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    Constanstes de Disociación de Ácidos y Bases Inorgánicas

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    The document provides a table of dissociation constants (pKa values) of inorganic acids and bases at various temperatures. The table lists numerous inorganic acids and bases along with their chemical formulas and the pKa values for different dissociation steps. Additional context is provided on how to calculate hydrogen ion and hydroxide ion concentrations from the pKa values.

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    Constanstes de Disociación de Ácidos y Bases Inorgánicas

    Uploaded by

    Ana
    19 views2 pages
    The document provides a table of dissociation constants (pKa values) of inorganic acids and bases at various temperatures. The table lists numerous inorganic acids and bases along with their chemical formulas and the pKa values for different dissociation steps. Additional context is provided on how to calculate hydrogen ion and hydroxide ion concentrations from the pKa values.

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    Constantes de disociación de ácidos y bases inorgánicas

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    The document provides a table of dissociation constants (pKa values) of inorganic acids and bases at various temperatures. The table lists numerous inorganic acids and bases along with their chemical formulas and the pKa values for different dissociation steps. Additional context is provided on how to calculate hydrogen ion and hydroxide ion concentrations from the pKa values.

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
    19 views2 pages

    Constanstes de Disociación de Ácidos y Bases Inorgánicas

    Uploaded by

    Ana
    The document provides a table of dissociation constants (pKa values) of inorganic acids and bases at various temperatures. The table lists numerous inorganic acids and bases along with their chemical formulas and the pKa values for different dissociation steps. Additional context is provided on how to calculate hydrogen ion and hydroxide ion concentrations from the pKa values.

    Copyright:

    © All Rights Reserved
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    DISSOCIATION CONSTANTS OF INORGANIC ACIDS AND BASES

    The data in this table are presented as values of pKa, defined as the negative logarithm of the acid dissociation constant Ka for the reaction

    BH 1 B– + H+

    Thus pKa = –log Ka , and the hydrogen ion concentration [H+] can be calculated from

    Ka =
    [H ] [B ]
    + –

    [BH]
    In the case of bases, the entry in the table is for the conjugate acid; e.g., ammonium ion for ammonia. The OH– concentration in the system

    NH3 + H2O 1 NH4+ + OH–

    can be calculated from the equation

    K b = K water / K a =
    [OH ] [NH ]
    –
    4
    +

    [NH 3 ]
    where Kwater = 1.01 × 10–14 at 25 °C. Note that pKa + pKb = pKwater.

    All values refer to dilute aqueous solutions at zero ionic strength at the temperature indicated. The table is arranged alphabetically by compound
    name.

    REFERENCE

    1. Perrin, D. D., Ionization Constants of Inorganic Acids and Bases in Aqueous Solution, Second Edition, Pergamon, Oxford, 1982.
    Name Formula Step t/°C pKa

    Aluminum(III) ion Al+3 25 5.0


    Ammonia NH3 25 9.25
    Arsenic acid H3AsO4 1 25 2.26
    2 25 6.76
    3 25 11.29
    Arsenious acid H2AsO3 25 9.29
    Barium(II) ion Ba+2 25 13.4
    Boric acid H3BO3 1 20 9.27
    2 20 >14
    Calcium(II) ion Ca+2 25 12.6
    Carbonic acid H2CO3 1 25 6.35
    2 25 10.33
    Chlorous acid HClO2 25 1.94
    Chromic acid H2CrO4 1 25 0.74
    2 25 6.49
    Cyanic acid HCNO 25 3.46
    Germanic acid H2GeO3 1 25 9.01
    2 25 12.3
    Hydrazine N2H4 25 8.1
    Hydrazoic acid HN3 25 4.6
    Hydrocyanic acid HCN 25 9.21
    Hydrofluoric acid HF 25 3.20
    Hydrogen peroxide H2O2 25 11.62
    Hydrogen selenide H2Se 1 25 3.89
    2 25 11.0
    Hydrogen sulfide H2S 1 25 7.05
    2 25 19
    Hydrogen telluride H2Te 1 18 2.6
    2 25 11
    Hydroxylamine NH2OH 25 5.94
    Hypobromous acid HBrO 25 8.55

    © 2000 CRC Press LLC

    TeamLRN
    DISSOCIATION CONSTANTS OF INORGANIC ACIDS AND BASES (continued)
    Name Formula Step t/°C pKa
    Hypochlorous acid HClO 25 7.40
    Hypoiodous acid HIO 25 10.5
    Iodic acid HIO3 25 0.78
    Lithium ion Li+ 25 13.8
    Magnesium(II) ion Mg+2 25 11.4
    Nitrous acid HNO2 25 3.25
    Perchloric acid HClO4 20 -1.6
    Periodic acid HIO4 25 1.64
    Phosphoric acid H3PO4 1 25 2.16
    2 25 7.21
    3 25 12.32
    Phosphorous acid H3PO3 1 20 1.3
    2 20 6.70
    Pyrophosphoric acid H4P2O7 1 25 0.91
    2 25 2.10
    3 25 6.70
    4 25 9.32
    Selenic acid H2SeO4 2 25 1.7
    Selenious acid H2SeO3 1 25 2.62
    2 25 8.32
    Silicic acid H4SiO4 1 30 9.9
    2 30 11.8
    3 30 12
    4 30 12
    Sodium ion Na+ 25 14.8
    Strontium(II) ion Sr+2 25 13.2
    Sulfamic acid NH2SO3H 25 1.05
    Sulfuric acid H2SO4 2 25 1.99
    Sulfurous acid H2SO3 1 25 1.85
    2 25 7.2
    Telluric acid H2TeO4 1 18 7.68
    2 18 11.0
    Tellurous acid H2TeO3 1 25 6.27
    2 25 8.43
    Tetrafluoroboric acid HBF4 25 0.5
    Thiocyanic acid HSCN 25 -1.8
    Water H2O 25 13.995

    © 2000 CRC Press LLC

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