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    Chem Ass 3084357142010

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    kidane
    The document is a chemistry assignment containing 16 questions related to coordination compounds and transition metal complexes. It asks students to define terms like nanomaterials and nanotechnology, describe concepts like Werner's postulates and ligand types, write chemical formulas using IUPAC nomenclature, determine coordination numbers and oxidation states, explain properties based on crystal field theory and hybridization, calculate net magnetic moments, and discuss advantages and disadvantages of coordination compounds.

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    Chem Ass 3084357142010

    Uploaded by

    kidane
    60 views2 pages
    The document is a chemistry assignment containing 16 questions related to coordination compounds and transition metal complexes. It asks students to define terms like nanomaterials and nanotechnology, describe concepts like Werner's postulates and ligand types, write chemical formulas using IUPAC nomenclature, determine coordination numbers and oxidation states, explain properties based on crystal field theory and hybridization, calculate net magnetic moments, and discuss advantages and disadvantages of coordination compounds.

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    Chem Ass 3084357142010

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    The document is a chemistry assignment containing 16 questions related to coordination compounds and transition metal complexes. It asks students to define terms like nanomaterials and nanotechnology, describe concepts like Werner's postulates and ligand types, write chemical formulas using IUPAC nomenclature, determine coordination numbers and oxidation states, explain properties based on crystal field theory and hybridization, calculate net magnetic moments, and discuss advantages and disadvantages of coordination compounds.

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    © All Rights Reserved
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    Download as docx, pdf, or txt
    60 views2 pages

    Chem Ass 3084357142010

    Uploaded by

    kidane
    The document is a chemistry assignment containing 16 questions related to coordination compounds and transition metal complexes. It asks students to define terms like nanomaterials and nanotechnology, describe concepts like Werner's postulates and ligand types, write chemical formulas using IUPAC nomenclature, determine coordination numbers and oxidation states, explain properties based on crystal field theory and hybridization, calculate net magnetic moments, and discuss advantages and disadvantages of coordination compounds.

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    © All Rights Reserved
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    of 2

    Mekell university

    College of Natural and Computional Science


    Chemistry Department
    General Chemistry
    Assignment (15)
    1. As u are material science student define the word nano material and Nano technology?
    2. Explain the bonding in coordination compounds in terms of Werner’s postulates.
    3. What is meant by unidentate, didentate and ambidentate ligands? Give two examples for
    4. Specify the coordination numbers and oxidation number of the following coordination
    entities:
    A. [Co(H2O)(CN)(en)2]2+ B. [CoBr2(en)2]+ C. [PtCl4]2−
    B. D. K3[Fe(CN)6] E. [Cr(NH3)3Cl3]
    5. Using IUPAC norms write the formulas for the following:
    (i) Tetrahydroxozincate(II)
    (ii) Potassium tetrachloridopalladate(II)
    (iii) Diamminedichloridoplatinum(II)
    (iv) Potassium tetracyanonickelate(II)
    (vi) Dichloridobis(ethane−1,2−diamine)platinum(IV) nitrate
    (vii) Potassium tri(oxalato)chromate(III)
    (viii) Hexaammineplatinum(IV)
    (ix) Tetrabromidocuprate(II)
    5. Using IUPAC norms write the systematic names of the following:
    A. [Co(NH3)6]Cl3 B. [Pt(NH3)2Cl(NH2CH3)]Cl
    C. [Co(NH3)4Cl(NO2)]Cl D. [Co(en)3]3+ E. [Ni(NO2)2 (ONO)2(NO)2]SO4
    6.Calculate the ∆o for [Co(NH3)6]3+, then determine if it is low- or high-spin
    7. Explain why Sc+3 and Zn are not classified as transition metals
    b) Explain how transition metals can form complex ions
    d) Explain why complex ions are often coloured
    e) Explain why Cu+ is not coloured

    8. Discuss the nature of bonding (hybridization), Magnetic property and sphere of the
    following coordination entities on the basis of CFT:
    (i) [Fe(CN)6]4− (ii) [V(NH3)6] (iii) [Co(C2O4)3]3− (iv) [CoF6]3−

    9.Arrange correct order of absorption of wavelength of light in the visible region for the
    complexes [Co(NH3)6]+3, [Co(CN)6]-3 and [Co(H2O)6]+3

    10. Determine the net magnetic moment of (µ) of Mn(Cl)2 complex ion

    11. According CFA,draw the electrons arrangment of metal ions in the three coordination
    complexes and calculate the CFSE of those metal ions

    [CoF6)-3, [Fe(CN)6]-4 and [Cu(NH3)6]+

    12. For the given “d” electrons of the central metal atom/ion in tetrahedral complex ,determaine
    the electronic configuration and Δth

    Arrangement in weak field ligand Arrangement in strong field ligand


    t2 g eg CFSE t2g eg CFSE
    d4
    d5
    d6
    d7
    d8
    d9

    13. The coordination number of the complex ion in the compound K[CrenCl2Br2] is

    14. If [Co(SCN)2(Cl)2]-1 complex have 8.30x10-19 J. So determine the wave length of [Co(en)2]+3
    complex at which absorbs light.

    15. Determine the net magnetic moment of Cerium (Ce) having [Xe]4F56d16S2 electron
    configuration.
    16.Write down at least three advantage and drawback of coordination compounds

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