibility of hazardous reactions No dangerous reactions known.
· Conditions to avoid No further relevant information available.
· Incompatible materials: No further relevant information available.
· Hazardous decomposition products: No dangerous decomposition products known.

11 Toxicological information
· Information on toxicological effects
· Acute toxicity:
· LD/LC50 values that are relevant for classification:
108-88-3 toluene
Oral LD50 5000 mg/kg (rat)
Dermal LD50 12124 mg/kg (rabbit)
Inhalative LC50/4 h 5320 mg/l (mouse)
· Primary irritant effect:
· on the skin: Irritant to skin and mucous membranes.
· on the eye: Irritating effect.
· Sensitization: No sensitizing effects known.
· Additional toxicological information:
The product shows the following dangers according to internally approved calculation methods for preparations:
Irritant
· Carcinogenic categories
· IARC (International Agency for Research on Cancer)
108-88-3 toluene 3
1333-86-4 Carbon black 2B
· NTP (National Toxicology Program)
None of the ingredients is listed.
· OSHA-Ca (Occupational Safety & Health Administration)
68911-87-5 ALKYL QUATERNARY AMMONIUM MONTMORILLONITE

12 Ecological information
· Toxicity
· Aquatic toxicity: No further relevant information available.
(Contd. on page 8)
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(Contd. of page 7)
· Persistence and degradability No further relevant information available.
· Behavior in environmental systems:
· Bioaccumulative potential No further relevant information available.
· Mobility in soil No further relevant information available.
· Additional ecological information:
· General notes:
Water hazard class 2 (Self-assessment): hazardous for water
Do not allow product to reach ground water, water course or sewage system.
Danger to drinking water if even small quantities leak into the ground.
· Results of PBT and vPvB assessment
· PBT: Not applicable.
· vPvB: Not applicable.
· Other adverse effects No further relevant information available.

13 Disposal considerations
· Waste treatment methods
· Recommendation:
Must not be disposed of together with household garbage. Do not allow product to reach sewage system.
· Uncleaned packagings:
· Recommendation: Disposal must be made according to official regulations.

* 14 Transport information
· UN-Number
· DOT, TDG, IMDG, IATA UN1263
· UN proper shipping name
· DOT Paint
· TDG 1263 Paint, special provision 640D
· IMDG, IATA PAINT
· Transport hazard class(es)
· DOT

· Class 3 Flammable liquids


· Label 3
· TDG, IMDG, IATA

· Class 3 Flammable liquids


· Label 3
(Contd. on page 9)
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(Contd. of page 8)

· Packing group
· DOT, TDG, IMDG, IATA II
· Environmental hazards:
· Marine pollutant: No
· Special precautions for user Warning: Flammable liquids
· EMS Number: F-E,S-E
· Transport in bulk according to Annex II of
MARPOL73/78 and the IBC Code Not applicable.
· Transport/Additional information:
· DOT
· Quantity limitations On passenger aircraft/rail: 5 L
On cargo aircraft only: 60 L
· TDG
· Excepted quantities (EQ) Code: E2
Maximum net quantity per inner packaging: 30 ml
Maximum net quantity per outer packaging: 500 ml
· IMDG
· Limited quantities (LQ) 5L
· Excepted quantities (EQ) Code: E2
Maximum net quantity per inner packaging: 30 ml
Maximum net quantity per outer packaging: 500 ml
· UN "Model Regulation": UN1263, Paint, special provision 640D, 3, II

* 15 Regulatory information
· Safety, health and environmental regulations/legislation specific for the substance or mixture
· Sara
· Section 355 (extremely hazardous substances):
None of the ingredient is listed.
· Section 313 (Specific toxic chemical listings):
ACRYLIC RESIN
108-88-3 toluene
67-56-1 methanol
· TSCA (Toxic Substances Control Act):
67-64-1 acetone
98-56-6 4-chloro-alpha,alpha,alpha-trifluorotoluene
108-88-3 toluene
1333-86-4 Carbon black
108-65-6 2-methoxy-1-methylethyl acetate
2807-30-9 2-(propyloxy)ethanol
68911-87-5 ALKYL QUATERNARY AMMONIUM MONTMORILLONITE
67-56-1 methanol
(Contd. on page 10)
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Trade name: 39101-LV; 39104-LV Flexible Bumper Coater

(Contd. of page 9)
7732-18-5 water, distilled, conductivity or of similar purity
· Proposition 65
· Chemicals known to cause cancer:
1333-86-4 Carbon black
· Chemicals known to cause reproductive toxicity for females:
108-88-3 toluene
· Chemicals known to cause reproductive toxicity for males:
None of the ingredients is listed.
· Chemicals known to cause developmental toxicity:
108-88-3 toluene
67-56-1 methanol
· Cancerogenity categories
· EPA (Environmental Protection Agency)
67-64-1 acetone I
108-88-3 toluene II
· TLV (Threshold Limit Value established by ACGIH)
67-64-1 acetone A4
108-88-3 toluene A4
1333-86-4 Carbon black A4
· NIOSH-Ca (National Institute for Occupational Safety and Health)
1333-86-4 Carbon black
67-56-1 methanol
· Canadian substance listings:
· Canadian Domestic Substances List (DSL)
67-64-1 acetone
98-56-6 4-chloro-alpha,alpha,alpha-trifluorotoluene
108-88-3 toluene
37244-96-5 NEPHELINE SYENITE
1333-86-4 Carbon black
108-65-6 2-methoxy-1-methylethyl acetate
2807-30-9 2-(propyloxy)ethanol
68911-87-5 ALKYL QUATERNARY AMMONIUM MONTMORILLONITE
67-56-1 methanol
7732-18-5 water, distilled, conductivity or of similar purity
· Canadian Ingredient Disclosure list (limit 0.1%)
None of the ingredients is listed.
· Canadian Ingredient Disclosure list (limit 1%)
67-64-1 acetone
108-88-3 toluene
1333-86-4 Carbon black
· GHS label elements The product is classified and labeled according to the Globally Harmonized System (GHS).
(Contd. on page 11)
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Trade name: 39101-LV; 39104-LV Flexible Bumper Coater

(Contd. of page 10)


· Hazard pictograms

GHS02 GHS07 GHS08

· Signal word Danger


· Hazard-determining components of labeling:
acetone
toluene
Carbon black
4-chloro-alpha,alpha,alpha-trifluorotoluene
· Hazard statements
H225 Highly flammable liquid and vapor.
H315 Causes skin irritation.
H319 Causes serious eye irritation.
H351 Suspected of causing cancer.
H361 Suspected of damaging fertility or the unborn child.
H335-H336 May cause respiratory irritation. May cause drowsiness or dizziness.
H373 May cause damage to organs through prolonged or repeated exposure.
· Precautionary statements
P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking.
P241 Use explosion-proof electrical/ventilating/lighting/equipment.
P260 Do not breathe dust/fume/gas/mist/vapors/spray.
P280 Wear protective gloves / eye protection / face protection.
P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin
with water/shower.
P305+P351+P338 If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present
and easy to do. Continue rinsing.
P321 Specific treatment (see on this label).
P405 Store locked up.
P501 Dispose of contents/container in accordance with local/regional/national/international
regulations.
· Chemical safety assessment: A Chemical Safety Assessment has not been carried out.

16 Other information
This information is based on our present knowledge. However, this shall not constitute a guarantee for any
specific product features and shall not establish a legally valid contractual relationship.
· Department issuing MSDS: Environment protection department.
· Contact: Steve Gaver ([email protected])
· Date of preparation / last revision 02/17/2015 / 1
· Abbreviations and acronyms:
ICAO: International Civil Aviation Organisation
IMDG: International Maritime Code for Dangerous Goods
DOT: US Department of Transportation
IATA: International Air Transport Association
ACGIH: American Conference of Governmental Industrial Hygienists
EINECS: European Inventory of Existing Commercial Chemical Substances
ELINCS: European List of Notified Chemical Substances
CAS: Chemical Abstracts Service (division of the American Chemical Society)
NFPA: National Fire Protection Association (USA)
(Contd. on page 12)
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Trade name: 39101-LV; 39104-LV Flexible Bumper Coater

(Contd. of page 11)


HMIS: Hazardous Materials Identification System (USA)
WHMIS: Workplace Hazardous Materials Information System (Canada)
VOC: Volatile Organic Compounds (USA, EU)
LC50: Lethal concentration, 50 percent
LD50: Lethal dose, 50 percent
Flam. Liq. 2: Flammable liquids, Hazard Category 2
Skin Irrit. 2: Skin corrosion/irritation, Hazard Category 2
Eye Irrit. 2A: Serious eye damage/eye irritation, Hazard Category 2A
Carc. 2: Carcinogenicity, Hazard Category 2
Repr. 2: Reproductive toxicity, Hazard Category 2
STOT SE 3: Specific target organ toxicity - Single exposure, Hazard Category 3
STOT RE 2: Specific target organ toxicity - Repeated exposure, Hazard Category 2
· * Data compared to the previous version altered.
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1 Identification
· Product identifier
· Trade name: 39143 Trim Black
· Article number: 39143
· Application of the substance / the mixture Coating
· Details of the supplier of the safety data sheet
· Manufacturer/Supplier:
SEM Products Inc.
1685 Overview Drive
Rock Hill, SC 29730
803 207 8225
· Information department:
[email protected] : SEM Products,Inc. 1685 Overview Dr. Rock Hill, SC 29730 : phone 1-800-831-
1122, M - TH 7am - 4pm EDT
· Emergency telephone number: CHEMTREC 1-800-424-9300

* 2 Hazard identification
· Classification of the substance or mixture

GHS02 GHS04 Flame, Gas cylinder

Flammable Aerosols - Category 1 H222 Extremely flammable aerosol.

GHS04 Gas cylinder

Gases Under Pressure - Compressed Gas H280 Contains gas under pressure; may
explode if heated.

GHS08 Health hazard

Carcinogenicity – Category 2 H351 Suspected of causing cancer.


Reproductive Toxicity - Category 2 H361-H362 Suspected of damaging fertility or the
unborn child. May cause harm to breast-
fed children.
Specific Target Organ Toxicity - Repeated Exposure - H373 May cause damage to organs through
Category 2 prolonged or repeated exposure.
Aspiration Hazard - Category 1 H304 May be fatal if swallowed and enters
airways.

GHS07

Skin Irritation - Category 2 H315 Causes skin irritation.


Eye Irritation - Category 2A H319 Causes serious eye irritation.
Specific Target Organ Toxicity - Single Exposure - H336 May cause drowsiness or dizziness.
Category 3
(Contd. on page 2)
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(Contd. of page 1)

· Label elements
· GHS label elements The product is classified and labeled according to the Globally Harmonized System (GHS).
· Hazard pictograms

GHS02 GHS04 GHS07 GHS08

· Signal word Danger


· Hazard-determining components of labeling:
toluene
acetone
butanone
n-butyl acetate
· Hazard statements
H222 Extremely flammable aerosol.
H280 Contains gas under pressure; may explode if heated.
H315 Causes skin irritation.
H319 Causes serious eye irritation.
H351 Suspected of causing cancer.
H361-H362 Suspected of damaging fertility or the unborn child. May cause harm to breast-fed children.
H336 May cause drowsiness or dizziness.
H373 May cause damage to organs through prolonged or repeated exposure.
H304 May be fatal if swallowed and enters airways.
· Precautionary statements
P263 Avoid contact during pregnancy and while nursing.
P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No
smoking.
P251 Do not pierce or burn, even after use.
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P211 Do not spray on an open flame or other ignition source.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P264 Wash thoroughly after handling.
P270 Do not eat, drink or smoke when using this product.
P271 Use only outdoors or in a well-ventilated area.
P201 Obtain special instructions before use.
P202 Do not handle until all safety precautions have been read and understood.
P301+P310 IF SWALLOWED: Immediately call a POISON CENTER/ doctor.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if
present and easy to do. Continue rinsing.
P321 Specific treatment (see on this label).
P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P312 Call a POISON CENTER/doctor if you feel unwell.
P308+P313 IF exposed or concerned: Get medical advice/attention.
P337+P313 If eye irritation persists: Get medical advice/attention.
P314 Get medical advice/attention if you feel unwell.
P331 Do NOT induce vomiting.
P302+P352 IF ON SKIN: Wash with plenty of water.
P362+P364 Take off contaminated clothing and wash it before reuse.
P405 Store locked up.
(Contd. on page 3)
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(Contd. of page 2)
P410+P403 Protect from sunlight. Store in a well-ventilated place.
P410+P412 Protect from sunlight. Do not expose to temperatures exceeding 50 °C/122 °F.
P403+P233 Store in a well-ventilated place. Keep container tightly closed.
P501 Dispose of contents/container in accordance with local/regional/national/international
regulations.
· Classification system:
· NFPA ratings (scale 0 - 4)
Health = 1
4 Fire = 4
1 3 Reactivity = 3
· HMIS-ratings (scale 0 - 4)
HEALTH *1 Health = *1
FIRE 4 Fire = 4
REACTIVITY 3 Reactivity = 3
· Other hazards
· Results of PBT and vPvB assessment
· PBT: Not applicable.
· vPvB: Not applicable.

* 3 Composition/Information on ingredients
· Chemical characterization: Mixtures
· Description:
Mixture: consisting of the following components.
Weight percentages
· Dangerous components:
67-64-1 acetone 15-40% w/w
68476-86-8 Petroleum gases, liquefied, sweetened 10-30% w/w
108-88-3 toluene 10-30% w/w
110-19-0 isobutyl acetate 5-10% w/w
1330-20-7 xylene 1-5% w/w
78-93-3 butanone 1-5% w/w
123-86-4 n-butyl acetate 0.5-1.5% w/w
1333-86-4 Carbon black ≤ 1% w/w

* 4 First aid measures


· Description of first aid measures
· General information: Immediately remove any clothing soiled by the product.
· After inhalation: In case of unconsciousness place patient stably in side position for transportation.
· After skin contact: Immediately wash with water and soap and rinse thoroughly.
· After eye contact:
Rinse opened eye for several minutes under running water. If symptoms persist, consult a doctor.
· After swallowing: If symptoms persist consult doctor.
(Contd. on page 4)
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(Contd. of page 3)
· Information for doctor:
· Most important symptoms and effects, both acute and delayed No further relevant information available.
· Indication of any immediate medical attention and special treatment needed
No further relevant information available.

* 5 Firefighting measures
· Extinguishing media
· Suitable extinguishing agents:
CO2, extinguishing powder or water spray. Fight larger fires with water spray or alcohol resistant foam.
· Special hazards arising from the substance or mixture
During heating or in case of fire poisonous gases are produced.
· Advice for firefighters
· Protective equipment: Mouth respiratory protective device.

* 6 Accidental release measures


· Personal precautions, protective equipment and emergency procedures
Mount respiratory protective device.
Wear protective equipment. Keep unprotected persons away.
· Environmental precautions: Do not allow to enter sewers/ surface or ground water.
· Methods and material for containment and cleaning up:
Dispose contaminated material as waste according to item 13.
Ensure adequate ventilation.
· Reference to other sections
See Section 7 for information on safe handling.
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information.

* 7 Handling and storage


· Handling:
· Precautions for safe handling
No special measures required.
Ensure good ventilation/exhaustion at the workplace.
Open and handle receptacle with care.
· Information about protection against explosions and fires:
Do not spray on a naked flame or any incandescent material.
Keep ignition sources away - Do not smoke.
Keep respiratory protective device available.
Pressurized container: protect from sunlight and do not expose to temperatures exceeding 50 °C, i.e. electric
lights. Do not pierce or burn, even after use.
· Conditions for safe storage, including any incompatibilities
· Storage:
· Requirements to be met by storerooms and receptacles:
Observe official regulations on storing packagings with pressurized containers.
· Information about storage in one common storage facility: Not required.
· Further information about storage conditions: Keep receptacle tightly sealed.
(Contd. on page 5)
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(Contd. of page 4)
· Specific end use(s) No further relevant information available.

* 8 Exposure controls/ Personal protection


· Additional information about design of technical systems: No further data; see item 7.
· Control parameters
· Components with limit values that require monitoring at the workplace:
67-64-1 acetone
EL Short-term value: 500 ppm
Long-term value: 250 ppm
EV Short-term value: 750 ppm
Long-term value: 500 ppm
108-88-3 toluene
EL Long-term value: 20 ppm
R
EV Long-term value: 20 ppm
110-19-0 isobutyl acetate
EL Long-term value: 150 ppm
EV Short-term value: 187 ppm
Long-term value: 150 ppm
1330-20-7 xylene
EL Short-term value: 150 ppm
Long-term value: 100 ppm
EV Short-term value: 650 mg/m³, 150 ppm
Long-term value: 435 mg/m³, 100 ppm
78-93-3 butanone
EL Short-term value: 100 ppm
Long-term value: 50 ppm
EV Short-term value: 885 mg/m³, 300 ppm
Long-term value: 590 mg/m³, 200 ppm
123-86-4 n-butyl acetate
EL Long-term value: 20 ppm
EV Short-term value: 950 mg/m³, 200 ppm
Long-term value: 710 mg/m³, 150 ppm
· Additional information: The lists that were valid during the creation were used as basis.
· Exposure controls
· Personal protective equipment:
· General protective and hygienic measures:
Keep away from foodstuffs, beverages and feed.
Immediately remove all soiled and contaminated clothing.
Wash hands before breaks and at the end of work.
Store protective clothing separately.
Avoid contact with the eyes and skin.
· Breathing equipment:
In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer exposure use
respiratory protective device that is independent of circulating air.
(Contd. on page 6)
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(Contd. of page 5)
· Protection of hands:
Due to missing tests no recommendation to the glove material can be given for the product/ the preparation/ the
chemical mixture.
Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation

Protective gloves

The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.
· Material of gloves
The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and
varies from manufacturer to manufacturer. As the product is a preparation of several substances, the resistance
of the glove material can not be calculated in advance and has therefore to be checked prior to the application.
· Penetration time of glove material
The exact break trough time has to be found out by the manufacturer of the protective gloves and has to be
observed.
· Eye protection:
Safety glasses

Tightly sealed goggles

* 9 Physical and chemical properties


· Information on basic physical and chemical properties
· General Information
· Appearance:
Form: Aerosol
Color: According to product specification
· Odor: Characteristic
· Odor threshold: Not determined.
· pH-value: Not determined.
· Change in condition
Melting point/Melting range: Undetermined.
Boiling point/Boiling range: 55 °C
· Flash point: -103 °C
· Flammability (solid, gaseous): Not applicable.
· Ignition temperature: 405 °C
· Decomposition temperature: Not determined.
· Auto igniting: Product is not selfigniting.
· Danger of explosion: In use, may form flammable/explosive vapour-air mixture.
· Explosion limits:
Lower: 1.2 Vol %
Upper: 13.0 Vol %
(Contd. on page 7)
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(Contd. of page 6)

· Vapor pressure at 20 °C: 233 hPa


· Density at 20 °C: 0.74763 g/cm³
· Relative density Not determined.
· Vapor density Not determined.
· Evaporation rate Not applicable.
· Solubility in / Miscibility with
Water: Not miscible or difficult to mix.
· Partition coefficient (n-octanol/water): Not determined.
· Viscosity:
Dynamic: Not determined.
Kinematic: Not determined.
· Solvent content:
Organic solvents: 92.0 %
VOC content: 60.7 %
645.1 g/l / 5.38 lb/gl
Solids content: 7.9 %
· Other information No further relevant information available.

10 Stability and reactivity


· Reactivity No further relevant information available.
· Chemical stability
· Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications.
· Possibility of hazardous reactions No dangerous reactions known.
· Conditions to avoid No further relevant information available.
· Incompatible materials: No further relevant information available.
· Hazardous decomposition products: No dangerous decomposition products known.

* 11 Toxicological information
· Information on toxicological effects
· Acute toxicity:
· LD/LC50 values that are relevant for classification:
108-88-3 toluene
Oral LD50 5000 mg/kg (rat)
Dermal LD50 12124 mg/kg (rabbit)
Inhalative LC50/4 h 5320 mg/l (mouse)
· Primary irritant effect:
· on the skin: Irritant to skin and mucous membranes.
· on the eye: Irritating effect.
· Sensitization: No sensitizing effects known.
· Additional toxicological information:
The product shows the following dangers according to internally approved calculation methods for preparations:
Irritant
(Contd. on page 8)
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(Contd. of page 7)

· Carcinogenic categories
· IARC (International Agency for Research on Cancer)
108-88-3 toluene 3
1330-20-7 xylene 3
1333-86-4 Carbon black 2B
111-76-2 2-butoxyethanol 3
68855-54-9 diatomaceous earth GROUP 1
9002-88-4 POLYETHYLENE 3
100-41-4 ethylbenzene 2B
· NTP (National Toxicology Program)
68855-54-9 diatomaceous earth HUMAN CARCINOGEN
· OSHA-Ca (Occupational Safety & Health Administration)
None of the ingredients is listed.

12 Ecological information
· Toxicity
· Aquatic toxicity: No further relevant information available.
· Persistence and degradability No further relevant information available.
· Behavior in environmental systems:
· Bioaccumulative potential No further relevant information available.
· Mobility in soil No further relevant information available.
· Additional ecological information:
· General notes:
Do not allow product to reach ground water, water course or sewage system, even in small quantities.
Danger to drinking water if even extremely small quantities leak into the ground.
· Results of PBT and vPvB assessment
· PBT: Not applicable.
· vPvB: Not applicable.
· Other adverse effects No further relevant information available.

13 Disposal considerations
· Waste treatment methods
· Recommendation:
Must not be disposed of together with household garbage. Do not allow product to reach sewage system.
· Uncleaned packagings:
· Recommendation: Disposal must be made according to official regulations.

* 14 Transport information
· UN-Number
· DOT, TDG, IMDG, IATA UN1950
(Contd. on page 9)
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(Contd. of page 8)

· UN proper shipping name


· DOT, IATA Aerosols, flammable
· TDG 1950 Aerosols
· IMDG AEROSOLS
· Transport hazard class(es)
· DOT

· Class 2.1
· Label 2.1
· TDG (Transport dangerous goods):

· Class 2 5F Gases
· Label 2.1
· IMDG, IATA

· Class 2.1
· Label 2.1
· Packing group
· DOT, TDG, IMDG, IATA Void
· Environmental hazards:
· Marine pollutant: No
· Special precautions for user Warning: Gases
· EMS Number: F-D,S-U
· Stowage Code SW1 Protected from sources of heat.
SW22 For AEROSOLS with a maximum capacity of 1 litre:
Category A. For AEROSOLS with a capacity above 1 litre:
Category B. For WASTE AEROSOLS: Category C, Clear of living
quarters.
· Segregation Code SG69 For AEROSOLS with a maximum capacity of 1 litre:
Segregation as for class 9. Stow "separated from" class 1 except for
division 1.4. For AEROSOLS with a capacity above 1 litre:
Segregation as for the appropriate subdivision of class 2. For
WASTE AEROSOLS: Segregation as for the appropriate subdivision
of class 2.
· Transport in bulk according to Annex II of
MARPOL73/78 and the IBC Code Not applicable.
(Contd. on page 10)
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(Contd. of page 9)

· Transport/Additional information:
· DOT
· Quantity limitations On passenger aircraft/rail: 75 kg
On cargo aircraft only: 150 kg
· TDG
· Excepted quantities (EQ) Code: E0
Not permitted as Excepted Quantity
· IMDG
· Limited quantities (LQ) 1L
· Excepted quantities (EQ) Code: E0
Not permitted as Excepted Quantity
· UN "Model Regulation": UN 1950 AEROSOLS, 2.1

* 15 Regulatory information
· Safety, health and environmental regulations/legislation specific for the substance or mixture
· Sara
· Section 355 (extremely hazardous substances):
None of the ingredient is listed.
· Section 313 (Specific toxic chemical listings):
108-88-3 toluene
ACRYLIC RESIN
1330-20-7 xylene
78-93-3 butanone
111-76-2 2-butoxyethanol
67-56-1 methanol
100-41-4 ethylbenzene
· TSCA (Toxic Substances Control Act):
67-64-1 acetone
68476-86-8 Petroleum gases, liquefied, sweetened
108-88-3 toluene
110-19-0 isobutyl acetate
1330-20-7 xylene
78-93-3 butanone
123-86-4 n-butyl acetate
16883-83-3 benzyl 3-isobutryloxy-1-isopropyl-2-2-dimethylpropyl phthalate
1333-86-4 Carbon black
68611-44-9 Modified Silica
111-76-2 2-butoxyethanol
68855-54-9 diatomaceous earth
9002-88-4 POLYETHYLENE
(Contd. on page 11)
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(Contd. of page 10)


67-56-1 methanol
100-41-4 ethylbenzene
· Proposition 65
· Chemicals known to cause cancer:
1330-20-7 xylene
1333-86-4 Carbon black
68855-54-9 diatomaceous earth
100-41-4 ethylbenzene
· Chemicals known to cause reproductive toxicity for females:
108-88-3 toluene
· Chemicals known to cause reproductive toxicity for males:
None of the ingredients is listed.
· Chemicals known to cause developmental toxicity:
108-88-3 toluene
67-56-1 methanol
· Cancerogenity categories
· EPA (Environmental Protection Agency)
67-64-1 acetone I
108-88-3 toluene II
1330-20-7 xylene I
78-93-3 butanone I
111-76-2 2-butoxyethanol NL
100-41-4 ethylbenzene D
· TLV (Threshold Limit Value established by ACGIH)
67-64-1 acetone A4
108-88-3 toluene A4
1330-20-7 xylene A4
1333-86-4 Carbon black A4
111-76-2 2-butoxyethanol A3
100-41-4 ethylbenzene A3
· NIOSH-Ca (National Institute for Occupational Safety and Health)
1333-86-4 Carbon black
67-56-1 methanol
· Canadian substance listings:
· Canadian Domestic Substances List (DSL)
67-64-1 acetone
68476-86-8 Petroleum gases, liquefied, sweetened
108-88-3 toluene
110-19-0 isobutyl acetate
1330-20-7 xylene
78-93-3 butanone
123-86-4 n-butyl acetate
(Contd. on page 12)
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(Contd. of page 11)


16883-83-3 benzyl 3-isobutryloxy-1-isopropyl-2-2-dimethylpropyl phthalate
1333-86-4 Carbon black
68611-44-9 Modified Silica
111-76-2 2-butoxyethanol
68855-54-9 diatomaceous earth
9002-88-4 POLYETHYLENE
67-56-1 methanol
100-41-4 ethylbenzene
· Canadian Ingredient Disclosure list (limit 0.1%)
None of the ingredients is listed.
· Canadian Ingredient Disclosure list (limit 1%)
67-64-1 acetone
108-88-3 toluene
110-19-0 isobutyl acetate
78-93-3 butanone
123-86-4 n-butyl acetate
· GHS label elements The product is classified and labeled according to the Globally Harmonized System (GHS).
· Hazard pictograms

GHS02 GHS04 GHS07 GHS08

· Signal word Danger


· Hazard-determining components of labeling:
toluene
acetone
butanone
n-butyl acetate
· Hazard statements
H222 Extremely flammable aerosol.
H280 Contains gas under pressure; may explode if heated.
H315 Causes skin irritation.
H319 Causes serious eye irritation.
H351 Suspected of causing cancer.
H361-H362 Suspected of damaging fertility or the unborn child. May cause harm to breast-fed children.
H336 May cause drowsiness or dizziness.
H373 May cause damage to organs through prolonged or repeated exposure.
H304 May be fatal if swallowed and enters airways.
· Precautionary statements
P263 Avoid contact during pregnancy and while nursing.
P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No
smoking.
P251 Do not pierce or burn, even after use.
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P211 Do not spray on an open flame or other ignition source.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
(Contd. on page 13)
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according to HPR, Schedule 1
Printing date 02/22/2016 Reviewed on 02/04/2016

Trade name: 39143 Trim Black

(Contd. of page 12)


P264 Wash thoroughly after handling.
P270 Do not eat, drink or smoke when using this product.
P271 Use only outdoors or in a well-ventilated area.
P201 Obtain special instructions before use.
P202 Do not handle until all safety precautions have been read and understood.
P301+P310 IF SWALLOWED: Immediately call a POISON CENTER/ doctor.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if
present and easy to do. Continue rinsing.
P321 Specific treatment (see on this label).
P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P312 Call a POISON CENTER/doctor if you feel unwell.
P308+P313 IF exposed or concerned: Get medical advice/attention.
P337+P313 If eye irritation persists: Get medical advice/attention.
P314 Get medical advice/attention if you feel unwell.
P331 Do NOT induce vomiting.
P302+P352 IF ON SKIN: Wash with plenty of water.
P362+P364 Take off contaminated clothing and wash it before reuse.
P405 Store locked up.
P410+P403 Protect from sunlight. Store in a well-ventilated place.
P410+P412 Protect from sunlight. Do not expose to temperatures exceeding 50 °C/122 °F.
P403+P233 Store in a well-ventilated place. Keep container tightly closed.
P501 Dispose of contents/container in accordance with local/regional/national/international
regulations.
· Chemical safety assessment: A Chemical Safety Assessment has not been carried out.

16 Other information
This information is based on our present knowledge. However, this shall not constitute a guarantee for any
specific product features and shall not establish a legally valid contractual relationship.
· Department issuing SDS: Environment protection department.
· Contact: Steve Gaver ([email protected])
· Date of preparation / last revision 02/22/2016 / 8
· Abbreviations and acronyms:
ICAO: International Civil Aviation Organisation
IMDG: International Maritime Code for Dangerous Goods
DOT: US Department of Transportation
IATA: International Air Transport Association
ACGIH: American Conference of Governmental Industrial Hygienists
EINECS: European Inventory of Existing Commercial Chemical Substances
ELINCS: European List of Notified Chemical Substances
CAS: Chemical Abstracts Service (division of the American Chemical Society)
NFPA: National Fire Protection Association (USA)
HMIS: Hazardous Materials Identification System (USA)
VOC: Volatile Organic Compounds (USA, EU)
LC50: Lethal concentration, 50 percent
LD50: Lethal dose, 50 percent
PBT: Persistent, Bioaccumulative and Toxic
vPvB: very Persistent and very Bioaccumulative
NIOSH: National Institute for Occupational Safety
OSHA: Occupational Safety & Health
Flammable Aerosols - Category 1: Flammable aerosols, Hazard Category 1
Gases Under Pressure - Compressed Gas: Gases under pressure: Compressed gas
Skin Irritation - Category 2: Skin corrosion/irritation, Hazard Category 2
Eye Irritation - Category 2A: Serious eye damage/eye irritation, Hazard Category 2A
Carcinogenicity – Category 2: Carcinogenicity, Hazard Category 2
(Contd. on page 14)
CA

42.0.12
Page 14/14
Safety Data Sheet
according to HPR, Schedule 1
Printing date 02/22/2016 Reviewed on 02/04/2016

Trade name: 39143 Trim Black

(Contd. of page 13)


Reproductive Toxicity - Category 2: Reproductive toxicity, Hazard Category 2
Specific Target Organ Toxicity - Single Exposure - Category 3: Specific target organ toxicity - Single exposure, Hazard Category 3

Specific Target Organ Toxicity - Repeated Exposure - Category 2: Specific target organ toxicity - Repeated exposure, Hazard Category 2

Aspiration Hazard - Category 1: Aspiration hazard, Hazard Category 1


· * Data compared to the previous version altered.
CA

42.0.12
SAFETY DATA SHEET
P60170

Section 1. Identification
Product name : Acrysol™ High Performance Body Solvent!
Product code : P60170
Other means of : Not available.
identification
Product type : Aerosol.
Relevant identified uses of the substance or mixture and uses advised against
Not applicable.

Manufacturer : Kent Automotive


8770 W. Bryn Mawr Ave., Suite 900
Chicago, IL 60631-3515

Emergency telephone : (888) 426-4851


number of the company
Product Information : (888) 937-5368
Telephone Number
Regulatory Information : (216) 566-2902
Telephone Number
Transportation Emergency : (800) 424-9300
Telephone Number

Section 2. Hazards identification


OSHA/HCS status : This material is considered hazardous by the OSHA Hazard Communication Standard
(29 CFR 1910.1200).
Classification of the : FLAMMABLE AEROSOLS - Category 1
substance or mixture GASES UNDER PRESSURE - Compressed gas
ACUTE TOXICITY (inhalation) - Category 4
SKIN CORROSION/IRRITATION - Category 2
SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 2A
CARCINOGENICITY - Category 2
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Respiratory tract
irritation and Narcotic effects) - Category 3
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) - Category 2
ASPIRATION HAZARD - Category 1
Percentage of the mixture consisting of ingredient(s) of unknown toxicity: 68.8%
GHS label elements
Hazard pictograms :

Signal word : Danger

Date of issue/Date of revision : 3/6/2015. Date of previous issue : No previous validation. Version :1 1/13
Section 2. Hazards identification
Hazard statements : Extremely flammable aerosol.
Contains gas under pressure; may explode if heated.
Harmful if inhaled.
Causes serious eye irritation.
Causes skin irritation.
Suspected of causing cancer.
May be fatal if swallowed and enters airways.
May cause respiratory irritation.
May cause drowsiness and dizziness.
May cause damage to organs through prolonged or repeated exposure.
Precautionary statements
General : Read label before use. Keep out of reach of children. If medical advice is needed, have
product container or label at hand.
Prevention : Obtain special instructions before use. Do not handle until all safety precautions have
been read and understood. Use personal protective equipment as required. Wear
protective gloves. Wear eye or face protection. Keep away from heat, hot surfaces,
sparks, open flames and other ignition sources. No smoking. Pressurized container: Do
not pierce or burn, even after use. Do not spray on an open flame or other ignition
source. Use only outdoors or in a well-ventilated area. Do not breathe dust or mist.
Wash hands thoroughly after handling.
Response : Get medical attention if you feel unwell. IF exposed or concerned: Get medical
attention. IF INHALED: Remove victim to fresh air and keep at rest in a position
comfortable for breathing. Call a POISON CENTER or physician if you feel unwell. IF
SWALLOWED: Immediately call a POISON CENTER or physician. Do NOT induce
vomiting. IF ON SKIN: Wash with plenty of soap and water. Take off contaminated
clothing. Wash contaminated clothing before reuse. If skin irritation occurs: Get
medical attention. IF IN EYES: Rinse cautiously with water for several minutes.
Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation
persists: Get medical attention.
Storage : Store locked up. Protect from sunlight. Do not expose to temperatures exceeding 50
°C/122 °F. Store in a well-ventilated place.
Disposal Dispose of contents and container in accordance with all local, regional, national and
international regulations.
Supplemental label DELAYED EFFECTS FROM LONG TERM OVEREXPOSURE. Contains solvents which
elements can cause permanent brain and nervous system damage. Intentional misuse by
deliberately concentrating and inhaling the contents can be harmful or fatal. WARNING:
This product contains chemicals known to the State of California to cause cancer and
birth defects or other reproductive harm. FOR INDUSTRIAL USE ONLY.
Please refer to the SDS for additional information. Keep upright in a cool, dry place. Do
not discard empty can in trash compactor.
Hazards not otherwise : None known.
classified

Section 3. Composition/information on ingredients


Substance/mixture : Mixture
Other means of : Not available.
identification

CAS number/other identifiers


Ingredient name % by weight CAS number
Lt. Aliphatic Hydrocarbon Solvent 56.0 64742-89-8
Xylene 16.1 1330-20-7
Propane 12.8 74-98-6
Butane 12.3 106-97-8
Ethylbenzene 2.9 100-41-4

Date of issue/Date of revision : 3/6/2015. Date of previous issue : No previous validation. Version :1 2/13
Section 3. Composition/information on ingredients
There are no additional ingredients present which, within the current knowledge of the supplier and in the
concentrations applicable, are classified as hazardous to health or the environment and hence require reporting
in this section.
Occupational exposure limits, if available, are listed in Section 8.

Section 4. First aid measures


Description of necessary first aid measures
Eye contact : Immediately flush eyes with plenty of water, occasionally lifting the upper and lower
eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10
minutes. Get medical attention.
Inhalation : Remove victim to fresh air and keep at rest in a position comfortable for breathing. If it
is suspected that fumes are still present, the rescuer should wear an appropriate mask
or self-contained breathing apparatus. If not breathing, if breathing is irregular or if
respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It
may be dangerous to the person providing aid to give mouth-to-mouth resuscitation.
Get medical attention. If necessary, call a poison center or physician. If unconscious,
place in recovery position and get medical attention immediately. Maintain an open
airway. Loosen tight clothing such as a collar, tie, belt or waistband.
Skin contact : Flush contaminated skin with plenty of water. Remove contaminated clothing and
shoes. Continue to rinse for at least 10 minutes. Get medical attention. Wash clothing
before reuse. Clean shoes thoroughly before reuse.
Ingestion : Get medical attention immediately. Call a poison center or physician. Wash out mouth
with water. Remove dentures if any. Remove victim to fresh air and keep at rest in a
position comfortable for breathing. If material has been swallowed and the exposed
person is conscious, give small quantities of water to drink. Stop if the exposed person
feels sick as vomiting may be dangerous. Aspiration hazard if swallowed. Can enter
lungs and cause damage. Do not induce vomiting. If vomiting occurs, the head should
be kept low so that vomit does not enter the lungs. Never give anything by mouth to an
unconscious person. If unconscious, place in recovery position and get medical
attention immediately. Maintain an open airway. Loosen tight clothing such as a collar,
tie, belt or waistband.

Most important symptoms/effects, acute and delayed


Potential acute health effects
Eye contact : Causes serious eye irritation.
Inhalation : Harmful if inhaled. Can cause central nervous system (CNS) depression. May cause
drowsiness and dizziness. May cause respiratory irritation.
Skin contact : Causes skin irritation.
Ingestion : Can cause central nervous system (CNS) depression. May be fatal if swallowed and
enters airways. Irritating to mouth, throat and stomach.
Over-exposure signs/symptoms
Eye contact : Adverse symptoms may include the following:
pain or irritation
watering
redness
Inhalation : Adverse symptoms may include the following:
respiratory tract irritation
coughing
nausea or vomiting
headache
drowsiness/fatigue
dizziness/vertigo
unconsciousness

Date of issue/Date of revision : 3/6/2015. Date of previous issue : No previous validation. Version :1 3/13
Section 4. First aid measures
Skin contact : Adverse symptoms may include the following:
irritation
redness
Ingestion : Adverse symptoms may include the following:
nausea or vomiting

Indication of immediate medical attention and special treatment needed, if necessary


Notes to physician : Treat symptomatically. Contact poison treatment specialist immediately if large
quantities have been ingested or inhaled.
Specific treatments : No specific treatment.
Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. If it is
suspected that fumes are still present, the rescuer should wear an appropriate mask or
self-contained breathing apparatus. It may be dangerous to the person providing aid to
give mouth-to-mouth resuscitation.

See toxicological information (Section 11)

Section 5. Fire-fighting measures


Extinguishing media
Suitable extinguishing : Use an extinguishing agent suitable for the surrounding fire.
media
Unsuitable extinguishing : None known.
media

Specific hazards arising : Extremely flammable aerosol. In a fire or if heated, a pressure increase will occur and
from the chemical the container may burst, with the risk of a subsequent explosion. Gas may accumulate
in low or confined areas or travel a considerable distance to a source of ignition and
flash back, causing fire or explosion. Bursting aerosol containers may be propelled from
a fire at high speed. Runoff to sewer may create fire or explosion hazard.
Hazardous thermal : Decomposition products may include the following materials:
decomposition products carbon dioxide
carbon monoxide

Special protective actions : Promptly isolate the scene by removing all persons from the vicinity of the incident if
for fire-fighters there is a fire. No action shall be taken involving any personal risk or without suitable
training. Move containers from fire area if this can be done without risk. Use water
spray to keep fire-exposed containers cool.
Special protective : Fire-fighters should wear appropriate protective equipment and self-contained breathing
equipment for fire-fighters apparatus (SCBA) with a full face-piece operated in positive pressure mode.

Section 6. Accidental release measures


Personal precautions, protective equipment and emergency procedures
For non-emergency : No action shall be taken involving any personal risk or without suitable training.
personnel Evacuate surrounding areas. Keep unnecessary and unprotected personnel from
entering. In the case of aerosols being ruptured, care should be taken due to the rapid
escape of the pressurized contents and propellant. If a large number of containers are
ruptured, treat as a bulk material spillage according to the instructions in the clean-up
section. Do not touch or walk through spilled material. Shut off all ignition sources. No
flares, smoking or flames in hazard area. Avoid breathing vapor or mist. Provide
adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put
on appropriate personal protective equipment.
For emergency responders : If specialised clothing is required to deal with the spillage, take note of any information in
Section 8 on suitable and unsuitable materials. See also the information in "For non-
emergency personnel".

Date of issue/Date of revision : 3/6/2015. Date of previous issue : No previous validation. Version :1 4/13
Section 6. Accidental release measures

Environmental precautions : Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains
and sewers. Inform the relevant authorities if the product has caused environmental
pollution (sewers, waterways, soil or air).

Methods and materials for containment and cleaning up


Small spill : Stop leak if without risk. Move containers from spill area. Use spark-proof tools and
explosion-proof equipment. Dilute with water and mop up if water-soluble. Alternatively,
or if water-insoluble, absorb with an inert dry material and place in an appropriate waste
disposal container. Dispose of via a licensed waste disposal contractor.
Large spill : Stop leak if without risk. Move containers from spill area. Use spark-proof tools and
explosion-proof equipment. Approach release from upwind. Prevent entry into sewers,
water courses, basements or confined areas. Wash spillages into an effluent treatment
plant or proceed as follows. Contain and collect spillage with non-combustible,
absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in
container for disposal according to local regulations (see Section 13). Dispose of via a
licensed waste disposal contractor. Contaminated absorbent material may pose the
same hazard as the spilled product. Note: see Section 1 for emergency contact
information and Section 13 for waste disposal.

Section 7. Handling and storage


Precautions for safe handling
Protective measures : Put on appropriate personal protective equipment (see Section 8). Pressurized
container: protect from sunlight and do not expose to temperatures exceeding 50°C. Do
not pierce or burn, even after use. Avoid exposure - obtain special instructions before
use. Do not handle until all safety precautions have been read and understood. Do not
get in eyes or on skin or clothing. Do not breathe vapor or mist. Do not swallow. Avoid
breathing gas. Use only with adequate ventilation. Wear appropriate respirator when
ventilation is inadequate. Store and use away from heat, sparks, open flame or any
other ignition source. Use explosion-proof electrical (ventilating, lighting and material
handling) equipment. Use only non-sparking tools. Empty containers retain product
residue and can be hazardous.
Advice on general : Eating, drinking and smoking should be prohibited in areas where this material is
occupational hygiene handled, stored and processed. Workers should wash hands and face before eating,
drinking and smoking. Remove contaminated clothing and protective equipment before
entering eating areas. See also Section 8 for additional information on hygiene
measures.

Conditions for safe storage, : Store in accordance with local regulations. Store away from direct sunlight in a dry, cool
including any and well-ventilated area, away from incompatible materials (see Section 10) and food
incompatibilities and drink. Protect from sunlight. Store locked up. Eliminate all ignition sources. Use
appropriate containment to avoid environmental contamination.

Section 8. Exposure controls/personal protection


Control parameters
Occupational exposure limits
Ingredient name Exposure limits
Xylene ACGIH TLV (United States, 4/2014).
TWA: 100 ppm 8 hours.
TWA: 434 mg/m³ 8 hours.
STEL: 150 ppm 15 minutes.
STEL: 651 mg/m³ 15 minutes.
OSHA PEL (United States, 2/2013).
TWA: 100 ppm 8 hours.
TWA: 435 mg/m³ 8 hours.

Date of issue/Date of revision : 3/6/2015. Date of previous issue : No previous validation. Version :1 5/13
Section 8. Exposure controls/personal protection
Propane NIOSH REL (United States, 10/2013).
TWA: 1000 ppm 10 hours.
TWA: 1800 mg/m³ 10 hours.
OSHA PEL (United States, 2/2013).
TWA: 1000 ppm 8 hours.
TWA: 1800 mg/m³ 8 hours.
Butane NIOSH REL (United States, 10/2013).
TWA: 800 ppm 10 hours.
TWA: 1900 mg/m³ 10 hours.
ACGIH TLV (United States, 4/2014).
STEL: 1000 ppm 15 minutes.
Ethylbenzene ACGIH TLV (United States, 4/2014).
TWA: 20 ppm 8 hours.
NIOSH REL (United States, 10/2013).
TWA: 100 ppm 10 hours.
TWA: 435 mg/m³ 10 hours.
STEL: 125 ppm 15 minutes.
STEL: 545 mg/m³ 15 minutes.
OSHA PEL (United States, 2/2013).
TWA: 100 ppm 8 hours.
TWA: 435 mg/m³ 8 hours.

Appropriate engineering : Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or
controls other engineering controls to keep worker exposure to airborne contaminants below any
recommended or statutory limits. The engineering controls also need to keep gas,
vapor or dust concentrations below any lower explosive limits. Use explosion-proof
ventilation equipment.
Environmental exposure : Emissions from ventilation or work process equipment should be checked to ensure
controls they comply with the requirements of environmental protection legislation. In some
cases, fume scrubbers, filters or engineering modifications to the process equipment
will be necessary to reduce emissions to acceptable levels.

Individual protection measures


Hygiene measures : Wash hands, forearms and face thoroughly after handling chemical products, before
eating, smoking and using the lavatory and at the end of the working period.
Appropriate techniques should be used to remove potentially contaminated clothing.
Wash contaminated clothing before reusing. Ensure that eyewash stations and safety
showers are close to the workstation location.
Eye/face protection : Safety eyewear complying with an approved standard should be used when a risk
assessment indicates this is necessary to avoid exposure to liquid splashes, mists,
gases or dusts. If contact is possible, the following protection should be worn, unless
the assessment indicates a higher degree of protection: chemical splash goggles.
Skin protection
Hand protection : Chemical-resistant, impervious gloves complying with an approved standard should be
worn at all times when handling chemical products if a risk assessment indicates this is
necessary. Considering the parameters specified by the glove manufacturer, check
during use that the gloves are still retaining their protective properties. It should be
noted that the time to breakthrough for any glove material may be different for different
glove manufacturers. In the case of mixtures, consisting of several substances, the
protection time of the gloves cannot be accurately estimated.
Body protection : Personal protective equipment for the body should be selected based on the task being
performed and the risks involved and should be approved by a specialist before
handling this product. When there is a risk of ignition from static electricity, wear anti-
static protective clothing. For the greatest protection from static discharges, clothing
should include anti-static overalls, boots and gloves.

Date of issue/Date of revision : 3/6/2015. Date of previous issue : No previous validation. Version :1 6/13
Section 8. Exposure controls/personal protection
Other skin protection : Appropriate footwear and any additional skin protection measures should be selected
based on the task being performed and the risks involved and should be approved by a
specialist before handling this product.
Respiratory protection : Use a properly fitted, air-purifying or air-fed respirator complying with an approved
standard if a risk assessment indicates this is necessary. Respirator selection must be
based on known or anticipated exposure levels, the hazards of the product and the safe
working limits of the selected respirator.

Section 9. Physical and chemical properties


Appearance
Physical state : Liquid.
Color : Not available.
Odor : Not available.
Odor threshold : Not available.
pH : Not available.
Melting point : Not available.
Boiling point : Not available.
Flash point : Closed cup: -29°C (-20.2°F) [Pensky-Martens Closed Cup]
Evaporation rate : 1.5 (butyl acetate = 1)
Flammability (solid, gas) : Not available.
Lower and upper explosive : Lower: 0.9%
(flammable) limits Upper: 9.5%
Vapor pressure : 13.5 kPa (101.325 mm Hg) [at 20°C]
Vapor density : 1.55 [Air = 1]
Relative density : 0.69
Solubility : Not available.
Partition coefficient: n- : Not available.
octanol/water
Auto-ignition temperature : Not available.
Decomposition temperature : Not available.
Viscosity : Kinematic (room temperature): <0.07 cm2/s (<7 cSt)
Kinematic (40°C (104°F)): <0.07 cm2/s (<7 cSt)
Aerosol product
Type of aerosol : Spray
Heat of combustion : 0.00004051 kJ/g

Section 10. Stability and reactivity


Reactivity : No specific test data related to reactivity available for this product or its ingredients.

Chemical stability : The product is stable.

Possibility of hazardous : Under normal conditions of storage and use, hazardous reactions will not occur.
reactions

Conditions to avoid : Avoid all possible sources of ignition (spark or flame).

Incompatible materials : No specific data.

Date of issue/Date of revision : 3/6/2015. Date of previous issue : No previous validation. Version :1 7/13
Section 10. Stability and reactivity
Hazardous decomposition : Under normal conditions of storage and use, hazardous decomposition products should
products not be produced.

Section 11. Toxicological information


Information on toxicological effects
Acute toxicity
Product/ingredient name Result Species Dose Exposure
Xylene LC50 Inhalation Gas. Rat 5000 ppm 4 hours
LD50 Oral Rat 4300 mg/kg -
Butane LC50 Inhalation Vapor Rat 658000 mg/m³ 4 hours
Ethylbenzene LD50 Dermal Rabbit >5000 mg/kg -
LD50 Oral Rat 3500 mg/kg -
Irritation/Corrosion
Product/ingredient name Result Species Score Exposure Observation
Xylene Eyes - Mild irritant Rabbit - 87 milligrams -
Eyes - Severe irritant Rabbit - 24 hours 5 -
milligrams
Skin - Mild irritant Rat - 8 hours 60 -
microliters
Skin - Moderate irritant Rabbit - 24 hours 500 -
milligrams
Skin - Moderate irritant Rabbit - 100 Percent -
Ethylbenzene Eyes - Severe irritant Rabbit - 500 -
milligrams
Skin - Mild irritant Rabbit - 24 hours 15 -
milligrams
Sensitization
Not available.
Mutagenicity
Not available.
Carcinogenicity
Not available.
Classification
Product/ingredient name OSHA IARC NTP
Xylene - 3 -
Ethylbenzene - 2B -
Reproductive toxicity
Not available.
Teratogenicity
Not available.
Specific target organ toxicity (single exposure)

Date of issue/Date of revision : 3/6/2015. Date of previous issue : No previous validation. Version :1 8/13
Section 11. Toxicological information
Name Category Route of Target organs
exposure
Lt. Aliphatic Hydrocarbon Solvent Category 3 Not applicable. Respiratory tract
irritation and
Narcotic effects
Xylene Category 3 Not applicable. Respiratory tract
irritation and
Narcotic effects
Propane Category 3 Not applicable. Respiratory tract
irritation and
Narcotic effects
Butane Category 3 Not applicable. Respiratory tract
irritation and
Narcotic effects
Ethylbenzene Category 3 Not applicable. Respiratory tract
irritation and
Narcotic effects
Specific target organ toxicity (repeated exposure)
Name Category Route of Target organs
exposure
Lt. Aliphatic Hydrocarbon Solvent Category 2 Not determined Not determined
Xylene Category 2 Not determined Not determined
Propane Category 2 Not determined Not determined
Butane Category 2 Not determined Not determined
Ethylbenzene Category 2 Not determined Not determined
Aspiration hazard
Name Result
Lt. Aliphatic Hydrocarbon Solvent ASPIRATION HAZARD - Category 1
Xylene ASPIRATION HAZARD - Category 1
Propane ASPIRATION HAZARD - Category 1
Butane ASPIRATION HAZARD - Category 1
Ethylbenzene ASPIRATION HAZARD - Category 1

Information on the likely : Not available.


routes of exposure
Potential acute health effects
Eye contact : Causes serious eye irritation.
Inhalation : Harmful if inhaled. Can cause central nervous system (CNS) depression. May cause
drowsiness and dizziness. May cause respiratory irritation.
Skin contact : Causes skin irritation.
Ingestion : Can cause central nervous system (CNS) depression. May be fatal if swallowed and
enters airways. Irritating to mouth, throat and stomach.

Symptoms related to the physical, chemical and toxicological characteristics


Eye contact : Adverse symptoms may include the following:
pain or irritation
watering
redness

Date of issue/Date of revision : 3/6/2015. Date of previous issue : No previous validation. Version :1 9/13
Inhalation : Adverse symptoms may include the following:
respiratory tract irritation
coughing
nausea or vomiting
headache
drowsiness/fatigue
dizziness/vertigo
unconsciousness
Skin contact : Adverse symptoms may include the following:
irritation
redness
Ingestion : Adverse symptoms may include the following:
nausea or vomiting

Delayed and immediate effects and also chronic effects from short and long term exposure
Short term exposure
Potential immediate : Not available.
effects
Potential delayed effects : Not available.
Long term exposure
Potential immediate : Not available.
effects
Potential delayed effects : Not available.
Potential chronic health effects
Not available.
General : May cause damage to organs through prolonged or repeated exposure.
Carcinogenicity : Suspected of causing cancer. Risk of cancer depends on duration and level of
exposure.
Mutagenicity : No known significant effects or critical hazards.
Teratogenicity : No known significant effects or critical hazards.
Developmental effects : No known significant effects or critical hazards.
Fertility effects : No known significant effects or critical hazards.

Numerical measures of toxicity


Acute toxicity estimates
Route ATE value
Oral 6847.2 mg/kg
Inhalation (gases) 9690.9 ppm

Section 12. Ecological information


Toxicity
Product/ingredient name Result Species Exposure
Lt. Aliphatic Hydrocarbon Acute LC50 >100000 ppm Fresh water Fish - Oncorhynchus mykiss 96 hours
Solvent
Xylene Acute LC50 8500 µg/l Marine water Crustaceans - Palaemonetes 48 hours
pugio
Acute LC50 13400 µg/l Fresh water Fish - Pimephales promelas 96 hours
Ethylbenzene Acute EC50 4600 µg/l Fresh water Algae - Pseudokirchneriella 72 hours
subcapitata
Acute EC50 3600 µg/l Fresh water Algae - Pseudokirchneriella 96 hours
subcapitata

Date of issue/Date of revision : 3/6/2015. Date of previous issue : No previous validation. Version :1 10/13
Section 12. Ecological information
Acute EC50 6530 µg/l Fresh water Crustaceans - Artemia sp. - 48 hours
Nauplii
Acute EC50 2930 µg/l Fresh water Daphnia - Daphnia magna - 48 hours
Neonate
Acute LC50 4200 µg/l Fresh water Fish - Oncorhynchus mykiss 96 hours

Persistence and degradability


Product/ingredient name Aquatic half-life Photolysis Biodegradability
Xylene - - Readily
Ethylbenzene - - Readily

Bioaccumulative potential
Product/ingredient name LogPow BCF Potential
Lt. Aliphatic Hydrocarbon - 10 to 2500 high
Solvent
Xylene - 8.1 to 25.9 low

Mobility in soil
Soil/water partition : Not available.
coefficient (KOC)

Other adverse effects : No known significant effects or critical hazards.

Section 13. Disposal considerations


Disposal methods : The generation of waste should be avoided or minimized wherever possible. Disposal
of this product, solutions and any by-products should at all times comply with the
requirements of environmental protection and waste disposal legislation and any
regional local authority requirements. Dispose of surplus and non-recyclable products
via a licensed waste disposal contractor. Waste should not be disposed of untreated to
the sewer unless fully compliant with the requirements of all authorities with jurisdiction.
Waste packaging should be recycled. Incineration or landfill should only be considered
when recycling is not feasible. This material and its container must be disposed of in a
safe way. Empty containers or liners may retain some product residues. Do not
puncture or incinerate container.

Section 14. Transport information


DOT TDG Mexico IATA IMDG
Classification Classification Classification
UN number UN1950 UN1950 UN1950 UN1950 UN1950

UN proper AEROSOLS AEROSOLS AEROSOLS AEROSOLS, AEROSOLS


shipping name flammable
Transport 2.1 2.1 2.1 2.1 2.1
hazard class(es)

Packing group - - - - -
Environmental No. No. No. No. No.
hazards

Date of issue/Date of revision : 3/6/2015. Date of previous issue : No previous validation. Version :1 11/13
Section 14. Transport information
Additional Special Special Special Special Emergency
information provisions provisions provisions provisions schedules (EmS)
LIMITED LIMITED (ERG#126) LIMITED LIMITED
QUANTITY QUANTITY QUANTITY QUANTITY, F-D,
S-U

Special precautions for user : Multi-modal shipping descriptions are provided for informational purposes and do not
consider container sizes. The presence of a shipping description for a particular
mode of transport (sea, air, etc.), does not indicate that the product is packaged
suitably for that mode of transport. All packaging must be reviewed for suitability prior
to shipment, and compliance with the applicable regulations is the sole responsibility
of the person offering the product for transport. People loading and unloading
dangerous goods must be trained on all of the risks deriving from the substances
and on all actions in case of emergency situations.

Transport in bulk according : Not available.


to Annex II of MARPOL
73/78 and the IBC Code

Section 15. Regulatory information


U.S. Federal regulations :
State regulations
California Prop. 65
WARNING: This product contains chemicals known to the State of California to cause cancer and birth defects or other
reproductive harm.

Section 16. Other information


Hazardous Material Information System (U.S.A.)
Health * 2

Flammability 4
Physical hazards 0

Caution: HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4
representing significant hazards or risks Although HMIS® ratings are not required on SDSs under 29 CFR 1910.
1200, the preparer may choose to provide them. HMIS® ratings are to be used with a fully implemented HMIS®
program. HMIS® is a registered mark of the National Paint & Coatings Association (NPCA).

The customer is responsible for determining the PPE code for this material.

Date of issue/Date of revision : 3/6/2015. Date of previous issue : No previous validation. Version :1 12/13
Section 16. Other information

Notice to reader
It is recommended that each customer or recipient of this Safety Data Sheet (SDS) study it carefully and consult
resources, as necessary or appropriate, to become aware of and understand the data contained in this SDS and
any hazards associated with the product. This information is provided in good faith and believed to be accurate
as of the effective date herein. However, no warranty, express or implied, is given. The information presented
here applies only to the product as shipped. The addition of any material can change the composition, hazards
and risks of the product. Regulatory requirements are subject to change and may differ between various
locations and jurisdictions. The customer/buyer/user is responsible to ensure that his activities comply with all
country, federal, state, provincial or local laws. The conditions for use of the product are not under the control of
the manufacturer; the customer/buyer/user is responsible to determine the conditions necessary for the safe use
of this product. The customer/buyer/user should not use the product for any purpose other than the purpose
shown in the applicable section of this SDS without first referring to the supplier and obtaining written handling
instructions. Due to the proliferation of sources for information such as manufacturer-specific SDS, the
manufacturer cannot be responsible for SDSs obtained from any other source.

Date of issue/Date of revision : 3/6/2015. Date of previous issue : No previous validation. Version :1 13/13
SAFETY DATA SHEET

1. Identification
Product identifier Air Tool Oil
Other means of identification
Product code SL2531, SL2533
Recommended use Lubricant for pneumatic equipment
Recommended restrictions None known.
Manufacturer/Importer/Supplier/Distributor information
Manufactured or sold by:
Company name CRC Industries, Inc.
Address 885 Louis Dr.
Warminster, PA 18974 US
Telephone
General Information 215-674-4300
Technical 800-521-3168
Assistance
Customer Service 800-272-4620
24-Hour Emergency 800-424-9300 (US)
(CHEMTREC) 703-527-3887 (International)
Website www.crcindustries.com

2. Hazard(s) identification
Physical hazards Not classified.
Health hazards Not classified.
Environmental hazards Not classified.
OSHA defined hazards Not classified.

Label elements
Hazard symbol None.
Signal word None.
Hazard statement The mixture does not meet the criteria for classification.
Precautionary statement
Prevention Use with adequate ventilation. Open doors and windows or use other means to ensure a fresh air
supply during use. Observe good industrial hygiene practices.
Response Wash hands after handling.
Storage Store away from incompatible materials.
Disposal Dispose of waste and residues in accordance with local authority requirements.
Hazard(s) not otherwise None known.
classified (HNOC)

3. Composition/information on ingredients
Mixtures
Chemical name Common name and synonyms CAS number %
Distillates (petroleum), 64742-53-6 90 - 100
Hydrotreated Light Naphthenic
Distillates (petroleum), 64741-96-4 3-5
solvent-refined heavy naphthenic
Phosphorodithioic acid, 68649-42-3 1-3
O,O-di-C1-14-alkyl esters, zinc
salts

Material name: Air Tool Oil SDS US

SL2531, SL2533 Version #: 01 Issue date: 10-23-2015 1/8


Specific chemical identity and/or percentage of composition has been withheld as a trade secret.

4. First-aid measures
Inhalation Remove victim to fresh air and keep at rest in a position comfortable for breathing. Get medical
attention if symptoms occur.
Skin contact Wash off with plenty of water. Remove and isolate contaminated clothing and shoes. Get medical
attention if irritation develops and persists. Wash contaminated clothing before reuse.
Eye contact Rinse immediately with plenty of water, also under the eyelids. Remove contact lenses, if present
and easy to do. Get medical attention if irritation develops and persists.
Ingestion Rinse mouth. Drink 1 or 2 glasses of water. Do not induce vomiting without advice from poison
control center. Never give anything by mouth to a victim who is unconscious or is having
convulsions. Get medical attention if symptoms occur. If ingestion of a large amount does occur,
call a poison control center immediately.
Most important Direct contact with eyes may cause temporary irritation.
symptoms/effects, acute and
delayed
Indication of immediate Treat symptomatically.
medical attention and special
treatment needed
General information Ensure that medical personnel are aware of the material(s) involved, and take precautions to
protect themselves.

5. Fire-fighting measures
Suitable extinguishing media Use fire-extinguishing media appropriate for surrounding materials.
Unsuitable extinguishing None known.
media
Specific hazards arising from During fire, gases hazardous to health may be formed.
the chemical
Special protective equipment Firefighters must use standard protective equipment including flame retardant coat, helmet with
and precautions for firefighters face shield, gloves, rubber boots, and in enclosed spaces, SCBA.
Fire fighting Cool containers exposed to heat with water spray and remove container, if no risk is involved.
equipment/instructions
General fire hazards No unusual fire or explosion hazards noted.

6. Accidental release measures


Personal precautions, Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Keep out of
protective equipment and low areas. Do not touch damaged containers or spilled material unless wearing appropriate
emergency procedures protective clothing. For personal protection, see section 8 of the SDS.
Methods and materials for The product is immiscible with water and will spread on the water surface.
containment and cleaning up
Large Spills: Stop the flow of material, if this is without risk. Dike the spilled material, where this is
possible. Cover with plastic sheet to prevent spreading. Absorb in vermiculite, dry sand or earth
and place into containers. Following product recovery, flush area with water.

Small Spills: Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to
remove residual contamination.

Never return spills to original containers for re-use. For waste disposal, see section 13 of the SDS.
Prevent entry into waterways, sewer, basements or confined areas.
Environmental precautions Avoid discharge into drains, water courses or onto the ground.

7. Handling and storage


Precautions for safe handling Wear appropriate personal protective equipment. Avoid prolonged or repeated contact with skin.
Avoid prolonged exposure. Use only in well-ventilated areas. When using, do not eat, drink or
smoke. Wash contaminated clothing before reuse. Use appropriate container to avoid
environmental contamination. For product usage instructions, please see the product label.
Conditions for safe storage, Keep away from heat and sources of ignition. Store in a cool, dry place out of direct sunlight. Store
including any incompatibilities in a well-ventilated place. Keep container tightly closed. Store away from incompatible materials
(see Section 10 of the SDS).

Material name: Air Tool Oil SDS US

SL2531, SL2533 Version #: 01 Issue date: 10-23-2015 2/8


8. Exposure controls/personal protection
Occupational exposure limits
US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000)
Components Type Value Form

Distillates (petroleum), PEL 5 mg/m3 Mist.


hydrotreated light
naphthenic (CAS
64742-53-6)
2000 mg/m3
500 ppm
Distillates (petroleum), PEL 5 mg/m3 Mist.
solvent-refined heavy
naphthenic (CAS
64741-96-4)
2000 mg/m3
500 ppm
US. ACGIH Threshold Limit Values
Components Type Value Form

Distillates (petroleum), TWA 5 mg/m3 Inhalable fraction.


hydrotreated light
naphthenic (CAS
64742-53-6)
Distillates (petroleum), TWA 5 mg/m3 Inhalable fraction.
solvent-refined heavy
naphthenic (CAS
64741-96-4)
US. NIOSH: Pocket Guide to Chemical Hazards
Components Type Value Form

Distillates (petroleum), Ceiling 1800 mg/m3


hydrotreated light
naphthenic (CAS
64742-53-6)
STEL 10 mg/m3 Mist.
Distillates (petroleum), Ceiling 1800 mg/m3
solvent-refined heavy
naphthenic (CAS
64741-96-4)
STEL 10 mg/m3 Mist.
Biological limit values No biological exposure limits noted for the ingredient(s).
Appropriate engineering Good general ventilation (typically 10 air changes per hour) should be used. Ventilation rates
controls should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation,
or other engineering controls to maintain airborne levels below recommended exposure limits. If
exposure limits have not been established, maintain airborne levels to an acceptable level.
General ventilation normally adequate.
Individual protection measures, such as personal protective equipment
Eye/face protection Wear safety glasses with side shields (or goggles).

Skin protection
Hand protection Wear protective gloves such as: Nitrile. Polyvinyl chloride (PVC).
Other Wear suitable protective clothing.
Respiratory protection If engineering controls are not feasible or if exposure exceeds the applicable exposure limits, use a
NIOSH-approved cartridge respirator with an organic vapor cartridge. Use a self-contained
breathing apparatus in confined spaces and for emergencies. Air monitoring is needed to
determine actual employee exposure levels.
Thermal hazards Wear appropriate thermal protective clothing, when necessary.
General hygiene Handle in accordance with good industrial hygiene and safety practice.
considerations

9. Physical and chemical properties


Appearance
Material name: Air Tool Oil SDS US

SL2531, SL2533 Version #: 01 Issue date: 10-23-2015 3/8


Physical state Liquid.
Form Liquid.
Color Amber.
Odor Mild petroleum.
Odor threshold Not available.
pH Not available.
Melting point/freezing point Not available.
Initial boiling point and boiling 680 °F (360 °C) estimated
range
Flash point 320 °F (160 °C) Cleveland Open Cup
Evaporation rate Slow.
Flammability (solid, gas) Not available.
Upper/lower flammability or explosive limits
Flammability limit - lower Not available.
(%)
Flammability limit - upper Not available.
(%)
Vapor pressure Not available.
Vapor density > 1 (air = 1)
Relative density 0.9 - 0.92
Solubility (water) Insoluble.
Partition coefficient Not available.
(n-octanol/water)
Auto-ignition temperature 500 °F (260 °C) estimated
Decomposition temperature Not available.
Viscosity (kinematic) 22.5 - 27.5 mm²/s (104 °F (40 °C))
Percent volatile Not available.

10. Stability and reactivity


Reactivity The product is stable and non-reactive under normal conditions of use, storage and transport.
Chemical stability Material is stable under normal conditions.
Possibility of hazardous No dangerous reaction known under conditions of normal use.
reactions
Conditions to avoid Heat, flames and sparks. Contact with incompatible materials.
Incompatible materials Strong oxidizing agents.
Hazardous decomposition Carbon oxides.
products

11. Toxicological information


Information on likely routes of exposure
Inhalation Prolonged or excessive inhalation may cause respiratory tract irritation.
Skin contact Prolonged skin contact may cause temporary irritation. Repeated exposure may cause skin
dryness or cracking.
Eye contact Direct contact with eyes may cause temporary irritation.
Ingestion Expected to be a low ingestion hazard.
Symptoms related to the Direct contact with eyes may cause temporary irritation.
physical, chemical and
toxicological characteristics
Information on toxicological effects
Acute toxicity Not available.

Material name: Air Tool Oil SDS US

SL2531, SL2533 Version #: 01 Issue date: 10-23-2015 4/8


Product Species Test Results
Air Tool Oil
Acute
Dermal
LD50 Rabbit 5100 mg/kg estimated
Inhalation
LC50 Rat 2295 mg/m³, 4 hours estimated
Oral
LD50 Rat 5097 mg/kg estimated

* Estimates for product may be based on additional component data not shown.
Skin corrosion/irritation Prolonged skin contact may cause temporary irritation.
Serious eye damage/eye Direct contact with eyes may cause temporary irritation.
irritation
Respiratory sensitization Not a respiratory sensitizer.
Skin sensitization This product is not expected to cause skin sensitization.
Germ cell mutagenicity No data available to indicate product or any components present at greater than 0.1% are
mutagenic or genotoxic.
Carcinogenicity This product is not considered to be a carcinogen by IARC, ACGIH, NTP, or OSHA.
IARC Monographs. Overall Evaluation of Carcinogenicity
Not available.
US. National Toxicology Program (NTP) Report on Carcinogens
Not available.
Reproductive toxicity This product is not expected to cause reproductive or developmental effects.
Specific target organ toxicity - Not classified.
single exposure
Specific target organ toxicity - Not classified.
repeated exposure
Aspiration hazard Not classified.
Chronic effects Prolonged inhalation may be harmful.
Further information This product has no known adverse effect on human health.

12. Ecological information


Ecotoxicity The product is not classified as environmentally hazardous. However, this does not exclude the
possibility that large or frequent spills can have a harmful or damaging effect on the environment.
Product Species Test Results
Air Tool Oil
Aquatic
Crustacea EC50 Daphnia 99.9848 mg/l, 48 hours estimated
Fish LC50 Fish 549.3577 mg/l, 96 hours estimated
Components Species Test Results
Phosphorodithioic acid, O,O-di-C1-14-alkyl esters, zinc salts (CAS 68649-42-3)
Aquatic
Crustacea EC50 Water flea (Daphnia magna) 1 - 5 mg/l, 48 hours
Fish LC50 Fathead minnow (Pimephales promelas) 1 - 5 mg/l, 96 hours

* Estimates for product may be based on additional component data not shown.
Persistence and degradability No data is available on the degradability of this product.
Bioaccumulative potential
Mobility in soil No data available.
Other adverse effects No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation
potential, endocrine disruption, global warming potential) are expected from this component.

Material name: Air Tool Oil SDS US

SL2531, SL2533 Version #: 01 Issue date: 10-23-2015 5/8


13. Disposal considerations
Disposal of waste from This product is not a RCRA hazardous waste (See 40 CFR Part 261.20 – 261.33). Empty
residues / unused products containers may be recycled. Collect and reclaim or dispose in sealed containers at licensed waste
disposal site. Dispose in accordance with all applicable regulations.
Hazardous waste code Not regulated.
Contaminated packaging Empty containers should be taken to an approved waste handling site for recycling or disposal.
Since emptied containers may retain product residue, follow label warnings even after container is
emptied.

14. Transport information


DOT
Not regulated as dangerous goods.
IATA
Not regulated as dangerous goods.
IMDG
Not regulated as dangerous goods.

15. Regulatory information


US federal regulations This product is not known to be a "Hazardous Chemical" as defined by the OSHA Hazard
Communication Standard, 29 CFR 1910.1200.
TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D)
Not regulated.
US. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)
Not listed.
SARA 304 Emergency release notification
Not regulated.
US EPCRA (SARA Title III) Section 313 - Toxic Chemical: Listed substance
Phosphorodithioic acid, O,O-di-C1-14-alkyl esters, zinc salts (CAS 68649-42-3)
CERCLA Hazardous Substance List (40 CFR 302.4)
Phosphorodithioic acid, O,O-di-C1-14-alkyl esters, zinc Listed.
salts (CAS 68649-42-3)
CERCLA Hazardous Substances: Reportable quantity
Not listed.
Spills or releases resulting in the loss of any ingredient at or above its RQ require immediate notification to the National
Response Center (800-424-8802) and to your Local Emergency Planning Committee.
Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List
Not regulated.
Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130)
Not regulated.
Safe Drinking Water Act Not regulated.
(SDWA)
Food and Drug Not regulated.
Administration (FDA)
Superfund Amendments and Reauthorization Act of 1986 (SARA)
Section 311/312 Immediate Hazard - No
Hazard categories Delayed Hazard - No
Fire Hazard - No
Pressure Hazard - No
Reactivity Hazard - No
SARA 302 Extremely No
hazardous substance
US state regulations
US. California. Candidate Chemicals List. Safer Consumer Products Regulations (Cal. Code Regs, tit. 22, 69502.3, subd.
(a))
Distillates (petroleum), Hydrotreated Light Naphthenic (CAS 64742-53-6)
Distillates (petroleum), solvent-refined heavy naphthenic (CAS 64741-96-4)

Material name: Air Tool Oil SDS US

SL2531, SL2533 Version #: 01 Issue date: 10-23-2015 6/8


US. California Controlled Substances. CA Department of Justice (California Health and Safety Code Section 11100)
Not listed.
US. Massachusetts RTK - Substance List
Distillates (petroleum), Hydrotreated Light Naphthenic (CAS 64742-53-6)
Distillates (petroleum), solvent-refined heavy naphthenic (CAS 64741-96-4)
US. New Jersey Worker and Community Right-to-Know Act
Phosphorodithioic acid, O,O-di-C1-14-alkyl esters, zinc salts (CAS 68649-42-3)
US. Rhode Island RTK
Phosphorodithioic acid, O,O-di-C1-14-alkyl esters, zinc salts (CAS 68649-42-3)
US. Pennsylvania Worker and Community Right-to-Know Law
Not listed.
US. California Proposition 65
California Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition 65): This material is not known to contain
any chemicals currently listed as carcinogens or reproductive toxins.
Volatile organic compounds (VOC) regulations
EPA
VOC content (40 CFR Not determined
51.100(s))
Consumer products Not regulated
(40 CFR 59, Subpt. C)
State
Consumer products Not regulated
VOC content (CA) 0%
VOC content (OTC) 0%
International Inventories
Country(s) or region Inventory name On inventory (yes/no)*
Australia Australian Inventory of Chemical Substances (AICS) Yes
Canada Domestic Substances List (DSL) Yes
Canada Non-Domestic Substances List (NDSL) No
China Inventory of Existing Chemical Substances in China (IECSC) Yes
Europe European Inventory of Existing Commercial Chemical Yes
Substances (EINECS)
Europe European List of Notified Chemical Substances (ELINCS) No
Japan Inventory of Existing and New Chemical Substances (ENCS) No
Korea Existing Chemicals List (ECL) Yes
New Zealand New Zealand Inventory Yes
Philippines Philippine Inventory of Chemicals and Chemical Substances Yes
(PICCS)
United States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory Yes
*A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s)
A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing
country(s).

16. Other information, including date of preparation or last revision


Issue date 10-23-2015
Prepared by Allison Cho
Version # 01
Further information Not available.
HMIS® ratings Health: 1
Flammability: 1
Physical hazard: 0
Personal protection: B
NFPA ratings Health: 1
Flammability: 1
Instability: 0

Material name: Air Tool Oil SDS US

SL2531, SL2533 Version #: 01 Issue date: 10-23-2015 7/8


NFPA ratings
1
1 0

Disclaimer The information contained in this document applies to this specific material as supplied. It may not
be valid for this material if it is used in combination with any other materials. This information is
accurate to the best of CRC Industries' knowledge or obtained from sources believed by CRC to
be accurate. Before using any product, read all warnings and directions on the label. For further
clarification of any information contained on this (M)SDS consult your supervisor, a health & safety
professional, or CRC Industries.

Material name: Air Tool Oil SDS US

SL2531, SL2533 Version #: 01 Issue date: 10-23-2015 8/8


KLEEN-FLO TUMBLER INDUSTRIES LIMITED MATERIAL SAFETY DATA SHEET PAGE 1

SECTION I-MATERIAL IDENTIFICATION AND USE

Material Name/Identifier: Air Tool Oil Stock No. 4168/4169/4170


Manufacturer's Name: Kleen-Flo Tumbler Industries Ltd Street Address: 75 Advance Blvd.
City: Brampton Province: Ontario
Postal Code: L6T 4N1 Emergency Phone #: CANUTEC:- 613-996-6666 (24HR)
Chemical Name: N.Ap. (mixture) Chemical Family: N.Ap. (mixture)
Chemical Formula: N.Ap. (mixture) Trade Names & Synonyms: None
Material Use: Lubricant Molecular Weight: N.Ap. (mixture)

SECTION II-HAZARDOUS INGREDIENTS OF MATERIAL


Hazardous Approximate C.A.S. LD50 LC50
Ingredients Concentration, % Species & Route Species & Route
Hydrotreated petroleum oil 60-100 64742-58-1 >2000 mg/kg rat-oral N/Av.
Naphthenic Oil 1 -10 64742-52-5 >2000 mg/kg rat-oral N/Av.
Hydrocarbon Distillate 1 -10 8052-41-3 > 5 g/kg rat-oral > 5 g/m3 rat-inh.
Zinc C1-C14 alkyldithiophosphates <1 68649-42-3 N/Av. N/Av.

SECTION III-PHYSICAL DATA FOR MATERIAL

Physical State: Liquid Odour/Appearance: Pleasant odour/ Clear, red oil


Specific Gravity: 0.84 Odour Threshold(p.p.m.): N/E
Boiling Point: >129ºC Evaporation Rate: N/E
Freezing Point: N/E Solubility in Water: Insoluble
% Volatile(by volume): N/Av. Vapour Pressure(mm)Hg: N/E
Vapour Density(Air=1): N/E Coefficient of Water/Oil Distribut: N/E
pH: N/Av.

SECTION IV-FIRE AND EXPLOSION HAZARD OF MATERIAL


Flammability (Yes/No) Yes If yes under which conditions: combustible liquid, may form
combustible vapours at or above flash point
Auto Ignition Temperature: N/E Means of Extinction: Carbon dioxide, dry chemical, foam, water fog
Flash Point, Tag. C.C 69ºC Hazardous Combustion Products: oxides of carbon, sulfur, zinc,
phosphorous, calcium. Hydrogen sulfide, alkyl mercaptons.
Upper Flammable Limit (%vol) 15-16 Lower Flammable Limit (% by volume): 1
Explosion Data: Sensitivity to Mechanical Impact: No. Sensitivity to Static Discharge: No

SECTION V-REACTIVITY DATA

Chemical Stability Yes/No: Yes If NO under r which conditions?


Incompatibility to Other Substances Yes/No: Yes If so which ones? Strong oxidizing agents
Reactivity and under what conditions? Not reactive under normal condition
Hazardous Decomposition Products: Oxides of carbon, Sulfur,Phosphorous, Calcium & Zinc.

N/E: not established N.Ap.:not applicable N/Av.: not available


Material Name/Identifier: Air Tool Oil Stock No. U4168/ U4169/ U4170 PAGE 2

SECTION VI-TOXICOLOGICAL PROPERTIES OF PRODUCT

Route of Entry: --SKIN CONTACT -x-SKIN ABSORPTION -x-EYE CONTACT -x-INHALATION -x-INGESTION
Effects of Acute Exposure: May cause skin, eye irritation, dizziness, headache, vomiting, nausea, cough, pulmonary irritation
Effects of Chronic Exposure: Prolong, repeated eye and skin contact can cause severe eye irritation, dermatitis.

LD 50 of Product: N/E LC 50 of Product: N/E


Irritancy of Product: Eyes, skin Exposure Limits of Product: N/E
Sensitization of Product: None known Toxicologically Synergistic Materials: N/E
--CARCINOGENICITY --REPRODUCTIVE EFFECTS --TERATOGENICITY --MUTAGENICITY None Known

SECTION VII-PREVENTIVE MEASURES


Personal Protective Equipment to be used:
Gloves(specify): Nitrile, chemical resistant gloves Eye (specify): Safety Glasses
Respiratory(specify): Not required in normal use Clothing: Not required
Respiratory Protection: If used indoors or on a continuous basis, use of NIOSH approved cartridge type respirator is recommended
Engineering Controls: Local or mechanical ventilation
Leak and Spill Procedure: Dike and absorb spill with inert absorbant material, keep spill out of sewers.
Waste Disposal: Dispose according to federal, state (Provincial) and local regulations
Storage Requirements: Keep at room temperature. Keep container closed when not in use.
Handling Procedures and Keep away from children. Handle with care. Do not inhale or ingest.
Equipment: Keep away from excessive heat, open flame, source of ignition.
DSL listing: All components are listed on the inventory.
TDG Classification: Not regulated
WHMIS Classification: B3, D2B Complies with CCCR 2001. (non-controlled)

SECTION VIII-FIRST AID MEASURES

Eye: Flush immediately with running water for at least 15 minutes. Consult physician immediately.
Skin: Remove contiminated clothing. Rinse with plenty of soapy. See doctor if irritation persist.
Inhalation Remove to fresh air. Restore breathing if required. See doctor if discomfort persist.
Ingestion: DO NOT INDUCE VOMITING. If person conscious, give a glasses of water. See doctor immediately.

SECTION IX-PREPARATION DATE OF M.S.D.S.

Additional Info/Comments: Sources Used: Handbook of Poisoning By: R.H. Dreisbach


Phone Number: (905) 793-4311 Prepared By: Quality Control Laboratory
Date Prepared: Janaury 2, 2015. Kleen-Flo Tumbler Industries Limited

THIS SHEET SUPERSEDES ANY OTHER M.S.D.S. PREVIOUSLY PREPARED


N/E: not established N.Ap.:not applicable N/Av.: not available
SAFETY DATA SHEET
1. IDENTIFICATION AND GENERAL INFORMATION
P/N#: Allegro 70% IPA Hygienic Wipe (1001, 1001-05, 1001-10)
Nomenclature: Personal Respirator Cleaning Pad
Recommended Use of the Chemical & Restrictions on Use:
Uses: Personal protective equipment cleaner. Respirator cleaner.
Company Name: Allegro Industries
Address: 1360 Shiloh Church Rd
Piedmont, SC 29673
864-846-8740
Chemtrac: 800-424-9300

2. HAZARDS IDENTIFICATION
Appearance: White solid
Physical State: Solid containing liquid Moist paper
Odor: Mild alcohol odor

Classification:
The information below is for the liquid in industrial quantities when used in an industrial setting. The solution as packed in a consumer quantity is considered
a consumer good and when used as intended is unlikely to present a hazard

Serious eye damage/eye irritation Category 2


Specific target organ toxicity (single exposure) Category 3
Flammable Liquids Category 2

Signal Word: Danger

Hazard Statements:
May cause respiratory irritation. May cause drowsiness or dizziness. Highly flammable liquid and vapor.

Precautionary Statements - Prevention:


Wash face, hands and any exposed skin thoroughly after handling
Wear eye/face protection
Avoid breathing dust/fume/gas/mist/vapors/spray
Use only outdoors or in a well-ventilated area
Keep away from heat/sparks/open flames/hot surfaces. — No smoking
Keep container tightly closed
Ground/bond container and receiving equipment
Use explosion-proof equipment
Use only non-sparking tools
Take precautionary measures against static discharge
Keep cool

Precautionary Statements - Response:


IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing
If eye irritation persists: Get medical advice/attention
IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower
IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing
IN CASE OF FIRE: Use CO2, dry chemical, or foam for extinction

Precautionary Statements - Storage:


Store in a well-ventilated place. Keep container tightly closed
Keep cool

Precautionary Statements - Disposal:


Dispose of contents/container to an approved waste disposal plant

MS017
REV:H
Date Revised: 08/31/2015 1 of 7
SAFETY DATA SHEET
3. COMPOSITION

Chemical Name CAS No Weight-%


Isopropyl Alcohol 67-63-0 60-75

**If Chemical Name/CAS No is "proprietary" and/or Weight-% is listed as a range, the specific chemical identity and/or percentage
of composition has been withheld as a trade secret.**

4. FIRST AID MEASURES


Eye Contact: Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Keep
eyes wide open while rinsing. If symptoms persist, call a physician.
Skin Contact: Wash with soap and water. If irritation persists or an allergic reaction occurs, call a physician.
Inhalation: Remove victim to fresh air and keep at rest in a position comfortable for breathing. If
breathing is difficult, give oxygen. If breathing has stopped, give artificial respiration. If
symptoms persist, call a physician.
Ingestion: Drink plenty of water. Never give anything by mouth to a person who is unconscious or convulsing. Consult a physician.
Most important symptoms and effects:
Symptoms: Causes serious eye irritation. May cause respiratory irritation. May cause drowsiness or dizziness. May cause central nervous system effects.
May cause gastrointestinal irritation, nausea, diarrhea, and vomiting.
Indication of any immediate medical attention and special treatment needed:
Notes to Physician: Chronic exposure may aggravate pre-existing skin conditions, impaired liver, kidney or pulmonary function.

5. FIRE FIGHTING MEASURES


Suitable Extinguishing Media:
Use extinguishing measures that are appropriate to local circumstances and the surrounding environment.
Unsuitable Extinguishing Media:
Not determined.
Specific Hazards Arising from the Chemical:
Flammable material.
Hazardous Combustion Products:
Carbon Oxides
Sensitivity to Mechanical Impact:
Not sensitive
Sensitivity to Static Discharge:
Yes

Protective equipment and precautions for firefighters:


As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full
protective gear.

6. ACCIDENTAL RELEASE MEASURES


Personal precautions, protective equipment and emergency procedures:
Personal Precautions: Use personal protective equipment as required. Avoid contact with eyes and skin. Remove all sources of ignition.

Methods and material for containment and cleaning up:


Methods for Containment: Extinguish all sources of ignition and ventilate area. Prevent further leakage or spillage if safe to do so.
Methods for Clean-Up: Use personal protective equipment as required. Soak up with absorbent material. Pick up and transfer to properly labeled containers.

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SAFETY DATA SHEET
7. HANDLING AND STORAGE
Precautions for safe handling:
Advice on Safe Handling: Wash face, hands, and any exposed skin thoroughly after handling. Wear eye/face protection.
Avoid breathing dust/fume/gas/mist/vapors/spray. Use only outdoors or in a well-ventilated
Keep away from heat/sparks/open flames/hot surfaces. — No smoking. Keep container tightly closed.
Ground/bond container and receiving equipment. Use explosion proof equipment. Use only non-sparking tools.
Take precautionary measures against static discharges. Keep cool. Avoid contact with skin, eyes or clothing.
Keep out of the reach of children. Handle in accordance with good industrial hygiene and safety practice.

Conditions for safe storage, including any incompatibilities:


Storage Conditions: Store in a well-ventilated place. Keep cool. Keep container tightly closed. P210 - Keep away from open flames/hot surfaces.
- No smoking. Keep out of reach of children. Keep away from animals.
Incompatible Materials: Strong oxidizing agents. Acids. Avoid contact with Aluminum, Zinc and other reactive metals.

8. EXPOSURE CONTROLS
Exposure Guidelines:

Chemical Name ACGIH TLV OSHA PEL NIOSH IDLH


Isopropyl Alcohol STEL: 400 ppm TWA: 400 ppm IDLH: 2000 ppm
67-63-0 TWA: 200 ppm TWA: 980 mg/m3 TWA: 400 ppm
(vacated) TWA: 400 ppm TWA: 980 mg/m3
(vacated) TWA: 980 mg/m3 STEL: 500 ppm
(vacated) STEL: 500 ppm STEL: 1225 mg/m3
(vacated) STEL: 1225 mg/m3

Appropriate engineering controls:


Engineering Controls: Showers. Eyewash stations. Ventilation systems.

Individual protection measures, such as personal protective equipment:


Eye/Face Protection: Wear eye/face protection.
Skin and Body Protection: Protective gloves.
Respiratory Protection: If exposure limits are exceeded or irritation is experienced, NIOSH/MSHA approved respiratory protection should be worn.
Positive-pressure supplied air respirators may be required for high airborne contaminant concentrations.
Respiratory protection must be provided in accordance with current local regulations.
General Hygiene
Considerations: When using do not eat, drink or smoke. Remove and wash contaminated clothing before reuse.
Provide regular cleaning of equipment, work areas and clothing.

9. PHYSICAL AND CHEMICAL PROPERTIES


Physical State: Solid containing liquid Moist paper
Appearance: White solid
Color: White
Odor: Mild alcohol odor
Odor Threshold: No information available
pH: No information available
Melting Point/Freezing
Point: No information available
Boiling Point/Boiling
Range: No information available
Flash Point: 12 °C / 54 °F
Evaporation Rate: No information available
Flammability (Solid, Gas): Not determined
Upper Flammability Limits: No information available
Lower Flammability Limit: No information available
Vapor Pressure: No information available
Vapor Density: No information available
Specific Gravity: No information available
Water Solubility: No information available
Solubility in other solvents: No information available
MS017
REV:H
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SAFETY DATA SHEET
Partition Coefficient: Not determined
Auto-ignition Temperature: No information available
Decomposition
Temperature: No information available
Kinematic Viscosity: Not determined
Dynamic Viscosity: Not determined
Explosive Properties: Not determined
Oxidizing Properties: Not determined
VOC Content: No information available

10. STABILITY AND REACTIVITY


Reactivity: Not reactive under normal conditions.
Chemical Stability: Stable under recommended storage conditions.
Possibility of Hazardous
Reactions: Hazardous polymerization does not occur.
Hazardous Polymerization: Hazardous polymerization does not occur.
Conditions to Avoid: Incompatible Materials. Heat, flames and sparks.
Incompatible Materials: Strong oxidizing agents. Acids. Avoid contact with Aluminum, Zinc and other reactive metals.
Hazardous Decomposition
Products: Carbon oxides.

11. TOXICOLOGICAL INFORMATION


Information on likely routes of exposure:
Product Information: May be harmful by inhalation, ingestion, or skin absorption
Eye Contact: Causes serious eye irritation.
Skin Contact: May cause mild skin irritation.
Inhalation: May cause respiratory irritation. May cause central nervous system depression with nausea, headache, dizziness,
vomiting, and incoordination.
Ingestion: May be harmful if swallowed. Ingestion may cause gastrointestinal irritation, nausea, vomiting and diarrhea.

Component Information:

Chemical Name Oral LD50 Dermal LD50 Inhalation LC50


Isopropyl Alcohol = 4396 mg/kg (Rat) = 12800 mg/kg (Rat) = 12870 = 72.6 mg/L (Rat) 4 h
67-63-0 mg/kg (Rabbit)

Information on physical, chemical and toxicological effects:


Symptoms: Please see section 4 of this SDS for symptoms.

Delayed and immediate effects as well as chronic effects from short and long-term exposure:
Serious eye damage/eye
Irritation: Causes serious eye irritation.
Carcinogenicity: Isopropyl Alcohol (IPA) is an IARC Monograph Group 3 chemical. IPA is a Group 1 when manufactured by the strong-acid process.

Chemical Name ACGIH IARC NTP OSHA


Isopropyl Alcohol Group 3 X
67-63-0
Legend
IARC (International Agency for Research on Cancer)
Group 3 IARC components are "not classifiable as human carcinogens"
OSHA (Occupational Safety and Health Administration of the US Department of Labor)
X - Present

STOT - single exposure: May cause respiratory irritation. May cause drowsiness or dizziness.
Chronic Toxicity: May cause skin effects.
Numerical measures
of toxicity: Not determined

MS017
REV:H
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SAFETY DATA SHEET

12. ECOLOGICAL INFORMATION


Ecotoxicity: The environmental impact of this product has not been fully investigated.

Component Information:

Chemical Name Algae/aquatic plants Fish Toxicity to Crustacea


micro-
organisms
Isopropyl Alcohol 1000: 96 h Desmodesmus 9640: 96 h Pimephales 13299: 48 h
67-63-0 subspicatus mg/L EC50 promelas mg/L LC50 flow- Daphnia
1000: 72 h Desmodesmus through 11130: 96 h magna
subspicatus mg/L EC50 Pimephales promelas mg/L mg/L EC50
LC50 static 1400000: 96 h
Lepomis macrochirus μg/L
LC50

Persistence/Degradability: Not determined


Bioaccumulation: Not determined

Mobility:
Chemical Name Partition Coefficient
Isopropyl Alcohol 0.05
67-63-0

Other Adverse Effects: Not determined

13. DISPOSAL CONSIDERATIONS


Waste Treatment Methods:
Disposal of Wastes: This material, as supplied, is not a hazardous waste according to Federal regulations (40 CFR 261). This material could become
a hazardous waste if it is mixed with or otherwise comes in contact with a hazardous waste, if chemical additions
are made to this material, or if the material is processed or otherwise altered. Consult 40 CFR 261 to determine whether
the altered material is a hazardous waste. Consult the appropriate state, regional, or local regulations for additional requirements.
Contaminated Packaging: Disposal should be in accordance with applicable regional, national and local laws and regulations.

California Hazardous Waste Status:


This product contains one or more substances that are listed with the State of California as a hazardous waste.
Chemical Name California Hazardous Waste Status
Isopropyl Alcohol Toxic
67-63-0 Ignitable

MS017
REV:H
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SAFETY DATA SHEET
14. TRANSPORT INFORMATION
Note: Please see current shipping paper for most up to date shipping information, including exemptions and special circumstances.
DOT:
UN/ID No: UN1219
Proper Shipping Name: Isopropyl alcohol solution
Hazard Class: 3
Packing Group: II

IATA: Not regulated


UN/ID No: UN1219
Proper Shipping Name: Isopropyl alcohol solution
Hazard Class: 3
Packing Group: II

IMDG: Not regulated


UN/ID No: UN1219
Proper Shipping Name: Isopropyl alcohol solution
Hazard Class: 3
Packing Group: II

15. REGULATORY INFORMATION


International Inventories:
TSCA: Complies
DSL: Does not comply
NDSL: Does not comply
EINECS: Does not comply
ELINCS: Does not comply
ENCS: Does not comply
IECSC: Does not comply
KECL: Does not comply
PICCS: Does not comply
AICS: Does not comply

Legend:
TSCA - United States Toxic Substances Control Act Section 8(b) Inventory
DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List
EINECS/ELINCS - European Inventory of Existing Chemical Substances/European List of Notified Chemical Substances
ENCS - Japan Existing and New Chemical Substances
IECSC - China Inventory of Existing Chemical Substances
KECL - Korean Existing and Evaluated Chemical Substances
PICCS - Philippines Inventory of Chemicals and Chemical Substances
AICS - Australian Inventory of Chemical Substances

US Federal Regulations:
CERCLA:
This material, as supplied, does not contain any substances regulated as hazardous substances under the Comprehensive Environmental Response
Compensation and Liability Act (CERCLA) (40 CFR 302) or the Superfund Amendments and Reauthorization Act (SARA) (40 CFR 355).

SARA 311/312 Hazard Categories:


Acute Health Hazard: Yes
Chronic Health Hazard: Yes
Fire Hazard: Yes
Sudden Release of Pressure Hazard: No
Reactive Hazard: No

SARA 313:
Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product contains a chemical
or chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372

MS017
REV:H
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SAFETY DATA SHEET
Chemical Name CAS No Weight-% SARA 313 - Threshold
Values %
Isopropyl Alcohol - 67-63-0 67-63-0 65-75 1.0

US State Regulations:

U.S. State Right-to-Know Regulations:

Chemical Name New Jersey Massachusetts Pennsylvania


Isopropyl Alcohol X X X
67-63-0

16. OTHER INFORMATION

NFPA HMIS
Health Hazards: 1 Health Hazards: 1
Flammability: 3 Flammability: 3
Instability: Not determined Physical Hazards: 0
Special Hazards: Not determined Personal Protection: B- Safety Glasses, Gloves

Revised August 31, 2015 Rev. H

DISCLAIMER: THE INFORMATION FURNISHED HEREIN IS BELIEVED TO BE ACCURATE AND REPRESENTS


THE BEST DATA CURRENTLY AVAILABLE TO US. NO WARRANTY, EXPRESSED OR IMPLIED IS MADE
AND ALLEGRO INDUSTRIES ASSUMES NO LEGAL RESPONSIBILITY OR LIABILITY RESULTING FROM ITS USE.

MS017
REV:H
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SAFETY DATA SHEET <#####>122000013012
Bactine Original First Aid Liquid
Version 1.0 Revision Date 05/29/2015

1. IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING

Product information

Product Name: Bactine Original First Aid Liquid


SDS Number: 122000013012

Use : Medicinal products

Company
BAYER HEALTHCARE LLC
Consumer Care
100 Bayer Boulevard PO Box 915
Whippany, NJ 07981-0915
USA
(800) 743-5423

In case of emergency: (800) 331-4536


Chemtrec: (800) 424-9300
BAYER INFORMATION PHONE:(800) 331-4536 OR (800) 743-5423

2. HAZARDS IDENTIFICATION

Emergency Overview
Colour: clear, cloudy, colourless Form: liquid Odour: characteristic.

GHS Classification:
Not a dangerous substance / mixture according to GHS.

GHS Label element:

This material is not subject to the Federal OSHA Hazard Communication Standard 29 CFR 1910.1200.

3. COMPOSITION/INFORMATION ON INGREDIENTS

Weight percent Components CAS-No.


2.49% Lidocaine Hydrochloride 73-78-9

Page 1 of 9
SAFETY DATA SHEET <#####>122000013012
Bactine Original First Aid Liquid
Version 1.0 Revision Date 05/29/2015

Label Ingredients: Benzakonium Chloride; Lidocaine hydrochloride; Edetate Disodium;


Nonoxynol 9; 1,2-Propanediol; Water;

Other Ingredients
Weight percent Components CAS-No.
5 - 10% Propane-1,2-diol 57-55-6

4. FIRST AID MEASURES

General advice: Take off all contaminated clothing immediately.

If inhaled: Remove to fresh air. Call a physician immediately.

In case of skin contact: If skin reactions occur, contact a physician.

In case of eye contact: In the case of contact with eyes, rinse immediately with plenty of water and
seek medical advice.

If swallowed: If swallowed, seek medical advice immediately and show this container or label.

Contact Number: Use the Bayer Emergency Number in Section 1

5. FIREFIGHTING MEASURES

Suitable extinguishing media: Use water spray, alcohol-resistant foam, dry chemical or carbon
dioxide.

Unsuitable extinguishing media: High volume water jet

Specific hazards during firefighting: Fire may cause evolution of: Carbon monoxide (CO)
Carbon dioxide (CO2)

Special protective equipment for firefighters: In the event of fire, wear self-contained breathing
apparatus.

Further information: Prevent fire extinguishing water from contaminating surface water or the
ground water system.

6. ACCIDENTAL RELEASE MEASURES

Personal precautions: Use personal protective equipment.

Methods for cleaning up: Cover spilled product with liquid-binding material (sand, silica gel, acid
binder, universal binder, hybilat). Take up mechanically and fill into labeled, closable containers.

Page 2 of 9
SAFETY DATA SHEET <#####>122000013012
Bactine Original First Aid Liquid
Version 1.0 Revision Date 05/29/2015

Additional advice: No special precautions required.

Further Accidental No special precautions required.


Release Notes

7. HANDLING AND STORAGE

Handling:
Keep this and all drugs out of the reach of children. Avoid contact with eyes. Store in a dry place
away from excessive heat. Reseal containers immediately after use. Use normal precautions for
storage of a drug.

Keep away from open flames, hot surfaces and sources of ignition.

Storage:
Storage temperature: 59 - 77 °F (15 - 25 °C)
Do not use after expiration date.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Propane-1,2-diol (57-55-6)
US. AIHA Workplace Environmental Exposure Level (WEEL) Guides
Time Weighted Average (TWA): 10 mg/m3 (Aerosol.)

Propane-1,2-diol (57-55-6)
US. AIHA Workplace Environmental Exposure Level (WEEL) Guides
Time Weighted Average (TWA): 10 mg/m3 (Aerosol.)

Respiratory protection:
Recommended Filter type: Organic vapor with prefilter

None required for consumer use of this product.

Hand protection:
Chemically resistant gloves.
None required for consumer use of this product.

Eye protection:
Safety glasses

None required for consumer use of this product.

Hygiene measures:
Cleanliness Guidelines (GMP) for manufacturing of drugs must be observed!

Other protective measures:


Wear suitable protective equipment.

Please consult label for end-user requirements.

Page 3 of 9
SAFETY DATA SHEET <#####>122000013012
Bactine Original First Aid Liquid
Version 1.0 Revision Date 05/29/2015

9. PHYSICAL AND CHEMICAL PROPERTIES

Form: liquid
Colour: clear, cloudy, colourless
Odour: characteristic
Odour Threshold: No applicable information is available
Melting point: No applicable information is available
Boiling point/boiling range: No applicable information is available
Density: No applicable information is available
Bulk density: No applicable information is available
Vapour pressure: No applicable information is available
Viscosity, dynamic: No applicable information is available
Viscosity, kinematic: No applicable information is available
Flow time: No applicable information is available
Surface tension: No applicable information is available
Miscibility with water: No applicable information is available
Water solubility: completely soluble
pH: 6 - 6.8
Relative density: No applicable information is available
Partition coefficient: No applicable information is available
Solubility(ies): No applicable information is available
Flash point: No applicable information is available
Flammability (solid, gas): No applicable information is available
Ignition temperature: No applicable information is available
Explosion limits: No applicable information is available

10. STABILITY AND REACTIVITY

Conditions to avoid: No data available

Materials to avoid: Oxidizing agents

Hazardous reactions: None known.

Thermal decomposition:

No data available

Hazardous decomposition products:


Carbon monoxide (CO), Carbon dioxide (CO2)

Oxidizing properties:

No statements available.

Page 4 of 9
SAFETY DATA SHEET <#####>122000013012
Bactine Original First Aid Liquid
Version 1.0 Revision Date 05/29/2015

Impact sensitivity:
No data available

11. TOXICOLOGICAL INFORMATION


Other information on toxicity:

No data is available on the product itself.

Acute oral toxicity:


Acute toxicity estimate (ATE) > 2,000 mg/kg
The substance or mixture has no acute oral toxicity
Method: Calculation method
Calculated for GHS Classification and Labelling.

Acute inhalation toxicity:


Propane-1,2-diol
LC50 Rabbit: > 317 mg/l, 2 h
The substance or mixture has no acute inhalation toxicity

Acute dermal toxicity:


Propane-1,2-diol
LD50 Rabbit: > 5,000 mg/kg
The substance or mixture has no acute dermal toxicity

Acute toxicity (other routes of administration):


Lidocaine Hydrochloride
TDL0 intravenous human: 7.1 mg/kg

LD50 intraperitoneal Rat: 122 mg/kg

LD50 subcutaneous Rat: 570 mg/kg

LD50 intravenous Rat: 21 mg/kg

LDL0 intravenous Dog: 65.7 mg/kg

LD50 intravenous Rabbit: 25.6 mg/kg

LD50 intravenous Mouse: 22 mg/kg

LD50 intraperitoneal Mouse: 119 mg/kg

LD50 intramuscular Mouse: 260 mg/kg

Skin irritation:
Propane-1,2-diol
Rabbit
Result: No skin irritation

Page 5 of 9
SAFETY DATA SHEET <#####>122000013012
Bactine Original First Aid Liquid
Version 1.0 Revision Date 05/29/2015

Lidocaine Hydrochloride
Rabbit
Result: Moderate skin irritation
Method: Draize Test
According to the classification criteria of the European Union, the product is not considered as
being a skin irritant.

Eye irritation:
Propane-1,2-diol
Rabbit
Result: No eye irritation

Lidocaine Hydrochloride
Rabbit
Result: Moderate eye irritation
Method: Draize Test
No eye irritation

Sensitisation:
Propane-1,2-diol
Human experience
Result: Does not cause skin sensitisation.

guinea pig
Result: Does not cause skin sensitisation.

Method: OECD 406

Subacute, subchronic and prolonged toxicity:


Propane-1,2-diol
NOEL 50,000 mg/kg, Rat Oral, Exposure time 24 month

NOEL 1 mg/l, Rat Inhalation, Exposure time 3 month


Number of exposures: once daily

Genotoxicity in vitro:
Propane-1,2-diol
Ames test Bacteria
Dose: yes
Result: negative
Method: OECD 471

Mammalian cells
Result: negative
Method: OECD 476

Lidocaine Hydrochloride
Ames test Salmonella typhimurium
Result: negative

Hamster ovary-cells
Result: negative

Page 6 of 9
SAFETY DATA SHEET <#####>122000013012
Bactine Original First Aid Liquid
Version 1.0 Revision Date 05/29/2015

Genotoxicity in vivo:
Propane-1,2-diol

Result: negative
Method: OECD 478

Carcinogenicity:
Propane-1,2-diol
Rat:
Exposure time: 2 a
Number of exposures: once daily
Result: negative

Reproductive toxicity:
Propane-1,2-diol
Application Route: Oral
Rat, female: Test period: 18 d
NOAEL: 1600 mg/kg
Result: Animal testing did not show any effects on fertility.

Teratogenicity:
Propane-1,2-diol
Rat, male: Number of exposures: once daily
Test period: 15 d
NOAEL: 1600 mg/l
Result: No indication of teratogenic effects.

Lidocaine Hydrochloride
Application Route: subcutaneous
Rat: NOAEL: 30 mg/kg 72 mg/kg/day
Result: Did not show teratogenic effects in animal experiments.

Application Route: intraperitoneal


Rat: NOAEL: 56 mg/kg/day
Result: Did not show teratogenic effects in animal experiments.

Pharmaceutic effects:
Analgesic Antiseptic

Carcinogenicity:
No Carcinogenic substances as defined by IARC, NTP and/or OSHA

STOT - single exposure:


No data available
STOT - repeated exposure:
No data available

12. ECOLOGICAL INFORMATION

General advice:
Do not allow to enter surface waters or groundwater. No data is available on the product itself.

Page 7 of 9
SAFETY DATA SHEET <#####>122000013012
Bactine Original First Aid Liquid
Version 1.0 Revision Date 05/29/2015

Toxicity to fish:
Propane-1,2-diol
Acute Fish toxicity: LC50 40,613 mg/l
Test species: Pimephales promelas (fathead minnow) Duration of test: 96 h

Toxicity to daphnia and other aquatic invertebrates:


Propane-1,2-diol
LC50 18,340 mg/l
Test species: Ceriodaphnia dubia (water flea) Duration of test: 48 h

Toxicity to algae:
Propane-1,2-diol
IC50 19,100 mg/l
tested on: Pseudokirchneriella subcapitata (green algae)

Toxicity to bacteria:
Propane-1,2-diol
NOEC 20,000 mg/l
tested on: Pseudomonas putida
Duration of test: 18 h

Biodegradability:
Propane-1,2-diol
87 - 92 %, 28 d rapidly biodegradable
Method: OECD 301 C

Bioaccumulation:
Propane-1,2-diol

Bioconcentration factor (BCF)


0.09

13. DISPOSAL CONSIDERATIONS

If discarded in its purchased form, this product would not be a hazardous waste either by listing or
by characteristic. However, under RCRA, it is the responsibility of the product user to determine at
the time of disposal, whether a material containing the product or derived from the product should
be classified as a hazardous waste. (40 CFR 261.20-24)

Waste disposal should be in accordance with existing federal, state and local environmental control
laws.

14. TRANSPORT INFORMATION

Land transport (CFR)


non-regulated

US Sea transport (IMDG)


non-regulated

Page 8 of 9
SAFETY DATA SHEET <#####>122000013012
Bactine Original First Aid Liquid
Version 1.0 Revision Date 05/29/2015

US Air transport (ICAO / IATA cargo aircraft only)


non-regulated

US Air transport (ICAO / IATA passenger and cargo aircraft)


non-regulated

International IATA non-regulated


IMDG non-regulated

15. REGULATORY INFORMATION

US. EPA Emergency Planning and Community Right-To-Know Act (EPCRA) SARA Title III Section
302 Extremely Hazardous Substance (40 CFR 355, Appendix A)
Components
None

US. EPA Emergency Planning and Community Right-To-Know Act (EPCRA) SARA Title III Section
313 Toxic Chemicals (40 CFR 372.65) - Supplier Notification Required
Components
None

US. EPA CERCLA Hazardous Substances (40 CFR 302) Components


None

Massachusetts, New Jersey or Pennsylvania Right to Know Substance Lists


Weight percent Components CAS-No.
5 - 10% Propane-1,2-diol 57-55-6

California Prop. 65

To the best of our knowledge, this product does not contain any of the listed chemicals, which the
state of California has found to cause cancer, birth defects or other reproductive harm.

OSHA Hazcom Standard Rating Not subject to OSHA

16. OTHER INFORMATION

Further information
The information provided in this Safety Data Sheet is correct to the best of our knowledge, information
and belief at the date of its publication. The information given is designed only as a guidance for safe
handling, use, processing, storage, transportation, disposal and release and is not to be considered a
warranty or quality specification. The information relates only to the specific material designated and
may not be valid for such material used in combination with any other materials or in any process,
unless specified in the text.

Page 9 of 9
SAFETY DATA SHEET
BD1108

Section 1. Identification
Product name : BD7-77 PLUS Penetrant
Product code : BD1108
Other means of : Not available.
identification
Product type : Aerosol.
Relevant identified uses of the substance or mixture and uses advised against
Not applicable.

Manufacturer : Class C Solutions Group


a business of MSC Industrial Supply Co.
75 Maxess Road
Melville, NY 11747-3151

Emergency telephone : (303) 623-5716


number of the company
Product Information : (866) 438-6767
Telephone Number
Regulatory Information : (216) 566-2902
Telephone Number
Transportation Emergency : (800) 424-9300
Telephone Number

Section 2. Hazards identification


OSHA/HCS status : This material is considered hazardous by the OSHA Hazard Communication Standard
(29 CFR 1910.1200).
Classification of the : FLAMMABLE AEROSOLS - Category 1
substance or mixture GASES UNDER PRESSURE - Compressed gas
SKIN CORROSION/IRRITATION - Category 2
SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 2A
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Respiratory tract
irritation and Narcotic effects) - Category 3
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) - Category 2
ASPIRATION HAZARD - Category 1
Percentage of the mixture consisting of ingredient(s) of unknown toxicity: 57%
GHS label elements
Hazard pictograms :

Signal word : Danger

Date of issue/Date of revision : 3/24/2015. Date of previous issue : No previous validation. Version :1 1/13
Section 2. Hazards identification
Hazard statements : Extremely flammable aerosol.
Contains gas under pressure; may explode if heated.
Causes serious eye irritation.
Causes skin irritation.
May be fatal if swallowed and enters airways.
May cause respiratory irritation.
May cause drowsiness and dizziness.
May cause damage to organs through prolonged or repeated exposure.
Precautionary statements
Prevention : Wear protective gloves. Wear eye or face protection. Keep away from heat, hot
surfaces, sparks, open flames and other ignition sources. No smoking. Pressurized
container: Do not pierce or burn, even after use. Do not spray on an open flame or
other ignition source. Use only outdoors or in a well-ventilated area. Do not breathe
dust or mist. Wash hands thoroughly after handling.
Response : Get medical attention if you feel unwell. IF INHALED: Remove victim to fresh air and
keep at rest in a position comfortable for breathing. Call a POISON CENTER or
physician if you feel unwell. IF SWALLOWED: Immediately call a POISON CENTER or
physician. Do NOT induce vomiting. IF ON SKIN: Wash with plenty of soap and water.
Take off contaminated clothing. Wash contaminated clothing before reuse. If skin
irritation occurs: Get medical attention. IF IN EYES: Rinse cautiously with water for
several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If
eye irritation persists: Get medical attention.
Storage : Store locked up. Protect from sunlight. Do not expose to temperatures exceeding 50
°C/122 °F. Store in a well-ventilated place.
Disposal Dispose of contents and container in accordance with all local, regional, national and
international regulations.
Supplemental label DELAYED EFFECTS FROM LONG TERM OVEREXPOSURE. Contains solvents which
elements can cause permanent brain and nervous system damage. Intentional misuse by
deliberately concentrating and inhaling the contents can be harmful or fatal. WARNING:
This product contains chemicals known to the State of California to cause cancer and
birth defects or other reproductive harm. FOR INDUSTRIAL USE ONLY.
Please refer to the SDS for additional information. Keep upright in a cool, dry place. Do
not discard empty can in trash compactor.
Hazards not otherwise : None known.
classified

Section 3. Composition/information on ingredients


Substance/mixture : Mixture
Other means of : Not available.
identification

CAS number/other identifiers


Ingredient name % by weight CAS number
Med. Aliphatic Hydrocarbon Solvent 49.3 64742-88-7
Kerosine, petroleum 15.0 8008-20-6
2-Butoxyethanol 10.5 111-76-2
Heavy Paraffinic Oil 8.0 64742-65-0
Propane 7.7 74-98-6
Butane 7.3 106-97-8
Calcium Dinonylnaphthalene Sulfonate 1.0 57855-77-3
There are no additional ingredients present which, within the current knowledge of the supplier and in the
concentrations applicable, are classified as hazardous to health or the environment and hence require reporting
in this section.
Occupational exposure limits, if available, are listed in Section 8.

Date of issue/Date of revision : 3/24/2015. Date of previous issue : No previous validation. Version :1 2/13
Section 4. First aid measures
Description of necessary first aid measures
Eye contact : Immediately flush eyes with plenty of water, occasionally lifting the upper and lower
eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10
minutes. Get medical attention.
Inhalation : Remove victim to fresh air and keep at rest in a position comfortable for breathing. If it
is suspected that fumes are still present, the rescuer should wear an appropriate mask
or self-contained breathing apparatus. If not breathing, if breathing is irregular or if
respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It
may be dangerous to the person providing aid to give mouth-to-mouth resuscitation.
Get medical attention. If necessary, call a poison center or physician. If unconscious,
place in recovery position and get medical attention immediately. Maintain an open
airway. Loosen tight clothing such as a collar, tie, belt or waistband.
Skin contact : Flush contaminated skin with plenty of water. Remove contaminated clothing and
shoes. Continue to rinse for at least 10 minutes. Get medical attention. Wash clothing
before reuse. Clean shoes thoroughly before reuse.
Ingestion : Get medical attention immediately. Call a poison center or physician. Wash out mouth
with water. Remove dentures if any. Remove victim to fresh air and keep at rest in a
position comfortable for breathing. If material has been swallowed and the exposed
person is conscious, give small quantities of water to drink. Stop if the exposed person
feels sick as vomiting may be dangerous. Aspiration hazard if swallowed. Can enter
lungs and cause damage. Do not induce vomiting. If vomiting occurs, the head should
be kept low so that vomit does not enter the lungs. Never give anything by mouth to an
unconscious person. If unconscious, place in recovery position and get medical
attention immediately. Maintain an open airway. Loosen tight clothing such as a collar,
tie, belt or waistband.

Most important symptoms/effects, acute and delayed


Potential acute health effects
Eye contact : Causes serious eye irritation.
Inhalation : Can cause central nervous system (CNS) depression. May cause drowsiness and
dizziness. May cause respiratory irritation.
Skin contact : Causes skin irritation.
Ingestion : Can cause central nervous system (CNS) depression. May be fatal if swallowed and
enters airways. Irritating to mouth, throat and stomach.
Over-exposure signs/symptoms
Eye contact : Adverse symptoms may include the following:
pain or irritation
watering
redness
Inhalation : Adverse symptoms may include the following:
respiratory tract irritation
coughing
nausea or vomiting
headache
drowsiness/fatigue
dizziness/vertigo
unconsciousness
Skin contact : Adverse symptoms may include the following:
irritation
redness
Ingestion : Adverse symptoms may include the following:
nausea or vomiting

Indication of immediate medical attention and special treatment needed, if necessary

Date of issue/Date of revision : 3/24/2015. Date of previous issue : No previous validation. Version :1 3/13
Section 4. First aid measures
Notes to physician : Treat symptomatically. Contact poison treatment specialist immediately if large
quantities have been ingested or inhaled.
Specific treatments : No specific treatment.
Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. If it is
suspected that fumes are still present, the rescuer should wear an appropriate mask or
self-contained breathing apparatus. It may be dangerous to the person providing aid to
give mouth-to-mouth resuscitation.

See toxicological information (Section 11)

Section 5. Fire-fighting measures


Extinguishing media
Suitable extinguishing : Use an extinguishing agent suitable for the surrounding fire.
media
Unsuitable extinguishing : None known.
media

Specific hazards arising : Extremely flammable aerosol. In a fire or if heated, a pressure increase will occur and
from the chemical the container may burst, with the risk of a subsequent explosion. Gas may accumulate
in low or confined areas or travel a considerable distance to a source of ignition and
flash back, causing fire or explosion. Bursting aerosol containers may be propelled from
a fire at high speed. Runoff to sewer may create fire or explosion hazard. Fire water
contaminated with this material must be contained and prevented from being discharged
to any waterway, sewer or drain.
Hazardous thermal : Decomposition products may include the following materials:
decomposition products carbon dioxide
carbon monoxide
sulfur oxides
metal oxide/oxides

Special protective actions : Promptly isolate the scene by removing all persons from the vicinity of the incident if
for fire-fighters there is a fire. No action shall be taken involving any personal risk or without suitable
training. Move containers from fire area if this can be done without risk. Use water
spray to keep fire-exposed containers cool.
Special protective : Fire-fighters should wear appropriate protective equipment and self-contained breathing
equipment for fire-fighters apparatus (SCBA) with a full face-piece operated in positive pressure mode.

Section 6. Accidental release measures


Personal precautions, protective equipment and emergency procedures
For non-emergency : No action shall be taken involving any personal risk or without suitable training.
personnel Evacuate surrounding areas. Keep unnecessary and unprotected personnel from
entering. In the case of aerosols being ruptured, care should be taken due to the rapid
escape of the pressurized contents and propellant. If a large number of containers are
ruptured, treat as a bulk material spillage according to the instructions in the clean-up
section. Do not touch or walk through spilled material. Shut off all ignition sources. No
flares, smoking or flames in hazard area. Avoid breathing vapor or mist. Provide
adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put
on appropriate personal protective equipment.
For emergency responders : If specialised clothing is required to deal with the spillage, take note of any information in
Section 8 on suitable and unsuitable materials. See also the information in "For non-
emergency personnel".

Environmental precautions :

Date of issue/Date of revision : 3/24/2015. Date of previous issue : No previous validation. Version :1 4/13
Section 6. Accidental release measures
Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains
and sewers. Inform the relevant authorities if the product has caused environmental
pollution (sewers, waterways, soil or air). Water polluting material. May be harmful to
the environment if released in large quantities.

Methods and materials for containment and cleaning up


Small spill : Stop leak if without risk. Move containers from spill area. Use spark-proof tools and
explosion-proof equipment. Dilute with water and mop up if water-soluble. Alternatively,
or if water-insoluble, absorb with an inert dry material and place in an appropriate waste
disposal container. Dispose of via a licensed waste disposal contractor.
Large spill : Stop leak if without risk. Move containers from spill area. Use spark-proof tools and
explosion-proof equipment. Approach release from upwind. Prevent entry into sewers,
water courses, basements or confined areas. Wash spillages into an effluent treatment
plant or proceed as follows. Contain and collect spillage with non-combustible,
absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in
container for disposal according to local regulations (see Section 13). Dispose of via a
licensed waste disposal contractor. Contaminated absorbent material may pose the
same hazard as the spilled product. Note: see Section 1 for emergency contact
information and Section 13 for waste disposal.

Section 7. Handling and storage


Precautions for safe handling
Protective measures : Put on appropriate personal protective equipment (see Section 8). Pressurized
container: protect from sunlight and do not expose to temperatures exceeding 50°C. Do
not pierce or burn, even after use. Do not breathe vapor or mist. Do not swallow.
Avoid contact with eyes, skin and clothing. Avoid breathing gas. Avoid release to the
environment. Use only with adequate ventilation. Wear appropriate respirator when
ventilation is inadequate. Store and use away from heat, sparks, open flame or any
other ignition source. Use explosion-proof electrical (ventilating, lighting and material
handling) equipment. Use only non-sparking tools. Empty containers retain product
residue and can be hazardous.
Advice on general : Eating, drinking and smoking should be prohibited in areas where this material is
occupational hygiene handled, stored and processed. Workers should wash hands and face before eating,
drinking and smoking. Remove contaminated clothing and protective equipment before
entering eating areas. See also Section 8 for additional information on hygiene
measures.

Conditions for safe storage, : Store in accordance with local regulations. Store away from direct sunlight in a dry, cool
including any and well-ventilated area, away from incompatible materials (see Section 10) and food
incompatibilities and drink. Protect from sunlight. Store locked up. Eliminate all ignition sources. Use
appropriate containment to avoid environmental contamination.

Section 8. Exposure controls/personal protection


Control parameters
Occupational exposure limits
Ingredient name Exposure limits
Med. Aliphatic Hydrocarbon Solvent OSHA PEL (United States, 2/2013).
TWA: 100 ppm 8 hours.
TWA: 400 mg/m³ 8 hours.
Kerosine, petroleum NIOSH REL (United States, 10/2013).
TWA: 100 mg/m³ 10 hours.
ACGIH TLV (United States, 4/2014).
Absorbed through skin.
TWA: 200 mg/m³, (as total hydrocarbon
vapor) 8 hours.

Date of issue/Date of revision : 3/24/2015. Date of previous issue : No previous validation. Version :1 5/13
Section 8. Exposure controls/personal protection
2-Butoxyethanol ACGIH TLV (United States, 4/2014).
TWA: 20 ppm 8 hours.
NIOSH REL (United States, 10/2013).
Absorbed through skin.
TWA: 5 ppm 10 hours.
TWA: 24 mg/m³ 10 hours.
OSHA PEL (United States, 2/2013).
Absorbed through skin.
TWA: 50 ppm 8 hours.
TWA: 240 mg/m³ 8 hours.
Heavy Paraffinic Oil ACGIH TLV (United States, 4/2014).
TWA: 5 mg/m³ 8 hours. Form: Inhalable
fraction
NIOSH REL (United States, 10/2013).
TWA: 5 mg/m³ 10 hours. Form: Mist
STEL: 10 mg/m³ 15 minutes. Form: Mist
OSHA PEL (United States, 2/2013).
TWA: 5 mg/m³ 8 hours.
Propane NIOSH REL (United States, 10/2013).
TWA: 1000 ppm 10 hours.
TWA: 1800 mg/m³ 10 hours.
OSHA PEL (United States, 2/2013).
TWA: 1000 ppm 8 hours.
TWA: 1800 mg/m³ 8 hours.
Butane NIOSH REL (United States, 10/2013).
TWA: 800 ppm 10 hours.
TWA: 1900 mg/m³ 10 hours.
ACGIH TLV (United States, 4/2014).
STEL: 1000 ppm 15 minutes.

Appropriate engineering : Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or
controls other engineering controls to keep worker exposure to airborne contaminants below any
recommended or statutory limits. The engineering controls also need to keep gas,
vapor or dust concentrations below any lower explosive limits. Use explosion-proof
ventilation equipment.
Environmental exposure : Emissions from ventilation or work process equipment should be checked to ensure
controls they comply with the requirements of environmental protection legislation. In some
cases, fume scrubbers, filters or engineering modifications to the process equipment
will be necessary to reduce emissions to acceptable levels.

Individual protection measures


Hygiene measures : Wash hands, forearms and face thoroughly after handling chemical products, before
eating, smoking and using the lavatory and at the end of the working period.
Appropriate techniques should be used to remove potentially contaminated clothing.
Wash contaminated clothing before reusing. Ensure that eyewash stations and safety
showers are close to the workstation location.
Eye/face protection : Safety eyewear complying with an approved standard should be used when a risk
assessment indicates this is necessary to avoid exposure to liquid splashes, mists,
gases or dusts. If contact is possible, the following protection should be worn, unless
the assessment indicates a higher degree of protection: chemical splash goggles.
Skin protection
Hand protection : Chemical-resistant, impervious gloves complying with an approved standard should be
worn at all times when handling chemical products if a risk assessment indicates this is
necessary. Considering the parameters specified by the glove manufacturer, check
during use that the gloves are still retaining their protective properties. It should be
noted that the time to breakthrough for any glove material may be different for different
glove manufacturers. In the case of mixtures, consisting of several substances, the
protection time of the gloves cannot be accurately estimated.
Date of issue/Date of revision : 3/24/2015. Date of previous issue : No previous validation. Version :1 6/13
Section 8. Exposure controls/personal protection
Body protection : Personal protective equipment for the body should be selected based on the task being
performed and the risks involved and should be approved by a specialist before
handling this product. When there is a risk of ignition from static electricity, wear anti-
static protective clothing. For the greatest protection from static discharges, clothing
should include anti-static overalls, boots and gloves.
Other skin protection : Appropriate footwear and any additional skin protection measures should be selected
based on the task being performed and the risks involved and should be approved by a
specialist before handling this product.
Respiratory protection : Use a properly fitted, air-purifying or air-fed respirator complying with an approved
standard if a risk assessment indicates this is necessary. Respirator selection must be
based on known or anticipated exposure levels, the hazards of the product and the safe
working limits of the selected respirator.

Section 9. Physical and chemical properties


Appearance
Physical state : Liquid.
Color : Not available.
Odor : Not available.
Odor threshold : Not available.
pH : Not available.
Melting point : Not available.
Boiling point : Not available.
Flash point : Closed cup: -29°C (-20.2°F) [Pensky-Martens Closed Cup]
Evaporation rate : 1 (butyl acetate = 1)
Flammability (solid, gas) : Not available.
Lower and upper explosive : Lower: 0.7%
(flammable) limits Upper: 10.6%
Vapor pressure : 13.5 kPa (101.325 mm Hg) [at 20°C]
Vapor density : 1.55 [Air = 1]
Relative density : 0.74
Solubility : Not available.
Partition coefficient: n- : Not available.
octanol/water
Auto-ignition temperature : Not available.
Decomposition temperature : Not available.
Viscosity : Kinematic (room temperature): <0.07 cm2/s (<7 cSt)
Kinematic (40°C (104°F)): <0.07 cm2/s (<7 cSt)
Aerosol product
Type of aerosol : Spray
Heat of combustion : 0.00003961 kJ/g

Section 10. Stability and reactivity


Reactivity : No specific test data related to reactivity available for this product or its ingredients.

Chemical stability : The product is stable.

Possibility of hazardous : Under normal conditions of storage and use, hazardous reactions will not occur.
reactions

Conditions to avoid : Avoid all possible sources of ignition (spark or flame).


Date of issue/Date of revision : 3/24/2015. Date of previous issue : No previous validation. Version :1 7/13
Section 10. Stability and reactivity

Incompatible materials : No specific data.

Hazardous decomposition : Under normal conditions of storage and use, hazardous decomposition products should
products not be produced.

Section 11. Toxicological information


Information on toxicological effects
Acute toxicity
Product/ingredient name Result Species Dose Exposure
Kerosine, petroleum LD50 Oral Rat 15 g/kg -
2-Butoxyethanol LCLo Inhalation Vapor Guinea pig >3.1 mg/l 1 hours
LD50 Dermal Guinea pig >2000 mg/kg -
LD50 Oral Rat 1300 mg/kg -
Heavy Paraffinic Oil LD50 Dermal Rabbit >5000 mg/kg -
LD50 Oral Rat >5000 mg/kg -
Butane LC50 Inhalation Vapor Rat 658000 mg/m³ 4 hours
Calcium Dinonylnaphthalene LD50 Dermal Rabbit >20 g/kg -
Sulfonate
LD50 Oral Rat >5000 mg/kg -
Irritation/Corrosion
Product/ingredient name Result Species Score Exposure Observation
Kerosine, petroleum Skin - Moderate irritant Rabbit - 0.5 Mililiters -
Skin - Moderate irritant Rabbit - 24 hours 100 -
Percent
Skin - Severe irritant Rabbit - 500 -
milligrams
2-Butoxyethanol Eyes - Moderate irritant Rabbit - 24 hours 100 -
milligrams
Eyes - Severe irritant Rabbit - 100 -
milligrams
Skin - Mild irritant Rabbit - 500 -
milligrams
Calcium Dinonylnaphthalene Skin - Moderate irritant Rabbit - 0.5 Mililiters -
Sulfonate
Sensitization
Not available.
Mutagenicity
Not available.
Carcinogenicity
Not available.

Classification
Product/ingredient name OSHA IARC NTP
Kerosine, petroleum - 3 -
2-Butoxyethanol - 3 -
Reproductive toxicity
Not available.
Teratogenicity
Not available.

Date of issue/Date of revision : 3/24/2015. Date of previous issue : No previous validation. Version :1 8/13
Section 11. Toxicological information
Specific target organ toxicity (single exposure)
Name Category Route of Target organs
exposure
Med. Aliphatic Hydrocarbon Solvent Category 3 Not applicable. Respiratory tract
irritation and
Narcotic effects
Kerosine, petroleum Category 3 Not applicable. Respiratory tract
irritation and
Narcotic effects
2-Butoxyethanol Category 3 Not applicable. Respiratory tract
irritation and
Narcotic effects
Heavy Paraffinic Oil Category 3 Not applicable. Respiratory tract
irritation and
Narcotic effects
Propane Category 3 Not applicable. Respiratory tract
irritation and
Narcotic effects
Butane Category 3 Not applicable. Respiratory tract
irritation and
Narcotic effects
Specific target organ toxicity (repeated exposure)
Name Category Route of Target organs
exposure
Med. Aliphatic Hydrocarbon Solvent Category 2 Not determined Not determined
Kerosine, petroleum Category 2 Not determined Not determined
2-Butoxyethanol Category 2 Not determined Not determined
Heavy Paraffinic Oil Category 2 Not determined Not determined
Propane Category 2 Not determined Not determined
Butane Category 2 Not determined Not determined
Aspiration hazard
Name Result
Med. Aliphatic Hydrocarbon Solvent ASPIRATION HAZARD - Category 1
Propane ASPIRATION HAZARD - Category 1
Butane ASPIRATION HAZARD - Category 1

Information on the likely : Not available.


routes of exposure
Potential acute health effects
Eye contact : Causes serious eye irritation.
Inhalation : Can cause central nervous system (CNS) depression. May cause drowsiness and
dizziness. May cause respiratory irritation.
Skin contact : Causes skin irritation.
Ingestion : Can cause central nervous system (CNS) depression. May be fatal if swallowed and
enters airways. Irritating to mouth, throat and stomach.

Symptoms related to the physical, chemical and toxicological characteristics


Eye contact : Adverse symptoms may include the following:
pain or irritation
watering
redness

Date of issue/Date of revision : 3/24/2015. Date of previous issue : No previous validation. Version :1 9/13
Inhalation : Adverse symptoms may include the following:
respiratory tract irritation
coughing
nausea or vomiting
headache
drowsiness/fatigue
dizziness/vertigo
unconsciousness
Skin contact : Adverse symptoms may include the following:
irritation
redness
Ingestion : Adverse symptoms may include the following:
nausea or vomiting

Delayed and immediate effects and also chronic effects from short and long term exposure
Short term exposure
Potential immediate : Not available.
effects
Potential delayed effects : Not available.
Long term exposure
Potential immediate : Not available.
effects
Potential delayed effects : Not available.
Potential chronic health effects
Not available.
General : May cause damage to organs through prolonged or repeated exposure.
Carcinogenicity : No known significant effects or critical hazards.
Mutagenicity : No known significant effects or critical hazards.
Teratogenicity : No known significant effects or critical hazards.
Developmental effects : No known significant effects or critical hazards.
Fertility effects : No known significant effects or critical hazards.

Numerical measures of toxicity


Acute toxicity estimates
Route ATE value
Oral 5330 mg/kg

Section 12. Ecological information


Toxicity
Product/ingredient name Result Species Exposure
2-Butoxyethanol Acute EC50 >1000 mg/l Fresh water Daphnia - Daphnia magna 48 hours
Acute LC50 800000 µg/l Marine water Crustaceans - Crangon crangon 48 hours
Acute LC50 1250000 µg/l Marine water Fish - Menidia beryllina 96 hours

Persistence and degradability


Product/ingredient name Aquatic half-life Photolysis Biodegradability
2-Butoxyethanol - - Readily

Date of issue/Date of revision : 3/24/2015. Date of previous issue : No previous validation. Version :1 10/13
Section 12. Ecological information
Bioaccumulative potential
Not available.

Mobility in soil
Soil/water partition : Not available.
coefficient (KOC)

Other adverse effects : No known significant effects or critical hazards.

Section 13. Disposal considerations


Disposal methods : The generation of waste should be avoided or minimized wherever possible. Disposal
of this product, solutions and any by-products should at all times comply with the
requirements of environmental protection and waste disposal legislation and any
regional local authority requirements. Dispose of surplus and non-recyclable products
via a licensed waste disposal contractor. Waste should not be disposed of untreated to
the sewer unless fully compliant with the requirements of all authorities with jurisdiction.
Waste packaging should be recycled. Incineration or landfill should only be considered
when recycling is not feasible. This material and its container must be disposed of in a
safe way. Empty containers or liners may retain some product residues. Do not
puncture or incinerate container.

Section 14. Transport information


DOT TDG Mexico IATA IMDG
Classification Classification Classification
UN number UN1950 UN1950 UN1950 UN1950 UN1950

UN proper AEROSOLS AEROSOLS AEROSOLS AEROSOLS, AEROSOLS


shipping name flammable
Transport 2.1 2.1 2.1 2.1 2.1
hazard class(es)

Packing group - - - - -
Environmental No. No. No. No. No.
hazards
Additional Special Special Special Special Emergency
information provisions provisions provisions provisions schedules (EmS)
LIMITED LIMITED (ERG#126) LIMITED LIMITED
QUANTITY QUANTITY QUANTITY QUANTITY, F-D,
S-U

Special precautions for user : Multi-modal shipping descriptions are provided for informational purposes and do not
consider container sizes. The presence of a shipping description for a particular
mode of transport (sea, air, etc.), does not indicate that the product is packaged
suitably for that mode of transport. All packaging must be reviewed for suitability prior
to shipment, and compliance with the applicable regulations is the sole responsibility
of the person offering the product for transport. People loading and unloading
dangerous goods must be trained on all of the risks deriving from the substances
and on all actions in case of emergency situations.

Date of issue/Date of revision : 3/24/2015. Date of previous issue : No previous validation. Version :1 11/13
Section 14. Transport information
Transport in bulk according : Not available.
to Annex II of MARPOL
73/78 and the IBC Code

Section 15. Regulatory information


U.S. Federal regulations :
State regulations
California Prop. 65
WARNING: This product contains chemicals known to the State of California to cause cancer and birth defects or other
reproductive harm.

Section 16. Other information


Hazardous Material Information System (U.S.A.)
Health 2

Flammability 4
Physical hazards 0

Caution: HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4
representing significant hazards or risks Although HMIS® ratings are not required on SDSs under 29 CFR 1910.
1200, the preparer may choose to provide them. HMIS® ratings are to be used with a fully implemented HMIS®
program. HMIS® is a registered mark of the National Paint & Coatings Association (NPCA). HMIS® materials may
be purchased exclusively from J. J. Keller (800) 327-6868.
The customer is responsible for determining the PPE code for this material.

Notice to reader
It is recommended that each customer or recipient of this Safety Data Sheet (SDS) study it carefully and consult
resources, as necessary or appropriate, to become aware of and understand the data contained in this SDS and
any hazards associated with the product. This information is provided in good faith and believed to be accurate
as of the effective date herein. However, no warranty, express or implied, is given. The information presented
here applies only to the product as shipped. The addition of any material can change the composition, hazards
and risks of the product. Regulatory requirements are subject to change and may differ between various
locations and jurisdictions. The customer/buyer/user is responsible to ensure that his activities comply with all
country, federal, state, provincial or local laws. The conditions for use of the product are not under the control of
the manufacturer; the customer/buyer/user is responsible to determine the conditions necessary for the safe use
of this product. The customer/buyer/user should not use the product for any purpose other than the purpose
shown in the applicable section of this SDS without first referring to the supplier and obtaining written handling
instructions. Due to the proliferation of sources for information such as manufacturer-specific SDS, the
manufacturer cannot be responsible for SDSs obtained from any other source.

Date of issue/Date of revision : 3/24/2015. Date of previous issue : No previous validation. Version :1 12/13
Section 16. Other information

Date of issue/Date of revision : 3/24/2015. Date of previous issue : No previous validation. Version :1 13/13
NFPA Hazard Rating
Flammability

0
Health 0 0 Reactivity

Material Safety Data Sheet


0 = Minimum 1 = Light 2 = Moderate 3 = Serious 4 = Extreme

1. PRODUCT AND COMPANY IDENTIFICATION


Product Name BIO-RUST
Product Identifier 53-G 241 (1,5L), 53-G 247 (20L), 53-G 248 (208L), 53-G 249 (1000L)
MSDS No. L-134E
Product Family Cleaning and Degreasing
Manufacturer / Supplier Walter Surface Technologies Inc., 5977 Trans-Canada Highway, Pointe-Claire, Qc, H9R 1C1,
1-888-592-5837, www.walter.com
Emergency Contact CANUTEC (Canadian Transport Emergency Centre), (613) 996-6666,
24 hours / 7 days
Information Use Non-corrosive rust remover

2. HAZARDS IDENTIFICATION
WHMIS Classification Not a WHMIS controlled product.
Potential Health Effects
Route of Exposure Skin contact; eye contact; ingestion
Skin Contact Not irritating
Eye Contact May cause slight eye irritation.
Ingestion May cause slight nausea.

3. COMPOSITION/INFORMATION ON INGREDIENTS
Contains no hazardous ingredients.

4. FIRST AID MEASURES


First Aid Procedures
Eye Contact Immediately flush the contaminated eye(s) with lukewarm, gently flowing water for 5 minutes,
while holding the eyelid(s) open. If irritation or pain persists, see a doctor.
Ingestion Have victim rinse mouth with water. Give plenty of water to drink. DO NOT INDUCE
VOMITING. Call a Poison Centre or doctor if the victim feels unwell.

5. FIRE FIGHTING MEASURES


Flammable Properties Does not burn.
Suitable Extinguishing Media Carbon dioxide, dry chemical powder or appropriate foam.
Unsuitable Extinguishing Media None known
Specific Hazards Arising from the This product presents no unusual hazards in a fire situation.
Chemical
Protective Equipment and No special precautions are necessary. Review Section 6 (Accidental Release Measures) for
Precautions for Firefighters important information on responding to leaks/spills.

Page 1 of 3
6. ACCIDENTAL RELEASE MEASURES
Personal Precautions Slippery after spillage or leakage.
Environmental Precautions No special precautions are necessary.
Methods for Containment and Contain and soak up spill with absorbent that does not react with spilled product. Flush spill
Clean-up area. Review Section 13 (Disposal Considerations) of this MSDS.

7. HANDLING AND STORAGE


Handling No special handling precautions are necessary.
Storage Protect from freezing.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION


Engineering Controls Provide eyewash in work area, if contact or splash hazard exists.
Personal Protective Equipment (PPE)
Eye/Face Protection Wear chemical safety goggles or face shield when contact is possible.
Skin Protection Wear chemical protective gloves for long lasting skin contact.

9. PHYSICAL AND CHEMICAL PROPERTIES


Physical State Liquid
Appearance Clear yellow liquid
Odour Mild
Boiling Point < 93 °C (199 °F)
Freezing Point 0 °C (32 °F)
Relative Density (water = 1) 1
Specific gravity 1.1 - 1.2
Solubility in Water Soluble
pH ~ 5,2
Evaporation Rate > 1 (diethyl ether = 1)
Flash Point Not applicable
Lower Flammable/Explosive Not applicable
Limit
Upper Flammable/Explosive Not applicable
Limit
Auto-ignition Temperature Not applicable

10. STABILITY AND REACTIVITY


Chemical Stability Normally stable
Conditions to Avoid High temperatures
Incompatible Materials Strong oxidizing agents (e.g. perchloric acid). And other reactive materials.
Hazardous Decomposition Carbon oxide.
Products

11. TOXICOLOGICAL INFORMATION


Eye Irritation / Corrosion Slight irritation of eyes possible.
Effects of Short-Term (Acute) Exposure
Ingestion May cause slight nausea.
Page 2 of 3
12. ECOLOGICAL INFORMATION
Ecotoxicity Studies were not located.
Persistence and Degradability No information was located.
Bioaccumulation / Accumulation No information was located.

Mobility Studies are not available.

13. DISPOSAL CONSIDERATIONS


Eliminate while respecting municipal, provincial and federal regulations.

14. TRANSPORT INFORMATION


Shipping Information Not regulated under Canadian TDG Regulations. Not regulated under US DOT Regulations.

Other Transport Information


Special Shipping Information Please note: Protect from freezing.

15. REGULATORY INFORMATION


Canada
Domestic Substances List (DSL) All ingredients are listed on the DSL.
CEPA - National Pollutant Not specifically listed.
Release Inventory (NPRI)
USA
US OSHA Regulatory Status While this material is not considered hazardous by the OSHA Hazard Communication Standard
(29 CFR 1910.1200), this MSDS contains valuable information critical to the safe handling and
proper use of the product. This MSDS should be retained and available for employees and
other users of this product.
Additional USA Regulatory Lists
CERCLA: RQ: None
SARA Title III - Section 302: None
SARA Title III - Section 311/312: None
SARA Title III - Section 313: None
New Jersey Right To Know: None
Section 112: Hazardous Air Pollutants (HAPS): None

16. OTHER INFORMATION


MSDS Prepared By Project Manager, Environmental Solutions and MRO
Phone No. 1-888-592-5837
Date of Preparation February 2015

Page 3 of 3
Material Safety Data Sheet
according to ANSI Z400.1- 2004 and 29 CFR 1910.1200

BON AMI® POWER FOAM GLASS CLEANER


Version 2.0 Print Date 11/17/2015

Revision Date 09/29/2015 MSDS Number 350000021130

1. PRODUCT AND COMPANY IDENTIFICATION

Product information
Trade name : BON AMI® POWER FOAM GLASS CLEANER

Use of the : Hard Surface Cleaner


Substance/Mixture
Company : S.C. Johnson and Son, Limited
1 Webster Street
Brantford ON N3T 5R1

Emergency telephone : 24 Hour Transport & Medical Emergency Phone (866) 231-
number 5406
24 Hour International Emergency Phone (952) 852-4647
24 Hour Canadian Transport Emergency Phone (CANUTEC)
(613) 996-6666

2. HAZARDS IDENTIFICATION
Emergency Overview
Appearance / Odor : translucent / aerosol Compressed gas / characteristic

Immediate Concerns : Caution


Avoid contact with skin, eyes and clothing.
Keep away from heat, sparks and flame.
Do not puncture or incinerate.
Do not store at temperatures above 120 Deg. F (50 Deg C), as
container may burst.
Contents under pressure.

Potential Health Effects


Exposure routes : Eye, Skin, Inhalation, Ingestion.

Eyes : May cause:


Mild eye irritation

Skin : Prolonged or repeated contact may dry skin and cause irritation.

Inhalation : No adverse effects expected when used as directed.

Ingestion : May cause irritation to mouth, throat and stomach.


May cause abdominal discomfort.

Aggravated Medical : Persons with pre-existing skin disorders may be more


Condition susceptible to irritating effects.

1/8
Material Safety Data Sheet
according to ANSI Z400.1- 2004 and 29 CFR 1910.1200

BON AMI® POWER FOAM GLASS CLEANER


Version 2.0 Print Date 11/17/2015

Revision Date 09/29/2015 MSDS Number 350000021130

3. COMPOSITION/INFORMATION ON INGREDIENTS

Hazardous chemicals present at or above reportable levels as defined by OSHA 29 CFR 1910.1200 or
the Canadian Controlled Products Regulations are listed in this table:

Chemical Name CAS-No. Weight percent


Isobutane 75-28-5 1.00 - 5.00
Propylene glycol monobutyl 5131-66-8
1.00 - 5.00
ether

For additional information on product ingredients, see www.whatsinsidescjohnson.com.

4. FIRST AID MEASURES

Eye contact : Rinse with plenty of water. Get medical attention if irritation
develops and persists.

Skin contact : Rinse with plenty of water. Get medical attention if irritation
develops and persists.

Inhalation : Remove to fresh air. If breathing is affected, get medical


attention.

Ingestion : Rinse mouth with water.

5. FIREFIGHTING MEASURES

Suitable extinguishing : Use water spray, alcohol-resistant foam, dry chemical or


media carbon dioxide.

Specific hazards during : Aerosol Product - Containers may rocket or explode in heat of
firefighting fire.

Further information : Fight fire from maximum distance or protected area. Cool and
use caution when approaching or handling fire-exposed
containers. Wear full protective clothing and positive pressure
self-contained breathing apparatus. In case of fire and/or
explosion do not breathe fumes.

Flash point : < -7 C


< 19.4 °F
Method: Tag Closed Cup (TCC)
Note: Propellant

Lower explosion limit : Note: No data available

2/8
Material Safety Data Sheet
according to ANSI Z400.1- 2004 and 29 CFR 1910.1200

BON AMI® POWER FOAM GLASS CLEANER


Version 2.0 Print Date 11/17/2015

Revision Date 09/29/2015 MSDS Number 350000021130

Upper explosion limit : Note: No data available

6. ACCIDENTAL RELEASE MEASURES

Personal precautions : Remove all sources of ignition.


Wear personal protective equipment.

Environmental precautions : Outside of normal use, avoid release to the environment.

Methods for cleaning up : If damage occurs to aerosol can:


Contain spillage, soak up with non-combustible absorbent
material, (e.g. sand, earth, diatomaceous earth, vermiculite)
and transfer to a container for disposal according to local /
national regulations (see section 13).
Use only non-sparking equipment.
Clean residue from spill site.

7. HANDLING AND STORAGE

Handling
Advice on safe handling : Do not puncture or incinerate.
Avoid breathing vapours, mist or gas.
Do not spray toward face.
Do not use in areas without adequate ventilation.
Use only as directed.
KEEP OUT OF REACH OF CHILDREN AND PETS.

Advice on protection : Keep away from heat and sources of ignition.


against fire and explosion

Storage
Requirements for storage : Do not store at temperatures above 120 Deg. F (50 Deg C), as
areas and containers container may burst.
Keep container closed when not in use.
Keep in a dry, cool and well-ventilated place.

3/8
Material Safety Data Sheet
according to ANSI Z400.1- 2004 and 29 CFR 1910.1200

BON AMI® POWER FOAM GLASS CLEANER


Version 2.0 Print Date 11/17/2015

Revision Date 09/29/2015 MSDS Number 350000021130

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Occupational Exposure Limits


Components CAS-No. mg/m3 ppm Non- Basis
standard
units
Isobutane 75-28-5 - 1,000 ppm - ACGIH
STEL

Personal protective equipment


Respiratory protection No personal respiratory protective equipment normally
required.

Hand protection : No special requirements.

Eye protection No special requirements.

Skin and body protection : No special requirements.

Hygiene measures : Handle in accordance with good industrial hygiene and safety
practice. Wash thoroughly after handling.

9. PHYSICAL AND CHEMICAL PROPERTIES

Form : aerosol
Compressed gas

Color : translucent

Odor : characteristic

pH : 11
at 25 C(undiluted)

Melting point : No data available

Boiling point : No data available

Freezing point : No data available

Flash point : < -7 C


< 19.4 °F
Method: Tag Closed Cup (TCC)
Propellant

4/8
Material Safety Data Sheet
according to ANSI Z400.1- 2004 and 29 CFR 1910.1200

BON AMI® POWER FOAM GLASS CLEANER


Version 2.0 Print Date 11/17/2015

Revision Date 09/29/2015 MSDS Number 350000021130

Evaporation rate : No data available

Flammability (solid, gas) : Does not sustain combustion.

Auto-ignition temperature : not auto-flammable

Lower explosion limit : No data available

Upper explosion limit : No data available

Vapour pressure : No data available

Density : 8.327 lb/gal


at 20 C
Water solubility : soluble

Partition coefficient: n- :
octanol/water No data available

Viscosity, dynamic : No data available

Viscosity, kinematic : No data available

Relative vapour density : No data available

Volatile Organic Compounds : 6.9 % - additional exemptions may apply


Total VOC (wt. %)* *as defined by US Federal and State Consumer Product
Regulations

10. STABILITY AND REACTIVITY

Conditions to avoid : Heat, flames and sparks.

Materials to avoid : Strong acids

Hazardous decomposition : Thermal decomposition can lead to release of irritating gases


products and vapours.

Thermal decomposition : Note: No data available

Hazardous reactions : Stable under recommended storage conditions.

11. TOXICOLOGICAL INFORMATION

Acute oral toxicity : LD50


Measured
> 5,000 mg/kg

5/8
Material Safety Data Sheet
according to ANSI Z400.1- 2004 and 29 CFR 1910.1200

BON AMI® POWER FOAM GLASS CLEANER


Version 2.0 Print Date 11/17/2015

Revision Date 09/29/2015 MSDS Number 350000021130

Acute inhalation toxicity : LC50


Measured
> 5.59 mg/l

Acute dermal toxicity : LD50


Measured
> 5,000 mg/kg

Chronic effects
Carcinogenicity : No data available

Mutagenicity : No data available

Reproductive effects : No data available

Teratogenicity : No data available

Sensitisation : Did not cause sensitisation on laboratory animals.

12. ECOLOGICAL INFORMATION

Ecotoxicity effects : No data available

13. DISPOSAL CONSIDERATIONS

Observe all applicable Federal, Provincial and State


regulations and Local/Municipal ordinances regarding
disposal.
Consumer may discard empty container in trash, or recycle
where facilities exist.

14. TRANSPORT INFORMATION

Land transport
 U.S. DOT and Canadian TDG Surface Transportation:
Proper shipping name AEROSOLS, Flammable, 2.1

6/8
Material Safety Data Sheet
according to ANSI Z400.1- 2004 and 29 CFR 1910.1200

BON AMI® POWER FOAM GLASS CLEANER


Version 2.0 Print Date 11/17/2015

Revision Date 09/29/2015 MSDS Number 350000021130

Class: 2.1
UN number 1950
Packaging group: None.
Note: Limited quantities derogation may be applicable to this product,
please check transport documents.

Sea transport
 IMDG:
Proper shipping name AEROSOLS, Flammable, 2.1
Class: 2
UN number: 1950
Packaging group: None.
EmS: F-D, S-U
Note: Limited quantities derogation may be applicable to this product,
please check transport documents.

Air transport
 ICAO/IATA:
Proper shipping name AEROSOLS, Flammable, 2.1
Class: 2.1
UN/ID No.: UN 1950
Packaging group: None.
Note: SC Johnson typically does not ship products via air. Refer to
IATA/ICAO Dangerous Goods Regulations for detailed instructions
when shipping this item by air.

15. REGULATORY INFORMATION

Notification status : All ingredients of this product are listed or are excluded from
listing on the U.S. Toxic Substances Control Act (TSCA)
Chemical Substance Inventory.

Notification status : All ingredients of this product comply with the New Substances
Notification requirements under the Canadian Environmental
Protection Act (CEPA).

California Prop. 65 : This product is not subject to the reporting requirements under
California's Proposition 65.
Canada Regulations : This product has been classified in accordance with hazard
criteria of the Controlled Products Regulations and the MSDS
contains all the information required by the Controlled Products
Regulations.

16. OTHER INFORMATION


HMIS Ratings
Health 1

7/8
Material Safety Data Sheet
according to ANSI Z400.1- 2004 and 29 CFR 1910.1200

BON AMI® POWER FOAM GLASS CLEANER


Version 2.0 Print Date 11/17/2015

Revision Date 09/29/2015 MSDS Number 350000021130

Flammability 4

Reactivity 0

NFPA Ratings
Health 1

Fire 4

Reactivity 0

Special -

This information is being provided in accordance with Occupational Safety and Health
Administration (OSHA) and Canada’s Workplace Hazard Material Information System (WHMIS)
regulations. The information supplied is designed for workplaces where product use and
frequency of exposure exceeds that established for the labeled consumer use.

Further information
This document has been prepared using data from sources considered to be technically reliable.
It does not constitute a warranty, expressed or implied, as to the accuracy of the information
contained herein. Actual conditions of use are beyond the seller's control. User is responsible to
evaluate all available information when using product for any particular use and to comply with all
Federal, State, Provincial and Local laws and regulations.

Prepared by SC Johnson Global Safety Assessment &


Regulatory Affairs (GSARA)

8/8
ZL-W01, PENTEL CO., LTD., 3, 2014/04/24, 1/6

Safety Data Sheet (SDS)

Preparation Date  2013/02/05


Revision Date 2014/04/24
Section 1 - CHEMICALS AND COMPANY IDENTIFICATION
Chemical Identifier ZL-W01
Product Code ZL-W010001
Company Name Pentel of America, LTD.
Address 2715 Columbia Street, Torrance Ca. 90503
Company Contact Michael Storie, TQC Manager 909.975.2238
Phone Number 800.421.1419 EXT. 2238
Fax Number 909.975.2291
Mail Address 4000 East Airport Drive, Suite C Ontario California 91761
Emergency Phone
Number 800-421-1972
Recommended Use Correction fluids
and Restriction on
Use
XEZL31-W、ZL31-WK、XEZL1-W、ZL1-WK、XZL6-
W、XEZL61-W、XEZL21-W、XZL7F1C、XZL7F1AD

Section 2 - HAZARDS IDENTIFICATION


GHS Classification
Physicochemical Flammable liquids Category 2
Hazards
Health Hazards Acute toxicity - inhalation (vapour) Category 4
Serious eye damage/eye irritation Category 2B
Carcinogenicity Category 2
Specific target organ toxicity (single exposure)
Category 3(narcotic effect)
Environmental Hazard to the aquatic environment (acute hazard)
Hazards Category 2
Hazard to the aquatic environment (long-term
hazard) Category 2
Other hazards than mentioned above are Not
applicable or No data available.
GHS Label Elements

Symbols

Signal Word Danger


Hazard Statements H225 Highly flammable liquid and vapour
H320 Causes eye irritation
H332 Harmful if inhaled
H336 May cause drowsiness and dizziness
H351 Suspected of causing cancer
H411 Toxic to aquatic life with long lasting effects
Precautionary
Statements
Prevention Keep container tightly closed.(P233)
Precautionary
Statements
Avoid breathing mist, vapours and spray.(P261)
Wear protective gloves, eye protection and face
protection.(P280)
ZL-W01, PENTEL CO., LTD., 3, 2014/04/24, 2/6

Wash hand thoroughly after handling.(P264)


Response IF ON SKIN or hair: Remove or take off
Precautionary immediately all contaminated clothing. Rinse skin
Statements with water or shower.(P303+P361+P353)
IF INHALED: Remove to fresh air and keep at rest
in a position comfortable for
breathing.(P304+P340)
IF IN EYES: Rinse cautiously with water for
several minutes. Remove contact lenses, if
present and easy to do. Continue
rinsing.(P305+P351+P338)
Call a doctor if you feel unwell.(P312)
If eye irritation persists: Get medical advice and
attention.(P337+P313)
In case of fire: Use appropriate media for
extinction.(P370+P378)
Storage Store in a well-ventilated place. Keep
Precautionary cool.(P403+P235)
Statements

Section 3 - COMPOSITION / INFORMATION ON INGREDIENTS


Distinction of Substance mixture
or Mixture
Chemical Name or Concentration or Its ENCS No./ISHL No.
Formula CAS RN
Generic Name Ranges ENCS No. ISHL No.
1-Propanol、2-methyl- 0.4% C4H10O (2)-3049 Existing 78-83-1
Methylcyclohexane 42.4% C7H14 (3)-2230 Existing 108-87-2
Titanium dioxide(Ⅳ) 40.5% TiO2 (1)- Existing 13463-67-7
558,(5)-
5225
Silicon dioxide 1.3% SiO2 (1)-548 Existing 7631-86-9

Impurities and/or No information available


Stabilizing Additives which
Contribute to the

Section 4 - FIRST AID MEASURES


Inhalation Get medical advice and attention if you feel unwell.

呼吸が困難な場合には、新鮮な空気のある場所に
移動し、呼吸しやすい姿勢で休憩させること。
Skin Contact Call a doctor if you feel unwell.
Wash with plenty of soap and water.
If skin irritation occurs: Get medical advice and
attention.
Eye Contact Rinse cautiously with water for several minutes.
Remove contact lenses, if present and easy to do.
Continue rinsing.
When the ocular stimulation lasts, Seek medical
treatment and advice.
Ingestion Rinse mouth. Do NOT induce vomiting.
Get medical advice and attention if you feel unwell.

Section 5 - FIRE FIGHTING MEASURES


Extinguishing Media Dry chemicals, CO2, fog, sand or regular foam.
Unsuitable Extinguishing Straight streams.
Media
ZL-W01, PENTEL CO., LTD., 3, 2014/04/24, 3/6

Protection of Fire Figther In fire fighting, wear respiratory protection and


chemical protective clothing.

Section 6 - ACCIDENTAL RELEASE MEASURES


Personal Precautions, Wear appropriate personal protective equipment
Protective Equipment and (Refer to "Section 8 - EXPOSURE CONTROLS /
Emergency Procedures PERSONAL PROTECTION") and avoid inhalation
or contact with eyes and skin.
Environmental Pay attention not to cause the influence on the
Precautions environment by discharging into rivers.
Methods and Equipment Allow material to solidify, and scrape up.
for Containment and
Cleaning up
Prevention Measures for Prevent flowing into drain, sewage, basement, and
Secondary Accidents closed area.

Section 7 - HANDLING AND STORAGE


Handling Technical Measures Provide ventilation system and use necessary
personal protective equipment as described in
"Section 8 - EXPOSURE CONTROLS /
PERSONAL PROTECTION".
Precautions for Safe Prohibit use of heat, sparks, and fire in the
Handling surrounding area.
Avoid contact with eyes and skin.
Avoid swallowing.
Wash hand thoroughly after handling.
Handle at a well-ventilated place.
Prevents Handling of Refer to "Section 10 - STABILITY AND
Imcompatible REACTIVITY".
Substances or
Mixtures
Storage Precautionary Technical Measures The storage facility should be provided with
Statements necessary lighting, lighting equipment, and
ventilator to store and handle dangerous goods.
Refer to "Section 10 - STABILITY AND
REACTIVITY".
Store in a well-ventilated and cool place keeping
container tightly closed.
Store locked up.
Material Used in Keep only in original container.
Packaging/Container

Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION


Engineering Controls Good general ventilation should be sufficient to
control airborne levels.
Personal Protective Respiratory Use personal respiratory equipment as required.
Equipment Protection
Hand Protection Use personal gloves as required.
Eye Protection Protection glasses (ordinary glasses, ordinary
glasses with side shields, and goggles).
Use personal eye protection as required.
Skin and Body Use personal protective clothing and face
Protection protection as required.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES


Appearance Physical State liquid
Form liquid
Colour white
Odour characteristic
ZL-W01, PENTEL CO., LTD., 3, 2014/04/24, 4/6

Odour threshold No data available


pH No data available
Melting Point/Freezing No data available
Point
Initial Boiling Point and No data available
Boiling Ranges
Flash Point -4.4℃ (Tag Closed Cup)
Evaporation Rate No data available
Flammability (solid, gas) No data available
Flammability or Explosive Lower Limit No data available
Limits
Upper Limit No data available
Vapour Pressure No data available
Vapour Density No data available
Specific Gravity (Density) No data available
Partition Coefficient : n- No data available
Octanol/Water
Auto-Ignition No data available
Decomposition No data available
Temperature
Viscosity No data available
Kinematic viscosity No data available
Flammability or Explosive
Limits
Section 10 - STABILITY AND REACTIVITY
Reactivity No data available
Chemical stability No data available
Possibility of Hazardous No data available
Reaction
Conditions to Avoid No data available
Imcompatible Substances No data available
or Mixtures
Hazardous Decomposition No data available
Products

Section 11 - TOXICOLOGICAL INFORMATION


Acute Toxicity No information available
Skin Corrosion/Irritation No data available
Serious eye damage/eye No data available
irritation
Respiratory or Skin No data available
Sensitization
Germ Cell Mutagenicity No data available
Carcinogenicity No data available
Reproductive Toxicity No data available
Specific target organ No data available
toxicity (single exposure)
Specific target organ No data available
toxicity (repeated
exposure)
Aspiration Hazard No data available

Section 12 - ECOLOGICAL INFORMATION


Hazard to the aquatic No data available
environment (acute
Hazard to the aquatic No data available
environment (long-term
hazard)
Hazard to the ozone layer No data available
ZL-W01, PENTEL CO., LTD., 3, 2014/04/24, 5/6

Section 13 - DISPOSAL CONSIDERATIONS


Residual Waste Disposal should be in accordance with applicable
regulations and standards by the respective local
governments.
Commission a waste disposal company, or a local
public body who are licensed by local or regional
government, to dispose of the material.
Contaminated Container Recycle containers after cleansing, or carry out
and Packaging the disposal under the related laws and regulations
and the standards of the local governments.

Section 14 - TRANSPORT INFORMATION


International Regulations Regulatory Conform to the provisions of IMO.
Information by Sea
UN No. 1263
Proper Shipping PAINT
Class 3
Packing Group Ⅱ
Marine Pollutant Not applicable
Transport in bulk Not applicable
according to
MARPOL
73/78,Annex Ⅱ,and
the IBC code
Regulatory Conform to the provisions of ICAO/IATA.
Information by Air
UN No. 1263
Proper Shipping PAINT
Class 3
Packing Group Ⅱ
Regulations in Japan Regulatory Not applicable
Information by Road
or Rail
Regulatory Conform to the provisions of the Ship Safety Law.
Information by Sea
UN No. 1263
Proper Shipping PAINT
Name.
Class 3
Packing Group Ⅱ
Marine Pollutant Not applicable
Transport in bulk Not applicable
according to
MARPOL
73/78,Annex Ⅱ,and
the IBC code
Regulatory Conform to the provisions of the Ship Safety Law.
Information by Air
UN No. 1263
Proper Shipping PAINT
Name.
Class 3
Packing Group Ⅱ
Emergency Response 128
Guide Number

Section 15 - REGULATORY INFORMATION


Regulatory information with regard to this product in your country or in your region should be
examined by your own responsibility.
ZL-W01, PENTEL CO., LTD., 3, 2014/04/24, 6/6

Regulatory information with regard to this product in your country or in your region should be
examined by your own responsibility.

Section 16 - OTHER INFORMATION


Information Contact No information available
Other Property This information is furnished without warranty
express or implied.
This information is believed to be accurate to the
best knowledge of PENTEL Co., Ltd. but not
assumes leagal responsibility for use of or reliance
upon this information.
MATERIAL SAFETY DATA SHEET
Date Revised: 07/11/2013 Page: 1
Cream Hardener MSDS Number: 120001

SECTION 1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Material Identity
Product Name: Cream Hardener
Product Numbers: Red- 100358,
Blue- 100354, 100359, 100360, 100361,
101474 and 101475, 196185, 196174
White- 100340, and 101607
Product Use: Polymerization initiator

Company Emergency Telephone Numbers:


ITW Evercoat CHEMTREC: 1-800-424-9300
a Division of Illinois Tool Works Inc. CANUTEC: 1-613-996-6666
6600 Cornell Road
Cincinnati, Ohio USA 45242
Phone: 513-489-7600 Prepared By: Safety Department
Packaged By:
Rocket Plastics Co.
P.O. Box 429514
Montgomery, Ohio USA 45242

SECTION 2. COMPOSITION / INFORMATION ON INGREDIENTS

Ingredient(s) CAS Number EINECS Number % (by weight)


Benzoyl Peroxide 94-36-0 202-327-6 48 – 51
Plasticizer, non-phthalate Proprietary Proprietary 25 – 30
Water 7732-18-5 231-791-2 15 – 20
Silica, amorphous 7631-86-9 231-545-4 0–2
Calcium Carbonate 1317-65-3 215-279-6 0–2
Pigments Various Various 0–2
OSHA Regulatory Status: This material is classified as hazardous under OSHA
regulations.

SECTION 3. HAZARDS IDENTIFICATION


***EMERGENCY OVERVIEW***
WARNING! CAUSES EYE AND SKIN IRRITATION. HARMFUL IF
SWALLOWED. OXIDIZER.

Potential Health Effects

Acute Effects (Short Term):


Eye: Contact with paste may result in irritation, redness, tearing, blurred
vision, and/or swelling. .
MATERIAL SAFETY DATA SHEET
Date Revised: 07/11/2013 Page: 2
Cream Hardener MSDS Number: 120001

Skin: May cause skin irritation. Prolonged or repeated contact may dry
the skin. Symptoms may include minor itching, redness, burning,
drying and cracking of skin, and skin burns. May be readily
absorbed through the skin.

Swallowing: Ingestion of this material may cause gastro-intestinal irritation,


nausea, diarrhea, and vomiting.

Inhalation: Inhalation of vapors can cause nasal and respiratory irritation,


dizziness, weakness, fatigue, nausea, headache possible
unconsciousness, and/or asphyxiation.
Aspiration of this material into the lungs due to vomiting may
produce chemical pneumonitis which can be fatal. If vomiting
occurs spontaneously, keep head below hips to prevent aspiration
of liquid into lungs.

Chronic Effects of Overexposure (Long Term):


Benzoyl Peroxide: Repeated or prolonged contact may cause skin
sensitization. Overexposure to this material has been known to
cause the following effects in lab animals: skin damage. Benzoyl
Peroxide has caused tumorigenic effects in laboratory animals.

Cancer Information: This product does not contain any substance, which is
listed as a carcinogen by NTP, IARC or OSHA in quantities greater than
0.1%.

Primary Route(s) of Entry: Inhalation, Skin contact, Eye contact, Ingestion,


skin absorption.

SECTION 4. FIRST AID MEASURES

Eyes: Flush eyes gently with water for at least 15 minutes. Seek medical
attention.
Skin: Immediately remove contaminated clothing. Wash exposed area
with soap and water. Seek medical attention. Launder clothing
before reuse.
Swallowing: Consult a physician or poison control center immediately. DO NOT
INDUCE VOMITING. Give victim a glass of water. If individual is
drowsy or unconscious, Do Not give anything by mouth; place
individual on the left side with the head down. If possible, do not
leave individual unattended.
MATERIAL SAFETY DATA SHEET
Date Revised: 07/11/2013 Page: 3
Cream Hardener MSDS Number: 120001
Inhalation: If symptoms develop, immediately move individual away from
exposure and into fresh air. Seek immediate medical attention; keep person
warm, but not hot and keep quiet. If person is not breathing, begin artificial
respiration. If breathing is difficult, oxygen may be benificial if administered by
trained personnel.

SECTION 5. FIRE FIGHTING MEASURES


Flash Point: 184 ºF (84 ºC)
Explosive Limit: Lower: N/D Upper: N/D
Autoignition Temperature: Not Determined
OSHA Flammability Class: Combustible Liquid – Class IIIA

Hazardous Products of Combustion: May form toxic and corrosive gases:


carbon dioxide, carbon monoxide, benzoic acid and various hydrocarbons.

Fire and Explosion Hazards: Fire hazard increases when material becomes
dry. Vapors are heavier than air and may travel along the ground or may
be moved by ventilation and ignited by pilot lights, other flames, sparks,
heaters, smoking, electric motors, static discharge, or other ignition
sources at locations distant from material handling point.

Extinguishing Media: Regular foam, carbon dioxide, dry chemical.

Fire Fighting Instructions: Fight fire like a fuel oil fire. Water may be used to
keep fire-exposed containers cool until fire is out. Wear a self-contained
breathing apparatus NIOSH approved with a full facepiece operated in the
positive pressure demand mode with appropriate turn-out gear and
chemical resistant personal protective equipment.

NFPA Rating: Health - 2, Flammability - 2, Reactivity - 2

SECTION 6. ACCIDENTAL RELEASE MEASURES

In Case of Spill: Spill, Leak or Release: Eliminate all sources of ignition such as
flares, flames (including pilot lights), and electrical sparks. Ventilate the area.
Wear proper protective equipment (Section 8). Avoid breathing vapors. Collect
with an inert absorbant and dispose of properly.

SECTION 7. HANDLING AND STORAGE

Handling: All hazard precautions given in the data sheet must be observed. Avoid
contact with eyes, skin and clothing. Wash thoroughly after handling. Use only
with adequate ventilation. Do not breathe vapors or spray mist. Do not take
internally. Close container after each use. Keep out of reach of children.
MATERIAL SAFETY DATA SHEET
Date Revised: 07/11/2013 Page: 4
Cream Hardener MSDS Number: 120001

Storage: Store material in a cool, well-ventilated area. For maximum product


quality, do not store product above 100F/38C. Do not flame, cut, braze, weld
or melt empty containers. Keep product away from heat, open flame, and other
sources of ignition. Do not use or store near heat, sparks, or open flame. Keep
container tightly closed. Avoid contact with incompatible materials such as strong
acids, alkalis and oxidizers.

SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION


Eye Protection: Chemical splash goggles in compliance with OSHA regulations are
recommended.
Skin Protection: Protective gloves and proper clothing should be worn to prevent
skin contact. Gloves should be made of neoprene or natural
rubber. To prevent repeated or prolonged skin contact, wear
impervious clothing and boots.
Respiratory Protection: Use a NIOSH approved respirator designed to remove
particulate matter and organic solvent vapors.
Engineering Controls: Provide sufficient mechanical (general and/or local exhaust)
ventilation to maintain exposure below acceptable limits.
Explosion-proof ventilation system is acceptable.

Exposure Guidelines:

Hazardous Ingredients CAS Number OSHA PEL/TWA ACGIH TLV


Benzoyl Peroxide 94-36-0 5 mg/m3 5 mg/m3
3 3
Calcium Carbonate 1317-65-3 15 mg/m 10 mg/m
Silica, amorphous 7631-86-9 20 mppcf N/E
Mppcf- millions of particles per cubic foot of air N/E-Not Established

SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

Boiling Point: Decomposes Vapor Density: (Air=1) >1


explosively
Specific Gravity / 1.2 / 10.0 lbs/gal Percent Volatiles by 10-20%
Density: weight:
Evaporation Rate: Slower than ethyl Physical State: Paste
ether.
Melting Point: 217 F / 103 C pH: Neutral
(decomposes)
Odor: Slight ester odor. Solubility: Insoluble

Vapor Pressure: (mmHg): N/E Appearance: Red, White, or


Blue Paste
MATERIAL SAFETY DATA SHEET
Date Revised: 07/11/2013 Page: 5
Cream Hardener MSDS Number: 120001
Octanol/Water Unknown VOC* (as packaged- 0 lbs/gal or 0 g/L
Partition less exempts and
Coefficient: water):
VHAP Content by 0%
weight – as
packaged:
*NOTE: This material is used as a catalyst with a variety of products. Refer to the other MSDS for
additional VOC information for the mixture.

SECTION 10. STABILITY AND REACTIVITY

Hazardous Polymerization: Product will not undergo polymerization under


normal conditions of use.
Hazardous Decomposition: May form toxic and corrosive gases: carbon
dioxide, carbon monoxide, benzoic acid and various hydrocarbons.
Chemical Stability: Stable under normal handling conditions.
Incompatibility: Avoid contact in uncontrolled conditions with: organic materials,
inorganic acids, strong oxidizing agents, accelerators, reducing materials,
alcohols, amines and strong bases.

SECTION 11. TOXICOLOGICAL INFORMATION

Acute Toxicity Data:


Ingredient CAS # LD50 Oral-Rat LC50 Inhalation-Rat
Benzoyl Peroxide 94-36-0 7,710 mg/kg N/E
Calcium Carbonate 1317-65-3 6,450 mg/kg N/E

Carcinogenicity: See Cancer Information, Section 3.


Mutagenicity: No significant evidence found.
Teratogenicity: No significant evidence found.

SECTION 12. ECOLOGICAL INFORMATION

Ecotoxicity: The ecological toxicity of this product is not known.

SECTION 13. DISPOSAL CONSIDERATION

RCRA Hazardous Waste: This material as supplied, if discarded,


would be regulated as a hazardous waste under RCRA (40 CFR 261).
Dispose of in accordance with applicable federal, state, and local
regulations. Incineration is the prefered method for disposal. DO NOT
incinerate in closed containers.

RCRA Hazard Class: This material would be regulated as EPA Hazardous


MATERIAL SAFETY DATA SHEET
Date Revised: 07/11/2013 Page: 6
Cream Hardener MSDS Number: 120001
Waste Number D001 based on the characteristic of ignitablity (oxidizer).

SECTION 14. TRANSPORT INFORMATION


DOT Description: The DOT Classification for shipping is dependant on
quantity, type of packaging (a kit may include other components), or
method of shipment.

SECTION 15. REGULATORY INFORMATION


US Federal Regulations
TSCA (Toxic Substances Control Act) Status
TSCA (USA) The intentional ingredients of this product are listed.
CERCLA RQ - 40 CFR 302.4(a)
None
SARA Title III: Section 302- Extremely Hazardous Substances
None
SARA Title III: Section 313- Toxic Chemical List
Component CAS Number Percentage
Benzoyl Peroxide 94-36-0 45-50%
EPA Hazardous Air Pollutants (HAPS) 40 CFR 63
None
International Regulations
EINECS (Europe) The intentional ingredients of this product are listed.
DSL (Canada) The intentional ingredients of this product are listed.
WHMIS Classification
Health Hazard: D2B, C, F (Toxic Effects, Oxidizer,
Dangerously Reactive Materials)
Physical Hazard: B3 (Combustible)
State and Local Regulations
California Proposition 65:
This product contains the following chemical(s) known to the state of
California to cause cancer. NONE
This product contains the following chemical(s) known to the state of
California to cause birth defects or reproductive harm. NONE

SECTION 16. OTHER INFORMATION


HMIS Rating: Health – 2, Flammability - 2, Reactivity - 2
Key- 0=Least, 1=Slight, 2=Moderate, 3=Serious, 4=Extreme, *=Chronic Effects

Other Precautions for Use: DO NOT return unused material to the original container.
DO NOT contaminate product with foreign materials, it may cause hazardous
decomposition. DO NOT add to hot material. This product must be mixed with
other components prior to use. Please refer to the Material Safety Data Sheet for
all components before using.
MATERIAL SAFETY DATA SHEET
Date Revised: 07/11/2013 Page: 7
Cream Hardener MSDS Number: 120001
Additional Information may be obtained by calling the Evercoat MSDS Hotline at
1-800-729-7600.

NOTICE: The information accumulated herein is believed to be correct as of the date issued from
sources, which are believed to be accurate and reliable. Since it is not possible to anticipate all
circumstances of use, recipients are advised to confirm, in advance of need, that the information
is current, applicable and suitable to their circumstances.
. Safety Data Sheet (SDS)
Date PreparedlRevised: 9/10/2014 Version no.: 01 Supersedes: (-)

1.) Identification of the Mixture and of the Company


Product identifier: Crown General Purpose Silicone Lubricant Bulk -

Product name:
8034 General Purpose Silicone Lubricant

Relevant identified uses of the substance: Maybe used on wood, nylon, metal, rubber, canvas, leather,
and chrome. Ideal for windows, doors, hinges, locks, weather stripping, seals, zippers, etc.
Uses advised against: Avoid materials with strong oxidizing agents, and strong acids or bases. May
adversely affect certain plastics.

CAS No: Not Applicable (mixture)


EC No: Not Applicable (mixture)
Index No: Not Applicable (mixture)
Manufacturer/Supplier: Aervoe Industries Incorporated
Street address/P.O. Box: 1100 Mark Circle
Country ID/Postcode/Place Gardnerville, Nevada 89410
Telephone number: 001 (0) 1-775-782-0100
e-mail: [email protected]
National contact: Aervoe industries Incorporated
For Product Information: 001 (0) 1-800-227-0196
Emergency telephone number: 001 (0) 1-800-424-9300 (CIIEMTREC — 24 hrs)
English Language Service

2 Hazards identification

Classifications

Physical Hazards: Flammable liquid- Category 1

Health Hazards:
Asp. Tox. 1
Carc. lB
Muta. lB

Environmental Hazards: N/AV

Labeling

Signal Word: Danger

Hazard Statements:
H224 — Extremely flammable liquid and vapour.
H304 — May be fatal if swallowed and enters airways
H340 — May cause genetic defects
H350 — May cause cancer
In
‘I

A Safety Data Sheet (SDS)


Date PreparedlRevised: 9/10/20 14 Version no.: 01 Supersedes: (-)

Precautionary Statements: P101 - If medical advice is needed, have product container or label at hand
P102 - Keep out of reach of children
P103 - Read label before use
P210 - Keep away from heat/sparks/open flames/hot surfaces no -

smoking
P211 - Do not spray on an open flame or other ignition source
P261 - Avoid breathing dust/fume/gas/mistlvapours/spray
P262 - Do not get in eyes, on skin, or on clothing
P264 - Wash thoroughly after handling
...

P280 - Wear protective gloves/eye protectionlface protection


P303+P361+P353 If on skin or hair, remove/takeoff immediately all
-

contaminated clothing. Rinse skin with water/shower.


P410+P412 - Protect from sunlight. Do not expose to temperatures
exceeding 50°C/I 22°F
P501 Dispose of contents/container in accordance with
local/regional/national/international regulation

Symbols/Pictograms:

3. Composition I Information on Ingredients

Composition

Chemical Synonyms CAS Number EINECS Weight Hazard Category H-Code


Number Percent
Aliphatic Solvent 64742-89-8 265-192-2 60- Care. 18 H350
Petroleum Naphtha 100% Muta. lB 1-1340
Distillates Asp. Tox. 1 1-1304

Dimethylsilo N/AV 63148-62-9 270-705-8 3-7% N/AV N/AV


xa ne

Other Product Information

Chemical Identity: Mixture

4.) First Aid Measures

General Advice: If symptoms persist, always call a doctor.


A. Safety Data Sheet (SDS)
Date PreparedfRevised: 9/10/2014 Version no.: 01 Supersedes: (-)

Inhalation First Aid: Remove victim to fresh air and provide oxygen if breathing is
difficult. If not breathing, give artificial respiration, preferably
mouth to mouth. Get medical attention immediately.
Skin Contact First Aid: Wash with soap and water. Remove contaminated clothing and
shoes. Get medical attention immediately. Wash clothing before
reuse.
Eye Contact First Aid: If contact with eyes, immediately flush eyes with plenty of water
for at least 15 minutes, while holding eyelids open. Get medical
attention immediately.
Ingestion First Aid: If swallowed, wash out mouth with water provided the person is
conscious. Do not induce vomiting. Never give anything by mouth
to an unconscious person. Get medical attention immediately.
Most Important
Symptoms/Effects: Exposure may cause slight irritation to the skin, eyes, and respiratory tract.
Excessive exposure may cause central nervous system effects.

5. Fire Fighting Measures

Flammable Properties: Flammable liquid


Auto Ignition Temperature: Not Available
Suitable extinguishing media: Carbon dioxide, dry chemical, water spray.
Unsuitable extinguishing media: None known
Special hazards arising from the
substance or mixture: None known
Hazardous combustion products: Carbon dioxide, Carbon monoxide
Fire & Explosion Hazards: Closed Containers may rupture due to the buildup of pressure
from extreme temperatures.
Precautions for fire-fighters: Use water spray to cool containers exposed to heat or fire to prevent
pressure build up. In the event of a fire, wear full protective clothing and
NIOSH- approved self-contained breathing apparatus with full face piece
operated in the pressure demand or other positive pressure mode.

6. Accidental Release Measures

PERSONAL PRECAUTIONARY MEASURES:


1) Follow personal protective equipment recommendations found in section 8.
2) Maintain adequate ventilation.

SPILL CLEAN-UP PROCEDURES:


1.) Evacuate unprotected personnel from the area.
2.) Remove sources of ignition if safe to do so.
3.) Pickup spilled materials using non-sparking tools and place in an appropriate container for disposal.
4.) Contain spill to prevent material from entering sewage or ground water systems.
5.) Always dispose of waste materials in accordance with all EU, National and Local Regulations.
— Safety Data Sheet (SDS)
Date Prepared/Revised: 9/10/20 14 Version no.: 01 Supersedes: (-)

7 Handling and Storage


Handling:
Flammable liquid, use in a well ventilated area.
Do not use near sources of ignition.
Do not to eat, drink and smoke while working with this material.
Wash hands after use.
Conditions for safe storage, including any incompatibilities:
Store out of direct sunlight.
Storage Temperature: 32° to 120°F (0° to 49°C).
No known incompatibilities.

I 8 Exposure Controls / Personal Protection

Appropriate engineering controls:


Ensure adequate ventilation. A system of local and/or general exhaust is recommended to keep
employee exposures below the Airborne Exposure Limits.
Keep away from sources of ignition.
Take precautionary measures against static discharge.

Personal Protection:
Eye & face protection devices such as safety glasses, safety goggles or face shield are recommended.

Skin protection
Wear the appropriate protective clothing, including boots, gloves, lab coat, apron or coveralls, as
appropriate, to prevent skin contact.

Respiratory protection:
Use only in an adequately ventilated area. For unknown vapor concentrations use a positive-pressure,
pressure-demand, self-contained breathing apparatus (SCBA).

Hazardous Ingredient CAS ACGIH TLV ACGIH TLV OSHA OSHA PEL
Number (TWA) (STEL) PEL (STEL)
(TWA)
Aliphatic Petroleum Distillates 64742-89-8 N/AV N!AV N/AV N/AV

Dimethylsiloxane 63 148-62-9 N/AV N/AV N/AV N/AV

*Values are based on the 2014 Guide to Occupational Exposure Values by ACGIH

9 Information on Basic Physical and Chemical Properties


A; Safety Data Sheet (SDS)
Date PreparecllRevised: 9/10/2014 Version no.: 01 Supersedes: (-)

Appearance: Clear Odor: Hydrocarbon Odor


Odor Threshold: N/AV pH: Not Applicable (solvent Base)
Melting Point: N/AV Freezing Point: N/AV
Initial Boiling Point: N/AV Boiling Point Range: N/AV
Flash Point: 530 F (12° C) Evaporation Rate: Faster than n-Butyl
Acetate
Flammability SolidlGas: Flammable liquid Upper LEL: 1.1% Lower LEL: 9.5%
Vapor Pressure: N/AV Vapor Density: Heavier Than Air
Relative Density: N/AV Solubility: Negligible
Partition Coefficient: Autoignition Temperature: N/AV
n-octanol/ water: N/AV
Decomposition Temperature: N/AV Viscosity: N/AV
Explosive Properties: N/AV Oxidizing Properties: N/AV

10. Stability & Reactivity

Possibility of hazardous reactions: Hazardous polymerization will not occur under normal conditions
Chemical stability: Stable under normal conditions
Conditions to avoid: Heat and ignition sources
Incompatible materials: Strong Oxidizing Agents
Hazardous decomposition products: Will not occur

11 Toxicological Information I
Reports have associated repeated and prolonged overexposure to solvents with permanent brain and
nervous system damage. Repeated overexposure can also damage kidneys, lungs, liver, heart and blood

Routes of exposure: Eyes, skin, ingestion, and/or inhalation

Acute toxicological data: N/AV

Eye irritation data: N/AV

Skin irritationlsensitizationlabsorption data: N/AV


Reproductive toxicity data: N/AV

Mutagenicity data: N/AV

Symptoms associated with physical contact: N/AV

Acute/chronic effects from shortllong


term exposure: Irritating to skin. Prolonged/repeated contact may
4

$4 Safety Data Sheet (SDS)


Date PreparedlRevised: 9/10/20 14 Version no.: 01 Supersedes: (-)
C
cause defatting of the skin which can lead to
dermatitis. Not expected to be a skin sensitizer.

Known reportable carcinogens via the


following agencies:

NTP: N/AV
IARC: N/AV
OSHA: N/AV

* Petroleum distillates may contain chemical carcinogens in limited quantities (<0.01%). These quantities are determined

by the supplier/fraction/purity of the distillate during the manufacturing process. Chemicals that may be present within
distillates are listed on California’s prop 65 list such as ETHYLBENZENE, BENZENE, and TOLUENE.

12 Ecological Information

Ecotoxicity: No Data Available


Persistence and degradability: No Data Available
Bioaccumulative potential: No Data Available
0
Mobility in soil: No Data Available
Results of PBT and vPvB assessment: No Data Available
Other adverse effects: No Data Available

I 13 Disposal Considerations

Waste Disposal: Dispose of material in accordance with EU, national and local requirements.
For proper disposal of used material, an assessment must be completed to determine the proper
and permissible waste management options permitted under applicable rules, regulations andlor
laws governing your location.
Product I Packaging disposal: Dispose of packaging in accordance with federal, state and local
requirements, regulations andlor laws governing your location.

• 14. Transportation Information

US DOT
UN Proper Shipping Name Hazard Packing Marine Special
Number Class Group Pollutant Provisions
UN 1993 FLAMMABLE LIQUID, 3 PGII Not Reference 49
N.O.S. (LIGHT Applicable CFR 172.101
ALIPHATIC
PETROLEUM NAPHTHA)

I1VIDG
Safety Data Sheet (SDS)
Date Prepared/Revised: 9/10/20 14 Version no.: 01 Supersedes: (-)

UN Proper Shipping Name Hazard Packing Marine Special


Number Class Group Pollutant Provisions
IJN 1993 FLAMMABLE LIQUID, 3 PGII Not Reference
N.O.S. (LIGHT Applicable IMDG code
ALIPHATIC part 3
PETROLEUM NAPHTHA)

IATA:
UN Proper Shipping Name Hazard Packing Marine Special
Number Class Group Pollutant Provisions
UN 1993 FLAMMABLE LIQUID, 3 PGII Not Reference
N.O.S. (LIGHT Applicable IATA
ALIPHATIC Dangerous
PETROLEUM NAPHTHA) Goods
Regulation

15. Regulatory Information

Workplace classification:
This product is considered hazardous under the OSHA Hazard Communication Standard (29 CFR
1910.1200). The Occupational Safety and Health Administration’s interpretation of the product’s hazard
to workers.
SARA Title 3:
Section 311/312 Categorizations (40 CFR 372): This product is a hazardous chemical under 29 CFR
1910.1200, and is categorized as an immediate and delayed health, and flammability physical hazard.
Superfund Amendment and Reauthorization Act (SARA) category. SARA requires reporting any spill of
any hazardous substance.
TSCA status: All chemicals in this product are listed, or are exempt from listing, on the TSCA
Inventory.
WHMIS: This product has been classified in accordance with the hazard criteria of the Controlled
Products Regulations (CPR) and the (M)SDS contains all of the information required by the CPR.
PROP 65 (CA): WARNING: This product may contain chemicals know to the state of California to
cause cancer, birth defects or other reproductive harm.

16. Other Information

This SDS has been completed in accordance with GHS RevO4 (2011): U.S OSHA, CMA, ANSI,
Canadian WHMIS standards, and European Directives.

Date of Preparation/Revision: 9/10/2014


Supersedes: (-)

To the best of our knowledge, the information contained herein is believed to be accurate. However, the
above data does not imply any guarantee or warranty of any kind, expressed or implied. The final
determination of the suitability of any material is the sole responsibility of the user. All materials made
S

44ê Safety Data Sheet (SDS)


Date PreparedlRevised: 9/10/20 14 Version no.: 01 Supersedes: (-)

present un-known hazards and should be used with caution. Although certain hazards are described
herein, we cannot guarantee these are the only hazards existing.
Safety Data Sheet

Revision Number: 005.0 Issue date: 05/20/2014

1. PRODUCT AND COMPANY IDENTIFICATION


Product name: LOCTITE SF 7387 AE known as IDH number: 209714
LOCTITE® 7387 DEPEND® ACTIVATO
Product type: Activator Item number: 21088
Restriction of Use: None identified Region: United States
Company address: Contact information:
Henkel Corporation Telephone: (860) 571-5100
One Henkel Way MEDICAL EMERGENCY Phone: Poison Control Center
Rocky Hill, Connecticut 06067 1-877-671-4608 (toll free) or 1-303-592-1711
TRANSPORT EMERGENCY Phone: CHEMTREC
1-800-424-9300 (toll free) or 1-703-527-3887
Internet: www.henkelna.com

2. HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
WARNING: CONTENTS UNDER PRESSURE.
FLAMMABLE AEROSOL.
CAUSES SKIN IRRITATION.
MAY CAUSE AN ALLERGIC SKIN REACTION.
CAUSES SERIOUS EYE IRRITATION.
MAY CAUSE DROWSINESS OR DIZZINESS.

HAZARD CLASS HAZARD CATEGORY


FLAMMABLE AEROSOL. 2
SKIN IRRITATION 2
EYE IRRITATION 2A
SKIN SENSITIZATION 1
SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE 3

PICTOGRAM(S)

Precautionary Statements

Prevention:
Keep away from heat,sparks, open flames, hot surfaces - no smoking. Do not spray on an open
flame or other ignition source. Pressurized container: Do not pierce or burn, even after use.
Avoid breathing mist or spray. Wash thoroughly after handling. Use only outdoors or in a well-
ventilated area. Contaminated work clothing should not be allowed out of the workplace. Wear
eye and face protection. Wear protective gloves.
Response:
IF ON SKIN: Wash with plenty of soap and water. IF INHALED: Remove person to fresh air and
keep comfortable for breathing.
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if
present and easy to remove. Continue rinsing. Call a poison control center or physician if you
feel unwell. If skin irritation or rash occurs: Get medical attention. If eye irritation persists: Get
medical attention. Take off contaminated clothing.
Storage:

IDH number: 209714 Product name: LOCTITE SF 7387 AE known as LOCTITE® 7387 DEPEND® ACTIVATO
Page 1 of 6
Store in a well-ventilated place. Keep container tightly closed. Store locked up. Protect from
sunlight. Do not expose to temperatures exceeding 50°C/122°F.
Disposal:
Dispose of contents and/or container according to Federal, State/Provincial and local
governmental regulations.

Classification complies with OSHA Hazard Communication Standard (29 CFR 1910.1200) and is consistent with the provisions of the
United Nations Globally Harmonized System of Classification and Labeling of Chemicals (GHS).

See Section 11 for additional toxicological information.

3. COMPOSITION / INFORMATION ON INGREDIENTS


Hazardous Component(s) CAS Number Percentage*
n-Heptane 142-82-5 30 - 60
Aldehyde-amine condensate Proprietary 10 - 30
Isobutane 75-28-5 10 - 30
2-Propanol 67-63-0 10 - 30
Methylcyclohexane 108-87-2 1-5
Octane 111-65-9 1-5

* Exact percentage is a trade secret. Concentration range is provided to assist users in providing appropriate protections.

4. FIRST AID MEASURES


Inhalation: Move to fresh air. If breathing is difficult, give oxygen. If not breathing, give
artificial respiration. Get medical attention.

Skin contact: Remove contaminated clothing and footwear. Immediately flush skin with
plenty of water (using soap, if available). Get medical attention. Wash clothing
before reuse.

Eye contact: Rinse immediately with plenty of water, also under the eyelids, for at least 15
minutes. If symptoms develop and persist, get medical attention.

Ingestion: Do not induce vomiting. Never give anything by mouth to an unconscious


person. Get medical attention.

Symptoms: See Section 11.

5. FIRE FIGHTING MEASURES


Extinguishing media: Foam, dry chemical or carbon dioxide.

Special firefighting procedures: Wear self-contained breathing apparatus and full protective clothing, such as
turn-out gear.

Unusual fire or explosion hazards: Vapors may accumulate in low or confined areas, travel considerable distance
to source of ignition, and flash back. Contents under pressure. Exposure to
temperatures above 49ºC (120°F) may cause container to burst. Do not
puncture or incinerate pressurized containers.

IDH number: 209714 Product name: LOCTITE SF 7387 AE known as LOCTITE® 7387 DEPEND® ACTIVATO
Page 2 of 6
Hazardous combustion products: Oxides of carbon. Oxides of nitrogen. Hydrocarbons. Irritating organic
vapours.

6. ACCIDENTAL RELEASE MEASURES


Use personal protection recommended in Section 8, isolate the hazard area and deny entry to unnecessary and unprotected
personnel.

Environmental precautions: Do not allow product to enter sewer or waterways.

Clean-up methods: Remove all sources of ignition. Ensure adequate ventilation. Keep
unnecessary personnel away. Soak up with inert absorbent material (e.g.
sand, silica gel, acid binder, universal binder, sawdust). Scrape up as much
material as possible. Store in a partly filled, closed container until disposal.
Refer to Section 8 "Exposure Controls / Personal Protection" prior to clean up.

7. HANDLING AND STORAGE


Handling: During use and until all vapors are gone: Keep area ventilated - do not
smoke; extinguish all flames, pilot lights, and heaters; turn off stoves, electrical
tools and appliances, and any other sources of ignition. Prevent contact with
eyes, skin and clothing. Do not breathe vapor and mist. Wash thoroughly
after handling. Do not puncture or incinerate pressurized containers. Refer to
Section 8.

Storage: For safe storage, store between 0 °C (32°F) and 38 °C (100.4 °F)
Keep in a cool, well ventilated area away from heat, sparks and open flame.
Keep container tightly closed until ready for use.

For information on product shelf life contact Henkel Customer Service at (800) 243-4874.

8. EXPOSURE CONTROLS / PERSONAL PROTECTION


Employers should complete an assessment of all workplaces to determine the need for, and selection of, proper exposure
controls and protective equipment for each task performed.

Hazardous Component(s) ACGIH TLV OSHA PEL AIHA WEEL OTHER


400 ppm TWA 500 ppm (2,000
n-Heptane None None
500 ppm STEL mg/m3) PEL
Aldehyde-amine condensate None None None None
Isobutane 1,000 ppm STEL None None None
200 ppm TWA 400 ppm (980
2-Propanol None None
400 ppm STEL mg/m3) PEL
500 ppm (2,000
Methylcyclohexane 400 ppm TWA None None
mg/m3) PEL
500 ppm (2,350
Octane 300 ppm TWA None None
mg/m3) PEL

Engineering controls: Use explosion-proof mechanical ventilation and local exhaust to control
contaminants to within their occupational exposure limits during the use of this
product.

Respiratory protection: Use NIOSH approved respirator if there is potential to exceed exposure
limit(s).

Eye/face protection: Safety goggles or safety glasses with side shields. Full face protection should
be used if the potential for splashing or spraying of product exists. Safety
showers and eye wash stations should be available.

Skin protection: Use chemical resistant, impermeable clothing including gloves and either an
apron or body suit to prevent skin contact. Neoprene gloves.

IDH number: 209714 Product name: LOCTITE SF 7387 AE known as LOCTITE® 7387 DEPEND® ACTIVATO
Page 3 of 6
9. PHYSICAL AND CHEMICAL PROPERTIES
Physical state: Liquid, Aerosol
Color: Amber
Odor: Aliphatic
Odor threshold: Not available.
pH: Not available.
Vapor pressure: 35 mm hg (20 °C (68°F))
Boiling point/range: 49 °C (120.2 °F) Approximately
Melting point/ range: Not available.
Specific gravity: 0.7694
Vapor density: Not available.
Flash point: -4 °C (24.8 °F)
Flammable/Explosive limits - lower: Not available.
Flammable/Explosive limits - upper: Not available.
Autoignition temperature: Not available.
Evaporation rate: Not available.
Solubility in water: Insoluble
Partition coefficient (n-octanol/water): Not available.
VOC content: 83.84 %; 645.1 g/l EPA Method 24
Viscosity: Not available.
Decomposition temperature: Not available.

10. STABILITY AND REACTIVITY


Stability: Stable under normal conditions of storage and use.

Hazardous reactions: Will not occur.

Hazardous decomposition Oxides of carbon. Oxides of nitrogen. Irritating organic vapours.


products:

Incompatible materials: Strong oxidizing agents. Strong acids and strong bases. Amines. Alkalis. Aldehydes. Chlorine.
Halogens. Ethylene oxide. Isocyanates.

Reactivity: Not available.

Conditions to avoid: Heat, flames, sparks and other sources of ignition. Store away from incompatible materials. Do
not puncture, incinerate, or expose to temperatures above 48.9 °C (120 °F).

11. TOXICOLOGICAL INFORMATION


Relevant routes of exposure: Skin, Inhalation, Eyes, Ingestion

IDH number: 209714 Product name: LOCTITE SF 7387 AE known as LOCTITE® 7387 DEPEND® ACTIVATO
Page 4 of 6
Potential Health Effects/Symptoms

Inhalation: May cause dizziness, incoordination, headache, nausea, and vomiting.


Skin contact: Causes skin irritation. May cause allergic skin reaction.
Eye contact: Causes serious eye irritation.
Ingestion: Ingestion may cause gastrointestinal irritation, nausea, vomiting and diarrhea. Aspirated
material can enter the lungs and result in pneumonitis.

Hazardous Component(s) LD50s and LC50s Immediate and Delayed Health Effects
n-Heptane Inhalation LC50 (RAT, 4 h) = 103 mg/l Central nervous system, Irritant
Aldehyde-amine condensate None No Records
Isobutane Inhalation LC50 (RAT, 15 min) = 570000 ppm Cardiac, Central nervous system, Lung
Oral LD50 (RAT) = 5,045 mg/kg
Oral LD50 (RABBIT) = 6,410 mg/kg
Oral LD50 (RAT) = 4.7 g/kg Allergen, Blood, Brain, Central nervous
2-Propanol
Oral LD50 (RABBIT) = 8.0 g/kg system, Irritant, Kidney, Liver, Spleen
Oral LD50 (RABBIT) = 5.03 g/kg
Dermal LD50 (RABBIT) = 12,800 mg/kg
Methylcyclohexane None Central nervous system, Irritant, Kidney, Liver
Octane Inhalation LC50 (RAT, 4 h) = 118 mg/l Central nervous system, Irritant, Lung

OSHA Carcinogen
Hazardous Component(s) NTP Carcinogen IARC Carcinogen
(Specifically Regulated)
n-Heptane No No No
Aldehyde-amine condensate No No No
Isobutane No No No
2-Propanol No No No
Methylcyclohexane No No No
Octane No No No

12. ECOLOGICAL INFORMATION


Ecological information: Not available.

13. DISPOSAL CONSIDERATIONS


Information provided is for unused product only.

Recommended method of disposal: Follow all local, state, federal and provincial regulations for disposal.

Hazardous waste number: D001: Ignitable.

14. TRANSPORT INFORMATION


The transport information provided in this section only applies to the material/formulation itself, and is not specific to any
package/configuration.

U.S. Department of Transportation Ground (49 CFR)


Proper shipping name: Aerosols, flammable
Hazard class or division: 2.1
Identification number: UN 1950
Packing group: None

International Air Transportation (ICAO/IATA)


Proper shipping name: Aerosols, flammable
Hazard class or division: 2.1
Identification number: UN 1950
Packing group: None
Exceptions: ID8000, May Qualify as Consumer Commodity, (Not more than 500 ml)

IDH number: 209714 Product name: LOCTITE SF 7387 AE known as LOCTITE® 7387 DEPEND® ACTIVATO
Page 5 of 6
Water Transportation (IMO/IMDG)
Proper shipping name: AEROSOLS (n-Heptane)
Hazard class or division: 2.1
Identification number: UN 1950
Packing group: None
Marine pollutant: n-Heptane
Exceptions: Limited quantity (Not more than 1 L).

15. REGULATORY INFORMATION


United States Regulatory Information

TSCA 8 (b) Inventory Status: All components are listed or are exempt from listing on the Toxic Substances Control Act
Inventory.
TSCA 12 (b) Export Notification: None above reporting de minimis

CERCLA/SARA Section 302 EHS: None above reporting de minimis


CERCLA/SARA Section 311/312: Immediate Health, Delayed Health, Fire, Sudden Release
CERCLA/SARA Section 313: None above reporting de minimis
CERCLA Reportable quantity: n-Heptane (CAS# 142-82-5) 100 lbs. (45.4 kg)
Isobutane (CAS# 75-28-5) 100 lbs. (45.4 kg)
2-Propanol (CAS# 67-63-0) 100 lbs. (45.4 kg)
Methylcyclohexane (CAS# 108-87-2) 100 lbs. (45.4 kg)
Octane (CAS# 111-65-9) 100 lbs. (45.4 kg)

California Proposition 65: This product contains a chemical known in the State of California to cause cancer. This
product contains a chemical known to the State of California to cause birth defects or other
reproductive harm.

Canada Regulatory Information

CEPA DSL/NDSL Status: All components are listed on or are exempt from listing on the Canadian Domestic
Substances List.

16. OTHER INFORMATION


This safety data sheet contains changes from the previous version in sections: New Safety Data Sheet format.

Prepared by: Sheila Gines, Regulatory Affairs Specialist

Issue date: 05/20/2014

DISCLAIMER: The data contained herein are furnished for information only and are believed to be reliable. However, Henkel
Corporation and its affiliates (“Henkel”) does not assume responsibility for any results obtained by persons over whose methods
Henkel has no control. It is the user’s responsibility to determine the suitability of Henkel’s products or any production methods
mentioned herein for a particular purpose, and to adopt such precautions as may be advisable for the protection of property and
persons against any hazards that may be involved in the handling and use of any Henkel’s products. In light of the foregoing,
Henkel specifically disclaims all warranties, express or implied, including warranties of merchantability and fitness for a particular
purpose, arising from sale or use of Henkel’s products. Henkel further disclaims any liability for consequential or incidental damages
of any kind, including lost profits.

IDH number: 209714 Product name: LOCTITE SF 7387 AE known as LOCTITE® 7387 DEPEND® ACTIVATO
Page 6 of 6
SAFETY DATA SHEET
DE1615

Section 1. Identification
Product name : DUPLI-COLOR™ Engine Enamel with Ceramic
Aluminum
Product code : DE1615
Other means of : Not available.
identification
Product type : Aerosol.
Relevant identified uses of the substance or mixture and uses advised against
Not applicable.

Manufacturer : Dupli-Color Products Company


Cleveland, OH 44115

Emergency telephone : (216) 566-2917


number of the company
Product Information : (800) 247-3270
Telephone Number
Regulatory Information : (216) 566-2902
Telephone Number
Transportation Emergency : (800) 424-9300
Telephone Number

Section 2. Hazards identification


OSHA/HCS status : This material is considered hazardous by the OSHA Hazard Communication Standard
(29 CFR 1910.1200).
Classification of the : FLAMMABLE AEROSOLS - Category 1
substance or mixture GASES UNDER PRESSURE - Compressed gas
SKIN CORROSION/IRRITATION - Category 2
SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 2A
TOXIC TO REPRODUCTION (Unborn child) - Category 1B
TOXIC TO REPRODUCTION (Fertility) - Category 2
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Respiratory tract
irritation) - Category 3
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Narcotic effects) -
Category 3
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) - Category 2
ASPIRATION HAZARD - Category 1
Percentage of the mixture consisting of ingredient(s) of unknown toxicity: 11.6%
GHS label elements
Hazard pictograms :

Signal word : Danger

Date of issue/Date of revision : 5/28/2016 Date of previous issue : 3/27/2016 Version : 2.01 1/16
Section 2. Hazards identification
Hazard statements : Extremely flammable aerosol.
Contains gas under pressure; may explode if heated.
Causes serious eye irritation.
Causes skin irritation.
May damage the unborn child.
Suspected of damaging fertility.
May be fatal if swallowed and enters airways.
May cause respiratory irritation.
May cause drowsiness or dizziness.
May cause damage to organs through prolonged or repeated exposure.
Precautionary statements
General : Read label before use. Keep out of reach of children. If medical advice is needed, have
product container or label at hand.
Prevention : Obtain special instructions before use. Do not handle until all safety precautions have
been read and understood. Wear protective gloves. Wear eye or face protection.
Wear protective clothing. Keep away from heat, hot surfaces, sparks, open flames and
other ignition sources. No smoking. Do not spray on an open flame or other ignition
source. Use only outdoors or in a well-ventilated area. Do not breathe dust or mist.
Wash hands thoroughly after handling. Pressurized container: Do not pierce or burn,
even after use.
Response : Get medical attention if you feel unwell. IF exposed or concerned: Get medical
attention. IF INHALED: Remove person to fresh air and keep comfortable for breathing.
Call a POISON CENTER or physician if you feel unwell. IF SWALLOWED:
Immediately call a POISON CENTER or physician. Do NOT induce vomiting. IF ON
SKIN: Wash with plenty of soap and water. Take off contaminated clothing and wash it
before reuse. If skin irritation occurs: Get medical attention. IF IN EYES: Rinse
cautiously with water for several minutes. Remove contact lenses, if present and easy
to do. Continue rinsing. If eye irritation persists: Get medical attention.
Storage : Store locked up. Protect from sunlight. Do not expose to temperatures exceeding 50
°C/122 °F. Store in a well-ventilated place.
Disposal Dispose of contents and container in accordance with all local, regional, national and
international regulations.
Supplemental label DANGER: Rags, steel wool, other waste soaked with this product, and sanding residue
elements may spontaneously catch fire if improperly discarded. Immediately place rags, steel
wool, other waste soaked with this product, and sanding residue in a sealed, water-filled,
metal container. Dispose of in accordance with local fire regulations. DELAYED
EFFECTS FROM LONG TERM OVEREXPOSURE. Contains solvents which can cause
permanent brain and nervous system damage. Intentional misuse by deliberately
concentrating and inhaling the contents can be harmful or fatal. WARNING: This
product contains chemicals known to the State of California to cause cancer and birth
defects or other reproductive harm.
Please refer to the SDS for additional information. Keep upright in a cool, dry place. Do
not discard empty can in trash compactor.
Hazards not otherwise : None known.
classified

Section 3. Composition/information on ingredients


Substance/mixture : Mixture
Other means of : Not available.
identification
CAS number/other identifiers

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Section 3. Composition/information on ingredients
Ingredient name % by weight CAS number
Acetone ≥25 - ≤50 67-64-1
Methyl Ethyl Ketone ≥10 - ≤25 78-93-3
Propane ≥10 - ≤25 74-98-6
Butane ≤10 106-97-8
Ethanol ≤3 64-17-5
2-Propanol ≤3 67-63-0
Butyl Benzyl Phthalate <1 85-68-7
Toluene <1 108-88-3
Any concentration shown as a range is to protect confidentiality or is due to batch variation.
There are no additional ingredients present which, within the current knowledge of the supplier and in the
concentrations applicable, are classified as hazardous to health and hence require reporting in this section.

Occupational exposure limits, if available, are listed in Section 8.

Section 4. First aid measures


Description of necessary first aid measures
Eye contact : Immediately flush eyes with plenty of water, occasionally lifting the upper and lower
eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10
minutes. Get medical attention.
Inhalation : Remove victim to fresh air and keep at rest in a position comfortable for breathing. If it
is suspected that fumes are still present, the rescuer should wear an appropriate mask
or self-contained breathing apparatus. If not breathing, if breathing is irregular or if
respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It
may be dangerous to the person providing aid to give mouth-to-mouth resuscitation.
Get medical attention. If necessary, call a poison center or physician. If unconscious,
place in recovery position and get medical attention immediately. Maintain an open
airway. Loosen tight clothing such as a collar, tie, belt or waistband. In case of
inhalation of decomposition products in a fire, symptoms may be delayed. The exposed
person may need to be kept under medical surveillance for 48 hours.
Skin contact : Flush contaminated skin with plenty of water. Remove contaminated clothing and
shoes. Wash contaminated clothing thoroughly with water before removing it, or wear
gloves. Continue to rinse for at least 10 minutes. Get medical attention. Wash clothing
before reuse. Clean shoes thoroughly before reuse.
Ingestion : Get medical attention immediately. Call a poison center or physician. Wash out mouth
with water. Remove dentures if any. Remove victim to fresh air and keep at rest in a
position comfortable for breathing. If material has been swallowed and the exposed
person is conscious, give small quantities of water to drink. Stop if the exposed person
feels sick as vomiting may be dangerous. Aspiration hazard if swallowed. Can enter
lungs and cause damage. Do not induce vomiting. If vomiting occurs, the head should
be kept low so that vomit does not enter the lungs. Never give anything by mouth to an
unconscious person. If unconscious, place in recovery position and get medical
attention immediately. Maintain an open airway. Loosen tight clothing such as a collar,
tie, belt or waistband.

Most important symptoms/effects, acute and delayed


Potential acute health effects
Eye contact : Causes serious eye irritation.
Inhalation : Can cause central nervous system (CNS) depression. May cause drowsiness or
dizziness. May cause respiratory irritation.
Skin contact : Causes skin irritation.
Ingestion : Can cause central nervous system (CNS) depression. May be fatal if swallowed and
enters airways.
Over-exposure signs/symptoms

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Section 4. First aid measures
Eye contact : Adverse symptoms may include the following:
pain or irritation
watering
redness
Inhalation : Adverse symptoms may include the following:
respiratory tract irritation
coughing
nausea or vomiting
headache
drowsiness/fatigue
dizziness/vertigo
unconsciousness
reduced fetal weight
increase in fetal deaths
skeletal malformations
Skin contact : Adverse symptoms may include the following:
irritation
redness
reduced fetal weight
increase in fetal deaths
skeletal malformations
Ingestion : Adverse symptoms may include the following:
nausea or vomiting
reduced fetal weight
increase in fetal deaths
skeletal malformations

Indication of immediate medical attention and special treatment needed, if necessary


Notes to physician : In case of inhalation of decomposition products in a fire, symptoms may be delayed.
The exposed person may need to be kept under medical surveillance for 48 hours.
Specific treatments : No specific treatment.
Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. If it is
suspected that fumes are still present, the rescuer should wear an appropriate mask or
self-contained breathing apparatus. It may be dangerous to the person providing aid to
give mouth-to-mouth resuscitation. Wash contaminated clothing thoroughly with water
before removing it, or wear gloves.

See toxicological information (Section 11)

Section 5. Fire-fighting measures


Extinguishing media
Suitable extinguishing : Use an extinguishing agent suitable for the surrounding fire.
media
Unsuitable extinguishing : None known.
media

Specific hazards arising : Extremely flammable aerosol. In a fire or if heated, a pressure increase will occur and
from the chemical the container may burst, with the risk of a subsequent explosion. Gas may accumulate
in low or confined areas or travel a considerable distance to a source of ignition and
flash back, causing fire or explosion. Bursting aerosol containers may be propelled from
a fire at high speed. Runoff to sewer may create fire or explosion hazard.
Hazardous thermal : Decomposition products may include the following materials:
decomposition products carbon dioxide
carbon monoxide
nitrogen oxides
metal oxide/oxides
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Section 5. Fire-fighting measures
Special protective actions : Promptly isolate the scene by removing all persons from the vicinity of the incident if
for fire-fighters there is a fire. No action shall be taken involving any personal risk or without suitable
training. Move containers from fire area if this can be done without risk. Use water
spray to keep fire-exposed containers cool.
Special protective : Fire-fighters should wear appropriate protective equipment and self-contained breathing
equipment for fire-fighters apparatus (SCBA) with a full face-piece operated in positive pressure mode.

Section 6. Accidental release measures


Personal precautions, protective equipment and emergency procedures
For non-emergency : No action shall be taken involving any personal risk or without suitable training.
personnel Evacuate surrounding areas. Keep unnecessary and unprotected personnel from
entering. In the case of aerosols being ruptured, care should be taken due to the rapid
escape of the pressurized contents and propellant. If a large number of containers are
ruptured, treat as a bulk material spillage according to the instructions in the clean-up
section. Do not touch or walk through spilled material. Shut off all ignition sources. No
flares, smoking or flames in hazard area. Avoid breathing vapor or mist. Provide
adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put
on appropriate personal protective equipment.
For emergency responders : If specialized clothing is required to deal with the spillage, take note of any information in
Section 8 on suitable and unsuitable materials. See also the information in "For non-
emergency personnel".

Environmental precautions : Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains
and sewers. Inform the relevant authorities if the product has caused environmental
pollution (sewers, waterways, soil or air).

Methods and materials for containment and cleaning up


Small spill : Stop leak if without risk. Move containers from spill area. Use spark-proof tools and
explosion-proof equipment. Dilute with water and mop up if water-soluble. Alternatively,
or if water-insoluble, absorb with an inert dry material and place in an appropriate waste
disposal container. Dispose of via a licensed waste disposal contractor.
Large spill : Stop leak if without risk. Move containers from spill area. Use spark-proof tools and
explosion-proof equipment. Approach release from upwind. Prevent entry into sewers,
water courses, basements or confined areas. Wash spillages into an effluent treatment
plant or proceed as follows. Contain and collect spillage with non-combustible,
absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in
container for disposal according to local regulations (see Section 13). Dispose of via a
licensed waste disposal contractor. Contaminated absorbent material may pose the
same hazard as the spilled product. Note: see Section 1 for emergency contact
information and Section 13 for waste disposal.

Section 7. Handling and storage


Precautions for safe handling
Protective measures : Put on appropriate personal protective equipment (see Section 8). Pressurized
container: protect from sunlight and do not expose to temperatures exceeding 50°C. Do
not pierce or burn, even after use. Avoid exposure - obtain special instructions before
use. Avoid exposure during pregnancy. Do not handle until all safety precautions have
been read and understood. Do not get in eyes or on skin or clothing. Do not breathe
vapor or mist. Do not swallow. Avoid breathing gas. Use only with adequate ventilation.
Wear appropriate respirator when ventilation is inadequate. Store and use away from
heat, sparks, open flame or any other ignition source. Use explosion-proof electrical
(ventilating, lighting and material handling) equipment. Use only non-sparking tools.
Empty containers retain product residue and can be hazardous.

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Section 7. Handling and storage
Advice on general : Eating, drinking and smoking should be prohibited in areas where this material is
occupational hygiene handled, stored and processed. Workers should wash hands and face before eating,
drinking and smoking. Remove contaminated clothing and protective equipment before
entering eating areas. See also Section 8 for additional information on hygiene
measures.

Conditions for safe storage, : Store in accordance with local regulations. Store away from direct sunlight in a dry, cool
including any and well-ventilated area, away from incompatible materials (see Section 10) and food
incompatibilities and drink. Protect from sunlight. Store locked up. Eliminate all ignition sources. Use
appropriate containment to avoid environmental contamination.

Section 8. Exposure controls/personal protection


Control parameters
Occupational exposure limits
Ingredient name Exposure limits
Acetone ACGIH TLV (United States, 3/2015).
TWA: 250 ppm 8 hours.
STEL: 500 ppm 15 minutes.
NIOSH REL (United States, 10/2013).
TWA: 250 ppm 10 hours.
TWA: 590 mg/m³ 10 hours.
OSHA PEL (United States, 2/2013).
TWA: 1000 ppm 8 hours.
TWA: 2400 mg/m³ 8 hours.
Methyl Ethyl Ketone ACGIH TLV (United States, 3/2015).
TWA: 200 ppm 8 hours.
TWA: 590 mg/m³ 8 hours.
STEL: 300 ppm 15 minutes.
STEL: 885 mg/m³ 15 minutes.
NIOSH REL (United States, 10/2013).
TWA: 200 ppm 10 hours.
TWA: 590 mg/m³ 10 hours.
STEL: 300 ppm 15 minutes.
STEL: 885 mg/m³ 15 minutes.
OSHA PEL (United States, 2/2013).
TWA: 200 ppm 8 hours.
TWA: 590 mg/m³ 8 hours.
Propane NIOSH REL (United States, 10/2013).
TWA: 1000 ppm 10 hours.
TWA: 1800 mg/m³ 10 hours.
OSHA PEL (United States, 2/2013).
TWA: 1000 ppm 8 hours.
TWA: 1800 mg/m³ 8 hours.
Butane NIOSH REL (United States, 10/2013).
TWA: 800 ppm 10 hours.
TWA: 1900 mg/m³ 10 hours.
ACGIH TLV (United States, 3/2015).
STEL: 1000 ppm 15 minutes.
Ethanol ACGIH TLV (United States, 3/2015).
STEL: 1000 ppm 15 minutes.
NIOSH REL (United States, 10/2013).
TWA: 1000 ppm 10 hours.
TWA: 1900 mg/m³ 10 hours.
OSHA PEL (United States, 2/2013).
TWA: 1000 ppm 8 hours.
TWA: 1900 mg/m³ 8 hours.

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Section 8. Exposure controls/personal protection
2-Propanol ACGIH TLV (United States, 3/2015).
TWA: 200 ppm 8 hours.
STEL: 400 ppm 15 minutes.
NIOSH REL (United States, 10/2013).
TWA: 400 ppm 10 hours.
TWA: 980 mg/m³ 10 hours.
STEL: 500 ppm 15 minutes.
STEL: 1225 mg/m³ 15 minutes.
OSHA PEL (United States, 2/2013).
TWA: 400 ppm 8 hours.
TWA: 980 mg/m³ 8 hours.
Butyl Benzyl Phthalate None.
Toluene OSHA PEL Z2 (United States, 2/2013).
TWA: 200 ppm 8 hours.
CEIL: 300 ppm
AMP: 500 ppm 10 minutes.
NIOSH REL (United States, 10/2013).
TWA: 100 ppm 10 hours.
TWA: 375 mg/m³ 10 hours.
STEL: 150 ppm 15 minutes.
STEL: 560 mg/m³ 15 minutes.
ACGIH TLV (United States, 3/2015).
TWA: 20 ppm 8 hours.

Appropriate engineering : Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or
controls other engineering controls to keep worker exposure to airborne contaminants below any
recommended or statutory limits. The engineering controls also need to keep gas,
vapor or dust concentrations below any lower explosive limits. Use explosion-proof
ventilation equipment.
Environmental exposure : Emissions from ventilation or work process equipment should be checked to ensure
controls they comply with the requirements of environmental protection legislation. In some
cases, fume scrubbers, filters or engineering modifications to the process equipment
will be necessary to reduce emissions to acceptable levels.

Individual protection measures


Hygiene measures : Wash hands, forearms and face thoroughly after handling chemical products, before
eating, smoking and using the lavatory and at the end of the working period.
Appropriate techniques should be used to remove potentially contaminated clothing.
Wash contaminated clothing before reusing. Ensure that eyewash stations and safety
showers are close to the workstation location.
Eye/face protection : Safety eyewear complying with an approved standard should be used when a risk
assessment indicates this is necessary to avoid exposure to liquid splashes, mists,
gases or dusts. If contact is possible, the following protection should be worn, unless
the assessment indicates a higher degree of protection: chemical splash goggles.
Skin protection
Hand protection : Chemical-resistant, impervious gloves complying with an approved standard should be
worn at all times when handling chemical products if a risk assessment indicates this is
necessary. Considering the parameters specified by the glove manufacturer, check
during use that the gloves are still retaining their protective properties. It should be
noted that the time to breakthrough for any glove material may be different for different
glove manufacturers. In the case of mixtures, consisting of several substances, the
protection time of the gloves cannot be accurately estimated.
Body protection : Personal protective equipment for the body should be selected based on the task being
performed and the risks involved and should be approved by a specialist before
handling this product. When there is a risk of ignition from static electricity, wear anti-
static protective clothing. For the greatest protection from static discharges, clothing
should include anti-static overalls, boots and gloves.
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Section 8. Exposure controls/personal protection
Other skin protection : Appropriate footwear and any additional skin protection measures should be selected
based on the task being performed and the risks involved and should be approved by a
specialist before handling this product.
Respiratory protection : Based on the hazard and potential for exposure, select a respirator that meets the
appropriate standard or certification. Respirators must be used according to a
respiratory protection program to ensure proper fitting, training, and other important
aspects of use.

Section 9. Physical and chemical properties


Appearance
Physical state : Liquid.
Color : Not available.
Odor : Not available.
Odor threshold : Not available.
pH : Not available.
Melting point : Not available.
Boiling point : Not available.
Flash point : Closed cup: -29°C (-20.2°F) [Pensky-Martens Closed Cup]
Evaporation rate : 5.6 (butyl acetate = 1)
Flammability (solid, gas) : Not available.
Lower and upper explosive : Lower: 1.05%
(flammable) limits Upper: 19%
Vapor pressure : 13.5 kPa (101.325 mm Hg) [at 20°C]
Vapor density : 1.5 [Air = 1]
Relative density : 0.76
Solubility : Not available.
Partition coefficient: n- : Not available.
octanol/water
Auto-ignition temperature : Not available.
Decomposition temperature : Not available.
Viscosity : Kinematic (room temperature): <0.205 cm2/s (<20.5 cSt)
Kinematic (40°C (104°F)): <0.205 cm2/s (<20.5 cSt)
Molecular weight : Not applicable.
Aerosol product
Type of aerosol : Spray
Heat of combustion : 29.26 kJ/g

Section 10. Stability and reactivity


Reactivity : No specific test data related to reactivity available for this product or its ingredients.

Chemical stability : The product is stable.

Possibility of hazardous : Under normal conditions of storage and use, hazardous reactions will not occur.
reactions

Conditions to avoid : Avoid all possible sources of ignition (spark or flame).

Incompatible materials : No specific data.

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Section 10. Stability and reactivity
Hazardous decomposition : Under normal conditions of storage and use, hazardous decomposition products should
products not be produced.

Section 11. Toxicological information


Information on toxicological effects
Acute toxicity
Product/ingredient name Result Species Dose Exposure
Acetone LD50 Oral Rat 5800 mg/kg -
Methyl Ethyl Ketone LD50 Dermal Rabbit 6480 mg/kg -
LD50 Oral Rat 2737 mg/kg -
Butane LC50 Inhalation Vapor Rat 658000 mg/m³ 4 hours
Ethanol LC50 Inhalation Vapor Rat 124700 mg/m³ 4 hours
LD50 Oral Rat 7 g/kg -
2-Propanol LD50 Dermal Rabbit 12800 mg/kg -
LD50 Oral Rat 5000 mg/kg -
Butyl Benzyl Phthalate LD50 Dermal Rabbit >10000 mg/kg -
LD50 Dermal Rat 6700 mg/kg -
LD50 Oral Rat 2330 mg/kg -
Toluene LC50 Inhalation Vapor Rat 49 g/m³ 4 hours
LD50 Oral Rat 636 mg/kg -
Irritation/Corrosion
Product/ingredient name Result Species Score Exposure Observation
Acetone Eyes - Mild irritant Human - 186300 parts -
per million
Eyes - Mild irritant Rabbit - 10 microliters -
Eyes - Moderate irritant Rabbit - 24 hours 20 -
milligrams
Eyes - Severe irritant Rabbit - 20 milligrams -
Skin - Mild irritant Rabbit - 24 hours 500 -
milligrams
Skin - Mild irritant Rabbit - 395 -
milligrams
Methyl Ethyl Ketone Skin - Mild irritant Rabbit - 24 hours 14 -
milligrams
Skin - Moderate irritant Rabbit - 24 hours 500 -
milligrams
Ethanol Eyes - Mild irritant Rabbit - 24 hours 500 -
milligrams
Eyes - Moderate irritant Rabbit - 0.066666667 -
minutes 100
milligrams
Eyes - Moderate irritant Rabbit - 100 -
microliters
Eyes - Severe irritant Rabbit - 500 -
milligrams
Skin - Mild irritant Rabbit - 400 -
milligrams
Skin - Moderate irritant Rabbit - 24 hours 20 -
milligrams
2-Propanol Eyes - Moderate irritant Rabbit - 24 hours 100 -
milligrams
Eyes - Moderate irritant Rabbit - 10 milligrams -
Eyes - Severe irritant Rabbit - 100 -
milligrams
Skin - Mild irritant Rabbit - 500 -
milligrams
Toluene Eyes - Mild irritant Rabbit - 0.5 minutes -

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Section 11. Toxicological information
100
milligrams
Eyes - Mild irritant Rabbit - 870 -
Micrograms
Eyes - Severe irritant Rabbit - 24 hours 2 -
milligrams
Skin - Mild irritant Pig - 24 hours 250 -
microliters
Skin - Mild irritant Rabbit - 435 -
milligrams
Skin - Moderate irritant Rabbit - 24 hours 20 -
milligrams
Skin - Moderate irritant Rabbit - 500 -
milligrams
Sensitization
Not available.

Mutagenicity
Not available.
Carcinogenicity
Not available.
Classification
Product/ingredient name OSHA IARC NTP
Ethanol - 1 -
2-Propanol - 3 -
Butyl Benzyl Phthalate - 3 -
Toluene - 3 -
Reproductive toxicity
Not available.
Teratogenicity
Not available.
Specific target organ toxicity (single exposure)
Name Category Route of Target organs
exposure
Acetone Category 3 Not applicable. Respiratory tract
irritation and
Narcotic effects
Methyl Ethyl Ketone Category 3 Not applicable. Respiratory tract
irritation and
Narcotic effects
Propane Category 3 Not applicable. Respiratory tract
irritation and
Narcotic effects
Butane Category 3 Not applicable. Respiratory tract
irritation and
Narcotic effects
Ethanol Category 3 Not applicable. Respiratory tract
irritation and
Narcotic effects
2-Propanol Category 3 Not applicable. Respiratory tract
irritation and
Narcotic effects
Toluene Category 3 Not applicable. Respiratory tract
irritation and
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Section 11. Toxicological information
Narcotic effects
Specific target organ toxicity (repeated exposure)
Name Category Route of Target organs
exposure
Acetone Category 2 Not determined Not determined
Methyl Ethyl Ketone Category 2 Not determined Not determined
Propane Category 2 Not determined Not determined
Butane Category 2 Not determined Not determined
Ethanol Category 2 Not determined Not determined
2-Propanol Category 2 Not determined Not determined
Toluene Category 2 Not determined Not determined
Aspiration hazard
Name Result
Propane ASPIRATION HAZARD - Category 1
Butane ASPIRATION HAZARD - Category 1
Toluene ASPIRATION HAZARD - Category 1

Information on the likely : Not available.


routes of exposure
Potential acute health effects
Eye contact : Causes serious eye irritation.
Inhalation : Can cause central nervous system (CNS) depression. May cause drowsiness or
dizziness. May cause respiratory irritation.
Skin contact : Causes skin irritation.
Ingestion : Can cause central nervous system (CNS) depression. May be fatal if swallowed and
enters airways.

Symptoms related to the physical, chemical and toxicological characteristics


Eye contact : Adverse symptoms may include the following:
pain or irritation
watering
redness
Inhalation : Adverse symptoms may include the following:
respiratory tract irritation
coughing
nausea or vomiting
headache
drowsiness/fatigue
dizziness/vertigo
unconsciousness
reduced fetal weight
increase in fetal deaths
skeletal malformations
Skin contact : Adverse symptoms may include the following:
irritation
redness
reduced fetal weight
increase in fetal deaths
skeletal malformations

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Ingestion : Adverse symptoms may include the following:
nausea or vomiting
reduced fetal weight
increase in fetal deaths
skeletal malformations

Delayed and immediate effects and also chronic effects from short and long term exposure
Short term exposure
Potential immediate : Not available.
effects
Potential delayed effects : Not available.
Long term exposure
Potential immediate : Not available.
effects
Potential delayed effects : Not available.
Potential chronic health effects
Not available.
General : May cause damage to organs through prolonged or repeated exposure.
Carcinogenicity : No known significant effects or critical hazards.
Mutagenicity : No known significant effects or critical hazards.
Teratogenicity : May damage the unborn child.
Developmental effects : No known significant effects or critical hazards.
Fertility effects : Suspected of damaging fertility.

Numerical measures of toxicity


Acute toxicity estimates
Route ATE value
Oral 10245.4 mg/kg

Section 12. Ecological information


Toxicity
Product/ingredient name Result Species Exposure
Acetone Acute EC50 7200000 µg/l Fresh water Algae - Selenastrum sp. 96 hours
Acute LC50 6000000 µg/l Fresh water Crustaceans - Gammarus pulex 48 hours
Acute LC50 6900 mg/l Fresh water Daphnia - Daphnia magna 48 hours
Acute LC50 5600 ppm Fresh water Fish - Poecilia reticulata 96 hours
Chronic NOEC 4.95 mg/l Marine water Algae - Ulva pertusa 96 hours
Chronic NOEC 0.016 ml/L Fresh water Crustaceans - Daphniidae 21 days
Chronic NOEC 0.1 ml/L Fresh water Daphnia - Daphnia magna - 21 days
Neonate
Methyl Ethyl Ketone Acute EC50 >500000 µg/l Marine water Algae - Skeletonema costatum 96 hours
Acute EC50 5091000 µg/l Fresh water Daphnia - Daphnia magna - 48 hours
Larvae
Acute LC50 3220000 µg/l Fresh water Fish - Pimephales promelas 96 hours
Ethanol Acute EC50 17.921 mg/l Marine water Algae - Ulva pertusa 96 hours
Acute EC50 2000 µg/l Fresh water Daphnia - Daphnia magna 48 hours
Acute LC50 25500 µg/l Marine water Crustaceans - Artemia 48 hours
franciscana - Larvae
Acute LC50 42000 µg/l Fresh water Fish - Oncorhynchus mykiss 4 days
Chronic NOEC 4.995 mg/l Marine water Algae - Ulva pertusa 96 hours
Chronic NOEC 100 ul/L Fresh water Daphnia - Daphnia magna - 21 days

Date of issue/Date of revision : 5/28/2016 Date of previous issue : 3/27/2016 Version : 2.01 12/16
Section 12. Ecological information
Neonate
Chronic NOEC 0.375 ul/L Fresh water Fish - Gambusia holbrooki - 12 weeks
Larvae
2-Propanol Acute LC50 1400000 µg/l Marine water Crustaceans - Crangon crangon 48 hours
Acute LC50 4200 mg/l Fresh water Fish - Rasbora heteromorpha 96 hours
Butyl Benzyl Phthalate Acute EC50 0.22 ppm Marine water Algae - Skeletonema costatum 72 hours
Acute EC50 100 µg/l Fresh water Algae - Pseudokirchneriella 96 hours
subcapitata
Acute EC50 1000 µg/l Fresh water Daphnia - Daphnia magna 48 hours
Acute LC50 3.69 mg/l Fresh water Crustaceans - Moina macrocopa - 48 hours
New born
Acute LC50 510 µg/l Marine water Fish - Cymatogaster aggregata - 96 hours
Juvenile (Fledgling, Hatchling,
Weanling)
Chronic NOEC 0.26 mg/l Fresh water Daphnia - Daphnia magna 21 days
Toluene Acute EC50 12500 µg/l Fresh water Algae - Pseudokirchneriella 72 hours
subcapitata
Acute EC50 11600 µg/l Fresh water Crustaceans - Gammarus 48 hours
pseudolimnaeus - Adult
Acute EC50 6000 µg/l Fresh water Daphnia - Daphnia magna - 48 hours
Juvenile (Fledgling, Hatchling,
Weanling)
Acute LC50 5500 µg/l Fresh water Fish - Oncorhynchus kisutch - Fry 96 hours
Chronic NOEC 1000 µg/l Fresh water Daphnia - Daphnia magna 21 days

Persistence and degradability


Product/ingredient name Aquatic half-life Photolysis Biodegradability
Acetone - - Readily
Methyl Ethyl Ketone - - Readily
Ethanol - - Readily
2-Propanol - - Readily
Toluene - - Readily

Bioaccumulative potential
Product/ingredient name LogPow BCF Potential
Butyl Benzyl Phthalate - 1693.25 high
Toluene - 90 low

Mobility in soil
Soil/water partition : Not available.
coefficient (KOC)

Other adverse effects : No known significant effects or critical hazards.

Section 13. Disposal considerations


Disposal methods : The generation of waste should be avoided or minimized wherever possible. Disposal
of this product, solutions and any by-products should at all times comply with the
requirements of environmental protection and waste disposal legislation and any
regional local authority requirements. Dispose of surplus and non-recyclable products
via a licensed waste disposal contractor. Waste should not be disposed of untreated to
the sewer unless fully compliant with the requirements of all authorities with jurisdiction.
Waste packaging should be recycled. Incineration or landfill should only be considered
when recycling is not feasible. This material and its container must be disposed of in a
safe way. Empty containers or liners may retain some product residues. Do not
puncture or incinerate container.
Date of issue/Date of revision : 5/28/2016 Date of previous issue : 3/27/2016 Version : 2.01 13/16
Section 14. Transport information
DOT TDG Mexico IATA IMDG
Classification Classification Classification
UN number UN1950 UN1950 UN1950 UN1950 UN1950

UN proper AEROSOLS AEROSOLS AEROSOLS AEROSOLS, AEROSOLS


shipping name flammable
Transport 2.1 2.1 2.1 2.1 2.1
hazard class(es)

Packing group - - - - -
Environmental No. No. No. No. No.
hazards
Additional Special Product classified Special Special Emergency
information provisions as per the provisions provisions schedules (EmS)
LIMITED following sections Not Applicable LIMITED F-D, S-U
QUANTITY of the QUANTITY
Transportation of Special
Dangerous Goods provisions
Regulations: 2. LIMITED
13-2.17 (Class 2). QUANTITY

Special
provisions
LIMITED
QUANTITY
ERG No. ERG No. ERG No.
126 126 126

Special precautions for user : Multi-modal shipping descriptions are provided for informational purposes and do not
consider container sizes. The presence of a shipping description for a particular
mode of transport (sea, air, etc.), does not indicate that the product is packaged
suitably for that mode of transport. All packaging must be reviewed for suitability
prior to shipment, and compliance with the applicable regulations is the sole
responsibility of the person offering the product for transport. People loading and
unloading dangerous goods must be trained on all of the risks deriving from the
substances and on all actions in case of emergency situations.

Transport in bulk according : Not available.


to Annex II of MARPOL and
the IBC Code
Proper shipping name : Not available.
Ship type : Not available.
Pollution category : Not available.

Date of issue/Date of revision : 5/28/2016 Date of previous issue : 3/27/2016 Version : 2.01 14/16
Section 15. Regulatory information
SARA 313
SARA 313 (40 CFR 372.45) supplier notification can be found on the Environmental Data Sheet.
California Prop. 65
WARNING: This product contains chemicals known to the State of California to cause cancer and birth defects or other
reproductive harm.

Section 16. Other information


Hazardous Material Information System (U.S.A.)
Health 2

Flammability 3

Physical hazards 1

The customer is responsible for determining the PPE code for this material.

Caution: HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4
representing significant hazards or risks Although HMIS® ratings are not required on SDSs under 29 CFR 1910.
1200, the preparer may choose to provide them. HMIS® ratings are to be used with a fully implemented HMIS®
program. HMIS® is a registered mark of the National Paint & Coatings Association (NPCA). HMIS® materials may
be purchased exclusively from J. J. Keller (800) 327-6868.
Procedure used to derive the classification
Classification Justification
FLAMMABLE AEROSOLS - Category 1 On basis of test data
GASES UNDER PRESSURE - Compressed gas Calculation method
SKIN CORROSION/IRRITATION - Category 2 Calculation method
SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 2A Calculation method
TOXIC TO REPRODUCTION (Unborn child) - Category 1B Calculation method
TOXIC TO REPRODUCTION (Fertility) - Category 2 Calculation method
SPECIFIC TARGET ORGAN TOXICITY (SINGLE Calculation method
EXPOSURE) (Respiratory tract irritation) - Category 3
SPECIFIC TARGET ORGAN TOXICITY (SINGLE Calculation method
EXPOSURE) (Narcotic effects) - Category 3
SPECIFIC TARGET ORGAN TOXICITY (REPEATED Calculation method
EXPOSURE) - Category 2
ASPIRATION HAZARD - Category 1 Calculation method

History
Date of printing : 5/28/2016
Date of issue/Date of : 5/28/2016
revision
Date of previous issue : 3/27/2016
Version : 2.01
Key to abbreviations : ATE = Acute Toxicity Estimate
BCF = Bioconcentration Factor
GHS = Globally Harmonized System of Classification and Labelling of Chemicals
IATA = International Air Transport Association
IBC = Intermediate Bulk Container
IMDG = International Maritime Dangerous Goods
LogPow = logarithm of the octanol/water partition coefficient
MARPOL = International Convention for the Prevention of Pollution From Ships, 1973
as modified by the Protocol of 1978. ("Marpol" = marine pollution)
UN = United Nations
Notice to reader

Date of issue/Date of revision : 5/28/2016 Date of previous issue : 3/27/2016 Version : 2.01 15/16
Section 16. Other information
It is recommended that each customer or recipient of this Safety Data Sheet (SDS) study it carefully and consult
resources, as necessary or appropriate, to become aware of and understand the data contained in this SDS and
any hazards associated with the product. This information is provided in good faith and believed to be accurate
as of the effective date herein. However, no warranty, express or implied, is given. The information presented
here applies only to the product as shipped. The addition of any material can change the composition, hazards
and risks of the product. Products shall not be repackaged, modified, or tinted except as specifically instructed
by Sherwin-Williams, including but not limited to the incorporation of non Sherwin-Williams products or the use
or addition of products in proportions not specified by Sherwin-Williams. Regulatory requirements are subject
to change and may differ between various locations and jurisdictions. The customer/buyer/user is responsible to
ensure that his activities comply with all country, federal, state, provincial or local laws. The conditions for use
of the product are not under the control of the manufacturer; the customer/buyer/user is responsible to
determine the conditions necessary for the safe use of this product. The customer/buyer/user should not use the
product for any purpose other than the purpose shown in the applicable section of this SDS without first
referring to the supplier and obtaining written handling instructions. Due to the proliferation of sources for
information such as manufacturer-specific SDS, the manufacturer cannot be responsible for SDSs obtained from
any other source.

Date of issue/Date of revision : 5/28/2016 Date of previous issue : 3/27/2016 Version : 2.01 16/16
SAFETY DATA SHEET
DAL1607

Section 1. Identification
Product name : DUPLI-COLOR® Acrylic Lacquer Aerosol Paint
Flat Black
Product code : DAL1607
Other means of : Not available.
identification
Product type : Aerosol.
Relevant identified uses of the substance or mixture and uses advised against
Not applicable.

Manufacturer : THE SHERWIN-WILLIAMS CO.


DUPLI-COLOR Products Group
Cleveland, OH 44115

Emergency telephone : (216) 566-2917


number of the company
Product Information : (800) 247-3270
Telephone Number
Regulatory Information : (216) 566-2902
Telephone Number
Transportation Emergency : (800) 424-9300
Telephone Number

Section 2. Hazards identification


OSHA/HCS status : This material is considered hazardous by the OSHA Hazard Communication Standard
(29 CFR 1910.1200).
Classification of the : FLAMMABLE AEROSOLS - Category 1
substance or mixture GASES UNDER PRESSURE - Compressed gas
SKIN CORROSION/IRRITATION - Category 2
SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 2A
CARCINOGENICITY - Category 1A
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Respiratory tract
irritation and Narcotic effects) - Category 3
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) - Category 2
ASPIRATION HAZARD - Category 1
Percentage of the mixture consisting of ingredient(s) of unknown toxicity: 11.8%
GHS label elements
Hazard pictograms :

Signal word : Danger

Date of issue/Date of revision : 4/21/2015. Date of previous issue : No previous validation. Version :1 1/15
Section 2. Hazards identification
Hazard statements : Extremely flammable aerosol.
Contains gas under pressure; may explode if heated.
Causes serious eye irritation.
Causes skin irritation.
May cause cancer.
May be fatal if swallowed and enters airways.
May cause respiratory irritation.
May cause drowsiness and dizziness.
May cause damage to organs through prolonged or repeated exposure.
Precautionary statements
General : Read label before use. Keep out of reach of children. If medical advice is needed, have
product container or label at hand.
Prevention : Obtain special instructions before use. Do not handle until all safety precautions have
been read and understood. Use personal protective equipment as required. Wear
protective gloves. Wear eye or face protection. Keep away from heat, hot surfaces,
sparks, open flames and other ignition sources. No smoking. Pressurized container: Do
not pierce or burn, even after use. Do not spray on an open flame or other ignition
source. Use only outdoors or in a well-ventilated area. Do not breathe dust or mist.
Wash hands thoroughly after handling.
Response : Get medical attention if you feel unwell. IF exposed or concerned: Get medical
attention. IF INHALED: Remove victim to fresh air and keep at rest in a position
comfortable for breathing. Call a POISON CENTER or physician if you feel unwell. IF
SWALLOWED: Immediately call a POISON CENTER or physician. Do NOT induce
vomiting. IF ON SKIN: Wash with plenty of soap and water. Take off contaminated
clothing. Wash contaminated clothing before reuse. If skin irritation occurs: Get
medical attention. IF IN EYES: Rinse cautiously with water for several minutes.
Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation
persists: Get medical attention.
Storage : Store locked up. Protect from sunlight. Do not expose to temperatures exceeding 50
°C/122 °F. Store in a well-ventilated place.
Disposal Dispose of contents and container in accordance with all local, regional, national and
international regulations.
Supplemental label DELAYED EFFECTS FROM LONG TERM OVEREXPOSURE. Contains solvents which
elements can cause permanent brain and nervous system damage. Intentional misuse by
deliberately concentrating and inhaling the contents can be harmful or fatal. WARNING:
This product contains chemicals known to the State of California to cause cancer and
birth defects or other reproductive harm. FOR INDUSTRIAL USE ONLY.
Please refer to the SDS for additional information. Keep upright in a cool, dry place. Do
not discard empty can in trash compactor.
Hazards not otherwise : None known.
classified

Section 3. Composition/information on ingredients


Substance/mixture : Mixture
Other means of : Not available.
identification

CAS number/other identifiers

Date of issue/Date of revision : 4/21/2015. Date of previous issue : No previous validation. Version :1 2/15
Section 3. Composition/information on ingredients
Ingredient name % by weight CAS number
Acetone 38.1 67-64-1
Methyl Ethyl Ketone 16.6 78-93-3
Propane 11.8 74-98-6
Butane 11.3 106-97-8
Ethanol 3.8 64-17-5
Ethyl Acetate 3.1 141-78-6
2-Propanol 1.1 67-63-0
Carbon Black 0.2 1333-86-4
Methyl Isobutyl Ketone 0.1 108-10-1
There are no additional ingredients present which, within the current knowledge of the supplier and in the
concentrations applicable, are classified as hazardous to health or the environment and hence require reporting
in this section.
Occupational exposure limits, if available, are listed in Section 8.

Section 4. First aid measures


Description of necessary first aid measures
Eye contact : Immediately flush eyes with plenty of water, occasionally lifting the upper and lower
eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10
minutes. Get medical attention.
Inhalation : Remove victim to fresh air and keep at rest in a position comfortable for breathing. If it
is suspected that fumes are still present, the rescuer should wear an appropriate mask
or self-contained breathing apparatus. If not breathing, if breathing is irregular or if
respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It
may be dangerous to the person providing aid to give mouth-to-mouth resuscitation.
Get medical attention. If necessary, call a poison center or physician. If unconscious,
place in recovery position and get medical attention immediately. Maintain an open
airway. Loosen tight clothing such as a collar, tie, belt or waistband. In case of
inhalation of decomposition products in a fire, symptoms may be delayed. The exposed
person may need to be kept under medical surveillance for 48 hours.
Skin contact : Flush contaminated skin with plenty of water. Remove contaminated clothing and
shoes. Wash contaminated clothing thoroughly with water before removing it, or wear
gloves. Continue to rinse for at least 10 minutes. Get medical attention. Wash clothing
before reuse. Clean shoes thoroughly before reuse.
Ingestion : Get medical attention immediately. Call a poison center or physician. Wash out mouth
with water. Remove dentures if any. Remove victim to fresh air and keep at rest in a
position comfortable for breathing. If material has been swallowed and the exposed
person is conscious, give small quantities of water to drink. Stop if the exposed person
feels sick as vomiting may be dangerous. Aspiration hazard if swallowed. Can enter
lungs and cause damage. Do not induce vomiting. If vomiting occurs, the head should
be kept low so that vomit does not enter the lungs. Never give anything by mouth to an
unconscious person. If unconscious, place in recovery position and get medical
attention immediately. Maintain an open airway. Loosen tight clothing such as a collar,
tie, belt or waistband.

Most important symptoms/effects, acute and delayed


Potential acute health effects
Eye contact : Causes serious eye irritation.
Inhalation : Can cause central nervous system (CNS) depression. May cause drowsiness and
dizziness. May cause respiratory irritation. Exposure to decomposition products may
cause a health hazard. Serious effects may be delayed following exposure.
Skin contact : Causes skin irritation.
Ingestion : Can cause central nervous system (CNS) depression. May be fatal if swallowed and
enters airways. Irritating to mouth, throat and stomach.
Over-exposure signs/symptoms
Date of issue/Date of revision : 4/21/2015. Date of previous issue : No previous validation. Version :1 3/15
Section 4. First aid measures
Eye contact : Adverse symptoms may include the following:
pain or irritation
watering
redness
Inhalation : Adverse symptoms may include the following:
respiratory tract irritation
coughing
nausea or vomiting
headache
drowsiness/fatigue
dizziness/vertigo
unconsciousness
Skin contact : Adverse symptoms may include the following:
irritation
redness
Ingestion : Adverse symptoms may include the following:
nausea or vomiting

Indication of immediate medical attention and special treatment needed, if necessary


Notes to physician : In case of inhalation of decomposition products in a fire, symptoms may be delayed.
The exposed person may need to be kept under medical surveillance for 48 hours.
Specific treatments : No specific treatment.
Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. If it is
suspected that fumes are still present, the rescuer should wear an appropriate mask or
self-contained breathing apparatus. It may be dangerous to the person providing aid to
give mouth-to-mouth resuscitation. Wash contaminated clothing thoroughly with water
before removing it, or wear gloves.

See toxicological information (Section 11)

Section 5. Fire-fighting measures


Extinguishing media
Suitable extinguishing : Use an extinguishing agent suitable for the surrounding fire.
media
Unsuitable extinguishing : None known.
media

Specific hazards arising : Extremely flammable aerosol. In a fire or if heated, a pressure increase will occur and
from the chemical the container may burst, with the risk of a subsequent explosion. Gas may accumulate
in low or confined areas or travel a considerable distance to a source of ignition and
flash back, causing fire or explosion. Bursting aerosol containers may be propelled from
a fire at high speed. Runoff to sewer may create fire or explosion hazard.
Hazardous thermal : Decomposition products may include the following materials:
decomposition products carbon dioxide
carbon monoxide
nitrogen oxides

Special protective actions : Promptly isolate the scene by removing all persons from the vicinity of the incident if
for fire-fighters there is a fire. No action shall be taken involving any personal risk or without suitable
training. Move containers from fire area if this can be done without risk. Use water
spray to keep fire-exposed containers cool.
Special protective : Fire-fighters should wear appropriate protective equipment and self-contained breathing
equipment for fire-fighters apparatus (SCBA) with a full face-piece operated in positive pressure mode.

Date of issue/Date of revision : 4/21/2015. Date of previous issue : No previous validation. Version :1 4/15
Section 6. Accidental release measures
Personal precautions, protective equipment and emergency procedures
For non-emergency : No action shall be taken involving any personal risk or without suitable training.
personnel Evacuate surrounding areas. Keep unnecessary and unprotected personnel from
entering. In the case of aerosols being ruptured, care should be taken due to the rapid
escape of the pressurized contents and propellant. If a large number of containers are
ruptured, treat as a bulk material spillage according to the instructions in the clean-up
section. Do not touch or walk through spilled material. Shut off all ignition sources. No
flares, smoking or flames in hazard area. Avoid breathing vapor or mist. Provide
adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put
on appropriate personal protective equipment.
For emergency responders : If specialised clothing is required to deal with the spillage, take note of any information in
Section 8 on suitable and unsuitable materials. See also the information in "For non-
emergency personnel".

Environmental precautions : Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains
and sewers. Inform the relevant authorities if the product has caused environmental
pollution (sewers, waterways, soil or air).

Methods and materials for containment and cleaning up


Small spill : Stop leak if without risk. Move containers from spill area. Use spark-proof tools and
explosion-proof equipment. Dilute with water and mop up if water-soluble. Alternatively,
or if water-insoluble, absorb with an inert dry material and place in an appropriate waste
disposal container. Dispose of via a licensed waste disposal contractor.
Large spill : Stop leak if without risk. Move containers from spill area. Use spark-proof tools and
explosion-proof equipment. Approach release from upwind. Prevent entry into sewers,
water courses, basements or confined areas. Wash spillages into an effluent treatment
plant or proceed as follows. Contain and collect spillage with non-combustible,
absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in
container for disposal according to local regulations (see Section 13). Dispose of via a
licensed waste disposal contractor. Contaminated absorbent material may pose the
same hazard as the spilled product. Note: see Section 1 for emergency contact
information and Section 13 for waste disposal.

Section 7. Handling and storage


Precautions for safe handling
Protective measures : Put on appropriate personal protective equipment (see Section 8). Pressurized
container: protect from sunlight and do not expose to temperatures exceeding 50°C. Do
not pierce or burn, even after use. Avoid exposure - obtain special instructions before
use. Do not handle until all safety precautions have been read and understood. Do not
get in eyes or on skin or clothing. Do not breathe vapor or mist. Do not swallow. Avoid
breathing gas. Use only with adequate ventilation. Wear appropriate respirator when
ventilation is inadequate. Store and use away from heat, sparks, open flame or any
other ignition source. Use explosion-proof electrical (ventilating, lighting and material
handling) equipment. Use only non-sparking tools. Empty containers retain product
residue and can be hazardous.
Advice on general : Eating, drinking and smoking should be prohibited in areas where this material is
occupational hygiene handled, stored and processed. Workers should wash hands and face before eating,
drinking and smoking. Remove contaminated clothing and protective equipment before
entering eating areas. See also Section 8 for additional information on hygiene
measures.

Conditions for safe storage, : Store in accordance with local regulations. Store away from direct sunlight in a dry, cool
including any and well-ventilated area, away from incompatible materials (see Section 10) and food
incompatibilities and drink. Protect from sunlight. Store locked up. Eliminate all ignition sources. Use
appropriate containment to avoid environmental contamination.

Date of issue/Date of revision : 4/21/2015. Date of previous issue : No previous validation. Version :1 5/15
Section 8. Exposure controls/personal protection
Control parameters
Occupational exposure limits
Ingredient name Exposure limits
Acetone ACGIH TLV (United States, 4/2014).
TWA: 500 ppm 8 hours.
TWA: 1188 mg/m³ 8 hours.
STEL: 750 ppm 15 minutes.
STEL: 1782 mg/m³ 15 minutes.
NIOSH REL (United States, 10/2013).
TWA: 250 ppm 10 hours.
TWA: 590 mg/m³ 10 hours.
OSHA PEL (United States, 2/2013).
TWA: 1000 ppm 8 hours.
TWA: 2400 mg/m³ 8 hours.
Methyl Ethyl Ketone ACGIH TLV (United States, 4/2014).
TWA: 200 ppm 8 hours.
TWA: 590 mg/m³ 8 hours.
STEL: 300 ppm 15 minutes.
STEL: 885 mg/m³ 15 minutes.
NIOSH REL (United States, 10/2013).
TWA: 200 ppm 10 hours.
TWA: 590 mg/m³ 10 hours.
STEL: 300 ppm 15 minutes.
STEL: 885 mg/m³ 15 minutes.
OSHA PEL (United States, 2/2013).
TWA: 200 ppm 8 hours.
TWA: 590 mg/m³ 8 hours.
Propane NIOSH REL (United States, 10/2013).
TWA: 1000 ppm 10 hours.
TWA: 1800 mg/m³ 10 hours.
OSHA PEL (United States, 2/2013).
TWA: 1000 ppm 8 hours.
TWA: 1800 mg/m³ 8 hours.
Butane NIOSH REL (United States, 10/2013).
TWA: 800 ppm 10 hours.
TWA: 1900 mg/m³ 10 hours.
ACGIH TLV (United States, 4/2014).
STEL: 1000 ppm 15 minutes.
Ethanol ACGIH TLV (United States, 4/2014).
STEL: 1000 ppm 15 minutes.
NIOSH REL (United States, 10/2013).
TWA: 1000 ppm 10 hours.
TWA: 1900 mg/m³ 10 hours.
OSHA PEL (United States, 2/2013).
TWA: 1000 ppm 8 hours.
TWA: 1900 mg/m³ 8 hours.
Ethyl Acetate ACGIH TLV (United States, 4/2014).
TWA: 400 ppm 8 hours.
TWA: 1440 mg/m³ 8 hours.
NIOSH REL (United States, 10/2013).
TWA: 400 ppm 10 hours.
TWA: 1400 mg/m³ 10 hours.
OSHA PEL (United States, 2/2013).
TWA: 400 ppm 8 hours.
TWA: 1400 mg/m³ 8 hours.
2-Propanol ACGIH TLV (United States, 4/2014).
TWA: 200 ppm 8 hours.
STEL: 400 ppm 15 minutes.

Date of issue/Date of revision : 4/21/2015. Date of previous issue : No previous validation. Version :1 6/15
Section 8. Exposure controls/personal protection
NIOSH REL (United States, 10/2013).
TWA: 400 ppm 10 hours.
TWA: 980 mg/m³ 10 hours.
STEL: 500 ppm 15 minutes.
STEL: 1225 mg/m³ 15 minutes.
OSHA PEL (United States, 2/2013).
TWA: 400 ppm 8 hours.
TWA: 980 mg/m³ 8 hours.
Carbon Black NIOSH REL (United States, 10/2013).
TWA: 3.5 mg/m³ 10 hours.
TWA: 0.1 mg of PAHs/cm³ 10 hours.
OSHA PEL (United States, 2/2013).
TWA: 3.5 mg/m³ 8 hours.
ACGIH TLV (United States, 4/2014).
TWA: 3 mg/m³ 8 hours. Form: Inhalable
fraction
Methyl Isobutyl Ketone ACGIH TLV (United States, 4/2014).
TWA: 20 ppm 8 hours.
STEL: 75 ppm 15 minutes.
NIOSH REL (United States, 10/2013).
TWA: 50 ppm 10 hours.
TWA: 205 mg/m³ 10 hours.
STEL: 75 ppm 15 minutes.
STEL: 300 mg/m³ 15 minutes.
OSHA PEL (United States, 2/2013).
TWA: 100 ppm 8 hours.
TWA: 410 mg/m³ 8 hours.

Appropriate engineering : Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or
controls other engineering controls to keep worker exposure to airborne contaminants below any
recommended or statutory limits. The engineering controls also need to keep gas,
vapor or dust concentrations below any lower explosive limits. Use explosion-proof
ventilation equipment.
Environmental exposure : Emissions from ventilation or work process equipment should be checked to ensure
controls they comply with the requirements of environmental protection legislation. In some
cases, fume scrubbers, filters or engineering modifications to the process equipment
will be necessary to reduce emissions to acceptable levels.

Individual protection measures


Hygiene measures : Wash hands, forearms and face thoroughly after handling chemical products, before
eating, smoking and using the lavatory and at the end of the working period.
Appropriate techniques should be used to remove potentially contaminated clothing.
Wash contaminated clothing before reusing. Ensure that eyewash stations and safety
showers are close to the workstation location.
Eye/face protection : Safety eyewear complying with an approved standard should be used when a risk
assessment indicates this is necessary to avoid exposure to liquid splashes, mists,
gases or dusts. If contact is possible, the following protection should be worn, unless
the assessment indicates a higher degree of protection: chemical splash goggles.
Skin protection
Hand protection : Chemical-resistant, impervious gloves complying with an approved standard should be
worn at all times when handling chemical products if a risk assessment indicates this is
necessary. Considering the parameters specified by the glove manufacturer, check
during use that the gloves are still retaining their protective properties. It should be
noted that the time to breakthrough for any glove material may be different for different
glove manufacturers. In the case of mixtures, consisting of several substances, the
protection time of the gloves cannot be accurately estimated.

Date of issue/Date of revision : 4/21/2015. Date of previous issue : No previous validation. Version :1 7/15
Section 8. Exposure controls/personal protection
Body protection : Personal protective equipment for the body should be selected based on the task being
performed and the risks involved and should be approved by a specialist before
handling this product. When there is a risk of ignition from static electricity, wear anti-
static protective clothing. For the greatest protection from static discharges, clothing
should include anti-static overalls, boots and gloves.
Other skin protection : Appropriate footwear and any additional skin protection measures should be selected
based on the task being performed and the risks involved and should be approved by a
specialist before handling this product.
Respiratory protection : Use a properly fitted, air-purifying or air-fed respirator complying with an approved
standard if a risk assessment indicates this is necessary. Respirator selection must be
based on known or anticipated exposure levels, the hazards of the product and the safe
working limits of the selected respirator.

Section 9. Physical and chemical properties


Appearance
Physical state : Liquid.
Color : Not available.
Odor : Not available.
Odor threshold : Not available.
pH : Not available.
Melting point : Not available.
Boiling point : Not available.
Flash point : Closed cup: -29°C (-20.2°F) [Pensky-Martens Closed Cup]
Evaporation rate : 5.6 (butyl acetate = 1)
Flammability (solid, gas) : Not available.
Lower and upper explosive : Lower: 1%
(flammable) limits Upper: 19%
Vapor pressure : 13.5 kPa (101.325 mm Hg) [at 20°C]
Vapor density : 1.5 [Air = 1]
Relative density : 0.73
Solubility : Not available.
Partition coefficient: n- : Not available.
octanol/water
Auto-ignition temperature : Not available.
Decomposition temperature : Not available.
Viscosity : Kinematic (room temperature): <0.07 cm2/s (<7 cSt)
Kinematic (40°C (104°F)): <0.07 cm2/s (<7 cSt)
Aerosol product
Type of aerosol : Spray
Heat of combustion : 0.00003086 kJ/g

Section 10. Stability and reactivity


Reactivity : No specific test data related to reactivity available for this product or its ingredients.

Chemical stability : The product is stable.

Possibility of hazardous : Under normal conditions of storage and use, hazardous reactions will not occur.
reactions

Conditions to avoid : Avoid all possible sources of ignition (spark or flame).


Date of issue/Date of revision : 4/21/2015. Date of previous issue : No previous validation. Version :1 8/15
Section 10. Stability and reactivity
Incompatible materials : No specific data.

Hazardous decomposition : Under normal conditions of storage and use, hazardous decomposition products should
products not be produced.

Section 11. Toxicological information


Information on toxicological effects
Acute toxicity
Product/ingredient name Result Species Dose Exposure
Acetone LD50 Oral Rat 5800 mg/kg -
Methyl Ethyl Ketone LD50 Dermal Rabbit 6480 mg/kg -
LD50 Oral Rat 2737 mg/kg -
Butane LC50 Inhalation Vapor Rat 658000 mg/m³ 4 hours
Ethanol LC50 Inhalation Vapor Rat 124700 mg/m³ 4 hours
LD50 Oral Rat 7 g/kg -
Ethyl Acetate LD50 Oral Rat 5620 mg/kg -
2-Propanol LD50 Dermal Rabbit 12800 mg/kg -
LD50 Oral Rat 5000 mg/kg -
Carbon Black LD50 Oral Rat >15400 mg/kg -
Methyl Isobutyl Ketone LD50 Oral Rat 2080 mg/kg -
Irritation/Corrosion
Product/ingredient name Result Species Score Exposure Observation
Acetone Eyes - Mild irritant Human - 186300 parts -
per million
Eyes - Mild irritant Rabbit - 10 microliters -
Eyes - Moderate irritant Rabbit - 24 hours 20 -
milligrams
Eyes - Severe irritant Rabbit - 20 milligrams -
Skin - Mild irritant Rabbit - 24 hours 500 -
milligrams
Skin - Mild irritant Rabbit - 395 -
milligrams
Methyl Ethyl Ketone Skin - Mild irritant Rabbit - 24 hours 14 -
milligrams
Skin - Moderate irritant Rabbit - 24 hours 500 -
milligrams
Ethanol Eyes - Mild irritant Rabbit - 24 hours 500 -
milligrams
Eyes - Moderate irritant Rabbit - 0.066666667 -
minutes 100
milligrams
Eyes - Moderate irritant Rabbit - 100 -
microliters
Eyes - Severe irritant Rabbit - 500 -
milligrams
Skin - Mild irritant Rabbit - 400 -
milligrams
Skin - Moderate irritant Rabbit - 24 hours 20 -
milligrams
2-Propanol Eyes - Moderate irritant Rabbit - 24 hours 100 -
milligrams
Eyes - Moderate irritant Rabbit - 10 milligrams -
Eyes - Severe irritant Rabbit - 100 -
milligrams
Skin - Mild irritant Rabbit - 500 -

Date of issue/Date of revision : 4/21/2015. Date of previous issue : No previous validation. Version :1 9/15
Section 11. Toxicological information
milligrams
Methyl Isobutyl Ketone Eyes - Moderate irritant Rabbit - 24 hours 100 -
microliters
Eyes - Severe irritant Rabbit - 40 milligrams -
Skin - Mild irritant Rabbit - 24 hours 500 -
milligrams
Sensitization
Not available.

Mutagenicity
Not available.
Carcinogenicity
Not available.
Classification
Product/ingredient name OSHA IARC NTP
Ethanol - 1 -
2-Propanol - 3 -
Carbon Black - 2B -
Methyl Isobutyl Ketone - 2B -
Reproductive toxicity
Not available.

Teratogenicity
Not available.
Specific target organ toxicity (single exposure)
Name Category Route of Target organs
exposure
Acetone Category 3 Not applicable. Respiratory tract
irritation and
Narcotic effects
Methyl Ethyl Ketone Category 3 Not applicable. Respiratory tract
irritation and
Narcotic effects
Propane Category 3 Not applicable. Respiratory tract
irritation and
Narcotic effects
Butane Category 3 Not applicable. Respiratory tract
irritation and
Narcotic effects
Ethanol Category 3 Not applicable. Respiratory tract
irritation and
Narcotic effects
2-Propanol Category 3 Not applicable. Respiratory tract
irritation and
Narcotic effects
Methyl Isobutyl Ketone Category 3 Not applicable. Respiratory tract
irritation and
Narcotic effects
Specific target organ toxicity (repeated exposure)

Date of issue/Date of revision : 4/21/2015. Date of previous issue : No previous validation. Version :1 10/15
Section 11. Toxicological information
Name Category Route of Target organs
exposure
Acetone Category 2 Not determined Not determined
Methyl Ethyl Ketone Category 2 Not determined Not determined
Propane Category 2 Not determined Not determined
Butane Category 2 Not determined Not determined
Ethanol Category 2 Not determined Not determined
2-Propanol Category 2 Not determined Not determined
Methyl Isobutyl Ketone Category 2 Not determined Not determined
Aspiration hazard
Name Result
Propane ASPIRATION HAZARD - Category 1
Butane ASPIRATION HAZARD - Category 1

Information on the likely : Not available.


routes of exposure
Potential acute health effects
Eye contact : Causes serious eye irritation.
Inhalation : Can cause central nervous system (CNS) depression. May cause drowsiness and
dizziness. May cause respiratory irritation. Exposure to decomposition products may
cause a health hazard. Serious effects may be delayed following exposure.
Skin contact : Causes skin irritation.
Ingestion : Can cause central nervous system (CNS) depression. May be fatal if swallowed and
enters airways. Irritating to mouth, throat and stomach.

Symptoms related to the physical, chemical and toxicological characteristics


Eye contact : Adverse symptoms may include the following:
pain or irritation
watering
redness
Inhalation : Adverse symptoms may include the following:
respiratory tract irritation
coughing
nausea or vomiting
headache
drowsiness/fatigue
dizziness/vertigo
unconsciousness
Skin contact : Adverse symptoms may include the following:
irritation
redness
Ingestion : Adverse symptoms may include the following:
nausea or vomiting

Delayed and immediate effects and also chronic effects from short and long term exposure
Short term exposure
Potential immediate : Not available.
effects
Potential delayed effects : Not available.
Long term exposure
Potential immediate : Not available.
effects
Date of issue/Date of revision : 4/21/2015. Date of previous issue : No previous validation. Version :1 11/15
Potential delayed effects : Not available.
Potential chronic health effects
Not available.
General : May cause damage to organs through prolonged or repeated exposure.
Carcinogenicity : May cause cancer. Risk of cancer depends on duration and level of exposure.
Mutagenicity : No known significant effects or critical hazards.
Teratogenicity : No known significant effects or critical hazards.
Developmental effects : No known significant effects or critical hazards.
Fertility effects : No known significant effects or critical hazards.

Numerical measures of toxicity


Acute toxicity estimates
Route ATE value
Oral 10254.2 mg/kg

Section 12. Ecological information


Toxicity
Product/ingredient name Result Species Exposure
Acetone Acute EC50 20.565 mg/l Marine water Algae - Ulva pertusa 96 hours
Acute LC50 6000000 µg/l Fresh water Crustaceans - Gammarus pulex 48 hours
Acute LC50 10000 µg/l Fresh water Daphnia - Daphnia magna 48 hours
Acute LC50 5600 ppm Fresh water Fish - Poecilia reticulata 96 hours
Chronic NOEC 4.95 mg/l Marine water Algae - Ulva pertusa 96 hours
Chronic NOEC 0.016 ml/L Fresh water Crustaceans - Daphniidae 21 days
Chronic NOEC 0.1 ml/L Fresh water Daphnia - Daphnia magna - 21 days
Neonate
Chronic NOEC 5 µg/l Marine water Fish - Gasterosteus aculeatus - 42 days
Larvae
Methyl Ethyl Ketone Acute EC50 >500000 µg/l Marine water Algae - Skeletonema costatum 96 hours
Acute EC50 5091000 µg/l Fresh water Daphnia - Daphnia magna - 48 hours
Larvae
Acute LC50 3220000 µg/l Fresh water Fish - Pimephales promelas 96 hours
Ethanol Acute EC50 17.921 mg/l Marine water Algae - Ulva pertusa 96 hours
Acute EC50 2000 µg/l Fresh water Daphnia - Daphnia magna 48 hours
Acute LC50 25500 µg/l Marine water Crustaceans - Artemia 48 hours
franciscana - Larvae
Acute LC50 42000 µg/l Fresh water Fish - Oncorhynchus mykiss 4 days
Chronic NOEC 4.995 mg/l Marine water Algae - Ulva pertusa 96 hours
Chronic NOEC 0.375 ul/L Fresh water Fish - Gambusia holbrooki - 12 weeks
Larvae
Ethyl Acetate Acute EC50 2500000 µg/l Fresh water Algae - Selenastrum sp. 96 hours
Acute LC50 750000 µg/l Fresh water Crustaceans - Gammarus pulex 48 hours
Acute LC50 154000 µg/l Fresh water Daphnia - Daphnia cucullata 48 hours
Acute LC50 212500 µg/l Fresh water Fish - Heteropneustes fossilis 96 hours
Chronic NOEC 2400 µg/l Fresh water Daphnia - Daphnia magna 21 days
Chronic NOEC 75.6 mg/l Fresh water Fish - Pimephales promelas - 32 days
Embryo
2-Propanol Acute LC50 1400000 µg/l Marine water Crustaceans - Crangon crangon 48 hours
Acute LC50 4200 mg/l Fresh water Fish - Rasbora heteromorpha 96 hours
Methyl Isobutyl Ketone Acute LC50 505000 µg/l Fresh water Fish - Pimephales promelas 96 hours
Chronic NOEC 78 mg/l Fresh water Daphnia - Daphnia magna 21 days
Chronic NOEC 168 mg/l Fresh water Fish - Pimephales promelas - 33 days
Embryo

Date of issue/Date of revision : 4/21/2015. Date of previous issue : No previous validation. Version :1 12/15
Section 12. Ecological information
Persistence and degradability
Product/ingredient name Aquatic half-life Photolysis Biodegradability
Acetone - - Readily
Methyl Ethyl Ketone - - Readily
Ethanol - - Readily
Ethyl Acetate - - Readily
2-Propanol - - Readily
Methyl Isobutyl Ketone - - Readily

Bioaccumulative potential
Product/ingredient name LogPow BCF Potential
Ethyl Acetate - 30 low

Mobility in soil
Soil/water partition : Not available.
coefficient (KOC)

Other adverse effects : No known significant effects or critical hazards.

Section 13. Disposal considerations


Disposal methods : The generation of waste should be avoided or minimized wherever possible. Disposal
of this product, solutions and any by-products should at all times comply with the
requirements of environmental protection and waste disposal legislation and any
regional local authority requirements. Dispose of surplus and non-recyclable products
via a licensed waste disposal contractor. Waste should not be disposed of untreated to
the sewer unless fully compliant with the requirements of all authorities with jurisdiction.
Waste packaging should be recycled. Incineration or landfill should only be considered
when recycling is not feasible. This material and its container must be disposed of in a
safe way. Empty containers or liners may retain some product residues. Do not
puncture or incinerate container.

Section 14. Transport information


DOT TDG Mexico IATA IMDG
Classification Classification Classification
UN number UN1950 UN1950 UN1950 UN1950 UN1950

UN proper AEROSOLS AEROSOLS AEROSOLS AEROSOLS, AEROSOLS


shipping name flammable
Transport 2.1 2.1 2.1 2.1 2.1
hazard class(es)

Packing group - - - - -
Environmental No. No. No. No. No.
hazards

Date of issue/Date of revision : 4/21/2015. Date of previous issue : No previous validation. Version :1 13/15
Section 14. Transport information
Additional Special Special Special Special Emergency
information provisions provisions provisions provisions schedules (EmS)
LIMITED LIMITED (ERG#126) LIMITED LIMITED
QUANTITY QUANTITY QUANTITY QUANTITY, F-D,
S-U

Special precautions for user : Multi-modal shipping descriptions are provided for informational purposes and do not
consider container sizes. The presence of a shipping description for a particular
mode of transport (sea, air, etc.), does not indicate that the product is packaged
suitably for that mode of transport. All packaging must be reviewed for suitability prior
to shipment, and compliance with the applicable regulations is the sole responsibility
of the person offering the product for transport. People loading and unloading
dangerous goods must be trained on all of the risks deriving from the substances
and on all actions in case of emergency situations.

Transport in bulk according : Not available.


to Annex II of MARPOL
73/78 and the IBC Code

Section 15. Regulatory information


U.S. Federal regulations :
State regulations
California Prop. 65
WARNING: This product contains chemicals known to the State of California to cause cancer and birth defects or other
reproductive harm.

Section 16. Other information


Hazardous Material Information System (U.S.A.)
Health * 2

Flammability 4
Physical hazards 0

Caution: HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4
representing significant hazards or risks Although HMIS® ratings are not required on SDSs under 29 CFR 1910.
1200, the preparer may choose to provide them. HMIS® ratings are to be used with a fully implemented HMIS®
program. HMIS® is a registered mark of the National Paint & Coatings Association (NPCA). HMIS® materials may
be purchased exclusively from J. J. Keller (800) 327-6868.
The customer is responsible for determining the PPE code for this material.

Date of issue/Date of revision : 4/21/2015. Date of previous issue : No previous validation. Version :1 14/15
Section 16. Other information

Notice to reader
It is recommended that each customer or recipient of this Safety Data Sheet (SDS) study it carefully and consult
resources, as necessary or appropriate, to become aware of and understand the data contained in this SDS and
any hazards associated with the product. This information is provided in good faith and believed to be accurate
as of the effective date herein. However, no warranty, express or implied, is given. The information presented
here applies only to the product as shipped. The addition of any material can change the composition, hazards
and risks of the product. Regulatory requirements are subject to change and may differ between various
locations and jurisdictions. The customer/buyer/user is responsible to ensure that his activities comply with all
country, federal, state, provincial or local laws. The conditions for use of the product are not under the control of
the manufacturer; the customer/buyer/user is responsible to determine the conditions necessary for the safe use
of this product. The customer/buyer/user should not use the product for any purpose other than the purpose
shown in the applicable section of this SDS without first referring to the supplier and obtaining written handling
instructions. Due to the proliferation of sources for information such as manufacturer-specific SDS, the
manufacturer cannot be responsible for SDSs obtained from any other source.

Date of issue/Date of revision : 4/21/2015. Date of previous issue : No previous validation. Version :1 15/15
SAFETY DATA SHEET
DAP1692

Section 1. Identification
Product name : DUPLI-COLOR® Sandable Primer
Gray Hot Rod
Product code : DAP1692
Other means of : Not available.
identification
Product type : Aerosol.
Relevant identified uses of the substance or mixture and uses advised against
Not applicable.

Manufacturer : Dupli-Color Products Company


Cleveland, OH 44115

Emergency telephone : (216) 566-2917


number of the company
Product Information : (800) 247-3270
Telephone Number
Regulatory Information : (216) 566-2902
Telephone Number
Transportation Emergency : (800) 424-9300
Telephone Number

Section 2. Hazards identification


OSHA/HCS status : This material is considered hazardous by the OSHA Hazard Communication Standard
(29 CFR 1910.1200).
Classification of the : FLAMMABLE AEROSOLS - Category 1
substance or mixture GASES UNDER PRESSURE - Compressed gas
SKIN CORROSION/IRRITATION - Category 2
SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 2A
SKIN SENSITIZATION - Category 1
CARCINOGENICITY - Category 2
TOXIC TO REPRODUCTION (Unborn child) - Category 2
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Respiratory tract
irritation) - Category 3
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Narcotic effects) -
Category 3
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) - Category 2
ASPIRATION HAZARD - Category 1
Percentage of the mixture consisting of ingredient(s) of unknown toxicity: 22.5%
GHS label elements
Hazard pictograms :

Signal word : Danger

Date of issue/Date of revision : 6/4/2016 Date of previous issue : 6/3/2016 Version :3 1/17
Section 2. Hazards identification
Hazard statements : Extremely flammable aerosol.
Contains gas under pressure; may explode if heated.
Causes serious eye irritation.
Causes skin irritation.
May cause an allergic skin reaction.
Suspected of damaging the unborn child.
Suspected of causing cancer.
May be fatal if swallowed and enters airways.
May cause respiratory irritation.
May cause drowsiness or dizziness.
May cause damage to organs through prolonged or repeated exposure.
Precautionary statements
General : Read label before use. Keep out of reach of children. If medical advice is needed, have
product container or label at hand.
Prevention : Obtain special instructions before use. Do not handle until all safety precautions have
been read and understood. Wear protective gloves. Wear eye or face protection.
Wear protective clothing. Keep away from heat, hot surfaces, sparks, open flames and
other ignition sources. No smoking. Do not spray on an open flame or other ignition
source. Use only outdoors or in a well-ventilated area. Do not breathe dust or mist.
Wash hands thoroughly after handling. Contaminated work clothing must not be
allowed out of the workplace. Pressurized container: Do not pierce or burn, even after
use.
Response : Get medical attention if you feel unwell. IF exposed or concerned: Get medical
attention. IF INHALED: Remove person to fresh air and keep comfortable for breathing.
Call a POISON CENTER or physician if you feel unwell. IF SWALLOWED:
Immediately call a POISON CENTER or physician. Do NOT induce vomiting. IF ON
SKIN: Wash with plenty of soap and water. Wash contaminated clothing before reuse.
If skin irritation or rash occurs: Get medical attention. IF IN EYES: Rinse cautiously
with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing. If eye irritation persists: Get medical attention.
Storage : Store locked up. Protect from sunlight. Do not expose to temperatures exceeding 50
°C/122 °F. Store in a well-ventilated place.
Disposal : Dispose of contents and container in accordance with all local, regional, national and
international regulations.
Supplemental label DANGER: Rags, steel wool, other waste soaked with this product, and sanding residue
elements may spontaneously catch fire if improperly discarded. Immediately place rags, steel
wool, other waste soaked with this product, and sanding residue in a sealed, water-filled,
metal container. Dispose of in accordance with local fire regulations. DELAYED
EFFECTS FROM LONG TERM OVEREXPOSURE. Contains solvents which can cause
permanent brain and nervous system damage. Intentional misuse by deliberately
concentrating and inhaling the contents can be harmful or fatal. WARNING: This
product contains chemicals known to the State of California to cause cancer and birth
defects or other reproductive harm.
Please refer to the SDS for additional information. Keep out of reach of children. Keep
upright in a cool, dry place. Do not discard empty can in trash compactor.
Hazards not otherwise : None known.
classified

Section 3. Composition/information on ingredients


Substance/mixture : Mixture
Other means of : Not available.
identification
CAS number/other identifiers

Date of issue/Date of revision : 6/4/2016 Date of previous issue : 6/3/2016 Version :3 2/17
Section 3. Composition/information on ingredients
Ingredient name % by weight CAS number
Acetone 35.04 67-64-1
Propane 14.95 74-98-6
Butane 14.36 106-97-8
Toluene 10.25 108-88-3
Lt. Aliphatic Hydrocarbon Solvent 6.49 64742-89-8
Titanium Dioxide 1.06 13463-67-7
Naphthalene 0.15 91-20-3
Methyl Ethyl Ketoxime 0.11 96-29-7
Any concentration shown as a range is to protect confidentiality or is due to batch variation.
There are no additional ingredients present which, within the current knowledge of the supplier and in the
concentrations applicable, are classified as hazardous to health and hence require reporting in this section.

Occupational exposure limits, if available, are listed in Section 8.

Section 4. First aid measures


Description of necessary first aid measures
Eye contact : Immediately flush eyes with plenty of water, occasionally lifting the upper and lower
eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10
minutes. Get medical attention.
Inhalation : Remove victim to fresh air and keep at rest in a position comfortable for breathing. If it
is suspected that fumes are still present, the rescuer should wear an appropriate mask
or self-contained breathing apparatus. If not breathing, if breathing is irregular or if
respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It
may be dangerous to the person providing aid to give mouth-to-mouth resuscitation.
Get medical attention. If necessary, call a poison center or physician. If unconscious,
place in recovery position and get medical attention immediately. Maintain an open
airway. Loosen tight clothing such as a collar, tie, belt or waistband.
Skin contact : Wash with plenty of soap and water. Remove contaminated clothing and shoes. Wash
contaminated clothing thoroughly with water before removing it, or wear gloves.
Continue to rinse for at least 10 minutes. Get medical attention. In the event of any
complaints or symptoms, avoid further exposure. Wash clothing before reuse. Clean
shoes thoroughly before reuse.
Ingestion : Get medical attention immediately. Call a poison center or physician. Wash out mouth
with water. Remove dentures if any. Remove victim to fresh air and keep at rest in a
position comfortable for breathing. If material has been swallowed and the exposed
person is conscious, give small quantities of water to drink. Stop if the exposed person
feels sick as vomiting may be dangerous. Aspiration hazard if swallowed. Can enter
lungs and cause damage. Do not induce vomiting. If vomiting occurs, the head should
be kept low so that vomit does not enter the lungs. Never give anything by mouth to an
unconscious person. If unconscious, place in recovery position and get medical
attention immediately. Maintain an open airway. Loosen tight clothing such as a collar,
tie, belt or waistband.

Most important symptoms/effects, acute and delayed


Potential acute health effects
Eye contact : Causes serious eye irritation.
Inhalation : Can cause central nervous system (CNS) depression. May cause drowsiness or
dizziness. May cause respiratory irritation.
Skin contact : Causes skin irritation. May cause an allergic skin reaction.
Ingestion : Can cause central nervous system (CNS) depression. May be fatal if swallowed and
enters airways.
Over-exposure signs/symptoms

Date of issue/Date of revision : 6/4/2016 Date of previous issue : 6/3/2016 Version :3 3/17
Section 4. First aid measures
Eye contact : Adverse symptoms may include the following:
pain or irritation
watering
redness
Inhalation : Adverse symptoms may include the following:
respiratory tract irritation
coughing
nausea or vomiting
headache
drowsiness/fatigue
dizziness/vertigo
unconsciousness
reduced fetal weight
increase in fetal deaths
skeletal malformations
Skin contact : Adverse symptoms may include the following:
irritation
redness
reduced fetal weight
increase in fetal deaths
skeletal malformations
Ingestion : Adverse symptoms may include the following:
nausea or vomiting
reduced fetal weight
increase in fetal deaths
skeletal malformations

Indication of immediate medical attention and special treatment needed, if necessary


Notes to physician : Treat symptomatically. Contact poison treatment specialist immediately if large
quantities have been ingested or inhaled.
Specific treatments : No specific treatment.
Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. If it is
suspected that fumes are still present, the rescuer should wear an appropriate mask or
self-contained breathing apparatus. It may be dangerous to the person providing aid to
give mouth-to-mouth resuscitation. Wash contaminated clothing thoroughly with water
before removing it, or wear gloves.

See toxicological information (Section 11)

Section 5. Fire-fighting measures


Extinguishing media
Suitable extinguishing : Use an extinguishing agent suitable for the surrounding fire.
media
Unsuitable extinguishing : None known.
media

Specific hazards arising : Extremely flammable aerosol. In a fire or if heated, a pressure increase will occur and
from the chemical the container may burst, with the risk of a subsequent explosion. Gas may accumulate
in low or confined areas or travel a considerable distance to a source of ignition and
flash back, causing fire or explosion. Bursting aerosol containers may be propelled from
a fire at high speed. Runoff to sewer may create fire or explosion hazard.
Hazardous thermal : Decomposition products may include the following materials:
decomposition products carbon dioxide
carbon monoxide
metal oxide/oxides

Date of issue/Date of revision : 6/4/2016 Date of previous issue : 6/3/2016 Version :3 4/17
Section 5. Fire-fighting measures

Special protective actions : Promptly isolate the scene by removing all persons from the vicinity of the incident if
for fire-fighters there is a fire. No action shall be taken involving any personal risk or without suitable
training. Move containers from fire area if this can be done without risk. Use water
spray to keep fire-exposed containers cool.
Special protective : Fire-fighters should wear appropriate protective equipment and self-contained breathing
equipment for fire-fighters apparatus (SCBA) with a full face-piece operated in positive pressure mode.

Section 6. Accidental release measures


Personal precautions, protective equipment and emergency procedures
For non-emergency : No action shall be taken involving any personal risk or without suitable training.
personnel Evacuate surrounding areas. Keep unnecessary and unprotected personnel from
entering. In the case of aerosols being ruptured, care should be taken due to the rapid
escape of the pressurized contents and propellant. If a large number of containers are
ruptured, treat as a bulk material spillage according to the instructions in the clean-up
section. Do not touch or walk through spilled material. Shut off all ignition sources. No
flares, smoking or flames in hazard area. Avoid breathing vapor or mist. Provide
adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put
on appropriate personal protective equipment.
For emergency responders : If specialized clothing is required to deal with the spillage, take note of any information in
Section 8 on suitable and unsuitable materials. See also the information in "For non-
emergency personnel".

Environmental precautions : Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains
and sewers. Inform the relevant authorities if the product has caused environmental
pollution (sewers, waterways, soil or air).

Methods and materials for containment and cleaning up


Small spill : Stop leak if without risk. Move containers from spill area. Use spark-proof tools and
explosion-proof equipment. Dilute with water and mop up if water-soluble. Alternatively,
or if water-insoluble, absorb with an inert dry material and place in an appropriate waste
disposal container. Dispose of via a licensed waste disposal contractor.
Large spill : Stop leak if without risk. Move containers from spill area. Use spark-proof tools and
explosion-proof equipment. Approach release from upwind. Prevent entry into sewers,
water courses, basements or confined areas. Wash spillages into an effluent treatment
plant or proceed as follows. Contain and collect spillage with non-combustible,
absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in
container for disposal according to local regulations (see Section 13). Dispose of via a
licensed waste disposal contractor. Contaminated absorbent material may pose the
same hazard as the spilled product. Note: see Section 1 for emergency contact
information and Section 13 for waste disposal.

Section 7. Handling and storage


Precautions for safe handling
Protective measures : Put on appropriate personal protective equipment (see Section 8). Persons with a
history of skin sensitization problems should not be employed in any process in which
this product is used. Pressurized container: protect from sunlight and do not expose to
temperatures exceeding 50°C. Do not pierce or burn, even after use. Avoid exposure -
obtain special instructions before use. Avoid exposure during pregnancy. Do not
handle until all safety precautions have been read and understood. Do not get in eyes
or on skin or clothing. Do not breathe vapor or mist. Do not swallow. Avoid breathing
gas. Use only with adequate ventilation. Wear appropriate respirator when ventilation is
inadequate. Store and use away from heat, sparks, open flame or any other ignition
source. Use explosion-proof electrical (ventilating, lighting and material handling)
equipment. Use only non-sparking tools. Empty containers retain product residue and
can be hazardous.

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Section 7. Handling and storage
Advice on general : Eating, drinking and smoking should be prohibited in areas where this material is
occupational hygiene handled, stored and processed. Workers should wash hands and face before eating,
drinking and smoking. Remove contaminated clothing and protective equipment before
entering eating areas. See also Section 8 for additional information on hygiene
measures.

Conditions for safe storage, : Store in accordance with local regulations. Store away from direct sunlight in a dry, cool
including any and well-ventilated area, away from incompatible materials (see Section 10) and food
incompatibilities and drink. Protect from sunlight. Store locked up. Eliminate all ignition sources. Use
appropriate containment to avoid environmental contamination.

Section 8. Exposure controls/personal protection


Control parameters
Occupational exposure limits (OSHA United States)
Ingredient name Exposure limits
Acetone ACGIH TLV (United States, 3/2015).
TWA: 250 ppm 8 hours.
STEL: 500 ppm 15 minutes.
NIOSH REL (United States, 10/2013).
TWA: 250 ppm 10 hours.
TWA: 590 mg/m³ 10 hours.
OSHA PEL (United States, 2/2013).
TWA: 1000 ppm 8 hours.
TWA: 2400 mg/m³ 8 hours.
Propane NIOSH REL (United States, 10/2013).
TWA: 1000 ppm 10 hours.
TWA: 1800 mg/m³ 10 hours.
OSHA PEL (United States, 2/2013).
TWA: 1000 ppm 8 hours.
TWA: 1800 mg/m³ 8 hours.
Butane NIOSH REL (United States, 10/2013).
TWA: 800 ppm 10 hours.
TWA: 1900 mg/m³ 10 hours.
ACGIH TLV (United States, 3/2015).
STEL: 1000 ppm 15 minutes.
Toluene OSHA PEL Z2 (United States, 2/2013).
TWA: 200 ppm 8 hours.
CEIL: 300 ppm
AMP: 500 ppm 10 minutes.
NIOSH REL (United States, 10/2013).
TWA: 100 ppm 10 hours.
TWA: 375 mg/m³ 10 hours.
STEL: 150 ppm 15 minutes.
STEL: 560 mg/m³ 15 minutes.
ACGIH TLV (United States, 3/2015).
TWA: 20 ppm 8 hours.
Lt. Aliphatic Hydrocarbon Solvent None.
Titanium Dioxide ACGIH TLV (United States, 3/2015).
TWA: 10 mg/m³ 8 hours.
OSHA PEL (United States, 2/2013).
TWA: 15 mg/m³ 8 hours. Form: Total dust
Naphthalene ACGIH TLV (United States, 3/2015).
Absorbed through skin.
TWA: 10 ppm 8 hours.
TWA: 52 mg/m³ 8 hours.
NIOSH REL (United States, 10/2013).
TWA: 10 ppm 10 hours.
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Section 8. Exposure controls/personal protection
TWA: 50 mg/m³ 10 hours.
STEL: 15 ppm 15 minutes.
STEL: 75 mg/m³ 15 minutes.
OSHA PEL (United States, 2/2013).
TWA: 10 ppm 8 hours.
TWA: 50 mg/m³ 8 hours.

Methyl Ethyl Ketoxime AIHA WEEL (United States, 10/2011). Skin


sensitizer.
TWA: 10 ppm 8 hours.

Occupational exposure limits (Canada)


Ingredient name Exposure limits
Acetone CA Alberta Provincial (Canada, 4/2009).
8 hrs OEL: 1200 mg/m³ 8 hours.
15 min OEL: 1800 mg/m³ 15 minutes.
8 hrs OEL: 500 ppm 8 hours.
15 min OEL: 750 ppm 15 minutes.
CA British Columbia Provincial (Canada,
5/2015).
TWA: 250 ppm 8 hours.
STEL: 500 ppm 15 minutes.
CA Ontario Provincial (Canada, 7/2015).
TWA: 500 ppm 8 hours.
STEL: 750 ppm 15 minutes.
CA Quebec Provincial (Canada, 1/2014).
TWAEV: 500 ppm 8 hours.
TWAEV: 1190 mg/m³ 8 hours.
STEV: 1000 ppm 15 minutes.
STEV: 2380 mg/m³ 15 minutes.
CA Saskatchewan Provincial (Canada,
7/2013).
STEL: 750 ppm 15 minutes.
TWA: 500 ppm 8 hours.
Propane CA Alberta Provincial (Canada, 4/2009).
8 hrs OEL: 1000 ppm 8 hours.
CA British Columbia Provincial (Canada,
5/2015).
TWA: 1000 ppm 8 hours.
CA Quebec Provincial (Canada, 1/2014).
TWAEV: 1000 ppm 8 hours.
TWAEV: 1800 mg/m³ 8 hours.
CA Ontario Provincial (Canada, 7/2015).
TWA: 1000 ppm 8 hours.
CA Saskatchewan Provincial (Canada,
7/2013).
STEL: 1250 ppm 15 minutes.
TWA: 1000 ppm 8 hours.
Butane CA Alberta Provincial (Canada, 4/2009).
8 hrs OEL: 1000 ppm 8 hours.
CA British Columbia Provincial (Canada,
5/2015).
TWA: 600 ppm 8 hours.
STEL: 750 ppm 15 minutes.
CA Quebec Provincial (Canada, 1/2014).
TWAEV: 800 ppm 8 hours.
TWAEV: 1900 mg/m³ 8 hours.

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Section 8. Exposure controls/personal protection
CA Ontario Provincial (Canada, 7/2015).
TWA: 800 ppm 8 hours.
CA Saskatchewan Provincial (Canada,
7/2013).
STEL: 1250 ppm 15 minutes.
TWA: 1000 ppm 8 hours.
Toluene CA Alberta Provincial (Canada, 4/2009).
Absorbed through skin.
8 hrs OEL: 50 ppm 8 hours.
8 hrs OEL: 188 mg/m³ 8 hours.
CA British Columbia Provincial (Canada,
5/2015).
TWA: 20 ppm 8 hours.
CA Ontario Provincial (Canada, 7/2015).
TWA: 20 ppm 8 hours.
CA Quebec Provincial (Canada, 1/2014).
Absorbed through skin.
TWAEV: 50 ppm 8 hours.
TWAEV: 188 mg/m³ 8 hours.
CA Saskatchewan Provincial (Canada,
7/2013). Absorbed through skin.
STEL: 60 ppm 15 minutes.
TWA: 50 ppm 8 hours.
Naphthalene CA Alberta Provincial (Canada, 4/2009).
Absorbed through skin.
15 min OEL: 15 ppm 15 minutes.
8 hrs OEL: 10 ppm 8 hours.
8 hrs OEL: 52 mg/m³ 8 hours.
15 min OEL: 79 mg/m³ 15 minutes.
CA British Columbia Provincial (Canada,
5/2015). Absorbed through skin.
TWA: 10 ppm 8 hours.
STEL: 15 ppm 15 minutes.
CA Ontario Provincial (Canada, 7/2015).
Absorbed through skin.
TWA: 10 ppm 8 hours.
STEL: 15 ppm 15 minutes.
CA Quebec Provincial (Canada, 1/2014).
TWAEV: 10 ppm 8 hours.
TWAEV: 52 mg/m³ 8 hours.
STEV: 15 ppm 15 minutes.
STEV: 79 mg/m³ 15 minutes.
CA Saskatchewan Provincial (Canada,
7/2013). Absorbed through skin.
STEL: 15 ppm 15 minutes.
TWA: 10 ppm 8 hours.
Methyl Ethyl Ketoxime AIHA WEEL (United States, 10/2011). Skin
sensitizer.
TWA: 10 ppm 8 hours.

Appropriate engineering : Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or
controls other engineering controls to keep worker exposure to airborne contaminants below any
recommended or statutory limits. The engineering controls also need to keep gas,
vapor or dust concentrations below any lower explosive limits. Use explosion-proof
ventilation equipment.
Environmental exposure :
controls

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Section 8. Exposure controls/personal protection
Emissions from ventilation or work process equipment should be checked to ensure
they comply with the requirements of environmental protection legislation. In some
cases, fume scrubbers, filters or engineering modifications to the process equipment
will be necessary to reduce emissions to acceptable levels.

Individual protection measures


Hygiene measures : Wash hands, forearms and face thoroughly after handling chemical products, before
eating, smoking and using the lavatory and at the end of the working period.
Appropriate techniques should be used to remove potentially contaminated clothing.
Contaminated work clothing should not be allowed out of the workplace. Wash
contaminated clothing before reusing. Ensure that eyewash stations and safety
showers are close to the workstation location.
Eye/face protection : Safety eyewear complying with an approved standard should be used when a risk
assessment indicates this is necessary to avoid exposure to liquid splashes, mists,
gases or dusts. If contact is possible, the following protection should be worn, unless
the assessment indicates a higher degree of protection: chemical splash goggles.
Skin protection
Hand protection : Chemical-resistant, impervious gloves complying with an approved standard should be
worn at all times when handling chemical products if a risk assessment indicates this is
necessary. Considering the parameters specified by the glove manufacturer, check
during use that the gloves are still retaining their protective properties. It should be
noted that the time to breakthrough for any glove material may be different for different
glove manufacturers. In the case of mixtures, consisting of several substances, the
protection time of the gloves cannot be accurately estimated.
Body protection : Personal protective equipment for the body should be selected based on the task being
performed and the risks involved and should be approved by a specialist before
handling this product. When there is a risk of ignition from static electricity, wear anti-
static protective clothing. For the greatest protection from static discharges, clothing
should include anti-static overalls, boots and gloves.
Other skin protection : Appropriate footwear and any additional skin protection measures should be selected
based on the task being performed and the risks involved and should be approved by a
specialist before handling this product.
Respiratory protection : Based on the hazard and potential for exposure, select a respirator that meets the
appropriate standard or certification. Respirators must be used according to a
respiratory protection program to ensure proper fitting, training, and other important
aspects of use.

Section 9. Physical and chemical properties


Appearance
Physical state : Liquid.
Color : Not available.
Odor : Not available.
Odor threshold : Not available.
pH : Not available.
Melting point : Not available.
Boiling point : Not available.
Flash point : Closed cup: -29°C (-20.2°F) [Pensky-Martens Closed Cup]
Evaporation rate : 5.6 (butyl acetate = 1)
Flammability (solid, gas) : Not available.
Lower and upper explosive : Lower: 0.9%
(flammable) limits Upper: 12.8%
Vapor pressure : 13.5 kPa (101.325 mm Hg) [at 20°C]
Vapor density : 1.55 [Air = 1]

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Section 9. Physical and chemical properties
Relative density : 0.75
Solubility : Not available.
Partition coefficient: n- : Not available.
octanol/water
Auto-ignition temperature : Not available.
Decomposition temperature : Not available.
Viscosity : Kinematic (room temperature): <0.205 cm2/s (<20.5 cSt)
Kinematic (40°C (104°F)): <0.205 cm2/s (<20.5 cSt)
Molecular weight : Not applicable.
Aerosol product
Type of aerosol : Spray
Heat of combustion : 29.89 kJ/g

Section 10. Stability and reactivity


Reactivity : No specific test data related to reactivity available for this product or its ingredients.

Chemical stability : The product is stable.

Possibility of hazardous : Under normal conditions of storage and use, hazardous reactions will not occur.
reactions

Conditions to avoid : Avoid all possible sources of ignition (spark or flame).

Incompatible materials : No specific data.

Hazardous decomposition : Under normal conditions of storage and use, hazardous decomposition products should
products not be produced.

Section 11. Toxicological information


Information on toxicological effects
Acute toxicity
Product/ingredient name Result Species Dose Exposure
Acetone LD50 Oral Rat 5800 mg/kg -
Butane LC50 Inhalation Vapor Rat 658000 mg/m³ 4 hours
Toluene LC50 Inhalation Vapor Rat 49 g/m³ 4 hours
LD50 Oral Rat 636 mg/kg -
Naphthalene LD50 Dermal Rabbit >20 g/kg -
LD50 Oral Rat 490 mg/kg -
Methyl Ethyl Ketoxime LD50 Oral Rat 930 mg/kg -
Irritation/Corrosion
Product/ingredient name Result Species Score Exposure Observation
Acetone Eyes - Mild irritant Human - 186300 parts -
per million
Eyes - Mild irritant Rabbit - 10 microliters -
Eyes - Moderate irritant Rabbit - 24 hours 20 -
milligrams
Eyes - Severe irritant Rabbit - 20 milligrams -
Skin - Mild irritant Rabbit - 24 hours 500 -
milligrams
Skin - Mild irritant Rabbit - 395 -

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Section 11. Toxicological information
milligrams
Toluene Eyes - Mild irritant Rabbit - 0.5 minutes -
100
milligrams
Eyes - Mild irritant Rabbit - 870 -
Micrograms
Eyes - Severe irritant Rabbit - 24 hours 2 -
milligrams
Skin - Mild irritant Pig - 24 hours 250 -
microliters
Skin - Mild irritant Rabbit - 435 -
milligrams
Skin - Moderate irritant Rabbit - 24 hours 20 -
milligrams
Skin - Moderate irritant Rabbit - 500 -
milligrams
Titanium Dioxide Skin - Mild irritant Human - 72 hours 300 -
Micrograms
Intermittent
Naphthalene Skin - Mild irritant Rabbit - 495 -
milligrams
Skin - Severe irritant Rabbit - 24 hours 0.05 -
Mililiters
Methyl Ethyl Ketoxime Eyes - Severe irritant Rabbit - 100 -
microliters
Sensitization
Not available.
Mutagenicity
Not available.
Carcinogenicity
Not available.
Classification
Product/ingredient name OSHA IARC NTP
Toluene - 3 -
Titanium Dioxide - 2B -
Naphthalene - 2B Reasonably anticipated to be a human carcinogen.
Reproductive toxicity
Not available.
Teratogenicity
Not available.
Specific target organ toxicity (single exposure)
Name Category Route of Target organs
exposure
Acetone Category 3 Not applicable. Respiratory tract
irritation and
Narcotic effects
Propane Category 3 Not applicable. Respiratory tract
irritation and
Narcotic effects
Butane Category 3 Not applicable. Respiratory tract
irritation and
Narcotic effects
Toluene Category 3 Not applicable. Respiratory tract
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Section 11. Toxicological information
irritation and
Narcotic effects
Lt. Aliphatic Hydrocarbon Solvent Category 3 Not applicable. Respiratory tract
irritation and
Narcotic effects
Naphthalene Category 3 Not applicable. Respiratory tract
irritation and
Narcotic effects
Specific target organ toxicity (repeated exposure)
Name Category Route of Target organs
exposure
Acetone Category 2 Not determined Not determined
Propane Category 2 Not determined Not determined
Butane Category 2 Not determined Not determined
Toluene Category 2 Not determined Not determined
Lt. Aliphatic Hydrocarbon Solvent Category 2 Not determined Not determined
Naphthalene Category 2 Not determined Not determined
Aspiration hazard
Name Result
Propane ASPIRATION HAZARD - Category 1
Butane ASPIRATION HAZARD - Category 1
Toluene ASPIRATION HAZARD - Category 1
Lt. Aliphatic Hydrocarbon Solvent ASPIRATION HAZARD - Category 1
Naphthalene ASPIRATION HAZARD - Category 1

Information on the likely : Not available.


routes of exposure
Potential acute health effects
Eye contact : Causes serious eye irritation.
Inhalation : Can cause central nervous system (CNS) depression. May cause drowsiness or
dizziness. May cause respiratory irritation.
Skin contact : Causes skin irritation. May cause an allergic skin reaction.
Ingestion : Can cause central nervous system (CNS) depression. May be fatal if swallowed and
enters airways.

Symptoms related to the physical, chemical and toxicological characteristics


Eye contact : Adverse symptoms may include the following:
pain or irritation
watering
redness
Inhalation : Adverse symptoms may include the following:
respiratory tract irritation
coughing
nausea or vomiting
headache
drowsiness/fatigue
dizziness/vertigo
unconsciousness
reduced fetal weight
increase in fetal deaths
skeletal malformations

Date of issue/Date of revision : 6/4/2016 Date of previous issue : 6/3/2016 Version :3 12/17
Skin contact : Adverse symptoms may include the following:
irritation
redness
reduced fetal weight
increase in fetal deaths
skeletal malformations
Ingestion : Adverse symptoms may include the following:
nausea or vomiting
reduced fetal weight
increase in fetal deaths
skeletal malformations

Delayed and immediate effects and also chronic effects from short and long term exposure
Short term exposure
Potential immediate : Not available.
effects
Potential delayed effects : Not available.
Long term exposure
Potential immediate : Not available.
effects
Potential delayed effects : Not available.
Potential chronic health effects
Not available.
General : May cause damage to organs through prolonged or repeated exposure. Once
sensitized, a severe allergic reaction may occur when subsequently exposed to very low
levels.
Carcinogenicity : Suspected of causing cancer. Risk of cancer depends on duration and level of
exposure.
Mutagenicity : No known significant effects or critical hazards.
Teratogenicity : Suspected of damaging the unborn child.
Developmental effects : No known significant effects or critical hazards.
Fertility effects : No known significant effects or critical hazards.

Numerical measures of toxicity


Acute toxicity estimates
Route ATE value
Oral 4539.5 mg/kg

Section 12. Ecological information


Toxicity
Product/ingredient name Result Species Exposure
Acetone Acute EC50 7200000 µg/l Fresh water Algae - Selenastrum sp. 96 hours
Acute LC50 6000000 µg/l Fresh water Crustaceans - Gammarus pulex 48 hours
Acute LC50 6900 mg/l Fresh water Daphnia - Daphnia magna 48 hours
Acute LC50 5600 ppm Fresh water Fish - Poecilia reticulata 96 hours
Chronic NOEC 4.95 mg/l Marine water Algae - Ulva pertusa 96 hours
Chronic NOEC 0.016 ml/L Fresh water Crustaceans - Daphniidae 21 days
Chronic NOEC 0.1 ml/L Fresh water Daphnia - Daphnia magna - 21 days
Neonate
Toluene Acute EC50 12500 µg/l Fresh water Algae - Pseudokirchneriella 72 hours
subcapitata

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Section 12. Ecological information
Acute EC50 11600 µg/l Fresh water Crustaceans - Gammarus 48 hours
pseudolimnaeus - Adult
Acute EC50 6000 µg/l Fresh water Daphnia - Daphnia magna - 48 hours
Juvenile (Fledgling, Hatchling,
Weanling)
Acute LC50 5500 µg/l Fresh water Fish - Oncorhynchus kisutch - Fry 96 hours
Chronic NOEC 1000 µg/l Fresh water Daphnia - Daphnia magna 21 days
Lt. Aliphatic Hydrocarbon Acute LC50 >100000 ppm Fresh water Fish - Oncorhynchus mykiss 96 hours
Solvent
Titanium Dioxide Acute LC50 >1000000 µg/l Marine water Fish - Fundulus heteroclitus 96 hours
Naphthalene Acute EC50 1600 µg/l Fresh water Daphnia - Daphnia magna - 48 hours
Neonate
Acute LC50 2350 µg/l Marine water Crustaceans - Palaemonetes 48 hours
pugio
Acute LC50 213 µg/l Fresh water Fish - Melanotaenia fluviatilis - 96 hours
Larvae
Methyl Ethyl Ketoxime Acute LC50 843000 µg/l Fresh water Fish - Pimephales promelas 96 hours

Persistence and degradability


Product/ingredient name Aquatic half-life Photolysis Biodegradability
Acetone - - Readily
Toluene - - Readily

Bioaccumulative potential
Product/ingredient name LogPow BCF Potential
Toluene - 90 low
Lt. Aliphatic Hydrocarbon - 10 to 2500 high
Solvent
Naphthalene - 36.5 to 168 low
Methyl Ethyl Ketoxime - 2.5 to 5.8 low

Mobility in soil
Soil/water partition : Not available.
coefficient (KOC)

Other adverse effects : No known significant effects or critical hazards.

Section 13. Disposal considerations


Disposal methods : The generation of waste should be avoided or minimized wherever possible. Disposal
of this product, solutions and any by-products should at all times comply with the
requirements of environmental protection and waste disposal legislation and any
regional local authority requirements. Dispose of surplus and non-recyclable products
via a licensed waste disposal contractor. Waste should not be disposed of untreated to
the sewer unless fully compliant with the requirements of all authorities with jurisdiction.
Waste packaging should be recycled. Incineration or landfill should only be considered
when recycling is not feasible. This material and its container must be disposed of in a
safe way. Empty containers or liners may retain some product residues. Do not
puncture or incinerate container.

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Section 14. Transport information
DOT TDG Mexico IATA IMDG
Classification Classification Classification
UN number UN1950 UN1950 UN1950 UN1950 UN1950

UN proper AEROSOLS AEROSOLS AEROSOLS AEROSOLS, AEROSOLS


shipping name flammable
Transport 2.1 2.1 2.1 2.1 2.1
hazard class(es)

Packing group - - - - -
Environmental No. No. No. No. No.
hazards
Additional - Product classified - - Emergency
information as per the schedules (EmS)
following sections F-D, S-U
of the
Transportation of
Dangerous Goods
Regulations: 2.
13-2.17 (Class 2).
ERG No. ERG No. ERG No.
126 126 126
Special precautions for user : Multi-modal shipping descriptions are provided for informational purposes and do not
consider container sizes. The presence of a shipping description for a particular
mode of transport (sea, air, etc.), does not indicate that the product is packaged
suitably for that mode of transport. All packaging must be reviewed for suitability
prior to shipment, and compliance with the applicable regulations is the sole
responsibility of the person offering the product for transport. People loading and
unloading dangerous goods must be trained on all of the risks deriving from the
substances and on all actions in case of emergency situations.

Transport in bulk according : Not available.


to Annex II of MARPOL and
the IBC Code
Proper shipping name : Not available.
Ship type : Not available.
Pollution category : Not available.

Section 15. Regulatory information


SARA 313
SARA 313 (40 CFR 372.45) supplier notification can be found on the Environmental Data Sheet.

Date of issue/Date of revision : 6/4/2016 Date of previous issue : 6/3/2016 Version :3 15/17
California Prop. 65
WARNING: This product contains chemicals known to the State of California to cause cancer and birth defects or other
reproductive harm.

Section 16. Other information


Hazardous Material Information System (U.S.A.)
Health * 2

Flammability 3

Physical hazards 0

The customer is responsible for determining the PPE code for this material.

Caution: HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4
representing significant hazards or risks Although HMIS® ratings are not required on SDSs under 29 CFR 1910.
1200, the preparer may choose to provide them. HMIS® ratings are to be used with a fully implemented HMIS®
program. HMIS® is a registered mark of the National Paint & Coatings Association (NPCA). HMIS® materials may
be purchased exclusively from J. J. Keller (800) 327-6868.
Procedure used to derive the classification
Classification Justification
FLAMMABLE AEROSOLS - Category 1 On basis of test data
GASES UNDER PRESSURE - Compressed gas Calculation method
SKIN CORROSION/IRRITATION - Category 2 Calculation method
SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 2A Calculation method
SKIN SENSITIZATION - Category 1 Calculation method
CARCINOGENICITY - Category 2 Calculation method
TOXIC TO REPRODUCTION (Unborn child) - Category 2 Calculation method
SPECIFIC TARGET ORGAN TOXICITY (SINGLE Calculation method
EXPOSURE) (Respiratory tract irritation) - Category 3
SPECIFIC TARGET ORGAN TOXICITY (SINGLE Calculation method
EXPOSURE) (Narcotic effects) - Category 3
SPECIFIC TARGET ORGAN TOXICITY (REPEATED Calculation method
EXPOSURE) - Category 2
ASPIRATION HAZARD - Category 1 Calculation method

History
Date of printing : 6/4/2016
Date of issue/Date of : 6/4/2016
revision
Date of previous issue : 6/3/2016
Version : 3
Key to abbreviations : ATE = Acute Toxicity Estimate
BCF = Bioconcentration Factor
GHS = Globally Harmonized System of Classification and Labelling of Chemicals
IATA = International Air Transport Association
IBC = Intermediate Bulk Container
IMDG = International Maritime Dangerous Goods
LogPow = logarithm of the octanol/water partition coefficient
MARPOL = International Convention for the Prevention of Pollution From Ships, 1973
as modified by the Protocol of 1978. ("Marpol" = marine pollution)
UN = United Nations
Notice to reader

Date of issue/Date of revision : 6/4/2016 Date of previous issue : 6/3/2016 Version :3 16/17
Section 16. Other information
It is recommended that each customer or recipient of this Safety Data Sheet (SDS) study it carefully and consult
resources, as necessary or appropriate, to become aware of and understand the data contained in this SDS and
any hazards associated with the product. This information is provided in good faith and believed to be accurate
as of the effective date herein. However, no warranty, express or implied, is given. The information presented
here applies only to the product as shipped. The addition of any material can change the composition, hazards
and risks of the product. Products shall not be repackaged, modified, or tinted except as specifically instructed
by Sherwin-Williams, including but not limited to the incorporation of non Sherwin-Williams products or the use
or addition of products in proportions not specified by Sherwin-Williams. Regulatory requirements are subject
to change and may differ between various locations and jurisdictions. The customer/buyer/user is responsible to
ensure that his activities comply with all country, federal, state, provincial or local laws. The conditions for use
of the product are not under the control of the manufacturer; the customer/buyer/user is responsible to
determine the conditions necessary for the safe use of this product. The customer/buyer/user should not use the
product for any purpose other than the purpose shown in the applicable section of this SDS without first
referring to the supplier and obtaining written handling instructions. Due to the proliferation of sources for
information such as manufacturer-specific SDS, the manufacturer cannot be responsible for SDSs obtained from
any other source.

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KLEEN-FLO TUMBLER INDUSTRIES LIMITED MATERIAL SAFETY DATA SHEET PAGE 1

SECTION I-MATERIAL IDENTIFICATION AND USE

Material Name/Identifier: Eco-Care Engine Degreaser Stock No. 022 / 023


Manufacturer's Name: Kleen-Flo Tumbler Industries Ltd Street Address: 75 Advance Blvd.
City: Brampton Province: Ontario
Postal Code: L6T 4N1 Emergency Phone #: CANUTEC:- 613-996-6666 (24HR)

Chemical Name: N.Ap.(mixture) Chemical Family: N.Ap.(mixture)


Chemical Formula: N.Ap. (Mixture) Trade Names & Synonyms: N/A
Material Use: Cleaner, Degreaser Molecular Weight: N.Ap.

SECTION II-HAZARDOUS INGREDIENTS OF MATERIAL

Hazardous Approximate LD50 LC50


Ingredients C.A.S. Concentration Species & Route Species & Route

D-limonene 5989-27-5 10 -30 % > 2 g/kg rat-oral N/E


Alcohol ethoxylate 68439-46-3 1-5% >2 g/kg rat-oral N/E
Diethylene glycol monobutyl 112-34-5 1-5% 6.56 g/kg rat-oral N/E
ether

SECTION III-PHYSICAL DATA FOR MATERIAL

Physical State: Liquid Odour/Appearance: Light citrus.clear light yellow liquid


Specific Gravity: 1.01 Odour Threshold(p.p.m.): N/E
Boiling Point: 100ºC (Approx.) Evaporation Rate: 1 (Water=1)
Freezing Point: 0 ºC Solubility in Water: Emulsifies
% wt. Volatile: N/E Vapour Pressure(mm)Hg: N/E
Vapour Density(Air=1): N/E Coefficient of Water/Oil Distribut: N/E
pH 11-12.3

SECTION IV-FIRE AND EXPLOSION HAZARD OF MATERIAL

Flammability Yes/No Yes, Combustible liquid If yes under which conditions:Open flame, heat, spark. May form
explosive air-vapour mixture at elevated temperature.
Auto Ignition Temperature: N/E Means of Extinction: carbon dioxide, dry powder, foam type
Flashpoint and Method: 52ºC TCC Hazardous Combustion Products: Oxides of carbon
and products of incomplete combustion.
Upper Flammable limit (% vol) N/Av. Lower Flammable Limit(% by volume): N/Av.
Explosion Data: Sensitivity to Mechanical Impact: No Sensitivity to Static Discharge: N/E

SECTION V-REACTIVITY DATA

Chemical Stability Yes/No: Yes If NO under Which conditions? N.Ap.


Incompatibility to Other Substances Yes/No: Yes If so which ones? Strong Oxidizers
Reactivity and under what conditions? none known
Hazardous Decomposition Products: Oxides of carbon

N/E: not established N.Ap.: not applicable N/Av.: not available


Material Name/Identifier: Eco-Care Engine Degreaser Stock No. 022 / 023 PAGE 2

SECTION VI-TOXICOLOGICAL PROPERTIES OF PRODUCT

Route of Entry: ALL routes --SKIN CONTACT --SKIN ABSORPTION --EYE CONTACT --INHALATION --INGESTION
Effects of Acute Exposure: Over exposure to vapour may irritate respiratory passages and/or cause dizziness, nausea or headaches.
May cause eye and skin irritation. Ingestion may cause gastrointestinal irritation and diarrhea.
Effects of Chronic Exposure: None known
LD 50 of Product: N/E LC 50 of Product: N/E
Irritancy of Product: Moderate skin and eye irritant Exposure Limits of Product: N/E
Sensitization of Product: N/E Toxicologically Synergistic Materials: N/E
--CARCINOGENICITY --REPRODUCTIVE EFFECTS --TERATOGENICITY --MUTAGENICITY None known

SECTION VII-PREVENTIVE MEASURES


Personal Protective Equipment to be used:
Gloves(specify): Solvent proof gloves Eye(specify): Splash proof eye goggles
Respiratory(specify): Maintain adequate ventilation Clothing: Not required
Respiratory Protection: If used indoors or on a continuous basis, use of cartridge respirator for organic vapour is recommended

Engineering Controls: Positive exhaust ventilation required for enclosed area

Leak and Spill Procedure: Use absorbent material and place in sealed container, rinse area with plenty of water.

Waste Disposal: According to your local and /or provincial regulation

Storage Requirements: Keep material at anbient temperature. Keep away form source of heat, spark and ignition.

Handling Procedures and No special procedure or equipment required.


Equipment:
DSL listing All components are listed
TDG Classification: Not regulated.

WHMIS Classification: B3, D2B

SECTION VIII-FIRST AID MEASURES

Eye: Wash with water for at least 15 minutes. Seek medical help if irritation persists.
Skin: Wash with soap and water. Seek medical help if irritation persists
Inhalation: Remove to fresh air. Seek medical help.
Ingestion: DO NOT INDUCE VOMITING. Give a glass of milk or water. Seek medical help immediately

SECTION IX-PREPARATION DATE OF M.S.D.S.

Additional Info/Comments: Sources Used:


Phone Number: (905) 793-4311 Prepared By: Quality Control Laboratory
Date Prepared: January 2, 2015. Kleen-Flo Tumbler Industries Limited

THIS SHEET SUPERSEDES ANY OTHER M.S.D.S. PREVIOUSLY PREPARED

N/Av.: not available N/Ap. : not applicable N/E: not established


SAFETY DATA SHEET

Envy Foaming Disinfectant Cleaner (US)


Version Number: 1 Preparation date: 2014-08-08

1. IDENTIFICATION

Product name: Envy Foaming Disinfectant Cleaner (US)


Product Code: 04531
SDS #: MS0800465
Recommended use: •Disi
nfectant
•Thispr oductisi ntendedt obeusedneat .
Uses advised against: Uses other than those identified are not recommended

Manufacturer, importer, supplier: Canadian Headquarters


US Headquarters Diversey, Inc. - Canada
Diversey, Inc. 2401 Bristol Circle
8310 16th St. Oakville, Ontario L6H 6P1
Sturtevant, Wisconsin 53177-1964 Phone: 1-800-668-3131
Phone: 1-888-352-2249
MSDS Internet Address: www.diversey.com

Emergency telephone number: 1-800-851-7145 (U.S.); 1-651-917-6133 (Int'l)

2. HAZARDS IDENTIFICATION

Classification for the undiluted product


Flammability Extremely flammable aerosol, Category 1

Signal Word: Danger

Precautionary Statements
EXTREMELY FLAMMABLE AEROSOL. HEATING MAY CAUSE AN EXPLOSION. CONTAINS GAS UNDER PRESSURE; MAY EXPLODE IF
HEATED.
Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Do not spray on an open flame or other ignition
source. Do not pierce or burn, even after use. Do not incinerate. Protect from sunlight. Store in a well-ventilated place. Do not expose to
temperatures exceeding 50 °C (122 °F) which may cause bursting. Dispose of in accordance with all federal, state and local applicable regulations.

Health hazards not otherwise classified (HHNOC) - Not applicable


Physical hazards not otherwise classified (PHNOC) - Not applicable

Classification for the diluted product @ RTU

Envy Foaming Disinfectant Cleaner (US) 1 of 5


Precautionary Statements

3. COMPOSITION/INFORMATION ON INGREDIENTS

Classified Ingredients
Ingredient(s) CAS # Weight %
Isobutane 75-28-5 3% - < 5%
Dipropylene glycol methyl ether 34590-94-8 1% - < 3%
Tetrapotassium pyrophosphate 7320-34-5 1% - < 3%
n-Alkyl (60% C14, 30% C16, 5% C12, 5% C18) 68391-01-5 > 0.1% - < 1%
dimethyl benzyl ammonium chloride
n-Alkyl (68% C12, 32% C14) dimethyl ethylbenzyl 68956-79-6 > 0.1% - < 1%
ammonium chloride

*Exact percentages are being withheld as trade secret information

4. FIRST AID MEASURES

Undiluted Product:
Eyes: Rinse with plenty of water. If irritation occurs and persists, get medical attention.
Skin: Rinse with plenty of water. If irritation occurs and persists, get medical attention.
Inhalation: No specific first aid measures are required.
Ingestion: Rinse mouth with water.

Most Important Symptoms/Effects: No information available.


Immediate medical attention and special treatment needed Not applicable.

Diluted Product:

Eyes: Rinse with plenty of water If irritation occurs and persists, get medical attention
Skin: Rinse with plenty of water If irritation occurs and persists, get medical attention
Inhalation: No specific first aid measures are required
Ingestion: Rinse mouth with water.

5. FIRE-FIGHTING MEASURES

Specific methods: Aerosol Product - Containers may rocket or explode in heat of fire
Suitable extinguishing media: Dry chemical, water spray, foam.
Specific hazards: NFPA 30B Level 1 Aerosol.

Special protective equipment for firefighters: As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH
(approved or equivalent) and full protective gear.
Extinguishing media which must not be used for safety reasons: No information available.

6. ACCIDENTAL RELEASE MEASURES

Personal precautions: Ensure adequate ventilation. Remove all sources of ignition.


Environmental precautions Clean-up methods - large spillage. Remove all sources of ignition. Absorb spill with inert material (e.g.
and clean-up methods: dry sand or earth), then place in a chemical waste container. Use a water rinse for final clean-up.

7. HANDLING AND STORAGE

Handling: Avoid contact with skin, eyes and clothing. Wash thoroughly after handling. Keep away from open flames, hot surfaces and sources of
ignition. CONTENTS UNDER PRESSURE. Do not puncture or incinerate. FOR COMMERCIAL AND INDUSTRIAL USE ONLY.
Storage:
Pressurized container: protect from sunlight and do not expose to temperatures exceeding 50 degrees C or 120 degrees F. Exposure to heat may
cause bursting. Do not pierce or burn, even after use. NFPA 30B Level 1 Aerosol. Protect from freezing. Store in a cool, dry, well ventilated area
away from heat or open flame.
Aerosol Level (if applicable) : Level 1

Envy Foaming Disinfectant Cleaner (US) 2 of 5


8. EXPOSURE CONTROLS / PERSONAL PROTECTION

Exposure Guidelines: .

Ingredient(s) CAS # ACGIH OSHA


Isobutane 75-28-5 1000 ppm (STEL) -
Dipropylene glycol methyl ether 34590-94-8 150 ppm (STEL) Skin
100 ppm (TWA) 100 ppm (TWA)
600 mg/m3 (TWA)
Tetrapotassium pyrophosphate 7320-34-5 - -
n-Alkyl (68% C12, 32% C14) dimethyl ethylbenzyl 68956-79-6 - -
ammonium chloride
n-Alkyl (60% C14, 30% C16, 5% C12, 5% C18) 68391-01-5 - -
dimethyl benzyl ammonium chloride

Undiluted Product:
Engineering measures to reduce exposure:
None known

Personal Protective Equipment


Eye protection: No special requirements under normal use conditions.
Hand protection: No special requirements under normal use conditions.
Skin and body protection: No special requirements under normal use conditions.
Respiratory protection: No special requirements under normal use conditions.
Hygiene measures: Handle in accordance with good industrial hygiene and safety practice.

Diluted Product:

Personal Protective Equipment


Eye protection: No special requirements under normal use conditions.
Hand protection: No special requirements under normal use conditions.
Skin and body protection: No special requirements under normal use conditions.
Respiratory protection: No special requirements under normal use conditions.
Hygiene measures: Handle in accordance with good industrial hygiene and safety practice.

9. PHYSICAL AND CHEMICAL PROPERTIES:

Physical State: Pressurized Liquid Color: Clear White


Evaporation Rate: No information available Odor: Lavender Ammonia
Odor threshold: No information available. Boiling point/range: Not determined
Melting point/range: Not determined Decomposition temperature: Not determined
Autoignition temperature: No information available Solubility: Completely Soluble
Solubility in other solvents: No information available Relative Density (relative to water): 0.98
Density: 8.17 lbs/gal 0.98 Kg/L Vapor density: No information available
Bulk density: No information available Vapor pressure: No information available.
Flash point: 19 °F -7 °C Partition coefficient (n-octanol/water): No information available
Dilution Flash Point: 19 °F -7 °C Viscosity: No information available
Elemental Phosphorus: 0.30 % by wt. VOC: 7.2 % *
pH: 12.1 VOC % by wt. at use dilution 7.2 % *
Dilution pH: 12.1 @ RTU Flammability (Solid or Gas): Not applicable
Metal Corrosion: Not determined
Flame Extension (inches): 0
Explosion limits: - upper: Not determined - lower: Not determined

* - Title 17, California Code of Regulations, Division 3, Chapter 1, Subchapter 8.5, Article 2, Consumer Products, Sections 94508

10. STABILITY AND REACTIVITY

Reactivity: Not Applicable


Stability: The product is stable
Hazardous decomposition products: None reasonably foreseeable.
Materials to avoid: None known.
Conditions to avoid: Keep away from open flames, hot surfaces and sources of ignition.

11. TOXICOLOGICAL INFORMATION

Envy Foaming Disinfectant Cleaner (US) 3 of 5


Information on likely routes of exposure:
Skin contact, Eye contact, Inhalation, Ingestion

Delayed, immediate, or chronic effects and symptoms from short and long-term exposure
Skin contact: Unlikely to be irritant in normal use.
Eye contact: May be mildly irritating to eyes.
Ingestion: No information available.
Inhalation: No information available.
Sensitization: No known effects.

Numerical measures of toxicity

12. ECOLOGICAL INFORMATION

Ecotoxicity: No information available.

Persistence and Degradability: No information available.

Bioaccumulation: No information available.

13. DISPOSAL CONSIDERATIONS

Waste from residues / unused products: This product, as sold, if discarded or disposed, is a hazardous waste according to Federal regulations
(40 CFR 261.4 (b)(4)). Dispose in compliance with all Federal, state, provincial, and local laws and regulations. If possible, recycle empty aerosol
cans to the nearest steel recycling center.
Contaminated Packaging: Do not re-use empty containers.
RCRA Hazard Class (undiluted product): D001 Ignitable Waste

14. TRANSPORT INFORMATION

DOT/TDG/IMDG: Please refer to the Diversey HazMat Library, only available through Internet Explorer, http://naextranet.diversey.com/dot/, for up
to date shipping information.

DOT (Ground) Bill of Lading Description: LTD. QTY.

IMDG (Ocean) Bill of Lading Description: UN1950, AEROSOLS, 2.1, LTD. QTY.

15. REGULATORY INFORMATION

International Inventories at CAS# Level


All components of this product are listed on the following inventories: U.S.A. (TSCA).

U.S. Regulations
EPA Reg. No. : 70627-35
This chemical is a pesticide product registered by the United States Environmental Protection Agency and is subject to certain labeling
requirements under federal pesticide law. These requirements differ from the classification criteria and hazard information required for safety data
sheets (SDS), and for workplace labels of non-pesticide chemicals. The hazard information required on the pesticide label is reproduced below. The
pesticide label also includes other important information, including directions for use.
FIFRA Text CAUTION: Causes moderate eye irritation. Avoid contact with eyes, skin or clothing. Wash thoroughly
with soap and water after handling. PHYSICAL AND CHEMICAL HAZARDS: CONTENTS UNDER
PRESSURE. Do not use or store near heat or open flame. Do not puncture or incinerate container.
Exposure to temperatures above 130° F may cause bursting.

California Proposition 65: This product is not subject to the reporting requirements under California's Proposition 65.

RIGHT TO KNOW (RTK)


Ingredient(s) CAS # MARTK: NJRTK: PARTK: RIRTK:

Envy Foaming Disinfectant Cleaner (US) 4 of 5


Water 7732-18-5 - - - -
Isobutane 75-28-5 X X X -
Dipropylene glycol methyl ether 34590-94-8 X X X -
Tetrapotassium pyrophosphate 7320-34-5 - - - -

CERCLA/ SARA
Ingredient(s) CAS # Weight % CERCLA/SARA RQ (lbs) Section 302 TPQ (lbs) Section 313
Dipropylene glycol methyl ether 34590-94-8 1% - < 3% X

Ingredient(s) CAA HAP CAA ODS CWA Priority Pollutants


Dipropylene glycol methyl ether X

SARA 311/312 Hazard Categories


Immediate: -
Delayed: -
Fire: X
Reactivity: -
Sudden Release of Pressure: X

Canada
WHMIS hazard class: Not for sale in Canada.

16. OTHER INFORMATION


NFPA
Health 1
Flammability 4
Instability 0

Version Number: 1
Preparation date: 2014-08-08

Reason for revision: Not applicable


Prepared by: NAPRAC
Additional advice: •Cont ai
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Odor
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Notice to Reader: This document has been prepared using data from sources considered technically reliable. It does not constitute a warranty,
express or implied, as to the accuracy of the information contained within. Actual conditions of use and handling are beyond seller's control. User is
responsible to evaluate all available information when using product for any particular use and to comply with all Federal, State, Provincial and
Local laws and regulations.

Envy Foaming Disinfectant Cleaner (US) 5 of 5


Material Safety Data Sheet
_______________________________________________

Revision Date 13-Sep-2013

1. CHEMICAL PRODUCT AND COMPANY Eye contact Flush with plenty of water for at least 15 minutes.
Seek medical attention.
INFORMATION
Skin contact Wash area thoroughly with soap and water.
Product code P91010 Remove and wash contaminated clothing before
Product name ETP Gold Cutting Fluid re-use. Seek medical attention if irritation persists.
Recommended Use Lubricant
Ingestion Do Not induce vomiting. Seek medical attention
Supplier Lawson Products, Inc. immediately.
8770 W.Bryn Mawr Ave.- Suite 900
Chicago, IL 60631 Inhalation Remove from exposure. Restore breathing. Keep
1-866-529-7664 warm and quiet. Contact physician if breathing
difficulty develops.
Emergency telephone number (888) 426-4851
5. FIRE FIGHTING MEASURES
2. HAZARDS IDENTIFICATION
Flash point °C > 93
Emergency Overview Flash point °F > 200
Irritant. Contents under pressure. Method Tag Closed Cup

Autoignition temperature °C Not Applicable


Aggravated Medical Conditions
Pre-existing skin sensitivity. May cause allergic skin reaction. Autoignition temperature °F Not Applicable

Principal Routes of Exposure Flammability Limits (% in Air)


Eyes. Inhalation. Skin contact. Upper No data available
Lower No data available
Potential health effects

Eyes May cause the following effects:. Irritation. Suitable extinguishing media
Redness. Itching. Burning sensation. Carbon dioxide (CO2). Alcohol foam. Dry chemical.

Skin Repeated or prolonged exposure may cause:. Skin Special protective equipment for firefighters
Irritation. Redness. Itching. Burning sensation. As in any fire, wear self-contained breathing apparatus pressure-demand,
MSHA/NIOSH (approved or equivalent) and full protective gear.
Inhalation Repeated or prolonged exposure may cause the
following effects:. Headaches. Dizziness. Nausea. Fire and Explosion Hazards
Irritating to respiratory system. Keep product and empty container away from heat and sources of
ignition. Containers may vent or burst under extreme or prolonged fire
No hazard under normal industrial and institutional conditions. Water should be used to cool closed containers to prevent
Ingestion
use. pressure build-up and possible autoignition or explosion when exposed to
extreme heat . Water spray may be ineffective. If water is used, fog
nozzles are preferable. During emergency conditions, overexposure to
decomposition products may cause a health hazard. Symptoms may not
be immediately apparent. Obtain medical attention.
3. COMPOSITION / INFORMATION ON INGREDIENTS
Sensitivity to shock
No information available.
Chemical Name CAS-No Weight %
Triethanolamine 102-71-6 7-13 Sensitivity to static discharge
Diethanolamine 111-42-2 0.5-1.5 No information available.

4. FIRST AID MEASURES 6. ACCIDENTAL RELEASE MEASURES

_______________________________________________

Page 1 / 3
Product code P91010 Product name ETP Gold
Cutting Fluid
_______________________________________________

6. ACCIDENTAL RELEASE MEASURES


Methods for cleaning up 9. PHYSICAL AND CHEMICAL PROPERTIES
Eliminate all sources of ignition. Ventilate area to maintain exposure
below permissible exposure limits. Soak up with inert absorbent material.
Form Aerosol
Color No information available
7. HANDLING AND STORAGE Odor No information available
Odor Threshold No information available
Handling pH 9.0
Avoid contact with skin and eyes. Avoid breathing vapors or mists. Keep Specific Gravity 1.06
container closed when not in use. Do not take internally. Keep out of Vapor pressure No data available
reach of children. Density 8.84 lbs/gal, 1059 g/l
Vapor density >1 (air=1)
Storage Evaporation Rate <1 (ether = 1)
Keep in properly labelled containers. Keep out of the reach of children. Water solubility No data available
VOC Content 0.11 lbs/gal; 13 g/l
NFPA Storage Code Partition Coefficient No data available
Store as Level 3 Aerosol (NFPA 30B) (n-octanol/water)
Boiling point/range °C 100 - 269
Boiling point/range °F 212 - 517
8. EXPOSURE CONTROLS / PERSONAL Melting point/range °C No data available
PROTECTION Melting point/range °F No data available
Flash point °C > 93
Flash point °F > 200
Chemical OSHA PEL OSHA PEL ACGIH OEL ACGIH OEL
Name (TWA) (Ceiling) (TWA) (STEL)
Diethanolamin - - 1 mg/m3 -
e 10. STABILITY AND REACTIVITY
Triethanolami - - 5 mg/m3 -
ne
Stability
Stable.
Ventilation and Environmental Controls
Use enough ventilation, local exhaust at the work area, general, or both, Conditions to avoid
to keep below the TLV's in the worker's breathing zone and the general None known.
area. General: as necessary.
Incompatability
Hygiene measures None.
Wash hands before breaks and immediately after handling the product.
Avoid contact with skin, eyes and clothing. Hazardous Decomposition Products
By fire:. Carbon dioxide. Carbon monoxide.
Other precautions
Avoid breathing vapors or mists. Polymerization
Will not occur.
Respiratory protection
Avoid breathing concentrated vapors or particles from all products not
specifically designed to be inhaled. Wear a NIOSH approved organic 11. TOXICOLOGICAL INFORMATION
vapor/particulate respirator.
Component Information
Hand Protection
Consult glove manufacturer to determine the proper type for a specific
Chemical Name LD50 LD50 LC50 (inhalation,rat)
operation. Use of a barrier cream on exposed skin is highly
(oral,rat (dermal
recommended .
) ,rat/rab
bit)
Eye protection
Wear safety glasses with side shields. Diethanolamine - - -
111-42-2
Skin and body protection Triethanolamine 4190 20 -
None necessary under normal conditions 102-71-6 mg/kg mL/kg

Other Protective Equipment Synergistic Products None known


A safety shower and eye wash station should be available for emergency
use. Potential health effects

Sensitization None known

_______________________________________________

Page 2 / 3
Product code P91010 Product name ETP Gold
Cutting Fluid
_______________________________________________

Chronic toxicity See Section 2 .


Chemical Name New Jersey - Pennsylvania California
Mutagenic effects None known RTK - RTK Prop. 65
Diethanolamine Listed Listed Carcinogen
Teratogenic effects None known Triethanolamine Not Listed Listed Not Listed

Reproductive toxicity None known

Target Organ Effects See Section 2 International Inventories


Carcinogenic effects See table below
Chemical Name EINECS DSL NDSL TSCA
Diethanolamine X X - X
Chemical ACGIH IARC NTP - NTP - OSHA
Triethanolamine X X - X
Name OEL - Known Suspected RTK
Carcinoge Carcinoge Human Carcinoge
ns ns Carcinoge ns CPR
ns This product has been classified in accordance with the hazard criteria of
Diethanolamin A3 Group 2B Not Listed Not Listed Listed the Controlled Product Regulations and the MSDS contains all of the
e information required by the Controlled Product Regulations
Triethanolami Not Listed Not Listed Not Listed Not Listed Not Listed
ne
16. OTHER INFORMATION
12. ECOLOGICAL INFORMATION
HMIS
Diethanolamine
Microtox Data Health - 2
Photobacterium phosphoreum EC50=73 mg/L (5 min) Flammability - 1
Pseudomonas fluorescens EC50>16 mg/L (16 h) Physical Hazard - 0
Pseudomonas putida EC50>16 mg/L (16 h)
Water Flea Data
Daphnia magna EC50=55 mg/L (48 h) Prepared By V. Shargorodsky, Regulatory Affairs
Engineer

Ecotoxicity effects No information available The information accumulated herein is believed to be accurate, but is not
warranted to be, whether originating with the company or not. Recipients
13. DISPOSAL CONSIDERATIONS are advised to confirm in advance of need that the information is current,
applicable, and suitable to their circumstances.

Disposal Information
As supplied, this product is classified as non-hazardous waste according
to RCRA regulations. Wastes resulting from the use of this product may
be disposed of on site or at an approved waste disposal facility. Do not
incinerate. Dispose in accordance with federal, state, and local
regulations.

14. TRANSPORTATION INFORMATION

DOT
Not Regulated

TDG
Not Regulated

15. REGULATORY INFORMATION

Chemical Name US EPA SARA 313 Emission Reporting


Diethanolamine Listed

State Regulations

_______________________________________________

Page 3 / 3
MATERIAL SAFETY DATA SHEET

Date Printed: 07/25/2008 Page: 1


Product Code(s): 1273

________________________________________________________________________________

1. CHEMICAL PRODUCT AND COMPANY INFORMATION

Product Name: European Auto Coat

Product Code(s): 1273

Manufacturer/Supplier: TRANSTAR AUTOBODY TECHNOLOGIES


2040 Heiserman Dr.
Brighton, MI, 48114, USA

24 Hour Emergency Phone(s): 800-424-9300 (CHEMTREC), 613-996-6666 (CANUTEC)

Business Phone: 810-220-3000

Product Use: Specialty Coating

MSDS Prepared By: Transtar Autobody Technologies

________________________________________________________________________________

2. COMPOSITION/INFORMATION ON INGREDIENTS

Ingredient(s) CAS Number % by Weight


---------------------------------------------------------------------------
Acetone 67-64-1 25- 40%
* Methylbenzene; Toluene 108-88-3 15- 25%
Propane 74-98-6 15.5
n-Butane 106-97-8 9.0
* Methyl Ethyl Ketone (MEK) 78-93-3 5 - 10%
* Propylene Glycol Monomethyl Ether Acetate108-65-6 0 - 5%
* Ethylene Glycol Monobutyl Ether 111-76-2 0 - 5%
Carbon Black Pigment 1333-86-4 0 - 5%

See Section 15. Regulatory Information for code descriptions


Weight percent (%) of 0.0 means chemical is in trace amounts.

________________________________________________________________________________

3. HAZARDS IDENTIFICATION

DANGER: EXTREMELY FLAMMABLE. CONTENTS UNDER PRESSURE. Aerosol cans


produce flammable vapors which can travel to a source of ignition and flash
back. IRRITANT.

HMIS Hazard Ratings: Health =3 , Flammability =4, Chemical Reactivity =0

Note: HMIS ratings involve data and interpretations that may vary
from company to company. They are intended only for rapid, general
identification of the magnitude of the specific hazard. To deal
adequately with the safe handling of this material, all the
information contained in this MSDS must be considered.

Potential Health Effects

Eyes: Moderate irritation to the eyes.

Skin: Moderate irritation to the skin.


MATERIAL SAFETY DATA SHEET

Date Printed: 07/25/2008 Page: 2


Product Code(s): 1273

________________________________________________________________________________
Inhalation: Moderate irritation to the respiratory system. May be harmful
if inhaled. High concentrations may be fatal.

Ingestion: Moderate irritation to the digestive tract.

________________________________________________________________________________

4. FIRST AID MEASURES

Seek professional medical attention for all over-exposures and/or


persistent problems.

Eyes Contact: Flush eyes with clean water for a minimum of 15 minutes.
Seek medical attention.

Skin Contact: Wash exposed area thoroughly with soap and water.

Inhalation: Remove person from area to fresh air. If breathing


difficulty persists, seek medical attention.

Ingestion: DO NOT INDUCE VOMITTING. Seek immediate medical attention.

________________________________________________________________________________

5. FIRE FIGHTING MEASURES

Flammable Properties

Flash Point: -4 Deg F, -20 Deg CMethod: TCC


Upper Explosive Limit (UEL): 12.8
Lower Explosive Limit (LEL): 1.1
Autoignition Temperature: No data

Extinguishing Media: Foam, Alcohol Foam, CO2, Dry Chemical, Water Fog,
Other.

Special Firefighting Procedures: Full fire fighter equipment including


SCBA should be worn to avoid skin contact and inhalation of
concentrated vapors. Minimize skin exposure. Highly toxic fumes may
be generated by thermal decomposition.

Hazardous Combustion Products: Carbon monoxide, carbon dioxide, oxides


of nitrogen.

Unusual Fire and Explosion Hazards: Vapors can travel to a source of


ignition and flash back. Aerosol cans contain flammable, pressurized
propellant. Cans will explode when exposed to flame, high heat and
temperatures. Combustion generates toxic fumes.

________________________________________________________________________________

6. ACCIDENTAL RELEASE MEASURES

For large spills or transportation accidents involving release of this


product, contact the Emergency Response Center: 800-424-9300.

Eliminate all sources of ignition, provide adequate ventilation, dike


spill area and add absorbent earth or sawdust to spilled liquid. Sweep
up and dispose of in appropriate containers in accordance with
Federal, State and/or Local regulations.
MATERIAL SAFETY DATA SHEET

Date Printed: 07/25/2008 Page: 3


Product Code(s): 1273

________________________________________________________________________________

________________________________________________________________________________

7. HANDLING AND STORAGE

Aerosol cans contain pressurized, flammable propellent. Cans will


burst if exposed to extreme heat or temperatures. Keep spray nozzle
pointed away from face and do not direct nozzle spray towards people
or animals. Avoid hot surfaces. Use in cool, well-ventilated areas.
Keep aerosol can capped when not in use. Keep away from excessive
heat and open flames. Follow all MSDS/label precautions even after
container is emptied because they may retain product residues. Store
in a cool area away from heat and flames. Do not reuse container when
empty.

________________________________________________________________________________

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Exposure Guidelines

Chemical Name/Exposure Limits CAS Number


---------------------------------------------------------------------------

Acetone 67-64-1
OSHA PEL: 1000 ppm, ACGIH TLV: 500 ppm, OTHER: STEL 750 ppm
* Methylbenzene; Toluene 108-88-3
OSHA PEL: 200 ppm, 300 ppm ceiling
ACGIH TLV: 50 ppm (skin)
IDLH: 500 ppm
Propane 74-98-6
OTHER: TWA1000ppm
n-Butane 106-97-8
OTHER: TWA 800ppm
* Methyl Ethyl Ketone (MEK) 78-93-3
OSHA PEL: 200 ppm, ACGIH TLV: 200 ppm, OTHER: STEL 300 ppm
* Propylene Glycol Monomethyl Ether Acetate 108-65-6
OSHA PEL: N/A, ACGIH TLV: N/A, OTHER: N/A
* Ethylene Glycol Monobutyl Ether 111-76-2
OSHA PEL: 50ppm, ACGIH TLV: 20ppm
Carbon Black Pigment 1333-86-4
OSHA PEL: 3.5 mg/m3, ACGIH TLV: 3.5mg/m3

Engineering Controls: General mechanical ventilation or local exhaust


should be utilized to keep vapor concentrations below exposure limits
(PEL & TLV). Ventilation equipment must be explosion proof.

Respiratory Protection: Utilize engineering controls to reduce


emission levels below the time weighted exposure limits (ACGIH TLV &
OSHA PEL). Wear an approved respirator if exposure limits are above
the exposure limits listed above.

Eye Protection: Use safety glasses or splash goggles.

Skin Protection: Use chemical resistant gloves.

Safe Work Practices: Eye washes and safety showers in the workplace
are recommended. Avoid contact with skin and eyes. Avoid breathing
vapors. Wash hands thoroughly after using and before eating, drinking
or smoking. Employee education and training in the safe use and
MATERIAL SAFETY DATA SHEET

Date Printed: 07/25/2008 Page: 4


Product Code(s): 1273
________________________________________________________________________________
handling of this product is required under the OSHA Hazard
Communication Standard 29CFR1200. When spraying an aerosol can, use
ventilation to minimize vapors. Smoking in area where this material
is used should be strictly prohibited. Always use protective clothing
and equipment. Remove all contaminated clothing and wash thoroughly
when finished working. Keep food and drink away from material and
from area where material is being used.

________________________________________________________________________________

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical Form: Homogeneous mixture


Physical State: Liquid
Color: Black
Odor: Organic solvent
Odor Threshold: No Data
Specific Gravity (water=1) 0.75
Vapor Pressure: No data
Vapor Density: Heavier than air
Material VOC: 3.40 lb/gl 407 g/l
Coating VOC: 5.37 lb/gl 644 g/l
Evaporation Rate: Faster than ether.
Boiling Point: -44øF
Melting Point: No data
Freezing Point: No data
Viscosity at Ambient Temperature: No data
Solubility in Water: Insoluble
Octanol/Water Partition Coefficient: No data
pH: No data

________________________________________________________________________________

10. STABILITY AND REACTIVITY

Stability: Stable

Incompatibility: Strong acids, strong bases and strong oxidizing


agents.

Hazardous Polymerization: Will not occur.

________________________________________________________________________________

11. TOXICOLOGICAL INFORMATION

Effects of Exposure:
ACUTE:
INHALATION - Dizziness, breathing difficulty, headaches, & loss of
coordination.
EYE CONTACT - Moderate irritation, tearing, redness, and blurred
vision.
SKIN CONTACT - Moderate irritant. Can dry and defat skin causing
cracks, irritation, and dermatitis.
INGESTION - Can cause gastrointestinal irritation, vomiting, nausea, &
diarrhea.

CHRONIC:
May affect liver, kidney and central nervous system with repeated
exposure.
MATERIAL SAFETY DATA SHEET

Date Printed: 07/25/2008 Page: 5


Product Code(s): 1273

________________________________________________________________________________

Aerosol spraying may create an oxygen deficient environment. Use


proper ventilation to remove vapors, mists and fumes.
Aerosol propellents can cause asphyxia characterized by blueness of
the skin, difficulty breathing, headaches, loss of coordination and
unconsciousness.

Acute Toxicity Data: No data.

Carcinogenicity: NTP -No, IARC -Yes, OSHA -No


This product has not been tested for carcinogenic effects. Some
chemicals in this product may be identified by NTP, IARC and/or OSHA
as carcinogenic, indicated above as "Yes". No further information
available.

Teratology: No data.

Reproduction: No data.

Mutagenicity: No data.

________________________________________________________________________________

12. ECOLOGICAL INFORMATION

No data.
________________________________________________________________________________

13. DISPOSAL CONSIDERATIONS

Subject to hazardous waste generation, treatment, storage and


disposal. Product should be disposed of in accordance with all
governmental regulations. Subject to hazardous waste generation,
treatment, storage and disposal under RCRA, 40CFR261. Product should
be disposed of in accordance with all Federal, State and local
regulations.
________________________________________________________________________________

14. TRANSPORT INFORMATION

The following transportation information is provided based on Transtar


Autobody Technologies interpretation of shipping regulations. Each
shipper is responsible for identifying, naming, marking and labeling
prior to offering for transport.

USA (DOT) Status: Consumer Commodity ORM-D

Water (IMDG) Status: UN1950, AEROSOL, 2.1, Limited Quantity

Air (ICAO,IATA) Status: UN1950, AEROSOL, 2.1, Limited Quantity

Canada (TDG) Status: Consumer Commodity ORM-D


________________________________________________________________________________

15. REGULATORY INFORMATION

The information listed in this section is not all inclusive of all regulations for
this product or the chemical components of this product.
MATERIAL SAFETY DATA SHEET

Date Printed: 07/25/2008 Page: 6


Product Code(s): 1273
________________________________________________________________________________

US Federal Regulations

TSCA Status: All known major components of this product are listed on
the TSCA Inventory and/or are otherwise in compliance with TSCA.

SARA 302 (EHS) Status: No EHS chemicals present.

SARA 311/312 Status: Immediate Health Hazard, Delayed Health Hazard,


Fire Hazard.

SARA 313 Status: * Indicates toxic chemical(s) subject to the


reporting requirements of section 313 of Title III and of 40 CFR 372.

OSHA Status: This material meets the requirement of hazardous material


and is subject to 29CFR1910.1200.

USA State Information

California Proposition 65: This product contain chemical(s)


known to the State of California to cause cancer or birth defects or
other reproductive harm.

Pennsylvania RtK Status: This material contains chemical(s) subject to


notification under Pennsylvania Right to Know.

New Jersey RtK Status: This material contains chemical(s) subject to


notification under New Jersey Right to Know.

Massachusetts RtK Status: This material contains chemical(s) subject


to notification under Massachusetts Right to Know.

Rhode Island RtK Status: This material contains chemical(s) subject to


notification under Rhode Island Right to Know.

International Regulations

Canada
DSL Status: All known major components of this product are listed on
the DSL Inventory and/or are otherwise in compliance with the DSL
NDSL Status: Contains no chemicals on the NDSL
WHMIS: AB5D2B

New Zealand
HSNO Number: HSR002515

EINECS Status: All components of this material are listed on the


EINECS Inventory.
________________________________________________________________________________

16. OTHER INFORMATION

To the best of our knowledge, the information contained herein is


accurate, obtained from sources believed by Transtar Autobody
Technologies to be accurate. As with all chemicals, KEEP AWAY FROM
CHILDREN AND ANIMALS. FOR PROFESSIONAL USE ONLY. The hazard
information contained herein is offered solely for the consideration
of the user, subject to his own investigation and verification of
compliance with applicable regulations, including the safe use of the
product under every foreseeable condition.
(.
Safety Data Sheet
Prepared in accordance with Commission Regulation (EU) 20151830
Revision DateO9-02-201 6
Revision Number 7

EVERCAT
SECTION 1 Identification of the substancelmixture and of the companylundertaking

1.1 Product identifier 100632


Everglass quart
1.2 Relevant identified uses of the Automotive repair
substance or mixture and uses
advised against
1.3 Details of the supplier of the ITW Evercoat
safety data sheet
a division of Illinois Tool Works Inc.
6600 Cornell Road
Cincinnati, OH 45242
513-489-7600
1.4 Emergency telephone number CHEM TEL: +1-813-248-0591

SECTION 2 Hazards identification

2.1 Classification of the substance or mixture


Classified in Skin Corrosion/Irritation Category 2
accordance to (EC) No.
1272/2008 Senous Eye Damage/Eye Irritation Category 2
Flammable Liquid Category 3

2.2 Label e’ements


Labelling according to Regulation (EC) No 1272/2008 [CLP]

Hazard pictograms

Signal Word Warning

Hazard Statements H226 - Flammable liquid and vapour.


H315 Causes skin irritation.
-

H319 Causes serious eye irritation.


-

Precautionary P233 - Keep container tightly closed.


Statements
P280 Wear protective gloves/protective clothing/eye protection/face
-

protection.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several
-

minutes. Remove contact lenses, if present and easy to do. Continue

Page 1 of 10
Safety Data Sheet
Prepared in accordance with Commission Regulation (EU) 20151830
Revision DateO9-02-201 6
Revision Number 7
rinsing.
P403+P235 Store in a well-ventilated place. Keep cool.
-

P337+P313 If eye irritation persists: Get medical advice/attention.


-

P240 Ground/bond container and receiving equipment.


-

Supplemental Hazard EUH2O8 Contains Acid anhydride. May produce an allergic reaction.
-

information (EU)

2.3 Other hazards No data available

SECTION 3 Compositionhinformation on ingredients


3.1. Substances

Not applicable

3.2. Mixtures

Chemical Name % CAS # (EC) No 127212008 M Factor SCL


Styrene 14.41 100-42-5 Acute Tox. 4; H332 No data No data
Acute Tox. 4; H332 available available
Acute Tox. 4; H332
Eye Irrit. 2; H319
Flam. Liq. 3; H226
Skin Irrit. 2; H315
Acid anhydride 0.75 85-43-8 Aquatic Chronic 3; H412 No data No data
Eye Dam. 1; H318 available available
Resp. Sens. 1; H334
Skin Sens. 1; H317
EUH2O8
Dimethylaniline(DMA) 0.11 121-69-7 AquaticChronic2; H411 Nodata Nodata
Acute Tox. 3; H31 I available available
Acute Tox. 3; H331
Acute Tox. 3; H331
Acute Tox. 3; H301
Acute Tox. 3; H331
Carc. 2; H351

For full text of H-statements; See Section 16

SECTION 4 First aid measures


4.1 Description of first aid measures
Inhalation Remove to fresh air. If breathing is difficult, have a trained individual administer
oxygen. If not breathing, give artificial respiration and have a trained individual
administer oxygen. Get medical attention immediately Get medical attention
immediately. Keep the victim warm and quiet. If the victim has stopped breathing
open airway, loosen collar and belt, and administer artificial respiration. If breathing
is difficult, oxygen may be beneficial if administered by trained personnel,
preferably on a doctor’s advice.

Page 2 of 10
Safety Data Sheet
Prepared in accordance with Commission Regulation (EU) 2015/830
Revision DateO9-02-2016
Revision Number 7
Eye Contact Flush eyes with plenty of water for at least 20 minutes retracting eyelids often. Tilt
the head to prevent chemical from transferring to the uncontaminated eye. Get
immediate medical attention. No data available
Skin Contact Wash with soap and water. Get medical attention if irritation develops or persists.
Remove contaminated clothing and continue flushing with water. Seek medical
advice if symptoms persist Wash clothing before reuse.
Ingestion Do not induce vomiting and seek medical attention immediately. Drink two glasses
of water or milk to dilute. Provide medical care provider with this MSDS. Do not
induce vomiting unless directed to do so by medical personnel.
Self protection of No data available
the first aider

4.2 Most important symptoms and effects, both acute and delayed
Symptom See Section 4.1
4.3 Indication of any immediate medical attention and special treatment needed
Note to Doctor No additional first aid information available

SECTION 5 Firefighting measures

5.1 Extinguishing media


Suitable extinguishing media Use alcohol resistant foam, carbon dioxide, dry chemical, or
water spray when fighting fires. Water or foam may cause frothing
if liquid is burning but it still may be a useful extinguishing agent if
carefully applied to the fire. Do not direct a water stream directly
into the hot burning liquid. Carbon dioxide Dry chemical
Unsuitable extinguishing media No data available
5.2 Special hazards arising from the substance or mixture
Fire andlor Explosion Hazards Vapors may be ignited by sparks, flames or other sources of
ignition if material is above the flash point giving rise to a fire
(Class B). Vapors are heavier than air and may travel to a source
of ignition and flash back.
Hazardous Combustion Products Carbon dioxide, Carbon monoxide, Phthalic anhydride,
Hydrocarbons
5.3 Advice for firefighters
Fire Fighting Methods and Protection Do not enter fire area without proper protection including
self-contained breathing apparatus and full protective
equipment. Fight fire from a safe distance and a
protected location due to the potential of hazardous
vapors and decomposition products. Flammable
component(s) of this material may be lighter than water
and burn while floating on the surface.

SECTION 6 Accidental release measures

Page 3 of 10
Safety Data Sheet
Prepared in accordance with Commission Regulation (EU) 20151830
Revision DateO9-02-2016
Revision Number 7
C
6.1 Personal precautions,
protective equipment and
emergency procedures
For Non-emergency Personnel Non-emergency personnel should be kept clear of the area.
For emergency responders No health affects expected from the clean-up of this material if
contact can be avoided. Follow personal protective equipment
recommendations found in Section VIII of this MSDS
6.2 Environmental precautions No data available
6.3 Methods and material for No special spill clean-up considerations. Collect and discard in
containment and cleaning up regular trash. Shut off ignition sources; including electrical
equipment and flames. Do not allow smoking in the area. Use an
inert absorbent such as sand or vermiculite. Place in properly
labeled closed container.
6.4 Reference to other sections Refer to section 13 for disposal information.

SECTION 7 Handling and storage

7.1 Precautions for safe handling Mildly irritating material. Avoid unnecessary exposure. Do not
get in eyes, on skin and clothing Wash hands before eating Use
with adequate ventilation Avoid contact with material, avoid
breathing dusts or fumes, use only in a well ventilated area.
7.2 Conditions for safe storage, Store in a cool dry place. Isolate from incompatible materials.
including any incompatibilities Store in a cool dry place Keep away from heat, sparks, and

7.3 Specific end use(s)


flame Store in a tightly closed container
Automotive repair
C
SECTION 8 Exposure controlslpersonal protection
Occupational Exposure limit values

Chemical Name ACGIH TLV-TWA ACGIH STEL IDLH.


Styrene 20 ppm 40 ppm STEL; 170 No data available
mg/m3 STEL

8.2 Exoosure controls

Appropriate engineering controls No exposure limits exist for the constituents of this product. Use
local exhaust ventilation or other engineering controls to minimize
exposures and maintain operator comfort.
Individual protection measures, such as personal protective equipment

Eye and face protection Wear chemically resistant safety glasses with side shields when
handling this product. Do not wear contact lenses. None
Skin Protection
Hand protection No information available
Other skin protection Not normally considered a skin hazard. Where use can result in
skin contact, practice good personal hygiene and wear a barrier

Page 4 of 10 C
Safety Data Sheet
Prepared in accordance with Commission Regulation (EU) 20151830
Revision DateOg-02-201 6
Revision Number 7

cream and/or impervious surgical style gloves. Wash hands and


other exposed areas with mild soap and water before eating,
drinking, and when leaving work.
Respiratory Protection Respiratory protection may be required to avoid overexposure
when handling this product. General or local exhaust ventilation
is the preferred means of protection. Use a respirator if general
room ventilation is not available or sufficient to eliminate
symptoms.
Thermal hazards No data available

Environmental exposure controls No data available

SECTION 9 Physical and chemical properties


9.1 Information on basic physical and chemical properties

Appearance Paste
Colour Blue
Odour Aromatic
Odour Threshold No data available
pH Neutral
Melting point I Freezing point -30.6
(°C)
Initial boiling point and boiling 145
range (°C)
Flash Point (°C) 49
Evaporation Rate No data available
Flammability (Solid, gas) No data available
Upperliower flammability or
explosive limits
Upper Flammable/Explosive 6.1
Limit, % in air
Lower Flammable/Explosive 1.1
Limit, % in air
Vapour Pressure 5.0 mmHg @ 68 °F / 20 °C (Styrene)
Vapour Density Heavier than air. Vapors that evolve from this product will tend to
settle and accumulate near the floor.
Relative Density 1.71
Solubility(ies) No data available
Partition coefficient: n- 1.36
octanol/water
Autoignition Temperature (°C) 490
Decomposition Temperature No data available
Viscosity No data available
Explosive properties No data available
Oxidizing properties No data available

Page 5 of 10
Safety Data Sheet
Prepared in accordance with Commission Regulation (EU) 20151830

9.2 Other information No data available


Revision DateO9-02-201 6
Revision Number 7
C
SECTION 10 Stability and reactivity

10.1 Reactivity No data available


10.2 Chemical stability Stable under normal conditions.
10.3 Possibility of hazardous No data available
reactions
10.4 Conditions to avoid No data available
10.5 Incompatible materials Peroxides; Strong acids; Strong oxidizing agents
10.6 Hazardous decomposition Carbon dioxide Carbon monoxide Hydrocarbons
products

SECTION 11 Toxicological information


11.1 Information on toxicological effects

Acute Toxicity
Based on available data, the classification criteria are not met.

Skin corrosionlirritation
[ pH .
Neutral I
Classification is based on pH and the components listed in Section 3.

Serious eye damage/irritation


C
L pH J Neutral

Classification is based on pH and the components listed in Section 3.

Respiratory or skin sensitization


EUH2O8 Contains Acid anhydride. May produce an allergic reaction.
-

Based on available data, the classification criteria are not met.

Germ cell mutagenicity


Based on available data, the classification criteria are not met.

Carcinogenicity
Based on available data, the classification criteria are not met.

Reproductive toxicity
Based on available data, the classification criteria are not met.

STOT-single exposure
Based on available data, the classification criteria are not met.

STOT-repeated exposure
Based on available data, the classification criteria are not met.

Aspiration hazard

Page 6 of 10 C
Safety Data Sheet
Prepared in accordance with Commission Regulation (EU) 20151830
Revision DateO9-02-201 6
Revision Number 7
Based on available data, the classification criteria are not met.

SECTION 12 Ecological information

12.1 Toxicity No data available

Ecotoxicity Data
Chemical Name CAS Number Aquatic EC5O Aquatic ERC5O Aquatic LC5O
Crustacea Algae Fish
No data available

12.2 Persistence and No data available


degradability
12.3 Bioaccumulative No data
potential
12.4 Mobility in soil No data available
12.5 Results of PBT and No data available
vPvB assessment
12.6 Other adverse No data available
effects
12.7 Additional No data available
information

SECTION 13 Disposal considerations


13.1 Waste treatment methods
Waste Description for Spent Spent or discarded material is a hazardous waste.
Product
Disposal Methods Dispose of by incineration following Federal, State, Local, or
Provincial regulations.
Waste Disposal Code(s) W080111
(European Waste Catalogue)

SECTION 14 Transport information

Ground:
14.1 UN number: UN3269
14.2 UN proper shipping name: POLYESTER RESIN KIT
14.3 Transport hazard class(es): 3
14.4 Packing group:
Exemptions: Limited Quantity

Air:
14.1 UN number: UN3269
14.2 UN proper shipping name: POLYESTER RESIN KIT

Page 7 of 10
Safety Data Sheet
Prepared in accordance with Commission Regulation (EU) 201 5/830
Revision DateOg-02-2016
Revision Number 7
C
14.3 Transport hazard class(es): 3
14.4 Packing group: Ill

Water:
14.1 UN number: UN3269
14.2 UN proper shipping name: POLYESTER RESIN KIT
14.3 Transport hazard class(es): 3
14.4 Packing group: Ill
Exemptions: Limited Quantity

14.5 Environmental hazards: No


14.6 Special precautions for user: No data available
14.7 Transport in bulk according No data available
to Annex II of MARPOL and the
IBC Code:

SECTION 15 Regulatory information


15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture

Chemical Name EINECS SVHC

Styrene Y N
Acid anhydride
Dimethylaniline (DMA)
Aniline
Y
Y
Y
N
N
N
C
Styrene Oxide Y N

15.2 Chemical safety assessment No data available

SECTION 16 Other information

SDS Abbreviations: No data available


References: No data available
Hazard phrase(s) H226 Flammable liquid and vapour.
-

referenced in section 3
H301 - Toxic if swallowed.
H302 Harmful if swallowed.
-

H31 1 - Toxic in contact with skin.


H312 - Harmful in contact with skin.
H315 Causes skin irritation.
-

H317 May cause an allergic skin reaction.


-

H318 Causes serious eye damage.


-

H319 Causes serious eye irritation.


-

Page 8 of 10 C
Safety Data Sheet
Prepared in accordance with Commission Regulation (EU) 20151830
Revision DateOg-02-2016
Revision Number 7
H331 - Toxic if inhaled.
H332 Harmful if inhaled.
-

H334 May cause allergy or asthma symptoms or breathing difficulties if


-

inhaled.
H336 May cause drowsiness or dizziness.
-

H341 Suspected of causing genetic defects.


H350 May cause cancer.
-

H351 - Suspected of causing cancer.


H372 Causes damage to organs through prolonged or repeated exposure.
-

H400 Very toxic to aquatic life.


-

H41 I - Toxic to aquatic life with long lasting effects.


H412 Harmful to aquatic life with long lasting effects.
-

Precautionary
Statements
Prevention P201 Obtain special instructions before use.
-

P202 Do not handle until all safety precautions have been read and
-

understood.
P210 Keep away from heat/sparks/open flames/hot surfaces. No
- —

smoking.
P233 Keep container tightly closed.
-

P240 Ground/bond container and receiving equipment.


-

P241 Use explosion-proof electrical/ventilating/lighting equipment.


-

P242 Use only non-sparking tools.


-

P243 Take precautionary measures against static discharge.


-

P260 Do not breathe dust/fume/gas/mist/vapours/spray.


-

P261 Avoid breathing dust/fume/gas/mist/vapours/spray.


-

P264 Wash thoroughly after handling.


-

P270 Do no eat, drink or smoke when using this product.


-

P272 Contaminated work clothing should not be allowed out of the


-

workplace.
P273 Avoid release to the environment.
-

P280 Wear protective gloves/protective clothing/eye protection/face


-

protection.
P284 Wear respiratory protection.
-

Response P302+P352 IF ON SKIN: Wash with plenty of soap and water.


-

P303+P361 +P353 IF ON SKIN (or hair): Remove/Take off immediately all


-

contaminated clothing. Rinse skin with water/shower.


P304+P341 IF INHALED: If breathing is difficult, remove victim to fresh air
-

and keep at rest in a position comfortable for breathing.


P305+P351+P338 IF IN EYES: Rinse cautiously with water for several
-

minutes. Remove contact lenses, if present and easy to do. Continue


rinsing.

Page 9 of 10
Safety Data Sheet
Prepared in accordance with Commission Regulation (EU) 20151830
Revision DateOg-02-201 6
Revision Number 7
P307+P31 I IF exposed: Call a POISON CENTER or doctor/physician.
-

P308+P313 IF exposed or concerned: Get medical advice/attention.


-

P314 Get medical advice/attention if you feel unwell.


-

P321 Specific treatment (see on this label).


-

P332+P313 If skin irritation occurs: Get medical advice/attention.


-

P333+P313 If skin irritation or rash occurs: Get medical advice/attention.


-

P337+P313 If eye irritation persists: Get medical advice/attention.


-

P342+P31 I If experiencing respiratory symptoms: Call a POISON


-

CENTER or doctor/physician.
P363 Wash contaminated clothing before reuse.
-

P370÷P378 In case of fire: Use for extinction.


-

Storage P233 Keep container tightly closed.


-

P403+P235 Store in a well-ventilated place. Keep cool.


-

P405 Store locked up.


-

Disposal P501 Dispose of contents/container in accordance with


-

local/regional/national/international regulation for hazardous wastes.

NOTICE: The information accumulated herein is believed to be correct as of the date issued from sources, which
are believed to be accurate and reliable. Since it is not possible to anticipate all circumstances of use, recipients
are advised to confirm, in advance of need, that the information is current, applicable and suitable to their
circumstances

Page 10 of 10
Safety Data Sheet

Revision Number: 005.1 Issue date: 06/08/2015

1. PRODUCT AND COMPANY IDENTIFICATION’


Product name: Extend(R) Rust Treatment IDH number: 497093
Product type: Rust converter Item number: 37557
Restriction of Use: None identified Region: United States
Company address: Contact information:
Henkel Corporation Telephone: (860) 571-5100
One Henkel Way MEDICAL EMERGENCY Phone: Poison Control Center
Rocky Hill, Connecticut 06067 1-877-671-4608 (toll free) or 1-303-592-1711
TRANSPORT EMERGENCY Phone: CHEMTREC
1-800-424-9300 (toll free) or 1-703-527-3887
Internet: www.henkelna.com

H:DS IDENTIFICATION
tivixi.rit.,y UVI(VIVV
DANGER: CONTENTS UNDER PRESSURE.
EXTREMELY FLAMMABLE AEROSOL.
HARMFUL IF SWALLOWED.
CAUSES SEVERE SKIN BURNS AND EYE DAMAGE.
MAY CAUSE DROWSINESS OR DIZZINESS.

n.,%ru CLASS HAZARD CATEGORY


FLAMMABLE AEROSOL. 1
ACUTE TOXICITY ORAL 4
SKIN CORROSION lB
SERIOUS EYE DAMAGE 1
SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE 3

Precautionary Statements

Prevention: Keep away from heat, sparks, open flames, hot surfaces no smoking. Do not spray on an
-

open flame or other ignition source. Do not pierce or burn, even after use. Do not breathe mist
or spray. Wash thoroughly after handling. Do not eat, drink or smoke when using this product.
Use only outdoors or in a well-ventilated area. Wear protective gloves, eye protection, and face
protection.
Response: If SWALLOWED: Immediately call poison control or physician if you feel unwell. IF
SWALLOWED: Rinse mouth. Do NOT induce vomiting. If on skin (or hair): Take off immediately
all contaminated clothing. IF INHALED: Remove person to fresh air and keep comfortable for
breathing.
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if
present and easy to do. Continue rinsing. Immediately call a poison control center or physician.
Wash contaminated clothing before reuse.
Storage: Store in a well-ventilated place. Keep container tightly closed. Store locked up. Protect from
sunlight. Do not expose to temperatures exceeding 50C/122°F.
Disposal: Dispose of contents and/or container according to Federal, State/Provincial and local
govemmental regulations.

IDH number: 497093 Product name: Extend(R) Rust Treatment


Page 1 of 6
Classification complies with OSHA Hazard Communication Standard (29 CFR 19101200) and is consistent with the provisions of the
United Nations Globally Harmonized System of Classification and Labeling of Chemicals (GHS).

See Section 11 for additional toxicological information.

OMPOSITIONIINFORMATION ON INGREDIENTS
V

.•
..

Hazardous Component(s) CAS Number Percentage*

2-Butoxyethanol 11 1-76-2 30-60


Acetone 67-64-1 30 60
-

Butyral resin Proprietary 5- 10


Formic acid 64-18-6 5- 10
3,4,5-Trihydroxybenzoic acid 149-91-7 0.1 1 -

Exact percentage Is a trade secret. Concentration range is provided to assist users in providing appropriate protecons.

[ V 4FIRSTDMEASURES
Inhalation: Move to fresh air. If breathing is difficult, give oxygen. If not breathing, give
artificial respiration. Seek medical advice.

Skin contact: Remove contaminated clothing and footwear. Wash with soap and water. If
symptoms develop and persist, get medical attention. Wash clothing before
reuse.

Eye contact: Immediately flush eyes with water for at least 15 minutes, while holding
eyelids open. Seek medical attention at once.

Ingestion: Rinse mouth, drink 1-2 glasses of water, do not induce vomiting, consult a
doctor.

Symptoms: See Section 11.

‘S,FIREFIGHTINGMEASURES
Extinguishing media: Carbon dioxide. Dry chemical. foam

Special firefighting procedures: Use water spray to keep fire exposed containers cool and disperse vapors.
Wear self-contained breathing apparatus and full protective clothing, such as
turn-out gear.

Unusual fire or explosion hazards: Closed containers may wpture (due to build up of pressure) when exposed to
extreme heat. Vapours may accumulate in low or confined areas, travel
considerable distance to source of ignition, and flash back.

Hazardous combustion products: Oxides of carbon. Hydrocarbons

6. ACCIDENTAL RELEASE MEASURES


Use personal protection recommended in Section 8, isolate the hazard area and deny entry to unnecessary and unprotected
personnel.

Environmental precautions: Do not allow material to contaminate ground water system. Do not let product
enter drains. Absorb spill with inert material. Shovel material into appropriate
container for disposal.

Clean-up methods: Absorb the spilled material with an inert absorbent (nonflammable) material.

IDH number: 497093


Page 2 of 6
Product name: Extend(R) Rust Treatment
0
. HNDLING AND STORAGE
Handling: Avoid breathing mists or aerosols of this product. Keep away from sources of
ignition no smoking. Avoid contact with eyes, skin and clothing.
-

Storage: Store in a cool, dry area. Keep containers closed when not in use.

8. EXPOSURE CONTROLS! PERSONAL PROTECTION

Employers should complete an assessment of all workplaces to determine the need for, and selection of, proper exposure
controls and protective equipment for each task performed.

Hazardous Component(s) ACGIH TLV OSHA PEL AIHA WEEL OTHER


50 ppm (240 mg/rn 3)
2-Butoxyethanol 20 ppm TWA PEL None None
(SKIN)
750 ppm STEL 1,000 ppm (2,400
Acetone None None
500 ppm TWA mglm3) PEL
Butyral resin None None None None
. 5 ppm TWA 5 ppm (9 mg/m3)
Formic acid None None
10 ppm STEL PEL
3,4,5-Trihydroxybenzoic acid None None None None

Engineering controls: Provide adequate local exhaust ventilation to maintain worker exposure below
exposure limits.

Respiratory protection: Use NIOSH approved respirator if there is potential to exceed exposure
limit(s).

Eye/face protection: Safety goggles or safety glasses with side shields. Full face protection should
be used if the potential for splashing or spraying of product exists.

Skin protection: Use impermeable gloves and protective clothing as necessary to prevent skin
contact.

9.. PHYSICAL AND CI-IEMICAL PROPERTIES


Physical state: Aerosol, Liquid
Color: Translucent
Odor: Acetone
Odor threshold: Not available.
pH: Not available.
Vapor pressure: Not available.
Boiling pointlrange: Not available.
Melting pointi range: Not available.
Specific gravity: 1.0000
Vapor density: Not available.
Flash point: <-17.7 °C (< 0.14 F) ; This product exhibits no flashback when tested for
flame extension.
Flammable/Explosive limits lower:
- 1.1 %
Flammable/Explosive limits - upper: 57%
Autoignition temperature: Not available.
Evaporation rate: Not available.
Solubility in water: Not available.
Partition coefficient (n-octanol/water): Not available.
VOC content: 50.4 %
Viscosity: Not available.
Decomposition temperature: Not available.

IDH number: 497093 Product name: Extend(R) Rust Treatment


Page 3 of 6
10.
Stability: Stable

Hazardous reactions: Will not occur.

Hazardous decomposition Irritating organic vapours. Oxides of carbon.


products:

Incompatible materials: Acids and bases. Oxidizing agents.

Reactivity: Not available.

Conditions to avoid: Keep away from heat, spark and flame.

j 11 TOXICOLOGICAL INFoRMATION: 1
Relevant routes of exposure: Skin, Inhalation, Eyes, Ingestion

Potential Health Effects/Symptoms

Inhalation: Vapours may cause drowsiness and dizziness.


Skin contact: Causes skin burns.
Eye contact: Causes serious eye damage.
Ingestion: Harmful if swallowed.

Hazardous Component(s) LD5Os and LC5Os Immediate and Delayed Health Effects
Oral LD5O (RAT) = 560 mg/kg
Oral LD5O (RABBIT) = 0.32 g/kg

0
Oral LD5O (RAT) = 1.48 g/kg Blood, Central nervous system, Irritant,
2-Buto xy ethanol
Dermal LD5O (RABBIT) = 400 mg/kg Kidney, Liver
Inhalation LC5O (RAT, 4 h) = 486 ppm
Inhalation_LC5O_(RAT,_4_h)_=_450_ppm
Oral LD5O (RABBIT) = 5,340 mg/kg
Oral LD5O (RAT) = 5,800 mg/kg
Oral LD5O (RAT) = 9,800 mg/kg Blood, Central nervous system, Irritant,
Acetone
Dermal LD5O (RABBIT) = 20,000 mg/kg Reproductive
Inhalation LC5O (RAT, 8 h) = 50.1 mg/I
Inhalation_LC5O_(RAT,_4_h)_=_76_mg/I
Butyral resin None No Records
Oral LD5O (RAT) = 730 mg/kg
Central nervous system, Corrosive, Irritant,
Formic acid Inhalation LC5O (RAT, 15 mm) = 15 mg/I
Kidney, Metabolic
Inhalation LC5O (RAT, 4 h) = 7.4 mg/I
3,4,5-Trihydroxybenzoic acid Oral LD5O (RABBIT) = 5.0 g/kg Irritant, Central nervous system

OSHA Carcinogen
Hazardous Component(s) NTP Carcinogen IARC Carcinogen
(Specifically Regulated)
2-Butoxyethanol No No No
Acetone No No No
Butyral resin No No No
Formic acid No No No
3,4,5-Trihydroxybenzoic acid No No No

12 ECOLOGICAL INFORMATIOI&
Ecological information: Not available.

IDH number: 497093


Page 4of6
Product name: Extend(R) Rust Treatment
C
.0

13. DISPOSAL CONSIDERATIONS


Information provided is for unused product only.

Recommended method of disposal: Not available.

Hazardous waste number: DOD 1: Ignitable.

14 TRANSPORT INFORMATION
The transport information provided in this section only applies to the materlailformulation itself, and is not specific to any
packagelconfiguration.

U.S. Department of Transportation Ground (49 CFR)


Proper shipping name: Aerosols, flammable
Hazard class or division: 2.1
Identification number: UN 1950
Packing group: None
DOT Hazardous Substance(s): Acetone

International Air Transportation (ICAOIIATA)


Proper shipping name: Aerosols, flammable
Hazard class or division: 2.1
Identification number: UN 1950
Packing group: None

Water Transportation (IMOIIMDG)


Proper shipping name: AEROSOLS
Hazard class or division: 2.1
Identification number: UN 1950
Packing group: None
Additional information: IMDG-Code: Segregation group 1-Acids

15. REGULATORY INFORMATION


United States Regulatory Information

TSCA 8 (b) Inventory Status: All components are listed or are exempt from listing on the Toxic Substances Control Act
Inventory.
TSCA 12 (b) Export Notification: None above reporting de minimis

CERCLAISARA Section 302 EHS: None above reporting de minimis


CERCLAISARA Section 3111312: Immediate Health, Delayed Health, Fire, Sudden Release
CERCLAISARA Section 313: This product contains the following toxic chemicals subject to the reporting requirements of
section 313 of the Emergency Planning and Community Right-To-Know Act of 1986 (40
CFR 372). 2-Butoxyethanol (CAS# 111-76-2).
CERCLA Reportable quantity: Acetone (CAS# 67-64-1) 5,000 lbs. (2,270 kg)
Formic acid (CAS# 64-1 8-6) 5,000 lbs. (2,270 kg)

California Proposition 65: This product contains a chemical known in the State of California to cause cancer. This
product contains a chemical known to the State of California to cause birth defects or other
reproductive harm.

Canada Regulatory Information

CEPA DSL/NDSL Status: All components are listed on or are exempt from listing on the Canadian Domestic
Substances List.

16. OTHER INFORMATION


This safety data sheet contains changes from the previous version in sections: New Safety Data Sheet format.

IDH number: 497093 Product name: Extend(R) Rust Treatment


Page 5 of 6
Prepared by: Catherine Bimler, Regulatory Affairs Specialist

Issue date: 06/08/2015

DISCLAIMER: The data contained herein are furnished for information only and are believed to be reliable. However, Henkel
Corporation and its affiliates (Henkel”) does not assume responsibility for any results obtained by persons over whose methods
Henkel has no control. It is the user’s responsibility to determine the suitability of Henkel’s products or any production methods
mentioned herein for a particular purpose, and to adopt such precautions as may be advisable for the protection of property and
persons against any hazards that may be involved in the handling and use of any Henkel’s products. In light of the foregoing,
Henkel specifically disclaims all warranties, express or implied, including warranties of merchantability and fitness for a particular
purpose, arising from sale or use of Henkel’s products. Henkel further disclaims any liability for consequential or incidental damages
of any kind, including lost profits.

IDH number: 497093 Product name: Extend(R) Rust Treatment


Page6of8
S
* YOUR SUPER CENTER FOR OVER 1,000 TOP PERFORMANCE
PRODUCTS SERVING INDUSTRIES WORLDWIDE

C OM

IOIG
GEAR OILS FILM FORMING LUBRICANT
MOTOR OILS Made with Liquilon®*
HYDRAULIC OILS PRODUCT DESCRIPTION TYPICAL OBSERVATiONS
1O1G Film Forming Lubricant is a premium Type Concentrated
PIPE COATINGS quality highly concentrated lubricant that resists Film Forming Lubricant
the corrosive effects of downhole chemicals. Color Green
THREAD SEALANTS 1O1G is made with LIQUILON®, which enhances Texture Smooth Paste
the lubricity and extreme pressure properties. Consistency Buttery
BEARING GREASES
LIQUIL0N is unaffected by acids, caustics, Active Component LIQUILOP
SPECIALTY downhole chemicals, and hydrocarbons including Density, lb/gal @ 77°F (25°C) 8.5
GREASES gasoline and solvents. Specific Gravity, @ 77°F (25°C) 1.02
Dropping Point,
THREAD IO1G is inert and thermally stable, The film ASTM 0-2265 >450°F (232°C)
COMPOUNDS forming properties of 1O1G eliminates wear, Flash Point, ASTM 0-92 >500°F (260°C)
guards against rust and corrosion, and prevents Penetration, ASTM 0-217
SUCI(ER ROD metal-to-metal contact thereby significantly Worked @ 77°F (25°C) 265—295
COATINGS reducing operating temperature. In many cases, Base Oil Viscosity
the power (electricity) to operate is reduced. cSt, 40°c 174.0
OUTSIDE 1O1G provides instant lubrication to equipment cSt, 100°C 17.0
PRES ER’JATIVES critical areas during start up. Corrosion Preventive Properties,
WI RELINE ASTM 0-1743 @ 125°F (51°C) Pass
GREASE SEALS BENEFITS Water Washout Characteristics,
ASTM D-1264 @ 100°F (37°C) 1.0%
CLEANERS & - Made with LIQUILON Evaporation Loss,
DEGREASERS - Highly concentrated ASTM 0-972 @ 210°F (96°C) 2.8%
Eliminates wear Oil Separation,
PiPE STORAGE Guards against rust and corrosion ASTM 0-1742 77°F (25°C) Nil
COMPOUNDS Oxidation Stability,
Prevents metal-tometaI contact
ASTM 0-942 210°F (98°C) 72 Hrs. PSI Loss 6
RUST & Provides residual lubrication
Shelf Life (unopened container) Two years
CORROSION Seals wirelirie tools from the effects of
N K 8 1TORS downhole chemicals
Ensures against galling and seizing during
THREAD LOCKING CONTAINER SIZE
makeup of wirellne tools
CO M P1) UNOS Small Case (12 jars)
- Provides instant lubrication during start up
Standard Case (6 jars)
VALVE Cart Case (6 cartridges)
LUBRICANTS & APPLICATION Pint Case (12 cans)
S F: A LAN IS 1 gal (4 L) pail
IO1G is recommended for use on 0-rings,
seal nipples, gaskets, packer plugs, and other 5 gal (19 L) pail
TOOL JOINT &
downhole tool accessories to ensure against 55 gal (208 L) drum
DRILL COLLAR
COMPOUNDS drying, cracking, and downhole contamination.

1O1G is also recommended for application to


wireline equipment and various downhole tools,
where lubrication and corrosion resistance are
vital. This lubricant will allow easy break-out and
disassembly of downhole tools that have been
subjected to adverse downhole chemicals.

© 2012, BALMAR, LLC Made in U.S.A. Menu Thctured by °Reglsterett trade name of
Oil Center Research, Inc. 09/10/09
WARRANTY Bocausa the con5llans at use anO lye suoenrsoe or
appl:tallcr. are beyord our can,Oi we assume no haStily rre any BALM JCtL R L L The product lofonnellon a.,d spewllcatisws listed In this
publicatan a,e constantly being updated to keep up

Cunryary in eulceized ,a change his pauulalcn what, nl,t,s Is all


616 WEST PONT DES MOUTON ROAD LAFAYETTE, LA 70507 with goverrjnenl regulations and lnulrnolcgy changes,
50005 deWcereo. whatue, said. dell aadeesan,r,t,c, 05 aunonase. Please visit our w,b site, www.oilcenler,cem, or
Each an stc.ld npreadlly do a,dme the sutabdky aISle product Sales Locations rorlar.t pair Account Rnp,asentsfive to, the mast
boacdo.,i,u,oiuacoe. LAFAYETTE, LA I HOUSTON, TX I LONGVIEW, TX I MIDLAND. TX I OKLAHOMA CITY, OK currant lnto,niakon relating to tn’s product.
©* YOUR SUPER CENTER FOR OVER 1,000 TOP PERFORMANCE
PRODUCTS SERVING INDUSTRIES WORLDWIDE
S —— — ,‘ ao

IOIEU
GEAR OILS FILM FORMING LUBRICANT
MOTOR OILS
Made with LIQUILON®*
HYDRAULIC OILS PRODUCT DESCRIPTION TYPICAL OBSERVATIONS
IO1EU Film Forming Lubricant is a premium Type Concentrated
PIPE COATINGS quality highly concentrated lubricant that resists Film Forming Lubricant
the corrosive effects of downhole chemicals. Color Green
THREAD SEALANTS 1O1EU is made with LIQUIL0N, which enhances Texture Smooth Paste
the lubricity and extreme pressure properties. Consistency Buttery
BEARING GREASES
LIQUILON® is unaffected by acids, caustics, Active Component LIQUILON
SPECIALTY downhole chemicals, and hydrocarbons including Density, lb/gal @ 77°F (25°C) 7.70
SR EAS ES gasoline and solvents. Specific Gravity, c 77°F (25°c) 0.922
1O1EU is inert and thermally stable. The film Dropping Point,
THREAD forming properties of 1OIEU eliminates wear, ASTM D-2265 >450°F (232°C)
COMPOUNDS guards against rust and corrosion, and prevents Flash Point, ASTM 0-92 >450°F (232°C)
metal-to-metal contact thereby significantly Penetration, ASTM D-217
SUCKER ROD Worked @ 77°F (25°c) 265—295
reducing operating temperature. In many cases,
COATINGS Base Oil Viscosity
the power (electricity> to operate is reduced.
IO1EU provides instant lubrication to equipment cSt, 40°c 174.0
OUTSIDE
critical areas during start up. cSt, 100°C 17.0
PRESERVATIVES Corrosion Preventive Properties,
ASTM 0-1743 @ 125°F (51°C) Pass
WI RELI NE BENEFITS
GREASE SEALS
Water Washout Characteristics,

CLEANERS &
DEGREJtSERS e
REACH Compliant
Made with LIQUILONA
HIghly concentrated
ASTM 0-1264 © 100°F (37°c)
Evaporation Loss,
ASTM 0-972 210°F (98°c)
1.0%

2.8%
C)
Oil Separation,
Eliminates wear
PIPE STORAGE ASTM 0-1742 @ 77°F (25°C) Nil
CO N P00 ND S Guards against rust and corrosion Oxidation Stability, ASTM 0-942
Prevents metal-to-metal contact @ 210°F (98°C) 72 Hrs. PSI Loss 6
RUST & Provides residual lubrication Shelf Life (unopened container) Two years
CORROSION Seals wireline tools from the effects of
INHIBITORS downhole chemicals
THREAD LOCKING Ensures against galling and seizing during CONTAINER SIZE
makeup of wiraline tools
COMPOUNDS Small Case (12—5oz jars)
Provides instant lubrication during start up Standard Case (6—lib jars)
VALVE Service temperatures 10°F to >400°F 1 gal (4 L) pail
LUBRICANTS & 5 gal (19 L) pail
S EALANTS A P P LI CAT tO N 55 gal (208 L) drum
TOOL JOINT & 1O1EU is recommended for use on 0-rings,
DRILL COLLAR seal nipples, gaskets, packer plugs, and other
COMPOUNDS downhole tool accessories to ensure against
drying, cracking, and downhole contamination.
1OIEU is also recommended for application to
:i- wireline equipment and various downhole tools,
where lubrication and corrosion resistance are
vital. This lubricant will allow easy break-out and
disassembly of downhole tools that have been
I!J subjected to adverse downhole chemicals.

152012, BALMAR, LLC Made in U.S.A. °Regiuterod trade name of


Mun,cfn,,tjrnd tty
Oil center Research, nc. 08/15/14
BAL IL. L. C. The prnduct infonnoton and speciticoliono listed in Ale
publicatIon are constantly being updoled a keep op
Conpor’) 0 nutflor,20 to chan2e tue p,noIsjon. which ,Olo,ee a all

hosed on lbehspnsThepptcutlo,,
616 WEST PONT DES MOUTON ROAD J LAFAYETTE,
Sales Locations:
LA 70507

LAFAYETTE, LA I HOUSTON, TX I LONG\IIEW, TX I MIDLAND, TX I OKLAHOMA CITY, 01<


with government rogulotlons and technology changes.
Please visit ourwob silo, www.oilcentor.com, or
contoci your Account Representative for the nest
current lnforn,atlor, rotating to tills product.
C
SAFETY DATA SHEET Page: 1 of 6
Film Forming Lubricant
Revision: 01/12/2016

1. Product and Company Identification


Product Code: 101 G
Product Name: Film Forming Lubricant
Company Name: Balmar, LLC Phone Number:
616 W. Pont Des Mouton Rd. (337)232-2496
Lafayette, LA 70507-4002
Email address: [email protected]
Emergency Contact: 01-703-527-3887

2. Hazards Identification
Skin Corrosionllrritation, Category 3

GHS Signal Word: Warning


GHS Hazard Phrases: H316 Causes mild skin irritation.
-

GHS Precaution Phrases: No phrases apply.


OHS Response Phrases: P332+313 - If skin irritation occurs, get medical advice/attention.
OHS Storage and Disposal No phrases apply.
Phrases:
Potential Health Effects Chronic: Effects may be delayed.
(Acute and Chronic):
Inhalation: The toxicological properties of this substance have not been fully investigated. Effects
may be delayed.
Skin Contact: May cause skin irritation.
Eye Contact: May cause eye irritation.
Ingestion: The toxicological properties of this substance have not been fully investigated.
Moderately toxic to humans by ingestion. May cause gastrointestinal irritation with
nausea, vomiting and diarrhea.

3. Compositionllnformation on Ingredients
GAS # Components (Chemical Name) Concentration
NA Mineral Oil 64.0-81.0%
NA Thickener 4.00 9.00 %
-

NA Coloring agent 3.00 5.00 %


-

1314-13-2 Zincoxide 1.00-5.00%

MIRS MSDS, (c) A V Systems, Inc. GHS format


SAFETY DATA SHEET Page: 2 of 6
Film Forming Lubricant Revision: 01/1212016

4. First Aid Measures I


mergency and First Aid
procedures:
n Case of Inhalation: Remove from exposure and move to fresh air immediately. If breathing is difficult, give
oxygen. Get medical aid.
n Case of Skin Contact: Flush skin with plenty of water for at least 15 minutes while removing contaminated
clothing and shoes. Wash clothing before reuse. Get medical aid.
n Case of Eye Contact: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and
lower eyelids. Get medical aid.
n Case of Ingestion: Never give anything by mouth to an unconscious person. Get medical aid. Do NOT
induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or
water. Consult a physician.
Note to Physician: Treat symptomatically and su pportively.

5 Fire Fighting Measures


Flash Pt: >232 F Method Used: Estimate
Explosive Limits: LEL: No data. UEL: No data.
Autoignition Pt: NA
Suitable Extinguishing Media:Use water spray, dry chemical, carbon dioxide, or appropriate foam. Substance is
noncombustible; use agent most appropriate to extinguish surrounding fire.
Fire Fighting Instructions: As in any fire, wear a self-contained breathing apparatus in pressure-demand,
MSHAINIOSH (approved or equivalent), and full protective gear. During a fire, irritating
and highly toxic gases may be generated by thermal decomposition or combustion.

Flammable Properties and


Material will not burn.
No data available. C
Hazards:

6. Accidental Release Measures


Steps To Be Taken In Case Use proper personal protective equipment as indicated in Section 8.
Material Is Released Or Spills/Leaks: Clean up spills immediately, observing precautions in the Protective
Spilled: Equipment section. Provide ventilation. Vacuum or sweep up material and place into a
suitable disposal container.

7. Handling and Storage


Precautions To Be Taken in Wash thoroughly after handling. Use with adequate ventilation. Avoid contact with eyes,
Handling: skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation. Wash
clothing before reuse.
Precautions To Be Taken in Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from
Storing: incompatible substances.

8. Exposure ControlslPersonal Protection


CAS # Partial Chemical Name OSHA TWA ACGIH TWA Other Limits
NA Mineral Oil No data. No data. No data.

NA Thickener No data. No data. No data.

NA Coloring agent PEL: 15 (dust) mg/m3 TLV: 10 mg/m3 No data.

1314-13-2 Zinc oxide PEL: 5 (fume); 15 (dust) TLV: 2 mg/m3 (R) No data.
mg/m3 STEL: 10 mg/m3 (R)
C-
MIRS MSDS, (c) A V Systems, Inc. GHS format
SAFETY DATA SHEET Page:3o16
Film Forming Lubricant Revision: 01/12/2016

Respiratory Equipment A respiratory protection program that meets OSHAs 29 CFR 1910.134 and ANSI Z88.2
(Specify Type): requirements or European Standard EN 149 must be followed whenever workplace
conditions warrant respirator use. Use respirators and components tested and approved
under appropriate government standards such as NIOSH (US) or CEN (EU).
Eye Protection: Wear appropriate protective eyeglasses or chemical safety goggles as described by
OSHA’s eye and face protection regulations in 29 CFR 1910.133 or European Standard
EN 166.
Protective Gloves: Wear appropriate protective gloves to prevent skin exposure.
Other Protective Clothing: Wear appropriate protective clothing to prevent skin exposure.
Engineering Controls Facilities storing or utilizing this material should be equipped with an eyewash facility and
(Ventilation etc.): a safety shower. Use adequate ventilation to keep airborne concentrations low.

9. Physical and Chemical Properties


Physical States: [ ] Gas [ ] Liquid [X] Solid
Appearance and Odor: Paste.
Petroleum-like.

Appearance: green.
Melting Point: > 232 F

Boiling Point: NP
Autoignition Pt: NA
Flash Pt: > 232 F Method Used: Estimate
Explosive Limits: LEL: No data. UEL: No data.
Specific Gravity (Water = 1): 1.02 at 77.0 F
Density: 8.51 at 77.0 F
Vapor Pressure (vs. Air or No data.
mm Hg):
Vapor Density (vs. Air = 1): No data.
Evaporation Rate: No data.
Solubility in Water: <1
Percent Volatile: No data.

10. Stability and Reactivity


Stability: Unstable [ ] Stable [X I
Conditions To Avoid - Incompatible materials.
Instability:
Incompatibility Materials To Oxidizing agents, magnesium, chlorinated rubber.
-

Avoid:
Hazardous Decomposition Or Carbon monoxide.
Byproducts:
Possibility of Hazardous Will occur [ ] Will not occur [X]
Reactions:
Conditions To Avoid - No data available.
Hazardous Reactions:

MIRS MSDS, (c) A V Systems, Inc. GHS format


SAFETY DATA SHEET Page:4of6
Film Forming Lubricant Revision: 01/12/2016

11. Toxicological Information


Toxicological Information: Epidemiology: No information found.
Teratogenicity: No information available.
C’
Reproductive Effects: No information found.
Mutagenicity: Neurotoxicity:
Carcinogenicity/Other CAS# 6966-09-2: Not listed byACGIH, IARC, NTP, or CA Prop 65.
Information: CAS# 1314-13-2: Not listed byACGIH, IARC, NTP, or CA Prop 65.
Carcinogenicity: NTP? No IARC Monographs? No OSHA Regulated? No
CAS # Components (Chemical Name) NTP IARC ACGIH OSHA
NA Mineral Oil n.a. n.a. n.a. n.a.
NA Thickener n.a. n.a. na. n.a.
NA Coloring agent n.a. 2B A4 n.a.
1314-13-2 Zinc oxide n.a. n.a. n.a. n.a.

12 Ecological Information
General Ecological Environmental: No information available.
Information:

13 Disposal Considerations
Waste Disposal Method: Chemical waste generators must determine whether a discarded chemical is classified as
a hazardous waste. US EPA guidelines for the classification determination are listed in 40
CFR Parts 261. Additionally, waste generators must consult state and local hazardous
waste regulations to ensure complete and accurate classification.
RCRA P-Series: None listed.
RCRA U-Series: None listed.

14. Transport Information


LAND TRANSPORT (US DOT):
DOT Proper Shipping Name: Not regulated as a hazardous material()
DOT Hazard Class:
UNINA Number:
LAND TRANSPORT (Canadian TDG):
TDG Shipping Name: No information available.

LAND TRANSPORT (European ADRIRID):


ADRIRID Shipping Name: No information available.
UN Number:
Hazard Class:
MARINE TRANSPORT (IMDGIIMO):
IMDG/IMO Shipping Name: Not regulated as a hazardous material
AIR TRANSPORT (ICAOIIATA):
ICAO/IATA Shipping Name: Not regulated as a hazardous material

MIRS MSDS, (c) A V Systems, Inc. GHS format


SAFETY DATA SHEET Page: 5 of 6
Film Forming Lubricant Revision: 01/12/2016

15. Regulatory Information


EPA SARA (Superfund Amendments and Reauthorization Act of 1986) Lists
CAS # Components (Chemical Name) S. 302 (EHS) S. 304 RQ S. 313 (TRI)
NA Mineral Oil No No No
NA Thickener No No No
NA Coloring agent No No No
1314-13-2 Zinc oxide No No Yes-Cat. N982
This material meets the EPA [X] Yes [ ] No Acute (immediate) Health Hazard
Hazard Categorie& defined [X] Yes [ ] No Chronic (delayed) Health Hazard
for SARA Title III Sections [ ] Yes [X] No Fire Hazard
311/312 as indicated: [ ] Yes [X] No Sudden Release of Pressure Hazard
[ I Yes [X] No Reactive Hazard

CAS # Components (Chemical Name) Other US EPA or State Lists


NA Mineral Oil CM HAPODC: No; CWA NPDES: No; TSCA: Yes -

Inventory; CA PROP.65: No; MA Oil/HazMat: No; NJ EHS:


No; NY Part 597: No; PA HSL: No
NA Thickener CM HAP,ODC: No; CWA NPDES: No; TSCA: Yes -

Inventory; CA PROP.65: No; MA Oil/HazMat: No; NJ EHS:


No; NY Part 597: No; PA HSL: No
NA Coloring agent CM HAP,ODC: No; CWA NPDES: No; TSCA: Yes -

Inventory; CA PROP.65: Yes; MA Oil/HazMat: No; NJ EHS:


Yes; NY Part 597: No; PA HSL: Yes 1 -

1314-13-2 Zinc oxide CM HAP,ODC: No; CWA NPDES: No; TSCA: Yes -

Inventory; CA PROP.65: No; MA OiI/HazMat: Yes Cat.; NJ


-

EHS: Yes 2037; NY Part 597: No; PA HSL: Yes E


- -

CAS # Components (Chemical Name) International Regulatory Lists


NA Mineral Oil Canadian DSL: Yes; REACH: Yes (R), (P), C2
-

NA Thickener Canadian DSL: Yes; REACH: Yes (P) -

NA Coloring agent Canadian DSL: Yes; REACH: Yes (R), (P)


-

1314-13-2 Zinc oxide Canadian DSL: Yes; REACH: Yes (R), (P)
-

16. Other Information


Revision Date: 01/1212016
.
Hazard Rating System: HEALTH
FLAMMABILITY_
• Flammability Instability

I!I
PPE B
HMIS: NFPA: Special Hazard

Additional Information About No data available.


This Product:
Company Policy or The information contained here is based upon data available to us and reflects our best
Disclaimer: professional judgment. Since it is impossible to anticipate the conditions under which our
products may be used, we cannot guarantee that the recommendations will be adequate
for all individuals and situations. Each user of this product should determine the suitability
of the product with zero or minimum hazards. Our products are improved daily as
up-to-date information and research data is recieved from our suppliers in our quest to
MIRS MSDS, (c) A V Systems, Inc. GHS format
SAFETY DATA SHEET Page:6of6

Film Forming Lubricant Revison 01/12/2016

use products with less or no hazards. Please feel free to contact us for current
(_N)
information.

C
MIRS MSDS, (c) A V Systems, Inc. GHS format
MATERIAL SAFETY DATA SHEET

GLANCE FOAMING GLASS CLEANER


HMIS NFPA Personal protective equipment
Health 1 1
Flammability 2 4
Physical Hazard / Instability 0 0
Version Number: 5 Preparation date: 2014-09-18

1. PRODUCT AND COMPANY IDENTIFICATION

Product name: GLANCE FOAMING GLASS CLEANER

MSDS #: MS0301498
Product Code: 04553
Recommended use: •GlassCl
eaner

Manufacturer, importer, supplier: Canadian Headquarters


US Headquarters Diversey, Inc. - Canada
Diversey, Inc. 3755 Laird Road
8310 16th St. Mississauga, Ontario L5L 0B3
Sturtevant, Wisconsin 53177-1964 Phone: 1-800-668-3131
Phone: 1-888-352-2249
MSDS Internet Address: www.diversey.com
Emergency telephone number: 1-800-851-7145 (U.S.); 1-651-917-6133 (Int'l)

2. HAZARDS IDENTIFICATION

EMERGENCY OVERVIEW
CAUTION. MAY BE MILDLY IRRITATING TO EYES. COMBUSTIBLE LIQUID AND VAPOR.

Principal routes of exposure: Eye contact. Skin contact. Inhalation.


Eye contact: May be mildly irritating to eyes.
Skin contact: None known.
Inhalation: None known.
Ingestion: None known.

3. COMPOSITION/INFORMATION ON INGREDIENTS

Ingredient(s) CAS # Weight % LD50 Oral - Rat LD50 Dermal - LC50 Inhalation -
(mg/kg) Rabbit Rat
Butane 106-97-8 1 - 5% 2000 Not available =658 g/m3 (4 h)
2-butoxyethanol 111-76-2 1 - 5% 1400 =99 mg/kg =450 ppm (4 h)
Isopropyl alcohol 67-63-0 1 - 5% 4396 =4059 mg/kg =72600 mg/m3 (4 h)
Propane 74-98-6 1 - 5% 2400 Not available =658 mg/L (4 h)
Sodium nitrite 7632-00-0 0.1 - 1.5% 85 Not available =5.5 mg/L (4 h)

4. FIRST AID MEASURES

Eye contact: Flush immediately with plenty of water. If irritation develops, get medical attention.
Skin contact: Rinse with plenty of water.
Inhalation: No specific first aid measures are required.
Ingestion: No specific first aid measures are required.

GLANCE FOAMING GLASS CLEANER 1 of 4


Aggravated Medical Conditions: None known.

5. FIRE-FIGHTING MEASURES

Suitable extinguishing media: Extinguish fire using agent suitable for surrounding fire.
Extinguishing media which must not be used for safety reasons: No information available.
Specific hazards: NFPA 30B Level 1 Aerosol. Aerosol product - Containers may rocket or explode in heat of fire.
Unusual hazards: None known.
Specific methods: Use water spray to keep fire-exposed containers cool.

Special protective equipment for firefighters: As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH
(approved or equivalent) and full protective gear.

6. ACCIDENTAL RELEASE MEASURES

Personal precautions: Eliminate all ignition sources (no smoking, flares, sparks or flames in immediate area).
Environmental precautions No information available.
and clean-up methods:

7. HANDLING AND STORAGE

Handling: Avoid contact with eyes. COMBUSTIBLE LIQUID AND VAPOR. Keep away from open flames, hot surfaces and sources of ignition. Use
only in well-ventilated areas. FOR COMMERCIAL AND INDUSTRIAL USE ONLY.
Storage: Protect from freezing. Keep tightly closed in a dry, cool and well-ventilated place. KEEP OUT OF REACH OF CHILDREN.

8. EXPOSURE CONTROLS / PERSONAL PROTECTION

Engineering measures to reduce exposure:


No special ventilation requirements General room ventilation is adequate

Personal Protective Equipment


Eye protection: No special requirements under normal use conditions.
Hand protection: No special requirements under normal use conditions
Skin and body protection: No special requirements under normal use conditions.
Respiratory protection: No special requirements under normal use conditions.
Hygiene measures: Handle in accordance with good industrial hygiene and safety practice.

Ingredient(s) CAS # ACGIH OSHA Mexico


Butane 106-97-8 1000 ppm (STEL) 800 ppm (TWA)
1900 mg/m3 (TWA)
2-butoxyethanol 111-76-2 20 ppm (TWA) Skin 75 ppm (STEL)
50 ppm (TWA) 360 mg/m3 (STEL)
240 mg/m3 (TWA) 26 ppm (TWA)
120 mg/m3 (TWA)
Isopropyl alcohol 67-63-0 400 ppm (STEL) 400 ppm (TWA) 500 ppm (STEL)
200 ppm (TWA) 980 mg/m3 (TWA) 1225 mg/m3 (STEL)
400 ppm (TWA)
980 mg/m3 (TWA)
Propane 74-98-6 1000 ppm (TWA) 1000 ppm (TWA)
1800 mg/m3 (TWA)

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Aerosol Bulk density: No information available


Appearance: No information available Evaporation Rate: No information available
Specific gravity: 0.9948 Color: Clear Colorless
Vapor density: No information available Odor: Solvent
Boiling point/range: Not determined Melting point/range: Not determined
Decomposition temperature: Not determined Autoignition temperature: No information available
Solubility: Partially Soluble Density: 8.3 lbs/gal 0.9948 Kg/L
Solubility in other solvents: No information available Flash point: -156 °F -104.4 °C
Partition coefficient (n-octanol/water): No information available Viscosity: No information available
Elemental Phosphorus: 0.00 % by wt. VOC: 8.82 % *
pH: 10.93 Dilution pH: 11.43 @ RTU
Explosion limits: - upper: Not determined - lower: Not determined

* - Title 17, California Code of Regulations, Division 3, Chapter 1, Subchapter 8.5, Article 2, Consumer Products, Sections 94508

GLANCE FOAMING GLASS CLEANER 2 of 4


10. STABILITY AND REACTIVITY

Stability: The product is stable


Polymerization: Hazardous polymerization does not occur.
Hazardous decomposition products: None reasonably foreseeable.
Conditions to avoid: Extremes of temperature and direct sunlight. Keep away from open flames, hot surfaces and sources of
ignition.

11. TOXICOLOGICAL INFORMATION

Acute toxicity: Oral LD50 estimated to be greater than 5000 mg/kg Dermal LD50 estimated to be > 2000 mg/kg
Component Information: See Section 3.

Chronic toxicity: None known

Specific effects
Carcinogenic effects: •Noneknown
Mutagenic effects: None known
Reproductive toxicity: None known
Target organ effects: None known

Ingredient(s) CAS # NTP IARC OSHA


Isopropyl alcohol 67-63-0 3 X
Sodium nitrite 7632-00-0 2A

12. ECOLOGICAL INFORMATION

Environmental Information: No data available.

13. DISPOSAL CONSIDERATIONS

Waste from residues / unused products:


Use up contents if possible before disposal. If possible, recycle empty aerosol cans to the nearest steel recycling center. This product, as sold, if
discarded or disposed, is a hazardous waste according to Federal regulations (40 CFR 261.4 (b)(4)). Dispose in compliance with all Federal, state,
provincial, and local laws and regulations.
RCRA Hazard Class (undiluted product): D001 Ignitable Waste

14. TRANSPORT INFORMATION

DOT/TDG/IMDG: Please refer to the Diversey HazMat Library, only available through Internet Explorer, http://naextranet.diversey.com/dot/, for up
to date shipping information.

DOT (Ground) Bill of Lading Description: LTD. QTY.

IMDG (Ocean) Bill of Lading Description: UN1950, AEROSOLS, 2.1, LTD. QTY.

15. REGULATORY INFORMATION

International Inventories at CAS# Level


All components of this product are listed on the following inventories: U.S.A. (TSCA), Canada (DSL/NDSL), Europe (EINECS/ELINCS/NLP),
Australia (AICS), Korea (ECL), Japan (ENCS), Philippines (PICCS), China (IECSC).

U.S. Regulations
California Proposition 65: This product is not subject to the reporting requirements under California's Proposition 65.

RIGHT TO KNOW (RTK)


Ingredient(s) CAS # MARTK: NJRTK: PARTK: RIRTK:
Water 7732-18-5 - - - -
Butane 106-97-8 X X X -
2-butoxyethanol 111-76-2 X X X -
Isopropyl alcohol 67-63-0 X X X -
Propane 74-98-6 X X X -
Sodium nitrite 7632-00-0 X X X X

GLANCE FOAMING GLASS CLEANER 3 of 4


CERCLA/ SARA
Ingredient(s) CAS # Weight % CERCLA/SARA RQ (lbs) Section 302 TPQ (lbs) Section 313
2-butoxyethanol 111-76-2 1 - 5% X
Isopropyl alcohol 67-63-0 1 - 5% X
Sodium nitrite 7632-00-0 0.1 - 1.5% 100 X

Ingredient(s) CAA HAP CAA ODS CWA Priority Pollutants


2-butoxyethanol X

SARA 311/312 Hazard Categories


Immediate: -
Delayed: -
Fire: X
Reactivity: -
Sudden Release of Pressure: X
Canada
WHMIS hazard class: A Compressed gases, B5 Flammable aerosol.

Ingredient(s) CAS # NPRI


2-butoxyethanol 111-76-2 X
Isopropyl alcohol 67-63-0 X
Propane 74-98-6 X
Sodium nitrite 7632-00-0 X

16. OTHER INFORMATION

Reason for revision: Not applicable


Prepared by: NAPRAC
Additional advice: •Doesnotcont ai
nanaddedf r
agrance
•Thispr oducthasbeencl assif
iedi naccor dancewi thhazar dcr iteri
aoft heCont r
oll
edPr oduct
s
Regulations and the MSDS contains all the information required by the Controlled Products
Regulations

Notice to Reader: This document has been prepared using data from sources considered technically reliable. It does not constitute a warranty,
express or implied, as to the accuracy of the information contained within. Actual conditions of use and handling are beyond seller's control. User is
responsible to evaluate all available information when using product for any particular use and to comply with all Federal, State, Provincial and
Local laws and regulations.

GLANCE FOAMING GLASS CLEANER 4 of 4


SAFETY DATA SHEET

1. Identification
Product number 1000000075
Product identifier GLASS CLEANER
Revision date 05-30-2015
Company information Sprayway, Inc.
1005 S. Westgate Drive
Addison, IL 60101 United States
Company phone General Assistance 1-630-628-3000
Emergency telephone US 1-866-836-8855
Emergency telephone outside 1-952-852-4646
US
Version # 02
Supersedes date 05-26-2015
Recommended use cleaner
Recommended restrictions None known.

2. Hazard(s) identification
Physical hazards Gases under pressure Liquefied gas
Health hazards Not classified.
Environmental hazards Not classified.
OSHA defined hazards Not classified.

Label elements

Signal word Warning


Hazard statement Contains gas under pressure; may explode if heated.
Precautionary statement
Prevention Observe good industrial hygiene practices.
Response Wash hands after handling.
Storage Protect from sunlight. Store in a well-ventilated place.
Disposal Dispose of waste and residues in accordance with local authority requirements.
Hazard(s) not otherwise None known.
classified (HNOC)
Supplemental information None.

3. Composition/information on ingredients
Mixtures
Chemical name Common name and synonyms CAS number %
2-Butoxyethanol 111-76-2 2.5 - 10
Ethyl Alcohol 64-17-5 2.5 - 10
Butane 106-97-8 1 - 2.5
Propane 74-98-6 1 - 2.5
Other components below reportable levels 90 - 100
*Designates that a specific chemical identity and/or percentage of composition has been withheld as a trade secret.

Product name: GLASS CLEANER SDS US

Product #: 1000000075 Version #: 02 Revision date: 05-30-2015 Issue date: 05-26-2015 1 / 10


4. First-aid measures
Inhalation Move to fresh air. Get medical attention if symptoms persist.
Skin contact Get medical attention if irritation develops and persists.
Eye contact Immediately flush with plenty of water for at least 15 minutes. If easy to do, remove contact lenses.
Continue rinsing. Get medical attention if irritation develops and persists.
Ingestion Rinse mouth.
Most important Direct contact with eyes may cause temporary irritation.
symptoms/effects, acute and
delayed
Indication of immediate Provide general supportive measures and treat symptomatically.
medical attention and special
treatment needed
General information Ensure that medical personnel are aware of the material(s) involved, and take precautions to
protect themselves.

5. Fire-fighting measures
Suitable extinguishing media Water fog. Foam. Dry chemical powder. Carbon dioxide (CO2).
Unsuitable extinguishing Do not use water jet as an extinguisher, as this will spread the fire.
media
Specific hazards arising from Contents under pressure. During fire, gases hazardous to health may be formed.
the chemical
Special protective equipment Self-contained breathing apparatus and full protective clothing must be worn in case of fire.
and precautions for firefighters
Fire-fighting In case of fire: Stop leak if safe to do so. Do not move cargo or vehicle if cargo has been exposed
equipment/instructions to heat. Move containers from fire area if you can do so without risk. Cool containers exposed to
heat with water spray and remove container, if no risk is involved. Containers should be cooled
with water to prevent vapor pressure build up. For massive fire in cargo area, use unmanned hose
holder or monitor nozzles, if possible. If not, withdraw and let fire burn out.
Specific methods Use standard firefighting procedures and consider the hazards of other involved materials.
General fire hazards No unusual fire or explosion hazards noted.

6. Accidental release measures


Personal precautions, Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Keep out of
protective equipment and low areas. Wear appropriate protective equipment and clothing during clean-up. Emergency
emergency procedures personnel need self-contained breathing equipment. Do not touch damaged containers or spilled
material unless wearing appropriate protective clothing. Ventilate closed spaces before entering
them. Local authorities should be advised if significant spillages cannot be contained. See Section
8 of the SDS for Personal Protective Equipment. For personal protection, see section 8 of the
SDS.
Methods and materials for Refer to attached safety data sheets and/or instructions for use. Eliminate all ignition sources (no
containment and cleaning up smoking, flares, sparks, or flames in immediate area). Keep combustibles (wood, paper, oil, etc.)
away from spilled material. Stop leak if you can do so without risk. Move the cylinder to a safe and
open area if the leak is irreparable. Isolate area until gas has dispersed. Prevent entry into
waterways, sewer, basements or confined areas. Wipe up with absorbent material (e.g. cloth,
fleece). Clean surface thoroughly to remove residual contamination. For waste disposal, see
section 13 of the SDS.
Environmental precautions Avoid discharge into drains, water courses or onto the ground.

7. Handling and storage


Precautions for safe handling Pressurized container: Do not pierce or burn, even after use. Do not use if spray button is missing
or defective. Do not spray on a naked flame or any other incandescent material. Do not smoke
while using or until sprayed surface is thoroughly dry. Do not cut, weld, solder, drill, grind, or
expose containers to heat, flame, sparks, or other sources of ignition. Ground and bond containers
when transferring material. Do not re-use empty containers. Do not get in eyes, on skin, or on
clothing. Avoid prolonged exposure. Use only in well-ventilated areas. Wear appropriate personal
protective equipment. Observe good industrial hygiene practices.

Product name: GLASS CLEANER SDS US

Product #: 1000000075 Version #: 02 Revision date: 05-30-2015 Issue date: 05-26-2015 2 / 10


Conditions for safe storage, Level 1 Aerosol.
including any incompatibilities
Pressurized container. Protect from sunlight and do not expose to temperatures exceeding
50°C/122 °F. Do not puncture, incinerate or crush. Do not handle or store near an open flame,
heat or other sources of ignition. Keep containers tightly closed in a dry, cool and well-ventilated
place. Refrigeration recommended. Store away from incompatible materials (see Section 10 of the
SDS).

8. Exposure controls/personal protection


Occupational exposure limits
US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000)
Components Type Value
2-Butoxyethanol (CAS PEL 240 mg/m3
111-76-2)
50 ppm
Ethyl Alcohol (CAS 64-17-5) PEL 1900 mg/m3
1000 ppm
Propane (CAS 74-98-6) PEL 1800 mg/m3
1000 ppm
US. ACGIH Threshold Limit Values
Components Type Value
2-Butoxyethanol (CAS TWA 20 ppm
111-76-2)
Butane (CAS 106-97-8) STEL 1000 ppm
Ethyl Alcohol (CAS 64-17-5) STEL 1000 ppm
US. NIOSH: Pocket Guide to Chemical Hazards
Components Type Value
2-Butoxyethanol (CAS TWA 24 mg/m3
111-76-2)
5 ppm
Butane (CAS 106-97-8) TWA 1900 mg/m3
800 ppm
Ethyl Alcohol (CAS 64-17-5) TWA 1900 mg/m3
1000 ppm
Propane (CAS 74-98-6) TWA 1800 mg/m3
1000 ppm
Biological limit values
ACGIH Biological Exposure Indices
Components Value Determinant Specimen Sampling Time
2-Butoxyethanol (CAS 200 mg/g Butoxyacetic Creatinine in *
111-76-2) acid (BAA), urine
with hydrolysis
* - For sampling details, please see the source document.
Exposure guidelines
US - California OELs: Skin designation
2-Butoxyethanol (CAS 111-76-2) Can be absorbed through the skin.
US - Minnesota Haz Subs: Skin designation applies
2-Butoxyethanol (CAS 111-76-2) Skin designation applies.
US - Tennesse OELs: Skin designation
2-Butoxyethanol (CAS 111-76-2) Can be absorbed through the skin.
US NIOSH Pocket Guide to Chemical Hazards: Skin designation
2-Butoxyethanol (CAS 111-76-2) Can be absorbed through the skin.
US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000)
2-Butoxyethanol (CAS 111-76-2) Can be absorbed through the skin.
Appropriate engineering Good general ventilation (typically 10 air changes per hour) should be used. Ventilation rates
controls should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation,
or other engineering controls to maintain airborne levels below recommended exposure limits. If
exposure limits have not been established, maintain airborne levels to an acceptable level.

Product name: GLASS CLEANER SDS US

Product #: 1000000075 Version #: 02 Revision date: 05-30-2015 Issue date: 05-26-2015 3 / 10


Individual protection measures, such as personal protective equipment
Eye/face protection If contact is likely, safety glasses with side shields are recommended.
Hand protection For prolonged or repeated skin contact use suitable protective gloves.
Skin protection
Other Wear suitable protective clothing.
Respiratory protection If permissible levels are exceeded use NIOSH mechanical filter / organic vapor cartridge or an
air-supplied respirator. If engineering controls do not maintain airborne concentrations below
recommended exposure limits (where applicable) or to an acceptable level (in countries where
exposure limits have not been established), an approved respirator must be worn.
Thermal hazards Wear appropriate thermal protective clothing, when necessary.
General hygiene When using do not smoke. Always observe good personal hygiene measures, such as washing
considerations after handling the material and before eating, drinking, and/or smoking. Routinely wash work
clothing and protective equipment to remove contaminants.

9. Physical and chemical properties


Appearance Clear.
Physical state Gas.
Form Aerosol. Liquefied gas.
Color Light yellow.
Odor Characteristic.
Odor threshold Not available.
pH 9.1 - 10.1 estimated
Melting point/freezing point Not available.
Initial boiling point and boiling 212 °F (100 °C) estimated
range
Flash point -156.0 °F (-104.4 °C) Propellant estimated
Evaporation rate Not available.
Flammability (solid, gas) Not available.
Upper/lower flammability or explosive limits
Flammability limit - lower Not available.
(%)
Flammability limit - upper Not available.
(%)
Explosive limit - lower (%) Not available.
Explosive limit - upper (%) Not available.
Vapor pressure 80 - 100 psig @70F estimated
Vapor density Not available.
Relative density Not available.
Solubility(ies)
Solubility (water) Not available.
Partition coefficient Not available.
(n-octanol/water)
Auto-ignition temperature Not available.
Decomposition temperature Not available.
Viscosity Not available.
Other information
Aerosol spray enclosed space
Deflagration density > 2.52 g/cm3 Tested
Aerosol spray ignition < 15 cm Tested estimated
distance
Specific gravity 0.977 - 0.997

Product name: GLASS CLEANER SDS US

Product #: 1000000075 Version #: 02 Revision date: 05-30-2015 Issue date: 05-26-2015 4 / 10


10. Stability and reactivity
Reactivity The product is stable and non-reactive under normal conditions of use, storage and transport.
Chemical stability Material is stable under normal conditions.
Possibility of hazardous No dangerous reaction known under conditions of normal use. Hazardous polymerization does not
reactions occur.
Conditions to avoid Avoid heat, sparks, open flames and other ignition sources. Avoid temperatures exceeding the
flash point. Contact with incompatible materials.
Incompatible materials Strong oxidizing agents.
Hazardous decomposition No hazardous decomposition products are known.
products

11. Toxicological information


Information on likely routes of exposure
Ingestion Expected to be a low ingestion hazard.
Inhalation Prolonged inhalation may be harmful.
Skin contact No adverse effects due to skin contact are expected.

2-Butoxy ethanol may be absorbed through the skin in toxic amounts if contact is repeated and
prolonged. These effects have not been observed in humans.

Eye contact Direct contact with eyes may cause temporary irritation.
Symptoms related to the Direct contact with eyes may cause temporary irritation.
physical, chemical and
toxicological characteristics
Information on toxicological effects
Acute toxicity May be harmful if swallowed. May be harmful in contact with skin. May be harmful if inhaled.
Expected to be a low hazard for usual industrial or commercial handling by trained personnel.
Components Species Test Results
2-Butoxyethanol (CAS 111-76-2)
Acute
Dermal
LD50 Guinea pig 230 ml/kg, 24 Hours
7.3 ml/kg, 4 Days
Rabbit 450 ml/kg, 24 Hours
435 mg/kg, 24 Hours
0.63 ml/kg
Rat > 2000 mg/kg, 24 Hours
Inhalation
LC50 Rabbit 400 ppm, 7 Hours
Rat 450 ppm, 4 Hours
Oral
LD100 Rabbit 695 mg/kg
LD50 Dog > 695 mg/kg
Guinea pig 1200 mg/kg
Rat 530 - 2800 mg/kg
Butane (CAS 106-97-8)
Acute
Inhalation
LC50 Mouse 1237 mg/l, 120 Minutes
52 %, 120 Minutes
Rat 1355 mg/l

Product name: GLASS CLEANER SDS US

Product #: 1000000075 Version #: 02 Revision date: 05-30-2015 Issue date: 05-26-2015 5 / 10


Components Species Test Results
Ethyl Alcohol (CAS 64-17-5)
Acute
Inhalation
LC50 Cat 85.41 mg/l, 4.5 Hours
43.68 mg/l, 6 Hours
Mouse > 60000 ppm
79.43 mg/l, 134 Minutes
Rat > 115.9 mg/l, 4 Hours
51.3 mg/l, 6 Hours
Oral
LD50 Monkey 6000 mg/kg
Mouse 10500 ml/kg
Rat 1187 - 2769 mg/kg
7800 ml/kg
Propane (CAS 74-98-6)
Acute
Inhalation
LC50 Mouse 1237 mg/l, 120 Minutes
52 %, 120 Minutes
Rat 1355 mg/l
658 mg/l/4h

* Estimates for product may be based on additional component data not shown.
Skin corrosion/irritation May be irritating to the skin. Prolonged skin contact may cause temporary irritation.
Serious eye damage/eye Direct contact with eyes may cause temporary irritation. May be irritating to eyes.
irritation
Respiratory or skin sensitization
Respiratory sensitization Not a respiratory sensitizer.
Skin sensitization This product is not expected to cause skin sensitization.
Germ cell mutagenicity No data available to indicate product or any components present at greater than 0.1% are
mutagenic or genotoxic.
Carcinogenicity This product is not considered to be a carcinogen by IARC, ACGIH, NTP, or OSHA.
IARC Monographs. Overall Evaluation of Carcinogenicity
2-Butoxyethanol (CAS 111-76-2) 3 Not classifiable as to carcinogenicity to humans.
OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)
Not listed.
Reproductive toxicity This product is not expected to cause reproductive or developmental effects.
Specific target organ toxicity - Not classified.
single exposure
Specific target organ toxicity - Not classified.
repeated exposure
Aspiration hazard Not an aspiration hazard. Not likely, due to the form of the product.
Chronic effects Prolonged inhalation may be harmful. May be harmful if absorbed through skin.

2-Butoxy ethanol may be absorbed through the skin in toxic amounts if contact is repeated and
prolonged. These effects have not been observed in humans.

12. Ecological information


Ecotoxicity Harmful to aquatic life.

Product name: GLASS CLEANER SDS US

Product #: 1000000075 Version #: 02 Revision date: 05-30-2015 Issue date: 05-26-2015 6 / 10


Product Species Test Results
GLASS CLEANER (CAS Mixture)
Aquatic
Crustacea EC50 Daphnia 13838.1602 mg/l, 48 hours estimated
Components Species Test Results
2-Butoxyethanol (CAS 111-76-2)
Aquatic
Fish LC50 Inland silverside (Menidia beryllina) 1250 mg/l, 96 hours
Ethyl Alcohol (CAS 64-17-5)
Aquatic
Crustacea EC50 Water flea (Daphnia magna) 7700 - 11200 mg/l, 48 hours
Fish LC50 Fathead minnow (Pimephales promelas) > 100.1 mg/l, 96 hours

* Estimates for product may be based on additional component data not shown.
Persistence and degradability No data is available on the degradability of this product.
Bioaccumulative potential No data available.
Partition coefficient n-octanol / water (log Kow)
2-Butoxyethanol 0.83
Butane 2.89
Ethyl Alcohol -0.31
Propane 2.36
Mobility in soil No data available.
Other adverse effects No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation
potential, endocrine disruption, global warming potential) are expected from this component.

13. Disposal considerations


Disposal instructions Consult authorities before disposal. Contents under pressure. Do not puncture, incinerate or crush.
Dispose of contents/container in accordance with local/regional/national/international regulations.
Local disposal regulations Dispose in accordance with all applicable regulations.
Hazardous waste code The waste code should be assigned in discussion between the user, the producer and the waste
disposal company.
Waste from residues / unused Dispose of in accordance with local regulations. Empty containers or liners may retain some
products product residues. This material and its container must be disposed of in a safe manner (see:
Disposal instructions).
Contaminated packaging Empty containers should be taken to an approved waste handling site for recycling or disposal.
Since emptied containers may retain product residue, follow label warnings even after container is
emptied. Do not re-use empty containers.

14. Transport information


DOT
UN number UN1950
UN proper shipping name Aerosols
Transport hazard class(es)
Class 2.2
Subsidiary risk -
Label(s) 2.2
Packing group Not applicable.
Special precautions for user Read safety instructions, SDS and emergency procedures before handling.
Packaging exceptions 306
Packaging non bulk None
Packaging bulk None
This product meets the exception requirements of section 173.306 as a limited quantity and may be shipped as a limited quantity.
Until 12/31/2020, the "Consumer Commodity - ORM-D" marking may still be used in place of the new limited quantity diamond
mark for packages of UN 1950 Aerosols. Limited quantities require the limited quantity diamond mark on cartons after 12/31/20
and may be used now in place of the "Consumer Commodity ORM-D" marking and both may be displayed concurrently.
IATA
UN number UN1950
UN proper shipping name Aerosols, non-flammable

Product name: GLASS CLEANER SDS US

Product #: 1000000075 Version #: 02 Revision date: 05-30-2015 Issue date: 05-26-2015 7 / 10


Transport hazard class(es)
Class 2.2
Subsidiary risk -
Label(s) 2.2
Packing group Not applicable.
Environmental hazards No.
ERG Code 2L
Special precautions for user Read safety instructions, SDS and emergency procedures before handling.
Other information
Passenger and cargo Allowed.
aircraft
Cargo aircraft only Allowed.
Packaging Exceptions LTD QTY
IMDG
UN number UN1950
UN proper shipping name AEROSOLS
Transport hazard class(es)
Class 2.2
Subsidiary risk -
Label(s) 2.2
Packing group Not applicable.
Environmental hazards
Marine pollutant No.
EmS Not available.
Special precautions for user Read safety instructions, SDS and emergency procedures before handling.
Packaging Exceptions LTD QTY
Transport in bulk according to Not applicable.
Annex II of MARPOL 73/78 and
the IBC Code
DOT

IATA; IMDG

15. Regulatory information


US federal regulations This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication
Standard, 29 CFR 1910.1200.
All components are on the U.S. EPA TSCA Inventory List.
TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D)
Not regulated.
CERCLA Hazardous Substance List (40 CFR 302.4)
Not listed.
Product name: GLASS CLEANER SDS US

Product #: 1000000075 Version #: 02 Revision date: 05-30-2015 Issue date: 05-26-2015 8 / 10


SARA 304 Emergency release notification
Not regulated.
OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)
Not listed.
Superfund Amendments and Reauthorization Act of 1986 (SARA)
Hazard categories Immediate Hazard - No
Delayed Hazard - No
Fire Hazard - No
Pressure Hazard - Yes
Reactivity Hazard - No
SARA 302 Extremely hazardous substance
Not listed.
SARA 311/312 Hazardous No
chemical
SARA 313 (TRI reporting)
Not regulated.

Other federal regulations


Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List
Not regulated.
Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130)
Butane (CAS 106-97-8)
Propane (CAS 74-98-6)
Safe Drinking Water Act Not regulated.
(SDWA)
US state regulations
US. Massachusetts RTK - Substance List
2-Butoxyethanol (CAS 111-76-2)
Butane (CAS 106-97-8)
Ethyl Alcohol (CAS 64-17-5)
Propane (CAS 74-98-6)
US. New Jersey Worker and Community Right-to-Know Act
2-Butoxyethanol (CAS 111-76-2)
Butane (CAS 106-97-8)
Ethyl Alcohol (CAS 64-17-5)
Propane (CAS 74-98-6)
US. Pennsylvania Worker and Community Right-to-Know Law
2-Butoxyethanol (CAS 111-76-2)
Butane (CAS 106-97-8)
Ethyl Alcohol (CAS 64-17-5)
Propane (CAS 74-98-6)
US. Rhode Island RTK
Butane (CAS 106-97-8)
Propane (CAS 74-98-6)
US. California Proposition 65
California Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition 65): This material is not known to contain
any chemicals currently listed as carcinogens or reproductive toxins.
International Inventories
Country(s) or region Inventory name On inventory (yes/no)*
Australia Australian Inventory of Chemical Substances (AICS) Yes
Canada Domestic Substances List (DSL) Yes
Canada Non-Domestic Substances List (NDSL) No
China Inventory of Existing Chemical Substances in China (IECSC) Yes
Europe European Inventory of Existing Commercial Chemical Yes
Substances (EINECS)
Europe European List of Notified Chemical Substances (ELINCS) No
Japan Inventory of Existing and New Chemical Substances (ENCS) No
Korea Existing Chemicals List (ECL) No
Product name: GLASS CLEANER SDS US

Product #: 1000000075 Version #: 02 Revision date: 05-30-2015 Issue date: 05-26-2015 9 / 10


Country(s) or region Inventory name On inventory (yes/no)*
New Zealand New Zealand Inventory No
Philippines Philippine Inventory of Chemicals and Chemical Substances No
(PICCS)
United States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory Yes
*A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s)
A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing
country(s).

16. Other information, including date of preparation or last revision


Issue date 05-26-2015
Revision date 05-30-2015
Version # 02
References EPA: AQUIRE database
NLM: Hazardous Substances Data Base
US. IARC Monographs on Occupational Exposures to Chemical Agents
Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge,
information and belief at the date of its publication. The information given is designed only as a
guidance for safe handling, use, processing, storage, transportation, disposal and release and is
not to be considered a warranty or quality specification. The information relates only to the specific
material designated and may not be valid for such material used in combination with any other
materials or in any process, unless specified in the text.
Revision Information Product and Company Identification: Alternate Trade Names

Product name: GLASS CLEANER SDS US

Product #: 1000000075 Version #: 02 Revision date: 05-30-2015 Issue date: 05-26-2015 10 / 10


Graffiti Wipes
Safety Data Sheet
SECTION 1: Product and company identification
Product name : Graffiti Wipes
Use of the substance/mixture : Premoistened wipe
Product code : 1447
Company : Total Solutions
P.O. Box 240014
Milwaukee, WI 53224 - USA
T (414) 354-6417
Emergency number : Chemtec: (800) 424-9300

SECTION 2: Hazards identification


2.1. Classification of the substance or mixture
Classification (GHS-US)
Eye Irrit. 2A H319
Full text of H-phrases: see section 16

2.2. Label elements


GHS-US labeling
Hazard pictograms (GHS-US) :

GHS07
Signal word (GHS-US) : Warning
Hazard statements (GHS-US) : Causes serious eye irritation
Precautionary statements (GHS-US) : Wash thoroughly after handling
Wear eye protection, protective clothing, protective gloves
If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present
and easy to do. Continue rinsing
If eye irritation persists: Get medical advice/attention

2.3. Other hazards


No additional information available
2.4. Unknown acute toxicity (GHS US)
Not applicable

SECTION 3: Composition/information on ingredients


3.1. Substance
Not applicable
Full text of H-phrases: see section 16
3.2. Mixture
Name Product identifier % Classification (GHS-US)
Dimethyl Adipate (CAS No) 627-93-0 10 - 30 Acute Tox. 4 (Oral), H302
Acute Tox. 4 (Inhalation), H332
UNDECETH-5 (CAS No) 34398-01-1 1-5 Acute Tox. 4 (Oral), H302
Eye Dam. 1, H318

SECTION 4: First aid measures


4.1. Description of first aid measures
First-aid measures general : If you feel unwell, seek medical advice (show the label where possible).
First-aid measures after inhalation : If you feel unwell, seek medical advice.
First-aid measures after skin contact : Gently wash with plenty of soap and water.
First-aid measures after eye contact : Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing. If eye irritation persists: Get medical advice/attention.
First-aid measures after ingestion : Rinse mouth with water. Do not induce vomiting.
4.2. Most important symptoms and effects, both acute and delayed
Symptoms/injuries : Not expected to present a significant hazard under anticipated conditions of normal use.

Date of issue: 7/13/2015 Revision date: 07/13/2015 Version: 1.1 P GHS SDS Page 1 of 5
Graffiti Wipes
Safety Data Sheet
Symptoms/injuries after inhalation : None under normal use.
Symptoms/injuries after skin contact : Contact during a long period may cause light irritation. Repeated exposure may cause skin dryness
or cracking.
Symptoms/injuries after eye contact : Causes serious eye irritation.
Symptoms/injuries after ingestion : Gastrointestinal complaints.
Chronic symptoms : No data available.
4.3. Indication of any immediate medical attention and special treatment needed
Treat symptomatically.

SECTION 5: Firefighting measures


5.1. Extinguishing media
Suitable extinguishing media : Foam. Carbon dioxide. Dry chemical powder.
Unsuitable extinguishing media : Do not use a heavy water stream.
5.2. Special hazards arising from the substance or mixture
Fire hazard : Combustible liquid.
Reactivity : Upon combustion: CO and CO2 are formed.
5.3. Advice for firefighters
Firefighting instructions : Exercise caution when fighting any chemical fire. Use water spray or fog for cooling exposed
containers. Take account of environmentally hazardous firefighting water.
Protection during firefighting : Do not enter fire area without proper protective equipment, including respiratory protection.

SECTION 6: Accidental release measures


6.1. Personal precautions, protective equipment and emergency procedures
General measures : Isolate from fire, if possible, without unnecessary risk.

6.1.1. For non-emergency personnel


Protective equipment : Protective goggles. Gloves. Protective clothing.
Emergency procedures : Evacuate unnecessary personnel. NO open flames, NO sparks, and NO smoking. Avoid contact with
skin, eyes and clothing. Ventilate spillage area.

6.1.2. For emergency responders


Protective equipment : Equip cleanup crew with proper protection.
Emergency procedures : Stop leak if safe to do so. Stop release. Ventilate area.
6.2. Environmental precautions
Avoid release to the environment. Prevent entry to sewers and public waters.
6.3. Methods and material for containment and cleaning up
For containment : Contain released substance, pump into suitable containers.
Methods for cleaning up : This material and its container must be disposed of in a safe way, and as per local legislation.
6.4. Reference to other sections
No additional information available

SECTION 7: Handling and storage


7.1. Precautions for safe handling
Precautions for safe handling : Comply with the legal requirements. Do not handle until all safety precautions have been read and
understood. Use personal protective equipment as required. Do not eat, drink or smoke when using
this product. Do not get in eyes, on skin, or on clothing. Handle and open the container with care.
Keep away from sources of ignition - No smoking.
Hygiene measures : Wash thoroughly after handling. Wash contaminated clothing before reuse.
7.2. Conditions for safe storage, including any incompatibilities
Technical measures : Comply with applicable regulations.
Storage conditions : Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
Incompatible products : Oxidizing agent. strong acids. Strong bases.
Incompatible materials : Sources of ignition. Heat sources.
Heat-ignition : KEEP SUBSTANCE AWAY FROM: heat sources. ignition sources.
Prohibitions on mixed storage : KEEP SUBSTANCE AWAY FROM: (strong) acids. (strong) bases. oxidizing agents.
Storage area : Meet the legal requirements. Store in a cool area. Store in a well-ventilated place.
Special rules on packaging : meet the legal requirements.

SECTION 8: Exposure controls/personal protection


Date of issue: 7/13/2015 Revision date: 07/13/2015 Version: 1.1 P GHS SDS Page 2 of 5
Graffiti Wipes
Safety Data Sheet
8.1. Control parameters
No additional information available

8.2. Exposure controls


Personal protective equipment : Use appropriate personal protective equipment when risk assessment indicates this is necessary.
Safety glasses. Gloves. Protective clothing.

SECTION 9: Physical and chemical properties


9.1. Information on basic physical and chemical properties
Physical state : Solid
Appearance : Premoistened wipe.
Odor : Mild odor
Odor threshold : No data available
pH : No data available
Melting point : No data available
Freezing point : No data available
Boiling point : No data available
Flash point : 163 °F Closed cup - Tested using the liquid component of the towelette
Relative evaporation rate (butyl acetate=1) : No data available
Flammability (solid, gas) : No data available
Explosion limits : No data available
Explosive properties : No data available
Oxidizing properties : No data available
Vapor pressure : No data available
Relative density : No data available
Relative vapor density at 20 °C : No data available
Specific gravity / density : 1.03 g/ml - Tested using the liquid component of the towelette
Solubility : Liquid component is soluble in water.
Log Pow : No data available
Log Kow : No data available
Auto-ignition temperature : No data available
Decomposition temperature : No data available
Viscosity : No data available
Viscosity, kinematic : No data available
Viscosity, dynamic : No data available
VOC content : < 20 % - Tested using the liquid component of the towelette

SECTION 10: Stability and reactivity


10.1. Reactivity
Upon combustion: CO and CO2 are formed.
10.2. Chemical stability
No additional information available
10.3. Possibility of hazardous reactions
Refer to section 10.1 on Reactivity.
10.4. Conditions to avoid
No additional information available
10.5. Incompatible materials
strong acids. Strong bases. Oxidizing agents.
10.6. Hazardous decomposition products
Under normal conditions of storage and use, hazardous decomposition products should not be produced.

Date of issue: 7/13/2015 Revision date: 07/13/2015 Version: 1.1 P GHS SDS Page 3 of 5
Graffiti Wipes
Safety Data Sheet
SECTION 11: Toxicological information
11.1. Information on toxicological effects

Acute toxicity : Not classified

UNDECETH-5 (34398-01-1)
LD50 oral rat > 1400 mg/kg
Skin corrosion/irritation : Not classified
Serious eye damage/irritation : Causes serious eye irritation.
Respiratory or skin sensitization : Not classified
Germ cell mutagenicity : Not classified
Carcinogenicity : Not classified
Reproductive toxicity : Not classified
Specific target organ toxicity (single exposure) : Not classified
Specific target organ toxicity (repeated : Not classified
exposure)
Aspiration hazard : Not classified
Symptoms/injuries after inhalation : None under normal use.
Symptoms/injuries after skin contact : Contact during a long period may cause light irritation. Repeated exposure may cause skin
dryness or cracking.
Symptoms/injuries after eye contact : Causes serious eye irritation.
Symptoms/injuries after ingestion : Gastrointestinal complaints.
Chronic symptoms : No data available.
Likely routes of exposure : Dermal

SECTION 12: Ecological information


12.1. Toxicity
Ecology - general : Not classified due to lack of data.

UNDECETH-5 (34398-01-1)
LC50 fish 1 < 10 mg/l
EC50 Daphnia 1 < 10 mg/l
ErC50 (algae) < 10 mg/l
12.2. Persistence and degradability
Graffiti Wipes
Persistence and degradability Not established.

12.3. Bioaccumulative potential


No additional information available

SECTION 13: Disposal considerations


13.1. Waste treatment methods
Waste treatment methods : Do not flush wipes.
Waste disposal recommendations : Dispose in a safe manner in accordance with local/national regulations.

SECTION 14: Transport information


Department of Transportation (DOT)

In accordance with DOT : Not regulated for transport


Additional information
Other information : No supplementary information available.

ADR
No additional information available
Transport by sea
No additional information available
Air transport
No additional information available

Date of issue: 7/13/2015 Revision date: 07/13/2015 Version: 1.1 P GHS SDS Page 4 of 5
Graffiti Wipes
Safety Data Sheet
SECTION 15: Regulatory information
All components of this product are listed, or excluded from listing, on the United States Environmental Protection Agency Toxic Substances
Control Act (TSCA) inventory.

This product or mixture does not contain a toxic chemical or chemicals in excess of the applicable de minimis concentration as specified in 40
CFR §372.38(a) subject to the reporting requirements of section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986
and 40 CFR Part 372.

UNDECETH-5 (34398-01-1)

SARA Section 311/312 Hazard Classes Immediate (acute) health hazard

California Proposition 65 - This product does not contain substances known to the state of California to cause cancer and/or reproductive toxicity.

SECTION 16: Other information


Training advice : Normal use of this product shall imply use in accordance with the instructions on the packaging.

Full text of H-phrases:


------ Acute Tox. 4 (Inhalation) Acute toxicity (inhalation) Category 4
------ Acute Tox. 4 (Oral) Acute toxicity (oral) Category 4
------ Eye Dam. 1 Serious eye damage/eye irritation Category 1
------ Eye Irrit. 2A Serious eye damage/eye irritation Category 2A
------ H302 Harmful if swallowed
------ H318 Causes serious eye damage
------ H319 Causes serious eye irritation
------ H332 Harmful if inhaled

NFPA health hazard : 1 - Exposure could cause irritation but only minor residual injury even if no treatment is given.
NFPA fire hazard : 2 - Must be moderately heated or exposed to relatively high temperature before ignition can occur.
NFPA reactivity : 0 - Normally stable, even under fire exposure conditions, and are not reactive with water.

Prepared by: Technical Department

This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environme ntal requirements only. It should not therefore be construed as
guaranteeing any specific property of the product. No warranty is expressed or implied regarding the accuracy of this data or the results obtained from the use thereof. Our company assumes n o
responsibility for personal injury or property damage to the vendee, users or third parties caused by the material. Such vend ees or users assume all risks associated with the use of this material.

Date of issue: 7/13/2015 Revision date: 07/13/2015 Version: 1.1 P GHS SDS Page 5 of 5
Material Safety Data Sheet
HHS 5000 500ml
Version 4.1 Revision Date 08/20/2014 Print Date 08/23/2014

NFPA: Flammability HMIS III:


HEALTH 2*
4
Reactivity
Health

2 0 FLAMMABILITY 4
PHYSICAL 0
Specific Hazard 0 = Insignificant, 1 =Slight,
2 =Moderate, 3 =High, 4 = Extreme

SECTION 1. PRODUCT AND COMPANY IDENTIFICATION

Commercial Product : HHS 5000 500ml


Name
Product code : 893.1063
SDS-Identcode : 10033262
Product Use Description : Anti-friction agent and lubricant
Company : Würth Canada Limited
345 Hanlon Creek Blvd
GUELPH, ON N1C 0A1
Canada
Telephone : +1 (905) 564 6225
Telefax : +1 (905) 564 3671
Responsible/issuing : [email protected]
person
Emergency telephone : In case of emergency please contact: CANUTEC (5:00
number pm - 8:00 am):
+1 (613) 996 6666
WÜRTH CANADA LIMITED (8:00 am - 5:00 pm):
+1 (905) 564 6225

SECTION 2. HAZARDS IDENTIFICATION

Emergency Overview

Regulatory status : This product, material or substance is a WHMIS controlled


product per Sections 33 - 66, Part IV of the CPR.

Signal Word : DANGER


Form : aerosol
Colour : yellow

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Material Safety Data Sheet
HHS 5000 500ml
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Odour : characteristic
Odour - Control : No data available
parameters
Hazard Summary : Extremely flammable aerosol.
Compressed gas
May cause fire.
Pressurized container. Protect from sunlight and do not
expose to temperatures exceeding 50°C / 122 °F.
Irritant
Possible reproductive hazard

Potential Health Effects

Skin : May cause skin irritation.

Inhalation : Harmful if inhaled.


May be fatal if inhaled.
May cause drowsiness or dizziness.
May cause respiratory tract irritation.

Chronic Exposure : This product contains a material that may cause adverse
reproductive effects.*

Target Organs : Skin


Central nervous system
Respiratory system
Reproductive system

ACGIH : No component of this product present at levels greater


than or equal to 0.1% is identified as a carcinogen or
potential carcinogen by ACGIH.

NTP : No component of this product present at levels greater


than or equal to 0.1% is identified as a known or
anticipated carcinogen by NTP.

IARC : Hydrocarbons, C6-C7, n-alkanes, isoalkanes, cyclics, <5%


n-hexane (CAS-No.: 64742-49-0)
low boiling point hydrogen treated naphtha (CAS-No.:
64742-49-0)

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Material Safety Data Sheet
HHS 5000 500ml
Version 4.1 Revision Date 08/20/2014 Print Date 08/23/2014

OSHA : No component of this product present at levels greater


than or equal to 0.1% is identified as a carcinogen or
potential carcinogen by OSHA.

SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS

Component CAS-No. Weight percent-


Weight percent

isobutane 75-28-5 >= 45 - < 50


propane 74-98-6 >= 5 - < 7
butane 106-97-8 >= 2 - < 3
n-hexane 110-54-3 >= 0.2 - < 0.5

SECTION 4. FIRST AID MEASURES

General advice : If you feel unwell, seek medical advice (show the label
where possible). First aider needs to protect himself. Move
out of dangerous area. Never give anything by mouth to
an unconscious person. Take off contaminated clothing
and shoes immediately.
Inhalation : If breathed in, move person into fresh air. In the case of
inhalation of aerosol/mist consult a physician if necessary.
Keep patient warm and at rest. If not breathing, give
artificial respiration. If breathing is difficult, give oxygen.
Skin contact : In case of contact, immediately flush skin with soap and
plenty of water. Do NOT use solvents or thinners. If skin
irritation persists, call a physician. Wash off with
polyethylene glycol and afterwards with plenty of water.
Eye contact : Protect unharmed eye. If easy to do, remove contact
lens, if worn. In the case of contact with eyes, rinse
immediately with plenty of water and seek medical
advice.
Ingestion : If swallowed, seek medical advice immediately and show
this container or label. If swallowed, DO NOT induce
vomiting. If a person vomits when lying on his back, place
him in the recovery position.

SECTION 5. FIREFIGHTING MEASURES

Form : aerosol

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Material Safety Data Sheet
HHS 5000 500ml
Version 4.1 Revision Date 08/20/2014 Print Date 08/23/2014

Flash point : -24 °C (-11 °F)


Note: Active ingredient

Flammability : Extremely flammable aerosol.

Ignition temperature : 200 °C (392 °F)

Lower explosion limit : 1 %(V)

Upper explosion limit : 11 %(V)

Suitable extinguishing : Carbon dioxide (CO2)


media Foam
Dry powder

Unsuitable extinguishing : High volume water jet


media

Specific hazards during : Do not use a solid water stream as it may scatter and
firefighting spread fire.
Exposure to decomposition products may be a hazard to
health.

Special protective : In the event of fire, wear self-contained breathing


equipment for firefighters apparatus.
Use personal protective equipment.

Further information : Standard procedure for chemical fires.


Use extinguishing measures that are appropriate to local
circumstances and the surrounding environment.
In the event of fire and/or explosion do not breathe
fumes.
Use water spray to cool unopened containers.
Collect contaminated fire extinguishing water separately.
This must not be discharged into drains.
Fire residues and contaminated fire extinguishing water
must be disposed of in accordance with local
regulations.
If the temperature rises there is danger of the vessels
bursting due to the high vapor pressure.

4 / 13
Material Safety Data Sheet
HHS 5000 500ml
Version 4.1 Revision Date 08/20/2014 Print Date 08/23/2014

SECTION 6. ACCIDENTAL RELEASE MEASURES

Personal precautions : Refer to protective measures listed in sections 7 and 8.


Use personal protective equipment.
Remove all sources of ignition.
Avoid contact with skin and eyes.
Ensure adequate ventilation, especially in confined areas.
Contaminated surfaces will be extremely slippery.
Immediately evacuate personnel to safe areas.
Avoid inhalation of vapour or mist.
Beware of vapours accumulating to form explosive
concentrations. Vapours can accumulate in low areas.

Environmental : Do not flush into surface water or sanitary sewer system.


precautions Prevent further leakage or spillage if safe to do so.
If the product contaminates rivers and lakes or drains
inform respective authorities.
Avoid release to the environment. Refer to special
instructions/ Safety data sheets.

Methods for cleaning up : Contain and collect spillage with non-combustible


absorbent material, (e.g. sand, earth, diatomaceous
earth, vermiculite) and place in container for disposal
according to local / national regulations.
Clean contaminated surface thoroughly.

SECTION 7. HANDLING AND STORAGE

Handling
Handling : For personal protection see section 8.
Limit the stocks at work place.
Use only in well-ventilated areas.
Do not breathe vapours or spray mist.
Avoid contact with skin and eyes.
Do not spray on a naked flame or any incandescent
material.
Prevent the creation of flammable or explosive
concentrations of vapour in air and avoid vapour
concentration higher than the occupational exposure
limits.
Take precautionary measures against static discharges.
Do not carry cloths that have come into contact with the

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Material Safety Data Sheet
HHS 5000 500ml
Version 4.1 Revision Date 08/20/2014 Print Date 08/23/2014

product in your clothing.

Advice on protection : Normal measures for preventive fire protection.


against fire and explosion Vapours are heavier than air and may spread along
floors.
Vapours may form explosive mixtures with air.
Keep away from heat and sources of ignition.
Do not smoke.
No sparking tools should be used.
Electrical equipment should be protected to the
appropriate standard.

Dust explosion class : Not applicable

Storage
Requirements for storage : Store in original container.
areas and containers BEWARE: Aerosol is pressurized. Keep away from heat.
Keep away from direct sunlight. Do not open by force or
throw into fire even after use. Do not spray on flames or
red-hot objects.
Keep containers tightly closed in a cool, well-ventilated
place.
Please observe the storage instructions for aerosols!

Advice on common : Incompatible with oxidizing agents.


storage
Keep away from food, drink and animal feedingstuffs.
Do not store together with oxidizing and self-igniting
products.

Storage temperature : >= 10 °C (>= 50 °F)

Other data : No decomposition if stored and applied as directed.

SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Exposure Guidelines

Components CAS-No. List Type: Value Update


isobutane 75-28-5 CA BC OEL TWA 1,000 ppm 2006-11-29
CA AB OEL TWA 1,000 ppm 2009-04-30

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Material Safety Data Sheet
HHS 5000 500ml
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CA ON OEL TWA 800 ppm 2012-06-12


distillates (petroleum),
hydrotreated heavy 64742-54-7 CA BC OEL TWA 1 mg/m3 2012-04-20
paraffinic
CA AB OEL TWA 5 mg/m3 2009-04-30
CA AB OEL STEL 10 mg/m3 2009-04-30
CA QC OEL TWAEV 5 mg/m3 2012-11-28
CA QC OEL STEV 10 mg/m3 2012-11-28
Hydrocarbons, C6-C7, n-
alkanes, isoalkanes, cyclics, 64742-49-0 CA AB OEL TWA 5 mg/m3 2009-04-30
<5% n-hexane
CA AB OEL STEL 10 mg/m3 2009-04-30
CA QC OEL TWAEV 5 mg/m3 2012-11-28
CA QC OEL STEV 10 mg/m3 2012-11-28
Hydrocarbons, C7, n-
CA AB OEL TWA 5 mg/m3 2009-04-30
alkanes, isoalkanes, cyclics
CA AB OEL STEL 10 mg/m3 2009-04-30
CA QC OEL TWAEV 5 mg/m3 2012-11-28
CA QC OEL STEV 10 mg/m3 2012-11-28
propane 74-98-6 CA AB OEL TWA 1,000 ppm 2009-04-30
CA BC OEL TWA 1,000 ppm 2006-11-29
1,000 ppm
CA QC OEL TWAEV 2006-12-29
1,800 mg/m3
CA ON OEL TWA 1,000 ppm 2010-11-05
distillates (petroleum),
hydrotreated heavy 64742-54-7 CA BC OEL TWA 1 mg/m3 2012-04-20
paraffinic
CA AB OEL TWA 5 mg/m3 2009-04-30
CA AB OEL STEL 10 mg/m3 2009-04-30
CA QC OEL TWAEV 5 mg/m3 2012-11-28
CA QC OEL STEV 10 mg/m3 2012-11-28
butane 106-97-8 CA AB OEL TWA 1,000 ppm 2009-04-30
CA BC OEL TWA 600 ppm 2006-11-29
CA BC OEL STEL 750 ppm 2006-11-29
800 ppm 1,900
CA QC OEL TWAEV 2006-12-29
mg/m3
CA ON OEL TWA 800 ppm 2012-06-12

Engineering measures : Provide sufficient air exchange and/or exhaust in work


rooms.

Eye protection : Tightly fitting safety goggles

Hand protection
Glove material : Nitrile rubber

Choose gloves to protect hands against chemicals


depending on the concentration and quantity of the
hazardous substance and specific to place of work.
For special applications, we recommend clarifying the
resistance to chemicals of the aforementioned protective
gloves with the glove manufacturer.

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Material Safety Data Sheet
HHS 5000 500ml
Version 4.1 Revision Date 08/20/2014 Print Date 08/23/2014

Skin and body protection : Flame retardant antistatic protective clothing.


Choose body protection according to the amount and
concentration of the dangerous substance at the work
place.

Respiratory protection : In case of insufficient ventilation, wear suitable respiratory


equipment.
Respirator with filter type AX

Hygiene measures : Handle in accordance with good industrial hygiene and


safety practice.
General industrial hygiene practice.
Do not inhale aerosol.
Avoid contact with skin, eyes and clothing.
When using do not eat, drink or smoke.
Wash hands before breaks and at the end of workday.
Follow the skin protection plan.
Wash contaminated clothing before re-use.

SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

Form : aerosol
Colour : yellow
Odour : characteristic
Flash point : -24 °C (-11 °F)
Note: Active ingredient

Ignition temperature : 200 °C (392 °F)

Lower explosion limit : 1 %(V)

Upper explosion limit : 11 %(V)

Flammability : Extremely flammable aerosol.

pH : Not applicable

Boiling point/boiling range : -40 °C(-40 °F)

Density : 0.808 g/cm3


at 20 °C (68 °F)Active ingredient

Water solubility : insoluble

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Material Safety Data Sheet
HHS 5000 500ml
Version 4.1 Revision Date 08/20/2014 Print Date 08/23/2014

SECTION 10. STABILITY AND REACTIVITY

Conditions to avoid : Heat, flames and sparks.

Materials to avoid : Oxidizing agents


Avoid contact with other chemicals.

Hazardous decomposition : Build-up of dangerous/toxic fumes possible in cases of


products fire/high temperature.

Hazardous reactions : Vapours may form explosive mixtures with air.


If the temperature rises there is danger of the vessels
bursting due to the high vapor pressure.

Note: No decomposition if stored and applied as


directed.

SECTION 11. TOXICOLOGICAL INFORMATION

Carcinogenicity : No data is available on the product itself.


Reproductive toxicity : No data is available on the product itself.
Teratogenicity : No data is available on the product itself.

Component:
isobutane 75-28-5 Acute inhalation toxicity: LC50 Mouse
Dose: 1,237 mg/l

propane 74-98-6 Acute inhalation toxicity: LC50 Mouse


Dose: 1,237 mg/l

n-hexane 110-54-3 Acute oral toxicity: LD50 Rat


Dose: ca. 16 g/kg
Method: OECD Test Guideline 401

Acute dermal toxicity: LD50 Rabbit


Dose: > 3,350 mg/kg
Method: OECD Test Guideline 402

Acute inhalation toxicity: LC50


Dose: 259.354 mg/l 73860 ppm
Exposure time: 4 h
Method: OECD Test Guideline 403

Skin irritation: Rabbit


Result: irritating
Method: OECD Test Guideline 404

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Material Safety Data Sheet
HHS 5000 500ml
Version 4.1 Revision Date 08/20/2014 Print Date 08/23/2014

Eye irritation: Rabbit


Result: No eye irritation
Method: OECD Test Guideline 405

Reproductive toxicity: Suspected human reproductive


toxicant
Suspected of damaging fertility.

SECTION 12. ECOLOGICAL INFORMATION

Additional ecological : The product should not be allowed to enter drains, water
information courses or the soil.

Component:
isobutane 75-28-5 Toxicity to fish:
LC50
Species: Fish
Dose: 147.54 mg/l
Exposure time: 96 h

Acute and prolonged toxicity for aquatic invertebrates:


LC50
Species: Daphnia (water flea)
Dose: 46.6 mg/l
Exposure time: 48 h

propane 74-98-6 Toxicity to fish:


LC50
Species: Fish
Dose: 147.54 mg/l
Exposure time: 96 h

Acute and prolonged toxicity for aquatic invertebrates:


LC50
Species: Daphnia magna (Water flea)
Dose: 69.43 mg/l
Exposure time: 48 h

butane 106-97-8 Toxicity to fish:


LC50
Species: Fish
Dose: 24.11 mg/l
Exposure time: 96 h

Acute and prolonged toxicity for aquatic invertebrates:


LC50
Species: Daphnia magna (Water flea)
Dose: 14.22 mg/l
Exposure time: 48 h

10 / 13
Material Safety Data Sheet
HHS 5000 500ml
Version 4.1 Revision Date 08/20/2014 Print Date 08/23/2014

Toxicity to algae:
EC50
Species: Selenastrum capricornutum (green algae)
Dose: 7.71 mg/l
Exposure time: 96 h

n-hexane 110-54-3 Toxicity to fish:


LC50
Species: Oryzias latipes (Orange-red killifish)
Dose: > 1,000 µg/l
Exposure time: 48 h

Acute and prolonged toxicity for aquatic invertebrates:


EC50
Species: Daphnia magna (Water flea)
Dose: 30 mg/l
Exposure time: 48 h

Toxicity to algae:
ErC50
Species: Pseudokirchneriella subcapitata (algae)
Dose: 9.285 mg/l
Exposure time: 72 h
Calculation
Toxicity to algae:
Growth inhibitionNOEC
Species: Pseudokirchneriella subcapitata (algae)
Dose: 2.077 mg/l
Exposure time: 72 h
Method:
Calculation
Toxicity to bacteria:
EC50
Species: Bacteria
Dose: 48.396 mg/l
Exposure time: 48 h
Calculation
Toxicity to bacteria:
NOEC
Species: Bacteria
Dose: 10.82 mg/l
Exposure time: 48 h
Calculation

SECTION 13. DISPOSAL CONSIDERATIONS

Adequate disposal : In accordance with local and national regulations.


This material and its container must be disposed of as
hazardous waste.

11 / 13
Material Safety Data Sheet
HHS 5000 500ml
Version 4.1 Revision Date 08/20/2014 Print Date 08/23/2014

SECTION 14. TRANSPORT INFORMATION

DOT 49 CFR
ID No : UN 1950
Proper shipping name : Aerosols
Class : 2.1
Labels : 2.1
Emergency Response : 126
Guidebook Number

TDGR
ID No : UN 1950
Proper shipping name : AEROSOLS
Class : 2.1
Labels : 2.1

ICAO/IATA-DGR
ID No : UN 1950
Proper shipping name : Aerosols, flammable
Class : 2.1
ICAO-Labels : 2.1
Packing instruction (cargo : 203
aircraft)
Packing instruction : 203
(passenger aircraft)
Packing instruction : Y203
(passenger aircraft)
Environmentally hazardous : no

IMDG-Code
ID No : UN 1950
Description of the goods : AEROSOLS

Class : 2.1
IMDG-Labels : 2.1
EmS Number 1 : F-D
EmS Number 2 : S-U

Marine pollutant : no

SECTION 15. REGULATORY INFORMATION

WHMIS Classification : A Compressed Gas

12 / 13
Material Safety Data Sheet
HHS 5000 500ml
Version 4.1 Revision Date 08/20/2014 Print Date 08/23/2014

Compressed Gas

B5 Flammable aerosol
Flammable aerosol

D2B Toxic Material Causing Other Toxic Effects


Moderate skin irritant
Mild respiratory irritant

D2A Very Toxic Material Causing Other Toxic Effects


Reproductive hazard

This product has been classified according to the hazard criteria of the CPR and the MSDS
contains all of the information required by the CPR.

SECTION 16. OTHER INFORMATION

Further information
The information provided in this Safety Data Sheet is correct to the best of our knowledge,
information and belief at the date of its publication. The information given is designed only
as a guidance for safe handling, use, processing, storage, transportation, disposal and
release and is not to be considered a warranty or quality specification. The information
relates only to the specific material designated and may not be valid for such material used
in combination with any other materials or in any process, unless specified in the text.

Prepared by : SAP Business Compliance Services GmbH


Birlenbacher Str. 19
D-57078 Siegen
Germany
Telephone: +49-(0)271-88072-0
Revision Date : 08/20/2014

13 / 13
Material Safety Data Sheet
High Build Undercoat 550G. Paintable
Version 1.0 Revision Date 12/03/2014 Print Date 12/05/2014

NFPA: Flammability HMIS III:


HEALTH 3*
1
Reactivity
Health

2 0 FLAMMABILITY 1
PHYSICAL 0
Specific Hazard 0 = Insignificant, 1 =Slight,
2 =Moderate, 3 =High, 4 = Extreme

SECTION 1. PRODUCT AND COMPANY IDENTIFICATION

Commercial Product : High Build Undercoat 550G. Paintable


Name
Product code : 890.9072
SDS-Identcode : 10047413
Product Use Description : Colouring agents, dyes
Company : Würth Canada Limited
345 Hanlon Creek Blvd
GUELPH, ON N1C 0A1
Canada
Telephone : +1 (905) 564 6225
Telefax : +1 (905) 564 3671
Responsible/issuing : [email protected]
person
Emergency telephone : In case of emergency please contact: CANUTEC (5:00
number pm - 8:00 am):
+1 (613) 996 6666
WÜRTH CANADA LIMITED (8:00 am - 5:00 pm):
+1 (905) 564 6225

SECTION 2. HAZARDS IDENTIFICATION

Emergency Overview

Form : Aerosol containing a liquefied gas


Colour : black
Odour : solvent-like
Odour - Control : No data available
parameters
Hazard Summary : Extremely flammable aerosol.

1 / 12
Material Safety Data Sheet
High Build Undercoat 550G. Paintable
Version 1.0 Revision Date 12/03/2014 Print Date 12/05/2014

May cause fire.


Compressed gas
Pressurized container. Protect from sunlight and do not
expose to temperatures exceeding 50°C / 122 °F.
Irritant
Reproductive hazard
Possible cancer hazard - may cause cancer

Potential Health Effects

Target Organs : Liver


Kidney
Eyes
Skin
Central nervous system

Eyes : May cause eye irritation.

Skin : May cause skin irritation.


Prolonged or repeated contact may dry skin and cause
irritation.

Inhalation : Harmful if inhaled.


May be fatal if inhaled.
May cause drowsiness or dizziness.

Chronic Exposure : This product contains a material that may cause adverse
reproductive effects.*

ACGIH : Carbon black (CAS-No.: 1333-86-4)


distillates (petroleum), hydrotreated light (CAS-No.:
64742-47-8)

NTP : No component of this product present at levels greater


than or equal to 0.1% is identified as a known or
anticipated carcinogen by NTP.

IARC : Titanium dioxide (CAS-No.: 13463-67-7)


Carbon black (CAS-No.: 1333-86-4)

2 / 12
Material Safety Data Sheet
High Build Undercoat 550G. Paintable
Version 1.0 Revision Date 12/03/2014 Print Date 12/05/2014

OSHA : No component of this product present at levels greater


than or equal to 0.1% is identified as a carcinogen or
potential carcinogen by OSHA.

SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS

Component CAS-No. Weight percent-


Weight percent

tert-butyl acetate 540-88-5 >= 55 - < 60


toluene 108-88-3 >= 25 - < 35
propane 74-98-6 >= 7 - < 10
isobutane 75-28-5 >= 3 - < 5
Carbon black 1333-86-4 >= 0.75 - < 1

SECTION 4. FIRST AID MEASURES

General advice : In the case of accident or if you feel unwell, seek medical
advice immediately (show the label where possible). First
aider needs to protect himself. Move out of dangerous
area. Never give anything by mouth to an unconscious
person. Take off contaminated clothing and shoes
immediately.
Inhalation : If breathed in, move person into fresh air. Call a physician
immediately. Keep patient warm and at rest. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen.
Skin contact : In case of contact, immediately flush skin with soap and
plenty of water. Do NOT use solvents or thinners. If skin
irritation persists, call a physician.
Eye contact : Protect unharmed eye. If easy to do, remove contact
lens, if worn. Rinse with water. Get medical attention.
Ingestion : If swallowed, seek medical advice immediately and show
this container or label. If swallowed, DO NOT induce
vomiting. If a person vomits when lying on his back, place
him in the recovery position. Get medical attention.

SECTION 5. FIREFIGHTING MEASURES

Form : Aerosol containing a liquefied gas


Ignition temperature : 450 °C (842 °F)
3 / 12
Material Safety Data Sheet
High Build Undercoat 550G. Paintable
Version 1.0 Revision Date 12/03/2014 Print Date 12/05/2014

Lower explosion limit : 2.1 %(V)

Upper explosion limit : 9.5 %(V)

Suitable extinguishing : Foam


media Alcohol-resistant foam
Dry chemical
Water mist

Specific hazards during : Do not use a solid water stream as it may scatter and
firefighting spread fire.
Hazardous decomposition products may be formed
under fire conditions (see section 10).
Exposure to decomposition products may be a hazard to
health.

Special protective : In the event of fire, wear self-contained breathing


equipment for firefighters apparatus.
Use personal protective equipment.

Further information : Standard procedure for chemical fires.


Use extinguishing measures that are appropriate to local
circumstances and the surrounding environment.
In the event of fire and/or explosion do not breathe
fumes.
Use water spray to cool unopened containers.
Collect contaminated fire extinguishing water separately.
This must not be discharged into drains.
Fire residues and contaminated fire extinguishing water
must be disposed of in accordance with local
regulations.
If the temperature rises there is danger of the vessels
bursting due to the high vapor pressure.

SECTION 6. ACCIDENTAL RELEASE MEASURES

Personal precautions : Refer to protective measures listed in sections 7 and 8.


Use personal protective equipment.
Remove all sources of ignition.
Avoid contact with skin and eyes.
4 / 12
Material Safety Data Sheet
High Build Undercoat 550G. Paintable
Version 1.0 Revision Date 12/03/2014 Print Date 12/05/2014

Ensure adequate ventilation, especially in confined areas.


Immediately evacuate personnel to safe areas.
Avoid inhalation of vapour or mist.
Beware of vapours accumulating to form explosive
concentrations. Vapours can accumulate in low areas.

Environmental : Do not flush into surface water or sanitary sewer system.


precautions Prevent further leakage or spillage if safe to do so.
If the product contaminates rivers and lakes or drains
inform respective authorities.

Methods for cleaning up : Contain and collect spillage with non-combustible


absorbent material, (e.g. sand, earth, diatomaceous
earth, vermiculite) and place in container for disposal
according to local / national regulations.
Clean contaminated surface thoroughly.

SECTION 7. HANDLING AND STORAGE

Handling
Handling : For personal protection see section 8.
Limit the stocks at work place.
Use only in well-ventilated areas.
Do not breathe vapours or spray mist.
Avoid contact with skin and eyes.
Do not spray on a naked flame or any incandescent
material.
Prevent the creation of flammable or explosive
concentrations of vapour in air and avoid vapour
concentration higher than the occupational exposure
limits.
Take precautionary measures against static discharges.
Handle with care.

Advice on protection : Normal measures for preventive fire protection.


against fire and explosion Vapours are heavier than air and may spread along
floors.
Vapours may form explosive mixtures with air.
Keep away from heat and sources of ignition.
Do not smoke.
No sparking tools should be used.
Electrical equipment should be protected to the
appropriate standard.

5 / 12
Material Safety Data Sheet
High Build Undercoat 550G. Paintable
Version 1.0 Revision Date 12/03/2014 Print Date 12/05/2014

Dust explosion class : Not applicable

Storage
Requirements for storage : Store in a place accessible by authorized persons only.
areas and containers Store in original container.
BEWARE: Aerosol is pressurized. Keep away from heat.
Keep away from direct sunlight. Do not open by force or
throw into fire even after use. Do not spray on flames or
red-hot objects.
Keep containers tightly closed in a cool, well-ventilated
place.
Please observe the storage instructions for aerosols!

Advice on common : Incompatible with oxidizing agents.


storage Keep away from reducing agents.

Keep away from food, drink and animal feedingstuffs.


Do not store together with oxidizing and self-igniting
products.

Other data : No decomposition if stored and applied as directed.

SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Exposure Guidelines

Components CAS-No. List Type: Value Update


200 ppm 950
tert-butyl acetate 540-88-5 CA AB OEL TWA 2007-01-01
mg/m3
CA BC OEL TWA 200 ppm 2006-11-29
200 ppm 950
CA QC OEL TWAEV 2006-12-29
mg/m3
50 ppm 188
toluene 108-88-3 CA AB OEL TWA 2007-01-01
mg/m3
CA BC OEL TWA 20 ppm 2009-02-09
50 ppm 188
CA QC OEL TWAEV 2006-12-29
mg/m3
propane 74-98-6 CA AB OEL TWA 1,000 ppm 2009-04-30
CA BC OEL TWA 1,000 ppm 2006-11-29
1,000 ppm
CA QC OEL TWAEV 2006-12-29
1,800 mg/m3
CA ON OEL TWA 1,000 ppm 2010-11-05
Calcium carbonate 1317-65-3 CA AB OEL TWA 10 mg/m3 2009-04-30
CA BC OEL TWA 10 mg/m3 2006-11-29

6 / 12
Material Safety Data Sheet
High Build Undercoat 550G. Paintable
Version 1.0 Revision Date 12/03/2014 Print Date 12/05/2014

CA BC OEL STEL 20 mg/m3 2006-11-29


CA QC OEL TWAEV 10 mg/m3 2012-11-28
isobutane 75-28-5 CA BC OEL TWA 1,000 ppm 2006-11-29
CA AB OEL TWA 1,000 ppm 2009-04-30
CA ON OEL TWA 800 ppm 2012-06-12
Hydrocarbons, C11-C14, n-
alkanes, isoalkanes, cyclics, 64742-47-8 CA BC OEL TWA 200 mg/m3 2006-11-29
<2% aromatics
CA QC OEL TWAEV 5 mg/m3 2006-12-29
CA QC OEL STEV 10 mg/m3 2006-12-29
CA ON OEL TWA 525 mg/m3 2010-11-05
CA AB OEL TWA 200 mg/m3 2009-04-30
CA AB OEL TWA 5 mg/m3 2009-04-30
CA AB OEL STEL 10 mg/m3 2009-04-30
CA QC OEL TWAEV 5 mg/m3 2012-11-28
CA QC OEL STEV 10 mg/m3 2012-11-28
Carbon black 1333-86-4 CA AB OEL TWA 3.5 mg/m3 2007-01-01
CA QC OEL TWAEV 3.5 mg/m3 2006-12-29
CA BC OEL TWA 3 mg/m3 2011-09-15

Engineering measures : Provide sufficient air exchange and/or exhaust in work


rooms.

Eye protection : Tightly fitting safety goggles

Hand protection : Choose gloves to protect hands against chemicals


depending on the concentration and quantity of the
hazardous substance and specific to place of work.
For special applications, we recommend clarifying the
resistance to chemicals of the aforementioned protective
gloves with the glove manufacturer.

Skin and body protection : Flame retardant antistatic protective clothing.


Choose body protection according to the amount and
concentration of the dangerous substance at the work
place.

Respiratory protection : When workers are facing concentrations above the


exposure limit they must use appropriate certified
respirators.
Product contains low-boiling liquids. Respiratory
protective equipment must be air supplied respirators.

Hygiene measures : Handle in accordance with good industrial hygiene and


safety practice.
General industrial hygiene practice.
Do not inhale aerosol.
Avoid contact with skin, eyes and clothing.
When using do not eat, drink or smoke.

7 / 12
Material Safety Data Sheet
High Build Undercoat 550G. Paintable
Version 1.0 Revision Date 12/03/2014 Print Date 12/05/2014

Wash hands before breaks and at the end of workday.


Follow the skin protection plan.
Take off all contaminated clothing immediately.
Wash contaminated clothing before re-use.

SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

Form : Aerosol containing a liquefied gas


Colour : black
Odour : solvent-like
Ignition temperature : 450 °C (842 °F)

Lower explosion limit : 2.1 %(V)

Upper explosion limit : 9.5 %(V)

pH : Not applicable

Boiling point/boiling range : >98 °C(208 °F)

Vapour pressure : 3.79 - 4.14 bar


at 20 °C (68 °F)

Relative vapour density : >1


(Air = 1.0)

Density : 0.90 g/cm3


at 25 °C (77 °F)
Water solubility : insoluble

Volatile organic : 29.5 %


compounds (VOC) content 265.35 g/l

SECTION 10. STABILITY AND REACTIVITY

Conditions to avoid : Heat, flames and sparks.

Materials to avoid : Strong oxidizing agents


Reducing agents
hydrides

Hazardous decomposition : Carbon oxides

8 / 12
Material Safety Data Sheet
High Build Undercoat 550G. Paintable
Version 1.0 Revision Date 12/03/2014 Print Date 12/05/2014

products Smoke
Hydrocarbons

Build-up of dangerous/toxic fumes possible in cases of


fire/high temperature.

Hazardous reactions : Note: No decomposition if stored and applied as


directed.

Vapours may form explosive mixtures with air.


If the temperature rises there is danger of the vessels
bursting due to the high vapor pressure.

SECTION 11. TOXICOLOGICAL INFORMATION

Carcinogenicity : No data is available on the product itself.


Reproductive toxicity : No data is available on the product itself.
Teratogenicity : No data is available on the product itself.
Further information : Symptoms of overexposure may be headache, dizziness,
tiredness, nausea and vomiting.
Vapours may cause drowsiness and dizziness.

Component:
toluene 108-88-3 Acute oral toxicity: LD50 Rat
Dose: 5,580 mg/kg

Acute dermal toxicity: LD50 Rabbit


Dose: ca. 12,267 mg/kg

Acute inhalation toxicity: LC50 Rat


Dose: >= 28.1 mg/lExposure time: 4 h
Method: OECD Test Guideline 403

Skin irritation: Rabbit


Result: irritating

Eye irritation: Rabbit


Result: No eye irritation
Method: OECD Test Guideline 405

Reproductive toxicity: Suspected human reproductive


toxicant, Suspected of damaging the unborn child.

isobutane 75-28-5 Acute inhalation toxicity: LC50 Mouse


Dose: 1,237 mg/lExposure time: 120 min

Mutagenicity: Tests on bacterial or mammalian cell


cultures did not show mutagenic effects.
9 / 12
Material Safety Data Sheet
High Build Undercoat 550G. Paintable
Version 1.0 Revision Date 12/03/2014 Print Date 12/05/2014

Reproductive toxicity: No toxicity to reproduction

Carbon black 1333-86-4 Eye irritation: Result: irritating

SECTION 12. ECOLOGICAL INFORMATION

Volatile organic : 29.5 %


compounds (VOC)
content
Additional ecological : The product should not be allowed to enter drains, water
information courses or the soil.

Component:
toluene 108-88-3 Toxicity to fish:
LC50
Species: Oncorhynchus kisutch (coho salmon)
Dose: 5.5 mg/l
Exposure time: 96 h

Acute and prolonged toxicity for aquatic invertebrates:


EC50
Species: Ceriodaphnia dubia (water flea)
Dose: 3.78 mg/l
Exposure time: 48 h

Toxicity to algae:
EC50
Species: Chlorella vulgaris (Fresh water algae)
Dose: 134 mg/l
Exposure time: 3 h

Toxicity to bacteria:
EC50
Species: Bacteria
Dose: 84 mg/l
Exposure time: 24 h

SECTION 13. DISPOSAL CONSIDERATIONS

Adequate disposal : In accordance with local and national regulations.

SECTION 14. TRANSPORT INFORMATION

10 / 12
Material Safety Data Sheet
High Build Undercoat 550G. Paintable
Version 1.0 Revision Date 12/03/2014 Print Date 12/05/2014

DOT 49 CFR
ID No : UN 1950
Proper shipping name : Aerosols
Class : 2.1
Labels : 2.1
Emergency Response : 126
Guidebook Number

TDGR
ID No : UN 1950
Proper shipping name : AEROSOLS
Class : 2.1
Labels : 2.1

ICAO/IATA-DGR
ID No : UN 1950
Proper shipping name : Aerosols, flammable
Class : 2.1
ICAO-Labels : 2.1
Packing instruction (cargo : 203
aircraft)
Packing instruction : 203
(passenger aircraft)
Packing instruction : Y203
(passenger aircraft)
Environmentally hazardous : no

IMDG-Code
ID No : UN 1950
Description of the goods : AEROSOLS

Class : 2.1
IMDG-Labels : 2.1
EmS Number 1 : F-D
EmS Number 2 : S-U

Marine pollutant : no

SECTION 15. REGULATORY INFORMATION

WHMIS Classification : A Compressed Gas


B1 Flammable gas
D2A Very Toxic Material Causing Other Toxic Effects
D2B Toxic Material Causing Other Toxic Effects

11 / 12
Material Safety Data Sheet
High Build Undercoat 550G. Paintable
Version 1.0 Revision Date 12/03/2014 Print Date 12/05/2014

Compressed Gas
Flammable gas
Carcinogen
Reproductive hazard
Moderate skin irritant

This product has been classified according to the hazard criteria of the CPR and the MSDS
contains all of the information required by the CPR.

SECTION 16. OTHER INFORMATION

Further information
The information provided in this Safety Data Sheet is correct to the best of our knowledge,
information and belief at the date of its publication. The information given is designed only
as a guidance for safe handling, use, processing, storage, transportation, disposal and
release and is not to be considered a warranty or quality specification. The information
relates only to the specific material designated and may not be valid for such material used
in combination with any other materials or in any process, unless specified in the text.

Prepared by : SAP Business Compliance Services GmbH


Birlenbacher Str. 19
D-57078 Siegen
Germany
Telephone: +49-(0)271-88072-0
Revision Date : 12/03/2014

12 / 12
JOHNSEN'S BRAKE CLEANER 16 OZ.
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
Revision date: 08/19/2014 : Version:

SECTION 1: Identification of the substance/mixture and of the company/undertaking


1.1. Product identifier
Product form : Mixture
Trade name : JOHNSEN'S BRAKE CLEANER 16 OZ.
Product code : 2420
1.2. Relevant identified uses of the substance or mixture and uses advised against
Use of the substance/mixture : Brake Parts Cleaner
1.3. Details of the supplier of the safety data sheet
Technical Chemical Company
P.O. BOX 139
Cleburne, Texas 76033
T 817-645-6088
1.4. Emergency telephone number
Emergency number : CHEMTREC 24 Hour 1-800-424-9300, 1-703-527-3887 (International)

SECTION 2: Hazards identification


2.1. Classification of the substance or mixture
Classification (GHS-US)
Compressed gas H280
Acute Tox. 4 (Inhalation) H332
Acute Tox. 4 (Inhalation:gas) H332
Eye Irrit. 2B H320
Carc. 1B H350
Full text of H-phrases: see section 16

2.2. Label elements


GHS-US labeling
Hazard pictograms (GHS-US) :

GHS04 GHS07 GHS08


Signal word (GHS-US) : Danger
Hazard statements (GHS-US) : H280 - Contains gas under pressure; may explode if heated
H320 - Causes eye irritation
H332 - Harmful if inhaled
H350 - May cause cancer
Precautionary statements (GHS-US) : P201 - Obtain special instructions
P202 - Do not handle until all safety precautions have been read and understood
P261 - Avoid breathing dust,fume,gas,mist,vapor spray
P264 - Wash affected areas thoroughly after handling
P271 - Use only outdoors or in a well-ventilated area
P280 - Wear protective gloves,protective clothing,eye protection,face protection
P304+P340 - If inhaled: Remove person to fresh air and keep comfortable for breathing
P305+P351+P338 - If in eyes: Rinse cautiously with water for several minutes. Remove contact
lenses, if present and easy to do. Continue rinsing
P308+P313 - If exposed or concerned: Get medical advice/attention
P312 - Call a POISON CONTROL CENTER, doctor, if you feel unwell.
P337+P313 - If eye irritation persists: Get medical advice/attention
P405 - Store locked up
P410+P403 - Protect from sunlight. Store in a well-ventilated place
P501 - Dispose of contents/container to appropriate waste disposal facility, in accordance with
local, regional, national, international regulations.
2.3. Other hazards
Other hazards not contributing to the : Contains gas under pressure; may explode if heated.
classification
2.4. Unknown acute toxicity (GHS-US)
No data available

13/02/2015 EN (English US) 1/9


JOHNSEN'S BRAKE CLEANER 16 OZ.
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations

SECTION 3: Composition/information on ingredients


3.1. Substance
Not applicable
3.2. Mixture
Name Product identifier % Classification (GHS-US)
Tetrachloroethylene (CAS No) 127-18-4 >= 95 Carc. 1B, H350
Aquatic Chronic 2, H411
Carbon Dioxide, Liquefied, Under Pressure (CAS No) 124-38-9 1-5 Compressed gas, H280
The exact percentage is a trade secret.

SECTION 4: First aid measures


4.1. Description of first aid measures
First-aid measures general : Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice
(show the label where possible).
First-aid measures after inhalation : Allow victim to breathe fresh air. Allow the victim to rest. Remove victim to fresh air and keep at
rest in a position comfortable for breathing. Call a POISON CENTER or doctor/physician if you
feel unwell.
First-aid measures after skin contact : Remove affected clothing and wash all exposed skin area with mild soap and water, followed by
warm water rinse.
First-aid measures after eye contact : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present
and easy to do. Continue rinsing.
First-aid measures after ingestion : Rinse mouth. Do NOT induce vomiting. Obtain emergency medical attention.
4.2. Most important symptoms and effects, both acute and delayed
Symptoms/injuries : May cause cancer.
Symptoms/injuries after inhalation : Danger of serious damage to health by prolonged exposure through inhalation. Harmful if
inhaled.
Symptoms/injuries after skin contact : May cause slight irritation . Itching. Skin rash/inflammation. Red skin.
Symptoms/injuries after eye contact : Irritation of the eye tissue. Inflammation/damage of the eye tissue. Redness of the eye tissue.
Causes eye irritation.
Symptoms/injuries after ingestion : May be harmful if swallowed and enters airways. May be fatal if swallowed and enters airways.
4.3. Indication of any immediate medical attention and special treatment needed
No additional information available

SECTION 5: Firefighting measures


5.1. Extinguishing media
Suitable extinguishing media : Foam. Dry powder. Carbon dioxide. Water spray. Sand.
Unsuitable extinguishing media : Do not use a heavy water stream.
5.2. Special hazards arising from the substance or mixture
Fire hazard : Not flammable.
5.3. Advice for firefighters
Firefighting instructions : Use water spray or fog for cooling exposed containers. Exercise caution when fighting any
chemical fire. Prevent fire-fighting water from entering environment.
Protection during firefighting : Do not enter fire area without proper protective equipment, including respiratory protection.
Other information : NFPA Aerosol Level 1.

SECTION 6: Accidental release measures


6.1. Personal precautions, protective equipment and emergency procedures
General measures : Remove ignition sources.

6.1.1. For non-emergency personnel


Protective equipment : Gloves. Safety glasses.
Emergency procedures : Evacuate unnecessary personnel.

6.1.2. For emergency responders


Protective equipment : Equip cleanup crew with proper protection.
Emergency procedures : Ventilate area.
6.2. Environmental precautions
Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters.

13/02/2015 EN (English US) 2/9


JOHNSEN'S BRAKE CLEANER 16 OZ.
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations

6.3. Methods and material for containment and cleaning up


For containment : Dam up the liquid spill. Contain released substance, pump into suitable containers. Plug the leak,
cut off the supply.
Methods for cleaning up : Store away from other materials.
6.4. Reference to other sections
See Heading 8. Exposure controls and personal protection.

SECTION 7: Handling and storage


7.1. Precautions for safe handling
Precautions for safe handling : Wash hands and other exposed areas with mild soap and water before eating, drinking or
smoking and when leaving work. Provide good ventilation in process area to prevent formation of
vapor. Use only outdoors or in a well-ventilated area. Avoid breathing dust,fume,gas,mist,vapor
spray. Obtain special instructions . Do not handle until all safety precautions have been read and
understood.
Hygiene measures : Wash hands and other exposed areas with mild soap and water before eating, drinking or
smoking and when leaving work. Do not eat, drink or smoke when using this product. Wash
affected areas thoroughly after handling. Wash contaminated clothing before reuse.
7.2. Conditions for safe storage, including any incompatibilities
Technical measures : Proper grounding procedures to avoid static electricity should be followed. Comply with
applicable regulations.
Storage conditions : Keep only in the original container in a cool, well ventilated place away from : Keep container
closed when not in use.
Incompatible products : Strong bases. Strong acids.
Incompatible materials : Sources of ignition. Direct sunlight.
Storage area : Store in a well-ventilated place.
7.3. Specific end use(s)
Follow Label Directions.

SECTION 8: Exposure controls/personal protection


8.1. Control parameters

Tetrachloroethylene (127-18-4)
USA ACGIH ACGIH TWA (mg/m³) 170 mg/m³
USA ACGIH ACGIH TWA (ppm) 25 ppm
USA ACGIH ACGIH STEL (mg/m³) 685 mg/m³
USA ACGIH ACGIH STEL (ppm) 100 ppm
USA OSHA OSHA PEL (TWA) (ppm) 100 ppm
USA OSHA OSHA PEL (Ceiling) (ppm) 200 ppm

Carbon Dioxide, Liquefied, Under Pressure (124-38-9)


USA ACGIH ACGIH TWA (mg/m³) 9000 mg/m³
USA ACGIH ACGIH TWA (ppm) 5000 ppm
USA ACGIH ACGIH STEL (mg/m³) 54000
USA ACGIH ACGIH STEL (ppm) 30000 ppm
USA OSHA OSHA PEL (TWA) (mg/m³) 9000 mg/m³
USA OSHA OSHA PEL (TWA) (ppm) 5000 ppm

8.2. Exposure controls


Appropriate engineering controls : Local exhaust venilation, vent hoods . Ensure good ventilation of the work station.
Personal protective equipment : Gloves. Safety glasses. Avoid all unnecessary exposure.

Hand protection : Wear protective gloves.


Eye protection : Chemical goggles or safety glasses.
Skin and body protection : Wear suitable protective clothing.
Respiratory protection : Wear appropriate mask.
Other information : Do not eat, drink or smoke during use.
13/02/2015 EN (English US) 3/9
JOHNSEN'S BRAKE CLEANER 16 OZ.
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations

SECTION 9: Physical and chemical properties


9.1. Information on basic physical and chemical properties
Physical state : Gas
Appearance : Liquid.
Molecular mass : 165.83 g/mol
Color : Colourless.
Odor : Sweet odour. Ether-like odour.
Odor threshold : 2.0 - 71 ppm
pH : 6.8 - 8.4
Relative evaporation rate (butyl acetate=1) : 2
Relative evaporation rate (ether=1) : 8
Melting point : -22 °C
Freezing point : No data available
Boiling point : 121 °C
Flash point : None
Critical temperature : 347 °C
Auto-ignition temperature : No data available
Decomposition temperature : > 150 °C
Flammability (solid, gas) : No data available
Vapor pressure : 19 hPa
Vapor pressure at 50 °C : 82 hPa
Relative vapor density at 20 °C : 5.8
Relative density : 1.62
Relative density of saturated gas/air mixture : 1.1
Specific gravity / density : 1623 kg/m³
Solubility : Insoluble in water. Substance sinks in water. Soluble in ethanol. Soluble in ether. Soluble in
acetone. Soluble in chloroform. Soluble in tetrachloromethane. Soluble in hexane. Soluble in
oils/fats.
Water: 0.015 g/100ml
Ethanol: soluble
Ether: soluble
Acetone: > 10 g/100ml
Log Pow : 3.40 (Experimental value; 2.53; Experimental value; Equivalent or similar to OECD 107; 23 °C)
Log Kow : No data available
Viscosity, kinematic : 0.555 mm²/s (20 °C)
Viscosity, dynamic : No data available
Explosive properties : No data available
Oxidizing properties : No data available
Explosive limits : No data available
9.2. Other information
Saturation concentration : 127 g/m³
VOC content : 0%

SECTION 10: Stability and reactivity


10.1. Reactivity
No additional information available
10.2. Chemical stability
Not established.
10.3. Possibility of hazardous reactions
Not established.
10.4. Conditions to avoid
Direct sunlight. Extremely high or low temperatures.
10.5. Incompatible materials
Strong acids. Strong bases.
10.6. Hazardous decomposition products
Toxic fume. . Carbon monoxide. Carbon dioxide.

13/02/2015 EN (English US) 4/9


JOHNSEN'S BRAKE CLEANER 16 OZ.
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations

SECTION 11: Toxicological information


11.1. Information on toxicological effects

Acute toxicity : Harmful if inhaled. Harmful if inhaled.


JOHNSEN'S BRAKE CLEANER 16 OZ.
LD50 oral rat 3835 mg/kg body weight
LD50 dermal rabbit > 3000 mg/kg (Rabbit; Literature study; >10000 mg/kg bodyweight; Rabbit; Experimental
value)
LC50 inhalation rat (mg/l) 27.58 mg/l/4h (Rat; Literature study)
LC50 inhalation rat (ppm) 5200 ppm/4h (Rat; Experimental value)

Tetrachloroethylene (127-18-4)
LD50 oral rat > 2000 mg/kg (Rat; Equivalent or similar to OECD 401; Literature study; 3835 mg/kg
bodyweight; Rat; Equivalent or similar to OECD 401; Experimental value; 3005 mg/kg
bodyweight; Rat; Experimental value)
LD50 dermal rabbit > 3000 mg/kg (Rabbit; Literature study; >10000 mg/kg bodyweight; Rabbit; Experimental
value)
LC50 inhalation rat (mg/l) 27.58 mg/l/4h (Rat; Literature study)
LC50 inhalation rat (ppm) 3786 ppm/4h (Rat; Experimental value)
Skin corrosion/irritation : Not classified
pH: 6.8 - 8.4
Serious eye damage/irritation : Causes eye irritation.
pH: 6.8 - 8.4
Respiratory or skin sensitization : Not classified
Germ cell mutagenicity : Not classified
Carcinogenicity : May cause cancer.
JOHNSEN'S BRAKE CLEANER 16 OZ.
IARC group 2A

Tetrachloroethylene (127-18-4)
IARC group 2A
Reproductive toxicity : Not classified
Specific target organ toxicity (single exposure) : Not classified
Specific target organ toxicity (repeated : Not classified
exposure)
Aspiration hazard : Not classified
Potential Adverse human health effects and : Based on available data, the classification criteria are not met. Harmful if inhaled.
symptoms
Symptoms/injuries after inhalation : Danger of serious damage to health by prolonged exposure through inhalation. Harmful if
inhaled.
Symptoms/injuries after skin contact : May cause slight irritation . Itching. Skin rash/inflammation. Red skin.
Symptoms/injuries after eye contact : Irritation of the eye tissue. Inflammation/damage of the eye tissue. Redness of the eye tissue.
Causes eye irritation.
Symptoms/injuries after ingestion : May be harmful if swallowed and enters airways. May be fatal if swallowed and enters airways.

SECTION 12: Ecological information


12.1. Toxicity
Ecology - general : Dangerous for the environment.
Ecology - air : Not classified as dangerous for the ozone layer (Regulation (EC) No 1005/2009). Not included in
the list of fluorinated greenhouse gases (Regulation (EC) No 842/2006). TA-Luft Klasse 5.2.5/I.
JOHNSEN'S BRAKE CLEANER 16 OZ.
LC50 fish 1 4.99 mg/l (96 h; Salmo gairdneri (Oncorhynchus mykiss); Locomotor effect)
EC50 Daphnia 1 8.5 mg/l (48 h; Daphnia magna; Locomotor effect)
LC50 fish 2 13 mg/l (96 h; Lepomis macrochirus)

Tetrachloroethylene (127-18-4)
LC50 fish 1 4.99 mg/l (96 h; Salmo gairdneri (Oncorhynchus mykiss); Locomotor effect)
EC50 Daphnia 1 8.5 mg/l (48 h; Daphnia magna; Locomotor effect)
LC50 fish 2 13 mg/l (96 h; Lepomis macrochirus)
Threshold limit algae 1 816 mg/l (96 h; Selenastrum capricornutum; Cell numbers)
Threshold limit algae 2 3.64 mg/l (72 h; Chlamydomonas angulosa; Growth rate)

13/02/2015 EN (English US) 5/9


JOHNSEN'S BRAKE CLEANER 16 OZ.
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations

Carbon Dioxide, Liquefied, Under Pressure (124-38-9)


LC50 fish 1 35 mg/l (96 h; Salmo gairdneri (Oncorhynchus mykiss); Lethal)
LC50 fish 2 60 - 240 mg/l (12 h; Salmo gairdneri (Oncorhynchus mykiss); Lethal)

12.2. Persistence and degradability


JOHNSEN'S BRAKE CLEANER 16 OZ.
Persistence and degradability Not readily biodegradable in water. Low potential for adsorption in soil.
Biochemical oxygen demand (BOD) 0.06 g O₂ /g substance
ThOD 0.39 g O₂ /g substance
BOD (% of ThOD) 0.15 % ThOD

Tetrachloroethylene (127-18-4)
Persistence and degradability Not readily biodegradable in water. Low potential for adsorption in soil.
Biochemical oxygen demand (BOD) 0.06 g O₂ /g substance
ThOD 0.39 g O₂ /g substance
BOD (% of ThOD) 0.15 % ThOD

Carbon Dioxide, Liquefied, Under Pressure (124-38-9)


Persistence and degradability Biodegradability: not applicable. Not applicable (gas).
Biochemical oxygen demand (BOD) Not applicable
Chemical oxygen demand (COD) Not applicable
ThOD Not applicable
BOD (% of ThOD) Not applicable

12.3. Bioaccumulative potential


JOHNSEN'S BRAKE CLEANER 16 OZ.
BCF fish 1 40 - 115 Salmo gairdneri (Oncorhynchus mykiss)
BCF fish 2 25.8 - 77.1 (8 weeks; Cyprinus carpio)
BCF other aquatic organisms 1 63 (Modiolus modiolus; Mantle, dry weight)
BCF other aquatic organisms 2 39 (Buccinum undatum; Muscles, dry weight)
Log Pow 3.40 (Experimental value; 2.53; Experimental value; Equivalent or similar to OECD 107; 23 °C)
Bioaccumulative potential Low potential for bioaccumulation (BCF < 500).

Tetrachloroethylene (127-18-4)
BCF fish 1 40 - 115 Salmo gairdneri (Oncorhynchus mykiss)
BCF fish 2 25.8 - 77.1 (8 weeks; Cyprinus carpio)
BCF other aquatic organisms 1 63 (Modiolus modiolus; Mantle, dry weight)
BCF other aquatic organisms 2 39 (Buccinum undatum; Muscles, dry weight)
Log Pow 3.40 (Experimental value; 2.53; Experimental value; Equivalent or similar to OECD 107; 23 °C)
Bioaccumulative potential Low potential for bioaccumulation (BCF < 500).

Carbon Dioxide, Liquefied, Under Pressure (124-38-9)


Log Pow 0.83 (Experimental value)
Bioaccumulative potential Bioaccumulation: not applicable.

12.4. Mobility in soil


JOHNSEN'S BRAKE CLEANER 16 OZ.
Surface tension 0.0313 N/m (20 °C)

Tetrachloroethylene (127-18-4)
Surface tension 0.0313 N/m (20 °C)

12.5. Other adverse effects


Other information : Avoid release to the environment.

SECTION 13: Disposal considerations


13.1. Waste treatment methods
Waste disposal recommendations : Dispose in a safe manner in accordance with local/national regulations. Dispose of
contents/container to appropriate waste disposal facility, in accordance with local, regional,
national, international regulations.
Ecology - waste materials : Avoid release to the environment.

13/02/2015 EN (English US) 6/9


JOHNSEN'S BRAKE CLEANER 16 OZ.
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations

SECTION 14: Transport information


In accordance with ADR / RID / IMDG / IATA / ADN
US DOT (ground): UN1950, Aerosols, 2.2, Limited Quantity
ICAO/IATA (air): UN1950, Aerosols, 2.2 , Limited Quantity
IMO/IMDG (water): UN1950, Aerosols, 2.2 , Limited Quantity

Not applicable

14.2. UN proper shipping name


Proper Shipping Name (DOT) : Aerosols
poison, (each not exceeding 1 L capacity)
Department of Transportation (DOT) Hazard : 2.2 - Class 2.2 - Non-flammable compressed gas 49 CFR 173.115
Classes
Hazard labels (DOT) : 2.2 - Non-flammable gas
6.1 - Poison inhalation hazard

DOT Packaging Exceptions (49 CFR 173.xxx) : 306


DOT Packaging Non Bulk (49 CFR 173.xxx) : None
DOT Packaging Bulk (49 CFR 173.xxx) : None
Marine pollutant : Yes
14.3. Additional information
Other information : No supplementary information available.

Overland transport
No additional information available
Transport by sea
DOT Vessel Stowage Location : A - The material may be stowed ‘‘on deck’’ or ‘‘under deck’’ on a cargo vessel and on a
passenger vessel.
DOT Vessel Stowage Other : 48 - Stow ‘‘away from’’ sources of heat,87 - Stow ‘‘separated from’’ Class 1 (explosives) except
Division 14,126 - Segregation same as for Class 9, miscellaneous hazardous materials

Air transport
DOT Quantity Limitations Passenger aircraft/rail : Forbidden
(49 CFR 173.27)
DOT Quantity Limitations Cargo aircraft only (49 : Forbidden
CFR 175.75)

SECTION 15: Regulatory information


15.1. US Federal regulations
JOHNSEN'S BRAKE CLEANER 16 OZ.
SARA Section 311/312 Hazard Classes Immediate (acute) health hazard
Delayed (chronic) health hazard
Sudden release of pressure hazard

Tetrachloroethylene (127-18-4)
Listed on the United States SARA Section 302
Listed on United States SARA Section 313
RQ (Reportable quantity, section 304 of EPA's 100 lb Tetrachloroethylene
List of Lists)
SARA Section 311/312 Hazard Classes Immediate (acute) health hazard
Delayed (chronic) health hazard

15.2. International regulations


CANADA
JOHNSEN'S BRAKE CLEANER 16 OZ.
WHMIS Classification Class D Division 1 Subdivision B - Toxic material causing immediate and serious toxic effects
Class D Division 2 Subdivision A - Very toxic material causing other toxic effects

Tetrachloroethylene (127-18-4)
Listed on the Canadian DSL (Domestic Sustances List)
13/02/2015 EN (English US) 7/9
JOHNSEN'S BRAKE CLEANER 16 OZ.
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations

Tetrachloroethylene (127-18-4)
WHMIS Classification Class D Division 1 Subdivision B - Toxic material causing immediate and serious toxic effects
Class D Division 2 Subdivision A - Very toxic material causing other toxic effects

EU-Regulations
No additional information available

Classification according to Regulation (EC) No. 1272/2008 [CLP]

Classification according to Directive 67/548/EEC [DSD] or 1999/45/EC [DPD]


Carc.Cat.3; R40
Full text of R-phrases: see section 16
15.2.2. National regulations

Tetrachloroethylene (127-18-4)
Listed on the Canadian IDL (Ingredient Disclosure List)

15.3. US State regulations


JOHNSEN'S BRAKE CLEANER 16 OZ.
State or local regulations Not for sale in California or New Jersey
U.S. - Pennsylvania - RTK (Right to Know) List
U.S. - California - Proposition 65 - Maximum Allowable Dose Levels (MADL)

Tetrachloroethylene (127-18-4)

U.S. - California - Proposition 65 - Maximum Allowable Dose Levels (MADL)


Not for sale in California or New Jersey
U.S. - Pennsylvania - RTK (Right to Know) List
U.S. - New Jersey - Right to Know Hazardous Substance List
U.S. - Massachusetts - Right To Know List
U.S. - Rhode Island - Hazardous Substance List

SECTION 16: Other information


Training advice : Normal use of this product shall imply use in accordance with the instructions on the packaging.
Other information : None.
Full text of H-phrases: see section 16:
------ Acute Tox. 4 (Inhalation) Acute toxicity (inhalation) Category 4
------ Acute Tox. 4 (Inhalation:gas) Acute toxicity (inhalation:gas) Category 4
------ Aquatic Chronic 2 Hazardous to the aquatic environment - Chronic Hazard Category 2
------ Carc. 1B Carcinogenicity Category 1B
------ Compressed gas Gases under pressure Compressed gas
------ Eye Irrit. 2B Serious eye damage/eye irritation Category 2B
------ H280 Contains gas under pressure; may explode if heated
------ H320 Causes eye irritation
------ H332 Harmful if inhaled
------ H350 May cause cancer
------ H411 Toxic to aquatic life with long lasting effects

NFPA health hazard : 2 - Intense or continued exposure could cause temporary


incapacitation or possible residual injury unless prompt
medical attention is given.
NFPA fire hazard : 0 - Materials that will not burn.
NFPA reactivity : 0 - Normally stable, even under fire exposure conditions,
and are not reactive with water.

HMIS III Rating


Health : 2 Moderate Hazard - Temporary or minor injury may occur
Flammability : 0 Minimal Hazard
Physical : 1 Slight Hazard

13/02/2015 EN (English US) 8/9


JOHNSEN'S BRAKE CLEANER 16 OZ.
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations

Personal Protection : B

SDS US (GHS HazCom 2012) - TCC

The Supplier identified in Section 1 of this MSDS has evaluated this product and certifies it to be labeled and packaged in compliance with the applicable provisions of the Federal Hazardous
Substance Act as stated in 16 CFR 1500 and enforced by the Consumer Product Safety Commission, and where applicable the products that require Child Resistant Closures are packaged in
accordance with the Poison Prevention Packaging Act as stated in 16 CFR 1700 and enforced by the Consumer Product Safety Commission. All closures have been tested in accordance with the
latest protocols. No other testing is required to certify compliance with the above. The date of manufacture is stamped on the product

Disclaimer: The information and recommendations contained herein are based upon tests believed to be reliable. However, the manufacturer/distributor of this product does not guarantee their
accuracy or completeness NOR SHALL ANY OF THIS INFORMATION CONSTITUTE A WARRANTY, WHETHER EXPRESSED OR IMPLIED, AS TO THE SAFETY OF THE GOODS, THE
MERCHANTABILITY OF THE GOODS, OR THE FITNESS OF THE GOODS FOR A PARTICULAR PURPOSE. Adjustment to conform to actual conditions of usage may be required. The
manufacturer/distributor assumes no responsibility for results obtained or for incidental or consequential damages, including lost profits, arising from the use of these data. No warranty against
infringement of any patent, copyright or trademark is made or implied.

13/02/2015 EN (English US) 9/9


Health 1 FLAMMABILITY

Flammability 1
MATERIAL SAFETY DATA SHEET 1

HEALTH 1 1 REACTIVITY
Reactivity 1
KOPR-KOTE THERMAL GRADE
PPI B
OTHER
HMIS SYMBOL NFPA SYMBOL
SECTION 1 - PRODUCT AND COMPANY IDENTIFICATION
Product Name: KOPR-KOTE THERMAL GRADE
Chemical Family: Mixture
Use: Lubricating grease anti-seize
Manufacturer/Supplier: Jet-Lube of Canada Ltd.
3820 – 97 Street
Edmonton, Alberta
Canada T6E 5S8
Phone: (780) 463-7441 Fax: (780) 463-7454
CCOHS: 1-800-668-4284
Emergency:
CANUTEC PH: (613) 996-6666 Cell: *666 TTY/TDD: 1-888-675-6863
SECTION 2 - COMPOSITION/INFORMATION ON INGREDIENTS
Hazardous Molybdenum
Components Talc Graphite Copper Disulphide
CAS NO. 14807-96-6 7782-42-5 7440-50-8 1317-33-5
WT % 3-7 7-13 5-10 1-5
2 mg/m3 (dust) 2.5 mg/m3
3
OSHA PEL 1 mg/m (dust) 15 mg/m3
2 mg/m3 (dust) 2 mg/m3
3
ACGIH TLV 1 mg/m (dust) 10 mg/m3
LD50 Not Available 10000 mg/kg Not Available >2000 mg/kg (oral,rat)
LC50 Not Available 64400 mg/m³ Not Available >2820 mg/m³ (rat)
OTHER: Not Applicable Not Applicable Not Applicable Not Applicable
SECTION 3 - HAZARDS IDENTIFICATION
Route of Entry: Eyes, Inhalation, Ingestion, Skin
Eyes: May cause irritation to eyes as a foreign object.
Inhalation: Viscous nature may block breathing passages if inhaled.
Ingestion: May cause diarrhea if ingested.
Skin: May cause irritation after prolonged skin exposure, especially for persons with hyper sensitivity.
SECTION 4 - FIRST AID MEASURES
Eyes: Flush with water until all residual material is gone. If irritation persists, seek medical help.
Ingestion: Do not induce vomiting. Wash out mouth. Contact a physician immediately.
Skin: Remove by wiping or with a waterless hand cleaner, followed by washing with soap and water.
Inhalation: Clear air passage. If breathing difficulty continues seek medical help.
SECTION 5 - FIRE FIGHTING MEASURES
Flammability: Nil at ambient temp
Extinguishing Media: Use dry chemicals, foam, halon, CO2
Flash Point (OC): >293C (560F)
Flammable Limits: Upper (Not Available) Lower (Not Available)
Explosive Properties: Sensitivity to Static Discharge (Not Available)
Sensitivity to Impact (Not Available)
LEL – 0.9% UEL - 7%
Auto-ignition Temp: >360C (680F)
Hazardous Combustion Products: Oxides of carbon, smoke and irritating
vapors as products of incomplete
combustion.
SECTION 6 - ACCIDENTAL RELEASE MEASURES
Spillage: Scoop up excess, then wipes down the affected area and pick up
residue with diatomaceous earth to avoid a walking hazard.
Environmental Precautions: Do not allow product to enter into drains.
SECTION 7 - HANDLING AND STORAGE
Handling Procedures: No special handling precautions are necessary. Do not pressurize, cut, heat or weld empty containers.
Storage Requirements: Store in a cool, well ventilated place.
SECTION 8 - EXPOSURE CONTROLS/PERSONAL PROTECTION
Exposure Limits: Talc Graphite Copper Molybdenum Disulphide
OSHA PEL 2mg/m³ 2.5mg/m³ 1mg/m³ 15mg/m³
ACGIH TLV 2mg/m³ 2.0mg/m³ 1mg/m³ 10mg/m³
Engineering Controls: If user’s operation generates vapors or mists, use ventilation to keep exposure to airborne contaminants below the exposure limit. Make up air
should always be supplied to balance air removed by exhaust ventilation. Ensure eyewash station and safety shower are close to work station.
Personal Protective Equipment (PPE's):
Respiratory Protection: None required.
Hand Protection: Protective gloves for hypersensitive persons.
Eye Protection: Protective glasses if applied to moving parts.
Body Protection: Protective Overalls.
SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES
Physical State: Paste Odor & Appearance:Light Petroleum & Dark Brown
Odor Threshold: Not Available Specific Gravity: 1.10 Typical
Vapor Pressure: <0.01 kPa Vapor Density: Not Available
Boiling Point: >370C (698F) Freezing Point: Not Available
pH: Neutral
3
Density: 1.10 g/cm
Coefficient of Water/Oil Distribution: Not Available
Evaporation Rate (Butyl Acetate = 1.0): <0.01
SECTION 10 - STABILITY AND REACTIVITY
Stability: Chemically stable under normal conditions. No photoreactive agents.
Conditions to Avoid: Powerful sources of ignition and extreme temperatures.
Materials to Avoid: Strong acids and oxidizing agents.
Hazardous Decomposition Products: May release COx, smoke and irritating vapors when heated to decomposition.
SECTION 11 - TOXICOLOGICAL INFORMATION
Effects of Short-Term (Acute) Exposure: No adverse affects know.
Effects of Long-Term (Chronic) Exposure: Long term dermal application may produce possible skin irritation. Elevated temperatures or mechanical action may form
vapors or fumes. Inhalation of oil mists or vapors may cause irritation of the upper respiratory tract.
Irritancy of Product: Products is not known to be an irritant.
Skin Sensitization: Product is not known to produce skin sensitization.
Respiratory Sensitization: Product is not known to produce respiratory sensitization.
Teratogenecity, Embryotoxicity & Reproductive Toxicity: Not Available
Mutagenicity: Product is not a known mutagen.
Carcinogen: Not classifiable as a human carcinogen IARC: Group 3 ACGIH: A4
Name of Synergistic Products/Effects: Not Available.
SECTION 12 - ECOLOGICAL INFORMATION
Possible Effects: May generate oil fractions that could act as a marine pollutant, but is highly unlikely.
Behavior: Product is non-reactive under ambient conditions. Bioaccumulation potential almost nil.
Environmental Fate: Highly unlikely to cause widespread contamination. May be toxic to marine and land organisms. Non-toxic to land and marine organisms.
SECTION 13 - DISPOSAL CONSIDERATIONS
Consult federal, provincial and local regulations for disposal of petroleum products.
Do not incinerate.
SECTION 14 - TRANSPORT INFORMATION
TDG (Canada): The mixture is not specifically listed in the Canadian Transportation of Dangerous Goods Regulations. The mixture is not regulated.
Land & Rail: Not Regulated
Marine: Regulated
Shipping Name: Environmentally Hazardous Substance, N.O.S (copper)
UN No.: UN3077
Packing Group: III
Classification: Class 9
Labeling Requirements: Class 9 and Marine Pollutant Labels
Placard Requirements: None
Labeling Requirements: Limited Quantities Label for containment less than LQI of 5L net Contents per containment.
Class 9 & Marine Pollutant label if >5L net contents per containment or large containment.
Placard Requirements: Limited Quantities – Non-Required
Large Containment – Class 9 & Marine Pollutant
Air Transport Requirements: Hazard Label – Miscellaneous
PG – III
Passenger and Cargo Aircraft Packing Instructions – 956
Max Net Qty/Package – 400 kg
Limited Quantity
Packing Instructions – Y956
Max Net Qty/Package – 30 kg G
Cargo Aircraft Only Packaging Instructions – 956
Max Net Qty/Package – 400kg
SECTION 15 -REGULATORY INFORMATION
WHMIS: Not Classified
DSL: All components listed
CPR Compliance: This product has been classified in accordance with the hazard criteria of the Controlled Product Regulations and the MSDS contains all of the
information required by those regulations.
SECTION 16 - OTHER INFORMATION
CPR - Controlled Product Regulations
DSL - Domestic Substance List
As of issue date, the information contained herein is accurate and reliable to the best of Jet-Lube of Canada Ltd.’s knowledge. Jet-Lube of Canada Ltd. does not warrant or guarantee its accuracy or reliability and shall not be liable for any loss or
damage arising out of the use thereof. It is the users’ responsibility to satisfy themselves that the information offered for their consideration is suitable for their particular use.

Prepared by: Jet-Lube of Canada Ltd. - Laboratory


Last Date of Revision: October 22, 2014
SAFETY DATA SHEET
03621

Section 1. Identification
Product name : KRYLON® Industrial QUIK-MARK™ Solvent-Based Inverted Marking Paint (APWA)
Blue
Product code : 03621
Other means of : Not available.
identification
Product type : Aerosol.
Relevant identified uses of the substance or mixture and uses advised against
Not applicable.

Manufacturer : THE SHERWIN-WILLIAMS COMPANY


KRYLON PRODUCTS GROUP
Cleveland, OH 44115

Emergency telephone : (216) 566-2917


number of the company
Product Information : (800) 247-3266
Telephone Number
Regulatory Information : (216) 566-2902
Telephone Number
Transportation Emergency : (800) 424-9300
Telephone Number

Section 2. Hazards identification


OSHA/HCS status : This material is considered hazardous by the OSHA Hazard Communication Standard
(29 CFR 1910.1200).
Classification of the : FLAMMABLE AEROSOLS - Category 1
substance or mixture GASES UNDER PRESSURE - Compressed gas
SKIN CORROSION/IRRITATION - Category 2
SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 2A
CARCINOGENICITY - Category 1A
TOXIC TO REPRODUCTION (Unborn child) - Category 2
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Respiratory tract
irritation) - Category 3
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Narcotic effects) -
Category 3
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) - Category 2
ASPIRATION HAZARD - Category 1
Percentage of the mixture consisting of ingredient(s) of unknown toxicity: 20%
GHS label elements
Hazard pictograms :

Signal word : Danger

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Section 2. Hazards identification
Hazard statements : Extremely flammable aerosol.
Contains gas under pressure; may explode if heated.
Causes serious eye irritation.
Causes skin irritation.
May cause cancer.
Suspected of damaging the unborn child.
May be fatal if swallowed and enters airways.
May cause respiratory irritation.
May cause drowsiness and dizziness.
May cause damage to organs through prolonged or repeated exposure.
Precautionary statements
General : Read label before use. Keep out of reach of children. If medical advice is needed, have
product container or label at hand.
Prevention : Obtain special instructions before use. Do not handle until all safety precautions have
been read and understood. Wear protective gloves. Wear eye or face protection.
Wear protective clothing. Keep away from heat, hot surfaces, sparks, open flames and
other ignition sources. No smoking. Do not spray on an open flame or other ignition
source. Use only outdoors or in a well-ventilated area. Do not breathe dust or mist.
Wash hands thoroughly after handling. Pressurized container: Do not pierce or burn,
even after use.
Response : Get medical attention if you feel unwell. IF exposed or concerned: Get medical
attention. IF INHALED: Remove person to fresh air and keep comfortable for breathing.
Call a POISON CENTER or physician if you feel unwell. IF SWALLOWED:
Immediately call a POISON CENTER or physician. Do NOT induce vomiting. IF ON
SKIN: Wash with plenty of soap and water. Take off contaminated clothing and wash it
before reuse. If skin irritation occurs: Get medical attention. IF IN EYES: Rinse
cautiously with water for several minutes. Remove contact lenses, if present and easy
to do. Continue rinsing. If eye irritation persists: Get medical attention.
Storage : Store locked up. Protect from sunlight. Do not expose to temperatures exceeding 50
°C/122 °F. Store in a well-ventilated place.
Disposal Dispose of contents and container in accordance with all local, regional, national and
international regulations.
Supplemental label DANGER: Rags, steel wool, other waste soaked with this product, and sanding residue
elements may spontaneously catch fire if improperly discarded. Immediately place rags, steel
wool, other waste soaked with this product, and sanding residue in a sealed, water-filled,
metal container. Dispose of in accordance with local fire regulations. DELAYED
EFFECTS FROM LONG TERM OVEREXPOSURE. Contains solvents which can cause
permanent brain and nervous system damage. Intentional misuse by deliberately
concentrating and inhaling the contents can be harmful or fatal. WARNING: This
product contains chemicals known to the State of California to cause cancer and birth
defects or other reproductive harm. Adequate ventilation required when sanding or
abrading the dried film. If Adequate ventilation cannot be provided wear an approved
particulate respirator (NIOSH approved). Follow respirator manufacturer's directions for
respirator use. DELAYED EFFECTS FROM LONG TERM OVEREXPOSURE. Abrading
or sanding of the dry film may release Crystalline Silica which has been shown to cause
lung damage and cancer under long term exposure.
Please refer to the SDS for additional information. Keep upright in a cool, dry place. Do
not discard empty can in trash compactor.
Hazards not otherwise : None known.
classified

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Section 3. Composition/information on ingredients
Substance/mixture : Mixture
Other means of : Not available.
identification
CAS number/other identifiers

Ingredient name % by weight CAS number


Acetone ≥10 - <25 67-64-1
Propane ≥10 - <25 74-98-6
Butane ≥10 - <25 106-97-8
Toluene ≥10 - <25 108-88-3
Lt. Aliphatic Hydrocarbon Solvent ≥5 - <10 64742-89-8
Titanium Dioxide ≥1 - <3 13463-67-7
Quartz ≥0.1 - <0.3 14808-60-7
Ethylbenzene ≥0.1 - <0.3 100-41-4
Any concentration shown as a range is to protect confidentiality or is due to batch variation.
There are no additional ingredients present which, within the current knowledge of the supplier and in the
concentrations applicable, are classified as hazardous to health and hence require reporting in this section.

Occupational exposure limits, if available, are listed in Section 8.

Section 4. First aid measures


Description of necessary first aid measures
Eye contact : Immediately flush eyes with plenty of water, occasionally lifting the upper and lower
eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10
minutes. Get medical attention.
Inhalation : Remove victim to fresh air and keep at rest in a position comfortable for breathing. If it
is suspected that fumes are still present, the rescuer should wear an appropriate mask
or self-contained breathing apparatus. If not breathing, if breathing is irregular or if
respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It
may be dangerous to the person providing aid to give mouth-to-mouth resuscitation.
Get medical attention. If necessary, call a poison center or physician. If unconscious,
place in recovery position and get medical attention immediately. Maintain an open
airway. Loosen tight clothing such as a collar, tie, belt or waistband.
Skin contact : Flush contaminated skin with plenty of water. Remove contaminated clothing and
shoes. Wash contaminated clothing thoroughly with water before removing it, or wear
gloves. Continue to rinse for at least 10 minutes. Get medical attention. Wash clothing
before reuse. Clean shoes thoroughly before reuse.
Ingestion : Get medical attention immediately. Call a poison center or physician. Wash out mouth
with water. Remove dentures if any. Remove victim to fresh air and keep at rest in a
position comfortable for breathing. If material has been swallowed and the exposed
person is conscious, give small quantities of water to drink. Stop if the exposed person
feels sick as vomiting may be dangerous. Aspiration hazard if swallowed. Can enter
lungs and cause damage. Do not induce vomiting. If vomiting occurs, the head should
be kept low so that vomit does not enter the lungs. Never give anything by mouth to an
unconscious person. If unconscious, place in recovery position and get medical
attention immediately. Maintain an open airway. Loosen tight clothing such as a collar,
tie, belt or waistband.

Most important symptoms/effects, acute and delayed


Potential acute health effects
Eye contact : Causes serious eye irritation.
Inhalation : Can cause central nervous system (CNS) depression. May cause drowsiness and
dizziness. May cause respiratory irritation.
Skin contact : Causes skin irritation.

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Section 4. First aid measures
Ingestion : Can cause central nervous system (CNS) depression. May be fatal if swallowed and
enters airways.
Over-exposure signs/symptoms
Eye contact : Adverse symptoms may include the following:
pain or irritation
watering
redness
Inhalation : Adverse symptoms may include the following:
respiratory tract irritation
coughing
nausea or vomiting
headache
drowsiness/fatigue
dizziness/vertigo
unconsciousness
reduced fetal weight
increase in fetal deaths
skeletal malformations
Skin contact : Adverse symptoms may include the following:
irritation
redness
reduced fetal weight
increase in fetal deaths
skeletal malformations
Ingestion : Adverse symptoms may include the following:
nausea or vomiting
reduced fetal weight
increase in fetal deaths
skeletal malformations

Indication of immediate medical attention and special treatment needed, if necessary


Notes to physician : Treat symptomatically. Contact poison treatment specialist immediately if large
quantities have been ingested or inhaled.
Specific treatments : No specific treatment.
Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. If it is
suspected that fumes are still present, the rescuer should wear an appropriate mask or
self-contained breathing apparatus. It may be dangerous to the person providing aid to
give mouth-to-mouth resuscitation. Wash contaminated clothing thoroughly with water
before removing it, or wear gloves.

See toxicological information (Section 11)

Section 5. Fire-fighting measures


Extinguishing media
Suitable extinguishing : Use an extinguishing agent suitable for the surrounding fire.
media
Unsuitable extinguishing : None known.
media

Specific hazards arising : Extremely flammable aerosol. In a fire or if heated, a pressure increase will occur and
from the chemical the container may burst, with the risk of a subsequent explosion. Gas may accumulate
in low or confined areas or travel a considerable distance to a source of ignition and
flash back, causing fire or explosion. Bursting aerosol containers may be propelled from
a fire at high speed. Runoff to sewer may create fire or explosion hazard.

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Section 5. Fire-fighting measures
Hazardous thermal : Decomposition products may include the following materials:
decomposition products carbon dioxide
carbon monoxide
metal oxide/oxides

Special protective actions : Promptly isolate the scene by removing all persons from the vicinity of the incident if
for fire-fighters there is a fire. No action shall be taken involving any personal risk or without suitable
training. Move containers from fire area if this can be done without risk. Use water
spray to keep fire-exposed containers cool.
Special protective : Fire-fighters should wear appropriate protective equipment and self-contained breathing
equipment for fire-fighters apparatus (SCBA) with a full face-piece operated in positive pressure mode.

Section 6. Accidental release measures


Personal precautions, protective equipment and emergency procedures
For non-emergency : No action shall be taken involving any personal risk or without suitable training.
personnel Evacuate surrounding areas. Keep unnecessary and unprotected personnel from
entering. In the case of aerosols being ruptured, care should be taken due to the rapid
escape of the pressurized contents and propellant. If a large number of containers are
ruptured, treat as a bulk material spillage according to the instructions in the clean-up
section. Do not touch or walk through spilled material. Shut off all ignition sources. No
flares, smoking or flames in hazard area. Avoid breathing vapor or mist. Provide
adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put
on appropriate personal protective equipment.
For emergency responders : If specialised clothing is required to deal with the spillage, take note of any information in
Section 8 on suitable and unsuitable materials. See also the information in "For non-
emergency personnel".

Environmental precautions : Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains
and sewers. Inform the relevant authorities if the product has caused environmental
pollution (sewers, waterways, soil or air).

Methods and materials for containment and cleaning up


Small spill : Stop leak if without risk. Move containers from spill area. Use spark-proof tools and
explosion-proof equipment. Dilute with water and mop up if water-soluble. Alternatively,
or if water-insoluble, absorb with an inert dry material and place in an appropriate waste
disposal container. Dispose of via a licensed waste disposal contractor.
Large spill : Stop leak if without risk. Move containers from spill area. Use spark-proof tools and
explosion-proof equipment. Approach release from upwind. Prevent entry into sewers,
water courses, basements or confined areas. Wash spillages into an effluent treatment
plant or proceed as follows. Contain and collect spillage with non-combustible,
absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in
container for disposal according to local regulations (see Section 13). Dispose of via a
licensed waste disposal contractor. Contaminated absorbent material may pose the
same hazard as the spilled product. Note: see Section 1 for emergency contact
information and Section 13 for waste disposal.

Section 7. Handling and storage


Precautions for safe handling
Protective measures : Put on appropriate personal protective equipment (see Section 8). Pressurized
container: protect from sunlight and do not expose to temperatures exceeding 50°C. Do
not pierce or burn, even after use. Avoid exposure - obtain special instructions before
use. Avoid exposure during pregnancy. Do not handle until all safety precautions have
been read and understood. Do not get in eyes or on skin or clothing. Do not breathe
vapor or mist. Do not swallow. Avoid breathing gas. Use only with adequate ventilation.
Wear appropriate respirator when ventilation is inadequate. Store and use away from
heat, sparks, open flame or any other ignition source. Use explosion-proof electrical
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Section 7. Handling and storage
(ventilating, lighting and material handling) equipment. Use only non-sparking tools.
Empty containers retain product residue and can be hazardous.
Advice on general : Eating, drinking and smoking should be prohibited in areas where this material is
occupational hygiene handled, stored and processed. Workers should wash hands and face before eating,
drinking and smoking. Remove contaminated clothing and protective equipment before
entering eating areas. See also Section 8 for additional information on hygiene
measures.

Conditions for safe storage, : Store in accordance with local regulations. Store away from direct sunlight in a dry, cool
including any and well-ventilated area, away from incompatible materials (see Section 10) and food
incompatibilities and drink. Protect from sunlight. Store locked up. Eliminate all ignition sources. Use
appropriate containment to avoid environmental contamination.

Section 8. Exposure controls/personal protection


Control parameters
Occupational exposure limits
Ingredient name Exposure limits
Acetone ACGIH TLV (United States, 3/2015).
TWA: 250 ppm 8 hours.
STEL: 500 ppm 15 minutes.
NIOSH REL (United States, 10/2013).
TWA: 250 ppm 10 hours.
TWA: 590 mg/m³ 10 hours.
OSHA PEL (United States, 2/2013).
TWA: 1000 ppm 8 hours.
TWA: 2400 mg/m³ 8 hours.
Propane NIOSH REL (United States, 10/2013).
TWA: 1000 ppm 10 hours.
TWA: 1800 mg/m³ 10 hours.
OSHA PEL (United States, 2/2013).
TWA: 1000 ppm 8 hours.
TWA: 1800 mg/m³ 8 hours.
Butane NIOSH REL (United States, 10/2013).
TWA: 800 ppm 10 hours.
TWA: 1900 mg/m³ 10 hours.
ACGIH TLV (United States, 3/2015).
STEL: 1000 ppm 15 minutes.
Toluene OSHA PEL Z2 (United States, 2/2013).
TWA: 200 ppm 8 hours.
CEIL: 300 ppm
AMP: 500 ppm 10 minutes.
NIOSH REL (United States, 10/2013).
TWA: 100 ppm 10 hours.
TWA: 375 mg/m³ 10 hours.
STEL: 150 ppm 15 minutes.
STEL: 560 mg/m³ 15 minutes.
ACGIH TLV (United States, 3/2015).
TWA: 20 ppm 8 hours.
Lt. Aliphatic Hydrocarbon Solvent None.
Titanium Dioxide ACGIH TLV (United States, 3/2015).
TWA: 10 mg/m³ 8 hours.
OSHA PEL (United States, 2/2013).
TWA: 15 mg/m³ 8 hours. Form: Total dust
Quartz OSHA PEL Z3 (United States, 2/2013).
TWA: 250 MPPCF / (%SiO2+5) 8 hours.
Form: Respirable
TWA: 10 MG/M3 / (%SiO2+2) 8 hours. Form:

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Section 8. Exposure controls/personal protection
Respirable
ACGIH TLV (United States, 3/2015).
TWA: 0.025 mg/m³ 8 hours. Form:
Respirable fraction
NIOSH REL (United States, 10/2013).
TWA: 0.05 mg/m³ 10 hours. Form: respirable
dust
Ethylbenzene ACGIH TLV (United States, 3/2015).
TWA: 20 ppm 8 hours.
NIOSH REL (United States, 10/2013).
TWA: 100 ppm 10 hours.
TWA: 435 mg/m³ 10 hours.
STEL: 125 ppm 15 minutes.
STEL: 545 mg/m³ 15 minutes.
OSHA PEL (United States, 2/2013).
TWA: 100 ppm 8 hours.
TWA: 435 mg/m³ 8 hours.

Appropriate engineering : Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or
controls other engineering controls to keep worker exposure to airborne contaminants below any
recommended or statutory limits. The engineering controls also need to keep gas,
vapor or dust concentrations below any lower explosive limits. Use explosion-proof
ventilation equipment.
Environmental exposure : Emissions from ventilation or work process equipment should be checked to ensure
controls they comply with the requirements of environmental protection legislation. In some
cases, fume scrubbers, filters or engineering modifications to the process equipment
will be necessary to reduce emissions to acceptable levels.

Individual protection measures


Hygiene measures : Wash hands, forearms and face thoroughly after handling chemical products, before
eating, smoking and using the lavatory and at the end of the working period.
Appropriate techniques should be used to remove potentially contaminated clothing.
Wash contaminated clothing before reusing. Ensure that eyewash stations and safety
showers are close to the workstation location.
Eye/face protection : Safety eyewear complying with an approved standard should be used when a risk
assessment indicates this is necessary to avoid exposure to liquid splashes, mists,
gases or dusts. If contact is possible, the following protection should be worn, unless
the assessment indicates a higher degree of protection: chemical splash goggles.
Skin protection
Hand protection : Chemical-resistant, impervious gloves complying with an approved standard should be
worn at all times when handling chemical products if a risk assessment indicates this is
necessary. Considering the parameters specified by the glove manufacturer, check
during use that the gloves are still retaining their protective properties. It should be
noted that the time to breakthrough for any glove material may be different for different
glove manufacturers. In the case of mixtures, consisting of several substances, the
protection time of the gloves cannot be accurately estimated.
Body protection : Personal protective equipment for the body should be selected based on the task being
performed and the risks involved and should be approved by a specialist before
handling this product. When there is a risk of ignition from static electricity, wear anti-
static protective clothing. For the greatest protection from static discharges, clothing
should include anti-static overalls, boots and gloves.
Other skin protection : Appropriate footwear and any additional skin protection measures should be selected
based on the task being performed and the risks involved and should be approved by a
specialist before handling this product.

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Section 8. Exposure controls/personal protection
Respiratory protection : Use a properly fitted, air-purifying or air-fed respirator complying with an approved
standard if a risk assessment indicates this is necessary. Respirator selection must be
based on known or anticipated exposure levels, the hazards of the product and the safe
working limits of the selected respirator.

Section 9. Physical and chemical properties


Appearance
Physical state : Liquid.
Color : Not available.
Odor : Not available.
Odor threshold : Not available.
pH : 7
Melting point : Not available.
Boiling point : Not available.
Flash point : Closed cup: -29°C (-20.2°F) [Pensky-Martens Closed Cup]
Evaporation rate : 5.6 (butyl acetate = 1)
Flammability (solid, gas) : Not available.
Lower and upper explosive : Lower: 0.9%
(flammable) limits Upper: 12.8%
Vapor pressure : 13.5 kPa (101.325 mm Hg) [at 20°C]
Vapor density : 1.55 [Air = 1]
Relative density : 0.86
Solubility : Not available.
Partition coefficient: n- : Not available.
octanol/water
Auto-ignition temperature : Not available.
Decomposition temperature : Not available.
Viscosity : Kinematic (room temperature): <0.205 cm2/s (<20.5 cSt)
Kinematic (40°C (104°F)): <0.205 cm2/s (<20.5 cSt)
Molecular weight : Not applicable.
Aerosol product
Type of aerosol : Spray
Heat of combustion : 23.72 kJ/g

Section 10. Stability and reactivity


Reactivity : No specific test data related to reactivity available for this product or its ingredients.

Chemical stability : The product is stable.

Possibility of hazardous : Under normal conditions of storage and use, hazardous reactions will not occur.
reactions

Conditions to avoid : Avoid all possible sources of ignition (spark or flame).

Incompatible materials : No specific data.

Hazardous decomposition : Under normal conditions of storage and use, hazardous decomposition products should
products not be produced.

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Section 11. Toxicological information
Information on toxicological effects
Acute toxicity
Product/ingredient name Result Species Dose Exposure
Acetone LD50 Oral Rat 5800 mg/kg -
Butane LC50 Inhalation Vapor Rat 658000 mg/m³ 4 hours
Toluene LC50 Inhalation Vapor Rat 49 g/m³ 4 hours
LD50 Oral Rat 636 mg/kg -
Ethylbenzene LD50 Dermal Rabbit >5000 mg/kg -
LD50 Oral Rat 3500 mg/kg -
Irritation/Corrosion
Product/ingredient name Result Species Score Exposure Observation
Acetone Eyes - Mild irritant Human - 186300 parts -
per million
Eyes - Mild irritant Rabbit - 10 microliters -
Eyes - Moderate irritant Rabbit - 24 hours 20 -
milligrams
Eyes - Severe irritant Rabbit - 20 milligrams -
Skin - Mild irritant Rabbit - 24 hours 500 -
milligrams
Skin - Mild irritant Rabbit - 395 -
milligrams
Toluene Eyes - Mild irritant Rabbit - 0.5 minutes -
100
milligrams
Eyes - Mild irritant Rabbit - 870 -
Micrograms
Eyes - Severe irritant Rabbit - 24 hours 2 -
milligrams
Skin - Mild irritant Pig - 24 hours 250 -
microliters
Skin - Mild irritant Rabbit - 435 -
milligrams
Skin - Moderate irritant Rabbit - 24 hours 20 -
milligrams
Skin - Moderate irritant Rabbit - 500 -
milligrams
Titanium Dioxide Skin - Mild irritant Human - 72 hours 300 -
Micrograms
Intermittent
Ethylbenzene Eyes - Severe irritant Rabbit - 500 -
milligrams
Skin - Mild irritant Rabbit - 24 hours 15 -
milligrams
Sensitization
Not available.
Mutagenicity
Not available.
Carcinogenicity
Not available.
Classification

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Section 11. Toxicological information
Product/ingredient name OSHA IARC NTP
Toluene - 3 -
Titanium Dioxide - 2B -
Quartz - 1 Known to be a human carcinogen.
Ethylbenzene - 2B -
Reproductive toxicity
Not available.

Teratogenicity
Not available.
Specific target organ toxicity (single exposure)
Name Category Route of Target organs
exposure
Acetone Category 3 Not applicable. Respiratory tract
irritation and
Narcotic effects
Propane Category 3 Not applicable. Respiratory tract
irritation and
Narcotic effects
Butane Category 3 Not applicable. Respiratory tract
irritation and
Narcotic effects
Toluene Category 3 Not applicable. Respiratory tract
irritation and
Narcotic effects
Lt. Aliphatic Hydrocarbon Solvent Category 3 Not applicable. Respiratory tract
irritation and
Narcotic effects
Ethylbenzene Category 3 Not applicable. Respiratory tract
irritation and
Narcotic effects
Specific target organ toxicity (repeated exposure)
Name Category Route of Target organs
exposure
Acetone Category 2 Not determined Not determined
Propane Category 2 Not determined Not determined
Butane Category 2 Not determined Not determined
Toluene Category 2 Not determined Not determined
Lt. Aliphatic Hydrocarbon Solvent Category 2 Not determined Not determined
Quartz Category 1 Inhalation Not determined
Ethylbenzene Category 2 Not determined Not determined
Aspiration hazard
Name Result
Propane ASPIRATION HAZARD - Category 1
Butane ASPIRATION HAZARD - Category 1
Toluene ASPIRATION HAZARD - Category 1
Lt. Aliphatic Hydrocarbon Solvent ASPIRATION HAZARD - Category 1
Ethylbenzene ASPIRATION HAZARD - Category 1

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Information on the likely : Not available.
routes of exposure
Potential acute health effects
Eye contact : Causes serious eye irritation.
Inhalation : Can cause central nervous system (CNS) depression. May cause drowsiness and
dizziness. May cause respiratory irritation.
Skin contact : Causes skin irritation.
Ingestion : Can cause central nervous system (CNS) depression. May be fatal if swallowed and
enters airways.

Symptoms related to the physical, chemical and toxicological characteristics


Eye contact : Adverse symptoms may include the following:
pain or irritation
watering
redness
Inhalation : Adverse symptoms may include the following:
respiratory tract irritation
coughing
nausea or vomiting
headache
drowsiness/fatigue
dizziness/vertigo
unconsciousness
reduced fetal weight
increase in fetal deaths
skeletal malformations
Skin contact : Adverse symptoms may include the following:
irritation
redness
reduced fetal weight
increase in fetal deaths
skeletal malformations
Ingestion : Adverse symptoms may include the following:
nausea or vomiting
reduced fetal weight
increase in fetal deaths
skeletal malformations

Delayed and immediate effects and also chronic effects from short and long term exposure
Short term exposure
Potential immediate : Not available.
effects
Potential delayed effects : Not available.
Long term exposure
Potential immediate : Not available.
effects
Potential delayed effects : Not available.
Potential chronic health effects
Not available.
General : May cause damage to organs through prolonged or repeated exposure.
Carcinogenicity : May cause cancer. Risk of cancer depends on duration and level of exposure.
Mutagenicity : No known significant effects or critical hazards.
Teratogenicity : Suspected of damaging the unborn child.
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Developmental effects : No known significant effects or critical hazards.
Fertility effects : No known significant effects or critical hazards.

Numerical measures of toxicity


Acute toxicity estimates
Route ATE value
Oral 4440.1 mg/kg

Section 12. Ecological information


Toxicity
Product/ingredient name Result Species Exposure
Acetone Acute EC50 20.565 mg/l Marine water Algae - Ulva pertusa 96 hours
Acute LC50 6000000 µg/l Fresh water Crustaceans - Gammarus pulex 48 hours
Acute LC50 10000 µg/l Fresh water Daphnia - Daphnia magna 48 hours
Acute LC50 5600 ppm Fresh water Fish - Poecilia reticulata 96 hours
Chronic NOEC 4.95 mg/l Marine water Algae - Ulva pertusa 96 hours
Chronic NOEC 0.016 ml/L Fresh water Crustaceans - Daphniidae 21 days
Chronic NOEC 0.1 ml/L Fresh water Daphnia - Daphnia magna - 21 days
Neonate
Chronic NOEC 5 µg/l Marine water Fish - Gasterosteus aculeatus - 42 days
Larvae
Toluene Acute EC50 12500 µg/l Fresh water Algae - Pseudokirchneriella 72 hours
subcapitata
Acute EC50 11600 µg/l Fresh water Crustaceans - Gammarus 48 hours
pseudolimnaeus - Adult
Acute EC50 6000 µg/l Fresh water Daphnia - Daphnia magna - 48 hours
Juvenile (Fledgling, Hatchling,
Weanling)
Acute LC50 5500 µg/l Fresh water Fish - Oncorhynchus kisutch - Fry 96 hours
Chronic NOEC 1000 µg/l Fresh water Daphnia - Daphnia magna 21 days
Lt. Aliphatic Hydrocarbon Acute LC50 >100000 ppm Fresh water Fish - Oncorhynchus mykiss 96 hours
Solvent
Titanium Dioxide Acute LC50 >1000000 µg/l Marine water Fish - Fundulus heteroclitus 96 hours
Ethylbenzene Acute EC50 4600 µg/l Fresh water Algae - Pseudokirchneriella 72 hours
subcapitata
Acute EC50 3600 µg/l Fresh water Algae - Pseudokirchneriella 96 hours
subcapitata
Acute EC50 6530 µg/l Fresh water Crustaceans - Artemia sp. - 48 hours
Nauplii
Acute EC50 2930 µg/l Fresh water Daphnia - Daphnia magna - 48 hours
Neonate
Acute LC50 4200 µg/l Fresh water Fish - Oncorhynchus mykiss 96 hours

Persistence and degradability


Product/ingredient name Aquatic half-life Photolysis Biodegradability
Acetone - - Readily
Toluene - - Readily
Ethylbenzene - - Readily

Bioaccumulative potential

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Section 12. Ecological information
Product/ingredient name LogPow BCF Potential
Toluene - 90 low
Lt. Aliphatic Hydrocarbon - 10 to 2500 high
Solvent
Titanium Dioxide - 352 low

Mobility in soil
Soil/water partition : Not available.
coefficient (KOC)

Other adverse effects : No known significant effects or critical hazards.

Section 13. Disposal considerations


Disposal methods : The generation of waste should be avoided or minimized wherever possible. Disposal
of this product, solutions and any by-products should at all times comply with the
requirements of environmental protection and waste disposal legislation and any
regional local authority requirements. Dispose of surplus and non-recyclable products
via a licensed waste disposal contractor. Waste should not be disposed of untreated to
the sewer unless fully compliant with the requirements of all authorities with jurisdiction.
Waste packaging should be recycled. Incineration or landfill should only be considered
when recycling is not feasible. This material and its container must be disposed of in a
safe way. Empty containers or liners may retain some product residues. Do not
puncture or incinerate container.

Section 14. Transport information


DOT TDG Mexico IATA IMDG
Classification Classification Classification
UN number UN1950 UN1950 UN1950 UN1950 UN1950

UN proper AEROSOLS AEROSOLS AEROSOLS AEROSOLS, AEROSOLS


shipping name flammable
Transport 2.1 2.1 2.1 2.1 2.1
hazard class(es)

Packing group - - - - -
Environmental No. No. No. No. No.
hazards
Additional Special Product classified Special Special Emergency
information provisions as per the provisions provisions schedules (EmS)
LIMITED following sections (ERG#126) LIMITED LIMITED
QUANTITY of the QUANTITY QUANTITY, F-D,
Transportation of S-U
Dangerous Goods
Regulations: 2.
13-2.17 (Class 2).

Special
provisions
LIMITED
QUANTITY

Date of issue/Date of revision : 1/4/2016 Date of previous issue : 11/5/2015 Version : 1.03 13/15
Section 14. Transport information
ERG No. ERG No. ERG No.
126 126 126

Special precautions for user : Multi-modal shipping descriptions are provided for informational purposes and do not
consider container sizes. The presence of a shipping description for a particular
mode of transport (sea, air, etc.), does not indicate that the product is packaged
suitably for that mode of transport. All packaging must be reviewed for suitability
prior to shipment, and compliance with the applicable regulations is the sole
responsibility of the person offering the product for transport. People loading and
unloading dangerous goods must be trained on all of the risks deriving from the
substances and on all actions in case of emergency situations.

Transport in bulk according : Not available.


to Annex II of MARPOL
73/78 and the IBC Code
Proper shipping name : Not available.
Ship type : Not available.
Pollution category : Not available.

Section 15. Regulatory information


SARA 313
SARA 313 (40 CFR 372.45) supplier notification can be found on the Environmental Data Sheet.
California Prop. 65
WARNING: This product contains chemicals known to the State of California to cause cancer and birth defects or other
reproductive harm.

Section 16. Other information


Hazardous Material Information System (U.S.A.)
Health * 2

Flammability 3

Physical hazards 0

The customer is responsible for determining the PPE code for this material.

Caution: HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4
representing significant hazards or risks Although HMIS® ratings are not required on SDSs under 29 CFR 1910.
1200, the preparer may choose to provide them. HMIS® ratings are to be used with a fully implemented HMIS®
program. HMIS® is a registered mark of the National Paint & Coatings Association (NPCA). HMIS® materials may
be purchased exclusively from J. J. Keller (800) 327-6868.
Procedure used to derive the classification
Classification Justification
Flam. Aerosol 1, H222 On basis of test data
Press. Gas Comp. Gas, H280 Calculation method
Skin Irrit. 2, H315 Calculation method
Eye Irrit. 2A, H319 Calculation method
Carc. 1A, H350 Calculation method
Repr. 2, H361 (Unborn child) Calculation method
STOT SE 3, H335 Calculation method
STOT SE 3, H336 Calculation method
STOT RE 2, H373 Calculation method
Asp. Tox. 1, H304 Calculation method

Date of issue/Date of revision : 1/4/2016 Date of previous issue : 11/5/2015 Version : 1.03 14/15
Section 16. Other information
History
Date of printing : 1/4/2016
Date of issue/Date of : 1/4/2016
revision
Date of previous issue : 11/5/2015
Version : 1.03
Key to abbreviations : ATE = Acute Toxicity Estimate
BCF = Bioconcentration Factor
GHS = Globally Harmonized System of Classification and Labelling of Chemicals
IATA = International Air Transport Association
IBC = Intermediate Bulk Container
IMDG = International Maritime Dangerous Goods
LogPow = logarithm of the octanol/water partition coefficient
MARPOL 73/78 = International Convention for the Prevention of Pollution From Ships,
1973 as modified by the Protocol of 1978. ("Marpol" = marine pollution)
UN = United Nations
Notice to reader
It is recommended that each customer or recipient of this Safety Data Sheet (SDS) study it carefully and consult
resources, as necessary or appropriate, to become aware of and understand the data contained in this SDS and
any hazards associated with the product. This information is provided in good faith and believed to be accurate
as of the effective date herein. However, no warranty, express or implied, is given. The information presented
here applies only to the product as shipped. The addition of any material can change the composition, hazards
and risks of the product. Products shall not be repackaged, modified, or tinted except as specifically instructed
by Sherwin-Williams, including but not limited to the incorporation of non Sherwin-Williams products or the use
or addition of products in proportions not specified by Sherwin-Williams. Regulatory requirements are subject
to change and may differ between various locations and jurisdictions. The customer/buyer/user is responsible to
ensure that his activities comply with all country, federal, state, provincial or local laws. The conditions for use
of the product are not under the control of the manufacturer; the customer/buyer/user is responsible to
determine the conditions necessary for the safe use of this product. The customer/buyer/user should not use the
product for any purpose other than the purpose shown in the applicable section of this SDS without first
referring to the supplier and obtaining written handling instructions. Due to the proliferation of sources for
information such as manufacturer-specific SDS, the manufacturer cannot be responsible for SDSs obtained from
any other source.

Date of issue/Date of revision : 1/4/2016 Date of previous issue : 11/5/2015 Version : 1.03 15/15
Material Safety Data Sheet

Revision Number: 006.0 Issue date: 02/07/2014

1. PRODUCT AND COMPANY IDENTIFICATION


Product name: LOCTITE® 242® THREADLOCKER IDH number: 135355
Product use: Sealant Item number: 24231
Region: Canada
Company address: Contact information:
Henkel Corporation Telephone: 905.814.6511
2515 Meadowpine Boulevard MEDICAL EMERGENCY Phone: Poison Control Center
Mississauga, Ontario L5N 6C3 1-877-671-4608 (toll free) or 1-303-592-1711
TRANSPORT EMERGENCY Phone: CHEMTREC
1-800-424-9300 (toll free) or 1-703-527-3887
Internet: www.henkelna.com

2. HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
Physical state: Liquid WHMIS hazard class: D.2.A, D.2.B
Color: Blue
Odor: Mild

WARNING: CAUSES EYE IRRITATION.


MAY CAUSE SKIN IRRITATION.
MAY CAUSE ALLERGIC SKIN REACTION.
MAY CAUSE RESPIRATORY TRACT IRRITATION.

Relevant routes of exposure: Skin, Inhalation, Eyes

Potential Health Effects

Inhalation: May cause respiratory tract irritation.


Skin contact: May cause allergic skin reaction. May cause skin irritation.
Eye contact: Contact with eyes will cause irritation.
Ingestion: Not expected to be harmful by ingestion.

Existing conditions aggravated by Eye, skin, and respiratory disorders.


exposure:

See Section 11 for additional toxicological information.

3. COMPOSITION / INFORMATION ON INGREDIENTS


Hazardous components CAS NUMBER %
Polyglycol dimethacrylate 25852-47-5 60 - 100
Oleic acid 5.5EO 9004-96-0 10 - 30
Silica, amorphous, fumed, crystal-free 112945-52-5 1-5
Cumene hydroperoxide 80-15-9 1-5
Propane-1,2-diol 57-55-6 1-5
Titanium dioxide 13463-67-7 0.1 - 1
Cumene 98-82-8 0.1 - 1

4. FIRST AID MEASURES


Inhalation: Move to fresh air. If breathing is difficult, give oxygen. If breathing has
stopped, give artificial respiration. Keep warm and quiet. Get medical
attention.

IDH number: 135355 Product name: LOCTITE® 242® THREADLOCKER


Page 1 of 5
Skin contact: Wash with soap and water. Remove contaminated clothing and footwear.
Wash clothing before reuse. If symptoms develop and persist, get medical
attention.

Eye contact: Flush with copious amounts of water, preferably, lukewarm water for at least
15 minutes, holding eyelids open all the time. Get medical attention.

Ingestion: Do not induce vomiting. Keep individual calm. Get medical attention.

5. FIRE FIGHTING MEASURES


Flash point: > 93.3 °C (> 199.94 °F) Tagliabue closed cup

Flame projection: Not applicable

Autoignition temperature: Not determined

Flammable/Explosive limits - lower: 2.6 % (propylene glycol)

Flammable/Explosive limits - upper: 12.5 % (propylene glycol)

Extinguishing media: Foam, dry chemical or carbon dioxide.

Special firefighting procedures: None

Unusual fire or explosion hazards: None

Hazardous combustion products: Oxides of carbon. Oxides of sulfur. Oxides of nitrogen. Irritating organic
vapours.

Sensitivity to Mechanical Impact: Not sensitive to mechanical impact.

Sensitivity to static discharge: Electrostatic charge may build-up during handling. Grounding of equipment is
recommended.

6. ACCIDENTAL RELEASE MEASURES


Use personal protection recommended in Section 8, isolate the hazard area and deny entry to unnecessary and unprotected
personnel.

Environmental precautions: Do not allow product to enter sewer or waterways.

Clean-up methods: Soak up with inert absorbent material (e.g. sand, silica gel, acid binder,
universal binder, sawdust). Store in a partly filled, closed container until
disposal.

7. HANDLING AND STORAGE


Handling: Prevent contact with eyes, skin and clothing. Do not breathe vapor and mist.
Wash thoroughly after handling.

Storage: For safe storage, store between 0 °C (32°F) and 32 °C (89.6 °F)
Keep in a cool, well ventilated area away from heat, sparks and open flame.
Keep container tightly closed until ready for use.

For information on product shelf life contact Henkel Canada Customer Service at 800-263-5043.

8. EXPOSURE CONTROLS / PERSONAL PROTECTION


Employers should complete an assessment of all workplaces to determine the need for, and selection of, proper exposure
controls and protective equipment for each task performed.

IDH number: 135355 Product name: LOCTITE® 242® THREADLOCKER


Page 2 of 5
Hazardous components ACGIH TLV OSHA PEL AIHA WEEL OTHER
Polyglycol dimethacrylate None None None None
Oleic acid 5.5EO None None None None
10 mg/m3 TWA
Inhalable dust. 20 MPPCF TWA
Silica, amorphous, fumed, crystal-free None None
3 mg/m3 TWA 0.8 mg/m3 TWA
Respirable fraction.
1 ppm (6 mg/m3)
Cumene hydroperoxide None None TWA None
(SKIN)
10 mg/m3 TWA
Propane-1,2-diol None None None
Aerosol.
15 mg/m3 PEL
Titanium dioxide 10 mg/m3 TWA None None
Total dust.
50 ppm (245
Cumene 50 ppm TWA mg/m3) PEL None None
(SKIN)

Engineering controls: No specific ventilation requirements noted, but forced ventilation may still be
required if concentrations exceed occupational exposure limits.

Respiratory protection: Use NIOSH approved respirator if there is potential to exceed exposure
limit(s).

Eye/face protection: Safety goggles or safety glasses with side shields.

Skin protection: Use impermeable gloves and protective clothing as necessary to prevent skin
contact. Neoprene gloves. Butyl rubber gloves. Natural rubber gloves.

9. PHYSICAL AND CHEMICAL PROPERTIES


Physical state: Liquid
Color: Blue
Odor: Mild
Odor threshold: Not available.
pH: Not applicable
Vapor pressure: < 5 mm hg (27 °C (80.6 °F))
Boiling point/range: > 149 °C (> 300.2 °F)
Melting point/ range: Not available.
Specific gravity: 1.1 at 23.9 °C (75.02 °F)
Vapor density: Not available.
Flash point: > 93.3 °C (> 199.94 °F) Tagliabue closed cup
Flame projection: Not applicable
Flammable/Explosive limits - lower: 2.6 % (propylene glycol)
Flammable/Explosive limits - upper: 12.5 % (propylene glycol)
Autoignition temperature: Not determined
Evaporation rate: Not available.
Solubility in water: Slight
Partition coefficient (n-octanol/water): Not available.
VOC content: 0.56 %; 6.17 g/l

IDH number: 135355 Product name: LOCTITE® 242® THREADLOCKER


Page 3 of 5
10. STABILITY AND REACTIVITY
Stability: Stable

Hazardous reactions: Will not occur.

Hazardous decomposition products: Oxides of carbon. Oxides of sulfur. Oxides of nitrogen. Irritating organic
vapours.

Incompatible materials: Strong oxidizing agents. Free radical initiators. Strong reducing agents.
Alkalis. Oxygen scavengers. Other polymerization initiators. Copper. Iron.
Zinc. Aluminum. Rust.

Conditions to avoid: See "Handling and Storage" (Section 7) and "Incompatibility" (Section 10).

11. TOXICOLOGICAL INFORMATION


Acute oral product toxicity: LD50 (rat) > 10,000 mg/kg

Acute dermal product toxicity: LD50 (rabbit) > 5,000 mg/kg

Toxicologically synergistic products: Not available.

Refer to the following for Irritancy of Product, Sensitization to Product, Carcinogenicity, Reproductive Toxicity, Teratogenicity,
and Mutagenicity.

OSHA Carcinogen
Hazardous Component(s) NTP Carcinogen IARC Carcinogen
(Specifically Regulated)
Polyglycol dimethacrylate No No No
Oleic acid 5.5EO No No No
Silica, amorphous, fumed, crystal-free No No No
Cumene hydroperoxide No No No
Propane-1,2-diol No No No
Titanium dioxide No Group 2B No
Cumene No Group 2B No

Hazardous components LD50s and LC50s Health Effects/Target Organs


Polyglycol dimethacrylate None Allergen, Irritant
Oleic acid 5.5EO None Irritant
Silica, amorphous, fumed, crystal-free None Nuisance dust
Allergen, Central nervous system, Corrosive,
Cumene hydroperoxide None
Irritant, Mutagen
Oral LD50 (RABBIT) = 18 g/kg
Propane-1,2-diol Irritant
Oral LD50 (RAT) = 30 g/kg
Irritant, Respiratory, Some evidence of
Titanium dioxide None
carcinogenicity
Oral LD50 (RAT) = 2.91 g/kg
Cumene Oral LD50 (RAT) = 1,400 mg/kg Central nervous system, Irritant, Lung
Inhalation LC50 (RAT, 4 h) = 8,000 mg/l

12. ECOLOGICAL INFORMATION


Ecological information: Not available.

IDH number: 135355 Product name: LOCTITE® 242® THREADLOCKER


Page 4 of 5
13. DISPOSAL CONSIDERATIONS
Information provided is for unused product only.

Recommended method of disposal: Follow all local, state, federal and provincial regulations for disposal.

14. TRANSPORT INFORMATION


The shipping classifications in this sections are for non-bulk packaging only (unless otherwise specified). Shipping classification may
be different for bulk packaging.

Canada Transportation of Dangerous Goods - Ground


Proper shipping name: Not regulated
Hazard class or division: None
Identification number: None
Packing group: None

International Air Transportation (ICAO/IATA)


Proper shipping name: Not regulated
Hazard class or division: None
Identification number: None
Packing group: None

Water Transportation (IMO/IMDG)


Proper shipping name: Not regulated
Hazard class or division: None
Identification number: None
Packing group: None

15. REGULATORY INFORMATION


Canada Regulatory Information

CEPA DSL/NDSL Status: All components are listed on or are exempt from listing on the Canadian Domestic
Substances List.

United States Regulatory Information

TSCA 8 (b) Inventory Status: All components are listed or are exempt from listing on the Toxic Substances Control Act
Inventory.

16. OTHER INFORMATION


This material safety data sheet contains changes from the previous version in sections: 7, 9 and 16

This product has been classified in accordance with the hazard criteria of the Controlled Products Regulation (CPR), and
the MSDS contains all the information required by the CPR.

Prepared by: Diane Annis, Sr. Regulatory Affairs Specialist

DISCLAIMER: The data contained herein are furnished for information only and are believed to be reliable. However, Henkel
Corporation and its affiliates (“Henkel”) does not assume responsibility for any results obtained by persons over whose methods
Henkel has no control. It is the user’s responsibility to determine the suitability of Henkel’s products or any production methods
mentioned herein for a particular purpose, and to adopt such precautions as may be advisable for the protection of property and
persons against any hazards that may be involved in the handling and use of any Henkel’s products. In light of the foregoing,
Henkel specifically disclaims all warranties, express or implied, including warranties of merchantability and fitness for a particular
purpose, arising from sale or use of Henkel’s products. Henkel further disclaims any liability for consequential or incidental damages
of any kind, including lost profits.

IDH number: 135355 Product name: LOCTITE® 242® THREADLOCKER


Page 5 of 5
MATERIAL SAFETY DATA SHEET

1. Product and Company Identification


Product identifier LPS® 1 (Aerosol)
Version # 02
Issue date 10-01-2014
Revision date 10-26-2014
Supersedes date 10-01-2014
CAS # Mixture
Part Number C30116
Product use An industrial lubricant designed to displace moisture from mechanical and electrical equipment,
provide light-duty lubrication and short-term rust prevention.
Manufacturer information LPS Laboratories, a division of Illinois Tool Works, Inc.
4647 Hugh Howell Rd
Tucker, Georgia 30084
United States
www.lpslabs.com
1-800-241-8334/ 770-243-8800
Chemtrec 1-800-424-9300
Supplier Not available.

2. Hazards Identification
Emergency overview DANGER

Flammable aerosol. Contents under pressure. Pressurized container may explode when exposed
to heat or flame. Irritating to eyes and skin. May cause an allergic skin reaction. May cause
drowsiness and dizziness.
Potential health effects
Routes of exposure Inhalation. Ingestion. Skin contact. Eye contact.
Eyes Contact with eyes may cause irritation. Avoid contact with eyes.
Skin May cause sensitization by skin contact. May cause skin irritation. Avoid contact with the skin.
Inhalation Intentional misuse by concentrating and inhaling the product can be harmful or fatal. May cause
irritation of respiratory tract. Prolonged inhalation may be harmful.
Ingestion Exposure by ingestion of an aerosol is unlikely. Irritating. May cause nausea, stomach pain and
vomiting.
Signs and symptoms Symptoms of overexposure may be headache, dizziness, tiredness, nausea and vomiting.
Symptoms may include redness, edema, drying, defatting and cracking of the skin.
Potential environmental effects Harmful to aquatic organisms. May cause long-term adverse effects in the aquatic environment.

3. Composition / Information on Ingredients


Hazardous components CAS # Percent
CARBON DIOXIDE 124-38-9 1-5

Non-hazardous components CAS # Percent


Distillates Petroleum, Hydroteated Light 64742-47-8 70 - 80
Distillates Petroleum Hydrotreated Med 64742-46-7 10 - 20
Sorbitan trioleate 26266-58-0 1-3
Calcium Sulfonate 61789-86-4 0.1 - 1

4. First Aid Measures


First aid procedures
Inhalation Move to fresh air. Get medical attention, if needed.

Material name: LPS® 1 (Aerosol) MSDS CANADA

802 Version #: 02 Revision date: 10-26-2014 Issue date: 10-01-2014 1/8


Skin contact Remove and isolate contaminated clothing and shoes. Immediately flush skin with plenty of water.
Get medical attention if irritation develops and persists. Wash clothing separately before reuse.
Eye contact Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, if
present and easy to do. Continue rinsing. Get medical attention if irritation develops and persists.
Ingestion In the unlikely event of swallowing contact a physician or poison control center. Rinse mouth
thoroughly. Do not induce vomiting without advice from poison control center. If vomiting occurs,
keep head low so that stomach content doesn't get into the lungs.
General advice Take off contaminated clothing and shoes immediately. If you feel unwell, seek medical advice
(show the label where possible). Ensure that medical personnel are aware of the material(s)
involved, and take precautions to protect themselves. Show this safety data sheet to the doctor in
attendance.

5. Fire Fighting Measures


Flammable properties Flammable by WHMIS criteria. Heat may cause the containers to explode. Ruptured cylinders may
rocket. Vapors may travel considerable distance to a source of ignition and flash back.
Extinguishing media
Suitable extinguishing Powder. Alcohol resistant foam. Water spray. Dry chemicals. Carbon dioxide (CO2).
media
Unsuitable extinguishing Do not use water jet as an extinguisher, as this will spread the fire.
media
Protection of firefighters
Specific hazards arising Contents under pressure. Pressurized container may explode when exposed to heat or flame.
from the chemical
Protective equipment for Firefighters should wear full protective clothing including self contained breathing apparatus.
firefighters Structural firefighters protective clothing will only provide limited protection.
Fire fighting Firefighters must use standard protective equipment including flame retardant coat, helmet with
equipment/instructions face shield, gloves, rubber boots, and in enclosed spaces, SCBA. Cool containers exposed to heat
with water spray and remove container, if no risk is involved. Containers should be cooled with
water to prevent vapor pressure build up. For massive fire in cargo area, use unmanned hose
holder or monitor nozzles, if possible. If not, withdraw and let fire burn out.
Specific methods Cool containers exposed to flames with water until well after the fire is out.
Explosion data
Sensitivity to static None known.
discharge
Sensitivity to mechanical None known.
impact
Hazardous combustion May include oxides of carbon.
products

6. Accidental Release Measures


Personal precautions Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Keep out of
low areas. Pay attention to flashback. Many gases are heavier than air and will spread along
ground and collect in low or confined areas (sewers, basements, tanks). Do not touch damaged
containers or spilled material unless wearing appropriate protective clothing. Ventilate closed
spaces before entering them. For personal protection, see section 8 of the MSDS.
Environmental precautions Prevent further leakage or spillage if safe to do so. Do not contaminate water.
Methods for containment Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area). Stop leak if
you can do so without risk. Move the cylinder to a safe and open area if the leak is irreparable.
Many gases are heavier than air and will spread along ground and collect in low or confined areas
(sewers, basements, tanks). Use water spray to reduce vapors or divert vapor cloud drift. Keep out
of low areas. Prevent entry into waterways, sewer, basements or confined areas.
Methods for cleaning up Ventilate the area. Should not be released into the environment. Stop the flow of material, if this is
without risk. Isolate area until gas has dispersed. Clean up in accordance with all applicable
regulations. For waste disposal, see section 13 of the MSDS.
Other information Clean up in accordance with all applicable regulations.

Material name: LPS® 1 (Aerosol) MSDS CANADA

802 Version #: 02 Revision date: 10-26-2014 Issue date: 10-01-2014 2/8


7. Handling and Storage
Handling Pressurized container: Do not pierce or burn, even after use. Do not use if spray button is missing
or defective. Do not spray on a naked flame or any other incandescent material. Do not smoke
while using or until sprayed surface is thoroughly dry. Do not cut, weld, solder, drill, grind, or
expose containers to heat, flame, sparks, or other sources of ignition. Do not re-use empty
containers. Do not get this material in contact with eyes. Do not get this material in contact with
skin. Avoid breathing mist or vapor. Avoid prolonged exposure. Do not get this material on
clothing. When using do not eat or drink. Do not use in areas without adequate ventilation. Wash
thoroughly after handling. Avoid release to the environment.
Storage Contents under pressure. The pressure in sealed containers can increase under the influence of
heat. Do not expose to heat or store at temperatures above 120°F/49°C as can may burst. Do not
puncture, incinerate or crush. Do not handle or store near an open flame, heat or other sources of
ignition. Store in a closed container away from incompatible materials. Store in a well-ventilated
place. Keep out of the reach of children. Use care in handling/storage. Store away from
incompatible materials (see Section 10 of the MSDS).

8. Exposure Controls / Personal Protection


Occupational exposure limits
ACGIH
Components Type Value Form

Distillates Petroleum, TWA 5 mg/m3 Oil mist


Hydroteated Light (CAS
64742-47-8)
US. ACGIH Threshold Limit Values
Components Type Value
CARBON DIOXIDE (CAS STEL 30000 ppm
124-38-9)
TWA 5000 ppm
Canada. Alberta OELs (Occupational Health & Safety Code, Schedule 1, Table 2)
Components Type Value
CARBON DIOXIDE (CAS STEL 54000 mg/m3
124-38-9)
30000 ppm
TWA 9000 mg/m3
5000 ppm
Canada. British Columbia OELs. (Occupational Exposure Limits for Chemical Substances, Occupational Health and
Safety Regulation 296/97, as amended)
Components Type Value Form
CARBON DIOXIDE (CAS STEL 15000 ppm
124-38-9)
TWA 5000 ppm
Distillates Petroleum, TWA 200 mg/m3 Non-aerosol.
Hydroteated Light (CAS
64742-47-8)
Canada. Manitoba OELs (Reg. 217/2006, The Workplace Safety And Health Act)
Components Type Value
CARBON DIOXIDE (CAS STEL 30000 ppm
124-38-9)
TWA 5000 ppm
Canada. Ontario OELs. (Control of Exposure to Biological or Chemical Agents)
Components Type Value
CARBON DIOXIDE (CAS STEL 30000 ppm
124-38-9)
TWA 5000 ppm
Canada. Quebec OELs. (Ministry of Labor - Regulation Respecting the Quality of the Work Environment)
Components Type Value
CARBON DIOXIDE (CAS STEL 54000 mg/m3
124-38-9)

Material name: LPS® 1 (Aerosol) MSDS CANADA

802 Version #: 02 Revision date: 10-26-2014 Issue date: 10-01-2014 3/8


Canada. Quebec OELs. (Ministry of Labor - Regulation Respecting the Quality of the Work Environment)
Components Type Value
30000 ppm
TWA 9000 mg/m3
5000 ppm
U.S. - OSHA
Components Type Value Form

Distillates Petroleum, PEL 5 mg/m3 Oil mist


Hydroteated Light (CAS
64742-47-8)
US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000)
Components Type Value
CARBON DIOXIDE (CAS PEL 9000 mg/m3
124-38-9)
5000 ppm
Biological limit values No biological exposure limits noted for the ingredient(s).
Exposure guidelines
Canada - British Columbia OELs: Skin designation
Distillates Petroleum, Hydroteated Light (CAS Can be absorbed through the skin.
64742-47-8)
Engineering controls Good general ventilation (typically 10 air changes per hour) should be used. Ventilation rates
should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation,
or other engineering controls to maintain airborne levels below recommended exposure limits. If
exposure limits have not been established, maintain airborne levels to an acceptable level. Ensure
adequate ventilation, especially in confined areas.
Personal protective equipment
Eye/face protection Wear safety glasses with side shields (or goggles).
Skin protection Avoid contact with the skin. Wear appropriate chemical resistant clothing.
Respiratory protection When workers are facing concentrations above the exposure limit they must use appropriate
certified respirators.
Hand protection Chemical resistant gloves are recommended.

9. Physical & Chemical Properties


Appearance Liquid.
Physical state Gas.
Form Aerosol.
Color Amber.
Odor Characteristic.
Odor threshold Not available.
pH Not applicable
Vapor pressure < 0.05 mm Hg @ 20°C
Vapor density > 1 (air = 1)
Boiling point 415.4 °F (213 °C)
Melting point/Freezing point < -58 °F (< -50 °C)
Solubility (water) Not soluble
Specific gravity 0.79 - 0.81 @ 20°C
Relative density 0.79 - 0.81 @ 20°C
Flash point 174.2 °F (79.0 °C) Tag Closed Cup (dispensed liquid)
Flammability limits in air, 7%
upper, % by volume
Flammability limits in air, 0.6 %
lower, % by volume
Auto-ignition temperature > 442.4 °F (> 228 °C)
VOC 0.4 % per US State & Federal Consumer Product Regulations
Material name: LPS® 1 (Aerosol) MSDS CANADA

802 Version #: 02 Revision date: 10-26-2014 Issue date: 10-01-2014 4/8


Evaporation rate < 0.1 (BuAc = 1)
Viscosity < 3.8 cSt @ 25°C
Percent volatile 95 - 96 %
Partition coefficient <1
(n-octanol/water)
Other data
Decomposition Not established
temperature
Flammability (solid, gas) Flammable gas.
Heat of combustion Not established

10. Chemical Stability & Reactivity Information


Chemical stability Material is stable under normal conditions.
Conditions to avoid Avoid temperatures exceeding the flash point. Contact with incompatible materials.
Incompatible materials Oxidizing agents.
Hazardous decomposition Carbon oxides.
products
Possibility of hazardous Hazardous polymerization does not occur.
reactions

11. Toxicological Information


Toxicological data
Components Species Test Results
Calcium Sulfonate (CAS 61789-86-4)
Acute
Dermal
LD50 Rabbit > 2000 mg/kg, 24 Hours
Rat > 2000 mg/kg, 24 Hours
Inhalation
LC50 Rat > 1.9 mg/l, 4 Hours
Oral
LD50 Rat 10000 - 20000 mg/kg
Distillates Petroleum Hydrotreated Med (CAS 64742-46-7)
Acute
Dermal
LD50 Rabbit > 2000 mg/kg, 24 Hours
Inhalation
LC50 Rat 7640 mg/m3, 4 Hours
1.72 mg/l, 4 Hours
Distillates Petroleum, Hydroteated Light (CAS 64742-47-8)
Acute
Dermal
LD50 Rabbit > 2000 mg/kg
> 2000 mg/kg, 24 Hours
Inhalation
LC50 Cat > 6.4 mg/l, 6 Hours
Rat > 7.5 mg/l, 6 Hours
> 4.3 mg/l, 4 Hours
> 0.1 mg/l, 8 Hours
Oral
LD50 Rat > 5000 mg/kg

Material name: LPS® 1 (Aerosol) MSDS CANADA

802 Version #: 02 Revision date: 10-26-2014 Issue date: 10-01-2014 5/8


Components Species Test Results
METHYL SALICYLATE (CAS 119-36-8)
Acute
Dermal
LD50 Guinea pig 0.7 ml/kg
Oral
LD50 Dog 2.1 g/kg
Guinea pig 1060 mg/kg
1.06 g/kg
Rabbit 2.8 g/kg
Rat 887 mg/kg
0.887 g/kg

Acute effects Narcotic effects. May cause an allergic skin reaction.


Sensitization Not classified.
Local effects Irritating to eyes. Irritating to skin. Ingestion may cause gastrointestinal irritation, nausea, vomiting
and diarrhea.
Chronic effects Prolonged inhalation may be harmful.
Carcinogenicity This product is not considered to be a carcinogen by IARC, ACGIH, NTP, or OSHA.
Skin corrosion/irritation Causes skin irritation.
Serious eye damage/irritation Direct contact with eyes may cause temporary irritation.
Mutagenicity No data available to indicate product or any components present at greater than 0.1% are
mutagenic or genotoxic.
Reproductive effects This product is not expected to cause reproductive or developmental effects.
Teratogenicity Not available.
Symptoms and target organs Symptoms may include stinging, tearing, redness, swelling, and blurred vision. Skin irritation.
Exposure may cause temporary irritation, redness, or discomfort. Defatting of the skin. Rash.
Vapors have a narcotic effect and may cause headache, fatigue, dizziness and nausea. Decrease
in motor functions. Behavioral changes.
Synergistic materials Not available.

12. Ecological Information


Ecotoxicological data
Components Species Test Results
Distillates Petroleum, Hydroteated Light (CAS 64742-47-8)
Aquatic
Fish LC50 Rainbow trout,donaldson trout 2.9 mg/l, 96 hours
(Oncorhynchus mykiss)

Ecotoxicity Harmful to aquatic life with long lasting effects.


Environmental effects Harmful to aquatic life with long lasting effects.
Aquatic toxicity Harmful to aquatic organisms. May cause long-term adverse effects in the aquatic environment.
Persistence and degradability Not inherently biodegradable.
Partition coefficient
LPS® 1 (Aerosol) <1
METHYL SALICYLATE 2.55
Other adverse effects None known.

13. Disposal Considerations


Disposal instructions Collect and reclaim or dispose in sealed containers at licensed waste disposal site. Contents
under pressure. Do not puncture, incinerate or crush. Do not allow this material to drain into
sewers/water supplies. Dispose in accordance with all applicable regulations.

Material name: LPS® 1 (Aerosol) MSDS CANADA

802 Version #: 02 Revision date: 10-26-2014 Issue date: 10-01-2014 6/8


Waste from residues / unused Dispose of in accordance with local regulations. Empty containers or liners may retain some
products product residues. This material and its container must be disposed of in a safe manner (see:
Disposal instructions).
Contaminated packaging Empty containers should be taken to an approved waste handling site for recycling or disposal.
Since emptied containers may retain product residue, follow label warnings even after container is
emptied. Do not re-use empty containers.

14. Transport Information


TDG
UN number UN1950
UN proper shipping name AEROSOLS, flammable
Transport hazard class(es)
Class 2.1
Subsidiary risk -
Packing group Not applicable.
Environmental hazards No
Special precautions for user Read safety instructions, MSDS and emergency procedures before handling.
IATA
UN number UN1950
UN proper shipping name Aerosols, flammable
Transport hazard class(es)
Class 2.1
Subsidiary risk -
Packing group Not applicable.
Environmental hazards No
ERG Code 10L
Special precautions for user Read safety instructions, MSDS and emergency procedures before handling.
Other information
Passenger and cargo Allowed.
aircraft
Cargo aircraft only Allowed.
IMDG
UN number UN1950
UN proper shipping name AEROSOLS, Flammable
Transport hazard class(es)
Class 2.1
Subsidiary risk -
Label(s) 2.1
Packing group Not applicable.
Environmental hazards
Marine pollutant No
EmS F-D, S-U
Special precautions for user Read safety instructions, MSDS and emergency procedures before handling.
IATA; IMDG; TDG

15. Regulatory Information


Canadian regulations This product has been classified in accordance with the hazard criteria of the CPR and the MSDS
contains all the information required by the CPR.
WHMIS status Controlled

Material name: LPS® 1 (Aerosol) MSDS CANADA

802 Version #: 02 Revision date: 10-26-2014 Issue date: 10-01-2014 7/8


WHMIS classification A - Compressed Gas
B5 - Flammable Aerosols
D2B - Other Toxic Effects-TOXIC
WHMIS labeling

International Inventories
Country(s) or region Inventory name On inventory (yes/no)*
Australia Australian Inventory of Chemical Substances (AICS) Yes
Canada Domestic Substances List (DSL) Yes
Canada Non-Domestic Substances List (NDSL) No
China Inventory of Existing Chemical Substances in China (IECSC) No
Europe European Inventory of Existing Commercial Chemical Yes
Substances (EINECS)
Europe European List of Notified Chemical Substances (ELINCS) No
Japan Inventory of Existing and New Chemical Substances (ENCS) No
Korea Existing Chemicals List (ECL) Yes
New Zealand New Zealand Inventory No
Philippines Philippine Inventory of Chemicals and Chemical Substances Yes
(PICCS)
United States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory Yes
*A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s)
A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing
country(s).

16. Other Information


Disclaimer LPS Laboratories cannot anticipate all conditions under which this information and its product, or
the products of other manufacturers in combination with its product, may be used. It is the user’s
responsibility to ensure safe conditions for handling, storage and disposal of the product, and to
assume liability for loss, injury, damage or expense due to improper use. The information provided
in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date
of its publication. The information given is designed only as a guidance for safe handling, use,
processing, storage, transportation, disposal and release and is not to be considered a warranty or
quality specification. The information relates only to the specific material designated and may not
be valid for such material used in combination with any other materials or in any process, unless
specified in the text.
Prepared by Not available.
This data sheet contains Product and Company Identification: Alternate Trade Names
changes from the previous
version in section(s):

Material name: LPS® 1 (Aerosol) MSDS CANADA

802 Version #: 02 Revision date: 10-26-2014 Issue date: 10-01-2014 8/8


MARVEL OIL CO., INC.
625 WILLOWBROOK CTR PKWY
WILLOWBROOK, IL 60527

SAFETY DATA SHEET

1. Product and Company Identification

1.1 Product Identifier


Product Name: Marvel Air Tool Oil
Product Code (SKU): MM85R1 (50100), MM080R (50093) - See Section 15 for
discontinued SKU’s

1.2 Relevant Identified Uses Of The Substance


Product Use: Engine Oil Additive – Fuel additive (EPA Registered)

1.3 Details of the Supplier of the SDS


Company Name: Marvel Oil Company, Inc.
Street Address: 625 Willowbrook Centre Parkway
City, State, Zip Code: Willowbrook, Illinois 60527

1.4 Emergency Telephone Numbers


Phone Number: 1(630)455-3700
Fax Number: 1(630)455-3868
Transportation: 1(800)424-9300 (CHEMTREC)
Medical Assistance: Call your local Poison Control Center

2. Hazard Identification:
2.1 Classification of the Substance or Mixture
Hazard Classification: Flammable liquid 3
Skin irritation 2
Reproductive Toxicity 2
Aspiration toxicity 1
2.2 Label Elements

Pictogram:
Signal Word: Danger

Hazard Statement: Flammable liquid and vapor. Causes skin irritation.


Suspected of damaging fertility of the un-born child. May be
fatal if swallowed and enters airways.

Precautionary Statement: Keep away from heat, sparks, open flames or hot surfaces.
Do not smoke. Keep containers tightly closed. Ground all
containers and receiving equipment. Use explosion proof
electrical, ventilation, and lighting equipment. Use only non-
sparking tools. Take precautionary measures against static
discharge. Wear protective gloves, clothing, eye glasses
and face shield. Do not handle until all safety precautions
have been read and understood. Wash hands thoroughly
after handling. If exposed, get medical attention. If on skin
or hair, remove immediately all contaminated clothing and
launder before re-use. Wash skin with soap and water. If
skin irritation occurs, get medical attention. If swallowed,
immediately call a poison control center or doctor. Do NOT
induce vomiting. Store in a well ventilated place. Dispose
of contents and container in accordance with all local, state,
national and international regulations.

2.3 Other Hazards


Description of additional HNOC: None

3. Information on Ingredients:

3.1 Substance not applicable

3.2 Mixture
Component CAS Number Concentration (wt%)
Petroleum Distillates (Hydrotreated Heavy 64742-52-5 60-100%
Naphthenic)
Petroleum Distillates (Stoddard Solvent) 8052-41-3 10-30%
Tricresyl Phosphate 1330-78-5 0.1-1.0%
Ortho Dichlorobenzene 95-50-1 0.1-1.0%
Para Dichlorobenzene 106-46-7 <0.1%

4. First Aid Measures:

4.1 Description of First Aid Measures


Inhalation: Remove to fresh air and promote deep breathing. Get medical attention if effects
persist or you feel un-well.
Skin: In case of skin contact, wash thoroughly with soap and water. Remove contaminated
clothing and footwear. Launder clothing before re-use. Call a physician if irritation develops or
persists.
Eyes: In case of eye contact, immediately flush eyes with plenty of water. Remove contact
lenses if worn. If irritation persists, get medical attention
Ingestion: If swallowed, do not induce vomiting. Never give anything by mouth to an
unconscious person. Immediately call a poison control center or physician.

4.2 Most important symptoms and effects – acute and chronic


Inhalation: May cause respiratory tract irritation. Vapors may cause drowsiness or
dizziness.
Skin: Cause skin irritation. Symptoms may include redness, edema, drying,
defatting, and cracking of skin.
Eyes: May cause temporary eye irritation. Symptoms may include discomfort or
pain, excess blinking and tearing, with redness and swelling.
Ingestion: May be fatal if swallowed and enters airways. This product may be
aspirated into the lungs and cause chemical pneumonitis. May cause
stomach distress, nausea, and vomiting.
4.3 Indication of any immediate medical attention and special treatment
Symptoms may not appear immediately. Seek medical attention if effects develop or persist and
you feel un-well.

5. Fire Fighting Measures:

5.1 Extinguishing media


Carbon dioxide, dry chemical, and alcohol foam
5.2 Special hazards arising from the substance or mixture
CO2, CO, and hydrocarbons

5.3 Advice for Fire Fighters


Keep up wind of fire. Wear full firefighting turn out gear (full bunker gear) and respiratory
protection (SCBA). Cool closed containers exposed to fire with water. See Section 8 for
personal protection.

6. Accidental Release Measures:

6.1 Personal precautions, protective equipment, and emergency procedures


Use personal protection recommended in Section 8. Isolate the hazard area and deny entry to
unnecessary and unprotected personnel. Eliminate all source of ignition.

6.2 Methods and materials for containment and clean up


For containment: Contain and absorb spill with inert material. Place in suitable container for
disposal. Do not flush to sewer or allow to enter waterways. See section 8 for PPE.
For clean up: Take up material and place in a suitable container. Vapors may be heavier than
air and may travel along the ground to a distant source of ignition. Provide adequate ventilation.

7. Handling and Storage

7.1 Precautions for safe handling


Keep away from source of ignition. Do not smoke. Take precaution to eliminate static discharge.
Avoid contact with skin and eyes. Avoid breathing vapor or mist. Do not swallow. Do not eat or
drink while handling. Wash hands with soap and water after handling. Use only non-sparking
tools.
7.2 Conditions for safe storage including incompatibilities
Keep out of reach of children. Store in a well ventilated place. Do not store above 49°C (120°F).
7.3 Specific end uses
Shelf Life: Shelf life is considered to be 7 – 10 years when properly stored.

8. Exposure Control/Personal Protection:

8.1 Control parameters


Exposure Limits 8 hr TWA: (OSHA PEL) (ACGIH TWA)
Petroleum Distillates (Hydrotreated Heavy not applicable not applicable
Naphthenic)
Petroleum Distillates (Stoddard Solvent) 500 ppm 100 ppm
Tricresyl Phosphate not applicable not applicable
Ortho Dichlorobenzene 50 ppm 25 ppm
Para Dichlorobenzene 75 ppm 10 ppm
8.2 Exposure controls
Use adequate ventilation to keep exposure below recommended limits. Ensure that eye wash
station and safety shower are close to work station.
Hand Protection Equipment: Wear chemical resistant gloves to prevent skin contact.
Eye Protection Equipment: Wear safety glasses or splash goggles to prevent eye contact.
Skin and Body Protection: Wear suitable protective clothing.
Respiration/Ventilation Protection Requirements: Provide good ventilation.
Ingestion Protection Requirements: Do not eat, drink or smoke while handling. Wash hands
with soap and water after handling. Launder all clothing and foot wear before re-use.

9. Physical And Chemical Properties:

9.1 Information of basic chemical and physical properties


Physical Form: thin liquid
Color: clear red
Odor: typical oily
Odor Threshold: not available
pH: not applicable – oil based product
Melting Point/Freeze Point: -51϶C (-60϶F)
Initial Boiling Point: not available
Flash Point (Seta Closed Cup): 53϶C (128϶F)
Flammability Limits: Explosive Limits: Upper: not available Lower: not available
Evaporation Rate: not available
Flammability Solid/Gas: not applicable
Vapor Pressure: not available
Vapor Density: not available
Specific Gravity: 0.876
Solubility in Water: insoluble
Auto Ignition Temperature: not available
Partition coefficient (n/octonol/water): not available
Viscosity (Kinimatic @ 100϶C): 2.0 – 3.0 cSt

9. 2 Other information
% NVM by Weight: 75.0%
% VOC Content (California): 24.92%

10. Stability and Reactivity:

10.1 Reactivity
Does not react under normal conditions
10.2 Chemical stability
Stable
10.3 Possibility of hazardous reactions
Does not react under normal conditions
10.4 Conditions to avoid
Heat and incompatible materials
10.5 Incompatible materials
Strong oxidizers such as bleach and peroxides
10.6 Hazardous decomposition products
CO2, CO and hydrocarbons

11. Toxicological Information:


11.1 Information on Toxicological effects

Marvel Mystery Oil


LD50 – Oral Rat >2000 mg/Kg
LD50 – Dermal Rabbit >2000 mg/Kg
LC50 – Inhalation Rat >20 mg/L (4 hr)

Petroleum Distillates Hydrotreated Heavy Naphthenic (64742-52-5)


LD50 – Oral Rat >5000 mg/Kg
LD50 – Dermal Rabbit >5000 mg/Kg
LC50 – Inhalation Rat >5 mg/L (4 hr)

Tricresyl Phosphate (1330-78-5)


LD50 – Oral Rat 3000 mg/Kg

o-Dichlorobenzene (95-50-1)
LD50 – Oral Rat 500 mg/Kg
LD50 – Dermal Rabbit >10000 mg/Kg
LC50 – Inhalation Rat 8.15 mg/L (4 hr)

p-Dichlorobenzene (106-46-7)
LD50 – Oral Rat >2000 mg/Kg
LD50 – Dermal Rabbit >2000 mg/Kg

Skin corrosion/irritation Causes skin irritation


Serious eye damage/irritation Based on available data, classification data are not met
Respiratory or skin sensitization Based on available data, classification data are not met
Germ cell mutagenicity Based on available data, classification data are not met
Carcinogenicity Based on available data, classification data are not met

o-Dichlorobenzene (95-50-1) IARC Group 3 – Not Classified


p-dichlorobenzene (106-46-7) IARC Group 2B – Possible carcinogen to humans.
NTP 1-Evidence of Carcinogenicity 3, Reasonably
anticipated to be a human Carcinogen

Reproductive toxicity Suspected of damaging fertility of un-born child


Specific target organs – single exposure
Based on available data, classification data are not met
Specific target organs – repeated exposure
Based on available data, classification data are not met
Aspiration hazard May be fatal if swallowed and enters air ways.
Symptoms/injuries after inhalation May cause respiratory tract irritation. Vapors may cause
drowsiness and dizziness.
Symptoms/injuries after skin contact Cause skin irritation. Symptoms may include redness,
edema, drying, defatting, and cracking of skin.
Symptoms/injuries after eye contact May cause temporary eye irritation. Symptoms may include
discomfort or pain, excess blinking and tearing, with redness
and swelling.
Symptoms/injuries after ingestion May be fatal if swallowed and enters airways. This product
may be aspirated into the lungs and cause chemical
pneumonitis. May cause stomach distress, nausea, and
vomiting.

12. Ecological Information:

12.1 Toxicity
Not recommended for release into aquatic systems without treatment
12.2 Persistence and degradability
Not established
12.3 Bioaccumulative potential
Not established
12.4 Mobility in soil
Not established
12.5 Other adverse effects
None known

13. Disposal Considerations:


13.1 Waste treatment methods
RCRA Hazardous Waste: Regulated as a hazardous waste (D-001 Ignitable).
Waste Disposal Method: Dispose of in accordance with local, state and federal
regulations
Waste Disposal Vessel: Metal drums are recommended.

14. Transportation Information:

14.1 UN number
1268
14.2 UN Proper shipping name
Petroleum Distillate n.o.s.
14.3 Transport Hazard class
3
14.4 Packaging group
III
14.5 Marine Pollutant
No
14.6 Transportation in Bulk
Not applicable
14.7 Special precautions
Use limited quantities

15. Regulatory Information:

15.1 US Federal Regulations


TSCA Status: All ingredients are commercially available and listed by the manufacturer under
TSCA.

15.2 Foreign Regulations

Canadian Status: All materials contained in this product are listed on the Canadian Domestic
Substance List (DSL). Consult Turtle Wax, Inc. regarding status of ingredients.
European Union: All materials contained in this product are listed on EINECS.
AICS: All materials are registered for AICS (Australia)

15.3 State Regulations

State Regulatory Information:


The following chemicals are specifically listed by individual states; other product specific health
and safety data in other sections of the SDS may also be applicable for state requirements. For
details on your regulatory requirements, contact the appropriate agency in your state.

California Prop 65:


CAS Number Concentration State Code
p-Dichlorobenzene (106-46-7) <0.1% Cancer

15.4 HIMS & NFPA Classifications


HIMS Classification: Health 2
Flammability 2
Reactivity 0
NFPA Classification: Health 2
Flammability 2
Reactivity 0

15.5 Discontinued SKU’s All discontinued SKU’s used this same formula.

MM080, MM085, MM85R, MM086, MM088R, MM089

16. Other Information:


Reason For Issue Conversion to OSHA GHS SDS Format
Prepared By James Heidel
Preparer’s Title Technical Director, R&D
SDS Administrator Jean Mayszak - Technical Compliance Manager, R&D
Approval Date March 10, 2015
Supersedes Date December 27, 2012
Revision Number #11

This information is, to the best of Turtle Wax, Inc.’s knowledge and belief, accurate and reliable.
However, no representation, warranty, or guarantee is made to its accuracy, reliability or completeness.
It is the user’s responsibility to satisfy oneself as to the suitableness and completeness of such
information for their own particular use.
Safety Data Sheet
Prepared in accordance with Commission Regulation (EU) 20151830
Revision DateO9-02-2016
Revision Number 6

EVERC@AT
SECTION 1 Identification of the substance/mixture and of the company/undertakinq

1.1 Product identifier 100416


Metal Glaze
1.2 Relevant identified uses of the Automotive repair
substance or mixture and uses
advised against
I 3 Details of the supplier of the ITW Evercoat
safety data sheet
a division of Illinois Tool Works Inc.
6600 Cornell Road
Cincinnati, OH 45242
513-489-7600
1.4 Emergency telephone number CHEM TEL: +1-813-248-0591

SECTION 2 Hazards identification

2.1 Classification of the substance or mixture


Classified in Respiratory Sensitisation Category I
accordance to (EC) No.
127212008 Skin Sensitisation Category 1
Skin Corrosion/Irritation Category 2
Serious Eye Damage/Eye Irritation Category 2
Flammable Liquid Category 3
Hazardous to the aquatic environment Chronic Category 3
-

2.2 Label elements


Labelling according to Regulation (EC) No 1272/2008 [CLP]

Hazard pictograms

Signal Word Danger

Hazard Statements H226 Flammable liquid and vapour.


-

H315 Causes skin irritation.


-

H317 - May cause an allergic skin reaction.


H319 Causes serious eye irritation.
-

Page 1 of 10
Safety Data Sheet
Prepared in accordance with Commission Regulation (EU) 20151830
Revision DateO9-02-2016
Revision Number 6
H334 May cause allergy or asthma symptoms or breathing difficulties if
-

inhaled.
H41 2 Harmful to aquatic life with long lasting effects.
-

Precautionary P233 Keep container tightly closed.


-

Statements
P280 Wear protective gloves/protective clothing/eye protection/face
-

protection.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several
-

minutes. Remove contact lenses, if present and easy to do. Continue


rinsing.
P403÷P235 Store in a well-ventilated place. Keep cool.
-

P261 - Avoid breathing dust/fume/gas/mist/vapours/spray.


P273 Avoid release to the environment.
-

Supplemental Hazard EUH2O8 Contains Acid anhydride. May produce an allergic reaction.
-

information (EU)

2.3 Other hazards No data available

SECTION 3 Compositionhinformation on ingredients


3.1. Substances
Not applicable

3.2. Mixtures

Chemical Name % CAS # (EC) No 127212008 M Factor SCL


Styrene 23.42 100-42-5 Acute Tox. 4; H332 No data No data
Acute Tox. 4; H332 available available
Acute Tox. 4; H332
Eye Irrit. 2; H319
Flam. Liq. 3; H226
Skin Irrit. 2; H315
Zinc Phosphate 1.19 7779-90-0 Aquatic Acute 1; H400 No data No data
Aquatic Chronic 1; H41 0 available available
Acidanhydride 1.18 85-43-8 AquaticChronic3; H412 Nodata Nodata
Eye Dam. 1; H318 available available
Resp. Sens. 1; H334
Skin Sens. 1; H317
EUH2O8

For full text of H-statements; See Section 16

SECTION 4 First aid measures


4.1 Description of first aid measures
Inhalation Remove to fresh air. If breathing is difficult, have a trained individual administer
oxygen. If not breathing, give artificial respiration and have a trained individual

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Safety Data Sheet
Prepared in accordance with Commission Regulation (EU) 20151830
Revision DateO9-02-2016
Revision Number 6

administer oxygen. Get medical attention immediately Get medical attention


immediately. Keep the victim warm and quiet. If the victim has stopped breathing
open airway, loosen collar and belt, and administer artificial respiration. If breathing
is difficult, oxygen may be beneficial if administered by trained personnel,
preferably on a doctor’s advice.
Eye Contact Flush eyes with plenty of water for at least 20 minutes retracting eyelids often. Tilt
the head to prevent chemical from transferring to the uncontaminated eye. Get
immediate medical attention. Immediately flush with plenty of water. After initial
flushing, remove any contact lenses and continue flushing for at least 15 minutes.
Have eyes examined and tested by medical personnel.
Skin Contact Wash with soap and water. Get medical attention if irritation develops or persists.
Remove contaminated clothing and continue flushing with water. Seek medical
advice if symptoms persist Wash clothing before reuse.
Ingestion Do not induce vomiting and seek medical attention immediately. Drink two glasses
of water or milk to dilute. Provide medical care provider with this MSDS. Do not
induce vomiting unless directed to do so by medical personnel.
Self protection of No data available
the first aider

4.2 Most important symptoms and effects, both acute and delayed
Symptom See Section 4.1
4.3 Indication of any immediate medical attention and special treatment needed
Note to Doctor No additional first aid information available

SECTION 5 Firefighting measures

5.1 Extinguishing media


Suitable extinguishing media Use alcohol resistant foam, carbon dioxide, or dry chemical
extinguishing agents. Water may be ineffective but water spray
can be used extinguish a fire if swept across the base of the
flames. Water can absorb heat and keep exposed material from
being damaged by fire. Carbon dioxide Dry chemical
Unsuitable extinguishing media No data available
5.2 Special hazards arising from the substance or mixture
Fire andlor Explosion Hazards Vapors may be ignited by sparks, flames or other sources of
ignition if material is above the flash point giving rise to a fire
(Class B). Vapors are heavier than air and may travel to a source
of ignition and flash back.
Hazardous Combustion Products Carbon dioxide, Carbon monoxide, Phthalic anhydride,
Hydrocarbons
5.3 Advice for firefighters
Fire Fighting Methods and Protection Do not enter fire area without proper protection including
self-contained breathing apparatus and full protective
equipment. Fight fire from a safe distance and a

Page 3 of 10
Safety Data Sheet
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Revision DateOQ-02-2016
Revision Number 6 C
protected location due to the potential of hazardous
vapors and decomposition products. Flammable
component(s) of this material may be lighter than water
and burn while floating on the surface.

SECTION 6 Accidental release measures

6.1 Personal precautions,


protective equipment and
emergency procedures
For Non-emergency Personnel Non-emergency personnel should be kept clear of the area.
For emergency responders No health affects expected from the clean-up of this material if
contact can be avoided. Follow personal protective equipment
recommendations found in Section VIII of this MSDS
6.2 Environmental precautions No data available
6.3 Methods and material for No special spill clean-up considerations. Collect and discard in
containment and cleaning up regular trash. Shut off ignition sources; including electrical
equipment and flames. Do not allow smoking in the area. Use an
inert absorbent such as sand or vermiculite. Place in properly
labeled closed container.
6.4 Reference to other sections Refer to section 13 for disposal information.

SECTION 7 Handling and storage

7.1 Precautions for safe handling Mildly irritating material. Avoid unnecessary exposure. Do not
get in eyes, on skin and clothing Wash hands before eating Use
C
with adequate ventilation Avoid contact with material, avoid
breathing dusts or fumes, use only in a well ventilated area.
7.2 Conditions for safe storage, Store in a cool dry ventilated location. Isolate from incompatible
including any incompatibilities materials and conditions. Keep container(s) closed. Store in a
cool dry place Keep away from heat, sparks, and flame Store in
a tightly closed container
7.3 Specific end use(s) Automotive repair

SECTION 8 Exposure controls/personal protection


Occupational Exposure limit values

Chemical Name ACGIH TLV-TWA ACGIH STEL IDLH


Styrene 20 ppm 40 ppm STEL; 170 No data available
mg/m3 STEL

8.2 Exposure controls

Appropriate engineering controls No exposure limits exist for the constituents of this product. Use
local exhaust ventilation or other engineering controls to minimize
exposures and maintain operator comfort.
Individual protection measures, such as personal protective equipment

Page 4 of 10 C
Safety Data Sheet
Prepared in accordance with Commission Regulation (EU) 20151830
Revision DateO9-02-201 6
Revision Number 6

Eye and face protection Wear chemically resistant safety glasses with side shields when
handling this product. Do not wear contact lenses. Wear goggles
if dusts can reach the exposure limit.
Skin Protection
Hand protection No information available
Other skin protection Not normally considered a skin hazard. Where use can result in
skin contact, practice good personal hygiene and wear a barrier
cream and/or impervious surgical style gloves. Wash hands and
other exposed areas with mild soap and water before eating,
drinking, and when leaving work.
Respiratory Protection Respiratory protection may be required to avoid overexposure
when handling this product. General or local exhaust ventilation
is the preferred means of protection. Use a respirator if general
room ventilation is not available or sufficient to eliminate
symptoms. Follow a respiratory protection program that meets
29 CFR 1910.134 and ANSI Z88.2 requirements whenever work
place conditions warrant the use of a respirator. Respiratory
protection may be required in addition to ventilation depending
upon conditions of use.
Thermal hazards No data available

Environmental exposure controls No data available

SECTION 9 Physical and chemical properties


9.1 Information on basic physical and chemical properties

Appearance Liquid
Colour Green
Odour Aromatic
Odour Threshold No data available
pH Neutral
Melting point I Freezing point -30.6
(°C)
Initial boiling point and boiling 145
range (°C)
Flash Point (°C) 31
Evaporation Rate No data available
Flammability (Solid, gas) No data available
Upperllower flammability or
explosive limits
Upper FlammablelExplosive 6.1
Limit, % in air
Lower Flammable!Explosive 1.1
Limit, % in air
Vapour Pressure 5.0 mmHg @ 68 °F / 20 °C (Styrene)
Vapour Density Heavier than air. Vapors that evolve from this product will tend to

Page 5 of 10
Safety Data Sheet
Prepared in accordance with Commission Regulation (EU) 20151830
Revision DateO9-02-201 6
Revision Number 6
settle and accumulate near the floor.
Relative Density 0.96
Solubility(ies) Minimal; 1-9%
Partition coefficient: n- 1.36
octanollwater
Autoignition Temperature (°C) 490
Decomposition Temperature No data available
Viscosity 20,800 - 25,600
Explosive properties No data available
Oxidizing properties No data available

9.2 Other information No data available

SECTION 10 Stability and reactivity

10.1 Reactivity No data available


10.2 Chemical stability Stable under normal conditions.
10.3 Possibility of hazardous No data available
reactions
10.4 Conditions to avoid Contamination
10.5 Incompatible materials Peroxides; Strong acids; Strong oxidizing agents
10.6 Hazardous decomposition Carbon dioxide Carbon monoxide Hydrocarbons
products

SECTION 11 Toxicological information


11.1 Information on toxicological effects

Acute Toxicity
Based on available data, the classification criteria are not met.

Skin corrosionlirritation
I pH I Neutral

Classification is based on pH and the components listed in Section 3.

Serious eye damagelirritation


pH I Neutral

Classification is based on pH and the components listed in Section 3.

Respiratory or skin sensitization


EUH2O8 Contains Acid anhydride. May produce an allergic reaction.
-

Classification has been based on toxicological information of the components in Section 3.

Germ cell mutagenicity


Based on available data, the classification criteria are not met.

Page 6 of 10
Safety Data Sheet
Prepared in accordance with Commission Regulation (EU) 20151830
Revision DateO9-OZ-201 6
Revision Number 6
Carcinogenicity
Based on available data, the classification criteria are not met.

Reproductive toxicity
Based on available data, the classification criteria are not met.

STOT-single exposure
Based on available data, the classification criteria are not met.

STOT-repeated exposure
Based on available data, the classification criteria are not met.

Aspiration hazard
Based on available data, the classification criteria are not met.

SECTION 12 Ecological information

12.1 Toxicity No data available

Ecotoxicity Data
Chemical Name CAS Number Aquatic EC5O Aquatic ERC5O Aquatic LC5O
Crustacea Algae Fish

.
No data available

12.2 Persistence and No data available


degradability
12.3 Bioaccumulative No data
potential
12.4 Mobility in soil No data available
12.5 Results of PBT and No data available
vPvB assessment
12.6 Other adverse No data available
effects
12.7 Additional No data available
information

SECTION 13 Disposal considerations


13.1 Waste treatment methods
Waste Description for Spent Spent or discarded material is a hazardous waste.
Product
Disposal Methods Dispose of by incineration following Federal, State, Local, or
Provincial regulations.
Waste Disposal Code(s) W080111
(European Waste Catalogue)

SECTION 14 Transport information

Page 7 of 10
Safety Data Sheet
Prepared in accordance with Commission Regulation (EU) 20151830
Revision DateO9-02-2016
Revision Number 6

Ground:
14.1 UN number: UN3269
14.2 UN proper shipping name: POLYESTER RESIN KIT
14.3 Transport hazard class(es): 3
14.4 Packing group: III
Exemptions: Limited Quantity

Air:
14.1 UN number: UN3269
14.2 UN proper shipping name: POLYESTER RESIN KIT
14.3 Transport hazard class(es): 3
14.4 Packing group: III

Water:
14.1 UN number: UN3269
14.2 UN proper shipping name: POLYESTER RESIN KIT
14.3 Transport hazard class(es): 3
14.4 Packing group: III
Exemptions: Limited Quantity

14.5 Environmental hazards: Yes


14.6 Special precautions for user: No data available
14.7 Transport in bulk according No data available
to Annex II of MARPOL and the
IBC Code:

SECTION 15 Regulatory information


15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture

Chemical Name EINECS SVHC

Styrene Y N
Zinc Phosphate Y N
Acid anhydride Y N
Acetone Y N
Diacetone alcohol Y N
1, 4 Benzenediol, 2,3,5-Trimethyl- Y N
1 ,4-Naphthoguinone Y N
p-Toluidene Y N
Styrene Oxide Y N

15.2 Chemical safety assessment No data available

SECTION 16 Other information

Page8oflO —
Safety Data Sheet
Prepared in accordance with Commission Regulation (EU) 201 5/830
Revision DateO9-02-2016
Revision Number 6

SDS Abbreviations: No data available


References: No data available
Hazard phrase(s) H225 Highly flammable liquid and vapour.
-

referenced in section 3
H226 Flammable liquid and vapour.
-

H301 - Toxic if swallowed.


H302 Harmful if swallowed.
-

H31 I - Toxic in contact with skin.


H31 2 Harmful in contact with skin.
-

H31 5 Causes skin irritation.


-

H317 May cause an allergic skin reaction.


-

H318 Causes serious eye damage.


-

H319 Causes serious eye irritation.


-

H331 - Toxic if inhaled.


H332 Harmful if inhaled.
-

H334 May cause allergy or asthma symptoms or breathing difficulties if


-

inhaled.
H336 - May cause drowsiness or dizziness.
H350 - May cause cancer.
H351 - Suspected of causing cancer.
H400 Very toxic to aquatic life.
-

H41 0 Very toxic to aquatic life with long lasting effects.


-

H41 2 - Harmful to aquatic life with long lasting effects.

Precautionary
Statements
Prevention P201 Obtain special instructions before use.
-

P202 Do not handle until all safety precautions have been read and
-

understood.
P210 Keep away from heat/sparks/open flames/hot surfaces. No
- —

smoking.
P233 Keep container tightly closed.
-

P240 Ground/bond container and receiving equipment.


-

P241 Use explosion-proof electrical/ventilating/lighting equipment.


-

P242 Use only non-sparking tools.


-

P243 Take precautionary measures against static discharge.


-

P260 Do not breathe dust/fume/gas/mist/vapours/spray.


-

P261 Avoid breathing dust/fume/gas/mist/vapours/spray.


-

P264 Wash thoroughly after handling.


-

P270 Do no eat, drink or smoke when using this product.


-

Page 9 of 10
Safety Data Sheet
Prepared in accordance with Commission Regulation (EU) 20151830
Revision DateOg-02-2016
Revision Number 6
P272 Contaminated work clothing should not be allowed out of the
-

workplace.
P273 Avoid release to the environment.
-

P280 Wear protective gloves/protective clothing/eye protection/face


-

protection.
P284 Wear respiratory protection.
-

Response P302+P352 IF ON SKIN: Wash with plenty of soap and water.


-

P303+P361 +P353 IF ON SKIN (or hair): Remove/Take off immediately all


-

contaminated clothing. Rinse skin with water/shower.


P304+P341 IF INHALED: If breathing is difficult, remove victim to fresh air
-

and keep at rest in a position comfortable for breathing.


P305+P351+P338 IF IN EYES: Rinse cautiously with water for several
-

minutes. Remove contact lenses, if present and easy to do. Continue


rinsing.
P307÷P31 1 IF exposed: Call a POISON CENTER or doctor/physician.
-

P308+P313 IF exposed or concerned: Get medical advice/attention.


-

P314- Get medical advice/attention if you feel unwell.


P321 Specific treatment (see on this label).
-

P332+P313 If skin irritation occurs: Get medical advice/attention.


-

P333+P313 If skin irritation or rash occurs: Get medical advice/attention.


-

P337+P313 If eye irritation persists: Get medical advice/attention.


-

P342+P31 I If experiencing respiratory symptoms: Call a POISON


-

CENTER or doctor/physician.
P363 Wash contaminated clothing before reuse.
-

P370+P378 In case of fire: Use for extinction.


-

Storage P233 Keep container tightly closed.


-

P403+P235 Store in a well-ventilated place. Keep cool.


-

P405 Store locked up.


-

Disposal P501 Dispose of contents/container in accordance with


-

local/regional/national/international regulation for hazardous wastes.

NOTICE: The information accumulated herein is believed to be correct as of the date issued from sources, which
are believed to be accurate and reliable. Since it is not possible to anticipate all circumstances of use, recipients
are advised to confirm, in advance of need, that the information is current, applicable and suitable to their
circumstances

PagelOoflO C
MATERIAL SAFETY DATA SHEET
Lloyds Laboratories Inc.

Moovit (Aerosol) Part # 11008, 11010, 11014


SECTION 1: PRODUCT AND COMPANY IDENTIFICATION

PRODUCT NAME: MOOVIT PRODUCT USE: Penetrating Lubricant.

MANUFACTURER: Lloyds Laboratories Inc. SUPPLIER: Lloyds Laboratories Inc.

ADDRESS: 613 Neal Drive, ADDRESS: 613 Neal Drive,


Peterborough, Peterborough,
Ontario, Ontario,
K9J 6X7 K9J 6X7

EMERGENCY #: 1 800 361-6766 EMERGENCY #: 1 800 361-6766

SECTION II: INFORMATION ON INGREDIENTS

Ingredients CAS# Wt% OSHA-TWA ACGIH-TWA LD50

Propane 74-98-6 7-13 1800 mg/m3 4508 mg/m3 Not available

Isobutane 75-28-5 7-13 Not available Not available Vapour LC 50 Acute: 0.0057
ppm 0.25 hours Rat.

SECTION III: HAZARDOUS IDENTIFICATION

Route of Entry: Eye, skin contact, ingestion.


Potential Health Effects:
Eye Contact: May cause irritation to eyes.
Skin Contact: May cause irritation upon repeated/prolonged contact.
Inhalation: May cause slight nose, throat and respiratory tract irritation.
Ingestion: May cause irritation to mouth, esophagus and stomach. May cause
gastric tract upset and/or damage.
Chronic Effects:
Carcinogenicity: No ingredients listed IARC or NTP or ACGIC. Non hazardous by
WHMIS/OSHA criteria.
Teratogenicity, The ingredients in this product were found not to be mutagenic when
Mutagenicity, tested by the Ames Assay, (OECD Guidelines for chemical testing,
Reproductive Effects: sec.471).
Skin: Repeated or prolonged exposures to dilutions can cause drying,
defatting and dermatitis.

Page: 1 of 4
MATERIAL SAFETY DATA SHEET
Lloyds Laboratories Inc.

Moovit (Aerosol) Part # 11008, 11010, 11014


SECTION IV: FIRST AID MEASURES

Eye Contact: Immediately flush with water for 15 minutes. Holding eyelids open during flushing. If
irritation persists, repeat flushing and obtain medical attention immediately.
Skin Contact: Flush with water. Remove contaminated clothing and launder before reuse.
Inhalation: Move victim to fresh air. If conscious, have victim take deep, slow breaths. Seek
medical attention if symptoms persist.
Ingestion: DO NOT INDUCE VOMITING. Rinse mouth with water, and then drink one glass of
water. Seek medical attention. Do not give anything to victim if unconscious or
convulsing.

SECTION V: FIRE FIGHTING MEASURES

Flammability: NFPA 30B Level 1 Aerosol.


Flash Point deg (C,TCC):

Means of Extinction: Use water spray to keep fire exposed containers cool. Dry chemicals, carbon
dioxide. Fight fire from protected location or maximum possible distance.
Special Fire Hazards: Fire fighters should wear self contained breathing apparatus as for surrounding
fire. Aerosol product - containers may rocket or explode.
Autoignition temperature: Not applicable.
Flame projection: 28.0 cm.
Sensitivity to static Not applicable.
discharge:
Unusual Fire and Explosion Aerosol product - containers may rocket or explode.
Hazards:
Hazardous decomposition Oxides of carbon, oxides of nitrogen.
products:

SECTION VI: ACCIDENTAL RELEASE MEASURES

Leak and Spill Before attempting clean up, refer to the hazard data provided above. Small spills
Procedures: may be absorbed with non reactive absorbent and placed in suitable, covered,
labeled container. For large quantities, dispose of in accordance with local,
provincial/ state or federal regulations.
For large spills prevent from entering sewers and waterways. For large spills
provide diking to prevent spreading.

SECTION VII: HANDLING AND STORAGE

Storage Requirements: KEEP OUT OF REACH OF CHILDREN.


Store in a dry, cool and well ventilated area. Protect from freezing. Do not
puncture or incinerate. Pressurized container: protect from sunlight and do not
expose to temperatures exceeding 120ºF or 50ºC. Do not pierce or burn, even
after use.

Page: 2 of 4
MATERIAL SAFETY DATA SHEET
Lloyds Laboratories Inc.

Moovit (Aerosol) Part # 11008, 11010, 11014


SECTION VIII: EXPOSURE CONTROL/PERSONAL PROTECTION

Gloves: Not normally required. Use Viton or Nitrile gloves to avoid prolonged or skin
contact repeated.
Eye Protection: Not normally required, if eye contact is possible chemical splash goggles are
recommended.
Respiratory Protection: Not normally required if good ventilation is maintained.
Other Protective As required by employer code. Eye bath, safety shower, protective clothing.
Equipment:
Engineering Controls: General ventilation normally required.

SECTION IX: PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Aerosol Odour and Appearance: Odourless, Odour Threshold Not
Opaque Purple applicable
Vapour Pressure 4394.5 Vapour Density (Air=1) Not Boiling Point (ºC) Not
(mm Hg): applicable applicable
% Volatile (Wt %): 7-13 % Solubility in water(20ºC) None Freezing Point (ºC) -50ºC

pH Not Specific Gravity .85 Evaporation Rate Not


applicable (nBuAc=1) applicable
Coeff. Water/Oil Not
Dist. applicable

SECTION X: STABILITY AND REACTIVITY

Conditions for Chemical Instability: Stable under normal conditions. Excessive heat or contamination
could cause decomposition.
Incompatible Materials: Reducing agents, strong acids, strong caustics, iron and other
metals.
Hazardous Decomposition Products: Oxides of carbon, Oxides of Nitrogen when heated.

SECTION XI: TOXICOLOGICAL INFORMATION

LD 50 values for individual components see section II.


Skin Sensitization (OECD Sec. 406) Non sensitizing.

SECTION XII: ECOLOGICAL INFORMATION

No data available on the adverse effects of this product on the environment.

SECTION XIII: DISPOSAL CONSIDERATIONS

Dispose of in accordance to all local, provincial/state and federal regulations.

Page: 3 of 4
MATERIAL SAFETY DATA SHEET
Lloyds Laboratories Inc.

Moovit (Aerosol) Part # 11008, 11010, 11014


SECTION XIV: TRANSPORTATION

T.D.G. Classification: Please refer to Bill of lading for up to date shipping information.
D.O.T. Classification: Please refer to Bill of lading for up to date shipping information.

SECTION XV: REGULATORY INFORMATION

Occupational Health and Safety


Regulations:
WHMIS Class: Class A Compressed Gas/Class B-5 Flammable aerosol.
OSHA & WHMIS: MSDS prepared pursuant to the Hazard Communication
Standard (CFR29.1920.1200) and Canadian WHMIS regulations.
Environmental Regulatory Lists:
SARA – Section 313 (Toxic Chemical None of these ingredients are listed.
Release Reporting) 40 CFR 372:
CERCLA – Section 102 (Reportable Butane, Propane.
Quantity) 40 CFR 302:
RCRA 40 CFR 261 (Subpart D): None of the ingredients are listed.
CLEAN WATER ACT – Section 311 None of these ingredients are listed.
(Reportable Qty) 40 CFR 116:
CLEAN AIR ACT – Section 312 (List of
Hazardous Pollutants) 40 CFR 63 Flammable substances Propane, Isobutane.
(Subpart C):
National Pollutant Release Inventory: None of these ingredients are listed.
Toxic Substances Control Act (TSCA): All ingredients are registered on the Chemical Substances
Inventory.
Canadian Domestic Substance List All ingredients are registered on the DSL.
(DSL):

SECTION XVI: OTHER INFORMATION

Date: June 7, 2013 Prepared By: Technical Services Telephone: 1 800 361-6766
Group

Disclaimer:
Information for this material safety data sheet was obtained from sources considered technically
accurate and reliable. While every effort has been made to ensure full disclosure of product hazards,
in some cases data is not available and is so stated. Since conditions of actual product use are
beyond the control of supplier, it is assumed that users of this material; have been fully trained
according to the mandatory requirements of WHMIS. No warranty, expressed or implied, is made
and supplier will not be liable for any losses, injuries for consequential damages, which may result
from the use or reliance on any information contained in this form. If user requires independent
information on ingredients in this or other material, we recommend contact with the Canadian
Centre for Occupational Health and Safety (CCOHS) in Hamilton, Ontario (905-572-4400) or CSST in
Montreal, Quebec (514-873-3990).

Page: 4 of 4
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t8531bo Material Safety Data Sheet 15:08
DC & FC TEST DEALER

C H R Y S L E R
HAZARD COMMUNICATION SHEET
5182604 DRAFT PART/COMMTY CD: 0VU01463
PREPARATION DATE: 03-09-10 STNDRD: N/AV SUPPLIER: 86056 MFGR: 03500
OSHA HAZ: YES HAZWOPER HAZ: YES CONS PROD/HAZ SUB: YES
-------------------------------------------------------------------------------
*** SECTION 01 - PRODUCT INFORMATION ***
-------------------------------------------------------------------------------
MFG BY: PART SALES & SERVICE FCA US LLC
26311 LAWRENCE AVE CENTERLINE MI 48015
EMERGENCY PHONE: 248-512-8002 AFTER HOURS: 248-576-8888
DIST BY: PART SALES & SERVICE FCA US LLC
26311 LAWRENCE AVE CENTERLINE MI 48015
EMERGENCY PHONE: 248-512-8002 AFTER HOURS: 248-576-8888
FCA US LLC INDUSTRIAL HYGIENE: 248-512-8260 AFTER HOURS: 248-576-8888
BRAND NAME: MOPAR MULTI-PURPOSE LUBE
MFG ID : N/AV
DESCRIPTION: LUBRICANT-POWERTRAIN,BODY
-------------------------------------------------------------------------------
*** SECTION 02 - INGREDIENTS ***
-------------------------------------------------------------------------------
HAZARDOUS INGREDIENTS: PERCENT
COMM NAME / CAS NO & CHEM NAME: BY WGT OSHA ACGIH CHRYS UNITS NOTATIONS
***EXISTING INGREDIENTS***
STODDARD SOLVENT 60-100 W 100 100 100 PPM
008052-41-3 STODDARD SOLVENT (8C
VM & P NAPHTHA 10-30 W 300 300 100 PPM
008032-32-4 MINERAL SPIRITS L 400 N/AP 400 A3
PETROLEUM PRODUCTS, LIQUEFIED GAS 10-30 W 1000 1000 1000 PPM
068476-86-8 PETROLEUM GASES, LIQ
GENERIC DESC: MULTIPURPOSE LUBRICANT CONTAINING MAINLY MINERAL SPIRITS.
-------------------------------------------------------------------------------
*** SECTION 03 - PHYSICAL DATA ***
-------------------------------------------------------------------------------
BOILING POINT : N/AV F SOLUB IN WATER: NEGLIGIBLE ( < 0.1% )
VAPOR PRESSURE: N/AV EVAP. RATE: N/AV REF: N/AV
VAPOR DENSITY : > 1.000 AT N/AV SPECIFIC GRAVITY: > 0.800 AT 59 F
PH AT FULL STRENGTH: N/AV PH AT REC. DILUT: N/AV
%VOLATILE BY VOL : N/AV VOLATILE ORGANIC COMP: N/AV N/AV
ODOR THRESHOLD: N/AV PPM FOR % POPULATION
FREEZING POINT: N/AV COEFF. OF WATER/OIL DIST: N/AV
APPEARANCE & ODOR: STATE: LIQUID..... ODOR: HYDROCARBON..... COLOR:
YELLOW..... APPEARANCE: CLEAR......
-------------------------------------------------------------------------------
*** SECTION 04 - FIRE AND EXPLOSION DATA ***
-------------------------------------------------------------------------------
FLASH POINT: 104 F PMCC IGN TEMP: N/AV LEL: N/AV UEL: N/AV
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SPECIAL FIRE & EXPLOSION HAZARDS:


CONTENTS UNDER PRESSURE. MAY EXPLODE IF EXPOSED TO HEAT OR FLAME. MATERIAL
IS FLAMMABLE. DO NOT LET IT RUN-OFF TO WATERCOURSE. REACTS ON CONTACT WITH
OXIDIZERS. MIST OR AEROSOL ACCUMULATIONS MAY FLASH IF IGNITED. VAPOR/GAS IS
HEAVIER THAN AIR AND MAY TRAVEL ALONG THE GROUND OR BE MOVED BY VENTILATION
AND CAUSE FLASH FIRES OR BE IGNITED EXPLOSIVELY BY PILOT LIGHTS, OTHER
FLAMES, SPARKS, HEATERS, SMOKING, ELECTRIC MOTORS, OR OTHER SOURCES OF
IGNITION AT LOCATIONS DISTANT FROM THE MATERIAL HANDLING POINT.
EXTINGUISHING MEDIA:
CARBON DIOXIDE, DRY CHEMICAL, FOAM OR WATER FOG OR ALCOHOL FOAM.
SPECIAL FIREFIGHTING PROCEDURES:
USE PROTECTIVE CLOTHING. USE SELF-CONTAINED BREATHING APPARATUS. AVOID
BREATHING VAPOR OR FUMES. USE WATER TO COOL FIRE EXPOSED CONTAINERS. WATER
SPRAY MAY BE INEFFECTIVE. IF WATER IS USED, FOG NOZZLES ARE PREFERABLE.
SENSITIVE TO MECHANICAL IMPACT?: YES SENSITIVE TO STATIC DISCHARGE?: YES
HAZARDOUS COMBUSTION PRODUCTS:
ORGANIC COMPOUNDS, CARBON MONOXIDE AND CARBON DIOXIDE.
FLAME PROJECTION: > 15 IN
-------------------------------------------------------------------------------
*** SECTION 05 - HEALTH HAZARD DATA ***
-------------------------------------------------------------------------------
EFFECTS OF OVEREXPOSURE - ACUTE & CHRONIC:
<<---INHALATION--->> VAPOR AND/OR MIST MAY PRODUCE THE FOLLOWING:
IRRITATION OF UPPER RESPIRATORY TRACT AND MAY BE IRRITATING TO EYES, NOSE,
AND THROAT. HIGH CONCENTRATION MAY PRODUCE THE FOLLOWING: ACUTE NERVOUS
SYSTEM DEPRESSION CHARACTERIZED BY HEADACHE, DIZZINESS, STAGGERING,
CONFUSION, UNCONSCIOUSNESS OR COMA. <<---SKIN CONTACT--->> LIQUID AND/OR
MIST MAY PRODUCE THE FOLLOWING: MINOR IRRITATION TO SLIGHT BURNING OF SKIN.
<<---EYE CONTACT--->> LIQUID AND/OR MIST MAY PRODUCE THE FOLLOWING:
IRRITATION AND TEARING. <<---INGESTION--->> MAY BE HARMFUL IF SWALLOWED.
CAUSES A BURNING SENSATION IN THE MOUTH AND STOMACH AND MUCOUS MEMBRANE
IRRITATION. MAY CAUSE UPSET STOMACH, NAUSEA, VOMITING AND DIARRHEA.
ASPIRATION (GOING DOWN THE WRONG PIPE INTO THE WINDPIPE) MAY CAUSE THE
FOLLOWING: CHEMICAL PNEUMONITIS (AN INFLAMMATION OF THE LUNGS SIMILAR TO
PNEUMONIA, WHICH IS CAUSED BY GETTING THE LIQUID FORM OF A CHEMICAL INTO THE
LUNGS). <<---SPECIAL TOXICITY--->> HIGH CONCENTRATION MAY PRODUCE THE
FOLLOWING: CARDIAC ABNORMALITIES, DAMAGE TO THE NERVOUS SYSTEM AND/OR BRAIN
DAMAGE.
EMERGENCY FIRST AID PROCEDURES:
<<---INHALATION--->> REMOVE TO FRESH AIR AT ONCE. IF PULMONARY SYMPTOMS
DEVELOP, CONSULT A PHYSICIAN. IF BREATHING IS DIFFICULT, GIVE OXYGEN.
ARTIFICIAL RESPIRATION IF BREATHING HAS STOPPED. CARDIAC RESUSCITATION IF
INDICATED. <<---SKIN CONTACT--->> REMOVE CONTAMINATED CLOTHING. WIPE OFF
WITH A CLOTH. IMMEDIATELY FLUSH CONTAMINATED AREA WITH LARGE AMOUNTS OF
WATER. WASH WITH SOAP AND WATER. IF CONDITION PERSISTS, CONSULT A PHYSICIAN.
<<---EYE CONTACT--->> REMOVE CONTACT LENSES TO ASSURE COMPLETE FLUSHING.
RINSE EYES IMMEDIATELY WITH LARGE AMOUNTS OF WATER, OCCASIONALLY LIFTING
Page 2 of 4
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BOTH UPPER AND LOWER LIDS. CONTINUE FOR 15 MINUTES. IF CONDITION PERSISTS,
CONSULT A PHYSICIAN. <<---INGESTION--->> DO NOT INDUCE VOMITING. IF
CONSCIOUS, GIVE LARGE QUANTITIES OF WATER OR MILK. CONTACT A PHYSICIAN.
NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. DO NOT MAKE
UNCONSCIOUS PATIENT VOMIT. IF VOMITING OCCURS, KEEP HEAD BELOW HIPS TO
PREVENT LIQUID FROM SEEPING INTO THE WINDPIPE AND LUNGS.
-------------------------------------------------------------------------------
*** SECTION 06 - REACTIVITY DATA ***
-------------------------------------------------------------------------------
STABILITY: STABLE
CONDITIONS TO AVOID:
HIGH TEMPERATURE, SPARKS OR OPEN FLAME.
MATERIALS TO AVOID:
STRONG OXIDIZING AGENTS.
HAZARDOUS POLYMERIZATION: WILL NOT OCCUR
POLYMERIZATION CONDITIONS TO AVOID:
POLYMERIZATION WILL NOT OCCUR.
HAZARDOUS DECOMPOSITION PRODUCTS:
ORGANIC COMPOUNDS, CARBON MONOXIDE AND CARBON DIOXIDE.
-------------------------------------------------------------------------------
*** SECTION 07 - SPILL OR LEAK PROCEDURES ***
-------------------------------------------------------------------------------
STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED:
WIPE UP OR SCRAPE UP SMALL SPILL OR RESIDUE. ABSORB ON AN INERT MATERIAL.
DISCARD INTO SEALED CONTAINERS FOR DISPOSAL. ELIMINATE ALL IGNITION SOURCES
(FLAMES, HOT SURFACES AND ELECTRICAL, STATIC OR FRICTIONAL SPARKS). WEAR
PROTECTIVE CLOTHING. WEAR RESPIRATORY PROTECTION. AVOID BREATHING VAPORS.
VENTILATE AREA. DO NOT FLUSH INTO SEWER SYSTEM. LARGE SPILL-CONTAIN WITH
DIKE. PUMP INTO STORAGE CONTAINER.
WASTE DISPOSAL METHODS:
DISPOSE OF IN A MANNER CONSISTENT WITH STATE, PROVINCIAL, LOCAL, AND
FEDERAL REGULATIONS.
-------------------------------------------------------------------------------
*** SECTION 08 - SPECIAL PROTECTION ***
-------------------------------------------------------------------------------
RESPIRATORY PROTECTION:
NO SPECIAL PROTECTION NEEDED UNDER NORMAL CONDITIONS. TO MAINTAIN THE TLV,
THE FOLLOWING MAY BE NEEDED: ORGANIC VAPOR RESPIRATOR.
VENTILATION TYPE:
TO MAINTAIN THE TLV, THE FOLLOWING MAY BE NEEDED: GOOD GENERAL VENTILATION
AND/OR LOCAL EXHAUST VENTILATION. VENTILATION EQUIPMENT SHOULD BE EXPLOSION
PROOF. VAPORS ARE HEAVIER THAN AIR. VENTILATION SHOULD DRAW FROM FLOOR LEVEL
TO BE EFFECTIVE.
PROTECTIVE GLOVES:
RECOMMENDED. IMPERMEABLE GLOVES.
EYE PROTECTION:
RECOMMENDED. SAFETY GLASSES WITH SIDE SHIELDS.
Page 3 of 4
99970000 Global Parts Order Processing September 7, 2016
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OTHER PROTECTIVE EQUIPMENT:


TO AVOID PROLONGED SKIN CONTACT, USE THE FOLLOWING: APRON (SAME MATERIAL AS
GLOVES) AND BOOTS (SAME MATERIAL AS GLOVES)-WEAR LONG SLEEVES. A SAFETY
SHOWER MAY BE NEEDED FOR EMERGENCY SITUATIONS. AN EYE WASH MAY BE NEEDED FOR
EMERGENCY SITUATIONS.
-------------------------------------------------------------------------------
*** SECTION 09 - SPECIAL PRECAUTIONS ***
-------------------------------------------------------------------------------
PRECAUTIONS TO BE TAKEN IN HANDLING & STORAGE:
STORE IN A COOL, DRY PLACE. STORE IN A WELL VENTILATED AREA. USE WITH
ADEQUATE VENTILATION. KEEP FROM HEAT, SPARK OR OPEN FLAMES. DO NOT PUNCTURE,
DROP OR SLIDE CONTAINERS. REACTS WITH OXIDIZERS. KEEP VALVE PROTECTION CAP
IN PLACE EXCEPT WHEN USING CYLINDER. OPEN CYLINDER VALVE SLOWLY. KEEP
CONTAINER UPRIGHT AND SECURED AT ALL TIMES. CONTAINERS OF THIS MATERIAL MAY
BE HAZARDOUS WHEN EMPTIED, SINCE EMPTIED CONTAINERS RETAIN PRODUCT RESIDUES
(VAPOR, LIQUID, AND/OR SOLID). DO NOT SMOKE OR EAT WHEN HANDLING THIS
SUBSTANCE; WASH THOROUGHLY AFTER USING. REMOVE CONTAMINATED CLOTHING AND
LAUNDER BEFORE REUSE. MAINTAIN GOOD HOUSEKEEPING AND HYGIENIC PRACTICES.
TAKE "NO SMOKING" PRECAUTIONS.
OTHER PRECAUTIONARY MEASURES:
AVOID BREATHING MIST. AVOID BREATHING VAPOR. AVOID EYE CONTACT. AVOID
PROLONGED OR REPEATED SKIN CONTACT. AVOID INGESTION. ASPIRATION OF MATERIAL
INTO THE LUNGS DUE TO VOMITING CAN CAUSE CHEMICAL PNEUMONITIS, WHICH CAN BE
FATAL. MAINTAIN GOOD HOUSEKEEPING AND HYGIENIC PRACTICES.
-------------------------------------------------------------------------------
*** SECTION 10 - WASTE LABELING INFORMATION ***
-------------------------------------------------------------------------------
DOT LABELING INFORMATION (49 CFR 100-199)
ID#: UN1950 ERG#: 126 HAZARD CLASS - PRMY: 2.1 PACKING GROUP: N/AP
PROPER SHIPPING NAME: WASTE AEROSOLS,FLAMMABLE
LABEL(S) REQUIRED: FLAMMABLE GAS
RCRA INFORMATION (40 CFR 122-124, 260-265)
WASTE CODE(S)/HZD: D001/I ¦ MICH:
THE ABOVE INFORMATION IS BASED ON DATA PROVIDED BY SUPPLIERS. TESTING IS NOT
NEEDED

Page 4 of 4
Safety Data Sheet

BNRG Revision Date 05-Jul-2016


Never-Seez Regular Grade Compound Series Supersedes Date: No information available
Version 1.01
________________________________________________________________________________________

Section 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE


COMPANY/UNDERTAKING
1.1. Product Identifier

Product Name Never-Seez Regular Grade Compound Series


Product Code BNRG

Product(s) Covered See section 16 for more information

1.2. Relevant Identified Uses of the Substance or Mixture and Uses Advised Against

Recommended use Lubricants, greases, release products.


Uses Advised Against No information available

1.3. Details of the Supplier of the Safety Data Sheet

Company Name
Bostik, Inc.
11320 W. Watertown Plank Road
Wauwatosa, Wisconsin 53226 USA
Phone: +1 (800) 843-0844 (Domestic Toll Free)
Phone: +1 (414) 774-2250 (International)
Fax: +1 (414) 774-8075
Email: [email protected]

1.4. Emergency Telephone Number

Emergency Telephone Telephone: 1-800-227-0332


(Outside U.S.) 1-703-527-3887

Section 2: HAZARD IDENTIFICATION


2.1. Classification of the Substance or Mixture

Not a dangerous substance or mixture according to OSHA 29 CFR 1910.1200

2.2. Label Elements

EMERGENCY OVERVIEW

Not a dangerous substance or mixture according to OSHA 29 CFR 1910.1200.

Appearance Paste Physical State Solid Odor Petroleum

Precautionary Statements - Prevention


Not applicable

Precautionary Statements - Response


Not applicable

Page 1 / 10
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Never-Seez Regular Grade Compound Series Supersedes Date: No information available
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________________________________________________________________________________________
Precautionary Statements - Storage
Not applicable

Precautionary Statements - Disposal


Not applicable

Hazards Not Otherwise Classified (HNOC)


Not applicable

Unknown Toxicity
0% of the mixture consists of ingredient(s) of unknown toxicity

2.3. Other Information

No information available.

Section 3: COMPOSITION/INFORMATION ON INGREDIENTS


3.1 Substances
This product is a mixture. Health hazard information is based on its components.

3.2 Mixtures

Chemical Name CAS No Weight-%


Graphite 7782-42-5 10 - 30
Copper 7440-50-8 5 - 10
Zinc oxide 1314-13-2 1-5
Aluminum 7429-90-5 1-5

The exact percentage (concentration) of composition has been withheld as a trade secret.

Section 4: FIRST AID MEASURES


4.1. Description of First Aid Measures

General Advice If medical advice is needed, have product container or label at hand.

Eye contact In case of contact with substance, immediately flush skin or eyes with running water for at
least 20 minutes. If eye irritation persists: Get medical advice/attention.

Skin Contact Wash off immediately with soap and plenty of water while removing all contaminated
clothes and shoes. Wash contaminated clothing before reuse. If skin irritation occurs: Get
medical advice/ attention.

Inhalation Remove victim to fresh air and keep at rest in a position comfortable for breathing. Get
medical attention if symptoms occur.

Ingestion Clean mouth with water and drink afterwards plenty of water. Do NOT induce vomiting.
Never give anything by mouth to an unconscious person. Get medical attention if symptoms
occur.

Self-protection of the First Aider Ensure that medical personnel are aware of the material(s) involved, take precautions to
protect themselves and prevent spread of contamination.

4.2. Most Important Symptoms and Effects, Both Acute and Delayed

Symptoms No information available.

Page 2 / 10
Safety Data Sheet
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Never-Seez Regular Grade Compound Series Supersedes Date: No information available
Version 1.01
________________________________________________________________________________________
4.3. Indication of Any Immediate Medical Attention and Special Treatment Needed

Note to physicians Treat symptomatically.

4.4. Reference to Other Sections

Reference to Other Sections Section 8: EXPOSURE CONTROLS/PERSONAL PROTECTION


Section 11: TOXICOLOGY INFORMATION

Section 5: FIRE-FIGHTING MEASURES


5.1. Extinguishing Media

Suitable Extinguishing Media


Dry chemical, CO2, water spray or regular foam. Move containers from fire area if you can do it without risk. Dike fire-control water
for later disposal.

Unsuitable Extinguishing Media


Do not scatter spilled material with high pressure water streams.

5.2. Special Hazards Arising from the Substance or Mixture

Specific Hazards Arising from the Chemical


Some may burn but none ignite readily.

Explosion Data
Sensitivity to Mechanical Impact None.
Sensitivity to Static Discharge None.

5.3. Advice for Firefighters

Protective Equipment and Precautions for Firefighters


As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full
protective gear.

Section 6: ACCIDENTAL RELEASE MEASURES


6.1. Personal Precautions, Protective Equipment and Emergency Procedures

Personal Precautions Do not touch or walk through spilled material. Stop leak if you can do it without risk.

6.2. Environmental Precautions

Environmental Precautions Prevent entry into waterways, sewers, basements or confined areas.

6.3. Methods and Material for Containment and Cleaning up

Methods for Containment Prevent dust cloud.

Methods for Cleaning up Use personal protective equipment as required. Take up with sand or other
non-combustible absorbent material and place into containers for later disposal. Clean
contaminated surface thoroughly.

6.4. Reference to other sections

Reference to Other Sections Section 7: HANDLING AND STORAGE


Section 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
Section 13: DISPOSAL CONSIDERATIONS

Page 3 / 10
Safety Data Sheet
BNRG Revision Date 05-Jul-2016
Never-Seez Regular Grade Compound Series Supersedes Date: No information available
Version 1.01
________________________________________________________________________________________

Section 7: HANDLING AND STORAGE


7.1. Precautions for Safe Handling

Advice on Safe Handling Use personal protective equipment as required. Handle in accordance with good industrial
hygiene and safety practice. Ensure adequate ventilation, especially in confined areas.

7.2. Conditions for Safe Storage, including any Incompatibilities

Storage Conditions Keep container tightly closed in a dry and well-ventilated place.

Incompatible Materials None known based on information supplied.

7.3. Specific End Use(s)

Other Information No information available.

7.4. References to Other Sections

Reference to Other Sections Section 13: DISPOSAL CONSIDERATIONS


Section 10: STABILITY AND REACTIVITY

Section 8: EXPOSURE CONTROLS/PERSONAL PROTECTION

8.1. Control Parameters

Exposure Guidelines .

Chemical Name ACGIH TLV NIOSH IDLH OSHA PEL Mexico


Graphite TWA: 2 mg/m3 respirable IDLH: 1250 mg/m3 TWA: 15 mg/m3 total dust TWA: 2 mg/m3
7782-42-5 fraction all forms except TWA: 2.5 mg/m3 natural synthetic
graphite fibers respirable dust TWA: 5 mg/m3 respirable
fraction synthetic
TWA: 15 mppcf natural
Copper TWA: 0.2 mg/m3 fume TWA: IDLH: 100 mg/m3 dust, fume TWA: 0.1 mg/m3 fume TWA: 0.2 mg/m3
7440-50-8 1 mg/m3 Cu dust and mist and mist IDLH: 100 mg/m3 TWA: 1 mg/m3 dust and TWA: 1 mg/m3
Cu dust and mist mist STEL: 2 mg/m3
TWA: 1 mg/m3 dust and
mist
TWA: 0.1 mg/m3 fume
TWA: 1 mg/m3 Cu dust and
mist
Zinc oxide STEL: 10 mg/m3 respirable IDLH: 500 mg/m3 TWA: 5 mg/m3 fume TWA: 5 mg/m3
1314-13-2 fraction Ceiling: 15 mg/m3 dust TWA: 15 mg/m3 total dust TWA: 10 mg/m3
TWA: 2 mg/m3 respirable TWA: 5 mg/m3 dust and TWA: 5 mg/m3 respirable STEL: 10 mg/m3
fraction fume fraction
STEL: 10 mg/m3 fume
Aluminum TWA: 1 mg/m3 respirable TWA: 10 mg/m3 total dust TWA: 15 mg/m3 total dust TWA: 10 mg/m3 TWA: 5
7429-90-5 fraction TWA: 5 mg/m3 respirable TWA: 5 mg/m3 respirable mg/m3
dust TWA: 5 mg/m3 Al fraction

Chemical Name Argentina Brazil Chile Venezuela


Graphite TWA: 2 mg/m3 - TWA: 1.6 mg/m3 TWA: 2 mg/m3
7782-42-5
Copper TWA: 0.2 mg/m3 - TWA: 0.16 mg/m3 TWA: 0.2 mg/m3
7440-50-8 TWA: 1 mg/m3 TWA: 0.8 mg/m3 TWA: 1 mg/m3
Zinc oxide TWA: 5 mg/m3 - TWA: 4 mg/m3 STEL: 10 mg/m3
1314-13-2 TWA: 10 mg/m3 TWA: 2 mg/m3
STEL: 10 mg/m3 TWA: 10 mg/m3
Aluminum TWA: 10 mg/m3 TWA: 5 - TWA: 8 mg/m3 TWA: 4 TWA: 10 mg/m3
Page 4 / 10
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________________________________________________________________________________________
7429-90-5 mg/m3 mg/m3

8.2. Exposure Controls

Engineering Controls Showers


Eyewash stations
Ventilation systems.

Personal protective equipment [PPE]


Eye/Face Protection Wear safety glasses with side shields (or goggles).
Skin and Body Protection Wear suitable chemical resistant gloves. The selection of suitable gloves does not only
depend on the material, but also on further marks of quality and various manufacturers.
Respiratory Protection If exposure limits are exceeded or irritation is experienced, NIOSH/MSHA approved
respiratory protection should be worn. Positive-pressure supplied air respirators may be
required for high airborne contaminant concentrations. Respiratory protection must be
provided in accordance with current local regulations.
General Hygiene Considerations When using do not eat, drink or smoke. Wash contaminated clothing before reuse.

Section 9: PHYSICAL AND CHEMICAL PROPERTIES


9.1. Information on Basic Physical and Chemical Properties
Physical State Solid
Appearance Paste
Color Grey
Odor Petroleum
Odor Threshold No information available

Property Values Remar


ks •Met
hod
pH No information available
Melting Point/Freezing Point No information available
Boiling Point No information available
Flash Point 246.1 °C / 475 °F
Evaporation Rate No information available
Flammability (solid, gas) No information available
Flammability Limit in Air
Upper Flammability Limit No information available
Lower Flammability Limit No information available
Vapor Pressure No information available
Vapor Density No information available
Specific Gravity No information available
Water Solubility No information available
Solubility in Other Solvents
Partition Coefficient No information available
Autoignition Temperature No information available
Decomposition Temperature No information available
Kinematic Viscosity No information available

Dynamic Viscosity No information available


Explosive Properties No information available
Oxidizing Properties No information available

9.2. Other Information


Softening Point No information available
Molecular Weight No information available
Solvent Content (%) No information available
Solid Content (%) 100.0

Page 5 / 10
Safety Data Sheet
BNRG Revision Date 05-Jul-2016
Never-Seez Regular Grade Compound Series Supersedes Date: No information available
Version 1.01
________________________________________________________________________________________
Density 1.190 g/cm³
VOC No information available

Section 10: STABILITY AND REACTIVITY


10.1. Reactivity

None under normal use conditions.

10.2. Chemical Stability

Stable under recommended storage conditions.

10.3. Possibility of Hazardous Reactions

None under normal processing.

10.4. Conditions to Avoid

Extremes of temperature and direct sunlight.

10.5. Incompatible Materials

None known based on information supplied.

10.6. Hazardous Decomposition Products

None known based on information supplied.

Section 11: TOXICOLOGY INFORMATION


11.1. Information on Toxicological Effects

Product Information No Data Available


Inhalation No Data Available.
Eye contact No Data Available.
Skin Contact No Data Available.
Ingestion No Data Available.

Component Information

Chemical Name Oral LD50 Dermal LD50 Inhalation LC50


Zinc oxide > 5000 mg/kg ( Rat ) - -
1314-13-2

Delayed and Immediate Effects as well as Chronic Effects from Short and Long-term Exposure

Symptoms No information available.


Skin Corrosion/Irritation No information available.
Serious Eye Damage/Eye Irritation No information available.
Irritation No information available.
Corrosivity No information available.
Sensitization No information available.
Germ Cell Mutagenicity No information available.
Reproductive Toxicity No information available.
Developmental Toxicity No information available.
Teratogenicity No information available.

Page 6 / 10
Safety Data Sheet
BNRG Revision Date 05-Jul-2016
Never-Seez Regular Grade Compound Series Supersedes Date: No information available
Version 1.01
________________________________________________________________________________________
STOT - Single Exposure No information available.
STOT - Repeated Exposure No information available.
Chronic Toxicity May cause adverse liver effects.
Target Organ Effects Central Vascular System (CVS), Eyes, Kidney, Liver, Respiratory system, Skin.
Aspiration Hazard No information available.
Carcinogenicity This product does not contain any carcinogens or potential carcinogens as listed by ACGIH,
OSHA, IARC or NTP at or above 0.1 wt%.

Section 12: ECOLOGICAL INFORMATION

This product contains a chemical which is listed as a severe marine pollutant according to DOT.

12.1. Toxicity

Chemical Name Algae/Aquatic Plants Fish Toxicity to Crustacea


Microorganisms
Copper EC50 72 h 0.0426 - 0.0535 LC50 96 h 0.0068 - 0.0156 EC50 48 h = 0.03 mg/L
7440-50-8 mg/L (Pseudokirchneriella mg/L (Pimephales promelas (Daphnia magna Static)
subcapitata) EC50 96 h ) LC50 96 h = 0.2 mg/L
0.031 - 0.054 mg/L (Pimephales promelas
(Pseudokirchneriella flow-through) LC50 96 h =
subcapitata) 0.052 mg/L (Oncorhynchus
mykiss flow-through) LC50
96 h = 1.25 mg/L (Lepomis
macrochirus static) LC50 96
h = 0.3 mg/L (Cyprinus
carpio semi-static) LC50 96
h < 0.3 mg/L (Pimephales
promelas static) LC50 96 h =
0.8 mg/L (Cyprinus carpio
static) LC50 96 h = 0.112
mg/L (Poecilia reticulata
flow-through)
Zinc oxide LC50 (96h) =0.7 mg/L Fish
1314-13-2 (Danio rerio)

12.2. Persistence and Degradability

No information available.

12.3. Bioaccumulative Potential

No information available.

12.4. Mobility in Soil

No information available.

12.5 Other adverse effects

No information available

Section 13: DISPOSAL CONSIDERATIONS

Page 7 / 10
Safety Data Sheet
BNRG Revision Date 05-Jul-2016
Never-Seez Regular Grade Compound Series Supersedes Date: No information available
Version 1.01
________________________________________________________________________________________
13.1. Waste Treatment Methods

Disposal of Wastes It is the responsibility of the waste generator to determine the toxicity and physical
properties of the material generated to determine the proper waste identification and
disposal methods in compliance with applicable regulations

Contaminated Packaging Dispose of in accordance with federal, state and local regulations

Section 14: TRANSPORTATION INFORMATION

Note: 49 CFR 171.4(c) "Exceptions. Except when all or part of the transportation is by vessel, the
requirements of this subchapter specific to marine pollutants do not apply to non-bulk
packagings transported by motor vehicle, rail car or aircraft."

DOT
UN/ID No UN3077
Proper Shipping Name Environmentally hazardous substances, solid, n.o.s
Hazard Class 9
Packing Group III
Special Provisions TP33, T1, IB8, IP3, N20, 146, A112, 335, 8, B54
Marine Pollutant This product contains a chemical which is listed as a severe marine pollutant according to
DOT.
Description UN3077 Environmentally hazardous substances, solid, n.o.s. (Copper, Zinc oxide), 9, III
Emergency Response Guide 171
Number

IATA
UN/ID No UN3077
Proper Shipping Name Environmentally hazardous substance, solid, n.o.s.
Hazard Class 9
Packing Group III
ERG Code 9L
Special Provisions A158, A179, A97
Description UN3077 Environmentally hazardous substance, solid, n.o.s. (Copper, Zinc oxide), 9, III

IMDG
UN/ID No UN3077
Proper Shipping Name Environmentally hazardous substance, solid, n.o.s.
Hazard Class 9
Packing Group III
EmS-No F-A, S-F
Special Provisions 274, 335
Description UN3077 Environmentally hazardous substance, solid, n.o.s. (Copper, Zinc oxide), 9, III

Section 15: REGULATORY INFORMATION


Global Inventories

TSCA Listed
DSL Listed

Legend:
TSCA - United States Toxic Substances Control Act Section 8(b) Inventory
DSL - Canadian Domestic Substances List
Listed - The components of this product are either listed or exempt from listing on inventory.
Not Listed - One or more components of this product are not listed on inventory.

Page 8 / 10
Safety Data Sheet
BNRG Revision Date 05-Jul-2016
Never-Seez Regular Grade Compound Series Supersedes Date: No information available
Version 1.01
________________________________________________________________________________________
Canada

This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and the
MSDS contains all the information required by the CPR

WHMIS Hazard Class


Non-controlled

United States of America

SARA 313
Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product contains a chemical
or chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372

Chemical Name CAS No


Copper 7440-50-8
Zinc oxide 1314-13-2
Aluminum 7429-90-5

SARA 311/312 Hazard Categories


Acute Health Hazard No
Chronic Health Hazard No
Fire Hazard No
Sudden release of pressure hazard No
Reactive Hazard No

California Proposition 65
This product does not contain one or more substances listed on Proposition 65 at or above 0.01 wt. %.

Europe

Restrictions of Use of Hazardous Substances (RoHS) Directive 2011/65/EU


This product does not contain Lead (7439-92-1), Cadmium (7440-43-9), Mercury (7439-97-6), Hexavalent chromium (7440-47-3),
Polybrominated biphenyls (PBB), and Polybrominated diphenyl ethers (PBDE) above the regulated limit mentioned in this
regulation.

EU-REACH (1907/2006) - Candidate List of Substances of Very High Concern (SVHC) for Authorization in accordance with
Article 59
This product does not contain candidate substances of very high concern at a concentration >=0.1% (Regulation (EC) No.
1907/2006 (REACH), Article 59)

Section 16: OTHER INFORMATION


Product(s) Covered

Page 9 / 10
Safety Data Sheet
BNRG Revision Date 05-Jul-2016
Never-Seez Regular Grade Compound Series Supersedes Date: No information available
Version 1.01
________________________________________________________________________________________
BNRG1-BTC12 N/SEEZ REG GRADE BTC1LB/C12
BNRG1-CTGC12 N/SEEZ REG GRADE Ct1LB/C12
BNRG1-FTC12 N/SEEZ REG GRADE C1LB/C12
BNRG130K1 N/SEEZ REG GRADE FD130LB
BNRG425D1 N/SEEZ REG GRADE MD425LB
BNRG42PS1 N/SEEZ REG GRADE MP42LB/P40
BNRG4TC24 N/SEEZ REG GRADE T4OZ/C24
BNRG8-FTC4 N/SEEZ REG GRADE C8LB(1GL)/C4
BNRG8BTC12 N/SEEZ REG GRADE BTC8OZ/C12
BNRGETC100 N/SEEZ REGGRADE Ppt7.5ML/C100

HMIS Health Hazards 1 Flammability 1 Physical Hazards 0 Personal Protection X

Key or Legend to Abbreviations and Acronyms Used in the Safety Data Sheet
No information available

Key Literature References and Sources for Data


No information available

Prepared By Product Safety & Regulatory Affairs

Revision Date 05-Jul-2016

Revision Note Not applicable.

Training Advice No information available

Additional information No information available

Disclaimer
The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its
publication. The information given is designed only as guidance for safe handling, use, processing, storage, transportation,
disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific
material designated and may not be valid for such material used in combination with any other materials or in any process, unless
specified in the text.

End of Safety Data Sheet

Page 10 / 10
Material Safety Data Sheet

Section 1: Material Identification and Use:

MATERIAL NAME/IDENTIFIER: ONE STEP HAND SANITIZER (ALCOHOL)


MANUFACTURER’S NAME Belvedere International Inc. CHEMICAL NAME: Compounded Product HAZARDS
STREET ADDRESS: 5675 Keaton Crescent CHEMICAL FAMILY: Not Applicable HEALTH 2
CITY: Mississauga CHEMICAL FORMULA: Not Applicable FLAMMABILITY 3
PROVINCE: Ontario MOLECULAR WEIGHT: Not Applicable REACTIVITY 0
POSTAL CODE: L5R 3G3 TRADE NAME: One Step PERSONAL PROTECTION N
EMERGENCY PHONE NO. (905) 568-0700 MATERIAL USE: Sanitizer

Section 2: Hazardous Ingredients:


HAZARDOUS INGREDIENTS % UN, NA, CAS NO. LD-50(SPECIES & ROUTE) LC-50 (SPECIES & ROUTE)
Ethyl Alcohol 62 % CAS #64-17-5 Not Available Not Available
UN # 1170

Section 3: Physical Data:


PHYSICAL STATE: Viscous Liquid BOILING POINT: 78.3 O C
COLOUR: Colourless, Clear FREEZING POINT: - 114.1 O C
ODOUR: Match Standard % VOLATILES: 60 % - 65 %
SPECIFIC GRAVITY: 0.8850 – 0.8950 VAPOUR PRESSURE: Not Available
pH: 7.0-8.0 VAPOUR DENSITY (AIR=1) Not Available
EVAPORATION RATE: 1.7 SOLUBILITY IN WATER (20ºc) Complete

Section 4: Fire and Explosion Data:


FLAMMABILITY: Flammable
CONDITIONS OF FLAMMABILITY Contact with spark or open flame
METHODS OF EXTINCTION: Water/Carbon Dioxide Foam
SPECIAL PROCEDURES: Keep product away from any source of sparks or
open flame
FLASHPOINT (ºC) AND METHOD 21 O C (Tag closed cup, ASTM D-56)
U.E.L. (% BY VOLUME) Not Available SENSITIVITY TO IMPACT: None
L.E.L. (% BY VOLUME) Not Available SENSITIVITY TO STATIC Not Available
DISCHARGE:
AUTO IGNITION TEMP. (ºC) Not Available RATE OF BURNING: Not Available
TDG FLAMMABILITY CLASSIFICATION Not Available EXPLOSIVE POWER: Not Available

Section 5: Reactivity Data:


CHEMICAL STABILITY: Stable
COMPATIBLE WITH OTHER SUBSTANCES: Yes
REACTIVITY UNDER WHAT CONDITIONS: Burning
HAZARDOUS DECOMPOSITION PRODUCTS: Burning can produce carbon monoxide and/or carbon dioxide
NAME UNSTABLE CONDITIONS: Mixture with oxidizing materials
NAME INCOMPATIBILITIES: Strong oxidizing materials

1
Material Safety Data Sheet

MATERIAL NAME/IDENTIFIER: ONE STEP HAND SANITIZER (ALCOHOL)

Section 6: Toxicological Properties:


ROUTE OF ENTRY: SKIN CONTACT SKIN ABSORPTION EYE CONTACT INHALATION ACUTE INHALATION CHRONIC INGESTION
x x x x
EFFECTS OF ACUTE EXPOSURE TO THE MATERIAL:
None under normal conditions.
EFFECTS OF CHRONIC EXPOSURE TO THE MATERIAL:
None under normal conditions.
LD-50 OF MATERIAL (ROUTE & SPECIES) LC-50 OF MATERIAL (ROUTE & SPECIES)
Not Available Not Available
EXPOSURE LIMIT FOR THE MATERIAL IRRITANCY OF THE MATERIAL
Not Available Concentrated product may cause eye irritation
SENSITIZING CAPACITY OF THE MATERIAL CARCINOGENICITY OF THE MATERIAL
None Known None Known
REPRODUCTIVE EFFECTS OF THE MATERIAL SYNERGISTIC MATERIALS
None Known None Known

Section 7: Preventive Measures:


PERSONAL PROTECTIVE EQUIPMENT: None required under normal conditions
GLOVES (SPECIFY): None required under normal conditions
RESPIRATOR (SPECIFY): None required under normal conditions
FOOTWEAR (SPECIFY): None required under normal conditions
CLOTHING (SPECIFY): None required under normal conditions
ENGINEERING CONTROLS (SPECIFY): Fire-proof and explosion-proof equipment must be used during manufacturing
LEAK & SPILLAGE PROCEDURE: Pick up large spills and transfer to suitable sealed containers

WASTE DISPOSAL: Contact local authorities for disposal method


HANDLING PROCEDURES & EQUIPMENT: Keep the product away from sources of heat, spark or open flame
STORAGE REQUIREMENTS Store between 15OC and 30OC
SPECIAL SHIPPING INFORMATION (TDG): Class 3 Flammable liquid ; Make certain that all shipping containers are properly
labeled
OTHER INFORMATION: Do not mix with other chemicals

Section 8: First Aid Measures:


INHALATION: Give plenty of fresh air. Call physician if dizziness or any discomfort is observed.
INGESTION: Give plenty of milk or water. Call Physician
EYE CONTACT: Flush for 10 minutes with running water. Call physician, if any irritation is present or develops.
SKIN CONTACT: None required under normal conditions

Section 9: Information Sources Used:

SOURCES: Raw material suppliers’ data sheets.

Section 10: WHMIS Classification:


WHMIS CLASS: Class B Division 2: Flammable liquid

Section 11: MSDS Preparation Information:


PREPARED BY: Claude Raad PHONE NUMBER: (905) 568-0700 DATE: December 11, 2014

2
00000665 MATERIAL SAFETY DATA SHEET Page 1
Pro Form Products Ltd.
604 McGeachie Drive
Milton; Ontario; L9T 3Y5
Canada

PRODUCT: PF7770-3 TRUCK LINE PLIOGRIP URETHANE ADHESIVE PART A


Section 01: Chemical product and company identification
Product name................................................ PF7770-3 TRUCK LINE PLIOGRIP URETHANE ADHESIVE PART A
Manufactured for........................................... Pro Form Products Ltd.
604 McGeachie Drive
Milton, Ontario L9T3Y5
Tel (905) 878-4990 Fax (905) 878-1189
24 hour emergency number:......................... IN CANADA CALL CANUTEC (613) 996-6666-IN THE UNITED STATES CALL
CHEMTREC (800) 424-9300.
Material use................................................... Adhesive applications.
Chemical family............................................. Aromatic isocyanate prepolymer.
Preparation date............................................ April 3, 2014.
Hazard rate
NFPA rating................................................... Health: 2 Fire: 1 Reactivity: 1.
HMIS............................................................. H: 2* F: 1 R: 1.

Section 02: Hazards identification

Signal Word................................................... DANGER.


Hazard Classification..................................... Respiratory Sensitizer 1. Skin Sensitizer 1. Eye Irritant 2. Skin Irritant 2. Acute Toxicity 4.
STOT SE 3. STOT RE 2.
Hazard Description........................................ H302 Harmful if swallowed. H312 Harmful in contact with skin. H315 Causes skin irritation.
H317 May cause an allergic skin reaction. H320 Causes eye irritation. H332 Harmful if
inhaled. H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled.
H335 May cause respiratory irritation. H373 May cause damage to the liver and kidneys
through prolonged or repeated contact.
Precautionary Statements............................. P202 Do not handle this product until all safety instructions have been read and
understood. P233 Keep container tightly closed. P251 Do not pierce or burn container,
even after use. P261 Avoid breathing mists, vapours and sprays. P264 Wash thoroughly
after handling. P270 Do not eat drink or smoke while using this product. P271 Use only
outdoors or in a well ventilated area. P272 Contaminated work clothing should not be
allowed out of the workplace. P273 Avoid release to the environment. P280 Wear
protective gloves and eye protection. P284 In case of inadequate ventilation wear
respiratory protection.

Section 03: COMPOSITION/INFORMATION ON INGREDIENTS


Hazardous Ingredients CAS # Wt. %

4,4'-DIPHENYLMETHANE 101-68-8 30-40


DIISOCYANATE (MDI)
TALC 14807-96-6 10-30
2,4-DIPHENYLMETHANE 5873-54-1 0.1-1.0
DIISOCYANATE (MDI)

Section 04: First aid measures


Eye contact.................................................... In case of contact, immediately flush eyes, keeping eyelids open, with plenty of water for at
least 15 minutes. Check for and remove any contact lenses. Obtain medical attention.
Skin contact................................................... Immediately flush skin with plenty of soap and water. Remove contaminated clothing.
Wash clothing before reuse. Do not peel solidified product off the skin. If irritation persists,
seek medical attention.
Inhalation....................................................... If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is
difficult, give oxygen, obtain medical attention.
Ingestion........................................................ Do not induce vomiting. Rinse mouth with water. Give 1 to 2 glasses of water to drink.
Never give anything by mouth to an unconscious person. If spontaneous vomiting occurs
have victim lean forward with head down to prevent aspiration of fluid into the lungs. Get
medical attention.
00000665 MATERIAL SAFETY DATA SHEET Page 2

PRODUCT: PF7770-3 TRUCK LINE PLIOGRIP URETHANE ADHESIVE PART A


Section 04: First aid measures
Additional information.................................... Eye: stain for evidence of corneal injury. If cornea is burned, instill antibiotic steroid
preparation frequently. Workplace vapours have produced reversible corneal epithelial
edema impairing vision. Skin: this compound is a known skin sensitizer. Treat
symptomatically as for contact dermatitis or thermal burns. If burned, treat as thermal burn.
Ingestion: treat symptomatically. There is no specific antidote. Inducing vomiting is
contraindicated because of the irritating nature of this compound. Respiratory: this
compound is a known pulmonary sensitizer. Treatment is essentially symptomatic. An
individual having a skin or pulmonary sensitization reaction to this material should be
removed from exposure to any isocyanate. In the event of an incident involving this product
ensure that medical authorities are provided a copy of this safety data sheet. In all cases, if
irritation persists seek medical attention.

Section 05: Fire fighting measures


Extinguishing media...................................... Dry chemical. Carbon dioxide. Foam. In cases of larger fires, water spray should be used.
Hazardous combustion products................... Oxides of carbon (CO,CO2). Oxides of nitrogen. Smoke. Hydrogen cyanide. Isocyanates.
Other potentially toxic fumes.
Special fire fighting procedures..................... Firefighter should be equipped with self-contained breathing apparatus and full protective
clothing to protect against potentially toxic and irritating fumes. During a fire, isocyanate
vapours and other irritating, highly toxic gases may be generated by thermal decomposition
or combustion. Cool fire-exposed containers with cold water spray. Heat will cause
pressure buildup and may cause explosive rupture. Heat will cause pressure buildup and
may cause explosive rupture.
Unusual fire / explosion hazards................... Reaction between water or foam and hot MDI can be vigorous.

Section 06: Accidental release measures


Leak/spill.......................................................Isolate area and keep unauthorized people away. Do not walk through spilled material.
Wear recommended protective equipment. Ventilate. Open windows and doors to allow
air circulation. Dike area to prevent spreading. The use of absorbent socks or spill pillows
may be required. Stop leak if safe to do so. Prevent runoff into drains, sewers, and other
waterways.
Major spills.................................................... If temporary control of isocyanate vapour is required, a blanket of protein foam may be
placed over spill. If transportation spill occurs in United States, call Chemtrec
1-800-424-9300. If transportation spill occurs in Canada, call Canutec at (613) 996-6666.
Large quantities may be pumped into closed, but not sealed, containers for disposal.
Minor spills.................................................... Cover spill area with suitable absorbent material (e.g., sand, earth, sawdust, vermiculite,
Oil-Dri, Kitty Litter, etc.). Saturate absorbent material with neutralizing solution.
Recommended portion is ten parts neutralizing solution to one part spilled material.
Suggested neutralization solution: 90% water + 5% concentrated ammonia + 5% detergent
(dish soap). Add an additional layer of absorbent material. Use shovel to move absorbent
material around to ensure that all spilled material comes in contact with the neutralizing
solution. Shovel all absorbed material, including absorbent socks or spill pillows, into an
appropriate salvage drum. Add further amounts of neutralizing solution. Allow to stand
(covered loosely) for 48 to 72 hours, to allow any gases to escape.
Clean up........................................................ Decontaminate spill area with neutralizing solution. Area can then be washed with soap
and water.

Section 07: Handling and storage


Handling procedures..................................... Avoid skin and eye contact. Do not breathe vapours, mist or dust. Use adequate
ventilation. Decomposition products can be highly toxic and irritating. Individuals with lung
or breathing problems or prior allergic reactions to isocyanates must not be exposed to
vapour or spray mist. Warning properties (irritation of the eyes, nose and throat or odour)
are not adequate to prevent chronic overexposure from inhalation. Handle in accordance
with good industrial hygiene and safety practices. Wash thoroughly after handling. Wear
respiratory protection if material is heated, sprayed, used in confined space, or if exposure
limit is exceeded. Employee education and training are important.
Storage needs............................................... Store in tightly closed containers to prevent moisture contamination. Store in a cool, dry
and well ventilated area. Do not reseal if contamination is suspected. Exposure to vapours
of heated isocyanates can be extremely dangerous.

Section 08: Exposure controls / personal protection


Protective equipment
Eye/type........................................................ Chemical safety goggles. Chemical safety goggles and full faceshield if a splash hazard
exists. Contact lenses should not be worn when working with this chemical.
Respiratory/type............................................ In case of insufficient ventilation, wear suitable respiratory equipment. An approved air
purifying respirator with organic vapour cartridges and particulate prefilter can be used to
minimize exposure. However, this should be permitted only for short periods of time (< 1
00000665 MATERIAL SAFETY DATA SHEET Page 3

PRODUCT: PF7770-3 TRUCK LINE PLIOGRIP URETHANE ADHESIVE PART A


Section 08: Exposure controls / personal protection
Respiratory/type............................................ hour) at relatively low concentrations (at or near the exposure limit). Protection provided by
air-purifying respirators is limited. The use of a positive pressure air supplied respirator is
mandatory when airborne concentrations are not known or airborne solvent levels are 10
times the appropriate exposure limit or spraying is performed in a confined space or with
limited ventilation. Be sure to use NIOSH approved respirator or equipment. Do not
exceed the use limits of the respirator.
Gloves/ type.................................................. Chemical resistant gloves: butyl rubber, nitrile rubber, neoprene, PVC. Practice good
hygiene, wash thoroughly before handling any food.
Clothing/type................................................. Wear adequate protective clothes. Wear long sleeves and trousers to prevent dermal
exposure.
Footwear/type................................................ Safety boots per local regulations.
Other/type...................................................... Eye wash facility should be in close proximity. Emergency shower should be in close
proximity. Educate and train employees on the safe use and handling of the product.
Ventilation requirements................................ Ventilate adequately. Exhaust air may need to be cleaned by scrubbers or filters to reduce
environmental contamination. Vent work area to ensure airborne concentrations are below
the current occupational exposure limits. Avoid breathing mists; if general ventilation or
local exhaust is inadequate, persons exposed to mists should wear approved breathing
devices.
Monitoring...................................................... Exposure levels must be monitored by accepted monitoring techniques to ensure that the
TLV is not exceeded.
Medical surveillance...................................... Medical supervision of all employees who handle or come in contact with isocyanates is
recommended. These should include preemployment and periodic medical examinations
with pulmonary function test (FEC, FVC as a minimum). Persons with asthmatic-type
conditions, chronic bronchitis, other chronic respiratory diseases or recurring skin eczema
or sensitization should be excluded from working with isocyanates. Once a person is
diagnosed as sensitized to an isocyanate, no further exposure can be permitted. These
should include preemployment and periodic medical examinations with pulmonary function
test (fev, fvc as a minimum). Persons with asthmatic-type conditions, chronic bronchitis,
other chronic respiratory diseases or recurrant skin eczema or sensitization should be
excluded from working with isocyanates. Once a person is diagnosed as sensitized to an
isocyanate, no further exposure can be permitted.
Exposure limits
ACGIH TLV OSHA PEL NIOSH
Ingredients TWA STEL PEL STEL REL

4,4'-DIPHENYLMETHAN 0.005 ppm No data 0.02 ppm No data 0.005 ppm


E DIISOCYANATE (MDI)
TALC 2 mg/m3 No data 2 mg/m3 No data 2 mg/m3
2,4-DIPHENYLMETHANE No data No data No data No data No data
DIISOCYANATE (MDI)

Section 09: Physical and chemical properties


Physical state................................................ Viscous liquid.
Colour............................................................ Beige.
Odour............................................................ No data.
Odour threshold (ppm).................................. No data.
Vapour pressure (mm Hg)............................. <0.013 hPa @ 25C.
Vapour density (air=1)................................... >1.
pH.................................................................. No data.
Specific gravity.............................................. 1.288 g/cm3 @ 20C - 10.72 lb/USG @ 25C.
Freezing point (deg C)................................... No data.
Solubility........................................................ Reacts slowly with water to liberate C02 gas.
Boiling point (deg C)...................................... >200.
Evaporation rate............................................ <1. (butyl acetate = 1).
Flash point (deg C), method.......................... >100.
Auto ignition temperature (deg C)................. No data.
Upper flammable limit (% vol)....................... No data.
Lower flammable limit (% vol)....................... No data.
Coefficient of water\oil distribution................. No data.
VOC............................................................... 0.0 g/L - 0.0 lb/usg.
Viscosity........................................................ No data.

Section 10: Stability and reactivity


Stability.......................................................... Stable at normal temperatures and pressures.
Reactivity conditions...................................... Contact with moisture and other materials will react with isocyanates.
Incompatibility................................................ Water, amines, strong bases, alcohols. Copper alloys.
Hazardous products of decomposition.......... See hazardous combustion products.
Hazardous polymerization............................. Contact with moisture, other materials that react with isocyanates, or temperatures above
177C, may cause polymerization.
00000665 MATERIAL SAFETY DATA SHEET Page 4

PRODUCT: PF7770-3 TRUCK LINE PLIOGRIP URETHANE ADHESIVE PART A


Section 11: Toxicological information
Route of entry ............................................... Eye contact. Skin contact. Inhalation.
Effects of acute exposure.............................. Skin irritant. Can cause reddening, itching and swelling. Persons previously sensitized
can experience allergic skin reaction with symptoms of reddening, itching, swelling and
rash. Cured material is difficult to remove. Contact with MDI can cause discolouration.
EYE: Product liquid, aerosols or vapours are irritating. Can cause tearing, reddening and
swelling. May cause temporary corneal injury. INHALATION: Vapour/mists at
concentrations above the exposure limits can irritate (burning sensation) the mucous
membranes in the respiratory tract. This can cause a runny nose, sore throat, coughing,
chest discomfort, difficulty breathing and reduced pulmonary functioning. Persons with
pre-existing, nonspecific bronchial hyperractivity can respond to concentrations below the
TLV with similar symptoms as well as asthma attack. These symptoms can be delayed up
to several hours after exposure. Effects are usually reversible. INGESTION: May cause
irritation. Symptoms can include sore throat, abdominal pain, nausea, vomiting and
diarrhea. Talc can be absorbed into the lungs and the digestive tract, and adversely affect
lung function.
Effects of chronic exposure........................... As a result of previous repeated overexposure or a single large dose, certain individuals
develop sensitization, which will cause them to react to a later exposure to product at levels
well below the TLV. Symptoms, including chest tightness, wheezing, cough, shortness of
breath or asthma attack, could be immediate or delayed. There are reports that once
sensitized, an individual can experience these symptoms upon exposure to dust, cold air or
other irritants. This increased lung sensitivity can persist for weeks and, in severe cases,
for several years. Prolonged or repeated exposure may cause lung damage, including a
decrease in lung function. Possible risk of irreversible effects. Prolonged skin contact may
cause reddening, swelling, rash, blistering, and in some cases, skin sensitization.
Sensitization can be permanent. Prolonged vapour contact with eyes may cause
conjunctivitis. Talc has been shown to cause fibrosis of the lungs.
Sensitizing capability of material................... Isocyanates are known to cause skin and respiratory sensitization in humans. Animal tests
have indicated that respiratory sensitization can result from skin contact with diisocyanates.
Carcinogenicity of material............................ This product contains non-asbestiform Talc, which is classified as a Group 3 (not
classifiable as to carcinogenicity to humans) by IARC .
Note............................................................... This product is an inert plastic when fully cured, and as such, is non-hazardous. Exposure
to unreacted chemicals can occur when handling the individual components in pails or
when using cartridges from the time of dispensing until the mixed material has cured. The
mixed material is actually curing as it is dispensed in an increasingly viscous form, making
it unlikely to present an inhalation hazard. The semi-viscous mixture does not flow like a
liquid when dispensed, thus minimizing the possibility of accidential skin contact.
Toxicological Data
Ingredients LC50-inh, rat LD50-Oral,rat

4,4'-DIPHENYLMETHANE 369 mg/m3 4 hours rat No data


DIISOCYANATE (MDI)
TALC No data No data
2,4-DIPHENYLMETHANE 370-490 MG/M3 (4HR) RAT No data
DIISOCYANATE (MDI)

Section 12: Ecological information


Environmental............................................... Do not allow to enter waters, waste water or soil.
Biodegradability............................................. No data.

Section 13: Disposal considerations


Waste disposal.............................................. Dispose of waste in accordance with all applicable federal, provincial/state and local
regulations. Industrial incineration is the preferred method. Empty containers retain
product residue; observe all precautions for the product. Decontaminate containers prior to
disposal. Empty decontaminated containers should be crushed to prevent reuse. Do not
heat or cut empty containers with electric or gas torch as vapours and gases may be toxic.

Section 14: Transport information


TDG Classification (Road)............................. Not regulated.
IATA Classification (Air)................................ Not regulated.
IMDG Classification (Marine)........................ Not regulated.
Marine Pollutant............................................ No.
00000665 MATERIAL SAFETY DATA SHEET Page 5

PRODUCT: PF7770-3 TRUCK LINE PLIOGRIP URETHANE ADHESIVE PART A


Section 15: Regulatory information
WHMIS classification..................................... D2A. D2B.
CEPA status.................................................. On Domestic Substances List (DSL).
Section 313................................................... None.
OSHA............................................................ This product is considered hazardous under the OSHA Hazard Communication Standard.
SARA Title III
Section 302 - extremely hazardous .............. None.
substances
Section 311/312 - hazard categories............. Immediate health, delayed health.
EPA hazardous air pollutants (HAPS) .......... Methylene Diphenyl Diisocyanate (MDI).
40CFR63
TSCA inventory status................................... All components are listed.
California Proposition 65............................... This product does not contain any chemical(s) known to the State of California to cause
cancer or reproductive toxicity.

Section 16: Other information


Prepared by: ................................................. REGULATORY AFFAIRS.
Telephone number:....................................... (800) 387-7981.
Disclaimer:..................................................... DISCLAIMER: All information appearing herein is based upon data obtained from
experience and recognized technical sources. To the best of our knowledge, it is believed
to be correct as of the date of issue but we make no representations as to its accuracy or
sufficiency and do not suggest or guarantee that any hazards listed herein are the only
ones which exist. The hazard information contained herein is offered solely for the
consideration of the user, subject to his own investigation and verification of compliance
with applicable regulations, including the safe use of the product under every foreseeable
condition. The information relates only to the product designated herein, and does not
relate to its use in combination with any other material or in any other process.
MATERIAL SAFETY DATA SHEET

PYRO-CHEM ABC
Product Code: 2001-2-012 ANa Issue Date: 01-08-2014

1. Product and Company Identification


Material name PYRO-CHEM ABC
Version # 01
Revision date 01-08-2014
CAS # Mixture
Product Code 2001-2-012 ANa
Product use Fire extinguishing agent
Manufacturer / Importer /
Supplier
Name Tyco Fire Protection Products
Address One Stanton Street
Marinette, WI 54143-2542
Phone 715-732-3465
Internet http://www.pyrochem.com
Emergency Phone Number CHEMTREC 800-424-9300 or 703-527-3887

2. Hazards Identification
Emergency overview WARNING

Irritating to eyes and skin.


OSHA regulatory status This product is considered hazardous under 29 CFR 1910.1200 (Hazard Communication).
Potential health effects
Routes of exposure Eye contact. Skin contact. Inhalation. Ingestion.
Eyes Avoid contact with eyes. Contact with eyes may cause irritation.
Skin Avoid contact with the skin. May cause skin irritation.
Inhalation Inhalation of dusts may cause respiratory irritation.
Ingestion Not a likely route of entry.
Target organs Eyes. Respiratory system. Skin.
Signs and symptoms Irritation of eyes and mucous membranes.

3. Composition / Information on Ingredients


Non-hazardous components CAS # Percent
Pigment Yellow 14 5468-75-7 0.1 - 1

Silicone fluid 63148-57-2 0.1 - 1

Calcium hydroxide phosphate (Ca5(OH)(PO4)3) 12167-74-7 2.5 - 10

FULLERS EARTH 8031-18-3 2.5 - 10

Ammonium Sulfate 7783-20-2 20 - 40

Ammonium Phosphate 7722-76-1 60 - 80

4. First Aid Measures


First aid procedures
Eye contact Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, if
present and easy to do. Continue rinsing. Get medical attention if irritation persists after washing.
Skin contact Wash off with warm water and soap. Get medical attention if irritation develops and persists.

Material name: PYRO-CHEM ABC MSDS US


1641 Version #: 01 Revision date: 01-08-2014 1/4
Inhalation Move to fresh air. Get medical attention, if needed.
Ingestion Rinse mouth. Do not induce vomiting without advice from poison control center. If vomiting
occurs, keep head low so that stomach content doesn't get into the lungs.
Notes to physician Symptoms may be delayed.
General advice If you feel unwell, seek medical advice (show the label where possible). Ensure that medical
personnel are aware of the material(s) involved, and take precautions to protect themselves.
Show this safety data sheet to the doctor in attendance.

5. Fire Fighting Measures


Flammable properties No unusual fire or explosion hazards noted.
Extinguishing media
Suitable extinguishing This product is not flammable. Use extinguishing agent suitable for type of surrounding fire.
media
Protection of firefighters
Specific hazards arising None known.
from the chemical
Hazardous combustion Carbon monoxide and carbon dioxide.
products

6. Accidental Release Measures


Personal precautions Local authorities should be advised if significant spillages cannot be contained. Avoid inhalation of
dust from the spilled material. Wear a dust mask if dust is generated above exposure limits.
Environmental precautions Prevent further leakage or spillage if safe to do so. Do not contaminate water.
Methods for containment If sweeping of a contaminated area is necessary use a dust suppressant agent which does not
react with the product. Prevent entry into waterways, sewer, basements or confined areas.
Methods for cleaning up Should not be released into the environment. Sweep up or vacuum up spillage and collect in
suitable container for disposal. Collect dust using a vacuum cleaner equipped with HEPA filter.
Avoid dust formation. Following product recovery, flush area with water.
Other information Clean up in accordance with all applicable regulations.

7. Handling and Storage


Handling Keep formation of airborne dusts to a minimum. Do not breathe dust. Avoid contact with eyes. Do
not use in areas without adequate ventilation. Wear personal protective equipment. Wash
thoroughly after handling.
Storage Store in a well-ventilated place. Keep container tightly closed. Guard against dust accumulation of
this material. Use care in handling/storage.

8. Exposure Controls / Personal Protection


Engineering controls Ensure adequate ventilation, especially in confined areas.
Personal protective equipment
Eye / face protection Do not get in eyes. Chemical goggles are recommended.
Skin protection No special protective equipment required.
Respiratory protection When workers are facing concentrations above the exposure limit they must use appropriate
certified respirators.
General hygiene Do not get in eyes.
considerations

9. Physical & Chemical Properties


Appearance
Form Powder.
Color Yellow.
Odor Odorless.
Physical state Solid.
pH Not available.
Melting point Not available.
Freezing point Not available.
Boiling point Not available.
Material name: PYRO-CHEM ABC MSDS US
1641 Version #: 01 Revision date: 01-08-2014 2/4
Flash point Not available.
Evaporation rate Not available.
Flammability limits in air, upper, Not available.
% by volume
Flammability limits in air, lower, Not available.
% by volume
Vapor pressure Not available.
Vapor density Not available.
Specific gravity Not available.
Relative density Not available.
Solubility (water) Not available.
Partition coefficient Not available
(n-octanol/water)
Auto-ignition temperature Not available.
Decomposition temperature Not available.
VOC Not available.

10. Chemical Stability & Reactivity Information


Chemical stability Material is stable under normal conditions.
Incompatible materials Strong acids.
Hazardous decomposition Carbon oxides.
products

11. Toxicological Information


Toxicological information The toxicity of this product has not been tested.
Carcinogenicity This product is not considered to be a carcinogen by IARC, ACGIH, NTP, or OSHA.
Further information This product has no known adverse effect on human health.

12. Ecological Information


Ecotoxicological data
Product Test Results
PYRO-CHEM ABC (Mixture) EC50 Daphnia: 167 mg/l 48.00 hours estimated
LC50 Fish: 3181 mg/l 96.00 hours estimated
Components Test Results
Ammonium Sulfate (7783-20-2) EC50 Water flea (Ceriodaphnia dubia): 52 - 67 mg/l 48.00
hours
LC50 Pink salmon (Oncorhynchus gorbuscha): 0.068 mg/l
96.00 hours
Ecotoxicity This material is not expected to be harmful to aquatic life.
Environmental effects An environmental hazard cannot be excluded in the event of unprofessional handling or disposal.
Persistence and degradability Not available.

13. Disposal Considerations


Disposal instructions This product, in its present state, when discarded or disposed of, is not a hazardous waste
according to Federal regulations (40 CFR 261.4 (b)(4)). Under RCRA, it is the responsibility of
the user of the product to determine, at the time of disposal, whether the product meets RCRA
criteria for hazardous waste. Dispose of waste material according to Local, State, Federal, and
Provincial Environmental Regulations.
Waste from residues / unused Dispose of in accordance with local regulations.
products

14. Transport Information


DOT
Not regulated as dangerous goods.

Material name: PYRO-CHEM ABC MSDS US


1641 Version #: 01 Revision date: 01-08-2014 3/4
15. Regulatory Information
US federal regulations This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication
Standard, 29 CFR 1910.1200.
CERCLA/SARA Hazardous Substances - Not applicable.
US EPCRA (SARA Title III) Section 313 - Toxic Chemical: De minimis concentration
Ammonium Phosphate (CAS 7722-76-1) 1.0 %
Ammonium Sulfate (CAS 7783-20-2) 1.0 %
US EPCRA (SARA Title III) Section 313 - Toxic Chemical: Listed substance
Ammonium Phosphate (CAS 7722-76-1) Listed.
Ammonium Sulfate (CAS 7783-20-2) Listed.
CERCLA (Superfund) reportable quantity
None
Superfund Amendments and Reauthorization Act of 1986 (SARA)
Hazard categories Acute Health - No
Chronic Health - No
Fire Hazard - No
Pressure Hazard - No
Reactivity Hazard - No
Section 302 extremely No
hazardous substance
Section 311 hazardous No
chemical
Inventory status
Country(s) or region Inventory name On inventory (yes/no)*
Australia Australian Inventory of Chemical Substances (AICS) No
Canada Domestic Substances List (DSL) Yes
Canada Non-Domestic Substances List (NDSL) No
China Inventory of Existing Chemical Substances in China (IECSC) Yes
Europe European Inventory of Existing Commercial Chemical Yes
Substances (EINECS)
Europe European List of Notified Chemical Substances (ELINCS) No
Japan Inventory of Existing and New Chemical Substances (ENCS) No
Korea Existing Chemicals List (ECL) Yes
New Zealand New Zealand Inventory Yes
Philippines Philippine Inventory of Chemicals and Chemical Substances Yes
(PICCS)
United States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory No
*A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s)
State regulations This product does not contain a chemical known to the State of California to cause cancer, birth
defects or other reproductive harm.
US - Pennsylvania RTK - Hazardous Substances: Listed substance
Ammonium Sulfate (CAS 7783-20-2) Listed.

16. Other Information


Further information HMIS® is a registered trade and service mark of the NPCA.
HMIS® ratings Health: 0
Flammability: 0
Physical hazard: 0
NFPA ratings Health: 0
Flammability: 0
Instability: 0
Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge,
information and belief at the date of its publication. The information given is designed only as a
guidance for safe handling, use, processing, storage, transportation, disposal and release and is
not to be considered a warranty or quality specification. The information relates only to the
specific material designated and may not be valid for such material used in combination with any
other materials or in any process, unless specified in the text.
Issue date 01-08-2014
Material name: PYRO-CHEM ABC MSDS US
1641 Version #: 01 Revision date: 01-08-2014 4/4
Material Safety Data Sheet

Section 1: Product & Company Identification

Product Name: QD™ Electronic Cleaner (aerosol)


Product Number (s): 75012, 75102
Product Use: Electronic cleaner

Manufacturer / Supplier Contact Information:


In United States: In Canada: In Mexico:
CRC Industries, Inc. CRC Canada Co. CRC Industries Mexico
885 Louis Drive 2-1246 Lorimar Drive Av. Benito Juárez 4055 G
Warminster, PA 18974 Mississauga, Ontario L5S 1R2 Colonia Orquídea
www.crcindustries.com www.crc-canada.ca San Luís Potosí, SLP CP 78394
1-215-674-4300 (General) 1-905-670-2291 www.crc-mexico.com
(800) 521-3168 (Technical) 52-444-824-1666
(800) 272-4620 (Customer Service)

24-Hr Emergency – CHEMTREC: (800) 424-9300 or (703) 527-3887

Section 2: Hazards Identification

Emergency Overview
DANGER: Extremely Flammable. Harmful or Fatal if Swallowed. Contents Under Pressure.
Appearance & Odor: Clear, colorless liquid with alcohol odor

Potential Health Effects:


ACUTE EFFECTS:
EYE: May cause mild irritation including stinging and redness, but does not injure eye.

SKIN: Single, brief exposures may cause mild irritation. Frequent or prolonged contact may cause more
severe irritation, defatting of the skin, and dermatitis.

INHALATION: High vapor concentrations are irritating to the respiratory tract and may cause headaches, dizziness,
anesthesia, drowsiness, unconsciousness and other central nervous system effects, including death.
May cause peripheral nervous system disorder and/or damage.

INGESTION: Low order of toxicity by ingestion. Main hazard is aspiration into the lungs during swallowing or
vomiting. Small amounts aspirated into the respiratory system may cause bronchopneumonia or
pulmonary adema, possibly progressing to death.

CHRONIC EFFECTS: Overexposure to n-hexane may cause progressive and potentially irreversible damage to the
peripheral nervous system, particularly in the arms and legs.

TARGET ORGANS: Central nervous system, peripheral nervous system, respiratory system

Medical Conditions Aggravated by Exposure: skin and respiratory conditions

See Section 11 for toxicology and carcinogenicity information on product ingredients.

Page 1 of 7
Product Name: QD™ Electronic Cleaner (aerosol)
Product Number (s): 75012, 75102

Section 3: Composition/Information on Ingredients

COMPONENT CAS NUMBER % by Wt.


Hexane isomers 64742-49-0 / 107-83-5 85 – 95
n-Hexane 110-54-3 6.6
Ethanol 64-17-5 <1
Carbon Dioxide 124-38-9 3–8

Section 4: First Aid Measures

Eye Contact: Immediately flush with plenty of water for 15 minutes. Call a physician if irritation persists.

Skin Contact: Remove contaminated clothing and wash affected area with soap and water. Call a physician if
irritation persists. Wash contaminated clothing prior to re-use.

Inhalation: Remove person to fresh air. Keep person calm. If not breathing, give artificial respiration. If
breathing is difficult give oxygen. Call a physician.

Ingestion: Do NOT induce vomiting. Contact a physician immediately.

Note to Physicians: Treat symptomatically. Gastric lavage using a cuffed endotracheal tube may be performed at your
discretion.

Section 5: Fire-Fighting Measures

Flammable Properties: This product is extremely flammable in accordance with aerosol flammability definitions.
(See 16 CFR 1500.3©(6) ).
Flash Point: < 0°F / < -17°C (TCC) Upper Explosive Limit: 9.0
Autoignition Temperature: 489°F / 254°C Lower Explosive Limit: 1.7

Fire and Explosion Data:


Suitable Extinguishing Media: Class B fire extinguishers, dry chemical, foam or CO2

Products of Combustion: Fumes, smoke and carbon monoxide

Explosion Hazards: Aerosol containers, when exposed to heat from fire, may build pressure and explode. Vapors
may accumulate in a confined space and create a flammable atmosphere.

Protection of Fire-Fighters: Firefighters should wear self-contained, NIOSH-approved breathing apparatus for
protection against suffocation and possible toxic decomposition products. Proper eye and
skin protection should be provided. Use water spray to keep fire-exposed containers cool
and to knock down vapors which may result from product decomposition. Do not spray
water directly on fire; product will float and could be reignited on surface of water.

Section 6: Accidental Release Measures

Personal Precautions: Use personal protection recommended in Section 8.

Environmental Precautions: Take precautions to prevent contamination of ground and surface waters. Do not flush into
sewers or storm drains.

Page 2 of 7
Product Name: QD™ Electronic Cleaner (aerosol)
Product Number (s): 75012, 75102
Methods for Containment & Clean-up: Dike area to contain spill. Remove all sources of ignition. Ventilate the area with
fresh air. If in confined space or limited air circulation area, clean-up workers
should wear appropriate respiratory protection. Recover or absorb spilled
material using an absorbent designed for chemical spills. Place used absorbents
into proper waste containers.

Section 7: Handling and Storage

Handling Procedures: Use proper grounding and bonding procedures for transferring materials. Do not use product
near any source of ignition. Avoid contact with eyes and skin. Avoid breathing vapors. Use
caution around energized equipment. The metal container will conduct electricity if it contacts a
live source. This may result in injury to the user from electrical shock and/or flash fire. For
product use instructions, please see the product label.

Storage Procedures: Store in a cool dry area out of direct sunlight. Aerosol cans must be maintained below 120°F /
49°C to prevent cans from rupturing.

Aerosol Storage Level: III

Section 8: Exposure Controls/Personal Protection

Exposure Guidelines:
OSHA ACGIH OTHER
COMPONENT TWA STEL TWA STEL TWA SOURCE UNIT

Hexane isomers 500(v) 1000(v) 500 1000 NE ppm


n-Hexane 500 NE 50(s) NE NE ppm
Ethanol 1000 NE 1000 NE NE ppm
Carbon Dioxide 5000 30000 (v) 5000 30000 NE ppm
N.E. – Not Established (c) – ceiling (s) – skin (v) – vacated

Controls and Protection:


Engineering Controls: Area should have ventilation to provide fresh air. Local exhaust ventilation is generally
preferred because it can control the emissions of the contaminant at the source, preventing
dispersion into the general work area. Use mechanical means if necessary to maintain vapor
levels below the exposure guidelines. If working in a confined space, follow applicable OSHA
regulations.

Respiratory Protection: None required for normal work where adequate ventilation is provided. If engineering controls
are not feasible or if exposure exceeds the applicable exposure limits, use a NIOSH-approved
cartridge respirator with organic vapor cartridge. Air monitoring is needed to determine actual
employee exposure levels. Use a self-contained breathing apparatus in confined spaces and
for emergencies.

Eye/face Protection: For normal conditions, wear safety glasses. Where there is reasonable probability of liquid
contact, wear splash-proof goggles.

Skin Protection: Use protective gloves such as nitrile, PVC, Viton®. Also, use full protective clothing if there is
prolonged or repeated contact of liquid with skin.

Section 9: Physical and Chemical Properties

Page 3 of 7
Product Name: QD™ Electronic Cleaner (aerosol)
Product Number (s): 75012, 75102
Physical State: liquid
Color: clear, colorless
Odor: alcohol
Odor Threshold: ND
Specific Gravity: 0.66
Initial Boiling Point: 140°F / 60°C
Freezing Point: < -76°F / < -60°C
Vapor Pressure: 175 mmHg @ 68°F / 20°C
Vapor Density: >1 (air = 1)
Evaporation Rate: very fast
Solubility: negligible in water
Coefficient of water/oil distribution: ND
pH: NA
Volatile Organic Compounds: wt %: 95 g/L: 627 lbs./gal: 5.2

Section 10: Stability and Reactivity

Stability: Stable

Conditions to Avoid: Sources of ignition, temperature extremes

Incompatible Materials: Strong oxidizers

Hazardous Decomposition Products: Oxides of carbon

Possibility of Hazardous Reactions: No

Section 11: Toxicological Information

Long-term toxicological studies have not been conducted for this product. The following information is available for
components of this product.

Acute Toxicity:

Component Oral LD50 (rat) Dermal LD50 (rabbit) Inhalation LC50 (rat)
Hexane isomers > 15,000 mg/kg > 2000 mg/kg No data
n-Hexane 28,710 mg/kg 3000 mg/kg 48,000 ppm/4H
Ethanol 760 mg/kg No data 20,000 ppm/10H
Carbon Dioxide No data No data 470,000 ppm/30M

Chronic Toxicity:
OSHA IARC NTP
Component Carcinogen Carcinogen Carcinogen Irritant Sensitizer
Hexane isomers No No No No Unknown
n-Hexane No No No E, S & R (moderate) Unknown
No No No E (mild) / Unknown
Ethanol
S (moderate)
Carbon Dioxide No No No No No

E – Eye S – Skin R - Respiratory


Reproductive Toxicity: No information available
Teratogenicity: No information available
Mutagenicity: No information available
Synergistic Effects: No information available

Page 4 of 7
Product Name: QD™ Electronic Cleaner (aerosol)
Product Number (s): 75012, 75102

Section 12: Ecological Information

Ecological studies have not been conducted for this product. The following information is available for components of this
product.

Ecotoxicity: n-hexane - 48 Hr EC50 water flea: 3.87 mg/L


96 Hr LC50 Lepomis macrochirus: 4.12 mg/L
Persistence / Degradability: No information available
Bioaccumulation / Accumulation: No information available
Mobility in Environment: No information available

Section 13: Disposal Considerations

Waste Classification: The dispensed liquid product is a RCRA hazardous waste for the characteristic of ignitability
with a waste code of D001. (See 40 CFR Part 261.20 – 261.33)
Any liquid product should be managed as a hazardous waste. Empty aerosol containers may
be recycled.

All disposal activities must comply with federal, state, provincial and local regulations. Local regulations may be more
stringent than state, provincial or national requirements.

Section 14: Transport Information

US DOT (ground): UN1950, Aerosols, flammable, 2.1, Limited Quantity**

ICAO/IATA (air): UN1950, Aerosols, flammable, 2.1, Limited Quantity

IMO/IMDG (water): UN1950, Aerosols, 2.1, Limited Quantity

Special Provisions: **This product can be classified and labeled as ‘Consumer Commodity, ORM-D’ for domestic
ground shipping until December 31, 2020.
If shipping as limited quantity by ground, note that shipping papers are not required.

Section 15: Regulatory Information

U.S. Federal Regulations:

Toxic Substances Control Act (TSCA):


All ingredients are either listed on the TSCA inventory or are exempt.

Comprehensive Environmental Response, Compensation and Liability Act (CERCLA):


Reportable Quantities (RQ’s) exist for the following ingredients: n-hexane (5000 lbs)

Spills or releases resulting in the loss of any ingredient at or above its RQ require immediate notification to
the National Response Center (800-424-8802) and to your Local Emergency Planning Committee.

Superfund Amendments Reauthorization Act (SARA) Title III:


Section 302 Extremely Hazardous Substances (EHS): None

Section 311/312 Hazard Categories: Fire Hazard Yes


Reactive Hazard No
Release of Pressure Yes
Page 5 of 7
Product Name: QD™ Electronic Cleaner (aerosol)
Product Number (s): 75012, 75102
Acute Health Hazard Yes
Chronic Health Hazard No

Section 313 Toxic Chemicals: This product contains the following substances subject to the reporting requirements
of Section 313 of Title III of the Superfund Amendments and Reauthorization Act of
1986 and 40 CFR Part 372:
n-hexane (6.6%)

Clean Air Act:


Section 112 Hazardous Air Pollutants (HAPs): n-hexane

Occupational Safety and Health Administration:


This product is regulated by the Hazard Communications Standard.

U.S. State Regulations:

California Safe Drinking Water and Toxic Enforcement Act (Prop 65):
This product may contain the following chemicals known to the state of
California to cause cancer, birth defects or other reproductive harm: None

Consumer Products VOC Regulations: NA

State Right to Know:


New Jersey: 75-83-2, 110-54-3, 79-29-8, 64-17-5, 124-38-9
Pennsylvania: 107-83-5, 75-83-2, 110-54-3, 79-29-8, 64-17-5, 124-38-9
Massachusetts: 107-83-5, 75-83-2, 110-54-3, 79-29-8, 64-17-5, 124-38-9
Rhode Island : 110-54-3, 64-17-5, 124-38-9

Canadian Regulations:

Controlled Products Regulations:


This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and the
MSDS contains all the information required by the Controlled Products Regulations.

WHMIS Hazard Class: A, B5, D2B

Canadian DSL Inventory: All ingredients are either listed on the DSL Inventory or are exempt.

European Union Regulations:

RoHS Compliance: This product is compliant with Directive 2002/95/EC of the European Parliament and of the
Council of 27 January 2003. This product does not contain any of the restricted substances as
listed in Article 4(1) of the RoHS Directive.

Additional Regulatory Information: None

Page 6 of 7
Product Name: QD™ Electronic Cleaner (aerosol)
Product Number (s): 75012, 75102

Section 16: Other Information

HMIS® (II) NFPA


Health: 1
Flammability: 3
3
Reactivity: 0
1 0
PPE: B

Ratings range from 0 (no hazard) to 4 (severe hazard)

Prepared By: Michelle Rudnick


CRC #: 985
Revision Date: 07/23/2014

Changes since last revision: Section 14: Transport Information

The information contained in this document applies to this specific material as supplied. It may not be valid for this
material if it is used in combination with any other materials. This information is accurate to the best of CRC Industries'
knowledge or obtained from sources believed by CRC to be accurate. Before using any product, read all warnings and
directions on the label. For further clarification of any information contained on this MSDS consult your supervisor, a
health & safety professional, or CRC Industries.

ACGIH: American Conference of Governmental Industrial Hygienists NA: Not Applicable


CAS: Chemical Abstract Service ND: Not Determined
CFR: Code of Federal Regulations NIOSH: National Institute of Occupational Safety & Health
DOT: Department of Transportation NFPA: National Fire Protection Association
DSL: Domestic Substance List NTP: National Toxicology Program
g/L: grams per Liter OSHA: Occupational Safety and Health Administration
HMIS: Hazardous Materials Identification System PMCC: Pensky-Martens Closed Cup
IARC: International Agency for Research on Cancer PPE: Personal Protection Equipment
IATA: International Air Transport Association ppm: Parts per Million
ICAO: International Civil Aviation Organization RoHS: Restriction of Hazardous Substances
IMDG: International Maritime Dangerous Goods STEL: Short Term Exposure Limit
IMO: International Maritime Organization TCC: Tag Closed Cup
lbs./gal: pounds per gallon TWA: Time Weighted Average
LC: Lethal Concentration WHMIS: Workplace Hazardous Materials Information
LD: Lethal Dose System

Page 7 of 7
MATERIAL SAFETY DATA SHEET MSDS DATE: 11/30/13

REFLEX 700 A
SECTION 1: PRODUCT AND COMPANY IDENTIFICATION

PRODUCT NAME: REFLEX 700 Component A


SYNONYMS: Modified Diphenylmethane Diisocyanate (MDI)
PRODUCT CODES: 872-1025

MANUFACTURER: Langeman Manufacturing Ltd.


ADDRESS: 56 Oak Street East
Leamington, ON, N8H 2C2
EMERGENCY PHONE: Chemtrec: 1-800-424-9300
OTHER CALLS: 1-519-326-6104
FAX PHONE: 1-519-326-4188

CHEMICAL NAME: Diphenylmethane Diisocyanate (MDI) Prepolymer


CHEMICAL FAMILY: Aromatic Isocyanate Prepolymer
CHEMICAL FORMULA: not applicable

PRODUCT USE: Polyurethane Coating for Truck Bedliners.


PREPARED BY: AdK

SECTION 1 NOTES:
CAS No. 39420-98-9

SECTION 2: COMPOSITION/INFORMATION ON INGREDIENTS

INGREDIENT:

Polyurethane Prepolymer: Proprietary formulation based on polyurethane technology.

SECTION 2 NOTES:

SECTION 3: HAZARDS IDENTIFICATION

EMERGENCY OVERVIEW:

May cause lung damage; May cause eye, skin, and respiratory tract irritation; Harmful if inhaled; May cause allergic respiratory reaction; May
cause allergic skin reaction; Toxic gases are given off during burning or thermal decomposition.

ROUTES OF ENTRY:
Skin: Contact from liquid and aerosols (spray application).
Inhalation: Although MDI is low in volatility, an inhalation hazard can exist from MDI aerosols or vapors formed during heating, foaming or
spraying.

POTENTIAL HEALTH EFFECTS

Acute Skin Contact: Isocyanates react with skin protein and moisture and can cause irritation which may include the following symptoms:
reddening, swelling, rash, scaling or blistering. Cured material is difficult to remove.
Acute Inhalation: MDI vapors or mist at concentrations above the TLV can irritate (burning sensation) the mucous membranes in the
respiratory tract (nose, throat, lungs) causing runny nose, sore throat, coughing, chest discomfort, shortness of breath and reduced
lung function (breathing obstruction). Persons with a preexisting, nonspecific bronchial hyper reactivity can respond to concentrations
below the TLV with similar symptoms as well as asthma attack. Exposure well above the TLV may lead to bronchitis, bronchial spasm
and pulmonary edema (fluid in lungs). These effects are usually reversible. Chemical or hypersensitive pneumonitis, with flu-like
symptoms (e.g., fever, chills) has also been reported. These symptoms can be delayed up to several hours after exposure.
Acute Eye Contact: Liquid, aerosols or vapors are irritating and can cause tearing, reddening and swelling. If left untreated, corneal damage
can occur and injury is slow to heal. However, damage is usually reversible. See First Aid Measures for treatment.
Acute Ingestion: Can result in irritation and corrosive action in the mouth, stomach tissue and digestive tract. Symptoms can include sore
throat, abdominal pain, nausea, vomiting and diarrhea.

PAGE 1 OF 6
MATERIAL SAFETY DATA SHEET MSDS DATE: 11/30/13

REFLEX 700 A
CHRONIC HEALTH HAZARDS:

Chronic Skin Contact: Prolonged contact can cause reddening, swelling, rash, scaling, blistering, and in some cases, skin sensitization.
Individuals who have skin sensitization can develop these symptoms from contact with liquid or vapors. Animal tests have indicated
that respiratory sensitization can result from skin contact with MDI. This data reinforces the need to prevent direct skin contact with
MDI. (See Toxicological Information, SENSITIZATION.)
Chronic Inhalation: As a result of previous repeated overexposures or a single large dose, certain individuals develop isocyanate
sensitization (chemical asthma) which will cause them to react to a later exposure to isocyanate at levels well below the TLV. These
symptoms, which can include chest tightness, wheezing, cough, shortness of breath or asthma attack, could be immediate or delayed
(up to several hours after exposure). Similar to many non-specific asthmatic responses, there are reports that once sensitized an
individual can experience these symptoms upon exposure to dust, cold air or other irritants. This increased lung sensitivity can persist
for weeks and in severe cases for several years. Overexposure to isocyanates has also been reported to cause lung damage (including
decrease in lung function) which may be permanent. Sensitization can either be temporary or permanent.
Chronic Eye Contact: None Found
Chronic Ingestion: None Found

MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE:


Asthma, other respiratory disorders (bronchitis, emphysema, bronchial hyper reactivity), skin allergies, eczema.

CARCINOGENICITY:

Neither MDI nor polymeric MDI are listed by the NTP, IARC or regulated by OSHA as carcinogens.

SECTION 4: FIRST AID MEASURES

Eyes: Flush with copious amount of water, preferably, lukewarm water for at least 15 minutes, holding eyelids open all the time. Refer
individual to physician or ophthalmologist for immediate follow-up.
Skin: Remove contaminated clothing. Wash affected skin thoroughly with soap and water. Wash contaminated clothing thoroughly before
reuse. For severe exposures, get under safety shower after removing clothing, then get medical attention. For lesser exposures, seek
medical attention if irritation develops or persists after the area is washed.
Inhilation: Move to an area free from risk of further exposure. Administer oxygen or artificial respiration as needed. Obtain medical attention.
Asthmatic-type symptoms may develop and may be immediate or delayed up to several hours. Consult physician should this occur.
Ingestion: DO NOT INDUCE VOMITING. Give 1 to 2 cups of milk or water to drink. DO NOT GIVE ANYTHING BY MOUTH TO AN
UNCONSCIOUS PERSON. Consult physician.
Note to Physician:
Eyes: Stain for evidence of corneal injury. If cornea is burned, instill antibiotic steroid preparation frequently. Workplace vapors have
produced reversible corneal epithelial edema impairing vision.
Skin: This compound is a known skin sensitizer. Treat symptomatically as for contact dermatitis or thermal burns. If burned, treat as thermal
burn. Ingestion. Treat symptomatically. There is no specific antidote. Inducing vomiting is contraindicated because of the irritating
nature of this compound.
Respiratory: This compound is a known pulmonary sensitizer. Treatment is essentially symptomatic. An individual having a skin or pulmonary
sensitization reaction to this material should be removed from exposure to any isocyanate.

SECTION 5: FIRE-FIGHTING MEASURES

Flammability Limits:
Upper Explosive Limit: (UEL) (%): Not Established

Lower Explosive Limit (LEL) (%): Not Established

Auto-Ignition Temperature: ~860 F (460 C) (similar material)

Flash Point: 421.0 °F (216.1 °C) Pensky-Martens Closed Cup (ASTM D-93)

PAGE 2 OF 6
MATERIAL SAFETY DATA SHEET MSDS DATE: 11/30/13

REFLEX 700 A
Extinguishing Media: Dry Chemical; Carbon Dioxide; Foam; Water spray for large fires.
Special Firefighting Procedures: Full emergency equipment with self-contained breathing apparatus and full protective clothing should be
worn by firefighters. During a fire, MDI vapors and other irritating, highly toxic gases may be generated by thermal decomposition or
combustion. (See Stability and Reactivity). At temperatures greater than 400 °F (204 °C), polymeric MDI can polymerize and
decompose which can cause pressure build-up in closed containers. Explosive rupture is possible. Therefore, use cold water to cool
fire-exposed containers.
Unusual Fire and Explosion Hazards: None reported for this product.

Health: 2 Flammability: 1 Reactivity: 1

SECTION 6: ACCIDENTAL RELEASE MEASURES

Accidental Release Measures:


Evacuate and ventilate spill area; dike spill to prevent entry into water system; wear full protective equipment, including respiratory
equipment during clean-up. (See Employee Protection Recommendations). Major Spill: Call Langeman Manufacturing at 519-326-
6104. If transportation spill, call CHEMTREC 800-424-9300. If temporary control of isocyanate vapor is required, a blanket of protein
foam (available at most fire departments) may be placed over the spill. Large quantities may be pumped into closed, but not sealed,
container for disposal. Minor Spill: Absorb isocyanates with sawdust or other absorbent, shovel into suitable unsealed containers,
transport to well-ventilated area (outside) and treat with neutralizing solution: mixture of water (80%) with non-ionic surfactant Tergitol
TMN-10 (20%), or; water (90%), concentrated ammonia (3-8%) and detergent (2%). Add about 10 parts of neutralizer per part of
isocyanate, with mixing. Allow to stand uncovered for 48 hours to let C02 escape. Clean-up: Decontaminate floor with decontamination
solution letting stand for at least 15 minutes.

SECTION 7: HANDLING AND STORAGE

Handling and Storage: Store in tightly closed containers to prevent moisture contamination. Do not reseal if contamination is suspected.
Avoid contact with skin and eyes. Do not breathe aerosols or vapors. Warning properties (irritation of the eyes, nose and throat or odor)
are not adequate to prevent chronic overexposure from inhalation. This material can produce asthmatic sensitization upon either single
inhalation exposure to a relatively high concentration or upon repeated inhalation exposures to lower concentrations. Exposure to
vapors of heated MDI can be extremely dangerous. Employee education and training in the safe use and handling of this compound
are required under the OSHA Hazard Communication Standard.
Storage Temperature: 60 °F (15 °C)/95 °F (35 °C)
Special Sensitivity: If container is exposed to high heat, 400 °F (204 ºC) it can be pressurized and possibly rupture. MDI reacts slowly with
water to form C02 gas. This gas can cause sealed containers to expand and possibly rupture.
Shelf Life: 6 months @ 77 °F (25 °C)
_________________________________________________________________________________________________________________
SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls: : Local exhaust should be used to maintain levels below the TLV whenever MDI is processed, heated or spray
applied. Standard reference sources regarding industrial ventilation (ie., ACGIH Industrial Ventilation) should be consulted for guidance
about adequate ventilation.
Eye Protection: Liquid chemical goggles. Vapor resistant goggles should be worn when contact lenses are in use. In a splash hazard
environment chemical goggles should be used in combination with a full face-shield.
Skin Protection: Permeation resistant gloves (butyl rubber, nitrile rubber, polyvinyl alcohol). However, please note that PVA degrades in
water. Cover as much of the exposed skin area as possible with appropriate clothing. If skin creams are used, keep the area covered
by the cream to a minimum. Ventilation Procedures
Respiratory Equipment: Concentrations greater than the TLV can occur when MDI is sprayed, heated or used in a poorly ventilated area. In
such cases, or whenever concentration: of MDI exceed the TLV or are not known, respiratory protection must be worn. A supplied air
respirator (either positive pressure or continuous flow type) is required. In an emergency situation, a self-contained breathing apparatus
may be used. MDI has poor warning properties, since the concentration at which MDI can be smelled is substantially higher than the
maximum exposure limit. Observe OSHA regulations for respirator use (29 CFR 1910.134).
Monitoring: Isocyanate exposure levels must be monitored. Monitoring of airborne isocyanates in the breathing zone of individuals should
become part of the overall employee exposure characterization program. Monitoring techniques have been developed by NIOSH, and
OSHA.
Medical Surveillance: Medical supervision of all employees who handle or come in contact with isocyanates is recommended. These should
include pre employment and periodic medical examinations with pulmonary function tests (FEV, FVC a: a minimum). Persons with
asthmatic-type conditions, chronic bronchitis, other chronic respiratory disease or recurrent skin eczema or sensitization should be
excluded from working with isocyanates. Once a person is diagnosed as sensitized to an isocyanate, no further exposure can be
permitted.
PAGE 3 OF 6
MATERIAL SAFETY DATA SHEET MSDS DATE: 11/30/13

REFLEX 700 A
Additional Protective Measures: Safety showers and eyewash stations should be available. Educate and train employees in safe use of
product. Follow all label instructions.

SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES

APPEARANCE: Yellowing Liquid


ODOR: Slightly musty odor
PH: Not Applicable
BOILING POINT: 406 °F (208 °C) @ 5 mmHg for MDI
MELTING/FREEZING POINT: Range 50 °F (10 °C) for MDI to 60 °F (16 °C)
VISCOSITY: Not Applicable
SOLUBILITY IN WATER Not soluble. Reacts slowly with water to liberate C02 gas.
SPECIFIC GRAVITY: 1.090 @ 77 °F (25 °C)
BULK DENSITY: 9.10 lbs/gal
% VOLATILE BY VOLUME: 0%
VAPOR PRESSURE: Less than 10-5 mmHg @ 77 °F (25 °C) for MDI
VAPOR DENSITY 8.5 (MDI) (Air =1) .............................

SECTION 10: STABILITY AND REACTIVITY

STABLE X UNSTABLE

Stability: Stable under normal circumstances.

Hazardous Polymerization:
May occur; Contact with moisture, other materials which react with isocyanates, temperatures above 400 °F (204 °C), may cause
polymerization.

Incompatibility (Materials to avoid): Water, amines, strong bases, alchohols, metal compounds and surface active materials.

Instability Conditions: Contamination with water.

Decomposition Conditions: By high heat and fire: carbon dioxide, carbon monoxide, oxides of nitrogen, HCN, HDI and other unknown
aliphatic fragments.

SECTION 11: TOXICOLOGICAL INFORMATION

Toxicity Data for: Diphenylmethane Diisocyanate (Monomeric and Polymeric)


Acute Toxicity:
ORAL LD5O ........................................................ Greater than 15,800 mg/kg (Rat)
DERHAL LD5O .................................................... Greater 5010 but less than 7,940 mg/kg (Rabbit)
INHALATION LC5O ............................................. The 4-hour LC5O for polymeric MDI in rats ranges from 370 to 490 mg/m3. The LC5O
for monomeric MDI was estimated to be between 172 and 187 mg/m3.
EYE EFFECTS .................................................... Slight to moderate irritation.
SKIN EFFECTS ................................................... Slight to moderate irritation.
SENSITIZATION ................................................. MDI has been shown to produce dermal sensitization in laboratory animals. Evidence
of respiratory sensitization has also been observed in guinea pigs. In addition, there is
some evidence suggestive of cross-sensitization between different types of
diisocyanates.

_________________________________________________________________________________________________________________
SECTION 12: ECOLOGICAL INFORMATION

Ecology Data for: Diphenylmethane Diisocyanate (Monomeric and Polymeric)


Aquatic Toxicity: LC5O - 24 hr. (static): Greater than 500 mg/liter for Daphnia magna, Limnea Stagnalis, and Zebra fish (Brachydanio rerio)
for both polymeric and monomeric MDI.

PAGE 4 OF 6
MATERIAL SAFETY DATA SHEET MSDS DATE: 11/30/13

REFLEX 700 A
SECTION 13: DISPOSAL CONSIDERATIONS

Waste Disposal Method: Waste must be disposed of in accordance with federal, state, and local environmental control regulations.
Incineration is the preferred method.
Empty Container Regulations: Empty containers must be handled with care due to product residue. Decontaminate containers prior to
disposal. Empty decontaminated containers should be crushed to prevent reuse. DO NOT HEAT OR CUT EMPTY CONTAINER WITH
ELECTRIC OR GAS TORCH. (See Fire Fighting Measures and Stability & Reactivity). Gases may be highly toxic.
Transportation Emergencies: Langeman Mfg Ltd. requires that CHEMTREC be immediately notified (800-424-9300) when this product is
unintentionally released from its container during its course of distribution, regardless of the amount released. Distribution includes
transportation, storage incidental to transportation, loading and unloading. Such notification must be immediate and made by the
person having knowledge of the release.

SECTION 14: TRANSPORT INFORMATION

TECHNICAL SHIPPING NAME ..................................... Methylene diphenyl diisocyanate


FREIGHT CLASS BULK ................................................ Methylene diphenyl diisocyanate
FREIGHT CLASS PACKAGE ........................................ Chemicals, NOI (Isocyanate), NMFC 60000
PRODUCT LABEL......................................................... Product Label Established
DOT (DOMESTIC SURFACE)

PROPER SHIPPING NAME .......................................... Other Regulated Substances, Liquid, N.O.S. * SEE NOTE BELOW
HAZARD CLASS OR DIVISION .................................... 9
UN/NA NUMBER ........................................................... NA3082
PACKAGING GROUP ................................................... PG III
HAZARDOUS SUBSTANCE ......................................... MDI, (Methylene diphenyl diisocyanate)
DOT PRODUCT RQ lbs (kgs)........................................ 33333 lbs (15119.8 kgs)
HAZARD LABEL(s......................................................... Class 9
HAZARD PLACARD(s) .................................................. Class 9

* WHEN IN INDIVIDUAL CONTAINERS OF LESS THAN THE PRODUCT RQ, THIS MATERIAL SHIPS AS NON-REGULATED.
IMO / IMDG CODE (OCEAN)

HAZARD CLASS DIVISION NUMBER: ......................... Non-Regulated


ICAO / IATA (AIR)

HAZARD CLASS DIVISION NUMBER: ......................... Non-Regulated

SECTION 15: REGULATORY INFORMATION

OSHA STATUS ............................................................. This product is hazardous under the criteria of the Federal OSHA Hazard
Communication Standard 29 CFR 1910.1200.
TSCA STATUS.............................................................. On TSCA Inventory
CERCLA REPORTABLE QUANTITY ............................ 5000 lbs for 4,4' - Diphenylmethane Diisocyanate, CAS# 101-68-8.
SARA TITLE III:
SECTION 302 EXTREMELY
HAZARDOUS SUBSTANCES: .......................... None
SECTION 311/312
HAZARD CATEGORIES ................................... Immediate Health Hazard; Delayed Health Hazard; Reactive Hazard
SECTION 313
TOXIC CHEMICALS ............................................ 4,4'-Diphenylmethane Diisocyanate, CAS# 101-68-8; Upper Bound 15%
RCRA STATUS ............................................................. MDI is not listed as a hazardous waste. To the best of our knowledge, MDI does not
meet the criteria of a hazardous waste if discarded in its purchased form. However,
under RCRA, it is the responsibility of the user of products to determine, at the time of
disposal, whether a product meets any of the criteria for a hazardous waste. This is
because product uses, transformations, mixtures, processes, etc., may render the
resulting material hazardous, under the criteria of ignitability, corrosivity, reactivity and
toxicity characteristics under the new Toxicity Characteristics Leaching Procedure
(TCLP) 40 Code of Federal Regulations 261.20-24.
The following chemicals are specifically listed by individual states; other product specific health and safety data in other sections of the
MSDS may also be applicable for state requirements. For details on your regulatory requirements you should contact the appropriate
agency in your state.
PAGE 5 OF 6
MATERIAL SAFETY DATA SHEET MSDS DATE: 11/30/13

REFLEX 700 A
CALIFORNIA PROPOSITION 65
To the best of our knowledge, this product contains no levels of listed substances, which the state of California has found to cause
cancer, birth defects or other reproductive effects.

SECTION 16: OTHER INFORMATION

OTHER INFORMATION:

NTP Not listed


IARC Not listed
OSHA ............................................................................ Not regulated

DISCLAIMER:

The information accumulated herein is believed to be accurate but is not warranted to be whether originating with the company or not.
Recipients are advised to confirm in advance that the information is current, applicable, and suitable to their circumstances.

PAGE 6 OF 6
M A T E R I A L S A F E T Y D A T A S H E E T
71024 Page 1

================== SECTION I - PRODUCT IDENTIFICATION =================

PRODUCT NAME: RUSTEX PRIMER GREY HMIS CODES: H F R P

PRODUCT IDENTIFIER: 71024 2 3 0 G


*
PRODUCT USE: General purpose coating.
PRODUCT IDENTIFICATION NUMBER: UN1263
WHMIS INFO: B2, D1B, D2A, D2B

MANUFACTURER'S NAME: Cloverdale Paint Inc


ADDRESS : 6950 King George Boulevard
Surrey, BC,
EMERGENCY PHONE : 613-996-6666 REVISION DATE: 28-May-14
INFORMATION PHONE : 604-596-6261
ABREVIATIONS : N/AP – NOT APPLICABLE N/AV – NOT AVAILABLE

================== SECTION II - HAZARDOUS INGREDIENTS =====================

REPORTABLE COMPONENTS CAS NUMBER WEIGHT PERCENT O.E.L.

*XYLENE 1330-20-7 15-40 ACGIH TLV: 100 PPM

LD50: ORAL:4g/kg rat, LC50: 6500 ppm/4H(RAT)

LD50: SKIN:5000 mg/kg(RABBIT)

TITANIUM DIOXIDE 13463-67-7 7-13 TLV (ACGIH): 10 mg/m3, total dust, 8 hr. TWA

ETHYLBENZENE 100-41-4 5-10 TWA: 100ppm LD50 (ORAL-RAT): 3500 mg/kg

LD50: SKIN:17800 mg/kg(RABBIT)

HIGH FLASH NAPHTHA MIXTURE 1-5 ACGIH TLV: 50 ppm

LD50:ORAL:>8.0 ml/kg(RAT), LC50:>10200


mg/m3/4H(RAT)

METHANOL 67-56-1 0.1-1 ACGIH TLV: 200 ppm

LD50: ORAL:5628 mg/kg(RAT), LC50: 64000


ppm/4H(RAT)

----------------------------------------------------------------------------------

*** No toxic chemical(s) subject to the reporting requirements of section 313 of Title III
and of 40 CFR 372 are present. ***
----------------------------------------------------------------------------------

=============== SECTION III - PHYSICAL/CHEMICAL CHARACTERISTICS ============

BOILING POINT: 65.0 deg C SPECIFIC GRAVITY (H2O=1): 1.18


VAPOR DENSITY: Heavier than air. PHYSICAL STATE: Liquid.
EVAPORATION RATE: Slower than n-Butyl Acetate.
COATING V.O.C.: 571 g/l (before thinning)
SOLUBILITY IN WATER: Insoluble.
APPEARANCE AND ODOR: Moderately thick liquid; Aromatic odor.
FREEZING POINT: Not available. pH: Not available.
M A T E R I A L S A F E T Y D A T A S H E E T
71024 Page 2

COEFFICIENT OF WATER/OIL DIST: N/AV ODOR THRESHOLD: 1-30 ppm

================= SECTION IV - FIRE AND EXPLOSION HAZARD DATA ==============

FLASH POINT: 24 C METHOD USED: Not available.


FLAMMABLE LIMITS IN AIR BY VOLUME- LOWER: Not available.
UPPER: Not available.

EXTINGUISHING MEDIA:
Foam, CO2, dry chemical, water fog.

SPECIAL FIREFIGHTING PROCEDURES


Respiratory equipment should be worn to avoid inhalation of concentrated vapours.
Water should not be used except as a fog to keep nearby containers cool.

UNUSUAL FIRE AND EXPLOSION HAZARDS


Handle as a flammable liquid. Vapours form an explosive mixture in air between the
upper and lower explosive limits, which, can be ignited by many sources such as
pilot lights, open flames, electrical boxes and switches. Vapour may travel along
the ground and flashback along vapour trail may occur.

FLAMMABILITY – T.D.G.R. CLASS:


TDG CLASS 3

SENSITIVITY TO IMPACT: NO

AUTO-IGNITION TEMPERATURE:
Not available

SENSITIVITY TO STATIC DISCHARGE: Yes

HAZARDOUS COMBUSTION PRODUCTS:


Carbon Monoxide, Carbon Dioxide and Oxides of Nitrogen.

======================== SECTION V - REACTIVITY DATA =======================

CHEMICAL STABILITY: STABLE

CONDITIONS TO AVOID:
Excessive heat, poor ventilation, corrosive atmospheres, excessive aging.

INCOMPATIBILITY (MATERIALS TO AVOID)


Alkaline materials, strong acids and oxidizing agents.

HAZARDOUS DECOMPOSITION OR BYPRODUCTS: Not available.

HAZARDOUS POLYMERIZATION:
Will not occur.

==================== SECTION VI - TOXICOLOGICAL DATA =======================

INHALATION HEALTH RISKS AND SYMPTOMS OF EXPOSURE


May cause respiratory irritation, dizziness, breathing difficulty, headaches and
loss of co-ordination.

SKIN AND EYE CONTACT HEALTH RISKS AND SYMPTOMS OF EXPOSURE


Eye Contact: May cause severe irritation, tearing, redness and blurred vision.
Skin Contact: May cause irritation.
M A T E R I A L S A F E T Y D A T A S H E E T
71024 Page 3

SKIN ABSORPTION HEALTH RISKS AND SYMPTOMS OF EXPOSURE


May dry and defat skin causing cracks, irritation and dermatitis.

INGESTION HEALTH RISKS AND SYMPTOMS OF EXPOSURE


Contains Methanol which is poisonous if swallowed. May cause blindness, narcosis,
headache, nausea and vomiting leading to severe illness.

HEALTH HAZARDS (ACUTE AND CHRONIC)


Acute: Contains Methanol which is poisonous if swallowed. Causes blindness.
Chronic: Repeated exposure by inhalation or absorption may cause systemic
poisoning. Prolonged exposure to crystalline silica dust by inhalation may cause
delayed lung injury/disease (Silicosis).

SENSITIZING CAPABILITY: Not available.

CARCINOGENICITY: NTP CARCINOGEN:No IARC MONOGRAPHS:Yes OSHA REGULATED:No


Ethylbenezene has been classified by the IARC as a Group 2B substance on the basis
of sufficient evidence for carcinogenicity in laboratory animals but inadequate
evidence for cancer in humans. In a lifetime inhalation study, exposure to 250
mg/m3 titanium dioxide dust resulted in the development of lung tumors in rats.
These tumors occurred only at dust levels that overwhelmed the animals' lung
clearance mechanisms and were different from common human lung tumors in both type
and location. The relevance of these findings to humans is unknown. The
International Agency for Research on Cancer (IARC) has classified Titanium Dioxide
as possibly carcinogenic to humans (Group 2B) based on inadequate evidence of
carcinogenicity in humans and sufficient evidence of carcinogenicity in
experimental animals.

TERATOGENICITY AND EMBRYOTOXICITY


High exposures to xylenes in some animal studies have been reported to cause
health effects on the developing embryo/fetus. These effects were often at levels
toxic to the mother. The significance of these findings to humans has not been
determined.

REPRODUCTIVE TOXICITY
Not available.

MUTAGENICITY
Not available.

TOXICOLOGICALLY SYNERGISTIC PRODUCTS


None known.

MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE


Anesthesia, respiratory tract irritation, dermatitis, nausea, vomiting.

================= SECTION VII - PREVENTIVE MEASURES =======================

STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED


Eliminate ignition sources. Provide good ventilation or wear appropriate breathing
apparatus. Absorb small spills with non-flammable absorbent. Contain spills by
diking with non-flammable absorbent. Notify environmental agency.

WASTE DISPOSAL METHOD


M A T E R I A L S A F E T Y D A T A S H E E T
71024 Page 4

Reclaim or dispose of through a licensed waste disposal company according to


Federal,Provincial and local regulations.

PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING


Flammable. Store in a cool, dry, well ventilated area away from heat and ignition
sources. Keep containers closed when not in use. Avoid breathing vapours or mist
and prolonged or repeated contact with skin. Launder contaminated clothing prior
to re-use. Use good personal hygiene. Product is a static accumulator. Transfer
equipment should be grounded or bonded.

OTHER PRECAUTIONS: Smoking in the area where this material is used must be
strictly prohibited.

RESPIRATORY PROTECTION
NIOSH approved for organic vapours and particulate matter.

VENTILATION
General mechanical ventilation or local exhaust should be suitable to keep vapour
concentrations below TLV. Ventilation equipment must be explosion proof. Make up
air should be supplied to balance air exhausted.

PROTECTIVE GLOVES
Solvent impervious e.g. Viton, Nitrile, PVC.

EYE PROTECTION
Chemical safety glasses, goggles or face shield.

OTHER PROTECTIVE CLOTHING OR EQUIPMENT


Use impermeable aprons and protective clothing whenever possible to prevent skin
contact.

WORK/HYGIENIC PRACTICES
Eye washes and safety showers in the workplace are recommended.

===================== SECTION VIII - FIRST AID MEASURES =====================

INHALATION OVEREXPOSURE: Move person to fresh air. If breathing stops, apply


artificial respiration and seek immediate medical attention.

EYE CONTACT: Flush with water for at least 15 minutes. Seek medical attention.

SKIN CONTACT: Wash thoroughly with mild soap and water.

INGESTION: Do not induce vomiting. Aspiration of solvents in this product can


cause inflammation of the lungs.

========================= SECTION IX - PREPARATION ========================

PREPARED BY: TECHNICAL DEPARTMENT

========================= SECTION X - DISCLAIMER ==========================


To the best of our knowledge, the information contained herein is accurate,
obtained from sources believed by Cloverdale Paint Inc. to be accurate. No
warranty concerning the accuracy of these sources is made and Cloverdale Paint
Inc. will not be held liable for claims relating to use of this information or
recommendations.
M A T E R I A L S A F E T Y D A T A S H E E T
Key1 Page 5
Location Product Name Manufacturer Name Manufacturer Part #

Welding 3M Scotch-Weld Epoxy Tyco Fire Protection 2001-2-012 ANa


Adhesive DP-100 Clear Products

Welding Acrysol Body Solvent Sika Canada Inc.


16 Oz NW
Welding Air Tool Oil Sika Corporation 604270
Welding Air Tool Oil Henkel Loctite Canada 32530
Inc.
Welding Bactine Original First Praxair Inc. 10001
Aid Liquid
Welding Bon Ami Power Foam Sem Products Inc. 39143
Glass Cleaner
Welding Correction pen (Multi- Henkel Loctite Canada 135465
Purpose) Inc.
Welding Cream Hardener Sluyter Company Ltd.
Welding Crown 8034 General Stockhausen Inc.
Purpose Silicone
Lubricant
Welding Dupli-Color Enamel Virox Technologies
Paint, Gloss Black
(OSHA)
Welding Dupli-Color Enamel Air Liquide Canada Inc
Paint, Gloss White
(OSHA White)
Welding Dupli-Color Engine Lawson Products Inc P60170
Enamel with Ceramic,
Aluminum
Welding Dupli-Color Engine Honeywell Safety S461
Enamel with Ceramic, Products
Aluminum
Welding Dupli-Color Lacquer CRC Industries 74095
Paint, Flat Black
Welding Dupli-Color Lacquer Honeywell Safety S468
Paint, Flat Black Products
Welding Dupli-Color Primer Kleen-Flo Tumbler 4168
Surfacer, Gray Hot Rod Industries Ltd.

Welding Dupli-Color Primer LA-CO Industries Inc.- 96800


Surfacer, Gray Hot Rod Markal Company

Welding Envy Foaming Corrosion Control


Disinfectant Cleaner Coating Ltd.
Welding ETP Gold Cutting Fluid Bayer Material Science
Welding ETP Gold Cutting Fluid WD 40 Products
Canada Ltd.
Welding European Auto Coat Barnes Group Inc. BD1108
Welding European Auto Coat Diversey Inc. 350000014153
Welding Everglass quart J. Walter Company Ltd. 53-G 245

Welding Extend(R) Rust Air Liquide Canada Inc EXCELARC 18


Treatment
Welding Film Forming Lubricant Air Liquide Canada Inc AL-J-001-0

Welding Glance Foaming Glass Lawson Products, Inc. CW1533


& Multi-Surface
Cleaner
Welding Glass Cleaner Air Liquide Canada
Welding High Build Undercoat Carworx Distribution 126.061
550G. Paintable - Inc.
890.9081
Welding Johnsens Brake Parts ITW Evercoat 100340
Cleaner
Welding Kopr-Kote Thermal Aervoe Industries Inc
Grade
Welding LPS 1 (Aerosol) Kleen-Flo Tumbler 022
Industries Ltd.
Welding Marvel Air Tool Oil Diversey Lever
Welding Metal Glaze Illinois Tool Works Inc. 100632

Welding Moovit (Aerosol) Henkel Corp 37557


Welding Mopar Multi-Purpose Balmar, LLC 101G
Lube
Welding One Step Hand Henkel Loctite Canada 51831
Sanitizer Inc.
Welding PF 7770-3 Truck Line Johnson Diversey 04553
Pliogrip Urethane
Adhesive Part A
Welding Pyro-Chem ABC Total Solutions 1447
Welding QD Electronic Cleaner Würth Canada Limitée 893-1063
(Aerosol)
Welding Rustex Primer Grey Sherwin Williams 03702
Welding Rustex Primer Grey Kleen-Flo Tumbler 645
Industries Ltd.
Welding Stokolan intensive Henkel Loctite Canada 27141
repair Inc.
Welding TEROSON SI 9160 CL OKS
known as SILATECH Spezialschmierstoffe
GmbH
SILICONE SEALANT IND

Welding Valve Action Paint Bostik Findley Inc.


Marker
Welding Way Oil Vistac 68, 229 Belvedere International
Incorporated

Welding Windex Original Glass Allegro Industries 1001, 1001-05, 1001-10


Cleaner with Ammonia-
D
Transit Dept (8050) > WD-40 Bulk Liquid WD 40 Products Matched English Canada
421 Osborne (8080) > Canada Ltd. WHMIS
Washrack (CWIN91)
Transit Dept (8050) > Windex Original Glass Diversey Inc. 350000014153 Matched English Canada
421 Osborne (8080) > Cleaner with Ammonia- WHMIS
Washrack (CWIN91) D
Transit Dept (8050) > Windshield Washer Nemco Resources 0790 Matched English Canada
421 Osborne (8080) > Fluid WWAF -40 & WHMIS
Washrack (CWIN91) WWAF -35°C
Transit Dept (8050) > Xk2 Zep Manufacturing 6745 Matched English Canada
421 Osborne (8080) > Company of Canada WHMIS
Washrack (CWIN91)
Transit Dept (8050) > Zep Spirit II Ready-To- Zep Manufacturing 0679 Matched English Canada
421 Osborne (8080) > Use Detergent Company of Canada WHMIS
Washrack (CWIN91) Disinfectant
Transit Dept (8050) > ZL-W01 Pentel of America Ltd Matched English Canada
421 Osborne (8080) > WHMIS
Washrack (CWIN91)
Transit Dept (8050) > 2-6 Casting Alloy, 15/85 The Canada Metal Matched English Canada
421 Osborne (8080) > ASTM 15B, 20/80 Company WHMIS
Welding Shop ASTM 20 B, 25/75
ASTM 30 A B, 30/70,
34/66, 35/65, 45/55
ASTM A B, Pirellie, "E"
Alloy
Transit Dept (8050) > 39143 Trim Black Sem Products Inc. 39143 Matched English Canada
421 Osborne (8080) > WHMIS
Welding Shop
Transit Dept (8050) > 3M Dynatron Putty-Cote 3M General Office LB-K100-0587-6 Matched English Canada
421 Osborne (8080) > 592, 592T, 593 WHMIS
Welding Shop
Transit Dept (8050) > 3M Panel Bonding 3M 08115 Matched English Canada
421 Osborne (8080) > Adhesive PN 08115 WHMIS
Welding Shop
Transit Dept (8050) > 404 Quick Set Instant Henkel Loctite Canada 135465 Matched English Canada
421 Osborne (8080) > Adhesive Inc. WHMIS
Welding Shop
Transit Dept (8050) > 470 Featherspray Sluyter Company Ltd. Matched English Canada
421 Osborne (8080) > WHMIS
Welding Shop
Transit Dept (8050) > 64001571, 64001573, Radnor Products 64001571, 64001573, Matched English Canada
421 Osborne (8080) > 64001575, 64001577, 64001575, 64001577, WHMIS
Welding Shop 64001579, 64001581, 64001579,
64001670, 64001671,
Transit Dept (8050) > Abrasive Sanding Discs KWH Mirka Matched English Canada
421 Osborne (8080) > WHMIS
Welding Shop
Transit Dept (8050) > Accel Tb Wipes Virox Technologies Matched English Canada
421 Osborne (8080) > WHMIS
Welding Shop
Transit Dept (8050) > Acetylene Air Liquide Canada Inc Matched English Canada
421 Osborne (8080) > WHMIS
Welding Shop
Transit Dept (8050) > Acrysol Body Solvent Lawson Products Inc P60170 Matched English Canada
421 Osborne (8080) > 16 Oz NW WHMIS
Welding Shop
Transit Dept (8050) > Air Tool Oil CRC Industries 74095 Matched English Canada
421 Osborne (8080) > WHMIS
Welding Shop
Transit Dept (8050) > Air Tool Oil Kleen-Flo Tumbler 4168 Matched English Canada
421 Osborne (8080) > Industries Ltd. WHMIS
Welding Shop
Transit Dept (8050) > Alloy Steel - HR&CR Castle Metals/A.M Matched English Canada
421 Osborne (8080) > Castle & Co. WHMIS
Welding Shop
Transit Dept (8050) > Argon (Gas/Liquid) Air Liquide Canada Inc Matched English Canada
421 Osborne (8080) > WHMIS
Welding Shop
Transit Dept (8050) > Bactine Original First Bayer Material Science Matched English Canada
421 Osborne (8080) > Aid Liquid WHMIS
Welding Shop
Transit Dept (8050) > BD7-77 Plus Penetrant Barnes Group Inc. BD1108 Matched English Canada
421 Osborne (8080) > WHMIS
Welding Shop
Transit Dept (8050) > Bio-Rust J. Walter Company Ltd. 53-G 245 Matched English Canada
421 Osborne (8080) > WHMIS
Welding Shop
Transit Dept (8050) > Blueshield Air Liquide Canada Inc EXCELARC 18 Matched English Canada
421 Osborne (8080) > WHMIS
Welding Shop
Transit Dept (8050) > Blueshield LA 6010; LA Air Liquide Canada Inc AL-J-001-0 Matched English Canada
421 Osborne (8080) > Ultra 11; LA 6013; LA WHMIS
Welding Shop 6013P; LA 7014; LA
7024; LA 24-HD
Transit Dept (8050) > Bon Ami Power Foam Diversey Inc. Matched English Canada
421 Osborne (8080) > Glass Cleaner WHMIS
Welding Shop
Transit Dept (8050) > Bronze Castle Metals/A.M Matched English Canada
421 Osborne (8080) > Castle & Co. WHMIS
Welding Shop
Transit Dept (8050) > Carbon Arc Electrodes - Lawson Products, Inc. CW1533 Matched English Canada
421 Osborne (8080) > 1/4" WHMIS
Welding Shop
Transit Dept (8050) > carbon dioxide/ALIGAL Air Liquide Canada Matched English Canada
421 Osborne (8080) > WHMIS
Welding Shop
Transit Dept (8050) > Carbon Dioxide/Inert Praxair Canada Inc. Matched English Canada
421 Osborne (8080) > Gas Mixture WHMIS
Welding Shop
Transit Dept (8050) > Carbon Steel - HR&CR Castle Metals/A.M Matched English Canada
421 Osborne (8080) > Castle & Co. WHMIS
Welding Shop
Transit Dept (8050) > Carbon Steel Electrode Sidergas S.R.L. 850001 Matched English Canada
421 Osborne (8080) > Sidergas S6 WHMIS
Welding Shop
Transit Dept (8050) > Carbon Steel Welding National Standard Matched English Canada
421 Osborne (8080) > Wire Company WHMIS
Welding Shop
Transit Dept (8050) > Cavity Protection Spray Carworx Distribution 126.061 Matched English Canada
421 Osborne (8080) > Inc. WHMIS
Welding Shop
Transit Dept (8050) > Coated Abrasives Flap Jet Equipment & Tools Matched English Canada
421 Osborne (8080) > Discs (Aluminum Oxide, Ltd WHMIS
Welding Shop Zirconia, Ceramic
Grains, Surface
Conditioning Disc, And
Semiflex Discs)
Transit Dept (8050) > Coated Finished Flap Saint-Gobain Matched English Canada
421 Osborne (8080) > Discs Abrasives, Inc. WHMIS
Welding Shop
Transit Dept (8050) > Cream Hardener ITW Evercoat 100340 Matched English Canada
421 Osborne (8080) > WHMIS
Welding Shop
Transit Dept (8050) > Cronacut Eagle 1100 Lawson Products, Inc. CW1906 Matched English Canada
421 Osborne (8080) > WHMIS
Welding Shop
Transit Dept (8050) > Crown 8034 General Aervoe Industries Inc Matched English Canada
421 Osborne (8080) > Purpose Silicone WHMIS
Welding Shop Lubricant
Transit Dept (8050) > Duster ITW Chemtronics Inc. ES1617C Matched English Canada
421 Osborne (8080) > WHMIS
Welding Shop
Transit Dept (8050) > E3 Tungsten Electrodes Praxair Inc. Matched English Canada
421 Osborne (8080) > WHMIS
Welding Shop
Transit Dept (8050) > Eco-Care Engine Kleen-Flo Tumbler 022 Matched English Canada
421 Osborne (8080) > Degreaser Industries Ltd. WHMIS
Welding Shop
Transit Dept (8050) > Envy Foaming Diversey Lever Matched English Canada
421 Osborne (8080) > Disinfectant Cleaner WHMIS
Welding Shop
Transit Dept (8050) > Everglass quart Illinois Tool Works Inc. 100632 Matched English Canada
421 Osborne (8080) > WHMIS
Welding Shop
Transit Dept (8050) > Extend(R) Rust Henkel Corp 37557 Matched English Canada
421 Osborne (8080) > Treatment WHMIS
Welding Shop
Transit Dept (8050) > Film Forming Lubricant Balmar, LLC 101G Matched English Canada
421 Osborne (8080) > WHMIS
Welding Shop
Transit Dept (8050) > Fleetweld 47 The Lincoln Electric Matched English Canada
421 Osborne (8080) > Company of Canada, WHMIS
Welding Shop Limited
Transit Dept (8050) > Gasket Eliminator 518 Henkel Loctite Canada 51831 Matched English Canada
421 Osborne (8080) > Sealant Inc. WHMIS
Welding Shop
Transit Dept (8050) > Glance Foaming Glass Johnson Diversey 04553 Matched English Canada
421 Osborne (8080) > & Multi-Surface Cleaner WHMIS
Welding Shop
Transit Dept (8050) > Graffiti wipes Total Solutions 1447 Matched English Canada
421 Osborne (8080) > WHMIS
Welding Shop
Transit Dept (8050) > HHS 5000 500ml Würth Canada Limitée 893-1063 Matched English Canada
421 Osborne (8080) > WHMIS
Welding Shop
Transit Dept (8050) > HP Grinding, HP XX, J. Walter Company Ltd. Matched English Canada
421 Osborne (8080) > Allsteel XX, Stainless, WHMIS
Welding Shop ALU, Concrete,
Pipefitter, Xcavator,
Ripcut, Chopcut,
Chopcut ALU, Portacut,
Zip, Zip Stainless,
Zipcut, Zip ALU,
Railcut, HP Cup Wheel,
Flexcut, Flexcut
Milscale
Transit Dept (8050) > Jetweld 1 The Lincoln Electric Matched English Canada
421 Osborne (8080) > Company of Canada, WHMIS
Welding Shop Limited
Transit Dept (8050) > Johnsens Brake Parts Technical Chemical 2420 Matched English Canada
421 Osborne (8080) > Cleaner Company WHMIS
Welding Shop
Transit Dept (8050) > Kopr-Kote Thermal Jet Lube of Canada Ltd. Matched English Canada
421 Osborne (8080) > Grade WHMIS
Welding Shop
Transit Dept (8050) > Krylon Industrial Quik- Sherwin Williams 03702 Matched English Canada
421 Osborne (8080) > Mark Solvent-Based WHMIS
Welding Shop Inverted Marking Paint
(Fluorescent), Orange
Transit Dept (8050) > Leaded Carbon and Joseph T. Ryerson & Matched English Canada
421 Osborne (8080) > Alloy Steels Son, Inc. WHMIS
Welding Shop
Transit Dept (8050) > Loctite 222Ms Henkel Loctite Canada 22221 Matched English Canada
421 Osborne (8080) > Threadlocker Low Inc. WHMIS
Welding Shop Strength
Transit Dept (8050) > Loctite 242 Henkel Loctite Canada 135355 Matched English Canada
421 Osborne (8080) > Threadlocker Inc. WHMIS
Welding Shop
Transit Dept (8050) > Loctite 262 Henkel Loctite Canada 26231 Matched English Canada
421 Osborne (8080) > Threadlocker Inc. WHMIS
Welding Shop
Transit Dept (8050) > Loctite 271 Henkel Loctite Canada 27141 Matched English Canada
421 Osborne (8080) > Threadlocker High Inc. WHMIS
Welding Shop Strength Part No.
27141
Transit Dept (8050) > Loctite 290 Henkel Loctite Canada 29031 Matched English Canada
421 Osborne (8080) > Threadlocker Inc. WHMIS
Welding Shop
Transit Dept (8050) > Low Carbon Steels Main Manufacturing Matched English Canada
421 Osborne (8080) > Products WHMIS
Welding Shop
Transit Dept (8050) > Lusin Alro OW 22 O OKS Matched English Canada
421 Osborne (8080) > Spezialschmierstoffe WHMIS
Welding Shop GmbH
Transit Dept (8050) > Marvel Air Tool Oil Marvel Oil Company 50093 Matched English Canada
421 Osborne (8080) > Inc. WHMIS
Welding Shop
Transit Dept (8050) > Moovit (Aerosol) Lloyds Laboratories Inc. 11008 Matched English Canada
421 Osborne (8080) > WHMIS
Welding Shop
Transit Dept (8050) > Never-Seez Regular Bostik Findley Inc. Matched English Canada
421 Osborne (8080) > Grade Cmpd. WHMIS
Welding Shop
Transit Dept (8050) > Nickel Based Alloy Castle Metals/A.M Matched English Canada
421 Osborne (8080) > Steel Castle & Co. WHMIS
Welding Shop
Transit Dept (8050) > One Step Hand Belvedere International Matched English Canada
421 Osborne (8080) > Sanitizer Incorporated WHMIS
Welding Shop
Transit Dept (8050) > Oxygen (Gas) Air Liquide Canada Inc 7782-44-7 Matched English Canada
421 Osborne (8080) > WHMIS
Welding Shop
Transit Dept (8050) > Personal Respirator Allegro Industries 1001, 1001-05, 1001-10 Matched English Canada
421 Osborne (8080) > Cleaning Pad WHMIS
Welding Shop
Transit Dept (8050) > Propane Air Liquide Canada Inc Matched English Canada
421 Osborne (8080) > WHMIS
Welding Shop
Transit Dept (8050) > Prostar Anti-Spatter Praxair Inc. 10001 Matched English Canada
421 Osborne (8080) > Nozzle Tip Dip WHMIS
Welding Shop
Transit Dept (8050) > Prostar D-2 Sidergas SRL Matched English Canada
421 Osborne (8080) > WHMIS
Welding Shop
Transit Dept (8050) > Prostar E7018; E7018- Praxair Matched English Canada
421 Osborne (8080) > 1; E7018 AC WHMIS
Welding Shop
Transit Dept (8050) > Prostar Mild Steel and Groupe Esab Canada Matched English Canada
421 Osborne (8080) > Low Hydrogen Covered Inc WHMIS
Welding Shop Electrodes
Transit Dept (8050) > Prostar S-3 Sidergas SPA Matched English Canada
421 Osborne (8080) > WHMIS
Welding Shop
Transit Dept (8050) > Prostar S-6 Sidergas SPA Matched English Canada
421 Osborne (8080) > WHMIS
Welding Shop
Transit Dept (8050) > Pyro-Chem ABC Tyco Fire Protection 2001-2-012 ANa Matched English Canada
421 Osborne (8080) > Products WHMIS
Welding Shop
Transit Dept (8050) > QD Electronic Cleaner CRC Industries 75012 Matched English Canada
421 Osborne (8080) > (Aerosol) WHMIS
Welding Shop
Transit Dept (8050) > Quench Oil Nemco Resources 0576 Matched English Canada
421 Osborne (8080) > WHMIS
Welding Shop
Transit Dept (8050) > RG45 - RG60 Welding Aufhauser Corporation Matched English Canada
421 Osborne (8080) > Rods WHMIS
Welding Shop
Transit Dept (8050) > Rust PReventive Dominion Sure Seal DOM 16P, DOM16Q Matched English Canada
421 Osborne (8080) > Coating, Black Group of Companies WHMIS
Welding Shop
Transit Dept (8050) > Shielded Metal ARC Hobart Brothers Matched English Canada
421 Osborne (8080) > Welding (Smaw) Company WHMIS
Welding Shop Electrodes
Transit Dept (8050) > Sika Cleaner-205 Sika Canada Inc. Matched English Canada
421 Osborne (8080) > WHMIS
Welding Shop
Transit Dept (8050) > Sikaflex 252 Sika Corporation 604270 Matched English Canada
421 Osborne (8080) > WHMIS
Welding Shop
Transit Dept (8050) > SpeedBonder 325 Henkel Loctite Canada 32530 Matched English Canada
421 Osborne (8080) > Structural Adhesive Inc. WHMIS
Welding Shop
Transit Dept (8050) > Stainless Specialty Brunswick Steel D2A, D2B Matched English Canada
421 Osborne (8080) > Steel WHMIS
Welding Shop
Transit Dept (8050) > Stainless Steel Castle Metals/A.M Matched English Canada
421 Osborne (8080) > Castle & Co. WHMIS
Welding Shop
Transit Dept (8050) > Stainless Steel and Thyssen Krupp Matched English Canada
421 Osborne (8080) > Alloys of Stainless Steel Materials NA WHMIS
Welding Shop
Transit Dept (8050) > Stainless Steel North American Matched English Canada
421 Osborne (8080) > Products, All Grades Stainless Product WHMIS
Welding Shop
Transit Dept (8050) > Stainless Steels Main Manufacturing Matched English Canada
421 Osborne (8080) > Products WHMIS
Welding Shop
Transit Dept (8050) > Stokolan intensive Deb Matched English Canada
421 Osborne (8080) > repair WHMIS
Welding Shop
Transit Dept (8050) > Super Duster 134 and MG Chemicals Ltd. 402A-140G Matched English Canada
421 Osborne (8080) > Super Duster 134 Plus WHMIS
Welding Shop
Transit Dept (8050) > Thoriated Tungsten Osram Sylvania Matched English Canada
421 Osborne (8080) > Electrodes WHMIS
Welding Shop
Transit Dept (8050) > Travabon Stockhausen Inc. Matched English Canada
421 Osborne (8080) > WHMIS
Welding Shop
Transit Dept (8050) > Tungsten Uniweld Products, Inc Matched English Canada
421 Osborne (8080) > WHMIS
Welding Shop
Transit Dept (8050) > Tungsten 2% Thoriated X-Ergon, A Partsmaster 65042000 Matched English Canada
421 Osborne (8080) > Co Div of NCH WHMIS
Welding Shop
Transit Dept (8050) > Tungsten Electrodes Global Tungsten & M0101 Matched English Canada
421 Osborne (8080) > Various Sizes Powders Corp. WHMIS
Welding Shop (Puretung, Zirtung, TIG
Welding, GTA Welding
Electrodes)
Transit Dept (8050) > Uvex Clear Lens Honeywell Safety S461 Matched English Canada
421 Osborne (8080) > Cleaner Products WHMIS
Welding Shop
Transit Dept (8050) > Uvex Clear Lens Honeywell Safety S468 Matched English Canada
421 Osborne (8080) > Cleaning Towelette Products WHMIS
Welding Shop
Transit Dept (8050) > Valve Action Paint LA-CO Industries Inc.- 96800 Matched English Canada
421 Osborne (8080) > Marker Markal Company WHMIS
Welding Shop
Transit Dept (8050) > Vitrified Abrasive Saint Gobain North 66253109044 Matched English Canada
421 Osborne (8080) > Product America WHMIS
Welding Shop
Transit Dept (8050) > Water Based Rush Corrosion Control Matched English Canada
421 Osborne (8080) > Inhibitor Coating Ltd. WHMIS
Welding Shop
Transit Dept (8050) > WD-40 Bulk Liquid WD 40 Products Matched English Canada
421 Osborne (8080) > Canada Ltd. WHMIS
Welding Shop
Transit Dept (8050) > Windex Original Glass Diversey Inc. 350000014153 Matched English Canada
421 Osborne (8080) > Cleaner with Ammonia- WHMIS
Welding Shop D
Transit Dept (8050) > Wrought Aluminum Sapa Extrusions North Matched English Canada
421 Osborne (8080) > Products America WHMIS
Welding Shop
Transit Dept (8050) > ZL-W01 Pentel of America Ltd Matched English Canada
421 Osborne (8080) > WHMIS
Welding Shop
Transit Dept (8050) > 41 Cut-Off Wheel Tyrolit North America 384142 In Progress English Canada
421 Osborne (8080) > Inc. WHMIS
Welding Shop
Transit Dept (8050) > Anti-Borax No. 1 Superior Flux & Mfg. In Progress English Canada
421 Osborne (8080) > Co. WHMIS
Welding Shop
Transit Dept (8050) > Aluminum Alloys Castle Metals/A.M Deactivated
421 Osborne (8080) > Castle & Co.
Welding Shop
Transit Dept (8050) > Arctec 1080 FC Arctec Alloys Ltd. Deactivated
421 Osborne (8080) >
Welding Shop
Transit Dept (8050) > Arctec 207 CNMG (AC- Arctec Alloys Ltd. Deactivated
421 Osborne (8080) > DC)
Welding Shop
Transit Dept (8050) > Arctec Unicrom 265 S Arctec Alloys Ltd. Deactivated
421 Osborne (8080) >
Welding Shop
Transit Dept (8050) > Bactine Original First Bayer Healthcare LLC - Deactivated
421 Osborne (8080) > Aid Liquid Consumer Care
Welding Shop
Transit Dept (8050) > Brass Castle Metals/A.M Deactivated
421 Osborne (8080) > Castle & Co.
Welding Shop
Transit Dept (8050) > Carbon Arc Electrodes - Lawson Products CW1533 Deactivated
421 Osborne (8080) > 1/4"
Welding Shop
Transit Dept (8050) > CEC 9598 Eutectic Castolin Deactivated
421 Osborne (8080) >
Welding Shop
Transit Dept (8050) > Cert 297 Hface Arc Lawson Products Inc 19478 Deactivated
421 Osborne (8080) > 3/16' 10#
Welding Shop
Transit Dept (8050) > CERT 7700 STL ARC Premier Farnell Corp. Deactivated
421 Osborne (8080) > ACDC 1/8
Welding Shop
Transit Dept (8050) > Cert 7700 STL ARC AC- Premier Farnell 12200 Deactivated
421 Osborne (8080) > DC 1/8 Corporation
Welding Shop
Transit Dept (8050) > Certanium 701 1/8 Certanium Alloys & 12804 Deactivated
421 Osborne (8080) > Research Co.
Welding Shop
Transit Dept (8050) > Certanium 705 1/8 AC- Certanium Alloys & 12370 Deactivated
421 Osborne (8080) > DC Research Co.
Welding Shop
Transit Dept (8050) > Certanium 706 1/8 AC- Certanium Alloys & 12775 Deactivated
421 Osborne (8080) > DC Research Co.
Welding Shop
Transit Dept (8050) > Certanium 707 Lawson Products P12565 Deactivated
421 Osborne (8080) >
Welding Shop
Transit Dept (8050) > Certanium 707 1/8 Certanium Alloys & 12610 Deactivated
421 Osborne (8080) > Research Co.
Welding Shop
Transit Dept (8050) > Certanium 707 3/32 Certanium Alloys & 12565 Deactivated
421 Osborne (8080) > Research Co.
Welding Shop
Transit Dept (8050) > Certanium 707 5/32 Certanium Alloys & Deactivated
421 Osborne (8080) > Research Co.
Welding Shop
Transit Dept (8050) > Copper - HR&CR Castle Metals/A.M Deactivated
421 Osborne (8080) > Castle & Co.
Welding Shop
Transit Dept (8050) > Cronacast 211 Lawson Products Inc CW1034 Deactivated
421 Osborne (8080) >
Welding Shop
Transit Dept (8050) > Cronacut Eagle 1100 Lawson Products CW1906 Deactivated
421 Osborne (8080) >
Welding Shop
Transit Dept (8050) > Cronaweld 333 Lawson Products CW1047 Deactivated
421 Osborne (8080) >
Welding Shop
Transit Dept (8050) > Crystal Flux, Cmc No. The Canada Metal Deactivated
421 Osborne (8080) > 153 Company
Welding Shop
Transit Dept (8050) > Dynabrade Air Lube Dynabrade, Inc. 95821, 9842, 95843 Deactivated
421 Osborne (8080) > (10W/NR)
Welding Shop
Transit Dept (8050) > Dynaflux Chem Sharp Dynaflux Inc. 600B Deactivated
421 Osborne (8080) > Chemical Tungsten
Welding Shop Sharpener
Transit Dept (8050) > EutecRod 180 Eutectic Castolin Deactivated
421 Osborne (8080) >
Welding Shop
Transit Dept (8050) > Inweld HF507 Inweld Canada Deactivated
421 Osborne (8080) >
Welding Shop
Transit Dept (8050) > Inweld SX554 Inweld Canada Deactivated
421 Osborne (8080) >
Welding Shop
Transit Dept (8050) > Inweld SX555 Inweld Canada Deactivated
421 Osborne (8080) >
Welding Shop
Transit Dept (8050) > Kleen-Flo Engine Kleen-Flo Tumbler 645 Deactivated
421 Osborne (8080) > Shampoo Industries Ltd.
Welding Shop
Transit Dept (8050) > Leaded Carbon and Ryerson Inc Deactivated
421 Osborne (8080) > Alloy Steels
Welding Shop
Transit Dept (8050) > PF 500 Non-Paintable Pro-Form Products Ltd. PF 500 Deactivated
421 Osborne (8080) > Rubberized Undercoat
Welding Shop
Transit Dept (8050) > Quench Oil 15 Petro-Canada Deactivated
421 Osborne (8080) >
Welding Shop
Transit Dept (8050) > Reflex 700 A Langeman 872-1025 Deactivated
421 Osborne (8080) > Manufacturing Ltd.
Welding Shop
Transit Dept (8050) > Reflex 700 B Langeman 983-1030 Deactivated
421 Osborne (8080) > Manufacturing Ltd.
Welding Shop
Transit Dept (8050) > Resinoid Bonded United Abrasives, Inc. Deactivated
421 Osborne (8080) > Abrasives
Welding Shop
Transit Dept (8050) > Titanium Castle Metals/A.M Deactivated
421 Osborne (8080) > Castle & Co.
Welding Shop
Transit Dept (8050) > W1060 (R45) - W1200 The Harris Products Deactivated
421 Osborne (8080) > (R60) Welding Rods Group
Welding Shop
Transit Dept (8050) > Welcing Electrode/Rod L-TEC Welding & Deactivated
421 Osborne (8080) > Cutting Systems
Welding Shop
Transit Dept (8050) > Xuper 6868 XHD Eutectic Castolin Deactivated
421 Osborne (8080) >
Welding Shop
Material Safety Data Sheet

Section 1: Product & Company Identification

Product Name: QD™ Electronic Cleaner (aerosol)


Product Number (s): 75012, 75102
Product Use: Electronic cleaner

Manufacturer / Supplier Contact Information:


In United States: In Canada: In Mexico:
CRC Industries, Inc. CRC Canada Co. CRC Industries Mexico
885 Louis Drive 2-1246 Lorimar Drive Av. Benito Juárez 4055 G
Warminster, PA 18974 Mississauga, Ontario L5S 1R2 Colonia Orquídea
www.crcindustries.com www.crc-canada.ca San Luís Potosí, SLP CP 78394
1-215-674-4300 (General) 1-905-670-2291 www.crc-mexico.com
(800) 521-3168 (Technical) 52-444-824-1666
(800) 272-4620 (Customer Service)

24-Hr Emergency – CHEMTREC: (800) 424-9300 or (703) 527-3887

Section 2: Hazards Identification

Emergency Overview
DANGER: Extremely Flammable. Harmful or Fatal if Swallowed. Contents Under Pressure.
Appearance & Odor: Clear, colorless liquid with alcohol odor

Potential Health Effects:


ACUTE EFFECTS:
EYE: May cause mild irritation including stinging and redness, but does not injure eye.

SKIN: Single, brief exposures may cause mild irritation. Frequent or prolonged contact may cause more
severe irritation, defatting of the skin, and dermatitis.

INHALATION: High vapor concentrations are irritating to the respiratory tract and may cause headaches, dizziness,
anesthesia, drowsiness, unconsciousness and other central nervous system effects, including death.
May cause peripheral nervous system disorder and/or damage.

INGESTION: Low order of toxicity by ingestion. Main hazard is aspiration into the lungs during swallowing or
vomiting. Small amounts aspirated into the respiratory system may cause bronchopneumonia or
pulmonary adema, possibly progressing to death.

CHRONIC EFFECTS: Overexposure to n-hexane may cause progressive and potentially irreversible damage to the
peripheral nervous system, particularly in the arms and legs.

TARGET ORGANS: Central nervous system, peripheral nervous system, respiratory system

Medical Conditions Aggravated by Exposure: skin and respiratory conditions

See Section 11 for toxicology and carcinogenicity information on product ingredients.

Page 1 of 7
Product Name: QD™ Electronic Cleaner (aerosol)
Product Number (s): 75012, 75102

Section 3: Composition/Information on Ingredients

COMPONENT CAS NUMBER % by Wt.


Hexane isomers 64742-49-0 / 107-83-5 85 – 95
n-Hexane 110-54-3 6.6
Ethanol 64-17-5 <1
Carbon Dioxide 124-38-9 3–8

Section 4: First Aid Measures

Eye Contact: Immediately flush with plenty of water for 15 minutes. Call a physician if irritation persists.

Skin Contact: Remove contaminated clothing and wash affected area with soap and water. Call a physician if
irritation persists. Wash contaminated clothing prior to re-use.

Inhalation: Remove person to fresh air. Keep person calm. If not breathing, give artificial respiration. If
breathing is difficult give oxygen. Call a physician.

Ingestion: Do NOT induce vomiting. Contact a physician immediately.

Note to Physicians: Treat symptomatically. Gastric lavage using a cuffed endotracheal tube may be performed at your
discretion.

Section 5: Fire-Fighting Measures

Flammable Properties: This product is extremely flammable in accordance with aerosol flammability definitions.
(See 16 CFR 1500.3©(6) ).
Flash Point: < 0°F / < -17°C (TCC) Upper Explosive Limit: 9.0
Autoignition Temperature: 489°F / 254°C Lower Explosive Limit: 1.7

Fire and Explosion Data:


Suitable Extinguishing Media: Class B fire extinguishers, dry chemical, foam or CO2

Products of Combustion: Fumes, smoke and carbon monoxide

Explosion Hazards: Aerosol containers, when exposed to heat from fire, may build pressure and explode. Vapors
may accumulate in a confined space and create a flammable atmosphere.

Protection of Fire-Fighters: Firefighters should wear self-contained, NIOSH-approved breathing apparatus for
protection against suffocation and possible toxic decomposition products. Proper eye and
skin protection should be provided. Use water spray to keep fire-exposed containers cool
and to knock down vapors which may result from product decomposition. Do not spray
water directly on fire; product will float and could be reignited on surface of water.

Section 6: Accidental Release Measures

Personal Precautions: Use personal protection recommended in Section 8.

Environmental Precautions: Take precautions to prevent contamination of ground and surface waters. Do not flush into
sewers or storm drains.

Page 2 of 7
Product Name: QD™ Electronic Cleaner (aerosol)
Product Number (s): 75012, 75102
Methods for Containment & Clean-up: Dike area to contain spill. Remove all sources of ignition. Ventilate the area with
fresh air. If in confined space or limited air circulation area, clean-up workers
should wear appropriate respiratory protection. Recover or absorb spilled
material using an absorbent designed for chemical spills. Place used absorbents
into proper waste containers.

Section 7: Handling and Storage

Handling Procedures: Use proper grounding and bonding procedures for transferring materials. Do not use product
near any source of ignition. Avoid contact with eyes and skin. Avoid breathing vapors. Use
caution around energized equipment. The metal container will conduct electricity if it contacts a
live source. This may result in injury to the user from electrical shock and/or flash fire. For
product use instructions, please see the product label.

Storage Procedures: Store in a cool dry area out of direct sunlight. Aerosol cans must be maintained below 120°F /
49°C to prevent cans from rupturing.

Aerosol Storage Level: III

Section 8: Exposure Controls/Personal Protection

Exposure Guidelines:
OSHA ACGIH OTHER
COMPONENT TWA STEL TWA STEL TWA SOURCE UNIT

Hexane isomers 500(v) 1000(v) 500 1000 NE ppm


n-Hexane 500 NE 50(s) NE NE ppm
Ethanol 1000 NE 1000 NE NE ppm
Carbon Dioxide 5000 30000 (v) 5000 30000 NE ppm
N.E. – Not Established (c) – ceiling (s) – skin (v) – vacated

Controls and Protection:


Engineering Controls: Area should have ventilation to provide fresh air. Local exhaust ventilation is generally
preferred because it can control the emissions of the contaminant at the source, preventing
dispersion into the general work area. Use mechanical means if necessary to maintain vapor
levels below the exposure guidelines. If working in a confined space, follow applicable OSHA
regulations.

Respiratory Protection: None required for normal work where adequate ventilation is provided. If engineering controls
are not feasible or if exposure exceeds the applicable exposure limits, use a NIOSH-approved
cartridge respirator with organic vapor cartridge. Air monitoring is needed to determine actual
employee exposure levels. Use a self-contained breathing apparatus in confined spaces and
for emergencies.

Eye/face Protection: For normal conditions, wear safety glasses. Where there is reasonable probability of liquid
contact, wear splash-proof goggles.

Skin Protection: Use protective gloves such as nitrile, PVC, Viton®. Also, use full protective clothing if there is
prolonged or repeated contact of liquid with skin.

Section 9: Physical and Chemical Properties

Page 3 of 7
Product Name: QD™ Electronic Cleaner (aerosol)
Product Number (s): 75012, 75102
Physical State: liquid
Color: clear, colorless
Odor: alcohol
Odor Threshold: ND
Specific Gravity: 0.66
Initial Boiling Point: 140°F / 60°C
Freezing Point: < -76°F / < -60°C
Vapor Pressure: 175 mmHg @ 68°F / 20°C
Vapor Density: >1 (air = 1)
Evaporation Rate: very fast
Solubility: negligible in water
Coefficient of water/oil distribution: ND
pH: NA
Volatile Organic Compounds: wt %: 95 g/L: 627 lbs./gal: 5.2

Section 10: Stability and Reactivity

Stability: Stable

Conditions to Avoid: Sources of ignition, temperature extremes

Incompatible Materials: Strong oxidizers

Hazardous Decomposition Products: Oxides of carbon

Possibility of Hazardous Reactions: No

Section 11: Toxicological Information

Long-term toxicological studies have not been conducted for this product. The following information is available for
components of this product.

Acute Toxicity:

Component Oral LD50 (rat) Dermal LD50 (rabbit) Inhalation LC50 (rat)
Hexane isomers > 15,000 mg/kg > 2000 mg/kg No data
n-Hexane 28,710 mg/kg 3000 mg/kg 48,000 ppm/4H
Ethanol 760 mg/kg No data 20,000 ppm/10H
Carbon Dioxide No data No data 470,000 ppm/30M

Chronic Toxicity:
OSHA IARC NTP
Component Carcinogen Carcinogen Carcinogen Irritant Sensitizer
Hexane isomers No No No No Unknown
n-Hexane No No No E, S & R (moderate) Unknown
No No No E (mild) / Unknown
Ethanol
S (moderate)
Carbon Dioxide No No No No No

E – Eye S – Skin R - Respiratory


Reproductive Toxicity: No information available
Teratogenicity: No information available
Mutagenicity: No information available
Synergistic Effects: No information available

Page 4 of 7
Product Name: QD™ Electronic Cleaner (aerosol)
Product Number (s): 75012, 75102

Section 12: Ecological Information

Ecological studies have not been conducted for this product. The following information is available for components of this
product.

Ecotoxicity: n-hexane - 48 Hr EC50 water flea: 3.87 mg/L


96 Hr LC50 Lepomis macrochirus: 4.12 mg/L
Persistence / Degradability: No information available
Bioaccumulation / Accumulation: No information available
Mobility in Environment: No information available

Section 13: Disposal Considerations

Waste Classification: The dispensed liquid product is a RCRA hazardous waste for the characteristic of ignitability
with a waste code of D001. (See 40 CFR Part 261.20 – 261.33)
Any liquid product should be managed as a hazardous waste. Empty aerosol containers may
be recycled.

All disposal activities must comply with federal, state, provincial and local regulations. Local regulations may be more
stringent than state, provincial or national requirements.

Section 14: Transport Information

US DOT (ground): UN1950, Aerosols, flammable, 2.1, Limited Quantity**

ICAO/IATA (air): UN1950, Aerosols, flammable, 2.1, Limited Quantity

IMO/IMDG (water): UN1950, Aerosols, 2.1, Limited Quantity

Special Provisions: **This product can be classified and labeled as ‘Consumer Commodity, ORM-D’ for domestic
ground shipping until December 31, 2020.
If shipping as limited quantity by ground, note that shipping papers are not required.

Section 15: Regulatory Information

U.S. Federal Regulations:

Toxic Substances Control Act (TSCA):


All ingredients are either listed on the TSCA inventory or are exempt.

Comprehensive Environmental Response, Compensation and Liability Act (CERCLA):


Reportable Quantities (RQ’s) exist for the following ingredients: n-hexane (5000 lbs)

Spills or releases resulting in the loss of any ingredient at or above its RQ require immediate notification to
the National Response Center (800-424-8802) and to your Local Emergency Planning Committee.

Superfund Amendments Reauthorization Act (SARA) Title III:


Section 302 Extremely Hazardous Substances (EHS): None

Section 311/312 Hazard Categories: Fire Hazard Yes


Reactive Hazard No
Release of Pressure Yes
Page 5 of 7
Product Name: QD™ Electronic Cleaner (aerosol)
Product Number (s): 75012, 75102
Acute Health Hazard Yes
Chronic Health Hazard No

Section 313 Toxic Chemicals: This product contains the following substances subject to the reporting requirements
of Section 313 of Title III of the Superfund Amendments and Reauthorization Act of
1986 and 40 CFR Part 372:
n-hexane (6.6%)

Clean Air Act:


Section 112 Hazardous Air Pollutants (HAPs): n-hexane

Occupational Safety and Health Administration:


This product is regulated by the Hazard Communications Standard.

U.S. State Regulations:

California Safe Drinking Water and Toxic Enforcement Act (Prop 65):
This product may contain the following chemicals known to the state of
California to cause cancer, birth defects or other reproductive harm: None

Consumer Products VOC Regulations: NA

State Right to Know:


New Jersey: 75-83-2, 110-54-3, 79-29-8, 64-17-5, 124-38-9
Pennsylvania: 107-83-5, 75-83-2, 110-54-3, 79-29-8, 64-17-5, 124-38-9
Massachusetts: 107-83-5, 75-83-2, 110-54-3, 79-29-8, 64-17-5, 124-38-9
Rhode Island : 110-54-3, 64-17-5, 124-38-9

Canadian Regulations:

Controlled Products Regulations:


This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and the
MSDS contains all the information required by the Controlled Products Regulations.

WHMIS Hazard Class: A, B5, D2B

Canadian DSL Inventory: All ingredients are either listed on the DSL Inventory or are exempt.

European Union Regulations:

RoHS Compliance: This product is compliant with Directive 2002/95/EC of the European Parliament and of the
Council of 27 January 2003. This product does not contain any of the restricted substances as
listed in Article 4(1) of the RoHS Directive.

Additional Regulatory Information: None

Page 6 of 7
Product Name: QD™ Electronic Cleaner (aerosol)
Product Number (s): 75012, 75102

Section 16: Other Information

HMIS® (II) NFPA


Health: 1
Flammability: 3
3
Reactivity: 0
1 0
PPE: B

Ratings range from 0 (no hazard) to 4 (severe hazard)

Prepared By: Michelle Rudnick


CRC #: 985
Revision Date: 07/23/2014

Changes since last revision: Section 14: Transport Information

The information contained in this document applies to this specific material as supplied. It may not be valid for this
material if it is used in combination with any other materials. This information is accurate to the best of CRC Industries'
knowledge or obtained from sources believed by CRC to be accurate. Before using any product, read all warnings and
directions on the label. For further clarification of any information contained on this MSDS consult your supervisor, a
health & safety professional, or CRC Industries.

ACGIH: American Conference of Governmental Industrial Hygienists NA: Not Applicable


CAS: Chemical Abstract Service ND: Not Determined
CFR: Code of Federal Regulations NIOSH: National Institute of Occupational Safety & Health
DOT: Department of Transportation NFPA: National Fire Protection Association
DSL: Domestic Substance List NTP: National Toxicology Program
g/L: grams per Liter OSHA: Occupational Safety and Health Administration
HMIS: Hazardous Materials Identification System PMCC: Pensky-Martens Closed Cup
IARC: International Agency for Research on Cancer PPE: Personal Protection Equipment
IATA: International Air Transport Association ppm: Parts per Million
ICAO: International Civil Aviation Organization RoHS: Restriction of Hazardous Substances
IMDG: International Maritime Dangerous Goods STEL: Short Term Exposure Limit
IMO: International Maritime Organization TCC: Tag Closed Cup
lbs./gal: pounds per gallon TWA: Time Weighted Average
LC: Lethal Concentration WHMIS: Workplace Hazardous Materials Information
LD: Lethal Dose System

Page 7 of 7
MATERIAL SAFETY DATA SHEET MSDS DATE: 11/30/13

REFLEX 700 A
SECTION 1: PRODUCT AND COMPANY IDENTIFICATION

PRODUCT NAME: REFLEX 700 Component A


SYNONYMS: Modified Diphenylmethane Diisocyanate (MDI)
PRODUCT CODES: 872-1025

MANUFACTURER: Langeman Manufacturing Ltd.


ADDRESS: 56 Oak Street East
Leamington, ON, N8H 2C2
EMERGENCY PHONE: Chemtrec: 1-800-424-9300
OTHER CALLS: 1-519-326-6104
FAX PHONE: 1-519-326-4188

CHEMICAL NAME: Diphenylmethane Diisocyanate (MDI) Prepolymer


CHEMICAL FAMILY: Aromatic Isocyanate Prepolymer
CHEMICAL FORMULA: not applicable

PRODUCT USE: Polyurethane Coating for Truck Bedliners.


PREPARED BY: AdK

SECTION 1 NOTES:
CAS No. 39420-98-9

SECTION 2: COMPOSITION/INFORMATION ON INGREDIENTS

INGREDIENT:

Polyurethane Prepolymer: Proprietary formulation based on polyurethane technology.

SECTION 2 NOTES:

SECTION 3: HAZARDS IDENTIFICATION

EMERGENCY OVERVIEW:

May cause lung damage; May cause eye, skin, and respiratory tract irritation; Harmful if inhaled; May cause allergic respiratory reaction; May
cause allergic skin reaction; Toxic gases are given off during burning or thermal decomposition.

ROUTES OF ENTRY:
Skin: Contact from liquid and aerosols (spray application).
Inhalation: Although MDI is low in volatility, an inhalation hazard can exist from MDI aerosols or vapors formed during heating, foaming or
spraying.

POTENTIAL HEALTH EFFECTS

Acute Skin Contact: Isocyanates react with skin protein and moisture and can cause irritation which may include the following symptoms:
reddening, swelling, rash, scaling or blistering. Cured material is difficult to remove.
Acute Inhalation: MDI vapors or mist at concentrations above the TLV can irritate (burning sensation) the mucous membranes in the
respiratory tract (nose, throat, lungs) causing runny nose, sore throat, coughing, chest discomfort, shortness of breath and reduced
lung function (breathing obstruction). Persons with a preexisting, nonspecific bronchial hyper reactivity can respond to concentrations
below the TLV with similar symptoms as well as asthma attack. Exposure well above the TLV may lead to bronchitis, bronchial spasm
and pulmonary edema (fluid in lungs). These effects are usually reversible. Chemical or hypersensitive pneumonitis, with flu-like
symptoms (e.g., fever, chills) has also been reported. These symptoms can be delayed up to several hours after exposure.
Acute Eye Contact: Liquid, aerosols or vapors are irritating and can cause tearing, reddening and swelling. If left untreated, corneal damage
can occur and injury is slow to heal. However, damage is usually reversible. See First Aid Measures for treatment.
Acute Ingestion: Can result in irritation and corrosive action in the mouth, stomach tissue and digestive tract. Symptoms can include sore
throat, abdominal pain, nausea, vomiting and diarrhea.

PAGE 1 OF 6
MATERIAL SAFETY DATA SHEET MSDS DATE: 11/30/13

REFLEX 700 A
CHRONIC HEALTH HAZARDS:

Chronic Skin Contact: Prolonged contact can cause reddening, swelling, rash, scaling, blistering, and in some cases, skin sensitization.
Individuals who have skin sensitization can develop these symptoms from contact with liquid or vapors. Animal tests have indicated
that respiratory sensitization can result from skin contact with MDI. This data reinforces the need to prevent direct skin contact with
MDI. (See Toxicological Information, SENSITIZATION.)
Chronic Inhalation: As a result of previous repeated overexposures or a single large dose, certain individuals develop isocyanate
sensitization (chemical asthma) which will cause them to react to a later exposure to isocyanate at levels well below the TLV. These
symptoms, which can include chest tightness, wheezing, cough, shortness of breath or asthma attack, could be immediate or delayed
(up to several hours after exposure). Similar to many non-specific asthmatic responses, there are reports that once sensitized an
individual can experience these symptoms upon exposure to dust, cold air or other irritants. This increased lung sensitivity can persist
for weeks and in severe cases for several years. Overexposure to isocyanates has also been reported to cause lung damage (including
decrease in lung function) which may be permanent. Sensitization can either be temporary or permanent.
Chronic Eye Contact: None Found
Chronic Ingestion: None Found

MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE:


Asthma, other respiratory disorders (bronchitis, emphysema, bronchial hyper reactivity), skin allergies, eczema.

CARCINOGENICITY:

Neither MDI nor polymeric MDI are listed by the NTP, IARC or regulated by OSHA as carcinogens.

SECTION 4: FIRST AID MEASURES

Eyes: Flush with copious amount of water, preferably, lukewarm water for at least 15 minutes, holding eyelids open all the time. Refer
individual to physician or ophthalmologist for immediate follow-up.
Skin: Remove contaminated clothing. Wash affected skin thoroughly with soap and water. Wash contaminated clothing thoroughly before
reuse. For severe exposures, get under safety shower after removing clothing, then get medical attention. For lesser exposures, seek
medical attention if irritation develops or persists after the area is washed.
Inhilation: Move to an area free from risk of further exposure. Administer oxygen or artificial respiration as needed. Obtain medical attention.
Asthmatic-type symptoms may develop and may be immediate or delayed up to several hours. Consult physician should this occur.
Ingestion: DO NOT INDUCE VOMITING. Give 1 to 2 cups of milk or water to drink. DO NOT GIVE ANYTHING BY MOUTH TO AN
UNCONSCIOUS PERSON. Consult physician.
Note to Physician:
Eyes: Stain for evidence of corneal injury. If cornea is burned, instill antibiotic steroid preparation frequently. Workplace vapors have
produced reversible corneal epithelial edema impairing vision.
Skin: This compound is a known skin sensitizer. Treat symptomatically as for contact dermatitis or thermal burns. If burned, treat as thermal
burn. Ingestion. Treat symptomatically. There is no specific antidote. Inducing vomiting is contraindicated because of the irritating
nature of this compound.
Respiratory: This compound is a known pulmonary sensitizer. Treatment is essentially symptomatic. An individual having a skin or pulmonary
sensitization reaction to this material should be removed from exposure to any isocyanate.

SECTION 5: FIRE-FIGHTING MEASURES

Flammability Limits:
Upper Explosive Limit: (UEL) (%): Not Established

Lower Explosive Limit (LEL) (%): Not Established

Auto-Ignition Temperature: ~860 F (460 C) (similar material)

Flash Point: 421.0 °F (216.1 °C) Pensky-Martens Closed Cup (ASTM D-93)

PAGE 2 OF 6
MATERIAL SAFETY DATA SHEET MSDS DATE: 11/30/13

REFLEX 700 A
Extinguishing Media: Dry Chemical; Carbon Dioxide; Foam; Water spray for large fires.
Special Firefighting Procedures: Full emergency equipment with self-contained breathing apparatus and full protective clothing should be
worn by firefighters. During a fire, MDI vapors and other irritating, highly toxic gases may be generated by thermal decomposition or
combustion. (See Stability and Reactivity). At temperatures greater than 400 °F (204 °C), polymeric MDI can polymerize and
decompose which can cause pressure build-up in closed containers. Explosive rupture is possible. Therefore, use cold water to cool
fire-exposed containers.
Unusual Fire and Explosion Hazards: None reported for this product.

Health: 2 Flammability: 1 Reactivity: 1

SECTION 6: ACCIDENTAL RELEASE MEASURES

Accidental Release Measures:


Evacuate and ventilate spill area; dike spill to prevent entry into water system; wear full protective equipment, including respiratory
equipment during clean-up. (See Employee Protection Recommendations). Major Spill: Call Langeman Manufacturing at 519-326-
6104. If transportation spill, call CHEMTREC 800-424-9300. If temporary control of isocyanate vapor is required, a blanket of protein
foam (available at most fire departments) may be placed over the spill. Large quantities may be pumped into closed, but not sealed,
container for disposal. Minor Spill: Absorb isocyanates with sawdust or other absorbent, shovel into suitable unsealed containers,
transport to well-ventilated area (outside) and treat with neutralizing solution: mixture of water (80%) with non-ionic surfactant Tergitol
TMN-10 (20%), or; water (90%), concentrated ammonia (3-8%) and detergent (2%). Add about 10 parts of neutralizer per part of
isocyanate, with mixing. Allow to stand uncovered for 48 hours to let C02 escape. Clean-up: Decontaminate floor with decontamination
solution letting stand for at least 15 minutes.

SECTION 7: HANDLING AND STORAGE

Handling and Storage: Store in tightly closed containers to prevent moisture contamination. Do not reseal if contamination is suspected.
Avoid contact with skin and eyes. Do not breathe aerosols or vapors. Warning properties (irritation of the eyes, nose and throat or odor)
are not adequate to prevent chronic overexposure from inhalation. This material can produce asthmatic sensitization upon either single
inhalation exposure to a relatively high concentration or upon repeated inhalation exposures to lower concentrations. Exposure to
vapors of heated MDI can be extremely dangerous. Employee education and training in the safe use and handling of this compound
are required under the OSHA Hazard Communication Standard.
Storage Temperature: 60 °F (15 °C)/95 °F (35 °C)
Special Sensitivity: If container is exposed to high heat, 400 °F (204 ºC) it can be pressurized and possibly rupture. MDI reacts slowly with
water to form C02 gas. This gas can cause sealed containers to expand and possibly rupture.
Shelf Life: 6 months @ 77 °F (25 °C)
_________________________________________________________________________________________________________________
SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls: : Local exhaust should be used to maintain levels below the TLV whenever MDI is processed, heated or spray
applied. Standard reference sources regarding industrial ventilation (ie., ACGIH Industrial Ventilation) should be consulted for guidance
about adequate ventilation.
Eye Protection: Liquid chemical goggles. Vapor resistant goggles should be worn when contact lenses are in use. In a splash hazard
environment chemical goggles should be used in combination with a full face-shield.
Skin Protection: Permeation resistant gloves (butyl rubber, nitrile rubber, polyvinyl alcohol). However, please note that PVA degrades in
water. Cover as much of the exposed skin area as possible with appropriate clothing. If skin creams are used, keep the area covered
by the cream to a minimum. Ventilation Procedures
Respiratory Equipment: Concentrations greater than the TLV can occur when MDI is sprayed, heated or used in a poorly ventilated area. In
such cases, or whenever concentration: of MDI exceed the TLV or are not known, respiratory protection must be worn. A supplied air
respirator (either positive pressure or continuous flow type) is required. In an emergency situation, a self-contained breathing apparatus
may be used. MDI has poor warning properties, since the concentration at which MDI can be smelled is substantially higher than the
maximum exposure limit. Observe OSHA regulations for respirator use (29 CFR 1910.134).
Monitoring: Isocyanate exposure levels must be monitored. Monitoring of airborne isocyanates in the breathing zone of individuals should
become part of the overall employee exposure characterization program. Monitoring techniques have been developed by NIOSH, and
OSHA.
Medical Surveillance: Medical supervision of all employees who handle or come in contact with isocyanates is recommended. These should
include pre employment and periodic medical examinations with pulmonary function tests (FEV, FVC a: a minimum). Persons with
asthmatic-type conditions, chronic bronchitis, other chronic respiratory disease or recurrent skin eczema or sensitization should be
excluded from working with isocyanates. Once a person is diagnosed as sensitized to an isocyanate, no further exposure can be
permitted.
PAGE 3 OF 6
MATERIAL SAFETY DATA SHEET MSDS DATE: 11/30/13

REFLEX 700 A
Additional Protective Measures: Safety showers and eyewash stations should be available. Educate and train employees in safe use of
product. Follow all label instructions.

SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES

APPEARANCE: Yellowing Liquid


ODOR: Slightly musty odor
PH: Not Applicable
BOILING POINT: 406 °F (208 °C) @ 5 mmHg for MDI
MELTING/FREEZING POINT: Range 50 °F (10 °C) for MDI to 60 °F (16 °C)
VISCOSITY: Not Applicable
SOLUBILITY IN WATER Not soluble. Reacts slowly with water to liberate C02 gas.
SPECIFIC GRAVITY: 1.090 @ 77 °F (25 °C)
BULK DENSITY: 9.10 lbs/gal
% VOLATILE BY VOLUME: 0%
VAPOR PRESSURE: Less than 10-5 mmHg @ 77 °F (25 °C) for MDI
VAPOR DENSITY 8.5 (MDI) (Air =1) .............................

SECTION 10: STABILITY AND REACTIVITY

STABLE X UNSTABLE

Stability: Stable under normal circumstances.

Hazardous Polymerization:
May occur; Contact with moisture, other materials which react with isocyanates, temperatures above 400 °F (204 °C), may cause
polymerization.

Incompatibility (Materials to avoid): Water, amines, strong bases, alchohols, metal compounds and surface active materials.

Instability Conditions: Contamination with water.

Decomposition Conditions: By high heat and fire: carbon dioxide, carbon monoxide, oxides of nitrogen, HCN, HDI and other unknown
aliphatic fragments.

SECTION 11: TOXICOLOGICAL INFORMATION

Toxicity Data for: Diphenylmethane Diisocyanate (Monomeric and Polymeric)


Acute Toxicity:
ORAL LD5O ........................................................ Greater than 15,800 mg/kg (Rat)
DERHAL LD5O .................................................... Greater 5010 but less than 7,940 mg/kg (Rabbit)
INHALATION LC5O ............................................. The 4-hour LC5O for polymeric MDI in rats ranges from 370 to 490 mg/m3. The LC5O
for monomeric MDI was estimated to be between 172 and 187 mg/m3.
EYE EFFECTS .................................................... Slight to moderate irritation.
SKIN EFFECTS ................................................... Slight to moderate irritation.
SENSITIZATION ................................................. MDI has been shown to produce dermal sensitization in laboratory animals. Evidence
of respiratory sensitization has also been observed in guinea pigs. In addition, there is
some evidence suggestive of cross-sensitization between different types of
diisocyanates.

_________________________________________________________________________________________________________________
SECTION 12: ECOLOGICAL INFORMATION

Ecology Data for: Diphenylmethane Diisocyanate (Monomeric and Polymeric)


Aquatic Toxicity: LC5O - 24 hr. (static): Greater than 500 mg/liter for Daphnia magna, Limnea Stagnalis, and Zebra fish (Brachydanio rerio)
for both polymeric and monomeric MDI.

PAGE 4 OF 6
MATERIAL SAFETY DATA SHEET MSDS DATE: 11/30/13

REFLEX 700 A
SECTION 13: DISPOSAL CONSIDERATIONS

Waste Disposal Method: Waste must be disposed of in accordance with federal, state, and local environmental control regulations.
Incineration is the preferred method.
Empty Container Regulations: Empty containers must be handled with care due to product residue. Decontaminate containers prior to
disposal. Empty decontaminated containers should be crushed to prevent reuse. DO NOT HEAT OR CUT EMPTY CONTAINER WITH
ELECTRIC OR GAS TORCH. (See Fire Fighting Measures and Stability & Reactivity). Gases may be highly toxic.
Transportation Emergencies: Langeman Mfg Ltd. requires that CHEMTREC be immediately notified (800-424-9300) when this product is
unintentionally released from its container during its course of distribution, regardless of the amount released. Distribution includes
transportation, storage incidental to transportation, loading and unloading. Such notification must be immediate and made by the
person having knowledge of the release.

SECTION 14: TRANSPORT INFORMATION

TECHNICAL SHIPPING NAME ..................................... Methylene diphenyl diisocyanate


FREIGHT CLASS BULK ................................................ Methylene diphenyl diisocyanate
FREIGHT CLASS PACKAGE ........................................ Chemicals, NOI (Isocyanate), NMFC 60000
PRODUCT LABEL......................................................... Product Label Established
DOT (DOMESTIC SURFACE)

PROPER SHIPPING NAME .......................................... Other Regulated Substances, Liquid, N.O.S. * SEE NOTE BELOW
HAZARD CLASS OR DIVISION .................................... 9
UN/NA NUMBER ........................................................... NA3082
PACKAGING GROUP ................................................... PG III
HAZARDOUS SUBSTANCE ......................................... MDI, (Methylene diphenyl diisocyanate)
DOT PRODUCT RQ lbs (kgs)........................................ 33333 lbs (15119.8 kgs)
HAZARD LABEL(s......................................................... Class 9
HAZARD PLACARD(s) .................................................. Class 9

* WHEN IN INDIVIDUAL CONTAINERS OF LESS THAN THE PRODUCT RQ, THIS MATERIAL SHIPS AS NON-REGULATED.
IMO / IMDG CODE (OCEAN)

HAZARD CLASS DIVISION NUMBER: ......................... Non-Regulated


ICAO / IATA (AIR)

HAZARD CLASS DIVISION NUMBER: ......................... Non-Regulated

SECTION 15: REGULATORY INFORMATION

OSHA STATUS ............................................................. This product is hazardous under the criteria of the Federal OSHA Hazard
Communication Standard 29 CFR 1910.1200.
TSCA STATUS.............................................................. On TSCA Inventory
CERCLA REPORTABLE QUANTITY ............................ 5000 lbs for 4,4' - Diphenylmethane Diisocyanate, CAS# 101-68-8.
SARA TITLE III:
SECTION 302 EXTREMELY
HAZARDOUS SUBSTANCES: .......................... None
SECTION 311/312
HAZARD CATEGORIES ................................... Immediate Health Hazard; Delayed Health Hazard; Reactive Hazard
SECTION 313
TOXIC CHEMICALS ............................................ 4,4'-Diphenylmethane Diisocyanate, CAS# 101-68-8; Upper Bound 15%
RCRA STATUS ............................................................. MDI is not listed as a hazardous waste. To the best of our knowledge, MDI does not
meet the criteria of a hazardous waste if discarded in its purchased form. However,
under RCRA, it is the responsibility of the user of products to determine, at the time of
disposal, whether a product meets any of the criteria for a hazardous waste. This is
because product uses, transformations, mixtures, processes, etc., may render the
resulting material hazardous, under the criteria of ignitability, corrosivity, reactivity and
toxicity characteristics under the new Toxicity Characteristics Leaching Procedure
(TCLP) 40 Code of Federal Regulations 261.20-24.
The following chemicals are specifically listed by individual states; other product specific health and safety data in other sections of the
MSDS may also be applicable for state requirements. For details on your regulatory requirements you should contact the appropriate
agency in your state.
PAGE 5 OF 6
MATERIAL SAFETY DATA SHEET MSDS DATE: 11/30/13

REFLEX 700 A
CALIFORNIA PROPOSITION 65
To the best of our knowledge, this product contains no levels of listed substances, which the state of California has found to cause
cancer, birth defects or other reproductive effects.

SECTION 16: OTHER INFORMATION

OTHER INFORMATION:

NTP Not listed


IARC Not listed
OSHA ............................................................................ Not regulated

DISCLAIMER:

The information accumulated herein is believed to be accurate but is not warranted to be whether originating with the company or not.
Recipients are advised to confirm in advance that the information is current, applicable, and suitable to their circumstances.

PAGE 6 OF 6
M A T E R I A L S A F E T Y D A T A S H E E T
71024 Page 1

================== SECTION I - PRODUCT IDENTIFICATION =================

PRODUCT NAME: RUSTEX PRIMER GREY HMIS CODES: H F R P

PRODUCT IDENTIFIER: 71024 2 3 0 G


*
PRODUCT USE: General purpose coating.
PRODUCT IDENTIFICATION NUMBER: UN1263
WHMIS INFO: B2, D1B, D2A, D2B

MANUFACTURER'S NAME: Cloverdale Paint Inc


ADDRESS : 6950 King George Boulevard
Surrey, BC,
EMERGENCY PHONE : 613-996-6666 REVISION DATE: 28-May-14
INFORMATION PHONE : 604-596-6261
ABREVIATIONS : N/AP – NOT APPLICABLE N/AV – NOT AVAILABLE

================== SECTION II - HAZARDOUS INGREDIENTS =====================

REPORTABLE COMPONENTS CAS NUMBER WEIGHT PERCENT O.E.L.

*XYLENE 1330-20-7 15-40 ACGIH TLV: 100 PPM

LD50: ORAL:4g/kg rat, LC50: 6500 ppm/4H(RAT)

LD50: SKIN:5000 mg/kg(RABBIT)

TITANIUM DIOXIDE 13463-67-7 7-13 TLV (ACGIH): 10 mg/m3, total dust, 8 hr. TWA

ETHYLBENZENE 100-41-4 5-10 TWA: 100ppm LD50 (ORAL-RAT): 3500 mg/kg

LD50: SKIN:17800 mg/kg(RABBIT)

HIGH FLASH NAPHTHA MIXTURE 1-5 ACGIH TLV: 50 ppm

LD50:ORAL:>8.0 ml/kg(RAT), LC50:>10200


mg/m3/4H(RAT)

METHANOL 67-56-1 0.1-1 ACGIH TLV: 200 ppm

LD50: ORAL:5628 mg/kg(RAT), LC50: 64000


ppm/4H(RAT)

----------------------------------------------------------------------------------

*** No toxic chemical(s) subject to the reporting requirements of section 313 of Title III
and of 40 CFR 372 are present. ***
----------------------------------------------------------------------------------

=============== SECTION III - PHYSICAL/CHEMICAL CHARACTERISTICS ============

BOILING POINT: 65.0 deg C SPECIFIC GRAVITY (H2O=1): 1.18


VAPOR DENSITY: Heavier than air. PHYSICAL STATE: Liquid.
EVAPORATION RATE: Slower than n-Butyl Acetate.
COATING V.O.C.: 571 g/l (before thinning)
SOLUBILITY IN WATER: Insoluble.
APPEARANCE AND ODOR: Moderately thick liquid; Aromatic odor.
FREEZING POINT: Not available. pH: Not available.
M A T E R I A L S A F E T Y D A T A S H E E T
71024 Page 2

COEFFICIENT OF WATER/OIL DIST: N/AV ODOR THRESHOLD: 1-30 ppm

================= SECTION IV - FIRE AND EXPLOSION HAZARD DATA ==============

FLASH POINT: 24 C METHOD USED: Not available.


FLAMMABLE LIMITS IN AIR BY VOLUME- LOWER: Not available.
UPPER: Not available.

EXTINGUISHING MEDIA:
Foam, CO2, dry chemical, water fog.

SPECIAL FIREFIGHTING PROCEDURES


Respiratory equipment should be worn to avoid inhalation of concentrated vapours.
Water should not be used except as a fog to keep nearby containers cool.

UNUSUAL FIRE AND EXPLOSION HAZARDS


Handle as a flammable liquid. Vapours form an explosive mixture in air between the
upper and lower explosive limits, which, can be ignited by many sources such as
pilot lights, open flames, electrical boxes and switches. Vapour may travel along
the ground and flashback along vapour trail may occur.

FLAMMABILITY – T.D.G.R. CLASS:


TDG CLASS 3

SENSITIVITY TO IMPACT: NO

AUTO-IGNITION TEMPERATURE:
Not available

SENSITIVITY TO STATIC DISCHARGE: Yes

HAZARDOUS COMBUSTION PRODUCTS:


Carbon Monoxide, Carbon Dioxide and Oxides of Nitrogen.

======================== SECTION V - REACTIVITY DATA =======================

CHEMICAL STABILITY: STABLE

CONDITIONS TO AVOID:
Excessive heat, poor ventilation, corrosive atmospheres, excessive aging.

INCOMPATIBILITY (MATERIALS TO AVOID)


Alkaline materials, strong acids and oxidizing agents.

HAZARDOUS DECOMPOSITION OR BYPRODUCTS: Not available.

HAZARDOUS POLYMERIZATION:
Will not occur.

==================== SECTION VI - TOXICOLOGICAL DATA =======================

INHALATION HEALTH RISKS AND SYMPTOMS OF EXPOSURE


May cause respiratory irritation, dizziness, breathing difficulty, headaches and
loss of co-ordination.

SKIN AND EYE CONTACT HEALTH RISKS AND SYMPTOMS OF EXPOSURE


Eye Contact: May cause severe irritation, tearing, redness and blurred vision.
Skin Contact: May cause irritation.
M A T E R I A L S A F E T Y D A T A S H E E T
71024 Page 3

SKIN ABSORPTION HEALTH RISKS AND SYMPTOMS OF EXPOSURE


May dry and defat skin causing cracks, irritation and dermatitis.

INGESTION HEALTH RISKS AND SYMPTOMS OF EXPOSURE


Contains Methanol which is poisonous if swallowed. May cause blindness, narcosis,
headache, nausea and vomiting leading to severe illness.

HEALTH HAZARDS (ACUTE AND CHRONIC)


Acute: Contains Methanol which is poisonous if swallowed. Causes blindness.
Chronic: Repeated exposure by inhalation or absorption may cause systemic
poisoning. Prolonged exposure to crystalline silica dust by inhalation may cause
delayed lung injury/disease (Silicosis).

SENSITIZING CAPABILITY: Not available.

CARCINOGENICITY: NTP CARCINOGEN:No IARC MONOGRAPHS:Yes OSHA REGULATED:No


Ethylbenezene has been classified by the IARC as a Group 2B substance on the basis
of sufficient evidence for carcinogenicity in laboratory animals but inadequate
evidence for cancer in humans. In a lifetime inhalation study, exposure to 250
mg/m3 titanium dioxide dust resulted in the development of lung tumors in rats.
These tumors occurred only at dust levels that overwhelmed the animals' lung
clearance mechanisms and were different from common human lung tumors in both type
and location. The relevance of these findings to humans is unknown. The
International Agency for Research on Cancer (IARC) has classified Titanium Dioxide
as possibly carcinogenic to humans (Group 2B) based on inadequate evidence of
carcinogenicity in humans and sufficient evidence of carcinogenicity in
experimental animals.

TERATOGENICITY AND EMBRYOTOXICITY


High exposures to xylenes in some animal studies have been reported to cause
health effects on the developing embryo/fetus. These effects were often at levels
toxic to the mother. The significance of these findings to humans has not been
determined.

REPRODUCTIVE TOXICITY
Not available.

MUTAGENICITY
Not available.

TOXICOLOGICALLY SYNERGISTIC PRODUCTS


None known.

MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE


Anesthesia, respiratory tract irritation, dermatitis, nausea, vomiting.

================= SECTION VII - PREVENTIVE MEASURES =======================

STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED


Eliminate ignition sources. Provide good ventilation or wear appropriate breathing
apparatus. Absorb small spills with non-flammable absorbent. Contain spills by
diking with non-flammable absorbent. Notify environmental agency.

WASTE DISPOSAL METHOD


M A T E R I A L S A F E T Y D A T A S H E E T
71024 Page 4

Reclaim or dispose of through a licensed waste disposal company according to


Federal,Provincial and local regulations.

PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING


Flammable. Store in a cool, dry, well ventilated area away from heat and ignition
sources. Keep containers closed when not in use. Avoid breathing vapours or mist
and prolonged or repeated contact with skin. Launder contaminated clothing prior
to re-use. Use good personal hygiene. Product is a static accumulator. Transfer
equipment should be grounded or bonded.

OTHER PRECAUTIONS: Smoking in the area where this material is used must be
strictly prohibited.

RESPIRATORY PROTECTION
NIOSH approved for organic vapours and particulate matter.

VENTILATION
General mechanical ventilation or local exhaust should be suitable to keep vapour
concentrations below TLV. Ventilation equipment must be explosion proof. Make up
air should be supplied to balance air exhausted.

PROTECTIVE GLOVES
Solvent impervious e.g. Viton, Nitrile, PVC.

EYE PROTECTION
Chemical safety glasses, goggles or face shield.

OTHER PROTECTIVE CLOTHING OR EQUIPMENT


Use impermeable aprons and protective clothing whenever possible to prevent skin
contact.

WORK/HYGIENIC PRACTICES
Eye washes and safety showers in the workplace are recommended.

===================== SECTION VIII - FIRST AID MEASURES =====================

INHALATION OVEREXPOSURE: Move person to fresh air. If breathing stops, apply


artificial respiration and seek immediate medical attention.

EYE CONTACT: Flush with water for at least 15 minutes. Seek medical attention.

SKIN CONTACT: Wash thoroughly with mild soap and water.

INGESTION: Do not induce vomiting. Aspiration of solvents in this product can


cause inflammation of the lungs.

========================= SECTION IX - PREPARATION ========================

PREPARED BY: TECHNICAL DEPARTMENT

========================= SECTION X - DISCLAIMER ==========================


To the best of our knowledge, the information contained herein is accurate,
obtained from sources believed by Cloverdale Paint Inc. to be accurate. No
warranty concerning the accuracy of these sources is made and Cloverdale Paint
Inc. will not be held liable for claims relating to use of this information or
recommendations.
M A T E R I A L S A F E T Y D A T A S H E E T
Key1 Page 5
Page 1 of 5
Sika Canada Inc. MATERIAL SAFETY DATA SHEET

SECTION I: PRODUCT INFORMATION

® th
PRODUCT: Sikaflex -252 REVISION DATE: February 24 , 2015

USAGE: ONE COMPONENT URETHANE BASED ADHESIVE / SEALANT

SUPPLIER: SIKA CANADA INC.


601, avenue Delmar
Pointe Claire, QC
H9R 4A9

EMERGENCY TELEPHONE NUMBER: CANUTEC (collect) (613) 996-6666

TDG CLASSIFICATION: Not Regulated WHMIS Classification: B3, D2A


UN NUMBER: Not Established Class: Not Applicable
Packaging Group: Not Applicable

SECTION II: HAZARDOUS INGREDIENTS

LD50 (mg/kg) LC50


Hazardous ingredients % T.L.V. # CAS
(route, species) (species, route)

ACGIH
XYLENE 1-5 100ppm (TWA) 1330-20-7 4300 (oral, rat) 6350ppmh/4H
150ppm (STEL)

POLYOL AND
ISOCYANATE 30-60 Not Established Not Available Not Established Not Established
PREPOLYMER

AMORPHOUS SILICA 5-10 Not Available 7631-86-9 Not Available Not Available

METHYLENE ACGIH
3
369mg/m /4H
BIS PHENYL 0,1-1,0 101-68-8 31 600 (oral, rat)
ISOCYANATE 0,005 ppm (rat)

SECTION III: PHYSICAL CHARACTERISTICS

Physical State: Paste Boiling Point: Not Established


Appearance and Odor: Various color, odorless Freezing Point: Not Established
Density: 1,21 g/ml
Odor Threshold: Not Established Water Solubility: Not Established
Evaporation Rate: Not Established pH: Not Established
Vapor Density: Not Established % volatile: Not Established
Vapor Pressure: Not Established Water/Oil Distribution: Not Established
Page 2 of 5
Sika Canada Inc. MATERIAL SAFETY DATA SHEET

®
PRODUCT: Sikaflex -252

SECTION IV: FIRE AND EXPLOSION HAZARDS

Flammability: No TDG inflammability Class: Not Regulated


Flammable upper limits (% vol.): Not Established
If Yes, under what conditions: Flammable lower limits (% vol.): Not Established
Flash Point (method used): > 80°C (TCC)
Extinguishing methods: Foam, dry chemical Auto-ignition temperature: Not Established
products, CO2, water for Dangerous Combustion Products: Carbon oxides,
large flames. Nitrogen oxide.

Special Methods: Firefighters must wear


complete protective Protect from mechanical impact: No
clothing with respiratory
equipment and they must Protect from static discharge: No
protect any exposed skin.
Heated isocyanates react
strongly with water.

SECTION V: REACTIVITY DATA

Chemical stability: Yes Dangerous decomposition products: Carbon oxides,


Nitrogen oxide,
If not, under what conditions:

Incompatibility with other material: Yes Polymerization Risks: No

If Yes, which ones: Acid, strong


oxidizer, amine.
Page 3 of 5
Sika Canada Inc. MATERIAL SAFETY DATA SHEET

®
PRODUCT: Sikaflex -252

SECTION VI: TOXIC PROPERTIES

ROUTE OF ENTRY / CONTACT

Eyes: Irritating. Carcinogenicity: Not Established

Skin: Irritating. Contact may result in dermatitis, Toxic effects


allergic reactions, and sensitization. on reproduction: Not Established

Inhalation: Vapor or mist from this product may Teratogenicity: Xylene is classified as a
cause irritation. development toxicant
(Embryo toxin)

Ingestion: May cause nausea, vomiting, fainting,


diarrhea, lung damage, G.I. system Mutagenicity: Not Established
disorder, constipation, ulcers.

Product with synergistic


effects: Not Established

Over exposure may cause breathing difficulties,


sensitization, headaches, nausea, vomiting. May
aggravate respiratory, skin, eye, lung problems and
allergies.

If the product is applied according to the manufacturer,


none of these symptoms should be encountered.

A person who is sensitized to isocyanate may have a


reaction with a level of isocyanate well below the T.L.V.

Xylene is a central nervous system depressor and in rare


cases, may cause a sensitization of the heart muscle
causing arrhythmia.

An acute or chronic exposure will increase the toxic effects mentioned in this section and may aggravate respiratory
problems. An over exposure may cause death.
Page 4 of 5
Sika Canada Inc. MATERIAL SAFETY DATA SHEET

®
PRODUCT: Sikaflex -252

SECTION VII: PREVENTIVE MEASURES

PERSONAL PROTECTIVE EQUIPMENT OTHERS

Gloves: Use chemical resistant gloves. Ventilation: Sufficient ventilation required

Respiratory equipment: Use a NIOSH approved respirator Procedure in case


if the TLV is exceeded. of leaks: Absorb with sand or other
absorbent material.
Eyes: Full face mask or safety glasses
Handling and Equipment
Shoes: Leather methods: Avoid skin, eye and clothing
contact
Clothing: Rubber Apron
Warehouse
Other: Eye wash station, shower Requirements: Keep all containers closed in a
cool, dry and well ventilated area.
Keep away from heat and open
flame.

Special Shipping
Instructions: See TDG class

Waste Disposal: Dispose of sand and rinse water


according to municipal, provincial
or federal laws for disposal of
chemical.
Page 5 of 5
Sika Canada Inc. MATERIAL SAFETY DATA SHEET

®
PRODUCT: Sikaflex -252

SECTION VIII: FIRST AID

Skin : Remove contaminated clothing and shoes.


Wash immediately with plenty of water.
Wash clothing before re-wearing.
Consult a physician if required.

Eyes : Rinse eyes immediately with plenty of water for several minutes, while holding
eyelids wide open, to ensure a proper wash.
See a physician immediately.

Inhalation : In the case of overexposure, evacuate to fresh air.


Consult a physician if required.

Ingestion : Drink plenty of water. Do not induce vomiting.


Do not give anything by mouth to an unconscious person.
See a physician immediately.

SECTION IX: PREPARATION INFORMATION

Prepared By: R & D of Sika Canada Inc.


Telephone #: (514) 697-2610
Fax #: (514) 694-2792

Notice To Reader

The information contained in this Material Safety Data Sheet applies only to the actual Sika Canada product identified and described herein. This
information is not intended to address, nor does it address the use or application of the identified Sika product in combination with any other material,
product or process. All of the information set forth herein is based on technical data regarding the identified product that Sika believes to be reliable
as of the date hereof. Prior to each use of any Sika product, the user must always read and follow the warnings and instructions on the product's
current Product Data Sheet, product label and Material Safety Data Sheet for each Sika product, which are available at web site and/or telephone
number listed in Section IX of this MSDS.

SIKA MAKES NO WARRANTIES EXPRESS OR IMPLIED AND ASSUMES NO LIABILITY ARISING FROM THIS INFORMATION OR ITS USE.
SIKA SHALL NOT BE LIABLE UNDER ANY LEGAL THEORY FOR SPECIAL OR CONSEQUENTIAL DAMAGES AND SHALL NOT BE
RESPONSIBLE FOR THE USE OF THIS PRODUCT IN A MANNER TO INFRINGE ON ANY PATENT OR ANY OTHER INTELLECTUAL
PROPERTY RIGHTS HELD BY OTHERS.

All sales of Sika products are subject to its current terms and conditions of sale available at www.sika.ca or 514-697-2610.

AQ 191 A
Date: 2012/02/01
App: S.G.
Revision date: 18/0612015 Revision: 1
1.

SAFETY DATA SHEET


Stokolan® intensive repair

SECTION 1 Identification of the substance!mbcture and of the oornpany/undertaldng


1
1.1. Product identifier
Product name Stokolan® intensive repair

Product number 99036413,99036414,99036415,99036416,99042843,9903641 7,9903641 89903641 9990364


20

Internal identification M 961

1.2. Relevant identified uses of the substance or mixture and uses advised against
Identified uses Hand Cream

1.3. Details of the supplier of the safety data sheet


Supplier Deb Ltd
Denby Hall Way
Denby
Derbyshire
DE5 8JZ
Main Tel. 01773 855100
Technical Tel 01773 855105
[email protected]

1.4. Emergency telephone number


Emergency telephone National Poisons Information Service (UK) 0844 8920111

[SECTION 2 Hazards identification

2.1. Classification of the substance or mixture


Classification
Physical hazards Not Classified

Health hazards Not Classified


Environmental hazards Not Classified

Classification (67!5481EEC or
I 9991451EC)

2.2. Label elements


Hazard statements NC Not Classified

2.3. Other hazards


This product does not contain any substances classified as PBT or vPvB.

[SECTION 3 Composiboniinformabon on ingredients ‘

3.2. Mixtures

116
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Stokolan® intensive repair

INCI AQUA (WATER)


VITIS VINIFERA SEED OIL
CAPRYLIC/CAPRIC TRIGLYCERIDE
DICAPRYLY ETHER
POLYGLYCERYL-4 DI ISOSTEARATE/POLYHYDROXYSTEARATE/SEBACATE
ISOPRPYL PALMITATE
UREA
SORBITOL
ZINC SULFATE
GINKGO BILOBA LEAF EXTRACT
ALLANTOIN
TOCOPHEROL
CERA ALBA
GLYCERIN
CHOLESTEROL
CERAMIDE NP
CERAMIDE NS
CERAMIDEEOS
CERAMIDE EOP
CERAMIDE AP
CAPROOYL PHYTOSPHINGOSINE
CAPROOYL SPHINGOSINE
HYDROGENATED CASTOR OIL
CERA MICROCRISTALLINA/PARAFFIN
CETYL ALCOHOL
BEHENIC ACID
CETEARETH-25
PHENOXYETHANOL
BENZOIC ACID
DEHYDROACETIC ACID
ETHYLHEXYLGLYCERIN
TRISODIUM DICARBOXYMETHYL ALANINATE
ALCOHOL
PROPYLENE GLYCOL
ASCORBYL PALMITATE
ASCORBIC ACID
CITRIC ACID
LACTIC ACID
PARFUM (FRAGRANCE)

SECTION 4 First aid measures

4.1. Desciiption of first aid measures


Inhalation Not relevant. Unlikely route of exposure as the product does not contain volatile substances.

Ingestion Rinse mouth thoroughly with water. Get medical attention if any discomfort continues.

Skin contact Not relevant.

Eye contact Remove any contact lenses and open eyelids wide apart. Continue to rinse for at least 15
minutes. Continue to rinse for at least 15 minutes. Get medical attention promptly if symptoms
occur after washing.

4.2. Most important symptoms and effects, both acute and delayed
Inhalation No specific symptoms known.

Ingestion No specific symptoms known.

2/6
Revision date: 1810612015 Revision: I

Stokolan® intensive repair

Skin contact Does not decompose when used and stored as recommended.

Eye contact May cause temporary eye irritation.

4.3. Indication of any immediate medical attention and special treatment needed
Notes for the doctor No specific recommendations.

SECTION 5 Firefighting measures

5.1. Extinguishing media


Suitable extinguishing media The product is not flammable. Use fire-extinguishing media suitable for the surrounding fire.

5.2. Special hazards arising from the substance or mixture


Hazardous combustion No known hazardous decomposition products.
products

5.3. Advice for firefighters


Protective actions during No specific firefighting precautions known.
firefighting

SECTION 6: Accidental release measures


6.1. Personal precautions, protective equipment and emergency procedures
Personal precautions Avoid contact with eyes.

6.2. Environmental precautions


Environmental precautions Not considered to be a significant hazard due to the small quantities used.

6.3. Methods and material for containment and deaning up


Methods for deaning up Flush away spillage with plenty of water. Avoid contamination of ponds or watercourses with
washing down water. Absorb spillage with non-combustible, absorbent material. Do not
discharge into drains or watercourses or onto the ground.

6.4. Reference to other sections


Reference to other sections For waste disposal, see Section 13.

SECTION 7 Handling and storage

7.1. Precautions for safe handling


Usage precautions Avoid contact with eyes.

7.2. Conditions for safe storage, induding any incompatibilities


Storage precautions Store in closed original container at temperatures between 0°C and 30°C.

7.3. Specific end use(s)


Specific end use(s) The identified uses for this product are detailed in Section 1.2.

SECTION 8: Exposure Controls!personal protection ;

I
8.1. Control parameters
Ingredient comments No exposure limits known for ingredient(s).

8.2. Exposure controls


Appropriate engineering Not relevant.
controls

3/6
Revision date: 1810612015 Revision: 1

Stokolan® intensive repair

Eyelface protection Not relevant. C


Hygiene measures Not relevant.
Respiratory protection No specific recommendations.

[SECTION 9 Physical and Chemical Propecties

9.1. Information on basic physical and chemical properties


Appearance Liquid

9.2. Other information


[SECTION 10: StabilIty and reactivity

10.1. Reactivity
Reactivity There are no known reactivity hazards associated with this product.

10.2. Chemical stability


Stability Stable at normal ambient temperatures.

10.3. Possibility of hazardous reactions


Possibility of hazardous None known.
reactions

10.4. Conditions to avoid


Conditions to avoid There are no known conditions that are likely to result in a hazardous situation.

10.5. Incompatible materials


Materials to avoid No specific material or group of materials is likely to react with the product to produce a
hazardous situation.
C
10.6. Hazardous decomposition products
Hazardous decomposition Does not decompose when used and stored as recommended.
products

[SECTION 11 ToxicologIcal Information

11.1. Information on toxicological effects

Inhalation No specific health hazards known.

Ingestion May cause discomfort if swallowed.

Skin contact Skin irritation should not occur when used as recommended.

Eye contact May cause temporary eye irritation.

SECTiON 12: Ecological Information

Ecotoxicity Not regarded as dangerous for the environment.

12.1. Toxicity
12.2. Persistence and degradability
Persistence and degradability The surfactant(s) contained in this product complies(comply) with the biodegradability criteria
as laid down in Regulation (EC) No. 648/2004 on detergents. Data to support this assertion
are held at the disposal of the competent authorities of the Member States and will be made
available to them at their direct request, or at the request of a detergent manufacturer. C
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Stokolan® intensive repair

12.3. Bioaccumulative potential


Bioaccumulative potential No data available on bioaccumulation.

12.4. Mobility in soil


Mobility The product is soluble in water.

12.5. Results of PBT and vPvB assessment


Results of PBT and vPvB This product does not contain any substances classified as PBT or vPvB.
assessment

12.6. Other adverse effects


Other adverse effects None known.

SECTION 13 Disposal considerations

13.1. Waste treatment methods


General information When handling waste, the safety precautions applying to handling of the product should be
considered.

Disposal methods Dispose of waste to licensed waste disposal site in accordance with the requirements of the
local Waste Disposal Authority.

[ SECTION 14: Transport information


Road transport notes Not classified.

Rail transport notes Not classified.

Sea transport notes Not classified.

Air transport notes Not classified.

14.1. UN number
Not applicable.

14.2. UN proper shipping name


Not applicable.

14.3. Transport hazard class(es)


Not applicable.

14.4. Packing group


Not applicable.

14.5. Environmental hazards


Environmentally hazardous substance/marine pollutant
No.

14.6. Special precautions for user


Not applicable.

14.7. Transport in bulk according to Annex II of MARPOL73I78 and the IBC Code
Transport in bulk according to Not applicable.
Annex II of MARPOL 73178
and the IBC Code

5/6
Revision date: 18/06/2015 Revision: I

Stokolan® intensive repair

SECTION 15: Regulatory Infomiation

15.1. Safety, health and environmental regulationsllegislation specific for the substance or mixture
EU legislation This is a cosmetic product regulated by Regulation EC no 1223/2009 (as amended) and is
thus exempt from the Safety Data Sheet requirements of Regulation EC no 453/2010. It is
also exempt from exempt from the classification and labelling rules of the Classification,
Labelling and Packaging Regulation (EC) No 127212008.

Water hazard classification WGK 1

15.2. Chemical safety assessment


No chemical safety assessment has been carried out.

SECTiON 16: Other information

Revision comments Revision of information NOTE: Lines within the margin indicate significant changes from the
previous revision.

Revision date 18/06/2015

Revision 1

SOS number 21025

This information relates only to the specific material designated and may not be valid for such material used in combination
with any other materials or in any process. Such information is, to the best of the company’s knowledge and belief, accurate
and reliable as of the date indicated. However, no warranty guarantee or representation is made to its accuracy, reliability or
completeness. It is the user’s responsibility to satisfy himself as to the suitability of such information for his own particular use.

6/6
Material Safety Data Sheet

Revision Number: 005.3 Issue date: 03/17/2016

1. PRODUCT AND COMPANY IDENTIFICATION


Product name: TEROSON SI 9160 CL known as IDH number: 475372
SILATECH® SILICONE SEALANT IND
Product type: Silicone Item number: 32389
Region: Canada
Company address: Contact information:
Henkel Corporation Telephone: 905.814.6511
2515 Meadowpine Boulevard MEDICAL EMERGENCY Phone: Poison Control Center
Mississauga, Ontario L5N 6C3 1-877-671-4608 (toll free) or 1-303-592-1711
TRANSPORT EMERGENCY Phone: CHEMTREC
1-800-424-9300 (toll free) or 1-703-527-3887
Internet: www.henkelna.com

2. HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
Physical state: Paste WHMIS hazard class: D.2.B
Color: Translucent
Odor: Acetic acid
WARNING: PROLONGED OR REPEATED CONTACT WITH UNCURED SEALANT MAY
CAUSE EYE, SKIN AND RESPIRATORY TRACT IRRITATION.
REPEATED OR PROLONGED CONTACT MAY CAUSE ALLERGIC SKIN
REACTION.

Relevant routes of exposure: Skin, Inhalation, Eyes

Potential Health Effects

Inhalation: Acetic acid produced during cure may irritate eyes, nose and throat. When heated to
temperatures exceeding 300° F (150° C) in the presence of air, silicones may form
formaldehyde vapors. Formaldehyde is a potential cancer hazard and a known skin and
respiratory sensitizer. Vapors irritate the eyes, nose and throat. Safe handling conditions may
be maintained by keeping formaldehyde vapor concentrations below the OSHA permissible
limit.
Skin contact: Prolonged or repeated contact with uncured sealant may cause skin irritation.
Eye contact: Vapors may irritate eyes. Contact with eyes will cause irritation.
Ingestion: Not expected under normal conditions of use. Not expected to be harmful by ingestion.

Existing conditions aggravated by Eye, skin, and respiratory disorders.


exposure:

This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR
1910.1200).

See Section 11 for additional toxicological information.

3. COMPOSITION / INFORMATION ON INGREDIENTS


Hazardous components CAS NUMBER %
Silicone Resin Proprietary 60 - 100
Distillates (petroleum), hydrotreated middle 64742-46-7 10 - 30
Silicon dioxide 7631-86-9 10 - 30
Triacetoxyethylsilane 17689-77-9 1-5
Methylsilanetriyl triacetate 4253-34-3 1-5

IDH number: 475372 Product name: TEROSON SI 9160 CL known as SILATECH® SILICONE SEALANT IND

Page 1 of 5
Acetic acid 64-19-7 1-5

Exposure to moisture during cure will release 1-5% acetic acid.

4. FIRST AID MEASURES


Inhalation: Move to fresh air. If breathing is difficult, give oxygen. If not breathing, give
artificial respiration. If symptoms develop and persist, get medical attention.

Skin contact: Wipe off paste with paper towel or cloth. Wash with soap and water. If
symptoms develop and persist, get medical attention.

Eye contact: Rinse thoroughly with plenty of water, also under the eyelids. If eye irritation
persists, consult a specialist.

Ingestion: Do not induce vomiting. If a person feels unwell or symptoms of skin irritation
appear, consult a physician.

5. FIRE FIGHTING MEASURES


Flash point: > 93 °C (> 199.4 °F)

Autoignition temperature: Not available.

Flammable/Explosive limits - lower: 4 % Upper/lower explosion limit

Flammable/Explosive limits - upper: 19.9 % Upper/lower explosion limit

Extinguishing media: Foam, dry chemical or carbon dioxide.

Special firefighting procedures: None

Unusual fire or explosion hazards: None

Hazardous combustion products: Formaldehyde. Silica mist. Acrid smoke and fumes.

6. ACCIDENTAL RELEASE MEASURES


Use personal protection recommended in Section 8, isolate the hazard area and deny entry to unnecessary and unprotected
personnel.

Environmental precautions: Do not allow product to enter sewer or waterways.

Clean-up methods: Scrape up as much material as possible. Spilled material will solidify. Store in
a partly filled, closed container until disposal. Maintain good ventilation for
large spills.

7. HANDLING AND STORAGE


Handling: Avoid contact with eyes, skin and clothing. Do not handle contact lenses until
all sealant has been removed from hands. Residual sealant may transfer to
lenses and cause eye irritation.

Storage: Store in a dry area below 90° F. Keep container closed.

For information on product shelf life contact Henkel Canada Customer Service at 800-263-5043.

8. EXPOSURE CONTROLS / PERSONAL PROTECTION


Employers should complete an assessment of all workplaces to determine the need for, and selection of, proper exposure
controls and protective equipment for each task performed.

IDH number: 475372 Product name: TEROSON SI 9160 CL known as SILATECH® SILICONE SEALANT IND
Page 2 of 5
Hazardous components ACGIH TLV OSHA PEL AIHA WEEL OTHER
Silicone Resin None None None None
5 mg/m3 TWA
Distillates (petroleum), hydrotreated middle 5 mg/m3 PEL Mist. None None
Inhalable fraction.
20 MPPCF TWA 3 mg/m3 TWA
Silicon dioxide 6 mg/m3 TWA None
0.8 mg/m3 TWA Respirable fraction.
Triacetoxyethylsilane None None None None
Methylsilanetriyl triacetate None None None None
15 ppm STEL 10 ppm (25
Acetic acid None None
10 ppm TWA mg/m3) PEL

Engineering controls: Ensure adequate ventilation, especially in confined areas. Use local ventilation
if general ventilation is insufficient to maintain vapor concentration below
established exposure limits.

Respiratory protection: Use NIOSH approved respirator if there is potential to exceed exposure
limit(s).

Eye/face protection: Safety goggles or safety glasses with side shields. Full face protection should
be used if the potential for splashing or spraying of product exists.

Skin protection: Chemical resistant, impermeable gloves. Nitrile gloves. Butyl rubber gloves.

9. PHYSICAL AND CHEMICAL PROPERTIES


Physical state: Paste
Color: Translucent
Odor: Acetic acid
Odor threshold: Not available.
pH: Not available.
Vapor pressure: < 10 mm hg (20 °C (68°F))
Boiling point/range: Not available.
Melting point/ range: Not available.
Specific gravity: 1.01 at 20 °C (68°F)
Vapor density: Heavier than air.
Flash point: > 93 °C (> 199.4 °F)
Flammable/Explosive limits - lower: 4%
Flammable/Explosive limits - upper: 19.9 %
Autoignition temperature: Not available.
Evaporation rate: Not available.
Solubility in water: Not determined
Partition coefficient (n-octanol/water): Not available.
VOC content: 3.0 %; 30 g/l
Viscosity: Not available.

10. STABILITY AND REACTIVITY


Stability: Stable

Sensitivity to Mechanical Impact: Not available.

Sensitivity to static discharge: Not available.


Hazardous reactions: Will not occur.

Hazardous decomposition Acetic acid is liberated slowly upon contact with moisture. Formaldehyde.
products:

Incompatible materials: Acids. Bases. Oxidizing agents. Water.

Conditions to avoid: Prolonged heating at temperatures above 150 °C. Exposure to moisture.

IDH number: 475372 Product name: TEROSON SI 9160 CL known as SILATECH® SILICONE SEALANT IND
Page 3 of 5
11. TOXICOLOGICAL INFORMATION

Toxicologically synergistic products: Not available.

Refer to the following for Irritancy of Product, Sensitization to Product, Carcinogenicity, Reproductive Toxicity, Teratogenicity,
and Mutagenicity.

OSHA Carcinogen
Hazardous components NTP Carcinogen IARC Carcinogen (Specifically ACGIH Carcinogen
Regulated)
Silicone Resin No No No No
Distillates (petroleum), hydrotreated
No No No Group A4
middle
Silicon dioxide No No No No
Triacetoxyethylsilane No No No No
Methylsilanetriyl triacetate No No No No
Acetic acid No No No No

Hazardous components LD50s and LC50s Health Effects/Target Organs


Silicone Resin None No Target Organs
Distillates (petroleum), hydrotreated
None Irritant
middle
Silicon dioxide Oral LD50 (RAT) = > 22,500 mg/kg Nuisance dust
Triacetoxyethylsilane None No Target Organs
Methylsilanetriyl triacetate None Irritant, Allergen
Oral LD50 (RABBIT) = 1,200 mg/kg
Oral LD50 (RAT) = 3.53 g/kg
Allergen, Corrosive, Eyes, Gastrointestinal,
Acetic acid Oral LD50 (RAT) = 3.31 g/kg
Immune system, Irritant, Kidney
Dermal LD50 (RABBIT) = 1,060 mg/kg
Inhalation LC50 (RAT, 4 h) = 11.4 mg/l

12. ECOLOGICAL INFORMATION


Ecological information: Not available.

13. DISPOSAL CONSIDERATIONS


Information provided is for unused product only.

Recommended cleaning agents: Follow all local, state, federal and provincial regulations for disposal. Cured
rubber can be incinerated or landfilled following EPA and local regulations.

Hazardous waste number: Not available.

14. TRANSPORT INFORMATION

Canada Transportation of Dangerous Goods - Ground


Proper shipping name: Not regulated
Hazard class or division: None
Identification number: None
Packing group: None

International Air Transportation (ICAO/IATA)


Proper shipping name: Not regulated
Hazard class or division: None
Identification number: None
Packing group: None

IDH number: 475372 Product name: TEROSON SI 9160 CL known as SILATECH® SILICONE SEALANT IND
Page 4 of 5
Water Transportation (IMO/IMDG)
Proper shipping name: Not regulated
Hazard class or division: None
Identification number: None
Packing group: None

15. REGULATORY INFORMATION


Canada Regulatory Information

CEPA DSL/NDSL Status: All components are listed on or are exempt from listing on the Canadian Domestic
Substances List.

United States Regulatory Information

TSCA 8 (b) Inventory Status: All components are listed or are exempt from listing on the Toxic Substances Control Act
Inventory.

16. OTHER INFORMATION


This material safety data sheet contains changes from the previous version in sections: Reviewed MSDS. Reissued with
new date.

This product has been classified in accordance with the hazard criteria of the Controlled Products Regulation (CPR), and
the MSDS contains all the information required by the CPR.

Prepared by: Timothy Pratt, Regulatory Affairs Specialist

DISCLAIMER: The data contained herein are furnished for information only and are believed to be reliable. However, Henkel Corporation and
its affiliates (“Henkel”) does not assume responsibility for any results obtained by persons over whose methods Henkel has no control. It is the
user’s responsibility to determine the suitability of Henkel’s products or any production methods mentioned herein for a particular purpose, and
to adopt such precautions as may be advisable for the protection of property and persons against any hazards that may be involved in the
handling and use of any Henkel’s products. In light of the foregoing, Henkel specifically disclaims all warranties, express or implied, including
warranties of merchantability and fitness for a particular purpose, arising from sale or use of Henkel’s products. Henkel further disclaims any
liability for consequential or incidental damages of any kind, including lost profits.

IDH number: 475372 Product name: TEROSON SI 9160 CL known as SILATECH® SILICONE SEALANT IND
Page 5 of 5
Safety Data Sheet

SECTION 1 PRODUCT AND COMPANY IDENTIFICATION

Way Oil Vistac 68, 220


Product Use: Industrial Oil
Product Number(s): 232511, 232512
Company Identification
Chevron Products Company
a division of Chevron U.S.A. Inc.
6001 Bollinger Canyon Rd.
San Ramon, CA 94583
United States of America
www.chevronlubricants.com

Transportation Emergency Response


CHEMTREC: (800) 424-9300 or (703) 527-3887
Health Emergency
Chevron Emergency Information Center: Located in the USA. International collect calls accepted. (800)
231-0623 or (510) 231-0623
Product Information
email : [email protected]
Product Information: 1 (800) 582-3835, [email protected]

SECTION 2 HAZARDS IDENTIFICATION

CLASSIFICATION: Not classified as hazardous according to 29 CFR 1910.1200 (2012).

SECTION 3 COMPOSITION/ INFORMATION ON INGREDIENTS

COMPONENTS CAS NUMBER AMOUNT


Highly refined mineral oil (C15 - C50) Mixture 70 - 99 %wt/wt
Distillates, hydrotreated middle 64742-46-7 70 - 99 %wt/wt

SECTION 4 FIRST AID MEASURES

Description of first aid measures


Eye: No specific first aid measures are required. As a precaution, remove contact lenses, if worn, and
flush eyes with water.

_____________________________________________________________________

Revision Number: 5 1 of 7 Way Oil Vistac 68, 220


Revision Date: JUNE 03, 2014 SDS : 7459
Skin: No specific first aid measures are required. As a precaution, remove clothing and shoes if
contaminated. To remove the material from skin, use soap and water. Discard contaminated clothing and
shoes or thoroughly clean before reuse.
Ingestion: No specific first aid measures are required. Do not induce vomiting. As a precaution, get
medical advice.
Inhalation: No specific first aid measures are required. If exposed to excessive levels of material in the air,
move the exposed person to fresh air. Get medical attention if coughing or respiratory discomfort occurs.

Most important symptoms and effects, both acute and delayed


IMMEDIATE SYMPTOMS AND HEALTH EFFECTS
Eye: Not expected to cause prolonged or significant eye irritation.
Skin: Contact with the skin is not expected to cause prolonged or significant irritation. Contact with the skin
is not expected to cause an allergic skin response. Not expected to be harmful to internal organs if
absorbed through the skin.
Ingestion: Not expected to be harmful if swallowed.
Inhalation: Not expected to be harmful if inhaled. Contains a petroleum-based mineral oil. May cause
respiratory irritation or other pulmonary effects following prolonged or repeated inhalation of oil mist at
airborne levels above the recommended mineral oil mist exposure limit. Symptoms of respiratory irritation
may include coughing and difficulty breathing.

DELAYED OR OTHER SYMPTOMS AND HEALTH EFFECTS: Not classified.

Indication of any immediate medical attention and special treatment needed


Not applicable.

SECTION 5 FIRE FIGHTING MEASURES

EXTINGUISHING MEDIA: Use water fog, foam, dry chemical or carbon dioxide (CO2) to extinguish flames.

PROTECTION OF FIRE FIGHTERS:


Fire Fighting Instructions: This material will burn although it is not easily ignited. See Section 7 for proper
handling and storage. For fires involving this material, do not enter any enclosed or confined fire space
without proper protective equipment, including self-contained breathing apparatus.
Combustion Products: Highly dependent on combustion conditions. A complex mixture of airborne
solids, liquids, and gases including carbon monoxide, carbon dioxide, and unidentified organic compounds
will be evolved when this material undergoes combustion.

SECTION 6 ACCIDENTAL RELEASE MEASURES

Protective Measures: Eliminate all sources of ignition in vicinity of spilled material.


Spill Management: Stop the source of the release if you can do it without risk. Contain release to prevent
further contamination of soil, surface water or groundwater. Clean up spill as soon as possible, observing
precautions in Exposure Controls/Personal Protection. Use appropriate techniques such as applying
non-combustible absorbent materials or pumping. Where feasible and appropriate, remove contaminated
soil. Place contaminated materials in disposable containers and dispose of in a manner consistent with
applicable regulations.
Reporting: Report spills to local authorities as appropriate or required.

SECTION 7 HANDLING AND STORAGE

Precautionary Measures: Do not get in eyes, on skin, or on clothing. Wash thoroughly after handling.
General Handling Information: Avoid contaminating soil or releasing this material into sewage and
drainage systems and bodies of water.
Static Hazard: Electrostatic charge may accumulate and create a hazardous condition when handling this
_____________________________________________________________________

Revision Number: 5 2 of 7 Way Oil Vistac 68, 220


Revision Date: JUNE 03, 2014 SDS : 7459
material. To minimize this hazard, bonding and grounding may be necessary but may not, by themselves,
be sufficient. Review all operations which have the potential of generating and accumulating an electrostatic
charge and/or a flammable atmosphere (including tank and container filling, splash filling, tank cleaning,
sampling, gauging, switch loading, filtering, mixing, agitation, and vacuum truck operations) and use
appropriate mitigating procedures. For more information, refer to OSHA Standard 29 CFR 1910.106,
'Flammable and Combustible Liquids', National Fire Protection Association (NFPA 77, 'Recommended
Practice on Static Electricity', and/or the American Petroleum Institute (API) Recommended Practice 2003,
'Protection Against Ignitions Arising Out of Static, Lightning, and Stray Currents'.
Container Warnings: Container is not designed to contain pressure. Do not use pressure to empty
container or it may rupture with explosive force. Empty containers retain product residue (solid, liquid,
and/or vapor) and can be dangerous. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose
such containers to heat, flame, sparks, static electricity, or other sources of ignition. They may explode and
cause injury or death. Empty containers should be completely drained, properly closed, and promptly
returned to a drum reconditioner or disposed of properly.

SECTION 8 EXPOSURE CONTROLS/PERSONAL PROTECTION

GENERAL CONSIDERATIONS:
Consider the potential hazards of this material (see Section 3), applicable exposure limits, job activities, and
other substances in the work place when designing engineering controls and selecting personal protective
equipment. If engineering controls or work practices are not adequate to prevent exposure to harmful
levels of this material, the personal protective equipment listed below is recommended. The user should
read and understand all instructions and limitations supplied with the equipment since protection is usually
provided for a limited time or under certain circumstances.

ENGINEERING CONTROLS:
Use in a well-ventilated area.

PERSONAL PROTECTIVE EQUIPMENT


Eye/Face Protection: No special eye protection is normally required. Where splashing is possible, wear
safety glasses with side shields as a good safety practice.
Skin Protection: No special protective clothing is normally required. Where splashing is possible, select
protective clothing depending on operations conducted, physical requirements and other substances in the
workplace. Suggested materials for protective gloves include: 4H (PE/EVAL), Nitrile Rubber, Silver Shield,
Viton.
Respiratory Protection: No respiratory protection is normally required.
If user operations generate an oil mist, determine if airborne concentrations are below the occupational
exposure limit for mineral oil mist. If not, wear an approved respirator that provides adequate protection
from the measured concentrations of this material. For air-purifying respirators use a particulate cartridge.
Use a positive pressure air-supplying respirator in circumstances where air-purifying respirators may not
provide adequate protection.

Occupational Exposure Limits:

Component Agency TWA STEL Ceiling Notation


Highly refined mineral oil (C15 - ACGIH 5 mg/m3 10 mg/m3 -- --
C50)
Highly refined mineral oil (C15 - OSHA Z-1 5 mg/m3 -- -- --
C50)
Consult local authorities for appropriate values.

SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES

Attention: the data below are typical values and do not constitute a specification.

_____________________________________________________________________

Revision Number: 5 3 of 7 Way Oil Vistac 68, 220


Revision Date: JUNE 03, 2014 SDS : 7459
Color: Brown
Physical State: Liquid
Odor: Petroleum odor
Odor Threshold: No data available
pH: Not Applicable
Vapor Pressure: <0.01 mmHg @ 37.8 °C (100 °F)
Vapor Density (Air = 1): >1
Initial Boiling Point: 315°C (599°F)
Solubility: Soluble in hydrocarbons; insoluble in water
Freezing Point: Not Applicable
Specific Gravity: 0.9117 @ 15.6°C (60.1°F) / 15.6°C (60.1°F) Minimum
Density: Not Applicable
Viscosity: 61.2 mm2/s @ 40°C (104°F) Minimum
Evaporation Rate: No data available
Decomposition temperature: No Data Available
Octanol/Water Partition Coefficient: No data available

FLAMMABLE PROPERTIES:
Flammability (solid, gas): No Data Available
Flashpoint: (Cleveland Open Cup) 170 °C (338 °F) (Min)
Autoignition: No data available
Flammability (Explosive) Limits (% by volume in air): Lower: Not Applicable Upper: Not Applicable

SECTION 10 STABILITY AND REACTIVITY

Reactivity: This material is not expected to react.


Chemical Stability: This material is considered stable under normal ambient and anticipated storage and
handling conditions of temperature and pressure.
Incompatibility With Other Materials: May react with strong acids or strong oxidizing agents, such as
chlorates, nitrates, peroxides, etc.
Hazardous Decomposition Products: None known (None expected)
Hazardous Polymerization: Hazardous polymerization will not occur.

SECTION 11 TOXICOLOGICAL INFORMATION

Information on toxicological effects


Serious Eye Damage/Irritation: The eye irritation hazard is based on evaluation of data for product
components.
Skin Corrosion/Irritation: The skin irritation hazard is based on evaluation of data for product
components.
Skin Sensitization: The skin sensitization hazard is based on evaluation of data for product components.
Acute Dermal Toxicity: The acute dermal toxicity hazard is based on evaluation of data for product
components.
Acute Oral Toxicity: The acute oral toxicity hazard is based on evaluation of data for product components.

Acute Inhalation Toxicity: The acute inhalation toxicity hazard is based on evaluation of data for product
components.

Acute Toxicity Estimate: Not Determined

_____________________________________________________________________

Revision Number: 5 4 of 7 Way Oil Vistac 68, 220


Revision Date: JUNE 03, 2014 SDS : 7459
Germ Cell Mutagenicity: The hazard evaluation is based on data for components or a similar material.
Carcinogenicity: The hazard evaluation is based on data for components or a similar material.
Reproductive Toxicity: The hazard evaluation is based on data for components or a similar material.

Specific Target Organ Toxicity - Single Exposure: The hazard evaluation is based on data for
components or a similar material.
Specific Target Organ Toxicity - Repeated Exposure: The hazard evaluation is based on data for
components or a similar material.

ADDITIONAL TOXICOLOGY INFORMATION:


This product contains petroleum base oils which may be refined by various processes including severe
solvent extraction, severe hydrocracking, or severe hydrotreating. None of the oils requires a cancer
warning under the OSHA Hazard Communication Standard (29 CFR 1910.1200). These oils have not been
listed in the National Toxicology Program (NTP) Annual Report nor have they been classified by the
International Agency for Research on Cancer (IARC) as; carcinogenic to humans (Group 1), probably
carcinogenic to humans (Group 2A), or possibly carcinogenic to humans (Group 2B). These oils have not
been classified by the American Conference of Governmental Industrial Hygienists (ACGIH) as: confirmed
human carcinogen (A1), suspected human carcinogen (A2), or confirmed animal carcinogen with unknown
relevance to humans (A3).

SECTION 12 ECOLOGICAL INFORMATION

ECOTOXICITY
This material is not expected to be harmful to aquatic organisms. The ecotoxicity hazard is based on an
evaluation of data for the components or a similar material. The product has not been tested. The
statement has been derived from the properties of the individual components.

MOBILITY
No data available.

PERSISTENCE AND DEGRADABILITY


This material is not expected to be readily biodegradable. The biodegradability of this material is based on
an evaluation of data for the components or a similar material.The product has not been tested. The
statement has been derived from the properties of the individual components.

POTENTIAL TO BIOACCUMULATE
Bioconcentration Factor: No data available.
Octanol/Water Partition Coefficient: No data available

SECTION 13 DISPOSAL CONSIDERATIONS

Use material for its intended purpose or recycle if possible. Oil collection services are available for used oil
recycling or disposal. Place contaminated materials in containers and dispose of in a manner consistent
with applicable regulations. Contact your sales representative or local environmental or health authorities
for approved disposal or recycling methods.

SECTION 14 TRANSPORT INFORMATION

The description shown may not apply to all shipping situations. Consult 49CFR, or appropriate Dangerous
Goods Regulations, for additional description requirements (e.g., technical name) and mode-specific or
quantity-specific shipping requirements.

_____________________________________________________________________

Revision Number: 5 5 of 7 Way Oil Vistac 68, 220


Revision Date: JUNE 03, 2014 SDS : 7459
DOT Shipping Description: NOT REGULATED AS A HAZARDOUS MATERIAL UNDER 49 CFR

IMO/IMDG Shipping Description: NOT REGULATED AS DANGEROUS GOODS FOR TRANSPORT


UNDER THE IMDG CODE

ICAO/IATA Shipping Description: NOT REGULATED AS DANGEROUS GOODS FOR TRANSPORT


UNDER ICAO

Transport in bulk according to Annex II of MARPOL 73/78 and the IBC code:
Not applicable

SECTION 15 REGULATORY INFORMATION

EPCRA 311/312 CATEGORIES: 1. Immediate (Acute) Health Effects: NO


2. Delayed (Chronic) Health Effects: NO
3. Fire Hazard: NO
4. Sudden Release of Pressure Hazard: NO
5. Reactivity Hazard: NO

REGULATORY LISTS SEARCHED:


01-1=IARC Group 1 03=EPCRA 313
01-2A=IARC Group 2A 04=CA Proposition 65
01-2B=IARC Group 2B 05=MA RTK
02=NTP Carcinogen 06=NJ RTK
07=PA RTK

No components of this material were found on the regulatory lists above.

CHEMICAL INVENTORIES:
All components comply with the following chemical inventory requirements: AICS (Australia), DSL
(Canada), IECSC (China), KECI (Korea), PICCS (Philippines), TSCA (United States).

One or more components does not comply with the following chemical inventory requirements: ENCS
(Japan).

NEW JERSEY RTK CLASSIFICATION:


Under the New Jersey Right-to-Know Act L. 1983 Chapter 315 N.J.S.A. 34:5A-1 et. seq., the product is to
be identified as follows: PETROLEUM OIL (Lubricating oil)

SECTION 16 OTHER INFORMATION

NFPA RATINGS: Health: 0 Flammability: 1 Reactivity: 0

HMIS RATINGS: Health: 1 Flammability: 1 Reactivity: 0


(0-Least, 1-Slight, 2-Moderate, 3-High, 4-Extreme, PPE:- Personal Protection Equipment Index
recommendation, *- Chronic Effect Indicator). These values are obtained using the guidelines or published
evaluations prepared by the National Fire Protection Association (NFPA) or the National Paint and Coating
Association (for HMIS ratings).

LABEL RECOMMENDATION:
Label Category : INDUSTRIAL OIL 1 - IND1

_____________________________________________________________________

Revision Number: 5 6 of 7 Way Oil Vistac 68, 220


Revision Date: JUNE 03, 2014 SDS : 7459
REVISION STATEMENT: This revision updates the following sections of this Safety Data Sheet: 1-16
Revision Date: JUNE 03, 2014

ABBREVIATIONS THAT MAY HAVE BEEN USED IN THIS DOCUMENT:


TLV - Threshold Limit Value TWA - Time Weighted Average
STEL - Short-term Exposure Limit PEL - Permissible Exposure Limit
GHS - Globally Harmonized System CAS - Chemical Abstract Service Number
ACGIH - American Conference of Governmental IMO/IMDG - International Maritime Dangerous Goods
Industrial Hygienists Code
API - American Petroleum Institute SDS - Safety Data Sheet
HMIS - Hazardous Materials Information System NFPA - National Fire Protection Association (USA)
DOT - Department of Transportation (USA) NTP - National Toxicology Program (USA)
IARC - International Agency for Research on OSHA - Occupational Safety and Health Administration
Cancer
NCEL - New Chemical Exposure Limit EPA - Environmental Protection Agency
SCBA - Self-Contained Breathing Apparatus

Prepared according to the 29 CFR 1910.1200 (2012) by Chevron Energy Technology Company, 6001
Bollinger Canyon Road San Ramon, CA 94583.

The above information is based on the data of which we are aware and is believed to be correct
as of the date hereof. Since this information may be applied under conditions beyond our
control and with which we may be unfamiliar and since data made available subsequent to the
date hereof may suggest modifications of the information, we do not assume any responsibility
for the results of its use. This information is furnished upon condition that the person receiving
it shall make his own determination of the suitability of the material for his particular purpose.

_____________________________________________________________________

Revision Number: 5 7 of 7 Way Oil Vistac 68, 220


Revision Date: JUNE 03, 2014 SDS : 7459
Safety Data Sheet

according to Hazard Communication Standard; 29 CFR 1910.1200 

WINDEX® CLENER ORIGINAL WITH AMMONIA-D®


Version 1.2 Print Date 03/24/2016

Revision Date 03/14/2016 SDS Number 350000014153

1. PRODUCT AND COMPANY IDENTIFICATION

Product information
Product name : WINDEX® CLENER ORIGINAL WITH AMMONIA-D®

Recommended use : Hard Surface Cleaner

Manufacturer, importer, : S.C. Johnson & Son, Inc.


supplier 1525 Howe Street
Racine WI 53403-2236

Telephone : +18005585252
Emergency telephone : 24 Hour Medical Emergency Phone: (866)231-5406
number 24 Hour International Emergency Phone: (703)527-3887
24 Hour Transport Emergency Phone: (800)424-9300

2. HAZARDS IDENTIFICATION
Classification of the substance or mixture

Globally Harmonized System (GHS) Classification


This product does not meet the criteria for classification in any hazard class according to regulation
OSHA 29 CFR 1910.1200.

Labelling

Precautionary statements
Other hazards : None identified

3. COMPOSITION/INFORMATION ON INGREDIENTS

This product does not contain hazardous chemicals at or above a reportable level as defined by OSHA
29 CFR 1910.1200

For additional information on product ingredients, see www.whatsinsidescjohnson.com.

4. FIRST AID MEASURES

Eye contact : No special requirements


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Safety Data Sheet

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WINDEX® CLENER ORIGINAL WITH AMMONIA-D®


Version 1.2 Print Date 03/24/2016

Revision Date 03/14/2016 SDS Number 350000014153

Skin contact : No special requirements

Inhalation : No special requirements.

Ingestion : No special requirements

5. FIREFIGHTING MEASURES

Suitable extinguishing : Use water spray, alcohol-resistant foam, dry chemical or


media carbon dioxide.

Specific hazards during : Container may melt and leak in heat of fire.
firefighting

Further information : Fight fire with normal precautions from a reasonable distance.
Standard procedure for chemical fires. Wear full protective
clothing and positive pressure self-contained breathing
apparatus.

6. ACCIDENTAL RELEASE MEASURES

Personal precautions : Wash thoroughly after handling.

Environmental : Outside of normal use, avoid release to the environment.


precautions

Methods and materials : Dike large spills.


for containment and Clean residue from spill site.
cleaning up

7. HANDLING AND STORAGE

Handling
Precautions for safe : Avoid contact with skin, eyes and clothing.
handling For personal protection see section 8.
KEEP OUT OF REACH OF CHILDREN AND PETS.

Advice on protection : Normal measures for preventive fire protection.

2/9
Safety Data Sheet

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WINDEX® CLENER ORIGINAL WITH AMMONIA-D®


Version 1.2 Print Date 03/24/2016

Revision Date 03/14/2016 SDS Number 350000014153

against fire and explosion

Storage
Requirements for storage : Keep container closed when not in use.
areas and containers
Other data : Stable under normal conditions.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Occupational Exposure Limits


ACGIH or OSHA exposure limits have not been established for this product or reportable ingredients
unless noted in the table above.

Personal protective equipment


Respiratory protection : No special requirements.

Hand protection : No special requirements.

Eye protection : No special requirements.

Skin and body protection : No special requirements.

Hygiene measures : Handle in accordance with good industrial hygiene and safety
practice. Wash thoroughly after handling.

9. PHYSICAL AND CHEMICAL PROPERTIES

Form : liquid

Color : blue

Odor : floral

Odour Threshold : Test not applicable for this product type

pH : 10.7
at (25 C)

3/9
Safety Data Sheet

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WINDEX® CLENER ORIGINAL WITH AMMONIA-D®


Version 1.2 Print Date 03/24/2016

Revision Date 03/14/2016 SDS Number 350000014153

Melting point/freezing point : 0C

Initial boiling point and : 100 C


boiling range

Flash point : does not flash

Evaporation rate : Test not applicable for this product type

Flammability (solid, gas) : Does not sustain combustion.

Upper/lower flammability or : Test not applicable for this product type


explosive limits

Vapour pressure : Calculated31.7 hPa

Vapour density : Test not applicable for this product type

Relative density : 1.00 g/cm3 at 25 C

Solubility(ies) : soluble

Partition coefficient: n- : Test not applicable for this product type


octanol/water

Auto-ignition temperature : Test not applicable for this product type

Decomposition temperature : Heating can release hazardous gases.

Viscosity, dynamic : similar to water

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Safety Data Sheet

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WINDEX® CLENER ORIGINAL WITH AMMONIA-D®


Version 1.2 Print Date 03/24/2016

Revision Date 03/14/2016 SDS Number 350000014153

Viscosity, kinematic : similar to water

Oxidizing properties : Test not applicable for this product type

Volatile Organic : 0.2 % - additional exemptions may apply


Compounds *as defined by US Federal and State Consumer Product
Total VOC (wt. %)* Regulations

Other information : None identified :

10. STABILITY AND REACTIVITY

Possibility of hazardous : If accidental mixing occurs and toxic gas is formed, exit area
reactions immediately. Do not return until well ventilated.

Conditions to avoid : Direct sources of heat.

Incompatible materials : Do not mix with bleach or any other household cleaners.
Strong bases

Hazardous decomposition : Thermal decomposition can lead to release of irritating gases


products and vapours.

11. TOXICOLOGICAL INFORMATION

Emergency Overview : This product does not meet the criteria for classification in any
hazard class according to regulation OSHA 29 CFR
1910.1200.

Acute oral toxicity : LD50 > 5000 mg/kg

Acute inhalation toxicity : LC50 > 10 mg/L

Acute dermal toxicity : LD50 > 5000 mg/kg


5/9
Safety Data Sheet

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WINDEX® CLENER ORIGINAL WITH AMMONIA-D®


Version 1.2 Print Date 03/24/2016

Revision Date 03/14/2016 SDS Number 350000014153

GHS Properties Classification Routes of entry


Acute toxicity No classification proposed Oral

Acute toxicity No classification proposed Dermal

Acute toxicity No classification proposed Inhalation - Dust and Mist

Acute toxicity No classification proposed Inhalation - Vapour

Acute toxicity No classification proposed Inhalation - Gas

Skin corrosion/irritation No classification proposed -

Serious eye No classification proposed -


damage/eye irritation
Skin sensitisation No classification proposed -

Respiratory No classification proposed -


sensitisation
Germ cell mutagenicity No classification proposed -

Carcinogenicity No classification proposed -

Reproductive toxicity No classification proposed -

Specific target organ No classification proposed -


toxicity - single
exposure
Specific target organ No classification proposed -
toxicity - repeated
exposure
Aspiration hazard No classification proposed -

Aggravated Medical : None known.


Condition

12. ECOLOGICAL INFORMATION

Product : The product itself has not been tested.


6/9
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WINDEX® CLENER ORIGINAL WITH AMMONIA-D®


Version 1.2 Print Date 03/24/2016

Revision Date 03/14/2016 SDS Number 350000014153

Toxicity
The ingredients in this formula have been reviewed and no adverse impact to the environment is
expected when used according to label directions.

No environmental data required.

Other adverse effects : None known.

13. DISPOSAL CONSIDERATIONS

Consumer may discard empty container in trash, or recycle


where facilities exist.

14. TRANSPORT INFORMATION

Please refer to the Bill of Lading/receiving documents for up-to-date shipping information.

Land transport
Not classified as dangerous in the meaning of transport regulations.

Sea transport
Not classified as dangerous in the meaning of transport regulations.

Air transport
Not classified as dangerous in the meaning of transport regulations.

15. REGULATORY INFORMATION

Notification status : All ingredients of this product are listed or are excluded from
listing on the U.S. Toxic Substances Control Act (TSCA)
Chemical Substance Inventory.

7/9
Safety Data Sheet

according to Hazard Communication Standard; 29 CFR 1910.1200 

WINDEX® CLENER ORIGINAL WITH AMMONIA-D®


Version 1.2 Print Date 03/24/2016

Revision Date 03/14/2016 SDS Number 350000014153

Notification status : All ingredients of this product comply with the New Substances
Notification requirements under the Canadian Environmental
Protection Act (CEPA).

California Prop. 65 : This product does not contain any chemicals known to State of
California to cause cancer, birth defects, or any other
reproductive harm.

16. OTHER INFORMATION


HMIS Ratings
Health 1

Flammability 0

Reactivity 0

NFPA Ratings
Health 1

Fire 0

Reactivity 0

Special -

This information is being provided in accordance with the Occupational Safety and Health Administration
(OSHA) regulation (29 CFR 1910.1200). The information supplied is designed for workplaces where
product use and frequency of exposure exceeds that established for the labeled consumer use.

Further information

8/9
Safety Data Sheet

according to Hazard Communication Standard; 29 CFR 1910.1200 

WINDEX® CLENER ORIGINAL WITH AMMONIA-D®


Version 1.2 Print Date 03/24/2016

Revision Date 03/14/2016 SDS Number 350000014153

This document has been prepared using data from sources considered to be technically reliable. It does
not constitute a warranty, expressed or implied, as to the accuracy of the information contained herein.
Actual conditions of use are beyond the seller's control. User is responsible to evaluate all available
information when using product for any particular use and to comply with all Federal, State, Provincial
and Local laws and regulations.

Prepared by SC Johnson Global Safety Assessment &


Regulatory Affairs (GSARA)

9/9
MATERIAL SAFETY DATA SHEET
SECTION I - PRODUCT IDENTIFICATION

Trade Names and Synonyms 2-6 Casting Alloy, 15/85 ASTM 15B, 20/80 ASTM 20 B, 25/75
ASTM 30 A B, 30/70, 34/66, 35/65, 45/55 ASTM A B, Pirellie, "E" Alloy
Chemical Names and Synonyms Leaded Solders
Chemical Family Lead Based Alloys & Solders

SECTION I I - INGREDIENTS

C.A.S. % W/W Exposure LD50


Ingredient Number Min Max Limit oral, rat
Lead 7439-92-1 50.00 93.50 0.05 mg/m3 790 mg/kg
Tin 7440-31-5 0.35 50.00 2.00 mg/m3 72 mg/kg (mouse)
Antimony 7440-36-0 0.00 2.20 0.50 mg/m3 15 mg/Kg (LDLo Man)

SECTION I I I - PHYSICAL DATA

Boiling Point ( deg C ) Pb 1740, Sb 1320 Spec Gravity 9.46 - 11


Vapour Pressure ( mm Hg ) Pb 1 mm @ 975 deg C % Volatile
Vapour Density ( Air=1 ) NP (by volume ) NP
Solubility in Water Nil Evaporation Rate
Appearance Metallic Silver Grey or Metallic Grey ( Ether = 1 ) NP
Odour None pH NP
Form Solid Melting Point ( deg C )
183 - 290

WHMIS Classification D2-A TDG Information


Shipping Name: Not Regulated
NP - Not Pertinent: UN Number: NP
U - Unknown: Class / Division: NP
Packing Group: NP

SECTION IV - FIRE AND EXPLOSION HAZARDS

Flash Point ( deg C ) and Method Flammable Limits in Air ( Vol % )


NP Upper: NP
Lower: NP
Means of Extinction: Class D - Dry Chemical, or Dry Sand

Page 1 of 3
SECTION V - HEALTH HAZARD AND FIRST AID DATA

EFFECTS: May cause headache, nausea, abdominal pains, fatigue,


Ingestion muscle/joint pain, kidney disjunction, wrist-drop.
FIRST AID: Give water or milk. If conscious, induce vomiting.
Report suspect cases to a physician for blood testing.
EFFECTS: Molten lead could splash into eye.
Eye Contact
FIRST AID: Flush with cool water for 15 minutes and seek immediate
medical aid.
EFFECTS: May cause local irritation.
Skin Contact
FIRST AID: NP

Skin Absorption NP

See "Ingestion", CNS damage (results in fatigue, tremors,


Inhalation hallucinations, convulsions, delirium), weight loss, sleep
disturbance.
Effects of Acute See " Ingestion Effects " and " Inhalation Effects ".
Exposure
Effects of Chronic Possible anemia, central nervous system and kidney
Exposure damage.

Carcinogenicity: IARC ( Yes )

Mutagenicity: No Teratogenicity: Yes Reproductive Effects: Yes

SECTION V I - REACTIVITY DATA

Stability: Stable - Yes Conditions to Avoid: NP


Incompatible Water: No Acid: No Oxidizers: Yes
Materials Corrosive: No Alkali: No Reducers: No
Other: No
Hazardous Decomposition Toxic lead oxide fumes will form at elevated temperature.
Products: Contact with sodium azide generates lead azide - a detonating compound.
Hazardous May Occur - NO Conditions to Avoid: NP
Polymerization: May not Occur - X

Page 2 of 3
SECTION V I I - PREVENTIVE MEASURES

Steps to be Taken in Case Collect in an appropriate container. ( Example:a strong cardboard box.)
Material is Released or Spilled: Wash hands and arms well after clean up is finished. Use water and
wet sweep or vacuum.
Waste Disposal Method: Return to manufacturer, scrap dealer, or secondary lead smelter.

Respiratory Protection: For prolonged exposure ( > 4 hrs/day or 20 hrs/week) Use respirator effective
against lead fumes or dust depending on particular job
Essential if particular
Local Exhaust: TWA's are exceeded. Special:
Engineering Controls

Mechanical ( General ): Other:

Protective Gloves: Cotton or other cloth glove Eye Protection: Safety glasses, goggles, face
shield if molten.

Other Protective Equipment: Heat resistant leggings and gloves if pouring molten metal.

SECTION V I I I - SPECIAL PRECAUTIONS

Precautions to be Taken in Handling and Storing: Wash hands and arms well after handling and/or
Eating or Smoking
Smoking. Adequate ventilation and respiratory protection should be provided when handling
dross from solder bath.
Special Precautions and Waste Disposal Methods: Do not dispose of into municipal garbage. Do not
dispose of into sewers or any body of water. Do not dispose of in a landfill site.

SECTION IX - PREPARATION INFORMATION

Prepared By: Health, Safety and Environmental Department

8271 rue Lafrenaie ● St. Leonard, Quebec ● H1P 2B1


(514) 327-2011 Toll Free (800) 363-7110 Fax (514) 327-7810

After-Hours Emergency Contact Number: 1 (613) 966-6666

Date: February 10, 2014

Page 3 of 3
r?.
I 3M’’ Dynatron Putty-Cote 592, 593 03/12/15

Safety Data Sheet


Copyright,20 I 5,3M Company.
All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is allowed
provided that: (l)the information is copied in full with no changes unless prior written agreement is obtained from 3M, and (2) neither
the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon.

Document Group: 24-2410-9 Version Number: 2.00


Issue Date: 03/12/15 Supercedes Date: 07/20/09

Product identifier
3MTM Dynatron Putty-Cote 592, 593

ID Number(s):

70-0080-0354-6, 70-0080-0355-3

Recommended use
Automotive, Autobody repair.

Supplier’s details

MANUFACTURER: 3M
DIVISION: Automotive Aftermarket

ADDRESS: 3M Center, St. Paul, MN 55 144-1000, USA


Telephone: 1-888-3M HELPS (1-888-364-3577)

Emergency telephone number


1-800-364-3577 or (651) 737-6501 (24 hours)

This product is a kit or a multipart product which consists of multiple, independently packaged components. A Safety Data
Sheet (SDS), Article Information Sheet (AIS), or Article Information Letter (AlL) for each of these components is included.
Please do not separate the component documents from this cover page. The document numbers for components of this
product are:

26-9510-4, 24-2371-3

DISCLAIMER: The information in this Safety Data Sheet (SDS) is believed to be correct as of the date issued. 3M MAKES NO
WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF
MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF
TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable for user’s method of
use or application. Given the variety of factors that can affect the use and application of a 3M product, some of which are uniquely
within the user’s knowledge and control, it is essential that the user evaluate the 3M product to determine whether it is fit for a
particular purpose and suitable for user’s method of use or application.

3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer may
have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness or accuracy.
In addition, information obtained from a database may not be as current as the information in the SDS available directly from 3M

Pagelof 2
-C’

3MTM Dynatron Putty-Cote 592, 593 03/12/15 I Q


3M USA SDSs are available at www.3M.com

Page2of 2
I 3M” Blue Cream Hardener 03/07/14

3M
Safety Data Sheet
Copyright,2014,3M Company.
All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is
allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is obtained from
3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon.

Document Group: 26-9510-4 Version Number: 9.01


Issue Date: 03/07/14 Supercedes Date: 02/19/14

I SECTION 1: Identification
1.1. Product identifier
3MT Blue Cream Hardener

Product Identification Numbers


LB-Kl 00-0788-3, LB-K100-0801-2, 41-0003-6567-0, 41-0003-6575-3, 41-0003-6576-1, 41-0003-6577-9, 41-0003-6578-7,
41-0003-6610-8, 41-0003-6613-2, 41-0003-6614-0, 60-4550-4563-7, 60-4550-4689-0, 70-0080-0038-5, 70-0080-0373-6, 70-
0080-0377-7, 70-0080-0380-1, 70-0080-0382-7, 70-0080-0386-8, 70-0080-03 89-2, 70-0080-0609-3

1.2. Recommended use and restrictions on use

Recommended use
Automotive, Hardener for Body Fillers

1.3. Supplier’s details


MANUFACTURER: 3M
DIVISION: Automotive Aftermarket

ADDRESS: 3M Center, St. Paul, MN 55 144-1000, USA


Telephone: 1-888-3M HELPS (1-888-364-3577)

1.4. Emergency telephone number


1-800-364-3577 or (651) 737-6501 (24 hours)

I SECTION 2: Hazard identification


The label elements below were prepared in accordance with OSHA Hazard Communication Standard, 29 CFR 1910.1200.
This information may be different from the actual product label information for labels regulated by other agencies.

2.1. Hazard classification


Organic Peroxide: Type E.
Serious Eye Damage/Irritation: Category 2A.
Skin Sensitizer: Category 1.

2.2. Label elements


Signal word
Warning

Symbols

Page 1 of 11
I 3MTM Blue Cream Hardener 03/07/14 I C
Flame Exclamation mark

Pictograms

Hazard Statements
Heating may cause a fire.

Causes serious eye irritation.


May cause an allergic skin reaction.

Precautionary Statements
General:
Keep out of reach of children.

Prevention:
Keep away from heat/sparks/open flames/hot surfaces. No smoking.
-

Keep away from clothing and other combustible materials.


Keep only in original container.
Avoid breathing dust/fume/gas/mist/vapors/spray.
Wear protective gloves and eye/face protection.
Wash thoroughly after handling.
Contaminated work clothing must not be allowed out of the workplace.
C
Response:
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
If eye irritation persists: Get medical advice/attention.
IF ON SKIN: Wash with plenty of soap and water.
If skin irritation or rash occurs: Get medical advice/attention.
Wash contaminated clothing before reuse.

Storage:
Protect from sunlight.
Store at temperatures not exceeding 32C/90F. Keep cool.
Store away from other materials.

Disposal:
Dispose of contents/container in accordance with applicable local/regional/national/international regulations.

Notes to Physician:
Not applicable

2.3. Hazards not otherwise classified


None.

8% of the mixture consists of ingredients of unknown acute dermal toxicity.


15% of the mixture consists of ingredients of unknown acute inhalation toxicity.

I SECTION 3: Composition/information on ingredients


C
Page 2 of 11
I 3M1M Blue Cream Hardener 03/07/14 I

Ingredient C.A.S. No. % by Wt


Benzoyl Peroxide 94-36-0 30 60 Trade Secret *
-

Water 7732-18-5 10- 30 Trade Secret *


Benzoic Acid, C9-1 1-Branched Alkyl Esters 131298-44-7 10- 30 Trade Secret *
Zinc Stearate 557-05-1 5 10 Trade Secret *
-

Calcium Sulfate 777 8-1 8-9 3 7 Trade Secret *


-

Oxirane, Polymer with Methyloxirane, Monobutyl Ether 9038-95-3 1 5 Trade Secret *


-

Ferric Ferrocyanide 14038-43-8 < 1 Trade Secret *


Ferric Ammonium Ferrocyanide 25869-00-5 < I Trade Secret *

*The specific chemical identity andJor exact percentage (concentration) of this composition has been withheld as a trade
secret.

I SECTION 4: First aid measures


4.1. Description of first aid measures

Inhalation:
Remove person to fresh air. If you feel unwell, get medical attention.

Skin Contact:
Immediately wash with soap and water. Remove contaminated clothing and wash before reuse. If signs/symptoms develop,
get medical attention.

Eye Contact:
Immediately flush with large amounts of water. Remove contact lenses if easy to do. Continue rinsing. Get medical
attention.

If Swallowed:
Rinse mouth. If you feel unwell, get medical attention.

4.2. Most important symptoms and effects, both acute and delayed
See Section 11.1. Information on toxicological effects.

4.3. Indication of any immediate medical attention and special treatment required
Not applicable

I SECTION 5: Fire-fighting measures


5.1. Suitable extinguishing media
In case of fire: Use a fire fighting agent suitable for ordinary combustible material such as water or foam to extinguish.

5.2. Special hazards arising from the substance or mixture


Closed containers exposed to heat from fire may build pressure and explode. Part of the oxygen for combustion is supplied
by the peroxide itself.

Hazardous Decomposition or By-Products


Substance Condition
Carbon monoxide During Combustion
Carbon dioxide During Combustion
Toxic Vapor, Gas, Particulate During Combustion

5.3. Special protective actions for fire-fighters

Page 3 of 11
I 3M’ Blue Cream Hardener 03/07/14

No unusual fire or explosion hazards are anticipated.

I SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures


Evacuate area. Keep away from heat/sparks/open flames/hot surfaces. No smoking. Use only non-sparking tools.
-

Ventilate the area with fresh air. Refer to other sections of this SDS for information regarding physical and health hazards,
respiratory protection, ventilation, and personal protective equipment.

6.2. Environmental precautions


Avoid release to the environment. For larger spills, cover drains and build dikes to prevent entry into sewer systems or
bodies of water.

6.3. Methods and material for containment and cleaning up


Collect as much of the spilled material as possible using non-sparking tools. Place in a closed container approved for
transportation by appropriate authorities. Clean up residue. Seal the container. Dispose of collected material as soon as
possible.

I SECTION 7: Handling and storage


7.1. Precautions for safe handling
Avoid breathing of dust created by cutting, sanding, grinding or machining. Keep out of reach of children. Keep away from
heat/sparks/open flames/hot surfaces. No smoking. Avoid breathing dust/fume/gas/mist/vapors/spray. Do not get in eyes,
-

on skin, or on clothing. Do not eat, drink or smoke when using this product. Wash thoroughly after handling.
Contaminated work clothing should not be allowed out of the workplace. Avoid release to the environment. Wash
contaminated clothing before reuse.

7.2. Conditions for safe storage including any incompatibilities


C’
Protect from sunlight. Store at temperatures not exceeding 32C/90F. Keep cool. Keep only in original container. Store
away from other materials. Keep/store away from clothing and other combustible materials.

I SECTION 8: Exposure controls/personal protection

8.1. Control parameters

Occupational exposure limits

Ingredient C.A.S. No. Agency Limit type Additional Comments


Zinc Stearate 557-05-I US Dept of TWA(as total dust):l5
Labor OSHA
- mg/m3;TWA(respirable
fraction):5 mg/m3
Calcium Sulfate 7778-18-9 Amer Conf of TWA(inhalable fraction):l0
Gov. Indust. rng/m3
1-lyg.
Calcium Sulfate 7778-18-9 US Dept of TWA(as total dust):15
Labor OSHA
- mg/m3;TWA(respirable
fraction):5 mg/m3
Benzoyl Peroxide 94-36-0 Amer Conf of TWA:5 mg/m3
Gov. Indust.
Hyg.
Benzoyl Peroxide 94-36-0 US Dept of TWA:5 mg/m3
Labor OSHA
-

Amer ConfofGov. Indust. Hyg. : American Conference of Governmental Industrial Hygienists


American Indust. Hygiene Assoc American Industrial Hygiene Association
Chemical Manufacturer Rec Guid : Chemical Manufacturer’s Recommended Guidelines
C
Page 4 of 11
I 3M
’ Blue Cream Hardener
1 03/07/14

US Dept of Labor OSHA : United States Department of Labor Occupational Safety and Health Administration
- -

TWA: Time-Weighted-Average
STEL: Short Term Exposure Limit
CElL: Ceiling

8.2. Exposure controls

8.2.1. Engineering controls


Use general dilution ventilation andlor local exhaust ventilation to control airborne exposures to below relevant Exposure
Limits and/or control dust/fume/gas/mist/vapors/spray. If ventilation is not adequate, use respiratory protection equipment.

8.2.2. Personal protective equipment (PPE)

Eye/face protection

Wear eye/face protection. Select and use eye/face protection to prevent contact based on the results of an exposure
assessment. The following eye/face protection(s) are recommended:
Indirect Vented Goggles

Skin/hand protection
Select and use gloves and/or protective clothing approved to relevant local standards to prevent skin contact based on the
results of an exposure assessment. Selection should be based on use factors such as exposure levels, concentration of the
substance or mixture, frequency and duration, physical challenges such as temperature extremes, and other use conditions.
Consult with your glove and/or protective clothing manufacturer for selection of appropriate compatible gloves/protective
clothing. Wear protective gloves.
Gloves made from the following material(s) are recommended: Nitrile Rubber

If this product is used in a manner that presents a higher potential for exposure (eg. spraying, high splash potential etc.), then
use of protective coveralls may be necessary. Select and use body protection to prevent contact based on the results of an
exposure assessment. The following protective clothing material(s) are recommended: Apron Nitrile —

Respiratory protection

Wear respiratory protection if ventilation is inadequate to prevent overexposure. An exposure assessment may be needed to
decide if a respirator is required. If a respirator is needed, use respirators as part of a full respiratory protection program.
Based on the results of the exposure assessment, select from the following respirator type(s) to reduce inhalation exposure:
Half facepiece or full facepiece air-purifying respirator suitable for organic vapors and particulates

For questions about suitability for a specific application, consult with your respirator manufacturer.

I SECTION 9: Physical and chemical properties


9.1. Information on basic physical and chemical properties
General Physical Form: Solid
Specific Physical Form: Paste
Odor, Color, Grade: Blue paste with slight ester odor
Odor threshold No Data Available
pH No Data Available
Melting point No Data A t’ailable
Boiling Point Not Applicable
Flash Point Ill °C [Test Method: Estimated]
Evaporation rate No Data Available
Flammability (solid, gas) Organic Peroxide: Type E.
Flammable Limits(LEL) Not Applicable
Flammable Limits(UEL) Not Applicable
Vapor Pressure No Data Available

Page 5 of 11
I 3M’ Blue Cream Hardener 03/07/14

Vapor Density No Data Available

Density 1.2 g/ml


Specific Gravity 1.2 [RefStd. WATER=1] [Details: @25 C]

Solubility in Water Negligible


Solubility- non-water No Data A vailable

Partition coefficient: n-octanoll water No Data Available


Autoignition temperature 410°C [Test Method: Estimated]
Decomposition temperature No Data Available
Viscosity 70,000 centipoise 150,000 centipoise
-

Hazardous Air Pollutants 2.0 % weight [Test Method: Calculated]


Volatile Organic Compounds 0 % weight [Test Method: calculated per CARB title 2]
Volatile Organic Compounds 0 gIl [Test Method: calculated SCAQMD rule 443.1]
VOC Less 1120 & Exempt Solvents 0 g/l [Test Method: calculated SCAQMD rule 443.1]

I SECTION 10: Stability and reactivity


10.1. Reactivity
This material may be reactive with certain agents under certain conditions see the remaining headings in this section.
-

10.2. Chemical stability


Stable.
C
10.3. Possibility of hazardous reactions
Hazardous polymerization will not occur.

10.4. Conditions to avoid


None known.

10.5. Incompatible materials


Accelerators

10.6. Hazardous decomposition products


Substance Condition
None known.

Refer to section 5.2 for hazardous decomposition products during combustion.

I SECTION 11: Toxicological information


The information below may not be consistent with the material classification in Section 2 if specific ingredient
classifications are mandated by a competent authority. In addition, toxicological data on ingredients may not be
reflected in the material classification and/or the signs and symptoms of exposure, because an ingredient may be
present below the threshold for labeling, an ingredient may not be available for exposure, or the data may not be
relevant to the material as a whole.

11.1. Information on Toxicological effects

Signs and Symptoms of Exposure

Page 6 of 11
I 3M’ Blue Cream Hardener 03/07114

Based on test data and/or information on the components, this material may produce the following health effects:

Inhalation:
May be harmful if inhaled. Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge,
headache, hoarseness, and nose and throat pain.

Dust from cutting, grinding, sanding or machining may cause irritation of the respiratory system. Signs/symptoms may
include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain.

Skin Contact:
Maybe harmful in contact with skin.
Contact with the skin during product use is not expected to result in significant irritation. Allergic Skin Reaction (non-photo
induced): Signs/symptoms may include redness, swelling, blistering, and itching.

Eye Contact:
Severe Eye Irritation: Signs/symptoms may include significant redness, swelling, pain, tearing, cloudy appearance of the
cornea, and impaired vision.

Dust created by cutting, grinding, sanding, or machining may cause eye irritation. Signs/symptoms may include redness,
swelling, pain, tearing, and blurred or hazy vision.

Ingestion:
Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhea.

Toxicological Data
If a component is disclosed in section 3 but does not appear in a table below, either no data are available for that endpoint or
the data are not sufficient for classification.

S.cute Toxicity
Name Route Species Value
Overall product Dermal No data available; calculated ATE 4,386 mg/kg
Overall product Inhalation- No data available; calculated ATE 10.5 mg/I
DustlMist(4
hr)
Overall product Ingestion No data available; calculated ATE> 5,000 mg/kg
Benzoyl Peroxide Dermal LD5O estimated to be 2,000 5,000 mg/kg
-

Benzoyl Peroxide Inhalation- Rat L.C50 > 24.3 mg/I


Dust/Mist
(4 hours)
Benzoyl Peroxide Ingestion Rat LD5O> 5,000 mg/kg
Benzoic Acid, C9-l I-Branched Alkyl Esters Dermal Rabbit LD5O> 2,000 mg/kg
Benzoic Acid, C9-I I-Branched Alkyl Esters Inhalation- Rat LC5O 2 mg/I
Dust/Mist
(4 hours)
Benzoic Acid, C9-l I-Branched AIkyl Esters Ingestion Rat LD5O> 5,000 mg/Icg
Zinc Stearste Dermal Rabbit LD5O> 2,000 mg/kg
Zinc Stearate Ingestion Rat LD5O> 5,000 mg/kg
Calcium Sulfate Ingestion Rat LD5O> 5,000 mg/kg
Oxirane, Polymer with Methyloxirane, Monobutyl Ether Dermal Rabbit LD5O> 16,960 mg/kg
Oxirane, Polymer with Methyloxirane, Monobutyl Ether Inhalation- Rat LC5O> 5 mg/i
Dust/Mist
(4 hours)
Oxirane, Polymer with Methyloxirane, Monobutyl Ether Ingestion Rat LD5O 4,240 mg/kg
Ferric Ammonium Ferrocyanide Ingestion Rat LD5O> 5,1 10 mg/kg
Ferric Ferrocyanide Ingestion Rat LD5O> 8,000 mg/kg
ATE = acute toxicity estimate

Skin Corrosion/Irritation
Name I Species Value

Page 7 of 11
I 3M” Blue Cream Hardener 03/07/14 I

Benzoyl Peroxide Rabbit Minimal irritation


Oxirane, Polymer with Methyloxirane, Monobutyl Ether Rabbit Minimal irritation

Serious Eye Damage/Irritation

Name Species Value


Benzoyl Peroxide Rabbit Severe irritant
Oxirane, Polymer with Methyloxirane, Monobutyl Ether Rabbit No significant irritation

Skin Sensitization

Name Species Value


Benzoyl Peroxide Human Sensitizing
and
animal

Respiratory Sensitization

Name Species Value

Germ Cell Mutagenicity

Name Route Value

Benzoyl Peroxide In Vitro Not mutagenic


Benzoyl Peroxide In vivo Not mutagenic

Carcinogenicity

Name Route Species Value


benzoyl Peroxide Ingestion Multiple Not carcinogenic
animal
apecies
Benzoyl Peroxide

Oxirane, Polymer with Methyloxirane, Monobutyl Ether


Dermal

Ingestion
Mouse

Rat
Some positive data exist, but the data are not
sufficient for classification
Not carcinogenic
C
Reproductive Toxicity

Reproductive and/or Developmental Effects


Name Route Value Species Test Result Exposure
Duration
Benzoyl Peroxide Ingestion Not toxic to female reproduction Rat NOAEL premating &
1,000 during
mg/lcg/day gestation
Benzoyl Peroxide Ingestion Some positive male reproductive data Rat NOAEL 500 premating &
exist, but the data are not aufficient for mg/kg/day during
classification gestation
Benzoyl Peroxide Ingestion Some positive developmental data exist, Rat NOAEL 500 premating &
but the data are not sufficient for mg/kg/day during
classification gestation
Oxirane, Polymer with Methyloxirane, Ingestion Not toxic to female reproduction Rat NOAEL 90 days
Monobutyl Ether 3,770
mg/kg/day
Oxirane, Polymer with Methyloxirane, Ingestion Not toxic to male reproduction Rat NOAEL 90 days
Monobutyl Ether 3,770
mg/kg/day
Oxirane, Polymer with Methyloxirane, Inhalation Some positive male reproductive data Rat NOAEL 1 2 weeks
Monobutyl Ether exist, but the data are not sufficient for mg/I
classification

Target Organ(s)

Specific Target Organ Toxicity - single exposure

Name Route Target Organ(s) Value Species Test Result Exposure


Duration
Oxirane, Polymer with Ingestion nervous system Some positive data exist, but the Rat NOAEL Not
Methyloxirane,_Monobutyl data_are_not_sufficient_for available

C
Page 8 of 11
I 3M Blue Cream Hardener 03/07/14

Ether I I I classification I I I
Specific Target Organ Toxicity - repeated exposure
Name Route Target Organ(s) Value Species Test Result Exposure
Duration
Oxirane, Polymer with Inhalation endocrine system I Some positive data exist, but the Rat NOAEL 1 2 weeks
Methyloxirane, Monobutyl hematopoietic data are not sufficient for mg/I
Ether system I liver I classification
nervous_system
Oxirane, Polymer with Inhalation kidney and/or Some positive data exist, but the Rat NOAEL .005 2 weeks
Methyloxirane, Monobutyl bladder data are not sufficient for mg/I
Ether classification
Oxirane, Polymer with Inhalation respiratory system Some positive data exist, but the Rat LOAEL .001 2 weeks
Methyloxirane, Monobutyl data are not sufficient for mg/I
Ether classification
Oxirane, Polymer with Inhalation heart All data are negative Rat NOAEL .5 2 weeks
Methyloxirsne, Monobutyl mg/I
Ether
Oxirane, Polymer with Ingestion liver I kidney and/or Some positive data exist, but the Rat NOAEL 145 90 days
Methyloxirane, Monobutyl bladder data are not sufficient for mg/kg/day
Ether classification
Oxirane, Polymer with Ingestion hematopoietic All data are negative Rat NOAEL 500 2 years
Methyloxirane, Monobulyl system mg/kg/day
Ether
Oxirane, Polymer with Ingestion heart I endocrine All data are negative Rat NOAEL 90 days
Methyloxirane, Monobutyl system I respiratory 3,770
Ether system mg/kg/day

Aspiration Hazard
Name Value

Please contact the address or phone number listed on the first page of the SDS for additional toxicological information
on this material and/or its components.

I SECTION 12 Ecological information


j
Ecotoxicological information

Please contact the address or phone number listed on the first page of the SDS for additional ecotoxicological information on this material
and/or its components.
Chemical fate information

Please contact the address or phone number listed on the first page of the SDS for additional chemical fate information on this material
and/or its components.

I SECTION 13: Disposal considerations 1


13.1. Disposal methods
Dispose of contents! container in accordance with the local/regional/national/international regulations.

Dispose of waste product in a permitted industrial waste facility. As a disposal alternative, incinerate uncured product in a
permitted waste incineration facility. Proper destruction may require the use of additional fuel during incineration processes.
Empty drums/barrels/containers used for transporting and handling hazardous chemicals (chemical
substances/mixtures/preparations classified as Hazardous as per applicable regulations) shall be considered, stored, treated &
disposed of as hazardous wastes unless otherwise defined by applicable waste regulations. Consult with the respective
regulating authorities to determine the available treatment and disposal facilities.

I SECTION 14 Transport Information

Page 9 of 11
I 3MTM Blue Cream Hardener 03/07/14

IFor Transport Information, please visit http://3M.comlTransportinfo or call 1-800-364-3577 or 651-737-6501. I


I SECTION 15 Regulatory information I
15.1. US Federal Regulations
Contact 3M for more information.

311/312 Hazard Categories:

Fire Hazard No
- Pressure Hazard No - Reactivity Hazard No
- Immediate Hazard Yes
- Delayed Hazard No
-

Section 313 Toxic Chemicals subject to the reporting requirements of that section and 40 CFR part 372 (EPCRA):

Ingredient C.A.S. No % by Wt
Zinc Stearate (ZINC COMPOUNDS) 557-05-1 5- 10
Benzoyl Peroxide 94-36-0 30 60
-

15.2. State Regulations


Contact 3M for more information.

15.3. Chemical Inventories


The components of this product are in compliance with the chemical notification requirements of TSCA.
(
Contact 3M for more information.

15.4. International Regulations


Contact 3M for more information.

This SDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200. I
I SECTION 16: Other information
NFPA Hazard Classification
Health: 2 Flammability: 2 Instability: 0 Special Hazards: Oxidizer

National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address
the hazards that are presented by short-term, acute exposure to a material under conditions of fire, spill, or similar
emergencies. Hazard ratings are primarily based on the inherent physical and toxic properties of the material but also include
the toxic properties of combustion or decomposition products that are known to be generated in significant quantities.

Document Group: 26-9510-4 Version Number: 9.01


Issue Date: 03/07/14 Supercedes Date: 02/19/14

DISCLAIMER: The information in this Safety Data Sheet (SDS) is believed to be correct as of the date issued. 3M MAKES
NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY
OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR
USAGE OF TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable
for users method of use or application. Given the variety of factors that can affect the use and application of a 3M product,
some of which are uniquely within the user’s knowledge and control, it is essential that the user evaluate the 3M product to

Page 10 of 11
3MTM Blue Cream Hardener 03/07/ 14

determine whether it is fit for a particular purpose and suitable for user’s method of use or application.

3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer
may have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness
or accuracy. In addition, information obtained from a database may not be as current as the information in the SDS available
directly from 3M

3M USA SDSs are available at www.3M.com

Page 11 of 11
I 3M DYNATRON® PUTTY-COTE 592, 592T, 593 12/15/15 I

3M
Safety Data Sheet
Copyright,201 5,3M Company.
All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is
allowed provided that: (I) the information is copied in full with no changes unless prior written agreement is obtained from
3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon.

Document Group: 24-2371-3 Version Number: 6.02


Issue Date: 12/15/15 Supercedes Date: 05/26/15

I SECTION 1: Identification
1.1. Product identifier
3MTM DYNATRON® PUTTY-COTE 592, 592T, 593

Product Identification Numbers


LB-K1 00-0587-6, LB-Kl 00-0587-7, LB-K1 08-2014-3, 41-3701-1520-0

1.2. Recommended use and restrictions on use

Recommended use
Automotive, Autobody repair.

1.3. Supplier’s details


MANUFACTURER: 3M
DIVISION: Automotive Aftermarket
ADDRESS: 3M Center, St. Paul, MN 55 144-1000, USA
Telephone: 1-888-3M HELPS (1 -888-364-3577)

1.4. Emergency telephone number


1-800-364-3577 or (651) 737-6501 (24 hours)

I SECTION 2: Hazard identification


The label elements below were prepared in accordance with OSHA Hazard Communication Standard, 29 CFR 19 10.1200.
This information may be different from the actual product label information for labels regulated by other agencies.

2.1. Hazard classification


Flammable Liquid: Category 3.
Serious Eye Damage/Irritation: Category 1.
Skin Sensitizer: Category 18.
Carcinogenicity: Category IA.
Specific Target Organ Toxicity (single exposure): Category I.
Specific Target Organ Toxicity (repeated exposure): Category 1.

2.2. Label elements


Signal word
Danger

C
Page 1 of 14
I 3M’ DYNATRON® PtJTTY-COTE 592, 592T, 593 12/15/15

Symbols
Flame I Corrosion Exclamation mark I Health Hazard

Hazard Statements
Flammable liquid and vapor.

Causes serious eye damage.


May cause an allergic skin reaction.
May cause cancer.

Causes damage to organs:


liver
sensory organs

Causes damage to organs through prolonged or repeated exposure:


respiratory system I
sensory organs

May cause damage to organs through prolonged or repeated exposure:


liver

Precautionary Statements
General:
Keep out of reach of children.

Prevention:
Obtain special instructions before use.
Do not handle until all safety precautions have been read and understood.
Keep away from heat/sparks/open flames/hot surfaces. No smoking.
-

Ground/bond container and receiving equipment.


Use only non-sparking tools.
Take precautionary measures against static discharge.
Keep container tightly closed.
Use explosion-proof electrical/ventilating/lighting equipment.
Do not breathe dust/fume/gas/mist/vapors/spray.
Wear protective gloves and eye/face protection.
Do not eat, drink or smoke when using this product.
Wash thoroughly after handling.
Contaminated work clothing must not be allowed out of the workplace.

Response:
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
Immediately call a POISON CENTER or doctor/physician.
IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower.
IF ON SK[N: Wash with plenty of soap and water.
If skin irritation or rash occurs: Get medical advice/attention.
Wash contaminated clothing before reuse.
Get medical advice/attention if you feel unwell.

Page 2 of 14
I 3M DYNATRON® PUTTY-COTE 592, 592T, 593 12115/15 •.10
In case of fire: Use a fire fighting agent suitable for flammable liquids such as dry chemical or carbon dioxide to
extinguish.

Storage:
Store in a well-ventilated place. Keep cool.
Store locked up.

Disposal:
Dispose of contents/container in accordance with applicable local/regional/national/international regulations.

2.3. Hazards not otherwise classified


None.

36% of the mixture consists of ingredients of unknown acute oral toxicity.


41% of the mixture consists of ingredients of unknown acute dermal toxicity.
49% of the mixture consists of ingredients of unknown acute inhalation toxicity.

SECTION 3 Composition/information on ingredients


Ingredient C.A.S. No. % by Wt
Proprietary Polyester Resin Trade Secret* 15 40 Trade Secret
-
*

Poly[oxy(methyl-l,2-ethanediyl)], .alpha.-hydro- 25322-69-4 10 - 30 Trade Secret *

omega. -hydroxy
Styrene Monomer 100-42-5 10 30 Trade Secret *
-

Defoamer Trade Secret* 1 0 30 Trade Secret *

0
-

2,4,7,9-Tetramethyl-5-Decyne-4,7-Diol 126-86-3 5 10 Trade Secret *


-

Limestone 13 17-65-3 3 7 Trade Secret *


-

Polyester Polymer Trade Secret* 3 7 Trade Secret *


Talc 14807-96-6 1 5 Trade Secret *
-

Titanium Dioxide 13463-67-7 - 5 Trade Secret *


Fatty Acid Amide Trade Secret* 1 5 Trade Secret *
-

Thickening Agent Trade Secret* < 3 Trade Secret *


Quartz Silica 14808-60-7 < 0.5 Trade Secret *

*The specific chemical identity andlor exact percentage (concentration) of this composition has been withheld as a trade
secret.

I SECTION 4 First aid measures


4.1. Description of first aid measures

Inhalation:
Remove person to fresh air. If you feel unwell, get medical attention.

Skin Contact:
Immediately wash with soap and water. Remove contaminated clothing and wash before reuse. If signs/symptoms develop,
get medical attention.

Eye Contact:
Immediately flush with large amounts of water for at least 15 minutes. Remove contact lenses if easy to do. Continue
rinsing. Immediately get medical attention.

If Swallowed:
Rinse mouth, If you feel unwell, get medical attention.

Page 3 of 14
I 3M IJYNATRON® PU TTY-COTE 592, 592T, 593 12/1 5115

4.2. Most important symptoms and effects, both acute and delayed
See Section 11.1. Information on toxicological effects.

4.3. Indication of any immediate medical attention and special treatment required
Not applicable

SECTION 5: Fire-fighting measures


5.1. Suitable extinguishing media
In case of fire: Use a fire fighting agent suitable for flammable liquids such as dry chemical or carbon dioxide to extinguish.

5.2. Special hazards arising from the substance or mixture


Closed containers exposed to heat from fire may build pressure and explode.

5.3. Special protective actions for fire-fighters


Water may not effectively extinguish tire; however, it should be used to keep fire-exposed containers and surfaces cool and
prevent explosive rupture.

SECTION 6: Accidental release measures


6.1. Personal precautions, protective equipment and emergency procedures
Evacuate area. Keep away from heat/sparks/open flames/hot surfaces. No smoking. Use only non-sparking tools. Ventilate
-

the area with fresh air. For large spill, or spills in confined spaces, provide mechanical ventilation to disperse or exhaust
vapors, in accordance with good industrial hygiene practice. Warning! A motor could be an ignition source and could cause
flammable gases or vapors in the spill area to burn or explode. Refer to other Sections of this SDS for information regarding
physical and health hazards, respiratory protection, ventilation, and personal protective equipment.

6.2. Environmental precautions


Avoid release to the environment. For larger spills, cover drains and build dikes to prevent entry into sewer systems or bodies
of water.

6.3. Methods and material for containment and cleaning up


Contain spill. Cover spill area with a fire-extinguishing foam. An appropriate aqueous film forming foam (AFFF) is
recommended. Working from around the edges of the spill inward, cover with bentonite, vermiculite, or commercially
available inorganic absorbent material. Mix in sufficient absorbent until it appears dry. Remember, adding an absorbent
material does not remove a physical, health, or environmental hazard. Collect as much of the spilled material as possible
using non-sparking tools. Place in a metal container approved for transportation by appropriate authorities. Clean up residue
with an appropriate solvent selected by a qualified and authorized person. Ventilate the area with fresh air. Read and follow
safety precautions on the solvent label and SDS. Seal the container. Dispose of collected material as soon as possible.

SECTION 7: Handling and storage


7.1. Precautions for safe handling
Keep out of reach of children. Do not handle until all safety precautions have been read and understood. Keep away from
heat/sparks/open flames/hot surfaces. No smoking. Use only non-sparking tools. Take precautionary measures against
-

static discharge. Do not breathe dust/fume/gas/mist/vapors/spray. Do not get in eyes, on skin, or on clothing. Do not eat,
drink or smoke when using this product. Wash thoroughly after handling. Contaminated work clothing should not be
allowed out of the workplace. Avoid release to the environment. Wash contaminated clothing before reuse. Avoid contact
with oxidizing agents (eg. chlorine, chromic acid etc.) Wear low static or properly grounded shoes. Use personal protective
equipment (gloves, respirators, etc.) as required. To minimize the risk of ignition, determine applicable electrical
classifications for the process using this product and select specific local exhaust ventilation equipment to avoid flammable
vapor accumulation. Ground/bond container and receiving equipment if there is potential for static electricity accumulation
during transfer. Vapors may travel long distances along the ground or floor to an ignition source and flash back.

Page 4 of 14
I 3MTM DYNATRON® PUTTY-COTE 592, 592T, 593 12/15/15

7.2. Conditions for safe storage including any incompatibilities


Store in a well-ventilated place. Keep cool. Keep container tightly closed to prevent loss of stabilizing materials. Protect
from sunlight. Store away from heat. Store away from acids. Store away from strong bases. Store away from oxidizing
agents. Store away from areas where product may come into contact with food or pharmaceuticals. Store in a dry place.

I SECTION 8: Exposure controls/personal protection


8.1. Control parameters

Occupational exposure limits


If a component is disclosed in section 3 but does not appear in the table below, an occupational exposure limit is not available
for the component.
Ingredient C.A.S. No. Agency Limit type Additional Comments
Styrene Monomer 100-42-5 ACGIH TWA:20 ppm;STEL:40 ppm A4: Not class, as human
carcin
Styrene Monomer 100-42-5 OSHA TWA: 100 ppm;CEIL:200 ppm
Limestone 1317-65-3 OSHA TWA(as total dust): 15
mg/m3 ;TWA(respirable
fraction):5 mg/m3
Titanium Dioxide 13463-67-7 ACGIH TWA:l0 mg/m3 A4: Not class, as human
carcin
Titanium Dioxide 13463-67-7 CMRG TWA(as respirable dust):5
mg/m3
Titanium Dioxide 13463-67-7 OSHA TWA(as total dust):15 mg/m3
Talc 14807-96-6 OSHA TWA concentration(as total
dust):0.3 mg/m3;TWA
concentration(respirable):0. I
mg/m3(2.4 millions of
C
particles/cu. ft.);TWA:20
millions of particles/cu. ft.
Talc 14807-96-6 ACGIH TWA(respirable fraction):2 A4: Not class, as human
rng/rn3 carcin
Talc 14807-96-6 CMRG TWA(as respirable dust):0.5
mg/m3
Quartz Silica 14808-60-7 ACGIH TWA(respirable A2: Suspected human
fraction):0.025 mg/m3 carcin.
Quartz Silica 14808-60-7 OSHA TWA concentration(as total
dust):0.3 mg/m3;TWA
concentration(respirable):0. 1
rng/m3(2.4 millions of
particles/cu. ft.)
Poly[oxy(methyl-1,2- 25322-69-4 AIHA TWA(as aerosol):lO mg/m3
ethanediyl)], .alpha.-hydro
.omega.-hydroxy
ACGIH : American Conference of Governmental Industrial Hygienists
AIHA : American Industrial Hygiene Association
CMRG : Chemical Manufacturer’s Recommended Guidelines
OSHA: United States Department of Labor Occupational Safety and Health Administration
-

TWA: Time-Weighted-Average
STEL: Short Term Exposure Limit
CElL: Ceiling

8.2. Exposure controls

8.2.1. Engineering controls


Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below relevant Exposure
C
Page 5 of 14
I 3M’ DYNATRON® PUTTY-COTE 592, 592T, 593 12/15/15

Limits andlor control dustlfume/gas/mistlvapors/spray. If ventilation is not adequate, use respiratory protection equipment.
Use explosion-proof ventilation equipment. Provide appropriate local exhaust ventilation for cutting, grinding, sanding or
machining.

8.2.2. Personal protective equipment (PPE)

Eye/face protection

Select and use eye/face protection to prevent contact based on the results of an exposure assessment. The following eye/face
protection(s) are recommended:
Full Face Shield
Indirect Vented Goggles

Skin/hand protection
Select and use gloves and/or protective clothing approved to relevant local standards to prevent skin contact based on the
results of an exposure assessment. Selection should be based on use factors such as exposure levels, concentration of the
substance or mixture, frequency and duration, physical challenges such as temperature extremes, and other use conditions.
Consult with your glove and/or protective clothing manufacturer for selection of appropriate compatible gloves/protective
clothing. Note: Nitrile gloves may be worn over polymer laminate gloves to improve dexterity.
Gloves made from the following material(s) are recommended: Polymer laminate

If this product is used in a manner that presents a higher potential for exposure (eg. spraying, high splash potential etc.), then
use of protective coveralls may be necessary. Select and use body protection to prevent contact based on the results of an
exposure assessment. The following protective clothing material(s) are recommended: Apron polymer laminate
-

Respiratory protection

An exposure assessment may be needed to decide if a respirator is required. If a respirator is needed, use respirators as part of
a full respiratory protection program. Based on the results of the exposure assessment, select from the following respirator
type(s) to reduce inhalation exposure:
Half facepiece or full facepiece air-purifying respirator suitable for organic vapors and particulates

For questions about suitability for a specific application, consult with your respirator manufacturer.

I SECTION 9: Physical and chemical properties


9.1. Information on basic physical and chemical properties
General Physical Form: Liquid
Specific Physical Form: Paste
Odor, Color, Grade: Solvent odor White Paste
Odor threshold No Data Available
pH No Data Available
1’4elting point No Data Available
Boiling Point 293 °F
Flash Point 90 °F [Test Method: Closed Cup]
Flash Point 32 °C [Test Method: SETAFLASH]
Evaporation rate No Data Available
Flammability (solid, gas) Not Applicable
Flammable Limits(LEL) No Data A vailable
Flammable Limits(UEL) A/a Data Available
Vapor Pressure No Data Available
Vapor Density 3.6 [RefStd: AIR=l]
Density 2.75 g/ml
Specific Gravity 2.75 [RefStd: WATER=l]
Solubility In Water No Data Available

Page 6 of 14
I 3M DYNATRON® PUTTY-COTE 592. 592T. 593 12/15/15

Solubility- non-water No Data Available


Partition coefficient: n-octanol/ water No Data Available
Autoignition temperature No Data Available
Decomposition temperature No Data Available
Viscosity 352,000 476,000 centipoise
-

Hazardous Air Pollutants 0.55 lb HAPS/Ib solids [Test Method: Calculated]


Volatile Organic Compounds 15.1 % weight [Test Method. calculated per CARE title 2]
Volatile Organic Compounds 414 g/l [Test Method: calculated SCAQMD rule 443.1]
Percent volatile 13.2 % weight
Percent volatile 15.2 % volume
VOC Less H20 & Exempt Solvents 415 g/l [Test Method: calculated SCAQMD rule 443.1]

I SECTION 10: Stability and reactivity


10.1. Reactivity
This material may be reactive with certain agents under certain conditions see the remaining headings in this section.
-

10.2. Chemical stability


Stable. Stable under normal conditions. May become unstable at elevated temperatures and/or pressure.

10.3. Possibility of hazardous reactions


Hazardous polymerization will not occur.

10.4. Conditions to avoid


Heat
Sparks and/or flames
C
10.5. Incompatible materials
Strong oxidizing agents
Strong acids
Alkali and alkaline earth metals
Strong oxidizing agents
Strong bases

10.6. Hazardous decomposition products


Substance Condition
Hydrocarbons Not Specified
Carbon monoxide Not Specified
Carbon dioxide Not Specified

I SECTION 11: Toxicological information


The information below may not be consistent with the material classification in Section 2 if specific ingredient
classifications are mandated by a competent authority. In addition, toxicological data on ingredients may not be
reflected in the material classification and/or the signs and symptoms of exposure, because an ingredient may be
present below the threshold for labeling, an ingredient may not be available for exposure, or the data may not be
relevant to the material as a whole.

11.1. Information on Toxicological effects

Signs and Symptoms of Exposure

Based on test data and/or information on the components, this material may produce the following health effects:
c
Page 7 of 14
[3Mm1 DYNATRON® PUTTY-COTE 592, 592T, 593 12115/15

Inhalation:
May be harmful if inhaled.
Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose
and throat pain.

May cause additional health effects (see below).

Skin Contact:
Mild Skin Irritation: Signs/symptoms may include localized redness, swelling, itching, and dryness. Allergic Skin Reaction
(non-photo induced): Signs/symptoms may include redness, swelling, blistering, and itching.

Eye Contact:
Corrosive (Eye Bums): Signs/symptoms may include cloudy appearance of the cornea, chemical burns, severe pain, tearing,
ulcerations, significantly impaired vision or complete loss of vision.

Ingestion:
May be harmful if swallowed.
Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhea.

May cause additional health effects (see below).

Additional Health Effects:

Single exposure may cause target organ effects:


Auditory Effects: Signs/symptoms may include hearing impairment, balance dysfunction and ringing in the ears.

Liver Effects: Signs/symptoms may include loss of appetite, weight loss, fatigue, weakness, abdominal tenderness and
jaundice.

Prolonged or repeated exposure may cause target organ effects:


Pneumoconiosis: Sign/symptoms may include persistent cough, breathlessness, chest pain, increased amounts of sputum, and
changes in lung function tests.

Ocular Effects: Signs/symptoms may include blurred or significantly impaired vision.

Auditory Effects: Signs/symptoms may include hearing impairment, balance dysfunction and ringing in the ears.

Liver Effects: Signs/symptoms may include loss of appetite, weight loss, fatigue, weakness, abdominal tenderness and
jaundice.

Carcinogenicity:
Contains a chemical or chemicals which can cause cancer.

Ingredient CAS No. Class Description Regulation


SILICA, CRYS AIRRESP 14808-60.7 Known human carcinogen National Toxicology Program Carcinogens
Quartz Silica 14808-60-7 Grp. I: Carcinogenic to humans International Agency for Research on Cancer
Styrene Monomer 100-42-5 Grp. 2B: Possible human care. International Agency for Research on Cancer
Styrene Monomer 100-42-5 Anticipated human carcinogen National Toxicology Program Carcinogens
Titanium Dioxide 13463-67-7 Grp. 2B: Possible human care. International Agency for Research on Cancer

Toxicological Data
If a component is disclosed in section 3 but does not appear in a table below, either no data are available for that endpoint or
the data are not sufficient for classification.

Acute Toxicity
I Name I Route I Species I Value

Page 8 of 14
I 3MTM DYNATRON® PUTTY-COTE 592, 592T, 593 12/15/15

Overall product Dermal No data available; calculated ATE> 5,000 mg/kg


Overall product Inhalation- No data available; calculated ATE 20 50 mg/I
-

Vapor(4 hr)
Overall product Ingestion No data available; calculated ATE 2,000 5,000
-

mg/kg
Styrene Monomer Dermal Rat LD5O> 2,000 mg/kg
Styrene Monomer Inhalation- Rat LC5O 8.3 mg/I
Vapor (4
hours)
Styrene Monomer Ingestion Rat LD5O 5,000 mg/kg
PoIy[oxy(methyl-I,2-ethanediyl)], .alpha.-hydro-.omega.- Dermal Rabbit LD5O> 10,000 mg/kg
hydroxy
Poly[oxy(methyl-I,2-ethanediyl)], .alpha.-hydro-.omega.- Ingestion Rat LD5O> 2,000 mg/kg
hydroxy
2,4,7,9-Tetramethyl-5-Decyne-4,7-Diol Dermal Rat LD5O > 2,000 mg/kg
2,4,7,9-Tetramethyl-5-Decyne-4,7-Diol Ingestion Rat LD5O> 500 mg/kg
Limestone Dermal Rat LD5O> 2,000 mg/lcg
Limestone Inhalation- Rat LC5O 3 mg/I
Dust/Mist
(4 hours)
Limestone Ingestion Rat LD5O 6,450 mg/kg
Polyester Polymer Ingestion LD5O estimated to be 2,000 5,000 mg/kg
-

Titanium Dioxide Dermal Rabbit LD5O> 10,000 mg/kg


Titanium Dioxide Inhalation- Rat LC5O > 6.82 mg/I
Dust/Mist
(4 hours)
Titanium Dioxide Ingestion Rat LD5O> 10,000 mg/kg
Talc Dermal LD5O estimated to be> 5,000 mg/kg
Talc Ingestion LD5O estimated to be> 5,000 mg/kg
Thickening Agent Dermal LD5O estimated to be> 5,000 mg/kg
Thickening Agent Inhalation-
Dust/Mist
(4 hours)
Rat LC5O> 12.6 mg/I
C,’
Thickening Agent Ingestion Rat LD5O> 5,000 mg/kg
Quartz Silica Dermal LD5O estimated lobe> 5,000 mg/kg
Quartz Silica Ingestion LD5O estimated to be> 5,000 mg/kg
ATE = acute toxicity estimate

Skin Corrosion/Irritation
Name Species Value

Styrene Monomer official Mild irritant


classifica
lion
Poly[oxy(methyl-l,2-ethanediyl)1, .alpha.-hydro-.omega.-hydroxy- Rabbit No significant irritation
2,4,7,9-Tetramethyl-5-Decyne-4,7-Diol Rabbit No significant irritation
Limestone Rabbit No significant irritation
Titanium Dioxide Rabbit No significant irritation
Talc Rabbit No significant irritation
Thickening Agent Rat No significant irritation
Quartz Silica Professio No significant irritation
nal
judgeme
nt

Serious Eye Damage/Irritation


Name Species Value

Styrene Monomer official Moderate irritant


classifies
tion
Poly[oxy(methyl-1,2-ethanediyl)], .alpha.-hydro-.omega.-hydroxy- Rabbit No significant irritation

C
2,4,7,9-Tetramelhyl-5-Decyne-4,7-Diol Rabbit Corrosive

Page 9 of 14
I 3MTM DYNATRON® PUTTY-COTE 592, 592T, 593 12/15/15

Limestone Rabbit No significant irritation


Titanium Dioxide Rabbit No significant irritation
Talc Rabbit No significant irritation
Thickening Agent Rabbit No significant irritation

Skin Sensittzation
Name Species Value
Styrene Monomer Guinea Not sensitizing
pig
2,4,7,9-Tetramethyl-5-Decyne-4,7-Diol Mouse Sensitizing
Titanium Dioxide Human Not sensitizing
and
animal

Respiratory Sensitization
Name Species Value

Talc Human Not sensitizing

Germ Cell Mutagenicity


Name Route Value

Styrene Monomer In Vitro Some positive data exist, but the data are not
sufficient for classification
Styrene Monomer In vivo Some positive data exist, but the data are not
sufficient for classification
Titanium Dioxide In Vitro Not mutagenic
Titanium Dioxide In vivo Not mutagenic
Talc In Vitro Not mutagenic
Talc In vivo Not mutagenic
Quartz Silica In Vitro Some poaitive data exist, but the data are not
sufficient for classification
Quartz Silica In vivo Some positive data exist, but the data are not
sufficient for classification

Carcinogenicity
Name Route Species Value
Styrene Monomer Ingestion Mouse Carcinogenic
Styrene Monomer Inhalation Human Carcinogenic
and
animal
Titanium Dioxide Ingestion Multiple Not carcinogenic
animal
species
Titanium Dioxide Inhalation Rat Carcinogenic
Talc Inhalation Rat Some positive data exist, but the data are not
sufficient for classification
Quartz Silica Inhalation Human Carcinogenic
and
animal

Reproductive Toxicity

Reproductive and/or Developmental Effects


Name Route Value Species Test Result Exposure
Duration
Styrene Monomer Ingestion Not toxic to female reproduction Rat NOAEL 21 3 generation
mg/kg/day
Styrene Monomer Inhalation Not toxic to female reproduction Rat NOAEL 2.1 2 generation
mg/I
Styrene Monomer Inhalation Not toxic to male reproduction Rat NOAEL 2.1 2 generation
mg/I
Styrene Monomer Ingestion Some positive male reproductive data Rat NOAEL 400 60 days

Page 10 of 14
I 3MTM DYNATRON® PUTTY-COTE 592, 592T, 593 12/15/15

exist, but the data are not sufficient for mg/kg/day


classification
Styrene Monomer Ingestion Some positive developmental data exist, Rat NOAEL 400 during
but the data are not sufficient for mg/kg/day gestation
classification
Styrene Monomer Inhalation Some positive developmental data exist, Multiple NOAEL 2.1 during
but the data are not sufficient for animal mg/I gestation
classification species
Limestone Ingestion Not toxic to development Rat NOAEL 625 premating &
mg/kg/day during
gestation
Talc Ingestion Not toxic to development Rat NOAEL 1,600 during
mg/kg organogenesi

Target Organ(s)

Specific Target Organ Toxicity - single exposure


Name Route Target Organ(s) Value Species Test Result Exposure
Duration
Styrene Monomer Inhalation auditory system Causes damage to organs Multiple LOAEL 4.3 not available
animal mg/I
species
Styrene Monomer Inhalation liver Causes damage to organs Mouse LOAEL 2.1 not available
mg/I
Styrene Monomer Inhalation central nervous May cause drowsiness or Human NOAEL Not occupational
system depression dizziness available exposure
Styrene Monomer Inhalation respiratory irritation Some positive data exist, but the Human NOAEL Not
data are not sufficient for and available
classification animal
Styrene Monomer

Styrene Monomer
Inhalation

Inhalation
endocrine system

kidney and/or
bladder
All data are negative

All data are negative


Rat

Multiple
animal
NOAEL Not
available
NOAEL 2.1
mg/I
not available

not available
C:
species
Limestone Inhalation respiratory system All data are negative Rat NOAEL 90 minutes
0.812 mg/I

Specific Target Organ Toxicity - repeated exposure


Name Route Target Organ(s) Value Species Test Result Exposure
Duration
Styrene Monomer Inhalation eyes Causes damage to organs through Human NOAEL Not occupational
prolonged or repeated exposure available exposure
Styrene Monomer Inhalation auditory system May cause damage to organs Multiple NOAEL 1.3 not available
though prolonged or repeated animal mg/I
exposure species
Styrene Monomer Inhalation liver May cause damage to organs Mouse LOAEL 0.85 13 weeks
though prolonged or repeated mg/I
exposure
Styrene Monomer Inhalation nervous system Some positive data exist, but the Multiple LOAEL 1.1 not available
data are not sufficient for animal mg/I
classification species
Styrene Monomer Inhalation hematopoietic Some positive data exist, but the Rat NOAEL 0.85 7 days
system data are not sufficient for mg/I
classification
Styrene Monomer Inhalation endocrine system Some positive data exist, but the Rat NOAEL 0.6 10 days
data are not sufficient for mg/I
classification
Styrene Monomer Inhalation respiratory system Some positive data exist, but the Multiple LOAEL 0.09 not available
data are not sufficient for animal mg/I
classification species
Styrene Monomer Inhalation heart bone, teeth, All data are negative Multiple NOAEL 4.3 2 years
nails, and/or hair I animal mg/I
muscles I kidney species
and/or bladder
Styrene Monomer Ingestion nervous system Some positive data exist, but the Rat LOAEL 500 8 weeks

C.
Page 11 of 14
I 3M DYNATRON® PUTTY-COTE 592. 592T. 593 12/15/15

data are not sufficient for mg/kg/day


classification
Styrene Monomer Ingestion immune system Some positive data exist, but the Multiple NOAEL Not not available
data are not sufficient for animal available
classification species
Styrene Monomer Ingestion liver kidney and/or Some positive data exist, but the Rat NOAEL 677 6 months
bladder data are not sufficient for mg/kg/day
classification
Styrene Monomer Ingestion hematopoietic Some positive data exist, but the Dog NOAEL 600 470 days
system data are not sufficient for mg/kg/day
classification
Styrene Monomer Ingestion heart respiratory All data are negative Rat NOAEL 35 105 weeks
system mg/kg/day
Limestone Inhalation respiratory system Some positive data exist, but the Human NOAEL Not occupational
data are not sufficient for available exposure
classification
Titanium Dioxide Inhalation respiratory system Some positive data exist, but the Rat LOAEL 0.01 2 years
data are not sufficient for mg/I
classification
Titanium Dioxide Inhalation pulmonary fibrosis All data are negative Human NOAEL Not occupational
available exposure
Talc Inhalation pneumoconiosis Causes damage to organs through Human NOAEL Not occupational
prolonged or repeated exposure available exposure
Talc Inhalation pulmonary fibrosis I Some positive data exist, but the Rat NOAEL 18 113 weeks
respiratory system data are not sufficient for mg/m3
classification
Quartz Silica Inhalation silicosis Causes damage to organs through Human NOAEL Not occupational
prolonged or repeated exposure available exposure

Aspiration Hazard
For the componentlcomponents, either no data are currently available or the data are not sufficient for classification.

Please contact the address or phone number listed on the first page of the SDS for additional toxicological information
on this material and/or its components.

I SECTION 12: Ecological information


Ecotoxicological information

Please contact the address or phone number listed on the first page of the SDS for additional ecotoxicological information on this material
and/or its components.
Chemical fate information

Please contact the address or phone number listed on the first page of the SDS for additional chemical fate information on this material
and/or its components.

I SECTION 13: Disposal considerations


13.1. Disposal methods
Dispose of contents! container in accordance with the local/regional/national/international regulations.

Dispose of completely cured (or polymerized) material in a permitted industrial waste facility. As a disposal alternative,
incinerate uncured product in a permitted waste incineration facility. Empty drums/barrels/containers used for transporting
and handling hazardous chemicals (chemical substances/mixtures/preparations classified as Hazardous as per applicable
regulations) shall be considered, stored, treated & disposed of as hazardous wastes unless otherwise defined by applicable
waste regulations. Consult with the respective regulating authorities to determine the available treatment and disposal
facilities.

SECTION 14: Transport Information

Page 12 of 14
I 3M DYNATRON® PUTTY-COTE 592, 592T, 593 12/15/15

For Transport Information, please visit http://3M.com/Transportinfo or call 1-800-364-3577 or 651-737-6501, I

I SECTION 15: Regulatory information


15.1. US Federal Regulations
Contact manufacturer for more information
311/312 Hazard Categories:

Fire Hazard Yes


- Pressure Hazard No
- Reactivity Hazard No - Immediate Hazard Yes- Delayed Hazard Yes
-

Section 313 Toxic Chemicals subject to the reporting requirements of that section and 40 CFR part 372 (EPCRA):

Ingredient C.A.S. No % by Wt
Styrene Monomer 100-42-5 Trade Secret 10- 30

15.2. State Regulations


Contact manufacturer for more information
California Proposition 65

Ingredient C.A.S. No. Classification


SILICA, CRYSTALLINE (AIRBORNE None Carcinogen
PARTICLES OF RESPIRABLE SIZE)
Titanium Dioxide 13463-67-7 Carcinogen

WARNING: This product contains a chemical known to the State of California to cause cancer.

15.3. Chemical Inventories


The components of this product are in compliance with the chemical notification requirements of TSCA.

Contact manufacturer for more information

15.4. International Regulations


Contact manufacturer for more information

This SDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200. I

I SECTION 16: Other information


NFPA Hazard Classification
Health: 3 Flammability: 3 Instability: I Special Hazards: None

National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address
the hazards that are presented by short-term, acute exposure to a material under conditions of fire, spill, or similar
emergencies. Hazard ratings are primarily based on the inherent physical and toxic properties of the material but also include
the toxic properties of combustion or decomposition products that are known to be generated in significant quantities.

HMIS Hazard Classification


Health: *3 Flammability: 3 Physical Hazard: 1 Personal Protection: X See PPE section.
-

Hazardous Material Identification System (HMIS® IV) hazard ratings are designed to inform employees of chemical hazards
in the workplace. These ratings are based on the inherent properties of the material under expected conditions of normal use

Page 13 of 14
3N1 DYNATRO® PUTTY-COTE 592, 592T, 593 12115/15

and are not intended for use in emergency situations. HMIS® IV ratings are to be used with a fully implemented HMIS® IV
program. HMIS® is a registered mark of the American Coatings Association (ACA).

Document Group: 24-2371-3 Version Number: 6.02


Issue Date: 12/15/15 Supercedes Date: 05/26/15

DISCLAIMER: The information in this Safety Data Sheet (SDS) is believed to be correct as of the date issued. 3M MAKES
NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY
OF MERCHANTABILITY OR FIThESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR
USAGE OF TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable
for user’s method of use or application. Given the variety of factors that can affect the use and application of a 3M product,
some of which are uniquely within the user’s knowledge and control, it is essential that the user evaluate the 3M product to
determine whether it is fit for a particular purpose and suitable for user’s method of use or application.

3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer
may have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness
or accuracy. In addition, information obtained from a database may not be as current as the information in the SDS available
directly from 3M

3M USA SDSs are available at www.3M.com

Page 14 of 14
0 0
I 3M’ Panel Bonding Adhesive PN 08115 09/24/15

3M
Safety Data Sheet
Copyright,201 5,3M Company.
All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is allowed
provided that: (1) the information is copied in full with no changes unless prior written agreement is obtained from 3M, and (2) neither
the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon.

Document Group: 07-1664-7 Version Number: 12.10


Issue Date: 09/24/15 Supercedes Date: 11/24/14

Product identifier
3MTM Panel Bonding Adhesive PN 08115

ID Number(s):

41-0003-6745-2, 41-0003-8009-1, 41-0003-8082-8, 41-9103-0505-5, 60-9800-3093-0, 60-9800-3246-4, 60-9800-4425-3, FS-9100-


3423-0, FS-9 100-3424-8, FS-9 100-3425-5, FS-9 100-5376-8

Recommended use
Automotive, Adhesive

Supplier’s details

MANUFACTURER: 3M
DIVISION: Automotive Aftermarket

ADDRESS: 3M Center, St. Paul, MN 55 144-1000, USA


Telephone: 1-888-3M HELPS (1-888-364-3577)

Emergency telephone number


1-800-364-3577 or (651) 737-6501 (24 hours)

This product is a kit or a multipart product which consists of multiple, independently packaged components. A Safety Data
Sheet (SDS), Article Information Sheet (AIS), or Article Information Letter (ALL) for each of these components is included.
Please do not separate the component documents from this cover page. The document numbers for components of this
product are:

09-3599-9, 32-4327-6

DISCLAIMER: The information in this Safety Data Sheet (SDS) is believed to be correct as of the date issued. 3M MAKES NO
WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF
MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF
TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable for user’s method of
use or application. Given the variety of factors that can affect the use and application of a 3M product, some of which are uniquely
within the user’s knowledge and control, it is essential that the user evaluate the 3M product to detennine whether it is fit for a
particular purpose and suitable for user’s method of use or application.

3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer may
have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness or accuracy.
In addition, information obtained from a database may not be as current as the information in the SDS available directly from 3M

Pagelof 2
‘1

I 3M Panel Bonding Adhesive PN 08115 09/24/15 I

3M USA SDSs are available at www.3M.com

C-,
Page2of 2
I 3MTM Panel Bonding (90 Minutes) Adhesive Part A (Accelerator) PN 08115, 38315, 58115 09/24/15 I

3M
Safety Data Sheet
Copyright,20 1 5,3M Company.
All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is
allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is obtained from
3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon.

Document Group: 09-3599-9 Version Number: 14.10


Issue Date: 09/24/15 Supercedes Date: 09/11/15

I SECTION 1: Identification
1.1. Product identifier
3MTM Panel Bonding (90 Minutes) Adhesive Part A (Accelerator) PN 08115, 38315, 58115

Product Identification Numbers


LB-K 100-0010-6

1.2. Recommended use and restrictions on use

Recommended use
Automotive, Use with Part B, MSDS 32-4327-6

1.3. Supplier’s details


MANUFACTURER: 3M
DIVISION: Automotive Aftermarket
ADDRESS: 3M Center, St. Paul, MN 55 144-1000, USA
Telephone: 1-888-3M HELPS (1-888-364-3577)

1.4. Emergency telephone number


1-800-364-3577 or (651) 737-6501 (24 hours)

I SECTION 2: Hazard identification


The label elements below were prepared in accordance with OSHA Hazard Communication Standard, 29 CFR 1910.1200.
This information may be different from the actual product label information for labels regulated by other agencies.

2.1. Hazard classification


Serious Eye Damage/Irritation: Category 1.
Skin Corrosion/Irritation: Category lB.
Skin Sensitizer: Category lB.
Reproductive Toxicity: Category I B.

2.2. Label elements


Signal word
Danger

Symbols
Corrosion Exclamation mark Health Hazard

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I 3MTM Panel Bonding (90 Minutes) Adhesive Part A (Accelerator) PN 08115, 38315, 58115 09/24/15 I

Pictograms

Hazard Statements
Causes severe skin burns and eye damage.
May cause an allergic skin reaction.
May damage fertility or the unborn child.

Precautionary Statements
General:
Keep out of reach of children.

Prevention:
Obtain special instructions before use.
Do not handle until all safety precautions have been read and understood.
Do not breathe dust/fume/gas/mist/vapors/spray.
Wear protective gloves, protective clothing, and eye/face protection.
Wash thoroughly after handling.
Contaminated work clothing must not be allowed out of the workplace.

Response:
IF INHALED: Remove person to fresh air and keep comfortable for breathing.
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower.
IF ON SKIN: Wash with plenty of soap and water.
Immediately call a POISON CENTER or doctor/physician.
If skin irritation or rash occurs: Get medical advice/attention.
Wash contaminated clothing before reuse.
IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.

Storage:
Store locked up.

Disposal:
Dispose of contents/container in accordance with applicable local/regional/national/international regulations.

2.3. Hazards not otherwise classified


May cause chemical gastrointestinal burns. Persons previously sensitized to amines may develop a cross-sensitization
reaction to certain other arnines.

36% of the mixture consists of ingredients of unknown acute oral toxicity.


37% of the mixture consists of ingredients of unknown acute dermal toxicity.

I SECTION 3: Composition/information on ingredients


Ingredient C.A.S. No. % by Wt
Polymeric Diamide 6891 1-25-1 15 40 Trade Secret *
-

Fused Silica 60676-86-0 10 30 Trade Secret *


-

Butadiene Aciylonitrile Copolymer 68683-29-4 9 30 Trade Secret *


C
-

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3MTh Panel Bonding (90 Minutes) Adhesive Part A(Accelerator) PN 08115,38315, 58115 09/24/15 -

Bis(3-Aminopropyl) Ether of Diethylene Glycol 4246-51-9 7 13 Trade Secret *


-

Tris(2,4,6-Dimethylaminomonomethyl)Phenol 90-72-2 5 10 Trade Secret *


-

Amine Epoxy Curing Agent 288-32-4 1 5 Trade Secret *


-

Dimethyl Siloxane, Reaction Product with Silica 67762-90-7 1 5 Trade Secret *


-

Inorganic Salt NJTSRN 04499600-63 17


- Trade Secret* I 5 Trade Secret *
-

Bis[(Dimethylamino)Methyl]Phenol 71074-89-0 0.1 1.5 Trade Secret


-
*

N-Aminoethylpiperazine 140-31-8 0.1 1.5 Trade Secret


-
*

Toluene 108-88-3 < 0.5 Trade Secret *

NJTS or NJTSRN: New Jersey Trade Secret Registry Number.

*The specific chemical identity andlor exact percentage (concentration) of this composition has been withheld as a trade
secret.

I SECTION 4: First aid measures


4.1. Description of first aid measures

Inhalation:
Remove person to fresh air. If you feel unwell, get medical attention.

Skin Contact:
Immediately flush with large amounts of water for at least 15 minutes. Remove contaminated clothing. Get immediate
medical attention. Wash clothing before reuse.

Eye Contact:
Immediately flush with large amounts of water for at least 15 minutes. Remove contact lenses if easy to do. Continue
rinsing. Immediately get medical attention.

If Swallowed:
Rinse mouth. Do not induce vomiting. Get immediate medical attention.

4.2. Most important symptoms and effects, both acute and delayed
See Section 11 .1. Information on toxicological effects.

4.3. Indication of any immediate medical attention and special treatment required
Not applicable

I SECTION 5: Fire-fighting measures


5.1. Suitable extinguishing media
In case of fire: Use a fire fighting agent suitable for ordinary combustible material such as water or foam to extinguish.

5.2. Special hazards arising from the substance or mixture


None inherent in this product.

Hazardous Decomposition or By-Products


Substance Condition
Carbon monoxide During Combustion
Carbon dioxide During Combustion

5.3. Special protective actions for fire-fighters


No special protective actions for fire-fighters are anticipated.

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I SECTION 6: Accidental release measures


6.1. Personal precautions, protective equipment and emergency procedures
Evacuate area. Ventilate the area with fresh air. For large spill, or spills in confined spaces, provide mechanical ventilation
to disperse or exhaust vapors, in accordance with good industrial hygiene practice. Refer to other sections of this SDS for
information regarding physical and health hazards, respiratory protection, ventilation, and personal protective equipment.

6.2. Environmental precautions


Avoid release to the environment. For larger spills, cover drains and build dikes to prevent entry into sewer systems or bodies
of water.

6.3. Methods and material for containment and cleaning up


Contain spill. Working from around the edges of the spill inward, cover with bentonite, vermiculite, or commercially
available inorganic absorbent material. Mix in sufficient absorbent until it appears dry. Remember, adding an absorbent
material does not remove a physical, health, or environmental hazard. Collect as much of the spilled material as possible.
Place in a closed container approved for transportation by appropriate authorities. Clean up residue with an appropriate
solvent selected by a qualified and authorized person. Ventilate the area with fresh air. Read and follow safety precautions on
the solvent label and SDS. Seal the container. Dispose of collected material as soon as possible.

I SECTION 7: Handling and storage


7.1. Precautions for safe handling
Do not use in a confined area with minimal air exchange. Keep out of reach of children. Do not handle until all safety
precautions have been read and understood. Do not breathe dust/fume/gas/mist/vapors/spray. Do not get in eyes, on skin, or
on clothing. Do not eat, drink or smoke when using this product. Wash thoroughly after handling. Contaminated work
clothing should not be allowed out of the workplace. Wash contaminated clothing before reuse. Avoid contact with
oxidizing agents (eg. chlorine, chromic acid etc.) Use personal protective equipment (gloves, respirators, etc.) as required.
C
7.2. Conditions for safe storage including any incompatibilities
Store away from acids. Store away from oxidizing agents.

I SECTION 8: Exposure controls/personal protection


8.1. Control parameters

Occupational exposure limits


If a component is disclosed in section 3 but does not appear in the table below, an occupational exposure limit is not available
for the component.
Ingredient C.A.S. No. Agency Limit type Additional Comments
Toluene 108-88-3 ACGIH TWA:20 ppm A4: Not class, as human
carcin
Toluene 108-88-3 CMRG STEL:75 ppm Skin Notation
Toluene 108-88-3 OSHA TWA:200 ppm;CEIL:300 ppm
SILICA, AMORPHOUS 60676-86-0 OSHA TWA concentration:0.8
rng/m3;TWA:20 millions of
particles/cu. ft.
Dimethyl Siloxane, Reaction 67762-90-7 CMRG CEIL:5 mg/m3
Product with Silica
SILICA, AMORPHOUS 67762-90-7 OSHA TWA concentration:0.8
mg/m3;TWA:20 millions of
particles/cu. ft.
Tris(2,4,6- 90-72-2 CMRG TWA:5 ppm
Dimethylaminomonomethyl)Phen
C
Page 4 of 13
I 3M
’ Panel Bonding (90 Minutes)
5 Adhesive Part A (Accelerator) PN 08115, 38315, 58115 09/24/15

Lol I I I I I
ACGIH : American Conference of Governmental Industrial Hygienists
AIHA: American Industrial Hygiene Association
CMRG: Chemical Manufactureis Recommended Guidelines
OSHA: United States Department of Labor Occupational Safety and Health Administration
TWA: Time-Weighted-Average
STEL: Short Term Exposure Limit
CElL: Ceiling

8.2. Exposure controls

8.2.1. Engineering controls


Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below relevant Exposure
Limits and/or control dustlfume/gas/mistJvapors/spray. If ventilation is not adequate, use respiratory protection equipment.

8.2.2. Personal protective equipment (PPE)

Eye/face protection

Select and use eye/face protection to prevent contact based on the results of an exposure assessment. The following eye/face
protection(s) are recommended:
Full Face Shield
Indirect Vented Goggles

Skin/hand protection
Select and use gloves and/or protective clothing approved to relevant local standards to prevent skin contact based on the
results of an exposure assessment. Selection should be based on use factors such as exposure levels, concentration of the
substance or mixture, frequency and duration, physical challenges such as temperature extremes, and other use conditions.
Consult with your glove and/or protective clothing manufacturer for selection of appropriate compatible gloves/protective
clothing. Note: Nitrile gloves may be worn over polymer laminate gloves to improve dexterity.
Gloves made from the following material(s) are recommended: Polymer laminate

If this product is used in a manner that presents a higher potential for exposure (eg. spraying, high splash potential etc.), then
use of protective coveralls may be necessary. Select and use body protection to prevent contact based on the results of an
exposure assessment. The following protective clothing material(s) are recommended: Apron polymer laminate
-

Respiratory protection

An exposure assessment may be needed to decide if a respirator is required. If a respirator is needed, use respirators as part of
a full respiratory protection program. Based on the results of the exposure assessment, select from the following respirator
type(s) to reduce inhalation exposure:
Half facepiece or full facepiece air-purifying respirator suitable for organic vapors and particulates

For questions about suitability for a specific application, consult with your respirator manufacturer.

I SECTION 9 Physical and chemical properties


9.1. Information on basic physical and chemical properties
General Physical Form: Liquid
Specific Physical Form: Viscous liquid
Odor, Color, Grade: Tan liquid, slight amine odor.
Odor threshold No Data Available
pH Not Applicable
Melting point Not Applicable
Boiling Point >1 10°C
Flash Point 110°C [Test Method: Closed Cup]
Evaporation rate <=1 [RefStd: BUOACI]

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I 3M’ Panel Bonding (90 Minutes) Adhesive Part A (Accelerator) PN 08115, 38315, 58115 09/24/15 I

Flammability (solid, gas) Not Applicable


Flammable Limits(LEL) No Data Available
Flammable Limits(UEL) No Data Available
Vapor Pressure <=200 mmHg [@ 20°C]
Vapor Density No Data Available
Density 1.2 g/ml
Specific Gravity 1.2 [RefStd: WATER= 1]
Solubility In Water No Data Available
Solubility- non-water No Data Available
Partition coefficient: n-octanol/ water No Data Available
Autoignition temperature No Data Available
Decomposition temperature No Data Available
Viscosity 100,000-225,000 centipoise [Test Method: Brookfield]
Hazardous Air Pollutants 0.01 lb HAPS/Ib solids [Test Method: Calculated]
Volatile Organic Compounds 4 gIl [Test Method: calculated SCAQMD rule 443.1]
Volatile Organic Compounds 0.4 % weight [Test Method: calculated per CARB title 2]
Percent volatile 0.4 % weight
VOC Less H20 & Exempt Solvents 4 g/l [Test Method: calculated SCAQMD rule 443.1]

I SECTION 10: Stability and reactivitv


10.1. Reactivity
This material is considered to be non reactive under normal use conditions.

10.2. Chemical stability


Stable.

10.3. Possibility of hazardous reactions


0
Hazardous polymerization will not occur.

10.4. Conditions to avoid


None known.

10.5. Incompatible materials


Strong oxidizing agents

10.6. Hazardous decomposition products


Substance Condition
None known.

Refer to section 5.2 for hazardous decomposition products during combustion.

I SECTION 11: Toxicological information


The information below may not be consistent with the material classification in Section 2 if specific ingredient
classifications are mandated by a competent authority. In addition, toxicological data on ingredients may not be
reflected in the material classification and/or the signs and symptoms of exposure, because an ingredient may be
present below the threshold for labeling, an ingredient may not be available for exposure, or the data may not be
relevant to the material as a whole.

11.1. Information on Toxicological effects

Signs and Symptoms of Exposure


C
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Based on test data and/or information on the components, this material may produce the following health effects:

Inhalation:
Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose
and throat pain.

May cause additional health effects (see below).

Skin Contact:
May be harmful in contact with skin.
Corrosive (Skin Burns): Signs/symptoms may include localized redness, swelling, itching, intense pain, blistering,
ulceration, and tissue destruction.

Allergic Skin Reaction (non-photo induced): Signs/symptoms may include redness, swelling, blistering, and itching.

Eye Contact:
Corrosive (Eye Bums): Signs/symptoms may include cloudy appearance of the cornea, chemical burns, severe pain, tearing,
ulcerations, significantly impaired vision or complete loss of vision.

Ingestion:
May be harmful if swallowed.
Gastrointestinal Corrosion: Signs/symptoms may include severe mouth, throat and abdominal pain; nausea; vomiting; and
diarrhea; blood in the feces and/or vomitus may also be seen.

May cause additional health effects (see below).

Additional Health Effects:

Reproductive/Developmental Toxicity:
Contains a chemical or chemicals which can cause birth defects or other reproductive harm.

Toxicological Data
If a component is disclosed in section 3 but does not appear in a table below, either no data are available for that endpoint or
the data are not sufficient for classification.

Acute Toxicity
Name Route Species Value
Overall product Dermal No data available; calculated ATE 2,000- 5,000
mg/kg
Overall product Ingestion No data available; calculated ATE 2,000 - 5,000
mg/kg
Fused Silica Dermal Rabbit LDSO> 5,000 mg/kg
Fused Silica Inhalation- Rat LC5O > 0.69 1 mg/I
Dust/Mist
(4 hours)
Fused Silica Ingestion Rat LD5O> 5,110 mg/kg
Butadiene Acrylonitrile Copolymer Demial Rabbit LD5O> 3,000 mg/kg
Butadiene Acrylonitrile Copolymer Ingestion Rat LD5O> 15,300 mg/kg
Bis(3-Aminopropyl) Ether of Diethylene Glycol Dermal Rabbit LD5O 2,500 mg/kg
Bis(3-Aminopropyl) Ether of Diethylene Glycol Ingestion Rat LD5O 3,160 mg/kg
Tris(2,4,6-Dimethylaminomonomethyl)Phenol Dermal Rat LD5O 1,280 mg/kg
Tria(2,4,6-Dimethylaminomonomethyl)Phenol Ingestion Rat LD5O 1,000 mg/kg
Dimethyl SiloxAne, Reaction Product with Silica Dermal Rabbit LD5O> 5,000 mg/kg
Dimethyl Siloxane, Reaction Product with Silica Inhalation- Rat LC5O >0.691 mg/I
Dust/Mist
(4 hours)
Dhnethyl Siloxane, Reaction Product with Silica Ingestion Rat LD5O >5,110 mg/kg
Amine Epoxy Curing Agent Dermal LD5O estimated to be 200- 1,000 mg/kg

Page 7 of 13
3MTM Panel Bonding (90 Minutes) Adhesive Part A (Accelerator) PN 08115, 38315, 58115 09/24/15 i

Amine Epoxy Curing Agent Ingestion Rat LD50 970 mg/kg


Inorganic Salt NJTSRN 04499600-6317
- Dermal Rat LD5O estimated to be> 5,000 mg/lcg
Inorganic Salt NJTSRN 04499600-63 17
- Ingestion Rat LD5O 9,285 mg/kg
Bis[(Dimethylamino)Methyl]Phenol Ingestion LD5O estimated to be 300- 2,000 mg/kg
N-Aminoethylpiperazine Dermal Rabbit LD5O 865 mg/kg
N-Aminoethylpiperazine Ingestion Rat LD5O 1,470 mg/kg
Toluene Dermal Rat LD5O 12,000 mg/kg
Toluene Inhalation- Rat LC5O 30 mg/I
Vapor (4
hours)
Toluene Ingestion Rat LD5O 5,550 mg/kg
ATE = acute toxicity estimate

Skin Corrosion/Irritation

Name Species Value

Overall product Rabbit Corrosive


Polymeric Diamide Rabbit Irritant
Fused Silica Rabbit No significant irritation
Bis(3-Aminopropyl) Ether of Diethylene Glycol Rabbit Corrosive
Tris(2,4,6-Dimethylsminomonomethyl)Phenol Rabbit Corrosive
Dimethyl Siloxane, Reaction Product with Silica Rabbit No significant irritation
Bis[(Dimethylamino)Methyl]Phenol similar Corrosive
compoun
da
N-Aminoethylpiperazine Rabbit Corrosive
Toluene Rabbit Irritant

Serious Eye Damage/Irritation


Name

Overall product
Species

similar
Value

Corrosive
C
health
hazards
Polymeric Diamide similar Corrosive
health
hazards
Fused Silica Rabbit No significant irritation
Bis(3-Asninopropyl) Ether of Diethylene Glycol similar Corrosive
health
hazards
Tris(2,4,6-Dimethylaminomonomethyl)Phenol Rabbit Corrosive
Dimethyl Siloxane, Reaction Product with Silica Rabbit No significant irritation
Bis[(Dimethylamino)MethyllPhenol similar Corrosive
compoun
ds
N-Aminoethylpiperazine Rabbit Corrosive
Toluene Rabbit Moderate irritant

Skin Sensitization
Name Species Value
Overall product Guinea Sensitizing
pig
Polymeric Diamide Guinea Sensitizing
pig
Fused Silica Human Not sensitizing
and
animal
Butadiene Acrylonitrile Copolymer Guinea Some positive data exist, but the data are not
pig sufficient for classification
Tris(2,4,6-Dimethylaminomonomethyl)Phenol Guinea Some positive data exist, but the data are not
pig sufficient for classification
Dimethyl Siloxane, Reaction Product with Silica Human Not sensitizing
and

Page 8 of 13
I 3M Panel Bonding (90 Minutes) Adhesive Part A (Accelerator) PN 08115. 38315. 58115 09/24/15

animal
N-Aminoethylpiperazine Guinea Senaitizing
pig
Toluene Guinea Not sensitizing
pig

Respiratory Sensitization

For the component/components, either no data are currently available or the data are not sufficient for classification.

Germ Cell Mutagenicity


Name Route Value

Fused Silica In Vitro Not mutagenic


Tris(2,4,6-Dimethylaminomonomethyl)Phenol In Vitro Not mutagenic
Dimethyl Siloxane, Reaction Product with Silica In Vitro Not mutagenic
N-Aminoethylpiperazine In vivo Not mutagenic
N-Aminoethylpiperazine In Vitro Some positive data exist, but the data are not
sufficient for classification
Toluene In Vitro Not mutagenic
Toluene In vivo Not mutagenic

Carcinogenicity
Name Route Species Value
Fused Silica Not Mouse Some positive data exist, but the data are not
Specified sufficient for classification
Dimethyl Siloxane, Reaction Product with Silica Not Mouse Some positive data exist, but the data are not
Specified sufficient for classification
Toluene Dermal Mouse Some positive data exist, but the data are not
sufficient for classification
Toluene Ingestion Rat Some positive data exist, but the data are not
sufficient for classification
Toluene Inhalation Mouse Some positive data exist, but the data are not
sufficient for classification

Reproductive Toxicity

Reproductive and/or Developmental Effects


Name Route Value Species Test Result Exposure
Duration
Fused Silica Ingestion Not toxic to female reproduction Rat NOAEL 509 1 generation
mg/kg/day
Fused Silica Inhalation Not toxic to male reproduction Rat NOAEL 497 1 generation
mg/kg/day
Fused Silica Ingestion Not toxic to development Rat NOAEL 1,350 during
mg/kg/day organogenesi

Dimethyl Siloxane, Reaction Product with Ingestion Not toxic to female reproduction Rat NOAEL 509 1 generation
Silica mg/kg/day
Dimethyl Siloxane, Reaction Product with Ingestion Not toxic to male reproduction Rat NOAEL 497 1 generation
Silica mg/kg/day
Dimethyl Siloxane, Reaction Product with Ingestion Not toxic to development Rat NOAEL 1,350 during
Silica mg/kg/dsy organogenesi

N-Aminoethylpiperazine Ingestion Not toxic to female reproduction Rat NOAEL 598 prernating &
mg/kg/day during
gestation
N-Aminoethylpiperazine Ingestion Not toxic to male reproduction Rat NOAEL 409 32 days
mg/kg/day
N-Aminoethylpiperazine Ingestion Not toxic to development Rat NOAEL 899 premating &
mg/kg/day during
gestation
Toluene Inhalation Some positive female reproductive data Human NOAEL Not occupational
exist, but the data are not sufficient for available exposure
classification

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Toluene Inhalation Some positive male reproductive data Rat NOAEL 2.3 1 generation
exist, but the data are not sufficient for mg/I
classification
Toluene Ingestion Toxic to development Rat LOAEL 520 during
mg/kg/day gestation
Toluene Inhalation Toxic to development Human NOAEL Not poisoning
available and/or abuse

Target Organ(s)

Specific Target Organ Toxicity - single exposure


Name Route Target Organ(s) Value Species Test Result Exposure
Duration
Bis(3-Aminopropyl) Ether Inhalation respiratory irritation Some positive data exist, but the NOAEL Not
of Diethylene Glycol data are not sufficient for available
classification
Tris(2,4,6- Inhalation respiratory irritation Some positive data exist, but the NOAEL Not
Dimethylaminomonomethy data are not sufficient for available
l)Phenol classification
N-Aminoethylpiperazine Inhalation respiratory irritation Some positive data exist, but the NOAEL Not
data are not sufficient for available
classification
Toluene Inhalation central nervous May cause drowsiness or Human NOAEL Not
system depression dizziness available
Toluene Inhalation respiratory irritation Some positive data exist, but the Human NOAEL Not
data are not sufficient for available
classification
Toluene Inhalation immune system Some positive data exist, but the Mouse NOAEL 3 hours
data are not sufficient for 0.004 mg/I
classification
Toluene Ingestion central nervous May cause drowsiness or Human NOAEL Not poisoning
system depression dizziness available and/or abuse

Specific Target Organ Toxicity - repeated exposure


Name Route Target Organ(s) Value Species Test Result Exposure
Duration
Fused Silica Inhalation respiratory system I All data are negative Human NOAEL Not occupational
silicosis available exposure
Tris(2,4,6- Dermal skin I liver I nervous Some positive data exist, but the Rat NOAEL 125 28 days
Dimethylaminomonomethy system data are not sufficient for mg/kg/day
l)Phenol classification
Tris(2,4,6- Dermsl auditory system I All data are negative Rat NOAEL 125 28 days
Dimethylaminomonomethy hematopoietic mg/kg/day
1)Phenol system I eyes
Dimethyl Siloxane, Inhalation respiratory system I All data are negative Human NOAEL Not occupational
Reaction Product with silicosis available exposure
Silica
N-Aminoethylpiperazine Ingestion heart I endocrine All data are negative Rat NOAEL 598 28 days
system I mg/kg/day
hematopoietic
system liver
nervous System I
kidney and/or
bladder
Toluene Inhalation auditory system Causes damage to organs through Human NOAEL Not poisoning
nervous system I prolonged or repeated exposure available and/or abuse
eyes I olfactory
system
Toluene Inhalation respiratory system Some positive data exist, but the Rat LOAEL 2.3 15 months
data are not sufficient for mg/I
classification
Toluene Inhalation heart I liver I kidney Some positive data exist, but the Rat NOAEL 11.3 15 weeks
and/or bladder data are not sufficient for mg/I
classification
Toluene Inhalation endocrine system Some positive data exist, but the Rat NOAEL 1.1 4 weeks
data are not sufficient for mg/I
classification

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Toluene Inhalation immune system Some positive data exist, but the Mouse NOAEL Not 20 days
data are not sufficient for available
classification
Toluene Inhalation bone, teeth, nails, Some positive data exist, but the Mouse NOAEL 1.1 8 weeks
and/or hair data are not sufficient for mg/I
classification
Toluene Inhalation hematopoietic Some positive data exist, but the Human NOAEL Not occupational
system I vascular data are not sufficient for available exposure
system classification
Toluene Ingestion nervous system Some positive data exist, but the Rat NOAEL 625 13 weeks
data are not sufficient for mg/kg/day
classification
Toluene Ingestion heart Some positive data exist, but the Rat NOAEL 13 weeks
data are not sufficient for 2,500
classification mg/kg/day
Toluene Ingestion liver I kidney and/or Some positive data exist, but the Multiple NOAEL 13 weeks
bladder data are not sufficient for animal 2,500
classification species mg/kg/day
Toluene Ingestion hematopoietic Some positive data exist, but the Mouse NOAEL 600 14 days
system data are not sufficient for mg/kg/day
classification
Toluene Ingestion endocrine system Some positive data exist, but the Mouse NOAEL 105 28 days
data are not sufficient for mg/kg/day
classification
Toluene Ingestion immune system Some positive data exist, but the Mouse NOAEL 105 4 weeks
dala are not sufficient for mg/kg/day
classification

Aspiration Hazard
Name Value
Toluene Aspiration hazard

Please contact the address or phone number listed on the first page of the SDS for additional toxicological information
on this material and/or its components.

I SECTION 12 Ecological information

Ecotoxicological information

Please contact the address or phone number listed on the first page of the SDS for additional ecotoxicological information on this material
and/or its components.
Chemical fate information

Please contact the address or phone number listed on the first page of the SDS for additional chemical fate information on this material
and/or its components,

I SECTION 13: Disposal considerations

13.1. Disposal methods


Dispose of contents! container in accordance with the local/regional/national/international regulations.

Dispose of completely cured (or polymerized) material in a permitted industrial waste facility. As a disposal alternative,
incinerate uncured product in a permitted waste incineration facility. Proper destruction may require the use of additional fuel
during incineration processes. Empty drums/barrels/containers used for transporting and handling hazardous chemicals
(chemical substances/mixtures/preparations classified as [-lazardous as per applicable regulations) shall be considered, stored,
treated & disposed of as hazardous wastes unless otherwise defined by applicable waste regulations. Consult with the
respective regulating authorities to determine the available treatment and disposal facilities.

SECTION 14: Transport Information

Page 11 of 13
I 3MTM Panel Bonding (90 Minutes) Adhesive Part A (Accelerator) PN 08115, 38315, 58115 09/24/15

For Transport Information, please visit http://3M.com/Transportinfo or call 1-800-364-3577 or 651-737-6501. j

I SECTION 15: Reu1atory information 1


15.1. US Federal Regulations
Contact 3M for more information.

311/312 Hazard Categories:

Fire Hazard No
- Pressure Hazard No
- Reactivity Hazard No - Immediate Hazard Yes - Delayed Hazard Yes
-

Section 313 Toxic Chemicals subject to the reporting requirements of that section and 40 CFR part 372 (EPCRA):

Ingredient C.A.S. No % by Wt
Inorganic Salt NJTSRN 04499600-63 17
- Trade Secret 1 5
-

(NITRATE COMPOUNDS (WATER


DISSOCIABLE; REPORTABLE ONLY WHEN
IN AQUEOUS SOLUTION))

15.2. State Regulations


Contact 3M for more information.

California Proposition 65

Enredient
Benzene
Benzene
C.A.S. No.
71-43-2
71-43-2
Classification
Male reproductive toxin
Carcinogen
0
Benzene 71-43-2 Developmental Toxin
Toluene 108-88-3 Female reproductive toxin
Toluene 108-88-3 Developmental Toxin

WARNING: This product contains a chemical known to the State of California to cause birth defects or other reproductive
harm.
WARNING: This product contains a chemical known to the State of California to cause cancer.

15.3. Chemical Inventories


The components of this product are in compliance with the chemical notification requirements of TSCA.

Contact 3M for more information.

15.4. International Regulations


Contact 3M for more information.

I This SDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200. I
I SECTION 16: Other information
NFPA Hazard Classification
Health: 3 Flammability: I Instability: 0 Special Hazards: None

National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address
the hazards that are presented by short-term, acute exposure to a material under conditions of fire, spill, or similar

Page 12 of 13
I 3MTM Panel Bonding (90 Minutes) Adhesive Part A (Accelerator) PN 08115, 38315, 58115 09/24/15 I

emergencies. Hazard ratings are primarily based on the inherent physical and toxic properties of the material but also include
the toxic properties of combustion or decomposition products that are known to be generated in significant quantities.

Document Group: 09-3599-9 Version Number: 14.10


Issue Date: 09/24/15 Supercedes Date: 09/11/15

DISCLAIMER: The information in this Safety Data Sheet (SDS) is believed to be correct as of the date issued. 3M MAKES
NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY
OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR
USAGE OF TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable
for user’s method of use or application. Given the variety of factors that can affect the use and application of a 3M product,
some of which are uniquely within the user’s knowledge and control, it is essential that the user evaluate the 3M product to
determine whether it is fit for a particular purpose and suitable for use?s method of use or application.

3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer
may have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness
or accuracy. In addition, information obtained from a database may not be as current as the information in the SDS available
directly from 3M

3M USA SDSs are available at www.3M.com

Page 13 of 13
I 3M Panel Bonding Adhesive Part B PNs 08115, 38315, 58115 09/23/15 I

3M
Safety Data Sheet
Copyright,201 5,3M Company.
All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is
allowed provided that: (I) the information is copied in full with no changes unless prior written agreement is obtained from
3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon.

Document Group: 32-4327-6 Version Number: 1.01


Issue Date: 09/23/15 Supercedes Date: 11/24/14

I SECTION 1: Identification
1.1. Product identifier
3MTM Panel Bonding Adhesive Part B PNs 08115, 38315, 58115

1.2. Recommended use and restrictions on use

Recommended use
Automotive, Structural Panel Bonding Adhesive

1.3. Supplier’s details


MANUFACTURER: 3M
DIVISION: Automotive Aftermarket
ADDRESS: 3M Center, St. Paul, MN 55 144-1000, USA
Telephone: 1-888-3M HELPS (1-888-364-3577)

1.4. Emergency telephone number


1-800-364-3577 or (651) 737-6501 (24 hours)

I SECTION 2: Hazard identification


The label elements below were prepared in accordance with OSHA Hazard Communication Standard, 29 CFR 1910.1200.
This infoniiation may be different from the actual product label information for labels regulated by other agencies.

2.1. Hazard classification


Serious Eye Damage/Irritation: Category 2A.
Skin Sensitizer: Category 1.
Carcinogenicity: Category 2.

2.2. Label elements


Signal word
Warning

Symbols
Exclamation mark Health Hazard

Pictograms

C
Page 1 of 13
I 3M Panel Bonding Adhesive Part B PNs 08115, 38315, 58115 09/23/15

Hazard Statements
Causes serious eye irritation.
May cause an allergic skin reaction.
Suspected of causing cancer.

Precautionary Statements
General:
Keep out of reach of children.

Prevention:
Obtain special instructions before use.
Do not handle until all safety precautions have been read and understood.
Avoid breathing dust/fume/gas/mist/vapors/spray.
Wear protective gloves and eye/face protection.
Wash thoroughly after handling.
Contaminated work clothing must not be allowed out of the workplace.

Response:
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
If eye irritation persists: Get medical advice/attention.
IF ON SKIN: Wash with plenty of soap and water.
If skin irritation or rash occurs: Get medical advice/attention.
Wash contaminated clothing before reuse.
IF exposed or concerned: Get medical advice/attention.

Storage:
Store locked up.

Disposal:
Dispose of contents/container in accordance with applicable local/regional/national/international regulations.

2.3. Hazards not otherwise classified


None.

34% of the mixture consists of ingredients of unknown acute inhalation toxicity.

I SECTION 3: Composition/information on ingredients


Ingredient C.A.S. No. % by Wt
4,4-Isopropylidenediphenol-Epichiorohydrin Polymer 25068-38-6 30 60 Trade Secret *
-

Oxide Glass Chemicals 65997-17-3 10- 30 Trade Secret *


Fused Silica 60676-86-0 7 13 Trade Secret *
-

l,4-Bis[(2,3-Epoxypropoxy)MethyljCyclohexane 14228-73-0 7 13 Trade Secret *


-

Acrylate Polymer Trade Secret* 5 10 Trade Secret *


-

Silica 7631 -8 6-9 1 5 Trade Secret *


-

3-(Trimethoxysilyl)propyl Glycidyl Ether 2530-83-8 0.5 1.5 Trade Secret *


-

Dimethyl Siloxane, Reaction Product With Silica 67762-90-7 0.5 1.5 Trade Secret *
-

Carbon Black 1333-86-4 < 0.5 Trade Secret *

Page 2 of 13
I 3M Panel Bonding Adhesive Part B PNs 08115, 38315, 58115 09/23/15

lEpichiorohydrin *
1106-89-8 1<0.02 Trade Secret

*The specific chemical identity and/or exact percentage (concentration) of this composition has been withheld as a trade
secret.

I SECTION 4: First aid measures


4.1. Description of first aid measures

Inhalation:
Remove person to fresh air. If you feel unwell, get medical attention.

Skin Contact:
Immediately wash with soap and water. Remove contaminated clothing and wash before reuse. If signs/symptoms develop,
get medical attention.

Eye Contact:
Immediately flush with large amounts of water. Remove contact lenses if easy to do. Continue rinsing. Get medical
attention.

If Swallowed:
Rinse mouth. If you feel unwell, get medical attention.

4.2. Most important symptoms and effects, both acute and delayed
See Section 11.1. Information on toxicological effects.

4.3. Indication of any immediate medical attention and special treatment required
Not applicable

I SECTION 5: Fire-fighting measures


5.1. Suitable extinguishing media
In case of fire: Use a fire fighting agent suitable for ordinary combustible material such as water or foam to extinguish.

5.2. Special hazards arising from the substance or mixture


None inherent in this product.

5.3. Special protective actions for fire-fighters


No special protective actions for fire-fighters are anticipated.

I SECTION 6: Accidental release measures


6.1. Personal precautions, protective equipment and emergency procedures
Evacuate area. Ventilate the area with fresh air. For large spill, or spills in confined spaces, provide mechanical ventilation
to disperse or exhaust vapors, in accordance with good industrial hygiene practice. Refer to other sections of this SDS for
information regarding physical and health hazards, respiratory protection, ventilation, and personal protective equipment.

6.2. Environmental precautions


Avoid release to the environment. For larger spills, cover drains and build dikes to prevent entry into sewer systems or bodies
of water.

6.3. Methods and material for containment and cleaning up


Contain spill. Working from around the edges of the spill inward, cover with bentonite, vermiculite, or commercially
available inorganic absorbent material. Mix in sufficient absorbent until it appears dry. Remember, adding an absorbent

Page 3 of 13
3M’ Panel Bonding Adhes lye Part B PNs 08115, 38315, 58115 09/23/15

material does not remove a physical, health, or environmental hazard. Collect as much of the spilled material as possible.
Place in a closed container approved for transportation by appropriate authorities. Clean up residue with an appropriate
solvent selected by a qualified and authorized person. Ventilate the area with fresh air. Read and follow safety precautions on
the solvent label and SDS. Seal the container. Dispose of collected material as soon as possible.

I SECTION 7: Handling and storage


7.1. Precautions for safe handling
Keep out of reach of children. Do not handle until all safety precautions have been read and understood. Avoid breathing
dust/fume/gas/mist/vapors/spray. Do not get in eyes, on skin, or on clothing. Do not eat, drink or smoke when using this
product. Wash thoroughly after handling. Contaminated work clothing should not be allowed out of the workplace. Avoid
release to the environment. Wash contaminated clothing before reuse. Avoid contact with oxidizing agents (eg. chlorine,
chromic acid etc.) Use personal protective equipment (gloves, respirators, etc.) as required.

7.2. Conditions for safe storage including any incompatibilities


Store away from acids. Store away from strong bases. Store away from oxidizing agents. Store away from amines.

I SECTION 8: Exposure controls/personal protection


8.1. Control parameters

Occupational exposure limits


If a component is disclosed in section 3 but does not appear in the table below, an occupational exposure limit is not available
for the component.
Ingredient C.A.S. No. Agency Limit type Additional Comments
Epichlorohydrin 106-89-8 ACGIH TWA:0.5 ppm A3: Confirmed animal
carcin., Skin Notation
Epichlorohydrin 106-89-8 OSHA TWA:19 mg/m3(5 ppm) Skin Notation
Carbon Black 1333-86-4 ACGIH TWA(inhalable fraction):3 A3: Confirmed animal
mg/m3 carcin.
Carbon Black 1333-86-4 CMRG TWA:0.5 mg/m3
Carbon Black 1333-86-4 OSHA TWA:3.5 mg/m3
3-(Trimethoxysilyl)propyl 2530-83-8 CMRG TWA:5 ppm
Glycidyl Ether
SILICA, AMORPHOUS 60676-86-0 OSHA TWA concentration:0.8
mg/m3;TWA:20 millions of
particles/cu. ft.
Oxide Glass Chemicals 65997-17-3 Manufacturer TWA(as dust):lO mg/m3
determined
Dimethyl Siloxane, Reaction 67762-90-7 CMRG CEIL:5 mg/m3
Product With Silica
SILICA, AMORPHOUS 67762-90-7 OSHA TWA concentration:0.8
mg/rn3;TWA:20 millions of
particles/cu. ft.
Silica 763 1-86-9 CMRG TWA(as respirable dust):3
mg/m3
SILICA, AMORPHOUS 763 1-86-9 OSHA TWA concentration:0.8
mg/m3;TWA:20 millions of
particles/cu. ft.
ACGIH: American Conference of Governmental Industrial Hygienists
AIHA : American Industrial Hygiene Association
CMRG: Chemical Manufacture?s Recommended Guidelines
OSHA: United States Department of Labor Occupational Safety and Health Administration
-

TWA: Time-Weighted-Average
STEL: Short Term Exposure Limit

Page 4 of 13
I 3M’ Panel Bonding Adhesive Part B PNs 08115,38315, 58115 09/23/15

CElL: Ceiling

8.2. Exposure controls

8.2.1. Engineering controls


Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below relevant Exposure
Limits and/or control dust/fume/gas/mist/vapors/spray. If ventilation is not adequate, use respiratory protection equipment.

8.2.2. Personal protective equipment (PPE)

Eye/face protection

Select and use eye/face protection to prevent contact based on the results of an exposure assessment. The following eye/face
protection(s) are recommended:
Indirect Vented Goggles

Skin/hand protection
Select and use gloves and/or protective clothing approved to relevant local standards to prevent skin contact based on the
results of an exposure assessment. Selection should be based on use factors such as exposure levels, concentration of the
substance or mixture, frequency and duration, physical challenges such as temperature extremes, and other use conditions.
Consult with your glove and/or protective clothing manufacturer for selection of appropriate compatible gloves/protective
clothing. Note: Nitrile gloves may be worn over polymer laminate gloves to improve dexterity.
Gloves made from the following material(s) are recommended: Polymer laminate

If this product is used in a manner that presents a higher potential for exposure (eg. spraying, high splash potential etc.), then
use of protective coveralls may be necessary. Select and use body protection to prevent contact based on the results of an
exposure assessment. The following protective clothing material(s) are recommended: Apron polymer laminate
-

Respiratory protection

An exposure assessment may be needed to decide if a respirator is required. If a respirator is needed, use respirators as part of
a full respiratory protection program. Based on the results of the exposure assessment, select from the following respirator
type(s) to reduce inhalation exposure:
Half facepiece or full facepiece air-purifying respirator suitable for organic vapors and particulates

For questions about suitability for a specific application, consult with your respirator manufacturer.

I SECTION 9: Physical and chemical properties


9.1. Information on basic physical and chemical properties
General Physical Form: Liquid
Odor, Color, Grade: Black, Viscous Liquid.
Odor threshold No Data A vailable
pH No Data Available
Melting point No Data Available
Boiling Point > 95 °F
Flash Point > 220 °F [Test Method: Closed Cup]
Evaporation rate <= I Units not avail, or not appl. [RefStd: BUOAC=lj
Flammability (solid, gas) Not Applicable
Flammable Limits(LEL) No Data A vailable
Flammable Limits(UEL) No Data A vailable
Vapor Pressure < 27 psia
Vapor Pressure No Data Available
Vapor Density No Data Available
Density 10.014 lb/gal
Specific Gravity 1.2 [RefStd: WATER=l]

Page 5 of 13
I 3M’ Panel Bonding Adhesive Part B PNs 08115, 38315, 58115 09/23/15

Solubility in Water Negligible


Solubility- non-water No Data Available
Partition coefficient: n-octanoll water No Data Available
Autoignition temperature No Data Available
Decomposition temperature No Data Available
Viscosity 100,000 centipoise -225,000 centipoise [Test Method:
Brookfield]
Hazardous Air Pollutants 0.00162 lb RAPS/gal
Volatile Organic Compounds 15 g/l [Test Method: calculated SCAQMD rule 443.1]
Volatile Organic Compounds 1.6 % weight [Test Method: calculated per CARB title 2]
Percent volatile 1.6% weight
VOC Less 1120 & Exempt Solvents 15 g/l [Test Method: calculated SCAQMD rule 443.1]

I SECTION 10: Stability and reactivity


10.1. Reactivity
This material may be reactive with certain agents under certain conditions see the remaining headings in this section.
-

10.2. Chemical stability


Stable.

10.3. Possibility of hazardous reactions


Hazardous polymerization will not occur.

10.4. Conditions to avoid


Sparks and/or flames

10.5. Incompatible materials


Amines
Strong acids
Strong bases
Strong oxidizing agents

10.6. Hazardous decomposition products


Substance Condition
Aldehydes Not Specified
Carbon monoxide Not Specified
Carbon dioxide Not Specified

I SECTION 11: Toxicological information


The information below may not be consistent with the material classification in Section 2 if specific ingredient
classifications are mandated by a competent authority. In addition, toxicological data on ingredients may not be
reflected in the material classification and/or the signs and symptoms of exposure, because an ingredient may be
present below the threshold for labeling, an ingredient may not be available for exposure, or the data may not be
relevant to the material as a whole.

11.1. Information on Toxicological effects

Signs and Symptoms of Exposure

Based on test data andlor information on the components, this material may produce the following health effects:

Page 6 of 13
4

I 3M’ Panel Bonding Adhesive Part B PNs 08115, 38315, 58115 09/23/15

Inhalation:
Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose
and throat pain.

May cause additional health effects (see below).

Skin Contact:
Mild Skin Irritation: Signs/symptoms may include localized redness, swelling, itching, and dryness. Allergic Skin Reaction
(non-photo induced): Signs/symptoms may include redness, swelling, blistering, and itching.

Eye Contact:
Severe Eye Irritation: Signs/symptoms may include significant redness, swelling, pain, tearing, cloudy appearance of the
cornea, and impaired vision.

Ingestion:
Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhea.

Additional Health Effects:

Carcinogenicity:
Contains a chemical or chemicals which can cause cancer.

Ineredient CAS No. Class Description Reeulation


Generic: GLASS FILAMENTS 65997-1 7-3 Anticipated human carcinogen National Toxicology Program Carcinogens
Carbon Black 1333-86-4 Grp. 2B: Possible human care. International Agency for Research on Cancer
Epichlorohydrin 106.89-8 Grp. 2A: Probable human care. International Agency for Research on Cancer
Epichlorohydrin 1 06-89-8 Anticipated human carcinogen National Toxicology Program Carcinogens

Toxicological Data
If a component is disclosed in section 3 but does not appear in a table below, either no data are available for that endpoint or
the data are not sufficient for classification.

Acute Toxicity
Name Route Species Value
Overall product Dermal No data available; calculated ATE> 5,000 mg/kg
Overall product Inhalation- No data available; calculated ATE> 12.5 mg/I
DustlMist(4
hr)
Overall product Ingestion No data available; calculated ATE> 5,000 mg/kg
4,4’-Tsopropylidenediphenol-Epichlorohydrin Polymer Dermal Rat LD5O> 1,600 mg/kg
4,4-Isopropylidenediphenol-Epichlorohydrin Polymer Ingestion Rat LD5O> 1,000 mg/kg
Oxide Glass Chemicals Dermal LD5O estimated to be> 5,000 mg/kg
Oxide Glass Chemicals Ingestion LD5O estimated to be 2,000- 5,000 mg/kg
l,4-Bis[(2,3-Epoxypropoxy)MethyllCyclohexane Dermal Rabbit LD5O 2,500 mg/kg
Fused Silica Dermal Rabbit LD5O> 5,000 mg/kg
1,4-Bis[(2,3-Epoxypropoxy)Methyl]Cyclohexane Ingestion Rat LD5O 2,450 mg/kg
Fused Silica Inhalation- Rat LC5O > 0.691 mg/I
Dust/Mist
(4 hours)
Fused Silica Ingestion Rat LD5O >5,110 mg/kg
Acrylate Polymer Dermal Rabbit LD5O> 5,000 mg/kg
Acrylate Polymer Ingestion Rat LD5O> 5,000 mg/kg
Silica Dermal Rabbit LD5O> 5,000 mg/kg
Silica Inhalation- Rat LC5O > 0.691 mg/I
Dust/Mist
(4 hours)
Silica Ingestion Rat LD5O> 5,110 mg/kg
3-(Trimethoxysilyl)propyl Glycidyl Ether Dermsl Rabbit LD5O 4,000 mg/kg
3-(Trimethoxysilyl)propyl Glycidyl Ether Inhalation- Rat LC5O> 5.3 mg/I
Dust/Mist

Page 7 of 13
I 3M”’ Panel Bonding Adhesive Part B PNsO8I15,38315, 58115 09/23/15

(4 hours)

3-(Trimethoxysilyl)propyl Glycidyl Ether Ingestion Rat LD5O 7,010 mg/kg

Dimethyl Siloxane, Reaction Product With Silica Dermal Rabbit LD50> 5,000 mg/kg

Dimethyl Siloxane, Reaction Product With Silica Inhalation- Rat LC5O > 0.691 mg/I

Dust/Mist

(4 hours)

Dimethyl Siloxane, Reaction Product With Silica Ingestion Rat LD5O> 5,110 mg/kg
Carbon Black Dermal Rabbit LD50> 3,000 mg/kg
Carbon Black Ingestion Rat LD5O> 8,000 mg/kg

Epichiorohydrin Dermal Rabbit LD5O 755 mg/kg

Epichiorohydrin Inhalation- Rat LC5O 1.7 mg/I

Vapor (4
hours)

Epichlorohydrin Ingestion Rat LD5O 260 mg/kg


ATE = acute toxicity estimate

Skin Corrosion/Irritation

Name Species Value

4,4’-Isopropylidenediphenol-Epichlorohydrin Polymer Rabbit Mild irritant

Oxide Glass Chemicals Professio No significant irritation


nal
judgeme
nt
I ,4-Bia[(2,3-Epoxypropoxy)MethyllCyclohexane Professio Mild irritant
nal

judgeme

nt

Fused Silica Rabbit No significant irritation


Acrylate Polymer Profeaaio Minimal irritation
nal
judgeme
nt

Silica Rabbit No significant irritation


3-(Trimethoxysilyl)propyl Glycidyl Ether Rabbit Mild irritant
Dimethyl Siloxane, Reaction Product With Silica Rabbit No significant irritation
Carbon Black Rabbit No significant irritation
Epichlorohydrin Human Corrosive
and
animal

Serious Eye Damage/Irritation


Name Species Value

4,4’-Isopropylidenediphenol-Epichlorohydrin Polymer Rabbit Moderate irritant

Oxide Glass Chemicals Professio No significant irritation

nal

judgeme

nt

I ,4-Bis[(2,3-Epoxypropoxy)Methyl}Cyclohexane Profesaio Mild irritant


nal
judgeme
nt
Fused Silica Rabbit No significant irritation
Aciylate Polymer Professio Mild irritant
nal
judgeme
nt
Silica Rabbit No significant irritation
3-(Trimethoxysilyl)propyl Glycidyl Ether Rabbit Corrosive
Dimethyl Siloxane, Reaction Product With Silica Rabbit No significant irritation
Carbon Black Rabbit No significant irritation
Epichlorohydrin Rabbit Corrosive

Skin Sensitization

Page 8 of 13
I 3MTM Panel Bonding Adhesive Part B PNs 08115, 38315, 58115 09/23/15

Name Species Value


4,4’-Isopropylidenediphenol-Epichlorohydrin Polymer Human Sensitizing
and
animal
l,4-Bis[(2,3-Epoxypropoxy)Methyl)Cyclohexsne similar Sensitizing
compoun
ds
Fused Silica Human Not sensitizing
and
animal
Silica Human Not sensitizing
and
animal
3-(Trimethoxysilyl)propyl Glycidyl Ether Guinea Some positive data exist, but the data are not
pig sufficient for clsssification
Dimethyl Siloxane, Reaction Product With Silica Human Not sensitizing
and
animal
Epichlorohydrin Human Sensitizing
and
animal

Respiratory Sensitization
Name Species Value

4,4’-Isopropylidenediphenol-Epichlorohydrin Polymer Human Some positive data exist, but the data are not
sufficient for classification

Germ Cell Mutagenicity


Name Route Value

4,4’-Isopropylidenediphenol-Epichlorohydrin Polymer In vivo Not mutagenic


4,4’-Isopropylidenediphenol-Epichlorohydrin Polymer In Vitro Some positive data exist, but the data are not
sufficient for classification
Oxide Glass Chemicals In Vitro Some positive dsta exist, but the data are not
sufficient for classification
Fused Silica In Vitro Not mutsgenic
Silica In Vitro Not mutagenic
3-(Trimethoxysilyl)propyl Glycidyl Ether In vivo Not mutsgenic
3-(Trimethoxysilyl)propyl Glycidyl Ether In Vitro Some positive data exist, but the data are not
sufficient for classification
Dimethyl Siloxane, Reaction Product With Silica In Vitro Not mutagenic
Carbon Black In Vitro Not mutagenic
Carbon Black In vivo Some positive data exist, but the data are ot
sufficient for classification
Epichlorohydrin In Vitro Some positive data exist, but the data are not
sufficient for classification
Epichlorohydrin In vivo Mutagenic

Carcinogenicity
Name Route Species Value
4,4’-Isopropylidenediphenol-Epichlorohyds-in Polymer Dermsl Mouse Some positive data exist, but the data are not
sufficient for classification
Oxide Glass Chemicals Inhalation Multiple Some positive data exist, but the data are not
animsi sufficient for classification
species
Fused Silica Not Mouse Some positive data exist, but the data are not
Specified sufficient for classification
Silica Not Mouse Some positive data exist, but the data are not
Specified sufficient for classification
3-(Trimethoxysilyl)propyl Glycidyl Ether Dermal Mouse Not carcinogenic
Dimethyl Siloxane, Reaction Product With Silica Not Mouse Some positive data exist, but the data are not
Specified sufficient for classification
Carbon Black Dermsl Mouse Not carcinogenic
Carbon Black Ingestion Mouse Not carcinogenic
C.,
Page 9 of 13
I 3M Panel Bonding Adhesive Part B PNs 08115, 38315, 58115 09/23/15

Carbon Black Inhalation Rat Carcinogenic


Epichlorohydrin Dermal Mouse Not carcinogenic
Epichiorohydrin Ingestion Rat Carcinogenic
Epichlorohydrin Inhalation Rat Carcinogenic

Reproductive Toxicity

Reproductive and/or Developmental Effects


Name Route Value Species Test Result Exposure
Duration
4,4’-lsopropylidenediphenol- Ingestion Not toxic to female reproduction Rat NOAEL 750 2 generation
Epichlorohydrin Polymer mg/kg/day
4,4’-Isopropylidenediphenol- Ingestion Not toxic to male reproduction Rat NOAEL 750 2 generation
Epichlorohydrin Polymer mg/kg/day
4,4’-lsopropylidenediphenol- Dermal Not toxic to development Rabbit NOAEL 300 during
Epichlorohydrin Polymer mg/kg/day organogenesi

4,4-Isopropytidenediphenol- Ingestion Not toxic to development Rat NOAEL 750 2 generation


Epichlorohydrin Polymer mg/kg/day
Fused Silica Ingestion Not toxic to female reproduction Rat NOAEL 509 1 generation
mg/kg/day
Fused Silica Inhalation Not toxic to male reproduction Rat NOAEL 497 1 generation
mg/kg/day
Fused Silica Ingestion Not toxic to development Rat NOAEL 1,350 during
mg/kg/day organogeneai

Silica Ingestion Not toxic to female reproduction Rat NOAEL 509 1 generation
mg/kg/day
Silica Ingestion Not toxic to male reproduction Rat NOAEL 497 1 generation
mg/kg/day
Silica Ingestion Not toxic to development Rat NOAEL 1,350 during
mg/kg/day organogenesi

3-(Trimethoxyailyl)propyl Glycidyl Ether Ingestion Not toxic to female reproduction Rat NOAEL 1,000 1 generation
mg/kg/day
3-(Trimethoxyailyl)propyl Glycidyl Ether Ingestion Not toxic to male reproduction Rat NOAEL 1,000 1 generation
mg/kg/day
3-(Trimethoxyailyl)propyl Glycidyl Ether Ingestion Some positive developmental data exist, Rat NOAEL 3,000 during
but the data are not sufficient for mg/kg/day organogenesi
classification a
Dimethyl Siloxane, Reaction Product With Ingestion Not toxic to female reproduction Rat NOAEL 509 1 generation
Silica mg/kg/day
Dimeihyl Siloxane, Reaction Product With Ingestion Not toxic to male reproduction Rat NOAEL 497 1 generation
Silica mg/kg/day
Dimethyl Siloxane, Reaction Product With Ingestion Not toxic to development Rat NOAEL 1,350 during
Silica mg/kg/day organogeneai

Epichlorohydrin Inhalation Not toxic to female reproduction Rat NOAEL 0.2 10 weeks
mg/I
Epichlorohydrin Inhalation Not toxic to development Multiple NOAEL 0.09 during
animal mg/I organogeneai
species a
Epichlorohydrin Ingestion Some positive developmental data exist, Multiple NOAEL 160 during
but the data are not sufficient for animal mg/kg/day gestation
classification species
Epichlorohydrin Ingestion Toxic to male reproduction Rat LOAEL 6.25 23 days
mg/kg/day
Epichtorohydrin Inhalation Toxic to male reproduction Rat NOAEL 0.02 10 weeks
mg/I

Target Organ(s)

Specific Target Organ Toxicity - single exposure


Name Route Target Organ(s) Value Species Test Result Exposure
Duration

Page 10 of 13
I 3MTM Panel Bonding Adhesive Part B PNs 08115, 38315, 58115 09/23/15 I C
I ,4-Bis[(2,3- Inhalation respiratory irritation Some positive data exist, but the NOAEL Not
Epoxypropoxy)MethyljCyc data are not sufficient for available
lohexane classification
Epichlorohydrin Inhalation respiratory irritation May cause respiratory irritation Human NOAEL not occupational
___________________ available exposure
Epichlorohydrin Inhalation liver Some positive data exist, but the Human NOAEL not occupational
data are not sufficient for available exposure
classification

Specific Target Organ Toxicity repeated exposure


-

Name Route Target Organ(s) Value Species Test Result Exposure


Duration

4,4’- Dermal liver Some positive data exist, but the Rat NOAEL 2 years
Isopropylidenediphenol- data are not sufficient for 1,000
Epichlorohydrin Polymer classification mg/kg/day
4,4’- Dermal nervous system All data are negative Rat NOAEL 13 weeks
Isopropylidenediphenol- 1,000
Epichlorohydrin Polymer mg/kg/day
4,4’- Ingestion auditory system I All data are negative Rat NOAEL 28 days
Isopropylidenediphenol- heart I endocrine 1,000
Epichlorohydrin Polymer system mg/kg/day
hematopoietic
system I liver I eyes I
kidney and/or
bladder
Oxide Glass Chemicals Inhalation respiratory system Some positive data exist, but the Human NOAEL not occupational
data are not sufficient for available exposure
classification
Fused Silica Inhalation respiratory system I All data are negative Human NOAEL Not occupational
silicosis available exposure
Silica Inhalation respiratory system I All data are negative Human NOAEL Not occupational
silicosis available exposure
3-(Trimelhoxysilyl)propyl Ingestion heart I endocrine All data are negative Rat NOAEL 28 days
Glycidyl Ether system I bone, teeth, 1,000
nails, and/or hair I mg/kg/day
hematopoietic
system I liver I
immune system I
nervous system I
kidney and/or
bladder I respiratory
system
Dimethyl Siloxane, Inhalation respiratory system I All data are negative Human NOAEL Not occupational
Reaction Product With silicosis available exposure
Silica
Carbon Black Inhalation pneumoconiosis Some positive data exist, but the Human NOAEL Not occupational
data are not sufficient for available exposure
classification
Epichiorohydrin Inhslation liver Causes damage to organs through Rat NOAEL 0.21 19 days
prolonged or repeated exposure mg/I
Epichlorohydrin Inhalation kidney and/or May cause damage to organs Rat NOAEL 0.04 136 weeks
bladder though prolonged or repeated mg/I
exposure
Epichlorohydrin Inhalation endocrine system Some positive data exist, but the Rat NOAEL 4 weeks
data are not sufficient for 0.377 mg/I
classification
Epichlorohydrin Inhalation immune system Some positive data exist, but the Rat LOAEL 4 weeks
data are not sufficient for 0.21 1 mg/I
classification
Epichlorohydrin Inhalation heart Some positive data exist, but the Rat NOAEL 0.02 98 days
data are not sufficient for mg/I
classification
Epichlorohydrin Inhalation nervous system Some positive data exist, but the Rat NOAEL 98 days
data are not sufficient for 0.002 mg/I
classification
Epichlorohydrin Inhalation respiratory system Some positive data exist, but the Multiple NOAEL 0.02 13 weeks
data are not sufficient for animal mg/I
classification species
C
Page 11 of 13
I 3lI’ Panel Bonding Adhesive Part B PNs 08115, 38315, 58115 09/23/15 I

Epichlorohydrin Inhalation blood All data are negative Rat NOAEL 90 days
0.189 mg/I
Epichiorohydrin Ingestion heart blood Some positive data exist, but the Rat NOAEL 80 12 weeks
data are not sufficient for mg/kg/day
classification
Epichlorohydrin Ingestion liver Some positive data exist, but the Rat NOAEL 25 90 days
data are not sufficient for mg/kg/day
classification

Aspiration Hazard
For the component/components, either no data are currently available or the data are not sufficient for classification.

Please contact the address or phone number listed on the first page of the SDS for additional toxicological information
on this material and/or its components.

I SECTION 12: Ecological information

Ecotoxicological information
Please contact the address or phone number listed on the first page of the SDS for additional ecotoxicological infonnation on this material
and/or its components.
Chemical fate information
Please contact the address or phone number listed on the first page of the SDS for additional chemical fate information on this material
and/or its components.

I SECTION 13: Disposal considerations

13.1. Disposal methods


Dispose of contents! container in accordance with the local/regional/national/international regulations.

Dispose of waste product in a permitted industrial waste facility. As a disposal alternative, incinerate in a permitted waste
incineration facility. Proper destruction may require the use of additional fuel during incineration processes. Empty
drums/barrels/containers used for transporting and handling hazardous chemicals (chemical substances/mixtures/preparations
classified as Hazardous as per applicable regulations) shall be considered, stored, treated & disposed of as hazardous wastes
unless otherwise defined by applicable waste regulations. Consult with the respective regulating authorities to determine the
available treatment and disposal facilities.

I SECTION 14: Transport Information


For Transport tnformation, please visit http://3Mcom/Transportinfo or call 1-800-364-3577 or 651-737-6501.

I SECTION 15 Regulatory information

15.1. US Federal Regulations


Contact 3M for more information.

311/312 Hazard Categories:

Fire Hazard No- Pressure Hazard No - Reactivity Hazard No - Immediate Hazard Yes - Delayed Hazard - Yes

15.2. State Regulations


Contact 3M for more information.

Page 12 of 13
3M’’ Panel Bonding Adhesive Part B PNs 08115, 38315, 58115 09/23/15 j

California Proposition 65

lnredient C.A.S. No. Classification


Epic hlorohydrin 106-89-8 Male reproductive toxin
Epichlorohydrin 106-89-8 Carcinogen
Carbon Black 1333-86-4 Carcinogen

WARNING: This product contains a chemical known to the State of California to cause birth defects or other reproductive
harm.
WARNING: This product contains a chemical known to the State of California to cause cancer.

15.3. Chemical Inventories


The components of this product are in compliance with the chemical notification requirements of TSCA.

Contact 3M for more information.

15.4. International Regulations


Contact 3M for more information.

I This SDS has beenjçpared to meet theU.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200.

I SECTION 16 Other information I


NFPA Hazard Classification
Health: 2 Flammability: 1 Instability: 0 Special Hazards: None

National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address
0
the hazards that are presented by short-term, acute exposure to a material under conditions of fire, spill, or similar
emergencies. Hazard ratings are primarily based on the inherent physical and toxic properties of the material but also include
the toxic properties of combustion or decomposition products that are known to be generated in significant quantities.

Document Group: 32-4327-6 Version Number: 1.01


Issue Date: 09/23/15 Supercedes Date: 11/24/14

DISCLAIMER: The information in this Safety Data Sheet (SDS) is believed to be correct as of the date issued. 3M MAKES
NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY
OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR
USAGE OF TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable
for user’s method of use or application. Given the variety of factors that can affect the use and application of a 3M product,
some of which are uniquely within the user’s knowledge and control, it is essential that the user evaluate the 3M product to
determine whether it is fit for a particular purpose and suitable for user’s method of use or application.

3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer
may have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness
or accuracy. In addition, information obtained from a database may not be as current as the information in the SDS available
directly from 3M

3M USA SDSs are available at www.3M.com

C
Page 13 of 13
3M™ Scotch-Weld™ Epoxy Adhesive DP100, Clear 04/16/15

Safety Data Sheet


Copyright,2015,3M Company.
All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is allowed
provided that: (1) the information is copied in full with no changes unless prior written agreement is obtained from 3M, and (2) neither
the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon.

Document Group: 11-3180-4 Version Number: 14.00


Issue Date: 04/16/15 Supercedes Date: 04/23/10

Product identifier
3M™ Scotch-Weld™ Epoxy Adhesive DP100, Clear

ID Number(s):

62-3575-1430-6, 62-3575-1435-5, 62-3575-3530-1, 62-3575-3830-5

Recommended use
Structural adhesive

Supplier's details

MANUFACTURER: 3M
DIVISION: Industrial Adhesives and Tapes Division

ADDRESS: 3M Center, St. Paul, MN 55144-1000, USA


Telephone: 1-888-3M HELPS (1-888-364-3577)

Emergency telephone number


1-800-364-3577 or (651) 737-6501 (24 hours)

This product is a kit or a multipart product which consists of multiple, independently packaged components. A Safety Data
Sheet (SDS), Article Information Sheet (AIS), or Article Information Letter (AIL) for each of these components is included.
Please do not separate the component documents from this cover page. The document numbers for components of this
product are:

10-3337-2, 10-3341-4

DISCLAIMER: The information in this Safety Data Sheet (SDS) is believed to be correct as of the date issued. 3M MAKES NO
WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF
MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF
TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable for user's method of
use or application. Given the variety of factors that can affect the use and application of a 3M product, some of which are uniquely
within the user's knowledge and control, it is essential that the user evaluate the 3M product to determine whether it is fit for a
particular purpose and suitable for user's method of use or application.

3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer may
have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness or accuracy.
In addition, information obtained from a database may not be as current as the information in the SDS available directly from 3M

________________________________________________________________________________________________________
Page 1 of 2
3M™ Scotch-Weld™ Epoxy Adhesive DP100, Clear 04/16/15

3M USA SDSs are available at www.3M.com

________________________________________________________________________________________________________
Page 2 of 2
3M™ Scotch-Weld™ Epoxy Adhesive DP100 Clear, Part A 04/16/15

Safety Data Sheet


Copyright,2015,3M Company.
All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is
allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is obtained from
3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon.

Document Group: 10-3341-4 Version Number: 22.00


Issue Date: 04/16/15 Supercedes Date: 01/06/10

SECTION 1: Identification
1.1. Product identifier
3M™ Scotch-Weld™ Epoxy Adhesive DP100 Clear, Part A

1.2. Recommended use and restrictions on use

Recommended use
Accelerator for 2 part epoxy adhesive, Structural adhesive

1.3. Supplier’s details


MANUFACTURER: 3M
DIVISION: Industrial Adhesives and Tapes Division
ADDRESS: 3M Center, St. Paul, MN 55144-1000, USA
Telephone: 1-888-3M HELPS (1-888-364-3577)

1.4. Emergency telephone number


1-800-364-3577 or (651) 737-6501 (24 hours)

SECTION 2: Hazard identification


2.1. Hazard classification
Serious Eye Damage/Irritation: Category 2A.
Skin Corrosion/Irritation: Category 2.

2.2. Label elements


Signal word
Warning

Symbols
Exclamation mark |

Pictograms

Hazard Statements

__________________________________________________________________________________________
Page 1 of 9
3M™ Scotch-Weld™ Epoxy Adhesive DP100 Clear, Part A 04/16/15

Causes serious eye irritation.


Causes skin irritation.

Precautionary Statements

Prevention:
Wear protective gloves and eye/face protection.
Wash thoroughly after handling.

Response:
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
If eye irritation persists: Get medical advice/attention.
IF ON SKIN: Wash with plenty of soap and water.
If skin irritation occurs: Get medical advice/attention.
Take off contaminated clothing and wash it before reuse.

2.3. Hazards not otherwise classified


None.

SECTION 3: Composition/information on ingredients


Ingredient C.A.S. No. % by Wt
Mercaptan Polymer (NJTS Reg. No. 04499600-6776) Trade Secret* 80 - 95 Trade Secret *
2,4,6-tris((Dimethylamino)methyl)phenol 90-72-2 5 - 15 Trade Secret *
bis((Dimethylamino)methyl)phenol 71074-89-0 0.1 - 1.5 Trade Secret *

NJTS or NJTSRN: New Jersey Trade Secret Registry Number.

*The specific chemical identity and/or exact percentage (concentration) of this composition has been withheld as a trade
secret.

SECTION 4: First aid measures


4.1. Description of first aid measures

Inhalation:
Remove person to fresh air. If you feel unwell, get medical attention.

Skin Contact:
Immediately wash with soap and water. Remove contaminated clothing and wash before reuse. If signs/symptoms develop,
get medical attention.

Eye Contact:
Immediately flush with large amounts of water. Remove contact lenses if easy to do. Continue rinsing. Get medical
attention.

If Swallowed:
Rinse mouth. If you feel unwell, get medical attention.

4.2. Most important symptoms and effects, both acute and delayed
See Section 11.1. Information on toxicological effects.

4.3. Indication of any immediate medical attention and special treatment required

__________________________________________________________________________________________
Page 2 of 9
3M™ Scotch-Weld™ Epoxy Adhesive DP100 Clear, Part A 04/16/15

Not applicable

SECTION 5: Fire-fighting measures


5.1. Suitable extinguishing media
In case of fire: Use a fire fighting agent suitable for ordinary combustible material such as water or foam to extinguish.

5.2. Special hazards arising from the substance or mixture


None inherent in this product.

Hazardous Decomposition or By-Products


Substance Condition
Carbon monoxide During Combustion
Carbon dioxide During Combustion
Hydrogen Sulfide During Combustion
Oxides of Nitrogen During Combustion
Oxides of Sulfur During Combustion

5.3. Special protective actions for fire-fighters


No special protective actions for fire-fighters are anticipated.

SECTION 6: Accidental release measures


6.1. Personal precautions, protective equipment and emergency procedures
Evacuate area. Ventilate the area with fresh air. For large spill, or spills in confined spaces, provide mechanical ventilation
to disperse or exhaust vapors, in accordance with good industrial hygiene practice. Warning! A motor could be an ignition
source and could cause flammable gases or vapors in the spill area to burn or explode. Refer to other sections of this SDS for
information regarding physical and health hazards, respiratory protection, ventilation, and personal protective equipment.

6.2. Environmental precautions


Avoid release to the environment.

6.3. Methods and material for containment and cleaning up


Contain spill. Working from around the edges of the spill inward, cover with bentonite, vermiculite, or commercially
available inorganic absorbent material. Mix in sufficient absorbent until it appears dry. Remember, adding an absorbent
material does not remove a physical, health, or environmental hazard. Collect as much of the spilled material as possible.
Place in a closed container approved for transportation by appropriate authorities. Clean up residue with an appropriate
solvent selected by a qualified and authorized person. Ventilate the area with fresh air. Read and follow safety precautions on
the solvent label and SDS. Seal the container. Dispose of collected material as soon as possible.

SECTION 7: Handling and storage


7.1. Precautions for safe handling
Avoid breathing dust/fume/gas/mist/vapors/spray. Do not get in eyes, on skin, or on clothing. Do not eat, drink or smoke
when using this product. Wash thoroughly after handling. Avoid contact with oxidizing agents (eg. chlorine, chromic acid
etc.)

7.2. Conditions for safe storage including any incompatibilities


Store away from oxidizing agents.

SECTION 8: Exposure controls/personal protection


8.1. Control parameters

__________________________________________________________________________________________
Page 3 of 9
3M™ Scotch-Weld™ Epoxy Adhesive DP100 Clear, Part A 04/16/15

Occupational exposure limits


If a component is disclosed in section 3 but does not appear in the table below, an occupational exposure limit is not available
for the component.
Ingredient C.A.S. No. Agency Limit type Additional Comments
2,4,6- 90-72-2 CMRG TWA:5 ppm
tris((Dimethylamino)methyl)phen
ol
ACGIH : American Conference of Governmental Industrial Hygienists
AIHA : American Industrial Hygiene Association
CMRG : Chemical Manufacturer's Recommended Guidelines
OSHA : United States Department of Labor - Occupational Safety and Health Administration
TWA: Time-Weighted-Average
STEL: Short Term Exposure Limit
CEIL: Ceiling

8.2. Exposure controls

8.2.1. Engineering controls


Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below relevant Exposure
Limits and/or control dust/fume/gas/mist/vapors/spray. If ventilation is not adequate, use respiratory protection equipment.

8.2.2. Personal protective equipment (PPE)

Eye/face protection

Select and use eye/face protection to prevent contact based on the results of an exposure assessment. The following eye/face
protection(s) are recommended:
Indirect Vented Goggles

Skin/hand protection
Select and use gloves and/or protective clothing approved to relevant local standards to prevent skin contact based on the
results of an exposure assessment. Selection should be based on use factors such as exposure levels, concentration of the
substance or mixture, frequency and duration, physical challenges such as temperature extremes, and other use conditions.
Consult with your glove and/or protective clothing manufacturer for selection of appropriate compatible gloves/protective
clothing.
Gloves made from the following material(s) are recommended: Butyl Rubber
Neoprene
Nitrile Rubber

Respiratory protection

An exposure assessment may be needed to decide if a respirator is required. If a respirator is needed, use respirators as part of
a full respiratory protection program. Based on the results of the exposure assessment, select from the following respirator
type(s) to reduce inhalation exposure:
Half facepiece or full facepiece air-purifying respirator suitable for organic vapors and particulates

For questions about suitability for a specific application, consult with your respirator manufacturer.

SECTION 9: Physical and chemical properties


9.1. Information on basic physical and chemical properties
General Physical Form: Liquid
Specific Physical Form: Viscous
Odor, Color, Grade: dark amber, strong mercaptan odor
Odor threshold No Data Available
pH Not Applicable

__________________________________________________________________________________________
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3M™ Scotch-Weld™ Epoxy Adhesive DP100 Clear, Part A 04/16/15

Melting point Not Applicable


Boiling Point >=257 ºC
Flash Point 257 ºC [Test Method: Closed Cup]
Evaporation rate Not Applicable
Flammability (solid, gas) Not Applicable
Flammable Limits(LEL) Not Applicable
Flammable Limits(UEL) Not Applicable
Vapor Pressure Negligible
Vapor Density Not Applicable
Density 1.15 g/ml
Specific Gravity 1.15 [Ref Std: WATER=1]
Solubility in Water Negligible
Solubility- non-water No Data Available
Partition coefficient: n-octanol/ water No Data Available
Autoignition temperature No Data Available
Decomposition temperature No Data Available
Viscosity 8,000 - 15,000 centipoise [@ 73 ºF ]
Hazardous Air Pollutants 0 % weight [Test Method: Calculated]
VOC Less H2O & Exempt Solvents 0 g/l [Test Method: calculated SCAQMD rule 443.1] [Details:
when used as intended with Part B]
VOC Less H2O & Exempt Solvents 0 g/l [Test Method: calculated SCAQMD rule 443.1] [Details: as
supplied]
VOC Less H2O & Exempt Solvents 0 % [Test Method: calculated SCAQMD rule 443.1] [Details:
when used as intended with Part B]

SECTION 10: Stability and reactivity


10.1. Reactivity
This material may be reactive with certain agents under certain conditions - see the remaining headings in this section.

10.2. Chemical stability


Stable.

10.3. Possibility of hazardous reactions


Hazardous polymerization will not occur.

10.4. Conditions to avoid


Heat is generated during cure. Do not cure a mass larger than 50 grams in a confined space to prevent a premature exothermic
reaction with production of intense heat and smoke.

10.5. Incompatible materials


Strong oxidizing agents

10.6. Hazardous decomposition products


Substance Condition
None known.

Refer to section 5.2 for hazardous decomposition products during combustion.

SECTION 11: Toxicological information


The information below may not be consistent with the material classification in Section 2 if specific ingredient
classifications are mandated by a competent authority. In addition, toxicological data on ingredients may not be

__________________________________________________________________________________________
Page 5 of 9
3M™ Scotch-Weld™ Epoxy Adhesive DP100 Clear, Part A 04/16/15

reflected in the material classification and/or the signs and symptoms of exposure, because an ingredient may be
present below the threshold for labeling, an ingredient may not be available for exposure, or the data may not be
relevant to the material as a whole.

11.1. Information on Toxicological effects

Signs and Symptoms of Exposure

Based on test data and/or information on the components, this material may produce the following health effects:

Inhalation:
Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose
and throat pain.

Skin Contact:
Skin Irritation: Signs/symptoms may include localized redness, swelling, itching, dryness, cracking, blistering, and pain.

Eye Contact:
Severe Eye Irritation: Signs/symptoms may include significant redness, swelling, pain, tearing, cloudy appearance of the
cornea, and impaired vision.

Ingestion:
May be harmful if swallowed.
Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhea.

Toxicological Data
If a component is disclosed in section 3 but does not appear in a table below, either no data are available for that endpoint or
the data are not sufficient for classification.

Acute Toxicity
Name Route Species Value
Overall product Ingestion No data available; calculated ATE 2,000 - 5,000
mg/kg
Mercaptan Polymer (NJTS Reg. No. 04499600-6776) Dermal Rabbit LD50 > 10,200 mg/kg
Mercaptan Polymer (NJTS Reg. No. 04499600-6776) Ingestion Rat LD50 2,600 mg/kg
2,4,6-tris((Dimethylamino)methyl)phenol Dermal Rat LD50 1,280 mg/kg
2,4,6-tris((Dimethylamino)methyl)phenol Ingestion Rat LD50 1,000 mg/kg
bis((Dimethylamino)methyl)phenol Ingestion LD50 estimated to be 300 - 2,000 mg/kg
ATE = acute toxicity estimate

Skin Corrosion/Irritation
Name Species Value

Overall product In vitro Irritant


data
2,4,6-tris((Dimethylamino)methyl)phenol Rabbit Corrosive
bis((Dimethylamino)methyl)phenol similar Corrosive
compoun
ds

Serious Eye Damage/Irritation


Name Species Value

Overall product In vitro Severe irritant


data
2,4,6-tris((Dimethylamino)methyl)phenol Rabbit Corrosive
bis((Dimethylamino)methyl)phenol similar Corrosive
compoun
ds

__________________________________________________________________________________________
Page 6 of 9
3M™ Scotch-Weld™ Epoxy Adhesive DP100 Clear, Part A 04/16/15

Skin Sensitization
Name Species Value
2,4,6-tris((Dimethylamino)methyl)phenol Guinea Some positive data exist, but the data are not
pig sufficient for classification

Respiratory Sensitization
For the component/components, either no data are currently available or the data are not sufficient for classification.

Germ Cell Mutagenicity


Name Route Value

2,4,6-tris((Dimethylamino)methyl)phenol In Vitro Not mutagenic

Carcinogenicity
For the component/components, either no data are currently available or the data are not sufficient for classification.

Reproductive Toxicity

Reproductive and/or Developmental Effects


For the component/components, either no data are currently available or the data are not sufficient for classification.

Target Organ(s)

Specific Target Organ Toxicity - single exposure


Name Route Target Organ(s) Value Species Test Result Exposure
Duration
2,4,6- Inhalation respiratory irritation Some positive data exist, but the NOAEL Not
tris((Dimethylamino)methy data are not sufficient for available
l)phenol classification

Specific Target Organ Toxicity - repeated exposure


Name Route Target Organ(s) Value Species Test Result Exposure
Duration
2,4,6- Dermal skin | liver | nervous Some positive data exist, but the Rat NOAEL 125 28 days
tris((Dimethylamino)meth system data are not sufficient for mg/kg/day
yl)phenol classification
2,4,6- Dermal auditory system | All data are negative Rat NOAEL 125 28 days
tris((Dimethylamino)meth hematopoietic mg/kg/day
yl)phenol system | eyes

Aspiration Hazard
For the component/components, either no data are currently available or the data are not sufficient for classification.

Please contact the address or phone number listed on the first page of the SDS for additional toxicological information
on this material and/or its components.

SECTION 12: Ecological information


Ecotoxicological information
Please contact the address or phone number listed on the first page of the SDS for additional ecotoxicological information on this material
and/or its components.
Chemical fate information
Please contact the address or phone number listed on the first page of the SDS for additional chemical fate information on this material
and/or its components.

__________________________________________________________________________________________
Page 7 of 9
3M™ Scotch-Weld™ Epoxy Adhesive DP100 Clear, Part A 04/16/15

SECTION 13: Disposal considerations


13.1. Disposal methods
Dispose of contents/ container in accordance with the local/regional/national/international regulations.

Dispose of completely cured (or polymerized) material in a permitted industrial waste facility. As a disposal alternative,
incinerate uncured product in a permitted waste incineration facility. Proper destruction may require the use of additional fuel
during incineration processes. If no other disposal options are available, waste product that has been completely cured or
polymerized may be placed in a landfill properly designed for industrial waste. Empty drums/barrels/containers used for
transporting and handling hazardous chemicals (chemical substances/mixtures/preparations classified as Hazardous as per
applicable regulations) shall be considered, stored, treated & disposed of as hazardous wastes unless otherwise defined by
applicable waste regulations. Consult with the respective regulating authorities to determine the available treatment and
disposal facilities.

EPA Hazardous Waste Number (RCRA): Not regulated

SECTION 14: Transport Information

For Transport Information, please visit http://3M.com/Transportinfo or call 1-800-364-3577 or 651-737-6501.

SECTION 15: Regulatory information

15.1. US Federal Regulations


Contact 3M for more information.

311/312 Hazard Categories:

Fire Hazard - No Pressure Hazard - No Reactivity Hazard - No Immediate Hazard - Yes Delayed Hazard - No

15.2. State Regulations


Contact 3M for more information.

15.3. Chemical Inventories


The components of this product are in compliance with the chemical notification requirements of TSCA.

Contact 3M for more information.

15.4. International Regulations


Contact 3M for more information.

This SDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200.

SECTION 16: Other information


NFPA Hazard Classification
Health: 2 Flammability: 1 Instability: 1 Special Hazards: None

National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address
the hazards that are presented by short-term, acute exposure to a material under conditions of fire, spill, or similar
emergencies. Hazard ratings are primarily based on the inherent physical and toxic properties of the material but also include

__________________________________________________________________________________________
Page 8 of 9
3M™ Scotch-Weld™ Epoxy Adhesive DP100 Clear, Part A 04/16/15

the toxic properties of combustion or decomposition products that are known to be generated in significant quantities.

Document Group: 10-3341-4 Version Number: 22.00


Issue Date: 04/16/15 Supercedes Date: 01/06/10

DISCLAIMER: The information in this Safety Data Sheet (SDS) is believed to be correct as of the date issued. 3M MAKES
NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY
OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR
USAGE OF TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable
for user's method of use or application. Given the variety of factors that can affect the use and application of a 3M product,
some of which are uniquely within the user's knowledge and control, it is essential that the user evaluate the 3M product to
determine whether it is fit for a particular purpose and suitable for user's method of use or application.

3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer
may have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness
or accuracy. In addition, information obtained from a database may not be as current as the information in the SDS available
directly from 3M

3M USA SDSs are available at www.3M.com

__________________________________________________________________________________________
Page 9 of 9
3M™ Scotch-Weld™ Epoxy Adhesive DP100 Clear, Part B 04/16/15

Safety Data Sheet


Copyright,2015,3M Company.
All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is
allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is obtained from
3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon.

Document Group: 10-3337-2 Version Number: 16.00


Issue Date: 04/16/15 Supercedes Date: 06/16/05

SECTION 1: Identification
1.1. Product identifier
3M™ Scotch-Weld™ Epoxy Adhesive DP100 Clear, Part B

Product Identification Numbers


DP-100

1.2. Recommended use and restrictions on use

Recommended use
Structural adhesive

1.3. Supplier’s details


MANUFACTURER: 3M
DIVISION: Industrial Adhesives and Tapes Division
ADDRESS: 3M Center, St. Paul, MN 55144-1000, USA
Telephone: 1-888-3M HELPS (1-888-364-3577)

1.4. Emergency telephone number


1-800-364-3577 or (651) 737-6501 (24 hours)

SECTION 2: Hazard identification


2.1. Hazard classification
Serious Eye Damage/Irritation: Category 2B.
Skin Sensitizer: Category 1.

2.2. Label elements


Signal word
Warning

Symbols
Exclamation mark |

Pictograms

__________________________________________________________________________________________
Page 1 of 9
3M™ Scotch-Weld™ Epoxy Adhesive DP100 Clear, Part B 04/16/15

Hazard Statements
Causes eye irritation.
May cause an allergic skin reaction.

Precautionary Statements

Prevention:
Avoid breathing dust/fume/gas/mist/vapors/spray.
Wear protective gloves.
Wash thoroughly after handling.
Contaminated work clothing must not be allowed out of the workplace.

Response:
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
If eye irritation persists: Get medical advice/attention.
IF ON SKIN: Wash with plenty of soap and water.
If skin irritation or rash occurs: Get medical advice/attention.
Wash contaminated clothing before reuse.

Disposal:
Dispose of contents/container in accordance with applicable local/regional/national/international regulations.

2.3. Hazards not otherwise classified


None.

SECTION 3: Composition/information on ingredients


Ingredient C.A.S. No. % by Wt
Epoxy Resin 25068-38-6 100

SECTION 4: First aid measures


4.1. Description of first aid measures

Inhalation:
Remove person to fresh air. If you feel unwell, get medical attention.

Skin Contact:
Immediately wash with soap and water. Remove contaminated clothing and wash before reuse. If signs/symptoms develop,
get medical attention.

Eye Contact:
Flush with large amounts of water. Remove contact lenses if easy to do. Continue rinsing. If signs/symptoms persist, get
medical attention.

If Swallowed:
Rinse mouth. If you feel unwell, get medical attention.

__________________________________________________________________________________________
Page 2 of 9
3M™ Scotch-Weld™ Epoxy Adhesive DP100 Clear, Part B 04/16/15

4.2. Most important symptoms and effects, both acute and delayed
See Section 11.1. Information on toxicological effects.

4.3. Indication of any immediate medical attention and special treatment required
Not applicable

SECTION 5: Fire-fighting measures


5.1. Suitable extinguishing media
In case of fire: Use a fire fighting agent suitable for ordinary combustible material such as water or foam to extinguish.

5.2. Special hazards arising from the substance or mixture


None inherent in this product.

Hazardous Decomposition or By-Products


Substance Condition
Aldehydes During Combustion
Carbon monoxide During Combustion
Carbon dioxide During Combustion
Ketones During Combustion

5.3. Special protective actions for fire-fighters


No special protective actions for fire-fighters are anticipated.

SECTION 6: Accidental release measures


6.1. Personal precautions, protective equipment and emergency procedures
Evacuate area. Ventilate the area with fresh air. For large spill, or spills in confined spaces, provide mechanical ventilation
to disperse or exhaust vapors, in accordance with good industrial hygiene practice. Warning! A motor could be an ignition
source and could cause flammable gases or vapors in the spill area to burn or explode. Refer to other sections of this SDS for
information regarding physical and health hazards, respiratory protection, ventilation, and personal protective equipment.

6.2. Environmental precautions


Avoid release to the environment. For larger spills, cover drains and build dikes to prevent entry into sewer systems or
bodies of water.

6.3. Methods and material for containment and cleaning up


Contain spill. Working from around the edges of the spill inward, cover with bentonite, vermiculite, or commercially
available inorganic absorbent material. Mix in sufficient absorbent until it appears dry. Remember, adding an absorbent
material does not remove a physical, health, or environmental hazard. Collect as much of the spilled material as possible.
Place in a closed container approved for transportation by appropriate authorities. Clean up residue with an appropriate
solvent selected by a qualified and authorized person. Ventilate the area with fresh air. Read and follow safety precautions on
the solvent label and SDS. Seal the container. Dispose of collected material as soon as possible.

SECTION 7: Handling and storage


7.1. Precautions for safe handling
Avoid breathing dust/fume/gas/mist/vapors/spray. Do not get in eyes, on skin, or on clothing. Do not eat, drink or smoke
when using this product. Wash thoroughly after handling. Contaminated work clothing should not be allowed out of the
workplace. Avoid release to the environment. Wash contaminated clothing before reuse. Avoid contact with oxidizing
agents (eg. chlorine, chromic acid etc.)

__________________________________________________________________________________________
Page 3 of 9
3M™ Scotch-Weld™ Epoxy Adhesive DP100 Clear, Part B 04/16/15

7.2. Conditions for safe storage including any incompatibilities


Store away from heat. Store away from acids. Store away from oxidizing agents.

SECTION 8: Exposure controls/personal protection


8.1. Control parameters

Occupational exposure limits


No occupational exposure limit values exist for any of the components listed in Section 3 of this SDS.

8.2. Exposure controls

8.2.1. Engineering controls


No engineering controls required.

8.2.2. Personal protective equipment (PPE)

Eye/face protection

Select and use eye/face protection to prevent contact based on the results of an exposure assessment. The following eye/face
protection(s) are recommended:
Indirect Vented Goggles

Skin/hand protection
Select and use gloves and/or protective clothing approved to relevant local standards to prevent skin contact based on the
results of an exposure assessment. Selection should be based on use factors such as exposure levels, concentration of the
substance or mixture, frequency and duration, physical challenges such as temperature extremes, and other use conditions.
Consult with your glove and/or protective clothing manufacturer for selection of appropriate compatible gloves/protective
clothing. Note: Nitrile gloves may be worn over polymer laminate gloves to improve dexterity.
Gloves made from the following material(s) are recommended: Polymer laminate

Respiratory protection
None required.

SECTION 9: Physical and chemical properties


9.1. Information on basic physical and chemical properties
General Physical Form: Liquid
Specific Physical Form: Viscous
Odor, Color, Grade: light straw colored, epoxy odor
Odor threshold No Data Available
pH Not Applicable
Melting point Not Applicable
Boiling Point >=249 ºC
Flash Point 249 ºC [Test Method: Pensky-Martens Closed Cup]
Evaporation rate Not Applicable
Flammability (solid, gas) Not Applicable
Flammable Limits(LEL) Not Applicable
Flammable Limits(UEL) Not Applicable
Vapor Pressure <=0.03 mmHg [@ 70 ºC]
Vapor Density Not Applicable
Density 1.17 g/ml
Specific Gravity 1.17
Solubility in Water Nil

__________________________________________________________________________________________
Page 4 of 9
3M™ Scotch-Weld™ Epoxy Adhesive DP100 Clear, Part B 04/16/15

Solubility- non-water No Data Available


Partition coefficient: n-octanol/ water No Data Available
Autoignition temperature No Data Available
Decomposition temperature No Data Available
Viscosity 10,000 - 30,000 centipoise [@ 73.4 ºF ] [Details: MITS data]
Hazardous Air Pollutants 0 % weight [Test Method: Calculated]
VOC Less H2O & Exempt Solvents 0 g/l [Test Method: calculated SCAQMD rule 443.1] [Details:
when used as intended with Part A]
VOC Less H2O & Exempt Solvents 0 g/l [Test Method: calculated SCAQMD rule 443.1] [Details: as
supplied]
VOC Less H2O & Exempt Solvents 0 % [Test Method: calculated SCAQMD rule 443.1] [Details:
when used as intended with Part A]

SECTION 10: Stability and reactivity


10.1. Reactivity
This material may be reactive with certain agents under certain conditions - see the remaining headings in this section.

10.2. Chemical stability


Stable.

10.3. Possibility of hazardous reactions


Hazardous polymerization will not occur.

10.4. Conditions to avoid


Heat is generated during cure. Do not cure a mass larger than 50 grams in a confined space to prevent a premature exothermic
reaction with production of intense heat and smoke.
Heat

10.5. Incompatible materials


Strong acids
Strong oxidizing agents

10.6. Hazardous decomposition products


Substance Condition
None known.

Refer to section 5.2 for hazardous decomposition products during combustion.

SECTION 11: Toxicological information


The information below may not be consistent with the material classification in Section 2 if specific ingredient
classifications are mandated by a competent authority. In addition, toxicological data on ingredients may not be
reflected in the material classification and/or the signs and symptoms of exposure, because an ingredient may be
present below the threshold for labeling, an ingredient may not be available for exposure, or the data may not be
relevant to the material as a whole.

11.1. Information on Toxicological effects

Signs and Symptoms of Exposure

Based on test data and/or information on the components, this material may produce the following health effects:

__________________________________________________________________________________________
Page 5 of 9
3M™ Scotch-Weld™ Epoxy Adhesive DP100 Clear, Part B 04/16/15

Inhalation:
No health effects are expected.

Skin Contact:
Mild Skin Irritation: Signs/symptoms may include localized redness, swelling, itching, and dryness. Allergic Skin Reaction
(non-photo induced): Signs/symptoms may include redness, swelling, blistering, and itching.

Eye Contact:
Moderate Eye Irritation: Signs/symptoms may include redness, swelling, pain, tearing, and blurred or hazy vision.

Ingestion:
Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhea.

Toxicological Data
If a component is disclosed in section 3 but does not appear in a table below, either no data are available for that endpoint or
the data are not sufficient for classification.

Acute Toxicity
Name Route Species Value
Epoxy Resin Dermal Rat LD50 > 1,600 mg/kg
Epoxy Resin Ingestion Rat LD50 > 1,000 mg/kg
ATE = acute toxicity estimate

Skin Corrosion/Irritation
Name Species Value

Epoxy Resin Rabbit Mild irritant

Serious Eye Damage/Irritation


Name Species Value

Epoxy Resin Rabbit Moderate irritant

Skin Sensitization
Name Species Value
Epoxy Resin Human Sensitizing
and
animal

Respiratory Sensitization
Name Species Value

Epoxy Resin Human Some positive data exist, but the data are not
sufficient for classification

Germ Cell Mutagenicity


Name Route Value

Epoxy Resin In vivo Not mutagenic


Epoxy Resin In Vitro Some positive data exist, but the data are not
sufficient for classification

Carcinogenicity
Name Route Species Value
Epoxy Resin Dermal Mouse Some positive data exist, but the data are not
sufficient for classification

Reproductive Toxicity

__________________________________________________________________________________________
Page 6 of 9
3M™ Scotch-Weld™ Epoxy Adhesive DP100 Clear, Part B 04/16/15

Reproductive and/or Developmental Effects


Name Route Value Species Test Result Exposure
Duration
Epoxy Resin Ingestion Not toxic to female reproduction Rat NOAEL 750 2 generation
mg/kg/day
Epoxy Resin Ingestion Not toxic to male reproduction Rat NOAEL 750 2 generation
mg/kg/day
Epoxy Resin Dermal Not toxic to development Rabbit NOAEL 300 during
mg/kg/day organogenesi
s
Epoxy Resin Ingestion Not toxic to development Rat NOAEL 750 2 generation
mg/kg/day

Target Organ(s)

Specific Target Organ Toxicity - single exposure


For the component/components, either no data are currently available or the data are not sufficient for classification.

Specific Target Organ Toxicity - repeated exposure


Name Route Target Organ(s) Value Species Test Result Exposure
Duration
Epoxy Resin Dermal liver Some positive data exist, but the Rat NOAEL 2 years
data are not sufficient for 1,000
classification mg/kg/day
Epoxy Resin Dermal nervous system All data are negative Rat NOAEL 13 weeks
1,000
mg/kg/day
Epoxy Resin Ingestion auditory system | All data are negative Rat NOAEL 28 days
heart | endocrine 1,000
system | mg/kg/day
hematopoietic
system | liver | eyes
| kidney and/or
bladder

Aspiration Hazard
For the component/components, either no data are currently available or the data are not sufficient for classification.

Please contact the address or phone number listed on the first page of the SDS for additional toxicological information
on this material and/or its components.

SECTION 12: Ecological information


Ecotoxicological information
Please contact the address or phone number listed on the first page of the SDS for additional ecotoxicological information on this material
and/or its components.
Chemical fate information
Please contact the address or phone number listed on the first page of the SDS for additional chemical fate information on this material
and/or its components.

SECTION 13: Disposal considerations


13.1. Disposal methods
Dispose of contents/ container in accordance with the local/regional/national/international regulations.

Dispose of completely cured (or polymerized) material in a permitted industrial waste facility. As a disposal alternative,
incinerate uncured product in a permitted waste incineration facility. Proper destruction may require the use of additional fuel

__________________________________________________________________________________________
Page 7 of 9
3M™ Scotch-Weld™ Epoxy Adhesive DP100 Clear, Part B 04/16/15

during incineration processes. Combustion products will include halogen acid (HCl/HF/HBr). Facility must be capable of
handling halogenated materials. If no other disposal options are available, waste product that has been completely cured or
polymerized may be placed in a landfill properly designed for industrial waste. Empty drums/barrels/containers used for
transporting and handling hazardous chemicals (chemical substances/mixtures/preparations classified as Hazardous as per
applicable regulations) shall be considered, stored, treated & disposed of as hazardous wastes unless otherwise defined by
applicable waste regulations. Consult with the respective regulating authorities to determine the available treatment and
disposal facilities.

EPA Hazardous Waste Number (RCRA): Not regulated

SECTION 14: Transport Information

For Transport Information, please visit http://3M.com/Transportinfo or call 1-800-364-3577 or 651-737-6501.

SECTION 15: Regulatory information

15.1. US Federal Regulations


Contact 3M for more information.

311/312 Hazard Categories:

Fire Hazard - No Pressure Hazard - No Reactivity Hazard - No Immediate Hazard - Yes Delayed Hazard - No

15.2. State Regulations


Contact 3M for more information.

15.3. Chemical Inventories


The components of this product are in compliance with the chemical notification requirements of TSCA.

Contact 3M for more information.

15.4. International Regulations


Contact 3M for more information.

This SDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200.

SECTION 16: Other information


NFPA Hazard Classification
Health: 2 Flammability: 1 Instability: 1 Special Hazards: None

National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address
the hazards that are presented by short-term, acute exposure to a material under conditions of fire, spill, or similar
emergencies. Hazard ratings are primarily based on the inherent physical and toxic properties of the material but also include
the toxic properties of combustion or decomposition products that are known to be generated in significant quantities.

Document Group: 10-3337-2 Version Number: 16.00


Issue Date: 04/16/15 Supercedes Date: 06/16/05

DISCLAIMER: The information in this Safety Data Sheet (SDS) is believed to be correct as of the date issued. 3M MAKES

__________________________________________________________________________________________
Page 8 of 9
3M™ Scotch-Weld™ Epoxy Adhesive DP100 Clear, Part B 04/16/15

NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY
OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR
USAGE OF TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable
for user's method of use or application. Given the variety of factors that can affect the use and application of a 3M product,
some of which are uniquely within the user's knowledge and control, it is essential that the user evaluate the 3M product to
determine whether it is fit for a particular purpose and suitable for user's method of use or application.

3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer
may have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness
or accuracy. In addition, information obtained from a database may not be as current as the information in the SDS available
directly from 3M

3M USA SDSs are available at www.3M.com

__________________________________________________________________________________________
Page 9 of 9
Material Safety Data Sheet

Revision Number: 008.0 Issue date: 01/20/2015

1. PRODUCT AND COMPANY IDENTIFICATION


Product name: LOCTITE 404 INSTANT ADHESIVE IDH number: 135465
known as LOCTITE® 404™ INSTANT
ADHESIVE
Product use: Adhesive Item number: 46551
Region: Canada
Company address: Contact information:
Henkel Corporation Telephone: 905.814.6511
2515 Meadowpine Boulevard MEDICAL EMERGENCY Phone: Poison Control Center
Mississauga, Ontario L5N 6C3 1-877-671-4608 (toll free) or 1-303-592-1711
TRANSPORT EMERGENCY Phone: CHEMTREC
1-800-424-9300 (toll free) or 1-703-527-3887
Internet: www.henkelna.com

2. HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
Physical state: Liquid WHMIS hazard class: B.3, D.2.A, D.2.B
Color: Clear, Colorless
Odor: Sharp, Irritating

WARNING: BONDS SKIN IN SECONDS.


MAY CAUSE EYE AND RESPIRATORY TRACT IRRITATION.

Relevant routes of exposure: Skin, Inhalation, Eyes

Potential Health Effects

Inhalation: Exposure to vapors above the established exposure limit results in respiratory irritation, which
may lead to difficulty in breathing and tightness in the chest.
Skin contact: Bonds skin in seconds. May cause skin irritation. Cyanoacrylates have been reported to cause
allergic reaction but due to rapid polymerization at the skin surface, an allergic response is rare.
Cyanoacrylates generate heat on solidification. In rare circumstances a large drop will burn the
skin. Cured adhesive does not present a health hazard even if bonded to the skin.
Eye contact: Irritating to eyes. Causes excessive tearing. Eyelids may bond.
Ingestion: Not expected to be harmful by ingestion. Rapidly polymerizes (solidifies) and bonds in mouth. It
is almost impossible to swallow.

Existing conditions aggravated by Eye, skin, and respiratory disorders.


exposure:

See Section 11 for additional toxicological information.

3. COMPOSITION / INFORMATION ON INGREDIENTS


Hazardous components CAS NUMBER %
Ethyl 2-cyanoacrylate 7085-85-0 60 - 100
Hydroquinone 123-31-9 0.1 - 1

4. FIRST AID MEASURES


Inhalation: Move to fresh air. If breathing is difficult, give oxygen. If not breathing, give
artificial respiration. If symptoms develop and persist, get medical attention.

IDH number: 135465 Product name: LOCTITE 404 INSTANT ADHESIVE known as LOCTITE® 404™ INSTANT ADHESIVE
Page 1 of 5
Skin contact: Do not pull bonded skin apart. Soak in warm soapy water. Gently peel apart
using a blunt instrument. If skin is burned due to the rapid generation of heat
by a large drop, seek medical attention. If lips are bonded, apply warm water
to the lips and encourage wetting and pressure from saliva in mouth. Peel or
roll lips apart. Do not pull lips apart with direct opposing force.

Eye contact: Immediately flush with plenty of water for at least 15 minutes. Get medical
attention. If eyelids are bonded closed, release eyelashes with warm water by
covering with a wet pad. Do not force eye open. Cyanoacrylate will bond to
eye protein and will cause a lachrymatory effect which will help to debond the
adhesive. Keep eye covered until debonding is complete, usually within 1-3
days. Medical attention should be sought in case solid particles of polymerized
cyanoacrylate trapped behind the eyelid caused abrasive damage.

Ingestion: Ensure breathing passages are not obstructed. The product will polymerize
rapidly and bond to the mouth making it almost impossible to swallow. Saliva
will separate any solidified product in several hours. Prevent the patient from
swallowing any separated mass.

Notes to physician: Surgery is not necessary to separate accidentally bonded tissues. Experience
has shown that bonded tissues are best treated by passive, non-surgical first
aid. If rapid curing has caused thermal burns they should be treated
symptomatically after adhesive is removed.

5. FIRE FIGHTING MEASURES


Flash point: 80 - 93 °C (176°F - 199.4 °F) Tagliabue closed cup

Autoignition temperature: 485 °C (905°F)

Flammable/Explosive limits - lower: Not determined

Flammable/Explosive limits - upper: Not determined

Extinguishing media: Water spray (fog), foam, dry chemical or carbon dioxide.

Special firefighting procedures: Wear a self-contained breathing apparatus with a full face piece operated in
pressure-demand or other positive pressure mode.

Unusual fire or explosion hazards: None

Hazardous combustion products: Trace amounts of toxic and/or irritating fumes may be released and the use of
breathing apparatus is recommended.

Sensitivity to Mechanical Impact: Not available.

Sensitivity to static discharge: Not available.

6. ACCIDENTAL RELEASE MEASURES


Use personal protection recommended in Section 8, isolate the hazard area and deny entry to unnecessary and unprotected
personnel.

Environmental precautions: Ventilate area. Do not allow product to enter sewer or waterways.

Clean-up methods: Do not use cloths for mopping up. Flood with water to complete polymerization
and scrape off the floor. Cured material can be disposed of as non-hazardous
waste. Refer to Section 8 "Exposure Controls / Personal Protection" prior to
clean up.

IDH number: 135465 Product name: LOCTITE 404 INSTANT ADHESIVE known as LOCTITE® 404™ INSTANT ADHESIVE
Page 2 of 5
7. HANDLING AND STORAGE
Handling: Prevent contact with eyes, skin and clothing. Do not breathe vapor and mist.
Wash thoroughly after handling. Avoid contact with fabric or paper goods.
Contact with these materials may cause rapid polymerization which can
generate smoke and strong irritating vapors, and cause thermal burns.

Storage: Keep in a cool, well ventilated area away from heat, sparks and open flame.
Keep container tightly closed until ready for use.

For information on product shelf life contact Henkel Canada Customer Service at 800-263-5043.

8. EXPOSURE CONTROLS / PERSONAL PROTECTION


Employers should complete an assessment of all workplaces to determine the need for, and selection of, proper exposure
controls and protective equipment for each task performed.

Hazardous components ACGIH TLV OSHA PEL AIHA WEEL OTHER


Ethyl 2-cyanoacrylate 0.2 ppm TWA None None None
1 mg/m3 TWA
Hydroquinone (Dermal 2 mg/m3 PEL None None
sensitization)

Engineering controls: Use positive down-draft exhaust ventilation if general ventilation is insufficient
to maintain vapor concentration below established exposure limits.

Respiratory protection: Use a NIOSH approved supplied air respirator with an organic cartridge if the
potential to exceed established exposure limits exists.

Eye/face protection: Safety goggles or safety glasses with side shields. Full face protection should
be used if the potential for splashing or spraying of product exists.

Skin protection: Use nitrile gloves and aprons as necessary to prevent contact. Do not use
PVC, nylon or cotton.

9. PHYSICAL AND CHEMICAL PROPERTIES


Physical state: Liquid
Color: Clear, Colorless
Odor: Sharp, Irritating
Odor threshold: 1 - 2 ppm
pH: Not applicable
Vapor pressure: < 0.2 mm hg
Boiling point/range: > 149 °C (> 300.2 °F)
Melting point/ range: Not determined
Specific gravity: 1.09 at 23.9 °C (75.02 °F)
Vapor density: 3 Approximately
Flash point: 80 - 93 °C (176°F - 199.4 °F) Tagliabue closed cup
Flammable/Explosive limits - lower: Not determined
Flammable/Explosive limits - upper: Not determined
Autoignition temperature: 485 °C (905°F)
Evaporation rate: Not available.
Solubility in water: Polymerises in presence of water.
Partition coefficient (n-octanol/water): Not determined
VOC content: < 2 %; < 20 g/l (California SCAQMD Method 316B) (Estimated)

IDH number: 135465 Product name: LOCTITE 404 INSTANT ADHESIVE known as LOCTITE® 404™ INSTANT ADHESIVE
Page 3 of 5
10. STABILITY AND REACTIVITY
Stability: Stable under recommended storage conditions.

Hazardous reactions: Rapid exothermic polymerization will occur in the presence of water, amines,
alkalis and alcohols.

Hazardous decomposition products: None

Incompatible materials: Water, amines, alkalis and alcohols.

Conditions to avoid: Spontaneous polymerization.

11. TOXICOLOGICAL INFORMATION


Acute oral product toxicity: LD50 (rat) > 5,000 mg/kg (Estimated)

Acute dermal product toxicity: LD50 (rabbit) > 2,000 mg/kg (Estimated)

Toxicologically synergistic products: Not available.

Refer to the following for Irritancy of Product, Sensitization to Product, Carcinogenicity, Reproductive Toxicity, Teratogenicity,
and Mutagenicity.

OSHA Carcinogen
Hazardous components NTP Carcinogen IARC Carcinogen (Specifically ACGIH Carcinogen
Regulated)
Ethyl 2-cyanoacrylate No No No No
Hydroquinone No No No Group A3

Hazardous components LD50s and LC50s Health Effects/Target Organs


Ethyl 2-cyanoacrylate None Irritant, Allergen, Respiratory
Oral LD50 (RAT) = 320 mg/kg Blood, Bone Marrow, Central nervous
Hydroquinone Oral LD50 (RABBIT) = 540 mg/kg system, Developmental, Eyes, Immune
Dermal LD50 (RAT) = > 900 mg/kg system, Irritant, Liver, Mutagen, Skin, Thyroid

12. ECOLOGICAL INFORMATION


Ecological information: Not available.

13. DISPOSAL CONSIDERATIONS


Information provided is for unused product only.

Recommended method of disposal: Follow all local, state, federal and provincial regulations for disposal.

14. TRANSPORT INFORMATION


Canada Transportation of Dangerous Goods - Ground
Proper shipping name: Not regulated
Hazard class or division: None
Identification number: None
Packing group: None

International Air Transportation (ICAO/IATA)


Proper shipping name: Aviation regulated liquid, n.o.s. (Cyanoacrylate ester)
Hazard class or division: 9
Identification number: UN 3334
Packing group: III
Exceptions: (Not more than 500ml) Unrestricted

IDH number: 135465 Product name: LOCTITE 404 INSTANT ADHESIVE known as LOCTITE® 404™ INSTANT ADHESIVE
Page 4 of 5
Water Transportation (IMO/IMDG)
Proper shipping name: Not regulated
Hazard class or division: None
Identification number: None
Packing group: None

15. REGULATORY INFORMATION


Canada Regulatory Information

CEPA DSL/NDSL Status: All components are listed on or are exempt from listing on the Canadian Domestic
Substances List.

United States Regulatory Information

TSCA 8 (b) Inventory Status: All components are listed or are exempt from listing on the Toxic Substances Control Act
Inventory.

16. OTHER INFORMATION


This material safety data sheet contains changes from the previous version in sections: Reviewed MSDS. Reissued with
new date.

This product has been classified in accordance with the hazard criteria of the Controlled Products Regulation (CPR), and
the MSDS contains all the information required by the CPR.

Prepared by: Catherine Bimler, Regulatory Affairs Specialist

DISCLAIMER: The data contained herein are furnished for information only and are believed to be reliable. However, Henkel
Corporation and its affiliates (“Henkel”) does not assume responsibility for any results obtained by persons over whose methods
Henkel has no control. It is the user’s responsibility to determine the suitability of Henkel’s products or any production methods
mentioned herein for a particular purpose, and to adopt such precautions as may be advisable for the protection of property and
persons against any hazards that may be involved in the handling and use of any Henkel’s products. In light of the foregoing,
Henkel specifically disclaims all warranties, express or implied, including warranties of merchantability and fitness for a particular
purpose, arising from sale or use of Henkel’s products. Henkel further disclaims any liability for consequential or incidental damages
of any kind, including lost profits.

IDH number: 135465 Product name: LOCTITE 404 INSTANT ADHESIVE known as LOCTITE® 404™ INSTANT ADHESIVE
Page 5 of 5
MATERIAL SAFETY DATA SHEET
470 FEATHERSPRAY
Page : 1

SLUYTER COMPANY LTD.


375 Steelcase Road East
Markham, Ontario L3R 1G3 Canada
Tel (905) 475-6011 Fax (905) 475-3119

SECTION 01: CHEMICAL PRODUCT AND COMPANY IDENTIFICATION


MANUFACTURER-----------------------SLUYTER COMPANY LTD.
375 Steelcase Road East
Markham, Ontario L3R 1G3 Canada
Tel (905) 475-6011
PRODUCT NAME-----------------------470 FEATHERSPRAY.
PRODUCT USES-----------------------Foam adhesive.
CHEMICAL FAMILY--------------------Solvent based adhesive (Pressurized).

SECTION 02: COMPOSITION / INFORMATION ON INGREDIENTS


INGREDIENTS / % CAS / TLV LD/50, ROUTE, SPECIES LC/50, ROUTE, SPECIES
ACETONE
10 - 30 67-64-1 9750 mg/kg 16000 ppm 4 hours
750 ppm Oral (Rat) Inhalation (Rat)
CYCLOHEXANE
10 - 30 110-82-7 12705 mg/kg 50 ppm 1 hour
300 ppm Oral (Rat) Inhalation (Rat)
HEXANE
30 - 60 110-54-3 28710 mg/kg 120000 mg/m3
50 ppm Oral (Rat) Inhalation MUS
ISOBUTANE
10 - 30 75-28-5 Not Indicated Not indicated
800 ppm
PROPANE
10 - 30 74-98-6 Not indicated Not Indicated
1000 ppm

SECTION 03: HAZARDS IDENTIFICATION


ROUTE OF ENTRY:--------------------
SKIN CONTACT-----------------Can cause moderate skin irritation,
defatting and dermatitis.
SKIN ABSORPTION--------------Not available.
INHALATION CHRONIC-----------Breathing of high vapour concentrations
could cause dizziness, headache or even
unconsciousness. May be anesthetic which
could result in other central nervous system effects.
INGESTION--------------------Can cause gastro-intestinal irritation,
nausea, vomiting and diarrhea. Small
amounts of liquid aspirated into
respiratory system could cause severe
health effects (e.g. Bronchopneumonia or Pulmonary Edema).
EYE CONTACT------------------Contains materials that are moderately
irritating to the eyes.
EFFECTS OF ACUTE EXPOSURE----------Refer to "ROUTE ENTRY" section.
EFFECTS OF CHRONIC EXPOSURE--------Prolonged or repeated exposure to N-Hexane
may damage peripheral nerve tissue of the
arms and legs, which may result in
muscular weakness or loss of sensation in
the extremities. Prolonged or repeated skin
contact may cause drying or cracking of the skin.

Ref: 0000201E Preparation Date : May.07.2015

EMERGENCY - CALL CANUTEC (613) 996-6666 (Collect)


MATERIAL SAFETY DATA SHEET
470 FEATHERSPRAY
Page : 2

SECTION 04: FIRST AID MEASURES


EYE CONTACT------------------------Check for and remove any contact lenses.
Immediately flush with water for a minimum
of 20 minutes and get medical attention.
SKIN CONTACT-----------------------Remove contaminated clothing. Wash
affected area with water and soap. Seek
medical attention if irritation occurs or persists.
INHALATION-------------------------Remove patient to fresh air. If not
breathing, trained personnel should
administer artificial respiration. Get
medical attention.
INGESTION--------------------------Do NOT induce vomiting. Get immediate
medical attention.
ADDITIONAL INFORMATION-------------Contact your local poison control centre.

SECTION 05: FIRE FIGHTING MEASURES


FLAMMABILITY-----------------------Flammable.
UNDER WHAT CONDITIONS--------------Flammable aerosol. A dangerous fire hazard
when exposed to heat, flames or
sparks. CAUTION: CONTENTS UNDER PRESSURE.
Temperatures above 50°C may cause container to explode.
SPECIAL PROCEDURES-----------------A self-contained breathing apparatus is
required for fire fighting personnel. Use
water spray to cool fire exposed surfaces
and to protect personnel.
FLASH POINT (METHOD)--------------- -18°C TAG Closed Cup. Flame projection > 45 cm.
AUTO IGNITION TEMPERATURE----------Not available.
UPPER FLAMMABLE LIMIT (% VOL)------7.00.
LOWER FLAMMABLE LIMIT (% VOL)------0.60.
EXTINGUISHING MEDIA----------------Alcohol foam, CO2 or dry chemical.
HAZARDOUS COMBUSTION PRODUCTS------Oxides of Carbon (CO and CO2). Toxic fumes.
SENSITIVITY TO MECHANICAL----------Not available.
IMPACT
SENSITIVITY TO STATIC--------------Not available.
DISCHARGE

SECTION 06: ACCIDENTAL RELEASE MEASURES


LEAK/SPILL-------------------------Ventilate. Remove all sources of ignition,
open flames, sparks and heaters. Wear
protective gear (See SECTION 8).Small
spills can be wiped. Large spills must be
collected for disposal. Use a
non-combustible absorbent inorganic
material. Clean thoroughly with solvent
based cleaner. Prevent run-off into drains,
sewers and other waterways.

SECTION 07: HANDLING AND STORAGE


HANDLING PROCEDURES----------------Avoid skin and eye contact. Avoid breathing
vapours. Use adequate ventilation. Keep away
from heat, sparks and open flame.
STORAGE NEEDS----------------------Store in a cool area, away from all
sources of heat and ignition. Store in a
dry, well ventilated area. Do NOT store

Ref: 0000201E Preparation Date : May.07.2015

EMERGENCY - CALL CANUTEC (613) 996-6666 (Collect)


MATERIAL SAFETY DATA SHEET
470 FEATHERSPRAY
Page : 3
above 49°C.

SECTION 08: EXPOSURE CONTROLS / PERSONAL PROTECTION


PROTECTIVE EQUIPMENT:--------------
EYE/TYPE---------------------Safety glasses.
RESPIRATORY/TYPE-------------If used indoors on a continuous basis or
if the TLV is exceeded, the use of a
cartridge type respirator (NIOSH/MSHA
approved) is recommended.
GLOVES/ TYPE-----------------Not applicable.
CLOTHING/TYPE----------------Wear adequate protective clothing.
FOOTWEAR/TYPE----------------Safety boots as specified in workplace regulations.
OTHER/TYPE-------------------Eye bath and safety shower.
VENTILATION REQUIREMENTS-----------Natural or mechanical (Explosion Proof)
ventilation to keep vapour levels well below the TLV.

SECTION 09: PHYSICAL AND CHEMICAL PROPERTIES


PHYSICAL STATE---------------------Aerosol Can.
ODOUR------------------------------Petroleum Solvent Odour.
SPECIFIC GRAVITY-------------------0.75 - 0.85 (Liquid Contents).
ODOUR THRESHOLD (ppm)--------------Not available.
VAPOUR PRESSURE--------------------90 psig @ 20°C.
VAPOUR DENSITY (AIR=1)------------- > 1.00.
EVAPORATION RATE-------------------Not available.
BOILING POINT (deg C)--------------56°C.
pH---------------------------------Not applicable.
SOLUBILITY IN WATER (% W/W)--------Negligible.
COEFFICIENT OF WATER\OIL-----------Not available.
DISTRIBUTION
FREEZING POINT--------------------- < 0°C.
MELTING POINT (deg C)--------------Not applicable.
MOLECULAR WEIGHT-------------------Not applicable.

SECTION 10: STABILITY AND REACTIVITY


INCOMPATIBILITY--------------------Strong acids and strong bases. Oxidizing agents.
REACTIVITY CONDITIONS--------------Excessive heat, sparks and open flame.
HAZARDOUS PRODUCTS OF--------------Oxides of Carbon (CO and C02). Toxic
DECOMPOSITION fumes. Smoke.

SECTION 11: TOXICOLOGICAL INFORMATION


EXPOSURE LIMIT OF MATERIAL---------See "HAZARDOUS INGREDIENTS" in SECTION 2.
IRRITANCY OF MATERIAL--------------Moderate.
SENSITIZING CAPABILITY OF----------Not available.
MATERIAL
CARCINOGENICITY OF MATERIAL--------No information is available and no adverse
carcinogenic effects are anticipated.
TERATOGENICITY---------------------No information is available and no adverse
teratogenicity effects are anticipated.
MUTAGENICITY-----------------------No information is available and no adverse
mutagenicity effects are anticipated.
REPRODUCTIVE EFFECTS---------------No information is available and no adverse
reproductive effects are anticipated.
SYNERGISTIC MATERIALS--------------Not available.

SECTION 12: ECOLOGICAL INFORMATION


Ref: 0000201E Preparation Date : May.07.2015

EMERGENCY - CALL CANUTEC (613) 996-6666 (Collect)


MATERIAL SAFETY DATA SHEET
470 FEATHERSPRAY
Page : 4

ENVIRONMENTAL----------------------Not available. Can be dangerous if allowed


to enter drinking water intakes. Product
has an unaesthetic appearance and can be a
nuisance. Do not contaminate domestic or
irrigation water supplies, lakes, streams,
ponds and rivers.
BIODEGRADABILITY-------------------Not available. The solvent portion of this
product is biodegradable and vaporizes rapidly.

SECTION 13: DISPOSAL CONSIDERATIONS


WASTE DISPOSAL---------------------Contents under pressure. Do NOT puncture,
incinerate or expose to heat, even when
empty. Spilled material and water rinses
are classified as chemical waste. To be
disposed of in accordance with current
Local, Provincial and Federal regulations.

SECTION 14: TRANSPORT INFORMATION


T.D.G. CLASSIFICATION-------------- SHIPPING NAME – Aerosols
WHMIS – Consumer Commodity
PACKAGING GROUP- Not Applicable
UN NUMBER - 1950
If the shipment exceeds 500 kg in weight - shipped as
CONSUMER COMMODITY - AEROSOLS FLAMMABLE CLASS 2.1.

SECTION 15: REGULATORY INFORMATION


CPR COMPLIANCE---------------------This product has been classified in
accordance with the hazard criteria of the
CPR and the MSDS contains all the
information required by the CPR.
WHMIS CLASSIFICATION---------------Class A Class B Div.5 Flammable. Aerosol
Class D Div.2 Subdiv.B.

SECTION 16: OTHER INFORMATION


IMPORTANT:-------------------------The information on this Material Safety
Data Sheet is furnished without warranty,
expressed or implied. All the information
appearing herein is based upon data
obtained from manufacturers and/or
recognized technical sources. While the
information is believed to be accurate, we
make no representations for the accuracy or sufficiency.

Ref: 0000201E Preparation Date : May.07.2015

EMERGENCY - CALL CANUTEC (613) 996-6666 (Collect)


MATERIAL SAFETY DATA SHEET
476 SPRAY ADHESIVE
Page : 1

SLUYTER COMPANY LTD.


375 Steelcase Road East
Markham, Ontario L3R 1G3 Canada
Tel (905) 475-6011 Fax (905) 475-3119

SECTION 01: CHEMICAL PRODUCT AND COMPANY IDENTIFICATION


MANUFACTURER-----------------------SLUYTER COMPANY LTD.
375 Steelcase Road East
Markham, Ontario L3R 1G3 Canada
Tel (905) 475-6011
PRODUCT NAME-----------------------476 SPRAY ADHESIVE
PRODUCT USES-----------------------Foam adhesive.
CHEMICAL FAMILY--------------------Solvent based adhesive (Pressurized).

SECTION 02: COMPOSITION / INFORMATION ON INGREDIENTS


INGREDIENTS / % CAS / TLV LD/50, ROUTE, SPECIES LC/50, ROUTE, SPECIES
ACETONE
10 - 30 67-64-1 9750 mg/kg 16000 ppm 4 hours
750 ppm Oral (Rat) Inhalation (Rat)
CYCLOHEXANE
10 - 30 110-82-7 12705 mg/kg 50 ppm 1 hour
300 ppm Oral (Rat) Inhalation (Rat)
HEXANE
30 - 60 110-54-3 28710 mg/kg 120000 mg/m3
50 ppm Oral (Rat) Inhalation MUS
ISOBUTANE
10 - 30 75-28-5 Not Indicated Not indicated
800 ppm
PROPANE
10 - 30 74-98-6 Not indicated Not Indicated
1000 ppm

SECTION 03: HAZARDS IDENTIFICATION


ROUTE OF ENTRY:--------------------
SKIN CONTACT-----------------Can cause moderate skin irritation,
defatting and dermatitis.
SKIN ABSORPTION--------------Not available.
INHALATION CHRONIC-----------Breathing of high vapour concentrations
could cause dizziness, headache or even
unconsciousness. May be anesthetic which
could result in other central nervous system effects.
INGESTION--------------------Can cause gastro-intestinal irritation,
nausea, vomiting and diarrhea. Small
amounts of liquid aspirated into
respiratory system could cause severe
health effects (e.g. Bronchopneumonia or Pulmonary Edema).
EYE CONTACT------------------Contains materials that are moderately
irritating to the eyes.
EFFECTS OF ACUTE EXPOSURE----------Refer to "ROUTE ENTRY" section.
EFFECTS OF CHRONIC EXPOSURE--------Prolonged or repeated exposure to N-Hexane
may damage peripheral nerve tissue of the
arms and legs, which may result in
muscular weakness or loss of sensation in
the extremities. Prolonged or repeated skin
contact may cause drying or cracking of the skin.

Ref: 0000202E Preparation Date : May.07.2015

EMERGENCY - CALL CANUTEC (613) 996-6666 (Collect)


MATERIAL SAFETY DATA SHEET
476 SPRAY ADHESIVE
Page : 2

SECTION 04: FIRST AID MEASURES


EYE CONTACT------------------------Check for and remove any contact lenses.
Immediately flush with water for a minimum
of 20 minutes and get medical attention.
SKIN CONTACT-----------------------Remove contaminated clothing. Wash
affected area with water and soap. Seek
medical attention if irritation occurs or persists.
INHALATION-------------------------Remove patient to fresh air. If not
breathing, trained personnel should
administer artificial respiration. Get
medical attention.
INGESTION--------------------------Do NOT induce vomiting. Get immediate
medical attention.
ADDITIONAL INFORMATION-------------Contact your local poison control centre.

SECTION 05: FIRE FIGHTING MEASURES


FLAMMABILITY-----------------------Flammable.
UNDER WHAT CONDITIONS--------------Flammable aerosol. A dangerous fire hazard
when exposed to heat, flames or
sparks. CAUTION: CONTENTS UNDER PRESSURE.
Temperatures above 50°C may cause container to explode.
SPECIAL PROCEDURES-----------------A self-contained breathing apparatus is
required for fire fighting personnel. Use
water spray to cool fire exposed surfaces
and to protect personnel.
FLASH POINT (METHOD)--------------- -18°C TAG Closed Cup. Flame projection > 45 cm.
AUTO IGNITION TEMPERATURE----------Not available.
UPPER FLAMMABLE LIMIT (% VOL)------7.00.
LOWER FLAMMABLE LIMIT (% VOL)------0.60.
EXTINGUISHING MEDIA----------------Alcohol foam, CO2 or dry chemical.
HAZARDOUS COMBUSTION PRODUCTS------Oxides of Carbon (CO and CO2). Toxic fumes.
SENSITIVITY TO MECHANICAL----------Not available.
IMPACT
SENSITIVITY TO STATIC--------------Not available.
DISCHARGE

SECTION 06: ACCIDENTAL RELEASE MEASURES


LEAK/SPILL-------------------------Ventilate. Remove all sources of ignition,
open flames, sparks and heaters. Wear
protective gear (See SECTION 8).Small
spills can be wiped. Large spills must be
collected for disposal. Use a
non-combustible absorbent inorganic
material. Clean thoroughly with solvent
based cleaner. Prevent run-off into drains,
sewers and other waterways.

SECTION 07: HANDLING AND STORAGE


HANDLING PROCEDURES----------------Avoid skin and eye contact. Avoid breathing
vapours. Use adequate ventilation. Keep away
from heat, sparks and open flame.
STORAGE NEEDS----------------------Store in a cool area, away from all
sources of heat and ignition. Store in a
dry, well ventilated area. Do NOT store

Ref: 0000202E Preparation Date : May.07.2015

EMERGENCY - CALL CANUTEC (613) 996-6666 (Collect)


MATERIAL SAFETY DATA SHEET
476 SPRAY ADHESIVE
Page : 3
above 49°C.

SECTION 08: EXPOSURE CONTROLS / PERSONAL PROTECTION


PROTECTIVE EQUIPMENT:--------------
EYE/TYPE---------------------Safety glasses.
RESPIRATORY/TYPE-------------If used indoors on a continuous basis or
if the TLV is exceeded, the use of a
cartridge type respirator (NIOSH/MSHA
approved) is recommended.
GLOVES/ TYPE-----------------Not applicable.
CLOTHING/TYPE----------------Wear adequate protective clothing.
FOOTWEAR/TYPE----------------Safety boots as specified in workplace regulations.
OTHER/TYPE-------------------Eye bath and safety shower.
VENTILATION REQUIREMENTS-----------Natural or mechanical (Explosion Proof)
ventilation to keep vapour levels well below the TLV.

SECTION 09: PHYSICAL AND CHEMICAL PROPERTIES


PHYSICAL STATE---------------------Aerosol Can.
ODOUR------------------------------Petroleum Solvent Odour.
SPECIFIC GRAVITY-------------------0.75 - 0.85 (Liquid Contents).
ODOUR THRESHOLD (ppm)--------------Not available.
VAPOUR PRESSURE--------------------90 psig @ 20°C.
VAPOUR DENSITY (AIR=1)------------- > 1.00.
EVAPORATION RATE-------------------Not available.
BOILING POINT (deg C)--------------56°C.
pH---------------------------------Not applicable.
SOLUBILITY IN WATER (% W/W)--------Negligible.
COEFFICIENT OF WATER\OIL-----------Not available.
DISTRIBUTION
FREEZING POINT--------------------- < 0°C.
MELTING POINT (deg C)--------------Not applicable.
MOLECULAR WEIGHT-------------------Not applicable.

SECTION 10: STABILITY AND REACTIVITY


INCOMPATIBILITY--------------------Strong acids and strong bases. Oxidizing agents.
REACTIVITY CONDITIONS--------------Excessive heat, sparks and open flame.
HAZARDOUS PRODUCTS OF--------------Oxides of Carbon (CO and C02). Toxic
DECOMPOSITION fumes. Smoke.

SECTION 11: TOXICOLOGICAL INFORMATION


EXPOSURE LIMIT OF MATERIAL---------See "HAZARDOUS INGREDIENTS" in SECTION 2.
IRRITANCY OF MATERIAL--------------Moderate.
SENSITIZING CAPABILITY OF----------Not available.
MATERIAL
CARCINOGENICITY OF MATERIAL--------No information is available and no adverse
carcinogenic effects are anticipated.
TERATOGENICITY---------------------No information is available and no adverse
teratogenicity effects are anticipated.
MUTAGENICITY-----------------------No information is available and no adverse
mutagenicity effects are anticipated.
REPRODUCTIVE EFFECTS---------------No information is available and no adverse
reproductive effects are anticipated.
SYNERGISTIC MATERIALS--------------Not available.

SECTION 12: ECOLOGICAL INFORMATION


Ref: 0000202E Preparation Date : May.07.2015

EMERGENCY - CALL CANUTEC (613) 996-6666 (Collect)


MATERIAL SAFETY DATA SHEET
476 SPRAY ADHESIVE
Page : 4

ENVIRONMENTAL----------------------Not available. Can be dangerous if allowed


to enter drinking water intakes. Product
has an unaesthetic appearance and can be a
nuisance. Do not contaminate domestic or
irrigation water supplies, lakes, streams,
ponds and rivers.
BIODEGRADABILITY-------------------Not available. The solvent portion of this
product is biodegradable and vaporizes rapidly.

SECTION 13: DISPOSAL CONSIDERATIONS


WASTE DISPOSAL---------------------Contents under pressure. Do NOT puncture,
incinerate or expose to heat, even when
empty. Spilled material and water rinses
are classified as chemical waste. To be
disposed of in accordance with current
Local, Provincial and Federal regulations.

SECTION 14: TRANSPORT INFORMATION


T.D.G. CLASSIFICATION-------------- SHIPPING NAME – Aerosols
WHMIS – Consumer Commodity
PACKAGING GROUP- Not Applicable
UN NUMBER - 1950
If the shipment exceeds 500 kg in weight - shipped as
CONSUMER COMMODITY - AEROSOLS FLAMMABLE CLASS 2.1.

SECTION 15: REGULATORY INFORMATION


CPR COMPLIANCE---------------------This product has been classified in
accordance with the hazard criteria of the
CPR and the MSDS contains all the
information required by the CPR.
WHMIS CLASSIFICATION---------------Class A Class B Div.5 Flammable. Aerosol
Class D Div.2 Subdiv.B.

SECTION 16: OTHER INFORMATION


IMPORTANT:-------------------------The information on this Material Safety
Data Sheet is furnished without warranty,
expressed or implied. All the information
appearing herein is based upon data
obtained from manufacturers and/or
recognized technical sources. While the
information is believed to be accurate, we
make no representations for the accuracy or sufficiency.

Ref: 0000202E Preparation Date : May.07.2015

EMERGENCY - CALL CANUTEC (613) 996-6666 (Collect)


Safety Data Sheet

Accel TB Wipes (US)


SECTION 1. IDENTIFICATION
Product Identifier Accel TB Wipes (US)
Recommended Use Disinfectant Cleaner.
Manufacturer Virox Technologies Inc., 2770 Coventry Rd., Oakville, ON, L6H 6R1, 905-813-0110
Emergency Phone No. Virox Technologies Inc., 1-800-387-7578
SDS No. 000807
SECTION 2. HAZARDS IDENTIFICATION
GHS Classification
Not classified under any GHS hazard classes.
GHS Label Elements
Signal Word: None
Hazard Pictogram: None
Hazard Statement (s): None
Precautionary Statement (s):
Prevention: Wash thoroughly after handling. See section 8 for Individual Protective Measures information.
Response: None
Storage: No other specific measures identified. See section 7 for Handling and Storage information.
Disposal: See section 13 for Waste Disposal information.
Other Hazards
The product contains no substances which at their given concentration are considered to be hazardous to health.
SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS
Mixture:
Chemical Name CAS No. % Other Identifiers
Hydrogen peroxide 7722-84-1 0.5
Notes
Active ingredients are listed above. All ingredients of this product are listed on the US EPA TSCA Inventory.
EPA Registration Number 74559-3
SECTION 4. FIRST-AID MEASURES
First-aid Measures
Inhalation
No specific first aid measures are required.
Skin Contact
No specific first aid measures are required.
Eye Contact
No specific first aid measures are required.
Ingestion
No specific first aid measures are required.
SECTION 5. FIRE-FIGHTING MEASURES
Extinguishing Media
Suitable Extinguishing Media
Not combustible. Use extinguishing agent suitable for surrounding fire.

Product Identifier: Accel TB Wipes (US)


SDS No.: 000807 Page 01 of 05
Date of Preparation: October 01, 2014
Unsuitable Extinguishing Media
None known.
Specific Hazards Arising from the Chemical
None known.
Special Protective Equipment and Precautions for Fire-fighters
Wear self-contained breathing apparatus for fire fighting if necessary.
SECTION 6. ACCIDENTAL RELEASE MEASURES
Personal Precautions, Protective Equipment, and Emergency Procedures
Use the personal protective equipment recommended in Section 8 of this safety data sheet.
Environmental Precautions
Review federal, provincial and local government requirements prior to disposal.
Methods and Materials for Containment and Cleaning Up
Never flush these wipes into toilets. Discard in solid waste bin.
Towelettes contaminated with blood or body fluids should be disposed of according to federal, provincial, and local
regulations for infectious waste disposal.
SECTION 7. HANDLING AND STORAGE
Precautions for Safe Handling
Use good industrial hygiene practices in handling this material. FOR COMMERCIAL AND INDUSTRIAL USE ONLY.
Conditions for Safe Storage
Store in an area that is out of direct sunlight. Avoid storage at elevated temperatures.
KEEP OUT OF REACH OF CHILDREN.
SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Exposure Guidelines
ACGIH OSHA PEL AIHA WEEL
Chemical Name TWA STEL TWA Ceiling 8-hr TWA TWA
Hydrogen Peroxide 1 ppm 1 ppm
Appropriate Engineering Controls
No specific ventilation requirements.
Individual Protection Measures
Eye/Face Protection
Not required if product is used as directed.
Skin Protection
Not required if product is used as directed.
Respiratory Protection
Not required if product is used as directed.
SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES
Basic Physical and Chemical Properties
Odour Threshold Not available
pH 2.5 - 3.5
Melting Point/Freezing Point Not available (freezing)
Initial Boiling Point/Range Not available
Flash Point > 93 ºC (199 ºF)
Evaporation Rate Not available
Flammability (solid, gas) Not applicable (liquid).
Upper/Lower Flammability or Not available (upper); Not available (lower)
Explosive Limit
Vapour Pressure Not available

Product Identifier: Accel TB Wipes (US)


SDS No.: 000807 Page 02 of 05
Date of Preparation: October 01, 2014
Vapour Density (air = 1) Not available
Relative Density (water = 1) 1.01 at 20 ºC
Solubility Soluble in water
Partition Coefficient, Not available
n-Octanol/Water (Log Kow)
Auto-ignition Temperature Not available
Viscosity 1.122 centistokes at 20 ºC (kinematic)
Other Information
Physical State Wet wipes
Critical Temperature Not available
Appearance Clear, colourless liquid saturated on wipes.
% Volatile 0.0%
Odour Faint, Characteristic odour
SECTION 10. STABILITY AND REACTIVITY
Reactivity
Not reactive.
Chemical Stability
This product is stable.
Possibility of Hazardous Reactions
Hazardous polymerization will not occur.
Conditions to Avoid
High temperatures.
Incompatible Materials
Do not mix with concentrated bleach products.
Hazardous Decomposition Products
None known.
SECTION 11. TOXICOLOGICAL INFORMATION
Likely Routes of Exposure
Inhalation; skin contact; eye contact; ingestion.
Acute Toxicity
LC50 (Inhalation): > 2.59 mg/L (Rats).
LD50 (oral): > 5000 mg / kg (Rats).
LD50 (Dermal): > 5000 mg/kg (Rabbit)
Skin Corrosion/Irritation
Not classified under GHS criteria.
Serious Eye Damage/Irritation
Not classified under GHS criteria.
STOT (Specific Target Organ Toxicity) - Single Exposure
Inhalation
Not classified under GHS criteria.
Skin Absorption
Not classified under GHS criteria.
Ingestion
Non-hazardous by GHS criteria. Like any product not designed to be ingested, this product may cause stomach
distress if ingested in large quantities.
Aspiration Hazard
Not classified under GHS criteria.

Product Identifier: Accel TB Wipes (US)


SDS No.: 000807 Page 03 of 05
Date of Preparation: October 01, 2014
STOT (Specific Target Organ Toxicity) - Repeated Exposure
Respiratory and/or Skin Sensitization
Skin Sensitization: not a skin sensitizer.
Respiratory sensitizer. not a respiratory sensitizer.
Carcinogenicity
Not classified under GHS criteria.
Reproductive Toxicity
Development of Offspring
Not classified under GHS criteria.
Sexual Function and Fertility
Not classified under GHS criteria.
Germ Cell Mutagenicity
Not classified under GHS criteria.
Interactive Effects
None known.
SECTION 12. ECOLOGICAL INFORMATION
This section is not required by OSHA.
SECTION 13. DISPOSAL CONSIDERATIONS
Disposal Methods
Review the STORAGE and DISPOSAL instructions on product label prior to disposal.
SECTION 14. TRANSPORT INFORMATION
Not regulated under Canadian TDG Regulations. Not regulated under US DOT Regulations.
Special Precautions Not applicable
for User
IMO/IMDG clarification:
Not regulated.
SECTION 15. REGULATORY INFORMATION
Safety, Health and Environmental Regulations
USA
Toxic Substances Control Act (TSCA) Section 8(b)
All ingredients are on the TSCA Inventory or are exempt from TSCA Inventory requirements under 40 CFR 720.

Other U.S. Federal Regulations

SARA 302/304/311/312 extremelt hazardous substances: No listed substance.


SARA 302/304 emergency planning and notification: No listed substance.

US Regulations:

EPA Registration No.: 74559-3

This chemical is a pesticide product registered by the US Environmental Protection Agency and is subject to certain
labelling requirements under federal pesticide law. These requirements differ from the classification criteria and
hazard information required for safety data sheets (SDS) and for workplace labels for non-pesticide chemicals. The
following is the hazard information as required on the pesticide label: KEEP OUT OF REACH OF CHILDREN.

California Prop. 65: No listed substance.

Product Identifier: Accel TB Wipes (US)


SDS No.: 000807 Page 04 of 05
Date of Preparation: October 01, 2014
SECTION 16. OTHER INFORMATION
HMIS Rating Health - 0 Flammability - 0 Physical Hazard - 0
SDS Prepared By Virox Technologies Inc.
Phone No. (800) 387-7578
Date of Preparation October 01, 2014
Additional Information For an updated MSDS please contact the supplier/ manufacturer listed on the first page of this
document. Information contained herein was obtained from sources considered technically
accurate and reliable. While every effort has been made to ensure full disclosure of product
hazards, in some cases data is not available and is so stated. Since condition of actual
product use are beyond control of the supplier, it is assumed that users of this material have
been fully trained according to the requirement of all applicable legislation and regulatory
instruments. No warranty, expressed or implied, is made and manufacturer/supplier will not be
liable for any losses, injuries or consequential damages which may result from the use of or
reliance on any information contained in this document. The contents of this document have
been prepared in accordance with the OSHA Hazard Communication Standards (2012) and
GHS (Globally Harmonized System of Classification and Labelling of Chemicals).

Product Identifier: Accel TB Wipes (US)


SDS No.: 000807 Page 05 of 05
Date of Preparation: October 01, 2014
Material Safety Data Sheet
Acetylene

1. Product and company identification


Product name : Acetylene
Synonym : ethyne; Ethyne (acetylene); Ethine; Methyl cyanide
Material uses : Various
CAS number : 74-86-2
Supplier/Manufacturer : Air Liquide Canada Inc.
1250, René-Lévesque West, Suite 1700
Montreal, QC
H3B 5E6
www.airliquide.ca
1-800-817-7697
Prepared by : IHS
In case of emergency : (514) 878-1667

2. Hazards identification
Physical state : Gas.
Color : Colorless.
Odor : Mild. Ethereal.
Emergency overview
Signal word : DANGER!
Hazard statements : FLAMMABLE GAS. MAY CAUSE FLASH FIRE. UNSTABLE. SENSITIVE TO HEAT
OR SHOCK. MAY BECOME EXPLOSIVE. HIGH PRESSURE GAS. GAS REDUCES
OXYGEN AVAILABLE FOR BREATHING. AT VERY HIGH CONCENTRATIONS, CAN
DISPLACE THE NORMAL AIR AND CAUSE SUFFOCATION FROM LACK OF
OXYGEN. MAY CAUSE TARGET ORGAN DAMAGE, BASED ON ANIMAL DATA.
Precautions : Contains gas under pressure. In a fire or if heated, a pressure increase will occur and
the container may burst or explode. At very high concentrations, can displace the
normal air and cause suffocation from lack of oxygen. Avoid shock and friction. Keep
away from heat, sparks and flame. Do not puncture or incinerate container. Do not
enter storage areas and confined spaces unless adequately ventilated. Do not breathe
gas. Avoid contact with skin and clothing. Use only with adequate ventilation. Keep
container tightly closed and sealed until ready for use. Keep container tightly closed.
Routes of entry : Dermal contact. Eye contact. Inhalation.
Potential acute health effects
Inhalation : At very high concentrations, can displace the normal air and cause suffocation from lack
of oxygen.
Ingestion : As this product is a gas, refer to the inhalation section.
Skin : Contact with rapidly expanding gas may cause burns or frostbite.
Eyes : Contact with rapidly expanding gas may cause burns or frostbite.
Potential chronic health effects
Chronic effects : May cause target organ damage, based on animal data.
Carcinogenicity : No known significant effects or critical hazards.
Mutagenicity : No known significant effects or critical hazards.
Teratogenicity : No known significant effects or critical hazards.
Developmental effects : No known significant effects or critical hazards.

9/4/2015 Canada 1/9


www.airliquide.ca
1-800-817-7697
Acetylene

2. Hazards identification
Fertility effects : No known significant effects or critical hazards.
Target organs : May cause damage to the following organs: lungs, upper respiratory tract, central
nervous system (CNS).

Over-exposure signs/symptoms
Inhalation : No specific data.
Ingestion : No specific data.
Skin : No specific data.
Eyes : No specific data.
Medical conditions : Pre-existing disorders involving any target organs mentioned in this MSDS as being at
aggravated by over- risk may be aggravated by over-exposure to this product.
exposure

3. Composition/information on ingredients
Name CAS number %
acetylene 74-86-2 100
There are no additional ingredients present which, within the current knowledge of the supplier and in the
concentrations applicable, are classified as hazardous to health or the environment and hence require reporting
in this section.

4. First aid measures


Eye contact : Check for and remove any contact lenses. Immediately flush eyes with plenty of water
for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical
attention immediately.
Skin contact : In case of contact, immediately flush skin with plenty of water for at least 15 minutes
while removing contaminated clothing and shoes. To avoid the risk of static discharges
and gas ignition, soak contaminated clothing thoroughly with water before removing it.
Wash clothing before reuse. Clean shoes thoroughly before reuse. Get medical
attention immediately.
Inhalation : Move exposed person to fresh air. If not breathing, if breathing is irregular or if
respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel.
Loosen tight clothing such as a collar, tie, belt or waistband. Get medical attention
immediately.
Ingestion : As this product is a gas, refer to the inhalation section.
Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. If it is
suspected that fumes are still present, the rescuer should wear an appropriate mask or
self-contained breathing apparatus. It may be dangerous to the person providing aid to
give mouth-to-mouth resuscitation.
Antidote information
Product/ingredient name Antidote information
No antidote information known

Notes to physician : No specific treatment. Treat symptomatically. Contact poison treatment specialist
immediately if large quantities have been ingested or inhaled.

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Acetylene

5. Fire-fighting measures
Flammability of the product : Contains gas under pressure. Flammable gas. Material will produce a vigorous
reaction under conditions of shock, pressure or temperature. In a fire or if heated, a
pressure increase will occur and the container may burst, with the risk of a subsequent
explosion.
Extinguishing media
Suitable : Use an extinguishing agent suitable for the surrounding fire.
Not suitable : None known.
Special exposure hazards : Promptly isolate the scene by removing all persons from the vicinity of the incident if
there is a fire. First move people out of line-of-sight of the scene and away from
windows. No action shall be taken involving any personal risk or without suitable
training. Contact supplier immediately for specialist advice. Move containers from fire
area if this can be done without risk. Use water spray to keep fire-exposed containers
cool. If involved in fire, shut off flow immediately if it can be done without risk. If this is
impossible, withdraw from area and allow fire to burn. Fight fire from protected location
or maximum possible distance. Do not fight fire when it reaches the material. Withdraw
from fire and let it burn.
Hazardous thermal : Decomposition products may include the following materials:
decomposition products carbon dioxide
carbon monoxide
Special protective : Fire-fighters should wear appropriate protective equipment and self-contained breathing
equipment for fire-fighters apparatus (SCBA) with a full face-piece operated in positive pressure mode. Fire-
fighters' protective clothing will only provide limited protection.

6. Accidental release measures


Personal precautions : Accidental releases pose a serious fire or explosion hazard. Immediately contact
emergency personnel. No action shall be taken involving any personal risk or without
suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected
personnel from entering. Shut off all ignition sources. No flares, smoking or flames in
hazard area. Avoid breathing gas. Provide adequate ventilation. Wear appropriate
respirator when ventilation is inadequate. Put on appropriate personal protective
equipment (see Section 8). If leak is in user's equipment, be certain to purge piping with
an inert gas prior to attempting repairs. Never fix a leak while the system is under
pressure. If leak is on container or container valve, contact the closest Air Liquide
Canada location.
Environmental precautions : Ensure emergency procedures to deal with accidental gas releases are in place to avoid
contamination of the environment. Inform the relevant authorities if the product has
caused environmental pollution (sewers, waterways, soil or air).
Methods for cleaning up
Small spill : Immediately contact emergency personnel. Stop leak if without risk. Use spark-proof
tools and explosion-proof equipment.
Large spill : Immediately contact emergency personnel. Stop leak if without risk. Use spark-proof
tools and explosion-proof equipment. Note: see Section 1 for emergency contact
information and Section 13 for waste disposal.

7. Handling and storage


Handling : Put on appropriate personal protective equipment (see Section 8). Eating, drinking and
smoking should be prohibited in areas where this material is handled, stored and
processed. Workers should wash hands and face before eating, drinking and smoking.
Remove contaminated clothing and protective equipment before entering eating areas.
Contains gas under pressure. Avoid contact with eyes, skin and clothing. Avoid
breathing gas. Use only with adequate ventilation. Wear appropriate respirator when
ventilation is inadequate. Do not enter storage areas and confined spaces unless
adequately ventilated. Store and use away from heat, sparks, open flame or any other
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Acetylene

7. Handling and storage


ignition source. Use a specifically designed Cap Removal Tool to loosen over tightened
or stuck valve protection caps. NEVER insert an object such a wrench, screwdriver, pry
bar, etc… into the closed valve protection cap openings. Doing so may inadvertently
damage or open the valve resulting in uncontrolled product release with dangerous
consequences. If you experience any difficulty using the cylinder package, discontinue
its use and contact the supplier. Use explosion-proof electrical (ventilating, lighting and
material handling) equipment. Use non-sparking tools. Valve protection caps must
remain in place unless cylinder is secured with valve outlet piped to usage point. Do not
drag, slide or roll cylinders. Use a suitable hand truck for cylinder movement. Use a
pressure regulator when connecting cylinder to lower pressure piping or systems. Do
not heat cylinder by any means to increase the discharge rate of product from the
cylinder. Use a check valve or trap in the discharge line to prevent hazardous back flow
to the cylinder. Do not tamper with (valve) safety device. Close valve after each use and
when empty.
Storage : Protect cylinders from physical damage. Store in cool, dry, well-ventilated area of non
combustible construction away from heavily trafficked areas and emergency exits. Do
not allow the temperature where cylinders are stored to exceed 52°C/125°F. Cylinders
must be stored upright and firmly secured to prevent falling or being knocked over. Full
and empty cylinders should be segregated. Use a "first in - first out" inventory system to
prevent full cylinders being stored for excessive periods of time. Store in accordance
with local regulations. Store in a segregated and approved area. Store in a dry, cool
and well-ventilated area, away from incompatible materials (see Section 10). Protect
from sunlight. Eliminate all ignition sources. Keep container tightly closed and sealed
until ready for use.

8. Exposure controls/personal protection


Occupational exposure limits TWA (8 hours) STEL (15 mins) Ceiling

Ingredient List name ppm mg/m³ Other ppm mg/m³ Other ppm mg/m³ Other Notations
acetylene Simple asphyxiant. [2]

[2]Oxygen Depletion [Asphyxiant]

Consult local authorities for acceptable exposure limits.


Recommended monitoring : If this product contains ingredients with exposure limits, personal, workplace
procedures atmosphere or biological monitoring may be required to determine the effectiveness of
the ventilation or other control measures and/or the necessity to use respiratory
protective equipment. Reference should be made to appropriate monitoring standards.
Reference to national guidance documents for methods for the determination of
hazardous substances will also be required.
Engineering measures : Use only with adequate ventilation. Engineering controls may be required to control the
primary or secondary risks associated with this product. Use process enclosures, local
exhaust ventilation or other engineering controls to keep worker exposure to airborne
contaminants below any recommended or statutory limits. The engineering controls
also need to keep gas, vapor or dust concentrations below any lower explosive limits.
Use explosion-proof ventilation equipment.
Hygiene measures : Wash hands, forearms and face thoroughly after handling chemical products, before
eating, smoking and using the lavatory and at the end of the working period.
Appropriate techniques should be used to remove potentially contaminated clothing.
Wash contaminated clothing before reusing. Ensure that eyewash stations and safety
showers are close to the workstation location.
Personal protection

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Acetylene

8. Exposure controls/personal protection


Respiratory : Use a properly fitted, air-purifying or air-fed respirator complying with an approved
standard if a risk assessment indicates this is necessary. If operating conditions cause
high gas concentrations to be produced or any recommended or statutory exposure limit
is exceeded, use an air-fed respirator or self-contained breathing apparatus. The gas
can cause asphyxiation without warning by replacing the oxygen in the air. Respirator
selection must be based on known or anticipated exposure levels, the hazards of the
product and the safe working limits of the selected respirator.
Hands : Chemical-resistant, impervious gloves complying with an approved standard should be
worn at all times when handling chemical products if a risk assessment indicates this is
necessary. Considering the parameters specified by the glove manufacturer, check
during use that the gloves are still retaining their protective properties. It should be
noted that the time to breakthrough for any glove material may be different for different
glove manufacturers. In the case of mixtures, consisting of several substances, the
protection time of the gloves cannot be accurately estimated.
Eyes : Safety eyewear complying with an approved standard should be used when a risk
assessment indicates this is necessary to avoid exposure to liquid splashes, mists or
dusts. If contact is possible, the following protection should be worn, unless the
assessment indicates a higher degree of protection: safety glasses with side-shields.
Skin : Personal protective equipment for the body should be selected based on the task being
performed and the risks involved and should be approved by a specialist before
handling this product.
When there is a risk of ignition from static electricity, wear anti-static protective clothing.
For the greatest protection from static discharges, clothing should include anti-static
overalls, boots and gloves.
Environmental exposure : Emissions from ventilation or work process equipment should be checked to ensure
controls they comply with the requirements of environmental protection legislation. In some
cases, fume scrubbers, filters or engineering modifications to the process equipment
will be necessary to reduce emissions to acceptable levels.

9. Physical and chemical properties


Physical state : Gas.
Flash point : Closed cup: -18.15°C (-0.67°F)
Auto-ignition temperature : 305°C (581°F)
Flammable limits : Lower: 2.5%
Upper: 100%
Color : Colorless.
Odor : Mild. Ethereal.
Molecular weight : 26.04 g/mole
Molecular formula : C2-H2
pH : Not available.
Boiling/condensation point : Not available.
Melting/freezing point : -81°C (-113.8°F)
Critical temperature : 35.25°C (95.4°F)
Relative density : 0.9
Density : 0.001 g/cm³ [20°C (68°F)]
Vapor pressure : 4535 kPa (34015.26 mm Hg) [room temperature]
Vapor density : 0.907 [Air = 1]
Odor threshold : Not available.
Evaporation rate : Not available.
Viscosity : Not available.

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Acetylene

9. Physical and chemical properties


Solubility : Not available.
Water solubility (g/l) : 1.2 g/l
LogKow : 0.37

10. Stability and reactivity


Chemical stability : Unstable (reactive) material. See "Possibility of Hazardous Reactions" for further
information.
Conditions to avoid : Avoid all possible sources of ignition (spark or flame). Do not pressurize, cut, weld,
braze, solder, drill, grind or expose containers to heat or sources of ignition. Avoid
shock and friction.
Incompatible materials : Reactive or incompatible with the following materials: oxidizing materials.
Reacts with oxygen. Violent reaction may occur.
Hazardous decomposition : Under normal conditions of storage and use, hazardous decomposition products should
products not be produced.
Possibility of hazardous : Hazardous reactions or instability may occur under certain conditions of storage or use.
reactions Conditions may include the following:
shock
friction
high temperature
Reactions may include the following:
risk of explosion
Under normal conditions of storage and use, hazardous polymerization will not occur.

11. Toxicological information


Acute toxicity
Not available.
Chronic toxicity
Not available.

Irritation/Corrosion
Not available.
Sensitizer
Not available.
Carcinogenicity
Classification
Not available.
Mutagenicity
Not available.
Teratogenicity
Not available.

Reproductive toxicity
Not available.

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Acetylene

12. Ecological information


Ecotoxicity : This product shows a low bioaccumulation potential.
Aquatic ecotoxicity
Not available.
Persistence/degradability
Not available.
Partition coefficient: n- : 0.37
octanol/water
Bioconcentration factor : Not available.
Mobility : Not available.
Toxicity of the products of : Not available.
biodegradation
Other adverse effects : No known significant effects or critical hazards.

13. Disposal considerations


Waste disposal : The generation of waste should be avoided or minimized wherever possible. Disposal of
this product, solutions and any by-products should at all times comply with the
requirements of environmental protection and waste disposal legislation and any
regional local authority requirements. Empty pressure vessels should be returned to the
supplier. Waste packaging should be recycled.
Disposal should be in accordance with applicable regional, national and local laws and regulations.
Refer to Section 7: HANDLING AND STORAGE and Section 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
for additional handling information and protection of employees.

14. Transport information


Regulatory UN number Proper shipping Classes PG* Label Additional
information name information
TDG Classification UN1001 ACETYLENE, 2.1 - Explosive Limit and
DISSOLVED Limited Quantity Index
0

Passenger Carrying Ship


Index
75

Passenger Carrying Road


or Rail Index
Forbidden

Special provisions
38

IMDG Class UN1001 ACETYLENE, 2.1 - Emergency schedules


DISSOLVED (EmS)
_F-D_, _S-U_

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Acetylene

14. Transport information


IATA-DGR Class UN1001 Acetylene, dissolved 2.1 - Passenger and Cargo
AircraftQuantity limitation:
Forbidden
Packaging instructions:
Forbidden
Cargo Aircraft Only
Quantity limitation: 15 kg
Packaging instructions: 200
Limited Quantities -
Passenger AircraftQuantity
limitation: Forbidden
Packaging instructions:
Forbidden

Special provisions
A1

PG* : Packing group

15. Regulatory information


United States inventory : This material is listed or exempted.
(TSCA 8b)
WHMIS (Canada) : Class A: Compressed gas.
Class B-1: Flammable gas.
Class F: Dangerously reactive material.
Canadian lists
Canadian NPRI : This material is listed.
CEPA Toxic substances : This material is not listed.
Canada inventory : This material is listed or exempted.
This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations
and the MSDS contains all the information required by the Controlled Products Regulations.
International regulations
International lists : Australia inventory (AICS): This material is listed or exempted.
China inventory (IECSC): This material is listed or exempted.
Japan inventory: This material is listed or exempted.
Korea inventory: This material is listed or exempted.
Malaysia Inventory (EHS Register): Not determined.
New Zealand Inventory of Chemicals (NZIoC): This material is listed or exempted.
Philippines inventory (PICCS): This material is listed or exempted.
Taiwan inventory (CSNN): Not determined.
Chemical Weapons : Not listed
Convention List Schedule
I Chemicals
Chemical Weapons : Not listed
Convention List Schedule
II Chemicals
Chemical Weapons : Not listed
Convention List Schedule
III Chemicals

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16. Other information


Label requirements : FLAMMABLE GAS. MAY CAUSE FLASH FIRE. UNSTABLE. SENSITIVE TO HEAT
OR SHOCK. MAY BECOME EXPLOSIVE. HIGH PRESSURE GAS. GAS REDUCES
OXYGEN AVAILABLE FOR BREATHING. AT VERY HIGH CONCENTRATIONS, CAN
DISPLACE THE NORMAL AIR AND CAUSE SUFFOCATION FROM LACK OF
OXYGEN. MAY CAUSE TARGET ORGAN DAMAGE, BASED ON ANIMAL DATA.
Hazardous Material :
Information System (U.S.A.)
Health * 0

Flammability 4
Physical hazards 3
Personal protective equipment G

Caution: HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4
representing significant hazards or risks Although HMIS® ratings are not required on MSDSs under 29 CFR 1910.
1200, the preparer may choose to provide them. HMIS® ratings are to be used with a fully implemented HMIS®
program. HMIS® is a registered mark of the National Paint & Coatings Association (NPCA). HMIS® materials may
be purchased exclusively from J. J. Keller (800) 327-6868.
The customer is responsible for determining the PPE code for this material.
Date of issue : 9/4/2015
Date of previous issue : 3/27/2014
Version : 6.01
Indicates information that has changed from previously issued version.
Notice to reader
THE INFORMATION, RECOMMENDATIONS AND DATA CONTAINED IN THIS DOCUMENT ARE INTENDED TO BE
USED BY PROPERLY TRAINED AND QUALIFIED PERSONNEL ONLY AND AT THEIR SOLE RISKS AND DISCRETION.
THE INFORMATION, RECOMMENDATIONS AND DATA HEREIN CONTAINED ARE DERIVED FROMSOURCES
WHICH WE BELIEVE TO BE RELIABLE. HOWEVER, AIR LIQUIDE CANADA INC. MAKES NO REPRESENTATION AND
GIVES NO WARRANTY OF ANY KIND WHATSOEVER WITH RESPECT TO THEIR ACCURACY OR COMPLETENESS
AND ASSUMES NO LIABILITY FOR DAMAGES OR LOSS ARISING DIRECTLY OR INDIRECTLY FROM THEIR USE,
WHETHER PROPER OR IMPROPER.

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SAFETY DATA SHEET
P60170

Section 1. Identification
Product name : Acrysol™ High Performance Body Solvent!
Product code : P60170
Other means of : Not available.
identification
Product type : Aerosol.
Relevant identified uses of the substance or mixture and uses advised against
Not applicable.

Manufacturer : Kent Automotive


8770 W. Bryn Mawr Ave., Suite 900
Chicago, IL 60631-3515

Emergency telephone : (888) 426-4851


number of the company
Product Information : (888) 937-5368
Telephone Number
Regulatory Information : (216) 566-2902
Telephone Number
Transportation Emergency : (800) 424-9300
Telephone Number

Section 2. Hazards identification


OSHA/HCS status : This material is considered hazardous by the OSHA Hazard Communication Standard
(29 CFR 1910.1200).
Classification of the : FLAMMABLE AEROSOLS - Category 1
substance or mixture GASES UNDER PRESSURE - Compressed gas
ACUTE TOXICITY (inhalation) - Category 4
SKIN CORROSION/IRRITATION - Category 2
SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 2A
CARCINOGENICITY - Category 2
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Respiratory tract
irritation and Narcotic effects) - Category 3
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) - Category 2
ASPIRATION HAZARD - Category 1
Percentage of the mixture consisting of ingredient(s) of unknown toxicity: 68.8%
GHS label elements
Hazard pictograms :

Signal word : Danger

Date of issue/Date of revision : 3/6/2015. Date of previous issue : No previous validation. Version :1 1/13
Section 2. Hazards identification
Hazard statements : Extremely flammable aerosol.
Contains gas under pressure; may explode if heated.
Harmful if inhaled.
Causes serious eye irritation.
Causes skin irritation.
Suspected of causing cancer.
May be fatal if swallowed and enters airways.
May cause respiratory irritation.
May cause drowsiness and dizziness.
May cause damage to organs through prolonged or repeated exposure.
Precautionary statements
General : Read label before use. Keep out of reach of children. If medical advice is needed, have
product container or label at hand.
Prevention : Obtain special instructions before use. Do not handle until all safety precautions have
been read and understood. Use personal protective equipment as required. Wear
protective gloves. Wear eye or face protection. Keep away from heat, hot surfaces,
sparks, open flames and other ignition sources. No smoking. Pressurized container: Do
not pierce or burn, even after use. Do not spray on an open flame or other ignition
source. Use only outdoors or in a well-ventilated area. Do not breathe dust or mist.
Wash hands thoroughly after handling.
Response : Get medical attention if you feel unwell. IF exposed or concerned: Get medical
attention. IF INHALED: Remove victim to fresh air and keep at rest in a position
comfortable for breathing. Call a POISON CENTER or physician if you feel unwell. IF
SWALLOWED: Immediately call a POISON CENTER or physician. Do NOT induce
vomiting. IF ON SKIN: Wash with plenty of soap and water. Take off contaminated
clothing. Wash contaminated clothing before reuse. If skin irritation occurs: Get
medical attention. IF IN EYES: Rinse cautiously with water for several minutes.
Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation
persists: Get medical attention.
Storage : Store locked up. Protect from sunlight. Do not expose to temperatures exceeding 50
°C/122 °F. Store in a well-ventilated place.
Disposal Dispose of contents and container in accordance with all local, regional, national and
international regulations.
Supplemental label DELAYED EFFECTS FROM LONG TERM OVEREXPOSURE. Contains solvents which
elements can cause permanent brain and nervous system damage. Intentional misuse by
deliberately concentrating and inhaling the contents can be harmful or fatal. WARNING:
This product contains chemicals known to the State of California to cause cancer and
birth defects or other reproductive harm. FOR INDUSTRIAL USE ONLY.
Please refer to the SDS for additional information. Keep upright in a cool, dry place. Do
not discard empty can in trash compactor.
Hazards not otherwise : None known.
classified

Section 3. Composition/information on ingredients


Substance/mixture : Mixture
Other means of : Not available.
identification

CAS number/other identifiers


Ingredient name % by weight CAS number
Lt. Aliphatic Hydrocarbon Solvent 56.0 64742-89-8
Xylene 16.1 1330-20-7
Propane 12.8 74-98-6
Butane 12.3 106-97-8
Ethylbenzene 2.9 100-41-4

Date of issue/Date of revision : 3/6/2015. Date of previous issue : No previous validation. Version :1 2/13
Section 3. Composition/information on ingredients
There are no additional ingredients present which, within the current knowledge of the supplier and in the
concentrations applicable, are classified as hazardous to health or the environment and hence require reporting
in this section.
Occupational exposure limits, if available, are listed in Section 8.

Section 4. First aid measures


Description of necessary first aid measures
Eye contact : Immediately flush eyes with plenty of water, occasionally lifting the upper and lower
eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10
minutes. Get medical attention.
Inhalation : Remove victim to fresh air and keep at rest in a position comfortable for breathing. If it
is suspected that fumes are still present, the rescuer should wear an appropriate mask
or self-contained breathing apparatus. If not breathing, if breathing is irregular or if
respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It
may be dangerous to the person providing aid to give mouth-to-mouth resuscitation.
Get medical attention. If necessary, call a poison center or physician. If unconscious,
place in recovery position and get medical attention immediately. Maintain an open
airway. Loosen tight clothing such as a collar, tie, belt or waistband.
Skin contact : Flush contaminated skin with plenty of water. Remove contaminated clothing and
shoes. Continue to rinse for at least 10 minutes. Get medical attention. Wash clothing
before reuse. Clean shoes thoroughly before reuse.
Ingestion : Get medical attention immediately. Call a poison center or physician. Wash out mouth
with water. Remove dentures if any. Remove victim to fresh air and keep at rest in a
position comfortable for breathing. If material has been swallowed and the exposed
person is conscious, give small quantities of water to drink. Stop if the exposed person
feels sick as vomiting may be dangerous. Aspiration hazard if swallowed. Can enter
lungs and cause damage. Do not induce vomiting. If vomiting occurs, the head should
be kept low so that vomit does not enter the lungs. Never give anything by mouth to an
unconscious person. If unconscious, place in recovery position and get medical
attention immediately. Maintain an open airway. Loosen tight clothing such as a collar,
tie, belt or waistband.

Most important symptoms/effects, acute and delayed


Potential acute health effects
Eye contact : Causes serious eye irritation.
Inhalation : Harmful if inhaled. Can cause central nervous system (CNS) depression. May cause
drowsiness and dizziness. May cause respiratory irritation.
Skin contact : Causes skin irritation.
Ingestion : Can cause central nervous system (CNS) depression. May be fatal if swallowed and
enters airways. Irritating to mouth, throat and stomach.
Over-exposure signs/symptoms
Eye contact : Adverse symptoms may include the following:
pain or irritation
watering
redness
Inhalation : Adverse symptoms may include the following:
respiratory tract irritation
coughing
nausea or vomiting
headache
drowsiness/fatigue
dizziness/vertigo
unconsciousness

Date of issue/Date of revision : 3/6/2015. Date of previous issue : No previous validation. Version :1 3/13
Section 4. First aid measures
Skin contact : Adverse symptoms may include the following:
irritation
redness
Ingestion : Adverse symptoms may include the following:
nausea or vomiting

Indication of immediate medical attention and special treatment needed, if necessary


Notes to physician : Treat symptomatically. Contact poison treatment specialist immediately if large
quantities have been ingested or inhaled.
Specific treatments : No specific treatment.
Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. If it is
suspected that fumes are still present, the rescuer should wear an appropriate mask or
self-contained breathing apparatus. It may be dangerous to the person providing aid to
give mouth-to-mouth resuscitation.

See toxicological information (Section 11)

Section 5. Fire-fighting measures


Extinguishing media
Suitable extinguishing : Use an extinguishing agent suitable for the surrounding fire.
media
Unsuitable extinguishing : None known.
media

Specific hazards arising : Extremely flammable aerosol. In a fire or if heated, a pressure increase will occur and
from the chemical the container may burst, with the risk of a subsequent explosion. Gas may accumulate
in low or confined areas or travel a considerable distance to a source of ignition and
flash back, causing fire or explosion. Bursting aerosol containers may be propelled from
a fire at high speed. Runoff to sewer may create fire or explosion hazard.
Hazardous thermal : Decomposition products may include the following materials:
decomposition products carbon dioxide
carbon monoxide

Special protective actions : Promptly isolate the scene by removing all persons from the vicinity of the incident if
for fire-fighters there is a fire. No action shall be taken involving any personal risk or without suitable
training. Move containers from fire area if this can be done without risk. Use water
spray to keep fire-exposed containers cool.
Special protective : Fire-fighters should wear appropriate protective equipment and self-contained breathing
equipment for fire-fighters apparatus (SCBA) with a full face-piece operated in positive pressure mode.

Section 6. Accidental release measures


Personal precautions, protective equipment and emergency procedures
For non-emergency : No action shall be taken involving any personal risk or without suitable training.
personnel Evacuate surrounding areas. Keep unnecessary and unprotected personnel from
entering. In the case of aerosols being ruptured, care should be taken due to the rapid
escape of the pressurized contents and propellant. If a large number of containers are
ruptured, treat as a bulk material spillage according to the instructions in the clean-up
section. Do not touch or walk through spilled material. Shut off all ignition sources. No
flares, smoking or flames in hazard area. Avoid breathing vapor or mist. Provide
adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put
on appropriate personal protective equipment.
For emergency responders : If specialised clothing is required to deal with the spillage, take note of any information in
Section 8 on suitable and unsuitable materials. See also the information in "For non-
emergency personnel".

Date of issue/Date of revision : 3/6/2015. Date of previous issue : No previous validation. Version :1 4/13
Section 6. Accidental release measures

Environmental precautions : Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains
and sewers. Inform the relevant authorities if the product has caused environmental
pollution (sewers, waterways, soil or air).

Methods and materials for containment and cleaning up


Small spill : Stop leak if without risk. Move containers from spill area. Use spark-proof tools and
explosion-proof equipment. Dilute with water and mop up if water-soluble. Alternatively,
or if water-insoluble, absorb with an inert dry material and place in an appropriate waste
disposal container. Dispose of via a licensed waste disposal contractor.
Large spill : Stop leak if without risk. Move containers from spill area. Use spark-proof tools and
explosion-proof equipment. Approach release from upwind. Prevent entry into sewers,
water courses, basements or confined areas. Wash spillages into an effluent treatment
plant or proceed as follows. Contain and collect spillage with non-combustible,
absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in
container for disposal according to local regulations (see Section 13). Dispose of via a
licensed waste disposal contractor. Contaminated absorbent material may pose the
same hazard as the spilled product. Note: see Section 1 for emergency contact
information and Section 13 for waste disposal.

Section 7. Handling and storage


Precautions for safe handling
Protective measures : Put on appropriate personal protective equipment (see Section 8). Pressurized
container: protect from sunlight and do not expose to temperatures exceeding 50°C. Do
not pierce or burn, even after use. Avoid exposure - obtain special instructions before
use. Do not handle until all safety precautions have been read and understood. Do not
get in eyes or on skin or clothing. Do not breathe vapor or mist. Do not swallow. Avoid
breathing gas. Use only with adequate ventilation. Wear appropriate respirator when
ventilation is inadequate. Store and use away from heat, sparks, open flame or any
other ignition source. Use explosion-proof electrical (ventilating, lighting and material
handling) equipment. Use only non-sparking tools. Empty containers retain product
residue and can be hazardous.
Advice on general : Eating, drinking and smoking should be prohibited in areas where this material is
occupational hygiene handled, stored and processed. Workers should wash hands and face before eating,
drinking and smoking. Remove contaminated clothing and protective equipment before
entering eating areas. See also Section 8 for additional information on hygiene
measures.

Conditions for safe storage, : Store in accordance with local regulations. Store away from direct sunlight in a dry, cool
including any and well-ventilated area, away from incompatible materials (see Section 10) and food
incompatibilities and drink. Protect from sunlight. Store locked up. Eliminate all ignition sources. Use
appropriate containment to avoid environmental contamination.

Section 8. Exposure controls/personal protection


Control parameters
Occupational exposure limits
Ingredient name Exposure limits
Xylene ACGIH TLV (United States, 4/2014).
TWA: 100 ppm 8 hours.
TWA: 434 mg/m³ 8 hours.
STEL: 150 ppm 15 minutes.
STEL: 651 mg/m³ 15 minutes.
OSHA PEL (United States, 2/2013).
TWA: 100 ppm 8 hours.
TWA: 435 mg/m³ 8 hours.

Date of issue/Date of revision : 3/6/2015. Date of previous issue : No previous validation. Version :1 5/13
Section 8. Exposure controls/personal protection
Propane NIOSH REL (United States, 10/2013).
TWA: 1000 ppm 10 hours.
TWA: 1800 mg/m³ 10 hours.
OSHA PEL (United States, 2/2013).
TWA: 1000 ppm 8 hours.
TWA: 1800 mg/m³ 8 hours.
Butane NIOSH REL (United States, 10/2013).
TWA: 800 ppm 10 hours.
TWA: 1900 mg/m³ 10 hours.
ACGIH TLV (United States, 4/2014).
STEL: 1000 ppm 15 minutes.
Ethylbenzene ACGIH TLV (United States, 4/2014).
TWA: 20 ppm 8 hours.
NIOSH REL (United States, 10/2013).
TWA: 100 ppm 10 hours.
TWA: 435 mg/m³ 10 hours.
STEL: 125 ppm 15 minutes.
STEL: 545 mg/m³ 15 minutes.
OSHA PEL (United States, 2/2013).
TWA: 100 ppm 8 hours.
TWA: 435 mg/m³ 8 hours.

Appropriate engineering : Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or
controls other engineering controls to keep worker exposure to airborne contaminants below any
recommended or statutory limits. The engineering controls also need to keep gas,
vapor or dust concentrations below any lower explosive limits. Use explosion-proof
ventilation equipment.
Environmental exposure : Emissions from ventilation or work process equipment should be checked to ensure
controls they comply with the requirements of environmental protection legislation. In some
cases, fume scrubbers, filters or engineering modifications to the process equipment
will be necessary to reduce emissions to acceptable levels.

Individual protection measures


Hygiene measures : Wash hands, forearms and face thoroughly after handling chemical products, before
eating, smoking and using the lavatory and at the end of the working period.
Appropriate techniques should be used to remove potentially contaminated clothing.
Wash contaminated clothing before reusing. Ensure that eyewash stations and safety
showers are close to the workstation location.
Eye/face protection : Safety eyewear complying with an approved standard should be used when a risk
assessment indicates this is necessary to avoid exposure to liquid splashes, mists,
gases or dusts. If contact is possible, the following protection should be worn, unless
the assessment indicates a higher degree of protection: chemical splash goggles.
Skin protection
Hand protection : Chemical-resistant, impervious gloves complying with an approved standard should be
worn at all times when handling chemical products if a risk assessment indicates this is
necessary. Considering the parameters specified by the glove manufacturer, check
during use that the gloves are still retaining their protective properties. It should be
noted that the time to breakthrough for any glove material may be different for different
glove manufacturers. In the case of mixtures, consisting of several substances, the
protection time of the gloves cannot be accurately estimated.
Body protection : Personal protective equipment for the body should be selected based on the task being
performed and the risks involved and should be approved by a specialist before
handling this product. When there is a risk of ignition from static electricity, wear anti-
static protective clothing. For the greatest protection from static discharges, clothing
should include anti-static overalls, boots and gloves.

Date of issue/Date of revision : 3/6/2015. Date of previous issue : No previous validation. Version :1 6/13
Section 8. Exposure controls/personal protection
Other skin protection : Appropriate footwear and any additional skin protection measures should be selected
based on the task being performed and the risks involved and should be approved by a
specialist before handling this product.
Respiratory protection : Use a properly fitted, air-purifying or air-fed respirator complying with an approved
standard if a risk assessment indicates this is necessary. Respirator selection must be
based on known or anticipated exposure levels, the hazards of the product and the safe
working limits of the selected respirator.

Section 9. Physical and chemical properties


Appearance
Physical state : Liquid.
Color : Not available.
Odor : Not available.
Odor threshold : Not available.
pH : Not available.
Melting point : Not available.
Boiling point : Not available.
Flash point : Closed cup: -29°C (-20.2°F) [Pensky-Martens Closed Cup]
Evaporation rate : 1.5 (butyl acetate = 1)
Flammability (solid, gas) : Not available.
Lower and upper explosive : Lower: 0.9%
(flammable) limits Upper: 9.5%
Vapor pressure : 13.5 kPa (101.325 mm Hg) [at 20°C]
Vapor density : 1.55 [Air = 1]
Relative density : 0.69
Solubility : Not available.
Partition coefficient: n- : Not available.
octanol/water
Auto-ignition temperature : Not available.
Decomposition temperature : Not available.
Viscosity : Kinematic (room temperature): <0.07 cm2/s (<7 cSt)
Kinematic (40°C (104°F)): <0.07 cm2/s (<7 cSt)
Aerosol product
Type of aerosol : Spray
Heat of combustion : 0.00004051 kJ/g

Section 10. Stability and reactivity


Reactivity : No specific test data related to reactivity available for this product or its ingredients.

Chemical stability : The product is stable.

Possibility of hazardous : Under normal conditions of storage and use, hazardous reactions will not occur.
reactions

Conditions to avoid : Avoid all possible sources of ignition (spark or flame).

Incompatible materials : No specific data.

Date of issue/Date of revision : 3/6/2015. Date of previous issue : No previous validation. Version :1 7/13
Section 10. Stability and reactivity
Hazardous decomposition : Under normal conditions of storage and use, hazardous decomposition products should
products not be produced.

Section 11. Toxicological information


Information on toxicological effects
Acute toxicity
Product/ingredient name Result Species Dose Exposure
Xylene LC50 Inhalation Gas. Rat 5000 ppm 4 hours
LD50 Oral Rat 4300 mg/kg -
Butane LC50 Inhalation Vapor Rat 658000 mg/m³ 4 hours
Ethylbenzene LD50 Dermal Rabbit >5000 mg/kg -
LD50 Oral Rat 3500 mg/kg -
Irritation/Corrosion
Product/ingredient name Result Species Score Exposure Observation
Xylene Eyes - Mild irritant Rabbit - 87 milligrams -
Eyes - Severe irritant Rabbit - 24 hours 5 -
milligrams
Skin - Mild irritant Rat - 8 hours 60 -
microliters
Skin - Moderate irritant Rabbit - 24 hours 500 -
milligrams
Skin - Moderate irritant Rabbit - 100 Percent -
Ethylbenzene Eyes - Severe irritant Rabbit - 500 -
milligrams
Skin - Mild irritant Rabbit - 24 hours 15 -
milligrams
Sensitization
Not available.
Mutagenicity
Not available.
Carcinogenicity
Not available.
Classification
Product/ingredient name OSHA IARC NTP
Xylene - 3 -
Ethylbenzene - 2B -
Reproductive toxicity
Not available.
Teratogenicity
Not available.
Specific target organ toxicity (single exposure)

Date of issue/Date of revision : 3/6/2015. Date of previous issue : No previous validation. Version :1 8/13
Section 11. Toxicological information
Name Category Route of Target organs
exposure
Lt. Aliphatic Hydrocarbon Solvent Category 3 Not applicable. Respiratory tract
irritation and
Narcotic effects
Xylene Category 3 Not applicable. Respiratory tract
irritation and
Narcotic effects
Propane Category 3 Not applicable. Respiratory tract
irritation and
Narcotic effects
Butane Category 3 Not applicable. Respiratory tract
irritation and
Narcotic effects
Ethylbenzene Category 3 Not applicable. Respiratory tract
irritation and
Narcotic effects
Specific target organ toxicity (repeated exposure)
Name Category Route of Target organs
exposure
Lt. Aliphatic Hydrocarbon Solvent Category 2 Not determined Not determined
Xylene Category 2 Not determined Not determined
Propane Category 2 Not determined Not determined
Butane Category 2 Not determined Not determined
Ethylbenzene Category 2 Not determined Not determined
Aspiration hazard
Name Result
Lt. Aliphatic Hydrocarbon Solvent ASPIRATION HAZARD - Category 1
Xylene ASPIRATION HAZARD - Category 1
Propane ASPIRATION HAZARD - Category 1
Butane ASPIRATION HAZARD - Category 1
Ethylbenzene ASPIRATION HAZARD - Category 1

Information on the likely : Not available.


routes of exposure
Potential acute health effects
Eye contact : Causes serious eye irritation.
Inhalation : Harmful if inhaled. Can cause central nervous system (CNS) depression. May cause
drowsiness and dizziness. May cause respiratory irritation.
Skin contact : Causes skin irritation.
Ingestion : Can cause central nervous system (CNS) depression. May be fatal if swallowed and
enters airways. Irritating to mouth, throat and stomach.

Symptoms related to the physical, chemical and toxicological characteristics


Eye contact : Adverse symptoms may include the following:
pain or irritation
watering
redness

Date of issue/Date of revision : 3/6/2015. Date of previous issue : No previous validation. Version :1 9/13
Inhalation : Adverse symptoms may include the following:
respiratory tract irritation
coughing
nausea or vomiting
headache
drowsiness/fatigue
dizziness/vertigo
unconsciousness
Skin contact : Adverse symptoms may include the following:
irritation
redness
Ingestion : Adverse symptoms may include the following:
nausea or vomiting

Delayed and immediate effects and also chronic effects from short and long term exposure
Short term exposure
Potential immediate : Not available.
effects
Potential delayed effects : Not available.
Long term exposure
Potential immediate : Not available.
effects
Potential delayed effects : Not available.
Potential chronic health effects
Not available.
General : May cause damage to organs through prolonged or repeated exposure.
Carcinogenicity : Suspected of causing cancer. Risk of cancer depends on duration and level of
exposure.
Mutagenicity : No known significant effects or critical hazards.
Teratogenicity : No known significant effects or critical hazards.
Developmental effects : No known significant effects or critical hazards.
Fertility effects : No known significant effects or critical hazards.

Numerical measures of toxicity


Acute toxicity estimates
Route ATE value
Oral 6847.2 mg/kg
Inhalation (gases) 9690.9 ppm

Section 12. Ecological information


Toxicity
Product/ingredient name Result Species Exposure
Lt. Aliphatic Hydrocarbon Acute LC50 >100000 ppm Fresh water Fish - Oncorhynchus mykiss 96 hours
Solvent
Xylene Acute LC50 8500 µg/l Marine water Crustaceans - Palaemonetes 48 hours
pugio
Acute LC50 13400 µg/l Fresh water Fish - Pimephales promelas 96 hours
Ethylbenzene Acute EC50 4600 µg/l Fresh water Algae - Pseudokirchneriella 72 hours
subcapitata
Acute EC50 3600 µg/l Fresh water Algae - Pseudokirchneriella 96 hours
subcapitata

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Section 12. Ecological information
Acute EC50 6530 µg/l Fresh water Crustaceans - Artemia sp. - 48 hours
Nauplii
Acute EC50 2930 µg/l Fresh water Daphnia - Daphnia magna - 48 hours
Neonate
Acute LC50 4200 µg/l Fresh water Fish - Oncorhynchus mykiss 96 hours

Persistence and degradability


Product/ingredient name Aquatic half-life Photolysis Biodegradability
Xylene - - Readily
Ethylbenzene - - Readily

Bioaccumulative potential
Product/ingredient name LogPow BCF Potential
Lt. Aliphatic Hydrocarbon - 10 to 2500 high
Solvent
Xylene - 8.1 to 25.9 low

Mobility in soil
Soil/water partition : Not available.
coefficient (KOC)

Other adverse effects : No known significant effects or critical hazards.

Section 13. Disposal considerations


Disposal methods : The generation of waste should be avoided or minimized wherever possible. Disposal
of this product, solutions and any by-products should at all times comply with the
requirements of environmental protection and waste disposal legislation and any
regional local authority requirements. Dispose of surplus and non-recyclable products
via a licensed waste disposal contractor. Waste should not be disposed of untreated to
the sewer unless fully compliant with the requirements of all authorities with jurisdiction.
Waste packaging should be recycled. Incineration or landfill should only be considered
when recycling is not feasible. This material and its container must be disposed of in a
safe way. Empty containers or liners may retain some product residues. Do not
puncture or incinerate container.

Section 14. Transport information


DOT TDG Mexico IATA IMDG
Classification Classification Classification
UN number UN1950 UN1950 UN1950 UN1950 UN1950

UN proper AEROSOLS AEROSOLS AEROSOLS AEROSOLS, AEROSOLS


shipping name flammable
Transport 2.1 2.1 2.1 2.1 2.1
hazard class(es)

Packing group - - - - -
Environmental No. No. No. No. No.
hazards

Date of issue/Date of revision : 3/6/2015. Date of previous issue : No previous validation. Version :1 11/13
Section 14. Transport information
Additional Special Special Special Special Emergency
information provisions provisions provisions provisions schedules (EmS)
LIMITED LIMITED (ERG#126) LIMITED LIMITED
QUANTITY QUANTITY QUANTITY QUANTITY, F-D,
S-U

Special precautions for user : Multi-modal shipping descriptions are provided for informational purposes and do not
consider container sizes. The presence of a shipping description for a particular
mode of transport (sea, air, etc.), does not indicate that the product is packaged
suitably for that mode of transport. All packaging must be reviewed for suitability prior
to shipment, and compliance with the applicable regulations is the sole responsibility
of the person offering the product for transport. People loading and unloading
dangerous goods must be trained on all of the risks deriving from the substances
and on all actions in case of emergency situations.

Transport in bulk according : Not available.


to Annex II of MARPOL
73/78 and the IBC Code

Section 15. Regulatory information


U.S. Federal regulations :
State regulations
California Prop. 65
WARNING: This product contains chemicals known to the State of California to cause cancer and birth defects or other
reproductive harm.

Section 16. Other information


Hazardous Material Information System (U.S.A.)
Health * 2

Flammability 4
Physical hazards 0

Caution: HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4
representing significant hazards or risks Although HMIS® ratings are not required on SDSs under 29 CFR 1910.
1200, the preparer may choose to provide them. HMIS® ratings are to be used with a fully implemented HMIS®
program. HMIS® is a registered mark of the National Paint & Coatings Association (NPCA).

The customer is responsible for determining the PPE code for this material.

Date of issue/Date of revision : 3/6/2015. Date of previous issue : No previous validation. Version :1 12/13
Section 16. Other information

Notice to reader
It is recommended that each customer or recipient of this Safety Data Sheet (SDS) study it carefully and consult
resources, as necessary or appropriate, to become aware of and understand the data contained in this SDS and
any hazards associated with the product. This information is provided in good faith and believed to be accurate
as of the effective date herein. However, no warranty, express or implied, is given. The information presented
here applies only to the product as shipped. The addition of any material can change the composition, hazards
and risks of the product. Regulatory requirements are subject to change and may differ between various
locations and jurisdictions. The customer/buyer/user is responsible to ensure that his activities comply with all
country, federal, state, provincial or local laws. The conditions for use of the product are not under the control of
the manufacturer; the customer/buyer/user is responsible to determine the conditions necessary for the safe use
of this product. The customer/buyer/user should not use the product for any purpose other than the purpose
shown in the applicable section of this SDS without first referring to the supplier and obtaining written handling
instructions. Due to the proliferation of sources for information such as manufacturer-specific SDS, the
manufacturer cannot be responsible for SDSs obtained from any other source.

Date of issue/Date of revision : 3/6/2015. Date of previous issue : No previous validation. Version :1 13/13
SAFETY DATA SHEET

1. Identification
Product identifier Air Tool Oil
Other means of identification
Product code SL2531, SL2533
Recommended use Lubricant for pneumatic equipment
Recommended restrictions None known.
Manufacturer/Importer/Supplier/Distributor information
Manufactured or sold by:
Company name CRC Industries, Inc.
Address 885 Louis Dr.
Warminster, PA 18974 US
Telephone
General Information 215-674-4300
Technical 800-521-3168
Assistance
Customer Service 800-272-4620
24-Hour Emergency 800-424-9300 (US)
(CHEMTREC) 703-527-3887 (International)
Website www.crcindustries.com

2. Hazard(s) identification
Physical hazards Not classified.
Health hazards Not classified.
Environmental hazards Not classified.
OSHA defined hazards Not classified.

Label elements
Hazard symbol None.
Signal word None.
Hazard statement The mixture does not meet the criteria for classification.
Precautionary statement
Prevention Use with adequate ventilation. Open doors and windows or use other means to ensure a fresh air
supply during use. Observe good industrial hygiene practices.
Response Wash hands after handling.
Storage Store away from incompatible materials.
Disposal Dispose of waste and residues in accordance with local authority requirements.
Hazard(s) not otherwise None known.
classified (HNOC)

3. Composition/information on ingredients
Mixtures
Chemical name Common name and synonyms CAS number %
Distillates (petroleum), 64742-53-6 90 - 100
Hydrotreated Light Naphthenic
Distillates (petroleum), 64741-96-4 3-5
solvent-refined heavy naphthenic
Phosphorodithioic acid, 68649-42-3 1-3
O,O-di-C1-14-alkyl esters, zinc
salts

Material name: Air Tool Oil SDS US

SL2531, SL2533 Version #: 01 Issue date: 10-23-2015 1/8


Specific chemical identity and/or percentage of composition has been withheld as a trade secret.

4. First-aid measures
Inhalation Remove victim to fresh air and keep at rest in a position comfortable for breathing. Get medical
attention if symptoms occur.
Skin contact Wash off with plenty of water. Remove and isolate contaminated clothing and shoes. Get medical
attention if irritation develops and persists. Wash contaminated clothing before reuse.
Eye contact Rinse immediately with plenty of water, also under the eyelids. Remove contact lenses, if present
and easy to do. Get medical attention if irritation develops and persists.
Ingestion Rinse mouth. Drink 1 or 2 glasses of water. Do not induce vomiting without advice from poison
control center. Never give anything by mouth to a victim who is unconscious or is having
convulsions. Get medical attention if symptoms occur. If ingestion of a large amount does occur,
call a poison control center immediately.
Most important Direct contact with eyes may cause temporary irritation.
symptoms/effects, acute and
delayed
Indication of immediate Treat symptomatically.
medical attention and special
treatment needed
General information Ensure that medical personnel are aware of the material(s) involved, and take precautions to
protect themselves.

5. Fire-fighting measures
Suitable extinguishing media Use fire-extinguishing media appropriate for surrounding materials.
Unsuitable extinguishing None known.
media
Specific hazards arising from During fire, gases hazardous to health may be formed.
the chemical
Special protective equipment Firefighters must use standard protective equipment including flame retardant coat, helmet with
and precautions for firefighters face shield, gloves, rubber boots, and in enclosed spaces, SCBA.
Fire fighting Cool containers exposed to heat with water spray and remove container, if no risk is involved.
equipment/instructions
General fire hazards No unusual fire or explosion hazards noted.

6. Accidental release measures


Personal precautions, Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Keep out of
protective equipment and low areas. Do not touch damaged containers or spilled material unless wearing appropriate
emergency procedures protective clothing. For personal protection, see section 8 of the SDS.
Methods and materials for The product is immiscible with water and will spread on the water surface.
containment and cleaning up
Large Spills: Stop the flow of material, if this is without risk. Dike the spilled material, where this is
possible. Cover with plastic sheet to prevent spreading. Absorb in vermiculite, dry sand or earth
and place into containers. Following product recovery, flush area with water.

Small Spills: Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to
remove residual contamination.

Never return spills to original containers for re-use. For waste disposal, see section 13 of the SDS.
Prevent entry into waterways, sewer, basements or confined areas.
Environmental precautions Avoid discharge into drains, water courses or onto the ground.

7. Handling and storage


Precautions for safe handling Wear appropriate personal protective equipment. Avoid prolonged or repeated contact with skin.
Avoid prolonged exposure. Use only in well-ventilated areas. When using, do not eat, drink or
smoke. Wash contaminated clothing before reuse. Use appropriate container to avoid
environmental contamination. For product usage instructions, please see the product label.
Conditions for safe storage, Keep away from heat and sources of ignition. Store in a cool, dry place out of direct sunlight. Store
including any incompatibilities in a well-ventilated place. Keep container tightly closed. Store away from incompatible materials
(see Section 10 of the SDS).

Material name: Air Tool Oil SDS US

SL2531, SL2533 Version #: 01 Issue date: 10-23-2015 2/8


8. Exposure controls/personal protection
Occupational exposure limits
US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000)
Components Type Value Form

Distillates (petroleum), PEL 5 mg/m3 Mist.


hydrotreated light
naphthenic (CAS
64742-53-6)
2000 mg/m3
500 ppm
Distillates (petroleum), PEL 5 mg/m3 Mist.
solvent-refined heavy
naphthenic (CAS
64741-96-4)
2000 mg/m3
500 ppm
US. ACGIH Threshold Limit Values
Components Type Value Form

Distillates (petroleum), TWA 5 mg/m3 Inhalable fraction.


hydrotreated light
naphthenic (CAS
64742-53-6)
Distillates (petroleum), TWA 5 mg/m3 Inhalable fraction.
solvent-refined heavy
naphthenic (CAS
64741-96-4)
US. NIOSH: Pocket Guide to Chemical Hazards
Components Type Value Form

Distillates (petroleum), Ceiling 1800 mg/m3


hydrotreated light
naphthenic (CAS
64742-53-6)
STEL 10 mg/m3 Mist.
Distillates (petroleum), Ceiling 1800 mg/m3
solvent-refined heavy
naphthenic (CAS
64741-96-4)
STEL 10 mg/m3 Mist.
Biological limit values No biological exposure limits noted for the ingredient(s).
Appropriate engineering Good general ventilation (typically 10 air changes per hour) should be used. Ventilation rates
controls should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation,
or other engineering controls to maintain airborne levels below recommended exposure limits. If
exposure limits have not been established, maintain airborne levels to an acceptable level.
General ventilation normally adequate.
Individual protection measures, such as personal protective equipment
Eye/face protection Wear safety glasses with side shields (or goggles).

Skin protection
Hand protection Wear protective gloves such as: Nitrile. Polyvinyl chloride (PVC).
Other Wear suitable protective clothing.
Respiratory protection If engineering controls are not feasible or if exposure exceeds the applicable exposure limits, use a
NIOSH-approved cartridge respirator with an organic vapor cartridge. Use a self-contained
breathing apparatus in confined spaces and for emergencies. Air monitoring is needed to
determine actual employee exposure levels.
Thermal hazards Wear appropriate thermal protective clothing, when necessary.
General hygiene Handle in accordance with good industrial hygiene and safety practice.
considerations

9. Physical and chemical properties


Appearance
Material name: Air Tool Oil SDS US

SL2531, SL2533 Version #: 01 Issue date: 10-23-2015 3/8


Physical state Liquid.
Form Liquid.
Color Amber.
Odor Mild petroleum.
Odor threshold Not available.
pH Not available.
Melting point/freezing point Not available.
Initial boiling point and boiling 680 °F (360 °C) estimated
range
Flash point 320 °F (160 °C) Cleveland Open Cup
Evaporation rate Slow.
Flammability (solid, gas) Not available.
Upper/lower flammability or explosive limits
Flammability limit - lower Not available.
(%)
Flammability limit - upper Not available.
(%)
Vapor pressure Not available.
Vapor density > 1 (air = 1)
Relative density 0.9 - 0.92
Solubility (water) Insoluble.
Partition coefficient Not available.
(n-octanol/water)
Auto-ignition temperature 500 °F (260 °C) estimated
Decomposition temperature Not available.
Viscosity (kinematic) 22.5 - 27.5 mm²/s (104 °F (40 °C))
Percent volatile Not available.

10. Stability and reactivity


Reactivity The product is stable and non-reactive under normal conditions of use, storage and transport.
Chemical stability Material is stable under normal conditions.
Possibility of hazardous No dangerous reaction known under conditions of normal use.
reactions
Conditions to avoid Heat, flames and sparks. Contact with incompatible materials.
Incompatible materials Strong oxidizing agents.
Hazardous decomposition Carbon oxides.
products

11. Toxicological information


Information on likely routes of exposure
Inhalation Prolonged or excessive inhalation may cause respiratory tract irritation.
Skin contact Prolonged skin contact may cause temporary irritation. Repeated exposure may cause skin
dryness or cracking.
Eye contact Direct contact with eyes may cause temporary irritation.
Ingestion Expected to be a low ingestion hazard.
Symptoms related to the Direct contact with eyes may cause temporary irritation.
physical, chemical and
toxicological characteristics
Information on toxicological effects
Acute toxicity Not available.

Material name: Air Tool Oil SDS US

SL2531, SL2533 Version #: 01 Issue date: 10-23-2015 4/8


Product Species Test Results
Air Tool Oil
Acute
Dermal
LD50 Rabbit 5100 mg/kg estimated
Inhalation
LC50 Rat 2295 mg/m³, 4 hours estimated
Oral
LD50 Rat 5097 mg/kg estimated

* Estimates for product may be based on additional component data not shown.
Skin corrosion/irritation Prolonged skin contact may cause temporary irritation.
Serious eye damage/eye Direct contact with eyes may cause temporary irritation.
irritation
Respiratory sensitization Not a respiratory sensitizer.
Skin sensitization This product is not expected to cause skin sensitization.
Germ cell mutagenicity No data available to indicate product or any components present at greater than 0.1% are
mutagenic or genotoxic.
Carcinogenicity This product is not considered to be a carcinogen by IARC, ACGIH, NTP, or OSHA.
IARC Monographs. Overall Evaluation of Carcinogenicity
Not available.
US. National Toxicology Program (NTP) Report on Carcinogens
Not available.
Reproductive toxicity This product is not expected to cause reproductive or developmental effects.
Specific target organ toxicity - Not classified.
single exposure
Specific target organ toxicity - Not classified.
repeated exposure
Aspiration hazard Not classified.
Chronic effects Prolonged inhalation may be harmful.
Further information This product has no known adverse effect on human health.

12. Ecological information


Ecotoxicity The product is not classified as environmentally hazardous. However, this does not exclude the
possibility that large or frequent spills can have a harmful or damaging effect on the environment.
Product Species Test Results
Air Tool Oil
Aquatic
Crustacea EC50 Daphnia 99.9848 mg/l, 48 hours estimated
Fish LC50 Fish 549.3577 mg/l, 96 hours estimated
Components Species Test Results
Phosphorodithioic acid, O,O-di-C1-14-alkyl esters, zinc salts (CAS 68649-42-3)
Aquatic
Crustacea EC50 Water flea (Daphnia magna) 1 - 5 mg/l, 48 hours
Fish LC50 Fathead minnow (Pimephales promelas) 1 - 5 mg/l, 96 hours

* Estimates for product may be based on additional component data not shown.
Persistence and degradability No data is available on the degradability of this product.
Bioaccumulative potential
Mobility in soil No data available.
Other adverse effects No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation
potential, endocrine disruption, global warming potential) are expected from this component.

Material name: Air Tool Oil SDS US

SL2531, SL2533 Version #: 01 Issue date: 10-23-2015 5/8


13. Disposal considerations
Disposal of waste from This product is not a RCRA hazardous waste (See 40 CFR Part 261.20 – 261.33). Empty
residues / unused products containers may be recycled. Collect and reclaim or dispose in sealed containers at licensed waste
disposal site. Dispose in accordance with all applicable regulations.
Hazardous waste code Not regulated.
Contaminated packaging Empty containers should be taken to an approved waste handling site for recycling or disposal.
Since emptied containers may retain product residue, follow label warnings even after container is
emptied.

14. Transport information


DOT
Not regulated as dangerous goods.
IATA
Not regulated as dangerous goods.
IMDG
Not regulated as dangerous goods.

15. Regulatory information


US federal regulations This product is not known to be a "Hazardous Chemical" as defined by the OSHA Hazard
Communication Standard, 29 CFR 1910.1200.
TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D)
Not regulated.
US. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)
Not listed.
SARA 304 Emergency release notification
Not regulated.
US EPCRA (SARA Title III) Section 313 - Toxic Chemical: Listed substance
Phosphorodithioic acid, O,O-di-C1-14-alkyl esters, zinc salts (CAS 68649-42-3)
CERCLA Hazardous Substance List (40 CFR 302.4)
Phosphorodithioic acid, O,O-di-C1-14-alkyl esters, zinc Listed.
salts (CAS 68649-42-3)
CERCLA Hazardous Substances: Reportable quantity
Not listed.
Spills or releases resulting in the loss of any ingredient at or above its RQ require immediate notification to the National
Response Center (800-424-8802) and to your Local Emergency Planning Committee.
Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List
Not regulated.
Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130)
Not regulated.
Safe Drinking Water Act Not regulated.
(SDWA)
Food and Drug Not regulated.
Administration (FDA)
Superfund Amendments and Reauthorization Act of 1986 (SARA)
Section 311/312 Immediate Hazard - No
Hazard categories Delayed Hazard - No
Fire Hazard - No
Pressure Hazard - No
Reactivity Hazard - No
SARA 302 Extremely No
hazardous substance
US state regulations
US. California. Candidate Chemicals List. Safer Consumer Products Regulations (Cal. Code Regs, tit. 22, 69502.3, subd.
(a))
Distillates (petroleum), Hydrotreated Light Naphthenic (CAS 64742-53-6)
Distillates (petroleum), solvent-refined heavy naphthenic (CAS 64741-96-4)

Material name: Air Tool Oil SDS US

SL2531, SL2533 Version #: 01 Issue date: 10-23-2015 6/8


US. California Controlled Substances. CA Department of Justice (California Health and Safety Code Section 11100)
Not listed.
US. Massachusetts RTK - Substance List
Distillates (petroleum), Hydrotreated Light Naphthenic (CAS 64742-53-6)
Distillates (petroleum), solvent-refined heavy naphthenic (CAS 64741-96-4)
US. New Jersey Worker and Community Right-to-Know Act
Phosphorodithioic acid, O,O-di-C1-14-alkyl esters, zinc salts (CAS 68649-42-3)
US. Rhode Island RTK
Phosphorodithioic acid, O,O-di-C1-14-alkyl esters, zinc salts (CAS 68649-42-3)
US. Pennsylvania Worker and Community Right-to-Know Law
Not listed.
US. California Proposition 65
California Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition 65): This material is not known to contain
any chemicals currently listed as carcinogens or reproductive toxins.
Volatile organic compounds (VOC) regulations
EPA
VOC content (40 CFR Not determined
51.100(s))
Consumer products Not regulated
(40 CFR 59, Subpt. C)
State
Consumer products Not regulated
VOC content (CA) 0%
VOC content (OTC) 0%
International Inventories
Country(s) or region Inventory name On inventory (yes/no)*
Australia Australian Inventory of Chemical Substances (AICS) Yes
Canada Domestic Substances List (DSL) Yes
Canada Non-Domestic Substances List (NDSL) No
China Inventory of Existing Chemical Substances in China (IECSC) Yes
Europe European Inventory of Existing Commercial Chemical Yes
Substances (EINECS)
Europe European List of Notified Chemical Substances (ELINCS) No
Japan Inventory of Existing and New Chemical Substances (ENCS) No
Korea Existing Chemicals List (ECL) Yes
New Zealand New Zealand Inventory Yes
Philippines Philippine Inventory of Chemicals and Chemical Substances Yes
(PICCS)
United States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory Yes
*A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s)
A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing
country(s).

16. Other information, including date of preparation or last revision


Issue date 10-23-2015
Prepared by Allison Cho
Version # 01
Further information Not available.
HMIS® ratings Health: 1
Flammability: 1
Physical hazard: 0
Personal protection: B
NFPA ratings Health: 1
Flammability: 1
Instability: 0

Material name: Air Tool Oil SDS US

SL2531, SL2533 Version #: 01 Issue date: 10-23-2015 7/8


NFPA ratings
1
1 0

Disclaimer The information contained in this document applies to this specific material as supplied. It may not
be valid for this material if it is used in combination with any other materials. This information is
accurate to the best of CRC Industries' knowledge or obtained from sources believed by CRC to
be accurate. Before using any product, read all warnings and directions on the label. For further
clarification of any information contained on this (M)SDS consult your supervisor, a health & safety
professional, or CRC Industries.

Material name: Air Tool Oil SDS US

SL2531, SL2533 Version #: 01 Issue date: 10-23-2015 8/8


KLEEN-FLO TUMBLER INDUSTRIES LIMITED MATERIAL SAFETY DATA SHEET PAGE 1

SECTION I-MATERIAL IDENTIFICATION AND USE

Material Name/Identifier: Air Tool Oil Stock No. 4168/4169/4170


Manufacturer's Name: Kleen-Flo Tumbler Industries Ltd Street Address: 75 Advance Blvd.
City: Brampton Province: Ontario
Postal Code: L6T 4N1 Emergency Phone #: CANUTEC:- 613-996-6666 (24HR)
Chemical Name: N.Ap. (mixture) Chemical Family: N.Ap. (mixture)
Chemical Formula: N.Ap. (mixture) Trade Names & Synonyms: None
Material Use: Lubricant Molecular Weight: N.Ap. (mixture)

SECTION II-HAZARDOUS INGREDIENTS OF MATERIAL


Hazardous Approximate C.A.S. LD50 LC50
Ingredients Concentration, % Species & Route Species & Route
Hydrotreated petroleum oil 60-100 64742-58-1 >2000 mg/kg rat-oral N/Av.
Naphthenic Oil 1 -10 64742-52-5 >2000 mg/kg rat-oral N/Av.
Hydrocarbon Distillate 1 -10 8052-41-3 > 5 g/kg rat-oral > 5 g/m3 rat-inh.
Zinc C1-C14 alkyldithiophosphates <1 68649-42-3 N/Av. N/Av.

SECTION III-PHYSICAL DATA FOR MATERIAL

Physical State: Liquid Odour/Appearance: Pleasant odour/ Clear, red oil


Specific Gravity: 0.84 Odour Threshold(p.p.m.): N/E
Boiling Point: >129ºC Evaporation Rate: N/E
Freezing Point: N/E Solubility in Water: Insoluble
% Volatile(by volume): N/Av. Vapour Pressure(mm)Hg: N/E
Vapour Density(Air=1): N/E Coefficient of Water/Oil Distribut: N/E
pH: N/Av.

SECTION IV-FIRE AND EXPLOSION HAZARD OF MATERIAL


Flammability (Yes/No) Yes If yes under which conditions: combustible liquid, may form
combustible vapours at or above flash point
Auto Ignition Temperature: N/E Means of Extinction: Carbon dioxide, dry chemical, foam, water fog
Flash Point, Tag. C.C 69ºC Hazardous Combustion Products: oxides of carbon, sulfur, zinc,
phosphorous, calcium. Hydrogen sulfide, alkyl mercaptons.
Upper Flammable Limit (%vol) 15-16 Lower Flammable Limit (% by volume): 1
Explosion Data: Sensitivity to Mechanical Impact: No. Sensitivity to Static Discharge: No

SECTION V-REACTIVITY DATA

Chemical Stability Yes/No: Yes If NO under r which conditions?


Incompatibility to Other Substances Yes/No: Yes If so which ones? Strong oxidizing agents
Reactivity and under what conditions? Not reactive under normal condition
Hazardous Decomposition Products: Oxides of carbon, Sulfur,Phosphorous, Calcium & Zinc.

N/E: not established N.Ap.:not applicable N/Av.: not available


Material Name/Identifier: Air Tool Oil Stock No. U4168/ U4169/ U4170 PAGE 2

SECTION VI-TOXICOLOGICAL PROPERTIES OF PRODUCT

Route of Entry: --SKIN CONTACT -x-SKIN ABSORPTION -x-EYE CONTACT -x-INHALATION -x-INGESTION
Effects of Acute Exposure: May cause skin, eye irritation, dizziness, headache, vomiting, nausea, cough, pulmonary irritation
Effects of Chronic Exposure: Prolong, repeated eye and skin contact can cause severe eye irritation, dermatitis.

LD 50 of Product: N/E LC 50 of Product: N/E


Irritancy of Product: Eyes, skin Exposure Limits of Product: N/E
Sensitization of Product: None known Toxicologically Synergistic Materials: N/E
--CARCINOGENICITY --REPRODUCTIVE EFFECTS --TERATOGENICITY --MUTAGENICITY None Known

SECTION VII-PREVENTIVE MEASURES


Personal Protective Equipment to be used:
Gloves(specify): Nitrile, chemical resistant gloves Eye (specify): Safety Glasses
Respiratory(specify): Not required in normal use Clothing: Not required
Respiratory Protection: If used indoors or on a continuous basis, use of NIOSH approved cartridge type respirator is recommended
Engineering Controls: Local or mechanical ventilation
Leak and Spill Procedure: Dike and absorb spill with inert absorbant material, keep spill out of sewers.
Waste Disposal: Dispose according to federal, state (Provincial) and local regulations
Storage Requirements: Keep at room temperature. Keep container closed when not in use.
Handling Procedures and Keep away from children. Handle with care. Do not inhale or ingest.
Equipment: Keep away from excessive heat, open flame, source of ignition.
DSL listing: All components are listed on the inventory.
TDG Classification: Not regulated
WHMIS Classification: B3, D2B Complies with CCCR 2001. (non-controlled)

SECTION VIII-FIRST AID MEASURES

Eye: Flush immediately with running water for at least 15 minutes. Consult physician immediately.
Skin: Remove contiminated clothing. Rinse with plenty of soapy. See doctor if irritation persist.
Inhalation Remove to fresh air. Restore breathing if required. See doctor if discomfort persist.
Ingestion: DO NOT INDUCE VOMITING. If person conscious, give a glasses of water. See doctor immediately.

SECTION IX-PREPARATION DATE OF M.S.D.S.

Additional Info/Comments: Sources Used: Handbook of Poisoning By: R.H. Dreisbach


Phone Number: (905) 793-4311 Prepared By: Quality Control Laboratory
Date Prepared: Janaury 2, 2015. Kleen-Flo Tumbler Industries Limited

THIS SHEET SUPERSEDES ANY OTHER M.S.D.S. PREVIOUSLY PREPARED


N/E: not established N.Ap.:not applicable N/Av.: not available
SAFETY DATA SHEET
ANTI-BORAX No. 1
DATE REVISED: January 1, 2016

Product Name: Anti-Borax No. 1


Manufacturer: Superior Flux & Mfg. Co. 6615 Parkland Blvd. Cleveland OH, 44139
Emergency Phone Number: 1-800-424-9300 (CHEMTREC)
Other Information Calls: (440) 349-3000
To the Purchaser: This MSDS contains important environmental, health, and toxicology information
for your employees who have ordered this product. Please be sure this information is given to them. If
you resell this product, a copy of the MSDS should be given to the buyer.

H.M.I.S. INFORMATION: HEALTH = 1 FLAMMABILITY = 0 REACTIVITY = 0

SECTION I -- IDENTIFICATION
Common Name: Anti-Borax No. 1
Chemical Family: Cast iron welding flux
CAS Number: NA
Chemical Name: NA
Formula: See Below
SECTION II – HAZARDS IDENTIFICATION
Classification of Substance or Mixture:
Classification (CLP): NA
Label Elements (CLP): NA
Signal Word: Danger

Irritant Health hazard

Risk Phrases: R62, R25, R36/37/38, R60/61


Safety Phrases: S-26, S-27, S-36/37/39, S-45
See section XVI for full text description of S and R phrases
Other Hazards: None if used properly

SECTION III- COMPOSITION INFORMATION


Components CAS Number % OSHA PEL
Boric Acid 10043-35-3 20-40 10 mg/m3

None of the materials in this product are listed in NTP, IARC, or OSHA as carcinogens.

MSDS. Anti-Borax No. 1. Page 1 of 4


SECTION IV – FIRST AID MEASURES
Inhalation: Remove to fresh air
Eyes: Flush with water for fifteen (15) Minutes. Call physician.
Skin: Wash thoroughly with soap and water.
Ingestion: If patient is fully conscious, give large amounts of water. Obtain medical attention
immediately.

Most Important Symptoms and effects, both acute and delayed


Primary Routes of Entry into Body: Fume inhalation, ingestion, skin, and eyes.
Symptoms of Overexposure: Salivation, coughing, choking, chills, may cause weight loss, brittle
bones, anemia, and stiff joints.
Medical Conditions Generally Aggravated by Exposure: Any weakness of the lungs, kidneys or liver
will be aggravated.
Chemical Listed as Carcinogen or Potential Carcinogen: None
OSHA Permissible Exposure Limit (PEL): 10 mg/m3
ACGIH Threshold Limit Value (TLV): 10 mg/m3

SECTION V - FIRE AND EXPLOSION HAZARD DATA

Flash Point: None


Flammable Limits: Lower-NA upper-NA
Extinguishing Media: Not needed
Auto Ignition Temperature: None
Special Fire Fighting Procedures: Normal caution when dealing with chemicals
Unusual Fire and Explosion Hazards: Boric oxide fumes

SECTION VI - ACCIDENTAL RELEASE MEASURES


Steps to be taken in Case Material is spilled: Clean up powder and flush remaining material with lots
of water

SECTION VII - HANDLING AND STORAGE


Storage Requirements: Store in plastic containers in cool area. Avoid contact with eyes, skin, and
clothing. Wash thoroughly after handling.
Handling Precautions: Keep containers away for excessive heat.

SECTION VIII - CONTROL MEASURES


Respiratory Protection (TYPE): NIOSH approved respirator.
Ventilation: Yes
Mechanical (General): Yes
Local Exhaust: Yes
Protective Gloves: Recommended, NIOSH approved
Eye Protection: Safety glasses
Other Protective Clothing or Equipment: Rubber apron

MSDS. Anti-Borax No. 1. Page 2 of 4


SECTION IX - PHYSICAL AND CHEMICAL CHARACTERISTICS
Boiling Point: NA
Specific Gravity (Water = 1): NA
Vapor Pressure (mm Hg): NA
Percent Volatile by Volume: 0%
Vapor Density (Air = 1): NA
Evaporation Rate (Butyl Acetate = 1): NA
Melting Point: 700°C/1292°F
Solubility in Water: Soluble
Reactivity in Water: None
Appearance and odor: Red granular powder

SECTION X - STABILITY AND REACTIVITY


Stability: Product is stable
(Conditions to Avoid): Excessive heat
Incompatibility: None
Hazardous Decomposition Products: Boric oxide fumes.
Hazardous Polymerization: Will not occur
(Conditions to Avoid): Excessive heat

SECTION XI - TOXICOLOGICAL INFORMATION


Acute Toxicity Data
1) Oral: LD-50 (rat): Not available
2) Inhalation: LC-50 (rat): Not available
3) Dermal: LD-50 (rabbit): Not available
4) Skin Irritation: (rabbit): Not available
Chronic Toxicity Data
1) Repeated Skin Application: (rat): Not available
2) Eye Irritation: (rabbit): Not available

SECTION XII - ECOLOGICAL INFORMATION


This material has not been tested for environmental effects.

SECTION XIII - DISPOSAL CONSIDERATIONS


Waste Disposal Method: Dispose of in accordance with EPA regulations

SECTION XIV- TRANSPORTATION


D.O.T. Proper Shipping Name: Non-Hazardous
Hazard Class: NA
Identification Number: NA
Packing Group: NA
Type D.O.T Label Required Information: NA

MSDS. Anti-Borax No. 1. Page 3 of 4


SECTION XV - REGULATORY INFORMATION
OSHA Hazardous Chemical According to 29 CFR 1910.1200: None

Carcinogenicity Classification (Components Present at 0.1% or More): Non-carcinogenic


International Agency for Research on Cancer (IARC): Not listed
American Conference of Governmental Industrial Hygienists (ACGIH): Not listed
National Toxicology Program (NTP): Not listed
Occupational Safety and Health Administration (OSHA): Not listed
None of the components of this product are listed on the U.S. toxic substances control act
inventory or otherwise comply with TSCA pre-manufacture notification requirements.

SECTION XVI - OTHER INFORMATION


The labeling of this product is indicated in Section II. The full text of all abbreviations indicated by
codes in the MSDS are as follows:

R25 Toxic if swallowed


R36 Irritating to eyes
R37 Irritating to respiratory system
R38 Irritating to skin
R60/61 May cause infertility/May cause harm to unborn child
R62 Possible risk of impaired fertility

S-26 In case of eye contact, rinse thoroughly and get medical attention
S-27 Take off immediately contaminated clothing
S-36/37/39 Wear suitable protective clothing, gloves, and eye/face protection
S-45 In case of accident or if feel unwell call medical advice immediately

H361f Suspected of damaging fertility

Further information:
Judgments as to the suitability of information herein or the purchaser's purposes are necessarily the purchaser's
responsibility. Reasonable care has been taken in the preparation of this material, but there are NO
WARRANTIES, NO REPRESENTATIONS AND NO RESPONSIBILITY AS TO THE ACCURACY OR THE
SUITABILITY OF THIS INFORMATION FOR ANY PURCHASER'S USE OR FOR ANY CONSEQUENCE
TO USE.

MSDS. Anti-Borax No. 1. Page 4 of 4


Material Safety Data Sheet
Argon (Gas)

1. Product and company identification


Product name : Argon (Gas)
Synonym : Argon.
Material uses : Various
CAS number : 7440-37-1
Supplier/Manufacturer : Air Liquide Canada Inc.
1250, René-Lévesque West, Suite 1700
Montreal, QC
H3B 5E6
www.airliquide.ca
1-800-817-7697
Prepared by : IHS
In case of emergency : (514) 878-1667

2. Hazards identification
Physical state : Gas.
Color : Colorless.
Odor : Odorless.
Emergency overview
Signal word : CAUTION!
Hazard statements : HIGH PRESSURE GAS. GAS REDUCES OXYGEN AVAILABLE FOR BREATHING.
MAY CAUSE TARGET ORGAN DAMAGE, BASED ON ANIMAL DATA.
Precautions : Contains gas under pressure. In a fire or if heated, a pressure increase will occur and
the container may burst or explode. At very high concentrations, can displace the
normal air and cause suffocation from lack of oxygen. Do not puncture or incinerate
container. Do not enter storage areas and confined spaces unless adequately
ventilated. Avoid breathing gas. Use only with adequate ventilation. Keep container
tightly closed and sealed until ready for use.
Routes of entry : Dermal contact. Eye contact. Inhalation.
Potential acute health effects
Inhalation : At very high concentrations, can displace the normal air and cause suffocation from lack
of oxygen.
Ingestion : As this product is a gas, refer to the inhalation section.
Skin : Contact with rapidly expanding gas may cause burns or frostbite.
Eyes : Contact with rapidly expanding gas may cause burns or frostbite.
Potential chronic health effects
Chronic effects : May cause target organ damage, based on animal data.
Carcinogenicity : No known significant effects or critical hazards.
Mutagenicity : No known significant effects or critical hazards.
Teratogenicity : No known significant effects or critical hazards.
Developmental effects : No known significant effects or critical hazards.

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1-800-817-7697
Argon (Gas)

2. Hazards identification
Fertility effects : No known significant effects or critical hazards.
Target organs : May cause damage to the following organs: lungs.

Over-exposure signs/symptoms
Inhalation : No specific data.
Ingestion : No specific data.
Skin : No specific data.
Eyes : No specific data.
Medical conditions : Pre-existing disorders involving any target organs mentioned in this MSDS as being at
aggravated by over- risk may be aggravated by over-exposure to this product.
exposure

3. Composition/information on ingredients
Name CAS number %
argon 7440-37-1 100
There are no additional ingredients present which, within the current knowledge of the supplier and in the
concentrations applicable, are classified as hazardous to health or the environment and hence require reporting
in this section.

4. First aid measures


Eye contact : Check for and remove any contact lenses. Immediately flush eyes with plenty of water
for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical
attention immediately.
Skin contact : In case of contact, immediately flush skin with plenty of water for at least 15 minutes
while removing contaminated clothing and shoes. Wash clothing before reuse. Clean
shoes thoroughly before reuse. Get medical attention immediately.
Inhalation : Move exposed person to fresh air. If not breathing, if breathing is irregular or if
respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel.
Loosen tight clothing such as a collar, tie, belt or waistband. Get medical attention
immediately.
Ingestion : As this product is a gas, refer to the inhalation section.
Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. If it is
suspected that fumes are still present, the rescuer should wear an appropriate mask or
self-contained breathing apparatus. It may be dangerous to the person providing aid to
give mouth-to-mouth resuscitation.
Antidote information
Product/ingredient name Antidote information
No antidote information known
Notes to physician : No specific treatment. Treat symptomatically. Contact poison treatment specialist
immediately if large quantities have been ingested or inhaled.

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Argon (Gas)

5. Fire-fighting measures
Flammability of the product : Contains gas under pressure. In a fire or if heated, a pressure increase will occur and
the container may burst or explode.
Extinguishing media
Suitable : Use an extinguishing agent suitable for the surrounding fire.
Not suitable : None known.
Special exposure hazards : Promptly isolate the scene by removing all persons from the vicinity of the incident if
there is a fire. No action shall be taken involving any personal risk or without suitable
training. Contact supplier immediately for specialist advice. Move containers from fire
area if this can be done without risk. Use water spray to keep fire-exposed containers
cool.
Hazardous thermal : No specific data.
decomposition products
Special protective : Fire-fighters should wear appropriate protective equipment and self-contained breathing
equipment for fire-fighters apparatus (SCBA) with a full face-piece operated in positive pressure mode.

6. Accidental release measures


Personal precautions : No action shall be taken involving any personal risk or without suitable training.
Evacuate surrounding areas. Keep unnecessary and unprotected personnel from
entering. Avoid breathing gas. Provide adequate ventilation. Wear appropriate
respirator when ventilation is inadequate. Put on appropriate personal protective
equipment (see Section 8). If leak is in user's equipment, be certain to purge piping with
an inert gas prior to attempting repairs. Never fix a leak while the system is under
pressure. If leak is on container or container valve, contact the closest Air Liquide
Canada location.
Environmental precautions : Ensure emergency procedures to deal with accidental gas releases are in place to avoid
contamination of the environment. Inform the relevant authorities if the product has
caused environmental pollution (sewers, waterways, soil or air).
Methods for cleaning up
Small spill : Immediately contact emergency personnel. Stop leak if without risk.
Large spill : Immediately contact emergency personnel. Stop leak if without risk. Note: see Section
1 for emergency contact information and Section 13 for waste disposal.

7. Handling and storage


Handling : Put on appropriate personal protective equipment (see Section 8). Eating, drinking and
smoking should be prohibited in areas where this material is handled, stored and
processed. Workers should wash hands and face before eating, drinking and smoking.
Remove contaminated clothing and protective equipment before entering eating areas.
Contains gas under pressure. Avoid contact with eyes, skin and clothing. Avoid
breathing gas. Use only with adequate ventilation. Wear appropriate respirator when
ventilation is inadequate. Valve protection caps must remain in place unless cylinder is
secured with valve outlet piped to usage point. Do not drag, slide or roll cylinders. Use a
suitable hand truck for cylinder movement. Use a pressure regulator when connecting
cylinder to lower pressure piping or systems. Do not heat cylinder by any means to
increase the discharge rate of product from the cylinder. Use a check valve or trap in
the discharge line to prevent hazardous back flow to the cylinder. Do not tamper with
(valve) safety device. Close valve after each use and when empty.

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Argon (Gas)

7. Handling and storage


Storage : Protect cylinders from physical damage. Store in cool, dry, well-ventilated area of non
combustible construction away from heavily trafficked areas and emergency exits. Do
not allow the temperature where cylinders are stored to exceed 52°C/125°F. Cylinders
must be stored upright and firmly secured to prevent falling or being knocked over. Full
and empty cylinders should be segregated. Use a "first in - first out" inventory system to
prevent full cylinders being stored for excessive periods of time. Store in accordance
with local regulations. Store in a segregated and approved area. Store in a dry, cool
and well-ventilated area, away from incompatible materials (see Section 10). Protect
from sunlight. Keep container tightly closed and sealed until ready for use.

8. Exposure controls/personal protection


Occupational exposure limits TWA (8 hours) STEL (15 mins) Ceiling

Ingredient List name ppm mg/m³ Other ppm mg/m³ Other ppm mg/m³ Other Notations
argon Simple asphyxiant. [2]

[2]Oxygen Depletion [Asphyxiant]

Consult local authorities for acceptable exposure limits.


Recommended monitoring : If this product contains ingredients with exposure limits, personal, workplace
procedures atmosphere or biological monitoring may be required to determine the effectiveness of
the ventilation or other control measures and/or the necessity to use respiratory
protective equipment. Reference should be made to appropriate monitoring standards.
Reference to national guidance documents for methods for the determination of
hazardous substances will also be required.
Engineering measures : Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or
other engineering controls to keep worker exposure to airborne contaminants below any
recommended or statutory limits.
Hygiene measures : Wash hands, forearms and face thoroughly after handling chemical products, before
eating, smoking and using the lavatory and at the end of the working period.
Appropriate techniques should be used to remove potentially contaminated clothing.
Wash contaminated clothing before reusing. Ensure that eyewash stations and safety
showers are close to the workstation location.
Personal protection
Respiratory : Use a properly fitted, air-purifying or air-fed respirator complying with an approved
standard if a risk assessment indicates this is necessary. If operating conditions cause
high gas concentrations to be produced or any recommended or statutory exposure limit
is exceeded, use an air-fed respirator or self-contained breathing apparatus. The gas
can cause asphyxiation without warning by replacing the oxygen in the air. Respirator
selection must be based on known or anticipated exposure levels, the hazards of the
product and the safe working limits of the selected respirator.
Hands : Chemical-resistant, impervious gloves complying with an approved standard should be
worn at all times when handling chemical products if a risk assessment indicates this is
necessary. Considering the parameters specified by the glove manufacturer, check
during use that the gloves are still retaining their protective properties. It should be
noted that the time to breakthrough for any glove material may be different for different
glove manufacturers. In the case of mixtures, consisting of several substances, the
protection time of the gloves cannot be accurately estimated.
Eyes : Safety eyewear complying with an approved standard should be used when a risk
assessment indicates this is necessary to avoid exposure to liquid splashes, mists or
dusts. If contact is possible, the following protection should be worn, unless the
assessment indicates a higher degree of protection: safety glasses with side-shields.
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Argon (Gas)

8. Exposure controls/personal protection


Skin : Personal protective equipment for the body should be selected based on the task being
performed and the risks involved and should be approved by a specialist before
handling this product.
Environmental exposure : Emissions from ventilation or work process equipment should be checked to ensure
controls they comply with the requirements of environmental protection legislation. In some
cases, fume scrubbers, filters or engineering modifications to the process equipment
will be necessary to reduce emissions to acceptable levels.

9. Physical and chemical properties


Physical state : Gas.
Flash point : Not available.
Auto-ignition temperature : Not available.
Flammable limits : Not available.
Color : Colorless.
Odor : Odorless.
Molecular weight : 39.95 g/mole
Molecular formula : Ar
pH : Not available.
Boiling/condensation point : -185.7°C (-302.3°F)
Melting/freezing point : -189.2°C (-308.6°F)
Critical temperature : -122.4°C (-188.3°F)
Density : Not available.
Vapor pressure : Not available.
Vapor density : 1.38 [Air = 1]
Odor threshold : Not available.
Evaporation rate : Not available.
Viscosity : Not available.
Solubility : Not available.
Water solubility (g/l) : 0.055 g/l
LogKow : 0.74

10. Stability and reactivity


Chemical stability : The product is stable.
Conditions to avoid : No specific data.
Incompatible materials : No specific data.
Hazardous decomposition : Under normal conditions of storage and use, hazardous decomposition products should
products not be produced.
Possibility of hazardous : Under normal conditions of storage and use, hazardous reactions will not occur.
reactions
Under normal conditions of storage and use, hazardous polymerization will not occur.

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Argon (Gas)

11. Toxicological information


Acute toxicity
Not available.
Chronic toxicity
Not available.

Irritation/Corrosion
Not available.
Sensitizer
Not available.
Carcinogenicity
Classification
Not available.

Mutagenicity
Not available.
Teratogenicity
Not available.
Reproductive toxicity
Not available.

12. Ecological information


Ecotoxicity : This product shows a low bioaccumulation potential.
Aquatic ecotoxicity
Not available.
Persistence/degradability
Not available.

Partition coefficient: n- : 0.74


octanol/water
Bioconcentration factor : Not available.
Mobility : Not available.
Toxicity of the products of : Not available.
biodegradation
Other adverse effects : No known significant effects or critical hazards.

13. Disposal considerations


Waste disposal : The generation of waste should be avoided or minimized wherever possible. Disposal of
this product, solutions and any by-products should at all times comply with the
requirements of environmental protection and waste disposal legislation and any
regional local authority requirements. Empty pressure vessels should be returned to the
supplier. Waste packaging should be recycled.
Disposal should be in accordance with applicable regional, national and local laws and regulations.

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Argon (Gas)

13. Disposal considerations


Refer to Section 7: HANDLING AND STORAGE and Section 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
for additional handling information and protection of employees.

14. Transport information


Regulatory UN number Proper shipping Classes PG* Label Additional
information name information
TDG Classification UN1006 ARGON, 2.2 - Explosive Limit and
COMPRESSED Limited Quantity Index
0.125

Passenger Carrying Road


or Rail Index
75

IMDG Class UN1006 ARGON, 2.2 - Emergency schedules


COMPRESSED (EmS)
F-C, S-V

IATA-DGR Class UN1006 Argon, compressed 2.2 - Passenger and Cargo


AircraftQuantity limitation:
75 kg
Packaging instructions: 200
Cargo Aircraft Only
Quantity limitation: 150 kg
Packaging instructions: 200
Limited Quantities -
Passenger AircraftQuantity
limitation: Forbidden
Packaging instructions:
Forbidden

Special provisions
A69

PG* : Packing group

15. Regulatory information


United States inventory : This material is listed or exempted.
(TSCA 8b)
WHMIS (Canada) : Class A: Compressed gas.
Canadian lists
Canadian NPRI : This material is not listed.
CEPA Toxic substances : This material is not listed.
Canada inventory : This material is listed or exempted.
This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations
and the MSDS contains all the information required by the Controlled Products Regulations.
International regulations

5/1/2014. Canada 7/8


www.airliquide.ca
1-800-817-7697
Argon (Gas)

15. Regulatory information


International lists : Australia inventory (AICS): This material is listed or exempted.
China inventory (IECSC): This material is listed or exempted.
Japan inventory: Not determined.
Korea inventory: This material is listed or exempted.
Malaysia Inventory (EHS Register): Not determined.
New Zealand Inventory of Chemicals (NZIoC): This material is listed or exempted.
Philippines inventory (PICCS): This material is listed or exempted.
Taiwan inventory (CSNN): This material is listed or exempted.
Chemical Weapons : Not listed
Convention List Schedule
I Chemicals
Chemical Weapons : Not listed
Convention List Schedule
II Chemicals
Chemical Weapons : Not listed
Convention List Schedule
III Chemicals

16. Other information


Label requirements : HIGH PRESSURE GAS. GAS REDUCES OXYGEN AVAILABLE FOR BREATHING.
MAY CAUSE TARGET ORGAN DAMAGE, BASED ON ANIMAL DATA.
Hazardous Material :
Information System (U.S.A.)
Health * 0

Flammability 0
Physical hazards 2
Personal protective equipment G

Caution: HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4
representing significant hazards or risks Although HMIS® ratings are not required on MSDSs under 29 CFR 1910.
1200, the preparer may choose to provide them. HMIS® ratings are to be used with a fully implemented HMIS®
program. HMIS® is a registered mark of the National Paint & Coatings Association (NPCA). HMIS® materials may
be purchased exclusively from J. J. Keller (800) 327-6868.
The customer is responsible for determining the PPE code for this material.
Date of issue : 5/1/2014.
Date of previous issue : 5/15/2011.
Version : 6
Indicates information that has changed from previously issued version.
Notice to reader
THE INFORMATION, RECOMMENDATIONS AND DATA CONTAINED IN THIS DOCUMENT ARE INTENDED TO BE
USED BY PROPERLY TRAINED AND QUALIFIED PERSONNEL ONLY AND AT THEIR SOLE RISKS AND DISCRETION.
THE INFORMATION, RECOMMENDATIONS AND DATA HEREIN CONTAINED ARE DERIVED FROMSOURCES
WHICH WE BELIEVE TO BE RELIABLE. HOWEVER, AIR LIQUIDE CANADA INC. MAKES NO REPRESENTATION AND
GIVES NO WARRANTY OF ANY KIND WHATSOEVER WITH RESPECT TO THEIR ACCURACY OR COMPLETENESS
AND ASSUMES NO LIABILITY FOR DAMAGES OR LOSS ARISING DIRECTLY OR INDIRECTLY FROM THEIR USE,
WHETHER PROPER OR IMPROPER.

5/1/2014. Canada 8/8


www.airliquide.ca
1-800-817-7697
SAFETY DATA SHEET <#####>122000013012
Bactine Original First Aid Liquid
Version 1.0 Revision Date 05/29/2015

1. IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING

Product information

Product Name: Bactine Original First Aid Liquid


SDS Number: 122000013012

Use : Medicinal products

Company
BAYER HEALTHCARE LLC
Consumer Care
100 Bayer Boulevard PO Box 915
Whippany, NJ 07981-0915
USA
(800) 743-5423

In case of emergency: (800) 331-4536


Chemtrec: (800) 424-9300
BAYER INFORMATION PHONE:(800) 331-4536 OR (800) 743-5423

2. HAZARDS IDENTIFICATION

Emergency Overview
Colour: clear, cloudy, colourless Form: liquid Odour: characteristic.

GHS Classification:
Not a dangerous substance / mixture according to GHS.

GHS Label element:

This material is not subject to the Federal OSHA Hazard Communication Standard 29 CFR 1910.1200.

3. COMPOSITION/INFORMATION ON INGREDIENTS

Weight percent Components CAS-No.


2.49% Lidocaine Hydrochloride 73-78-9

Page 1 of 9
SAFETY DATA SHEET <#####>122000013012
Bactine Original First Aid Liquid
Version 1.0 Revision Date 05/29/2015

Label Ingredients: Benzakonium Chloride; Lidocaine hydrochloride; Edetate Disodium;


Nonoxynol 9; 1,2-Propanediol; Water;

Other Ingredients
Weight percent Components CAS-No.
5 - 10% Propane-1,2-diol 57-55-6

4. FIRST AID MEASURES

General advice: Take off all contaminated clothing immediately.

If inhaled: Remove to fresh air. Call a physician immediately.

In case of skin contact: If skin reactions occur, contact a physician.

In case of eye contact: In the case of contact with eyes, rinse immediately with plenty of water and
seek medical advice.

If swallowed: If swallowed, seek medical advice immediately and show this container or label.

Contact Number: Use the Bayer Emergency Number in Section 1

5. FIREFIGHTING MEASURES

Suitable extinguishing media: Use water spray, alcohol-resistant foam, dry chemical or carbon
dioxide.

Unsuitable extinguishing media: High volume water jet

Specific hazards during firefighting: Fire may cause evolution of: Carbon monoxide (CO)
Carbon dioxide (CO2)

Special protective equipment for firefighters: In the event of fire, wear self-contained breathing
apparatus.

Further information: Prevent fire extinguishing water from contaminating surface water or the
ground water system.

6. ACCIDENTAL RELEASE MEASURES

Personal precautions: Use personal protective equipment.

Methods for cleaning up: Cover spilled product with liquid-binding material (sand, silica gel, acid
binder, universal binder, hybilat). Take up mechanically and fill into labeled, closable containers.

Page 2 of 9
SAFETY DATA SHEET <#####>122000013012
Bactine Original First Aid Liquid
Version 1.0 Revision Date 05/29/2015

Additional advice: No special precautions required.

Further Accidental No special precautions required.


Release Notes

7. HANDLING AND STORAGE

Handling:
Keep this and all drugs out of the reach of children. Avoid contact with eyes. Store in a dry place
away from excessive heat. Reseal containers immediately after use. Use normal precautions for
storage of a drug.

Keep away from open flames, hot surfaces and sources of ignition.

Storage:
Storage temperature: 59 - 77 °F (15 - 25 °C)
Do not use after expiration date.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Propane-1,2-diol (57-55-6)
US. AIHA Workplace Environmental Exposure Level (WEEL) Guides
Time Weighted Average (TWA): 10 mg/m3 (Aerosol.)

Propane-1,2-diol (57-55-6)
US. AIHA Workplace Environmental Exposure Level (WEEL) Guides
Time Weighted Average (TWA): 10 mg/m3 (Aerosol.)

Respiratory protection:
Recommended Filter type: Organic vapor with prefilter

None required for consumer use of this product.

Hand protection:
Chemically resistant gloves.
None required for consumer use of this product.

Eye protection:
Safety glasses

None required for consumer use of this product.

Hygiene measures:
Cleanliness Guidelines (GMP) for manufacturing of drugs must be observed!

Other protective measures:


Wear suitable protective equipment.

Please consult label for end-user requirements.

Page 3 of 9
SAFETY DATA SHEET <#####>122000013012
Bactine Original First Aid Liquid
Version 1.0 Revision Date 05/29/2015

9. PHYSICAL AND CHEMICAL PROPERTIES

Form: liquid
Colour: clear, cloudy, colourless
Odour: characteristic
Odour Threshold: No applicable information is available
Melting point: No applicable information is available
Boiling point/boiling range: No applicable information is available
Density: No applicable information is available
Bulk density: No applicable information is available
Vapour pressure: No applicable information is available
Viscosity, dynamic: No applicable information is available
Viscosity, kinematic: No applicable information is available
Flow time: No applicable information is available
Surface tension: No applicable information is available
Miscibility with water: No applicable information is available
Water solubility: completely soluble
pH: 6 - 6.8
Relative density: No applicable information is available
Partition coefficient: No applicable information is available
Solubility(ies): No applicable information is available
Flash point: No applicable information is available
Flammability (solid, gas): No applicable information is available
Ignition temperature: No applicable information is available
Explosion limits: No applicable information is available

10. STABILITY AND REACTIVITY

Conditions to avoid: No data available

Materials to avoid: Oxidizing agents

Hazardous reactions: None known.

Thermal decomposition:

No data available

Hazardous decomposition products:


Carbon monoxide (CO), Carbon dioxide (CO2)

Oxidizing properties:

No statements available.

Page 4 of 9
SAFETY DATA SHEET <#####>122000013012
Bactine Original First Aid Liquid
Version 1.0 Revision Date 05/29/2015

Impact sensitivity:
No data available

11. TOXICOLOGICAL INFORMATION


Other information on toxicity:

No data is available on the product itself.

Acute oral toxicity:


Acute toxicity estimate (ATE) > 2,000 mg/kg
The substance or mixture has no acute oral toxicity
Method: Calculation method
Calculated for GHS Classification and Labelling.

Acute inhalation toxicity:


Propane-1,2-diol
LC50 Rabbit: > 317 mg/l, 2 h
The substance or mixture has no acute inhalation toxicity

Acute dermal toxicity:


Propane-1,2-diol
LD50 Rabbit: > 5,000 mg/kg
The substance or mixture has no acute dermal toxicity

Acute toxicity (other routes of administration):


Lidocaine Hydrochloride
TDL0 intravenous human: 7.1 mg/kg

LD50 intraperitoneal Rat: 122 mg/kg

LD50 subcutaneous Rat: 570 mg/kg

LD50 intravenous Rat: 21 mg/kg

LDL0 intravenous Dog: 65.7 mg/kg

LD50 intravenous Rabbit: 25.6 mg/kg

LD50 intravenous Mouse: 22 mg/kg

LD50 intraperitoneal Mouse: 119 mg/kg

LD50 intramuscular Mouse: 260 mg/kg

Skin irritation:
Propane-1,2-diol
Rabbit
Result: No skin irritation

Page 5 of 9
SAFETY DATA SHEET <#####>122000013012
Bactine Original First Aid Liquid
Version 1.0 Revision Date 05/29/2015

Lidocaine Hydrochloride
Rabbit
Result: Moderate skin irritation
Method: Draize Test
According to the classification criteria of the European Union, the product is not considered as
being a skin irritant.

Eye irritation:
Propane-1,2-diol
Rabbit
Result: No eye irritation

Lidocaine Hydrochloride
Rabbit
Result: Moderate eye irritation
Method: Draize Test
No eye irritation

Sensitisation:
Propane-1,2-diol
Human experience
Result: Does not cause skin sensitisation.

guinea pig
Result: Does not cause skin sensitisation.

Method: OECD 406

Subacute, subchronic and prolonged toxicity:


Propane-1,2-diol
NOEL 50,000 mg/kg, Rat Oral, Exposure time 24 month

NOEL 1 mg/l, Rat Inhalation, Exposure time 3 month


Number of exposures: once daily

Genotoxicity in vitro:
Propane-1,2-diol
Ames test Bacteria
Dose: yes
Result: negative
Method: OECD 471

Mammalian cells
Result: negative
Method: OECD 476

Lidocaine Hydrochloride
Ames test Salmonella typhimurium
Result: negative

Hamster ovary-cells
Result: negative

Page 6 of 9
SAFETY DATA SHEET <#####>122000013012
Bactine Original First Aid Liquid
Version 1.0 Revision Date 05/29/2015

Genotoxicity in vivo:
Propane-1,2-diol

Result: negative
Method: OECD 478

Carcinogenicity:
Propane-1,2-diol
Rat:
Exposure time: 2 a
Number of exposures: once daily
Result: negative

Reproductive toxicity:
Propane-1,2-diol
Application Route: Oral
Rat, female: Test period: 18 d
NOAEL: 1600 mg/kg
Result: Animal testing did not show any effects on fertility.

Teratogenicity:
Propane-1,2-diol
Rat, male: Number of exposures: once daily
Test period: 15 d
NOAEL: 1600 mg/l
Result: No indication of teratogenic effects.

Lidocaine Hydrochloride
Application Route: subcutaneous
Rat: NOAEL: 30 mg/kg 72 mg/kg/day
Result: Did not show teratogenic effects in animal experiments.

Application Route: intraperitoneal


Rat: NOAEL: 56 mg/kg/day
Result: Did not show teratogenic effects in animal experiments.

Pharmaceutic effects:
Analgesic Antiseptic

Carcinogenicity:
No Carcinogenic substances as defined by IARC, NTP and/or OSHA

STOT - single exposure:


No data available
STOT - repeated exposure:
No data available

12. ECOLOGICAL INFORMATION

General advice:
Do not allow to enter surface waters or groundwater. No data is available on the product itself.

Page 7 of 9
SAFETY DATA SHEET <#####>122000013012
Bactine Original First Aid Liquid
Version 1.0 Revision Date 05/29/2015

Toxicity to fish:
Propane-1,2-diol
Acute Fish toxicity: LC50 40,613 mg/l
Test species: Pimephales promelas (fathead minnow) Duration of test: 96 h

Toxicity to daphnia and other aquatic invertebrates:


Propane-1,2-diol
LC50 18,340 mg/l
Test species: Ceriodaphnia dubia (water flea) Duration of test: 48 h

Toxicity to algae:
Propane-1,2-diol
IC50 19,100 mg/l
tested on: Pseudokirchneriella subcapitata (green algae)

Toxicity to bacteria:
Propane-1,2-diol
NOEC 20,000 mg/l
tested on: Pseudomonas putida
Duration of test: 18 h

Biodegradability:
Propane-1,2-diol
87 - 92 %, 28 d rapidly biodegradable
Method: OECD 301 C

Bioaccumulation:
Propane-1,2-diol

Bioconcentration factor (BCF)


0.09

13. DISPOSAL CONSIDERATIONS

If discarded in its purchased form, this product would not be a hazardous waste either by listing or
by characteristic. However, under RCRA, it is the responsibility of the product user to determine at
the time of disposal, whether a material containing the product or derived from the product should
be classified as a hazardous waste. (40 CFR 261.20-24)

Waste disposal should be in accordance with existing federal, state and local environmental control
laws.

14. TRANSPORT INFORMATION

Land transport (CFR)


non-regulated

US Sea transport (IMDG)


non-regulated

Page 8 of 9
SAFETY DATA SHEET <#####>122000013012
Bactine Original First Aid Liquid
Version 1.0 Revision Date 05/29/2015

US Air transport (ICAO / IATA cargo aircraft only)


non-regulated

US Air transport (ICAO / IATA passenger and cargo aircraft)


non-regulated

International IATA non-regulated


IMDG non-regulated

15. REGULATORY INFORMATION

US. EPA Emergency Planning and Community Right-To-Know Act (EPCRA) SARA Title III Section
302 Extremely Hazardous Substance (40 CFR 355, Appendix A)
Components
None

US. EPA Emergency Planning and Community Right-To-Know Act (EPCRA) SARA Title III Section
313 Toxic Chemicals (40 CFR 372.65) - Supplier Notification Required
Components
None

US. EPA CERCLA Hazardous Substances (40 CFR 302) Components


None

Massachusetts, New Jersey or Pennsylvania Right to Know Substance Lists


Weight percent Components CAS-No.
5 - 10% Propane-1,2-diol 57-55-6

California Prop. 65

To the best of our knowledge, this product does not contain any of the listed chemicals, which the
state of California has found to cause cancer, birth defects or other reproductive harm.

OSHA Hazcom Standard Rating Not subject to OSHA

16. OTHER INFORMATION

Further information
The information provided in this Safety Data Sheet is correct to the best of our knowledge, information
and belief at the date of its publication. The information given is designed only as a guidance for safe
handling, use, processing, storage, transportation, disposal and release and is not to be considered a
warranty or quality specification. The information relates only to the specific material designated and
may not be valid for such material used in combination with any other materials or in any process,
unless specified in the text.

Page 9 of 9
SAFETY DATA SHEET
BD1108

Section 1. Identification
Product name : BD7-77 PLUS Penetrant
Product code : BD1108
Other means of : Not available.
identification
Product type : Aerosol.
Relevant identified uses of the substance or mixture and uses advised against
Not applicable.

Manufacturer : Class C Solutions Group


a business of MSC Industrial Supply Co.
75 Maxess Road
Melville, NY 11747-3151

Emergency telephone : (303) 623-5716


number of the company
Product Information : (866) 438-6767
Telephone Number
Regulatory Information : (216) 566-2902
Telephone Number
Transportation Emergency : (800) 424-9300
Telephone Number

Section 2. Hazards identification


OSHA/HCS status : This material is considered hazardous by the OSHA Hazard Communication Standard
(29 CFR 1910.1200).
Classification of the : FLAMMABLE AEROSOLS - Category 1
substance or mixture GASES UNDER PRESSURE - Compressed gas
SKIN CORROSION/IRRITATION - Category 2
SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 2A
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Respiratory tract
irritation and Narcotic effects) - Category 3
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) - Category 2
ASPIRATION HAZARD - Category 1
Percentage of the mixture consisting of ingredient(s) of unknown toxicity: 57%
GHS label elements
Hazard pictograms :

Signal word : Danger

Date of issue/Date of revision : 3/24/2015. Date of previous issue : No previous validation. Version :1 1/13
Section 2. Hazards identification
Hazard statements : Extremely flammable aerosol.
Contains gas under pressure; may explode if heated.
Causes serious eye irritation.
Causes skin irritation.
May be fatal if swallowed and enters airways.
May cause respiratory irritation.
May cause drowsiness and dizziness.
May cause damage to organs through prolonged or repeated exposure.
Precautionary statements
Prevention : Wear protective gloves. Wear eye or face protection. Keep away from heat, hot
surfaces, sparks, open flames and other ignition sources. No smoking. Pressurized
container: Do not pierce or burn, even after use. Do not spray on an open flame or
other ignition source. Use only outdoors or in a well-ventilated area. Do not breathe
dust or mist. Wash hands thoroughly after handling.
Response : Get medical attention if you feel unwell. IF INHALED: Remove victim to fresh air and
keep at rest in a position comfortable for breathing. Call a POISON CENTER or
physician if you feel unwell. IF SWALLOWED: Immediately call a POISON CENTER or
physician. Do NOT induce vomiting. IF ON SKIN: Wash with plenty of soap and water.
Take off contaminated clothing. Wash contaminated clothing before reuse. If skin
irritation occurs: Get medical attention. IF IN EYES: Rinse cautiously with water for
several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If
eye irritation persists: Get medical attention.
Storage : Store locked up. Protect from sunlight. Do not expose to temperatures exceeding 50
°C/122 °F. Store in a well-ventilated place.
Disposal Dispose of contents and container in accordance with all local, regional, national and
international regulations.
Supplemental label DELAYED EFFECTS FROM LONG TERM OVEREXPOSURE. Contains solvents which
elements can cause permanent brain and nervous system damage. Intentional misuse by
deliberately concentrating and inhaling the contents can be harmful or fatal. WARNING:
This product contains chemicals known to the State of California to cause cancer and
birth defects or other reproductive harm. FOR INDUSTRIAL USE ONLY.
Please refer to the SDS for additional information. Keep upright in a cool, dry place. Do
not discard empty can in trash compactor.
Hazards not otherwise : None known.
classified

Section 3. Composition/information on ingredients


Substance/mixture : Mixture
Other means of : Not available.
identification

CAS number/other identifiers


Ingredient name % by weight CAS number
Med. Aliphatic Hydrocarbon Solvent 49.3 64742-88-7
Kerosine, petroleum 15.0 8008-20-6
2-Butoxyethanol 10.5 111-76-2
Heavy Paraffinic Oil 8.0 64742-65-0
Propane 7.7 74-98-6
Butane 7.3 106-97-8
Calcium Dinonylnaphthalene Sulfonate 1.0 57855-77-3
There are no additional ingredients present which, within the current knowledge of the supplier and in the
concentrations applicable, are classified as hazardous to health or the environment and hence require reporting
in this section.
Occupational exposure limits, if available, are listed in Section 8.

Date of issue/Date of revision : 3/24/2015. Date of previous issue : No previous validation. Version :1 2/13
Section 4. First aid measures
Description of necessary first aid measures
Eye contact : Immediately flush eyes with plenty of water, occasionally lifting the upper and lower
eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10
minutes. Get medical attention.
Inhalation : Remove victim to fresh air and keep at rest in a position comfortable for breathing. If it
is suspected that fumes are still present, the rescuer should wear an appropriate mask
or self-contained breathing apparatus. If not breathing, if breathing is irregular or if
respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It
may be dangerous to the person providing aid to give mouth-to-mouth resuscitation.
Get medical attention. If necessary, call a poison center or physician. If unconscious,
place in recovery position and get medical attention immediately. Maintain an open
airway. Loosen tight clothing such as a collar, tie, belt or waistband.
Skin contact : Flush contaminated skin with plenty of water. Remove contaminated clothing and
shoes. Continue to rinse for at least 10 minutes. Get medical attention. Wash clothing
before reuse. Clean shoes thoroughly before reuse.
Ingestion : Get medical attention immediately. Call a poison center or physician. Wash out mouth
with water. Remove dentures if any. Remove victim to fresh air and keep at rest in a
position comfortable for breathing. If material has been swallowed and the exposed
person is conscious, give small quantities of water to drink. Stop if the exposed person
feels sick as vomiting may be dangerous. Aspiration hazard if swallowed. Can enter
lungs and cause damage. Do not induce vomiting. If vomiting occurs, the head should
be kept low so that vomit does not enter the lungs. Never give anything by mouth to an
unconscious person. If unconscious, place in recovery position and get medical
attention immediately. Maintain an open airway. Loosen tight clothing such as a collar,
tie, belt or waistband.

Most important symptoms/effects, acute and delayed


Potential acute health effects
Eye contact : Causes serious eye irritation.
Inhalation : Can cause central nervous system (CNS) depression. May cause drowsiness and
dizziness. May cause respiratory irritation.
Skin contact : Causes skin irritation.
Ingestion : Can cause central nervous system (CNS) depression. May be fatal if swallowed and
enters airways. Irritating to mouth, throat and stomach.
Over-exposure signs/symptoms
Eye contact : Adverse symptoms may include the following:
pain or irritation
watering
redness
Inhalation : Adverse symptoms may include the following:
respiratory tract irritation
coughing
nausea or vomiting
headache
drowsiness/fatigue
dizziness/vertigo
unconsciousness
Skin contact : Adverse symptoms may include the following:
irritation
redness
Ingestion : Adverse symptoms may include the following:
nausea or vomiting

Indication of immediate medical attention and special treatment needed, if necessary

Date of issue/Date of revision : 3/24/2015. Date of previous issue : No previous validation. Version :1 3/13
Section 4. First aid measures
Notes to physician : Treat symptomatically. Contact poison treatment specialist immediately if large
quantities have been ingested or inhaled.
Specific treatments : No specific treatment.
Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. If it is
suspected that fumes are still present, the rescuer should wear an appropriate mask or
self-contained breathing apparatus. It may be dangerous to the person providing aid to
give mouth-to-mouth resuscitation.

See toxicological information (Section 11)

Section 5. Fire-fighting measures


Extinguishing media
Suitable extinguishing : Use an extinguishing agent suitable for the surrounding fire.
media
Unsuitable extinguishing : None known.
media

Specific hazards arising : Extremely flammable aerosol. In a fire or if heated, a pressure increase will occur and
from the chemical the container may burst, with the risk of a subsequent explosion. Gas may accumulate
in low or confined areas or travel a considerable distance to a source of ignition and
flash back, causing fire or explosion. Bursting aerosol containers may be propelled from
a fire at high speed. Runoff to sewer may create fire or explosion hazard. Fire water
contaminated with this material must be contained and prevented from being discharged
to any waterway, sewer or drain.
Hazardous thermal : Decomposition products may include the following materials:
decomposition products carbon dioxide
carbon monoxide
sulfur oxides
metal oxide/oxides

Special protective actions : Promptly isolate the scene by removing all persons from the vicinity of the incident if
for fire-fighters there is a fire. No action shall be taken involving any personal risk or without suitable
training. Move containers from fire area if this can be done without risk. Use water
spray to keep fire-exposed containers cool.
Special protective : Fire-fighters should wear appropriate protective equipment and self-contained breathing
equipment for fire-fighters apparatus (SCBA) with a full face-piece operated in positive pressure mode.

Section 6. Accidental release measures


Personal precautions, protective equipment and emergency procedures
For non-emergency : No action shall be taken involving any personal risk or without suitable training.
personnel Evacuate surrounding areas. Keep unnecessary and unprotected personnel from
entering. In the case of aerosols being ruptured, care should be taken due to the rapid
escape of the pressurized contents and propellant. If a large number of containers are
ruptured, treat as a bulk material spillage according to the instructions in the clean-up
section. Do not touch or walk through spilled material. Shut off all ignition sources. No
flares, smoking or flames in hazard area. Avoid breathing vapor or mist. Provide
adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put
on appropriate personal protective equipment.
For emergency responders : If specialised clothing is required to deal with the spillage, take note of any information in
Section 8 on suitable and unsuitable materials. See also the information in "For non-
emergency personnel".

Environmental precautions :

Date of issue/Date of revision : 3/24/2015. Date of previous issue : No previous validation. Version :1 4/13
Section 6. Accidental release measures
Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains
and sewers. Inform the relevant authorities if the product has caused environmental
pollution (sewers, waterways, soil or air). Water polluting material. May be harmful to
the environment if released in large quantities.

Methods and materials for containment and cleaning up


Small spill : Stop leak if without risk. Move containers from spill area. Use spark-proof tools and
explosion-proof equipment. Dilute with water and mop up if water-soluble. Alternatively,
or if water-insoluble, absorb with an inert dry material and place in an appropriate waste
disposal container. Dispose of via a licensed waste disposal contractor.
Large spill : Stop leak if without risk. Move containers from spill area. Use spark-proof tools and
explosion-proof equipment. Approach release from upwind. Prevent entry into sewers,
water courses, basements or confined areas. Wash spillages into an effluent treatment
plant or proceed as follows. Contain and collect spillage with non-combustible,
absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in
container for disposal according to local regulations (see Section 13). Dispose of via a
licensed waste disposal contractor. Contaminated absorbent material may pose the
same hazard as the spilled product. Note: see Section 1 for emergency contact
information and Section 13 for waste disposal.

Section 7. Handling and storage


Precautions for safe handling
Protective measures : Put on appropriate personal protective equipment (see Section 8). Pressurized
container: protect from sunlight and do not expose to temperatures exceeding 50°C. Do
not pierce or burn, even after use. Do not breathe vapor or mist. Do not swallow.
Avoid contact with eyes, skin and clothing. Avoid breathing gas. Avoid release to the
environment. Use only with adequate ventilation. Wear appropriate respirator when
ventilation is inadequate. Store and use away from heat, sparks, open flame or any
other ignition source. Use explosion-proof electrical (ventilating, lighting and material
handling) equipment. Use only non-sparking tools. Empty containers retain product
residue and can be hazardous.
Advice on general : Eating, drinking and smoking should be prohibited in areas where this material is
occupational hygiene handled, stored and processed. Workers should wash hands and face before eating,
drinking and smoking. Remove contaminated clothing and protective equipment before
entering eating areas. See also Section 8 for additional information on hygiene
measures.

Conditions for safe storage, : Store in accordance with local regulations. Store away from direct sunlight in a dry, cool
including any and well-ventilated area, away from incompatible materials (see Section 10) and food
incompatibilities and drink. Protect from sunlight. Store locked up. Eliminate all ignition sources. Use
appropriate containment to avoid environmental contamination.

Section 8. Exposure controls/personal protection


Control parameters
Occupational exposure limits
Ingredient name Exposure limits
Med. Aliphatic Hydrocarbon Solvent OSHA PEL (United States, 2/2013).
TWA: 100 ppm 8 hours.
TWA: 400 mg/m³ 8 hours.
Kerosine, petroleum NIOSH REL (United States, 10/2013).
TWA: 100 mg/m³ 10 hours.
ACGIH TLV (United States, 4/2014).
Absorbed through skin.
TWA: 200 mg/m³, (as total hydrocarbon
vapor) 8 hours.

Date of issue/Date of revision : 3/24/2015. Date of previous issue : No previous validation. Version :1 5/13
Section 8. Exposure controls/personal protection
2-Butoxyethanol ACGIH TLV (United States, 4/2014).
TWA: 20 ppm 8 hours.
NIOSH REL (United States, 10/2013).
Absorbed through skin.
TWA: 5 ppm 10 hours.
TWA: 24 mg/m³ 10 hours.
OSHA PEL (United States, 2/2013).
Absorbed through skin.
TWA: 50 ppm 8 hours.
TWA: 240 mg/m³ 8 hours.
Heavy Paraffinic Oil ACGIH TLV (United States, 4/2014).
TWA: 5 mg/m³ 8 hours. Form: Inhalable
fraction
NIOSH REL (United States, 10/2013).
TWA: 5 mg/m³ 10 hours. Form: Mist
STEL: 10 mg/m³ 15 minutes. Form: Mist
OSHA PEL (United States, 2/2013).
TWA: 5 mg/m³ 8 hours.
Propane NIOSH REL (United States, 10/2013).
TWA: 1000 ppm 10 hours.
TWA: 1800 mg/m³ 10 hours.
OSHA PEL (United States, 2/2013).
TWA: 1000 ppm 8 hours.
TWA: 1800 mg/m³ 8 hours.
Butane NIOSH REL (United States, 10/2013).
TWA: 800 ppm 10 hours.
TWA: 1900 mg/m³ 10 hours.
ACGIH TLV (United States, 4/2014).
STEL: 1000 ppm 15 minutes.

Appropriate engineering : Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or
controls other engineering controls to keep worker exposure to airborne contaminants below any
recommended or statutory limits. The engineering controls also need to keep gas,
vapor or dust concentrations below any lower explosive limits. Use explosion-proof
ventilation equipment.
Environmental exposure : Emissions from ventilation or work process equipment should be checked to ensure
controls they comply with the requirements of environmental protection legislation. In some
cases, fume scrubbers, filters or engineering modifications to the process equipment
will be necessary to reduce emissions to acceptable levels.

Individual protection measures


Hygiene measures : Wash hands, forearms and face thoroughly after handling chemical products, before
eating, smoking and using the lavatory and at the end of the working period.
Appropriate techniques should be used to remove potentially contaminated clothing.
Wash contaminated clothing before reusing. Ensure that eyewash stations and safety
showers are close to the workstation location.
Eye/face protection : Safety eyewear complying with an approved standard should be used when a risk
assessment indicates this is necessary to avoid exposure to liquid splashes, mists,
gases or dusts. If contact is possible, the following protection should be worn, unless
the assessment indicates a higher degree of protection: chemical splash goggles.
Skin protection
Hand protection : Chemical-resistant, impervious gloves complying with an approved standard should be
worn at all times when handling chemical products if a risk assessment indicates this is
necessary. Considering the parameters specified by the glove manufacturer, check
during use that the gloves are still retaining their protective properties. It should be
noted that the time to breakthrough for any glove material may be different for different
glove manufacturers. In the case of mixtures, consisting of several substances, the
protection time of the gloves cannot be accurately estimated.
Date of issue/Date of revision : 3/24/2015. Date of previous issue : No previous validation. Version :1 6/13
Section 8. Exposure controls/personal protection
Body protection : Personal protective equipment for the body should be selected based on the task being
performed and the risks involved and should be approved by a specialist before
handling this product. When there is a risk of ignition from static electricity, wear anti-
static protective clothing. For the greatest protection from static discharges, clothing
should include anti-static overalls, boots and gloves.
Other skin protection : Appropriate footwear and any additional skin protection measures should be selected
based on the task being performed and the risks involved and should be approved by a
specialist before handling this product.
Respiratory protection : Use a properly fitted, air-purifying or air-fed respirator complying with an approved
standard if a risk assessment indicates this is necessary. Respirator selection must be
based on known or anticipated exposure levels, the hazards of the product and the safe
working limits of the selected respirator.

Section 9. Physical and chemical properties


Appearance
Physical state : Liquid.
Color : Not available.
Odor : Not available.
Odor threshold : Not available.
pH : Not available.
Melting point : Not available.
Boiling point : Not available.
Flash point : Closed cup: -29°C (-20.2°F) [Pensky-Martens Closed Cup]
Evaporation rate : 1 (butyl acetate = 1)
Flammability (solid, gas) : Not available.
Lower and upper explosive : Lower: 0.7%
(flammable) limits Upper: 10.6%
Vapor pressure : 13.5 kPa (101.325 mm Hg) [at 20°C]
Vapor density : 1.55 [Air = 1]
Relative density : 0.74
Solubility : Not available.
Partition coefficient: n- : Not available.
octanol/water
Auto-ignition temperature : Not available.
Decomposition temperature : Not available.
Viscosity : Kinematic (room temperature): <0.07 cm2/s (<7 cSt)
Kinematic (40°C (104°F)): <0.07 cm2/s (<7 cSt)
Aerosol product
Type of aerosol : Spray
Heat of combustion : 0.00003961 kJ/g

Section 10. Stability and reactivity


Reactivity : No specific test data related to reactivity available for this product or its ingredients.

Chemical stability : The product is stable.

Possibility of hazardous : Under normal conditions of storage and use, hazardous reactions will not occur.
reactions

Conditions to avoid : Avoid all possible sources of ignition (spark or flame).


Date of issue/Date of revision : 3/24/2015. Date of previous issue : No previous validation. Version :1 7/13
Section 10. Stability and reactivity

Incompatible materials : No specific data.

Hazardous decomposition : Under normal conditions of storage and use, hazardous decomposition products should
products not be produced.

Section 11. Toxicological information


Information on toxicological effects
Acute toxicity
Product/ingredient name Result Species Dose Exposure
Kerosine, petroleum LD50 Oral Rat 15 g/kg -
2-Butoxyethanol LCLo Inhalation Vapor Guinea pig >3.1 mg/l 1 hours
LD50 Dermal Guinea pig >2000 mg/kg -
LD50 Oral Rat 1300 mg/kg -
Heavy Paraffinic Oil LD50 Dermal Rabbit >5000 mg/kg -
LD50 Oral Rat >5000 mg/kg -
Butane LC50 Inhalation Vapor Rat 658000 mg/m³ 4 hours
Calcium Dinonylnaphthalene LD50 Dermal Rabbit >20 g/kg -
Sulfonate
LD50 Oral Rat >5000 mg/kg -
Irritation/Corrosion
Product/ingredient name Result Species Score Exposure Observation
Kerosine, petroleum Skin - Moderate irritant Rabbit - 0.5 Mililiters -
Skin - Moderate irritant Rabbit - 24 hours 100 -
Percent
Skin - Severe irritant Rabbit - 500 -
milligrams
2-Butoxyethanol Eyes - Moderate irritant Rabbit - 24 hours 100 -
milligrams
Eyes - Severe irritant Rabbit - 100 -
milligrams
Skin - Mild irritant Rabbit - 500 -
milligrams
Calcium Dinonylnaphthalene Skin - Moderate irritant Rabbit - 0.5 Mililiters -
Sulfonate
Sensitization
Not available.
Mutagenicity
Not available.
Carcinogenicity
Not available.

Classification
Product/ingredient name OSHA IARC NTP
Kerosine, petroleum - 3 -
2-Butoxyethanol - 3 -
Reproductive toxicity
Not available.
Teratogenicity
Not available.

Date of issue/Date of revision : 3/24/2015. Date of previous issue : No previous validation. Version :1 8/13
Section 11. Toxicological information
Specific target organ toxicity (single exposure)
Name Category Route of Target organs
exposure
Med. Aliphatic Hydrocarbon Solvent Category 3 Not applicable. Respiratory tract
irritation and
Narcotic effects
Kerosine, petroleum Category 3 Not applicable. Respiratory tract
irritation and
Narcotic effects
2-Butoxyethanol Category 3 Not applicable. Respiratory tract
irritation and
Narcotic effects
Heavy Paraffinic Oil Category 3 Not applicable. Respiratory tract
irritation and
Narcotic effects
Propane Category 3 Not applicable. Respiratory tract
irritation and
Narcotic effects
Butane Category 3 Not applicable. Respiratory tract
irritation and
Narcotic effects
Specific target organ toxicity (repeated exposure)
Name Category Route of Target organs
exposure
Med. Aliphatic Hydrocarbon Solvent Category 2 Not determined Not determined
Kerosine, petroleum Category 2 Not determined Not determined
2-Butoxyethanol Category 2 Not determined Not determined
Heavy Paraffinic Oil Category 2 Not determined Not determined
Propane Category 2 Not determined Not determined
Butane Category 2 Not determined Not determined
Aspiration hazard
Name Result
Med. Aliphatic Hydrocarbon Solvent ASPIRATION HAZARD - Category 1
Propane ASPIRATION HAZARD - Category 1
Butane ASPIRATION HAZARD - Category 1

Information on the likely : Not available.


routes of exposure
Potential acute health effects
Eye contact : Causes serious eye irritation.
Inhalation : Can cause central nervous system (CNS) depression. May cause drowsiness and
dizziness. May cause respiratory irritation.
Skin contact : Causes skin irritation.
Ingestion : Can cause central nervous system (CNS) depression. May be fatal if swallowed and
enters airways. Irritating to mouth, throat and stomach.

Symptoms related to the physical, chemical and toxicological characteristics


Eye contact : Adverse symptoms may include the following:
pain or irritation
watering
redness

Date of issue/Date of revision : 3/24/2015. Date of previous issue : No previous validation. Version :1 9/13
Inhalation : Adverse symptoms may include the following:
respiratory tract irritation
coughing
nausea or vomiting
headache
drowsiness/fatigue
dizziness/vertigo
unconsciousness
Skin contact : Adverse symptoms may include the following:
irritation
redness
Ingestion : Adverse symptoms may include the following:
nausea or vomiting

Delayed and immediate effects and also chronic effects from short and long term exposure
Short term exposure
Potential immediate : Not available.
effects
Potential delayed effects : Not available.
Long term exposure
Potential immediate : Not available.
effects
Potential delayed effects : Not available.
Potential chronic health effects
Not available.
General : May cause damage to organs through prolonged or repeated exposure.
Carcinogenicity : No known significant effects or critical hazards.
Mutagenicity : No known significant effects or critical hazards.
Teratogenicity : No known significant effects or critical hazards.
Developmental effects : No known significant effects or critical hazards.
Fertility effects : No known significant effects or critical hazards.

Numerical measures of toxicity


Acute toxicity estimates
Route ATE value
Oral 5330 mg/kg

Section 12. Ecological information


Toxicity
Product/ingredient name Result Species Exposure
2-Butoxyethanol Acute EC50 >1000 mg/l Fresh water Daphnia - Daphnia magna 48 hours
Acute LC50 800000 µg/l Marine water Crustaceans - Crangon crangon 48 hours
Acute LC50 1250000 µg/l Marine water Fish - Menidia beryllina 96 hours

Persistence and degradability


Product/ingredient name Aquatic half-life Photolysis Biodegradability
2-Butoxyethanol - - Readily

Date of issue/Date of revision : 3/24/2015. Date of previous issue : No previous validation. Version :1 10/13
Section 12. Ecological information
Bioaccumulative potential
Not available.

Mobility in soil
Soil/water partition : Not available.
coefficient (KOC)

Other adverse effects : No known significant effects or critical hazards.

Section 13. Disposal considerations


Disposal methods : The generation of waste should be avoided or minimized wherever possible. Disposal
of this product, solutions and any by-products should at all times comply with the
requirements of environmental protection and waste disposal legislation and any
regional local authority requirements. Dispose of surplus and non-recyclable products
via a licensed waste disposal contractor. Waste should not be disposed of untreated to
the sewer unless fully compliant with the requirements of all authorities with jurisdiction.
Waste packaging should be recycled. Incineration or landfill should only be considered
when recycling is not feasible. This material and its container must be disposed of in a
safe way. Empty containers or liners may retain some product residues. Do not
puncture or incinerate container.

Section 14. Transport information


DOT TDG Mexico IATA IMDG
Classification Classification Classification
UN number UN1950 UN1950 UN1950 UN1950 UN1950

UN proper AEROSOLS AEROSOLS AEROSOLS AEROSOLS, AEROSOLS


shipping name flammable
Transport 2.1 2.1 2.1 2.1 2.1
hazard class(es)

Packing group - - - - -
Environmental No. No. No. No. No.
hazards
Additional Special Special Special Special Emergency
information provisions provisions provisions provisions schedules (EmS)
LIMITED LIMITED (ERG#126) LIMITED LIMITED
QUANTITY QUANTITY QUANTITY QUANTITY, F-D,
S-U

Special precautions for user : Multi-modal shipping descriptions are provided for informational purposes and do not
consider container sizes. The presence of a shipping description for a particular
mode of transport (sea, air, etc.), does not indicate that the product is packaged
suitably for that mode of transport. All packaging must be reviewed for suitability prior
to shipment, and compliance with the applicable regulations is the sole responsibility
of the person offering the product for transport. People loading and unloading
dangerous goods must be trained on all of the risks deriving from the substances
and on all actions in case of emergency situations.

Date of issue/Date of revision : 3/24/2015. Date of previous issue : No previous validation. Version :1 11/13
Section 14. Transport information
Transport in bulk according : Not available.
to Annex II of MARPOL
73/78 and the IBC Code

Section 15. Regulatory information


U.S. Federal regulations :
State regulations
California Prop. 65
WARNING: This product contains chemicals known to the State of California to cause cancer and birth defects or other
reproductive harm.

Section 16. Other information


Hazardous Material Information System (U.S.A.)
Health 2

Flammability 4
Physical hazards 0

Caution: HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4
representing significant hazards or risks Although HMIS® ratings are not required on SDSs under 29 CFR 1910.
1200, the preparer may choose to provide them. HMIS® ratings are to be used with a fully implemented HMIS®
program. HMIS® is a registered mark of the National Paint & Coatings Association (NPCA). HMIS® materials may
be purchased exclusively from J. J. Keller (800) 327-6868.
The customer is responsible for determining the PPE code for this material.

Notice to reader
It is recommended that each customer or recipient of this Safety Data Sheet (SDS) study it carefully and consult
resources, as necessary or appropriate, to become aware of and understand the data contained in this SDS and
any hazards associated with the product. This information is provided in good faith and believed to be accurate
as of the effective date herein. However, no warranty, express or implied, is given. The information presented
here applies only to the product as shipped. The addition of any material can change the composition, hazards
and risks of the product. Regulatory requirements are subject to change and may differ between various
locations and jurisdictions. The customer/buyer/user is responsible to ensure that his activities comply with all
country, federal, state, provincial or local laws. The conditions for use of the product are not under the control of
the manufacturer; the customer/buyer/user is responsible to determine the conditions necessary for the safe use
of this product. The customer/buyer/user should not use the product for any purpose other than the purpose
shown in the applicable section of this SDS without first referring to the supplier and obtaining written handling
instructions. Due to the proliferation of sources for information such as manufacturer-specific SDS, the
manufacturer cannot be responsible for SDSs obtained from any other source.

Date of issue/Date of revision : 3/24/2015. Date of previous issue : No previous validation. Version :1 12/13
Section 16. Other information

Date of issue/Date of revision : 3/24/2015. Date of previous issue : No previous validation. Version :1 13/13
NFPA Hazard Rating
Flammability

0
Health 0 0 Reactivity

Material Safety Data Sheet


0 = Minimum 1 = Light 2 = Moderate 3 = Serious 4 = Extreme

1. PRODUCT AND COMPANY IDENTIFICATION


Product Name BIO-RUST
Product Identifier 53-G 241 (1,5L), 53-G 247 (20L), 53-G 248 (208L), 53-G 249 (1000L)
MSDS No. L-134E
Product Family Cleaning and Degreasing
Manufacturer / Supplier Walter Surface Technologies Inc., 5977 Trans-Canada Highway, Pointe-Claire, Qc, H9R 1C1,
1-888-592-5837, www.walter.com
Emergency Contact CANUTEC (Canadian Transport Emergency Centre), (613) 996-6666,
24 hours / 7 days
Information Use Non-corrosive rust remover

2. HAZARDS IDENTIFICATION
WHMIS Classification Not a WHMIS controlled product.
Potential Health Effects
Route of Exposure Skin contact; eye contact; ingestion
Skin Contact Not irritating
Eye Contact May cause slight eye irritation.
Ingestion May cause slight nausea.

3. COMPOSITION/INFORMATION ON INGREDIENTS
Contains no hazardous ingredients.

4. FIRST AID MEASURES


First Aid Procedures
Eye Contact Immediately flush the contaminated eye(s) with lukewarm, gently flowing water for 5 minutes,
while holding the eyelid(s) open. If irritation or pain persists, see a doctor.
Ingestion Have victim rinse mouth with water. Give plenty of water to drink. DO NOT INDUCE
VOMITING. Call a Poison Centre or doctor if the victim feels unwell.

5. FIRE FIGHTING MEASURES


Flammable Properties Does not burn.
Suitable Extinguishing Media Carbon dioxide, dry chemical powder or appropriate foam.
Unsuitable Extinguishing Media None known
Specific Hazards Arising from the This product presents no unusual hazards in a fire situation.
Chemical
Protective Equipment and No special precautions are necessary. Review Section 6 (Accidental Release Measures) for
Precautions for Firefighters important information on responding to leaks/spills.

Page 1 of 3
6. ACCIDENTAL RELEASE MEASURES
Personal Precautions Slippery after spillage or leakage.
Environmental Precautions No special precautions are necessary.
Methods for Containment and Contain and soak up spill with absorbent that does not react with spilled product. Flush spill
Clean-up area. Review Section 13 (Disposal Considerations) of this MSDS.

7. HANDLING AND STORAGE


Handling No special handling precautions are necessary.
Storage Protect from freezing.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION


Engineering Controls Provide eyewash in work area, if contact or splash hazard exists.
Personal Protective Equipment (PPE)
Eye/Face Protection Wear chemical safety goggles or face shield when contact is possible.
Skin Protection Wear chemical protective gloves for long lasting skin contact.

9. PHYSICAL AND CHEMICAL PROPERTIES


Physical State Liquid
Appearance Clear yellow liquid
Odour Mild
Boiling Point < 93 °C (199 °F)
Freezing Point 0 °C (32 °F)
Relative Density (water = 1) 1
Specific gravity 1.1 - 1.2
Solubility in Water Soluble
pH ~ 5,2
Evaporation Rate > 1 (diethyl ether = 1)
Flash Point Not applicable
Lower Flammable/Explosive Not applicable
Limit
Upper Flammable/Explosive Not applicable
Limit
Auto-ignition Temperature Not applicable

10. STABILITY AND REACTIVITY


Chemical Stability Normally stable
Conditions to Avoid High temperatures
Incompatible Materials Strong oxidizing agents (e.g. perchloric acid). And other reactive materials.
Hazardous Decomposition Carbon oxide.
Products

11. TOXICOLOGICAL INFORMATION


Eye Irritation / Corrosion Slight irritation of eyes possible.
Effects of Short-Term (Acute) Exposure
Ingestion May cause slight nausea.
Page 2 of 3
12. ECOLOGICAL INFORMATION
Ecotoxicity Studies were not located.
Persistence and Degradability No information was located.
Bioaccumulation / Accumulation No information was located.

Mobility Studies are not available.

13. DISPOSAL CONSIDERATIONS


Eliminate while respecting municipal, provincial and federal regulations.

14. TRANSPORT INFORMATION


Shipping Information Not regulated under Canadian TDG Regulations. Not regulated under US DOT Regulations.

Other Transport Information


Special Shipping Information Please note: Protect from freezing.

15. REGULATORY INFORMATION


Canada
Domestic Substances List (DSL) All ingredients are listed on the DSL.
CEPA - National Pollutant Not specifically listed.
Release Inventory (NPRI)
USA
US OSHA Regulatory Status While this material is not considered hazardous by the OSHA Hazard Communication Standard
(29 CFR 1910.1200), this MSDS contains valuable information critical to the safe handling and
proper use of the product. This MSDS should be retained and available for employees and
other users of this product.
Additional USA Regulatory Lists
CERCLA: RQ: None
SARA Title III - Section 302: None
SARA Title III - Section 311/312: None
SARA Title III - Section 313: None
New Jersey Right To Know: None
Section 112: Hazardous Air Pollutants (HAPS): None

16. OTHER INFORMATION


MSDS Prepared By Project Manager, Environmental Solutions and MRO
Phone No. 1-888-592-5837
Date of Preparation February 2015

Page 3 of 3
Missing
pictogram

Material Safety Data Sheet - MSDS


Section 1. Chemical Product and Company Identification
Product name Classification Classification
Blueshield CSA: AWS:
LA 6010; E41010/ E4310; E6010;
LA ULTRA 11; E41011/ E4311; E6011;
LA 6013; E41013/ E4313; E6013;
LA 6013P; E41013/ E4313; E6013;
LA 7014; E48014/ E4914; E7014;
LA 7024; E48024/ E4924; E7024;
LA 24-HD; E48024/ E4924; E7024;
Description : SMAW - Mild-Steel Electrode. Generic Code : AL-J-001-0
In case of emergency : 1-514-878-1667 Date of issue : 01/13/2014
Supplier : Air Liquide Canada Inc., 1250, René-Lévesque Ouest, Suite 1700,
Montréal, QC H3B 5E6

Missing
pictogram

Section 2. Hazards Identification


Physical state and Appearance : Solid.
Emergency overview : These hazards relate to welding fumes (electrodes in use) and not to the electrodes as sold.
WARNING!
ELECTRIC SHOCK can kill.
FUMES AND GASES can be dangerous to your health.
ARC RAYS can injure eyes and burn skin.
MAY BE HARMFUL IF INHALED. CAUSES RESPIRATORY TRACT, EYE AND SKIN IRRITATION. MAY CAUSE ALLERGIC
SKIN REACTION. CONTAINS MATERIAL THAT MAY CAUSE TARGET ORGAN DAMAGE, BASED ON ANIMAL DATA.
CANCER HAZARD - CONTAINS MATERIAL WHICH CAN CAUSE CANCER.
Do not handle until all safety precautions have been read and understood. Obtain special instructions before use. Use only with
adequate ventilation. Do not eat, drink or smoke when using this product. Avoid contact with eyes, skin and clothing. Keep
container tightly closed. Use personal protective equipment as required. Wash thoroughly after handling.

Routes of entry : Dermal contact. Eye contact. Inhalation.


Potential acute health effects
Eyes : Very hazardous by the following route of exposure: of eye contact (irritant). Inflammation of the eye is characterized by redness,
watering and itching.
Skin : Hazardous by the following route of exposure: of skin contact (corrosive, irritant, sensitizer). Skin contact may produce burns.
Skin inflammation is characterized by itching, scaling, reddening or, occasionally, blistering.
Inhalation : Hazardous by the following route of exposure: of inhalation (lung irritant).
Ingestion : Since the product (welding fumes) is a gas and that it is mostly probable that it will be inhaled more than ingested, please consider
first to look at the preventive measures in case of inhalation.
Potential chronic health effects :

Carcinogenicity

Product/ingredient name ACGIH OSHA IARC NTP EU


Titanium dioxide A4 - 2B - Carc. 2, H351
Sodium fluoride A4 - 3 - -
Talc A1 - 1 - Carc. 1A, H350
Mutagenic effects Not available.
Teratogenic effects: Not available.
Medical conditions aggravated : Pre-existing skin disorders and disorders involving any other target organs mentioned in this MSDS as being at risk may be
by over-exposure aggravated by over-exposure to this product.
(*) See Abbreviations (section 16).

Section 3. Composition, Information on Ingredients


Name CAS # % by weight UN number

Iron 7439-89-6 40 - 85 Not available.


Calcium carbonate 471-34-1 0.01 - 35 Not available.
Titanium dioxide 13463-67-7 0.1 - 13 Not available.
Mica-group minerals 12001-26-2 1-7 Not available.
Sodium fluoride 7681-49-4 0.01 - 4 UN1690
Manganese 7439-96-5 0.5 - 3 Not available.
Bentonite 1302-78-9 0.01 - 1 Not available.
Kaolin 1332-58-7 0.01 - 0.5 Not available.
The fumes emitted by the electrodes, in use, are hazardous. This MSDS is written for workers using these electrodes.

1-800-817-7697
Page: 1/5
www.airliquide.ca AL-J-001-0
See Section 8 for Exposure Limits of the oxides found in the welding fumes.

Section 4. First Aid Measures


Eye contact : Check for and remove any contact lenses. Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting
the upper and lower eyelids. Get medical attention immediately.
Skin contact : In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and
shoes. Wash clothing before reuse. Clean shoes thoroughly before reuse. Get medical attention immediately.
Inhalation : Move exposed person to fresh air. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial
respiration or oxygen by trained personnel. Loosen tight clothing such as a collar, tie, belt or waistband. Get medical attention
immediately.
Ingestion : Wash out mouth with water. Do not induce vomiting unless directed to do so by medical personnel. Never give anything by mouth
to an unconscious person. Get medical attention immediately.

Section 5. Fire Fighting Measures


Flammability of the product : Non-flammable. Emits toxic fumes when heated.
Explosibility : Non-explosive in the presence of the following materials or conditions: open flames, sparks and static discharge, heat and shocks
and mechanical impacts.
Fire-fighting media and : Use an extinguishing agent suitable for the surrounding fire.
instructions

Section 6. Accidental Release Measures


Small/Large Spill and Leak : Use appropriate tools to transfer the spilled solid to a convenient waste disposal container.

Section 7. Handling and Storage


Handling : Avoid contact with eyes. Avoid breathing dust. Avoid prolonged or repeated contact with skin. Do not get on skin or clothing.
Keep container closed. Use only with adequate ventilation. Wash thoroughly after handling. Avoid contact of spilled material and
runoff with soil and surface waterways.
Storage : All filler metals in their original, unopened containers should be kept in a relatively dry storage area at temperatures between 15°C
(60°F) and 30°C (80°F) and 50% maximum relative humidity.

Section 8. Exposure Controls, Personal Protection


Engineering controls : Use only with adequate ventilation. If user operations generate dust, fumes, gas, vapor or mist, use process enclosures, local
exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or
statutory limits.
Personal protection
Eyes : Safety glasses with side shields. Face shield with radiation shielding.
Body : Full suit. Fire resistant.
Respiratory : Dust respirator. Be sure to use an approved/certified respirator or equivalent. Wear a canister breathing apparatus (respirator) or
a supplied-air respirator, when required, to weld in a confined space or when room exhaust or ventilation does not keep exposure
below the acceptable values.
Hands : Gloves. Fire resistant.
Feet : Metal cap, safety boots.

Occupational exposure limits TWA (8 hours) STEL (15 mins) Ceiling

Ingredient List name ppm mg/m³ Other ppm mg/m³ Other ppm mg/m³ Other Notations
Titanium dioxide US ACGIH 6/2013 - 10 - - - - - - -
AB 4/2009 - 10 - - - - - - -
BC 7/2013 - 3 - - - - - - - [a]
- 10 - - - - - - - [b]
ON 1/2013 - 10 - - - - - - - [c]
QC 12/2012 - 10 - - - - - - - [d]
Mica-group minerals US ACGIH 6/2013 - 3 - - - - - - - [e]
AB 4/2009 - 3 - - - - - - - [f]
BC 7/2013 - 3 - - - - - - - [f]
ON 1/2013 - 3 - - - - - - - [e]
QC 12/2012 - 3 - - - - - - - [g]
Sodium fluoride, as F US ACGIH 6/2013 - 2.5 - - - - - - -
AB 4/2009 - 2.5 - - - - - - -
BC 7/2013 - 2.5 - - - - - - -
ON 1/2013 - 2.5 - - - - - - -
QC 12/2012 - 2.5 - - - - - - -
Manganese, as Mn US ACGIH 6/2013 - 0.1 - - - - - - - [h]
US ACGIH 6/2013 - 0.2 - - - - - - - [e]
AB 4/2009 - 0.2 - - - - - - -
BC 7/2013 - 0.2 - - - - - - -
ON 1/2013 - 0.2 - - - - - - -
QC 12/2012 - 1 - - 3 - - - - [i]
Kaolin US ACGIH 6/2013 - 2 - - - - - - - [e]
AB 4/2009 - 2 - - - - - - - [f]
BC 7/2013 - 2 - - - - - - - [f]
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ON 1/2013 - 2 - - - - - - - [e]
QC 12/2012 - 5 - - - - - - - [g]
Iron US ACGIH - 10 - - - - - - - [j]
Calcium carbonate AB 4/2009 - 10 - - - - - - - [3]
- 10 - - - - - - - [d]
[3]Skin sensitization
Form: [a]Respirable dust [b]Total dust [c]total dust [d]Total dust. [e]Respirable fraction [f]Respirable [g]Respirable dust. [h]Inhalable fraction [i]fume [j]
Inhalable particle.

Section 9. Physical and Chemical Properties


Physical state and Appearance : Solid.
Color : Reddish-brown. Grayish-white.
Odor : Odorless.
Melting/freezing point : 1540 to 2030°C (2804 to 3686°F)
Specific gravity : Not available.
Solubility : Insoluble in the following materials: cold water and hot water.

Section 10. Stability and Reactivity


Stability and reactivity : The product is stable.
Hazardous decomposition : Metallic oxides. carbon oxides (CO, CO₂) Arc radiation can support the production of ozone and nitrogen oxides.
products
Hazardous polymerization : Under normal conditions of storage and use, hazardous polymerization will not occur.

Section 11. Toxicological Information


Product/ingredient name Result Species Dose Exposure
Calcium carbonate LD50 Oral Rat 6450 mg/kg -
Sodium fluoride LD50 Oral Rat 31 mg/kg -
Manganese LD50 Oral Rat 9 g/kg -
Chronic effects and other toxic : CARCINOGENIC EFFECTS: Classified + (Proven.) by NIOSH [Titanium dioxide]. Classified 2B (Possible for humans.) by IARC, 3
effects on humans (Possible for humans.) by European Union [Titanium dioxide]. Classified A4 (Not classifiable for humans or animals.) by ACGIH
[Titanium dioxide]. Classified A4 (Not classifiable for humans or animals.) by ACGIH, 3 (Not classifiable for humans.) by IARC
[Sodium fluoride]. Classified A4 (Not classifiable for humans or animals.) by ACGIH [Manganese]. Classified A4 (Not classifiable
for humans or animals.) by ACGIH [Aluminium oxide]. Classified A4 (Not classifiable for humans or animals.) by ACGIH, 3 (Not
classifiable for humans.) by IARC [Calcium fluoride]. Classified A4 (Not classifiable for humans or animals.) by ACGIH [Zirconium].
Classified A4 (Not classifiable for humans or animals.) by ACGIH [Kaolin]. Classified A1 (Confirmed for humans.) by ACGIH, 1
(Proven for humans.) by IARC, 1 (Proven for humans.) by European Union [Talc].
Contains material which may cause damage to the following organs: blood, kidneys, lungs, the nervous system, liver, heart,
bladder, upper respiratory tract, skin, bones, central nervous system (CNS), eye, lens or cornea, teeth.

Very hazardous by the following route of exposure: of eye contact (irritant).


Hazardous by the following route of exposure: of skin contact (corrosive, irritant, sensitizer), of inhalation (lung irritant).

Section 12. Ecological Information


Ecotoxicity data

Product/ingredient name Result Species Exposure


Iron Acute EC50 3700 µg/l Fresh water Aquatic plants - Lemna minor 4 days
Acute LC50 33000 to 100000 µg/l Marine water Crustaceans - Crangon crangon 48 hours
Acute LC50 6.48 µg/l Marine water Fish - Periophthalmus waltoni - Adult 96 hours
Chronic NOEC 100 mg/l Marine water Algae - Glenodinium halli 72 hours
Calcium carbonate Acute LC50 56000 ppm Fresh water Fish - Gambusia affinis - Adult 96 hours
Chronic NOEC 61 mg/g Fresh water Fish - Oncorhynchus mykiss - Juvenile 28 days
(Fledgling, Hatchling, Weanling)
Titanium dioxide Acute EC50 5.83 mg/l Fresh water Algae - Pseudokirchneriella subcapitata - 72 hours
Exponential growth phase
Acute LC50 3 mg/l Fresh water Crustaceans - Ceriodaphnia dubia - 48 hours
Neonate
Acute LC50 5.5 ppm Fresh water Daphnia - Daphnia magna - Juvenile 48 hours
(Fledgling, Hatchling, Weanling)
Acute LC50 1000 mg/l Fresh water Fish - Pimephales promelas 96 hours
Acute LC50 >1000000 µg/l Marine water Fish - Fundulus heteroclitus 96 hours
Chronic NOEC 0.984 mg/l Fresh water Algae - Pseudokirchneriella subcapitata - 72 hours
Exponential growth phase
Sodium fluoride Acute EC50 181000 µg/l Marine water Algae - Skeletonema costatum 96 hours
Acute EC50 850000 µg/l Fresh water Algae - Scenedesmus subspicatus - 72 hours
Exponential growth phase
Acute EC50 179.4 mg/l Fresh water Crustaceans - Cypris subglobosa 48 hours
Acute EC50 98000 µg/l Fresh water Daphnia - Daphnia magna - Neonate 48 hours
Acute LC50 51000 µg/l Fresh water Fish - Oncorhynchus mykiss 96 hours
Chronic NOEC 14000 µg/l Fresh water Daphnia - Daphnia magna 21 days
Chronic NOEC 3.1 mg/l Fresh water Fish - Acipenser baerii - Juvenile 90 days
(Fledgling, Hatchling, Weanling)

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Manganese Acute EC50 31000 µg/l Fresh water Aquatic plants - Lemna minor 4 days
Acute LC50 29000 µg/l Daphnia - Daphnia magna 48 hours
Acute LC50 28 mg/l Fresh water Fish - Pimephales promelas 96 hours
Bentonite Acute LC50 19000000 µg/l Fresh water Fish - Oncorhynchus mykiss 96 hours
Products of degradation : Not applicable.

Section 13. Disposal Considerations


Waste information : Waste must be disposed of in accordance with federal, state and local environmental control regulations. Recycle, if possible.
Consult your local or regional authorities.

Section 14. Transport Information


No transport class is found applicable to this product.

Section 15. Regulatory Information


HCS Classification : These hazards relate to welding fumes (electrodes in use) and not to the electrodes as sold.
Irritating material
Sensitizing material
Carcinogen
Target organ effects
U.S. Federal regulations : TSCA 8(a) CDR Exempt/Partial exemption: Not determined
United States inventory (TSCA 8b): Not determined.
Commerce control list precursor: Sodium fluoride
SARA 302/304: No products were found.
SARA 311/312 Hazards identification: Immediate (acute) health hazard, Delayed (chronic) health hazard
Clean Water Act (CWA) 311: Sodium fluoride

SARA 313

Product name CAS number %

Form R - Reporting requirements Manganese 7439-96-5 0.5 - 3

Supplier notification Manganese 7439-96-5 0.5 - 3

SARA 313 notifications must not be detached from the MSDS and any copying and redistribution of the MSDS shall include copying and redistribution
of the notice attached to copies of the MSDS subsequently redistributed.

State regulations : Massachusetts : The following components are listed: TITANIUM DIOXIDE; MICA DUST; SODIUM FLUORIDE;
MANGANESE
New York : The following components are listed: Sodium fluoride
New Jersey : The following components are listed: TITANIUM DIOXIDE; TITANIUM OXIDE (TiO2); MICA;
SODIUM FLUORIDE; MANGANESE; KAOLIN; SOAPSTONE
Pennsylvania : The following components are listed: TITANIUM OXIDE (TIO2); SODIUM FLUORIDE (NAF);
MANGANESE; KAOLIN; SOAPSTONE DUST
WARNING: This product contains a chemical known to the State of California to cause cancer.
WHMIS (Canada) : These hazards relate to welding fumes (electrodes in use) and not to the electrodes as sold.
Class D-2A: Material causing other toxic effects (Very toxic).
Class D-2B: Material causing other toxic effects (Toxic).
CEPA Toxic substances: The following components are listed: Inorganic fluorides
Canadian ARET: None of the components are listed.
Canadian NPRI: The following components are listed: Sodium fluoride; Manganese (and its compounds)
Alberta Designated Substances: None of the components are listed.
Ontario Designated Substances: None of the components are listed.
Quebec Designated Substances: None of the components are listed.
This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and the MSDS contains all the information
required by the Controlled Products Regulations.

Section 16. Other Information


Label requirements : See Section 2.
Hazardous Material Information System (U.S.A.) : Health: 2* Fire: 0 Reactivity: 0
National Fire Protection Association (U.S.A.) : Health: 2 Fire: 0 Reactivity: 0 Other: None
References : - 29CFR Part1910.1200 OSHA MSDS Requirements. - 49CFR Table List of Hazardous Materials, UN#, Proper Shipping Names,
PG. - Canadian Transport of Dangerous Goods, Regulations and Schedules, Clear Language version 2005. - CRC Handbook of
chemistry and physics, 67th edition. CRC Press inc., Boca Raton, Florida. - Manufacturer's Material Safety Data Sheet. ANSI Z400.
1, MSDS Standard, 2004. ANSI Z49.1 Safety in Welding and Cutting, The American Welding Society, P.O. Box 351040, Miami, FL
33135. Canadian Standard Association, CSA W117.2, Code for Safety in Welding and Cutting, 2003.

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Abbreviations and acronyms : ACGIH: American Conference of Governmental Industrial Hygiene.
ACGIH-A1-Confirmed Human Carcinogen.
ACGIH-A2-Suspected Human Carcinogen.
ACGIH-A3-Animal Carcinogen.
ACGIH-A4-Not Classifiable as a Human Carcinogen.
ACGIH-A5-Not suspected as a Human Carcinogen.
IARC: International Agency for Research on Cancer.
IARC 1: Proven.
IARC 2A: Probable for human.
IARC 2B: Possible for human.
IARC 3: Not classifiable for human.
NIOSH: National Institute of Occupational Safety and Health.
NIOSH +: Proven.
NIOSH: None.
EU: European Union
Carc. 1A : May cause cancer (Known)
Carc. 1B : May cause cancer (Presumed)
Carc. 2 : Suspected of causing cancer
NTP: National Toxicology program.
NTP 1: Known to be human carcinogens.
NTP 2: Reasonably Anticipated to be human carcinogens.
Responsible name : IHS
Date of previous issue : 01/15/2011
Version : 5
Notice to reader
THE INFORMATION, RECOMMENDATIONS AND DATA CONTAINED IN THIS DOCUMENT ARE INTENDED TO BE USED BY PROPERLY TRAINED AND
QUALIFIED PERSONNEL ONLY AND AT THEIR SOLE RISKS AND DISCRETION. THE INFORMATION, RECOMMENDATIONS AND DATA HEREIN CONTAINED
ARE DERIVED FROM SOURCES WHICH WE BELIEVE TO BE RELIABLE. HOWEVER, AIR LIQUIDE CANADA INC. MAKES NO REPRESENTATION AND GIVES
NO WARRANTY OF ANY KIND WHATSOEVER WITH RESPECT TO THEIR ACCURACY OR COMPLETENESS AND ASSUMES NO LIABILITY FOR DAMAGES OR
LOSS ARISING DIRECTLY OR INDIRECTLY FROM THEIR USE, WHETHER PROPER OR IMPROPER.

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Missing
pictogram

Material Safety Data Sheet - MSDS


Section 1. Chemical Product and Company Identification
Product name Classification Classification
Blueshield CSA: AWS:
EXCELARC 18; E48018/ E4918; E7018;
LA 7018; E48018-1/ E4918-1-H4; E7018-1-H4;
LA 18 LMP; E48018-1/ E4918-1-H4; E7018-1-H4;
LA 18 PLUS; E48018-1/ E4918-1-H4; E7018-1-H4;
LA 18 PLUS LMP; E48018-1/ E4918-1-H4; E7018-1-H4;
NUCLEARC LA 7018; E48018-1/ E4918-1-H4; E7018-1-H4;
LA 7028; E48028/ E4928; E7028;
LA 18 PLUS COMPLETE; E48018-1/ E4918-1-H4; E7018-1-H4R;
Description : SMAW - Low-Hydrogen Electrodes. Generic Code : AL-J-002-0
In case of emergency : 1-514-878-1667 Date of issue : 01/13/2014
Supplier : Air Liquide Canada Inc., 1250, René-Lévesque Ouest, Suite 1700,
Montréal, QC H3B 5E6

Missing
pictogram

Section 2. Hazards Identification


Physical state and Appearance : Solid.
Emergency overview : These hazards relate to welding fumes (electrodes in use) and not to the electrodes as sold.
WARNING!
ELECTRIC SHOCK can kill.
FUMES AND GASES can be dangerous to your health.
ARC RAYS can injure eyes and burn skin.
MAY BE HARMFUL IF INHALED. CAUSES RESPIRATORY TRACT, EYE AND SKIN IRRITATION. MAY CAUSE ALLERGIC
SKIN REACTION. CONTAINS MATERIAL THAT MAY CAUSE TARGET ORGAN DAMAGE, BASED ON ANIMAL DATA.
CANCER HAZARD - CONTAINS MATERIAL WHICH CAN CAUSE CANCER.
Do not handle until all safety precautions have been read and understood. Obtain special instructions before use. Use only with
adequate ventilation. Do not eat, drink or smoke when using this product. Avoid contact with eyes, skin and clothing. Keep
container tightly closed. Use personal protective equipment as required. Wash thoroughly after handling.

Routes of entry : Dermal contact. Eye contact. Inhalation.


Potential acute health effects
Eyes : Very hazardous by the following route of exposure: of eye contact (irritant). Inflammation of the eye is characterized by redness,
watering and itching.
Skin : Hazardous by the following route of exposure: of skin contact (corrosive, irritant, sensitizer). Skin contact may produce burns.
Skin inflammation is characterized by itching, scaling, reddening or, occasionally, blistering.
Inhalation : Hazardous by the following route of exposure: of inhalation (lung irritant).
Ingestion : Since the product (welding fumes) is a gas and that it is mostly probable that it will be inhaled more than ingested, please consider
first to look at the preventive measures in case of inhalation.
Potential chronic health effects :

Carcinogenicity

Product/ingredient name ACGIH OSHA IARC NTP EU


Titanium dioxide A4 - 2B - Carc. 2, H351
Calcium fluoride A4 - 3 - -
Crystalline silica respirable A2 - 1 Known to be a human carcinogen. Carc. 1A, H350
nickel A5 - 2B Reasonably anticipated to be a human carcinogen. Carc. 2, H351
Mutagenic effects Not available.
Teratogenic effects: Not available.
Medical conditions aggravated : Pre-existing skin disorders and disorders involving any other target organs mentioned in this MSDS as being at risk may be
by over-exposure aggravated by over-exposure to this product.
(*) See Abbreviations (section 16).

Section 3. Composition, Information on Ingredients


Name CAS # % by weight UN number

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Iron 7439-89-6 45 - 70 Not available.
Titanium dioxide 13463-67-7 0.1 - 15 Not available.
Calcium carbonate 471-34-1 0.01 - 15 Not available.
Calcium fluoride 7789-75-5 0.01 - 10 Not available.
Zirconium 7440-67-7 0.01 - 6 Not available.
Manganese 7439-96-5 0.01 - 4 Not available.
Ferrosilicon 8049-17-0 0.01 - 2.5 UN1408
Aluminium oxide 1344-28-1 0.01 - 2 Not available.
Crystalline silica respirable 14808-60-7 0.1 - 1 Not available.
Nickel 7440-02-0 0.01 - 0.5 Not available.
The fumes emitted by the electrodes, in use, are hazardous. This MSDS is written for workers using these electrodes.
See Section 8 for Exposure Limits of the oxides found in the welding fumes.

Section 4. First Aid Measures


Eye contact : Check for and remove any contact lenses. Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting
the upper and lower eyelids. Get medical attention immediately.
Skin contact : In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and
shoes. Wash clothing before reuse. Clean shoes thoroughly before reuse. Get medical attention immediately.
Inhalation : Move exposed person to fresh air. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial
respiration or oxygen by trained personnel. Loosen tight clothing such as a collar, tie, belt or waistband. Get medical attention
immediately.
Ingestion : Wash out mouth with water. Do not induce vomiting unless directed to do so by medical personnel. Never give anything by mouth
to an unconscious person. Get medical attention immediately.

Section 5. Fire Fighting Measures


Flammability of the product : Non-flammable. Emits toxic fumes when heated.
Explosibility : Non-explosive in the presence of the following materials or conditions: open flames, sparks and static discharge, heat and shocks
and mechanical impacts.
Fire-fighting media and : Use an extinguishing agent suitable for the surrounding fire.
instructions

Section 6. Accidental Release Measures


Small/Large Spill and Leak : Use appropriate tools to transfer the spilled solid to a convenient waste disposal container.

Section 7. Handling and Storage


Handling : Avoid contact with eyes. Avoid breathing dust. Avoid prolonged or repeated contact with skin. Do not get on skin or clothing.
Keep container closed. Use only with adequate ventilation. Wash thoroughly after handling. Avoid contact of spilled material and
runoff with soil and surface waterways.
Storage : All filler metals in their original, unopened containers should be kept in a relatively dry storage area at temperatures between 15°C
(60°F) and 30°C (80°F) and 50% maximum relative humidity.

Section 8. Exposure Controls, Personal Protection


Engineering controls : Use only with adequate ventilation. If user operations generate dust, fumes, gas, vapor or mist, use process enclosures, local
exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or
statutory limits.
Personal protection
Eyes
: Safety glasses with side shields. Face shield with radiation shielding.
Body
: Full suit. Fire resistant.
Respiratory : Dust respirator. Be sure to use an approved/certified respirator or equivalent. Wear a canister breathing apparatus (respirator) or
a supplied-air respirator, when required, to weld in a confined space or when room exhaust or ventilation does not keep exposure
below the acceptable values.
Hands : Gloves. Fire resistant.
Feet : Metal cap, safety boots.

Occupational exposure limits TWA (8 hours) STEL (15 mins) Ceiling

Ingredient List name ppm mg/m³ Other ppm mg/m³ Other ppm mg/m³ Other Notations
Titanium dioxide US ACGIH 6/2013 - 10 - - - - - - -
AB 4/2009 - 10 - - - - - - -
BC 7/2013 - 3 - - - - - - - [a]
- 10 - - - - - - - [b]
ON 1/2013 - 10 - - - - - - - [c]
QC 12/2012 - 10 - - - - - - - [d]
Aluminium oxide US ACGIH 6/2013 - 1 - - - - - - - [e]
AB 4/2009 - 10 - - - - - - -
BC 7/2013 - 1 - - - - - - - [f]
ON 1/2013 - 1 - - - - - - - [e]
Aluminium oxide, as Al QC 12/2012 - 10 - - - - - - - [d]
Manganese, as Mn US ACGIH 6/2013 - 0.1 - - - - - - - [g]
US ACGIH 6/2013 - 0.2 - - - - - - - [e]

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AB 4/2009 - 0.2 - - - - - - -
BC 7/2013 - 0.2 - - - - - - -
ON 1/2013 - 0.2 - - - - - - -
QC 12/2012 - 1 - - 3 - - - - [h]
Zirconium, as Zr US ACGIH 6/2013 - 5 - - 10 - - - -
AB 4/2009 - 5 - - 10 - - - -
BC 7/2013 - 5 - - 10 - - - -
ON 1/2013 - 5 - - 10 - - - -
QC 12/2012 - 5 - - 10 - - - -
Calcium fluoride, as F US ACGIH 6/2013 - 2.5 - - - - - - -
AB 4/2009 - 2.5 - - - - - - -
BC 7/2013 - 2.5 - - - - - - -
ON 1/2013 - 2.5 - - - - - - -
QC 12/2012 - 2.5 - - - - - - -
Crystalline silica respirable US ACGIH 6/2013 - 0.025 - - - - - - - [e]
AB 4/2009 - 0.025 - - - - - - - [i]
BC 7/2013 - 0.025 - - - - - - - [f]
ON 1/2013 - 0.1 - - - - - - - [j]
QC 12/2012 - 0.1 - - - - - - - [k]
Nickel US ACGIH 6/2013 - 1.5 - - - - - - - [g]
AB 4/2009 - 1.5 - - - - - - -
Nickel, as Ni BC 7/2013 - 0.05 - - - - - - -
Nickel ON 1/2013 - 1 - - - - - - - [l]
QC 12/2012 - 1 - - - - - - -
Iron US ACGIH - 10 - - - - - - - [m]
Calcium carbonate AB 4/2009 - 10 - - - - - - - [3]
- 10 - - - - - - - [d]
[3]Skin sensitization
Form: [a]Respirable dust [b]Total dust [c]total dust [d]Total dust. [e]Respirable fraction [f]Respirable [g]Inhalable fraction [h]fume [i]Respirable particulate
[j]Respirable fraction: means that size fraction of the airborne particulate deposited in the gas-exchange region of the respiratory tract and collected
during air sampling with a particle size-selective device that, (a) meets the ACGIH particle size–selective sampling criteria for airborne particulate matter;
and (b) has the cut point of 4 µm at 50 per cent collection efficiency. [k]Respirable dust. [l]Inhalable fraction: means that size fraction of the airborne
particulate deposited anywhere in the respiratory tract and collected during air sampling with a particle size-selective device that, (a) meets the ACGIH
particle size-selective sampling criteria for airborne particulate matter; and (b) has the cut point of 100 µm at 50 per cent collection efficiency. [m]Inhalable
particle.

Section 9. Physical and Chemical Properties


Physical state and Appearance : Solid.
Color : Reddish-brown. Grayish-white.
Odor : Odorless.
Melting/freezing point : 1540 to 2030°C (2804 to 3686°F)
Specific gravity : Not available.
Solubility : Insoluble in the following materials: cold water and hot water.

Section 10. Stability and Reactivity


Stability and reactivity : The product is stable.
Hazardous decomposition : Metallic oxides. carbon oxides (CO, CO₂) Arc radiation can support the production of ozone and nitrogen oxides.
products
Hazardous polymerization : Under normal conditions of storage and use, hazardous polymerization will not occur.

Section 11. Toxicological Information


Product/ingredient name Result Species Dose Exposure
Calcium carbonate LD50 Oral Rat 6450 mg/kg -
Ferrosilicon LD50 Dermal Rabbit >20 g/kg -
Manganese LD50 Oral Rat 9 g/kg -
Calcium fluoride LD50 Oral Rat 4250 mg/kg -
Chronic effects and other toxic : CARCINOGENIC EFFECTS: Classified + (Proven.) by NIOSH [Titanium dioxide]. Classified 2B (Possible for humans.) by IARC, 3
effects on humans (Possible for humans.) by European Union [Titanium dioxide]. Classified A4 (Not classifiable for humans or animals.) by ACGIH
[Titanium dioxide]. Classified A4 (Not classifiable for humans or animals.) by ACGIH, 3 (Not classifiable for humans.) by IARC
[Calcium fluoride]. Classified A4 (Not classifiable for humans or animals.) by ACGIH [Zirconium]. Classified A4 (Not classifiable
for humans or animals.) by ACGIH [Manganese]. Classified A4 (Not classifiable for humans or animals.) by ACGIH [Aluminium
oxide]. Classified 1 (Proven for humans.) by IARC, 1 (Known to be human carcinogens.) by NTP, + (Proven.) by NIOSH, 1 (Proven
for humans.) by European Union [Crystalline silica respirable]. Classified A2 (Suspected for humans.) by ACGIH [Crystalline silica
respirable]. Classified + (Proven.) by NIOSH [Nickel]. Classified 2B (Possible for humans.) by IARC, 3 (Possible for humans.) by
European Union [Nickel]. Classified 2 (Reasonably anticipated to be human carcinogens.) by NTP [Nickel]. Classified A5 (Not
suspected for humans.) by ACGIH [Nickel].
Contains material which may cause damage to the following organs: blood, kidneys, lungs, the nervous system, upper respiratory
tract, skin, eyes, bones, central nervous system (CNS), teeth.

Very hazardous by the following route of exposure: of eye contact (irritant).


Hazardous by the following route of exposure: of skin contact (corrosive, irritant, sensitizer), of inhalation (lung irritant).

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Section 12. Ecological Information
Ecotoxicity data

Product/ingredient name Result Species Exposure


Iron Acute EC50 3700 µg/l Fresh water Aquatic plants - Lemna minor 4 days
Acute LC50 33000 to 100000 µg/l Marine water Crustaceans - Crangon crangon 48 hours
Acute LC50 6.48 µg/l Marine water Fish - Periophthalmus waltoni - Adult 96 hours
Chronic NOEC 100 mg/l Marine water Algae - Glenodinium halli 72 hours
Titanium dioxide Acute EC50 5.83 mg/l Fresh water Algae - Pseudokirchneriella subcapitata - 72 hours
Exponential growth phase
Acute LC50 3 mg/l Fresh water Crustaceans - Ceriodaphnia dubia - 48 hours
Neonate
Acute LC50 5.5 ppm Fresh water Daphnia - Daphnia magna - Juvenile 48 hours
(Fledgling, Hatchling, Weanling)
Acute LC50 1000 mg/l Fresh water Fish - Pimephales promelas 96 hours
Acute LC50 >1000000 µg/l Marine water Fish - Fundulus heteroclitus 96 hours
Chronic NOEC 0.984 mg/l Fresh water Algae - Pseudokirchneriella subcapitata - 72 hours
Exponential growth phase
Calcium carbonate Acute LC50 56000 ppm Fresh water Fish - Gambusia affinis - Adult 96 hours
Chronic NOEC 61 mg/g Fresh water Fish - Oncorhynchus mykiss - Juvenile 28 days
(Fledgling, Hatchling, Weanling)
Manganese Acute EC50 31000 µg/l Fresh water Aquatic plants - Lemna minor 4 days
Acute LC50 29000 µg/l Daphnia - Daphnia magna 48 hours
Acute LC50 28 mg/l Fresh water Fish - Pimephales promelas 96 hours
Nickel Acute EC50 2 ppm Marine water Algae - Macrocystis pyrifera - Young 4 days
Acute EC50 450 µg/l Fresh water Aquatic plants - Lemna minor 4 days
Acute EC50 1000 µg/l Marine water Daphnia - Daphnia magna 48 hours
Acute IC50 0.31 mg/l Marine water Crustaceans - Americamysis bahia - 48 hours
Juvenile (Fledgling, Hatchling, Weanling)
Acute LC50 47.5 ng/L Fresh water Fish - Heteropneustes fossilis 96 hours
Chronic NOEC 100 mg/l Marine water Algae - Glenodinium halli 72 hours
Chronic NOEC 3.5 µg/l Fresh water Fish - Cyprinus carpio 4 weeks
Products of degradation : Not applicable.

Section 13. Disposal Considerations


Waste information : Waste must be disposed of in accordance with federal, state and local environmental control regulations. Recycle, if possible.
Consult your local or regional authorities.

Section 14. Transport Information


No transport class is found applicable to this product.

Section 15. Regulatory Information


HCS Classification : These hazards relate to welding fumes (electrodes in use) and not to the electrodes as sold.
Irritating material
Sensitizing material
Carcinogen
Target organ effects
U.S. Federal regulations : TSCA 8(a) CDR Exempt/Partial exemption: Not determined
United States inventory (TSCA 8b): Not determined.
SARA 302/304: No products were found.
SARA 311/312 Hazards identification: Immediate (acute) health hazard, Delayed (chronic) health hazard
Clean Water Act (CWA) 307: Copper; Nickel

SARA 313

Product name CAS number %

Form R - Reporting requirements Manganese 7439-96-5 0.01 - 4


Aluminium oxide 1344-28-1 0.01 - 2
Nickel 7440-02-0 0.01 - 0.5

Supplier notification Manganese 7439-96-5 0.01 - 4


Aluminium oxide 1344-28-1 0.01 - 2
Nickel 7440-02-0 0.01 - 0.5
SARA 313 notifications must not be detached from the MSDS and any copying and redistribution of the MSDS shall include copying and redistribution
of the notice attached to copies of the MSDS subsequently redistributed.

State regulations : Massachusetts : The following components are listed: TITANIUM DIOXIDE; ALUMINUM OXIDE; MANGANESE;
ZIRCONIUM
New York : The following components are listed: Nickel

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New Jersey : The following components are listed: TITANIUM DIOXIDE; TITANIUM OXIDE (TiO2); ALUMINUM
OXIDE; alpha-ALUMINA; FERROSILICON; FERROCERIUM; MANGANESE; ZIRCONIUM;
FLUORIDES; SILICA, QUARTZ; QUARTZ (SiO2); NICKEL
Pennsylvania : The following components are listed: TITANIUM OXIDE (TIO2); ALUMINUM OXIDE (AL2O3);
MANGANESE; ZIRCONIUM; QUARTZ (SIO2); NICKEL
WARNING: This product contains a chemical known to the State of California to cause cancer.
WHMIS (Canada) : These hazards relate to welding fumes (electrodes in use) and not to the electrodes as sold.
Class D-2A: Material causing other toxic effects (Very toxic).
Class D-2B: Material causing other toxic effects (Toxic).
CEPA Toxic substances: The following components are listed: Inorganic fluorides
Canadian ARET: None of the components are listed.
Canadian NPRI: The following components are listed: Aluminum oxide (fibrous forms only); Manganese (and its compounds);
Calcium fluoride
Alberta Designated Substances: None of the components are listed.
Ontario Designated Substances: None of the components are listed.
Quebec Designated Substances: None of the components are listed.
This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and the MSDS contains all the information
required by the Controlled Products Regulations.

Section 16. Other Information


Label requirements : See Section 2.
Hazardous Material Information System (U.S.A.) : Health: 2* Fire: 0 Reactivity: 0
National Fire Protection Association (U.S.A.) : Health: 2 Fire: 0 Reactivity: 0 Other: None
References : - 29CFR Part1910.1200 OSHA MSDS Requirements. - 49CFR Table List of Hazardous Materials, UN#, Proper Shipping Names,
PG. - Canadian Transport of Dangerous Goods, Regulations and Schedules, Clear Language version 2005. - CRC Handbook of
chemistry and physics, 67th edition. CRC Press inc., Boca Raton, Florida. - Manufacturer's Material Safety Data Sheet. ANSI Z400.
1, MSDS Standard, 2004. ANSI Z49.1 Safety in Welding and Cutting, The American Welding Society, P.O. Box 351040, Miami, FL
33135. Canadian Standard Association, CSA W117.2, Code for Safety in Welding and Cutting, 2003.
Abbreviations and acronyms : ACGIH: American Conference of Governmental Industrial Hygiene.
ACGIH-A1-Confirmed Human Carcinogen.
ACGIH-A2-Suspected Human Carcinogen.
ACGIH-A3-Animal Carcinogen.
ACGIH-A4-Not Classifiable as a Human Carcinogen.
ACGIH-A5-Not suspected as a Human Carcinogen.
IARC: International Agency for Research on Cancer.
IARC 1: Proven.
IARC 2A: Probable for human.
IARC 2B: Possible for human.
IARC 3: Not classifiable for human.
NIOSH: National Institute of Occupational Safety and Health.
NIOSH +: Proven.
NIOSH: None.
EU: European Union
Carc. 1A : May cause cancer (Known)
Carc. 1B : May cause cancer (Presumed)
Carc. 2 : Suspected of causing cancer
NTP: National Toxicology program.
NTP 1: Known to be human carcinogens.
NTP 2: Reasonably Anticipated to be human carcinogens.
Responsible name : IHS
Date of previous issue : 01/15/2011
Version : 5
Notice to reader
THE INFORMATION, RECOMMENDATIONS AND DATA CONTAINED IN THIS DOCUMENT ARE INTENDED TO BE USED BY PROPERLY TRAINED AND
QUALIFIED PERSONNEL ONLY AND AT THEIR SOLE RISKS AND DISCRETION. THE INFORMATION, RECOMMENDATIONS AND DATA HEREIN CONTAINED
ARE DERIVED FROM SOURCES WHICH WE BELIEVE TO BE RELIABLE. HOWEVER, AIR LIQUIDE CANADA INC. MAKES NO REPRESENTATION AND GIVES
NO WARRANTY OF ANY KIND WHATSOEVER WITH RESPECT TO THEIR ACCURACY OR COMPLETENESS AND ASSUMES NO LIABILITY FOR DAMAGES OR
LOSS ARISING DIRECTLY OR INDIRECTLY FROM THEIR USE, WHETHER PROPER OR IMPROPER.

1-800-817-7697
Page: 5/5
www.airliquide.ca AL-J-002-0
Material Safety Data Sheet
according to ANSI Z400.1- 2004 and 29 CFR 1910.1200

BON AMI® POWER FOAM GLASS CLEANER


Version 2.0 Print Date 11/17/2015

Revision Date 09/29/2015 MSDS Number 350000021130

1. PRODUCT AND COMPANY IDENTIFICATION

Product information
Trade name : BON AMI® POWER FOAM GLASS CLEANER

Use of the : Hard Surface Cleaner


Substance/Mixture
Company : S.C. Johnson and Son, Limited
1 Webster Street
Brantford ON N3T 5R1

Emergency telephone : 24 Hour Transport & Medical Emergency Phone (866) 231-
number 5406
24 Hour International Emergency Phone (952) 852-4647
24 Hour Canadian Transport Emergency Phone (CANUTEC)
(613) 996-6666

2. HAZARDS IDENTIFICATION
Emergency Overview
Appearance / Odor : translucent / aerosol Compressed gas / characteristic

Immediate Concerns : Caution


Avoid contact with skin, eyes and clothing.
Keep away from heat, sparks and flame.
Do not puncture or incinerate.
Do not store at temperatures above 120 Deg. F (50 Deg C), as
container may burst.
Contents under pressure.

Potential Health Effects


Exposure routes : Eye, Skin, Inhalation, Ingestion.

Eyes : May cause:


Mild eye irritation

Skin : Prolonged or repeated contact may dry skin and cause irritation.

Inhalation : No adverse effects expected when used as directed.

Ingestion : May cause irritation to mouth, throat and stomach.


May cause abdominal discomfort.

Aggravated Medical : Persons with pre-existing skin disorders may be more


Condition susceptible to irritating effects.

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Material Safety Data Sheet
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BON AMI® POWER FOAM GLASS CLEANER


Version 2.0 Print Date 11/17/2015

Revision Date 09/29/2015 MSDS Number 350000021130

3. COMPOSITION/INFORMATION ON INGREDIENTS

Hazardous chemicals present at or above reportable levels as defined by OSHA 29 CFR 1910.1200 or
the Canadian Controlled Products Regulations are listed in this table:

Chemical Name CAS-No. Weight percent


Isobutane 75-28-5 1.00 - 5.00
Propylene glycol monobutyl 5131-66-8
1.00 - 5.00
ether

For additional information on product ingredients, see www.whatsinsidescjohnson.com.

4. FIRST AID MEASURES

Eye contact : Rinse with plenty of water. Get medical attention if irritation
develops and persists.

Skin contact : Rinse with plenty of water. Get medical attention if irritation
develops and persists.

Inhalation : Remove to fresh air. If breathing is affected, get medical


attention.

Ingestion : Rinse mouth with water.

5. FIREFIGHTING MEASURES

Suitable extinguishing : Use water spray, alcohol-resistant foam, dry chemical or


media carbon dioxide.

Specific hazards during : Aerosol Product - Containers may rocket or explode in heat of
firefighting fire.

Further information : Fight fire from maximum distance or protected area. Cool and
use caution when approaching or handling fire-exposed
containers. Wear full protective clothing and positive pressure
self-contained breathing apparatus. In case of fire and/or
explosion do not breathe fumes.

Flash point : < -7 C


< 19.4 °F
Method: Tag Closed Cup (TCC)
Note: Propellant

Lower explosion limit : Note: No data available

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Material Safety Data Sheet
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BON AMI® POWER FOAM GLASS CLEANER


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Revision Date 09/29/2015 MSDS Number 350000021130

Upper explosion limit : Note: No data available

6. ACCIDENTAL RELEASE MEASURES

Personal precautions : Remove all sources of ignition.


Wear personal protective equipment.

Environmental precautions : Outside of normal use, avoid release to the environment.

Methods for cleaning up : If damage occurs to aerosol can:


Contain spillage, soak up with non-combustible absorbent
material, (e.g. sand, earth, diatomaceous earth, vermiculite)
and transfer to a container for disposal according to local /
national regulations (see section 13).
Use only non-sparking equipment.
Clean residue from spill site.

7. HANDLING AND STORAGE

Handling
Advice on safe handling : Do not puncture or incinerate.
Avoid breathing vapours, mist or gas.
Do not spray toward face.
Do not use in areas without adequate ventilation.
Use only as directed.
KEEP OUT OF REACH OF CHILDREN AND PETS.

Advice on protection : Keep away from heat and sources of ignition.


against fire and explosion

Storage
Requirements for storage : Do not store at temperatures above 120 Deg. F (50 Deg C), as
areas and containers container may burst.
Keep container closed when not in use.
Keep in a dry, cool and well-ventilated place.

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Material Safety Data Sheet
according to ANSI Z400.1- 2004 and 29 CFR 1910.1200

BON AMI® POWER FOAM GLASS CLEANER


Version 2.0 Print Date 11/17/2015

Revision Date 09/29/2015 MSDS Number 350000021130

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Occupational Exposure Limits


Components CAS-No. mg/m3 ppm Non- Basis
standard
units
Isobutane 75-28-5 - 1,000 ppm - ACGIH
STEL

Personal protective equipment


Respiratory protection No personal respiratory protective equipment normally
required.

Hand protection : No special requirements.

Eye protection No special requirements.

Skin and body protection : No special requirements.

Hygiene measures : Handle in accordance with good industrial hygiene and safety
practice. Wash thoroughly after handling.

9. PHYSICAL AND CHEMICAL PROPERTIES

Form : aerosol
Compressed gas

Color : translucent

Odor : characteristic

pH : 11
at 25 C(undiluted)

Melting point : No data available

Boiling point : No data available

Freezing point : No data available

Flash point : < -7 C


< 19.4 °F
Method: Tag Closed Cup (TCC)
Propellant

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Material Safety Data Sheet
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BON AMI® POWER FOAM GLASS CLEANER


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Revision Date 09/29/2015 MSDS Number 350000021130

Evaporation rate : No data available

Flammability (solid, gas) : Does not sustain combustion.

Auto-ignition temperature : not auto-flammable

Lower explosion limit : No data available

Upper explosion limit : No data available

Vapour pressure : No data available

Density : 8.327 lb/gal


at 20 C
Water solubility : soluble

Partition coefficient: n- :
octanol/water No data available

Viscosity, dynamic : No data available

Viscosity, kinematic : No data available

Relative vapour density : No data available

Volatile Organic Compounds : 6.9 % - additional exemptions may apply


Total VOC (wt. %)* *as defined by US Federal and State Consumer Product
Regulations

10. STABILITY AND REACTIVITY

Conditions to avoid : Heat, flames and sparks.

Materials to avoid : Strong acids

Hazardous decomposition : Thermal decomposition can lead to release of irritating gases


products and vapours.

Thermal decomposition : Note: No data available

Hazardous reactions : Stable under recommended storage conditions.

11. TOXICOLOGICAL INFORMATION

Acute oral toxicity : LD50


Measured
> 5,000 mg/kg

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Material Safety Data Sheet
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BON AMI® POWER FOAM GLASS CLEANER


Version 2.0 Print Date 11/17/2015

Revision Date 09/29/2015 MSDS Number 350000021130

Acute inhalation toxicity : LC50


Measured
> 5.59 mg/l

Acute dermal toxicity : LD50


Measured
> 5,000 mg/kg

Chronic effects
Carcinogenicity : No data available

Mutagenicity : No data available

Reproductive effects : No data available

Teratogenicity : No data available

Sensitisation : Did not cause sensitisation on laboratory animals.

12. ECOLOGICAL INFORMATION

Ecotoxicity effects : No data available

13. DISPOSAL CONSIDERATIONS

Observe all applicable Federal, Provincial and State


regulations and Local/Municipal ordinances regarding
disposal.
Consumer may discard empty container in trash, or recycle
where facilities exist.

14. TRANSPORT INFORMATION

Land transport
 U.S. DOT and Canadian TDG Surface Transportation:
Proper shipping name AEROSOLS, Flammable, 2.1

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Material Safety Data Sheet
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BON AMI® POWER FOAM GLASS CLEANER


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Revision Date 09/29/2015 MSDS Number 350000021130

Class: 2.1
UN number 1950
Packaging group: None.
Note: Limited quantities derogation may be applicable to this product,
please check transport documents.

Sea transport
 IMDG:
Proper shipping name AEROSOLS, Flammable, 2.1
Class: 2
UN number: 1950
Packaging group: None.
EmS: F-D, S-U
Note: Limited quantities derogation may be applicable to this product,
please check transport documents.

Air transport
 ICAO/IATA:
Proper shipping name AEROSOLS, Flammable, 2.1
Class: 2.1
UN/ID No.: UN 1950
Packaging group: None.
Note: SC Johnson typically does not ship products via air. Refer to
IATA/ICAO Dangerous Goods Regulations for detailed instructions
when shipping this item by air.

15. REGULATORY INFORMATION

Notification status : All ingredients of this product are listed or are excluded from
listing on the U.S. Toxic Substances Control Act (TSCA)
Chemical Substance Inventory.

Notification status : All ingredients of this product comply with the New Substances
Notification requirements under the Canadian Environmental
Protection Act (CEPA).

California Prop. 65 : This product is not subject to the reporting requirements under
California's Proposition 65.
Canada Regulations : This product has been classified in accordance with hazard
criteria of the Controlled Products Regulations and the MSDS
contains all the information required by the Controlled Products
Regulations.

16. OTHER INFORMATION


HMIS Ratings
Health 1

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Material Safety Data Sheet
according to ANSI Z400.1- 2004 and 29 CFR 1910.1200

BON AMI® POWER FOAM GLASS CLEANER


Version 2.0 Print Date 11/17/2015

Revision Date 09/29/2015 MSDS Number 350000021130

Flammability 4

Reactivity 0

NFPA Ratings
Health 1

Fire 4

Reactivity 0

Special -

This information is being provided in accordance with Occupational Safety and Health
Administration (OSHA) and Canada’s Workplace Hazard Material Information System (WHMIS)
regulations. The information supplied is designed for workplaces where product use and
frequency of exposure exceeds that established for the labeled consumer use.

Further information
This document has been prepared using data from sources considered to be technically reliable.
It does not constitute a warranty, expressed or implied, as to the accuracy of the information
contained herein. Actual conditions of use are beyond the seller's control. User is responsible to
evaluate all available information when using product for any particular use and to comply with all
Federal, State, Provincial and Local laws and regulations.

Prepared by SC Johnson Global Safety Assessment &


Regulatory Affairs (GSARA)

8/8
Page 1 of 13
Safety Data Sheet
acc. to OSHA HCS (29 CFR 1910.1200)
Printing date 07/01/2015 Reviewed on 07/01/2015

1 Identification
· Product identifier
· Trade name: Bronze
· Other Product Identifiers: Silicon Bronze, Leaded Bronze, Aluminum Bronze
· Recommended use and restriction on use
· Recommended use: Raw materials.
· Restrictions on use: Contact manufacturer.
· Details of the supplier of the Safety Data Sheet
· Manufacturer/Supplier:
Castle Metals
1420 Kensington Road Suite 220
Oak Brook IL 60523
(847) 349-3000
· Emergency telephone number: (847)-349-3000

2 Hazard(s) identification
· Classification of the substance or mixture
The product is not classified as hazardous according to the Globally Harmonized System (GHS).
· Additional information:
There are no other hazards not otherwise classified that have been identified.
0 percent of the mixture consists of ingredient(s) of unknown toxicity.
Not hazardous as delivered. Long term inhalation of product dusts formed during use is harmful.
· Label elements
· GHS label elements
The product is not classified as hazardous according to OSHA GHS regulations within the United States.
· Hazard pictograms Not Regulated
· Signal word Not Regulated
· Hazard-determining components of labeling: None.
· Hazard statements Not Regulated
· Precautionary statements Not Regulated
· Hazard description:
· WHMIS-symbols: Not hazardous under WHMIS.
· Classification system:
· NFPA ratings (scale 0 - 4)
Health = 0
0 Fire = 0
0 0 Reactivity = 0

· HMIS-ratings (scale 0 - 4)

HEALTH 0 Health = 0
FIRE 0 Fire = 0
REACTIVITY 0 Reactivity = 0
· Other hazards
· Results of PBT and vPvB assessment
· PBT: Not applicable.
(Contd. on page 2)

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Trade name: Bronze

(Contd. of page 1)
· vPvB: Not applicable.

3 Composition/information on ingredients
· Chemical characterization: Mixtures
· Description: Mixture of the substances listed below with nonhazardous additions.
· Dangerous components:
7440-50-8 copper 70-99%
7440-02-0 nickel 0-14%
Carc. 2, H351; STOT RE 1, H372
Skin Sens. 1, H317
7429-90-5 aluminum 0-14%
7439-89-6 iron <5%
7440-21-3 silicon <4%
Flam. Sol. 2, H228
7439-96-5 manganese, powdered <4%
Flam. Sol. 1, H228
7440-48-4 cobalt <2%
Resp. Sens. 1, H334; Carc. 2, H351
Skin Sens. 1, H317
7440-66-6 zinc powder -zinc dust (pyrophoric) <1%
Pyr. Sol. 1, H250; Water-react. 1, H260
7440-31-5 tin <1%
7439-92-1 lead <1%
Carc. 2, H351; Repr. 1A, H360; STOT RE 1, H372
· Additional information:
For the listed ingredients, the identity and exact percentages are being withheld as a trade secret.

4 First-aid measures
· Description of first aid measures
· General information: No special measures required.
· After inhalation: Supply fresh air; consult doctor in case of complaints.
· After skin contact:
Brush off loose particles from skin.
Immediately wash with water and soap and rinse thoroughly.
· After eye contact:
Remove contact lenses if worn, if possible.
Rinse opened eye for several minutes under running water. If symptoms persist, consult a doctor.
· After swallowing:
Rinse out mouth and then drink plenty of water.
Do not induce vomiting; immediately call for medical help.
· Information for doctor:
· Most important symptoms and effects, both acute and delayed
No further relevant information available.
(Contd. on page 3)

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Trade name: Bronze

(Contd. of page 2)
· Danger No further relevant information available.
· Indication of any immediate medical attention and special treatment needed
No further relevant information available.

5 Fire-fighting measures
· Extinguishing media
· Suitable extinguishing agents:
Special powder for metal fires. Do not use water.
Dry sand
Graphite powder.
Copper Powder.
Dry sodium chloride
· For safety reasons unsuitable extinguishing agents: Water
· Special hazards arising from the substance or mixture
Formation of toxic gases is possible during heating or in case of fire.
· Advice for firefighters
· Protective equipment:
Wear self-contained respiratory protective device.
Wear fully protective suit.
· Additional information No further relevant information available.

6 Accidental release measures


· Personal precautions, protective equipment and emergency procedures
Ensure adequate ventilation.
Do not breathe dust.
Avoid formation of dust.
Use personal protective equipment as required.
For large spills, use respiratory protective device against the effects of fumes/dust/aerosol.
· Environmental precautions: Do not allow to enter sewers/ surface or ground water.
· Methods and material for containment and cleaning up:
Pick up mechanically.
Dispose of the collected material according to regulations.
Send for recovery or disposal in suitable receptacles.
· Reference to other sections
See Section 7 for information on safe handling.
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information.

7 Handling and storage


· Handling:
· Precautions for safe handling
Use only in well ventilated areas.
Prevent formation of dust.
Any deposit of dust which cannot be avoided must be regularly removed.
(Contd. on page 4)

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Trade name: Bronze

(Contd. of page 3)
Use proper precautions around molten material.
· Information about protection against explosions and fires:
Keep respiratory protective device available.
· Conditions for safe storage, including any incompatibilities
· Storage:
· Requirements to be met by storerooms and receptacles: No special requirements.
· Information about storage in one common storage facility:
Store away from foodstuffs.
Do not store together with acids.
Do not store together with alkalis (caustic solutions).
Store away from oxidizing agents.
· Further information about storage conditions: None.
· Specific end use(s) No further relevant information available.

8 Exposure controls/personal protection


· Additional information about design of technical systems: No further data; see item 7.
· Control parameters
· Components with limit values that require monitoring at the workplace:
7440-50-8 copper
PEL (USA) Long-term value: 1* 0.1** mg/m³
as Cu *dusts and mists **fume
REL (USA) Long-term value: 1* 0.1** mg/m³
as Cu *dusts and mists **fume
TLV (USA) Long-term value: 1* 0.2** mg/m³
*dusts and mists; **fume; as Cu
EL (Canada) Long-term value: 1* 0.2** mg/m³
*dusts and mists; **fume, as Cu
EV (Canada) Long-term value: 0.2* 1** mg/m³
as copper, *fume;**dust and mists
LMPE (Mexico) Long-term value: 0.2* 1** mg/m³
*humo (como Cu);**polvo y niebla (como Cu)
7440-02-0 nickel
PEL (USA) Long-term value: 1 mg/m³
REL (USA) Long-term value: 0.015 mg/m³
as Ni; See Pocket Guide App. A
TLV (USA) Long-term value: 1.5* mg/m³
elemental, *inhalable fraction
EL (Canada) Long-term value: 0.05 mg/m³
ACGIH A1, IARC 2B
EV (Canada) Long-term value: 1 mg/m³
Inhalable fraction
LMPE (Mexico) Long-term value: 1.5* mg/m³
*elemental:A5, fracción inhalable
(Contd. on page 5)

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Trade name: Bronze

(Contd. of page 4)
7429-90-5 aluminum
PEL (USA) Long-term value: 15*; 15** mg/m³
*Total dust; ** Respirable fraction
REL (USA) Long-term value: 10* 5** mg/m³
as Al*Total dust**Respirable/pyro powd./welding f.
TLV (USA) Long-term value: 1* mg/m³
as Al; *as respirable fraction
EL (Canada) Long-term value: 1.0 mg/m³
respirable, as Al
EV (Canada) Long-term value: 5 mg/m³
aluminium-containing (as aluminium)
LMPE (Mexico) Long-term value: 1* mg/m³
A4, *fracciòn respirable
7439-89-6 iron
EV (Canada) Long-term value: 1* 5** mg/m³
as iron;*salts, water-soluble;**welding fume
LMPE (Mexico) Long-term value: 1 mg/m³
7440-21-3 silicon
PEL (USA) Long-term value: 15* 5** mg/m³
*total dust **respirable fraction
REL (USA) Long-term value: 10* 5** mg/m³
*total dust **respirable fraction
TLV (USA) TLV withdrawn
EL (Canada) Long-term value: 10* 3** mg/m³
*total dust;**respirable fraction
EV (Canada) Long-term value: 10 mg/m³
total dust
LMPE (Mexico) Short-term value: 20 mg/m³
Long-term value: 10 mg/m³
(e)
7439-96-5 manganese, powdered
PEL (USA) Ceiling limit value: 5 mg/m³
as Mn
REL (USA) Short-term value: 3 mg/m³
Long-term value: 1 mg/m³
fume, as Mn
TLV (USA) Long-term value: 0.02* 0.1* mg/m³
as Mn; *respirable **inhalable fraction
EL (Canada) Long-term value: 0.2 mg/m³
as Mn; R
EV (Canada) Long-term value: 0.2 mg/m³
as manganese
LMPE (Mexico) Long-term value: 0.2 mg/m³
como Mn
(Contd. on page 6)

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Trade name: Bronze

(Contd. of page 5)
7440-48-4 cobalt
PEL (USA) Long-term value: 0.1* mg/m³
as Co; *for metal dust and fume
REL (USA) Long-term value: 0.05 mg/m³
as Co; metal dust & fume
TLV (USA) Long-term value: 0.02; NIC - 0.02* mg/m³
BEI; *hard metals:thoracic ;NIC-A2,RSEN;as W
EL (Canada) Long-term value: 0.02 mg/m³
as Co; IARC 2B
EV (Canada) Long-term value: 0.1 mg/m³
LMPE (Mexico) Long-term value: 0.02 mg/m³
A3, IBE
7439-92-1 lead
PEL (USA) Long-term value: 0.05* mg/m³
*see 29 CFR 1910.1025
REL (USA) Long-term value: 0.05* mg/m³
*8-hr TWA,excl. lead arsenate;See PocketGuideApp.C
TLV (USA) Long-term value: 0.05* mg/m³
*and inorganic compounds, as Pb; BEI
EL (Canada) Long-term value: 0.05 mg/m³
R; IARC 2B
EV (Canada) Long-term value: 0.05 mg/m³
as Pb, Skin (organic compounds)
LMPE (Mexico) Long-term value: 0.05 mg/m³
A3, IBE
7440-31-5 tin
PEL (USA) Long-term value: 2 mg/m³
metal
REL (USA) Long-term value: 2 mg/m³
TLV (USA) Long-term value: 2 mg/m³
metal
EL (Canada) Long-term value: 2 mg/m³
metal
EV (Canada) Long-term value: 2* 0.1** mg/m³
*metal, oxide, inorg. compds.;**org. compds.: Skin
LMPE (Mexico) Long-term value: 2* mg/m³
*metal
(Contd. on page 7)

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Trade name: Bronze

(Contd. of page 6)
· Ingredients with biological limit values:
7440-48-4 cobalt
BEI (USA) 15 µg/L
Medium: urine
Time: end of shift at end of workweek
Parameter: Cobalt (background)

1 µg/L
Medium: blood
Time: end of shift at end of workweek
Parameter: Cobalt (background, semi-quantitative)
7439-92-1 lead
BEI (USA) 30 µg/100 ml
Medium: blood
Time: not critical
Parameter: Lead

10 µg/100 ml
Medium: blood
Time: not critical
Parameter: Lead (women of child bearing potential)
· Additional information: No further relevant information available.
· Exposure controls
· Personal protective equipment:
· General protective and hygienic measures:
The usual precautionary measures for handling chemicals should be followed.
Keep away from foodstuffs, beverages and feed.
Store protective clothing separately.
Wash hands before breaks and at the end of work.
Avoid contact with the eyes.
Avoid close or long term contact with the skin.
· Engineering controls: No further relevant information available.
· Breathing equipment:
Particulate mask should filter at least 99% of airborne particles.
Use respiratory protection when grinding or cutting material.
· Protection of hands:
Wear gloves for the protection against mechanical hazards according to OSHA and NIOSH rules.
· Eye protection:

Safety glasses

· Body protection: Protective work clothing


· Limitation and supervision of exposure into the environment Avoid release to the environment.
· Risk management measures See Section 7 for additional information.

(Contd. on page 8)

41.0
Page 8 of 13
Safety Data Sheet
acc. to OSHA HCS (29 CFR 1910.1200)
Printing date 07/01/2015 Reviewed on 07/01/2015

Trade name: Bronze

(Contd. of page 7)

9 Physical and chemical properties


· Information on basic physical and chemical properties
· General Information
· Appearance:
Form: Solid material
Color: Bronze colored
· Odor: Odorless
· Odor threshold: Not determined.
· pH-value: Not applicable.
· Change in condition
Melting point/Melting range: 927 °C (1701 °F)
Boiling point/Boiling range: Undetermined.
· Flash point: Not applicable.
· Flammability (solid, gaseous): Not determined.
· Auto-ignition temperature: Not determined.
· Decomposition temperature: Not determined.
· Auto igniting: Product is not self-igniting.
· Danger of explosion: Product does not present an explosion hazard.
· Explosion limits:
Lower: Not determined.
Upper: Not determined.
· Vapor pressure: Not applicable.
· Density at 20 °C (68 °F): >7 g/cm³ (>58.415 lbs/gal)
· Relative density Not determined.
· Vapour density Not applicable.
· Evaporation rate Not applicable.
· Solubility in / Miscibility with
Water: Insoluble.
· Partition coefficient (n-octanol/water): Not determined.
· Viscosity:
Dynamic: Not applicable.
Kinematic: Not applicable.
· Other information No further relevant information available.

10 Stability and reactivity


· Reactivity
· Chemical stability
· Thermal decomposition / conditions to be avoided: Heating may cause release of toxic fumes.
(Contd. on page 9)

41.0
Page 9 of 13
Safety Data Sheet
acc. to OSHA HCS (29 CFR 1910.1200)
Printing date 07/01/2015 Reviewed on 07/01/2015

Trade name: Bronze

(Contd. of page 8)
· Possibility of hazardous reactions
Reacts with strong acids and alkali.
Reacts with strong oxidizing agents.
Reacts with halogenated compounds.
As the product is supplied it is not capable of dust explosion; however enrichment with fine dust causes
risk of dust explosion.
· Conditions to avoid Avoid acids.
· Incompatible materials: Oxidizers, strong bases, strong acids
· Hazardous decomposition products:
Possible in traces:
Toxic metal oxide smoke
Leadoxide vapor

11 Toxicological information
· Information on toxicological effects
· Acute toxicity:
· LD/LC50 values that are relevant for classification:
7439-96-5 manganese, powdered
Oral LD50 9000 mg/kg (rat)
7440-48-4 cobalt
Oral LD50 6170 mg/kg (rat)
7439-92-1 lead
Oral LD50 >2000 mg/kg (rat)
· Primary irritant effect:
· on the skin: No irritant effect.
· on the eye: No irritating effect.
· Sensitization: No sensitizing effects known.
· Additional toxicological information:
The product is not subject to classification according to internally approved calculation methods for
preparations:
When used and handled according to specifications, the product does not have any harmful effects
according to our experience and the information provided to us.
· Carcinogenic categories
· NTP (National Toxicology Program)
7440-02-0 nickel R
· OSHA-Ca (Occupational Safety & Health Administration)
None of the ingredients is listed.
· Probable Routes of Exposure
Eye contact.
Skin contact.
· Repeated Dose Toxicity:
May cause metal fume disease.
Repeated or long-term inhalation of product dusts may cause pulmonary disease.
(Contd. on page 10)

41.0
Page 10 of 13
Safety Data Sheet
acc. to OSHA HCS (29 CFR 1910.1200)
Printing date 07/01/2015 Reviewed on 07/01/2015

Trade name: Bronze

(Contd. of page 9)
· CMR effects (carcinogenity, mutagenicity and toxicity for reproduction):
· Germ cell mutagenicity Based on available data, the classification criteria are not met.
· Carcinogenicity Based on available data, the classification criteria are not met.
· Reproductive toxicity Based on available data, the classification criteria are not met.
· STOT-single exposure Based on available data, the classification criteria are not met.
· STOT-repeated exposure Based on available data, the classification criteria are not met.
· Aspiration hazard Based on available data, the classification criteria are not met.

12 Ecological information
· Toxicity
· Aquatic toxicity: No further relevant information available.
· Persistence and degradability No further relevant information available.
· Behavior in environmental systems:
· Bioaccumulative potential May be accumulated in organism
· Mobility in soil No further relevant information available.
· Additional ecological information:
· General notes:
The product contains heavy metals. Avoid transfer into the environment. Specific preliminary treatments
are necessary.
· Other adverse effects No further relevant information available.

13 Disposal considerations
· Waste treatment methods
· Recommendation:
Contact manufacturer for recycling information.
The user of this material has the responsibility to dispose of unused material, residues and containers in
compliance with all relevant local, state and federal laws and regulations regarding treatment, storage and
disposal for hazardous and nonhazardous wastes.
· Uncleaned packagings:
· Recommendation: Disposal must be made according to official regulations.

14 Transport information
· UN-Number
· DOT, ADR, ADN, IMDG, IATA Not Regulated
· UN proper shipping name
· DOT, ADR, ADN, IMDG, IATA Not Regulated
· Transport hazard class(es)
· DOT, ADR, IMDG, IATA
· Class Not Regulated
· Label -
· ADN/R Class: Not Regulated
(Contd. on page 11)

41.0
Page 11 of 13
Safety Data Sheet
acc. to OSHA HCS (29 CFR 1910.1200)
Printing date 07/01/2015 Reviewed on 07/01/2015

Trade name: Bronze

(Contd. of page 10)


· Packing group
· DOT, ADR, IMDG, IATA Not Regulated
· Environmental hazards:
· Marine pollutant: No
· Special precautions for user Not applicable.
· Transport in bulk according to Annex II of
MARPOL73/78 and the IBC Code Not applicable.
· UN "Model Regulation": -

15 Regulatory information
· Safety, health and environmental regulations/legislation specific for the substance or mixture
· United States (USA)
· SARA
· Section 355 (extremely hazardous substances):
None of the ingredients is listed.
· Section 313 (Specific toxic chemical listings):
7440-50-8 copper
7440-02-0 nickel
7429-90-5 aluminum
7439-96-5 manganese, powdered
7440-48-4 cobalt
· TSCA (Toxic Substances Control Act):
All ingredients are listed.
· Proposition 65 (California)
· Chemicals known to cause cancer:
7440-02-0 nickel
7440-48-4 cobalt
· Chemicals known to cause reproductive toxicity for females:
None of the ingredients are listed.
· Chemicals known to cause reproductive toxicity for males:
None of the ingredients is listed.
· Chemicals known to cause developmental toxicity:
None of the ingredients is listed.
· Carcinogenic categories
· EPA (Environmental Protection Agency)
7440-50-8 copper D
7439-96-5 manganese, powdered D
1314-13-2 zinc oxide D, I, II
· IARC (International Agency for Research on Cancer)
7440-02-0 nickel 1
(Contd. on page 12)

41.0
Page 12 of 13
Safety Data Sheet
acc. to OSHA HCS (29 CFR 1910.1200)
Printing date 07/01/2015 Reviewed on 07/01/2015

Trade name: Bronze

(Contd. of page 11)


7440-48-4 cobalt 2B
· TLV (Threshold Limit Value established by ACGIH)
7440-02-0 nickel A5
7429-90-5 aluminum A4
7440-48-4 cobalt A3
· NIOSH-Ca (National Institute for Occupational Safety and Health)
7440-02-0 nickel
· State Right to Know Listings
None of the ingredients is listed.
· Canadian substance listings:
· Canadian Domestic Substances List (DSL)
All ingredients are listed.
· Canadian Ingredient Disclosure list (limit 0.1%)
7440-02-0 nickel
7440-48-4 cobalt
· Canadian Ingredient Disclosure list (limit 1%)
7440-50-8 copper
7429-90-5 aluminum
7439-96-5 manganese, powdered
· Other regulations, limitations and prohibitive regulations
This product has been classified in accordance with hazard criteria of the Controlled Products Regulations
and the SDS contains all the information required by the Controlled Products Regulations.
· Chemical safety assessment: A Chemical Safety Assessment has not been carried out.

16 Other information
This information is based on our present knowledge. However, this shall not constitute a guarantee for any
specific product features and shall not establish a legally valid contractual relationship.
· Date of preparation / last revision 07/01/2015 / -
· Abbreviations and acronyms:
ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement concerning the
International Carriage of Dangerous Goods by Road)
IMDG: International Maritime Code for Dangerous Goods
DOT: US Department of Transportation
IATA: International Air Transport Association
ACGIH: American Conference of Governmental Industrial Hygienists
EINECS: European Inventory of Existing Commercial Chemical Substances
ELINCS: European List of Notified Chemical Substances
CAS: Chemical Abstracts Service (division of the American Chemical Society)
NFPA: National Fire Protection Association (USA)
HMIS: Hazardous Materials Identification System (USA)
WHMIS: Workplace Hazardous Materials Information System (Canada)
LC50: Lethal concentration, 50 percent
LD50: Lethal dose, 50 percent
Flam. Sol. 1: Flammable solids, Hazard Category 1
Flam. Sol. 2: Flammable solids, Hazard Category 2
(Contd. on page 13)

41.0
Page 13 of 13
Safety Data Sheet
acc. to OSHA HCS (29 CFR 1910.1200)
Printing date 07/01/2015 Reviewed on 07/01/2015

Trade name: Bronze

(Contd. of page 12)


Pyr. Sol. 1: Pyorphoric Solids, Hazard Category 1
Water-react. 1: Substances and Mixtures which, in contact with water, emit flammable gases, Hazard Category 1

Resp. Sens. 1: Sensitisation - Respirat., Hazard Category 1


Skin Sens. 1: Sensitisation - Skin, Hazard Category 1
Carc. 2: Carcinogenicity, Hazard Category 2
Repr. 1A: Reproductive toxicity, Hazard Category 1A
STOT RE 1: Specific target organ toxicity - Repeated exposure, Hazard Category 1
· Sources
SDS Prepared by:
ChemTel Inc.
1305 North Florida Avenue
Tampa, Florida USA 33602-2902
Toll Free North America 1-888-255-3924 Intl. +01 813-248-0573
Website: www.chemtelinc.com

41.0
Material Safety Data Sheet
_____________________________________________
__

Revision Date 15-Mar-2016

1. CHEMICAL PRODUCT AND COMPANY Inhalation Short term (acute) overexposure to welding
fumes may result in the following effects.
INFORMATION Inhalation of copper oxide fumes can cause metal
fume fever. Initial symptoms of metal fume fever
Product code CW1533 can include sweating, shivering, headache, fever,
Product name Carbon Arc Electrodes - 1/4" chills, thirstiness, muscle aches, nausea,
Recommended Use Welding Rod vomiting, weakness, and tiredness. Individuals
with Wilson's Disease are more susceptible to
Supplier Cronatron, A Lawson Brand copper poisoning. Prolonged or repeated
Lawson Products, Inc. breathing of graphite dust can result in
8770 W.Bryn Mawr Ave.- Suite 900 pneumoconiosis.
Chicago, IL 60631
1-866-529-7664 Ingestion Not likely to occur.
Emergency telephone number (888) 426-4851

2. HAZARDS IDENTIFICATION
3. COMPOSITION / INFORMATION ON
Emergency Overview
Hazardous fumes are generated by welding, soldering or brazing.
INGREDIENTS
Exposure to welding related processes, materials, fumes or gases
might be linked to certain neurological and physical disorders and Chemical Name CAS-No Weight %
cancer. Protect yourself and others at all times. A NIOSH approved, Graphite 7782-42-5 10-90
proper fitting and well-maintained respirator should be worn at all times Carbon 7440-44-0 10-90
while using this product. Keep your head out of the fumes and gases. Copper 7440-50-8 10-30
Use adequate ventilation and/or exhaust to keep fumes and gases
from your breathing zone and the general area. Keep others without
proper respiratory protection away from the fumes and gases and your 4. FIRST AID MEASURES
work zone while using this product.
General advice If no detectable pulse, begin Cardio Pulmonary
Aggravated Medical Conditions Resuscitation (CPR). Employ First Aid techniques
Pre-existing respiratory conditions may be aggravated by exposure to recommended by the Red Cross.
welding fumes. Pre-existing kidney and/or liver disorders may be
aggravated by exposure to this product. Eye contact Flush eyes with plenty of water. Seek medical
attention if irritation persists.
Principal Routes of Exposure
Eyes. Skin. Inhalation of welding fumes. Skin contact Wash off immediately with plenty of water. Seek
medical attention if irritation persists.
General Welding Statement
Fumes and gases can be dangerous to your health. Arc Rays can Ingestion No specific treatment is necessary since this
injure eyes and burn skin. Electric shock can kill. For electric shock, material is not likely to be hazardous by ingestion.
disconnect and turn off the power. The ACGIH and OSHA have set the
exposure level for welding fumes at 5 mg/m3. Train the welder not to Inhalation If breathing is difficult, give oxygen. Administer
touch live electrical parts and to insulate himself from work and ground. artificial respiration if not breathing. Call a
Welding fumes must be considered as possible carcinogens under physician immediately.
OSHA 29 CFR 1910.1200.
5. FIRE FIGHTING MEASURES
Potential health effects
Flash point °C Not Applicable
Eyes May cause the following effects:. Causes burns. Flash point °F Not Applicable
Irritation. Method Not Applicable

Skin Skin burns. Autoignition temperature °C No data available

_____________________________________________
__

Page 1 / 4
Product code CW1533 Product name Carbon Arc
Electrodes - 1/4"
_____________________________________________
__

Autoignition temperature °F No data available 8. EXPOSURE CONTROLS / PERSONAL


PROTECTION
Flammability Limits (% in Air)
Upper No data available
Lower No data available Chemical OSHA PEL OSHA PEL ACGIH OEL ACGIH OEL
Name (TWA) (Ceiling) (TWA) (STEL)
Carbon - - - -
Suitable extinguishing media Graphite 15 mg/m3 - 2 mg/m3 -
Water. Carbon dioxide (CO2). Dry chemical powder. 5 mg/m3
Copper 0.1 mg/m3 - 0.2 mg/m3 -
Extinguishing media which must NOT be used for safety reasons 1 mg/m3 1 mg/m3
None. Ventilation and Environmental Controls
Use enough ventilation, local exhaust at the work area, general, or
Special protective equipment for firefighters both, to keep below the TLV's in the worker's breathing zone and the
As in any fire, wear self-contained breathing apparatus general area.
pressure-demand, MSHA/NIOSH (approved or equivalent) and full
protective gear. Hygiene measures
Handle in accordance with good industrial hygiene and safety practice.
Fire and Explosion Hazards
Product is nonflammable and nonexplosive under normal conditions of Respiratory protection
use. Welding arcs and sparks can ignite combustibles. Refer to Use respirable fume respirator (P100) or supplied air when welding in
American National Standard Z49.1 for fire prevention during welding. confined spaces, or where local exhaust does not keep the exposure
below TLV. Follow OSHA respirator regulations (29 CFR 1910.134)
Sensitivity to shock and if necessary, wear a MSHA/NIOSH approved respirator. Train
No information available. welder to keep head out of fumes.

Sensitivity to static discharge Hand Protection


No information available. Welder's gloves. Leather gloves.

Eye protection
6. ACCIDENTAL RELEASE MEASURES Wear helmet or face shield with filter lens. As a rule of thumb, start
with a shade which is too dark to see the work area. Then go to the
Methods for cleaning up next lighter shade which gives sufficient view of the work area. Provide
Collect and contain for disposal. protective screens and flash goggles,if necessary, to shield others.

7. HANDLING AND STORAGE Hearing Protection


Ear plugs should be worn
Handling
Use normal safe handling procedures. Refer to American National Skin and body protection
Standard Z49.1 for fire prevention during welding. Sufficient to provide protection from radiation,heat, sparks and
electrical shock.May include arm and shoulder protectors,aprons and
Storage dark substantial clothing. See ANSI Z49.1.
No information available.
Other Protective Equipment
Wear head, hand and body protection which help prevent injury from
radiation, sparks, heat, and electrical shock. See ANSI Z49.1.

_____________________________________________
__

Page 2 / 4
Product code CW1533 Product name Carbon Arc
Electrodes - 1/4"
_____________________________________________
__

Polymerization
9. PHYSICAL AND CHEMICAL PROPERTIES Hazardous polymerization does not occur.

Form Solid 11. TOXICOLOGICAL INFORMATION


Color Black / Copper
Odor None Component Information
Odor Threshold No information available
pH No data available Chemical Name LD50 (oral,rat) LD50 LC50
Specific Gravity 1.9-2.3 (dermal,rat/rab (inhalation,rat)
Vapor pressure Not Applicable bit)
Vapor density Not Applicable Carbon 10000 mg/kg - -
Evaporation Rate Not Applicable 7440-44-0
Water solubility Insoluble
Graphite 10000 mg/kg - -
Partition Coefficient No data available
7782-42-5
(n-octanol/water)
Boiling point/range °C 2300 Copper - - -
Boiling point/range °F 4172 7440-50-8
Melting point/range °C 1803 Synergistic Products None known.
Melting point/range °F 3277
Flash point °C Not Applicable Specific Hazards Copper dust and fume affect the
Flash point °F Not Applicable respiratory system, lungs, skin,
liver and eyes.

Potential health effects


10. STABILITY AND REACTIVITY

Stability Sensitization May cause sensitization of


Stable. susceptible persons.
Conditions to avoid Chronic toxicity See Section 2.
None known.
Mutagenic effects None known.
Incompatability
None known.
Teratogenic effects None known.
Hazardous Decomposition Products
Welding fumes cannot be classified simply. Their composition and Reproductive toxicity None known.
quantity are dependent upon the metal being welded, the process,
procedures and electrodes being used. Other conditions which also Target Organ Effects None Known.
influence the composition and quantity of the fumes and gases to
which workers may be exposed include;. Coatings on the metal being Carcinogenic effects See table below.
welded (such as paint, plating, or galvanizing), number of welders and
volume of work area. Contaminants in the atmosphere such as IARC
Chemical ACGIH NTP - NTP - OSHA
chlorinated hydrocarbon vapors from cleaning and degreasing
Name OEL - Known Suspecte RTK
operations. The amount and type of ventilation, the position of the
Carcinog Carcinog d Human Carcinog
welder's head with respect to the fume plume. When the electrode is
ens ens Carcinog ens
consumed, the fume and gas decomposition products are different in
ens
percent and form from the ingredients listed in Section 3.
Decomposition products include those originating from the Graphite Not Listed Not Listed Not Listed Not Listed Not Listed
volatilization, reaction or oxidation of the wire or rod plus those from Carbon Not Listed Not Listed Not Listed Not Listed Not Listed
the base metal and coating. Reasonably expected decomposition Copper Not Listed Not Listed Not Listed Not Listed Not Listed
products from normal use of these products include the oxides of the
material listed in the ingredients section, as well as carbon monoxide,
carbon dioxide, ozone and nitrogen oxides. The concentration of a
12. ECOLOGICAL INFORMATION
given fume or gas component may decrease or increase by many
times the original concentration in the electrode. One recommended Copper
way to determine the composition and quantity of fumes and gases to Water Flea Data
which workers are exposed is to take an air sample inside the welder's 0.03: 48 h Daphnia magna mg/L EC50 Static
helmet, if worn, or in the worker's breathing zone. See ANSI/AWS
F1.1.
13. DISPOSAL CONSIDERATIONS

_____________________________________________
__

Page 3 / 4
Product code CW1533 Product name Carbon Arc
Electrodes - 1/4"
_____________________________________________
__

Waste from residues / unused products


Can be landfilled or incinerated, when in compliance with local
regulations. Dispose of all product, residues and clean-up materials in
accordance with local, state, and federal regulations.

14. TRANSPORTATION INFORMATION

DOT

Not Regulated

TDG

Not Regulated

15. REGULATORY INFORMATION

US EPA SARA 313

Chemical Name US EPA SARA 313 Emission


Reporting
Copper Listed

State Regulations

Chemical Name New Jersey - Pennsylvania - California


RTK RTK Prop. 65
Graphite Not Listed Listed Not Listed
Carbon Not Listed Not Listed Not Listed
Copper Not Listed Listed Not Listed

International Inventories

Chemical Name EINEC DSL NDSL TSCA Graphit


S e
X X - X Carbon X
X - X Copper X X
- X
CPR
This product has been classified in accordance with the hazard criteria
of the Controlled Product Regulations and the MSDS contains all of the
information required by the Controlled Product Regulations.

16. OTHER INFORMATION

Prepared By V. Shargorodsky, Regulatory


Affairs Engineer

The information accumulated herein is believed to be accurate, but is


not warranted to be, whether originating with the company or not.
Recipients are advised to confirm in advance of need that the
information is current, applicable, and suitable to their circumstances.

_____________________________________________
__

Page 4 / 4
Material Safety Data Sheet
Carbon Dioxide (Liquefied gas)

1. Product and company identification


Product name : Carbon Dioxide (Liquefied gas)
Synonym : Dry ice; Carbonic acid gas; Carbon dioxide in coal mines; Carbon dioxide.
Trade name : ALIGAL™ 2
Material uses : Various/Special atmospheres for food.
CAS number : 124-38-9
Supplier/Manufacturer : Air Liquide Canada Inc.
1250, René-Lévesque West, Suite 1700
Montreal, QC
H3B 5E6
www.airliquide.ca
1-800-817-7697
Prepared by : IHS
In case of emergency : (514) 878-1667

2. Hazards identification
Physical state : Gas. [Liquefied gas]
Color : Colorless.
Odor : Odorless.
Emergency overview
Signal word : CAUTION!
Hazard statements : GAS REDUCES OXYGEN AVAILABLE FOR BREATHING. AT VERY HIGH
CONCENTRATIONS, CAN DISPLACE THE NORMAL AIR AND CAUSE
SUFFOCATION FROM LACK OF OXYGEN. MAY CAUSE TARGET ORGAN
DAMAGE, BASED ON ANIMAL DATA.
Precautions : At very high concentrations, can displace the normal air and cause suffocation from lack
of oxygen. Do not enter storage areas and confined spaces unless adequately
ventilated. Do not breathe gas. Use only with adequate ventilation. Keep container
tightly closed and sealed until ready for use.
Routes of entry : Dermal contact. Eye contact. Inhalation.
Potential acute health effects
Inhalation : At very high concentrations, can displace the normal air and cause suffocation from lack
of oxygen.
Ingestion : Ingestion of liquid can cause burns similar to frostbite.
Skin : Dermal contact with rapidly evaporating liquid could result in freezing of the tissues or
frostbite.
Eyes : Liquid can cause burns similar to frostbite.
Potential chronic health effects
Chronic effects : May cause target organ damage, based on animal data.
Carcinogenicity : No known significant effects or critical hazards.
Mutagenicity : No known significant effects or critical hazards.
Teratogenicity : No known significant effects or critical hazards.
Developmental effects : No known significant effects or critical hazards.
6/1/2014. Canada 1/9
www.airliquide.ca
1-800-817-7697
Carbon Dioxide (Liquefied gas)

2. Hazards identification

Fertility effects : No known significant effects or critical hazards.


Target organs : May cause damage to the following organs: lungs, cardiovascular system, upper
respiratory tract, central nervous system (CNS).

Over-exposure signs/symptoms
Inhalation : No specific data.
Ingestion : Adverse symptoms may include the following:
frostbite
Skin : Adverse symptoms may include the following:
frostbite
Eyes : Adverse symptoms may include the following:
frostbite
Medical conditions : Pre-existing disorders involving any target organs mentioned in this MSDS as being at
aggravated by over- risk may be aggravated by over-exposure to this product.
exposure

3. Composition/information on ingredients
Name CAS number %
Carbon dioxide 124-38-9 >99.5
There are no additional ingredients present which, within the current knowledge of the supplier and in the
concentrations applicable, are classified as hazardous to health or the environment and hence require reporting
in this section.

4. First aid measures


Eye contact : Check for and remove any contact lenses. Immediately flush eyes with plenty of water
for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical
attention immediately.
Skin contact : In case of contact with liquid, warm frozen tissues slowly with lukewarm water. Wash
clothing before reuse. Clean shoes thoroughly before reuse. Get medical attention
immediately.
Inhalation : Move exposed person to fresh air. If not breathing, if breathing is irregular or if
respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel.
Loosen tight clothing such as a collar, tie, belt or waistband. Get medical attention
immediately.
Ingestion : As this product rapidly becomes a gas when released, refer to the inhalation section.
Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. If it is
suspected that fumes are still present, the rescuer should wear an appropriate mask or
self-contained breathing apparatus. It may be dangerous to the person providing aid to
give mouth-to-mouth resuscitation.
Antidote information
Product/ingredient name Antidote information
No antidote information known
Notes to physician : No specific treatment. Treat symptomatically. Contact poison treatment specialist
immediately if large quantities have been ingested or inhaled.

6/1/2014. Canada 2/9


www.airliquide.ca
1-800-817-7697
Carbon Dioxide (Liquefied gas)

5. Fire-fighting measures
Flammability of the product : Contains gas under pressure. In a fire or if heated, a pressure increase will occur and
the container may burst or explode.
Extinguishing media
Suitable : Use an extinguishing agent suitable for the surrounding fire.
Not suitable : None known.
Special exposure hazards : Promptly isolate the scene by removing all persons from the vicinity of the incident if
there is a fire. No action shall be taken involving any personal risk or without suitable
training. Contact supplier immediately for specialist advice. Move containers from fire
area if this can be done without risk. Use water spray to keep fire-exposed containers
cool.
Hazardous thermal : Decomposition products may include the following materials:
decomposition products carbon dioxide
carbon monoxide
Special protective : Fire-fighters should wear appropriate protective equipment and self-contained breathing
equipment for fire-fighters apparatus (SCBA) with a full face-piece operated in positive pressure mode. For
incidents involving large quantities, thermally insulated undergarments and thick textile
or leather gloves should be worn.

6. Accidental release measures


Personal precautions : No action shall be taken involving any personal risk or without suitable training.
Evacuate surrounding areas. Keep unnecessary and unprotected personnel from
entering. Do not touch or walk through spilled material. Avoid breathing gas. Provide
adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put
on appropriate personal protective equipment (see Section 8). If leak is in user's
equipment, be certain to purge piping with an inert gas prior to attempting repairs. Never
fix a leak while the system is under pressure. If leak is on container or container valve,
contact the closest Air Liquide Canada location.
Environmental precautions : Ensure emergency procedures to deal with accidental gas releases are in place to avoid
contamination of the environment. Avoid dispersal of spilled material and runoff and
contact with soil, waterways, drains and sewers. Inform the relevant authorities if the
product has caused environmental pollution (sewers, waterways, soil or air).
Methods for cleaning up
Small spill : Immediately contact emergency personnel. Stop leak if without risk.
Large spill : Immediately contact emergency personnel. Stop leak if without risk. Note: see Section
1 for emergency contact information and Section 13 for waste disposal.

7. Handling and storage


Handling : Put on appropriate personal protective equipment (see Section 8). Eating, drinking and
smoking should be prohibited in areas where this material is handled, stored and
processed. Workers should wash hands and face before eating, drinking and smoking.
Remove contaminated clothing and protective equipment before entering eating areas.
Contains gas under pressure. Do not get in eyes or on skin or clothing. Avoid breathing
gas. Use only with adequate ventilation. Wear appropriate respirator when ventilation
is inadequate. Valve protection caps must remain in place unless cylinder is secured
with valve outlet piped to usage point. Do not drag, slide or roll cylinders. Use a suitable
hand truck for cylinder movement. Use a pressure regulator when connecting cylinder to
lower pressure piping or systems. Do not heat cylinder by any means to increase the
discharge rate of product from the cylinder. Use a check valve or trap in the discharge
line to prevent hazardous back flow to the cylinder. Do not tamper with (valve) safety

6/1/2014. Canada 3/9


www.airliquide.ca
1-800-817-7697
Carbon Dioxide (Liquefied gas)

7. Handling and storage


device. Close valve after each use and when empty.
Storage : Protect cylinders from physical damage. Store in cool, dry, well-ventilated area of non
combustible construction away from heavily trafficked areas and emergency exits. Do
not allow the temperature where cylinders are stored to exceed 52°C/125°F. Cylinders
must be stored upright and firmly secured to prevent falling or being knocked over. Full
and empty cylinders should be segregated. Use a "first in - first out" inventory system to
prevent full cylinders being stored for excessive periods of time. Store in accordance
with local regulations. Store in a segregated and approved area. Store in a dry, cool
and well-ventilated area, away from incompatible materials (see Section 10). Protect
from sunlight. Keep container tightly closed and sealed until ready for use.

8. Exposure controls/personal protection


Occupational exposure limits TWA (8 hours) STEL (15 mins) Ceiling

Ingredient List name ppm mg/m³ Other ppm mg/m³ Other ppm mg/m³ Other Notations
Carbon dioxide US ACGIH 6/2013 5000 9000 - 30000 54000 - - - - [2]
AB 4/2009 5000 9000 - 30000 54000 - - - -
BC 7/2013 5000 - - 15000 - - - - -
ON 1/2013 5000 9000 - 30000 54000 - - - -
QC 12/2012 5000 9000 - 30000 54000 - - - -

[2]Oxygen Depletion [Asphyxiant]

Consult local authorities for acceptable exposure limits.


Recommended monitoring : If this product contains ingredients with exposure limits, personal, workplace
procedures atmosphere or biological monitoring may be required to determine the effectiveness of
the ventilation or other control measures and/or the necessity to use respiratory
protective equipment. Reference should be made to appropriate monitoring standards.
Reference to national guidance documents for methods for the determination of
hazardous substances will also be required.
Engineering measures : Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or
other engineering controls to keep worker exposure to airborne contaminants below any
recommended or statutory limits.
Hygiene measures : Wash hands, forearms and face thoroughly after handling chemical products, before
eating, smoking and using the lavatory and at the end of the working period.
Appropriate techniques should be used to remove potentially contaminated clothing.
Wash contaminated clothing before reusing. Ensure that eyewash stations and safety
showers are close to the workstation location.
Personal protection
Respiratory : Use a properly fitted, air-purifying or air-fed respirator complying with an approved
standard if a risk assessment indicates this is necessary. If operating conditions cause
high gas concentrations to be produced or any recommended or statutory exposure limit
is exceeded, use an air-fed respirator or self-contained breathing apparatus. The gas
can cause asphyxiation without warning by replacing the oxygen in the air. Respirator
selection must be based on known or anticipated exposure levels, the hazards of the
product and the safe working limits of the selected respirator.

6/1/2014. Canada 4/9


www.airliquide.ca
1-800-817-7697
Carbon Dioxide (Liquefied gas)

8. Exposure controls/personal protection


Hands : Chemical-resistant, impervious gloves complying with an approved standard should be
worn at all times when handling chemical products if a risk assessment indicates this is
necessary. If contact with the liquid is possible, insulated gloves suitable for low
temperatures should be worn. Considering the parameters specified by the glove
manufacturer, check during use that the gloves are still retaining their protective
properties. It should be noted that the time to breakthrough for any glove material may
be different for different glove manufacturers. In the case of mixtures, consisting of
several substances, the protection time of the gloves cannot be accurately estimated.
Eyes : Safety eyewear complying with an approved standard should be used when a risk
assessment indicates this is necessary to avoid exposure to liquid splashes, mists or
dusts. If contact is possible, the following protection should be worn, unless the
assessment indicates a higher degree of protection: safety glasses with side-shields.
Skin : Personal protective equipment for the body should be selected based on the task being
performed and the risks involved and should be approved by a specialist before
handling this product.
Environmental exposure : Emissions from ventilation or work process equipment should be checked to ensure
controls they comply with the requirements of environmental protection legislation. In some
cases, fume scrubbers, filters or engineering modifications to the process equipment
will be necessary to reduce emissions to acceptable levels.

9. Physical and chemical properties


Physical state : Gas. [Liquefied gas]
Flash point : Not available.
Auto-ignition temperature : Not available.
Flammable limits : Not available.
Color : Colorless.
Odor : Odorless.
Molecular weight : 44.01 g/mole
Molecular formula : C-O2
pH : Not available.
Boiling/condensation point : -78.55°C (-109.4°F)
Melting/freezing point : Sublimation temperature: -78.5°C (-109.3°F)
Critical temperature : 30.9°C (87.6°F)
Relative density : 1.56
Density : Not available.
Vapor pressure : 5720 kPa (42903.49 mm Hg) [room temperature]
Vapor density : 1.53 [Air = 1]
Odor threshold : Not available.
Evaporation rate : Not available.
Viscosity : Not available.
Solubility : Partially soluble in the following materials: cold water.
Water solubility (g/l) : 1.64 g/l
LogKow : 0.83

6/1/2014. Canada 5/9


www.airliquide.ca
1-800-817-7697
Carbon Dioxide (Liquefied gas)

10. Stability and reactivity


Chemical stability : The product is stable.
Conditions to avoid : No specific data.
Incompatible materials : No specific data.
Hazardous decomposition : Under normal conditions of storage and use, hazardous decomposition products should
products not be produced.
Possibility of hazardous : Under normal conditions of storage and use, hazardous reactions will not occur.
reactions
Under normal conditions of storage and use, hazardous polymerization will not occur.

11. Toxicological information


Acute toxicity
Not available.
Chronic toxicity
Not available.

Irritation/Corrosion
Not available.
Sensitizer
Not available.

Carcinogenicity
Classification
Not available.

Mutagenicity
Not available.
Teratogenicity
Not available.

Reproductive toxicity
Not available.

12. Ecological information


Ecotoxicity : This product shows a low bioaccumulation potential.
Aquatic ecotoxicity
Not available.
Persistence/degradability
Not available.
Partition coefficient: n- : 0.83
octanol/water
Bioconcentration factor : Not available.
Mobility : Not available.

6/1/2014. Canada 6/9


www.airliquide.ca
1-800-817-7697
Carbon Dioxide (Liquefied gas)

12. Ecological information


Toxicity of the products of : Not available.
biodegradation
Other adverse effects : No known significant effects or critical hazards.

13. Disposal considerations


Waste disposal : The generation of waste should be avoided or minimized wherever possible. Disposal of
this product, solutions and any by-products should at all times comply with the
requirements of environmental protection and waste disposal legislation and any
regional local authority requirements. Empty pressure vessels should be returned to the
supplier. Waste packaging should be recycled.
Disposal should be in accordance with applicable regional, national and local laws and regulations.
Refer to Section 7: HANDLING AND STORAGE and Section 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
for additional handling information and protection of employees.

14. Transport information


Regulatory UN number Proper shipping Classes PG* Label Additional
information name information
TDG Classification UN2187 CARBON DIOXIDE, 2.2 - Explosive Limit and
REFRIGERATED Limited Quantity Index
0.12
LIQUID
Passenger Carrying Road
or Rail Index
50

IMDG Class UN2187 CARBON DIOXIDE, 2.2 - Emergency schedules


REFRIGERATED (EmS)
F-C, S-V
LIQUID

IATA-DGR Class UN2187 Carbon dioxide, 2.2 - Passenger and Cargo


refrigerated liquid AircraftQuantity limitation:
50 kg
Packaging instructions: 202
Cargo Aircraft Only
Quantity limitation: 500 kg
Packaging instructions: 202
Limited Quantities -
Passenger AircraftQuantity
limitation: Forbidden
Packaging instructions:
Forbidden

PG* : Packing group

15. Regulatory information


United States inventory : This material is listed or exempted.
(TSCA 8b)
WHMIS (Canada) : Class A: Compressed gas.
Canadian lists
Canadian NPRI : This material is not listed.
CEPA Toxic substances : This material is listed.
Canada inventory : This material is listed or exempted.
6/1/2014. Canada 7/9
www.airliquide.ca
1-800-817-7697
Carbon Dioxide (Liquefied gas)

15. Regulatory information


This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations
and the MSDS contains all the information required by the Controlled Products Regulations.
International regulations
International lists : Australia inventory (AICS): This material is listed or exempted.
China inventory (IECSC): This material is listed or exempted.
Japan inventory: This material is listed or exempted.
Korea inventory: This material is listed or exempted.
Malaysia Inventory (EHS Register): Not determined.
New Zealand Inventory of Chemicals (NZIoC): This material is listed or exempted.
Philippines inventory (PICCS): This material is listed or exempted.
Taiwan inventory (CSNN): This material is listed or exempted.
Chemical Weapons : Not listed
Convention List Schedule
I Chemicals
Chemical Weapons : Not listed
Convention List Schedule
II Chemicals
Chemical Weapons : Not listed
Convention List Schedule
III Chemicals

16. Other information


Label requirements : GAS REDUCES OXYGEN AVAILABLE FOR BREATHING. AT VERY HIGH
CONCENTRATIONS, CAN DISPLACE THE NORMAL AIR AND CAUSE
SUFFOCATION FROM LACK OF OXYGEN. MAY CAUSE TARGET ORGAN
DAMAGE, BASED ON ANIMAL DATA.
Hazardous Material :
Information System (U.S.A.)
Health * 0

Flammability 0
Physical hazards 2
Personal protective equipment X

Caution: HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4
representing significant hazards or risks Although HMIS® ratings are not required on MSDSs under 29 CFR 1910.
1200, the preparer may choose to provide them. HMIS® ratings are to be used with a fully implemented HMIS®
program. HMIS® is a registered mark of the National Paint & Coatings Association (NPCA). HMIS® materials may
be purchased exclusively from J. J. Keller (800) 327-6868.
The customer is responsible for determining the PPE code for this material.
Date of issue : 6/1/2014.
Date of previous issue : 6/15/2011.
Version : 6
Indicates information that has changed from previously issued version.
Notice to reader

6/1/2014. Canada 8/9


www.airliquide.ca
1-800-817-7697
Carbon Dioxide (Liquefied gas)

16. Other information


THE INFORMATION, RECOMMENDATIONS AND DATA CONTAINED IN THIS DOCUMENT ARE INTENDED TO BE
USED BY PROPERLY TRAINED AND QUALIFIED PERSONNEL ONLY AND AT THEIR SOLE RISKS AND DISCRETION.
THE INFORMATION, RECOMMENDATIONS AND DATA HEREIN CONTAINED ARE DERIVED FROMSOURCES
WHICH WE BELIEVE TO BE RELIABLE. HOWEVER, AIR LIQUIDE CANADA INC. MAKES NO REPRESENTATION AND
GIVES NO WARRANTY OF ANY KIND WHATSOEVER WITH RESPECT TO THEIR ACCURACY OR COMPLETENESS
AND ASSUMES NO LIABILITY FOR DAMAGES OR LOSS ARISING DIRECTLY OR INDIRECTLY FROM THEIR USE,
WHETHER PROPER OR IMPROPER.

Notes ALIGALTM : Trademark of L'Air Liquide S.A.

6/1/2014. Canada 9/9


www.airliquide.ca
1-800-817-7697
126.06 1 - CAVITY PROTECTION SPRAY 50 ML Page 1 of4

CAVITY PROTECTION SPRAY 50 ML

Product: 126.061 Revision Date: 2014/03/28

Section 1: PRODUCT INFORMATION


Section 2: HAZARDOUS INGREDIENTS
Section 3: PHYSJCAL DATA
Section 4: FIRE & EXPLOSION DATA
Section 5: REACTIVITY DATA
Section 6: TOXICOLOGICAL PROPERTIES
Section 7: PREVENTATIVE MEASURES
Section 8: FIRST AID MEASURES
Section 9: ADDITIONAL INFORMATION

Ii Section 1: PRODUCT INFORMATION i


Product name: Cavity Protection Spray 50 ml
Manufacturer: CarWorx Distribution Inc.
165, Graveline
St-Laurent, Quebec
H4T 1R3
Manufacturer emergency
Canutec 613-996-6666
phone number:
Supplier: Same as manufacturer
Chemical family: Mixture
Product uses: Chemical
TDG classification: AEROSOLS
UN 1950
Class 2.1
WHMIS classification: A, B5, D2B
DSL status: The substance(s) listed in section 2 appear on the Domestic Substances List
Revision details: Updated MSDS
Supplier MSDS date: 20 14/03/28
Information phone number: 514-745-5959 (1-877-745-5959)

Section 2: HAZARDOUS INGREDIENTS

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126.06 1 - CAVITY PROTECTION SPRAY 50 ML Page 2 of 4

64742- SOLVENT NAPHTHA, LIGHT NOT


89-8 ALIPHATIC AVAILABLE
74-98-6 5 PROPANE 1000 PPM NOT > 800000
AVAILABLE PPM/15MIN
RAT INHALATION
8008-20-6 9 KEROSENE 200 MG/M3 2835 MG/KG NOT AVAILABLE
(SKIN) RABBIT ORAL
15000 MG/KG
RAT_ORAL

II Section 3: PHYSICAL DATA II


Physical state: Liquid (aerosol)
Appearance & odor: Spirit/thinner odor
Light yellow
Odor threshold (ppm): Not available
pH: Not available
Specific gravity © 20 °C: Not available
Boiling point (°C): Not available
Vapour pressure (mmHg): Not available
Vapour density (air=1): Not available
Freezing point (°C): Not available
Evaporation rate
Not available
(butyl acetate = 1):
By volume: Not available
Solubility in water (%): Not available
Coefficient of water\oil dist.: Not available
VOC: Not available

Section 4: FIRE & EXPLOSION DATA II


Flammability: Flammable aerosol
Conditions of flammability: Heat, sparks and open flames
Extinguishing media: Foam
Carbon dioxide
Powder
Special procedures: Firefighters should wear the usual protective gear
Wear a self contained breathing apparatus
Flash point (°C), method: Not available
Auto-ignition temperature (°
Not available
C):
Upper flammability
Not available
limit (% vol):
Lower flammability
Not available
limit (% vol):
Hazardous combustion
None known
products:
Sensitivity to static
Not available
discharge:
Sensitivity to mechanical
Contents under pressure
impact:
Rate of burning: Not available
Explosive power: Aerosol containers are extremely flammable. Containers may rupture if
exposed to heat or fire

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126.06 1 - CAVITY PROTECTION SPRAY 50 ML Page 3 of 4

Ii Section 5: REACTIVITY DATA i


Chemical stability: Product is stable
Conditions of instability: None known
Hazardous polymerization: Not available
Incompatible substances: Not available
Hazardous decomposition
None known
products:

I Section 6: TOXICOLOGICAL PROPERTIES


Route of entry: Skin contact, eye contact, inhalation and ingestion
Eye contact: Irritant
Skin contact: Irritant
Inhalation: May cause headache and nausea
Harmful if inhaled
Ingestion: May be harmful if swallowed
Effects of chronic exposure: See effects of acute exposure
LD5O of product, species &
Not available for mixture, see the ingredients section
route:
LC5O of product, species &
Not available for mixture, see the ingredients section
route:
Exposure limit of material: Not available for mixture, see the ingredients section
Sensitization to product: Not available
Carcinogenic effects: Not available
Reproductive effects: Not available
Teratogenicity: Not available
Mutagenicity: Not available
Synergistic materials: Not available

Section 7: PREVENTATIVE MEASURES


Gloves/Type: Wear appropriate gloves
Respiratory/Type: NIOSH approved respirator, if necessary
Eye/Type: Safety glasses or goggles
Footwear/Type: Safety shoes per local regulations
Clothing/Type: As required to prevent skin contact
Other/Type: Eye wash facility should be in close proximity
Emergency shower should be in close proximity
Ventilation requirements: Ventilate adequately
Leak/Spill: Eliminate all sources of ignition
Absorb with inert material
Prevent entry into drains, sewers, and other waterways
Wear appropriate protective equipment
Place in appropriate container
Waste disposal: In accordance with municipal, provincial and federal regulations
Handling procedures and Protect against physical damage
equipment: Keep away from heat, sparks, and open flame
Use adequate ventilation
Wear personal protective equipment appropriate to task
Wash clothing before re-use
Wash thoroughly after handling

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126.061 - CAVITY PROTECTION SPRAY 50 ML Page 4 of 4

Keep out of reach of children


Avoid breathing vapor and spray
Avoid contact with skin, eyes and clothing
Storage requirements: Store in a cool and well ventilated area
Keep away from ignition sources
Keep containers tightly closed
Store away from food, drink and animal feed
Special shipping information: See transportation information

Section 8: FIRST AID MEASURES ij


Skin contact: Remove contaminated clothing
Wash with mild soap and water
Consult a physician if irritation persists
Eye contact: Flush with water for at least 15 minutes
Get medical attention
Inhalation: Remove victim to fresh air. If not breathing, qualified personnel should
administer artificial respiration. Get medical attention
Ingestion: Get medical attention immediately
Additional information: The above information is believed to be correct but does not purport to be
all inclusive and shall be used only as a guide. This company shall not be
held liable for any inaccuracies

I Section 9: ADDITIONAL INFORMATION


General note: This material safety data sheet was prepared from information obtained
from various sources, including product suppliers and the Canadian Center
for Occupational Health and Safety
Issued by: Environment, health and safety
Data prepared by: Conform-Action Data Systems
A division of 2843471 Canada Inc.
1840 Transcanada, suite 101
Dorval, QC H9P 1H7
Tel: (514) 683-2060 Fax: (514) 683-1445
24 hr. 1-866-628-7522 [email protected]

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ZL-W01, PENTEL CO., LTD., 3, 2014/04/24, 1/6

Safety Data Sheet (SDS)

Preparation Date  2013/02/05


Revision Date 2014/04/24
Section 1 - CHEMICALS AND COMPANY IDENTIFICATION
Chemical Identifier ZL-W01
Product Code ZL-W010001
Company Name Pentel of America, LTD.
Address 2715 Columbia Street, Torrance Ca. 90503
Company Contact Michael Storie, TQC Manager 909.975.2238
Phone Number 800.421.1419 EXT. 2238
Fax Number 909.975.2291
Mail Address 4000 East Airport Drive, Suite C Ontario California 91761
Emergency Phone
Number 800-421-1972
Recommended Use Correction fluids
and Restriction on
Use
XEZL31-W、ZL31-WK、XEZL1-W、ZL1-WK、XZL6-
W、XEZL61-W、XEZL21-W、XZL7F1C、XZL7F1AD

Section 2 - HAZARDS IDENTIFICATION


GHS Classification
Physicochemical Flammable liquids Category 2
Hazards
Health Hazards Acute toxicity - inhalation (vapour) Category 4
Serious eye damage/eye irritation Category 2B
Carcinogenicity Category 2
Specific target organ toxicity (single exposure)
Category 3(narcotic effect)
Environmental Hazard to the aquatic environment (acute hazard)
Hazards Category 2
Hazard to the aquatic environment (long-term
hazard) Category 2
Other hazards than mentioned above are Not
applicable or No data available.
GHS Label Elements

Symbols

Signal Word Danger


Hazard Statements H225 Highly flammable liquid and vapour
H320 Causes eye irritation
H332 Harmful if inhaled
H336 May cause drowsiness and dizziness
H351 Suspected of causing cancer
H411 Toxic to aquatic life with long lasting effects
Precautionary
Statements
Prevention Keep container tightly closed.(P233)
Precautionary
Statements
Avoid breathing mist, vapours and spray.(P261)
Wear protective gloves, eye protection and face
protection.(P280)
ZL-W01, PENTEL CO., LTD., 3, 2014/04/24, 2/6

Wash hand thoroughly after handling.(P264)


Response IF ON SKIN or hair: Remove or take off
Precautionary immediately all contaminated clothing. Rinse skin
Statements with water or shower.(P303+P361+P353)
IF INHALED: Remove to fresh air and keep at rest
in a position comfortable for
breathing.(P304+P340)
IF IN EYES: Rinse cautiously with water for
several minutes. Remove contact lenses, if
present and easy to do. Continue
rinsing.(P305+P351+P338)
Call a doctor if you feel unwell.(P312)
If eye irritation persists: Get medical advice and
attention.(P337+P313)
In case of fire: Use appropriate media for
extinction.(P370+P378)
Storage Store in a well-ventilated place. Keep
Precautionary cool.(P403+P235)
Statements

Section 3 - COMPOSITION / INFORMATION ON INGREDIENTS


Distinction of Substance mixture
or Mixture
Chemical Name or Concentration or Its ENCS No./ISHL No.
Formula CAS RN
Generic Name Ranges ENCS No. ISHL No.
1-Propanol、2-methyl- 0.4% C4H10O (2)-3049 Existing 78-83-1
Methylcyclohexane 42.4% C7H14 (3)-2230 Existing 108-87-2
Titanium dioxide(Ⅳ) 40.5% TiO2 (1)- Existing 13463-67-7
558,(5)-
5225
Silicon dioxide 1.3% SiO2 (1)-548 Existing 7631-86-9

Impurities and/or No information available


Stabilizing Additives which
Contribute to the

Section 4 - FIRST AID MEASURES


Inhalation Get medical advice and attention if you feel unwell.

呼吸が困難な場合には、新鮮な空気のある場所に
移動し、呼吸しやすい姿勢で休憩させること。
Skin Contact Call a doctor if you feel unwell.
Wash with plenty of soap and water.
If skin irritation occurs: Get medical advice and
attention.
Eye Contact Rinse cautiously with water for several minutes.
Remove contact lenses, if present and easy to do.
Continue rinsing.
When the ocular stimulation lasts, Seek medical
treatment and advice.
Ingestion Rinse mouth. Do NOT induce vomiting.
Get medical advice and attention if you feel unwell.

Section 5 - FIRE FIGHTING MEASURES


Extinguishing Media Dry chemicals, CO2, fog, sand or regular foam.
Unsuitable Extinguishing Straight streams.
Media
ZL-W01, PENTEL CO., LTD., 3, 2014/04/24, 3/6

Protection of Fire Figther In fire fighting, wear respiratory protection and


chemical protective clothing.

Section 6 - ACCIDENTAL RELEASE MEASURES


Personal Precautions, Wear appropriate personal protective equipment
Protective Equipment and (Refer to "Section 8 - EXPOSURE CONTROLS /
Emergency Procedures PERSONAL PROTECTION") and avoid inhalation
or contact with eyes and skin.
Environmental Pay attention not to cause the influence on the
Precautions environment by discharging into rivers.
Methods and Equipment Allow material to solidify, and scrape up.
for Containment and
Cleaning up
Prevention Measures for Prevent flowing into drain, sewage, basement, and
Secondary Accidents closed area.

Section 7 - HANDLING AND STORAGE


Handling Technical Measures Provide ventilation system and use necessary
personal protective equipment as described in
"Section 8 - EXPOSURE CONTROLS /
PERSONAL PROTECTION".
Precautions for Safe Prohibit use of heat, sparks, and fire in the
Handling surrounding area.
Avoid contact with eyes and skin.
Avoid swallowing.
Wash hand thoroughly after handling.
Handle at a well-ventilated place.
Prevents Handling of Refer to "Section 10 - STABILITY AND
Imcompatible REACTIVITY".
Substances or
Mixtures
Storage Precautionary Technical Measures The storage facility should be provided with
Statements necessary lighting, lighting equipment, and
ventilator to store and handle dangerous goods.
Refer to "Section 10 - STABILITY AND
REACTIVITY".
Store in a well-ventilated and cool place keeping
container tightly closed.
Store locked up.
Material Used in Keep only in original container.
Packaging/Container

Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION


Engineering Controls Good general ventilation should be sufficient to
control airborne levels.
Personal Protective Respiratory Use personal respiratory equipment as required.
Equipment Protection
Hand Protection Use personal gloves as required.
Eye Protection Protection glasses (ordinary glasses, ordinary
glasses with side shields, and goggles).
Use personal eye protection as required.
Skin and Body Use personal protective clothing and face
Protection protection as required.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES


Appearance Physical State liquid
Form liquid
Colour white
Odour characteristic
ZL-W01, PENTEL CO., LTD., 3, 2014/04/24, 4/6

Odour threshold No data available


pH No data available
Melting Point/Freezing No data available
Point
Initial Boiling Point and No data available
Boiling Ranges
Flash Point -4.4℃ (Tag Closed Cup)
Evaporation Rate No data available
Flammability (solid, gas) No data available
Flammability or Explosive Lower Limit No data available
Limits
Upper Limit No data available
Vapour Pressure No data available
Vapour Density No data available
Specific Gravity (Density) No data available
Partition Coefficient : n- No data available
Octanol/Water
Auto-Ignition No data available
Decomposition No data available
Temperature
Viscosity No data available
Kinematic viscosity No data available
Flammability or Explosive
Limits
Section 10 - STABILITY AND REACTIVITY
Reactivity No data available
Chemical stability No data available
Possibility of Hazardous No data available
Reaction
Conditions to Avoid No data available
Imcompatible Substances No data available
or Mixtures
Hazardous Decomposition No data available
Products

Section 11 - TOXICOLOGICAL INFORMATION


Acute Toxicity No information available
Skin Corrosion/Irritation No data available
Serious eye damage/eye No data available
irritation
Respiratory or Skin No data available
Sensitization
Germ Cell Mutagenicity No data available
Carcinogenicity No data available
Reproductive Toxicity No data available
Specific target organ No data available
toxicity (single exposure)
Specific target organ No data available
toxicity (repeated
exposure)
Aspiration Hazard No data available

Section 12 - ECOLOGICAL INFORMATION


Hazard to the aquatic No data available
environment (acute
Hazard to the aquatic No data available
environment (long-term
hazard)
Hazard to the ozone layer No data available
ZL-W01, PENTEL CO., LTD., 3, 2014/04/24, 5/6

Section 13 - DISPOSAL CONSIDERATIONS


Residual Waste Disposal should be in accordance with applicable
regulations and standards by the respective local
governments.
Commission a waste disposal company, or a local
public body who are licensed by local or regional
government, to dispose of the material.
Contaminated Container Recycle containers after cleansing, or carry out
and Packaging the disposal under the related laws and regulations
and the standards of the local governments.

Section 14 - TRANSPORT INFORMATION


International Regulations Regulatory Conform to the provisions of IMO.
Information by Sea
UN No. 1263
Proper Shipping PAINT
Class 3
Packing Group Ⅱ
Marine Pollutant Not applicable
Transport in bulk Not applicable
according to
MARPOL
73/78,Annex Ⅱ,and
the IBC code
Regulatory Conform to the provisions of ICAO/IATA.
Information by Air
UN No. 1263
Proper Shipping PAINT
Class 3
Packing Group Ⅱ
Regulations in Japan Regulatory Not applicable
Information by Road
or Rail
Regulatory Conform to the provisions of the Ship Safety Law.
Information by Sea
UN No. 1263
Proper Shipping PAINT
Name.
Class 3
Packing Group Ⅱ
Marine Pollutant Not applicable
Transport in bulk Not applicable
according to
MARPOL
73/78,Annex Ⅱ,and
the IBC code
Regulatory Conform to the provisions of the Ship Safety Law.
Information by Air
UN No. 1263
Proper Shipping PAINT
Name.
Class 3
Packing Group Ⅱ
Emergency Response 128
Guide Number

Section 15 - REGULATORY INFORMATION


Regulatory information with regard to this product in your country or in your region should be
examined by your own responsibility.
ZL-W01, PENTEL CO., LTD., 3, 2014/04/24, 6/6

Regulatory information with regard to this product in your country or in your region should be
examined by your own responsibility.

Section 16 - OTHER INFORMATION


Information Contact No information available
Other Property This information is furnished without warranty
express or implied.
This information is believed to be accurate to the
best knowledge of PENTEL Co., Ltd. but not
assumes leagal responsibility for use of or reliance
upon this information.
MATERIAL SAFETY DATA SHEET
Date Revised: 07/11/2013 Page: 1
Cream Hardener MSDS Number: 120001

SECTION 1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Material Identity
Product Name: Cream Hardener
Product Numbers: Red- 100358,
Blue- 100354, 100359, 100360, 100361,
101474 and 101475, 196185, 196174
White- 100340, and 101607
Product Use: Polymerization initiator

Company Emergency Telephone Numbers:


ITW Evercoat CHEMTREC: 1-800-424-9300
a Division of Illinois Tool Works Inc. CANUTEC: 1-613-996-6666
6600 Cornell Road
Cincinnati, Ohio USA 45242
Phone: 513-489-7600 Prepared By: Safety Department
Packaged By:
Rocket Plastics Co.
P.O. Box 429514
Montgomery, Ohio USA 45242

SECTION 2. COMPOSITION / INFORMATION ON INGREDIENTS

Ingredient(s) CAS Number EINECS Number % (by weight)


Benzoyl Peroxide 94-36-0 202-327-6 48 – 51
Plasticizer, non-phthalate Proprietary Proprietary 25 – 30
Water 7732-18-5 231-791-2 15 – 20
Silica, amorphous 7631-86-9 231-545-4 0–2
Calcium Carbonate 1317-65-3 215-279-6 0–2
Pigments Various Various 0–2
OSHA Regulatory Status: This material is classified as hazardous under OSHA
regulations.

SECTION 3. HAZARDS IDENTIFICATION


***EMERGENCY OVERVIEW***
WARNING! CAUSES EYE AND SKIN IRRITATION. HARMFUL IF
SWALLOWED. OXIDIZER.

Potential Health Effects

Acute Effects (Short Term):


Eye: Contact with paste may result in irritation, redness, tearing, blurred
vision, and/or swelling. .
MATERIAL SAFETY DATA SHEET
Date Revised: 07/11/2013 Page: 2
Cream Hardener MSDS Number: 120001

Skin: May cause skin irritation. Prolonged or repeated contact may dry
the skin. Symptoms may include minor itching, redness, burning,
drying and cracking of skin, and skin burns. May be readily
absorbed through the skin.

Swallowing: Ingestion of this material may cause gastro-intestinal irritation,


nausea, diarrhea, and vomiting.

Inhalation: Inhalation of vapors can cause nasal and respiratory irritation,


dizziness, weakness, fatigue, nausea, headache possible
unconsciousness, and/or asphyxiation.
Aspiration of this material into the lungs due to vomiting may
produce chemical pneumonitis which can be fatal. If vomiting
occurs spontaneously, keep head below hips to prevent aspiration
of liquid into lungs.

Chronic Effects of Overexposure (Long Term):


Benzoyl Peroxide: Repeated or prolonged contact may cause skin
sensitization. Overexposure to this material has been known to
cause the following effects in lab animals: skin damage. Benzoyl
Peroxide has caused tumorigenic effects in laboratory animals.

Cancer Information: This product does not contain any substance, which is
listed as a carcinogen by NTP, IARC or OSHA in quantities greater than
0.1%.

Primary Route(s) of Entry: Inhalation, Skin contact, Eye contact, Ingestion,


skin absorption.

SECTION 4. FIRST AID MEASURES

Eyes: Flush eyes gently with water for at least 15 minutes. Seek medical
attention.
Skin: Immediately remove contaminated clothing. Wash exposed area
with soap and water. Seek medical attention. Launder clothing
before reuse.
Swallowing: Consult a physician or poison control center immediately. DO NOT
INDUCE VOMITING. Give victim a glass of water. If individual is
drowsy or unconscious, Do Not give anything by mouth; place
individual on the left side with the head down. If possible, do not
leave individual unattended.
MATERIAL SAFETY DATA SHEET
Date Revised: 07/11/2013 Page: 3
Cream Hardener MSDS Number: 120001
Inhalation: If symptoms develop, immediately move individual away from
exposure and into fresh air. Seek immediate medical attention; keep person
warm, but not hot and keep quiet. If person is not breathing, begin artificial
respiration. If breathing is difficult, oxygen may be benificial if administered by
trained personnel.

SECTION 5. FIRE FIGHTING MEASURES


Flash Point: 184 ºF (84 ºC)
Explosive Limit: Lower: N/D Upper: N/D
Autoignition Temperature: Not Determined
OSHA Flammability Class: Combustible Liquid – Class IIIA

Hazardous Products of Combustion: May form toxic and corrosive gases:


carbon dioxide, carbon monoxide, benzoic acid and various hydrocarbons.

Fire and Explosion Hazards: Fire hazard increases when material becomes
dry. Vapors are heavier than air and may travel along the ground or may
be moved by ventilation and ignited by pilot lights, other flames, sparks,
heaters, smoking, electric motors, static discharge, or other ignition
sources at locations distant from material handling point.

Extinguishing Media: Regular foam, carbon dioxide, dry chemical.

Fire Fighting Instructions: Fight fire like a fuel oil fire. Water may be used to
keep fire-exposed containers cool until fire is out. Wear a self-contained
breathing apparatus NIOSH approved with a full facepiece operated in the
positive pressure demand mode with appropriate turn-out gear and
chemical resistant personal protective equipment.

NFPA Rating: Health - 2, Flammability - 2, Reactivity - 2

SECTION 6. ACCIDENTAL RELEASE MEASURES

In Case of Spill: Spill, Leak or Release: Eliminate all sources of ignition such as
flares, flames (including pilot lights), and electrical sparks. Ventilate the area.
Wear proper protective equipment (Section 8). Avoid breathing vapors. Collect
with an inert absorbant and dispose of properly.

SECTION 7. HANDLING AND STORAGE

Handling: All hazard precautions given in the data sheet must be observed. Avoid
contact with eyes, skin and clothing. Wash thoroughly after handling. Use only
with adequate ventilation. Do not breathe vapors or spray mist. Do not take
internally. Close container after each use. Keep out of reach of children.
MATERIAL SAFETY DATA SHEET
Date Revised: 07/11/2013 Page: 4
Cream Hardener MSDS Number: 120001

Storage: Store material in a cool, well-ventilated area. For maximum product


quality, do not store product above 100F/38C. Do not flame, cut, braze, weld
or melt empty containers. Keep product away from heat, open flame, and other
sources of ignition. Do not use or store near heat, sparks, or open flame. Keep
container tightly closed. Avoid contact with incompatible materials such as strong
acids, alkalis and oxidizers.

SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION


Eye Protection: Chemical splash goggles in compliance with OSHA regulations are
recommended.
Skin Protection: Protective gloves and proper clothing should be worn to prevent
skin contact. Gloves should be made of neoprene or natural
rubber. To prevent repeated or prolonged skin contact, wear
impervious clothing and boots.
Respiratory Protection: Use a NIOSH approved respirator designed to remove
particulate matter and organic solvent vapors.
Engineering Controls: Provide sufficient mechanical (general and/or local exhaust)
ventilation to maintain exposure below acceptable limits.
Explosion-proof ventilation system is acceptable.

Exposure Guidelines:

Hazardous Ingredients CAS Number OSHA PEL/TWA ACGIH TLV


Benzoyl Peroxide 94-36-0 5 mg/m3 5 mg/m3
3 3
Calcium Carbonate 1317-65-3 15 mg/m 10 mg/m
Silica, amorphous 7631-86-9 20 mppcf N/E
Mppcf- millions of particles per cubic foot of air N/E-Not Established

SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

Boiling Point: Decomposes Vapor Density: (Air=1) >1


explosively
Specific Gravity / 1.2 / 10.0 lbs/gal Percent Volatiles by 10-20%
Density: weight:
Evaporation Rate: Slower than ethyl Physical State: Paste
ether.
Melting Point: 217 F / 103 C pH: Neutral
(decomposes)
Odor: Slight ester odor. Solubility: Insoluble

Vapor Pressure: (mmHg): N/E Appearance: Red, White, or


Blue Paste
MATERIAL SAFETY DATA SHEET
Date Revised: 07/11/2013 Page: 5
Cream Hardener MSDS Number: 120001
Octanol/Water Unknown VOC* (as packaged- 0 lbs/gal or 0 g/L
Partition less exempts and
Coefficient: water):
VHAP Content by 0%
weight – as
packaged:
*NOTE: This material is used as a catalyst with a variety of products. Refer to the other MSDS for
additional VOC information for the mixture.

SECTION 10. STABILITY AND REACTIVITY

Hazardous Polymerization: Product will not undergo polymerization under


normal conditions of use.
Hazardous Decomposition: May form toxic and corrosive gases: carbon
dioxide, carbon monoxide, benzoic acid and various hydrocarbons.
Chemical Stability: Stable under normal handling conditions.
Incompatibility: Avoid contact in uncontrolled conditions with: organic materials,
inorganic acids, strong oxidizing agents, accelerators, reducing materials,
alcohols, amines and strong bases.

SECTION 11. TOXICOLOGICAL INFORMATION

Acute Toxicity Data:


Ingredient CAS # LD50 Oral-Rat LC50 Inhalation-Rat
Benzoyl Peroxide 94-36-0 7,710 mg/kg N/E
Calcium Carbonate 1317-65-3 6,450 mg/kg N/E

Carcinogenicity: See Cancer Information, Section 3.


Mutagenicity: No significant evidence found.
Teratogenicity: No significant evidence found.

SECTION 12. ECOLOGICAL INFORMATION

Ecotoxicity: The ecological toxicity of this product is not known.

SECTION 13. DISPOSAL CONSIDERATION

RCRA Hazardous Waste: This material as supplied, if discarded,


would be regulated as a hazardous waste under RCRA (40 CFR 261).
Dispose of in accordance with applicable federal, state, and local
regulations. Incineration is the prefered method for disposal. DO NOT
incinerate in closed containers.

RCRA Hazard Class: This material would be regulated as EPA Hazardous


MATERIAL SAFETY DATA SHEET
Date Revised: 07/11/2013 Page: 6
Cream Hardener MSDS Number: 120001
Waste Number D001 based on the characteristic of ignitablity (oxidizer).

SECTION 14. TRANSPORT INFORMATION


DOT Description: The DOT Classification for shipping is dependant on
quantity, type of packaging (a kit may include other components), or
method of shipment.

SECTION 15. REGULATORY INFORMATION


US Federal Regulations
TSCA (Toxic Substances Control Act) Status
TSCA (USA) The intentional ingredients of this product are listed.
CERCLA RQ - 40 CFR 302.4(a)
None
SARA Title III: Section 302- Extremely Hazardous Substances
None
SARA Title III: Section 313- Toxic Chemical List
Component CAS Number Percentage
Benzoyl Peroxide 94-36-0 45-50%
EPA Hazardous Air Pollutants (HAPS) 40 CFR 63
None
International Regulations
EINECS (Europe) The intentional ingredients of this product are listed.
DSL (Canada) The intentional ingredients of this product are listed.
WHMIS Classification
Health Hazard: D2B, C, F (Toxic Effects, Oxidizer,
Dangerously Reactive Materials)
Physical Hazard: B3 (Combustible)
State and Local Regulations
California Proposition 65:
This product contains the following chemical(s) known to the state of
California to cause cancer. NONE
This product contains the following chemical(s) known to the state of
California to cause birth defects or reproductive harm. NONE

SECTION 16. OTHER INFORMATION


HMIS Rating: Health – 2, Flammability - 2, Reactivity - 2
Key- 0=Least, 1=Slight, 2=Moderate, 3=Serious, 4=Extreme, *=Chronic Effects

Other Precautions for Use: DO NOT return unused material to the original container.
DO NOT contaminate product with foreign materials, it may cause hazardous
decomposition. DO NOT add to hot material. This product must be mixed with
other components prior to use. Please refer to the Material Safety Data Sheet for
all components before using.
MATERIAL SAFETY DATA SHEET
Date Revised: 07/11/2013 Page: 7
Cream Hardener MSDS Number: 120001
Additional Information may be obtained by calling the Evercoat MSDS Hotline at
1-800-729-7600.

NOTICE: The information accumulated herein is believed to be correct as of the date issued from
sources, which are believed to be accurate and reliable. Since it is not possible to anticipate all
circumstances of use, recipients are advised to confirm, in advance of need, that the information
is current, applicable and suitable to their circumstances.
. Safety Data Sheet (SDS)
Date PreparedlRevised: 9/10/2014 Version no.: 01 Supersedes: (-)

1.) Identification of the Mixture and of the Company


Product identifier: Crown General Purpose Silicone Lubricant Bulk -

Product name:
8034 General Purpose Silicone Lubricant

Relevant identified uses of the substance: Maybe used on wood, nylon, metal, rubber, canvas, leather,
and chrome. Ideal for windows, doors, hinges, locks, weather stripping, seals, zippers, etc.
Uses advised against: Avoid materials with strong oxidizing agents, and strong acids or bases. May
adversely affect certain plastics.

CAS No: Not Applicable (mixture)


EC No: Not Applicable (mixture)
Index No: Not Applicable (mixture)
Manufacturer/Supplier: Aervoe Industries Incorporated
Street address/P.O. Box: 1100 Mark Circle
Country ID/Postcode/Place Gardnerville, Nevada 89410
Telephone number: 001 (0) 1-775-782-0100
e-mail: [email protected]
National contact: Aervoe industries Incorporated
For Product Information: 001 (0) 1-800-227-0196
Emergency telephone number: 001 (0) 1-800-424-9300 (CIIEMTREC — 24 hrs)
English Language Service

2 Hazards identification

Classifications

Physical Hazards: Flammable liquid- Category 1

Health Hazards:
Asp. Tox. 1
Carc. lB
Muta. lB

Environmental Hazards: N/AV

Labeling

Signal Word: Danger

Hazard Statements:
H224 — Extremely flammable liquid and vapour.
H304 — May be fatal if swallowed and enters airways
H340 — May cause genetic defects
H350 — May cause cancer
In
‘I

A Safety Data Sheet (SDS)


Date PreparedlRevised: 9/10/20 14 Version no.: 01 Supersedes: (-)

Precautionary Statements: P101 - If medical advice is needed, have product container or label at hand
P102 - Keep out of reach of children
P103 - Read label before use
P210 - Keep away from heat/sparks/open flames/hot surfaces no -

smoking
P211 - Do not spray on an open flame or other ignition source
P261 - Avoid breathing dust/fume/gas/mistlvapours/spray
P262 - Do not get in eyes, on skin, or on clothing
P264 - Wash thoroughly after handling
...

P280 - Wear protective gloves/eye protectionlface protection


P303+P361+P353 If on skin or hair, remove/takeoff immediately all
-

contaminated clothing. Rinse skin with water/shower.


P410+P412 - Protect from sunlight. Do not expose to temperatures
exceeding 50°C/I 22°F
P501 Dispose of contents/container in accordance with
local/regional/national/international regulation

Symbols/Pictograms:

3. Composition I Information on Ingredients

Composition

Chemical Synonyms CAS Number EINECS Weight Hazard Category H-Code


Number Percent
Aliphatic Solvent 64742-89-8 265-192-2 60- Care. 18 H350
Petroleum Naphtha 100% Muta. lB 1-1340
Distillates Asp. Tox. 1 1-1304

Dimethylsilo N/AV 63148-62-9 270-705-8 3-7% N/AV N/AV


xa ne

Other Product Information

Chemical Identity: Mixture

4.) First Aid Measures

General Advice: If symptoms persist, always call a doctor.


A. Safety Data Sheet (SDS)
Date PreparedfRevised: 9/10/2014 Version no.: 01 Supersedes: (-)

Inhalation First Aid: Remove victim to fresh air and provide oxygen if breathing is
difficult. If not breathing, give artificial respiration, preferably
mouth to mouth. Get medical attention immediately.
Skin Contact First Aid: Wash with soap and water. Remove contaminated clothing and
shoes. Get medical attention immediately. Wash clothing before
reuse.
Eye Contact First Aid: If contact with eyes, immediately flush eyes with plenty of water
for at least 15 minutes, while holding eyelids open. Get medical
attention immediately.
Ingestion First Aid: If swallowed, wash out mouth with water provided the person is
conscious. Do not induce vomiting. Never give anything by mouth
to an unconscious person. Get medical attention immediately.
Most Important
Symptoms/Effects: Exposure may cause slight irritation to the skin, eyes, and respiratory tract.
Excessive exposure may cause central nervous system effects.

5. Fire Fighting Measures

Flammable Properties: Flammable liquid


Auto Ignition Temperature: Not Available
Suitable extinguishing media: Carbon dioxide, dry chemical, water spray.
Unsuitable extinguishing media: None known
Special hazards arising from the
substance or mixture: None known
Hazardous combustion products: Carbon dioxide, Carbon monoxide
Fire & Explosion Hazards: Closed Containers may rupture due to the buildup of pressure
from extreme temperatures.
Precautions for fire-fighters: Use water spray to cool containers exposed to heat or fire to prevent
pressure build up. In the event of a fire, wear full protective clothing and
NIOSH- approved self-contained breathing apparatus with full face piece
operated in the pressure demand or other positive pressure mode.

6. Accidental Release Measures

PERSONAL PRECAUTIONARY MEASURES:


1) Follow personal protective equipment recommendations found in section 8.
2) Maintain adequate ventilation.

SPILL CLEAN-UP PROCEDURES:


1.) Evacuate unprotected personnel from the area.
2.) Remove sources of ignition if safe to do so.
3.) Pickup spilled materials using non-sparking tools and place in an appropriate container for disposal.
4.) Contain spill to prevent material from entering sewage or ground water systems.
5.) Always dispose of waste materials in accordance with all EU, National and Local Regulations.
— Safety Data Sheet (SDS)
Date Prepared/Revised: 9/10/20 14 Version no.: 01 Supersedes: (-)

7 Handling and Storage


Handling:
Flammable liquid, use in a well ventilated area.
Do not use near sources of ignition.
Do not to eat, drink and smoke while working with this material.
Wash hands after use.
Conditions for safe storage, including any incompatibilities:
Store out of direct sunlight.
Storage Temperature: 32° to 120°F (0° to 49°C).
No known incompatibilities.

I 8 Exposure Controls / Personal Protection

Appropriate engineering controls:


Ensure adequate ventilation. A system of local and/or general exhaust is recommended to keep
employee exposures below the Airborne Exposure Limits.
Keep away from sources of ignition.
Take precautionary measures against static discharge.

Personal Protection:
Eye & face protection devices such as safety glasses, safety goggles or face shield are recommended.

Skin protection
Wear the appropriate protective clothing, including boots, gloves, lab coat, apron or coveralls, as
appropriate, to prevent skin contact.

Respiratory protection:
Use only in an adequately ventilated area. For unknown vapor concentrations use a positive-pressure,
pressure-demand, self-contained breathing apparatus (SCBA).

Hazardous Ingredient CAS ACGIH TLV ACGIH TLV OSHA OSHA PEL
Number (TWA) (STEL) PEL (STEL)
(TWA)
Aliphatic Petroleum Distillates 64742-89-8 N/AV N!AV N/AV N/AV

Dimethylsiloxane 63 148-62-9 N/AV N/AV N/AV N/AV

*Values are based on the 2014 Guide to Occupational Exposure Values by ACGIH

9 Information on Basic Physical and Chemical Properties


A; Safety Data Sheet (SDS)
Date PreparecllRevised: 9/10/2014 Version no.: 01 Supersedes: (-)

Appearance: Clear Odor: Hydrocarbon Odor


Odor Threshold: N/AV pH: Not Applicable (solvent Base)
Melting Point: N/AV Freezing Point: N/AV
Initial Boiling Point: N/AV Boiling Point Range: N/AV
Flash Point: 530 F (12° C) Evaporation Rate: Faster than n-Butyl
Acetate
Flammability SolidlGas: Flammable liquid Upper LEL: 1.1% Lower LEL: 9.5%
Vapor Pressure: N/AV Vapor Density: Heavier Than Air
Relative Density: N/AV Solubility: Negligible
Partition Coefficient: Autoignition Temperature: N/AV
n-octanol/ water: N/AV
Decomposition Temperature: N/AV Viscosity: N/AV
Explosive Properties: N/AV Oxidizing Properties: N/AV

10. Stability & Reactivity

Possibility of hazardous reactions: Hazardous polymerization will not occur under normal conditions
Chemical stability: Stable under normal conditions
Conditions to avoid: Heat and ignition sources
Incompatible materials: Strong Oxidizing Agents
Hazardous decomposition products: Will not occur

11 Toxicological Information I
Reports have associated repeated and prolonged overexposure to solvents with permanent brain and
nervous system damage. Repeated overexposure can also damage kidneys, lungs, liver, heart and blood

Routes of exposure: Eyes, skin, ingestion, and/or inhalation

Acute toxicological data: N/AV

Eye irritation data: N/AV

Skin irritationlsensitizationlabsorption data: N/AV


Reproductive toxicity data: N/AV

Mutagenicity data: N/AV

Symptoms associated with physical contact: N/AV

Acute/chronic effects from shortllong


term exposure: Irritating to skin. Prolonged/repeated contact may
4

$4 Safety Data Sheet (SDS)


Date PreparedlRevised: 9/10/20 14 Version no.: 01 Supersedes: (-)
C
cause defatting of the skin which can lead to
dermatitis. Not expected to be a skin sensitizer.

Known reportable carcinogens via the


following agencies:

NTP: N/AV
IARC: N/AV
OSHA: N/AV

* Petroleum distillates may contain chemical carcinogens in limited quantities (<0.01%). These quantities are determined

by the supplier/fraction/purity of the distillate during the manufacturing process. Chemicals that may be present within
distillates are listed on California’s prop 65 list such as ETHYLBENZENE, BENZENE, and TOLUENE.

12 Ecological Information

Ecotoxicity: No Data Available


Persistence and degradability: No Data Available
Bioaccumulative potential: No Data Available
0
Mobility in soil: No Data Available
Results of PBT and vPvB assessment: No Data Available
Other adverse effects: No Data Available

I 13 Disposal Considerations

Waste Disposal: Dispose of material in accordance with EU, national and local requirements.
For proper disposal of used material, an assessment must be completed to determine the proper
and permissible waste management options permitted under applicable rules, regulations andlor
laws governing your location.
Product I Packaging disposal: Dispose of packaging in accordance with federal, state and local
requirements, regulations andlor laws governing your location.

• 14. Transportation Information

US DOT
UN Proper Shipping Name Hazard Packing Marine Special
Number Class Group Pollutant Provisions
UN 1993 FLAMMABLE LIQUID, 3 PGII Not Reference 49
N.O.S. (LIGHT Applicable CFR 172.101
ALIPHATIC
PETROLEUM NAPHTHA)

I1VIDG
Safety Data Sheet (SDS)
Date Prepared/Revised: 9/10/20 14 Version no.: 01 Supersedes: (-)

UN Proper Shipping Name Hazard Packing Marine Special


Number Class Group Pollutant Provisions
IJN 1993 FLAMMABLE LIQUID, 3 PGII Not Reference
N.O.S. (LIGHT Applicable IMDG code
ALIPHATIC part 3
PETROLEUM NAPHTHA)

IATA:
UN Proper Shipping Name Hazard Packing Marine Special
Number Class Group Pollutant Provisions
UN 1993 FLAMMABLE LIQUID, 3 PGII Not Reference
N.O.S. (LIGHT Applicable IATA
ALIPHATIC Dangerous
PETROLEUM NAPHTHA) Goods
Regulation

15. Regulatory Information

Workplace classification:
This product is considered hazardous under the OSHA Hazard Communication Standard (29 CFR
1910.1200). The Occupational Safety and Health Administration’s interpretation of the product’s hazard
to workers.
SARA Title 3:
Section 311/312 Categorizations (40 CFR 372): This product is a hazardous chemical under 29 CFR
1910.1200, and is categorized as an immediate and delayed health, and flammability physical hazard.
Superfund Amendment and Reauthorization Act (SARA) category. SARA requires reporting any spill of
any hazardous substance.
TSCA status: All chemicals in this product are listed, or are exempt from listing, on the TSCA
Inventory.
WHMIS: This product has been classified in accordance with the hazard criteria of the Controlled
Products Regulations (CPR) and the (M)SDS contains all of the information required by the CPR.
PROP 65 (CA): WARNING: This product may contain chemicals know to the state of California to
cause cancer, birth defects or other reproductive harm.

16. Other Information

This SDS has been completed in accordance with GHS RevO4 (2011): U.S OSHA, CMA, ANSI,
Canadian WHMIS standards, and European Directives.

Date of Preparation/Revision: 9/10/2014


Supersedes: (-)

To the best of our knowledge, the information contained herein is believed to be accurate. However, the
above data does not imply any guarantee or warranty of any kind, expressed or implied. The final
determination of the suitability of any material is the sole responsibility of the user. All materials made
S

44ê Safety Data Sheet (SDS)


Date PreparedlRevised: 9/10/20 14 Version no.: 01 Supersedes: (-)

present un-known hazards and should be used with caution. Although certain hazards are described
herein, we cannot guarantee these are the only hazards existing.
SAFETY DATA SHEET
DE1615

Section 1. Identification
Product name : DUPLI-COLOR™ Engine Enamel with Ceramic
Aluminum
Product code : DE1615
Other means of : Not available.
identification
Product type : Aerosol.
Relevant identified uses of the substance or mixture and uses advised against
Not applicable.

Manufacturer : Dupli-Color Products Company


Cleveland, OH 44115

Emergency telephone : (216) 566-2917


number of the company
Product Information : (800) 247-3270
Telephone Number
Regulatory Information : (216) 566-2902
Telephone Number
Transportation Emergency : (800) 424-9300
Telephone Number

Section 2. Hazards identification


OSHA/HCS status : This material is considered hazardous by the OSHA Hazard Communication Standard
(29 CFR 1910.1200).
Classification of the : FLAMMABLE AEROSOLS - Category 1
substance or mixture GASES UNDER PRESSURE - Compressed gas
SKIN CORROSION/IRRITATION - Category 2
SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 2A
TOXIC TO REPRODUCTION (Unborn child) - Category 1B
TOXIC TO REPRODUCTION (Fertility) - Category 2
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Respiratory tract
irritation) - Category 3
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Narcotic effects) -
Category 3
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) - Category 2
ASPIRATION HAZARD - Category 1
Percentage of the mixture consisting of ingredient(s) of unknown toxicity: 11.6%
GHS label elements
Hazard pictograms :

Signal word : Danger

Date of issue/Date of revision : 5/28/2016 Date of previous issue : 3/27/2016 Version : 2.01 1/16
Section 2. Hazards identification
Hazard statements : Extremely flammable aerosol.
Contains gas under pressure; may explode if heated.
Causes serious eye irritation.
Causes skin irritation.
May damage the unborn child.
Suspected of damaging fertility.
May be fatal if swallowed and enters airways.
May cause respiratory irritation.
May cause drowsiness or dizziness.
May cause damage to organs through prolonged or repeated exposure.
Precautionary statements
General : Read label before use. Keep out of reach of children. If medical advice is needed, have
product container or label at hand.
Prevention : Obtain special instructions before use. Do not handle until all safety precautions have
been read and understood. Wear protective gloves. Wear eye or face protection.
Wear protective clothing. Keep away from heat, hot surfaces, sparks, open flames and
other ignition sources. No smoking. Do not spray on an open flame or other ignition
source. Use only outdoors or in a well-ventilated area. Do not breathe dust or mist.
Wash hands thoroughly after handling. Pressurized container: Do not pierce or burn,
even after use.
Response : Get medical attention if you feel unwell. IF exposed or concerned: Get medical
attention. IF INHALED: Remove person to fresh air and keep comfortable for breathing.
Call a POISON CENTER or physician if you feel unwell. IF SWALLOWED:
Immediately call a POISON CENTER or physician. Do NOT induce vomiting. IF ON
SKIN: Wash with plenty of soap and water. Take off contaminated clothing and wash it
before reuse. If skin irritation occurs: Get medical attention. IF IN EYES: Rinse
cautiously with water for several minutes. Remove contact lenses, if present and easy
to do. Continue rinsing. If eye irritation persists: Get medical attention.
Storage : Store locked up. Protect from sunlight. Do not expose to temperatures exceeding 50
°C/122 °F. Store in a well-ventilated place.
Disposal Dispose of contents and container in accordance with all local, regional, national and
international regulations.
Supplemental label DANGER: Rags, steel wool, other waste soaked with this product, and sanding residue
elements may spontaneously catch fire if improperly discarded. Immediately place rags, steel
wool, other waste soaked with this product, and sanding residue in a sealed, water-filled,
metal container. Dispose of in accordance with local fire regulations. DELAYED
EFFECTS FROM LONG TERM OVEREXPOSURE. Contains solvents which can cause
permanent brain and nervous system damage. Intentional misuse by deliberately
concentrating and inhaling the contents can be harmful or fatal. WARNING: This
product contains chemicals known to the State of California to cause cancer and birth
defects or other reproductive harm.
Please refer to the SDS for additional information. Keep upright in a cool, dry place. Do
not discard empty can in trash compactor.
Hazards not otherwise : None known.
classified

Section 3. Composition/information on ingredients


Substance/mixture : Mixture
Other means of : Not available.
identification
CAS number/other identifiers

Date of issue/Date of revision : 5/28/2016 Date of previous issue : 3/27/2016 Version : 2.01 2/16
Section 3. Composition/information on ingredients
Ingredient name % by weight CAS number
Acetone ≥25 - ≤50 67-64-1
Methyl Ethyl Ketone ≥10 - ≤25 78-93-3
Propane ≥10 - ≤25 74-98-6
Butane ≤10 106-97-8
Ethanol ≤3 64-17-5
2-Propanol ≤3 67-63-0
Butyl Benzyl Phthalate <1 85-68-7
Toluene <1 108-88-3
Any concentration shown as a range is to protect confidentiality or is due to batch variation.
There are no additional ingredients present which, within the current knowledge of the supplier and in the
concentrations applicable, are classified as hazardous to health and hence require reporting in this section.

Occupational exposure limits, if available, are listed in Section 8.

Section 4. First aid measures


Description of necessary first aid measures
Eye contact : Immediately flush eyes with plenty of water, occasionally lifting the upper and lower
eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10
minutes. Get medical attention.
Inhalation : Remove victim to fresh air and keep at rest in a position comfortable for breathing. If it
is suspected that fumes are still present, the rescuer should wear an appropriate mask
or self-contained breathing apparatus. If not breathing, if breathing is irregular or if
respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It
may be dangerous to the person providing aid to give mouth-to-mouth resuscitation.
Get medical attention. If necessary, call a poison center or physician. If unconscious,
place in recovery position and get medical attention immediately. Maintain an open
airway. Loosen tight clothing such as a collar, tie, belt or waistband. In case of
inhalation of decomposition products in a fire, symptoms may be delayed. The exposed
person may need to be kept under medical surveillance for 48 hours.
Skin contact : Flush contaminated skin with plenty of water. Remove contaminated clothing and
shoes. Wash contaminated clothing thoroughly with water before removing it, or wear
gloves. Continue to rinse for at least 10 minutes. Get medical attention. Wash clothing
before reuse. Clean shoes thoroughly before reuse.
Ingestion : Get medical attention immediately. Call a poison center or physician. Wash out mouth
with water. Remove dentures if any. Remove victim to fresh air and keep at rest in a
position comfortable for breathing. If material has been swallowed and the exposed
person is conscious, give small quantities of water to drink. Stop if the exposed person
feels sick as vomiting may be dangerous. Aspiration hazard if swallowed. Can enter
lungs and cause damage. Do not induce vomiting. If vomiting occurs, the head should
be kept low so that vomit does not enter the lungs. Never give anything by mouth to an
unconscious person. If unconscious, place in recovery position and get medical
attention immediately. Maintain an open airway. Loosen tight clothing such as a collar,
tie, belt or waistband.

Most important symptoms/effects, acute and delayed


Potential acute health effects
Eye contact : Causes serious eye irritation.
Inhalation : Can cause central nervous system (CNS) depression. May cause drowsiness or
dizziness. May cause respiratory irritation.
Skin contact : Causes skin irritation.
Ingestion : Can cause central nervous system (CNS) depression. May be fatal if swallowed and
enters airways.
Over-exposure signs/symptoms

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Section 4. First aid measures
Eye contact : Adverse symptoms may include the following:
pain or irritation
watering
redness
Inhalation : Adverse symptoms may include the following:
respiratory tract irritation
coughing
nausea or vomiting
headache
drowsiness/fatigue
dizziness/vertigo
unconsciousness
reduced fetal weight
increase in fetal deaths
skeletal malformations
Skin contact : Adverse symptoms may include the following:
irritation
redness
reduced fetal weight
increase in fetal deaths
skeletal malformations
Ingestion : Adverse symptoms may include the following:
nausea or vomiting
reduced fetal weight
increase in fetal deaths
skeletal malformations

Indication of immediate medical attention and special treatment needed, if necessary


Notes to physician : In case of inhalation of decomposition products in a fire, symptoms may be delayed.
The exposed person may need to be kept under medical surveillance for 48 hours.
Specific treatments : No specific treatment.
Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. If it is
suspected that fumes are still present, the rescuer should wear an appropriate mask or
self-contained breathing apparatus. It may be dangerous to the person providing aid to
give mouth-to-mouth resuscitation. Wash contaminated clothing thoroughly with water
before removing it, or wear gloves.

See toxicological information (Section 11)

Section 5. Fire-fighting measures


Extinguishing media
Suitable extinguishing : Use an extinguishing agent suitable for the surrounding fire.
media
Unsuitable extinguishing : None known.
media

Specific hazards arising : Extremely flammable aerosol. In a fire or if heated, a pressure increase will occur and
from the chemical the container may burst, with the risk of a subsequent explosion. Gas may accumulate
in low or confined areas or travel a considerable distance to a source of ignition and
flash back, causing fire or explosion. Bursting aerosol containers may be propelled from
a fire at high speed. Runoff to sewer may create fire or explosion hazard.
Hazardous thermal : Decomposition products may include the following materials:
decomposition products carbon dioxide
carbon monoxide
nitrogen oxides
metal oxide/oxides
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Section 5. Fire-fighting measures
Special protective actions : Promptly isolate the scene by removing all persons from the vicinity of the incident if
for fire-fighters there is a fire. No action shall be taken involving any personal risk or without suitable
training. Move containers from fire area if this can be done without risk. Use water
spray to keep fire-exposed containers cool.
Special protective : Fire-fighters should wear appropriate protective equipment and self-contained breathing
equipment for fire-fighters apparatus (SCBA) with a full face-piece operated in positive pressure mode.

Section 6. Accidental release measures


Personal precautions, protective equipment and emergency procedures
For non-emergency : No action shall be taken involving any personal risk or without suitable training.
personnel Evacuate surrounding areas. Keep unnecessary and unprotected personnel from
entering. In the case of aerosols being ruptured, care should be taken due to the rapid
escape of the pressurized contents and propellant. If a large number of containers are
ruptured, treat as a bulk material spillage according to the instructions in the clean-up
section. Do not touch or walk through spilled material. Shut off all ignition sources. No
flares, smoking or flames in hazard area. Avoid breathing vapor or mist. Provide
adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put
on appropriate personal protective equipment.
For emergency responders : If specialized clothing is required to deal with the spillage, take note of any information in
Section 8 on suitable and unsuitable materials. See also the information in "For non-
emergency personnel".

Environmental precautions : Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains
and sewers. Inform the relevant authorities if the product has caused environmental
pollution (sewers, waterways, soil or air).

Methods and materials for containment and cleaning up


Small spill : Stop leak if without risk. Move containers from spill area. Use spark-proof tools and
explosion-proof equipment. Dilute with water and mop up if water-soluble. Alternatively,
or if water-insoluble, absorb with an inert dry material and place in an appropriate waste
disposal container. Dispose of via a licensed waste disposal contractor.
Large spill : Stop leak if without risk. Move containers from spill area. Use spark-proof tools and
explosion-proof equipment. Approach release from upwind. Prevent entry into sewers,
water courses, basements or confined areas. Wash spillages into an effluent treatment
plant or proceed as follows. Contain and collect spillage with non-combustible,
absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in
container for disposal according to local regulations (see Section 13). Dispose of via a
licensed waste disposal contractor. Contaminated absorbent material may pose the
same hazard as the spilled product. Note: see Section 1 for emergency contact
information and Section 13 for waste disposal.

Section 7. Handling and storage


Precautions for safe handling
Protective measures : Put on appropriate personal protective equipment (see Section 8). Pressurized
container: protect from sunlight and do not expose to temperatures exceeding 50°C. Do
not pierce or burn, even after use. Avoid exposure - obtain special instructions before
use. Avoid exposure during pregnancy. Do not handle until all safety precautions have
been read and understood. Do not get in eyes or on skin or clothing. Do not breathe
vapor or mist. Do not swallow. Avoid breathing gas. Use only with adequate ventilation.
Wear appropriate respirator when ventilation is inadequate. Store and use away from
heat, sparks, open flame or any other ignition source. Use explosion-proof electrical
(ventilating, lighting and material handling) equipment. Use only non-sparking tools.
Empty containers retain product residue and can be hazardous.

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Section 7. Handling and storage
Advice on general : Eating, drinking and smoking should be prohibited in areas where this material is
occupational hygiene handled, stored and processed. Workers should wash hands and face before eating,
drinking and smoking. Remove contaminated clothing and protective equipment before
entering eating areas. See also Section 8 for additional information on hygiene
measures.

Conditions for safe storage, : Store in accordance with local regulations. Store away from direct sunlight in a dry, cool
including any and well-ventilated area, away from incompatible materials (see Section 10) and food
incompatibilities and drink. Protect from sunlight. Store locked up. Eliminate all ignition sources. Use
appropriate containment to avoid environmental contamination.

Section 8. Exposure controls/personal protection


Control parameters
Occupational exposure limits
Ingredient name Exposure limits
Acetone ACGIH TLV (United States, 3/2015).
TWA: 250 ppm 8 hours.
STEL: 500 ppm 15 minutes.
NIOSH REL (United States, 10/2013).
TWA: 250 ppm 10 hours.
TWA: 590 mg/m³ 10 hours.
OSHA PEL (United States, 2/2013).
TWA: 1000 ppm 8 hours.
TWA: 2400 mg/m³ 8 hours.
Methyl Ethyl Ketone ACGIH TLV (United States, 3/2015).
TWA: 200 ppm 8 hours.
TWA: 590 mg/m³ 8 hours.
STEL: 300 ppm 15 minutes.
STEL: 885 mg/m³ 15 minutes.
NIOSH REL (United States, 10/2013).
TWA: 200 ppm 10 hours.
TWA: 590 mg/m³ 10 hours.
STEL: 300 ppm 15 minutes.
STEL: 885 mg/m³ 15 minutes.
OSHA PEL (United States, 2/2013).
TWA: 200 ppm 8 hours.
TWA: 590 mg/m³ 8 hours.
Propane NIOSH REL (United States, 10/2013).
TWA: 1000 ppm 10 hours.
TWA: 1800 mg/m³ 10 hours.
OSHA PEL (United States, 2/2013).
TWA: 1000 ppm 8 hours.
TWA: 1800 mg/m³ 8 hours.
Butane NIOSH REL (United States, 10/2013).
TWA: 800 ppm 10 hours.
TWA: 1900 mg/m³ 10 hours.
ACGIH TLV (United States, 3/2015).
STEL: 1000 ppm 15 minutes.
Ethanol ACGIH TLV (United States, 3/2015).
STEL: 1000 ppm 15 minutes.
NIOSH REL (United States, 10/2013).
TWA: 1000 ppm 10 hours.
TWA: 1900 mg/m³ 10 hours.
OSHA PEL (United States, 2/2013).
TWA: 1000 ppm 8 hours.
TWA: 1900 mg/m³ 8 hours.

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Section 8. Exposure controls/personal protection
2-Propanol ACGIH TLV (United States, 3/2015).
TWA: 200 ppm 8 hours.
STEL: 400 ppm 15 minutes.
NIOSH REL (United States, 10/2013).
TWA: 400 ppm 10 hours.
TWA: 980 mg/m³ 10 hours.
STEL: 500 ppm 15 minutes.
STEL: 1225 mg/m³ 15 minutes.
OSHA PEL (United States, 2/2013).
TWA: 400 ppm 8 hours.
TWA: 980 mg/m³ 8 hours.
Butyl Benzyl Phthalate None.
Toluene OSHA PEL Z2 (United States, 2/2013).
TWA: 200 ppm 8 hours.
CEIL: 300 ppm
AMP: 500 ppm 10 minutes.
NIOSH REL (United States, 10/2013).
TWA: 100 ppm 10 hours.
TWA: 375 mg/m³ 10 hours.
STEL: 150 ppm 15 minutes.
STEL: 560 mg/m³ 15 minutes.
ACGIH TLV (United States, 3/2015).
TWA: 20 ppm 8 hours.

Appropriate engineering : Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or
controls other engineering controls to keep worker exposure to airborne contaminants below any
recommended or statutory limits. The engineering controls also need to keep gas,
vapor or dust concentrations below any lower explosive limits. Use explosion-proof
ventilation equipment.
Environmental exposure : Emissions from ventilation or work process equipment should be checked to ensure
controls they comply with the requirements of environmental protection legislation. In some
cases, fume scrubbers, filters or engineering modifications to the process equipment
will be necessary to reduce emissions to acceptable levels.

Individual protection measures


Hygiene measures : Wash hands, forearms and face thoroughly after handling chemical products, before
eating, smoking and using the lavatory and at the end of the working period.
Appropriate techniques should be used to remove potentially contaminated clothing.
Wash contaminated clothing before reusing. Ensure that eyewash stations and safety
showers are close to the workstation location.
Eye/face protection : Safety eyewear complying with an approved standard should be used when a risk
assessment indicates this is necessary to avoid exposure to liquid splashes, mists,
gases or dusts. If contact is possible, the following protection should be worn, unless
the assessment indicates a higher degree of protection: chemical splash goggles.
Skin protection
Hand protection : Chemical-resistant, impervious gloves complying with an approved standard should be
worn at all times when handling chemical products if a risk assessment indicates this is
necessary. Considering the parameters specified by the glove manufacturer, check
during use that the gloves are still retaining their protective properties. It should be
noted that the time to breakthrough for any glove material may be different for different
glove manufacturers. In the case of mixtures, consisting of several substances, the
protection time of the gloves cannot be accurately estimated.
Body protection : Personal protective equipment for the body should be selected based on the task being
performed and the risks involved and should be approved by a specialist before
handling this product. When there is a risk of ignition from static electricity, wear anti-
static protective clothing. For the greatest protection from static discharges, clothing
should include anti-static overalls, boots and gloves.
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Section 8. Exposure controls/personal protection
Other skin protection : Appropriate footwear and any additional skin protection measures should be selected
based on the task being performed and the risks involved and should be approved by a
specialist before handling this product.
Respiratory protection : Based on the hazard and potential for exposure, select a respirator that meets the
appropriate standard or certification. Respirators must be used according to a
respiratory protection program to ensure proper fitting, training, and other important
aspects of use.

Section 9. Physical and chemical properties


Appearance
Physical state : Liquid.
Color : Not available.
Odor : Not available.
Odor threshold : Not available.
pH : Not available.
Melting point : Not available.
Boiling point : Not available.
Flash point : Closed cup: -29°C (-20.2°F) [Pensky-Martens Closed Cup]
Evaporation rate : 5.6 (butyl acetate = 1)
Flammability (solid, gas) : Not available.
Lower and upper explosive : Lower: 1.05%
(flammable) limits Upper: 19%
Vapor pressure : 13.5 kPa (101.325 mm Hg) [at 20°C]
Vapor density : 1.5 [Air = 1]
Relative density : 0.76
Solubility : Not available.
Partition coefficient: n- : Not available.
octanol/water
Auto-ignition temperature : Not available.
Decomposition temperature : Not available.
Viscosity : Kinematic (room temperature): <0.205 cm2/s (<20.5 cSt)
Kinematic (40°C (104°F)): <0.205 cm2/s (<20.5 cSt)
Molecular weight : Not applicable.
Aerosol product
Type of aerosol : Spray
Heat of combustion : 29.26 kJ/g

Section 10. Stability and reactivity


Reactivity : No specific test data related to reactivity available for this product or its ingredients.

Chemical stability : The product is stable.

Possibility of hazardous : Under normal conditions of storage and use, hazardous reactions will not occur.
reactions

Conditions to avoid : Avoid all possible sources of ignition (spark or flame).

Incompatible materials : No specific data.

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Section 10. Stability and reactivity
Hazardous decomposition : Under normal conditions of storage and use, hazardous decomposition products should
products not be produced.

Section 11. Toxicological information


Information on toxicological effects
Acute toxicity
Product/ingredient name Result Species Dose Exposure
Acetone LD50 Oral Rat 5800 mg/kg -
Methyl Ethyl Ketone LD50 Dermal Rabbit 6480 mg/kg -
LD50 Oral Rat 2737 mg/kg -
Butane LC50 Inhalation Vapor Rat 658000 mg/m³ 4 hours
Ethanol LC50 Inhalation Vapor Rat 124700 mg/m³ 4 hours
LD50 Oral Rat 7 g/kg -
2-Propanol LD50 Dermal Rabbit 12800 mg/kg -
LD50 Oral Rat 5000 mg/kg -
Butyl Benzyl Phthalate LD50 Dermal Rabbit >10000 mg/kg -
LD50 Dermal Rat 6700 mg/kg -
LD50 Oral Rat 2330 mg/kg -
Toluene LC50 Inhalation Vapor Rat 49 g/m³ 4 hours
LD50 Oral Rat 636 mg/kg -
Irritation/Corrosion
Product/ingredient name Result Species Score Exposure Observation
Acetone Eyes - Mild irritant Human - 186300 parts -
per million
Eyes - Mild irritant Rabbit - 10 microliters -
Eyes - Moderate irritant Rabbit - 24 hours 20 -
milligrams
Eyes - Severe irritant Rabbit - 20 milligrams -
Skin - Mild irritant Rabbit - 24 hours 500 -
milligrams
Skin - Mild irritant Rabbit - 395 -
milligrams
Methyl Ethyl Ketone Skin - Mild irritant Rabbit - 24 hours 14 -
milligrams
Skin - Moderate irritant Rabbit - 24 hours 500 -
milligrams
Ethanol Eyes - Mild irritant Rabbit - 24 hours 500 -
milligrams
Eyes - Moderate irritant Rabbit - 0.066666667 -
minutes 100
milligrams
Eyes - Moderate irritant Rabbit - 100 -
microliters
Eyes - Severe irritant Rabbit - 500 -
milligrams
Skin - Mild irritant Rabbit - 400 -
milligrams
Skin - Moderate irritant Rabbit - 24 hours 20 -
milligrams
2-Propanol Eyes - Moderate irritant Rabbit - 24 hours 100 -
milligrams
Eyes - Moderate irritant Rabbit - 10 milligrams -
Eyes - Severe irritant Rabbit - 100 -
milligrams
Skin - Mild irritant Rabbit - 500 -
milligrams
Toluene Eyes - Mild irritant Rabbit - 0.5 minutes -

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Section 11. Toxicological information
100
milligrams
Eyes - Mild irritant Rabbit - 870 -
Micrograms
Eyes - Severe irritant Rabbit - 24 hours 2 -
milligrams
Skin - Mild irritant Pig - 24 hours 250 -
microliters
Skin - Mild irritant Rabbit - 435 -
milligrams
Skin - Moderate irritant Rabbit - 24 hours 20 -
milligrams
Skin - Moderate irritant Rabbit - 500 -
milligrams
Sensitization
Not available.

Mutagenicity
Not available.
Carcinogenicity
Not available.
Classification
Product/ingredient name OSHA IARC NTP
Ethanol - 1 -
2-Propanol - 3 -
Butyl Benzyl Phthalate - 3 -
Toluene - 3 -
Reproductive toxicity
Not available.
Teratogenicity
Not available.
Specific target organ toxicity (single exposure)
Name Category Route of Target organs
exposure
Acetone Category 3 Not applicable. Respiratory tract
irritation and
Narcotic effects
Methyl Ethyl Ketone Category 3 Not applicable. Respiratory tract
irritation and
Narcotic effects
Propane Category 3 Not applicable. Respiratory tract
irritation and
Narcotic effects
Butane Category 3 Not applicable. Respiratory tract
irritation and
Narcotic effects
Ethanol Category 3 Not applicable. Respiratory tract
irritation and
Narcotic effects
2-Propanol Category 3 Not applicable. Respiratory tract
irritation and
Narcotic effects
Toluene Category 3 Not applicable. Respiratory tract
irritation and
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Section 11. Toxicological information
Narcotic effects
Specific target organ toxicity (repeated exposure)
Name Category Route of Target organs
exposure
Acetone Category 2 Not determined Not determined
Methyl Ethyl Ketone Category 2 Not determined Not determined
Propane Category 2 Not determined Not determined
Butane Category 2 Not determined Not determined
Ethanol Category 2 Not determined Not determined
2-Propanol Category 2 Not determined Not determined
Toluene Category 2 Not determined Not determined
Aspiration hazard
Name Result
Propane ASPIRATION HAZARD - Category 1
Butane ASPIRATION HAZARD - Category 1
Toluene ASPIRATION HAZARD - Category 1

Information on the likely : Not available.


routes of exposure
Potential acute health effects
Eye contact : Causes serious eye irritation.
Inhalation : Can cause central nervous system (CNS) depression. May cause drowsiness or
dizziness. May cause respiratory irritation.
Skin contact : Causes skin irritation.
Ingestion : Can cause central nervous system (CNS) depression. May be fatal if swallowed and
enters airways.

Symptoms related to the physical, chemical and toxicological characteristics


Eye contact : Adverse symptoms may include the following:
pain or irritation
watering
redness
Inhalation : Adverse symptoms may include the following:
respiratory tract irritation
coughing
nausea or vomiting
headache
drowsiness/fatigue
dizziness/vertigo
unconsciousness
reduced fetal weight
increase in fetal deaths
skeletal malformations
Skin contact : Adverse symptoms may include the following:
irritation
redness
reduced fetal weight
increase in fetal deaths
skeletal malformations

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Ingestion : Adverse symptoms may include the following:
nausea or vomiting
reduced fetal weight
increase in fetal deaths
skeletal malformations

Delayed and immediate effects and also chronic effects from short and long term exposure
Short term exposure
Potential immediate : Not available.
effects
Potential delayed effects : Not available.
Long term exposure
Potential immediate : Not available.
effects
Potential delayed effects : Not available.
Potential chronic health effects
Not available.
General : May cause damage to organs through prolonged or repeated exposure.
Carcinogenicity : No known significant effects or critical hazards.
Mutagenicity : No known significant effects or critical hazards.
Teratogenicity : May damage the unborn child.
Developmental effects : No known significant effects or critical hazards.
Fertility effects : Suspected of damaging fertility.

Numerical measures of toxicity


Acute toxicity estimates
Route ATE value
Oral 10245.4 mg/kg

Section 12. Ecological information


Toxicity
Product/ingredient name Result Species Exposure
Acetone Acute EC50 7200000 µg/l Fresh water Algae - Selenastrum sp. 96 hours
Acute LC50 6000000 µg/l Fresh water Crustaceans - Gammarus pulex 48 hours
Acute LC50 6900 mg/l Fresh water Daphnia - Daphnia magna 48 hours
Acute LC50 5600 ppm Fresh water Fish - Poecilia reticulata 96 hours
Chronic NOEC 4.95 mg/l Marine water Algae - Ulva pertusa 96 hours
Chronic NOEC 0.016 ml/L Fresh water Crustaceans - Daphniidae 21 days
Chronic NOEC 0.1 ml/L Fresh water Daphnia - Daphnia magna - 21 days
Neonate
Methyl Ethyl Ketone Acute EC50 >500000 µg/l Marine water Algae - Skeletonema costatum 96 hours
Acute EC50 5091000 µg/l Fresh water Daphnia - Daphnia magna - 48 hours
Larvae
Acute LC50 3220000 µg/l Fresh water Fish - Pimephales promelas 96 hours
Ethanol Acute EC50 17.921 mg/l Marine water Algae - Ulva pertusa 96 hours
Acute EC50 2000 µg/l Fresh water Daphnia - Daphnia magna 48 hours
Acute LC50 25500 µg/l Marine water Crustaceans - Artemia 48 hours
franciscana - Larvae
Acute LC50 42000 µg/l Fresh water Fish - Oncorhynchus mykiss 4 days
Chronic NOEC 4.995 mg/l Marine water Algae - Ulva pertusa 96 hours
Chronic NOEC 100 ul/L Fresh water Daphnia - Daphnia magna - 21 days

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Section 12. Ecological information
Neonate
Chronic NOEC 0.375 ul/L Fresh water Fish - Gambusia holbrooki - 12 weeks
Larvae
2-Propanol Acute LC50 1400000 µg/l Marine water Crustaceans - Crangon crangon 48 hours
Acute LC50 4200 mg/l Fresh water Fish - Rasbora heteromorpha 96 hours
Butyl Benzyl Phthalate Acute EC50 0.22 ppm Marine water Algae - Skeletonema costatum 72 hours
Acute EC50 100 µg/l Fresh water Algae - Pseudokirchneriella 96 hours
subcapitata
Acute EC50 1000 µg/l Fresh water Daphnia - Daphnia magna 48 hours
Acute LC50 3.69 mg/l Fresh water Crustaceans - Moina macrocopa - 48 hours
New born
Acute LC50 510 µg/l Marine water Fish - Cymatogaster aggregata - 96 hours
Juvenile (Fledgling, Hatchling,
Weanling)
Chronic NOEC 0.26 mg/l Fresh water Daphnia - Daphnia magna 21 days
Toluene Acute EC50 12500 µg/l Fresh water Algae - Pseudokirchneriella 72 hours
subcapitata
Acute EC50 11600 µg/l Fresh water Crustaceans - Gammarus 48 hours
pseudolimnaeus - Adult
Acute EC50 6000 µg/l Fresh water Daphnia - Daphnia magna - 48 hours
Juvenile (Fledgling, Hatchling,
Weanling)
Acute LC50 5500 µg/l Fresh water Fish - Oncorhynchus kisutch - Fry 96 hours
Chronic NOEC 1000 µg/l Fresh water Daphnia - Daphnia magna 21 days

Persistence and degradability


Product/ingredient name Aquatic half-life Photolysis Biodegradability
Acetone - - Readily
Methyl Ethyl Ketone - - Readily
Ethanol - - Readily
2-Propanol - - Readily
Toluene - - Readily

Bioaccumulative potential
Product/ingredient name LogPow BCF Potential
Butyl Benzyl Phthalate - 1693.25 high
Toluene - 90 low

Mobility in soil
Soil/water partition : Not available.
coefficient (KOC)

Other adverse effects : No known significant effects or critical hazards.

Section 13. Disposal considerations


Disposal methods : The generation of waste should be avoided or minimized wherever possible. Disposal
of this product, solutions and any by-products should at all times comply with the
requirements of environmental protection and waste disposal legislation and any
regional local authority requirements. Dispose of surplus and non-recyclable products
via a licensed waste disposal contractor. Waste should not be disposed of untreated to
the sewer unless fully compliant with the requirements of all authorities with jurisdiction.
Waste packaging should be recycled. Incineration or landfill should only be considered
when recycling is not feasible. This material and its container must be disposed of in a
safe way. Empty containers or liners may retain some product residues. Do not
puncture or incinerate container.
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Section 14. Transport information
DOT TDG Mexico IATA IMDG
Classification Classification Classification
UN number UN1950 UN1950 UN1950 UN1950 UN1950

UN proper AEROSOLS AEROSOLS AEROSOLS AEROSOLS, AEROSOLS


shipping name flammable
Transport 2.1 2.1 2.1 2.1 2.1
hazard class(es)

Packing group - - - - -
Environmental No. No. No. No. No.
hazards
Additional Special Product classified Special Special Emergency
information provisions as per the provisions provisions schedules (EmS)
LIMITED following sections Not Applicable LIMITED F-D, S-U
QUANTITY of the QUANTITY
Transportation of Special
Dangerous Goods provisions
Regulations: 2. LIMITED
13-2.17 (Class 2). QUANTITY

Special
provisions
LIMITED
QUANTITY
ERG No. ERG No. ERG No.
126 126 126

Special precautions for user : Multi-modal shipping descriptions are provided for informational purposes and do not
consider container sizes. The presence of a shipping description for a particular
mode of transport (sea, air, etc.), does not indicate that the product is packaged
suitably for that mode of transport. All packaging must be reviewed for suitability
prior to shipment, and compliance with the applicable regulations is the sole
responsibility of the person offering the product for transport. People loading and
unloading dangerous goods must be trained on all of the risks deriving from the
substances and on all actions in case of emergency situations.

Transport in bulk according : Not available.


to Annex II of MARPOL and
the IBC Code
Proper shipping name : Not available.
Ship type : Not available.
Pollution category : Not available.

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Section 15. Regulatory information
SARA 313
SARA 313 (40 CFR 372.45) supplier notification can be found on the Environmental Data Sheet.
California Prop. 65
WARNING: This product contains chemicals known to the State of California to cause cancer and birth defects or other
reproductive harm.

Section 16. Other information


Hazardous Material Information System (U.S.A.)
Health 2

Flammability 3

Physical hazards 1

The customer is responsible for determining the PPE code for this material.

Caution: HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4
representing significant hazards or risks Although HMIS® ratings are not required on SDSs under 29 CFR 1910.
1200, the preparer may choose to provide them. HMIS® ratings are to be used with a fully implemented HMIS®
program. HMIS® is a registered mark of the National Paint & Coatings Association (NPCA). HMIS® materials may
be purchased exclusively from J. J. Keller (800) 327-6868.
Procedure used to derive the classification
Classification Justification
FLAMMABLE AEROSOLS - Category 1 On basis of test data
GASES UNDER PRESSURE - Compressed gas Calculation method
SKIN CORROSION/IRRITATION - Category 2 Calculation method
SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 2A Calculation method
TOXIC TO REPRODUCTION (Unborn child) - Category 1B Calculation method
TOXIC TO REPRODUCTION (Fertility) - Category 2 Calculation method
SPECIFIC TARGET ORGAN TOXICITY (SINGLE Calculation method
EXPOSURE) (Respiratory tract irritation) - Category 3
SPECIFIC TARGET ORGAN TOXICITY (SINGLE Calculation method
EXPOSURE) (Narcotic effects) - Category 3
SPECIFIC TARGET ORGAN TOXICITY (REPEATED Calculation method
EXPOSURE) - Category 2
ASPIRATION HAZARD - Category 1 Calculation method

History
Date of printing : 5/28/2016
Date of issue/Date of : 5/28/2016
revision
Date of previous issue : 3/27/2016
Version : 2.01
Key to abbreviations : ATE = Acute Toxicity Estimate
BCF = Bioconcentration Factor
GHS = Globally Harmonized System of Classification and Labelling of Chemicals
IATA = International Air Transport Association
IBC = Intermediate Bulk Container
IMDG = International Maritime Dangerous Goods
LogPow = logarithm of the octanol/water partition coefficient
MARPOL = International Convention for the Prevention of Pollution From Ships, 1973
as modified by the Protocol of 1978. ("Marpol" = marine pollution)
UN = United Nations
Notice to reader

Date of issue/Date of revision : 5/28/2016 Date of previous issue : 3/27/2016 Version : 2.01 15/16
Section 16. Other information
It is recommended that each customer or recipient of this Safety Data Sheet (SDS) study it carefully and consult
resources, as necessary or appropriate, to become aware of and understand the data contained in this SDS and
any hazards associated with the product. This information is provided in good faith and believed to be accurate
as of the effective date herein. However, no warranty, express or implied, is given. The information presented
here applies only to the product as shipped. The addition of any material can change the composition, hazards
and risks of the product. Products shall not be repackaged, modified, or tinted except as specifically instructed
by Sherwin-Williams, including but not limited to the incorporation of non Sherwin-Williams products or the use
or addition of products in proportions not specified by Sherwin-Williams. Regulatory requirements are subject
to change and may differ between various locations and jurisdictions. The customer/buyer/user is responsible to
ensure that his activities comply with all country, federal, state, provincial or local laws. The conditions for use
of the product are not under the control of the manufacturer; the customer/buyer/user is responsible to
determine the conditions necessary for the safe use of this product. The customer/buyer/user should not use the
product for any purpose other than the purpose shown in the applicable section of this SDS without first
referring to the supplier and obtaining written handling instructions. Due to the proliferation of sources for
information such as manufacturer-specific SDS, the manufacturer cannot be responsible for SDSs obtained from
any other source.

Date of issue/Date of revision : 5/28/2016 Date of previous issue : 3/27/2016 Version : 2.01 16/16
SAFETY DATA SHEET
DAL1607

Section 1. Identification
Product name : DUPLI-COLOR® Acrylic Lacquer Aerosol Paint
Flat Black
Product code : DAL1607
Other means of : Not available.
identification
Product type : Aerosol.
Relevant identified uses of the substance or mixture and uses advised against
Not applicable.

Manufacturer : THE SHERWIN-WILLIAMS CO.


DUPLI-COLOR Products Group
Cleveland, OH 44115

Emergency telephone : (216) 566-2917


number of the company
Product Information : (800) 247-3270
Telephone Number
Regulatory Information : (216) 566-2902
Telephone Number
Transportation Emergency : (800) 424-9300
Telephone Number

Section 2. Hazards identification


OSHA/HCS status : This material is considered hazardous by the OSHA Hazard Communication Standard
(29 CFR 1910.1200).
Classification of the : FLAMMABLE AEROSOLS - Category 1
substance or mixture GASES UNDER PRESSURE - Compressed gas
SKIN CORROSION/IRRITATION - Category 2
SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 2A
CARCINOGENICITY - Category 1A
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Respiratory tract
irritation and Narcotic effects) - Category 3
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) - Category 2
ASPIRATION HAZARD - Category 1
Percentage of the mixture consisting of ingredient(s) of unknown toxicity: 11.8%
GHS label elements
Hazard pictograms :

Signal word : Danger

Date of issue/Date of revision : 4/21/2015. Date of previous issue : No previous validation. Version :1 1/15
Section 2. Hazards identification
Hazard statements : Extremely flammable aerosol.
Contains gas under pressure; may explode if heated.
Causes serious eye irritation.
Causes skin irritation.
May cause cancer.
May be fatal if swallowed and enters airways.
May cause respiratory irritation.
May cause drowsiness and dizziness.
May cause damage to organs through prolonged or repeated exposure.
Precautionary statements
General : Read label before use. Keep out of reach of children. If medical advice is needed, have
product container or label at hand.
Prevention : Obtain special instructions before use. Do not handle until all safety precautions have
been read and understood. Use personal protective equipment as required. Wear
protective gloves. Wear eye or face protection. Keep away from heat, hot surfaces,
sparks, open flames and other ignition sources. No smoking. Pressurized container: Do
not pierce or burn, even after use. Do not spray on an open flame or other ignition
source. Use only outdoors or in a well-ventilated area. Do not breathe dust or mist.
Wash hands thoroughly after handling.
Response : Get medical attention if you feel unwell. IF exposed or concerned: Get medical
attention. IF INHALED: Remove victim to fresh air and keep at rest in a position
comfortable for breathing. Call a POISON CENTER or physician if you feel unwell. IF
SWALLOWED: Immediately call a POISON CENTER or physician. Do NOT induce
vomiting. IF ON SKIN: Wash with plenty of soap and water. Take off contaminated
clothing. Wash contaminated clothing before reuse. If skin irritation occurs: Get
medical attention. IF IN EYES: Rinse cautiously with water for several minutes.
Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation
persists: Get medical attention.
Storage : Store locked up. Protect from sunlight. Do not expose to temperatures exceeding 50
°C/122 °F. Store in a well-ventilated place.
Disposal Dispose of contents and container in accordance with all local, regional, national and
international regulations.
Supplemental label DELAYED EFFECTS FROM LONG TERM OVEREXPOSURE. Contains solvents which
elements can cause permanent brain and nervous system damage. Intentional misuse by
deliberately concentrating and inhaling the contents can be harmful or fatal. WARNING:
This product contains chemicals known to the State of California to cause cancer and
birth defects or other reproductive harm. FOR INDUSTRIAL USE ONLY.
Please refer to the SDS for additional information. Keep upright in a cool, dry place. Do
not discard empty can in trash compactor.
Hazards not otherwise : None known.
classified

Section 3. Composition/information on ingredients


Substance/mixture : Mixture
Other means of : Not available.
identification

CAS number/other identifiers

Date of issue/Date of revision : 4/21/2015. Date of previous issue : No previous validation. Version :1 2/15
Section 3. Composition/information on ingredients
Ingredient name % by weight CAS number
Acetone 38.1 67-64-1
Methyl Ethyl Ketone 16.6 78-93-3
Propane 11.8 74-98-6
Butane 11.3 106-97-8
Ethanol 3.8 64-17-5
Ethyl Acetate 3.1 141-78-6
2-Propanol 1.1 67-63-0
Carbon Black 0.2 1333-86-4
Methyl Isobutyl Ketone 0.1 108-10-1
There are no additional ingredients present which, within the current knowledge of the supplier and in the
concentrations applicable, are classified as hazardous to health or the environment and hence require reporting
in this section.
Occupational exposure limits, if available, are listed in Section 8.

Section 4. First aid measures


Description of necessary first aid measures
Eye contact : Immediately flush eyes with plenty of water, occasionally lifting the upper and lower
eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10
minutes. Get medical attention.
Inhalation : Remove victim to fresh air and keep at rest in a position comfortable for breathing. If it
is suspected that fumes are still present, the rescuer should wear an appropriate mask
or self-contained breathing apparatus. If not breathing, if breathing is irregular or if
respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It
may be dangerous to the person providing aid to give mouth-to-mouth resuscitation.
Get medical attention. If necessary, call a poison center or physician. If unconscious,
place in recovery position and get medical attention immediately. Maintain an open
airway. Loosen tight clothing such as a collar, tie, belt or waistband. In case of
inhalation of decomposition products in a fire, symptoms may be delayed. The exposed
person may need to be kept under medical surveillance for 48 hours.
Skin contact : Flush contaminated skin with plenty of water. Remove contaminated clothing and
shoes. Wash contaminated clothing thoroughly with water before removing it, or wear
gloves. Continue to rinse for at least 10 minutes. Get medical attention. Wash clothing
before reuse. Clean shoes thoroughly before reuse.
Ingestion : Get medical attention immediately. Call a poison center or physician. Wash out mouth
with water. Remove dentures if any. Remove victim to fresh air and keep at rest in a
position comfortable for breathing. If material has been swallowed and the exposed
person is conscious, give small quantities of water to drink. Stop if the exposed person
feels sick as vomiting may be dangerous. Aspiration hazard if swallowed. Can enter
lungs and cause damage. Do not induce vomiting. If vomiting occurs, the head should
be kept low so that vomit does not enter the lungs. Never give anything by mouth to an
unconscious person. If unconscious, place in recovery position and get medical
attention immediately. Maintain an open airway. Loosen tight clothing such as a collar,
tie, belt or waistband.

Most important symptoms/effects, acute and delayed


Potential acute health effects
Eye contact : Causes serious eye irritation.
Inhalation : Can cause central nervous system (CNS) depression. May cause drowsiness and
dizziness. May cause respiratory irritation. Exposure to decomposition products may
cause a health hazard. Serious effects may be delayed following exposure.
Skin contact : Causes skin irritation.
Ingestion : Can cause central nervous system (CNS) depression. May be fatal if swallowed and
enters airways. Irritating to mouth, throat and stomach.
Over-exposure signs/symptoms
Date of issue/Date of revision : 4/21/2015. Date of previous issue : No previous validation. Version :1 3/15
Section 4. First aid measures
Eye contact : Adverse symptoms may include the following:
pain or irritation
watering
redness
Inhalation : Adverse symptoms may include the following:
respiratory tract irritation
coughing
nausea or vomiting
headache
drowsiness/fatigue
dizziness/vertigo
unconsciousness
Skin contact : Adverse symptoms may include the following:
irritation
redness
Ingestion : Adverse symptoms may include the following:
nausea or vomiting

Indication of immediate medical attention and special treatment needed, if necessary


Notes to physician : In case of inhalation of decomposition products in a fire, symptoms may be delayed.
The exposed person may need to be kept under medical surveillance for 48 hours.
Specific treatments : No specific treatment.
Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. If it is
suspected that fumes are still present, the rescuer should wear an appropriate mask or
self-contained breathing apparatus. It may be dangerous to the person providing aid to
give mouth-to-mouth resuscitation. Wash contaminated clothing thoroughly with water
before removing it, or wear gloves.

See toxicological information (Section 11)

Section 5. Fire-fighting measures


Extinguishing media
Suitable extinguishing : Use an extinguishing agent suitable for the surrounding fire.
media
Unsuitable extinguishing : None known.
media

Specific hazards arising : Extremely flammable aerosol. In a fire or if heated, a pressure increase will occur and
from the chemical the container may burst, with the risk of a subsequent explosion. Gas may accumulate
in low or confined areas or travel a considerable distance to a source of ignition and
flash back, causing fire or explosion. Bursting aerosol containers may be propelled from
a fire at high speed. Runoff to sewer may create fire or explosion hazard.
Hazardous thermal : Decomposition products may include the following materials:
decomposition products carbon dioxide
carbon monoxide
nitrogen oxides

Special protective actions : Promptly isolate the scene by removing all persons from the vicinity of the incident if
for fire-fighters there is a fire. No action shall be taken involving any personal risk or without suitable
training. Move containers from fire area if this can be done without risk. Use water
spray to keep fire-exposed containers cool.
Special protective : Fire-fighters should wear appropriate protective equipment and self-contained breathing
equipment for fire-fighters apparatus (SCBA) with a full face-piece operated in positive pressure mode.

Date of issue/Date of revision : 4/21/2015. Date of previous issue : No previous validation. Version :1 4/15
Section 6. Accidental release measures
Personal precautions, protective equipment and emergency procedures
For non-emergency : No action shall be taken involving any personal risk or without suitable training.
personnel Evacuate surrounding areas. Keep unnecessary and unprotected personnel from
entering. In the case of aerosols being ruptured, care should be taken due to the rapid
escape of the pressurized contents and propellant. If a large number of containers are
ruptured, treat as a bulk material spillage according to the instructions in the clean-up
section. Do not touch or walk through spilled material. Shut off all ignition sources. No
flares, smoking or flames in hazard area. Avoid breathing vapor or mist. Provide
adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put
on appropriate personal protective equipment.
For emergency responders : If specialised clothing is required to deal with the spillage, take note of any information in
Section 8 on suitable and unsuitable materials. See also the information in "For non-
emergency personnel".

Environmental precautions : Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains
and sewers. Inform the relevant authorities if the product has caused environmental
pollution (sewers, waterways, soil or air).

Methods and materials for containment and cleaning up


Small spill : Stop leak if without risk. Move containers from spill area. Use spark-proof tools and
explosion-proof equipment. Dilute with water and mop up if water-soluble. Alternatively,
or if water-insoluble, absorb with an inert dry material and place in an appropriate waste
disposal container. Dispose of via a licensed waste disposal contractor.
Large spill : Stop leak if without risk. Move containers from spill area. Use spark-proof tools and
explosion-proof equipment. Approach release from upwind. Prevent entry into sewers,
water courses, basements or confined areas. Wash spillages into an effluent treatment
plant or proceed as follows. Contain and collect spillage with non-combustible,
absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in
container for disposal according to local regulations (see Section 13). Dispose of via a
licensed waste disposal contractor. Contaminated absorbent material may pose the
same hazard as the spilled product. Note: see Section 1 for emergency contact
information and Section 13 for waste disposal.

Section 7. Handling and storage


Precautions for safe handling
Protective measures : Put on appropriate personal protective equipment (see Section 8). Pressurized
container: protect from sunlight and do not expose to temperatures exceeding 50°C. Do
not pierce or burn, even after use. Avoid exposure - obtain special instructions before
use. Do not handle until all safety precautions have been read and understood. Do not
get in eyes or on skin or clothing. Do not breathe vapor or mist. Do not swallow. Avoid
breathing gas. Use only with adequate ventilation. Wear appropriate respirator when
ventilation is inadequate. Store and use away from heat, sparks, open flame or any
other ignition source. Use explosion-proof electrical (ventilating, lighting and material
handling) equipment. Use only non-sparking tools. Empty containers retain product
residue and can be hazardous.
Advice on general : Eating, drinking and smoking should be prohibited in areas where this material is
occupational hygiene handled, stored and processed. Workers should wash hands and face before eating,
drinking and smoking. Remove contaminated clothing and protective equipment before
entering eating areas. See also Section 8 for additional information on hygiene
measures.

Conditions for safe storage, : Store in accordance with local regulations. Store away from direct sunlight in a dry, cool
including any and well-ventilated area, away from incompatible materials (see Section 10) and food
incompatibilities and drink. Protect from sunlight. Store locked up. Eliminate all ignition sources. Use
appropriate containment to avoid environmental contamination.

Date of issue/Date of revision : 4/21/2015. Date of previous issue : No previous validation. Version :1 5/15
Section 8. Exposure controls/personal protection
Control parameters
Occupational exposure limits
Ingredient name Exposure limits
Acetone ACGIH TLV (United States, 4/2014).
TWA: 500 ppm 8 hours.
TWA: 1188 mg/m³ 8 hours.
STEL: 750 ppm 15 minutes.
STEL: 1782 mg/m³ 15 minutes.
NIOSH REL (United States, 10/2013).
TWA: 250 ppm 10 hours.
TWA: 590 mg/m³ 10 hours.
OSHA PEL (United States, 2/2013).
TWA: 1000 ppm 8 hours.
TWA: 2400 mg/m³ 8 hours.
Methyl Ethyl Ketone ACGIH TLV (United States, 4/2014).
TWA: 200 ppm 8 hours.
TWA: 590 mg/m³ 8 hours.
STEL: 300 ppm 15 minutes.
STEL: 885 mg/m³ 15 minutes.
NIOSH REL (United States, 10/2013).
TWA: 200 ppm 10 hours.
TWA: 590 mg/m³ 10 hours.
STEL: 300 ppm 15 minutes.
STEL: 885 mg/m³ 15 minutes.
OSHA PEL (United States, 2/2013).
TWA: 200 ppm 8 hours.
TWA: 590 mg/m³ 8 hours.
Propane NIOSH REL (United States, 10/2013).
TWA: 1000 ppm 10 hours.
TWA: 1800 mg/m³ 10 hours.
OSHA PEL (United States, 2/2013).
TWA: 1000 ppm 8 hours.
TWA: 1800 mg/m³ 8 hours.
Butane NIOSH REL (United States, 10/2013).
TWA: 800 ppm 10 hours.
TWA: 1900 mg/m³ 10 hours.
ACGIH TLV (United States, 4/2014).
STEL: 1000 ppm 15 minutes.
Ethanol ACGIH TLV (United States, 4/2014).
STEL: 1000 ppm 15 minutes.
NIOSH REL (United States, 10/2013).
TWA: 1000 ppm 10 hours.
TWA: 1900 mg/m³ 10 hours.
OSHA PEL (United States, 2/2013).
TWA: 1000 ppm 8 hours.
TWA: 1900 mg/m³ 8 hours.
Ethyl Acetate ACGIH TLV (United States, 4/2014).
TWA: 400 ppm 8 hours.
TWA: 1440 mg/m³ 8 hours.
NIOSH REL (United States, 10/2013).
TWA: 400 ppm 10 hours.
TWA: 1400 mg/m³ 10 hours.
OSHA PEL (United States, 2/2013).
TWA: 400 ppm 8 hours.
TWA: 1400 mg/m³ 8 hours.
2-Propanol ACGIH TLV (United States, 4/2014).
TWA: 200 ppm 8 hours.
STEL: 400 ppm 15 minutes.

Date of issue/Date of revision : 4/21/2015. Date of previous issue : No previous validation. Version :1 6/15
Section 8. Exposure controls/personal protection
NIOSH REL (United States, 10/2013).
TWA: 400 ppm 10 hours.
TWA: 980 mg/m³ 10 hours.
STEL: 500 ppm 15 minutes.
STEL: 1225 mg/m³ 15 minutes.
OSHA PEL (United States, 2/2013).
TWA: 400 ppm 8 hours.
TWA: 980 mg/m³ 8 hours.
Carbon Black NIOSH REL (United States, 10/2013).
TWA: 3.5 mg/m³ 10 hours.
TWA: 0.1 mg of PAHs/cm³ 10 hours.
OSHA PEL (United States, 2/2013).
TWA: 3.5 mg/m³ 8 hours.
ACGIH TLV (United States, 4/2014).
TWA: 3 mg/m³ 8 hours. Form: Inhalable
fraction
Methyl Isobutyl Ketone ACGIH TLV (United States, 4/2014).
TWA: 20 ppm 8 hours.
STEL: 75 ppm 15 minutes.
NIOSH REL (United States, 10/2013).
TWA: 50 ppm 10 hours.
TWA: 205 mg/m³ 10 hours.
STEL: 75 ppm 15 minutes.
STEL: 300 mg/m³ 15 minutes.
OSHA PEL (United States, 2/2013).
TWA: 100 ppm 8 hours.
TWA: 410 mg/m³ 8 hours.

Appropriate engineering : Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or
controls other engineering controls to keep worker exposure to airborne contaminants below any
recommended or statutory limits. The engineering controls also need to keep gas,
vapor or dust concentrations below any lower explosive limits. Use explosion-proof
ventilation equipment.
Environmental exposure : Emissions from ventilation or work process equipment should be checked to ensure
controls they comply with the requirements of environmental protection legislation. In some
cases, fume scrubbers, filters or engineering modifications to the process equipment
will be necessary to reduce emissions to acceptable levels.

Individual protection measures


Hygiene measures : Wash hands, forearms and face thoroughly after handling chemical products, before
eating, smoking and using the lavatory and at the end of the working period.
Appropriate techniques should be used to remove potentially contaminated clothing.
Wash contaminated clothing before reusing. Ensure that eyewash stations and safety
showers are close to the workstation location.
Eye/face protection : Safety eyewear complying with an approved standard should be used when a risk
assessment indicates this is necessary to avoid exposure to liquid splashes, mists,
gases or dusts. If contact is possible, the following protection should be worn, unless
the assessment indicates a higher degree of protection: chemical splash goggles.
Skin protection
Hand protection : Chemical-resistant, impervious gloves complying with an approved standard should be
worn at all times when handling chemical products if a risk assessment indicates this is
necessary. Considering the parameters specified by the glove manufacturer, check
during use that the gloves are still retaining their protective properties. It should be
noted that the time to breakthrough for any glove material may be different for different
glove manufacturers. In the case of mixtures, consisting of several substances, the
protection time of the gloves cannot be accurately estimated.

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Section 8. Exposure controls/personal protection
Body protection : Personal protective equipment for the body should be selected based on the task being
performed and the risks involved and should be approved by a specialist before
handling this product. When there is a risk of ignition from static electricity, wear anti-
static protective clothing. For the greatest protection from static discharges, clothing
should include anti-static overalls, boots and gloves.
Other skin protection : Appropriate footwear and any additional skin protection measures should be selected
based on the task being performed and the risks involved and should be approved by a
specialist before handling this product.
Respiratory protection : Use a properly fitted, air-purifying or air-fed respirator complying with an approved
standard if a risk assessment indicates this is necessary. Respirator selection must be
based on known or anticipated exposure levels, the hazards of the product and the safe
working limits of the selected respirator.

Section 9. Physical and chemical properties


Appearance
Physical state : Liquid.
Color : Not available.
Odor : Not available.
Odor threshold : Not available.
pH : Not available.
Melting point : Not available.
Boiling point : Not available.
Flash point : Closed cup: -29°C (-20.2°F) [Pensky-Martens Closed Cup]
Evaporation rate : 5.6 (butyl acetate = 1)
Flammability (solid, gas) : Not available.
Lower and upper explosive : Lower: 1%
(flammable) limits Upper: 19%
Vapor pressure : 13.5 kPa (101.325 mm Hg) [at 20°C]
Vapor density : 1.5 [Air = 1]
Relative density : 0.73
Solubility : Not available.
Partition coefficient: n- : Not available.
octanol/water
Auto-ignition temperature : Not available.
Decomposition temperature : Not available.
Viscosity : Kinematic (room temperature): <0.07 cm2/s (<7 cSt)
Kinematic (40°C (104°F)): <0.07 cm2/s (<7 cSt)
Aerosol product
Type of aerosol : Spray
Heat of combustion : 0.00003086 kJ/g

Section 10. Stability and reactivity


Reactivity : No specific test data related to reactivity available for this product or its ingredients.

Chemical stability : The product is stable.

Possibility of hazardous : Under normal conditions of storage and use, hazardous reactions will not occur.
reactions

Conditions to avoid : Avoid all possible sources of ignition (spark or flame).


Date of issue/Date of revision : 4/21/2015. Date of previous issue : No previous validation. Version :1 8/15
Section 10. Stability and reactivity
Incompatible materials : No specific data.

Hazardous decomposition : Under normal conditions of storage and use, hazardous decomposition products should
products not be produced.

Section 11. Toxicological information


Information on toxicological effects
Acute toxicity
Product/ingredient name Result Species Dose Exposure
Acetone LD50 Oral Rat 5800 mg/kg -
Methyl Ethyl Ketone LD50 Dermal Rabbit 6480 mg/kg -
LD50 Oral Rat 2737 mg/kg -
Butane LC50 Inhalation Vapor Rat 658000 mg/m³ 4 hours
Ethanol LC50 Inhalation Vapor Rat 124700 mg/m³ 4 hours
LD50 Oral Rat 7 g/kg -
Ethyl Acetate LD50 Oral Rat 5620 mg/kg -
2-Propanol LD50 Dermal Rabbit 12800 mg/kg -
LD50 Oral Rat 5000 mg/kg -
Carbon Black LD50 Oral Rat >15400 mg/kg -
Methyl Isobutyl Ketone LD50 Oral Rat 2080 mg/kg -
Irritation/Corrosion
Product/ingredient name Result Species Score Exposure Observation
Acetone Eyes - Mild irritant Human - 186300 parts -
per million
Eyes - Mild irritant Rabbit - 10 microliters -
Eyes - Moderate irritant Rabbit - 24 hours 20 -
milligrams
Eyes - Severe irritant Rabbit - 20 milligrams -
Skin - Mild irritant Rabbit - 24 hours 500 -
milligrams
Skin - Mild irritant Rabbit - 395 -
milligrams
Methyl Ethyl Ketone Skin - Mild irritant Rabbit - 24 hours 14 -
milligrams
Skin - Moderate irritant Rabbit - 24 hours 500 -
milligrams
Ethanol Eyes - Mild irritant Rabbit - 24 hours 500 -
milligrams
Eyes - Moderate irritant Rabbit - 0.066666667 -
minutes 100
milligrams
Eyes - Moderate irritant Rabbit - 100 -
microliters
Eyes - Severe irritant Rabbit - 500 -
milligrams
Skin - Mild irritant Rabbit - 400 -
milligrams
Skin - Moderate irritant Rabbit - 24 hours 20 -
milligrams
2-Propanol Eyes - Moderate irritant Rabbit - 24 hours 100 -
milligrams
Eyes - Moderate irritant Rabbit - 10 milligrams -
Eyes - Severe irritant Rabbit - 100 -
milligrams
Skin - Mild irritant Rabbit - 500 -

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Section 11. Toxicological information
milligrams
Methyl Isobutyl Ketone Eyes - Moderate irritant Rabbit - 24 hours 100 -
microliters
Eyes - Severe irritant Rabbit - 40 milligrams -
Skin - Mild irritant Rabbit - 24 hours 500 -
milligrams
Sensitization
Not available.

Mutagenicity
Not available.
Carcinogenicity
Not available.
Classification
Product/ingredient name OSHA IARC NTP
Ethanol - 1 -
2-Propanol - 3 -
Carbon Black - 2B -
Methyl Isobutyl Ketone - 2B -
Reproductive toxicity
Not available.

Teratogenicity
Not available.
Specific target organ toxicity (single exposure)
Name Category Route of Target organs
exposure
Acetone Category 3 Not applicable. Respiratory tract
irritation and
Narcotic effects
Methyl Ethyl Ketone Category 3 Not applicable. Respiratory tract
irritation and
Narcotic effects
Propane Category 3 Not applicable. Respiratory tract
irritation and
Narcotic effects
Butane Category 3 Not applicable. Respiratory tract
irritation and
Narcotic effects
Ethanol Category 3 Not applicable. Respiratory tract
irritation and
Narcotic effects
2-Propanol Category 3 Not applicable. Respiratory tract
irritation and
Narcotic effects
Methyl Isobutyl Ketone Category 3 Not applicable. Respiratory tract
irritation and
Narcotic effects
Specific target organ toxicity (repeated exposure)

Date of issue/Date of revision : 4/21/2015. Date of previous issue : No previous validation. Version :1 10/15
Section 11. Toxicological information
Name Category Route of Target organs
exposure
Acetone Category 2 Not determined Not determined
Methyl Ethyl Ketone Category 2 Not determined Not determined
Propane Category 2 Not determined Not determined
Butane Category 2 Not determined Not determined
Ethanol Category 2 Not determined Not determined
2-Propanol Category 2 Not determined Not determined
Methyl Isobutyl Ketone Category 2 Not determined Not determined
Aspiration hazard
Name Result
Propane ASPIRATION HAZARD - Category 1
Butane ASPIRATION HAZARD - Category 1

Information on the likely : Not available.


routes of exposure
Potential acute health effects
Eye contact : Causes serious eye irritation.
Inhalation : Can cause central nervous system (CNS) depression. May cause drowsiness and
dizziness. May cause respiratory irritation. Exposure to decomposition products may
cause a health hazard. Serious effects may be delayed following exposure.
Skin contact : Causes skin irritation.
Ingestion : Can cause central nervous system (CNS) depression. May be fatal if swallowed and
enters airways. Irritating to mouth, throat and stomach.

Symptoms related to the physical, chemical and toxicological characteristics


Eye contact : Adverse symptoms may include the following:
pain or irritation
watering
redness
Inhalation : Adverse symptoms may include the following:
respiratory tract irritation
coughing
nausea or vomiting
headache
drowsiness/fatigue
dizziness/vertigo
unconsciousness
Skin contact : Adverse symptoms may include the following:
irritation
redness
Ingestion : Adverse symptoms may include the following:
nausea or vomiting

Delayed and immediate effects and also chronic effects from short and long term exposure
Short term exposure
Potential immediate : Not available.
effects
Potential delayed effects : Not available.
Long term exposure
Potential immediate : Not available.
effects
Date of issue/Date of revision : 4/21/2015. Date of previous issue : No previous validation. Version :1 11/15
Potential delayed effects : Not available.
Potential chronic health effects
Not available.
General : May cause damage to organs through prolonged or repeated exposure.
Carcinogenicity : May cause cancer. Risk of cancer depends on duration and level of exposure.
Mutagenicity : No known significant effects or critical hazards.
Teratogenicity : No known significant effects or critical hazards.
Developmental effects : No known significant effects or critical hazards.
Fertility effects : No known significant effects or critical hazards.

Numerical measures of toxicity


Acute toxicity estimates
Route ATE value
Oral 10254.2 mg/kg

Section 12. Ecological information


Toxicity
Product/ingredient name Result Species Exposure
Acetone Acute EC50 20.565 mg/l Marine water Algae - Ulva pertusa 96 hours
Acute LC50 6000000 µg/l Fresh water Crustaceans - Gammarus pulex 48 hours
Acute LC50 10000 µg/l Fresh water Daphnia - Daphnia magna 48 hours
Acute LC50 5600 ppm Fresh water Fish - Poecilia reticulata 96 hours
Chronic NOEC 4.95 mg/l Marine water Algae - Ulva pertusa 96 hours
Chronic NOEC 0.016 ml/L Fresh water Crustaceans - Daphniidae 21 days
Chronic NOEC 0.1 ml/L Fresh water Daphnia - Daphnia magna - 21 days
Neonate
Chronic NOEC 5 µg/l Marine water Fish - Gasterosteus aculeatus - 42 days
Larvae
Methyl Ethyl Ketone Acute EC50 >500000 µg/l Marine water Algae - Skeletonema costatum 96 hours
Acute EC50 5091000 µg/l Fresh water Daphnia - Daphnia magna - 48 hours
Larvae
Acute LC50 3220000 µg/l Fresh water Fish - Pimephales promelas 96 hours
Ethanol Acute EC50 17.921 mg/l Marine water Algae - Ulva pertusa 96 hours
Acute EC50 2000 µg/l Fresh water Daphnia - Daphnia magna 48 hours
Acute LC50 25500 µg/l Marine water Crustaceans - Artemia 48 hours
franciscana - Larvae
Acute LC50 42000 µg/l Fresh water Fish - Oncorhynchus mykiss 4 days
Chronic NOEC 4.995 mg/l Marine water Algae - Ulva pertusa 96 hours
Chronic NOEC 0.375 ul/L Fresh water Fish - Gambusia holbrooki - 12 weeks
Larvae
Ethyl Acetate Acute EC50 2500000 µg/l Fresh water Algae - Selenastrum sp. 96 hours
Acute LC50 750000 µg/l Fresh water Crustaceans - Gammarus pulex 48 hours
Acute LC50 154000 µg/l Fresh water Daphnia - Daphnia cucullata 48 hours
Acute LC50 212500 µg/l Fresh water Fish - Heteropneustes fossilis 96 hours
Chronic NOEC 2400 µg/l Fresh water Daphnia - Daphnia magna 21 days
Chronic NOEC 75.6 mg/l Fresh water Fish - Pimephales promelas - 32 days
Embryo
2-Propanol Acute LC50 1400000 µg/l Marine water Crustaceans - Crangon crangon 48 hours
Acute LC50 4200 mg/l Fresh water Fish - Rasbora heteromorpha 96 hours
Methyl Isobutyl Ketone Acute LC50 505000 µg/l Fresh water Fish - Pimephales promelas 96 hours
Chronic NOEC 78 mg/l Fresh water Daphnia - Daphnia magna 21 days
Chronic NOEC 168 mg/l Fresh water Fish - Pimephales promelas - 33 days
Embryo

Date of issue/Date of revision : 4/21/2015. Date of previous issue : No previous validation. Version :1 12/15
Section 12. Ecological information
Persistence and degradability
Product/ingredient name Aquatic half-life Photolysis Biodegradability
Acetone - - Readily
Methyl Ethyl Ketone - - Readily
Ethanol - - Readily
Ethyl Acetate - - Readily
2-Propanol - - Readily
Methyl Isobutyl Ketone - - Readily

Bioaccumulative potential
Product/ingredient name LogPow BCF Potential
Ethyl Acetate - 30 low

Mobility in soil
Soil/water partition : Not available.
coefficient (KOC)

Other adverse effects : No known significant effects or critical hazards.

Section 13. Disposal considerations


Disposal methods : The generation of waste should be avoided or minimized wherever possible. Disposal
of this product, solutions and any by-products should at all times comply with the
requirements of environmental protection and waste disposal legislation and any
regional local authority requirements. Dispose of surplus and non-recyclable products
via a licensed waste disposal contractor. Waste should not be disposed of untreated to
the sewer unless fully compliant with the requirements of all authorities with jurisdiction.
Waste packaging should be recycled. Incineration or landfill should only be considered
when recycling is not feasible. This material and its container must be disposed of in a
safe way. Empty containers or liners may retain some product residues. Do not
puncture or incinerate container.

Section 14. Transport information


DOT TDG Mexico IATA IMDG
Classification Classification Classification
UN number UN1950 UN1950 UN1950 UN1950 UN1950

UN proper AEROSOLS AEROSOLS AEROSOLS AEROSOLS, AEROSOLS


shipping name flammable
Transport 2.1 2.1 2.1 2.1 2.1
hazard class(es)

Packing group - - - - -
Environmental No. No. No. No. No.
hazards

Date of issue/Date of revision : 4/21/2015. Date of previous issue : No previous validation. Version :1 13/15
Section 14. Transport information
Additional Special Special Special Special Emergency
information provisions provisions provisions provisions schedules (EmS)
LIMITED LIMITED (ERG#126) LIMITED LIMITED
QUANTITY QUANTITY QUANTITY QUANTITY, F-D,
S-U

Special precautions for user : Multi-modal shipping descriptions are provided for informational purposes and do not
consider container sizes. The presence of a shipping description for a particular
mode of transport (sea, air, etc.), does not indicate that the product is packaged
suitably for that mode of transport. All packaging must be reviewed for suitability prior
to shipment, and compliance with the applicable regulations is the sole responsibility
of the person offering the product for transport. People loading and unloading
dangerous goods must be trained on all of the risks deriving from the substances
and on all actions in case of emergency situations.

Transport in bulk according : Not available.


to Annex II of MARPOL
73/78 and the IBC Code

Section 15. Regulatory information


U.S. Federal regulations :
State regulations
California Prop. 65
WARNING: This product contains chemicals known to the State of California to cause cancer and birth defects or other
reproductive harm.

Section 16. Other information


Hazardous Material Information System (U.S.A.)
Health * 2

Flammability 4
Physical hazards 0

Caution: HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4
representing significant hazards or risks Although HMIS® ratings are not required on SDSs under 29 CFR 1910.
1200, the preparer may choose to provide them. HMIS® ratings are to be used with a fully implemented HMIS®
program. HMIS® is a registered mark of the National Paint & Coatings Association (NPCA). HMIS® materials may
be purchased exclusively from J. J. Keller (800) 327-6868.
The customer is responsible for determining the PPE code for this material.

Date of issue/Date of revision : 4/21/2015. Date of previous issue : No previous validation. Version :1 14/15
Section 16. Other information

Notice to reader
It is recommended that each customer or recipient of this Safety Data Sheet (SDS) study it carefully and consult
resources, as necessary or appropriate, to become aware of and understand the data contained in this SDS and
any hazards associated with the product. This information is provided in good faith and believed to be accurate
as of the effective date herein. However, no warranty, express or implied, is given. The information presented
here applies only to the product as shipped. The addition of any material can change the composition, hazards
and risks of the product. Regulatory requirements are subject to change and may differ between various
locations and jurisdictions. The customer/buyer/user is responsible to ensure that his activities comply with all
country, federal, state, provincial or local laws. The conditions for use of the product are not under the control of
the manufacturer; the customer/buyer/user is responsible to determine the conditions necessary for the safe use
of this product. The customer/buyer/user should not use the product for any purpose other than the purpose
shown in the applicable section of this SDS without first referring to the supplier and obtaining written handling
instructions. Due to the proliferation of sources for information such as manufacturer-specific SDS, the
manufacturer cannot be responsible for SDSs obtained from any other source.

Date of issue/Date of revision : 4/21/2015. Date of previous issue : No previous validation. Version :1 15/15
SAFETY DATA SHEET
DAP1692

Section 1. Identification
Product name : DUPLI-COLOR® Sandable Primer
Gray Hot Rod
Product code : DAP1692
Other means of : Not available.
identification
Product type : Aerosol.
Relevant identified uses of the substance or mixture and uses advised against
Not applicable.

Manufacturer : Dupli-Color Products Company


Cleveland, OH 44115

Emergency telephone : (216) 566-2917


number of the company
Product Information : (800) 247-3270
Telephone Number
Regulatory Information : (216) 566-2902
Telephone Number
Transportation Emergency : (800) 424-9300
Telephone Number

Section 2. Hazards identification


OSHA/HCS status : This material is considered hazardous by the OSHA Hazard Communication Standard
(29 CFR 1910.1200).
Classification of the : FLAMMABLE AEROSOLS - Category 1
substance or mixture GASES UNDER PRESSURE - Compressed gas
SKIN CORROSION/IRRITATION - Category 2
SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 2A
SKIN SENSITIZATION - Category 1
CARCINOGENICITY - Category 2
TOXIC TO REPRODUCTION (Unborn child) - Category 2
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Respiratory tract
irritation) - Category 3
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Narcotic effects) -
Category 3
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) - Category 2
ASPIRATION HAZARD - Category 1
Percentage of the mixture consisting of ingredient(s) of unknown toxicity: 22.5%
GHS label elements
Hazard pictograms :

Signal word : Danger

Date of issue/Date of revision : 6/4/2016 Date of previous issue : 6/3/2016 Version :3 1/17
Section 2. Hazards identification
Hazard statements : Extremely flammable aerosol.
Contains gas under pressure; may explode if heated.
Causes serious eye irritation.
Causes skin irritation.
May cause an allergic skin reaction.
Suspected of damaging the unborn child.
Suspected of causing cancer.
May be fatal if swallowed and enters airways.
May cause respiratory irritation.
May cause drowsiness or dizziness.
May cause damage to organs through prolonged or repeated exposure.
Precautionary statements
General : Read label before use. Keep out of reach of children. If medical advice is needed, have
product container or label at hand.
Prevention : Obtain special instructions before use. Do not handle until all safety precautions have
been read and understood. Wear protective gloves. Wear eye or face protection.
Wear protective clothing. Keep away from heat, hot surfaces, sparks, open flames and
other ignition sources. No smoking. Do not spray on an open flame or other ignition
source. Use only outdoors or in a well-ventilated area. Do not breathe dust or mist.
Wash hands thoroughly after handling. Contaminated work clothing must not be
allowed out of the workplace. Pressurized container: Do not pierce or burn, even after
use.
Response : Get medical attention if you feel unwell. IF exposed or concerned: Get medical
attention. IF INHALED: Remove person to fresh air and keep comfortable for breathing.
Call a POISON CENTER or physician if you feel unwell. IF SWALLOWED:
Immediately call a POISON CENTER or physician. Do NOT induce vomiting. IF ON
SKIN: Wash with plenty of soap and water. Wash contaminated clothing before reuse.
If skin irritation or rash occurs: Get medical attention. IF IN EYES: Rinse cautiously
with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing. If eye irritation persists: Get medical attention.
Storage : Store locked up. Protect from sunlight. Do not expose to temperatures exceeding 50
°C/122 °F. Store in a well-ventilated place.
Disposal : Dispose of contents and container in accordance with all local, regional, national and
international regulations.
Supplemental label DANGER: Rags, steel wool, other waste soaked with this product, and sanding residue
elements may spontaneously catch fire if improperly discarded. Immediately place rags, steel
wool, other waste soaked with this product, and sanding residue in a sealed, water-filled,
metal container. Dispose of in accordance with local fire regulations. DELAYED
EFFECTS FROM LONG TERM OVEREXPOSURE. Contains solvents which can cause
permanent brain and nervous system damage. Intentional misuse by deliberately
concentrating and inhaling the contents can be harmful or fatal. WARNING: This
product contains chemicals known to the State of California to cause cancer and birth
defects or other reproductive harm.
Please refer to the SDS for additional information. Keep out of reach of children. Keep
upright in a cool, dry place. Do not discard empty can in trash compactor.
Hazards not otherwise : None known.
classified

Section 3. Composition/information on ingredients


Substance/mixture : Mixture
Other means of : Not available.
identification
CAS number/other identifiers

Date of issue/Date of revision : 6/4/2016 Date of previous issue : 6/3/2016 Version :3 2/17
Section 3. Composition/information on ingredients
Ingredient name % by weight CAS number
Acetone 35.04 67-64-1
Propane 14.95 74-98-6
Butane 14.36 106-97-8
Toluene 10.25 108-88-3
Lt. Aliphatic Hydrocarbon Solvent 6.49 64742-89-8
Titanium Dioxide 1.06 13463-67-7
Naphthalene 0.15 91-20-3
Methyl Ethyl Ketoxime 0.11 96-29-7
Any concentration shown as a range is to protect confidentiality or is due to batch variation.
There are no additional ingredients present which, within the current knowledge of the supplier and in the
concentrations applicable, are classified as hazardous to health and hence require reporting in this section.

Occupational exposure limits, if available, are listed in Section 8.

Section 4. First aid measures


Description of necessary first aid measures
Eye contact : Immediately flush eyes with plenty of water, occasionally lifting the upper and lower
eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10
minutes. Get medical attention.
Inhalation : Remove victim to fresh air and keep at rest in a position comfortable for breathing. If it
is suspected that fumes are still present, the rescuer should wear an appropriate mask
or self-contained breathing apparatus. If not breathing, if breathing is irregular or if
respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It
may be dangerous to the person providing aid to give mouth-to-mouth resuscitation.
Get medical attention. If necessary, call a poison center or physician. If unconscious,
place in recovery position and get medical attention immediately. Maintain an open
airway. Loosen tight clothing such as a collar, tie, belt or waistband.
Skin contact : Wash with plenty of soap and water. Remove contaminated clothing and shoes. Wash
contaminated clothing thoroughly with water before removing it, or wear gloves.
Continue to rinse for at least 10 minutes. Get medical attention. In the event of any
complaints or symptoms, avoid further exposure. Wash clothing before reuse. Clean
shoes thoroughly before reuse.
Ingestion : Get medical attention immediately. Call a poison center or physician. Wash out mouth
with water. Remove dentures if any. Remove victim to fresh air and keep at rest in a
position comfortable for breathing. If material has been swallowed and the exposed
person is conscious, give small quantities of water to drink. Stop if the exposed person
feels sick as vomiting may be dangerous. Aspiration hazard if swallowed. Can enter
lungs and cause damage. Do not induce vomiting. If vomiting occurs, the head should
be kept low so that vomit does not enter the lungs. Never give anything by mouth to an
unconscious person. If unconscious, place in recovery position and get medical
attention immediately. Maintain an open airway. Loosen tight clothing such as a collar,
tie, belt or waistband.

Most important symptoms/effects, acute and delayed


Potential acute health effects
Eye contact : Causes serious eye irritation.
Inhalation : Can cause central nervous system (CNS) depression. May cause drowsiness or
dizziness. May cause respiratory irritation.
Skin contact : Causes skin irritation. May cause an allergic skin reaction.
Ingestion : Can cause central nervous system (CNS) depression. May be fatal if swallowed and
enters airways.
Over-exposure signs/symptoms

Date of issue/Date of revision : 6/4/2016 Date of previous issue : 6/3/2016 Version :3 3/17
Section 4. First aid measures
Eye contact : Adverse symptoms may include the following:
pain or irritation
watering
redness
Inhalation : Adverse symptoms may include the following:
respiratory tract irritation
coughing
nausea or vomiting
headache
drowsiness/fatigue
dizziness/vertigo
unconsciousness
reduced fetal weight
increase in fetal deaths
skeletal malformations
Skin contact : Adverse symptoms may include the following:
irritation
redness
reduced fetal weight
increase in fetal deaths
skeletal malformations
Ingestion : Adverse symptoms may include the following:
nausea or vomiting
reduced fetal weight
increase in fetal deaths
skeletal malformations

Indication of immediate medical attention and special treatment needed, if necessary


Notes to physician : Treat symptomatically. Contact poison treatment specialist immediately if large
quantities have been ingested or inhaled.
Specific treatments : No specific treatment.
Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. If it is
suspected that fumes are still present, the rescuer should wear an appropriate mask or
self-contained breathing apparatus. It may be dangerous to the person providing aid to
give mouth-to-mouth resuscitation. Wash contaminated clothing thoroughly with water
before removing it, or wear gloves.

See toxicological information (Section 11)

Section 5. Fire-fighting measures


Extinguishing media
Suitable extinguishing : Use an extinguishing agent suitable for the surrounding fire.
media
Unsuitable extinguishing : None known.
media

Specific hazards arising : Extremely flammable aerosol. In a fire or if heated, a pressure increase will occur and
from the chemical the container may burst, with the risk of a subsequent explosion. Gas may accumulate
in low or confined areas or travel a considerable distance to a source of ignition and
flash back, causing fire or explosion. Bursting aerosol containers may be propelled from
a fire at high speed. Runoff to sewer may create fire or explosion hazard.
Hazardous thermal : Decomposition products may include the following materials:
decomposition products carbon dioxide
carbon monoxide
metal oxide/oxides

Date of issue/Date of revision : 6/4/2016 Date of previous issue : 6/3/2016 Version :3 4/17
Section 5. Fire-fighting measures

Special protective actions : Promptly isolate the scene by removing all persons from the vicinity of the incident if
for fire-fighters there is a fire. No action shall be taken involving any personal risk or without suitable
training. Move containers from fire area if this can be done without risk. Use water
spray to keep fire-exposed containers cool.
Special protective : Fire-fighters should wear appropriate protective equipment and self-contained breathing
equipment for fire-fighters apparatus (SCBA) with a full face-piece operated in positive pressure mode.

Section 6. Accidental release measures


Personal precautions, protective equipment and emergency procedures
For non-emergency : No action shall be taken involving any personal risk or without suitable training.
personnel Evacuate surrounding areas. Keep unnecessary and unprotected personnel from
entering. In the case of aerosols being ruptured, care should be taken due to the rapid
escape of the pressurized contents and propellant. If a large number of containers are
ruptured, treat as a bulk material spillage according to the instructions in the clean-up
section. Do not touch or walk through spilled material. Shut off all ignition sources. No
flares, smoking or flames in hazard area. Avoid breathing vapor or mist. Provide
adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put
on appropriate personal protective equipment.
For emergency responders : If specialized clothing is required to deal with the spillage, take note of any information in
Section 8 on suitable and unsuitable materials. See also the information in "For non-
emergency personnel".

Environmental precautions : Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains
and sewers. Inform the relevant authorities if the product has caused environmental
pollution (sewers, waterways, soil or air).

Methods and materials for containment and cleaning up


Small spill : Stop leak if without risk. Move containers from spill area. Use spark-proof tools and
explosion-proof equipment. Dilute with water and mop up if water-soluble. Alternatively,
or if water-insoluble, absorb with an inert dry material and place in an appropriate waste
disposal container. Dispose of via a licensed waste disposal contractor.
Large spill : Stop leak if without risk. Move containers from spill area. Use spark-proof tools and
explosion-proof equipment. Approach release from upwind. Prevent entry into sewers,
water courses, basements or confined areas. Wash spillages into an effluent treatment
plant or proceed as follows. Contain and collect spillage with non-combustible,
absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in
container for disposal according to local regulations (see Section 13). Dispose of via a
licensed waste disposal contractor. Contaminated absorbent material may pose the
same hazard as the spilled product. Note: see Section 1 for emergency contact
information and Section 13 for waste disposal.

Section 7. Handling and storage


Precautions for safe handling
Protective measures : Put on appropriate personal protective equipment (see Section 8). Persons with a
history of skin sensitization problems should not be employed in any process in which
this product is used. Pressurized container: protect from sunlight and do not expose to
temperatures exceeding 50°C. Do not pierce or burn, even after use. Avoid exposure -
obtain special instructions before use. Avoid exposure during pregnancy. Do not
handle until all safety precautions have been read and understood. Do not get in eyes
or on skin or clothing. Do not breathe vapor or mist. Do not swallow. Avoid breathing
gas. Use only with adequate ventilation. Wear appropriate respirator when ventilation is
inadequate. Store and use away from heat, sparks, open flame or any other ignition
source. Use explosion-proof electrical (ventilating, lighting and material handling)
equipment. Use only non-sparking tools. Empty containers retain product residue and
can be hazardous.

Date of issue/Date of revision : 6/4/2016 Date of previous issue : 6/3/2016 Version :3 5/17
Section 7. Handling and storage
Advice on general : Eating, drinking and smoking should be prohibited in areas where this material is
occupational hygiene handled, stored and processed. Workers should wash hands and face before eating,
drinking and smoking. Remove contaminated clothing and protective equipment before
entering eating areas. See also Section 8 for additional information on hygiene
measures.

Conditions for safe storage, : Store in accordance with local regulations. Store away from direct sunlight in a dry, cool
including any and well-ventilated area, away from incompatible materials (see Section 10) and food
incompatibilities and drink. Protect from sunlight. Store locked up. Eliminate all ignition sources. Use
appropriate containment to avoid environmental contamination.

Section 8. Exposure controls/personal protection


Control parameters
Occupational exposure limits (OSHA United States)
Ingredient name Exposure limits
Acetone ACGIH TLV (United States, 3/2015).
TWA: 250 ppm 8 hours.
STEL: 500 ppm 15 minutes.
NIOSH REL (United States, 10/2013).
TWA: 250 ppm 10 hours.
TWA: 590 mg/m³ 10 hours.
OSHA PEL (United States, 2/2013).
TWA: 1000 ppm 8 hours.
TWA: 2400 mg/m³ 8 hours.
Propane NIOSH REL (United States, 10/2013).
TWA: 1000 ppm 10 hours.
TWA: 1800 mg/m³ 10 hours.
OSHA PEL (United States, 2/2013).
TWA: 1000 ppm 8 hours.
TWA: 1800 mg/m³ 8 hours.
Butane NIOSH REL (United States, 10/2013).
TWA: 800 ppm 10 hours.
TWA: 1900 mg/m³ 10 hours.
ACGIH TLV (United States, 3/2015).
STEL: 1000 ppm 15 minutes.
Toluene OSHA PEL Z2 (United States, 2/2013).
TWA: 200 ppm 8 hours.
CEIL: 300 ppm
AMP: 500 ppm 10 minutes.
NIOSH REL (United States, 10/2013).
TWA: 100 ppm 10 hours.
TWA: 375 mg/m³ 10 hours.
STEL: 150 ppm 15 minutes.
STEL: 560 mg/m³ 15 minutes.
ACGIH TLV (United States, 3/2015).
TWA: 20 ppm 8 hours.
Lt. Aliphatic Hydrocarbon Solvent None.
Titanium Dioxide ACGIH TLV (United States, 3/2015).
TWA: 10 mg/m³ 8 hours.
OSHA PEL (United States, 2/2013).
TWA: 15 mg/m³ 8 hours. Form: Total dust
Naphthalene ACGIH TLV (United States, 3/2015).
Absorbed through skin.
TWA: 10 ppm 8 hours.
TWA: 52 mg/m³ 8 hours.
NIOSH REL (United States, 10/2013).
TWA: 10 ppm 10 hours.
Date of issue/Date of revision : 6/4/2016 Date of previous issue : 6/3/2016 Version :3 6/17
Section 8. Exposure controls/personal protection
TWA: 50 mg/m³ 10 hours.
STEL: 15 ppm 15 minutes.
STEL: 75 mg/m³ 15 minutes.
OSHA PEL (United States, 2/2013).
TWA: 10 ppm 8 hours.
TWA: 50 mg/m³ 8 hours.

Methyl Ethyl Ketoxime AIHA WEEL (United States, 10/2011). Skin


sensitizer.
TWA: 10 ppm 8 hours.

Occupational exposure limits (Canada)


Ingredient name Exposure limits
Acetone CA Alberta Provincial (Canada, 4/2009).
8 hrs OEL: 1200 mg/m³ 8 hours.
15 min OEL: 1800 mg/m³ 15 minutes.
8 hrs OEL: 500 ppm 8 hours.
15 min OEL: 750 ppm 15 minutes.
CA British Columbia Provincial (Canada,
5/2015).
TWA: 250 ppm 8 hours.
STEL: 500 ppm 15 minutes.
CA Ontario Provincial (Canada, 7/2015).
TWA: 500 ppm 8 hours.
STEL: 750 ppm 15 minutes.
CA Quebec Provincial (Canada, 1/2014).
TWAEV: 500 ppm 8 hours.
TWAEV: 1190 mg/m³ 8 hours.
STEV: 1000 ppm 15 minutes.
STEV: 2380 mg/m³ 15 minutes.
CA Saskatchewan Provincial (Canada,
7/2013).
STEL: 750 ppm 15 minutes.
TWA: 500 ppm 8 hours.
Propane CA Alberta Provincial (Canada, 4/2009).
8 hrs OEL: 1000 ppm 8 hours.
CA British Columbia Provincial (Canada,
5/2015).
TWA: 1000 ppm 8 hours.
CA Quebec Provincial (Canada, 1/2014).
TWAEV: 1000 ppm 8 hours.
TWAEV: 1800 mg/m³ 8 hours.
CA Ontario Provincial (Canada, 7/2015).
TWA: 1000 ppm 8 hours.
CA Saskatchewan Provincial (Canada,
7/2013).
STEL: 1250 ppm 15 minutes.
TWA: 1000 ppm 8 hours.
Butane CA Alberta Provincial (Canada, 4/2009).
8 hrs OEL: 1000 ppm 8 hours.
CA British Columbia Provincial (Canada,
5/2015).
TWA: 600 ppm 8 hours.
STEL: 750 ppm 15 minutes.
CA Quebec Provincial (Canada, 1/2014).
TWAEV: 800 ppm 8 hours.
TWAEV: 1900 mg/m³ 8 hours.

Date of issue/Date of revision : 6/4/2016 Date of previous issue : 6/3/2016 Version :3 7/17
Section 8. Exposure controls/personal protection
CA Ontario Provincial (Canada, 7/2015).
TWA: 800 ppm 8 hours.
CA Saskatchewan Provincial (Canada,
7/2013).
STEL: 1250 ppm 15 minutes.
TWA: 1000 ppm 8 hours.
Toluene CA Alberta Provincial (Canada, 4/2009).
Absorbed through skin.
8 hrs OEL: 50 ppm 8 hours.
8 hrs OEL: 188 mg/m³ 8 hours.
CA British Columbia Provincial (Canada,
5/2015).
TWA: 20 ppm 8 hours.
CA Ontario Provincial (Canada, 7/2015).
TWA: 20 ppm 8 hours.
CA Quebec Provincial (Canada, 1/2014).
Absorbed through skin.
TWAEV: 50 ppm 8 hours.
TWAEV: 188 mg/m³ 8 hours.
CA Saskatchewan Provincial (Canada,
7/2013). Absorbed through skin.
STEL: 60 ppm 15 minutes.
TWA: 50 ppm 8 hours.
Naphthalene CA Alberta Provincial (Canada, 4/2009).
Absorbed through skin.
15 min OEL: 15 ppm 15 minutes.
8 hrs OEL: 10 ppm 8 hours.
8 hrs OEL: 52 mg/m³ 8 hours.
15 min OEL: 79 mg/m³ 15 minutes.
CA British Columbia Provincial (Canada,
5/2015). Absorbed through skin.
TWA: 10 ppm 8 hours.
STEL: 15 ppm 15 minutes.
CA Ontario Provincial (Canada, 7/2015).
Absorbed through skin.
TWA: 10 ppm 8 hours.
STEL: 15 ppm 15 minutes.
CA Quebec Provincial (Canada, 1/2014).
TWAEV: 10 ppm 8 hours.
TWAEV: 52 mg/m³ 8 hours.
STEV: 15 ppm 15 minutes.
STEV: 79 mg/m³ 15 minutes.
CA Saskatchewan Provincial (Canada,
7/2013). Absorbed through skin.
STEL: 15 ppm 15 minutes.
TWA: 10 ppm 8 hours.
Methyl Ethyl Ketoxime AIHA WEEL (United States, 10/2011). Skin
sensitizer.
TWA: 10 ppm 8 hours.

Appropriate engineering : Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or
controls other engineering controls to keep worker exposure to airborne contaminants below any
recommended or statutory limits. The engineering controls also need to keep gas,
vapor or dust concentrations below any lower explosive limits. Use explosion-proof
ventilation equipment.
Environmental exposure :
controls

Date of issue/Date of revision : 6/4/2016 Date of previous issue : 6/3/2016 Version :3 8/17
Section 8. Exposure controls/personal protection
Emissions from ventilation or work process equipment should be checked to ensure
they comply with the requirements of environmental protection legislation. In some
cases, fume scrubbers, filters or engineering modifications to the process equipment
will be necessary to reduce emissions to acceptable levels.

Individual protection measures


Hygiene measures : Wash hands, forearms and face thoroughly after handling chemical products, before
eating, smoking and using the lavatory and at the end of the working period.
Appropriate techniques should be used to remove potentially contaminated clothing.
Contaminated work clothing should not be allowed out of the workplace. Wash
contaminated clothing before reusing. Ensure that eyewash stations and safety
showers are close to the workstation location.
Eye/face protection : Safety eyewear complying with an approved standard should be used when a risk
assessment indicates this is necessary to avoid exposure to liquid splashes, mists,
gases or dusts. If contact is possible, the following protection should be worn, unless
the assessment indicates a higher degree of protection: chemical splash goggles.
Skin protection
Hand protection : Chemical-resistant, impervious gloves complying with an approved standard should be
worn at all times when handling chemical products if a risk assessment indicates this is
necessary. Considering the parameters specified by the glove manufacturer, check
during use that the gloves are still retaining their protective properties. It should be
noted that the time to breakthrough for any glove material may be different for different
glove manufacturers. In the case of mixtures, consisting of several substances, the
protection time of the gloves cannot be accurately estimated.
Body protection : Personal protective equipment for the body should be selected based on the task being
performed and the risks involved and should be approved by a specialist before
handling this product. When there is a risk of ignition from static electricity, wear anti-
static protective clothing. For the greatest protection from static discharges, clothing
should include anti-static overalls, boots and gloves.
Other skin protection : Appropriate footwear and any additional skin protection measures should be selected
based on the task being performed and the risks involved and should be approved by a
specialist before handling this product.
Respiratory protection : Based on the hazard and potential for exposure, select a respirator that meets the
appropriate standard or certification. Respirators must be used according to a
respiratory protection program to ensure proper fitting, training, and other important
aspects of use.

Section 9. Physical and chemical properties


Appearance
Physical state : Liquid.
Color : Not available.
Odor : Not available.
Odor threshold : Not available.
pH : Not available.
Melting point : Not available.
Boiling point : Not available.
Flash point : Closed cup: -29°C (-20.2°F) [Pensky-Martens Closed Cup]
Evaporation rate : 5.6 (butyl acetate = 1)
Flammability (solid, gas) : Not available.
Lower and upper explosive : Lower: 0.9%
(flammable) limits Upper: 12.8%
Vapor pressure : 13.5 kPa (101.325 mm Hg) [at 20°C]
Vapor density : 1.55 [Air = 1]

Date of issue/Date of revision : 6/4/2016 Date of previous issue : 6/3/2016 Version :3 9/17
Section 9. Physical and chemical properties
Relative density : 0.75
Solubility : Not available.
Partition coefficient: n- : Not available.
octanol/water
Auto-ignition temperature : Not available.
Decomposition temperature : Not available.
Viscosity : Kinematic (room temperature): <0.205 cm2/s (<20.5 cSt)
Kinematic (40°C (104°F)): <0.205 cm2/s (<20.5 cSt)
Molecular weight : Not applicable.
Aerosol product
Type of aerosol : Spray
Heat of combustion : 29.89 kJ/g

Section 10. Stability and reactivity


Reactivity : No specific test data related to reactivity available for this product or its ingredients.

Chemical stability : The product is stable.

Possibility of hazardous : Under normal conditions of storage and use, hazardous reactions will not occur.
reactions

Conditions to avoid : Avoid all possible sources of ignition (spark or flame).

Incompatible materials : No specific data.

Hazardous decomposition : Under normal conditions of storage and use, hazardous decomposition products should
products not be produced.

Section 11. Toxicological information


Information on toxicological effects
Acute toxicity
Product/ingredient name Result Species Dose Exposure
Acetone LD50 Oral Rat 5800 mg/kg -
Butane LC50 Inhalation Vapor Rat 658000 mg/m³ 4 hours
Toluene LC50 Inhalation Vapor Rat 49 g/m³ 4 hours
LD50 Oral Rat 636 mg/kg -
Naphthalene LD50 Dermal Rabbit >20 g/kg -
LD50 Oral Rat 490 mg/kg -
Methyl Ethyl Ketoxime LD50 Oral Rat 930 mg/kg -
Irritation/Corrosion
Product/ingredient name Result Species Score Exposure Observation
Acetone Eyes - Mild irritant Human - 186300 parts -
per million
Eyes - Mild irritant Rabbit - 10 microliters -
Eyes - Moderate irritant Rabbit - 24 hours 20 -
milligrams
Eyes - Severe irritant Rabbit - 20 milligrams -
Skin - Mild irritant Rabbit - 24 hours 500 -
milligrams
Skin - Mild irritant Rabbit - 395 -

Date of issue/Date of revision : 6/4/2016 Date of previous issue : 6/3/2016 Version :3 10/17
Section 11. Toxicological information
milligrams
Toluene Eyes - Mild irritant Rabbit - 0.5 minutes -
100
milligrams
Eyes - Mild irritant Rabbit - 870 -
Micrograms
Eyes - Severe irritant Rabbit - 24 hours 2 -
milligrams
Skin - Mild irritant Pig - 24 hours 250 -
microliters
Skin - Mild irritant Rabbit - 435 -
milligrams
Skin - Moderate irritant Rabbit - 24 hours 20 -
milligrams
Skin - Moderate irritant Rabbit - 500 -
milligrams
Titanium Dioxide Skin - Mild irritant Human - 72 hours 300 -
Micrograms
Intermittent
Naphthalene Skin - Mild irritant Rabbit - 495 -
milligrams
Skin - Severe irritant Rabbit - 24 hours 0.05 -
Mililiters
Methyl Ethyl Ketoxime Eyes - Severe irritant Rabbit - 100 -
microliters
Sensitization
Not available.
Mutagenicity
Not available.
Carcinogenicity
Not available.
Classification
Product/ingredient name OSHA IARC NTP
Toluene - 3 -
Titanium Dioxide - 2B -
Naphthalene - 2B Reasonably anticipated to be a human carcinogen.
Reproductive toxicity
Not available.
Teratogenicity
Not available.
Specific target organ toxicity (single exposure)
Name Category Route of Target organs
exposure
Acetone Category 3 Not applicable. Respiratory tract
irritation and
Narcotic effects
Propane Category 3 Not applicable. Respiratory tract
irritation and
Narcotic effects
Butane Category 3 Not applicable. Respiratory tract
irritation and
Narcotic effects
Toluene Category 3 Not applicable. Respiratory tract
Date of issue/Date of revision : 6/4/2016 Date of previous issue : 6/3/2016 Version :3 11/17
Section 11. Toxicological information
irritation and
Narcotic effects
Lt. Aliphatic Hydrocarbon Solvent Category 3 Not applicable. Respiratory tract
irritation and
Narcotic effects
Naphthalene Category 3 Not applicable. Respiratory tract
irritation and
Narcotic effects
Specific target organ toxicity (repeated exposure)
Name Category Route of Target organs
exposure
Acetone Category 2 Not determined Not determined
Propane Category 2 Not determined Not determined
Butane Category 2 Not determined Not determined
Toluene Category 2 Not determined Not determined
Lt. Aliphatic Hydrocarbon Solvent Category 2 Not determined Not determined
Naphthalene Category 2 Not determined Not determined
Aspiration hazard
Name Result
Propane ASPIRATION HAZARD - Category 1
Butane ASPIRATION HAZARD - Category 1
Toluene ASPIRATION HAZARD - Category 1
Lt. Aliphatic Hydrocarbon Solvent ASPIRATION HAZARD - Category 1
Naphthalene ASPIRATION HAZARD - Category 1

Information on the likely : Not available.


routes of exposure
Potential acute health effects
Eye contact : Causes serious eye irritation.
Inhalation : Can cause central nervous system (CNS) depression. May cause drowsiness or
dizziness. May cause respiratory irritation.
Skin contact : Causes skin irritation. May cause an allergic skin reaction.
Ingestion : Can cause central nervous system (CNS) depression. May be fatal if swallowed and
enters airways.

Symptoms related to the physical, chemical and toxicological characteristics


Eye contact : Adverse symptoms may include the following:
pain or irritation
watering
redness
Inhalation : Adverse symptoms may include the following:
respiratory tract irritation
coughing
nausea or vomiting
headache
drowsiness/fatigue
dizziness/vertigo
unconsciousness
reduced fetal weight
increase in fetal deaths
skeletal malformations

Date of issue/Date of revision : 6/4/2016 Date of previous issue : 6/3/2016 Version :3 12/17
Skin contact : Adverse symptoms may include the following:
irritation
redness
reduced fetal weight
increase in fetal deaths
skeletal malformations
Ingestion : Adverse symptoms may include the following:
nausea or vomiting
reduced fetal weight
increase in fetal deaths
skeletal malformations

Delayed and immediate effects and also chronic effects from short and long term exposure
Short term exposure
Potential immediate : Not available.
effects
Potential delayed effects : Not available.
Long term exposure
Potential immediate : Not available.
effects
Potential delayed effects : Not available.
Potential chronic health effects
Not available.
General : May cause damage to organs through prolonged or repeated exposure. Once
sensitized, a severe allergic reaction may occur when subsequently exposed to very low
levels.
Carcinogenicity : Suspected of causing cancer. Risk of cancer depends on duration and level of
exposure.
Mutagenicity : No known significant effects or critical hazards.
Teratogenicity : Suspected of damaging the unborn child.
Developmental effects : No known significant effects or critical hazards.
Fertility effects : No known significant effects or critical hazards.

Numerical measures of toxicity


Acute toxicity estimates
Route ATE value
Oral 4539.5 mg/kg

Section 12. Ecological information


Toxicity
Product/ingredient name Result Species Exposure
Acetone Acute EC50 7200000 µg/l Fresh water Algae - Selenastrum sp. 96 hours
Acute LC50 6000000 µg/l Fresh water Crustaceans - Gammarus pulex 48 hours
Acute LC50 6900 mg/l Fresh water Daphnia - Daphnia magna 48 hours
Acute LC50 5600 ppm Fresh water Fish - Poecilia reticulata 96 hours
Chronic NOEC 4.95 mg/l Marine water Algae - Ulva pertusa 96 hours
Chronic NOEC 0.016 ml/L Fresh water Crustaceans - Daphniidae 21 days
Chronic NOEC 0.1 ml/L Fresh water Daphnia - Daphnia magna - 21 days
Neonate
Toluene Acute EC50 12500 µg/l Fresh water Algae - Pseudokirchneriella 72 hours
subcapitata

Date of issue/Date of revision : 6/4/2016 Date of previous issue : 6/3/2016 Version :3 13/17
Section 12. Ecological information
Acute EC50 11600 µg/l Fresh water Crustaceans - Gammarus 48 hours
pseudolimnaeus - Adult
Acute EC50 6000 µg/l Fresh water Daphnia - Daphnia magna - 48 hours
Juvenile (Fledgling, Hatchling,
Weanling)
Acute LC50 5500 µg/l Fresh water Fish - Oncorhynchus kisutch - Fry 96 hours
Chronic NOEC 1000 µg/l Fresh water Daphnia - Daphnia magna 21 days
Lt. Aliphatic Hydrocarbon Acute LC50 >100000 ppm Fresh water Fish - Oncorhynchus mykiss 96 hours
Solvent
Titanium Dioxide Acute LC50 >1000000 µg/l Marine water Fish - Fundulus heteroclitus 96 hours
Naphthalene Acute EC50 1600 µg/l Fresh water Daphnia - Daphnia magna - 48 hours
Neonate
Acute LC50 2350 µg/l Marine water Crustaceans - Palaemonetes 48 hours
pugio
Acute LC50 213 µg/l Fresh water Fish - Melanotaenia fluviatilis - 96 hours
Larvae
Methyl Ethyl Ketoxime Acute LC50 843000 µg/l Fresh water Fish - Pimephales promelas 96 hours

Persistence and degradability


Product/ingredient name Aquatic half-life Photolysis Biodegradability
Acetone - - Readily
Toluene - - Readily

Bioaccumulative potential
Product/ingredient name LogPow BCF Potential
Toluene - 90 low
Lt. Aliphatic Hydrocarbon - 10 to 2500 high
Solvent
Naphthalene - 36.5 to 168 low
Methyl Ethyl Ketoxime - 2.5 to 5.8 low

Mobility in soil
Soil/water partition : Not available.
coefficient (KOC)

Other adverse effects : No known significant effects or critical hazards.

Section 13. Disposal considerations


Disposal methods : The generation of waste should be avoided or minimized wherever possible. Disposal
of this product, solutions and any by-products should at all times comply with the
requirements of environmental protection and waste disposal legislation and any
regional local authority requirements. Dispose of surplus and non-recyclable products
via a licensed waste disposal contractor. Waste should not be disposed of untreated to
the sewer unless fully compliant with the requirements of all authorities with jurisdiction.
Waste packaging should be recycled. Incineration or landfill should only be considered
when recycling is not feasible. This material and its container must be disposed of in a
safe way. Empty containers or liners may retain some product residues. Do not
puncture or incinerate container.

Date of issue/Date of revision : 6/4/2016 Date of previous issue : 6/3/2016 Version :3 14/17
Section 14. Transport information
DOT TDG Mexico IATA IMDG
Classification Classification Classification
UN number UN1950 UN1950 UN1950 UN1950 UN1950

UN proper AEROSOLS AEROSOLS AEROSOLS AEROSOLS, AEROSOLS


shipping name flammable
Transport 2.1 2.1 2.1 2.1 2.1
hazard class(es)

Packing group - - - - -
Environmental No. No. No. No. No.
hazards
Additional - Product classified - - Emergency
information as per the schedules (EmS)
following sections F-D, S-U
of the
Transportation of
Dangerous Goods
Regulations: 2.
13-2.17 (Class 2).
ERG No. ERG No. ERG No.
126 126 126
Special precautions for user : Multi-modal shipping descriptions are provided for informational purposes and do not
consider container sizes. The presence of a shipping description for a particular
mode of transport (sea, air, etc.), does not indicate that the product is packaged
suitably for that mode of transport. All packaging must be reviewed for suitability
prior to shipment, and compliance with the applicable regulations is the sole
responsibility of the person offering the product for transport. People loading and
unloading dangerous goods must be trained on all of the risks deriving from the
substances and on all actions in case of emergency situations.

Transport in bulk according : Not available.


to Annex II of MARPOL and
the IBC Code
Proper shipping name : Not available.
Ship type : Not available.
Pollution category : Not available.

Section 15. Regulatory information


SARA 313
SARA 313 (40 CFR 372.45) supplier notification can be found on the Environmental Data Sheet.

Date of issue/Date of revision : 6/4/2016 Date of previous issue : 6/3/2016 Version :3 15/17
California Prop. 65
WARNING: This product contains chemicals known to the State of California to cause cancer and birth defects or other
reproductive harm.

Section 16. Other information


Hazardous Material Information System (U.S.A.)
Health * 2

Flammability 3

Physical hazards 0

The customer is responsible for determining the PPE code for this material.

Caution: HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4
representing significant hazards or risks Although HMIS® ratings are not required on SDSs under 29 CFR 1910.
1200, the preparer may choose to provide them. HMIS® ratings are to be used with a fully implemented HMIS®
program. HMIS® is a registered mark of the National Paint & Coatings Association (NPCA). HMIS® materials may
be purchased exclusively from J. J. Keller (800) 327-6868.
Procedure used to derive the classification
Classification Justification
FLAMMABLE AEROSOLS - Category 1 On basis of test data
GASES UNDER PRESSURE - Compressed gas Calculation method
SKIN CORROSION/IRRITATION - Category 2 Calculation method
SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 2A Calculation method
SKIN SENSITIZATION - Category 1 Calculation method
CARCINOGENICITY - Category 2 Calculation method
TOXIC TO REPRODUCTION (Unborn child) - Category 2 Calculation method
SPECIFIC TARGET ORGAN TOXICITY (SINGLE Calculation method
EXPOSURE) (Respiratory tract irritation) - Category 3
SPECIFIC TARGET ORGAN TOXICITY (SINGLE Calculation method
EXPOSURE) (Narcotic effects) - Category 3
SPECIFIC TARGET ORGAN TOXICITY (REPEATED Calculation method
EXPOSURE) - Category 2
ASPIRATION HAZARD - Category 1 Calculation method

History
Date of printing : 6/4/2016
Date of issue/Date of : 6/4/2016
revision
Date of previous issue : 6/3/2016
Version : 3
Key to abbreviations : ATE = Acute Toxicity Estimate
BCF = Bioconcentration Factor
GHS = Globally Harmonized System of Classification and Labelling of Chemicals
IATA = International Air Transport Association
IBC = Intermediate Bulk Container
IMDG = International Maritime Dangerous Goods
LogPow = logarithm of the octanol/water partition coefficient
MARPOL = International Convention for the Prevention of Pollution From Ships, 1973
as modified by the Protocol of 1978. ("Marpol" = marine pollution)
UN = United Nations
Notice to reader

Date of issue/Date of revision : 6/4/2016 Date of previous issue : 6/3/2016 Version :3 16/17
Section 16. Other information
It is recommended that each customer or recipient of this Safety Data Sheet (SDS) study it carefully and consult
resources, as necessary or appropriate, to become aware of and understand the data contained in this SDS and
any hazards associated with the product. This information is provided in good faith and believed to be accurate
as of the effective date herein. However, no warranty, express or implied, is given. The information presented
here applies only to the product as shipped. The addition of any material can change the composition, hazards
and risks of the product. Products shall not be repackaged, modified, or tinted except as specifically instructed
by Sherwin-Williams, including but not limited to the incorporation of non Sherwin-Williams products or the use
or addition of products in proportions not specified by Sherwin-Williams. Regulatory requirements are subject
to change and may differ between various locations and jurisdictions. The customer/buyer/user is responsible to
ensure that his activities comply with all country, federal, state, provincial or local laws. The conditions for use
of the product are not under the control of the manufacturer; the customer/buyer/user is responsible to
determine the conditions necessary for the safe use of this product. The customer/buyer/user should not use the
product for any purpose other than the purpose shown in the applicable section of this SDS without first
referring to the supplier and obtaining written handling instructions. Due to the proliferation of sources for
information such as manufacturer-specific SDS, the manufacturer cannot be responsible for SDSs obtained from
any other source.

Date of issue/Date of revision : 6/4/2016 Date of previous issue : 6/3/2016 Version :3 17/17
SAFETY DATA SHEET

Envy Foaming Disinfectant Cleaner (US)


Version Number: 1 Preparation date: 2014-08-08

1. IDENTIFICATION

Product name: Envy Foaming Disinfectant Cleaner (US)


Product Code: 04531
SDS #: MS0800465
Recommended use: •Disi
nfectant
•Thispr oductisi ntendedt obeusedneat .
Uses advised against: Uses other than those identified are not recommended

Manufacturer, importer, supplier: Canadian Headquarters


US Headquarters Diversey, Inc. - Canada
Diversey, Inc. 2401 Bristol Circle
8310 16th St. Oakville, Ontario L6H 6P1
Sturtevant, Wisconsin 53177-1964 Phone: 1-800-668-3131
Phone: 1-888-352-2249
MSDS Internet Address: www.diversey.com

Emergency telephone number: 1-800-851-7145 (U.S.); 1-651-917-6133 (Int'l)

2. HAZARDS IDENTIFICATION

Classification for the undiluted product


Flammability Extremely flammable aerosol, Category 1

Signal Word: Danger

Precautionary Statements
EXTREMELY FLAMMABLE AEROSOL. HEATING MAY CAUSE AN EXPLOSION. CONTAINS GAS UNDER PRESSURE; MAY EXPLODE IF
HEATED.
Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Do not spray on an open flame or other ignition
source. Do not pierce or burn, even after use. Do not incinerate. Protect from sunlight. Store in a well-ventilated place. Do not expose to
temperatures exceeding 50 °C (122 °F) which may cause bursting. Dispose of in accordance with all federal, state and local applicable regulations.

Health hazards not otherwise classified (HHNOC) - Not applicable


Physical hazards not otherwise classified (PHNOC) - Not applicable

Classification for the diluted product @ RTU

Envy Foaming Disinfectant Cleaner (US) 1 of 5


Precautionary Statements

3. COMPOSITION/INFORMATION ON INGREDIENTS

Classified Ingredients
Ingredient(s) CAS # Weight %
Isobutane 75-28-5 3% - < 5%
Dipropylene glycol methyl ether 34590-94-8 1% - < 3%
Tetrapotassium pyrophosphate 7320-34-5 1% - < 3%
n-Alkyl (60% C14, 30% C16, 5% C12, 5% C18) 68391-01-5 > 0.1% - < 1%
dimethyl benzyl ammonium chloride
n-Alkyl (68% C12, 32% C14) dimethyl ethylbenzyl 68956-79-6 > 0.1% - < 1%
ammonium chloride

*Exact percentages are being withheld as trade secret information

4. FIRST AID MEASURES

Undiluted Product:
Eyes: Rinse with plenty of water. If irritation occurs and persists, get medical attention.
Skin: Rinse with plenty of water. If irritation occurs and persists, get medical attention.
Inhalation: No specific first aid measures are required.
Ingestion: Rinse mouth with water.

Most Important Symptoms/Effects: No information available.


Immediate medical attention and special treatment needed Not applicable.

Diluted Product:

Eyes: Rinse with plenty of water If irritation occurs and persists, get medical attention
Skin: Rinse with plenty of water If irritation occurs and persists, get medical attention
Inhalation: No specific first aid measures are required
Ingestion: Rinse mouth with water.

5. FIRE-FIGHTING MEASURES

Specific methods: Aerosol Product - Containers may rocket or explode in heat of fire
Suitable extinguishing media: Dry chemical, water spray, foam.
Specific hazards: NFPA 30B Level 1 Aerosol.

Special protective equipment for firefighters: As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH
(approved or equivalent) and full protective gear.
Extinguishing media which must not be used for safety reasons: No information available.

6. ACCIDENTAL RELEASE MEASURES

Personal precautions: Ensure adequate ventilation. Remove all sources of ignition.


Environmental precautions Clean-up methods - large spillage. Remove all sources of ignition. Absorb spill with inert material (e.g.
and clean-up methods: dry sand or earth), then place in a chemical waste container. Use a water rinse for final clean-up.

7. HANDLING AND STORAGE

Handling: Avoid contact with skin, eyes and clothing. Wash thoroughly after handling. Keep away from open flames, hot surfaces and sources of
ignition. CONTENTS UNDER PRESSURE. Do not puncture or incinerate. FOR COMMERCIAL AND INDUSTRIAL USE ONLY.
Storage:
Pressurized container: protect from sunlight and do not expose to temperatures exceeding 50 degrees C or 120 degrees F. Exposure to heat may
cause bursting. Do not pierce or burn, even after use. NFPA 30B Level 1 Aerosol. Protect from freezing. Store in a cool, dry, well ventilated area
away from heat or open flame.
Aerosol Level (if applicable) : Level 1

Envy Foaming Disinfectant Cleaner (US) 2 of 5


8. EXPOSURE CONTROLS / PERSONAL PROTECTION

Exposure Guidelines: .

Ingredient(s) CAS # ACGIH OSHA


Isobutane 75-28-5 1000 ppm (STEL) -
Dipropylene glycol methyl ether 34590-94-8 150 ppm (STEL) Skin
100 ppm (TWA) 100 ppm (TWA)
600 mg/m3 (TWA)
Tetrapotassium pyrophosphate 7320-34-5 - -
n-Alkyl (68% C12, 32% C14) dimethyl ethylbenzyl 68956-79-6 - -
ammonium chloride
n-Alkyl (60% C14, 30% C16, 5% C12, 5% C18) 68391-01-5 - -
dimethyl benzyl ammonium chloride

Undiluted Product:
Engineering measures to reduce exposure:
None known

Personal Protective Equipment


Eye protection: No special requirements under normal use conditions.
Hand protection: No special requirements under normal use conditions.
Skin and body protection: No special requirements under normal use conditions.
Respiratory protection: No special requirements under normal use conditions.
Hygiene measures: Handle in accordance with good industrial hygiene and safety practice.

Diluted Product:

Personal Protective Equipment


Eye protection: No special requirements under normal use conditions.
Hand protection: No special requirements under normal use conditions.
Skin and body protection: No special requirements under normal use conditions.
Respiratory protection: No special requirements under normal use conditions.
Hygiene measures: Handle in accordance with good industrial hygiene and safety practice.

9. PHYSICAL AND CHEMICAL PROPERTIES:

Physical State: Pressurized Liquid Color: Clear White


Evaporation Rate: No information available Odor: Lavender Ammonia
Odor threshold: No information available. Boiling point/range: Not determined
Melting point/range: Not determined Decomposition temperature: Not determined
Autoignition temperature: No information available Solubility: Completely Soluble
Solubility in other solvents: No information available Relative Density (relative to water): 0.98
Density: 8.17 lbs/gal 0.98 Kg/L Vapor density: No information available
Bulk density: No information available Vapor pressure: No information available.
Flash point: 19 °F -7 °C Partition coefficient (n-octanol/water): No information available
Dilution Flash Point: 19 °F -7 °C Viscosity: No information available
Elemental Phosphorus: 0.30 % by wt. VOC: 7.2 % *
pH: 12.1 VOC % by wt. at use dilution 7.2 % *
Dilution pH: 12.1 @ RTU Flammability (Solid or Gas): Not applicable
Metal Corrosion: Not determined
Flame Extension (inches): 0
Explosion limits: - upper: Not determined - lower: Not determined

* - Title 17, California Code of Regulations, Division 3, Chapter 1, Subchapter 8.5, Article 2, Consumer Products, Sections 94508

10. STABILITY AND REACTIVITY

Reactivity: Not Applicable


Stability: The product is stable
Hazardous decomposition products: None reasonably foreseeable.
Materials to avoid: None known.
Conditions to avoid: Keep away from open flames, hot surfaces and sources of ignition.

11. TOXICOLOGICAL INFORMATION

Envy Foaming Disinfectant Cleaner (US) 3 of 5


Information on likely routes of exposure:
Skin contact, Eye contact, Inhalation, Ingestion

Delayed, immediate, or chronic effects and symptoms from short and long-term exposure
Skin contact: Unlikely to be irritant in normal use.
Eye contact: May be mildly irritating to eyes.
Ingestion: No information available.
Inhalation: No information available.
Sensitization: No known effects.

Numerical measures of toxicity

12. ECOLOGICAL INFORMATION

Ecotoxicity: No information available.

Persistence and Degradability: No information available.

Bioaccumulation: No information available.

13. DISPOSAL CONSIDERATIONS

Waste from residues / unused products: This product, as sold, if discarded or disposed, is a hazardous waste according to Federal regulations
(40 CFR 261.4 (b)(4)). Dispose in compliance with all Federal, state, provincial, and local laws and regulations. If possible, recycle empty aerosol
cans to the nearest steel recycling center.
Contaminated Packaging: Do not re-use empty containers.
RCRA Hazard Class (undiluted product): D001 Ignitable Waste

14. TRANSPORT INFORMATION

DOT/TDG/IMDG: Please refer to the Diversey HazMat Library, only available through Internet Explorer, http://naextranet.diversey.com/dot/, for up
to date shipping information.

DOT (Ground) Bill of Lading Description: LTD. QTY.

IMDG (Ocean) Bill of Lading Description: UN1950, AEROSOLS, 2.1, LTD. QTY.

15. REGULATORY INFORMATION

International Inventories at CAS# Level


All components of this product are listed on the following inventories: U.S.A. (TSCA).

U.S. Regulations
EPA Reg. No. : 70627-35
This chemical is a pesticide product registered by the United States Environmental Protection Agency and is subject to certain labeling
requirements under federal pesticide law. These requirements differ from the classification criteria and hazard information required for safety data
sheets (SDS), and for workplace labels of non-pesticide chemicals. The hazard information required on the pesticide label is reproduced below. The
pesticide label also includes other important information, including directions for use.
FIFRA Text CAUTION: Causes moderate eye irritation. Avoid contact with eyes, skin or clothing. Wash thoroughly
with soap and water after handling. PHYSICAL AND CHEMICAL HAZARDS: CONTENTS UNDER
PRESSURE. Do not use or store near heat or open flame. Do not puncture or incinerate container.
Exposure to temperatures above 130° F may cause bursting.

California Proposition 65: This product is not subject to the reporting requirements under California's Proposition 65.

RIGHT TO KNOW (RTK)


Ingredient(s) CAS # MARTK: NJRTK: PARTK: RIRTK:

Envy Foaming Disinfectant Cleaner (US) 4 of 5


Water 7732-18-5 - - - -
Isobutane 75-28-5 X X X -
Dipropylene glycol methyl ether 34590-94-8 X X X -
Tetrapotassium pyrophosphate 7320-34-5 - - - -

CERCLA/ SARA
Ingredient(s) CAS # Weight % CERCLA/SARA RQ (lbs) Section 302 TPQ (lbs) Section 313
Dipropylene glycol methyl ether 34590-94-8 1% - < 3% X

Ingredient(s) CAA HAP CAA ODS CWA Priority Pollutants


Dipropylene glycol methyl ether X

SARA 311/312 Hazard Categories


Immediate: -
Delayed: -
Fire: X
Reactivity: -
Sudden Release of Pressure: X

Canada
WHMIS hazard class: Not for sale in Canada.

16. OTHER INFORMATION


NFPA
Health 1
Flammability 4
Instability 0

Version Number: 1
Preparation date: 2014-08-08

Reason for revision: Not applicable


Prepared by: NAPRAC
Additional advice: •Cont ai
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Notice to Reader: This document has been prepared using data from sources considered technically reliable. It does not constitute a warranty,
express or implied, as to the accuracy of the information contained within. Actual conditions of use and handling are beyond seller's control. User is
responsible to evaluate all available information when using product for any particular use and to comply with all Federal, State, Provincial and
Local laws and regulations.

Envy Foaming Disinfectant Cleaner (US) 5 of 5


Material Safety Data Sheet
_______________________________________________

Revision Date 13-Sep-2013

1. CHEMICAL PRODUCT AND COMPANY Eye contact Flush with plenty of water for at least 15 minutes.
Seek medical attention.
INFORMATION
Skin contact Wash area thoroughly with soap and water.
Product code P91010 Remove and wash contaminated clothing before
Product name ETP Gold Cutting Fluid re-use. Seek medical attention if irritation persists.
Recommended Use Lubricant
Ingestion Do Not induce vomiting. Seek medical attention
Supplier Lawson Products, Inc. immediately.
8770 W.Bryn Mawr Ave.- Suite 900
Chicago, IL 60631 Inhalation Remove from exposure. Restore breathing. Keep
1-866-529-7664 warm and quiet. Contact physician if breathing
difficulty develops.
Emergency telephone number (888) 426-4851
5. FIRE FIGHTING MEASURES
2. HAZARDS IDENTIFICATION
Flash point °C > 93
Emergency Overview Flash point °F > 200
Irritant. Contents under pressure. Method Tag Closed Cup

Autoignition temperature °C Not Applicable


Aggravated Medical Conditions
Pre-existing skin sensitivity. May cause allergic skin reaction. Autoignition temperature °F Not Applicable

Principal Routes of Exposure Flammability Limits (% in Air)


Eyes. Inhalation. Skin contact. Upper No data available
Lower No data available
Potential health effects

Eyes May cause the following effects:. Irritation. Suitable extinguishing media
Redness. Itching. Burning sensation. Carbon dioxide (CO2). Alcohol foam. Dry chemical.

Skin Repeated or prolonged exposure may cause:. Skin Special protective equipment for firefighters
Irritation. Redness. Itching. Burning sensation. As in any fire, wear self-contained breathing apparatus pressure-demand,
MSHA/NIOSH (approved or equivalent) and full protective gear.
Inhalation Repeated or prolonged exposure may cause the
following effects:. Headaches. Dizziness. Nausea. Fire and Explosion Hazards
Irritating to respiratory system. Keep product and empty container away from heat and sources of
ignition. Containers may vent or burst under extreme or prolonged fire
No hazard under normal industrial and institutional conditions. Water should be used to cool closed containers to prevent
Ingestion
use. pressure build-up and possible autoignition or explosion when exposed to
extreme heat . Water spray may be ineffective. If water is used, fog
nozzles are preferable. During emergency conditions, overexposure to
decomposition products may cause a health hazard. Symptoms may not
be immediately apparent. Obtain medical attention.
3. COMPOSITION / INFORMATION ON INGREDIENTS
Sensitivity to shock
No information available.
Chemical Name CAS-No Weight %
Triethanolamine 102-71-6 7-13 Sensitivity to static discharge
Diethanolamine 111-42-2 0.5-1.5 No information available.

4. FIRST AID MEASURES 6. ACCIDENTAL RELEASE MEASURES

_______________________________________________

Page 1 / 3
Product code P91010 Product name ETP Gold
Cutting Fluid
_______________________________________________

6. ACCIDENTAL RELEASE MEASURES


Methods for cleaning up 9. PHYSICAL AND CHEMICAL PROPERTIES
Eliminate all sources of ignition. Ventilate area to maintain exposure
below permissible exposure limits. Soak up with inert absorbent material.
Form Aerosol
Color No information available
7. HANDLING AND STORAGE Odor No information available
Odor Threshold No information available
Handling pH 9.0
Avoid contact with skin and eyes. Avoid breathing vapors or mists. Keep Specific Gravity 1.06
container closed when not in use. Do not take internally. Keep out of Vapor pressure No data available
reach of children. Density 8.84 lbs/gal, 1059 g/l
Vapor density >1 (air=1)
Storage Evaporation Rate <1 (ether = 1)
Keep in properly labelled containers. Keep out of the reach of children. Water solubility No data available
VOC Content 0.11 lbs/gal; 13 g/l
NFPA Storage Code Partition Coefficient No data available
Store as Level 3 Aerosol (NFPA 30B) (n-octanol/water)
Boiling point/range °C 100 - 269
Boiling point/range °F 212 - 517
8. EXPOSURE CONTROLS / PERSONAL Melting point/range °C No data available
PROTECTION Melting point/range °F No data available
Flash point °C > 93
Flash point °F > 200
Chemical OSHA PEL OSHA PEL ACGIH OEL ACGIH OEL
Name (TWA) (Ceiling) (TWA) (STEL)
Diethanolamin - - 1 mg/m3 -
e 10. STABILITY AND REACTIVITY
Triethanolami - - 5 mg/m3 -
ne
Stability
Stable.
Ventilation and Environmental Controls
Use enough ventilation, local exhaust at the work area, general, or both, Conditions to avoid
to keep below the TLV's in the worker's breathing zone and the general None known.
area. General: as necessary.
Incompatability
Hygiene measures None.
Wash hands before breaks and immediately after handling the product.
Avoid contact with skin, eyes and clothing. Hazardous Decomposition Products
By fire:. Carbon dioxide. Carbon monoxide.
Other precautions
Avoid breathing vapors or mists. Polymerization
Will not occur.
Respiratory protection
Avoid breathing concentrated vapors or particles from all products not
specifically designed to be inhaled. Wear a NIOSH approved organic 11. TOXICOLOGICAL INFORMATION
vapor/particulate respirator.
Component Information
Hand Protection
Consult glove manufacturer to determine the proper type for a specific
Chemical Name LD50 LD50 LC50 (inhalation,rat)
operation. Use of a barrier cream on exposed skin is highly
(oral,rat (dermal
recommended .
) ,rat/rab
bit)
Eye protection
Wear safety glasses with side shields. Diethanolamine - - -
111-42-2
Skin and body protection Triethanolamine 4190 20 -
None necessary under normal conditions 102-71-6 mg/kg mL/kg

Other Protective Equipment Synergistic Products None known


A safety shower and eye wash station should be available for emergency
use. Potential health effects

Sensitization None known

_______________________________________________

Page 2 / 3
Product code P91010 Product name ETP Gold
Cutting Fluid
_______________________________________________

Chronic toxicity See Section 2 .


Chemical Name New Jersey - Pennsylvania California
Mutagenic effects None known RTK - RTK Prop. 65
Diethanolamine Listed Listed Carcinogen
Teratogenic effects None known Triethanolamine Not Listed Listed Not Listed

Reproductive toxicity None known

Target Organ Effects See Section 2 International Inventories


Carcinogenic effects See table below
Chemical Name EINECS DSL NDSL TSCA
Diethanolamine X X - X
Chemical ACGIH IARC NTP - NTP - OSHA
Triethanolamine X X - X
Name OEL - Known Suspected RTK
Carcinoge Carcinoge Human Carcinoge
ns ns Carcinoge ns CPR
ns This product has been classified in accordance with the hazard criteria of
Diethanolamin A3 Group 2B Not Listed Not Listed Listed the Controlled Product Regulations and the MSDS contains all of the
e information required by the Controlled Product Regulations
Triethanolami Not Listed Not Listed Not Listed Not Listed Not Listed
ne
16. OTHER INFORMATION
12. ECOLOGICAL INFORMATION
HMIS
Diethanolamine
Microtox Data Health - 2
Photobacterium phosphoreum EC50=73 mg/L (5 min) Flammability - 1
Pseudomonas fluorescens EC50>16 mg/L (16 h) Physical Hazard - 0
Pseudomonas putida EC50>16 mg/L (16 h)
Water Flea Data
Daphnia magna EC50=55 mg/L (48 h) Prepared By V. Shargorodsky, Regulatory Affairs
Engineer

Ecotoxicity effects No information available The information accumulated herein is believed to be accurate, but is not
warranted to be, whether originating with the company or not. Recipients
13. DISPOSAL CONSIDERATIONS are advised to confirm in advance of need that the information is current,
applicable, and suitable to their circumstances.

Disposal Information
As supplied, this product is classified as non-hazardous waste according
to RCRA regulations. Wastes resulting from the use of this product may
be disposed of on site or at an approved waste disposal facility. Do not
incinerate. Dispose in accordance with federal, state, and local
regulations.

14. TRANSPORTATION INFORMATION

DOT
Not Regulated

TDG
Not Regulated

15. REGULATORY INFORMATION

Chemical Name US EPA SARA 313 Emission Reporting


Diethanolamine Listed

State Regulations

_______________________________________________

Page 3 / 3
MATERIAL SAFETY DATA SHEET

Date Printed: 07/25/2008 Page: 1


Product Code(s): 1273

________________________________________________________________________________

1. CHEMICAL PRODUCT AND COMPANY INFORMATION

Product Name: European Auto Coat

Product Code(s): 1273

Manufacturer/Supplier: TRANSTAR AUTOBODY TECHNOLOGIES


2040 Heiserman Dr.
Brighton, MI, 48114, USA

24 Hour Emergency Phone(s): 800-424-9300 (CHEMTREC), 613-996-6666 (CANUTEC)

Business Phone: 810-220-3000

Product Use: Specialty Coating

MSDS Prepared By: Transtar Autobody Technologies

________________________________________________________________________________

2. COMPOSITION/INFORMATION ON INGREDIENTS

Ingredient(s) CAS Number % by Weight


---------------------------------------------------------------------------
Acetone 67-64-1 25- 40%
* Methylbenzene; Toluene 108-88-3 15- 25%
Propane 74-98-6 15.5
n-Butane 106-97-8 9.0
* Methyl Ethyl Ketone (MEK) 78-93-3 5 - 10%
* Propylene Glycol Monomethyl Ether Acetate108-65-6 0 - 5%
* Ethylene Glycol Monobutyl Ether 111-76-2 0 - 5%
Carbon Black Pigment 1333-86-4 0 - 5%

See Section 15. Regulatory Information for code descriptions


Weight percent (%) of 0.0 means chemical is in trace amounts.

________________________________________________________________________________

3. HAZARDS IDENTIFICATION

DANGER: EXTREMELY FLAMMABLE. CONTENTS UNDER PRESSURE. Aerosol cans


produce flammable vapors which can travel to a source of ignition and flash
back. IRRITANT.

HMIS Hazard Ratings: Health =3 , Flammability =4, Chemical Reactivity =0

Note: HMIS ratings involve data and interpretations that may vary
from company to company. They are intended only for rapid, general
identification of the magnitude of the specific hazard. To deal
adequately with the safe handling of this material, all the
information contained in this MSDS must be considered.

Potential Health Effects

Eyes: Moderate irritation to the eyes.

Skin: Moderate irritation to the skin.


MATERIAL SAFETY DATA SHEET

Date Printed: 07/25/2008 Page: 2


Product Code(s): 1273

________________________________________________________________________________
Inhalation: Moderate irritation to the respiratory system. May be harmful
if inhaled. High concentrations may be fatal.

Ingestion: Moderate irritation to the digestive tract.

________________________________________________________________________________

4. FIRST AID MEASURES

Seek professional medical attention for all over-exposures and/or


persistent problems.

Eyes Contact: Flush eyes with clean water for a minimum of 15 minutes.
Seek medical attention.

Skin Contact: Wash exposed area thoroughly with soap and water.

Inhalation: Remove person from area to fresh air. If breathing


difficulty persists, seek medical attention.

Ingestion: DO NOT INDUCE VOMITTING. Seek immediate medical attention.

________________________________________________________________________________

5. FIRE FIGHTING MEASURES

Flammable Properties

Flash Point: -4 Deg F, -20 Deg CMethod: TCC


Upper Explosive Limit (UEL): 12.8
Lower Explosive Limit (LEL): 1.1
Autoignition Temperature: No data

Extinguishing Media: Foam, Alcohol Foam, CO2, Dry Chemical, Water Fog,
Other.

Special Firefighting Procedures: Full fire fighter equipment including


SCBA should be worn to avoid skin contact and inhalation of
concentrated vapors. Minimize skin exposure. Highly toxic fumes may
be generated by thermal decomposition.

Hazardous Combustion Products: Carbon monoxide, carbon dioxide, oxides


of nitrogen.

Unusual Fire and Explosion Hazards: Vapors can travel to a source of


ignition and flash back. Aerosol cans contain flammable, pressurized
propellant. Cans will explode when exposed to flame, high heat and
temperatures. Combustion generates toxic fumes.

________________________________________________________________________________

6. ACCIDENTAL RELEASE MEASURES

For large spills or transportation accidents involving release of this


product, contact the Emergency Response Center: 800-424-9300.

Eliminate all sources of ignition, provide adequate ventilation, dike


spill area and add absorbent earth or sawdust to spilled liquid. Sweep
up and dispose of in appropriate containers in accordance with
Federal, State and/or Local regulations.
MATERIAL SAFETY DATA SHEET

Date Printed: 07/25/2008 Page: 3


Product Code(s): 1273

________________________________________________________________________________

________________________________________________________________________________

7. HANDLING AND STORAGE

Aerosol cans contain pressurized, flammable propellent. Cans will


burst if exposed to extreme heat or temperatures. Keep spray nozzle
pointed away from face and do not direct nozzle spray towards people
or animals. Avoid hot surfaces. Use in cool, well-ventilated areas.
Keep aerosol can capped when not in use. Keep away from excessive
heat and open flames. Follow all MSDS/label precautions even after
container is emptied because they may retain product residues. Store
in a cool area away from heat and flames. Do not reuse container when
empty.

________________________________________________________________________________

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Exposure Guidelines

Chemical Name/Exposure Limits CAS Number


---------------------------------------------------------------------------

Acetone 67-64-1
OSHA PEL: 1000 ppm, ACGIH TLV: 500 ppm, OTHER: STEL 750 ppm
* Methylbenzene; Toluene 108-88-3
OSHA PEL: 200 ppm, 300 ppm ceiling
ACGIH TLV: 50 ppm (skin)
IDLH: 500 ppm
Propane 74-98-6
OTHER: TWA1000ppm
n-Butane 106-97-8
OTHER: TWA 800ppm
* Methyl Ethyl Ketone (MEK) 78-93-3
OSHA PEL: 200 ppm, ACGIH TLV: 200 ppm, OTHER: STEL 300 ppm
* Propylene Glycol Monomethyl Ether Acetate 108-65-6
OSHA PEL: N/A, ACGIH TLV: N/A, OTHER: N/A
* Ethylene Glycol Monobutyl Ether 111-76-2
OSHA PEL: 50ppm, ACGIH TLV: 20ppm
Carbon Black Pigment 1333-86-4
OSHA PEL: 3.5 mg/m3, ACGIH TLV: 3.5mg/m3

Engineering Controls: General mechanical ventilation or local exhaust


should be utilized to keep vapor concentrations below exposure limits
(PEL & TLV). Ventilation equipment must be explosion proof.

Respiratory Protection: Utilize engineering controls to reduce


emission levels below the time weighted exposure limits (ACGIH TLV &
OSHA PEL). Wear an approved respirator if exposure limits are above
the exposure limits listed above.

Eye Protection: Use safety glasses or splash goggles.

Skin Protection: Use chemical resistant gloves.

Safe Work Practices: Eye washes and safety showers in the workplace
are recommended. Avoid contact with skin and eyes. Avoid breathing
vapors. Wash hands thoroughly after using and before eating, drinking
or smoking. Employee education and training in the safe use and
MATERIAL SAFETY DATA SHEET

Date Printed: 07/25/2008 Page: 4


Product Code(s): 1273
________________________________________________________________________________
handling of this product is required under the OSHA Hazard
Communication Standard 29CFR1200. When spraying an aerosol can, use
ventilation to minimize vapors. Smoking in area where this material
is used should be strictly prohibited. Always use protective clothing
and equipment. Remove all contaminated clothing and wash thoroughly
when finished working. Keep food and drink away from material and
from area where material is being used.

________________________________________________________________________________

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical Form: Homogeneous mixture


Physical State: Liquid
Color: Black
Odor: Organic solvent
Odor Threshold: No Data
Specific Gravity (water=1) 0.75
Vapor Pressure: No data
Vapor Density: Heavier than air
Material VOC: 3.40 lb/gl 407 g/l
Coating VOC: 5.37 lb/gl 644 g/l
Evaporation Rate: Faster than ether.
Boiling Point: -44øF
Melting Point: No data
Freezing Point: No data
Viscosity at Ambient Temperature: No data
Solubility in Water: Insoluble
Octanol/Water Partition Coefficient: No data
pH: No data

________________________________________________________________________________

10. STABILITY AND REACTIVITY

Stability: Stable

Incompatibility: Strong acids, strong bases and strong oxidizing


agents.

Hazardous Polymerization: Will not occur.

________________________________________________________________________________

11. TOXICOLOGICAL INFORMATION

Effects of Exposure:
ACUTE:
INHALATION - Dizziness, breathing difficulty, headaches, & loss of
coordination.
EYE CONTACT - Moderate irritation, tearing, redness, and blurred
vision.
SKIN CONTACT - Moderate irritant. Can dry and defat skin causing
cracks, irritation, and dermatitis.
INGESTION - Can cause gastrointestinal irritation, vomiting, nausea, &
diarrhea.

CHRONIC:
May affect liver, kidney and central nervous system with repeated
exposure.
MATERIAL SAFETY DATA SHEET

Date Printed: 07/25/2008 Page: 5


Product Code(s): 1273

________________________________________________________________________________

Aerosol spraying may create an oxygen deficient environment. Use


proper ventilation to remove vapors, mists and fumes.
Aerosol propellents can cause asphyxia characterized by blueness of
the skin, difficulty breathing, headaches, loss of coordination and
unconsciousness.

Acute Toxicity Data: No data.

Carcinogenicity: NTP -No, IARC -Yes, OSHA -No


This product has not been tested for carcinogenic effects. Some
chemicals in this product may be identified by NTP, IARC and/or OSHA
as carcinogenic, indicated above as "Yes". No further information
available.

Teratology: No data.

Reproduction: No data.

Mutagenicity: No data.

________________________________________________________________________________

12. ECOLOGICAL INFORMATION

No data.
________________________________________________________________________________

13. DISPOSAL CONSIDERATIONS

Subject to hazardous waste generation, treatment, storage and


disposal. Product should be disposed of in accordance with all
governmental regulations. Subject to hazardous waste generation,
treatment, storage and disposal under RCRA, 40CFR261. Product should
be disposed of in accordance with all Federal, State and local
regulations.
________________________________________________________________________________

14. TRANSPORT INFORMATION

The following transportation information is provided based on Transtar


Autobody Technologies interpretation of shipping regulations. Each
shipper is responsible for identifying, naming, marking and labeling
prior to offering for transport.

USA (DOT) Status: Consumer Commodity ORM-D

Water (IMDG) Status: UN1950, AEROSOL, 2.1, Limited Quantity

Air (ICAO,IATA) Status: UN1950, AEROSOL, 2.1, Limited Quantity

Canada (TDG) Status: Consumer Commodity ORM-D


________________________________________________________________________________

15. REGULATORY INFORMATION

The information listed in this section is not all inclusive of all regulations for
this product or the chemical components of this product.
MATERIAL SAFETY DATA SHEET

Date Printed: 07/25/2008 Page: 6


Product Code(s): 1273
________________________________________________________________________________

US Federal Regulations

TSCA Status: All known major components of this product are listed on
the TSCA Inventory and/or are otherwise in compliance with TSCA.

SARA 302 (EHS) Status: No EHS chemicals present.

SARA 311/312 Status: Immediate Health Hazard, Delayed Health Hazard,


Fire Hazard.

SARA 313 Status: * Indicates toxic chemical(s) subject to the


reporting requirements of section 313 of Title III and of 40 CFR 372.

OSHA Status: This material meets the requirement of hazardous material


and is subject to 29CFR1910.1200.

USA State Information

California Proposition 65: This product contain chemical(s)


known to the State of California to cause cancer or birth defects or
other reproductive harm.

Pennsylvania RtK Status: This material contains chemical(s) subject to


notification under Pennsylvania Right to Know.

New Jersey RtK Status: This material contains chemical(s) subject to


notification under New Jersey Right to Know.

Massachusetts RtK Status: This material contains chemical(s) subject


to notification under Massachusetts Right to Know.

Rhode Island RtK Status: This material contains chemical(s) subject to


notification under Rhode Island Right to Know.

International Regulations

Canada
DSL Status: All known major components of this product are listed on
the DSL Inventory and/or are otherwise in compliance with the DSL
NDSL Status: Contains no chemicals on the NDSL
WHMIS: AB5D2B

New Zealand
HSNO Number: HSR002515

EINECS Status: All components of this material are listed on the


EINECS Inventory.
________________________________________________________________________________

16. OTHER INFORMATION

To the best of our knowledge, the information contained herein is


accurate, obtained from sources believed by Transtar Autobody
Technologies to be accurate. As with all chemicals, KEEP AWAY FROM
CHILDREN AND ANIMALS. FOR PROFESSIONAL USE ONLY. The hazard
information contained herein is offered solely for the consideration
of the user, subject to his own investigation and verification of
compliance with applicable regulations, including the safe use of the
product under every foreseeable condition.
(.
Safety Data Sheet
Prepared in accordance with Commission Regulation (EU) 20151830
Revision DateO9-02-201 6
Revision Number 7

EVERCAT
SECTION 1 Identification of the substancelmixture and of the companylundertaking

1.1 Product identifier 100632


Everglass quart
1.2 Relevant identified uses of the Automotive repair
substance or mixture and uses
advised against
1.3 Details of the supplier of the ITW Evercoat
safety data sheet
a division of Illinois Tool Works Inc.
6600 Cornell Road
Cincinnati, OH 45242
513-489-7600
1.4 Emergency telephone number CHEM TEL: +1-813-248-0591

SECTION 2 Hazards identification

2.1 Classification of the substance or mixture


Classified in Skin Corrosion/Irritation Category 2
accordance to (EC) No.
1272/2008 Senous Eye Damage/Eye Irritation Category 2
Flammable Liquid Category 3

2.2 Label e’ements


Labelling according to Regulation (EC) No 1272/2008 [CLP]

Hazard pictograms

Signal Word Warning

Hazard Statements H226 - Flammable liquid and vapour.


H315 Causes skin irritation.
-

H319 Causes serious eye irritation.


-

Precautionary P233 - Keep container tightly closed.


Statements
P280 Wear protective gloves/protective clothing/eye protection/face
-

protection.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several
-

minutes. Remove contact lenses, if present and easy to do. Continue

Page 1 of 10
Safety Data Sheet
Prepared in accordance with Commission Regulation (EU) 20151830
Revision DateO9-02-201 6
Revision Number 7
rinsing.
P403+P235 Store in a well-ventilated place. Keep cool.
-

P337+P313 If eye irritation persists: Get medical advice/attention.


-

P240 Ground/bond container and receiving equipment.


-

Supplemental Hazard EUH2O8 Contains Acid anhydride. May produce an allergic reaction.
-

information (EU)

2.3 Other hazards No data available

SECTION 3 Compositionhinformation on ingredients


3.1. Substances

Not applicable

3.2. Mixtures

Chemical Name % CAS # (EC) No 127212008 M Factor SCL


Styrene 14.41 100-42-5 Acute Tox. 4; H332 No data No data
Acute Tox. 4; H332 available available
Acute Tox. 4; H332
Eye Irrit. 2; H319
Flam. Liq. 3; H226
Skin Irrit. 2; H315
Acid anhydride 0.75 85-43-8 Aquatic Chronic 3; H412 No data No data
Eye Dam. 1; H318 available available
Resp. Sens. 1; H334
Skin Sens. 1; H317
EUH2O8
Dimethylaniline(DMA) 0.11 121-69-7 AquaticChronic2; H411 Nodata Nodata
Acute Tox. 3; H31 I available available
Acute Tox. 3; H331
Acute Tox. 3; H331
Acute Tox. 3; H301
Acute Tox. 3; H331
Carc. 2; H351

For full text of H-statements; See Section 16

SECTION 4 First aid measures


4.1 Description of first aid measures
Inhalation Remove to fresh air. If breathing is difficult, have a trained individual administer
oxygen. If not breathing, give artificial respiration and have a trained individual
administer oxygen. Get medical attention immediately Get medical attention
immediately. Keep the victim warm and quiet. If the victim has stopped breathing
open airway, loosen collar and belt, and administer artificial respiration. If breathing
is difficult, oxygen may be beneficial if administered by trained personnel,
preferably on a doctor’s advice.

Page 2 of 10
Safety Data Sheet
Prepared in accordance with Commission Regulation (EU) 2015/830
Revision DateO9-02-2016
Revision Number 7
Eye Contact Flush eyes with plenty of water for at least 20 minutes retracting eyelids often. Tilt
the head to prevent chemical from transferring to the uncontaminated eye. Get
immediate medical attention. No data available
Skin Contact Wash with soap and water. Get medical attention if irritation develops or persists.
Remove contaminated clothing and continue flushing with water. Seek medical
advice if symptoms persist Wash clothing before reuse.
Ingestion Do not induce vomiting and seek medical attention immediately. Drink two glasses
of water or milk to dilute. Provide medical care provider with this MSDS. Do not
induce vomiting unless directed to do so by medical personnel.
Self protection of No data available
the first aider

4.2 Most important symptoms and effects, both acute and delayed
Symptom See Section 4.1
4.3 Indication of any immediate medical attention and special treatment needed
Note to Doctor No additional first aid information available

SECTION 5 Firefighting measures

5.1 Extinguishing media


Suitable extinguishing media Use alcohol resistant foam, carbon dioxide, dry chemical, or
water spray when fighting fires. Water or foam may cause frothing
if liquid is burning but it still may be a useful extinguishing agent if
carefully applied to the fire. Do not direct a water stream directly
into the hot burning liquid. Carbon dioxide Dry chemical
Unsuitable extinguishing media No data available
5.2 Special hazards arising from the substance or mixture
Fire andlor Explosion Hazards Vapors may be ignited by sparks, flames or other sources of
ignition if material is above the flash point giving rise to a fire
(Class B). Vapors are heavier than air and may travel to a source
of ignition and flash back.
Hazardous Combustion Products Carbon dioxide, Carbon monoxide, Phthalic anhydride,
Hydrocarbons
5.3 Advice for firefighters
Fire Fighting Methods and Protection Do not enter fire area without proper protection including
self-contained breathing apparatus and full protective
equipment. Fight fire from a safe distance and a
protected location due to the potential of hazardous
vapors and decomposition products. Flammable
component(s) of this material may be lighter than water
and burn while floating on the surface.

SECTION 6 Accidental release measures

Page 3 of 10
Safety Data Sheet
Prepared in accordance with Commission Regulation (EU) 20151830
Revision DateO9-02-2016
Revision Number 7
C
6.1 Personal precautions,
protective equipment and
emergency procedures
For Non-emergency Personnel Non-emergency personnel should be kept clear of the area.
For emergency responders No health affects expected from the clean-up of this material if
contact can be avoided. Follow personal protective equipment
recommendations found in Section VIII of this MSDS
6.2 Environmental precautions No data available
6.3 Methods and material for No special spill clean-up considerations. Collect and discard in
containment and cleaning up regular trash. Shut off ignition sources; including electrical
equipment and flames. Do not allow smoking in the area. Use an
inert absorbent such as sand or vermiculite. Place in properly
labeled closed container.
6.4 Reference to other sections Refer to section 13 for disposal information.

SECTION 7 Handling and storage

7.1 Precautions for safe handling Mildly irritating material. Avoid unnecessary exposure. Do not
get in eyes, on skin and clothing Wash hands before eating Use
with adequate ventilation Avoid contact with material, avoid
breathing dusts or fumes, use only in a well ventilated area.
7.2 Conditions for safe storage, Store in a cool dry place. Isolate from incompatible materials.
including any incompatibilities Store in a cool dry place Keep away from heat, sparks, and

7.3 Specific end use(s)


flame Store in a tightly closed container
Automotive repair
C
SECTION 8 Exposure controlslpersonal protection
Occupational Exposure limit values

Chemical Name ACGIH TLV-TWA ACGIH STEL IDLH.


Styrene 20 ppm 40 ppm STEL; 170 No data available
mg/m3 STEL

8.2 Exoosure controls

Appropriate engineering controls No exposure limits exist for the constituents of this product. Use
local exhaust ventilation or other engineering controls to minimize
exposures and maintain operator comfort.
Individual protection measures, such as personal protective equipment

Eye and face protection Wear chemically resistant safety glasses with side shields when
handling this product. Do not wear contact lenses. None
Skin Protection
Hand protection No information available
Other skin protection Not normally considered a skin hazard. Where use can result in
skin contact, practice good personal hygiene and wear a barrier

Page 4 of 10 C
Safety Data Sheet
Prepared in accordance with Commission Regulation (EU) 20151830
Revision DateOg-02-201 6
Revision Number 7

cream and/or impervious surgical style gloves. Wash hands and


other exposed areas with mild soap and water before eating,
drinking, and when leaving work.
Respiratory Protection Respiratory protection may be required to avoid overexposure
when handling this product. General or local exhaust ventilation
is the preferred means of protection. Use a respirator if general
room ventilation is not available or sufficient to eliminate
symptoms.
Thermal hazards No data available

Environmental exposure controls No data available

SECTION 9 Physical and chemical properties


9.1 Information on basic physical and chemical properties

Appearance Paste
Colour Blue
Odour Aromatic
Odour Threshold No data available
pH Neutral
Melting point I Freezing point -30.6
(°C)
Initial boiling point and boiling 145
range (°C)
Flash Point (°C) 49
Evaporation Rate No data available
Flammability (Solid, gas) No data available
Upperliower flammability or
explosive limits
Upper Flammable/Explosive 6.1
Limit, % in air
Lower Flammable/Explosive 1.1
Limit, % in air
Vapour Pressure 5.0 mmHg @ 68 °F / 20 °C (Styrene)
Vapour Density Heavier than air. Vapors that evolve from this product will tend to
settle and accumulate near the floor.
Relative Density 1.71
Solubility(ies) No data available
Partition coefficient: n- 1.36
octanol/water
Autoignition Temperature (°C) 490
Decomposition Temperature No data available
Viscosity No data available
Explosive properties No data available
Oxidizing properties No data available

Page 5 of 10
Safety Data Sheet
Prepared in accordance with Commission Regulation (EU) 20151830

9.2 Other information No data available


Revision DateO9-02-201 6
Revision Number 7
C
SECTION 10 Stability and reactivity

10.1 Reactivity No data available


10.2 Chemical stability Stable under normal conditions.
10.3 Possibility of hazardous No data available
reactions
10.4 Conditions to avoid No data available
10.5 Incompatible materials Peroxides; Strong acids; Strong oxidizing agents
10.6 Hazardous decomposition Carbon dioxide Carbon monoxide Hydrocarbons
products

SECTION 11 Toxicological information


11.1 Information on toxicological effects

Acute Toxicity
Based on available data, the classification criteria are not met.

Skin corrosionlirritation
[ pH .
Neutral I
Classification is based on pH and the components listed in Section 3.

Serious eye damage/irritation


C
L pH J Neutral

Classification is based on pH and the components listed in Section 3.

Respiratory or skin sensitization


EUH2O8 Contains Acid anhydride. May produce an allergic reaction.
-

Based on available data, the classification criteria are not met.

Germ cell mutagenicity


Based on available data, the classification criteria are not met.

Carcinogenicity
Based on available data, the classification criteria are not met.

Reproductive toxicity
Based on available data, the classification criteria are not met.

STOT-single exposure
Based on available data, the classification criteria are not met.

STOT-repeated exposure
Based on available data, the classification criteria are not met.

Aspiration hazard

Page 6 of 10 C
Safety Data Sheet
Prepared in accordance with Commission Regulation (EU) 20151830
Revision DateO9-02-201 6
Revision Number 7
Based on available data, the classification criteria are not met.

SECTION 12 Ecological information

12.1 Toxicity No data available

Ecotoxicity Data
Chemical Name CAS Number Aquatic EC5O Aquatic ERC5O Aquatic LC5O
Crustacea Algae Fish
No data available

12.2 Persistence and No data available


degradability
12.3 Bioaccumulative No data
potential
12.4 Mobility in soil No data available
12.5 Results of PBT and No data available
vPvB assessment
12.6 Other adverse No data available
effects
12.7 Additional No data available
information

SECTION 13 Disposal considerations


13.1 Waste treatment methods
Waste Description for Spent Spent or discarded material is a hazardous waste.
Product
Disposal Methods Dispose of by incineration following Federal, State, Local, or
Provincial regulations.
Waste Disposal Code(s) W080111
(European Waste Catalogue)

SECTION 14 Transport information

Ground:
14.1 UN number: UN3269
14.2 UN proper shipping name: POLYESTER RESIN KIT
14.3 Transport hazard class(es): 3
14.4 Packing group:
Exemptions: Limited Quantity

Air:
14.1 UN number: UN3269
14.2 UN proper shipping name: POLYESTER RESIN KIT

Page 7 of 10
Safety Data Sheet
Prepared in accordance with Commission Regulation (EU) 201 5/830
Revision DateOg-02-2016
Revision Number 7
C
14.3 Transport hazard class(es): 3
14.4 Packing group: Ill

Water:
14.1 UN number: UN3269
14.2 UN proper shipping name: POLYESTER RESIN KIT
14.3 Transport hazard class(es): 3
14.4 Packing group: Ill
Exemptions: Limited Quantity

14.5 Environmental hazards: No


14.6 Special precautions for user: No data available
14.7 Transport in bulk according No data available
to Annex II of MARPOL and the
IBC Code:

SECTION 15 Regulatory information


15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture

Chemical Name EINECS SVHC

Styrene Y N
Acid anhydride
Dimethylaniline (DMA)
Aniline
Y
Y
Y
N
N
N
C
Styrene Oxide Y N

15.2 Chemical safety assessment No data available

SECTION 16 Other information

SDS Abbreviations: No data available


References: No data available
Hazard phrase(s) H226 Flammable liquid and vapour.
-

referenced in section 3
H301 - Toxic if swallowed.
H302 Harmful if swallowed.
-

H31 1 - Toxic in contact with skin.


H312 - Harmful in contact with skin.
H315 Causes skin irritation.
-

H317 May cause an allergic skin reaction.


-

H318 Causes serious eye damage.


-

H319 Causes serious eye irritation.


-

Page 8 of 10 C
Safety Data Sheet
Prepared in accordance with Commission Regulation (EU) 20151830
Revision DateOg-02-2016
Revision Number 7
H331 - Toxic if inhaled.
H332 Harmful if inhaled.
-

H334 May cause allergy or asthma symptoms or breathing difficulties if


-

inhaled.
H336 May cause drowsiness or dizziness.
-

H341 Suspected of causing genetic defects.


H350 May cause cancer.
-

H351 - Suspected of causing cancer.


H372 Causes damage to organs through prolonged or repeated exposure.
-

H400 Very toxic to aquatic life.


-

H41 I - Toxic to aquatic life with long lasting effects.


H412 Harmful to aquatic life with long lasting effects.
-

Precautionary
Statements
Prevention P201 Obtain special instructions before use.
-

P202 Do not handle until all safety precautions have been read and
-

understood.
P210 Keep away from heat/sparks/open flames/hot surfaces. No
- —

smoking.
P233 Keep container tightly closed.
-

P240 Ground/bond container and receiving equipment.


-

P241 Use explosion-proof electrical/ventilating/lighting equipment.


-

P242 Use only non-sparking tools.


-

P243 Take precautionary measures against static discharge.


-

P260 Do not breathe dust/fume/gas/mist/vapours/spray.


-

P261 Avoid breathing dust/fume/gas/mist/vapours/spray.


-

P264 Wash thoroughly after handling.


-

P270 Do no eat, drink or smoke when using this product.


-

P272 Contaminated work clothing should not be allowed out of the


-

workplace.
P273 Avoid release to the environment.
-

P280 Wear protective gloves/protective clothing/eye protection/face


-

protection.
P284 Wear respiratory protection.
-

Response P302+P352 IF ON SKIN: Wash with plenty of soap and water.


-

P303+P361 +P353 IF ON SKIN (or hair): Remove/Take off immediately all


-

contaminated clothing. Rinse skin with water/shower.


P304+P341 IF INHALED: If breathing is difficult, remove victim to fresh air
-

and keep at rest in a position comfortable for breathing.


P305+P351+P338 IF IN EYES: Rinse cautiously with water for several
-

minutes. Remove contact lenses, if present and easy to do. Continue


rinsing.

Page 9 of 10
Safety Data Sheet
Prepared in accordance with Commission Regulation (EU) 20151830
Revision DateOg-02-201 6
Revision Number 7
P307+P31 I IF exposed: Call a POISON CENTER or doctor/physician.
-

P308+P313 IF exposed or concerned: Get medical advice/attention.


-

P314 Get medical advice/attention if you feel unwell.


-

P321 Specific treatment (see on this label).


-

P332+P313 If skin irritation occurs: Get medical advice/attention.


-

P333+P313 If skin irritation or rash occurs: Get medical advice/attention.


-

P337+P313 If eye irritation persists: Get medical advice/attention.


-

P342+P31 I If experiencing respiratory symptoms: Call a POISON


-

CENTER or doctor/physician.
P363 Wash contaminated clothing before reuse.
-

P370÷P378 In case of fire: Use for extinction.


-

Storage P233 Keep container tightly closed.


-

P403+P235 Store in a well-ventilated place. Keep cool.


-

P405 Store locked up.


-

Disposal P501 Dispose of contents/container in accordance with


-

local/regional/national/international regulation for hazardous wastes.

NOTICE: The information accumulated herein is believed to be correct as of the date issued from sources, which
are believed to be accurate and reliable. Since it is not possible to anticipate all circumstances of use, recipients
are advised to confirm, in advance of need, that the information is current, applicable and suitable to their
circumstances

Page 10 of 10
Safety Data Sheet

Revision Number: 005.1 Issue date: 06/08/2015

1. PRODUCT AND COMPANY IDENTIFICATION’


Product name: Extend(R) Rust Treatment IDH number: 497093
Product type: Rust converter Item number: 37557
Restriction of Use: None identified Region: United States
Company address: Contact information:
Henkel Corporation Telephone: (860) 571-5100
One Henkel Way MEDICAL EMERGENCY Phone: Poison Control Center
Rocky Hill, Connecticut 06067 1-877-671-4608 (toll free) or 1-303-592-1711
TRANSPORT EMERGENCY Phone: CHEMTREC
1-800-424-9300 (toll free) or 1-703-527-3887
Internet: www.henkelna.com

H:DS IDENTIFICATION
tivixi.rit.,y UVI(VIVV
DANGER: CONTENTS UNDER PRESSURE.
EXTREMELY FLAMMABLE AEROSOL.
HARMFUL IF SWALLOWED.
CAUSES SEVERE SKIN BURNS AND EYE DAMAGE.
MAY CAUSE DROWSINESS OR DIZZINESS.

n.,%ru CLASS HAZARD CATEGORY


FLAMMABLE AEROSOL. 1
ACUTE TOXICITY ORAL 4
SKIN CORROSION lB
SERIOUS EYE DAMAGE 1
SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE 3

Precautionary Statements

Prevention: Keep away from heat, sparks, open flames, hot surfaces no smoking. Do not spray on an
-

open flame or other ignition source. Do not pierce or burn, even after use. Do not breathe mist
or spray. Wash thoroughly after handling. Do not eat, drink or smoke when using this product.
Use only outdoors or in a well-ventilated area. Wear protective gloves, eye protection, and face
protection.
Response: If SWALLOWED: Immediately call poison control or physician if you feel unwell. IF
SWALLOWED: Rinse mouth. Do NOT induce vomiting. If on skin (or hair): Take off immediately
all contaminated clothing. IF INHALED: Remove person to fresh air and keep comfortable for
breathing.
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if
present and easy to do. Continue rinsing. Immediately call a poison control center or physician.
Wash contaminated clothing before reuse.
Storage: Store in a well-ventilated place. Keep container tightly closed. Store locked up. Protect from
sunlight. Do not expose to temperatures exceeding 50C/122°F.
Disposal: Dispose of contents and/or container according to Federal, State/Provincial and local
govemmental regulations.

IDH number: 497093 Product name: Extend(R) Rust Treatment


Page 1 of 6
Classification complies with OSHA Hazard Communication Standard (29 CFR 19101200) and is consistent with the provisions of the
United Nations Globally Harmonized System of Classification and Labeling of Chemicals (GHS).

See Section 11 for additional toxicological information.

OMPOSITIONIINFORMATION ON INGREDIENTS
V

.•
..

Hazardous Component(s) CAS Number Percentage*

2-Butoxyethanol 11 1-76-2 30-60


Acetone 67-64-1 30 60
-

Butyral resin Proprietary 5- 10


Formic acid 64-18-6 5- 10
3,4,5-Trihydroxybenzoic acid 149-91-7 0.1 1 -

Exact percentage Is a trade secret. Concentration range is provided to assist users in providing appropriate protecons.

[ V 4FIRSTDMEASURES
Inhalation: Move to fresh air. If breathing is difficult, give oxygen. If not breathing, give
artificial respiration. Seek medical advice.

Skin contact: Remove contaminated clothing and footwear. Wash with soap and water. If
symptoms develop and persist, get medical attention. Wash clothing before
reuse.

Eye contact: Immediately flush eyes with water for at least 15 minutes, while holding
eyelids open. Seek medical attention at once.

Ingestion: Rinse mouth, drink 1-2 glasses of water, do not induce vomiting, consult a
doctor.

Symptoms: See Section 11.

‘S,FIREFIGHTINGMEASURES
Extinguishing media: Carbon dioxide. Dry chemical. foam

Special firefighting procedures: Use water spray to keep fire exposed containers cool and disperse vapors.
Wear self-contained breathing apparatus and full protective clothing, such as
turn-out gear.

Unusual fire or explosion hazards: Closed containers may wpture (due to build up of pressure) when exposed to
extreme heat. Vapours may accumulate in low or confined areas, travel
considerable distance to source of ignition, and flash back.

Hazardous combustion products: Oxides of carbon. Hydrocarbons

6. ACCIDENTAL RELEASE MEASURES


Use personal protection recommended in Section 8, isolate the hazard area and deny entry to unnecessary and unprotected
personnel.

Environmental precautions: Do not allow material to contaminate ground water system. Do not let product
enter drains. Absorb spill with inert material. Shovel material into appropriate
container for disposal.

Clean-up methods: Absorb the spilled material with an inert absorbent (nonflammable) material.

IDH number: 497093


Page 2 of 6
Product name: Extend(R) Rust Treatment
0
. HNDLING AND STORAGE
Handling: Avoid breathing mists or aerosols of this product. Keep away from sources of
ignition no smoking. Avoid contact with eyes, skin and clothing.
-

Storage: Store in a cool, dry area. Keep containers closed when not in use.

8. EXPOSURE CONTROLS! PERSONAL PROTECTION

Employers should complete an assessment of all workplaces to determine the need for, and selection of, proper exposure
controls and protective equipment for each task performed.

Hazardous Component(s) ACGIH TLV OSHA PEL AIHA WEEL OTHER


50 ppm (240 mg/rn 3)
2-Butoxyethanol 20 ppm TWA PEL None None
(SKIN)
750 ppm STEL 1,000 ppm (2,400
Acetone None None
500 ppm TWA mglm3) PEL
Butyral resin None None None None
. 5 ppm TWA 5 ppm (9 mg/m3)
Formic acid None None
10 ppm STEL PEL
3,4,5-Trihydroxybenzoic acid None None None None

Engineering controls: Provide adequate local exhaust ventilation to maintain worker exposure below
exposure limits.

Respiratory protection: Use NIOSH approved respirator if there is potential to exceed exposure
limit(s).

Eye/face protection: Safety goggles or safety glasses with side shields. Full face protection should
be used if the potential for splashing or spraying of product exists.

Skin protection: Use impermeable gloves and protective clothing as necessary to prevent skin
contact.

9.. PHYSICAL AND CI-IEMICAL PROPERTIES


Physical state: Aerosol, Liquid
Color: Translucent
Odor: Acetone
Odor threshold: Not available.
pH: Not available.
Vapor pressure: Not available.
Boiling pointlrange: Not available.
Melting pointi range: Not available.
Specific gravity: 1.0000
Vapor density: Not available.
Flash point: <-17.7 °C (< 0.14 F) ; This product exhibits no flashback when tested for
flame extension.
Flammable/Explosive limits lower:
- 1.1 %
Flammable/Explosive limits - upper: 57%
Autoignition temperature: Not available.
Evaporation rate: Not available.
Solubility in water: Not available.
Partition coefficient (n-octanol/water): Not available.
VOC content: 50.4 %
Viscosity: Not available.
Decomposition temperature: Not available.

IDH number: 497093 Product name: Extend(R) Rust Treatment


Page 3 of 6
10.
Stability: Stable

Hazardous reactions: Will not occur.

Hazardous decomposition Irritating organic vapours. Oxides of carbon.


products:

Incompatible materials: Acids and bases. Oxidizing agents.

Reactivity: Not available.

Conditions to avoid: Keep away from heat, spark and flame.

j 11 TOXICOLOGICAL INFoRMATION: 1
Relevant routes of exposure: Skin, Inhalation, Eyes, Ingestion

Potential Health Effects/Symptoms

Inhalation: Vapours may cause drowsiness and dizziness.


Skin contact: Causes skin burns.
Eye contact: Causes serious eye damage.
Ingestion: Harmful if swallowed.

Hazardous Component(s) LD5Os and LC5Os Immediate and Delayed Health Effects
Oral LD5O (RAT) = 560 mg/kg
Oral LD5O (RABBIT) = 0.32 g/kg

0
Oral LD5O (RAT) = 1.48 g/kg Blood, Central nervous system, Irritant,
2-Buto xy ethanol
Dermal LD5O (RABBIT) = 400 mg/kg Kidney, Liver
Inhalation LC5O (RAT, 4 h) = 486 ppm
Inhalation_LC5O_(RAT,_4_h)_=_450_ppm
Oral LD5O (RABBIT) = 5,340 mg/kg
Oral LD5O (RAT) = 5,800 mg/kg
Oral LD5O (RAT) = 9,800 mg/kg Blood, Central nervous system, Irritant,
Acetone
Dermal LD5O (RABBIT) = 20,000 mg/kg Reproductive
Inhalation LC5O (RAT, 8 h) = 50.1 mg/I
Inhalation_LC5O_(RAT,_4_h)_=_76_mg/I
Butyral resin None No Records
Oral LD5O (RAT) = 730 mg/kg
Central nervous system, Corrosive, Irritant,
Formic acid Inhalation LC5O (RAT, 15 mm) = 15 mg/I
Kidney, Metabolic
Inhalation LC5O (RAT, 4 h) = 7.4 mg/I
3,4,5-Trihydroxybenzoic acid Oral LD5O (RABBIT) = 5.0 g/kg Irritant, Central nervous system

OSHA Carcinogen
Hazardous Component(s) NTP Carcinogen IARC Carcinogen
(Specifically Regulated)
2-Butoxyethanol No No No
Acetone No No No
Butyral resin No No No
Formic acid No No No
3,4,5-Trihydroxybenzoic acid No No No

12 ECOLOGICAL INFORMATIOI&
Ecological information: Not available.

IDH number: 497093


Page 4of6
Product name: Extend(R) Rust Treatment
C
.0

13. DISPOSAL CONSIDERATIONS


Information provided is for unused product only.

Recommended method of disposal: Not available.

Hazardous waste number: DOD 1: Ignitable.

14 TRANSPORT INFORMATION
The transport information provided in this section only applies to the materlailformulation itself, and is not specific to any
packagelconfiguration.

U.S. Department of Transportation Ground (49 CFR)


Proper shipping name: Aerosols, flammable
Hazard class or division: 2.1
Identification number: UN 1950
Packing group: None
DOT Hazardous Substance(s): Acetone

International Air Transportation (ICAOIIATA)


Proper shipping name: Aerosols, flammable
Hazard class or division: 2.1
Identification number: UN 1950
Packing group: None

Water Transportation (IMOIIMDG)


Proper shipping name: AEROSOLS
Hazard class or division: 2.1
Identification number: UN 1950
Packing group: None
Additional information: IMDG-Code: Segregation group 1-Acids

15. REGULATORY INFORMATION


United States Regulatory Information

TSCA 8 (b) Inventory Status: All components are listed or are exempt from listing on the Toxic Substances Control Act
Inventory.
TSCA 12 (b) Export Notification: None above reporting de minimis

CERCLAISARA Section 302 EHS: None above reporting de minimis


CERCLAISARA Section 3111312: Immediate Health, Delayed Health, Fire, Sudden Release
CERCLAISARA Section 313: This product contains the following toxic chemicals subject to the reporting requirements of
section 313 of the Emergency Planning and Community Right-To-Know Act of 1986 (40
CFR 372). 2-Butoxyethanol (CAS# 111-76-2).
CERCLA Reportable quantity: Acetone (CAS# 67-64-1) 5,000 lbs. (2,270 kg)
Formic acid (CAS# 64-1 8-6) 5,000 lbs. (2,270 kg)

California Proposition 65: This product contains a chemical known in the State of California to cause cancer. This
product contains a chemical known to the State of California to cause birth defects or other
reproductive harm.

Canada Regulatory Information

CEPA DSL/NDSL Status: All components are listed on or are exempt from listing on the Canadian Domestic
Substances List.

16. OTHER INFORMATION


This safety data sheet contains changes from the previous version in sections: New Safety Data Sheet format.

IDH number: 497093 Product name: Extend(R) Rust Treatment


Page 5 of 6
Prepared by: Catherine Bimler, Regulatory Affairs Specialist

Issue date: 06/08/2015

DISCLAIMER: The data contained herein are furnished for information only and are believed to be reliable. However, Henkel
Corporation and its affiliates (Henkel”) does not assume responsibility for any results obtained by persons over whose methods
Henkel has no control. It is the user’s responsibility to determine the suitability of Henkel’s products or any production methods
mentioned herein for a particular purpose, and to adopt such precautions as may be advisable for the protection of property and
persons against any hazards that may be involved in the handling and use of any Henkel’s products. In light of the foregoing,
Henkel specifically disclaims all warranties, express or implied, including warranties of merchantability and fitness for a particular
purpose, arising from sale or use of Henkel’s products. Henkel further disclaims any liability for consequential or incidental damages
of any kind, including lost profits.

IDH number: 497093 Product name: Extend(R) Rust Treatment


Page6of8
S
* YOUR SUPER CENTER FOR OVER 1,000 TOP PERFORMANCE
PRODUCTS SERVING INDUSTRIES WORLDWIDE

C OM

IOIG
GEAR OILS FILM FORMING LUBRICANT
MOTOR OILS Made with Liquilon®*
HYDRAULIC OILS PRODUCT DESCRIPTION TYPICAL OBSERVATiONS
1O1G Film Forming Lubricant is a premium Type Concentrated
PIPE COATINGS quality highly concentrated lubricant that resists Film Forming Lubricant
the corrosive effects of downhole chemicals. Color Green
THREAD SEALANTS 1O1G is made with LIQUILON®, which enhances Texture Smooth Paste
the lubricity and extreme pressure properties. Consistency Buttery
BEARING GREASES
LIQUIL0N is unaffected by acids, caustics, Active Component LIQUILOP
SPECIALTY downhole chemicals, and hydrocarbons including Density, lb/gal @ 77°F (25°C) 8.5
GREASES gasoline and solvents. Specific Gravity, @ 77°F (25°C) 1.02
Dropping Point,
THREAD IO1G is inert and thermally stable, The film ASTM 0-2265 >450°F (232°C)
COMPOUNDS forming properties of 1O1G eliminates wear, Flash Point, ASTM 0-92 >500°F (260°C)
guards against rust and corrosion, and prevents Penetration, ASTM 0-217
SUCI(ER ROD metal-to-metal contact thereby significantly Worked @ 77°F (25°C) 265—295
COATINGS reducing operating temperature. In many cases, Base Oil Viscosity
the power (electricity) to operate is reduced. cSt, 40°c 174.0
OUTSIDE 1O1G provides instant lubrication to equipment cSt, 100°C 17.0
PRES ER’JATIVES critical areas during start up. Corrosion Preventive Properties,
WI RELINE ASTM 0-1743 @ 125°F (51°C) Pass
GREASE SEALS BENEFITS Water Washout Characteristics,
ASTM D-1264 @ 100°F (37°C) 1.0%
CLEANERS & - Made with LIQUILON Evaporation Loss,
DEGREASERS - Highly concentrated ASTM 0-972 @ 210°F (96°C) 2.8%
Eliminates wear Oil Separation,
PiPE STORAGE Guards against rust and corrosion ASTM 0-1742 77°F (25°C) Nil
COMPOUNDS Oxidation Stability,
Prevents metal-tometaI contact
ASTM 0-942 210°F (98°C) 72 Hrs. PSI Loss 6
RUST & Provides residual lubrication
Shelf Life (unopened container) Two years
CORROSION Seals wirelirie tools from the effects of
N K 8 1TORS downhole chemicals
Ensures against galling and seizing during
THREAD LOCKING CONTAINER SIZE
makeup of wirellne tools
CO M P1) UNOS Small Case (12 jars)
- Provides instant lubrication during start up
Standard Case (6 jars)
VALVE Cart Case (6 cartridges)
LUBRICANTS & APPLICATION Pint Case (12 cans)
S F: A LAN IS 1 gal (4 L) pail
IO1G is recommended for use on 0-rings,
seal nipples, gaskets, packer plugs, and other 5 gal (19 L) pail
TOOL JOINT &
downhole tool accessories to ensure against 55 gal (208 L) drum
DRILL COLLAR
COMPOUNDS drying, cracking, and downhole contamination.

1O1G is also recommended for application to


wireline equipment and various downhole tools,
where lubrication and corrosion resistance are
vital. This lubricant will allow easy break-out and
disassembly of downhole tools that have been
subjected to adverse downhole chemicals.

© 2012, BALMAR, LLC Made in U.S.A. Menu Thctured by °Reglsterett trade name of
Oil Center Research, Inc. 09/10/09
WARRANTY Bocausa the con5llans at use anO lye suoenrsoe or
appl:tallcr. are beyord our can,Oi we assume no haStily rre any BALM JCtL R L L The product lofonnellon a.,d spewllcatisws listed In this
publicatan a,e constantly being updated to keep up

Cunryary in eulceized ,a change his pauulalcn what, nl,t,s Is all


616 WEST PONT DES MOUTON ROAD LAFAYETTE, LA 70507 with goverrjnenl regulations and lnulrnolcgy changes,
50005 deWcereo. whatue, said. dell aadeesan,r,t,c, 05 aunonase. Please visit our w,b site, www.oilcenler,cem, or
Each an stc.ld npreadlly do a,dme the sutabdky aISle product Sales Locations rorlar.t pair Account Rnp,asentsfive to, the mast
boacdo.,i,u,oiuacoe. LAFAYETTE, LA I HOUSTON, TX I LONGVIEW, TX I MIDLAND. TX I OKLAHOMA CITY, OK currant lnto,niakon relating to tn’s product.
©* YOUR SUPER CENTER FOR OVER 1,000 TOP PERFORMANCE
PRODUCTS SERVING INDUSTRIES WORLDWIDE
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IOIEU
GEAR OILS FILM FORMING LUBRICANT
MOTOR OILS
Made with LIQUILON®*
HYDRAULIC OILS PRODUCT DESCRIPTION TYPICAL OBSERVATIONS
IO1EU Film Forming Lubricant is a premium Type Concentrated
PIPE COATINGS quality highly concentrated lubricant that resists Film Forming Lubricant
the corrosive effects of downhole chemicals. Color Green
THREAD SEALANTS 1O1EU is made with LIQUIL0N, which enhances Texture Smooth Paste
the lubricity and extreme pressure properties. Consistency Buttery
BEARING GREASES
LIQUILON® is unaffected by acids, caustics, Active Component LIQUILON
SPECIALTY downhole chemicals, and hydrocarbons including Density, lb/gal @ 77°F (25°C) 7.70
SR EAS ES gasoline and solvents. Specific Gravity, c 77°F (25°c) 0.922
1O1EU is inert and thermally stable. The film Dropping Point,
THREAD forming properties of 1OIEU eliminates wear, ASTM D-2265 >450°F (232°C)
COMPOUNDS guards against rust and corrosion, and prevents Flash Point, ASTM 0-92 >450°F (232°C)
metal-to-metal contact thereby significantly Penetration, ASTM D-217
SUCKER ROD Worked @ 77°F (25°c) 265—295
reducing operating temperature. In many cases,
COATINGS Base Oil Viscosity
the power (electricity> to operate is reduced.
IO1EU provides instant lubrication to equipment cSt, 40°c 174.0
OUTSIDE
critical areas during start up. cSt, 100°C 17.0
PRESERVATIVES Corrosion Preventive Properties,
ASTM 0-1743 @ 125°F (51°C) Pass
WI RELI NE BENEFITS
GREASE SEALS
Water Washout Characteristics,

CLEANERS &
DEGREJtSERS e
REACH Compliant
Made with LIQUILONA
HIghly concentrated
ASTM 0-1264 © 100°F (37°c)
Evaporation Loss,
ASTM 0-972 210°F (98°c)
1.0%

2.8%
C)
Oil Separation,
Eliminates wear
PIPE STORAGE ASTM 0-1742 @ 77°F (25°C) Nil
CO N P00 ND S Guards against rust and corrosion Oxidation Stability, ASTM 0-942
Prevents metal-to-metal contact @ 210°F (98°C) 72 Hrs. PSI Loss 6
RUST & Provides residual lubrication Shelf Life (unopened container) Two years
CORROSION Seals wireline tools from the effects of
INHIBITORS downhole chemicals
THREAD LOCKING Ensures against galling and seizing during CONTAINER SIZE
makeup of wiraline tools
COMPOUNDS Small Case (12—5oz jars)
Provides instant lubrication during start up Standard Case (6—lib jars)
VALVE Service temperatures 10°F to >400°F 1 gal (4 L) pail
LUBRICANTS & 5 gal (19 L) pail
S EALANTS A P P LI CAT tO N 55 gal (208 L) drum
TOOL JOINT & 1O1EU is recommended for use on 0-rings,
DRILL COLLAR seal nipples, gaskets, packer plugs, and other
COMPOUNDS downhole tool accessories to ensure against
drying, cracking, and downhole contamination.
1OIEU is also recommended for application to
:i- wireline equipment and various downhole tools,
where lubrication and corrosion resistance are
vital. This lubricant will allow easy break-out and
disassembly of downhole tools that have been
I!J subjected to adverse downhole chemicals.

152012, BALMAR, LLC Made in U.S.A. °Regiuterod trade name of


Mun,cfn,,tjrnd tty
Oil center Research, nc. 08/15/14
BAL IL. L. C. The prnduct infonnoton and speciticoliono listed in Ale
publicatIon are constantly being updoled a keep op
Conpor’) 0 nutflor,20 to chan2e tue p,noIsjon. which ,Olo,ee a all

hosed on lbehspnsThepptcutlo,,
616 WEST PONT DES MOUTON ROAD J LAFAYETTE,
Sales Locations:
LA 70507

LAFAYETTE, LA I HOUSTON, TX I LONG\IIEW, TX I MIDLAND, TX I OKLAHOMA CITY, 01<


with government rogulotlons and technology changes.
Please visit ourwob silo, www.oilcentor.com, or
contoci your Account Representative for the nest
current lnforn,atlor, rotating to tills product.
C
SAFETY DATA SHEET Page: 1 of 6
Film Forming Lubricant
Revision: 01/12/2016

1. Product and Company Identification


Product Code: 101 G
Product Name: Film Forming Lubricant
Company Name: Balmar, LLC Phone Number:
616 W. Pont Des Mouton Rd. (337)232-2496
Lafayette, LA 70507-4002
Email address: [email protected]
Emergency Contact: 01-703-527-3887

2. Hazards Identification
Skin Corrosionllrritation, Category 3

GHS Signal Word: Warning


GHS Hazard Phrases: H316 Causes mild skin irritation.
-

GHS Precaution Phrases: No phrases apply.


OHS Response Phrases: P332+313 - If skin irritation occurs, get medical advice/attention.
OHS Storage and Disposal No phrases apply.
Phrases:
Potential Health Effects Chronic: Effects may be delayed.
(Acute and Chronic):
Inhalation: The toxicological properties of this substance have not been fully investigated. Effects
may be delayed.
Skin Contact: May cause skin irritation.
Eye Contact: May cause eye irritation.
Ingestion: The toxicological properties of this substance have not been fully investigated.
Moderately toxic to humans by ingestion. May cause gastrointestinal irritation with
nausea, vomiting and diarrhea.

3. Compositionllnformation on Ingredients
GAS # Components (Chemical Name) Concentration
NA Mineral Oil 64.0-81.0%
NA Thickener 4.00 9.00 %
-

NA Coloring agent 3.00 5.00 %


-

1314-13-2 Zincoxide 1.00-5.00%

MIRS MSDS, (c) A V Systems, Inc. GHS format


SAFETY DATA SHEET Page: 2 of 6
Film Forming Lubricant Revision: 01/1212016

4. First Aid Measures I


mergency and First Aid
procedures:
n Case of Inhalation: Remove from exposure and move to fresh air immediately. If breathing is difficult, give
oxygen. Get medical aid.
n Case of Skin Contact: Flush skin with plenty of water for at least 15 minutes while removing contaminated
clothing and shoes. Wash clothing before reuse. Get medical aid.
n Case of Eye Contact: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and
lower eyelids. Get medical aid.
n Case of Ingestion: Never give anything by mouth to an unconscious person. Get medical aid. Do NOT
induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or
water. Consult a physician.
Note to Physician: Treat symptomatically and su pportively.

5 Fire Fighting Measures


Flash Pt: >232 F Method Used: Estimate
Explosive Limits: LEL: No data. UEL: No data.
Autoignition Pt: NA
Suitable Extinguishing Media:Use water spray, dry chemical, carbon dioxide, or appropriate foam. Substance is
noncombustible; use agent most appropriate to extinguish surrounding fire.
Fire Fighting Instructions: As in any fire, wear a self-contained breathing apparatus in pressure-demand,
MSHAINIOSH (approved or equivalent), and full protective gear. During a fire, irritating
and highly toxic gases may be generated by thermal decomposition or combustion.

Flammable Properties and


Material will not burn.
No data available. C
Hazards:

6. Accidental Release Measures


Steps To Be Taken In Case Use proper personal protective equipment as indicated in Section 8.
Material Is Released Or Spills/Leaks: Clean up spills immediately, observing precautions in the Protective
Spilled: Equipment section. Provide ventilation. Vacuum or sweep up material and place into a
suitable disposal container.

7. Handling and Storage


Precautions To Be Taken in Wash thoroughly after handling. Use with adequate ventilation. Avoid contact with eyes,
Handling: skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation. Wash
clothing before reuse.
Precautions To Be Taken in Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from
Storing: incompatible substances.

8. Exposure ControlslPersonal Protection


CAS # Partial Chemical Name OSHA TWA ACGIH TWA Other Limits
NA Mineral Oil No data. No data. No data.

NA Thickener No data. No data. No data.

NA Coloring agent PEL: 15 (dust) mg/m3 TLV: 10 mg/m3 No data.

1314-13-2 Zinc oxide PEL: 5 (fume); 15 (dust) TLV: 2 mg/m3 (R) No data.
mg/m3 STEL: 10 mg/m3 (R)
C-
MIRS MSDS, (c) A V Systems, Inc. GHS format
SAFETY DATA SHEET Page:3o16
Film Forming Lubricant Revision: 01/12/2016

Respiratory Equipment A respiratory protection program that meets OSHAs 29 CFR 1910.134 and ANSI Z88.2
(Specify Type): requirements or European Standard EN 149 must be followed whenever workplace
conditions warrant respirator use. Use respirators and components tested and approved
under appropriate government standards such as NIOSH (US) or CEN (EU).
Eye Protection: Wear appropriate protective eyeglasses or chemical safety goggles as described by
OSHA’s eye and face protection regulations in 29 CFR 1910.133 or European Standard
EN 166.
Protective Gloves: Wear appropriate protective gloves to prevent skin exposure.
Other Protective Clothing: Wear appropriate protective clothing to prevent skin exposure.
Engineering Controls Facilities storing or utilizing this material should be equipped with an eyewash facility and
(Ventilation etc.): a safety shower. Use adequate ventilation to keep airborne concentrations low.

9. Physical and Chemical Properties


Physical States: [ ] Gas [ ] Liquid [X] Solid
Appearance and Odor: Paste.
Petroleum-like.

Appearance: green.
Melting Point: > 232 F

Boiling Point: NP
Autoignition Pt: NA
Flash Pt: > 232 F Method Used: Estimate
Explosive Limits: LEL: No data. UEL: No data.
Specific Gravity (Water = 1): 1.02 at 77.0 F
Density: 8.51 at 77.0 F
Vapor Pressure (vs. Air or No data.
mm Hg):
Vapor Density (vs. Air = 1): No data.
Evaporation Rate: No data.
Solubility in Water: <1
Percent Volatile: No data.

10. Stability and Reactivity


Stability: Unstable [ ] Stable [X I
Conditions To Avoid - Incompatible materials.
Instability:
Incompatibility Materials To Oxidizing agents, magnesium, chlorinated rubber.
-

Avoid:
Hazardous Decomposition Or Carbon monoxide.
Byproducts:
Possibility of Hazardous Will occur [ ] Will not occur [X]
Reactions:
Conditions To Avoid - No data available.
Hazardous Reactions:

MIRS MSDS, (c) A V Systems, Inc. GHS format


SAFETY DATA SHEET Page:4of6
Film Forming Lubricant Revision: 01/12/2016

11. Toxicological Information


Toxicological Information: Epidemiology: No information found.
Teratogenicity: No information available.
C’
Reproductive Effects: No information found.
Mutagenicity: Neurotoxicity:
Carcinogenicity/Other CAS# 6966-09-2: Not listed byACGIH, IARC, NTP, or CA Prop 65.
Information: CAS# 1314-13-2: Not listed byACGIH, IARC, NTP, or CA Prop 65.
Carcinogenicity: NTP? No IARC Monographs? No OSHA Regulated? No
CAS # Components (Chemical Name) NTP IARC ACGIH OSHA
NA Mineral Oil n.a. n.a. n.a. n.a.
NA Thickener n.a. n.a. na. n.a.
NA Coloring agent n.a. 2B A4 n.a.
1314-13-2 Zinc oxide n.a. n.a. n.a. n.a.

12 Ecological Information
General Ecological Environmental: No information available.
Information:

13 Disposal Considerations
Waste Disposal Method: Chemical waste generators must determine whether a discarded chemical is classified as
a hazardous waste. US EPA guidelines for the classification determination are listed in 40
CFR Parts 261. Additionally, waste generators must consult state and local hazardous
waste regulations to ensure complete and accurate classification.
RCRA P-Series: None listed.
RCRA U-Series: None listed.

14. Transport Information


LAND TRANSPORT (US DOT):
DOT Proper Shipping Name: Not regulated as a hazardous material()
DOT Hazard Class:
UNINA Number:
LAND TRANSPORT (Canadian TDG):
TDG Shipping Name: No information available.

LAND TRANSPORT (European ADRIRID):


ADRIRID Shipping Name: No information available.
UN Number:
Hazard Class:
MARINE TRANSPORT (IMDGIIMO):
IMDG/IMO Shipping Name: Not regulated as a hazardous material
AIR TRANSPORT (ICAOIIATA):
ICAO/IATA Shipping Name: Not regulated as a hazardous material

MIRS MSDS, (c) A V Systems, Inc. GHS format


SAFETY DATA SHEET Page: 5 of 6
Film Forming Lubricant Revision: 01/12/2016

15. Regulatory Information


EPA SARA (Superfund Amendments and Reauthorization Act of 1986) Lists
CAS # Components (Chemical Name) S. 302 (EHS) S. 304 RQ S. 313 (TRI)
NA Mineral Oil No No No
NA Thickener No No No
NA Coloring agent No No No
1314-13-2 Zinc oxide No No Yes-Cat. N982
This material meets the EPA [X] Yes [ ] No Acute (immediate) Health Hazard
Hazard Categorie& defined [X] Yes [ ] No Chronic (delayed) Health Hazard
for SARA Title III Sections [ ] Yes [X] No Fire Hazard
311/312 as indicated: [ ] Yes [X] No Sudden Release of Pressure Hazard
[ I Yes [X] No Reactive Hazard

CAS # Components (Chemical Name) Other US EPA or State Lists


NA Mineral Oil CM HAPODC: No; CWA NPDES: No; TSCA: Yes -

Inventory; CA PROP.65: No; MA Oil/HazMat: No; NJ EHS:


No; NY Part 597: No; PA HSL: No
NA Thickener CM HAP,ODC: No; CWA NPDES: No; TSCA: Yes -

Inventory; CA PROP.65: No; MA Oil/HazMat: No; NJ EHS:


No; NY Part 597: No; PA HSL: No
NA Coloring agent CM HAP,ODC: No; CWA NPDES: No; TSCA: Yes -

Inventory; CA PROP.65: Yes; MA Oil/HazMat: No; NJ EHS:


Yes; NY Part 597: No; PA HSL: Yes 1 -

1314-13-2 Zinc oxide CM HAP,ODC: No; CWA NPDES: No; TSCA: Yes -

Inventory; CA PROP.65: No; MA OiI/HazMat: Yes Cat.; NJ


-

EHS: Yes 2037; NY Part 597: No; PA HSL: Yes E


- -

CAS # Components (Chemical Name) International Regulatory Lists


NA Mineral Oil Canadian DSL: Yes; REACH: Yes (R), (P), C2
-

NA Thickener Canadian DSL: Yes; REACH: Yes (P) -

NA Coloring agent Canadian DSL: Yes; REACH: Yes (R), (P)


-

1314-13-2 Zinc oxide Canadian DSL: Yes; REACH: Yes (R), (P)
-

16. Other Information


Revision Date: 01/1212016
.
Hazard Rating System: HEALTH
FLAMMABILITY_
• Flammability Instability

I!I
PPE B
HMIS: NFPA: Special Hazard

Additional Information About No data available.


This Product:
Company Policy or The information contained here is based upon data available to us and reflects our best
Disclaimer: professional judgment. Since it is impossible to anticipate the conditions under which our
products may be used, we cannot guarantee that the recommendations will be adequate
for all individuals and situations. Each user of this product should determine the suitability
of the product with zero or minimum hazards. Our products are improved daily as
up-to-date information and research data is recieved from our suppliers in our quest to
MIRS MSDS, (c) A V Systems, Inc. GHS format
SAFETY DATA SHEET Page:6of6

Film Forming Lubricant Revison 01/12/2016

use products with less or no hazards. Please feel free to contact us for current
(_N)
information.

C
MIRS MSDS, (c) A V Systems, Inc. GHS format
MATERIAL SAFETY DATA SHEET

GLANCE FOAMING GLASS CLEANER


HMIS NFPA Personal protective equipment
Health 1 1
Flammability 2 4
Physical Hazard / Instability 0 0
Version Number: 5 Preparation date: 2014-09-18

1. PRODUCT AND COMPANY IDENTIFICATION

Product name: GLANCE FOAMING GLASS CLEANER

MSDS #: MS0301498
Product Code: 04553
Recommended use: •GlassCl
eaner

Manufacturer, importer, supplier: Canadian Headquarters


US Headquarters Diversey, Inc. - Canada
Diversey, Inc. 3755 Laird Road
8310 16th St. Mississauga, Ontario L5L 0B3
Sturtevant, Wisconsin 53177-1964 Phone: 1-800-668-3131
Phone: 1-888-352-2249
MSDS Internet Address: www.diversey.com
Emergency telephone number: 1-800-851-7145 (U.S.); 1-651-917-6133 (Int'l)

2. HAZARDS IDENTIFICATION

EMERGENCY OVERVIEW
CAUTION. MAY BE MILDLY IRRITATING TO EYES. COMBUSTIBLE LIQUID AND VAPOR.

Principal routes of exposure: Eye contact. Skin contact. Inhalation.


Eye contact: May be mildly irritating to eyes.
Skin contact: None known.
Inhalation: None known.
Ingestion: None known.

3. COMPOSITION/INFORMATION ON INGREDIENTS

Ingredient(s) CAS # Weight % LD50 Oral - Rat LD50 Dermal - LC50 Inhalation -
(mg/kg) Rabbit Rat
Butane 106-97-8 1 - 5% 2000 Not available =658 g/m3 (4 h)
2-butoxyethanol 111-76-2 1 - 5% 1400 =99 mg/kg =450 ppm (4 h)
Isopropyl alcohol 67-63-0 1 - 5% 4396 =4059 mg/kg =72600 mg/m3 (4 h)
Propane 74-98-6 1 - 5% 2400 Not available =658 mg/L (4 h)
Sodium nitrite 7632-00-0 0.1 - 1.5% 85 Not available =5.5 mg/L (4 h)

4. FIRST AID MEASURES

Eye contact: Flush immediately with plenty of water. If irritation develops, get medical attention.
Skin contact: Rinse with plenty of water.
Inhalation: No specific first aid measures are required.
Ingestion: No specific first aid measures are required.

GLANCE FOAMING GLASS CLEANER 1 of 4


Aggravated Medical Conditions: None known.

5. FIRE-FIGHTING MEASURES

Suitable extinguishing media: Extinguish fire using agent suitable for surrounding fire.
Extinguishing media which must not be used for safety reasons: No information available.
Specific hazards: NFPA 30B Level 1 Aerosol. Aerosol product - Containers may rocket or explode in heat of fire.
Unusual hazards: None known.
Specific methods: Use water spray to keep fire-exposed containers cool.

Special protective equipment for firefighters: As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH
(approved or equivalent) and full protective gear.

6. ACCIDENTAL RELEASE MEASURES

Personal precautions: Eliminate all ignition sources (no smoking, flares, sparks or flames in immediate area).
Environmental precautions No information available.
and clean-up methods:

7. HANDLING AND STORAGE

Handling: Avoid contact with eyes. COMBUSTIBLE LIQUID AND VAPOR. Keep away from open flames, hot surfaces and sources of ignition. Use
only in well-ventilated areas. FOR COMMERCIAL AND INDUSTRIAL USE ONLY.
Storage: Protect from freezing. Keep tightly closed in a dry, cool and well-ventilated place. KEEP OUT OF REACH OF CHILDREN.

8. EXPOSURE CONTROLS / PERSONAL PROTECTION

Engineering measures to reduce exposure:


No special ventilation requirements General room ventilation is adequate

Personal Protective Equipment


Eye protection: No special requirements under normal use conditions.
Hand protection: No special requirements under normal use conditions
Skin and body protection: No special requirements under normal use conditions.
Respiratory protection: No special requirements under normal use conditions.
Hygiene measures: Handle in accordance with good industrial hygiene and safety practice.

Ingredient(s) CAS # ACGIH OSHA Mexico


Butane 106-97-8 1000 ppm (STEL) 800 ppm (TWA)
1900 mg/m3 (TWA)
2-butoxyethanol 111-76-2 20 ppm (TWA) Skin 75 ppm (STEL)
50 ppm (TWA) 360 mg/m3 (STEL)
240 mg/m3 (TWA) 26 ppm (TWA)
120 mg/m3 (TWA)
Isopropyl alcohol 67-63-0 400 ppm (STEL) 400 ppm (TWA) 500 ppm (STEL)
200 ppm (TWA) 980 mg/m3 (TWA) 1225 mg/m3 (STEL)
400 ppm (TWA)
980 mg/m3 (TWA)
Propane 74-98-6 1000 ppm (TWA) 1000 ppm (TWA)
1800 mg/m3 (TWA)

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Aerosol Bulk density: No information available


Appearance: No information available Evaporation Rate: No information available
Specific gravity: 0.9948 Color: Clear Colorless
Vapor density: No information available Odor: Solvent
Boiling point/range: Not determined Melting point/range: Not determined
Decomposition temperature: Not determined Autoignition temperature: No information available
Solubility: Partially Soluble Density: 8.3 lbs/gal 0.9948 Kg/L
Solubility in other solvents: No information available Flash point: -156 °F -104.4 °C
Partition coefficient (n-octanol/water): No information available Viscosity: No information available
Elemental Phosphorus: 0.00 % by wt. VOC: 8.82 % *
pH: 10.93 Dilution pH: 11.43 @ RTU
Explosion limits: - upper: Not determined - lower: Not determined

* - Title 17, California Code of Regulations, Division 3, Chapter 1, Subchapter 8.5, Article 2, Consumer Products, Sections 94508

GLANCE FOAMING GLASS CLEANER 2 of 4


10. STABILITY AND REACTIVITY

Stability: The product is stable


Polymerization: Hazardous polymerization does not occur.
Hazardous decomposition products: None reasonably foreseeable.
Conditions to avoid: Extremes of temperature and direct sunlight. Keep away from open flames, hot surfaces and sources of
ignition.

11. TOXICOLOGICAL INFORMATION

Acute toxicity: Oral LD50 estimated to be greater than 5000 mg/kg Dermal LD50 estimated to be > 2000 mg/kg
Component Information: See Section 3.

Chronic toxicity: None known

Specific effects
Carcinogenic effects: •Noneknown
Mutagenic effects: None known
Reproductive toxicity: None known
Target organ effects: None known

Ingredient(s) CAS # NTP IARC OSHA


Isopropyl alcohol 67-63-0 3 X
Sodium nitrite 7632-00-0 2A

12. ECOLOGICAL INFORMATION

Environmental Information: No data available.

13. DISPOSAL CONSIDERATIONS

Waste from residues / unused products:


Use up contents if possible before disposal. If possible, recycle empty aerosol cans to the nearest steel recycling center. This product, as sold, if
discarded or disposed, is a hazardous waste according to Federal regulations (40 CFR 261.4 (b)(4)). Dispose in compliance with all Federal, state,
provincial, and local laws and regulations.
RCRA Hazard Class (undiluted product): D001 Ignitable Waste

14. TRANSPORT INFORMATION

DOT/TDG/IMDG: Please refer to the Diversey HazMat Library, only available through Internet Explorer, http://naextranet.diversey.com/dot/, for up
to date shipping information.

DOT (Ground) Bill of Lading Description: LTD. QTY.

IMDG (Ocean) Bill of Lading Description: UN1950, AEROSOLS, 2.1, LTD. QTY.

15. REGULATORY INFORMATION

International Inventories at CAS# Level


All components of this product are listed on the following inventories: U.S.A. (TSCA), Canada (DSL/NDSL), Europe (EINECS/ELINCS/NLP),
Australia (AICS), Korea (ECL), Japan (ENCS), Philippines (PICCS), China (IECSC).

U.S. Regulations
California Proposition 65: This product is not subject to the reporting requirements under California's Proposition 65.

RIGHT TO KNOW (RTK)


Ingredient(s) CAS # MARTK: NJRTK: PARTK: RIRTK:
Water 7732-18-5 - - - -
Butane 106-97-8 X X X -
2-butoxyethanol 111-76-2 X X X -
Isopropyl alcohol 67-63-0 X X X -
Propane 74-98-6 X X X -
Sodium nitrite 7632-00-0 X X X X

GLANCE FOAMING GLASS CLEANER 3 of 4


CERCLA/ SARA
Ingredient(s) CAS # Weight % CERCLA/SARA RQ (lbs) Section 302 TPQ (lbs) Section 313
2-butoxyethanol 111-76-2 1 - 5% X
Isopropyl alcohol 67-63-0 1 - 5% X
Sodium nitrite 7632-00-0 0.1 - 1.5% 100 X

Ingredient(s) CAA HAP CAA ODS CWA Priority Pollutants


2-butoxyethanol X

SARA 311/312 Hazard Categories


Immediate: -
Delayed: -
Fire: X
Reactivity: -
Sudden Release of Pressure: X
Canada
WHMIS hazard class: A Compressed gases, B5 Flammable aerosol.

Ingredient(s) CAS # NPRI


2-butoxyethanol 111-76-2 X
Isopropyl alcohol 67-63-0 X
Propane 74-98-6 X
Sodium nitrite 7632-00-0 X

16. OTHER INFORMATION

Reason for revision: Not applicable


Prepared by: NAPRAC
Additional advice: •Doesnotcont ai
nanaddedf r
agrance
•Thispr oducthasbeencl assif
iedi naccor dancewi thhazar dcr iteri
aoft heCont r
oll
edPr oduct
s
Regulations and the MSDS contains all the information required by the Controlled Products
Regulations

Notice to Reader: This document has been prepared using data from sources considered technically reliable. It does not constitute a warranty,
express or implied, as to the accuracy of the information contained within. Actual conditions of use and handling are beyond seller's control. User is
responsible to evaluate all available information when using product for any particular use and to comply with all Federal, State, Provincial and
Local laws and regulations.

GLANCE FOAMING GLASS CLEANER 4 of 4


SAFETY DATA SHEET

1. Identification
Product number 1000000075
Product identifier GLASS CLEANER
Revision date 05-30-2015
Company information Sprayway, Inc.
1005 S. Westgate Drive
Addison, IL 60101 United States
Company phone General Assistance 1-630-628-3000
Emergency telephone US 1-866-836-8855
Emergency telephone outside 1-952-852-4646
US
Version # 02
Supersedes date 05-26-2015
Recommended use cleaner
Recommended restrictions None known.

2. Hazard(s) identification
Physical hazards Gases under pressure Liquefied gas
Health hazards Not classified.
Environmental hazards Not classified.
OSHA defined hazards Not classified.

Label elements

Signal word Warning


Hazard statement Contains gas under pressure; may explode if heated.
Precautionary statement
Prevention Observe good industrial hygiene practices.
Response Wash hands after handling.
Storage Protect from sunlight. Store in a well-ventilated place.
Disposal Dispose of waste and residues in accordance with local authority requirements.
Hazard(s) not otherwise None known.
classified (HNOC)
Supplemental information None.

3. Composition/information on ingredients
Mixtures
Chemical name Common name and synonyms CAS number %
2-Butoxyethanol 111-76-2 2.5 - 10
Ethyl Alcohol 64-17-5 2.5 - 10
Butane 106-97-8 1 - 2.5
Propane 74-98-6 1 - 2.5
Other components below reportable levels 90 - 100
*Designates that a specific chemical identity and/or percentage of composition has been withheld as a trade secret.

Product name: GLASS CLEANER SDS US

Product #: 1000000075 Version #: 02 Revision date: 05-30-2015 Issue date: 05-26-2015 1 / 10


4. First-aid measures
Inhalation Move to fresh air. Get medical attention if symptoms persist.
Skin contact Get medical attention if irritation develops and persists.
Eye contact Immediately flush with plenty of water for at least 15 minutes. If easy to do, remove contact lenses.
Continue rinsing. Get medical attention if irritation develops and persists.
Ingestion Rinse mouth.
Most important Direct contact with eyes may cause temporary irritation.
symptoms/effects, acute and
delayed
Indication of immediate Provide general supportive measures and treat symptomatically.
medical attention and special
treatment needed
General information Ensure that medical personnel are aware of the material(s) involved, and take precautions to
protect themselves.

5. Fire-fighting measures
Suitable extinguishing media Water fog. Foam. Dry chemical powder. Carbon dioxide (CO2).
Unsuitable extinguishing Do not use water jet as an extinguisher, as this will spread the fire.
media
Specific hazards arising from Contents under pressure. During fire, gases hazardous to health may be formed.
the chemical
Special protective equipment Self-contained breathing apparatus and full protective clothing must be worn in case of fire.
and precautions for firefighters
Fire-fighting In case of fire: Stop leak if safe to do so. Do not move cargo or vehicle if cargo has been exposed
equipment/instructions to heat. Move containers from fire area if you can do so without risk. Cool containers exposed to
heat with water spray and remove container, if no risk is involved. Containers should be cooled
with water to prevent vapor pressure build up. For massive fire in cargo area, use unmanned hose
holder or monitor nozzles, if possible. If not, withdraw and let fire burn out.
Specific methods Use standard firefighting procedures and consider the hazards of other involved materials.
General fire hazards No unusual fire or explosion hazards noted.

6. Accidental release measures


Personal precautions, Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Keep out of
protective equipment and low areas. Wear appropriate protective equipment and clothing during clean-up. Emergency
emergency procedures personnel need self-contained breathing equipment. Do not touch damaged containers or spilled
material unless wearing appropriate protective clothing. Ventilate closed spaces before entering
them. Local authorities should be advised if significant spillages cannot be contained. See Section
8 of the SDS for Personal Protective Equipment. For personal protection, see section 8 of the
SDS.
Methods and materials for Refer to attached safety data sheets and/or instructions for use. Eliminate all ignition sources (no
containment and cleaning up smoking, flares, sparks, or flames in immediate area). Keep combustibles (wood, paper, oil, etc.)
away from spilled material. Stop leak if you can do so without risk. Move the cylinder to a safe and
open area if the leak is irreparable. Isolate area until gas has dispersed. Prevent entry into
waterways, sewer, basements or confined areas. Wipe up with absorbent material (e.g. cloth,
fleece). Clean surface thoroughly to remove residual contamination. For waste disposal, see
section 13 of the SDS.
Environmental precautions Avoid discharge into drains, water courses or onto the ground.

7. Handling and storage


Precautions for safe handling Pressurized container: Do not pierce or burn, even after use. Do not use if spray button is missing
or defective. Do not spray on a naked flame or any other incandescent material. Do not smoke
while using or until sprayed surface is thoroughly dry. Do not cut, weld, solder, drill, grind, or
expose containers to heat, flame, sparks, or other sources of ignition. Ground and bond containers
when transferring material. Do not re-use empty containers. Do not get in eyes, on skin, or on
clothing. Avoid prolonged exposure. Use only in well-ventilated areas. Wear appropriate personal
protective equipment. Observe good industrial hygiene practices.

Product name: GLASS CLEANER SDS US

Product #: 1000000075 Version #: 02 Revision date: 05-30-2015 Issue date: 05-26-2015 2 / 10


Conditions for safe storage, Level 1 Aerosol.
including any incompatibilities
Pressurized container. Protect from sunlight and do not expose to temperatures exceeding
50°C/122 °F. Do not puncture, incinerate or crush. Do not handle or store near an open flame,
heat or other sources of ignition. Keep containers tightly closed in a dry, cool and well-ventilated
place. Refrigeration recommended. Store away from incompatible materials (see Section 10 of the
SDS).

8. Exposure controls/personal protection


Occupational exposure limits
US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000)
Components Type Value
2-Butoxyethanol (CAS PEL 240 mg/m3
111-76-2)
50 ppm
Ethyl Alcohol (CAS 64-17-5) PEL 1900 mg/m3
1000 ppm
Propane (CAS 74-98-6) PEL 1800 mg/m3
1000 ppm
US. ACGIH Threshold Limit Values
Components Type Value
2-Butoxyethanol (CAS TWA 20 ppm
111-76-2)
Butane (CAS 106-97-8) STEL 1000 ppm
Ethyl Alcohol (CAS 64-17-5) STEL 1000 ppm
US. NIOSH: Pocket Guide to Chemical Hazards
Components Type Value
2-Butoxyethanol (CAS TWA 24 mg/m3
111-76-2)
5 ppm
Butane (CAS 106-97-8) TWA 1900 mg/m3
800 ppm
Ethyl Alcohol (CAS 64-17-5) TWA 1900 mg/m3
1000 ppm
Propane (CAS 74-98-6) TWA 1800 mg/m3
1000 ppm
Biological limit values
ACGIH Biological Exposure Indices
Components Value Determinant Specimen Sampling Time
2-Butoxyethanol (CAS 200 mg/g Butoxyacetic Creatinine in *
111-76-2) acid (BAA), urine
with hydrolysis
* - For sampling details, please see the source document.
Exposure guidelines
US - California OELs: Skin designation
2-Butoxyethanol (CAS 111-76-2) Can be absorbed through the skin.
US - Minnesota Haz Subs: Skin designation applies
2-Butoxyethanol (CAS 111-76-2) Skin designation applies.
US - Tennesse OELs: Skin designation
2-Butoxyethanol (CAS 111-76-2) Can be absorbed through the skin.
US NIOSH Pocket Guide to Chemical Hazards: Skin designation
2-Butoxyethanol (CAS 111-76-2) Can be absorbed through the skin.
US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000)
2-Butoxyethanol (CAS 111-76-2) Can be absorbed through the skin.
Appropriate engineering Good general ventilation (typically 10 air changes per hour) should be used. Ventilation rates
controls should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation,
or other engineering controls to maintain airborne levels below recommended exposure limits. If
exposure limits have not been established, maintain airborne levels to an acceptable level.

Product name: GLASS CLEANER SDS US

Product #: 1000000075 Version #: 02 Revision date: 05-30-2015 Issue date: 05-26-2015 3 / 10


Individual protection measures, such as personal protective equipment
Eye/face protection If contact is likely, safety glasses with side shields are recommended.
Hand protection For prolonged or repeated skin contact use suitable protective gloves.
Skin protection
Other Wear suitable protective clothing.
Respiratory protection If permissible levels are exceeded use NIOSH mechanical filter / organic vapor cartridge or an
air-supplied respirator. If engineering controls do not maintain airborne concentrations below
recommended exposure limits (where applicable) or to an acceptable level (in countries where
exposure limits have not been established), an approved respirator must be worn.
Thermal hazards Wear appropriate thermal protective clothing, when necessary.
General hygiene When using do not smoke. Always observe good personal hygiene measures, such as washing
considerations after handling the material and before eating, drinking, and/or smoking. Routinely wash work
clothing and protective equipment to remove contaminants.

9. Physical and chemical properties


Appearance Clear.
Physical state Gas.
Form Aerosol. Liquefied gas.
Color Light yellow.
Odor Characteristic.
Odor threshold Not available.
pH 9.1 - 10.1 estimated
Melting point/freezing point Not available.
Initial boiling point and boiling 212 °F (100 °C) estimated
range
Flash point -156.0 °F (-104.4 °C) Propellant estimated
Evaporation rate Not available.
Flammability (solid, gas) Not available.
Upper/lower flammability or explosive limits
Flammability limit - lower Not available.
(%)
Flammability limit - upper Not available.
(%)
Explosive limit - lower (%) Not available.
Explosive limit - upper (%) Not available.
Vapor pressure 80 - 100 psig @70F estimated
Vapor density Not available.
Relative density Not available.
Solubility(ies)
Solubility (water) Not available.
Partition coefficient Not available.
(n-octanol/water)
Auto-ignition temperature Not available.
Decomposition temperature Not available.
Viscosity Not available.
Other information
Aerosol spray enclosed space
Deflagration density > 2.52 g/cm3 Tested
Aerosol spray ignition < 15 cm Tested estimated
distance
Specific gravity 0.977 - 0.997

Product name: GLASS CLEANER SDS US

Product #: 1000000075 Version #: 02 Revision date: 05-30-2015 Issue date: 05-26-2015 4 / 10


10. Stability and reactivity
Reactivity The product is stable and non-reactive under normal conditions of use, storage and transport.
Chemical stability Material is stable under normal conditions.
Possibility of hazardous No dangerous reaction known under conditions of normal use. Hazardous polymerization does not
reactions occur.
Conditions to avoid Avoid heat, sparks, open flames and other ignition sources. Avoid temperatures exceeding the
flash point. Contact with incompatible materials.
Incompatible materials Strong oxidizing agents.
Hazardous decomposition No hazardous decomposition products are known.
products

11. Toxicological information


Information on likely routes of exposure
Ingestion Expected to be a low ingestion hazard.
Inhalation Prolonged inhalation may be harmful.
Skin contact No adverse effects due to skin contact are expected.

2-Butoxy ethanol may be absorbed through the skin in toxic amounts if contact is repeated and
prolonged. These effects have not been observed in humans.

Eye contact Direct contact with eyes may cause temporary irritation.
Symptoms related to the Direct contact with eyes may cause temporary irritation.
physical, chemical and
toxicological characteristics
Information on toxicological effects
Acute toxicity May be harmful if swallowed. May be harmful in contact with skin. May be harmful if inhaled.
Expected to be a low hazard for usual industrial or commercial handling by trained personnel.
Components Species Test Results
2-Butoxyethanol (CAS 111-76-2)
Acute
Dermal
LD50 Guinea pig 230 ml/kg, 24 Hours
7.3 ml/kg, 4 Days
Rabbit 450 ml/kg, 24 Hours
435 mg/kg, 24 Hours
0.63 ml/kg
Rat > 2000 mg/kg, 24 Hours
Inhalation
LC50 Rabbit 400 ppm, 7 Hours
Rat 450 ppm, 4 Hours
Oral
LD100 Rabbit 695 mg/kg
LD50 Dog > 695 mg/kg
Guinea pig 1200 mg/kg
Rat 530 - 2800 mg/kg
Butane (CAS 106-97-8)
Acute
Inhalation
LC50 Mouse 1237 mg/l, 120 Minutes
52 %, 120 Minutes
Rat 1355 mg/l

Product name: GLASS CLEANER SDS US

Product #: 1000000075 Version #: 02 Revision date: 05-30-2015 Issue date: 05-26-2015 5 / 10


Components Species Test Results
Ethyl Alcohol (CAS 64-17-5)
Acute
Inhalation
LC50 Cat 85.41 mg/l, 4.5 Hours
43.68 mg/l, 6 Hours
Mouse > 60000 ppm
79.43 mg/l, 134 Minutes
Rat > 115.9 mg/l, 4 Hours
51.3 mg/l, 6 Hours
Oral
LD50 Monkey 6000 mg/kg
Mouse 10500 ml/kg
Rat 1187 - 2769 mg/kg
7800 ml/kg
Propane (CAS 74-98-6)
Acute
Inhalation
LC50 Mouse 1237 mg/l, 120 Minutes
52 %, 120 Minutes
Rat 1355 mg/l
658 mg/l/4h

* Estimates for product may be based on additional component data not shown.
Skin corrosion/irritation May be irritating to the skin. Prolonged skin contact may cause temporary irritation.
Serious eye damage/eye Direct contact with eyes may cause temporary irritation. May be irritating to eyes.
irritation
Respiratory or skin sensitization
Respiratory sensitization Not a respiratory sensitizer.
Skin sensitization This product is not expected to cause skin sensitization.
Germ cell mutagenicity No data available to indicate product or any components present at greater than 0.1% are
mutagenic or genotoxic.
Carcinogenicity This product is not considered to be a carcinogen by IARC, ACGIH, NTP, or OSHA.
IARC Monographs. Overall Evaluation of Carcinogenicity
2-Butoxyethanol (CAS 111-76-2) 3 Not classifiable as to carcinogenicity to humans.
OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)
Not listed.
Reproductive toxicity This product is not expected to cause reproductive or developmental effects.
Specific target organ toxicity - Not classified.
single exposure
Specific target organ toxicity - Not classified.
repeated exposure
Aspiration hazard Not an aspiration hazard. Not likely, due to the form of the product.
Chronic effects Prolonged inhalation may be harmful. May be harmful if absorbed through skin.

2-Butoxy ethanol may be absorbed through the skin in toxic amounts if contact is repeated and
prolonged. These effects have not been observed in humans.

12. Ecological information


Ecotoxicity Harmful to aquatic life.

Product name: GLASS CLEANER SDS US

Product #: 1000000075 Version #: 02 Revision date: 05-30-2015 Issue date: 05-26-2015 6 / 10


Product Species Test Results
GLASS CLEANER (CAS Mixture)
Aquatic
Crustacea EC50 Daphnia 13838.1602 mg/l, 48 hours estimated
Components Species Test Results
2-Butoxyethanol (CAS 111-76-2)
Aquatic
Fish LC50 Inland silverside (Menidia beryllina) 1250 mg/l, 96 hours
Ethyl Alcohol (CAS 64-17-5)
Aquatic
Crustacea EC50 Water flea (Daphnia magna) 7700 - 11200 mg/l, 48 hours
Fish LC50 Fathead minnow (Pimephales promelas) > 100.1 mg/l, 96 hours

* Estimates for product may be based on additional component data not shown.
Persistence and degradability No data is available on the degradability of this product.
Bioaccumulative potential No data available.
Partition coefficient n-octanol / water (log Kow)
2-Butoxyethanol 0.83
Butane 2.89
Ethyl Alcohol -0.31
Propane 2.36
Mobility in soil No data available.
Other adverse effects No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation
potential, endocrine disruption, global warming potential) are expected from this component.

13. Disposal considerations


Disposal instructions Consult authorities before disposal. Contents under pressure. Do not puncture, incinerate or crush.
Dispose of contents/container in accordance with local/regional/national/international regulations.
Local disposal regulations Dispose in accordance with all applicable regulations.
Hazardous waste code The waste code should be assigned in discussion between the user, the producer and the waste
disposal company.
Waste from residues / unused Dispose of in accordance with local regulations. Empty containers or liners may retain some
products product residues. This material and its container must be disposed of in a safe manner (see:
Disposal instructions).
Contaminated packaging Empty containers should be taken to an approved waste handling site for recycling or disposal.
Since emptied containers may retain product residue, follow label warnings even after container is
emptied. Do not re-use empty containers.

14. Transport information


DOT
UN number UN1950
UN proper shipping name Aerosols
Transport hazard class(es)
Class 2.2
Subsidiary risk -
Label(s) 2.2
Packing group Not applicable.
Special precautions for user Read safety instructions, SDS and emergency procedures before handling.
Packaging exceptions 306
Packaging non bulk None
Packaging bulk None
This product meets the exception requirements of section 173.306 as a limited quantity and may be shipped as a limited quantity.
Until 12/31/2020, the "Consumer Commodity - ORM-D" marking may still be used in place of the new limited quantity diamond
mark for packages of UN 1950 Aerosols. Limited quantities require the limited quantity diamond mark on cartons after 12/31/20
and may be used now in place of the "Consumer Commodity ORM-D" marking and both may be displayed concurrently.
IATA
UN number UN1950
UN proper shipping name Aerosols, non-flammable

Product name: GLASS CLEANER SDS US

Product #: 1000000075 Version #: 02 Revision date: 05-30-2015 Issue date: 05-26-2015 7 / 10


Transport hazard class(es)
Class 2.2
Subsidiary risk -
Label(s) 2.2
Packing group Not applicable.
Environmental hazards No.
ERG Code 2L
Special precautions for user Read safety instructions, SDS and emergency procedures before handling.
Other information
Passenger and cargo Allowed.
aircraft
Cargo aircraft only Allowed.
Packaging Exceptions LTD QTY
IMDG
UN number UN1950
UN proper shipping name AEROSOLS
Transport hazard class(es)
Class 2.2
Subsidiary risk -
Label(s) 2.2
Packing group Not applicable.
Environmental hazards
Marine pollutant No.
EmS Not available.
Special precautions for user Read safety instructions, SDS and emergency procedures before handling.
Packaging Exceptions LTD QTY
Transport in bulk according to Not applicable.
Annex II of MARPOL 73/78 and
the IBC Code
DOT

IATA; IMDG

15. Regulatory information


US federal regulations This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication
Standard, 29 CFR 1910.1200.
All components are on the U.S. EPA TSCA Inventory List.
TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D)
Not regulated.
CERCLA Hazardous Substance List (40 CFR 302.4)
Not listed.
Product name: GLASS CLEANER SDS US

Product #: 1000000075 Version #: 02 Revision date: 05-30-2015 Issue date: 05-26-2015 8 / 10


SARA 304 Emergency release notification
Not regulated.
OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)
Not listed.
Superfund Amendments and Reauthorization Act of 1986 (SARA)
Hazard categories Immediate Hazard - No
Delayed Hazard - No
Fire Hazard - No
Pressure Hazard - Yes
Reactivity Hazard - No
SARA 302 Extremely hazardous substance
Not listed.
SARA 311/312 Hazardous No
chemical
SARA 313 (TRI reporting)
Not regulated.

Other federal regulations


Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List
Not regulated.
Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130)
Butane (CAS 106-97-8)
Propane (CAS 74-98-6)
Safe Drinking Water Act Not regulated.
(SDWA)
US state regulations
US. Massachusetts RTK - Substance List
2-Butoxyethanol (CAS 111-76-2)
Butane (CAS 106-97-8)
Ethyl Alcohol (CAS 64-17-5)
Propane (CAS 74-98-6)
US. New Jersey Worker and Community Right-to-Know Act
2-Butoxyethanol (CAS 111-76-2)
Butane (CAS 106-97-8)
Ethyl Alcohol (CAS 64-17-5)
Propane (CAS 74-98-6)
US. Pennsylvania Worker and Community Right-to-Know Law
2-Butoxyethanol (CAS 111-76-2)
Butane (CAS 106-97-8)
Ethyl Alcohol (CAS 64-17-5)
Propane (CAS 74-98-6)
US. Rhode Island RTK
Butane (CAS 106-97-8)
Propane (CAS 74-98-6)
US. California Proposition 65
California Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition 65): This material is not known to contain
any chemicals currently listed as carcinogens or reproductive toxins.
International Inventories
Country(s) or region Inventory name On inventory (yes/no)*
Australia Australian Inventory of Chemical Substances (AICS) Yes
Canada Domestic Substances List (DSL) Yes
Canada Non-Domestic Substances List (NDSL) No
China Inventory of Existing Chemical Substances in China (IECSC) Yes
Europe European Inventory of Existing Commercial Chemical Yes
Substances (EINECS)
Europe European List of Notified Chemical Substances (ELINCS) No
Japan Inventory of Existing and New Chemical Substances (ENCS) No
Korea Existing Chemicals List (ECL) No
Product name: GLASS CLEANER SDS US

Product #: 1000000075 Version #: 02 Revision date: 05-30-2015 Issue date: 05-26-2015 9 / 10


Country(s) or region Inventory name On inventory (yes/no)*
New Zealand New Zealand Inventory No
Philippines Philippine Inventory of Chemicals and Chemical Substances No
(PICCS)
United States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory Yes
*A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s)
A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing
country(s).

16. Other information, including date of preparation or last revision


Issue date 05-26-2015
Revision date 05-30-2015
Version # 02
References EPA: AQUIRE database
NLM: Hazardous Substances Data Base
US. IARC Monographs on Occupational Exposures to Chemical Agents
Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge,
information and belief at the date of its publication. The information given is designed only as a
guidance for safe handling, use, processing, storage, transportation, disposal and release and is
not to be considered a warranty or quality specification. The information relates only to the specific
material designated and may not be valid for such material used in combination with any other
materials or in any process, unless specified in the text.
Revision Information Product and Company Identification: Alternate Trade Names

Product name: GLASS CLEANER SDS US

Product #: 1000000075 Version #: 02 Revision date: 05-30-2015 Issue date: 05-26-2015 10 / 10


Material Safety Data Sheet
High Build Undercoat 550G. Paintable
Version 1.0 Revision Date 12/03/2014 Print Date 12/05/2014

NFPA: Flammability HMIS III:


HEALTH 3*
1
Reactivity
Health

2 0 FLAMMABILITY 1
PHYSICAL 0
Specific Hazard 0 = Insignificant, 1 =Slight,
2 =Moderate, 3 =High, 4 = Extreme

SECTION 1. PRODUCT AND COMPANY IDENTIFICATION

Commercial Product : High Build Undercoat 550G. Paintable


Name
Product code : 890.9072
SDS-Identcode : 10047413
Product Use Description : Colouring agents, dyes
Company : Würth Canada Limited
345 Hanlon Creek Blvd
GUELPH, ON N1C 0A1
Canada
Telephone : +1 (905) 564 6225
Telefax : +1 (905) 564 3671
Responsible/issuing : [email protected]
person
Emergency telephone : In case of emergency please contact: CANUTEC (5:00
number pm - 8:00 am):
+1 (613) 996 6666
WÜRTH CANADA LIMITED (8:00 am - 5:00 pm):
+1 (905) 564 6225

SECTION 2. HAZARDS IDENTIFICATION

Emergency Overview

Form : Aerosol containing a liquefied gas


Colour : black
Odour : solvent-like
Odour - Control : No data available
parameters
Hazard Summary : Extremely flammable aerosol.

1 / 12
Material Safety Data Sheet
High Build Undercoat 550G. Paintable
Version 1.0 Revision Date 12/03/2014 Print Date 12/05/2014

May cause fire.


Compressed gas
Pressurized container. Protect from sunlight and do not
expose to temperatures exceeding 50°C / 122 °F.
Irritant
Reproductive hazard
Possible cancer hazard - may cause cancer

Potential Health Effects

Target Organs : Liver


Kidney
Eyes
Skin
Central nervous system

Eyes : May cause eye irritation.

Skin : May cause skin irritation.


Prolonged or repeated contact may dry skin and cause
irritation.

Inhalation : Harmful if inhaled.


May be fatal if inhaled.
May cause drowsiness or dizziness.

Chronic Exposure : This product contains a material that may cause adverse
reproductive effects.*

ACGIH : Carbon black (CAS-No.: 1333-86-4)


distillates (petroleum), hydrotreated light (CAS-No.:
64742-47-8)

NTP : No component of this product present at levels greater


than or equal to 0.1% is identified as a known or
anticipated carcinogen by NTP.

IARC : Titanium dioxide (CAS-No.: 13463-67-7)


Carbon black (CAS-No.: 1333-86-4)

2 / 12
Material Safety Data Sheet
High Build Undercoat 550G. Paintable
Version 1.0 Revision Date 12/03/2014 Print Date 12/05/2014

OSHA : No component of this product present at levels greater


than or equal to 0.1% is identified as a carcinogen or
potential carcinogen by OSHA.

SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS

Component CAS-No. Weight percent-


Weight percent

tert-butyl acetate 540-88-5 >= 55 - < 60


toluene 108-88-3 >= 25 - < 35
propane 74-98-6 >= 7 - < 10
isobutane 75-28-5 >= 3 - < 5
Carbon black 1333-86-4 >= 0.75 - < 1

SECTION 4. FIRST AID MEASURES

General advice : In the case of accident or if you feel unwell, seek medical
advice immediately (show the label where possible). First
aider needs to protect himself. Move out of dangerous
area. Never give anything by mouth to an unconscious
person. Take off contaminated clothing and shoes
immediately.
Inhalation : If breathed in, move person into fresh air. Call a physician
immediately. Keep patient warm and at rest. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen.
Skin contact : In case of contact, immediately flush skin with soap and
plenty of water. Do NOT use solvents or thinners. If skin
irritation persists, call a physician.
Eye contact : Protect unharmed eye. If easy to do, remove contact
lens, if worn. Rinse with water. Get medical attention.
Ingestion : If swallowed, seek medical advice immediately and show
this container or label. If swallowed, DO NOT induce
vomiting. If a person vomits when lying on his back, place
him in the recovery position. Get medical attention.

SECTION 5. FIREFIGHTING MEASURES

Form : Aerosol containing a liquefied gas


Ignition temperature : 450 °C (842 °F)
3 / 12
Material Safety Data Sheet
High Build Undercoat 550G. Paintable
Version 1.0 Revision Date 12/03/2014 Print Date 12/05/2014

Lower explosion limit : 2.1 %(V)

Upper explosion limit : 9.5 %(V)

Suitable extinguishing : Foam


media Alcohol-resistant foam
Dry chemical
Water mist

Specific hazards during : Do not use a solid water stream as it may scatter and
firefighting spread fire.
Hazardous decomposition products may be formed
under fire conditions (see section 10).
Exposure to decomposition products may be a hazard to
health.

Special protective : In the event of fire, wear self-contained breathing


equipment for firefighters apparatus.
Use personal protective equipment.

Further information : Standard procedure for chemical fires.


Use extinguishing measures that are appropriate to local
circumstances and the surrounding environment.
In the event of fire and/or explosion do not breathe
fumes.
Use water spray to cool unopened containers.
Collect contaminated fire extinguishing water separately.
This must not be discharged into drains.
Fire residues and contaminated fire extinguishing water
must be disposed of in accordance with local
regulations.
If the temperature rises there is danger of the vessels
bursting due to the high vapor pressure.

SECTION 6. ACCIDENTAL RELEASE MEASURES

Personal precautions : Refer to protective measures listed in sections 7 and 8.


Use personal protective equipment.
Remove all sources of ignition.
Avoid contact with skin and eyes.
4 / 12
Material Safety Data Sheet
High Build Undercoat 550G. Paintable
Version 1.0 Revision Date 12/03/2014 Print Date 12/05/2014

Ensure adequate ventilation, especially in confined areas.


Immediately evacuate personnel to safe areas.
Avoid inhalation of vapour or mist.
Beware of vapours accumulating to form explosive
concentrations. Vapours can accumulate in low areas.

Environmental : Do not flush into surface water or sanitary sewer system.


precautions Prevent further leakage or spillage if safe to do so.
If the product contaminates rivers and lakes or drains
inform respective authorities.

Methods for cleaning up : Contain and collect spillage with non-combustible


absorbent material, (e.g. sand, earth, diatomaceous
earth, vermiculite) and place in container for disposal
according to local / national regulations.
Clean contaminated surface thoroughly.

SECTION 7. HANDLING AND STORAGE

Handling
Handling : For personal protection see section 8.
Limit the stocks at work place.
Use only in well-ventilated areas.
Do not breathe vapours or spray mist.
Avoid contact with skin and eyes.
Do not spray on a naked flame or any incandescent
material.
Prevent the creation of flammable or explosive
concentrations of vapour in air and avoid vapour
concentration higher than the occupational exposure
limits.
Take precautionary measures against static discharges.
Handle with care.

Advice on protection : Normal measures for preventive fire protection.


against fire and explosion Vapours are heavier than air and may spread along
floors.
Vapours may form explosive mixtures with air.
Keep away from heat and sources of ignition.
Do not smoke.
No sparking tools should be used.
Electrical equipment should be protected to the
appropriate standard.

5 / 12
Material Safety Data Sheet
High Build Undercoat 550G. Paintable
Version 1.0 Revision Date 12/03/2014 Print Date 12/05/2014

Dust explosion class : Not applicable

Storage
Requirements for storage : Store in a place accessible by authorized persons only.
areas and containers Store in original container.
BEWARE: Aerosol is pressurized. Keep away from heat.
Keep away from direct sunlight. Do not open by force or
throw into fire even after use. Do not spray on flames or
red-hot objects.
Keep containers tightly closed in a cool, well-ventilated
place.
Please observe the storage instructions for aerosols!

Advice on common : Incompatible with oxidizing agents.


storage Keep away from reducing agents.

Keep away from food, drink and animal feedingstuffs.


Do not store together with oxidizing and self-igniting
products.

Other data : No decomposition if stored and applied as directed.

SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Exposure Guidelines

Components CAS-No. List Type: Value Update


200 ppm 950
tert-butyl acetate 540-88-5 CA AB OEL TWA 2007-01-01
mg/m3
CA BC OEL TWA 200 ppm 2006-11-29
200 ppm 950
CA QC OEL TWAEV 2006-12-29
mg/m3
50 ppm 188
toluene 108-88-3 CA AB OEL TWA 2007-01-01
mg/m3
CA BC OEL TWA 20 ppm 2009-02-09
50 ppm 188
CA QC OEL TWAEV 2006-12-29
mg/m3
propane 74-98-6 CA AB OEL TWA 1,000 ppm 2009-04-30
CA BC OEL TWA 1,000 ppm 2006-11-29
1,000 ppm
CA QC OEL TWAEV 2006-12-29
1,800 mg/m3
CA ON OEL TWA 1,000 ppm 2010-11-05
Calcium carbonate 1317-65-3 CA AB OEL TWA 10 mg/m3 2009-04-30
CA BC OEL TWA 10 mg/m3 2006-11-29

6 / 12
Material Safety Data Sheet
High Build Undercoat 550G. Paintable
Version 1.0 Revision Date 12/03/2014 Print Date 12/05/2014

CA BC OEL STEL 20 mg/m3 2006-11-29


CA QC OEL TWAEV 10 mg/m3 2012-11-28
isobutane 75-28-5 CA BC OEL TWA 1,000 ppm 2006-11-29
CA AB OEL TWA 1,000 ppm 2009-04-30
CA ON OEL TWA 800 ppm 2012-06-12
Hydrocarbons, C11-C14, n-
alkanes, isoalkanes, cyclics, 64742-47-8 CA BC OEL TWA 200 mg/m3 2006-11-29
<2% aromatics
CA QC OEL TWAEV 5 mg/m3 2006-12-29
CA QC OEL STEV 10 mg/m3 2006-12-29
CA ON OEL TWA 525 mg/m3 2010-11-05
CA AB OEL TWA 200 mg/m3 2009-04-30
CA AB OEL TWA 5 mg/m3 2009-04-30
CA AB OEL STEL 10 mg/m3 2009-04-30
CA QC OEL TWAEV 5 mg/m3 2012-11-28
CA QC OEL STEV 10 mg/m3 2012-11-28
Carbon black 1333-86-4 CA AB OEL TWA 3.5 mg/m3 2007-01-01
CA QC OEL TWAEV 3.5 mg/m3 2006-12-29
CA BC OEL TWA 3 mg/m3 2011-09-15

Engineering measures : Provide sufficient air exchange and/or exhaust in work


rooms.

Eye protection : Tightly fitting safety goggles

Hand protection : Choose gloves to protect hands against chemicals


depending on the concentration and quantity of the
hazardous substance and specific to place of work.
For special applications, we recommend clarifying the
resistance to chemicals of the aforementioned protective
gloves with the glove manufacturer.

Skin and body protection : Flame retardant antistatic protective clothing.


Choose body protection according to the amount and
concentration of the dangerous substance at the work
place.

Respiratory protection : When workers are facing concentrations above the


exposure limit they must use appropriate certified
respirators.
Product contains low-boiling liquids. Respiratory
protective equipment must be air supplied respirators.

Hygiene measures : Handle in accordance with good industrial hygiene and


safety practice.
General industrial hygiene practice.
Do not inhale aerosol.
Avoid contact with skin, eyes and clothing.
When using do not eat, drink or smoke.

7 / 12
Material Safety Data Sheet
High Build Undercoat 550G. Paintable
Version 1.0 Revision Date 12/03/2014 Print Date 12/05/2014

Wash hands before breaks and at the end of workday.


Follow the skin protection plan.
Take off all contaminated clothing immediately.
Wash contaminated clothing before re-use.

SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

Form : Aerosol containing a liquefied gas


Colour : black
Odour : solvent-like
Ignition temperature : 450 °C (842 °F)

Lower explosion limit : 2.1 %(V)

Upper explosion limit : 9.5 %(V)

pH : Not applicable

Boiling point/boiling range : >98 °C(208 °F)

Vapour pressure : 3.79 - 4.14 bar


at 20 °C (68 °F)

Relative vapour density : >1


(Air = 1.0)

Density : 0.90 g/cm3


at 25 °C (77 °F)
Water solubility : insoluble

Volatile organic : 29.5 %


compounds (VOC) content 265.35 g/l

SECTION 10. STABILITY AND REACTIVITY

Conditions to avoid : Heat, flames and sparks.

Materials to avoid : Strong oxidizing agents


Reducing agents
hydrides

Hazardous decomposition : Carbon oxides

8 / 12
Material Safety Data Sheet
High Build Undercoat 550G. Paintable
Version 1.0 Revision Date 12/03/2014 Print Date 12/05/2014

products Smoke
Hydrocarbons

Build-up of dangerous/toxic fumes possible in cases of


fire/high temperature.

Hazardous reactions : Note: No decomposition if stored and applied as


directed.

Vapours may form explosive mixtures with air.


If the temperature rises there is danger of the vessels
bursting due to the high vapor pressure.

SECTION 11. TOXICOLOGICAL INFORMATION

Carcinogenicity : No data is available on the product itself.


Reproductive toxicity : No data is available on the product itself.
Teratogenicity : No data is available on the product itself.
Further information : Symptoms of overexposure may be headache, dizziness,
tiredness, nausea and vomiting.
Vapours may cause drowsiness and dizziness.

Component:
toluene 108-88-3 Acute oral toxicity: LD50 Rat
Dose: 5,580 mg/kg

Acute dermal toxicity: LD50 Rabbit


Dose: ca. 12,267 mg/kg

Acute inhalation toxicity: LC50 Rat


Dose: >= 28.1 mg/lExposure time: 4 h
Method: OECD Test Guideline 403

Skin irritation: Rabbit


Result: irritating

Eye irritation: Rabbit


Result: No eye irritation
Method: OECD Test Guideline 405

Reproductive toxicity: Suspected human reproductive


toxicant, Suspected of damaging the unborn child.

isobutane 75-28-5 Acute inhalation toxicity: LC50 Mouse


Dose: 1,237 mg/lExposure time: 120 min

Mutagenicity: Tests on bacterial or mammalian cell


cultures did not show mutagenic effects.
9 / 12
Material Safety Data Sheet
High Build Undercoat 550G. Paintable
Version 1.0 Revision Date 12/03/2014 Print Date 12/05/2014

Reproductive toxicity: No toxicity to reproduction

Carbon black 1333-86-4 Eye irritation: Result: irritating

SECTION 12. ECOLOGICAL INFORMATION

Volatile organic : 29.5 %


compounds (VOC)
content
Additional ecological : The product should not be allowed to enter drains, water
information courses or the soil.

Component:
toluene 108-88-3 Toxicity to fish:
LC50
Species: Oncorhynchus kisutch (coho salmon)
Dose: 5.5 mg/l
Exposure time: 96 h

Acute and prolonged toxicity for aquatic invertebrates:


EC50
Species: Ceriodaphnia dubia (water flea)
Dose: 3.78 mg/l
Exposure time: 48 h

Toxicity to algae:
EC50
Species: Chlorella vulgaris (Fresh water algae)
Dose: 134 mg/l
Exposure time: 3 h

Toxicity to bacteria:
EC50
Species: Bacteria
Dose: 84 mg/l
Exposure time: 24 h

SECTION 13. DISPOSAL CONSIDERATIONS

Adequate disposal : In accordance with local and national regulations.

SECTION 14. TRANSPORT INFORMATION

10 / 12
Material Safety Data Sheet
High Build Undercoat 550G. Paintable
Version 1.0 Revision Date 12/03/2014 Print Date 12/05/2014

DOT 49 CFR
ID No : UN 1950
Proper shipping name : Aerosols
Class : 2.1
Labels : 2.1
Emergency Response : 126
Guidebook Number

TDGR
ID No : UN 1950
Proper shipping name : AEROSOLS
Class : 2.1
Labels : 2.1

ICAO/IATA-DGR
ID No : UN 1950
Proper shipping name : Aerosols, flammable
Class : 2.1
ICAO-Labels : 2.1
Packing instruction (cargo : 203
aircraft)
Packing instruction : 203
(passenger aircraft)
Packing instruction : Y203
(passenger aircraft)
Environmentally hazardous : no

IMDG-Code
ID No : UN 1950
Description of the goods : AEROSOLS

Class : 2.1
IMDG-Labels : 2.1
EmS Number 1 : F-D
EmS Number 2 : S-U

Marine pollutant : no

SECTION 15. REGULATORY INFORMATION

WHMIS Classification : A Compressed Gas


B1 Flammable gas
D2A Very Toxic Material Causing Other Toxic Effects
D2B Toxic Material Causing Other Toxic Effects

11 / 12
Material Safety Data Sheet
High Build Undercoat 550G. Paintable
Version 1.0 Revision Date 12/03/2014 Print Date 12/05/2014

Compressed Gas
Flammable gas
Carcinogen
Reproductive hazard
Moderate skin irritant

This product has been classified according to the hazard criteria of the CPR and the MSDS
contains all of the information required by the CPR.

SECTION 16. OTHER INFORMATION

Further information
The information provided in this Safety Data Sheet is correct to the best of our knowledge,
information and belief at the date of its publication. The information given is designed only
as a guidance for safe handling, use, processing, storage, transportation, disposal and
release and is not to be considered a warranty or quality specification. The information
relates only to the specific material designated and may not be valid for such material used
in combination with any other materials or in any process, unless specified in the text.

Prepared by : SAP Business Compliance Services GmbH


Birlenbacher Str. 19
D-57078 Siegen
Germany
Telephone: +49-(0)271-88072-0
Revision Date : 12/03/2014

12 / 12
JOHNSEN'S BRAKE CLEANER 16 OZ.
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
Revision date: 08/19/2014 : Version:

SECTION 1: Identification of the substance/mixture and of the company/undertaking


1.1. Product identifier
Product form : Mixture
Trade name : JOHNSEN'S BRAKE CLEANER 16 OZ.
Product code : 2420
1.2. Relevant identified uses of the substance or mixture and uses advised against
Use of the substance/mixture : Brake Parts Cleaner
1.3. Details of the supplier of the safety data sheet
Technical Chemical Company
P.O. BOX 139
Cleburne, Texas 76033
T 817-645-6088
1.4. Emergency telephone number
Emergency number : CHEMTREC 24 Hour 1-800-424-9300, 1-703-527-3887 (International)

SECTION 2: Hazards identification


2.1. Classification of the substance or mixture
Classification (GHS-US)
Compressed gas H280
Acute Tox. 4 (Inhalation) H332
Acute Tox. 4 (Inhalation:gas) H332
Eye Irrit. 2B H320
Carc. 1B H350
Full text of H-phrases: see section 16

2.2. Label elements


GHS-US labeling
Hazard pictograms (GHS-US) :

GHS04 GHS07 GHS08


Signal word (GHS-US) : Danger
Hazard statements (GHS-US) : H280 - Contains gas under pressure; may explode if heated
H320 - Causes eye irritation
H332 - Harmful if inhaled
H350 - May cause cancer
Precautionary statements (GHS-US) : P201 - Obtain special instructions
P202 - Do not handle until all safety precautions have been read and understood
P261 - Avoid breathing dust,fume,gas,mist,vapor spray
P264 - Wash affected areas thoroughly after handling
P271 - Use only outdoors or in a well-ventilated area
P280 - Wear protective gloves,protective clothing,eye protection,face protection
P304+P340 - If inhaled: Remove person to fresh air and keep comfortable for breathing
P305+P351+P338 - If in eyes: Rinse cautiously with water for several minutes. Remove contact
lenses, if present and easy to do. Continue rinsing
P308+P313 - If exposed or concerned: Get medical advice/attention
P312 - Call a POISON CONTROL CENTER, doctor, if you feel unwell.
P337+P313 - If eye irritation persists: Get medical advice/attention
P405 - Store locked up
P410+P403 - Protect from sunlight. Store in a well-ventilated place
P501 - Dispose of contents/container to appropriate waste disposal facility, in accordance with
local, regional, national, international regulations.
2.3. Other hazards
Other hazards not contributing to the : Contains gas under pressure; may explode if heated.
classification
2.4. Unknown acute toxicity (GHS-US)
No data available

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JOHNSEN'S BRAKE CLEANER 16 OZ.
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations

SECTION 3: Composition/information on ingredients


3.1. Substance
Not applicable
3.2. Mixture
Name Product identifier % Classification (GHS-US)
Tetrachloroethylene (CAS No) 127-18-4 >= 95 Carc. 1B, H350
Aquatic Chronic 2, H411
Carbon Dioxide, Liquefied, Under Pressure (CAS No) 124-38-9 1-5 Compressed gas, H280
The exact percentage is a trade secret.

SECTION 4: First aid measures


4.1. Description of first aid measures
First-aid measures general : Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice
(show the label where possible).
First-aid measures after inhalation : Allow victim to breathe fresh air. Allow the victim to rest. Remove victim to fresh air and keep at
rest in a position comfortable for breathing. Call a POISON CENTER or doctor/physician if you
feel unwell.
First-aid measures after skin contact : Remove affected clothing and wash all exposed skin area with mild soap and water, followed by
warm water rinse.
First-aid measures after eye contact : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present
and easy to do. Continue rinsing.
First-aid measures after ingestion : Rinse mouth. Do NOT induce vomiting. Obtain emergency medical attention.
4.2. Most important symptoms and effects, both acute and delayed
Symptoms/injuries : May cause cancer.
Symptoms/injuries after inhalation : Danger of serious damage to health by prolonged exposure through inhalation. Harmful if
inhaled.
Symptoms/injuries after skin contact : May cause slight irritation . Itching. Skin rash/inflammation. Red skin.
Symptoms/injuries after eye contact : Irritation of the eye tissue. Inflammation/damage of the eye tissue. Redness of the eye tissue.
Causes eye irritation.
Symptoms/injuries after ingestion : May be harmful if swallowed and enters airways. May be fatal if swallowed and enters airways.
4.3. Indication of any immediate medical attention and special treatment needed
No additional information available

SECTION 5: Firefighting measures


5.1. Extinguishing media
Suitable extinguishing media : Foam. Dry powder. Carbon dioxide. Water spray. Sand.
Unsuitable extinguishing media : Do not use a heavy water stream.
5.2. Special hazards arising from the substance or mixture
Fire hazard : Not flammable.
5.3. Advice for firefighters
Firefighting instructions : Use water spray or fog for cooling exposed containers. Exercise caution when fighting any
chemical fire. Prevent fire-fighting water from entering environment.
Protection during firefighting : Do not enter fire area without proper protective equipment, including respiratory protection.
Other information : NFPA Aerosol Level 1.

SECTION 6: Accidental release measures


6.1. Personal precautions, protective equipment and emergency procedures
General measures : Remove ignition sources.

6.1.1. For non-emergency personnel


Protective equipment : Gloves. Safety glasses.
Emergency procedures : Evacuate unnecessary personnel.

6.1.2. For emergency responders


Protective equipment : Equip cleanup crew with proper protection.
Emergency procedures : Ventilate area.
6.2. Environmental precautions
Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters.

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JOHNSEN'S BRAKE CLEANER 16 OZ.
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations

6.3. Methods and material for containment and cleaning up


For containment : Dam up the liquid spill. Contain released substance, pump into suitable containers. Plug the leak,
cut off the supply.
Methods for cleaning up : Store away from other materials.
6.4. Reference to other sections
See Heading 8. Exposure controls and personal protection.

SECTION 7: Handling and storage


7.1. Precautions for safe handling
Precautions for safe handling : Wash hands and other exposed areas with mild soap and water before eating, drinking or
smoking and when leaving work. Provide good ventilation in process area to prevent formation of
vapor. Use only outdoors or in a well-ventilated area. Avoid breathing dust,fume,gas,mist,vapor
spray. Obtain special instructions . Do not handle until all safety precautions have been read and
understood.
Hygiene measures : Wash hands and other exposed areas with mild soap and water before eating, drinking or
smoking and when leaving work. Do not eat, drink or smoke when using this product. Wash
affected areas thoroughly after handling. Wash contaminated clothing before reuse.
7.2. Conditions for safe storage, including any incompatibilities
Technical measures : Proper grounding procedures to avoid static electricity should be followed. Comply with
applicable regulations.
Storage conditions : Keep only in the original container in a cool, well ventilated place away from : Keep container
closed when not in use.
Incompatible products : Strong bases. Strong acids.
Incompatible materials : Sources of ignition. Direct sunlight.
Storage area : Store in a well-ventilated place.
7.3. Specific end use(s)
Follow Label Directions.

SECTION 8: Exposure controls/personal protection


8.1. Control parameters

Tetrachloroethylene (127-18-4)
USA ACGIH ACGIH TWA (mg/m³) 170 mg/m³
USA ACGIH ACGIH TWA (ppm) 25 ppm
USA ACGIH ACGIH STEL (mg/m³) 685 mg/m³
USA ACGIH ACGIH STEL (ppm) 100 ppm
USA OSHA OSHA PEL (TWA) (ppm) 100 ppm
USA OSHA OSHA PEL (Ceiling) (ppm) 200 ppm

Carbon Dioxide, Liquefied, Under Pressure (124-38-9)


USA ACGIH ACGIH TWA (mg/m³) 9000 mg/m³
USA ACGIH ACGIH TWA (ppm) 5000 ppm
USA ACGIH ACGIH STEL (mg/m³) 54000
USA ACGIH ACGIH STEL (ppm) 30000 ppm
USA OSHA OSHA PEL (TWA) (mg/m³) 9000 mg/m³
USA OSHA OSHA PEL (TWA) (ppm) 5000 ppm

8.2. Exposure controls


Appropriate engineering controls : Local exhaust venilation, vent hoods . Ensure good ventilation of the work station.
Personal protective equipment : Gloves. Safety glasses. Avoid all unnecessary exposure.

Hand protection : Wear protective gloves.


Eye protection : Chemical goggles or safety glasses.
Skin and body protection : Wear suitable protective clothing.
Respiratory protection : Wear appropriate mask.
Other information : Do not eat, drink or smoke during use.
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JOHNSEN'S BRAKE CLEANER 16 OZ.
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations

SECTION 9: Physical and chemical properties


9.1. Information on basic physical and chemical properties
Physical state : Gas
Appearance : Liquid.
Molecular mass : 165.83 g/mol
Color : Colourless.
Odor : Sweet odour. Ether-like odour.
Odor threshold : 2.0 - 71 ppm
pH : 6.8 - 8.4
Relative evaporation rate (butyl acetate=1) : 2
Relative evaporation rate (ether=1) : 8
Melting point : -22 °C
Freezing point : No data available
Boiling point : 121 °C
Flash point : None
Critical temperature : 347 °C
Auto-ignition temperature : No data available
Decomposition temperature : > 150 °C
Flammability (solid, gas) : No data available
Vapor pressure : 19 hPa
Vapor pressure at 50 °C : 82 hPa
Relative vapor density at 20 °C : 5.8
Relative density : 1.62
Relative density of saturated gas/air mixture : 1.1
Specific gravity / density : 1623 kg/m³
Solubility : Insoluble in water. Substance sinks in water. Soluble in ethanol. Soluble in ether. Soluble in
acetone. Soluble in chloroform. Soluble in tetrachloromethane. Soluble in hexane. Soluble in
oils/fats.
Water: 0.015 g/100ml
Ethanol: soluble
Ether: soluble
Acetone: > 10 g/100ml
Log Pow : 3.40 (Experimental value; 2.53; Experimental value; Equivalent or similar to OECD 107; 23 °C)
Log Kow : No data available
Viscosity, kinematic : 0.555 mm²/s (20 °C)
Viscosity, dynamic : No data available
Explosive properties : No data available
Oxidizing properties : No data available
Explosive limits : No data available
9.2. Other information
Saturation concentration : 127 g/m³
VOC content : 0%

SECTION 10: Stability and reactivity


10.1. Reactivity
No additional information available
10.2. Chemical stability
Not established.
10.3. Possibility of hazardous reactions
Not established.
10.4. Conditions to avoid
Direct sunlight. Extremely high or low temperatures.
10.5. Incompatible materials
Strong acids. Strong bases.
10.6. Hazardous decomposition products
Toxic fume. . Carbon monoxide. Carbon dioxide.

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JOHNSEN'S BRAKE CLEANER 16 OZ.
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations

SECTION 11: Toxicological information


11.1. Information on toxicological effects

Acute toxicity : Harmful if inhaled. Harmful if inhaled.


JOHNSEN'S BRAKE CLEANER 16 OZ.
LD50 oral rat 3835 mg/kg body weight
LD50 dermal rabbit > 3000 mg/kg (Rabbit; Literature study; >10000 mg/kg bodyweight; Rabbit; Experimental
value)
LC50 inhalation rat (mg/l) 27.58 mg/l/4h (Rat; Literature study)
LC50 inhalation rat (ppm) 5200 ppm/4h (Rat; Experimental value)

Tetrachloroethylene (127-18-4)
LD50 oral rat > 2000 mg/kg (Rat; Equivalent or similar to OECD 401; Literature study; 3835 mg/kg
bodyweight; Rat; Equivalent or similar to OECD 401; Experimental value; 3005 mg/kg
bodyweight; Rat; Experimental value)
LD50 dermal rabbit > 3000 mg/kg (Rabbit; Literature study; >10000 mg/kg bodyweight; Rabbit; Experimental
value)
LC50 inhalation rat (mg/l) 27.58 mg/l/4h (Rat; Literature study)
LC50 inhalation rat (ppm) 3786 ppm/4h (Rat; Experimental value)
Skin corrosion/irritation : Not classified
pH: 6.8 - 8.4
Serious eye damage/irritation : Causes eye irritation.
pH: 6.8 - 8.4
Respiratory or skin sensitization : Not classified
Germ cell mutagenicity : Not classified
Carcinogenicity : May cause cancer.
JOHNSEN'S BRAKE CLEANER 16 OZ.
IARC group 2A

Tetrachloroethylene (127-18-4)
IARC group 2A
Reproductive toxicity : Not classified
Specific target organ toxicity (single exposure) : Not classified
Specific target organ toxicity (repeated : Not classified
exposure)
Aspiration hazard : Not classified
Potential Adverse human health effects and : Based on available data, the classification criteria are not met. Harmful if inhaled.
symptoms
Symptoms/injuries after inhalation : Danger of serious damage to health by prolonged exposure through inhalation. Harmful if
inhaled.
Symptoms/injuries after skin contact : May cause slight irritation . Itching. Skin rash/inflammation. Red skin.
Symptoms/injuries after eye contact : Irritation of the eye tissue. Inflammation/damage of the eye tissue. Redness of the eye tissue.
Causes eye irritation.
Symptoms/injuries after ingestion : May be harmful if swallowed and enters airways. May be fatal if swallowed and enters airways.

SECTION 12: Ecological information


12.1. Toxicity
Ecology - general : Dangerous for the environment.
Ecology - air : Not classified as dangerous for the ozone layer (Regulation (EC) No 1005/2009). Not included in
the list of fluorinated greenhouse gases (Regulation (EC) No 842/2006). TA-Luft Klasse 5.2.5/I.
JOHNSEN'S BRAKE CLEANER 16 OZ.
LC50 fish 1 4.99 mg/l (96 h; Salmo gairdneri (Oncorhynchus mykiss); Locomotor effect)
EC50 Daphnia 1 8.5 mg/l (48 h; Daphnia magna; Locomotor effect)
LC50 fish 2 13 mg/l (96 h; Lepomis macrochirus)

Tetrachloroethylene (127-18-4)
LC50 fish 1 4.99 mg/l (96 h; Salmo gairdneri (Oncorhynchus mykiss); Locomotor effect)
EC50 Daphnia 1 8.5 mg/l (48 h; Daphnia magna; Locomotor effect)
LC50 fish 2 13 mg/l (96 h; Lepomis macrochirus)
Threshold limit algae 1 816 mg/l (96 h; Selenastrum capricornutum; Cell numbers)
Threshold limit algae 2 3.64 mg/l (72 h; Chlamydomonas angulosa; Growth rate)

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JOHNSEN'S BRAKE CLEANER 16 OZ.
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations

Carbon Dioxide, Liquefied, Under Pressure (124-38-9)


LC50 fish 1 35 mg/l (96 h; Salmo gairdneri (Oncorhynchus mykiss); Lethal)
LC50 fish 2 60 - 240 mg/l (12 h; Salmo gairdneri (Oncorhynchus mykiss); Lethal)

12.2. Persistence and degradability


JOHNSEN'S BRAKE CLEANER 16 OZ.
Persistence and degradability Not readily biodegradable in water. Low potential for adsorption in soil.
Biochemical oxygen demand (BOD) 0.06 g O₂ /g substance
ThOD 0.39 g O₂ /g substance
BOD (% of ThOD) 0.15 % ThOD

Tetrachloroethylene (127-18-4)
Persistence and degradability Not readily biodegradable in water. Low potential for adsorption in soil.
Biochemical oxygen demand (BOD) 0.06 g O₂ /g substance
ThOD 0.39 g O₂ /g substance
BOD (% of ThOD) 0.15 % ThOD

Carbon Dioxide, Liquefied, Under Pressure (124-38-9)


Persistence and degradability Biodegradability: not applicable. Not applicable (gas).
Biochemical oxygen demand (BOD) Not applicable
Chemical oxygen demand (COD) Not applicable
ThOD Not applicable
BOD (% of ThOD) Not applicable

12.3. Bioaccumulative potential


JOHNSEN'S BRAKE CLEANER 16 OZ.
BCF fish 1 40 - 115 Salmo gairdneri (Oncorhynchus mykiss)
BCF fish 2 25.8 - 77.1 (8 weeks; Cyprinus carpio)
BCF other aquatic organisms 1 63 (Modiolus modiolus; Mantle, dry weight)
BCF other aquatic organisms 2 39 (Buccinum undatum; Muscles, dry weight)
Log Pow 3.40 (Experimental value; 2.53; Experimental value; Equivalent or similar to OECD 107; 23 °C)
Bioaccumulative potential Low potential for bioaccumulation (BCF < 500).

Tetrachloroethylene (127-18-4)
BCF fish 1 40 - 115 Salmo gairdneri (Oncorhynchus mykiss)
BCF fish 2 25.8 - 77.1 (8 weeks; Cyprinus carpio)
BCF other aquatic organisms 1 63 (Modiolus modiolus; Mantle, dry weight)
BCF other aquatic organisms 2 39 (Buccinum undatum; Muscles, dry weight)
Log Pow 3.40 (Experimental value; 2.53; Experimental value; Equivalent or similar to OECD 107; 23 °C)
Bioaccumulative potential Low potential for bioaccumulation (BCF < 500).

Carbon Dioxide, Liquefied, Under Pressure (124-38-9)


Log Pow 0.83 (Experimental value)
Bioaccumulative potential Bioaccumulation: not applicable.

12.4. Mobility in soil


JOHNSEN'S BRAKE CLEANER 16 OZ.
Surface tension 0.0313 N/m (20 °C)

Tetrachloroethylene (127-18-4)
Surface tension 0.0313 N/m (20 °C)

12.5. Other adverse effects


Other information : Avoid release to the environment.

SECTION 13: Disposal considerations


13.1. Waste treatment methods
Waste disposal recommendations : Dispose in a safe manner in accordance with local/national regulations. Dispose of
contents/container to appropriate waste disposal facility, in accordance with local, regional,
national, international regulations.
Ecology - waste materials : Avoid release to the environment.

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JOHNSEN'S BRAKE CLEANER 16 OZ.
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations

SECTION 14: Transport information


In accordance with ADR / RID / IMDG / IATA / ADN
US DOT (ground): UN1950, Aerosols, 2.2, Limited Quantity
ICAO/IATA (air): UN1950, Aerosols, 2.2 , Limited Quantity
IMO/IMDG (water): UN1950, Aerosols, 2.2 , Limited Quantity

Not applicable

14.2. UN proper shipping name


Proper Shipping Name (DOT) : Aerosols
poison, (each not exceeding 1 L capacity)
Department of Transportation (DOT) Hazard : 2.2 - Class 2.2 - Non-flammable compressed gas 49 CFR 173.115
Classes
Hazard labels (DOT) : 2.2 - Non-flammable gas
6.1 - Poison inhalation hazard

DOT Packaging Exceptions (49 CFR 173.xxx) : 306


DOT Packaging Non Bulk (49 CFR 173.xxx) : None
DOT Packaging Bulk (49 CFR 173.xxx) : None
Marine pollutant : Yes
14.3. Additional information
Other information : No supplementary information available.

Overland transport
No additional information available
Transport by sea
DOT Vessel Stowage Location : A - The material may be stowed ‘‘on deck’’ or ‘‘under deck’’ on a cargo vessel and on a
passenger vessel.
DOT Vessel Stowage Other : 48 - Stow ‘‘away from’’ sources of heat,87 - Stow ‘‘separated from’’ Class 1 (explosives) except
Division 14,126 - Segregation same as for Class 9, miscellaneous hazardous materials

Air transport
DOT Quantity Limitations Passenger aircraft/rail : Forbidden
(49 CFR 173.27)
DOT Quantity Limitations Cargo aircraft only (49 : Forbidden
CFR 175.75)

SECTION 15: Regulatory information


15.1. US Federal regulations
JOHNSEN'S BRAKE CLEANER 16 OZ.
SARA Section 311/312 Hazard Classes Immediate (acute) health hazard
Delayed (chronic) health hazard
Sudden release of pressure hazard

Tetrachloroethylene (127-18-4)
Listed on the United States SARA Section 302
Listed on United States SARA Section 313
RQ (Reportable quantity, section 304 of EPA's 100 lb Tetrachloroethylene
List of Lists)
SARA Section 311/312 Hazard Classes Immediate (acute) health hazard
Delayed (chronic) health hazard

15.2. International regulations


CANADA
JOHNSEN'S BRAKE CLEANER 16 OZ.
WHMIS Classification Class D Division 1 Subdivision B - Toxic material causing immediate and serious toxic effects
Class D Division 2 Subdivision A - Very toxic material causing other toxic effects

Tetrachloroethylene (127-18-4)
Listed on the Canadian DSL (Domestic Sustances List)
13/02/2015 EN (English US) 7/9
JOHNSEN'S BRAKE CLEANER 16 OZ.
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations

Tetrachloroethylene (127-18-4)
WHMIS Classification Class D Division 1 Subdivision B - Toxic material causing immediate and serious toxic effects
Class D Division 2 Subdivision A - Very toxic material causing other toxic effects

EU-Regulations
No additional information available

Classification according to Regulation (EC) No. 1272/2008 [CLP]

Classification according to Directive 67/548/EEC [DSD] or 1999/45/EC [DPD]


Carc.Cat.3; R40
Full text of R-phrases: see section 16
15.2.2. National regulations

Tetrachloroethylene (127-18-4)
Listed on the Canadian IDL (Ingredient Disclosure List)

15.3. US State regulations


JOHNSEN'S BRAKE CLEANER 16 OZ.
State or local regulations Not for sale in California or New Jersey
U.S. - Pennsylvania - RTK (Right to Know) List
U.S. - California - Proposition 65 - Maximum Allowable Dose Levels (MADL)

Tetrachloroethylene (127-18-4)

U.S. - California - Proposition 65 - Maximum Allowable Dose Levels (MADL)


Not for sale in California or New Jersey
U.S. - Pennsylvania - RTK (Right to Know) List
U.S. - New Jersey - Right to Know Hazardous Substance List
U.S. - Massachusetts - Right To Know List
U.S. - Rhode Island - Hazardous Substance List

SECTION 16: Other information


Training advice : Normal use of this product shall imply use in accordance with the instructions on the packaging.
Other information : None.
Full text of H-phrases: see section 16:
------ Acute Tox. 4 (Inhalation) Acute toxicity (inhalation) Category 4
------ Acute Tox. 4 (Inhalation:gas) Acute toxicity (inhalation:gas) Category 4
------ Aquatic Chronic 2 Hazardous to the aquatic environment - Chronic Hazard Category 2
------ Carc. 1B Carcinogenicity Category 1B
------ Compressed gas Gases under pressure Compressed gas
------ Eye Irrit. 2B Serious eye damage/eye irritation Category 2B
------ H280 Contains gas under pressure; may explode if heated
------ H320 Causes eye irritation
------ H332 Harmful if inhaled
------ H350 May cause cancer
------ H411 Toxic to aquatic life with long lasting effects

NFPA health hazard : 2 - Intense or continued exposure could cause temporary


incapacitation or possible residual injury unless prompt
medical attention is given.
NFPA fire hazard : 0 - Materials that will not burn.
NFPA reactivity : 0 - Normally stable, even under fire exposure conditions,
and are not reactive with water.

HMIS III Rating


Health : 2 Moderate Hazard - Temporary or minor injury may occur
Flammability : 0 Minimal Hazard
Physical : 1 Slight Hazard

13/02/2015 EN (English US) 8/9


JOHNSEN'S BRAKE CLEANER 16 OZ.
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations

Personal Protection : B

SDS US (GHS HazCom 2012) - TCC

The Supplier identified in Section 1 of this MSDS has evaluated this product and certifies it to be labeled and packaged in compliance with the applicable provisions of the Federal Hazardous
Substance Act as stated in 16 CFR 1500 and enforced by the Consumer Product Safety Commission, and where applicable the products that require Child Resistant Closures are packaged in
accordance with the Poison Prevention Packaging Act as stated in 16 CFR 1700 and enforced by the Consumer Product Safety Commission. All closures have been tested in accordance with the
latest protocols. No other testing is required to certify compliance with the above. The date of manufacture is stamped on the product

Disclaimer: The information and recommendations contained herein are based upon tests believed to be reliable. However, the manufacturer/distributor of this product does not guarantee their
accuracy or completeness NOR SHALL ANY OF THIS INFORMATION CONSTITUTE A WARRANTY, WHETHER EXPRESSED OR IMPLIED, AS TO THE SAFETY OF THE GOODS, THE
MERCHANTABILITY OF THE GOODS, OR THE FITNESS OF THE GOODS FOR A PARTICULAR PURPOSE. Adjustment to conform to actual conditions of usage may be required. The
manufacturer/distributor assumes no responsibility for results obtained or for incidental or consequential damages, including lost profits, arising from the use of these data. No warranty against
infringement of any patent, copyright or trademark is made or implied.

13/02/2015 EN (English US) 9/9


Health 1 FLAMMABILITY

Flammability 1
MATERIAL SAFETY DATA SHEET 1

HEALTH 1 1 REACTIVITY
Reactivity 1
KOPR-KOTE THERMAL GRADE
PPI B
OTHER
HMIS SYMBOL NFPA SYMBOL
SECTION 1 - PRODUCT AND COMPANY IDENTIFICATION
Product Name: KOPR-KOTE THERMAL GRADE
Chemical Family: Mixture
Use: Lubricating grease anti-seize
Manufacturer/Supplier: Jet-Lube of Canada Ltd.
3820 – 97 Street
Edmonton, Alberta
Canada T6E 5S8
Phone: (780) 463-7441 Fax: (780) 463-7454
CCOHS: 1-800-668-4284
Emergency:
CANUTEC PH: (613) 996-6666 Cell: *666 TTY/TDD: 1-888-675-6863
SECTION 2 - COMPOSITION/INFORMATION ON INGREDIENTS
Hazardous Molybdenum
Components Talc Graphite Copper Disulphide
CAS NO. 14807-96-6 7782-42-5 7440-50-8 1317-33-5
WT % 3-7 7-13 5-10 1-5
2 mg/m3 (dust) 2.5 mg/m3
3
OSHA PEL 1 mg/m (dust) 15 mg/m3
2 mg/m3 (dust) 2 mg/m3
3
ACGIH TLV 1 mg/m (dust) 10 mg/m3
LD50 Not Available 10000 mg/kg Not Available >2000 mg/kg (oral,rat)
LC50 Not Available 64400 mg/m³ Not Available >2820 mg/m³ (rat)
OTHER: Not Applicable Not Applicable Not Applicable Not Applicable
SECTION 3 - HAZARDS IDENTIFICATION
Route of Entry: Eyes, Inhalation, Ingestion, Skin
Eyes: May cause irritation to eyes as a foreign object.
Inhalation: Viscous nature may block breathing passages if inhaled.
Ingestion: May cause diarrhea if ingested.
Skin: May cause irritation after prolonged skin exposure, especially for persons with hyper sensitivity.
SECTION 4 - FIRST AID MEASURES
Eyes: Flush with water until all residual material is gone. If irritation persists, seek medical help.
Ingestion: Do not induce vomiting. Wash out mouth. Contact a physician immediately.
Skin: Remove by wiping or with a waterless hand cleaner, followed by washing with soap and water.
Inhalation: Clear air passage. If breathing difficulty continues seek medical help.
SECTION 5 - FIRE FIGHTING MEASURES
Flammability: Nil at ambient temp
Extinguishing Media: Use dry chemicals, foam, halon, CO2
Flash Point (OC): >293C (560F)
Flammable Limits: Upper (Not Available) Lower (Not Available)
Explosive Properties: Sensitivity to Static Discharge (Not Available)
Sensitivity to Impact (Not Available)
LEL – 0.9% UEL - 7%
Auto-ignition Temp: >360C (680F)
Hazardous Combustion Products: Oxides of carbon, smoke and irritating
vapors as products of incomplete
combustion.
SECTION 6 - ACCIDENTAL RELEASE MEASURES
Spillage: Scoop up excess, then wipes down the affected area and pick up
residue with diatomaceous earth to avoid a walking hazard.
Environmental Precautions: Do not allow product to enter into drains.
SECTION 7 - HANDLING AND STORAGE
Handling Procedures: No special handling precautions are necessary. Do not pressurize, cut, heat or weld empty containers.
Storage Requirements: Store in a cool, well ventilated place.
SECTION 8 - EXPOSURE CONTROLS/PERSONAL PROTECTION
Exposure Limits: Talc Graphite Copper Molybdenum Disulphide
OSHA PEL 2mg/m³ 2.5mg/m³ 1mg/m³ 15mg/m³
ACGIH TLV 2mg/m³ 2.0mg/m³ 1mg/m³ 10mg/m³
Engineering Controls: If user’s operation generates vapors or mists, use ventilation to keep exposure to airborne contaminants below the exposure limit. Make up air
should always be supplied to balance air removed by exhaust ventilation. Ensure eyewash station and safety shower are close to work station.
Personal Protective Equipment (PPE's):
Respiratory Protection: None required.
Hand Protection: Protective gloves for hypersensitive persons.
Eye Protection: Protective glasses if applied to moving parts.
Body Protection: Protective Overalls.
SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES
Physical State: Paste Odor & Appearance:Light Petroleum & Dark Brown
Odor Threshold: Not Available Specific Gravity: 1.10 Typical
Vapor Pressure: <0.01 kPa Vapor Density: Not Available
Boiling Point: >370C (698F) Freezing Point: Not Available
pH: Neutral
3
Density: 1.10 g/cm
Coefficient of Water/Oil Distribution: Not Available
Evaporation Rate (Butyl Acetate = 1.0): <0.01
SECTION 10 - STABILITY AND REACTIVITY
Stability: Chemically stable under normal conditions. No photoreactive agents.
Conditions to Avoid: Powerful sources of ignition and extreme temperatures.
Materials to Avoid: Strong acids and oxidizing agents.
Hazardous Decomposition Products: May release COx, smoke and irritating vapors when heated to decomposition.
SECTION 11 - TOXICOLOGICAL INFORMATION
Effects of Short-Term (Acute) Exposure: No adverse affects know.
Effects of Long-Term (Chronic) Exposure: Long term dermal application may produce possible skin irritation. Elevated temperatures or mechanical action may form
vapors or fumes. Inhalation of oil mists or vapors may cause irritation of the upper respiratory tract.
Irritancy of Product: Products is not known to be an irritant.
Skin Sensitization: Product is not known to produce skin sensitization.
Respiratory Sensitization: Product is not known to produce respiratory sensitization.
Teratogenecity, Embryotoxicity & Reproductive Toxicity: Not Available
Mutagenicity: Product is not a known mutagen.
Carcinogen: Not classifiable as a human carcinogen IARC: Group 3 ACGIH: A4
Name of Synergistic Products/Effects: Not Available.
SECTION 12 - ECOLOGICAL INFORMATION
Possible Effects: May generate oil fractions that could act as a marine pollutant, but is highly unlikely.
Behavior: Product is non-reactive under ambient conditions. Bioaccumulation potential almost nil.
Environmental Fate: Highly unlikely to cause widespread contamination. May be toxic to marine and land organisms. Non-toxic to land and marine organisms.
SECTION 13 - DISPOSAL CONSIDERATIONS
Consult federal, provincial and local regulations for disposal of petroleum products.
Do not incinerate.
SECTION 14 - TRANSPORT INFORMATION
TDG (Canada): The mixture is not specifically listed in the Canadian Transportation of Dangerous Goods Regulations. The mixture is not regulated.
Land & Rail: Not Regulated
Marine: Regulated
Shipping Name: Environmentally Hazardous Substance, N.O.S (copper)
UN No.: UN3077
Packing Group: III
Classification: Class 9
Labeling Requirements: Class 9 and Marine Pollutant Labels
Placard Requirements: None
Labeling Requirements: Limited Quantities Label for containment less than LQI of 5L net Contents per containment.
Class 9 & Marine Pollutant label if >5L net contents per containment or large containment.
Placard Requirements: Limited Quantities – Non-Required
Large Containment – Class 9 & Marine Pollutant
Air Transport Requirements: Hazard Label – Miscellaneous
PG – III
Passenger and Cargo Aircraft Packing Instructions – 956
Max Net Qty/Package – 400 kg
Limited Quantity
Packing Instructions – Y956
Max Net Qty/Package – 30 kg G
Cargo Aircraft Only Packaging Instructions – 956
Max Net Qty/Package – 400kg
SECTION 15 -REGULATORY INFORMATION
WHMIS: Not Classified
DSL: All components listed
CPR Compliance: This product has been classified in accordance with the hazard criteria of the Controlled Product Regulations and the MSDS contains all of the
information required by those regulations.
SECTION 16 - OTHER INFORMATION
CPR - Controlled Product Regulations
DSL - Domestic Substance List
As of issue date, the information contained herein is accurate and reliable to the best of Jet-Lube of Canada Ltd.’s knowledge. Jet-Lube of Canada Ltd. does not warrant or guarantee its accuracy or reliability and shall not be liable for any loss or
damage arising out of the use thereof. It is the users’ responsibility to satisfy themselves that the information offered for their consideration is suitable for their particular use.

Prepared by: Jet-Lube of Canada Ltd. - Laboratory


Last Date of Revision: October 22, 2014
MATERIAL SAFETY DATA SHEET

1. Product and Company Identification


Product identifier LPS® 1 (Aerosol)
Version # 02
Issue date 10-01-2014
Revision date 10-26-2014
Supersedes date 10-01-2014
CAS # Mixture
Part Number C30116
Product use An industrial lubricant designed to displace moisture from mechanical and electrical equipment,
provide light-duty lubrication and short-term rust prevention.
Manufacturer information LPS Laboratories, a division of Illinois Tool Works, Inc.
4647 Hugh Howell Rd
Tucker, Georgia 30084
United States
www.lpslabs.com
1-800-241-8334/ 770-243-8800
Chemtrec 1-800-424-9300
Supplier Not available.

2. Hazards Identification
Emergency overview DANGER

Flammable aerosol. Contents under pressure. Pressurized container may explode when exposed
to heat or flame. Irritating to eyes and skin. May cause an allergic skin reaction. May cause
drowsiness and dizziness.
Potential health effects
Routes of exposure Inhalation. Ingestion. Skin contact. Eye contact.
Eyes Contact with eyes may cause irritation. Avoid contact with eyes.
Skin May cause sensitization by skin contact. May cause skin irritation. Avoid contact with the skin.
Inhalation Intentional misuse by concentrating and inhaling the product can be harmful or fatal. May cause
irritation of respiratory tract. Prolonged inhalation may be harmful.
Ingestion Exposure by ingestion of an aerosol is unlikely. Irritating. May cause nausea, stomach pain and
vomiting.
Signs and symptoms Symptoms of overexposure may be headache, dizziness, tiredness, nausea and vomiting.
Symptoms may include redness, edema, drying, defatting and cracking of the skin.
Potential environmental effects Harmful to aquatic organisms. May cause long-term adverse effects in the aquatic environment.

3. Composition / Information on Ingredients


Hazardous components CAS # Percent
CARBON DIOXIDE 124-38-9 1-5

Non-hazardous components CAS # Percent


Distillates Petroleum, Hydroteated Light 64742-47-8 70 - 80
Distillates Petroleum Hydrotreated Med 64742-46-7 10 - 20
Sorbitan trioleate 26266-58-0 1-3
Calcium Sulfonate 61789-86-4 0.1 - 1

4. First Aid Measures


First aid procedures
Inhalation Move to fresh air. Get medical attention, if needed.

Material name: LPS® 1 (Aerosol) MSDS CANADA

802 Version #: 02 Revision date: 10-26-2014 Issue date: 10-01-2014 1/8


Skin contact Remove and isolate contaminated clothing and shoes. Immediately flush skin with plenty of water.
Get medical attention if irritation develops and persists. Wash clothing separately before reuse.
Eye contact Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, if
present and easy to do. Continue rinsing. Get medical attention if irritation develops and persists.
Ingestion In the unlikely event of swallowing contact a physician or poison control center. Rinse mouth
thoroughly. Do not induce vomiting without advice from poison control center. If vomiting occurs,
keep head low so that stomach content doesn't get into the lungs.
General advice Take off contaminated clothing and shoes immediately. If you feel unwell, seek medical advice
(show the label where possible). Ensure that medical personnel are aware of the material(s)
involved, and take precautions to protect themselves. Show this safety data sheet to the doctor in
attendance.

5. Fire Fighting Measures


Flammable properties Flammable by WHMIS criteria. Heat may cause the containers to explode. Ruptured cylinders may
rocket. Vapors may travel considerable distance to a source of ignition and flash back.
Extinguishing media
Suitable extinguishing Powder. Alcohol resistant foam. Water spray. Dry chemicals. Carbon dioxide (CO2).
media
Unsuitable extinguishing Do not use water jet as an extinguisher, as this will spread the fire.
media
Protection of firefighters
Specific hazards arising Contents under pressure. Pressurized container may explode when exposed to heat or flame.
from the chemical
Protective equipment for Firefighters should wear full protective clothing including self contained breathing apparatus.
firefighters Structural firefighters protective clothing will only provide limited protection.
Fire fighting Firefighters must use standard protective equipment including flame retardant coat, helmet with
equipment/instructions face shield, gloves, rubber boots, and in enclosed spaces, SCBA. Cool containers exposed to heat
with water spray and remove container, if no risk is involved. Containers should be cooled with
water to prevent vapor pressure build up. For massive fire in cargo area, use unmanned hose
holder or monitor nozzles, if possible. If not, withdraw and let fire burn out.
Specific methods Cool containers exposed to flames with water until well after the fire is out.
Explosion data
Sensitivity to static None known.
discharge
Sensitivity to mechanical None known.
impact
Hazardous combustion May include oxides of carbon.
products

6. Accidental Release Measures


Personal precautions Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Keep out of
low areas. Pay attention to flashback. Many gases are heavier than air and will spread along
ground and collect in low or confined areas (sewers, basements, tanks). Do not touch damaged
containers or spilled material unless wearing appropriate protective clothing. Ventilate closed
spaces before entering them. For personal protection, see section 8 of the MSDS.
Environmental precautions Prevent further leakage or spillage if safe to do so. Do not contaminate water.
Methods for containment Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area). Stop leak if
you can do so without risk. Move the cylinder to a safe and open area if the leak is irreparable.
Many gases are heavier than air and will spread along ground and collect in low or confined areas
(sewers, basements, tanks). Use water spray to reduce vapors or divert vapor cloud drift. Keep out
of low areas. Prevent entry into waterways, sewer, basements or confined areas.
Methods for cleaning up Ventilate the area. Should not be released into the environment. Stop the flow of material, if this is
without risk. Isolate area until gas has dispersed. Clean up in accordance with all applicable
regulations. For waste disposal, see section 13 of the MSDS.
Other information Clean up in accordance with all applicable regulations.

Material name: LPS® 1 (Aerosol) MSDS CANADA

802 Version #: 02 Revision date: 10-26-2014 Issue date: 10-01-2014 2/8


7. Handling and Storage
Handling Pressurized container: Do not pierce or burn, even after use. Do not use if spray button is missing
or defective. Do not spray on a naked flame or any other incandescent material. Do not smoke
while using or until sprayed surface is thoroughly dry. Do not cut, weld, solder, drill, grind, or
expose containers to heat, flame, sparks, or other sources of ignition. Do not re-use empty
containers. Do not get this material in contact with eyes. Do not get this material in contact with
skin. Avoid breathing mist or vapor. Avoid prolonged exposure. Do not get this material on
clothing. When using do not eat or drink. Do not use in areas without adequate ventilation. Wash
thoroughly after handling. Avoid release to the environment.
Storage Contents under pressure. The pressure in sealed containers can increase under the influence of
heat. Do not expose to heat or store at temperatures above 120°F/49°C as can may burst. Do not
puncture, incinerate or crush. Do not handle or store near an open flame, heat or other sources of
ignition. Store in a closed container away from incompatible materials. Store in a well-ventilated
place. Keep out of the reach of children. Use care in handling/storage. Store away from
incompatible materials (see Section 10 of the MSDS).

8. Exposure Controls / Personal Protection


Occupational exposure limits
ACGIH
Components Type Value Form

Distillates Petroleum, TWA 5 mg/m3 Oil mist


Hydroteated Light (CAS
64742-47-8)
US. ACGIH Threshold Limit Values
Components Type Value
CARBON DIOXIDE (CAS STEL 30000 ppm
124-38-9)
TWA 5000 ppm
Canada. Alberta OELs (Occupational Health & Safety Code, Schedule 1, Table 2)
Components Type Value
CARBON DIOXIDE (CAS STEL 54000 mg/m3
124-38-9)
30000 ppm
TWA 9000 mg/m3
5000 ppm
Canada. British Columbia OELs. (Occupational Exposure Limits for Chemical Substances, Occupational Health and
Safety Regulation 296/97, as amended)
Components Type Value Form
CARBON DIOXIDE (CAS STEL 15000 ppm
124-38-9)
TWA 5000 ppm
Distillates Petroleum, TWA 200 mg/m3 Non-aerosol.
Hydroteated Light (CAS
64742-47-8)
Canada. Manitoba OELs (Reg. 217/2006, The Workplace Safety And Health Act)
Components Type Value
CARBON DIOXIDE (CAS STEL 30000 ppm
124-38-9)
TWA 5000 ppm
Canada. Ontario OELs. (Control of Exposure to Biological or Chemical Agents)
Components Type Value
CARBON DIOXIDE (CAS STEL 30000 ppm
124-38-9)
TWA 5000 ppm
Canada. Quebec OELs. (Ministry of Labor - Regulation Respecting the Quality of the Work Environment)
Components Type Value
CARBON DIOXIDE (CAS STEL 54000 mg/m3
124-38-9)

Material name: LPS® 1 (Aerosol) MSDS CANADA

802 Version #: 02 Revision date: 10-26-2014 Issue date: 10-01-2014 3/8


Canada. Quebec OELs. (Ministry of Labor - Regulation Respecting the Quality of the Work Environment)
Components Type Value
30000 ppm
TWA 9000 mg/m3
5000 ppm
U.S. - OSHA
Components Type Value Form

Distillates Petroleum, PEL 5 mg/m3 Oil mist


Hydroteated Light (CAS
64742-47-8)
US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000)
Components Type Value
CARBON DIOXIDE (CAS PEL 9000 mg/m3
124-38-9)
5000 ppm
Biological limit values No biological exposure limits noted for the ingredient(s).
Exposure guidelines
Canada - British Columbia OELs: Skin designation
Distillates Petroleum, Hydroteated Light (CAS Can be absorbed through the skin.
64742-47-8)
Engineering controls Good general ventilation (typically 10 air changes per hour) should be used. Ventilation rates
should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation,
or other engineering controls to maintain airborne levels below recommended exposure limits. If
exposure limits have not been established, maintain airborne levels to an acceptable level. Ensure
adequate ventilation, especially in confined areas.
Personal protective equipment
Eye/face protection Wear safety glasses with side shields (or goggles).
Skin protection Avoid contact with the skin. Wear appropriate chemical resistant clothing.
Respiratory protection When workers are facing concentrations above the exposure limit they must use appropriate
certified respirators.
Hand protection Chemical resistant gloves are recommended.

9. Physical & Chemical Properties


Appearance Liquid.
Physical state Gas.
Form Aerosol.
Color Amber.
Odor Characteristic.
Odor threshold Not available.
pH Not applicable
Vapor pressure < 0.05 mm Hg @ 20°C
Vapor density > 1 (air = 1)
Boiling point 415.4 °F (213 °C)
Melting point/Freezing point < -58 °F (< -50 °C)
Solubility (water) Not soluble
Specific gravity 0.79 - 0.81 @ 20°C
Relative density 0.79 - 0.81 @ 20°C
Flash point 174.2 °F (79.0 °C) Tag Closed Cup (dispensed liquid)
Flammability limits in air, 7%
upper, % by volume
Flammability limits in air, 0.6 %
lower, % by volume
Auto-ignition temperature > 442.4 °F (> 228 °C)
VOC 0.4 % per US State & Federal Consumer Product Regulations
Material name: LPS® 1 (Aerosol) MSDS CANADA

802 Version #: 02 Revision date: 10-26-2014 Issue date: 10-01-2014 4/8


Evaporation rate < 0.1 (BuAc = 1)
Viscosity < 3.8 cSt @ 25°C
Percent volatile 95 - 96 %
Partition coefficient <1
(n-octanol/water)
Other data
Decomposition Not established
temperature
Flammability (solid, gas) Flammable gas.
Heat of combustion Not established

10. Chemical Stability & Reactivity Information


Chemical stability Material is stable under normal conditions.
Conditions to avoid Avoid temperatures exceeding the flash point. Contact with incompatible materials.
Incompatible materials Oxidizing agents.
Hazardous decomposition Carbon oxides.
products
Possibility of hazardous Hazardous polymerization does not occur.
reactions

11. Toxicological Information


Toxicological data
Components Species Test Results
Calcium Sulfonate (CAS 61789-86-4)
Acute
Dermal
LD50 Rabbit > 2000 mg/kg, 24 Hours
Rat > 2000 mg/kg, 24 Hours
Inhalation
LC50 Rat > 1.9 mg/l, 4 Hours
Oral
LD50 Rat 10000 - 20000 mg/kg
Distillates Petroleum Hydrotreated Med (CAS 64742-46-7)
Acute
Dermal
LD50 Rabbit > 2000 mg/kg, 24 Hours
Inhalation
LC50 Rat 7640 mg/m3, 4 Hours
1.72 mg/l, 4 Hours
Distillates Petroleum, Hydroteated Light (CAS 64742-47-8)
Acute
Dermal
LD50 Rabbit > 2000 mg/kg
> 2000 mg/kg, 24 Hours
Inhalation
LC50 Cat > 6.4 mg/l, 6 Hours
Rat > 7.5 mg/l, 6 Hours
> 4.3 mg/l, 4 Hours
> 0.1 mg/l, 8 Hours
Oral
LD50 Rat > 5000 mg/kg

Material name: LPS® 1 (Aerosol) MSDS CANADA

802 Version #: 02 Revision date: 10-26-2014 Issue date: 10-01-2014 5/8


Components Species Test Results
METHYL SALICYLATE (CAS 119-36-8)
Acute
Dermal
LD50 Guinea pig 0.7 ml/kg
Oral
LD50 Dog 2.1 g/kg
Guinea pig 1060 mg/kg
1.06 g/kg
Rabbit 2.8 g/kg
Rat 887 mg/kg
0.887 g/kg

Acute effects Narcotic effects. May cause an allergic skin reaction.


Sensitization Not classified.
Local effects Irritating to eyes. Irritating to skin. Ingestion may cause gastrointestinal irritation, nausea, vomiting
and diarrhea.
Chronic effects Prolonged inhalation may be harmful.
Carcinogenicity This product is not considered to be a carcinogen by IARC, ACGIH, NTP, or OSHA.
Skin corrosion/irritation Causes skin irritation.
Serious eye damage/irritation Direct contact with eyes may cause temporary irritation.
Mutagenicity No data available to indicate product or any components present at greater than 0.1% are
mutagenic or genotoxic.
Reproductive effects This product is not expected to cause reproductive or developmental effects.
Teratogenicity Not available.
Symptoms and target organs Symptoms may include stinging, tearing, redness, swelling, and blurred vision. Skin irritation.
Exposure may cause temporary irritation, redness, or discomfort. Defatting of the skin. Rash.
Vapors have a narcotic effect and may cause headache, fatigue, dizziness and nausea. Decrease
in motor functions. Behavioral changes.
Synergistic materials Not available.

12. Ecological Information


Ecotoxicological data
Components Species Test Results
Distillates Petroleum, Hydroteated Light (CAS 64742-47-8)
Aquatic
Fish LC50 Rainbow trout,donaldson trout 2.9 mg/l, 96 hours
(Oncorhynchus mykiss)

Ecotoxicity Harmful to aquatic life with long lasting effects.


Environmental effects Harmful to aquatic life with long lasting effects.
Aquatic toxicity Harmful to aquatic organisms. May cause long-term adverse effects in the aquatic environment.
Persistence and degradability Not inherently biodegradable.
Partition coefficient
LPS® 1 (Aerosol) <1
METHYL SALICYLATE 2.55
Other adverse effects None known.

13. Disposal Considerations


Disposal instructions Collect and reclaim or dispose in sealed containers at licensed waste disposal site. Contents
under pressure. Do not puncture, incinerate or crush. Do not allow this material to drain into
sewers/water supplies. Dispose in accordance with all applicable regulations.

Material name: LPS® 1 (Aerosol) MSDS CANADA

802 Version #: 02 Revision date: 10-26-2014 Issue date: 10-01-2014 6/8


Waste from residues / unused Dispose of in accordance with local regulations. Empty containers or liners may retain some
products product residues. This material and its container must be disposed of in a safe manner (see:
Disposal instructions).
Contaminated packaging Empty containers should be taken to an approved waste handling site for recycling or disposal.
Since emptied containers may retain product residue, follow label warnings even after container is
emptied. Do not re-use empty containers.

14. Transport Information


TDG
UN number UN1950
UN proper shipping name AEROSOLS, flammable
Transport hazard class(es)
Class 2.1
Subsidiary risk -
Packing group Not applicable.
Environmental hazards No
Special precautions for user Read safety instructions, MSDS and emergency procedures before handling.
IATA
UN number UN1950
UN proper shipping name Aerosols, flammable
Transport hazard class(es)
Class 2.1
Subsidiary risk -
Packing group Not applicable.
Environmental hazards No
ERG Code 10L
Special precautions for user Read safety instructions, MSDS and emergency procedures before handling.
Other information
Passenger and cargo Allowed.
aircraft
Cargo aircraft only Allowed.
IMDG
UN number UN1950
UN proper shipping name AEROSOLS, Flammable
Transport hazard class(es)
Class 2.1
Subsidiary risk -
Label(s) 2.1
Packing group Not applicable.
Environmental hazards
Marine pollutant No
EmS F-D, S-U
Special precautions for user Read safety instructions, MSDS and emergency procedures before handling.
IATA; IMDG; TDG

15. Regulatory Information


Canadian regulations This product has been classified in accordance with the hazard criteria of the CPR and the MSDS
contains all the information required by the CPR.
WHMIS status Controlled

Material name: LPS® 1 (Aerosol) MSDS CANADA

802 Version #: 02 Revision date: 10-26-2014 Issue date: 10-01-2014 7/8


WHMIS classification A - Compressed Gas
B5 - Flammable Aerosols
D2B - Other Toxic Effects-TOXIC
WHMIS labeling

International Inventories
Country(s) or region Inventory name On inventory (yes/no)*
Australia Australian Inventory of Chemical Substances (AICS) Yes
Canada Domestic Substances List (DSL) Yes
Canada Non-Domestic Substances List (NDSL) No
China Inventory of Existing Chemical Substances in China (IECSC) No
Europe European Inventory of Existing Commercial Chemical Yes
Substances (EINECS)
Europe European List of Notified Chemical Substances (ELINCS) No
Japan Inventory of Existing and New Chemical Substances (ENCS) No
Korea Existing Chemicals List (ECL) Yes
New Zealand New Zealand Inventory No
Philippines Philippine Inventory of Chemicals and Chemical Substances Yes
(PICCS)
United States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory Yes
*A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s)
A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing
country(s).

16. Other Information


Disclaimer LPS Laboratories cannot anticipate all conditions under which this information and its product, or
the products of other manufacturers in combination with its product, may be used. It is the user’s
responsibility to ensure safe conditions for handling, storage and disposal of the product, and to
assume liability for loss, injury, damage or expense due to improper use. The information provided
in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date
of its publication. The information given is designed only as a guidance for safe handling, use,
processing, storage, transportation, disposal and release and is not to be considered a warranty or
quality specification. The information relates only to the specific material designated and may not
be valid for such material used in combination with any other materials or in any process, unless
specified in the text.
Prepared by Not available.
This data sheet contains Product and Company Identification: Alternate Trade Names
changes from the previous
version in section(s):

Material name: LPS® 1 (Aerosol) MSDS CANADA

802 Version #: 02 Revision date: 10-26-2014 Issue date: 10-01-2014 8/8


MARVEL OIL CO., INC.
625 WILLOWBROOK CTR PKWY
WILLOWBROOK, IL 60527

SAFETY DATA SHEET

1. Product and Company Identification

1.1 Product Identifier


Product Name: Marvel Air Tool Oil
Product Code (SKU): MM85R1 (50100), MM080R (50093) - See Section 15 for
discontinued SKU’s

1.2 Relevant Identified Uses Of The Substance


Product Use: Engine Oil Additive – Fuel additive (EPA Registered)

1.3 Details of the Supplier of the SDS


Company Name: Marvel Oil Company, Inc.
Street Address: 625 Willowbrook Centre Parkway
City, State, Zip Code: Willowbrook, Illinois 60527

1.4 Emergency Telephone Numbers


Phone Number: 1(630)455-3700
Fax Number: 1(630)455-3868
Transportation: 1(800)424-9300 (CHEMTREC)
Medical Assistance: Call your local Poison Control Center

2. Hazard Identification:
2.1 Classification of the Substance or Mixture
Hazard Classification: Flammable liquid 3
Skin irritation 2
Reproductive Toxicity 2
Aspiration toxicity 1
2.2 Label Elements

Pictogram:
Signal Word: Danger

Hazard Statement: Flammable liquid and vapor. Causes skin irritation.


Suspected of damaging fertility of the un-born child. May be
fatal if swallowed and enters airways.

Precautionary Statement: Keep away from heat, sparks, open flames or hot surfaces.
Do not smoke. Keep containers tightly closed. Ground all
containers and receiving equipment. Use explosion proof
electrical, ventilation, and lighting equipment. Use only non-
sparking tools. Take precautionary measures against static
discharge. Wear protective gloves, clothing, eye glasses
and face shield. Do not handle until all safety precautions
have been read and understood. Wash hands thoroughly
after handling. If exposed, get medical attention. If on skin
or hair, remove immediately all contaminated clothing and
launder before re-use. Wash skin with soap and water. If
skin irritation occurs, get medical attention. If swallowed,
immediately call a poison control center or doctor. Do NOT
induce vomiting. Store in a well ventilated place. Dispose
of contents and container in accordance with all local, state,
national and international regulations.

2.3 Other Hazards


Description of additional HNOC: None

3. Information on Ingredients:

3.1 Substance not applicable

3.2 Mixture
Component CAS Number Concentration (wt%)
Petroleum Distillates (Hydrotreated Heavy 64742-52-5 60-100%
Naphthenic)
Petroleum Distillates (Stoddard Solvent) 8052-41-3 10-30%
Tricresyl Phosphate 1330-78-5 0.1-1.0%
Ortho Dichlorobenzene 95-50-1 0.1-1.0%
Para Dichlorobenzene 106-46-7 <0.1%

4. First Aid Measures:

4.1 Description of First Aid Measures


Inhalation: Remove to fresh air and promote deep breathing. Get medical attention if effects
persist or you feel un-well.
Skin: In case of skin contact, wash thoroughly with soap and water. Remove contaminated
clothing and footwear. Launder clothing before re-use. Call a physician if irritation develops or
persists.
Eyes: In case of eye contact, immediately flush eyes with plenty of water. Remove contact
lenses if worn. If irritation persists, get medical attention
Ingestion: If swallowed, do not induce vomiting. Never give anything by mouth to an
unconscious person. Immediately call a poison control center or physician.

4.2 Most important symptoms and effects – acute and chronic


Inhalation: May cause respiratory tract irritation. Vapors may cause drowsiness or
dizziness.
Skin: Cause skin irritation. Symptoms may include redness, edema, drying,
defatting, and cracking of skin.
Eyes: May cause temporary eye irritation. Symptoms may include discomfort or
pain, excess blinking and tearing, with redness and swelling.
Ingestion: May be fatal if swallowed and enters airways. This product may be
aspirated into the lungs and cause chemical pneumonitis. May cause
stomach distress, nausea, and vomiting.
4.3 Indication of any immediate medical attention and special treatment
Symptoms may not appear immediately. Seek medical attention if effects develop or persist and
you feel un-well.

5. Fire Fighting Measures:

5.1 Extinguishing media


Carbon dioxide, dry chemical, and alcohol foam
5.2 Special hazards arising from the substance or mixture
CO2, CO, and hydrocarbons

5.3 Advice for Fire Fighters


Keep up wind of fire. Wear full firefighting turn out gear (full bunker gear) and respiratory
protection (SCBA). Cool closed containers exposed to fire with water. See Section 8 for
personal protection.

6. Accidental Release Measures:

6.1 Personal precautions, protective equipment, and emergency procedures


Use personal protection recommended in Section 8. Isolate the hazard area and deny entry to
unnecessary and unprotected personnel. Eliminate all source of ignition.

6.2 Methods and materials for containment and clean up


For containment: Contain and absorb spill with inert material. Place in suitable container for
disposal. Do not flush to sewer or allow to enter waterways. See section 8 for PPE.
For clean up: Take up material and place in a suitable container. Vapors may be heavier than
air and may travel along the ground to a distant source of ignition. Provide adequate ventilation.

7. Handling and Storage

7.1 Precautions for safe handling


Keep away from source of ignition. Do not smoke. Take precaution to eliminate static discharge.
Avoid contact with skin and eyes. Avoid breathing vapor or mist. Do not swallow. Do not eat or
drink while handling. Wash hands with soap and water after handling. Use only non-sparking
tools.
7.2 Conditions for safe storage including incompatibilities
Keep out of reach of children. Store in a well ventilated place. Do not store above 49°C (120°F).
7.3 Specific end uses
Shelf Life: Shelf life is considered to be 7 – 10 years when properly stored.

8. Exposure Control/Personal Protection:

8.1 Control parameters


Exposure Limits 8 hr TWA: (OSHA PEL) (ACGIH TWA)
Petroleum Distillates (Hydrotreated Heavy not applicable not applicable
Naphthenic)
Petroleum Distillates (Stoddard Solvent) 500 ppm 100 ppm
Tricresyl Phosphate not applicable not applicable
Ortho Dichlorobenzene 50 ppm 25 ppm
Para Dichlorobenzene 75 ppm 10 ppm
8.2 Exposure controls
Use adequate ventilation to keep exposure below recommended limits. Ensure that eye wash
station and safety shower are close to work station.
Hand Protection Equipment: Wear chemical resistant gloves to prevent skin contact.
Eye Protection Equipment: Wear safety glasses or splash goggles to prevent eye contact.
Skin and Body Protection: Wear suitable protective clothing.
Respiration/Ventilation Protection Requirements: Provide good ventilation.
Ingestion Protection Requirements: Do not eat, drink or smoke while handling. Wash hands
with soap and water after handling. Launder all clothing and foot wear before re-use.

9. Physical And Chemical Properties:

9.1 Information of basic chemical and physical properties


Physical Form: thin liquid
Color: clear red
Odor: typical oily
Odor Threshold: not available
pH: not applicable – oil based product
Melting Point/Freeze Point: -51϶C (-60϶F)
Initial Boiling Point: not available
Flash Point (Seta Closed Cup): 53϶C (128϶F)
Flammability Limits: Explosive Limits: Upper: not available Lower: not available
Evaporation Rate: not available
Flammability Solid/Gas: not applicable
Vapor Pressure: not available
Vapor Density: not available
Specific Gravity: 0.876
Solubility in Water: insoluble
Auto Ignition Temperature: not available
Partition coefficient (n/octonol/water): not available
Viscosity (Kinimatic @ 100϶C): 2.0 – 3.0 cSt

9. 2 Other information
% NVM by Weight: 75.0%
% VOC Content (California): 24.92%

10. Stability and Reactivity:

10.1 Reactivity
Does not react under normal conditions
10.2 Chemical stability
Stable
10.3 Possibility of hazardous reactions
Does not react under normal conditions
10.4 Conditions to avoid
Heat and incompatible materials
10.5 Incompatible materials
Strong oxidizers such as bleach and peroxides
10.6 Hazardous decomposition products
CO2, CO and hydrocarbons

11. Toxicological Information:


11.1 Information on Toxicological effects

Marvel Mystery Oil


LD50 – Oral Rat >2000 mg/Kg
LD50 – Dermal Rabbit >2000 mg/Kg
LC50 – Inhalation Rat >20 mg/L (4 hr)

Petroleum Distillates Hydrotreated Heavy Naphthenic (64742-52-5)


LD50 – Oral Rat >5000 mg/Kg
LD50 – Dermal Rabbit >5000 mg/Kg
LC50 – Inhalation Rat >5 mg/L (4 hr)

Tricresyl Phosphate (1330-78-5)


LD50 – Oral Rat 3000 mg/Kg

o-Dichlorobenzene (95-50-1)
LD50 – Oral Rat 500 mg/Kg
LD50 – Dermal Rabbit >10000 mg/Kg
LC50 – Inhalation Rat 8.15 mg/L (4 hr)

p-Dichlorobenzene (106-46-7)
LD50 – Oral Rat >2000 mg/Kg
LD50 – Dermal Rabbit >2000 mg/Kg

Skin corrosion/irritation Causes skin irritation


Serious eye damage/irritation Based on available data, classification data are not met
Respiratory or skin sensitization Based on available data, classification data are not met
Germ cell mutagenicity Based on available data, classification data are not met
Carcinogenicity Based on available data, classification data are not met

o-Dichlorobenzene (95-50-1) IARC Group 3 – Not Classified


p-dichlorobenzene (106-46-7) IARC Group 2B – Possible carcinogen to humans.
NTP 1-Evidence of Carcinogenicity 3, Reasonably
anticipated to be a human Carcinogen

Reproductive toxicity Suspected of damaging fertility of un-born child


Specific target organs – single exposure
Based on available data, classification data are not met
Specific target organs – repeated exposure
Based on available data, classification data are not met
Aspiration hazard May be fatal if swallowed and enters air ways.
Symptoms/injuries after inhalation May cause respiratory tract irritation. Vapors may cause
drowsiness and dizziness.
Symptoms/injuries after skin contact Cause skin irritation. Symptoms may include redness,
edema, drying, defatting, and cracking of skin.
Symptoms/injuries after eye contact May cause temporary eye irritation. Symptoms may include
discomfort or pain, excess blinking and tearing, with redness
and swelling.
Symptoms/injuries after ingestion May be fatal if swallowed and enters airways. This product
may be aspirated into the lungs and cause chemical
pneumonitis. May cause stomach distress, nausea, and
vomiting.

12. Ecological Information:

12.1 Toxicity
Not recommended for release into aquatic systems without treatment
12.2 Persistence and degradability
Not established
12.3 Bioaccumulative potential
Not established
12.4 Mobility in soil
Not established
12.5 Other adverse effects
None known

13. Disposal Considerations:


13.1 Waste treatment methods
RCRA Hazardous Waste: Regulated as a hazardous waste (D-001 Ignitable).
Waste Disposal Method: Dispose of in accordance with local, state and federal
regulations
Waste Disposal Vessel: Metal drums are recommended.

14. Transportation Information:

14.1 UN number
1268
14.2 UN Proper shipping name
Petroleum Distillate n.o.s.
14.3 Transport Hazard class
3
14.4 Packaging group
III
14.5 Marine Pollutant
No
14.6 Transportation in Bulk
Not applicable
14.7 Special precautions
Use limited quantities

15. Regulatory Information:

15.1 US Federal Regulations


TSCA Status: All ingredients are commercially available and listed by the manufacturer under
TSCA.

15.2 Foreign Regulations

Canadian Status: All materials contained in this product are listed on the Canadian Domestic
Substance List (DSL). Consult Turtle Wax, Inc. regarding status of ingredients.
European Union: All materials contained in this product are listed on EINECS.
AICS: All materials are registered for AICS (Australia)

15.3 State Regulations

State Regulatory Information:


The following chemicals are specifically listed by individual states; other product specific health
and safety data in other sections of the SDS may also be applicable for state requirements. For
details on your regulatory requirements, contact the appropriate agency in your state.

California Prop 65:


CAS Number Concentration State Code
p-Dichlorobenzene (106-46-7) <0.1% Cancer

15.4 HIMS & NFPA Classifications


HIMS Classification: Health 2
Flammability 2
Reactivity 0
NFPA Classification: Health 2
Flammability 2
Reactivity 0

15.5 Discontinued SKU’s All discontinued SKU’s used this same formula.

MM080, MM085, MM85R, MM086, MM088R, MM089

16. Other Information:


Reason For Issue Conversion to OSHA GHS SDS Format
Prepared By James Heidel
Preparer’s Title Technical Director, R&D
SDS Administrator Jean Mayszak - Technical Compliance Manager, R&D
Approval Date March 10, 2015
Supersedes Date December 27, 2012
Revision Number #11

This information is, to the best of Turtle Wax, Inc.’s knowledge and belief, accurate and reliable.
However, no representation, warranty, or guarantee is made to its accuracy, reliability or completeness.
It is the user’s responsibility to satisfy oneself as to the suitableness and completeness of such
information for their own particular use.
Safety Data Sheet
Prepared in accordance with Commission Regulation (EU) 20151830
Revision DateO9-02-2016
Revision Number 6

EVERC@AT
SECTION 1 Identification of the substance/mixture and of the company/undertakinq

1.1 Product identifier 100416


Metal Glaze
1.2 Relevant identified uses of the Automotive repair
substance or mixture and uses
advised against
I 3 Details of the supplier of the ITW Evercoat
safety data sheet
a division of Illinois Tool Works Inc.
6600 Cornell Road
Cincinnati, OH 45242
513-489-7600
1.4 Emergency telephone number CHEM TEL: +1-813-248-0591

SECTION 2 Hazards identification

2.1 Classification of the substance or mixture


Classified in Respiratory Sensitisation Category I
accordance to (EC) No.
127212008 Skin Sensitisation Category 1
Skin Corrosion/Irritation Category 2
Serious Eye Damage/Eye Irritation Category 2
Flammable Liquid Category 3
Hazardous to the aquatic environment Chronic Category 3
-

2.2 Label elements


Labelling according to Regulation (EC) No 1272/2008 [CLP]

Hazard pictograms

Signal Word Danger

Hazard Statements H226 Flammable liquid and vapour.


-

H315 Causes skin irritation.


-

H317 - May cause an allergic skin reaction.


H319 Causes serious eye irritation.
-

Page 1 of 10
Safety Data Sheet
Prepared in accordance with Commission Regulation (EU) 20151830
Revision DateO9-02-2016
Revision Number 6
H334 May cause allergy or asthma symptoms or breathing difficulties if
-

inhaled.
H41 2 Harmful to aquatic life with long lasting effects.
-

Precautionary P233 Keep container tightly closed.


-

Statements
P280 Wear protective gloves/protective clothing/eye protection/face
-

protection.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several
-

minutes. Remove contact lenses, if present and easy to do. Continue


rinsing.
P403÷P235 Store in a well-ventilated place. Keep cool.
-

P261 - Avoid breathing dust/fume/gas/mist/vapours/spray.


P273 Avoid release to the environment.
-

Supplemental Hazard EUH2O8 Contains Acid anhydride. May produce an allergic reaction.
-

information (EU)

2.3 Other hazards No data available

SECTION 3 Compositionhinformation on ingredients


3.1. Substances
Not applicable

3.2. Mixtures

Chemical Name % CAS # (EC) No 127212008 M Factor SCL


Styrene 23.42 100-42-5 Acute Tox. 4; H332 No data No data
Acute Tox. 4; H332 available available
Acute Tox. 4; H332
Eye Irrit. 2; H319
Flam. Liq. 3; H226
Skin Irrit. 2; H315
Zinc Phosphate 1.19 7779-90-0 Aquatic Acute 1; H400 No data No data
Aquatic Chronic 1; H41 0 available available
Acidanhydride 1.18 85-43-8 AquaticChronic3; H412 Nodata Nodata
Eye Dam. 1; H318 available available
Resp. Sens. 1; H334
Skin Sens. 1; H317
EUH2O8

For full text of H-statements; See Section 16

SECTION 4 First aid measures


4.1 Description of first aid measures
Inhalation Remove to fresh air. If breathing is difficult, have a trained individual administer
oxygen. If not breathing, give artificial respiration and have a trained individual

Page2oflo C
Safety Data Sheet
Prepared in accordance with Commission Regulation (EU) 20151830
Revision DateO9-02-2016
Revision Number 6

administer oxygen. Get medical attention immediately Get medical attention


immediately. Keep the victim warm and quiet. If the victim has stopped breathing
open airway, loosen collar and belt, and administer artificial respiration. If breathing
is difficult, oxygen may be beneficial if administered by trained personnel,
preferably on a doctor’s advice.
Eye Contact Flush eyes with plenty of water for at least 20 minutes retracting eyelids often. Tilt
the head to prevent chemical from transferring to the uncontaminated eye. Get
immediate medical attention. Immediately flush with plenty of water. After initial
flushing, remove any contact lenses and continue flushing for at least 15 minutes.
Have eyes examined and tested by medical personnel.
Skin Contact Wash with soap and water. Get medical attention if irritation develops or persists.
Remove contaminated clothing and continue flushing with water. Seek medical
advice if symptoms persist Wash clothing before reuse.
Ingestion Do not induce vomiting and seek medical attention immediately. Drink two glasses
of water or milk to dilute. Provide medical care provider with this MSDS. Do not
induce vomiting unless directed to do so by medical personnel.
Self protection of No data available
the first aider

4.2 Most important symptoms and effects, both acute and delayed
Symptom See Section 4.1
4.3 Indication of any immediate medical attention and special treatment needed
Note to Doctor No additional first aid information available

SECTION 5 Firefighting measures

5.1 Extinguishing media


Suitable extinguishing media Use alcohol resistant foam, carbon dioxide, or dry chemical
extinguishing agents. Water may be ineffective but water spray
can be used extinguish a fire if swept across the base of the
flames. Water can absorb heat and keep exposed material from
being damaged by fire. Carbon dioxide Dry chemical
Unsuitable extinguishing media No data available
5.2 Special hazards arising from the substance or mixture
Fire andlor Explosion Hazards Vapors may be ignited by sparks, flames or other sources of
ignition if material is above the flash point giving rise to a fire
(Class B). Vapors are heavier than air and may travel to a source
of ignition and flash back.
Hazardous Combustion Products Carbon dioxide, Carbon monoxide, Phthalic anhydride,
Hydrocarbons
5.3 Advice for firefighters
Fire Fighting Methods and Protection Do not enter fire area without proper protection including
self-contained breathing apparatus and full protective
equipment. Fight fire from a safe distance and a

Page 3 of 10
Safety Data Sheet
Prepared in accordance with Commission Regulation (EU) 20151830
Revision DateOQ-02-2016
Revision Number 6 C
protected location due to the potential of hazardous
vapors and decomposition products. Flammable
component(s) of this material may be lighter than water
and burn while floating on the surface.

SECTION 6 Accidental release measures

6.1 Personal precautions,


protective equipment and
emergency procedures
For Non-emergency Personnel Non-emergency personnel should be kept clear of the area.
For emergency responders No health affects expected from the clean-up of this material if
contact can be avoided. Follow personal protective equipment
recommendations found in Section VIII of this MSDS
6.2 Environmental precautions No data available
6.3 Methods and material for No special spill clean-up considerations. Collect and discard in
containment and cleaning up regular trash. Shut off ignition sources; including electrical
equipment and flames. Do not allow smoking in the area. Use an
inert absorbent such as sand or vermiculite. Place in properly
labeled closed container.
6.4 Reference to other sections Refer to section 13 for disposal information.

SECTION 7 Handling and storage

7.1 Precautions for safe handling Mildly irritating material. Avoid unnecessary exposure. Do not
get in eyes, on skin and clothing Wash hands before eating Use
C
with adequate ventilation Avoid contact with material, avoid
breathing dusts or fumes, use only in a well ventilated area.
7.2 Conditions for safe storage, Store in a cool dry ventilated location. Isolate from incompatible
including any incompatibilities materials and conditions. Keep container(s) closed. Store in a
cool dry place Keep away from heat, sparks, and flame Store in
a tightly closed container
7.3 Specific end use(s) Automotive repair

SECTION 8 Exposure controls/personal protection


Occupational Exposure limit values

Chemical Name ACGIH TLV-TWA ACGIH STEL IDLH


Styrene 20 ppm 40 ppm STEL; 170 No data available
mg/m3 STEL

8.2 Exposure controls

Appropriate engineering controls No exposure limits exist for the constituents of this product. Use
local exhaust ventilation or other engineering controls to minimize
exposures and maintain operator comfort.
Individual protection measures, such as personal protective equipment

Page 4 of 10 C
Safety Data Sheet
Prepared in accordance with Commission Regulation (EU) 20151830
Revision DateO9-02-201 6
Revision Number 6

Eye and face protection Wear chemically resistant safety glasses with side shields when
handling this product. Do not wear contact lenses. Wear goggles
if dusts can reach the exposure limit.
Skin Protection
Hand protection No information available
Other skin protection Not normally considered a skin hazard. Where use can result in
skin contact, practice good personal hygiene and wear a barrier
cream and/or impervious surgical style gloves. Wash hands and
other exposed areas with mild soap and water before eating,
drinking, and when leaving work.
Respiratory Protection Respiratory protection may be required to avoid overexposure
when handling this product. General or local exhaust ventilation
is the preferred means of protection. Use a respirator if general
room ventilation is not available or sufficient to eliminate
symptoms. Follow a respiratory protection program that meets
29 CFR 1910.134 and ANSI Z88.2 requirements whenever work
place conditions warrant the use of a respirator. Respiratory
protection may be required in addition to ventilation depending
upon conditions of use.
Thermal hazards No data available

Environmental exposure controls No data available

SECTION 9 Physical and chemical properties


9.1 Information on basic physical and chemical properties

Appearance Liquid
Colour Green
Odour Aromatic
Odour Threshold No data available
pH Neutral
Melting point I Freezing point -30.6
(°C)
Initial boiling point and boiling 145
range (°C)
Flash Point (°C) 31
Evaporation Rate No data available
Flammability (Solid, gas) No data available
Upperllower flammability or
explosive limits
Upper FlammablelExplosive 6.1
Limit, % in air
Lower Flammable!Explosive 1.1
Limit, % in air
Vapour Pressure 5.0 mmHg @ 68 °F / 20 °C (Styrene)
Vapour Density Heavier than air. Vapors that evolve from this product will tend to

Page 5 of 10
Safety Data Sheet
Prepared in accordance with Commission Regulation (EU) 20151830
Revision DateO9-02-201 6
Revision Number 6
settle and accumulate near the floor.
Relative Density 0.96
Solubility(ies) Minimal; 1-9%
Partition coefficient: n- 1.36
octanollwater
Autoignition Temperature (°C) 490
Decomposition Temperature No data available
Viscosity 20,800 - 25,600
Explosive properties No data available
Oxidizing properties No data available

9.2 Other information No data available

SECTION 10 Stability and reactivity

10.1 Reactivity No data available


10.2 Chemical stability Stable under normal conditions.
10.3 Possibility of hazardous No data available
reactions
10.4 Conditions to avoid Contamination
10.5 Incompatible materials Peroxides; Strong acids; Strong oxidizing agents
10.6 Hazardous decomposition Carbon dioxide Carbon monoxide Hydrocarbons
products

SECTION 11 Toxicological information


11.1 Information on toxicological effects

Acute Toxicity
Based on available data, the classification criteria are not met.

Skin corrosionlirritation
I pH I Neutral

Classification is based on pH and the components listed in Section 3.

Serious eye damagelirritation


pH I Neutral

Classification is based on pH and the components listed in Section 3.

Respiratory or skin sensitization


EUH2O8 Contains Acid anhydride. May produce an allergic reaction.
-

Classification has been based on toxicological information of the components in Section 3.

Germ cell mutagenicity


Based on available data, the classification criteria are not met.

Page 6 of 10
Safety Data Sheet
Prepared in accordance with Commission Regulation (EU) 20151830
Revision DateO9-OZ-201 6
Revision Number 6
Carcinogenicity
Based on available data, the classification criteria are not met.

Reproductive toxicity
Based on available data, the classification criteria are not met.

STOT-single exposure
Based on available data, the classification criteria are not met.

STOT-repeated exposure
Based on available data, the classification criteria are not met.

Aspiration hazard
Based on available data, the classification criteria are not met.

SECTION 12 Ecological information

12.1 Toxicity No data available

Ecotoxicity Data
Chemical Name CAS Number Aquatic EC5O Aquatic ERC5O Aquatic LC5O
Crustacea Algae Fish

.
No data available

12.2 Persistence and No data available


degradability
12.3 Bioaccumulative No data
potential
12.4 Mobility in soil No data available
12.5 Results of PBT and No data available
vPvB assessment
12.6 Other adverse No data available
effects
12.7 Additional No data available
information

SECTION 13 Disposal considerations


13.1 Waste treatment methods
Waste Description for Spent Spent or discarded material is a hazardous waste.
Product
Disposal Methods Dispose of by incineration following Federal, State, Local, or
Provincial regulations.
Waste Disposal Code(s) W080111
(European Waste Catalogue)

SECTION 14 Transport information

Page 7 of 10
Safety Data Sheet
Prepared in accordance with Commission Regulation (EU) 20151830
Revision DateO9-02-2016
Revision Number 6

Ground:
14.1 UN number: UN3269
14.2 UN proper shipping name: POLYESTER RESIN KIT
14.3 Transport hazard class(es): 3
14.4 Packing group: III
Exemptions: Limited Quantity

Air:
14.1 UN number: UN3269
14.2 UN proper shipping name: POLYESTER RESIN KIT
14.3 Transport hazard class(es): 3
14.4 Packing group: III

Water:
14.1 UN number: UN3269
14.2 UN proper shipping name: POLYESTER RESIN KIT
14.3 Transport hazard class(es): 3
14.4 Packing group: III
Exemptions: Limited Quantity

14.5 Environmental hazards: Yes


14.6 Special precautions for user: No data available
14.7 Transport in bulk according No data available
to Annex II of MARPOL and the
IBC Code:

SECTION 15 Regulatory information


15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture

Chemical Name EINECS SVHC

Styrene Y N
Zinc Phosphate Y N
Acid anhydride Y N
Acetone Y N
Diacetone alcohol Y N
1, 4 Benzenediol, 2,3,5-Trimethyl- Y N
1 ,4-Naphthoguinone Y N
p-Toluidene Y N
Styrene Oxide Y N

15.2 Chemical safety assessment No data available

SECTION 16 Other information

Page8oflO —
Safety Data Sheet
Prepared in accordance with Commission Regulation (EU) 201 5/830
Revision DateO9-02-2016
Revision Number 6

SDS Abbreviations: No data available


References: No data available
Hazard phrase(s) H225 Highly flammable liquid and vapour.
-

referenced in section 3
H226 Flammable liquid and vapour.
-

H301 - Toxic if swallowed.


H302 Harmful if swallowed.
-

H31 I - Toxic in contact with skin.


H31 2 Harmful in contact with skin.
-

H31 5 Causes skin irritation.


-

H317 May cause an allergic skin reaction.


-

H318 Causes serious eye damage.


-

H319 Causes serious eye irritation.


-

H331 - Toxic if inhaled.


H332 Harmful if inhaled.
-

H334 May cause allergy or asthma symptoms or breathing difficulties if


-

inhaled.
H336 - May cause drowsiness or dizziness.
H350 - May cause cancer.
H351 - Suspected of causing cancer.
H400 Very toxic to aquatic life.
-

H41 0 Very toxic to aquatic life with long lasting effects.


-

H41 2 - Harmful to aquatic life with long lasting effects.

Precautionary
Statements
Prevention P201 Obtain special instructions before use.
-

P202 Do not handle until all safety precautions have been read and
-

understood.
P210 Keep away from heat/sparks/open flames/hot surfaces. No
- —

smoking.
P233 Keep container tightly closed.
-

P240 Ground/bond container and receiving equipment.


-

P241 Use explosion-proof electrical/ventilating/lighting equipment.


-

P242 Use only non-sparking tools.


-

P243 Take precautionary measures against static discharge.


-

P260 Do not breathe dust/fume/gas/mist/vapours/spray.


-

P261 Avoid breathing dust/fume/gas/mist/vapours/spray.


-

P264 Wash thoroughly after handling.


-

P270 Do no eat, drink or smoke when using this product.


-

Page 9 of 10
Safety Data Sheet
Prepared in accordance with Commission Regulation (EU) 20151830
Revision DateOg-02-2016
Revision Number 6
P272 Contaminated work clothing should not be allowed out of the
-

workplace.
P273 Avoid release to the environment.
-

P280 Wear protective gloves/protective clothing/eye protection/face


-

protection.
P284 Wear respiratory protection.
-

Response P302+P352 IF ON SKIN: Wash with plenty of soap and water.


-

P303+P361 +P353 IF ON SKIN (or hair): Remove/Take off immediately all


-

contaminated clothing. Rinse skin with water/shower.


P304+P341 IF INHALED: If breathing is difficult, remove victim to fresh air
-

and keep at rest in a position comfortable for breathing.


P305+P351+P338 IF IN EYES: Rinse cautiously with water for several
-

minutes. Remove contact lenses, if present and easy to do. Continue


rinsing.
P307÷P31 1 IF exposed: Call a POISON CENTER or doctor/physician.
-

P308+P313 IF exposed or concerned: Get medical advice/attention.


-

P314- Get medical advice/attention if you feel unwell.


P321 Specific treatment (see on this label).
-

P332+P313 If skin irritation occurs: Get medical advice/attention.


-

P333+P313 If skin irritation or rash occurs: Get medical advice/attention.


-

P337+P313 If eye irritation persists: Get medical advice/attention.


-

P342+P31 I If experiencing respiratory symptoms: Call a POISON


-

CENTER or doctor/physician.
P363 Wash contaminated clothing before reuse.
-

P370+P378 In case of fire: Use for extinction.


-

Storage P233 Keep container tightly closed.


-

P403+P235 Store in a well-ventilated place. Keep cool.


-

P405 Store locked up.


-

Disposal P501 Dispose of contents/container in accordance with


-

local/regional/national/international regulation for hazardous wastes.

NOTICE: The information accumulated herein is believed to be correct as of the date issued from sources, which
are believed to be accurate and reliable. Since it is not possible to anticipate all circumstances of use, recipients
are advised to confirm, in advance of need, that the information is current, applicable and suitable to their
circumstances

PagelOoflO C
MATERIAL SAFETY DATA SHEET
Lloyds Laboratories Inc.

Moovit (Aerosol) Part # 11008, 11010, 11014


SECTION 1: PRODUCT AND COMPANY IDENTIFICATION

PRODUCT NAME: MOOVIT PRODUCT USE: Penetrating Lubricant.

MANUFACTURER: Lloyds Laboratories Inc. SUPPLIER: Lloyds Laboratories Inc.

ADDRESS: 613 Neal Drive, ADDRESS: 613 Neal Drive,


Peterborough, Peterborough,
Ontario, Ontario,
K9J 6X7 K9J 6X7

EMERGENCY #: 1 800 361-6766 EMERGENCY #: 1 800 361-6766

SECTION II: INFORMATION ON INGREDIENTS

Ingredients CAS# Wt% OSHA-TWA ACGIH-TWA LD50

Propane 74-98-6 7-13 1800 mg/m3 4508 mg/m3 Not available

Isobutane 75-28-5 7-13 Not available Not available Vapour LC 50 Acute: 0.0057
ppm 0.25 hours Rat.

SECTION III: HAZARDOUS IDENTIFICATION

Route of Entry: Eye, skin contact, ingestion.


Potential Health Effects:
Eye Contact: May cause irritation to eyes.
Skin Contact: May cause irritation upon repeated/prolonged contact.
Inhalation: May cause slight nose, throat and respiratory tract irritation.
Ingestion: May cause irritation to mouth, esophagus and stomach. May cause
gastric tract upset and/or damage.
Chronic Effects:
Carcinogenicity: No ingredients listed IARC or NTP or ACGIC. Non hazardous by
WHMIS/OSHA criteria.
Teratogenicity, The ingredients in this product were found not to be mutagenic when
Mutagenicity, tested by the Ames Assay, (OECD Guidelines for chemical testing,
Reproductive Effects: sec.471).
Skin: Repeated or prolonged exposures to dilutions can cause drying,
defatting and dermatitis.

Page: 1 of 4
MATERIAL SAFETY DATA SHEET
Lloyds Laboratories Inc.

Moovit (Aerosol) Part # 11008, 11010, 11014


SECTION IV: FIRST AID MEASURES

Eye Contact: Immediately flush with water for 15 minutes. Holding eyelids open during flushing. If
irritation persists, repeat flushing and obtain medical attention immediately.
Skin Contact: Flush with water. Remove contaminated clothing and launder before reuse.
Inhalation: Move victim to fresh air. If conscious, have victim take deep, slow breaths. Seek
medical attention if symptoms persist.
Ingestion: DO NOT INDUCE VOMITING. Rinse mouth with water, and then drink one glass of
water. Seek medical attention. Do not give anything to victim if unconscious or
convulsing.

SECTION V: FIRE FIGHTING MEASURES

Flammability: NFPA 30B Level 1 Aerosol.


Flash Point deg (C,TCC):

Means of Extinction: Use water spray to keep fire exposed containers cool. Dry chemicals, carbon
dioxide. Fight fire from protected location or maximum possible distance.
Special Fire Hazards: Fire fighters should wear self contained breathing apparatus as for surrounding
fire. Aerosol product - containers may rocket or explode.
Autoignition temperature: Not applicable.
Flame projection: 28.0 cm.
Sensitivity to static Not applicable.
discharge:
Unusual Fire and Explosion Aerosol product - containers may rocket or explode.
Hazards:
Hazardous decomposition Oxides of carbon, oxides of nitrogen.
products:

SECTION VI: ACCIDENTAL RELEASE MEASURES

Leak and Spill Before attempting clean up, refer to the hazard data provided above. Small spills
Procedures: may be absorbed with non reactive absorbent and placed in suitable, covered,
labeled container. For large quantities, dispose of in accordance with local,
provincial/ state or federal regulations.
For large spills prevent from entering sewers and waterways. For large spills
provide diking to prevent spreading.

SECTION VII: HANDLING AND STORAGE

Storage Requirements: KEEP OUT OF REACH OF CHILDREN.


Store in a dry, cool and well ventilated area. Protect from freezing. Do not
puncture or incinerate. Pressurized container: protect from sunlight and do not
expose to temperatures exceeding 120ºF or 50ºC. Do not pierce or burn, even
after use.

Page: 2 of 4
MATERIAL SAFETY DATA SHEET
Lloyds Laboratories Inc.

Moovit (Aerosol) Part # 11008, 11010, 11014


SECTION VIII: EXPOSURE CONTROL/PERSONAL PROTECTION

Gloves: Not normally required. Use Viton or Nitrile gloves to avoid prolonged or skin
contact repeated.
Eye Protection: Not normally required, if eye contact is possible chemical splash goggles are
recommended.
Respiratory Protection: Not normally required if good ventilation is maintained.
Other Protective As required by employer code. Eye bath, safety shower, protective clothing.
Equipment:
Engineering Controls: General ventilation normally required.

SECTION IX: PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Aerosol Odour and Appearance: Odourless, Odour Threshold Not
Opaque Purple applicable
Vapour Pressure 4394.5 Vapour Density (Air=1) Not Boiling Point (ºC) Not
(mm Hg): applicable applicable
% Volatile (Wt %): 7-13 % Solubility in water(20ºC) None Freezing Point (ºC) -50ºC

pH Not Specific Gravity .85 Evaporation Rate Not


applicable (nBuAc=1) applicable
Coeff. Water/Oil Not
Dist. applicable

SECTION X: STABILITY AND REACTIVITY

Conditions for Chemical Instability: Stable under normal conditions. Excessive heat or contamination
could cause decomposition.
Incompatible Materials: Reducing agents, strong acids, strong caustics, iron and other
metals.
Hazardous Decomposition Products: Oxides of carbon, Oxides of Nitrogen when heated.

SECTION XI: TOXICOLOGICAL INFORMATION

LD 50 values for individual components see section II.


Skin Sensitization (OECD Sec. 406) Non sensitizing.

SECTION XII: ECOLOGICAL INFORMATION

No data available on the adverse effects of this product on the environment.

SECTION XIII: DISPOSAL CONSIDERATIONS

Dispose of in accordance to all local, provincial/state and federal regulations.

Page: 3 of 4
MATERIAL SAFETY DATA SHEET
Lloyds Laboratories Inc.

Moovit (Aerosol) Part # 11008, 11010, 11014


SECTION XIV: TRANSPORTATION

T.D.G. Classification: Please refer to Bill of lading for up to date shipping information.
D.O.T. Classification: Please refer to Bill of lading for up to date shipping information.

SECTION XV: REGULATORY INFORMATION

Occupational Health and Safety


Regulations:
WHMIS Class: Class A Compressed Gas/Class B-5 Flammable aerosol.
OSHA & WHMIS: MSDS prepared pursuant to the Hazard Communication
Standard (CFR29.1920.1200) and Canadian WHMIS regulations.
Environmental Regulatory Lists:
SARA – Section 313 (Toxic Chemical None of these ingredients are listed.
Release Reporting) 40 CFR 372:
CERCLA – Section 102 (Reportable Butane, Propane.
Quantity) 40 CFR 302:
RCRA 40 CFR 261 (Subpart D): None of the ingredients are listed.
CLEAN WATER ACT – Section 311 None of these ingredients are listed.
(Reportable Qty) 40 CFR 116:
CLEAN AIR ACT – Section 312 (List of
Hazardous Pollutants) 40 CFR 63 Flammable substances Propane, Isobutane.
(Subpart C):
National Pollutant Release Inventory: None of these ingredients are listed.
Toxic Substances Control Act (TSCA): All ingredients are registered on the Chemical Substances
Inventory.
Canadian Domestic Substance List All ingredients are registered on the DSL.
(DSL):

SECTION XVI: OTHER INFORMATION

Date: June 7, 2013 Prepared By: Technical Services Telephone: 1 800 361-6766
Group

Disclaimer:
Information for this material safety data sheet was obtained from sources considered technically
accurate and reliable. While every effort has been made to ensure full disclosure of product hazards,
in some cases data is not available and is so stated. Since conditions of actual product use are
beyond the control of supplier, it is assumed that users of this material; have been fully trained
according to the mandatory requirements of WHMIS. No warranty, expressed or implied, is made
and supplier will not be liable for any losses, injuries for consequential damages, which may result
from the use or reliance on any information contained in this form. If user requires independent
information on ingredients in this or other material, we recommend contact with the Canadian
Centre for Occupational Health and Safety (CCOHS) in Hamilton, Ontario (905-572-4400) or CSST in
Montreal, Quebec (514-873-3990).

Page: 4 of 4
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DC & FC TEST DEALER

C H R Y S L E R
HAZARD COMMUNICATION SHEET
5182604 DRAFT PART/COMMTY CD: 0VU01463
PREPARATION DATE: 03-09-10 STNDRD: N/AV SUPPLIER: 86056 MFGR: 03500
OSHA HAZ: YES HAZWOPER HAZ: YES CONS PROD/HAZ SUB: YES
-------------------------------------------------------------------------------
*** SECTION 01 - PRODUCT INFORMATION ***
-------------------------------------------------------------------------------
MFG BY: PART SALES & SERVICE FCA US LLC
26311 LAWRENCE AVE CENTERLINE MI 48015
EMERGENCY PHONE: 248-512-8002 AFTER HOURS: 248-576-8888
DIST BY: PART SALES & SERVICE FCA US LLC
26311 LAWRENCE AVE CENTERLINE MI 48015
EMERGENCY PHONE: 248-512-8002 AFTER HOURS: 248-576-8888
FCA US LLC INDUSTRIAL HYGIENE: 248-512-8260 AFTER HOURS: 248-576-8888
BRAND NAME: MOPAR MULTI-PURPOSE LUBE
MFG ID : N/AV
DESCRIPTION: LUBRICANT-POWERTRAIN,BODY
-------------------------------------------------------------------------------
*** SECTION 02 - INGREDIENTS ***
-------------------------------------------------------------------------------
HAZARDOUS INGREDIENTS: PERCENT
COMM NAME / CAS NO & CHEM NAME: BY WGT OSHA ACGIH CHRYS UNITS NOTATIONS
***EXISTING INGREDIENTS***
STODDARD SOLVENT 60-100 W 100 100 100 PPM
008052-41-3 STODDARD SOLVENT (8C
VM & P NAPHTHA 10-30 W 300 300 100 PPM
008032-32-4 MINERAL SPIRITS L 400 N/AP 400 A3
PETROLEUM PRODUCTS, LIQUEFIED GAS 10-30 W 1000 1000 1000 PPM
068476-86-8 PETROLEUM GASES, LIQ
GENERIC DESC: MULTIPURPOSE LUBRICANT CONTAINING MAINLY MINERAL SPIRITS.
-------------------------------------------------------------------------------
*** SECTION 03 - PHYSICAL DATA ***
-------------------------------------------------------------------------------
BOILING POINT : N/AV F SOLUB IN WATER: NEGLIGIBLE ( < 0.1% )
VAPOR PRESSURE: N/AV EVAP. RATE: N/AV REF: N/AV
VAPOR DENSITY : > 1.000 AT N/AV SPECIFIC GRAVITY: > 0.800 AT 59 F
PH AT FULL STRENGTH: N/AV PH AT REC. DILUT: N/AV
%VOLATILE BY VOL : N/AV VOLATILE ORGANIC COMP: N/AV N/AV
ODOR THRESHOLD: N/AV PPM FOR % POPULATION
FREEZING POINT: N/AV COEFF. OF WATER/OIL DIST: N/AV
APPEARANCE & ODOR: STATE: LIQUID..... ODOR: HYDROCARBON..... COLOR:
YELLOW..... APPEARANCE: CLEAR......
-------------------------------------------------------------------------------
*** SECTION 04 - FIRE AND EXPLOSION DATA ***
-------------------------------------------------------------------------------
FLASH POINT: 104 F PMCC IGN TEMP: N/AV LEL: N/AV UEL: N/AV
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SPECIAL FIRE & EXPLOSION HAZARDS:


CONTENTS UNDER PRESSURE. MAY EXPLODE IF EXPOSED TO HEAT OR FLAME. MATERIAL
IS FLAMMABLE. DO NOT LET IT RUN-OFF TO WATERCOURSE. REACTS ON CONTACT WITH
OXIDIZERS. MIST OR AEROSOL ACCUMULATIONS MAY FLASH IF IGNITED. VAPOR/GAS IS
HEAVIER THAN AIR AND MAY TRAVEL ALONG THE GROUND OR BE MOVED BY VENTILATION
AND CAUSE FLASH FIRES OR BE IGNITED EXPLOSIVELY BY PILOT LIGHTS, OTHER
FLAMES, SPARKS, HEATERS, SMOKING, ELECTRIC MOTORS, OR OTHER SOURCES OF
IGNITION AT LOCATIONS DISTANT FROM THE MATERIAL HANDLING POINT.
EXTINGUISHING MEDIA:
CARBON DIOXIDE, DRY CHEMICAL, FOAM OR WATER FOG OR ALCOHOL FOAM.
SPECIAL FIREFIGHTING PROCEDURES:
USE PROTECTIVE CLOTHING. USE SELF-CONTAINED BREATHING APPARATUS. AVOID
BREATHING VAPOR OR FUMES. USE WATER TO COOL FIRE EXPOSED CONTAINERS. WATER
SPRAY MAY BE INEFFECTIVE. IF WATER IS USED, FOG NOZZLES ARE PREFERABLE.
SENSITIVE TO MECHANICAL IMPACT?: YES SENSITIVE TO STATIC DISCHARGE?: YES
HAZARDOUS COMBUSTION PRODUCTS:
ORGANIC COMPOUNDS, CARBON MONOXIDE AND CARBON DIOXIDE.
FLAME PROJECTION: > 15 IN
-------------------------------------------------------------------------------
*** SECTION 05 - HEALTH HAZARD DATA ***
-------------------------------------------------------------------------------
EFFECTS OF OVEREXPOSURE - ACUTE & CHRONIC:
<<---INHALATION--->> VAPOR AND/OR MIST MAY PRODUCE THE FOLLOWING:
IRRITATION OF UPPER RESPIRATORY TRACT AND MAY BE IRRITATING TO EYES, NOSE,
AND THROAT. HIGH CONCENTRATION MAY PRODUCE THE FOLLOWING: ACUTE NERVOUS
SYSTEM DEPRESSION CHARACTERIZED BY HEADACHE, DIZZINESS, STAGGERING,
CONFUSION, UNCONSCIOUSNESS OR COMA. <<---SKIN CONTACT--->> LIQUID AND/OR
MIST MAY PRODUCE THE FOLLOWING: MINOR IRRITATION TO SLIGHT BURNING OF SKIN.
<<---EYE CONTACT--->> LIQUID AND/OR MIST MAY PRODUCE THE FOLLOWING:
IRRITATION AND TEARING. <<---INGESTION--->> MAY BE HARMFUL IF SWALLOWED.
CAUSES A BURNING SENSATION IN THE MOUTH AND STOMACH AND MUCOUS MEMBRANE
IRRITATION. MAY CAUSE UPSET STOMACH, NAUSEA, VOMITING AND DIARRHEA.
ASPIRATION (GOING DOWN THE WRONG PIPE INTO THE WINDPIPE) MAY CAUSE THE
FOLLOWING: CHEMICAL PNEUMONITIS (AN INFLAMMATION OF THE LUNGS SIMILAR TO
PNEUMONIA, WHICH IS CAUSED BY GETTING THE LIQUID FORM OF A CHEMICAL INTO THE
LUNGS). <<---SPECIAL TOXICITY--->> HIGH CONCENTRATION MAY PRODUCE THE
FOLLOWING: CARDIAC ABNORMALITIES, DAMAGE TO THE NERVOUS SYSTEM AND/OR BRAIN
DAMAGE.
EMERGENCY FIRST AID PROCEDURES:
<<---INHALATION--->> REMOVE TO FRESH AIR AT ONCE. IF PULMONARY SYMPTOMS
DEVELOP, CONSULT A PHYSICIAN. IF BREATHING IS DIFFICULT, GIVE OXYGEN.
ARTIFICIAL RESPIRATION IF BREATHING HAS STOPPED. CARDIAC RESUSCITATION IF
INDICATED. <<---SKIN CONTACT--->> REMOVE CONTAMINATED CLOTHING. WIPE OFF
WITH A CLOTH. IMMEDIATELY FLUSH CONTAMINATED AREA WITH LARGE AMOUNTS OF
WATER. WASH WITH SOAP AND WATER. IF CONDITION PERSISTS, CONSULT A PHYSICIAN.
<<---EYE CONTACT--->> REMOVE CONTACT LENSES TO ASSURE COMPLETE FLUSHING.
RINSE EYES IMMEDIATELY WITH LARGE AMOUNTS OF WATER, OCCASIONALLY LIFTING
Page 2 of 4
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BOTH UPPER AND LOWER LIDS. CONTINUE FOR 15 MINUTES. IF CONDITION PERSISTS,
CONSULT A PHYSICIAN. <<---INGESTION--->> DO NOT INDUCE VOMITING. IF
CONSCIOUS, GIVE LARGE QUANTITIES OF WATER OR MILK. CONTACT A PHYSICIAN.
NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. DO NOT MAKE
UNCONSCIOUS PATIENT VOMIT. IF VOMITING OCCURS, KEEP HEAD BELOW HIPS TO
PREVENT LIQUID FROM SEEPING INTO THE WINDPIPE AND LUNGS.
-------------------------------------------------------------------------------
*** SECTION 06 - REACTIVITY DATA ***
-------------------------------------------------------------------------------
STABILITY: STABLE
CONDITIONS TO AVOID:
HIGH TEMPERATURE, SPARKS OR OPEN FLAME.
MATERIALS TO AVOID:
STRONG OXIDIZING AGENTS.
HAZARDOUS POLYMERIZATION: WILL NOT OCCUR
POLYMERIZATION CONDITIONS TO AVOID:
POLYMERIZATION WILL NOT OCCUR.
HAZARDOUS DECOMPOSITION PRODUCTS:
ORGANIC COMPOUNDS, CARBON MONOXIDE AND CARBON DIOXIDE.
-------------------------------------------------------------------------------
*** SECTION 07 - SPILL OR LEAK PROCEDURES ***
-------------------------------------------------------------------------------
STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED:
WIPE UP OR SCRAPE UP SMALL SPILL OR RESIDUE. ABSORB ON AN INERT MATERIAL.
DISCARD INTO SEALED CONTAINERS FOR DISPOSAL. ELIMINATE ALL IGNITION SOURCES
(FLAMES, HOT SURFACES AND ELECTRICAL, STATIC OR FRICTIONAL SPARKS). WEAR
PROTECTIVE CLOTHING. WEAR RESPIRATORY PROTECTION. AVOID BREATHING VAPORS.
VENTILATE AREA. DO NOT FLUSH INTO SEWER SYSTEM. LARGE SPILL-CONTAIN WITH
DIKE. PUMP INTO STORAGE CONTAINER.
WASTE DISPOSAL METHODS:
DISPOSE OF IN A MANNER CONSISTENT WITH STATE, PROVINCIAL, LOCAL, AND
FEDERAL REGULATIONS.
-------------------------------------------------------------------------------
*** SECTION 08 - SPECIAL PROTECTION ***
-------------------------------------------------------------------------------
RESPIRATORY PROTECTION:
NO SPECIAL PROTECTION NEEDED UNDER NORMAL CONDITIONS. TO MAINTAIN THE TLV,
THE FOLLOWING MAY BE NEEDED: ORGANIC VAPOR RESPIRATOR.
VENTILATION TYPE:
TO MAINTAIN THE TLV, THE FOLLOWING MAY BE NEEDED: GOOD GENERAL VENTILATION
AND/OR LOCAL EXHAUST VENTILATION. VENTILATION EQUIPMENT SHOULD BE EXPLOSION
PROOF. VAPORS ARE HEAVIER THAN AIR. VENTILATION SHOULD DRAW FROM FLOOR LEVEL
TO BE EFFECTIVE.
PROTECTIVE GLOVES:
RECOMMENDED. IMPERMEABLE GLOVES.
EYE PROTECTION:
RECOMMENDED. SAFETY GLASSES WITH SIDE SHIELDS.
Page 3 of 4
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OTHER PROTECTIVE EQUIPMENT:


TO AVOID PROLONGED SKIN CONTACT, USE THE FOLLOWING: APRON (SAME MATERIAL AS
GLOVES) AND BOOTS (SAME MATERIAL AS GLOVES)-WEAR LONG SLEEVES. A SAFETY
SHOWER MAY BE NEEDED FOR EMERGENCY SITUATIONS. AN EYE WASH MAY BE NEEDED FOR
EMERGENCY SITUATIONS.
-------------------------------------------------------------------------------
*** SECTION 09 - SPECIAL PRECAUTIONS ***
-------------------------------------------------------------------------------
PRECAUTIONS TO BE TAKEN IN HANDLING & STORAGE:
STORE IN A COOL, DRY PLACE. STORE IN A WELL VENTILATED AREA. USE WITH
ADEQUATE VENTILATION. KEEP FROM HEAT, SPARK OR OPEN FLAMES. DO NOT PUNCTURE,
DROP OR SLIDE CONTAINERS. REACTS WITH OXIDIZERS. KEEP VALVE PROTECTION CAP
IN PLACE EXCEPT WHEN USING CYLINDER. OPEN CYLINDER VALVE SLOWLY. KEEP
CONTAINER UPRIGHT AND SECURED AT ALL TIMES. CONTAINERS OF THIS MATERIAL MAY
BE HAZARDOUS WHEN EMPTIED, SINCE EMPTIED CONTAINERS RETAIN PRODUCT RESIDUES
(VAPOR, LIQUID, AND/OR SOLID). DO NOT SMOKE OR EAT WHEN HANDLING THIS
SUBSTANCE; WASH THOROUGHLY AFTER USING. REMOVE CONTAMINATED CLOTHING AND
LAUNDER BEFORE REUSE. MAINTAIN GOOD HOUSEKEEPING AND HYGIENIC PRACTICES.
TAKE "NO SMOKING" PRECAUTIONS.
OTHER PRECAUTIONARY MEASURES:
AVOID BREATHING MIST. AVOID BREATHING VAPOR. AVOID EYE CONTACT. AVOID
PROLONGED OR REPEATED SKIN CONTACT. AVOID INGESTION. ASPIRATION OF MATERIAL
INTO THE LUNGS DUE TO VOMITING CAN CAUSE CHEMICAL PNEUMONITIS, WHICH CAN BE
FATAL. MAINTAIN GOOD HOUSEKEEPING AND HYGIENIC PRACTICES.
-------------------------------------------------------------------------------
*** SECTION 10 - WASTE LABELING INFORMATION ***
-------------------------------------------------------------------------------
DOT LABELING INFORMATION (49 CFR 100-199)
ID#: UN1950 ERG#: 126 HAZARD CLASS - PRMY: 2.1 PACKING GROUP: N/AP
PROPER SHIPPING NAME: WASTE AEROSOLS,FLAMMABLE
LABEL(S) REQUIRED: FLAMMABLE GAS
RCRA INFORMATION (40 CFR 122-124, 260-265)
WASTE CODE(S)/HZD: D001/I ¦ MICH:
THE ABOVE INFORMATION IS BASED ON DATA PROVIDED BY SUPPLIERS. TESTING IS NOT
NEEDED

Page 4 of 4
Material Safety Data Sheet

Section 1: Material Identification and Use:

MATERIAL NAME/IDENTIFIER: ONE STEP HAND SANITIZER (ALCOHOL)


MANUFACTURER’S NAME Belvedere International Inc. CHEMICAL NAME: Compounded Product HAZARDS
STREET ADDRESS: 5675 Keaton Crescent CHEMICAL FAMILY: Not Applicable HEALTH 2
CITY: Mississauga CHEMICAL FORMULA: Not Applicable FLAMMABILITY 3
PROVINCE: Ontario MOLECULAR WEIGHT: Not Applicable REACTIVITY 0
POSTAL CODE: L5R 3G3 TRADE NAME: One Step PERSONAL PROTECTION N
EMERGENCY PHONE NO. (905) 568-0700 MATERIAL USE: Sanitizer

Section 2: Hazardous Ingredients:


HAZARDOUS INGREDIENTS % UN, NA, CAS NO. LD-50(SPECIES & ROUTE) LC-50 (SPECIES & ROUTE)
Ethyl Alcohol 62 % CAS #64-17-5 Not Available Not Available
UN # 1170

Section 3: Physical Data:


PHYSICAL STATE: Viscous Liquid BOILING POINT: 78.3 O C
COLOUR: Colourless, Clear FREEZING POINT: - 114.1 O C
ODOUR: Match Standard % VOLATILES: 60 % - 65 %
SPECIFIC GRAVITY: 0.8850 – 0.8950 VAPOUR PRESSURE: Not Available
pH: 7.0-8.0 VAPOUR DENSITY (AIR=1) Not Available
EVAPORATION RATE: 1.7 SOLUBILITY IN WATER (20ºc) Complete

Section 4: Fire and Explosion Data:


FLAMMABILITY: Flammable
CONDITIONS OF FLAMMABILITY Contact with spark or open flame
METHODS OF EXTINCTION: Water/Carbon Dioxide Foam
SPECIAL PROCEDURES: Keep product away from any source of sparks or
open flame
FLASHPOINT (ºC) AND METHOD 21 O C (Tag closed cup, ASTM D-56)
U.E.L. (% BY VOLUME) Not Available SENSITIVITY TO IMPACT: None
L.E.L. (% BY VOLUME) Not Available SENSITIVITY TO STATIC Not Available
DISCHARGE:
AUTO IGNITION TEMP. (ºC) Not Available RATE OF BURNING: Not Available
TDG FLAMMABILITY CLASSIFICATION Not Available EXPLOSIVE POWER: Not Available

Section 5: Reactivity Data:


CHEMICAL STABILITY: Stable
COMPATIBLE WITH OTHER SUBSTANCES: Yes
REACTIVITY UNDER WHAT CONDITIONS: Burning
HAZARDOUS DECOMPOSITION PRODUCTS: Burning can produce carbon monoxide and/or carbon dioxide
NAME UNSTABLE CONDITIONS: Mixture with oxidizing materials
NAME INCOMPATIBILITIES: Strong oxidizing materials

1
Material Safety Data Sheet

MATERIAL NAME/IDENTIFIER: ONE STEP HAND SANITIZER (ALCOHOL)

Section 6: Toxicological Properties:


ROUTE OF ENTRY: SKIN CONTACT SKIN ABSORPTION EYE CONTACT INHALATION ACUTE INHALATION CHRONIC INGESTION
x x x x
EFFECTS OF ACUTE EXPOSURE TO THE MATERIAL:
None under normal conditions.
EFFECTS OF CHRONIC EXPOSURE TO THE MATERIAL:
None under normal conditions.
LD-50 OF MATERIAL (ROUTE & SPECIES) LC-50 OF MATERIAL (ROUTE & SPECIES)
Not Available Not Available
EXPOSURE LIMIT FOR THE MATERIAL IRRITANCY OF THE MATERIAL
Not Available Concentrated product may cause eye irritation
SENSITIZING CAPACITY OF THE MATERIAL CARCINOGENICITY OF THE MATERIAL
None Known None Known
REPRODUCTIVE EFFECTS OF THE MATERIAL SYNERGISTIC MATERIALS
None Known None Known

Section 7: Preventive Measures:


PERSONAL PROTECTIVE EQUIPMENT: None required under normal conditions
GLOVES (SPECIFY): None required under normal conditions
RESPIRATOR (SPECIFY): None required under normal conditions
FOOTWEAR (SPECIFY): None required under normal conditions
CLOTHING (SPECIFY): None required under normal conditions
ENGINEERING CONTROLS (SPECIFY): Fire-proof and explosion-proof equipment must be used during manufacturing
LEAK & SPILLAGE PROCEDURE: Pick up large spills and transfer to suitable sealed containers

WASTE DISPOSAL: Contact local authorities for disposal method


HANDLING PROCEDURES & EQUIPMENT: Keep the product away from sources of heat, spark or open flame
STORAGE REQUIREMENTS Store between 15OC and 30OC
SPECIAL SHIPPING INFORMATION (TDG): Class 3 Flammable liquid ; Make certain that all shipping containers are properly
labeled
OTHER INFORMATION: Do not mix with other chemicals

Section 8: First Aid Measures:


INHALATION: Give plenty of fresh air. Call physician if dizziness or any discomfort is observed.
INGESTION: Give plenty of milk or water. Call Physician
EYE CONTACT: Flush for 10 minutes with running water. Call physician, if any irritation is present or develops.
SKIN CONTACT: None required under normal conditions

Section 9: Information Sources Used:

SOURCES: Raw material suppliers’ data sheets.

Section 10: WHMIS Classification:


WHMIS CLASS: Class B Division 2: Flammable liquid

Section 11: MSDS Preparation Information:


PREPARED BY: Claude Raad PHONE NUMBER: (905) 568-0700 DATE: December 11, 2014

2
00000665 MATERIAL SAFETY DATA SHEET Page 1
Pro Form Products Ltd.
604 McGeachie Drive
Milton; Ontario; L9T 3Y5
Canada

PRODUCT: PF7770-3 TRUCK LINE PLIOGRIP URETHANE ADHESIVE PART A


Section 01: Chemical product and company identification
Product name................................................ PF7770-3 TRUCK LINE PLIOGRIP URETHANE ADHESIVE PART A
Manufactured for........................................... Pro Form Products Ltd.
604 McGeachie Drive
Milton, Ontario L9T3Y5
Tel (905) 878-4990 Fax (905) 878-1189
24 hour emergency number:......................... IN CANADA CALL CANUTEC (613) 996-6666-IN THE UNITED STATES CALL
CHEMTREC (800) 424-9300.
Material use................................................... Adhesive applications.
Chemical family............................................. Aromatic isocyanate prepolymer.
Preparation date............................................ April 3, 2014.
Hazard rate
NFPA rating................................................... Health: 2 Fire: 1 Reactivity: 1.
HMIS............................................................. H: 2* F: 1 R: 1.

Section 02: Hazards identification

Signal Word................................................... DANGER.


Hazard Classification..................................... Respiratory Sensitizer 1. Skin Sensitizer 1. Eye Irritant 2. Skin Irritant 2. Acute Toxicity 4.
STOT SE 3. STOT RE 2.
Hazard Description........................................ H302 Harmful if swallowed. H312 Harmful in contact with skin. H315 Causes skin irritation.
H317 May cause an allergic skin reaction. H320 Causes eye irritation. H332 Harmful if
inhaled. H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled.
H335 May cause respiratory irritation. H373 May cause damage to the liver and kidneys
through prolonged or repeated contact.
Precautionary Statements............................. P202 Do not handle this product until all safety instructions have been read and
understood. P233 Keep container tightly closed. P251 Do not pierce or burn container,
even after use. P261 Avoid breathing mists, vapours and sprays. P264 Wash thoroughly
after handling. P270 Do not eat drink or smoke while using this product. P271 Use only
outdoors or in a well ventilated area. P272 Contaminated work clothing should not be
allowed out of the workplace. P273 Avoid release to the environment. P280 Wear
protective gloves and eye protection. P284 In case of inadequate ventilation wear
respiratory protection.

Section 03: COMPOSITION/INFORMATION ON INGREDIENTS


Hazardous Ingredients CAS # Wt. %

4,4'-DIPHENYLMETHANE 101-68-8 30-40


DIISOCYANATE (MDI)
TALC 14807-96-6 10-30
2,4-DIPHENYLMETHANE 5873-54-1 0.1-1.0
DIISOCYANATE (MDI)

Section 04: First aid measures


Eye contact.................................................... In case of contact, immediately flush eyes, keeping eyelids open, with plenty of water for at
least 15 minutes. Check for and remove any contact lenses. Obtain medical attention.
Skin contact................................................... Immediately flush skin with plenty of soap and water. Remove contaminated clothing.
Wash clothing before reuse. Do not peel solidified product off the skin. If irritation persists,
seek medical attention.
Inhalation....................................................... If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is
difficult, give oxygen, obtain medical attention.
Ingestion........................................................ Do not induce vomiting. Rinse mouth with water. Give 1 to 2 glasses of water to drink.
Never give anything by mouth to an unconscious person. If spontaneous vomiting occurs
have victim lean forward with head down to prevent aspiration of fluid into the lungs. Get
medical attention.
00000665 MATERIAL SAFETY DATA SHEET Page 2

PRODUCT: PF7770-3 TRUCK LINE PLIOGRIP URETHANE ADHESIVE PART A


Section 04: First aid measures
Additional information.................................... Eye: stain for evidence of corneal injury. If cornea is burned, instill antibiotic steroid
preparation frequently. Workplace vapours have produced reversible corneal epithelial
edema impairing vision. Skin: this compound is a known skin sensitizer. Treat
symptomatically as for contact dermatitis or thermal burns. If burned, treat as thermal burn.
Ingestion: treat symptomatically. There is no specific antidote. Inducing vomiting is
contraindicated because of the irritating nature of this compound. Respiratory: this
compound is a known pulmonary sensitizer. Treatment is essentially symptomatic. An
individual having a skin or pulmonary sensitization reaction to this material should be
removed from exposure to any isocyanate. In the event of an incident involving this product
ensure that medical authorities are provided a copy of this safety data sheet. In all cases, if
irritation persists seek medical attention.

Section 05: Fire fighting measures


Extinguishing media...................................... Dry chemical. Carbon dioxide. Foam. In cases of larger fires, water spray should be used.
Hazardous combustion products................... Oxides of carbon (CO,CO2). Oxides of nitrogen. Smoke. Hydrogen cyanide. Isocyanates.
Other potentially toxic fumes.
Special fire fighting procedures..................... Firefighter should be equipped with self-contained breathing apparatus and full protective
clothing to protect against potentially toxic and irritating fumes. During a fire, isocyanate
vapours and other irritating, highly toxic gases may be generated by thermal decomposition
or combustion. Cool fire-exposed containers with cold water spray. Heat will cause
pressure buildup and may cause explosive rupture. Heat will cause pressure buildup and
may cause explosive rupture.
Unusual fire / explosion hazards................... Reaction between water or foam and hot MDI can be vigorous.

Section 06: Accidental release measures


Leak/spill.......................................................Isolate area and keep unauthorized people away. Do not walk through spilled material.
Wear recommended protective equipment. Ventilate. Open windows and doors to allow
air circulation. Dike area to prevent spreading. The use of absorbent socks or spill pillows
may be required. Stop leak if safe to do so. Prevent runoff into drains, sewers, and other
waterways.
Major spills.................................................... If temporary control of isocyanate vapour is required, a blanket of protein foam may be
placed over spill. If transportation spill occurs in United States, call Chemtrec
1-800-424-9300. If transportation spill occurs in Canada, call Canutec at (613) 996-6666.
Large quantities may be pumped into closed, but not sealed, containers for disposal.
Minor spills.................................................... Cover spill area with suitable absorbent material (e.g., sand, earth, sawdust, vermiculite,
Oil-Dri, Kitty Litter, etc.). Saturate absorbent material with neutralizing solution.
Recommended portion is ten parts neutralizing solution to one part spilled material.
Suggested neutralization solution: 90% water + 5% concentrated ammonia + 5% detergent
(dish soap). Add an additional layer of absorbent material. Use shovel to move absorbent
material around to ensure that all spilled material comes in contact with the neutralizing
solution. Shovel all absorbed material, including absorbent socks or spill pillows, into an
appropriate salvage drum. Add further amounts of neutralizing solution. Allow to stand
(covered loosely) for 48 to 72 hours, to allow any gases to escape.
Clean up........................................................ Decontaminate spill area with neutralizing solution. Area can then be washed with soap
and water.

Section 07: Handling and storage


Handling procedures..................................... Avoid skin and eye contact. Do not breathe vapours, mist or dust. Use adequate
ventilation. Decomposition products can be highly toxic and irritating. Individuals with lung
or breathing problems or prior allergic reactions to isocyanates must not be exposed to
vapour or spray mist. Warning properties (irritation of the eyes, nose and throat or odour)
are not adequate to prevent chronic overexposure from inhalation. Handle in accordance
with good industrial hygiene and safety practices. Wash thoroughly after handling. Wear
respiratory protection if material is heated, sprayed, used in confined space, or if exposure
limit is exceeded. Employee education and training are important.
Storage needs............................................... Store in tightly closed containers to prevent moisture contamination. Store in a cool, dry
and well ventilated area. Do not reseal if contamination is suspected. Exposure to vapours
of heated isocyanates can be extremely dangerous.

Section 08: Exposure controls / personal protection


Protective equipment
Eye/type........................................................ Chemical safety goggles. Chemical safety goggles and full faceshield if a splash hazard
exists. Contact lenses should not be worn when working with this chemical.
Respiratory/type............................................ In case of insufficient ventilation, wear suitable respiratory equipment. An approved air
purifying respirator with organic vapour cartridges and particulate prefilter can be used to
minimize exposure. However, this should be permitted only for short periods of time (< 1
00000665 MATERIAL SAFETY DATA SHEET Page 3

PRODUCT: PF7770-3 TRUCK LINE PLIOGRIP URETHANE ADHESIVE PART A


Section 08: Exposure controls / personal protection
Respiratory/type............................................ hour) at relatively low concentrations (at or near the exposure limit). Protection provided by
air-purifying respirators is limited. The use of a positive pressure air supplied respirator is
mandatory when airborne concentrations are not known or airborne solvent levels are 10
times the appropriate exposure limit or spraying is performed in a confined space or with
limited ventilation. Be sure to use NIOSH approved respirator or equipment. Do not
exceed the use limits of the respirator.
Gloves/ type.................................................. Chemical resistant gloves: butyl rubber, nitrile rubber, neoprene, PVC. Practice good
hygiene, wash thoroughly before handling any food.
Clothing/type................................................. Wear adequate protective clothes. Wear long sleeves and trousers to prevent dermal
exposure.
Footwear/type................................................ Safety boots per local regulations.
Other/type...................................................... Eye wash facility should be in close proximity. Emergency shower should be in close
proximity. Educate and train employees on the safe use and handling of the product.
Ventilation requirements................................ Ventilate adequately. Exhaust air may need to be cleaned by scrubbers or filters to reduce
environmental contamination. Vent work area to ensure airborne concentrations are below
the current occupational exposure limits. Avoid breathing mists; if general ventilation or
local exhaust is inadequate, persons exposed to mists should wear approved breathing
devices.
Monitoring...................................................... Exposure levels must be monitored by accepted monitoring techniques to ensure that the
TLV is not exceeded.
Medical surveillance...................................... Medical supervision of all employees who handle or come in contact with isocyanates is
recommended. These should include preemployment and periodic medical examinations
with pulmonary function test (FEC, FVC as a minimum). Persons with asthmatic-type
conditions, chronic bronchitis, other chronic respiratory diseases or recurring skin eczema
or sensitization should be excluded from working with isocyanates. Once a person is
diagnosed as sensitized to an isocyanate, no further exposure can be permitted. These
should include preemployment and periodic medical examinations with pulmonary function
test (fev, fvc as a minimum). Persons with asthmatic-type conditions, chronic bronchitis,
other chronic respiratory diseases or recurrant skin eczema or sensitization should be
excluded from working with isocyanates. Once a person is diagnosed as sensitized to an
isocyanate, no further exposure can be permitted.
Exposure limits
ACGIH TLV OSHA PEL NIOSH
Ingredients TWA STEL PEL STEL REL

4,4'-DIPHENYLMETHAN 0.005 ppm No data 0.02 ppm No data 0.005 ppm


E DIISOCYANATE (MDI)
TALC 2 mg/m3 No data 2 mg/m3 No data 2 mg/m3
2,4-DIPHENYLMETHANE No data No data No data No data No data
DIISOCYANATE (MDI)

Section 09: Physical and chemical properties


Physical state................................................ Viscous liquid.
Colour............................................................ Beige.
Odour............................................................ No data.
Odour threshold (ppm).................................. No data.
Vapour pressure (mm Hg)............................. <0.013 hPa @ 25C.
Vapour density (air=1)................................... >1.
pH.................................................................. No data.
Specific gravity.............................................. 1.288 g/cm3 @ 20C - 10.72 lb/USG @ 25C.
Freezing point (deg C)................................... No data.
Solubility........................................................ Reacts slowly with water to liberate C02 gas.
Boiling point (deg C)...................................... >200.
Evaporation rate............................................ <1. (butyl acetate = 1).
Flash point (deg C), method.......................... >100.
Auto ignition temperature (deg C)................. No data.
Upper flammable limit (% vol)....................... No data.
Lower flammable limit (% vol)....................... No data.
Coefficient of water\oil distribution................. No data.
VOC............................................................... 0.0 g/L - 0.0 lb/usg.
Viscosity........................................................ No data.

Section 10: Stability and reactivity


Stability.......................................................... Stable at normal temperatures and pressures.
Reactivity conditions...................................... Contact with moisture and other materials will react with isocyanates.
Incompatibility................................................ Water, amines, strong bases, alcohols. Copper alloys.
Hazardous products of decomposition.......... See hazardous combustion products.
Hazardous polymerization............................. Contact with moisture, other materials that react with isocyanates, or temperatures above
177C, may cause polymerization.
00000665 MATERIAL SAFETY DATA SHEET Page 4

PRODUCT: PF7770-3 TRUCK LINE PLIOGRIP URETHANE ADHESIVE PART A


Section 11: Toxicological information
Route of entry ............................................... Eye contact. Skin contact. Inhalation.
Effects of acute exposure.............................. Skin irritant. Can cause reddening, itching and swelling. Persons previously sensitized
can experience allergic skin reaction with symptoms of reddening, itching, swelling and
rash. Cured material is difficult to remove. Contact with MDI can cause discolouration.
EYE: Product liquid, aerosols or vapours are irritating. Can cause tearing, reddening and
swelling. May cause temporary corneal injury. INHALATION: Vapour/mists at
concentrations above the exposure limits can irritate (burning sensation) the mucous
membranes in the respiratory tract. This can cause a runny nose, sore throat, coughing,
chest discomfort, difficulty breathing and reduced pulmonary functioning. Persons with
pre-existing, nonspecific bronchial hyperractivity can respond to concentrations below the
TLV with similar symptoms as well as asthma attack. These symptoms can be delayed up
to several hours after exposure. Effects are usually reversible. INGESTION: May cause
irritation. Symptoms can include sore throat, abdominal pain, nausea, vomiting and
diarrhea. Talc can be absorbed into the lungs and the digestive tract, and adversely affect
lung function.
Effects of chronic exposure........................... As a result of previous repeated overexposure or a single large dose, certain individuals
develop sensitization, which will cause them to react to a later exposure to product at levels
well below the TLV. Symptoms, including chest tightness, wheezing, cough, shortness of
breath or asthma attack, could be immediate or delayed. There are reports that once
sensitized, an individual can experience these symptoms upon exposure to dust, cold air or
other irritants. This increased lung sensitivity can persist for weeks and, in severe cases,
for several years. Prolonged or repeated exposure may cause lung damage, including a
decrease in lung function. Possible risk of irreversible effects. Prolonged skin contact may
cause reddening, swelling, rash, blistering, and in some cases, skin sensitization.
Sensitization can be permanent. Prolonged vapour contact with eyes may cause
conjunctivitis. Talc has been shown to cause fibrosis of the lungs.
Sensitizing capability of material................... Isocyanates are known to cause skin and respiratory sensitization in humans. Animal tests
have indicated that respiratory sensitization can result from skin contact with diisocyanates.
Carcinogenicity of material............................ This product contains non-asbestiform Talc, which is classified as a Group 3 (not
classifiable as to carcinogenicity to humans) by IARC .
Note............................................................... This product is an inert plastic when fully cured, and as such, is non-hazardous. Exposure
to unreacted chemicals can occur when handling the individual components in pails or
when using cartridges from the time of dispensing until the mixed material has cured. The
mixed material is actually curing as it is dispensed in an increasingly viscous form, making
it unlikely to present an inhalation hazard. The semi-viscous mixture does not flow like a
liquid when dispensed, thus minimizing the possibility of accidential skin contact.
Toxicological Data
Ingredients LC50-inh, rat LD50-Oral,rat

4,4'-DIPHENYLMETHANE 369 mg/m3 4 hours rat No data


DIISOCYANATE (MDI)
TALC No data No data
2,4-DIPHENYLMETHANE 370-490 MG/M3 (4HR) RAT No data
DIISOCYANATE (MDI)

Section 12: Ecological information


Environmental............................................... Do not allow to enter waters, waste water or soil.
Biodegradability............................................. No data.

Section 13: Disposal considerations


Waste disposal.............................................. Dispose of waste in accordance with all applicable federal, provincial/state and local
regulations. Industrial incineration is the preferred method. Empty containers retain
product residue; observe all precautions for the product. Decontaminate containers prior to
disposal. Empty decontaminated containers should be crushed to prevent reuse. Do not
heat or cut empty containers with electric or gas torch as vapours and gases may be toxic.

Section 14: Transport information


TDG Classification (Road)............................. Not regulated.
IATA Classification (Air)................................ Not regulated.
IMDG Classification (Marine)........................ Not regulated.
Marine Pollutant............................................ No.
00000665 MATERIAL SAFETY DATA SHEET Page 5

PRODUCT: PF7770-3 TRUCK LINE PLIOGRIP URETHANE ADHESIVE PART A


Section 15: Regulatory information
WHMIS classification..................................... D2A. D2B.
CEPA status.................................................. On Domestic Substances List (DSL).
Section 313................................................... None.
OSHA............................................................ This product is considered hazardous under the OSHA Hazard Communication Standard.
SARA Title III
Section 302 - extremely hazardous .............. None.
substances
Section 311/312 - hazard categories............. Immediate health, delayed health.
EPA hazardous air pollutants (HAPS) .......... Methylene Diphenyl Diisocyanate (MDI).
40CFR63
TSCA inventory status................................... All components are listed.
California Proposition 65............................... This product does not contain any chemical(s) known to the State of California to cause
cancer or reproductive toxicity.

Section 16: Other information


Prepared by: ................................................. REGULATORY AFFAIRS.
Telephone number:....................................... (800) 387-7981.
Disclaimer:..................................................... DISCLAIMER: All information appearing herein is based upon data obtained from
experience and recognized technical sources. To the best of our knowledge, it is believed
to be correct as of the date of issue but we make no representations as to its accuracy or
sufficiency and do not suggest or guarantee that any hazards listed herein are the only
ones which exist. The hazard information contained herein is offered solely for the
consideration of the user, subject to his own investigation and verification of compliance
with applicable regulations, including the safe use of the product under every foreseeable
condition. The information relates only to the product designated herein, and does not
relate to its use in combination with any other material or in any other process.
MATERIAL SAFETY DATA SHEET

PYRO-CHEM ABC
Product Code: 2001-2-012 ANa Issue Date: 01-08-2014

1. Product and Company Identification


Material name PYRO-CHEM ABC
Version # 01
Revision date 01-08-2014
CAS # Mixture
Product Code 2001-2-012 ANa
Product use Fire extinguishing agent
Manufacturer / Importer /
Supplier
Name Tyco Fire Protection Products
Address One Stanton Street
Marinette, WI 54143-2542
Phone 715-732-3465
Internet http://www.pyrochem.com
Emergency Phone Number CHEMTREC 800-424-9300 or 703-527-3887

2. Hazards Identification
Emergency overview WARNING

Irritating to eyes and skin.


OSHA regulatory status This product is considered hazardous under 29 CFR 1910.1200 (Hazard Communication).
Potential health effects
Routes of exposure Eye contact. Skin contact. Inhalation. Ingestion.
Eyes Avoid contact with eyes. Contact with eyes may cause irritation.
Skin Avoid contact with the skin. May cause skin irritation.
Inhalation Inhalation of dusts may cause respiratory irritation.
Ingestion Not a likely route of entry.
Target organs Eyes. Respiratory system. Skin.
Signs and symptoms Irritation of eyes and mucous membranes.

3. Composition / Information on Ingredients


Non-hazardous components CAS # Percent
Pigment Yellow 14 5468-75-7 0.1 - 1

Silicone fluid 63148-57-2 0.1 - 1

Calcium hydroxide phosphate (Ca5(OH)(PO4)3) 12167-74-7 2.5 - 10

FULLERS EARTH 8031-18-3 2.5 - 10

Ammonium Sulfate 7783-20-2 20 - 40

Ammonium Phosphate 7722-76-1 60 - 80

4. First Aid Measures


First aid procedures
Eye contact Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, if
present and easy to do. Continue rinsing. Get medical attention if irritation persists after washing.
Skin contact Wash off with warm water and soap. Get medical attention if irritation develops and persists.

Material name: PYRO-CHEM ABC MSDS US


1641 Version #: 01 Revision date: 01-08-2014 1/4
Inhalation Move to fresh air. Get medical attention, if needed.
Ingestion Rinse mouth. Do not induce vomiting without advice from poison control center. If vomiting
occurs, keep head low so that stomach content doesn't get into the lungs.
Notes to physician Symptoms may be delayed.
General advice If you feel unwell, seek medical advice (show the label where possible). Ensure that medical
personnel are aware of the material(s) involved, and take precautions to protect themselves.
Show this safety data sheet to the doctor in attendance.

5. Fire Fighting Measures


Flammable properties No unusual fire or explosion hazards noted.
Extinguishing media
Suitable extinguishing This product is not flammable. Use extinguishing agent suitable for type of surrounding fire.
media
Protection of firefighters
Specific hazards arising None known.
from the chemical
Hazardous combustion Carbon monoxide and carbon dioxide.
products

6. Accidental Release Measures


Personal precautions Local authorities should be advised if significant spillages cannot be contained. Avoid inhalation of
dust from the spilled material. Wear a dust mask if dust is generated above exposure limits.
Environmental precautions Prevent further leakage or spillage if safe to do so. Do not contaminate water.
Methods for containment If sweeping of a contaminated area is necessary use a dust suppressant agent which does not
react with the product. Prevent entry into waterways, sewer, basements or confined areas.
Methods for cleaning up Should not be released into the environment. Sweep up or vacuum up spillage and collect in
suitable container for disposal. Collect dust using a vacuum cleaner equipped with HEPA filter.
Avoid dust formation. Following product recovery, flush area with water.
Other information Clean up in accordance with all applicable regulations.

7. Handling and Storage


Handling Keep formation of airborne dusts to a minimum. Do not breathe dust. Avoid contact with eyes. Do
not use in areas without adequate ventilation. Wear personal protective equipment. Wash
thoroughly after handling.
Storage Store in a well-ventilated place. Keep container tightly closed. Guard against dust accumulation of
this material. Use care in handling/storage.

8. Exposure Controls / Personal Protection


Engineering controls Ensure adequate ventilation, especially in confined areas.
Personal protective equipment
Eye / face protection Do not get in eyes. Chemical goggles are recommended.
Skin protection No special protective equipment required.
Respiratory protection When workers are facing concentrations above the exposure limit they must use appropriate
certified respirators.
General hygiene Do not get in eyes.
considerations

9. Physical & Chemical Properties


Appearance
Form Powder.
Color Yellow.
Odor Odorless.
Physical state Solid.
pH Not available.
Melting point Not available.
Freezing point Not available.
Boiling point Not available.
Material name: PYRO-CHEM ABC MSDS US
1641 Version #: 01 Revision date: 01-08-2014 2/4
Flash point Not available.
Evaporation rate Not available.
Flammability limits in air, upper, Not available.
% by volume
Flammability limits in air, lower, Not available.
% by volume
Vapor pressure Not available.
Vapor density Not available.
Specific gravity Not available.
Relative density Not available.
Solubility (water) Not available.
Partition coefficient Not available
(n-octanol/water)
Auto-ignition temperature Not available.
Decomposition temperature Not available.
VOC Not available.

10. Chemical Stability & Reactivity Information


Chemical stability Material is stable under normal conditions.
Incompatible materials Strong acids.
Hazardous decomposition Carbon oxides.
products

11. Toxicological Information


Toxicological information The toxicity of this product has not been tested.
Carcinogenicity This product is not considered to be a carcinogen by IARC, ACGIH, NTP, or OSHA.
Further information This product has no known adverse effect on human health.

12. Ecological Information


Ecotoxicological data
Product Test Results
PYRO-CHEM ABC (Mixture) EC50 Daphnia: 167 mg/l 48.00 hours estimated
LC50 Fish: 3181 mg/l 96.00 hours estimated
Components Test Results
Ammonium Sulfate (7783-20-2) EC50 Water flea (Ceriodaphnia dubia): 52 - 67 mg/l 48.00
hours
LC50 Pink salmon (Oncorhynchus gorbuscha): 0.068 mg/l
96.00 hours
Ecotoxicity This material is not expected to be harmful to aquatic life.
Environmental effects An environmental hazard cannot be excluded in the event of unprofessional handling or disposal.
Persistence and degradability Not available.

13. Disposal Considerations


Disposal instructions This product, in its present state, when discarded or disposed of, is not a hazardous waste
according to Federal regulations (40 CFR 261.4 (b)(4)). Under RCRA, it is the responsibility of
the user of the product to determine, at the time of disposal, whether the product meets RCRA
criteria for hazardous waste. Dispose of waste material according to Local, State, Federal, and
Provincial Environmental Regulations.
Waste from residues / unused Dispose of in accordance with local regulations.
products

14. Transport Information


DOT
Not regulated as dangerous goods.

Material name: PYRO-CHEM ABC MSDS US


1641 Version #: 01 Revision date: 01-08-2014 3/4
15. Regulatory Information
US federal regulations This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication
Standard, 29 CFR 1910.1200.
CERCLA/SARA Hazardous Substances - Not applicable.
US EPCRA (SARA Title III) Section 313 - Toxic Chemical: De minimis concentration
Ammonium Phosphate (CAS 7722-76-1) 1.0 %
Ammonium Sulfate (CAS 7783-20-2) 1.0 %
US EPCRA (SARA Title III) Section 313 - Toxic Chemical: Listed substance
Ammonium Phosphate (CAS 7722-76-1) Listed.
Ammonium Sulfate (CAS 7783-20-2) Listed.
CERCLA (Superfund) reportable quantity
None
Superfund Amendments and Reauthorization Act of 1986 (SARA)
Hazard categories Acute Health - No
Chronic Health - No
Fire Hazard - No
Pressure Hazard - No
Reactivity Hazard - No
Section 302 extremely No
hazardous substance
Section 311 hazardous No
chemical
Inventory status
Country(s) or region Inventory name On inventory (yes/no)*
Australia Australian Inventory of Chemical Substances (AICS) No
Canada Domestic Substances List (DSL) Yes
Canada Non-Domestic Substances List (NDSL) No
China Inventory of Existing Chemical Substances in China (IECSC) Yes
Europe European Inventory of Existing Commercial Chemical Yes
Substances (EINECS)
Europe European List of Notified Chemical Substances (ELINCS) No
Japan Inventory of Existing and New Chemical Substances (ENCS) No
Korea Existing Chemicals List (ECL) Yes
New Zealand New Zealand Inventory Yes
Philippines Philippine Inventory of Chemicals and Chemical Substances Yes
(PICCS)
United States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory No
*A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s)
State regulations This product does not contain a chemical known to the State of California to cause cancer, birth
defects or other reproductive harm.
US - Pennsylvania RTK - Hazardous Substances: Listed substance
Ammonium Sulfate (CAS 7783-20-2) Listed.

16. Other Information


Further information HMIS® is a registered trade and service mark of the NPCA.
HMIS® ratings Health: 0
Flammability: 0
Physical hazard: 0
NFPA ratings Health: 0
Flammability: 0
Instability: 0
Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge,
information and belief at the date of its publication. The information given is designed only as a
guidance for safe handling, use, processing, storage, transportation, disposal and release and is
not to be considered a warranty or quality specification. The information relates only to the
specific material designated and may not be valid for such material used in combination with any
other materials or in any process, unless specified in the text.
Issue date 01-08-2014
Material name: PYRO-CHEM ABC MSDS US
1641 Version #: 01 Revision date: 01-08-2014 4/4

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