MSDS Teg

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MATERIAL SAFETY DATA SHEET

1. CHEMICAL PRODUCT AND COMPANY INFORMATION

Product Code and Name : TEG TRIETHYLENE GLYCOL


Chemical Family : Glycol

Synonym : Triglycol

COMPANY INFORMATION

Manufacturer Name : PT. POLYCHEM INDONESIA Tbk


Head Office : JL. DAAN MOGOT KM.21 – DESA PORIS PLAWAD, KEC. CIPONDOH
TANGERANG 15122 – BANTEN INDONESIA
Factory : Desa Mangunreja, Jl. Bojonegara Kec. Pulo Ampel, Kab. Serang,
Banten - INDONESIA
Office Telephone : + 62 (021) 5512896 (Hunting); Fax : (021) 5510599 - 5510991
Factory Telephone : + 62 (0254) 5750055 (Emergency Call); Fax : (0254) 5750059

2. COMPOSITION/INFORMATION ON INGREDIENTS

COMPOSITION :

Name : Triethylene Glycol

CAS # : 112 – 27 – 6

% by weight : 99 – 99.80

3. HAZARD IDENTIFICATION

EMERGENCY OVERVIEW

Appearance : Colorless Liquid

Odor : Mild Odor

WARNING STATEMENT

WARNING : HARMFUL IF SWALLOWED


CAN CAUSE LIVER AND KIDNEY DAMAGE IF SWALLOWED
MAY CAUSE DIZZINESS AND DROWSINESS

THIS PRODUT IS NOT TO BE USED IN FOOD, DRUG, COSMETIC OR


POTABLE WATER APPLICATIONS
Flammability

Hazrdous Material 1 National Fire 1


Information System Fire 1 Protection Association
(United Sates) Health 1 0 Reactivity
Reactivity 0 NFPA (United States)
Personal Protection J
Specific Danger

POTENTIAL HEALTH EFFECTS :

Primary Route of Exposure

EYE X Skin X Inhalation X Ingestion

Effects of Overexposure

Acute :

Eyes May cause irritation, experienced as temporary discomport.

Skin Brief contact is not irritating. Prolonged contact, as with clothing


wetted material, may cause defatting of skin or irritation, seen as
local redness possible mild dicomport. Other than the potential
skin irritation effects noted above, acute (short terms) adverse
effects are not expected from brief skin contact.

Inhalation Vapors or mist, in excess of permissible concentrations, or


unusually high concentrations generated from spraying, heating
the material or as from exposure in poorly ventilated areas or
confined spaces, may cause irritation of the nose and throat,
headache, nausea and drowsiness. Inhalation may cause
dizziness, drowsiness, euphoria, loss of coordination,
disorientation, headache, nausea and vomiting. In poorly
ventilated areas or confined spaces, unconsciousness and
asphyxiation may result. Prolonged or repeated overexposure may
result in the absorption of potentially harmful amounts of material.

Ingestion Contains ethylene glycol, which are toxic when swallowed. A lethal
dose for an adult is 1 – 2 ml per kilogram, or about 4 ounces
(one-half cup). Symptoms include headache, weakness, confusion,
dizziness, staggering, slurred speech, loss of coordination,
faintness, nausea and vomiting, increased heart rate, decreased
blood pressure, difficulty breathing and seeing, pulmonary edema,
unconsciousness, convulsion, collapse, and coma. Symptoms may
be delayed. Decreased urine output and kidney failure may also
occur. Severe poisoning may cause death.

Sensitization Properties Unknown


4. FIRST AID MEASURES

EYES :

Flush eyes with plenty of water for several minutes. Get medical attention if eye irritation
develops or persists.

SKIN :

Wash skin with plenty of soap and water for several minutes. Get medical attention if skin
irritation develops or persists.

INHALATION :

If inhaled, remove to fresh air. If not breathing, clear person's airway and give artificial
respiration. If breathing is difficult, qualified medical personnel may administer oxygen. Get
medical attention immediately.

5. FIRE FIGHTING MEASURES

Flammability : Combustible at high temperature.

Auto – Ignition Temperature : 371 °C

Flash Point : CLOSED CUP : 177 °C, OPEN CUP : 165.5 °C

Flammable Limits : LOWER : 0.9 %


UPPER : 9.2 %

Recommended Fire Extinguishing Agents :

Use water spray, foam, dry chemical or Carbon Dioxide to extinguish flames. Use water
spray to cool fire exposed containers.

Unusual or Explosive Hazards : None

Protective Equipment for Fire Fighters :

Wear full protective clothing and breathing apparatus. Approach fire from upwind to avoid
hazardous vapors and toxic decomposition products.

6. ACCIDENTIAL REALEASE MEASURES

Ventilate area. Avoid breathing vapor. Wear appropriate personal protective equipment,
including appropriate respiratory protection. Contain spill if possible. Wipe up or absorb on
suitable material and shovel up. Prevent entry into sewers and waterways. Avoid contact
with skin, eyes or clothing.
7. HANDLING AND STORAGE

HANDLING :
Minimum feasible handling temperatures should be maintained.

STORAGE :
Periods of exposure to high temperatures should be minimized. Water contamination should
be avoided.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Measures :

Provide exhaust ventilation to keep airborne concentration of vapors below the threshold
limit value. Ensure that eyewash and safety showers are near the work stations.

Eye/Face Protection :
Safety glasses, chemical type goggles, or face shield recommended to prevent eye contact.

Skin Protection :
Workers should wash exposed skin several times daily soap and water. Soiled work clothing
should be laundered or dry-cleaned.

Respiratory Protection :
Airborne concentrations should be kept to lowest levels possible. If vapor, mist or dust is
generated and the occupational exposure limit of the product, or any component of the
product, is exceeded, use appropriate NIOSH or MSHA approved air purifying or air supplied
respirator after determining the airborne concentration of the contaminant. Air supplied
respirators should always be worn when airborne concentration of the contaminant or
oxygen content is unknown.

Ventilation :
Local exhaust ventilation recommended if generating vapor, dust, or mist. If exhaust
ventilation is not available or inadequate, use MSHA or NIOSH approved respiratory as
appropriate.

Exposure Limit for the Total Product :


None established for product.

9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance : Colorless Liquid

Odor : Mild odor

Boiling Point (°C) : 287.8 (550 F)


Melting/Freezing Point (°C) : - 7.2 (19 F)

Specify Gravity (water = 1 ) : 1.1255

pH (50% aq) : 5.5 – 8.0

Vapor Pressure : < .1 mmHg at 20 °C (68 F)

Viscosity : 43 cST at 20 °C (68 F)

VOC Content : 6% by ASTM D 2369

Vapor Density (Air =1) : 5.1

Solubility in Water : Easily Soluble in Water

Other : None

10. STABILITY AND REACTIVITY

Stability :

This product is stable.


Does not react violently with Air, Water, Strong Oxidizing, Others.

Hazardous Polymerization
DOES NOT OCCUR
Product evolved when subject to Heat or Combustion :
Toxic levels of carbon Monoxide, Carbon Dioxide, Aldehyde and Ketones.

11. TOXICOLOGY INFORMATION

Toxicological Information (Animal Toxicity Data)

Oral : Animal data does not reflect human toxicity


Inhalation : Not determined
Dermal : LD50 believed to be > 2.00 g/kg (rabbit) practically non toxic

IRRITATION INDEX, ESTIMATION OR IRRITATION (SPECIES)

Skin : (Draize) believed to be < .50/8.0 (rabbit) no appreciable effect.


Eyes : (Draize) believed to be 15.00/110 (rabbit) no appreciable effect.
Sensitization : Not Determined
12. ECOLOGICAL INFORMATION :

Aquatic Toxicity : Not determined.

Mobility : Not determined.

Persistence and Biodegradability : Not determined.

Potential Bioaccumulate : Not determined.

Remarks : None

13. DISPOSAL CONSIDERATIONS :

Waste Disposal Methods :


This product has been evaluated for RCRA characteristics and does not meet the criteria of a
hazardous waste if discarded in its purchased form. Uder RCRA, it is the responsibility of the
user of the product to determine at the time of disposal, whether the product meets RCRA
criteria for hazardous waste. This is because product uses, transformations, mixtures,
processes, etc. may render the result materials hazardous.

Remarks : None

14. TRANSPORT INFORMATION

Not classified as dangerous in the meaning of transport regulations through road


and sea.

15. REGULATORY INFORMATION

OSHA : Hazardous by definition of Hazard Communication standard.

DSCL (EEC) : R 41 – Risk of damage to eyes

HMIS (USA) :

Health Hazard 1
Fire Hazards 1
Reactivity 0
Personal Protection 1

NATIONAL FIRE PROTECTION ASSOCIATION

Health 1
Flammability 1
Reactivity 0
16. OTHER INFORMATION

Due to toxicity considerations with this glycol, the following applications are considered to
be prohibited applications. Potable Water Applications ; Food, Drug and Cosmetic
Formulation; Antifreeze for potable water systems in recreational vehicle and seasonal
homes; Antifreeze for fire systems.

The information above is believed to be accurate and represent the best information
currently available to us. However, we make no warranty of merchantability or any other
warranty, express or implied, with respect to such information and we assume no liability
resulting from its use. Users should make their own investigations to determine the
suitability of the information for their particular purposes. In no event shall Polychem
Indonesia Tbk be liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary damages, howsoever
arising, even if PT. Polychem Indonesia Tbk has been advised of the possibility of such
damages.

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