Product Conformity Certificate: ULTRAMAT / OXYMAT 6 Multi-Component Analyser

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PRODUCT CONFORMITY CERTIFICATE

This is to certify that the

ULTRAMAT / OXYMAT 6 Multi-component analyser


Manufactured by:

Siemens AG
DE-76181
Karlsruhe,
Germany

has been assessed by Sira Certification Service


And for the conditions stated on this certificate complies with:

MCERTS Performance Standards for Continuous Emission


Monitoring Systems (CEMS) and T-CEMS, Version 4 dated July 2018
EN15267-3:2007,
& QAL 1 as defined in EN 14181: 2014

Certification Ranges :

O2 0 to 5 % vol to 0 to 25 % vol
NO 0-100 mg/m3 to 0-200 mg/m3
CO 0-50 mg/m3 to 0-75 mg/3
SO2 0-75 mg/m3

Project No. : 674/0374/ 70211412


Certificate No : Sira MC040035/07
Initial Certification : 25 February 2004
This Certificate issued : 24 February 2019 Emily Alexander
Renewal Date : 24 February 2024 Environmental Project Engineer

MCERTS is operated on behalf of the Environment Agency by


Sira Certification Service
Unit 6, Hawarden Industrial Park
Hawarden, Deeside, CH5 3US
Tel: +44 (0)1244 670 900

The MCERTS certificate consists of this document in its entirety.


For conditions of use, please consider all the information within.
This certificate may only be reproduced in its entirety and without change
To authenticate the validity of this certificate please visit www.csagroupuk.org/mcerts

Page 1 of 9
Form 1335
Issue 5
Certificate Contents
Approved Site Application ........................................................................................................ 2
Basis of Certification ............................................................................................................... 2
Product Certified..................................................................................................................... 3
Certified Performance ............................................................................................................. 4
Description............................................................................................................................. 9
General Notes ........................................................................................................................ 9

Approved Site Application

Any potential user should ensure, in consultation with the manufacturer, that the monitoring system
is suitable for the intended application. For general guidance on stack emission monitoring
techniques refer to Environment Agency Technical Guidance Note M2: Monitoring of stack emissions
to air. Operators with installations falling under the Large Combustion Plant Directive or Waste
Incineration Directive must refer to Technical Guidance Note M20: Quality Assurance of Continuous
Emission Monitoring Systems, for guidance on the suitability of CEMS for their installations. M2 and
M20 are available on the Agency’s website at www.mcerts.net

On the basis of the assessment and the ranges required for compliance with EU Directives this
instrument is considered suitable for use on waste incineration and large coal-fired combustion plant
applications. This CEM has been proven suitable for its measuring task (parameter and composition
of the flue gas) by use of the QAL 1 procedure specified in EN14181, for LCPD and WID applications
for the ranges specified. The lowest certified range for each determinand shall not be more than
1.5X the emission limit value (ELV) for WID applications, and not more than 2.5X the ELV for LCPD
and other types of application.

The field trial was conducted over 6 months with the Ultramat / Oxymat 6 installed on a waste
incinerator.

Basis of Certification

This certification is based on the following Test Report(s) and on Sira’s assessment and ongoing
surveillance of the product and the manufacturing process:

TÜV Süddeutschland Report Number 24019084 dated February 1999


TÜV Süddeutschland Report Number 13213066 dated April 2009
TÜV Süddeutschland Report Number 1701476b dated November 2011 (HCl Interference)

Certificate No : Sira MC040035/07


This Certificate issued : 24 February 2019

This certificate may only be reproduced in its entirety and without change
To authenticate the validity of this certificate please visit www.csagroupuk.org/mcerts

Page 2 of 9
Form 1335
Issue 5
Product Certified

The measuring system consists of the following parts:

1. Sample Probe 2. Heated Filter 3. Heated 4. Gas 5. Analyser


Sample Line Conditioning
Model: Model: Model: Model: Model:
M&C SP 2000 HR Integrated in H300 Integral M&C/Siemens Ultramat/Oxymat
Sample Probe: S- Length: 16m 7MB1993 6
2K-150

Allowable variations could include:

 A different brand or model of sampling system of the same type, provided that there is
evidence the alternative system works with similar types of CEM.

 Additional manifolds and heated valves used to allow more than one analyser to share a
sampling system.

This certificate applies to all instruments fitted with software version 4 (serial number X2-635)
onwards.

Certificate No : Sira MC040035/07


This Certificate issued : 24 February 2019

This certificate may only be reproduced in its entirety and without change
To authenticate the validity of this certificate please visit www.csagroupuk.org/mcerts

Page 3 of 9
Form 1335
Issue 5
Certified Performance

The instrument was evaluated for use under the following conditions:

Ambient Temperature Range: +5°C to +45°C


Instrument IP rating: ‘E’ model IP20
‘F’ model IP40

Note: For outdoor installations the analyser needs to be mounted into an IP65 environment. If the instrument is supplied
with an enclosure, then the ambient temperature shall be monitored inside the enclosure to ensure that it stays within the
above ambient temperature range.

Unless otherwise stated the evaluation was carried out on the certification range CO 0 to 50mg/m3, NO 0 to 100mg/m3,
SO2 0 to 75mg/m3, and O2 0 to 25%vol
Test Results expressed as % of the Other results MCERTS
certification range specification
<0.5 <1 <2 <5
Response time

SO2 120s <200s

NO 81s <200s

CO 75s <200s

O2 38s <200s

Repeatability standard deviation at zero


point

SO2 0.3 <2.0%

NO 0.4 <2.0%

CO 0.4 <2.0%

O2 0.01 <0.2%

Repeatability standard deviation at span


point

SO2 0.2 <2.0%

NO 0.2 <2.0%

CO 0.3 <2.0%

O2 0.02 <0.2%

Certificate No : Sira MC040035/07


This Certificate issued : 24 February 2019

This certificate may only be reproduced in its entirety and without change
To authenticate the validity of this certificate please visit www.csagroupuk.org/mcerts

Page 4 of 9
Form 1335
Issue 5
Test Results expressed as % of the Other results MCERTS
certification range specification
<0.5 <1 <2 <5
Lack-of-fit

SO2 0-400 mg/m3 -0.32 <2.0%

NO 0-100 mg/m3 -0.26 <2.0%

NO 0-200 mg/m3 0.45 <2.0%

CO 0-50 mg/m3 0.27 <2.0%

CO 0-75 mg/m3 -0.22 <2.0%

O2 0-5 % vol -0.08 <0.2%

O2 0-25 5 vol -0.05 <0.2%

Influence of ambient temperature zero


point – E model

SO2 -3.3 <5.0%

NO 1.9 <5.0%

CO -2.2 <5.0%

O2 0.12 <0.50%

Influence of ambient temperature zero


point – F model

SO2 2.4 <5.0%

NO 4.3 <5.0%

CO -1.7 <5.0%

O2 -0.12 <0.50%

Influence of ambient temperature span


point - E model

SO2 4.4 <5.0%

NO 1.6 <5.0%

CO 3.1 <5.0%

O2 0.14 <0.50%

Certificate No : Sira MC040035/07


This Certificate issued : 24 February 2019

This certificate may only be reproduced in its entirety and without change
To authenticate the validity of this certificate please visit www.csagroupuk.org/mcerts

Page 5 of 9
Form 1335
Issue 5
Test Results expressed as % of the Other results MCERTS
certification range specification
<0.5 <1 <2 <5
Influence of ambient temperature span
point - F model

SO2 2.4 <5.0%

NO 4.4 <5.0%

CO 1.3 <5.0%

O2 0.10 <0.50%

Influence of sample gas flow for


extractive CEMS

SO2, NO, CO, <1 <2.0%

O2 <0.2 <0.2%

Influence of voltage variations 185 to <2.0%


No effect
264V <0.2% O2

Influence of vibration (10 to 60Hz


Not tested To be reported
(±0.3mm), 60 to 150Hz at 19.6m/s2)

Cross-sensitivity at zero Note 1

SO2 3.4 <4.0%

NO -2.7 <4.0%

CO 3.9 <4.0%

O2 -0.11 <0.40%

Cross-sensitivity at span Note 1

SO2 -2.7 <4.0%

NO -2.7 <4.0%

CO 3.7 <4.0%

O2 0.17 <0.40%

Measurement uncertainty Guidance - at least 25% below max


permissible uncertainty

SO2 (for an ELV of 50mg/m3) 7.60% 15%

NO (for an ELV of 32.6mg/m3) 10.61% 15%

CO (for an ELV of 50mg/m3) 7.32% 7.5%

O2 (for a range of 25%vol) 0.32%vol -

Certificate No : Sira MC040035/07


This Certificate issued : 24 February 2019

This certificate may only be reproduced in its entirety and without change
To authenticate the validity of this certificate please visit www.csagroupuk.org/mcerts

Page 6 of 9
Form 1335
Issue 5
Test Results expressed as % of the Other results MCERTS
certification range specification
<0.5 <1 <2 <5
Calibration function (field)

SO2 0.99 >0.90

NO 0.99 >0.90

CO 0.99 >0.90

O2 0.99 >0.90

Response time (field) Note 2

SO2 120s <200s

NO 81s <200s

CO 75s <200s

O2 38s <200s

Lack of fit (field) Note 3

SO2, NO, CO <2.0% <2.0%

O2 <0.2% <0.2%

Maintenance interval

NO, CO, O2 4 weeks >8 days

SO2 8 days >8 days

Zero and Span drift requirement Statement from manufacturer:


The zero point is created by purging the measuring Clause
cell with an IR-inactive gas (e.g. N2) The resulting 6.13 & 10.13
spectrum corresponds to measurement on a gas free
measurement path. The relevant measured Manufacturer
concentration values are determined by means of the shall provide a
instrument's calibration function. description of
the technique to
The span point is created by purging the measuring determine and
cell with a gas consisting of the measured component compensate for
in a concentration of 60-90% of the measuring range,
zero and span
residual gas is IR-inactive N2 (10-40%). The relevant drift.
measured concentration values are determined by
means of the instrument's calibration function.

Certificate No : Sira MC040035/07


This Certificate issued : 24 February 2019

This certificate may only be reproduced in its entirety and without change
To authenticate the validity of this certificate please visit www.csagroupuk.org/mcerts

Page 7 of 9
Form 1335
Issue 5
Test Results expressed as % of the Other results MCERTS
certification range specification
<0.5 <1 <2 <5
Change in zero point over maintenance
interval

SO2 1.6 <3.0%

NO 0.9 <3.0%

CO 0.4 <3.0%

O2 0.02 <0.2%

Change in span point over maintenance


interval

SO2 1.7 <3.0%

NO 0.7 <3.0%

CO 0.6 <3.0%

O2 0.01 <0.2%

Availability
>95%
SO2 , O2 99.3%
(>98% for O2)
CO, NO 99.7%

Reproducibility

SO2 0.2 <3.3%

NO 0.2 <3.3%

CO 0.3 <3.3%

O2 0.02 <0.20%

SO2 0.2 <3.3%

Note 1: Cross sensitivity test has been conducted with the following interferents: O 2, H2O, CO, CO2, CH4, N2O, NO, NO2,
NH3, SO2 and HCl.

Note 2: Results stated are from the laboratory test

Note 3: Test data derived from calibration function test

Certificate No : Sira MC040035/07


This Certificate issued : 24 February 2019

This certificate may only be reproduced in its entirety and without change
To authenticate the validity of this certificate please visit www.csagroupuk.org/mcerts

Page 8 of 9
Form 1335
Issue 5
Description

The ULTRAMAT / OXYMAT 6 gas analysers are based on the NDIR two-beam alternating light
principle and can be used to measure such gases as CO, CO2, NO, SO2, NH3, H2O, CH4 and other
hydrocarbons. The OXYMAT part of the system measures O2 using the paramagnetic alternating
pressure sensing method. The ULTRAMAT / OXYMAT 6 is a 19-inch multi gas analyser.

Single-channel analysers measure up to 2 gas components simultaneously. Dual-channel analysers


can measure up to 4 gas components simultaneously.

The measuring cell can be dismantled for cleaning (rather than replacement) and is alarm indicated.

Auto calibration is available. For the ULTRAMAT 6 auto or manual range changing is available over
a minimum ratio 10:1 between maximum and minimum ranges. As four measuring ranges are
available, two intermediate ranges are available between these maximum and minimum limits. For
the OXYMAT 6 auto or manual range changing between four ranges is available. Remote operation
of the range change is also possible.

One electrically isolated signal output 0-20mA or 4-20mA per component are standard and a
PROFIBUS version can be supplied as an option.

General Notes

1. This certificate is based upon the equipment tested. The Manufacturer is responsible for
ensuring that on-going production complies with the standard(s) and performance criteria
defined in this Certificate. The Manufacturer is required to maintain an approved quality
management system controlling the manufacture of the certified product. Both the product
and the quality management system shall be subject to regular surveillance according to
‘Regulations Applicable to the Holders of Sira Certificates’. The design of the product certified
is defined in the Sira Design Schedule for certificate No. Sira MC040032/01

2. If certified product is found not to comply, Sira Certification Service should be notified
immediately at the address shown on this certificate.

3. The Certification Marks that can be applied to the product or used in publicity material are
defined in ‘Regulations Applicable to the Holders of Sira Certificates’.

4. This document remains the property of Sira and shall be returned when requested by the
company.

Certificate No : Sira MC040035/07


This Certificate issued : 24 February 2019

This certificate may only be reproduced in its entirety and without change
To authenticate the validity of this certificate please visit www.csagroupuk.org/mcerts

Page 9 of 9
Form 1335
Issue 5

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