Freon ™ MO59 (R-417A) Refrigerant: Safety Data Sheet
Freon ™ MO59 (R-417A) Refrigerant: Safety Data Sheet
Freon ™ MO59 (R-417A) Refrigerant: Safety Data Sheet
SECTION 1. IDENTIFICATION
SDS-Identcode : 130000000132
Restrictions on use : For professional and industrial installation and use only.
Simple Asphyxiant
Hazard Statements : H280 Contains gas under pressure; may explode if heated.
May displace oxygen and cause rapid suffocation.
Precautionary Statements :
Storage:
P410 + P403 Protect from sunlight. Store in a well-ventilated
place.
Other hazards
Vapors are heavier than air and can cause suffocation by reducing oxygen available for breathing.
Misuse or intentional inhalation abuse may cause death without warning symptoms, due to cardi-
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SAFETY DATA SHEET
ac effects.
Rapid evaporation of the product may cause frostbite.
Components
Chemical name CAS-No. Concentration (% w/w)
1,1,1,2-Tetrafluoroethane* 811-97-2 50
Pentafluoroethane* 354-33-6 46.6
Butane 106-97-8 3.4
* Voluntarily-disclosed non-hazardous substance
General advice : In the case of accident or if you feel unwell, seek medical
advice immediately.
When symptoms persist or in all cases of doubt seek medical
advice.
In case of skin contact : Thaw frosted parts with lukewarm water. Do not rub affected
area.
Get medical attention immediately.
Protection of first-aiders : No special precautions are necessary for first aid responders.
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SAFETY DATA SHEET
Specific hazards during fire : Exposure to combustion products may be a hazard to health.
fighting If the temperature rises there is danger of the vessels bursting
due to the high vapor pressure.
Specific extinguishing meth- : Use extinguishing measures that are appropriate to local cir-
ods cumstances and the surrounding environment.
Fight fire remotely due to the risk of explosion.
Use water spray to cool unopened containers.
Remove undamaged containers from fire area if it is safe to do
so.
Evacuate area.
Technical measures : Use equipment rated for cylinder pressure. Use a backflow
preventative device in piping. Close valve after each use and
when empty.
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SAFETY DATA SHEET
Conditions for safe storage : Cylinders should be stored upright and firmly secured to
prevent falling or being knocked over.
Separate full containers from empty containers.
Do not store near combustible materials.
Avoid area where salt or other corrosive materials are present.
Keep in properly labeled containers.
Keep in a cool, well-ventilated place.
Keep away from direct sunlight.
Store in accordance with the particular national regulations.
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SAFETY DATA SHEET
Further information on stor- : The product has an indefinite shelf life when stored properly.
age stability
Hand protection
Material : Heat resistant gloves
Protective measures : Wear cold insulating gloves/ face shield/ eye protection.
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SAFETY DATA SHEET
Hygiene measures : Ensure that eye flushing systems and safety showers are
located close to the working place.
When using do not eat, drink or smoke.
Wash contaminated clothing before re-use.
Color : colorless
pH : No data available
Solubility(ies)
Water solubility : No data available
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SAFETY DATA SHEET
Viscosity
Viscosity, kinematic : Not applicable
1,1,1,2-Tetrafluoroethane:
Acute inhalation toxicity : LC50 (Rat): > 567000 ppm
Exposure time: 4 h
Test atmosphere: gas
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SAFETY DATA SHEET
Pentafluoroethane:
Acute inhalation toxicity : LC0 (Rat): > 800000 ppm
Exposure time: 4 h
Test atmosphere: gas
Method: OECD Test Guideline 403
Butane:
Acute inhalation toxicity : LC50 (Rat): 570000 ppm
Exposure time: 15 min
Test atmosphere: gas
Remarks: Based on data from similar materials
Skin corrosion/irritation
Not classified based on available information.
Components:
1,1,1,2-Tetrafluoroethane:
Species : Rabbit
Result : No skin irritation
1,1,1,2-Tetrafluoroethane:
Species : Rabbit
Result : No eye irritation
Skin sensitization
Not classified based on available information.
Respiratory sensitization
Not classified based on available information.
Components:
1,1,1,2-Tetrafluoroethane:
Routes of exposure : Skin contact
Species : Guinea pig
Result : negative
Species : Rat
Result : negative
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SAFETY DATA SHEET
1,1,1,2-Tetrafluoroethane:
Germ cell mutagenicity - : Weight of evidence does not support classification as a germ
Assessment cell mutagen.
Pentafluoroethane:
Genotoxicity in vitro : Test Type: Chromosome aberration test in vitro
Method: OECD Test Guideline 473
Result: negative
Genotoxicity in vivo : Test Type: Mammalian erythrocyte micronucleus test (in vivo
cytogenetic assay)
Species: Mouse
Application Route: inhalation (gas)
Method: OECD Test Guideline 474
Result: negative
Butane:
Genotoxicity in vitro : Test Type: Bacterial reverse mutation assay (AMES)
Method: OECD Test Guideline 471
Result: negative
Genotoxicity in vivo : Test Type: Mammalian erythrocyte micronucleus test (in vivo
cytogenetic assay)
Species: Rat
Application Route: inhalation (gas)
Method: OECD Test Guideline 474
Result: negative
Remarks: Based on data from similar materials
Carcinogenicity
Not classified based on available information.
Components:
1,1,1,2-Tetrafluoroethane:
Carcinogenicity - Assess- : Weight of evidence does not support classification as a car-
ment cinogen
IARC No ingredient of this product present at levels greater than or equal to 0.1% is
identified as probable, possible or confirmed human carcinogen by IARC.
OSHA No component of this product present at levels greater than or equal to 0.1% is
on OSHA’s list of regulated carcinogens.
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SAFETY DATA SHEET
NTP No ingredient of this product present at levels greater than or equal to 0.1% is
identified as a known or anticipated carcinogen by NTP.
Reproductive toxicity
Not classified based on available information.
Components:
1,1,1,2-Tetrafluoroethane:
Reproductive toxicity - As- : Weight of evidence does not support classification for
sessment reproductive toxicity
Pentafluoroethane:
Effects on fertility : Test Type: One-generation reproduction toxicity study
Species: Rat
Application Route: inhalation (vapor)
Result: negative
Remarks: Based on data from similar materials
Butane:
Effects on fertility : Test Type: Combined repeated dose toxicity study with the
reproduction/developmental toxicity screening test
Species: Rat
Application Route: inhalation (gas)
Method: OECD Test Guideline 422
Result: negative
Effects on fetal development : Test Type: Combined repeated dose toxicity study with the
reproduction/developmental toxicity screening test
Species: Rat
Application Route: inhalation (gas)
Method: OECD Test Guideline 422
Result: negative
STOT-single exposure
Not classified based on available information.
Components:
Butane:
Assessment : May cause drowsiness or dizziness.
Remarks : Based on data from similar materials
STOT-repeated exposure
Not classified based on available information.
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SAFETY DATA SHEET
Components:
1,1,1,2-Tetrafluoroethane:
Assessment : No significant health effects observed in animals at concentra-
tions of 250 ppmV/6h/d or less.
Components:
1,1,1,2-Tetrafluoroethane:
Species : Rat
NOAEL : 50000 ppm
LOAEL : > 50000 ppm
Application Route : inhalation (gas)
Exposure time : 90 d
Method : OECD Test Guideline 413
Remarks : No significant adverse effects were reported
Pentafluoroethane:
Species : Rat
NOAEL : >= 50000 ppm
Application Route : inhalation (gas)
Exposure time : 13 Weeks
Method : OECD Test Guideline 413
Butane:
Species : Rat
NOAEL : >= 9000 ppm
Application Route : inhalation (gas)
Exposure time : 6 Weeks
Method : OECD Test Guideline 422
Aspiration toxicity
Not classified based on available information.
Ecotoxicity
Components:
1,1,1,2-Tetrafluoroethane:
Toxicity to fish : LC50 (Oncorhynchus mykiss (rainbow trout)): 450 mg/l
Exposure time: 96 h
Toxicity to daphnia and other : EC50 (Daphnia magna (Water flea)): 980 mg/l
aquatic invertebrates Exposure time: 48 h
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SAFETY DATA SHEET
Pentafluoroethane:
Toxicity to fish : LC50 (Oncorhynchus mykiss (rainbow trout)): 450 mg/l
Exposure time: 96 h
Method: Directive 67/548/EEC, Annex V, C.1.
Remarks: Based on data from similar materials
Toxicity to daphnia and other : EC50 (Daphnia magna (Water flea)): 980 mg/l
aquatic invertebrates Exposure time: 48 h
Method: Directive 67/548/EEC, Annex V, C.2.
Remarks: Based on data from similar materials
Components:
1,1,1,2-Tetrafluoroethane:
Biodegradability : Result: Not readily biodegradable.
Pentafluoroethane:
Biodegradability : Result: Not readily biodegradable.
Biodegradation: 5 %
Exposure time: 28 d
Method: OECD Test Guideline 301D
Butane:
Biodegradability : Result: Readily biodegradable.
Remarks: Based on data from similar materials
Bioaccumulative potential
Components:
1,1,1,2-Tetrafluoroethane:
Partition coefficient: n- : log Pow: 1.06
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SAFETY DATA SHEET
octanol/water
Pentafluoroethane:
Partition coefficient: n- : Pow: 1.48 (77 °F / 25 °C)
octanol/water
Butane:
Partition coefficient: n- : log Pow: 2.89
octanol/water
Mobility in soil
No data available
Other adverse effects
Product:
Results of PBT and vPvB : This mixture contains no substance considered to be persis-
assessment tent, bioaccumulating and toxic (PBT). This mixture contains
no substance considered to be very persistent and very bio-
accumulating (vPvB).
Disposal methods
Waste from residues : Dispose of in accordance with local regulations.
International Regulations
UNRTDG
UN number : UN 1078
Proper shipping name : REFRIGERANT GAS, N.O.S.
(1,1,1,2-Tetrafluoroethane, Pentafluoroethane)
Class : 2.2
Packing group : Not assigned by regulation
Labels : 2.2
IATA-DGR
UN/ID No. : UN 1078
Proper shipping name : Refrigerant gas, n.o.s.
(1,1,1,2-Tetrafluoroethane, Pentafluoroethane)
Class : 2.2
Packing group : Not assigned by regulation
Labels : Non-flammable, non-toxic Gas
Packing instruction (cargo : 200
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SAFETY DATA SHEET
aircraft)
Packing instruction (passen- : 200
ger aircraft)
IMDG-Code
UN number : UN 1078
Proper shipping name : REFRIGERANT GAS, N.O.S.
(1,1,1,2-Tetrafluoroethane, Pentafluoroethane)
Class : 2.2
Packing group : Not assigned by regulation
Labels : 2.2
EmS Code : F-C, S-V
Marine pollutant : no
Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable for product as supplied.
Domestic regulation
49 CFR
UN/ID/NA number : UN 1078
Proper shipping name : Refrigerant gases, n.o.s.
(1,1,1,2-Tetrafluoroethane, Pentafluoroethane)
Class : 2.2
Packing group : Not assigned by regulation
Labels : NON-FLAMMABLE GAS
ERG Code : 126
Marine pollutant : no
Special precautions for user
The transport classification(s) provided herein are for informational purposes only, and solely
based upon the properties of the unpackaged material as it is described within this Safety Data
Sheet. Transportation classifications may vary by mode of transportation, package sizes, and
variations in regional or country regulations.
SARA 313 : This material does not contain any chemical components with
known CAS numbers that exceed the threshold (De Minimis)
reporting levels established by SARA Title III, Section 313.
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SAFETY DATA SHEET
US State Regulations
Further information
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Health
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PHYSICAL HAZARD
3
Freon™ and any associated logos are trademarks or copyrights of The Chemours Company FC,
LLC.
Chemours™ and the Chemours Logo are trademarks of The Chemours Company.
Before use read Chemours safety information.
For further information contact the local Chemours office or nominated distributors.
All chemical substances in this material are included on or exempted from listing on the TSCA
Inventory of Chemical Substances.
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SAFETY DATA SHEET
AICS - Australian Inventory of Chemical Substances; ASTM - American Society for the Testing of
Materials; bw - Body weight; CERCLA - Comprehensive Environmental Response, Compensation,
and Liability Act; CMR - Carcinogen, Mutagen or Reproductive Toxicant; DIN - Standard of the
German Institute for Standardisation; DOT - Department of Transportation; DSL - Domestic Sub-
stances List (Canada); ECx - Concentration associated with x% response; EHS - Extremely Haz-
ardous Substance; ELx - Loading rate associated with x% response; EmS - Emergency Schedule;
ENCS - Existing and New Chemical Substances (Japan); ErCx - Concentration associated with
x% growth rate response; ERG - Emergency Response Guide; GHS - Globally Harmonized Sys-
tem; GLP - Good Laboratory Practice; HMIS - Hazardous Materials Identification System; IARC -
International Agency for Research on Cancer; IATA - International Air Transport Association; IBC
- International Code for the Construction and Equipment of Ships carrying Dangerous Chemicals
in Bulk; IC50 - Half maximal inhibitory concentration; ICAO - International Civil Aviation Organiza-
tion; IECSC - Inventory of Existing Chemical Substances in China; IMDG - International Maritime
Dangerous Goods; IMO - International Maritime Organization; ISHL - Industrial Safety and Health
Law (Japan); ISO - International Organisation for Standardization; KECI - Korea Existing Chemi-
cals Inventory; LC50 - Lethal Concentration to 50 % of a test population; LD50 - Lethal Dose to
50% of a test population (Median Lethal Dose); MARPOL - International Convention for the Pre-
vention of Pollution from Ships; MSHA - Mine Safety and Health Administration; n.o.s. - Not Oth-
erwise Specified; NFPA - National Fire Protection Association; NO(A)EC - No Observed (Adverse)
Effect Concentration; NO(A)EL - No Observed (Adverse) Effect Level; NOELR - No Observable
Effect Loading Rate; NTP - National Toxicology Program; NZIoC - New Zealand Inventory of
Chemicals; OECD - Organization for Economic Co-operation and Development; OPPTS - Office
of Chemical Safety and Pollution Prevention; PBT - Persistent, Bioaccumulative and Toxic sub-
stance; PICCS - Philippines Inventory of Chemicals and Chemical Substances; (Q)SAR - (Quanti-
tative) Structure Activity Relationship; RCRA - Resource Conservation and Recovery Act;
REACH - Regulation (EC) No 1907/2006 of the European Parliament and of the Council concern-
ing the Registration, Evaluation, Authorisation and Restriction of Chemicals; RQ - Reportable
Quantity; SADT - Self-Accelerating Decomposition Temperature; SARA - Superfund Amend-
ments and Reauthorization Act; SDS - Safety Data Sheet; TCSI - Taiwan Chemical Substance
Inventory; TSCA - Toxic Substances Control Act (United States); UN - United Nations; UNRTDG -
United Nations Recommendations on the Transport of Dangerous Goods; vPvB - Very Persistent
and Very Bioaccumulative
Sources of key data used to : Internal technical data, data from raw material SDSs, OECD
compile the Material Safety eChem Portal search results and European Chemicals Agen-
Data Sheet cy, http://echa.europa.eu/
The information provided in this Safety Data Sheet is correct to the best of our knowledge,
information and belief at the date of its publication. The information is designed only as a
guidance for safe handling, use, processing, storage, transportation, disposal and release and
shall not be considered a warranty or quality specification of any type. The information provided
relates only to the specific material identified at the top of this SDS and may not be valid when the
SDS material is used in combination with any other materials or in any process, unless specified
in the text. Material users should review the information and recommendations in the specific
context of their intended manner of handling, use, processing and storage, including an
assessment of the appropriateness of the SDS material in the user’s end product, if applicable.
US / Z8
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