A Review of Organosilanes

in Organic Chemistry
• Silyl Protecting and Derivatisation Reagents
• Organosilanes as Reducing Agents
• Silanes in Cross-coupling Chemistry
• Allylsilanes Used to Stabilize α-Carbanions and β-Carbocations
Introduction
Organosilanes have varied uses in organic chemistry from the most frequently employed protecting groups to intermediates in
organic synthesis. The Acros Organics portfolio of organosilanes is continuously expanding to meet your chemistry needs. In this
brochure you will find an overview of four of the most important applications of organosilanes:

• Silyl Protecting and Derivatisation Reagents 1, 2

• Organosilanes as Reducing Agents 3
• Silanes in Cross-coupling Chemistry 4
• Allylsilanes Used to Stabilize α-Carbanions and β-Carbocations4

Silyl Protecting and Derivatisation Reagents

Silicon protecting groups are probably the most frequently employed of all protecting groups, and modern natural product synthesis
is inconceivable without them.5 Silylating agents are mostly used to protect alcohols and phenols, but have also found application in
the protection of amines, carboxylic acids, amides, thiols and alkynes.

By varying the substituents attached to silicon, the steric and electronic characteristics of the protecting group can be finely tuned,
allowing a wide variety of both reaction and deprotection conditions. The leaving group also plays an important role in the reactivity
and use of silylating reagents. Whilst chlorotrimethylsilane [product code: 42643] liberates hydrogen chloride on reaction, other
TMS protection reagents liberate neutral or basic by-products. For example, N,N-Diethyl-1,1,1-trimethylsilylamine [15569] is a
moderately strong silylating reagent liberating volatile diethylamine, while allyltrimethylsilane [19699], used to protects acids and
thiols, generates gaseous propene as a by-product.6

The high affinity of silicon for fluorine is particularly advantageous, permitting deprotection of the silyl group with tetrabutylammonium
fluoride [20195], a reagent that is compatible with a wide range of orthogonal protecting groups and other functional groups. The
actual stability of a silyl protecting group depends on the pH of the medium, the exact reaction conditions, steric and electronic
effects but, in general terms, the stability to hydrolysis increases:7

Acidic hydrolysis: Basic hydrolysis:

Me3Si< Ph2MeSi < Et3Si < tBuMe2Si < iPr3Si < tBuPh2Si Me3Si ~ Ph2MeSi < Et3Si < tBuMe2Si ~ tBuPh2Si < iPr3Si

Acros Organics have recently introduced a range of commonly used silyl chlorides (shown in the table on page 3) in AcroSeal®
packaging, allowing easy handling and excellent stability of these moisture-sensitive protecting reagents.

The Acros Organics range includes many synthetic intermediates with silyl protection already in place. A selection of typical
products is illustrated here. For more examples, see the product list at the end of this brochure or visit www.acros.com.
O O
Br O
HO H Si
HO N B N
Si Si
OH Si O
O

[33784] [43024] [42817] [43869] [43869]

[33784] [43024] [42817]

References
1. Greene, T.; Wuts, P.; “Protecting Groups in Organic Synthesis”, 2nd Ed., Wiley, New York, 1991.
2. Blau, K.; Halket, J.; “Handbook of Derivatives for Chromatography”, 2nd Ed., J. Wiley and Sons, New York, 1993.
3. Chatgilialoglu, C.; Acc. Chem. Res., 1992, 25, 188.
4. Coats, R. M.; Denmark, S.; “Handbook of Reagents for Organic Synthesis. Reagents, Auxillaries and Catalysts for C-C Bond Formation”;
J. Wiley and Sons, GB, 1999.
5. Kocienski; P. J.; “Protecting Groups”, 3rd Ed., Thieme: Stuttgart, 1994.
6. Morita, T. et al.; Tetrahedron Lett., 1983, 21, 835.
7. Nelson, T. D.; Crouch, R. D.; Synthesis, 1996, 1031.

2
A selection of Organochlorosilane Protecting Group Reagents available from the AcroSeal ® range:
Group Reagent Code Notes
Chlorotrimethylsilane 42643 Used for the protection of alcohols, alkynes,
amines and amino acids, carboxylic acids,
Me3Si (TMS) Chlorotrimethylsilane, 1M solution in THF 38161
phenols, ketones. Most easily cleaved of all silyl
Chlorotrimethylsilane, 1M solution in DCM 38160 protecting groups in acid and base.
Used for the protection of alcohols. TES ethers
Et3Si (TES) Chlorotriethylsilane, 1M solution in THF 43325 can be selectively deprotected in the presence of
TBDMS ethers8.
tert-Butyldimethylsilyl chloride, 1.0M in DCM 36910 Used for the protection of alcohols, amines, thiols,
lactams and carboxylic acids. Reaction with an
t
BuMe2Si alcohol requires a catalyst such as imidazole.
tert-Butyldimethylsilyl chloride, 50 wt.% in PhMe 43311
(TBDMS) [20094] is a convenient, ready-to-use DMF
solution of TBDMSCl (0.5M) and imidazole
BDCS, silylation reagent 20094 (1.0M).
Greater steric demand. Therefore, more stable
t
BuPh2Si than TBDMS to acid hydrolysis (>100x).
tert-Butylchlorodiphenylsilane 43092
(TBDPS) Primary alcohols are protected in the presence of
secondary alcohols.
Used for the protection of diols, diamines and
Ph2Si Dichlorophenylsilane 43089
hydroxyacids.9

Derivatisation of a compound by reaction with a silylating agent is of particular utility in gas chromatography (GC) analysis.
Molecules containing functional groups such as carboxylic acid, hydroxyl, amine, thiol and phosphate, which may be difficult to
analyse by GC, can be readily converted into silylated derivatives that are generally less polar, more volatile and have greater thermal
stability and are, therefore, more suitable for GC analysis.

Typical Derivatisation Reagents from Acros Organics

Derivatisation Reagent Code Structure Notes
Si
O Commonly used derivatisation agents for acidic
functional groups; i.e., alcohols, enols, amines, amides,
N,O-Bis(trimethylsilyl)acetamide 15646
N carboxylic acids, amino acids, phenols, steroids,
Si biogenic amines, alkaloids, phosphites and thiols.2, 10

One of the most potent silylation reagents used today.

N,O-Bis(trimethylsilyl)trifluoroacetamide 16800 It has two advantages over BSA in GC analysis:
Si i) The by-products and the reagent itself are highly volatile
O so they cause minimal interference with the GC analysis.
N,O-Bis(trimethylsilyl)trifluoroacetamide,
38932 F ii) The presence of fluorine atoms results in less
with 1% TMSCl N
F fouling of flame-ionisation detectors.
F Si
[38932] contains 1% TMSCl, which increases
N,O-Bis(trimethylsilyl)trifluoroacetamide, packaged
32120 the silylating power of the mixture for analytical
in 1 ml ampoules
derivatisations.
O
F MSTFA and its by-product are even more volatile than
N-Methyl-N-(trimethylsilyl)trifluoroacetamide Si
22158 N BSTFA and its by-product. Used in the analysis of
(MSTFA) F
F steroids11, fatty acids12 and nucleic acids by GC/MS.

Dichloromethylsilane Cl
Used for derivatisation of diols, diamines and
43088 Si Cl
AcroSeal® hydroyxacids.

References
8. Toshima et al.; Tetrahedron Lett. 1989, 30, 6413.
9. Barlos, K. et al.; J. Org. Chem., 1982, 47, 1324.
10. Knapp, D. R.; “Handbook of Analytical Derivatization Reactions” John Wiley & Sons, New York, 1979.
11. Donike, M.; Zimmermann, J.; J. Chromatogr., 1980, 202, 483.
12. Blum, W.; J. High Res. Chromatogr., Chromatogr. Commun., 1985, 718 & 1986, 350.

3
Organosilanes as Reducing Agents
Organosilanes with one or more hydrogen atoms attached to silicon have the ability to behave as either ionic or free-radical reducing
agents. Changing the groups attached to silicon modifies the character of the Si-H bond and allows the organosilane reagent to be tailored
to give a particular type of reduction. Substrates that can form a stable carbenium ion intermediate such as alcohols, olefins, esters, lactones,
aldehydes, ketones, acetals, ketals and imines are reduced with reagents like triethylsilane [21292], which is used in combination with an acid.
Triphenylsilane [16482] and tris(trimethylsilyl)silane [29106] are used for free radical reductions, in place of tri-n-butyltin hydride.13 The
breadth of reductions possible with organosilanes is illustrated below. These organosilanes and the reduction by-products are generally safer
and more easily handled and disposed of than traditional reducing agents such as lithium aluminium hydride and tributyltin hydride.

The ease of reduction of various functional groups with silyl hydrides, available from Acros Organics
Silyl hydride Cl3SiH Et3SiH Ph3SiH Ph2SiH2 PhSiH3 TMS3SiH PMHS(a)
Acros Organics Code 17460 21292 16482 32977 29169 29106 17509
++ ++ +
+ ++ +
+ ++ ++
++
++ + + +
++ ++ +
++

( ++ ++
+ ++ +
++
+ +
+
+ + ++ +
(a)
Polymethylhydrosiloxane, a high molecular weight reducing agent

Hydrosilylation
Alkynes, alkenes and ketones undergo free radical hydrosilylation with silyl hydrides. The regio- and stereocontrol is dependant upon
the substrate substituents, the organosilane and the particular catalyst used. For example, α-vinylsilanes have been prepared in high
yield by reaction of triethoxysilane [16481] with a range of terminal alkynes in the presence of [CpRu(MeCN)3]PF6 [37789].14

OTBDPS
OTBDPS
Si(OEt) 3
OTBDPS (EtO)3SiH [16481]

[CpRu(MeCN)3]PF6[37789] Si(OEt) 3
0°C to r.t, 1 h, DCM
20 : 1 (87% yield)
α β

References
13. Burke, S. D.; Danheiser. R.; “Handbook of Reagents for Organic Synthesis - Oxidising and Reducing Reagents” John Wiley and Sons Ltd., 1999.
14. Trost, Barry M.; Ball, Zachary T. ; J. Am. Chem. Soc., 2005, 127, 17644.

4
Silanes in Cross-coupling Chemistry
Many metal-catalysed coupling methods have been developed for the formation of carbon-carbon bonds, utilising a range of
organometallic species. Examples include Stille (Sn), Kumada (Mg), Suzuki (B) and Negishi (Zn) coupling. For an overview of these
methodologies, the Acros Organics “Palladium Catalysed Coupling Chemistry” brochure is available at www.acros.com.

The Hiyama coupling is typically a palladium- or nickel-catalysed coupling of organohalides or triflates with organosilanes.15 The
use of organosilanes in place of organometallic reagents (Mg, Zn and Sn) is often advantageous due to their low toxicity, chemical
stability and ease of handling.

The coupling reaction is promoted by activation of the organosilane with a fluoride source, converting the silicon compound RSiR’3
to a RSi-R’3F intermediate that is more amenable to transmetalation. Alternatively, a strong base can be used. Many organosilicon
compounds can undergo coupling reactions, including dialkylsilanols16 and trialkoxysilanes.
R
R OH
Si
R2-X
R1
dialkylsilanols R2-R1

R Pd(0) catalyst
O where R= normally Me or Et
O O Fluoride source R1= Aryl, alkenyl, alkynyl, allyl, (alkyl)
R Si R or base R2 = aryl, alkenyl, allyl
R1
trialkoxysilanes

Trialkoxysilanes
Trimethoxy and triethoxysilanes are readily prepared from an organometallic species17, 18 by reaction with tetramethyl
orthosilicate [20382] and tetraethylorthosilicate [42036] or by transition metal-catalysed silylation19 with triethoxysilane [16481].
Organotrimethoxysilanes have been successfully applied as coupling reagents in the Hiyama coupling reaction with aryl chlorides
and bromides, vinyl halides, aryl triflates, and allylic benzoates.20, 21, 22
3 mol % Pd(OAc)2
OMe 3 mol % IPrHCl
Si 2 eq. TBAF in R2
+ X R2
THF/dioxane
OMe OMe or
i) Mg
R1 {[(t-Bu)2P(OH)(t-Bu)2PO)]PdCl}2 R1
ii) Si(OR)4
X= Cl, Br TBAF, THF/MeCN
X Si(OR)3
or
i) Rh or Pd catalyst R1 OEt
R1 10 mol % Pd2(dba)
ii) (RO)3Si H +
X= Br, I Si
TBAF, THF
OBz OEt OEt
R1
R1

References
15. Hatanaka, Y.; Hiyama, T.; J. Org. Chem., 1988; 53, 918.
16. Denmark, S. E.; Regens, C. S.; Acc. Chem. Res., 2008, 41, 1486-1499.
17. Murata, Miki; Shimazaki, Ryuta; Watanabe, Shinji; Masuda, Yuzuru.; Synthesis, 2001, 15, 2231.
18. Manoso, Amy S.; Ahn, Chuljin; Soheili, Arash; Handy, Christopher J.; Correia, Reuben; Seganish, W. Michael; DeShong, Philip; J. Org. Chem,
2004, 69, 8305.
19. Manoso, Amy S.; DeShong, Philip; J. Org. Chem, 2001, 66, 7449.
20. Lee, Hon Man; Nolan, Steven P.; Org. Lett., 2000, 2, 2053.
21. Wolf, Christian; Lerebours, Rachel; Tanzini, Elizabeth H.; Synthesis, 2003, 13, 2069.
22. Correia, Reuben; DeShong, Philip; J. Org. Chem, 2001, 66, 7159.

5
Recently, an efficient Hiyama coupling reaction between benzylic halides and aryltrialkoxysilanes using Pd nanoparticles has been
developed, accommodating many functional groups and leading to the synthesis of a diverse range of diarylmethanes in high yield.23
No expensive ligands are required to generate the catalyst, which is prepared by stirring K2PdCl4 [19512] with PEG-600 [19224] for
15 minutes at 70oC. PEG acts as both a stabilizing and reducing agent.

X
R1 K2PdCl4 PEG-600 R1
+ Si(OR)3
or or
TBAF in THF, 70°C R2
R2

R1 R1
X

X= Cl, Br, OTs R= Me, Et

R2

Styrenes have been prepared in high yield by reaction of vinyltrimethoxylsilane [43306], triethoxyvinylsilane [17461] and vinyl
tris(2-methoxyethoxy)silane [25051] with aryl halides in aqueous sodium hydroxide, under conventional or microwave heating.
Ligandless Pd(OAc)2 [19518] acts as an efficient source of Pd nanoparticles at low loading (0.1 mol % Pd).24

Si(OR)3
R X R

Pd(OAc)2, NaOH, water

X= Br, I heat or MW
Yields 70-98%
R= MeCO, MeO, Bn, Cl,

Dimethylsilanols
Aryl and alkenyl dimethylsilanols can be easily synthesised by direct metallation of heterocycles or by metal-halogen exchange of aryl
or alkenyl halides, followed by quenching with hexamethylcyclotrisiloxane [21646] or dichlorodimethylsilane [11331]. Denmark et
al.25 have developed methodology to allow the efficient cross coupling of hetroaryldimethylsilanols with aryl iodides in the presence
of Pd2(dba)3.CHCl3[36934]. Cross coupling of Boc-protected dimethyl(2-indolyl)silanol is particularly difficult due to decreased
nucleophilicity at C-2. They found that silanolates generated in-situ from NaOtBu undergo Pd-catalysed cross coupling with aryl
iodides in the presence of CuI, while silanolates generated with NaH couple without an additive. The methodology was extended to
thiophene, furan and pyrrole nucleophiles with both electron-deficient and electron-rich aryl iodides.

I R

i) LDA, Me2SiCl2, THF, 0°C, 18h OH

Si
N ii) sat. NaHCO3 R N
N Me Me
boc 71% boc NaH or NaOtBu /CuI boc
R
i) n-BuLi, Et2O, reflux, 5h Pd2(dba)3.CHCl3 (5 mol %)
OH toluene
N Si
ii)
Si N
Me
O O
N Me Me
57% Me Me
Si Si
O
Yields 70-85%

References
23. Srimani, Dipankar; Bej, Ansuman; Sarkar, Amitabha; J. Org. Chem, 2010, 75, 4296.
24. Alacid, Emilio; Najera, Carmen; J. Org. Chem, 2008, 73, 2315.
25. Denmark, Scott E.; Baird, John D.; Regens, Christopher S.; J. Org. Chem, 2008, 73, 1440.

6
Allylsilanes Used to Stabilize α-Carbanions
and β-Carbocations
Silicon, being more electropositive than carbon, exerts a considerable electronic effect on carbons α and β to it in an organic molecule.
Silanes that are activated in the α position can form stabilised carbanions, enhancing their reactivity to metallation, and subsequent
reaction with an electrophile. Stabilisation of a carbocation on the β carbon allows electrophilic substitution in vinyl, aryl, allyl or
alkynyl silanes, with the silyl group acting as a leaving group.

Allylsilanes are useful intermediates in

(-)
organic synthesis as the silicon is capable E Si
Me E+ Me BuLi
Si
Me E+ Me
Si E Si
E + Me Me
of stabilising both α-anionic charges and Elimination
Me Me
Me
Me Me
Me

β-cationic charges.26 stabilised -cation

stabilised -anion

Simple allylsilanes are made directly by Me

i) Mg
silylation of a metal allyl species, but Me
Si
other approaches are used to construct Br ii) Me3SiCl
Me
[30741]
more complex systems.

In the synthesis of the tricyclic core of

neoliacinic acid,27 the allylsilane (A) was O OH
required for the introduction of the side i) TIPS-Cl [22126] Me TESO Me
R' Si Me HO OTIPS
HO O TIPSO
chain. Treatment of the ester [43618] with Me
Me ii) Me Me Me Si Me H
an organocerium reagent, generated by Si MgCl Me Me O
[43618] Me Me TESO
reaction of trimethylsilylmethylmagnesium [37746] H H
O
Peterson
chloride [37746] with anhydrous cerium CeCl3, THF, -78oC SiO2 Elimination
OH O
(III) chloride, resulted in a double Grignard Me
addition of TMSCH2δ-. After workup, Me Tricyclic core
Si
TIPSO Me of
exposure of the tertiary alcohol to silica neoliacinic acid
Me (A)
gel facilitated the Peterson elimination,
providing the required allylsilane with
predictable regiochemistry.
Me Me OEt
Allylsilanes react regiospecifically Et O OEt
Me TMSOTf
with a variety of electrophiles in the +
Me DCM, -75°C
presence of a suitable Lewis acid to give Si
Me 3hours
allylic products. The TMSOTf [20944]- Me Me OEt
catalysed reaction of (3-methylcyclohex- Electrophilic Elimination
addition
1-enylmethyl)trimethylsilane [33904]
SiMe 3
with 1,1-diethoxyethane [10222] gives +
racemic allylic product in 79% yield. 28 -silyl cation

References
26. Thomas, S. E.; ‘Organic Synthesis. The Roles of Boron and Silicon.’ Oxford Uni. Press, 1991.
27. Clark, J. S.; Baxter, C. A., Dossetter, A.; Poigny, S.; Castro, J. L.; Whittingham, W. G.; J. Org. Chem., 2008, 73, 1040.
28. Polla, M; Frejd, T.; Acta Chemica Scandinavica, 1993, 47, 716.

7
Selected Acros Organics Organosilanes
Product Name Product Code CASNo Purity
Allyl(chloromethyl)dimethylsilane sum of isomers 394630010, 1 g; 394630050, 5 g 75422-66-1 90%
Allyldichloromethylsilane 338190250, 25 mL 1873-92-3 97%
Allyl(diisopropyl)(4-methoxyphenyl)silane MO01086DA, 1 g 216107-40-3 95%
Allyltrichlorosilane 313220050, 5 g; 313220250, 25 g 107-37-9 95%
Allyltrimethoxysilane 388940050, 5 mL; 388940250, 25 mL 2551-83-9 97+%
Allyltrimethylsilane 196990100, 10 mL; 196990500, 50 mL; 196992500, 250 mL 762-72-1 99%
Allyltrimethylsilane 349990100, 10 mL; 349990500, 50 mL 762-72-1 97%
3-[2-(2-Aminoethylamino)ethylamino]propyl-trimethoxysilane tech. 346170250, 25 mL; 346171000, 100 mL; 346175000, 500 mL 35141-30-1
3-Aminopropyldimethylmethoxysilane 336600010, 1 g; 336600050, 5 g 31024-26-7 97%
151080050, 5 g; 151081000, 100 g; 151085000, 500 g;
3-Aminopropyltriethoxysilane 919-30-2 99%
151080025, 2.5 kg
3-Aminopropyltriethoxysilane AcroSeal® 430941000, 100 mL; 430948000, 800 mL 919-30-2 99%
3-Aminopropyltrimethoxysilane 313251000, 100 mL; 313255000, 500 mL 13822-56-5 95%
Azidotrimethylsilane 167930100, 10 mL; 167930500, 50 mL; 167932500, 250 mL 4648-54-8 97%
BDCS silylation reagent, AcroSeal® 200941000, 100 mL; 200948000, 800 mL 1185092-02-7
N-Benzyl-3-(tert-butyldimethylsilanyloxymethyl)piperid-4-one MO07912DA, 1 g; MO07912DE, 5 g 325486-37-1 95%
Benzyloxytrimethylsilane 391990050, 5 g; 391990250, 25 g; 391991000, 100 g 14642-79-6 94%
1,2-Bis(chlorodimethylsilyl)ethane 313260050, 5 g; 313260250, 25 g 13528-93-3 96%
Bis(1H-inden-1-yl)dimethylsilane 388480010, 1 g; 388480050, 5 g 18666-26-7 97%
Bis(2,3,4,5-tetramethyl-2,4-cyclopentadiene-1-yl)dimethylsilane 388901000, 100 mg; 388905000, 500 mg 89597-05-7 95+%
1,1-Bis(trichlorosilylmethyl)ethylene 338650010, 1 g; 338650050, 5 g 78948-04-6
N,O-Bis(trimethylsilyl)acetamide 156460250, 25 mL; 156461000, 100 mL; 156460011, 1 L 10416-59-8 95%
Bis(trimethylsilyl)acetylene 182010100, 10 g; 182010500, 50 g 14630-40-1 99%
Bis(trimethylsilyl)-N-tert-butylacetaldimine 330960010, 1 g 127896-07-5 95+%
alpha,alpha-Bis(trimethylsilyl)-tert-butylketimine 331165000, 500 mg 147227-26-7
Bis(trimethylsilyl)carbodiimide 375130010, 1 g; 375130050, 5 g; 375130250, 25 g 1000-70-0 98%
1,4-Bis[(trimethylsilyl)ethynyl]benzene 390620010, 1 g; 390620050, 5 g 17938-13-5 98%
N,O-Bis(trimethylsilyl)hydroxylamine 215980010, 1 g; 215980050, 5 g; 215980250, 25 g 22737-37-7 97%
Bis(trimethylsilyl) malonate 313300100, 10 g; 313300500, 50 g 18457-04-0 98%
1,1-Bis(trimethylsilyloxy)-1,3-butadiene 331050010, 1 g 87121-06-0
1,1-Bis(trimethylsilyloxy)-3,3-dimethyl-1-butene 331025000, 500 mg 31469-23-5
1,2-Bis(trimethylsilyloxy)ethane 209580100, 10 g; 209580500, 50 g 7381-30-8 98%
beta,beta-Bis(trimethylsilyloxy)styrene 330950010, 1 g 31491-21-1
Bis(trimethylsilyl)sulfide 367370010, 1 g; 367370050, 5 g; 367370250, 25 g 3385-94-2 95%
Bis(trimethylsilyl)telluride 291660050, 5 mL 4551-16-0 98%
168000050, 5 g; 168000250, 25 g; 168001000, 100 g;
N,O-Bis(trimethylsilyl)trifluoroacetamide 25561-30-2 98+%
168005000, 500 g
N,O-Bis(trimethylsilyl)trifluoroacetamide packaged in 1 ml ampoules 321200100, 10 mL 25561-30-2 98%
N,O-Bis(trimethylsilyl)trifluoroacetamide with 1% trimethylsilyl
389320250, 25 g; 389321000, 100 g; 389325000, 500 g 25561-30-2
chloride
N-BOC-2-trimethylsilylindole 390330010, 1 g; 390330050, 5 g 146337-49-7 97+%
(2-Bromoethoxy)-tert-butyldimethylsilane 399830010, 1 g; 399830100, 10 g 86864-60-0 99%
(Bromomethyl)chlorodimethylsilane 313320050, 5 g; 313320250, 25 g 16532-02-8 95%
(4-Bromophenoxy)-tert-butyldimethylsilane 427090050, 5 mL; 427090250, 25 mL 67963-68-2 97%

8
Product Name Product Code CASNo Purity
(3-Bromophenoxy)triisopropylsilane MO07899DA, 1 g 571202-87-4 97%
(3-Bromopropoxy)-tert-butyldimethylsilane stabilized over sodium
438690010, 1 mL; 438690050, 5 mL; 438690250, 25 mL 89031-84-5 97%
carbonate
Bromotriethylsilane 440280050, 5 mL; 440280250, 25 mL 1112-48-7 95%
4-Bromo-1-(triisopropylsilyl)-1H-indole CC39510CB, 250 mg; CC39510DA, 1 g; CC39510DE, 5 g 412048-44-3 97%
5-Bromo-1-(triisopropylsilyl)-1H-indole MO00980DA, 1 g; MO00980EA, 10 g 128564-66-9 97%
186650050, 5 g; 186650250, 25 g; 186651000, 100 g;
Bromotrimethylsilane 2857-97-8 98%
186655000, 500 g
Bromotrimethylsilane AcroSeal® 430751000, 100 mL 2857-97-8 98%
183930050, 5 g; 183930250, 25 g; 183931000, 100 g;
tert-Butylchlorodimethylsilane 18162-48-6 98%
183935000, 500 g
tert-Butylchlorodimethylsilane 1.0M solution in dichloromethane,
369101000, 100 mL 18162-48-6
AcroSeal®
tert-Butylchlorodiphenylsilane 187500100, 10 g; 187500500, 50 g; 187502500, 250 g 58479-61-1 98%
tert-Butylchlorodiphenylsilane AcroSeal ®
430921000, 100 mL 58479-61-1 98%
n-Butyldimethylchlorosilane 432260100, 10 mL; 432260500, 50 mL 1000-50-6 97+%
(tert-Butyldimethylsiloxy)acetaldehyde 397510010, 1 g; 397510050, 5 g 102191-92-4 90%
(tert-Butyldimethylsilyl)acetylene 381300010, 1 g; 381300050, 5 g 86318-61-8 97%
(4R)-N-(tert-Butyldimethylsilyl)azetidin-2-one-4-carboxylic acid 337840010, 1 g; 337840050, 5 g 162856-35-1 99%
(4S)-N-(tert-Butyldimethylsilyl)azetidin-2-one-4-carboxylic acid 337862500, 250 mg; 337860010, 1 g 82938-50-9 99%
tert-Butyldimethylsilyl chloride 50 wt.% solution in toluene,
433111000, 100 mL 18162-48-6
AcroSeal®
1-(tert-Butyldimethylsilyl)-1H-indol-6-ylboronic acid 430240010, 1 g 913835-60-6 97%
N-(tert-Butyldimethylsilyl)-N-methyl-trifluoroacetamide 221540010, 1 g; 221540050, 5 g; 221540250, 25 g 77377-52-7 98%
4-[(tert-Butyldimethylsilyl)oxy]benzaldehyde 428170010, 1 g 120743-99-9 97%
4-(tert-Butyldimethylsilyloxy)cyclohexanone 426850010, 1 g; 426850050, 5 g 55145-45-4 97%
3-(tert-Butyldimethylsilyloxy)phenylboronic acid 398340010, 1 g; 398340050, 5 g 261621-12-9 96+%
1-(tert-Butyldimethylsilyloxy)-2-propanone 431230050, 5 mL; 431230250, 25 mL 74685-00-0 98%
tert-Butyldimethylsilyl trifluoromethanesulfonate 209860050, 5 mL; 209860250, 25 mL 69739-34-0 98%
Butyltrichlorosilane 435600250, 25 mL 7521-80-4 99%
(3-Butynyloxy)trimethylsilane 390560010, 1 g; 390560050, 5 g 17869-75-9 98%
2-Carbomethoxyethyldimethoxymethylsilane 336610010, 1 g; 336610050, 5 g 76301-03-6
Chloro(chloromethyl)dimethylsilane AcroSeal® 434021000, 100 mL 1719-57-9 98%
Chlorodiethylisopropylsilane 435650250, 25 mL 107149-56-4 95+%
Chlorodiisopropylsilane 313440050, 5 g 2227-29-4 95%
Chlorodimethylethylsilane 313500050, 5 g; 313500250, 25 g 6917-76-6 97%
Chlorodimethylphenylsilane 151070050, 5 g; 151070250, 25 g; 151071000, 100 g 768-33-2 95%
Chlorodimethylsilane 162840100, 10 g; 162840500, 50 g; 162842500, 250 g 1066-35-9 96%
Chlorodimethylthexylsilane 408600050, 5 g; 408600250, 25 g; 408601000, 100 g 67373-56-2 95%
(Chloromethyl)trichlorosilane 320470050, 5 g; 320470250, 25 g 1558-25-4 95%
Chloromethyltrimethylsilane 194760250, 25 g; 194761000, 100 g 2344-80-1 98+%
(3-Chloropropyl)triethoxysilane 391890050, 5 g; 391890250, 25 g; 391890010, 1 kg 5089-70-3 97+%
(3-Chloropropyl)trimethoxysilane 137280250, 25 mL; 137281000, 100 mL; 137285000, 500 mL 2530-87-2 98+%
2-(4-Chlorosulfonylphenyl)ethyltrimethoxysilane 50% solution in
337470050, 5 g; 337470250, 25 g 126519-89-9
dichloromethane
2-(4-Chlorosulfonylphenyl)ethyltrimethoxysilane 50% solution in
428991000, 100 mL 126519-89-9
dichloromethane, AcroSeal®

9
Product Name Product Code CASNo Purity
215940050, 5 mL; 215940250, 25 mL; 215941000, 100 mL;
Chlorotriethylsilane 994-30-9 99%
215945000, 500 mL
Chlorotriethylsilane 1M solution in THF, AcroSeal® 433251000, 100 mL 994-30-9
Chlorotriisopropylsilane 221260100, 10 g; 221260500, 50 g; 221262500, 250 g 13154-24-0 97%
Chlorotriisopropylsilane 377350050, 5 g; 377350250, 25 g; 377351000, 100 g 13154-24-0 95%
110120250, 25 mL; 110121000, 100 mL; 110122500, 250 mL;
Chlorotrimethylsilane 75-77-4 98%
110120010, 1 L
Chlorotrimethylsilane AcroSeal® 426431000, 100 mL 75-77-4 98%
Chlorotrimethylsilane 1M solution in dichloromethane, AcroSeal ®
381601000, 100 mL; 381608000, 800 mL 75-77-4
Chlorotrimethylsilane 1M solution in THF, AcroSeal® 381611000, 100 mL; 381618000, 800 mL 75-77-4
Chlorotriphenylsilane 151250250, 25 g; 151251000, 100 g 76-86-8 95%
Chlorotripropylsilane 313930050, 5 g; 313930250, 25 g 995-25-5 98%
3-Cyanopropyldimethylchlorosilane 313380100, 10 mL; 313380500, 50 mL 18156-15-5 95%
Cyanopropylmethyldichlorosilane 432250050, 5 mL; 432250250, 25 mL 1190-16-5 97%
3-Cyanopropyltrichlorosilane 277110250, 25 mL; 277111000, 100 mL 1071-27-8 97%
Cyclohexylmethyldichlorosilane 432220100, 10 mL; 432220500, 50 mL 5578-42-7 97+%
Cyclopentadienyltrimethylsilane 387160010, 1 g; 387160050, 5 g 3559-74-8
Cyclopropyl(trimethylsilyl)acetylene 387520010, 1 g; 387520050, 5 g 81166-84-9 97+%
Decyldimethylchlorosilane 432190050, 5 mL; 432190250, 25 mL 38051-57-9 97%
Diacetoxydimethylsilane 426690250, 25 g 2182-66-3 95%
Diacetoxydimethylsilane AcroSeal® 434011000, 100 mL 2182-66-3 98%
Di-tert-Butylchlorosilane 432900010, 1 g; 432900050, 5 g; 432900250, 25 g 56310-18-0 95%
Dichloro(chloromethyl)methylsilane 313370250, 25 g; 313371000, 100 g 1558-33-4 95%
Dichlorodiethylsilane 338100050, 5 g; 338100250, 25 g 1719-53-5 97%
113310050, 5 mL; 113312500, 250 mL; 113310010, 1 L;
Dichlorodimethylsilane 75-78-5 99+%
113310025, 2.5 L
Dichloromethylsilane AcroSeal® 430881000, 100 mL; 430888000, 800 mL 75-78-5 99+%
Dichlorodiphenylsilane 113341000, 100 mL; 113345000, 500 mL; 113340025, 2.5 L 80-10-4 97%
Dichlorophenylsilane AcroSeal® 430891000, 100 mL; 430898000, 800 mL 80-10-4 97%
Dichloromethylphenylsilane 147380100, 10 mL; 147381000, 100 mL; 147385000 500 mL 149-74-6 98%
Dichloromethylsilane 147391000, 100 mL; 147395000, 500 mL; 147390025 2.5 L 75-54-7 97%
Dichloromethylsilane AcroSeal® 430901000, 100 mL; 430908000, 800 mL 75-54-7 97%
147430100, 10 g; 147431000, 100 g; 147435000, 500 g;
Dichloromethylvinylsilane 124-70-9 97%
147430025, 2.5 kg
Dichlorophenylsilane 432340250, 25 mL 1631-84-1 95%
1,3-Dichloro-1,1,3,3-tetraisopropyldisiloxane 215280050, 5 mL; 215280250, 25 mL 69304-37-6 96%
Diethoxydimethylsilane 174631000, 100 mL; 174635000, 500 mL 78-62-6 97%
N,N-Diethyl-1,1,1-trimethylsilylamine 155690050, 5 g; 155690250, 25 g; 155691000, 100 g 996-50-9 98+%
Diiodosilane 388920010, 1 g; 388920050, 5 g 13760-02-6
Diisopropyldichlorosilane 432360050, 5 g; 432360250, 25 g 7751-38-4 97%
Dimethoxydimethylsilane AcroSeal® 351531000, 100 mL; 351530010, 1 L 1112-39-6 95%
(3,3-Dimethylcyclohex-1-enylmethyl)trimethylsilane 339000010, 1 g 150929-92-3 98%
Dimethyldi-2-thienylsilane 390370010, 1 g; 390370050, 5 g 17888-49-2 95+%
Dimethylethoxysilane 392000050, 5 g; 392000250, 25 g; 392001000, 100 g 14857-34-2 95%
Dimethylmethoxychlorosilane 432200100, 10 mL 1825-68-9
Dimethyloctadecyl[3-(trimethoxysilyl)propyl]ammonium chloride
338531000, 100 mL 27668-52-6
60% in methanol

10
Product Name Product Code CASNo Purity
Dimethylphenylsilane 215930050, 5 g; 215930250, 25 g 766-77-8 98%
Dimethylphenylsilanol 390510010, 1 g; 390510050, 5 g 5272-18-4 97%
1,3-Dimethyl-1,1,3,3-tetravinyldisiloxane 338500010, 1 g 16045-78-6 95%
Dimethyl (p-tolyl)silanol 390920010, 1 g; 390920050, 5 g 17920-15-9 95%
N,N-Dimethyltrimethylsilylamine 209970100, 10 mL; 209970500, 50 mL 2083-91-2 97%
Dimethylvinylchlorosilane 336730050, 5 g; 336730250, 25 g 1719-58-0 97%
2-(Diphenylphosphino)ethyltriethoxysilane 391860010, 1 g; 391860050, 5 g; 391860250, 25 g 18586-39-5 92%
Diphenylsilane 329770050, 5 g; 329770250, 25 g 775-12-2 97%
Diphenyltetramethyldisilane 387880010, 1 g 1145-98-8 97%
Divinyltetramethyldisiloxane 249210100, 10 g; 249210500, 50 g; 249212500, 250 g 2627-95-4 97%
Dodecyldimethylchlorosilane 432230250, 25 mL; 432231000, 100 mL 66604-31-7 97%
(1-Ethoxycyclopropoxy)trimethylsilane 368900050, 5 g; 368900250, 25 g; 368901000, 100 g 27374-25-0 99%
Ethoxytrimethylsilane 313820050, 5 g; 313820250, 25 g; 313821000, 100 g 1825-62-3 95%
Ethylmethyldichlorosilane 432890250, 25 mL 4525-44-4 97%
(Ethylthio)trimethylsilane 345000010, 1 g; 345000100, 10 g 5573-62-6 90%
Ethyltrichlorosilane AcroSeal® 313511000, 100 mL; 313510010, 1 L 115-21-9 99%
Ethyltrimethoxysilane AcroSeal® 433081000, 100 mL; 433080010, 1 L 5314-55-6 97%
Ethyl 3-(trimethylsilyl)propiolate 381550010, 1 g; 381550050, 5 g; 381550250, 25 g 16205-84-8 99%
Fluorodimethylphenylsilane 382900010, 1 g; 382900050, 5 g 454-57-9 97%
Fluorodiphenylmethylsilane 382910010, 1 g; 382910050, 5 g 17739-53-6 97%
216540050, 5 g; 216541000, 100 g; 216545000, 500 g;
3-Glycidoxypropyltrimethoxysilane 2530-83-8 97%
216540025, 2.5 kg
Heptamethyldisilazane 215920500, 50 g 920-68-3 99%
Hexakis-6-(dimethyl-tert-butylsilyl)-alpha-cyclodextrin 298980010, 1 g 118646-79-0 96%
Hexamethylcyclotrisiloxane 216460250, 25 g; 216461000, 100 g 541-05-9 98%
Hexamethyldisilane 202690100, 10 mL; 202690500, 50 mL; 202692500, 250 mL 1450-14-2 98+%
120580100, 10 mL; 120581000, 100 mL; 120585000, 500 mL;
1,1,1,3,3,3-Hexamethyldisilazane 999-97-3 98%
120580025, 2.5 L
1,1,1,3,3,3-Hexamethyldisilazane AcroSeal® 430851000, 100 mL 999-97-3 98%
194790100, 10 mL; 194791000, 100 mL; 194795000, 500 mL;
Hexamethyldisiloxane 107-46-0 98+%
194790025, 2.5 L
1,1,3,3,5,5-Hexamethyltrisiloxane 337570050, 5 mL; 337570250, 25 mL 1189-93-1 97%
1,1,3,3,5,5-Hexamethyltrisiloxane AcroSeal® 433071000, 100 mL 1189-93-1 95+%
Hexaphenyldisilane 304620010, 1 g 1450-23-3
(Iodomethyl)trimethylsilane 205090050, 5 mL; 205090250, 25 mL 4206-67-1 99%
Iodotrimethylsilane stabilized 187490050, 5 mL; 187490250, 25 mL; 187491000, 100 mL 16029-98-4 95-97%
Iodotrimethylsilane stabilized, AcroSeal® 426421000, 100 mL 16029-98-4 95-97%
Isobutyltrichlorosilane 338060050, 5 mL 18169-57-8 98%
(3-Isocyanatopropyl)triethoxysilane 391900250, 25 g; 391901000, 100 g 24801-88-5 95%
Isopropyldimethylchlorosilane 313570250, 25 g 3634-56-8 95%
Lithium bis(trimethylsilyl)amide 338140100, 10 g; 338140500, 50 g; 338142500, 250 g 4039-32-1 95%
Lithium bis(trimethylsilyl)amide 0.9M solution in
380231000, 100 mL; 380238000, 800 mL 4039-32-1
methylcyclohexane, AcroSeal®
Lithium bis(trimethylsilyl)amide 1.0M sol. in methyl tert-butyl
345671000, 100 mL; 345678000, 800 mL 4039-32-1
ether, AcroSeal®
Lithium bis(trimethylsilyl)amide 1M solution in THF/
347701000, 100 mL; 347708000, 800 mL 4039-32-1
Ethylbenzene, AcroSeal®

11
Product Name Product Code CASNo Purity
Lithium trimethylsilanolate 1M solution in dichloromethane,
428821000, 100 mL; 428828000, 800 mL 2004-14-0
AcroSeal®
Lithium trimethylsilanolate 1M solution in THF, AcroSeal® 428811000, 100 mL; 428818000, 800 mL 2004-14-0
Lithium (trimethylsilyl)acetylide 0.5M solution in THF, AcroSeal ®
380651000, 100 mL; 380658000, 800 mL 54655-07-1
(3-Mercaptopropyl)trimethoxysilane tech. 174650500, 50 g; 174652500, 250 g 4420-74-0 85%
Methoxy(4-methoxyphenyl)dimethylsilane 390450010, 1 g; 390450050, 5 g 62244-48-8 97%
N-(Methoxymethyl)-N-(trimethylsilylmethyl)benzylamine 344300050, 5 g; 344300250, 25 g 93102-05-7 96%
Methoxytrimethylsilane 392470250, 25 g; 392471000, 100 g; 392472500, 250 g 1825-61-2 96+%
1-Methoxy-3-(trimethylsilyloxy)-1,3-butadiene 199550050, 5 g 59414-23-2 90%
Methyl (S)-(-)-4-bromo-3-tert-butyldimethylsilyloxybutanoate 414082500, 250 mg 101703-35-9 98%
Methyldiethoxysilane 392260050, 5 g; 392260250, 25 g; 392261000, 100 g 2031-62-1 97%
Methylphenylvinylsilane 336680050, 5 g 17878-39-6 97%
Methylpropyldichlorosilane 432880250, 25 mL 4518-94-9 97%
Methyltriallylsilane 304590010, 1 g 1112-91-0 97%
Methyltrichlorosilane 127930100, 10 mL; 127935000, 500 mL; 127930025, 2.5 L 75-79-6 98+%
Methyltriethoxysilane 174620250, 25 mL; 174622500, 250 mL 2031-67-6 98+%
250540050, 5 mL; 250540500, 50 mL; 250542500, 250 mL;
Methyltrimethoxysilane 1185-55-3 97%
250540010, 1 L
Methyltrimethoxysilane AcroSeal® 432641000, 100 mL; 432640010, 1 L 1185-55-3 97%
N-Methyl-N-(trimethylsilyl)acetamide 215950010, 1 g; 215950100, 10 g 7449-74-3 98%
Methyl (trimethylsilyl)acetate 215890050, 5 g 2916-76-9 98%
N-Methyl-N-(trimethylsilyl)trifluoroacetamide 221580050, 5 g; 221580250, 25 g; 221581000, 100 g 24589-78-4 97%
4-Nitrophenyl 2-(trimethylsilyl)ethyl carbonate 440070050, 5 g; 440070250, 25 g 80149-80-0 95%
Octadecyltrichlorosilane 147400250, 25 mL; 147401000, 100 mL; 147405000, 500 mL 112-04-9 95%
Octadecyltrimethoxysilane tech. 313600250, 25 mL; 313601000, 100 mL 3069-42-9 90%
Octamethylcyclotetrasiloxane 216470250, 25 g; 216471000, 100 g; 216475000, 500 g 556-67-2 98%
Octamethyltrisiloxane 216481000, 100 g 107-51-7 98%
Octylmethyldichlorosilane 255260050, 5 mL; 255260250, 25 mL 14799-93-0 97%
Octyltrichlorosilane 216501000, 100 g; 216505000, 500 g 5283-66-9 97%
n-Octyltriethoxysilane 338080250, 25 mL; 338081000, 100 mL 2943-75-1 97%
(Pentamethylcyclopentadien-1-yl)trimethylsilane 389040010, 1 g; 389040050, 5 g 87778-95-8 97%
1,1,3,5,5-Pentaphenyl-1,3,5-trimethyltrisiloxane 338615000, 500 mL 3390-61-2
Pentyltrichlorosilane 433100500, 50 g 107-72-2
Phenethyltrichlorosilane 432240010, 1 g 940-41-0 95%
Phenoxytrimethylsilane 388600050, 5 mL; 388600250, 25 mL 1529-17-5 97+%
Phenylsilane 291690050, 5 mL; 291690250, 25 mL; 291691000, 100 mL 694-53-1 97+%
Phenyltrichlorosilane 131000100, 10 mL; 131002500, 250 mL; 131000010, 1 L 98-13-5 95%
Phenyltriethoxysilane 174642500, 250 g; 174640010, 1 kg 780-69-8 98%
Phenyltrimethoxysilane 370640500, 50 mL; 370642500, 250 mL; 370640010, 1 L 2996-92-1 85%
Poly(dimethylsiloxane) 178442500, 250 g; 178445000, 500 g; 178440025, 2.5 kg 9016-00-6
Polymethylhydrosiloxane 175091000, 100 g; 175095000, 500 g 9004-73-3
Potassium bis(trimethylsilyl)amide 0.7M (15 wt.%) solution in
418231000, 100 mL; 418238000,800 mL 40949-94-8
toluene, AcroSeal®
Potassium trimethylsilanolate 426920250, 25 g; 426921000, 100 g 10519-96-7 95%

12
Product Name Product Code CASNo Purity
Propargyloxytrimethylsilane 313900025, 2.5 g; 313900100, 10 g 5582-62-7 97%
Propargyltrimethylsilane stabilized 366630010, 1 g; 366630050, 5 g 13361-64-3 80-90%
n-Propyltrichlorosilane 147411000, 100 mL; 147410010, 1 L 141-57-1 98%
Silicon(IV) chloride 201160500, 50 mL; 201165000, 500 mL; 201160025, 2.5 L 10026-04-7 99.8+%
Silicon(IV) chloride 1M solution in methylene chloride, AcroSeal® 428761000, 100 mL 10026-04-7
Sodium bis(trimethylsilyl)amide 215960050, 5 g; 215960250, 25 g; 215961000, 100 g 1070-89-9 95+%
Sodium bis(trimethylsilyl)amide 2M solution in THF, AcroSeal ®
277851000, 100 mL; 277858000, 800 mL 1070-89-9
Sodium trimethylsilanolate 1M solution in dichloromethane,
428841000, 100 mL; 428848000, 800 mL 18027-10-6
AcroSeal®
Sodium trimethylsilanolate 1M solution in THF, AcroSeal® 428831000, 100 mL; 428838000, 800 mL 18027-10-6
Tetraallylsilane 304600010, 1 g 1112-66-9 98%
Tetrabutyl orthosilicate 313690050, 5 g; 313690250, 25 g 4766-57-8 95%
157811000, 100 mL; 157812500, 250 mL; 157810010, 1 L;
Tetraethyl orthosilicate 78-10-4 98%
157810025, 2.5 L
Tetraethyl orthosilicate AcroSeal® 420361000, 100 mL; 420360010, 1 L 78-10-4
[4’-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl]
390870010, 1 g; 390870050, 5 g 98+%
trimethylsilane
4-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)-1-
CC39539CB, 250 mg; CC39539DA, 1 g 690632-17-8 97%
(triisopropylsilyl)-1H-indole
5-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)-1-
MO00983CB, 250 mg; MO00983DA, 1 g 690631-97-1 97%
(triisopropylsilyl)-1H-indole
1,1,3,3-Tetramethyldisiloxane 216510250, 25 mL; 216511000, 100 mL; 216515000, 500 mL 3277-26-7 97%
203820250, 25 g; 203821000, 100 g; 203825000, 500 g;
Tetramethyl orthosilicate 681-84-5 99%
203820025, 2.5 kg
Tetramethylsilane NMR gade 138470250, 25 g; 138471000, 100 g 75-76-3 99.9+%
Tetramethylsilane 268861000, 100 mL; 268865000, 500 mL; 268860025, 2.5 L 75-76-3 99%
Tetramethylsilane AcroSeal® 427331000, 100 mL 75-76-3 99%
Tetramethylsilane NMR gade 445900250, 25 g; 445901000, 100 g 75-76-3
Tetraphenyldimethyldisilane 304570010, 1 g 1172-76-5 97%
N-TIPS indole-3-boronic acid pinacol ester 441030010, 1 g; 441030050, 5 g 476004-82-7 97%
N-TIPS pyrrole-3-boronic acid pinacol ester 441020010, 1 g; 441020050, 5 g 365564-11-0 95%
p-Tolyltrimethylsilane 383630010, 1 g; 383630050, 5 g 3728-43-6 99%
Trichlorosilane 174600050, 5 mL; 174602500, 250 mL; 174600010, 1 L 10025-78-2 99%
Triethoxysilane 164810100, 10 g; 164810500, 50 g 998-30-1 95%
Triethoxyvinylsilane 174610250, 25 g; 174615000, 500 g 78-08-0 97%
212920050, 5 g; 212920250, 25 g; 212921000, 100 g;
Triethylsilane 617-86-7 99%
212925000, 500 g
Triethylsilane AcroSeal® 446161000, 100 mL 617-86-7 99%
Triethylsilanol 313760010, 1 mL 597-52-4 97%
(Triethylsilyl)acetylene 368730010, 1 g; 368730050, 5 g 1777-03-3 97%
5-Triethylsilyl-4-pentyn-1-ol 381340050, 5 g 174064-02-9 97+%
Triethylsilyl trifluoromethanesulfonate 312700100, 10 g; 312700500, 50 g 79271-56-0 99%
Triethylvinylsilane 313770050, 5 g 1112-54-5 97%
(Trifluoromethyl)trimethylsilane 279720010, 1 mL; 279720050, 5 mL; 279720250, 25 mL 81290-20-2 99%
(Trifluoromethyl)trimethylsilane 0.5M solution in THF 368320050, 5 mL; 368320250, 25 mL; 368321000, 100 mL 81290-20-2
(Trifluoromethyl)trimethylsilane 0.5M solution in THF, AcroSeal® 429171000, 100 mL 81290-20-2

13
Product Name Product Code CASNo Purity
(3,3,3-Trifluoropropyl)chlorodimethylsilane 432210050, 5 g; 432210250, 25 g 1481-41-0 95%
Triisopropylsilane 214920100, 10 g; 214920500, 50 g; 214922500, 250 g 6485-79-6 98%
Triisopropylsilane 372410100, 10 g; 372410500, 50 g 6485-79-6 95%
(Triisopropylsilyl)acetylene 368740050, 5 g; 368740250, 25 g 89343-06-6 97%
Triisopropylsilyl-trifluoromethanesulfonate 250700100, 10 g; 250700500, 50 g 80522-42-5 97%
Trimethoxysilane 392170050, 5 g; 392170250, 25 g; 392171000, 100 g 2487-90-3 95%
3-(Trimethoxysilyl)propyl acrylate stabilized 426600050, 5 g; 426600250, 25 g 4369-14-6 90%
N-[3-(Trimethoxysilyl)propyl]ethylenediamine 216531000, 100 g; 216535000, 500 g 1760-24-3 97%
3-(Trimethoxysilyl)propyl methacrylate 216550050, 5 mL; 216551000, 100 mL; 216555000, 500 mL 2530-85-0 98%
N-(Trimethylsilyl)acetamide 207590250, 25 g; 207591000, 100 g 13435-12-6 97%
Trimethylsilyl acetate 391980250, 25 g; 391981000, 100 g 2754-27-0 97%
(Trimethylsilyl)acetonitrile 426570010, 1 g; 426570050, 5 g 18293-53-3 97%
Trimethylsilylacetylene 203570050, 5 g; 203570250, 25 g; 203571000, 100 g 1066-54-2 98%
N-(Trimethylsilyl)allylamine 338680010, 1 g; 338680050, 5 g 10519-97-8 95%
2-Trimethylsilylanisole 391780010, 1 g; 391780050, 5 g 704-43-8 98%
3-Trimethylsilylanisole 391790010, 1 g; 391790050, 5 g 17876-90-3 97%
4-Trimethylsilylanisole 390900010, 1 g; 390900050, 5 g 877-68-9 97%
1-(Trimethylsilyl)-1H-benzotriazole 426260010, 1 g; 426260050, 5 g 43183-36-4 97%
Trimethylsilyl bromoacetate 215990050, 5 g 18291-80-0 98%
2-Trimethylsilyl-N-tert-butylacetaldimine 331150010, 1 g 73198-78-4
6-Trimethylsilyl-N-tert-butyl-2,4-hexadienaldimine 331132500, 250 mg 171814-36-1
4-Trimethylsilyl-3-butyn-1-ol 381320050, 5 g 2117-12-6 98%
199560050, 5 g; 199560250, 25 g; 199561000, 100 g;
Trimethylsilyl cyanide 7677-24-9 98%
199565000, 500 g
Trimethylsilyl cyanide AcroSeal® 422061000, 100 mL 7677-24-9 98%
(Trimethylsilyl)diazomethane approx. 2M solution in diethyl ether 397620050, 5 mL; 397620250, 25 mL; 397621000, 100 mL 18107-18-1
(Trimethylsilyl)diazomethane approx. 2M solution in diethyl ether,
429201000, 100 mL 18107-18-1
AcroSeal®
385330050, 5 mL; 385330250, 25 mL; 385331000, 100 mL;
(Trimethylsilyl)diazomethane ca. 2.0M solution in hexanes, tech. 18107-18-1
385335000, 500 mL
(Trimethylsilyl)diazomethane approx. 2.0M solution in hexanes,
429211000, 100 mL;, 18107-18-1
AcroSeal®
Trimethylsilyl diethylphosphonoacetate 338170010, 1 mL; 338170050, 5 mL; 338170250, 25 mL 66130-90-3 95%
Trimethylsilyl 3,3-dimethylacrylate 330940010, 1 g 25436-25-3
2-(Trimethylsilyl)ethanol 210480100, 10 mL; 210480500, 50 mL; 210482500, 250 mL 2916-68-9 99%
2-(Trimethylsilyl)ethoxymethyl chloride tech., stabilized 219020050, 5 mL; 219020250, 25 mL; 219021000, 100 mL 76513-69-4 90%
2-(Trimethylsilylethoxymethyl)triphenylphosphonium chloride 428240010, 1 g; 428240050, 5 g; 428240250, 25 g 82495-75-8 97%
2-(Trimethylsilylethynyl)pyridine 380800010, 1 g; 380800050, 5 g 86521-05-3 97%
O-(Trimethylsilyl)hydroxylamine 367950010, 1 g; 367950050, 5 g 22737-36-6 97%
N-(Trimethylsilyl)imidazole 167130250, 25 g; 167131000, 100 g; 167132500, 250 g 18156-74-6 97%
Trimethylsilyl isocyanate 224730050, 5 g; 224730250, 25 g 1118-02-1 95%
Trimethylsilyl isothiocyanate 213380100, 10 g; 213380500, 50 g 2290-65-5 97%
Trimethylsilyl methacrylate stabilized 338620050, 5 g 13688-56-7 97%
Trimethylsilylmethyl acetate 216000050, 5 g 2917-65-9 99%
2-(Trimethylsilylmethyl)allyl acetate 381380010, 1 g; 381380050, 5 g; 381380250, 25 g 72047-94-0 98%

14
Product Name Product Code CASNo Purity
(Trimethylsilyl)methyllithium 0.7M (10 wt%) solution in hexanes,
377451000, 100 mL; 377458000, 800 mL 1822-00-0
AcroSeal®
(Trimethylsilyl)methylmagnesium chloride 1.3M solution in THF,
377461000, 100 mL; 377468000, 800 mL 13170-43-9
AcroSeal®
(Trimethylsilyl)methyl trifluoromethanesulfonate 389010010, 1 g; 389010050, 5 g 64035-64-9 95+%
4-(Trimethylsilyl)morpholine 369200050, 5 g; 369200250, 25 g 13368-42-8 96%
3-(Trimethylsilyloxy)-1-butyne 389240050, 5 g; 389240250, 25 g 17869-76-0 97%
5-Trimethylsilyl-4-pentyn-1-ol 381330050, 5 g; 381330250, 25 g 13224-84-5 97%
3-(Trimethylsilyl)-1-propanol 214930050, 5 g 2917-47-7 97%
3-Trimethylsilylpropargyl aldehyde diethyl acetal 380930010, 1 g; 380930050, 5 g 87219-80-5 97+%
3-(Trimethylsilyl)propargyl bromide 399840010, 1 g; 399840050, 5 g 38002-45-8 97%
98 atom%
3-(Trimethylsilyl)propionic acid-d4 sodium salt 432120010, 1 g 24493-21-8
D
1-(Trimethylsilyl)-1-propyne 223530010, 1 g; 223530050, 5 g 6224-91-5 98%
3-Trimethylsilyl-2-propyn-1-ol 313890010, 1 g 5272-36-6 99%
2-(Trimethylsilyl)pyridine 390360010, 1 g; 390360100, 10 g 13737-04-7 97+%
2-(Trimethylsilyl)thiazole 292290010, 1 mL; 292290050, 5 mL; 292290250, 25 mL 79265-30-8 96%
Trimethylsilyl trifluoromethanesulfonate 209440100, 10 mL; 209440500, 50 mL; 209442500, 250 mL 27607-77-8 99%
Trimethylstannylbutyldimethylsilane 382500010, 1 g 103731-29-9 97%
Trimethylstannyldimethylphenylsilan 325200050, 5 g 94397-44-1 96%
Trimethylstannylmethyldiphenylsilan 325210010, 1 g; 325210050, 5 g 149013-84-3 96%
Trimethyl-2-thienylsilane 308280050, 5 g 18245-28-8 97%
Trimethyl(2-thienyl)silane AC30828EA, 10 g 18245-28-8 97%
Trioctylsilane 434900050, 5 g; 434900250, 25 g 18765-09-8 95%
Triphenylvinylsilane 350990050, 5 g; 350990250, 25 g 18666-68-7 95%
Tri-n-propylsilane 390320050, 5 g; 390320250, 25 g 998-29-8 99%
Tris[N,N-bis(trimethylsilyl)amide]erbium(III) 381580010, 1 g 103457-72-3 99%
Tris(trimethylsilyl)amine 378770050, 5 g; 378770250, 25 g 1586-73-8 99%
Tris(trimethylsilyl) borate 381240250, 25 g; 381241000, 100 g 4325-85-3
Tris(trimethylsilyloxy)ethylene 216010010, 1 g; 216010050, 5 g; 216010250, 25 g 69097-20-7 95%
Tris(trimethylsilyloxy)silane 313940050, 5 g; 313940250, 25 g 1873-89-8 97%
[Tris(trimethylsilyl)]phosphine 291700010, 1 mL; 291700050, 5 mL 15573-38-3 98%
Tris(trimethylsilyl) phosphite 428520050, 5 g; 428520250, 25 g; 428521000, 100 g 1795-31-9 92%
Tris(trimethylsilyl)silane 291060025, 2.5 mL; 291060250, 25 mL 1873-77-4 96%
Vinylmethylbis(trimethylsilyloxy)silane 338480050, 5 mL 5356-85-4 95%
Vinyloxytrimethylsilane 338700010, 1 g; 338700050, 5 g 6213-94-1 97%
Vinyltrimethoxysilane 216521000, 100 g; 216525000, 500 g 2768-02-7 98%
Vinyltrimethoxysilane AcroSeal ® 433061000, 100 mL; 433060010, 1 L 2768-02-7 97%
Vinyltrimethylsilane 200330250, 25 mL; 200331000, 100 mL 754-05-2 97%
Vinyl tris(2-methoxyethoxy) silane 250510100, 10 mL; 250511000, 100 mL 1067-53-4 96%
Vinyltris(trimethylsilyloxy)silane 338470010, 1 mL 5356-84-3 95%

15
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