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    The document describes an experiment to calculate the heat of neutralization of a strong acid and strong base using a calorimeter. 50mL of 1M NaOH and 50mL of 1M HCl were placed in the calorimeter and the temperature change was measured. The mass of the calorimeter and solutions were measured before and after the reaction. The heat of neutralization was calculated using the temperature change, masses, specific heats, and molarities/volumes. The calculated heat of neutralization of NaOH and HCl was -57.05 kJ/mol.

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    Practical

    Uploaded by

    Pakistan ideologue
    89 views2 pages
    The document describes an experiment to calculate the heat of neutralization of a strong acid and strong base using a calorimeter. 50mL of 1M NaOH and 50mL of 1M HCl were placed in the calorimeter and the temperature change was measured. The mass of the calorimeter and solutions were measured before and after the reaction. The heat of neutralization was calculated using the temperature change, masses, specific heats, and molarities/volumes. The calculated heat of neutralization of NaOH and HCl was -57.05 kJ/mol.

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    The document describes an experiment to calculate the heat of neutralization of a strong acid and strong base using a calorimeter. 50mL of 1M NaOH and 50mL of 1M HCl were placed in the calorimeter and the temperature change was measured. The mass of the calorimeter and solutions were measured before and after the reaction. The heat of neutralization was calculated using the temperature change, masses, specific heats, and molarities/volumes. The calculated heat of neutralization of NaOH and HCl was -57.05 kJ/mol.

    Copyright:

    © All Rights Reserved
    Download as DOCX, PDF, TXT or read online from Scribd
    Download as docx, pdf, or txt
    89 views2 pages

    Practical

    Uploaded by

    Pakistan ideologue
    The document describes an experiment to calculate the heat of neutralization of a strong acid and strong base using a calorimeter. 50mL of 1M NaOH and 50mL of 1M HCl were placed in the calorimeter and the temperature change was measured. The mass of the calorimeter and solutions were measured before and after the reaction. The heat of neutralization was calculated using the temperature change, masses, specific heats, and molarities/volumes. The calculated heat of neutralization of NaOH and HCl was -57.05 kJ/mol.

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    © All Rights Reserved
    Download as DOCX, PDF, TXT or read online from Scribd
    Download as docx, pdf, or txt
    of 2

    EXPERIMENT NO 5.

    To calculate the heat of neutralization of strong acid Vs strong base using calorimeter

    Apparatus

    Calorimeter with stirrer, thermometer with rough balance.

    Procedure

    Prepare IM of NaoH & IM of HCL of exact molarities, IM. Out of IM prepared NaoH take
    4gm of it, add 100 ml of distilled water, for P preparing approximately IM HCL, take
    10ml of conc HSL & dilute it to 100ml with distilled water. Prepare 0.5m oxalic acid by
    dissolving 31.5gms of it in 250ml of distilled water. First of all, prepare standard solution
    of 1M NaoH by it and then with standard 1M NaoH, prepare 1M HCL of exact molarity.

    Take a calorimeter, wash it along with stirrer. Weigh this calorimeter on a rough
    balance. Take 50ml of 1M NaoH in it. Note the initial temperature of NaoH by the help of
    thermometer.

    Add 50ml of 1M HCL in it. There will be a rise in temperature when acid and alkali react
    together. Note the rise in temperature of mixture when the temperature stops rising,
    weigh the calorimeter and mixture solution. Find out the mass of solution and calculate
    the heat of neutralization.

    Equation

    HCL + NaoH -- NaCl + H2O + 13.88 KCAL

    Observation and Calculations

    Weight of calorimeter + stirrer = m1 = 56.5g

    Add 50ml of 0.5M Acid solution in calorimeter then initial temperature of acid = t1= 21 C

    Add 50ml of 0.5M base solution in calorimeter then final temperature of solution = t2=
    24 C

    Change of temperature = t2 – t1 = 24 C – 21 C

    =3C

    Weight of calorimeter + solution = m2= 165g

    Weight of solution = m3 = m2 – m1 = 108.5g

    Specific heat of copper calorimeter = S1 = 0.091


    Specific heat of solution = S2= 1

    Heat of neutralization = (m1S1 + m2S2) x 1000


    M x V x 100

    Here, M = morality = 1M

    V = Volume = 25ml

    Heat of neutralization = (m1S1 + m2S2) x 1000


    M x V x 100

    = 56.5 (0.091) + 108.5 (1) x 1000


    1 x 25 x 1000

    Heat of neutralization in Kcal = 1363 Kcal / mol

    Heat of neutralization in KJ = J = 1 C = 4.184J

    = -13.63 x 4.184

    = -57.05 KJ/mol

    Result

    The heat of neutralization of NaoH and HCL is 57.05 KJ/mol.

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