Material Safety Data Sheet: 1. Product and Company Identification

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MATERIAL SAFETY DATA SHEET

1. Product and Company Identification


Material name 6010, 6011, 6013, MILDSTEEL ELECTRODES
Version # 01
Issue date 25-March-2014
Revision date -
Supersedes date -
CAS # Mixture
Product type Coated carbon steel alloys
Product use Carbon Steel Welding
Manufacturer information
Manufacturer/Supplier Harris Products Group
4501 Quality Place
Mason, Ohio 45040 US
[email protected]
Telephone number 513-754-2000
Emergency Telephone 1-888-609-1762 (US, Canada, Mexico only)
Numbers
Please quote 333988

2. Hazards Identification
Physical state Solid.
Appearance Coated metal rods.
Emergency overview WARNING

May cause eye, skin and respiratory tract irritation. Toxic: danger of serious damage to health by
prolonged exposure through inhalation.
OSHA regulatory status This product is considered hazardous under 29 CFR 1910.1200 (Hazard Communication).
Potential health effects
Routes of exposure Inhalation. Skin contact. Eye contact.
Eyes Fumes from heated material may cause eye irritation. Dust may irritate the eyes. Exposure to hot
material may cause thermal burns.
Skin Exposure to hot material may cause thermal burns. Dust may irritate skin.
Inhalation Inhalation of fumes may cause a flu-like illness called metal fume fever. Inhalation of dusts may
cause respiratory irritation.
Ingestion Ingestion is not likely to be a primary route of occupational exposure.
Target organs Respiratory system. Eyes. Skin. Central nervous system.
Chronic effects Chronic inhalation of fumes or dust may cause irritation or other respiratory conditions (e.g.,
bronchitis). May cause lung damage.
Chronic inhalation of high concentrations of iron oxide fumes or dust may lead to benign
pneumoconiosis (siderosis).
Overexposure to manganese fumes may affect the brain and central nervous system, resulting in
poor coordination, difficulty speaking, and arm or leg tremor. This condition can be irreversible.
Refer to Section 11 Toxicological Information for more details.
Signs and symptoms Contact may cause irritation and redness. Dust may irritate respiratory system. Symptoms of
overexposure may be headache, dizziness, tiredness, nausea and vomiting. Typical metal fume
fever begins four to twelve hours after sufficient exposure to freshly formed fumes. The first
symptoms are a metallic taste, dryness and irritation of the throat. Cough and shortness of breath
may occur along with headache, fatigue, nausea, vomiting, muscle and joint pain, fever and chills.
The syndrome runs its course in 24-48 hours.
Potential environmental effects Alloys in massive forms present a limited hazard for the environment.

6010, 6011, 6013, MILDSTEEL ELECTRODES CPH MSDS NA


918578 Version #: 01 Revision date: - Issue date: 25-March-2014 1 / 10
3. Composition / Information on Ingredients
Components CAS # Percent
Iron 7439-89-6 70 - 90
Titanium dioxide 13463-67-7 10
Aluminum oxide 1344-28-1 5
Cellulose 9004-34-6 5
Manganese 7439-96-5 5
Mica 12001-26-2 5
Magnesium carbonate 546-93-0 2
Aluminum silicate 12141-46-7 1
Calcium carbonate 1317-65-3 1
Potassium silicate 1312-76-1 1
Potassium titanate 12030-97-6 1
Sodium silicate 1344-09-8 1
Zirconium silicate 1214-23-4 1

4. First Aid Measures


First aid procedures
Eye contact Rinse immediately with plenty of water for at least 15 minutes. Remove any contact lenses. Get
medical attention if irritation develops or persists.
Skin contact Remove contaminated clothes and rinse skin thoroughly with water for at least 15 minutes. Get
medical attention if irritation develops and persists.
Inhalation Remove person from contaminated area to fresh air. Apply artificial respiration if needed. Call a
physician if symptoms develop or persist.
Ingestion Do NOT induce vomiting. Immediately rinse mouth and drink a cupful of water. Never give anything
by mouth to an unconscious person. Get medical attention immediately.
Notes to physician Treat symptomatically. Symptoms may be delayed.
General advice Show this safety data sheet to the doctor in attendance.

5. Fire Fighting Measures


Flammable properties Solid metal is not flammable; however, finely divided metallic dust or powder may form an
explosive mixture with air. Do not use water on molten metal: Explosion hazard could result.
Extinguishing media
Suitable extinguishing Extinguish with foam, carbon dioxide or dry powder.
media
Unsuitable extinguishing Do not use water or halogenated extinguishing media.
media
Protection of firefighters
Specific hazards arising Fire or high temperatures create: Metal oxides.
from the chemical
Fire fighting Self-contained breathing apparatus and full protective clothing must be worn in case of fire. Move
equipment/instructions containers from fire area if you can do it without risk.

6. Accidental Release Measures


Personal precautions Keep unnecessary personnel away. Avoid inhalation of dust from the spilled material. Wear
protective clothing as described in Section 8 of this MSDS. Do not touch damaged containers or
spilled material unless wearing appropriate protective clothing.
Environmental precautions Prevent further leakage or spillage if safe to do so. Do not contaminate water.
Methods for containment Stop leak if you can do so without risk. Local authorities should be advised if significant spillages
cannot be contained.
Methods for cleaning up Collect for salvage or disposal. Put material in suitable, covered, labeled containers. Avoid the
generation of dusts during clean-up. For waste disposal, see Section 13 of the MSDS.
Other information Clean up in accordance with all applicable regulations.
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918578 Version #: 01 Revision date: - Issue date: 25-March-2014 2 / 10
7. Handling and Storage
Handling Follow the recommendations in ANSI Z49.1, Safety in welding and cutting (ANSI=American
National Standard Institute). Avoid inhalation of dust and fumes. Use process enclosures, local
exhaust ventilation, or other engineering controls to control sources of dust and fumes. Keep
formation of airborne dusts to a minimum. Avoid contact with skin and eyes. Wear appropriate
personal protective equipment (See Section 8). Do not eat, drink or smoke when using the
product. Wash thoroughly after handling. Avoid release to the environment.
Storage Store in tightly closed original container in a dry, cool and well-ventilated place. Store in a closed
container away from incompatible materials. Keep away from food, drink and animal feedingstuffs.

8. Exposure Controls / Personal Protection


Occupational exposure limits
US. ACGIH Threshold Limit Values

Components Type Value Form


Aluminum oxide (CAS TWA 1 mg/m3 Respirable fraction.
1344-28-1)
Cellulose (CAS 9004-34-6) TWA 10 mg/m3
Manganese (CAS TWA 0.1 mg/m3 Inhalable fraction.
7439-96-5)
0.02 mg/m3 Respirable fraction.
Mica (CAS 12001-26-2) TWA 3 mg/m3 Respirable fraction.
Titanium dioxide (CAS TWA 10 mg/m3
13463-67-7)
Zirconium silicate (CAS STEL 10 mg/m3
1214-23-4)
TWA 5 mg/m3
US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000)

Components Type Value Form


Aluminum oxide (CAS PEL 5 mg/m3 Respirable fraction.
1344-28-1)
15 mg/m3 Total dust.
Calcium carbonate (CAS PEL 5 mg/m3 Respirable fraction.
1317-65-3)
15 mg/m3 Total dust.
Cellulose (CAS 9004-34-6) PEL 5 mg/m3 Respirable fraction.
15 mg/m3 Total dust.
Magnesium carbonate PEL 5 mg/m3 Respirable fraction.
(CAS 546-93-0)
15 mg/m3 Total dust.
Manganese (CAS Ceiling 5 mg/m3 Fume.
7439-96-5)
Titanium dioxide (CAS PEL 15 mg/m3 Total dust.
13463-67-7)
Zirconium silicate (CAS PEL 5 mg/m3
1214-23-4)
US. OSHA Table Z-3 (29 CFR 1910.1000)

Components Type Value


Mica (CAS 12001-26-2) TWA 20 mppcf
Canada. Alberta OELs (Occupational Health & Safety Code, Schedule 1, Table 2)

Components Type Value Form


Aluminum oxide (CAS TWA 10 mg/m3
1344-28-1)
Calcium carbonate (CAS TWA 10 mg/m3
1317-65-3)
Cellulose (CAS 9004-34-6) TWA 10 mg/m3
Manganese (CAS TWA 0.2 mg/m3
7439-96-5)
Mica (CAS 12001-26-2) TWA 3 mg/m3 Respirable.

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918578 Version #: 01 Revision date: - Issue date: 25-March-2014 3 / 10
Canada. Alberta OELs (Occupational Health & Safety Code, Schedule 1, Table 2)

Components Type Value Form


Titanium dioxide (CAS TWA 10 mg/m3
13463-67-7)
Zirconium silicate (CAS STEL 10 mg/m3
1214-23-4)
TWA 5 mg/m3
Canada. British Columbia OELs. (Occupational Exposure Limits for Chemical Substances, Occupational Health and
Safety Regulation 296/97, as amended)

Components Type Value Form


Aluminum oxide (CAS TWA 1 mg/m3 Respirable.
1344-28-1)
Calcium carbonate (CAS STEL 20 mg/m3 Total dust.
1317-65-3)
TWA 3 mg/m3 Respirable fraction.
10 mg/m3 Total dust.
Cellulose (CAS 9004-34-6) TWA 3 mg/m3 Respirable fraction.
10 mg/m3 Total dust.
Manganese (CAS TWA 0.2 mg/m3
7439-96-5)
Mica (CAS 12001-26-2) TWA 3 mg/m3 Respirable.
Titanium dioxide (CAS TWA 3 mg/m3 Respirable fraction.
13463-67-7)
10 mg/m3 Total dust.
Zirconium silicate (CAS STEL 10 mg/m3
1214-23-4)
TWA 5 mg/m3
Canada. Manitoba OELs (Reg. 217/2006, The Workplace Safety And Health Act)

Components Type Value Form


Aluminum oxide (CAS TWA 1 mg/m3 Respirable fraction.
1344-28-1)
Cellulose (CAS 9004-34-6) TWA 10 mg/m3
Manganese (CAS TWA 0.1 mg/m3 Inhalable fraction.
7439-96-5)
0.02 mg/m3 Respirable fraction.
Mica (CAS 12001-26-2) TWA 3 mg/m3 Respirable fraction.
Titanium dioxide (CAS TWA 10 mg/m3
13463-67-7)
Zirconium silicate (CAS STEL 10 mg/m3
1214-23-4)
TWA 5 mg/m3
Canada. Ontario OELs. (Control of Exposure to Biological or Chemical Agents)

Components Type Value Form


Aluminum oxide (CAS TWA 1 mg/m3 Respirable fraction.
1344-28-1)
Cellulose (CAS 9004-34-6) TWA 10 mg/m3
Magnesium carbonate TWA 10 mg/m3 Total dust.
(CAS 546-93-0)
Manganese (CAS TWA 0.2 mg/m3
7439-96-5)
Mica (CAS 12001-26-2) TWA 3 mg/m3 Respirable fraction.
Titanium dioxide (CAS TWA 10 mg/m3
13463-67-7)
Zirconium silicate (CAS STEL 10 mg/m3
1214-23-4)
TWA 5 mg/m3

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Canada. Quebec OELs. (Ministry of Labor - Regulation Respecting the Quality of the Work Environment)

Components Type Value Form


Aluminum oxide (CAS TWA 10 mg/m3 Total dust.
1344-28-1)
Calcium carbonate (CAS TWA 10 mg/m3 Total dust.
1317-65-3)
Cellulose (CAS 9004-34-6) TWA 10 mg/m3 Total dust.
Magnesium carbonate TWA 10 mg/m3 Total dust.
(CAS 546-93-0)
Manganese (CAS STEL 3 mg/m3 Fume.
7439-96-5)
TWA 5 mg/m3 Dust.
1 mg/m3 Fume.
Mica (CAS 12001-26-2) TWA 3 mg/m3 Respirable dust.
Titanium dioxide (CAS TWA 10 mg/m3 Total dust.
13463-67-7)
Zirconium silicate (CAS STEL 10 mg/m3
1214-23-4)
TWA 5 mg/m3
Mexico. Occupational Exposure Limit Values

Components Type Value Form


Aluminum oxide (CAS TWA 10 mg/m3
1344-28-1)
Calcium carbonate (CAS STEL 20 mg/m3
1317-65-3)
TWA 10 mg/m3
Cellulose (CAS 9004-34-6) STEL 20 mg/m3
TWA 10 mg/m3
Magnesium carbonate STEL 20 mg/m3
(CAS 546-93-0)
TWA 10 mg/m3
Manganese (CAS STEL 3 mg/m3 Fume.
7439-96-5)
TWA 1 mg/m3 Fume.
0.2 mg/m3
Mica (CAS 12001-26-2) TWA 3 mg/m3
Titanium dioxide (CAS STEL 20 mg/m3
13463-67-7)
TWA 10 mg/m3
Zirconium silicate (CAS STEL 10 mg/m3
1214-23-4)
TWA 5 mg/m3
Engineering controls Provide adequate ventilation. Observe occupational exposure limits and minimize the risk of
inhalation of dust and fumes. Shower, hand and eye washing facilities near the workplace are
recommended.
Personal protective equipment
Eye / face protection Wear safety glasses with side shields (or goggles). When welding, it is recommended that safety
glasses, goggles, or face-shield with filter lens of appropriate shade number (per ANSI
Z49.1-1988, “Safety in Welding and Cutting”) be worn.
Skin protection Protective clothing is recommended. When welding, wear protective clothing that protects from
sparks and flame (per ANSI Z49.1-1988, “Safety in Welding and Cutting”).
Respiratory protection Use a respirator when local exhaust or ventilation is not adequate to keep exposures below the
TLV. In a confined space a supplied respirator may be required. Selection and use of respiratory
protective equipment should be in accordance with OSHA General Industry Standard 29 CFR
1910.134; or in Canada with CSA Standard Z94.4. Use a NIOSH/MSHA approved respirator if
there is a risk of exposure to dust/fume at levels exceeding the exposure limits.
General hygiene Always observe good personal hygiene measures, such as washing after handling the material
considerations and before eating, drinking, and/or smoking. Routinely wash work clothing and protective
equipment to remove contaminants.

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918578 Version #: 01 Revision date: - Issue date: 25-March-2014 5 / 10
9. Physical & Chemical Properties
Appearance Coated metal rods.
Physical state Solid.
Form Solid.
Color Not available.
Odor Odorless.
Odor threshold Not available.
pH Not applicable.
Vapor pressure Not applicable
Vapor density Not applicable.
Boiling point 5432 °F (3000 °C) as Iron
Melting point/Freezing point 2795 °F (1535 °C) as Iron
Solubility (water) Insoluble.
Specific gravity 7.86 @20°C as Iron
Flash point Not available.
Flammability limits in air, Not available.
upper, % by volume
Flammability limits in air, Not available.
lower, % by volume
Auto-ignition temperature Not available.

10. Chemical Stability & Reactivity Information


Chemical stability Material is stable under normal conditions.
Conditions to avoid Contact with incompatible materials.
Incompatible materials Strong oxidizing agents. Strong acids. Strong bases. Acetylene. Ammonia. Hydrogen peroxide
(H2O2). Chlorine. Bromine, iodine, turpentine, magnesium metal. Hydrogen sulfide. Ammonium
nitrate.
Hazardous decomposition Toxic metal oxides are emitted when heated above the melting point. Welding fumes and gases
products cannot be classified simply. The composition and quantity of both are dependent upon the metal
being welded, the process, procedure and electrodes used.
Other conditions which also influence the composition and quantity of the fumes and gases to
which workers may be exposed include: coatings on the metal being welded (such as paint,
plating, or galvanizing), the number of welders and the volume of the worker area, the quality and
amount of ventilation, the position of the welder's head with respect to the fume plume, as well as
the presence of contaminants in the atmosphere (such as chlorinated hydrocarbon vapors from
cleaning and degreasing activities.)

Fumes can be reasonably expected to include: Metal oxides.


Possibility of hazardous Hazardous polymerization does not occur.
reactions

11. Toxicological Information


Toxicological data
Components Species Test Results
Iron (CAS 7439-89-6)
Acute
Oral
LD50 Rat 30 g/kg
Manganese (CAS 7439-96-5)
Acute
Oral
LD50 Rat 9000 mg/kg

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Components Species Test Results
Sodium silicate (CAS 1344-09-8)
Acute
Oral
LD50 Mouse 1100 mg/kg
Rat 1.1 g/kg
Sensitization This product is not expected to cause skin sensitization.
Acute effects When heated, the vapors/fumes given off may cause respiratory tract irritation. High
concentrations of freshly formed fumes/dusts of metal oxides can produce symptoms of metal
fume fever.
Local effects Elevated temperatures or mechanical action may form dust and fumes which may be irritating to
the eye, mucous membranes and respiratory tract.
Chronic effects Chronic inhalation of high concentrations of iron oxide fumes or dust may lead to benign
pneumoconiosis (siderosis). Overexposure to manganese fumes may affect the brain and central
nervous system, resulting in poor coordination, difficulty speaking, and arm or leg tremor. This
condition can be irreversible
Carcinogenicity Titanium Dioxide is listed by IARC as possibly carcinogenic to humans (Group 2B). This listing is
based on inadequate evidence of carcinogenicity in humans and sufficient evidence in
experimental animals. Titanium dioxide is considered carcinogenic only when in an inhalable
powdered form.
ACGIH Carcinogens
Aluminum oxide (CAS 1344-28-1) A4 Not classifiable as a human carcinogen.
Aluminum silicate (CAS 12141-46-7) A4 Not classifiable as a human carcinogen.
Manganese (CAS 7439-96-5) A4 Not classifiable as a human carcinogen.
Titanium dioxide (CAS 13463-67-7) A4 Not classifiable as a human carcinogen.
Zirconium silicate (CAS 1214-23-4) A4 Not classifiable as a human carcinogen.
IARC Monographs. Overall Evaluation of Carcinogenicity
Titanium dioxide (CAS 13463-67-7) 2B Possibly carcinogenic to humans.
Epidemiology Based on epidemiological studies, pre-existing pulmonary disorders may be aggravated by
prolonged exposure to high concentrations of metal dust or fumes.
Mutagenicity No data available.
Reproductive effects This product is not reported to cause reproductive effects in humans. Manganese metal may
damage the reproductive system and has shown teratogenic effects in laboratory animals.
Further information No other specific acute or chronic health impact noted.

12. Ecological Information


Ecotoxicological data
Components Species Test Results
Iron (CAS 7439-89-6)
Aquatic
Fish LC50 Channel catfish (Ictalurus punctatus) > 500 mg/l, 96 hours
Sodium silicate (CAS 1344-09-8)
Aquatic
Crustacea EC50 Water flea (Ceriodaphnia dubia) 0.28 - 0.57 mg/l, 48 hours
Fish LC50 Western mosquitofish (Gambusia affinis) 1800 mg/l, 96 hours

Ecotoxicity Alloys in massive forms present a limited hazard for the environment.
Environmental effects Significant environmental persistence and bioaccumulation can be expected.
Persistence and degradability The product is not biodegradable.
Bioaccumulation / The product contains potentially bioaccumulating substances.
Accumulation
Mobility in environmental Alloys in massive forms are not mobile in the environment.
media

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13. Disposal Considerations
Waste codes The waste code should be assigned in discussion between the user, the producer and the waste
disposal company.
Disposal instructions Dispose in accordance with all applicable regulations.
Waste from residues / unused Scrapped material should be sent for refining to recover precious metal content. Solid metal and
products alloys in the form of particles may be reactive. Its hazardous characteristics, including fire and
explosion, should be determined prior to disposal.
Contaminated packaging Since emptied containers may retain product residue, follow label warnings even after container is
emptied.

14. Transport Information


DOT
Not regulated as a hazardous material by DOT.
IATA
Not regulated as dangerous goods.
IMDG
Not regulated as dangerous goods.
TDG
Not regulated as dangerous goods.

15. Regulatory Information


US federal regulations This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication
Standard, 29 CFR 1910.1200.
All components are on the U.S. EPA TSCA Inventory List.
TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D)
Not regulated.
Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List
Manganese (CAS 7439-96-5)
US EPCRA (SARA Title III) Section 313 - Toxic Chemical: De minimis concentration
Aluminum oxide (CAS 1344-28-1) 1.0 %
Manganese (CAS 7439-96-5) 1.0 %
US EPCRA (SARA Title III) Section 313 - Toxic Chemical: Listed substance
Aluminum oxide (CAS 1344-28-1) Listed.
Manganese (CAS 7439-96-5) Listed.
CERCLA (Superfund) reportable quantity (lbs) (40 CFR 302.4)
None
Superfund Amendments and Reauthorization Act of 1986 (SARA)
Hazard categories Immediate Hazard - Yes
Delayed Hazard - Yes
Fire Hazard - No
Pressure Hazard - No
Reactivity Hazard - No
SARA 302 Extremely hazardous substance
Not listed.
SARA 311/312 Hazardous Yes
chemical
Drug Enforcement Not controlled
Administration (DEA) (21 CFR
1308.11-15)
Canadian regulations This product has been classified in accordance with the hazard criteria of the CPR and the MSDS
contains all the information required by the CPR.
WHMIS status Controlled
WHMIS classification D2A - Other Toxic Effects-VERY TOXIC

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WHMIS labeling

Inventory status
Country(s) or region Inventory name On inventory (yes/no)*
Canada Domestic Substances List (DSL) No
Canada Non-Domestic Substances List (NDSL) Yes
United States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory No
*A "Yes" indicates this product complies with the inventory requirements administered by the governing country(s).
A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing
country(s).
State regulations WARNING: This product contains chemical(s) known to the State of California to cause cancer
and birth defects or other reproductive harm.
US - California Hazardous Substances (Director's): Listed substance
Aluminum oxide (CAS 1344-28-1) Listed.
Iron (CAS 7439-89-6) Listed.
Manganese (CAS 7439-96-5) Listed.
Mica (CAS 12001-26-2) Listed.
Zirconium silicate (CAS 1214-23-4) Listed.
US - California Proposition 65 - Carcinogens & Reproductive Toxicity (CRT): Listed substance
Titanium dioxide (CAS 13463-67-7) Listed.
US - California Proposition 65 - CRT: Listed date/Carcinogenic substance
Titanium dioxide (CAS 13463-67-7) Listed: September 2, 2011 Carcinogenic.
US. Massachusetts RTK - Substance List
Aluminum oxide (CAS 1344-28-1) Listed.
Calcium carbonate (CAS 1317-65-3) Listed.
Cellulose (CAS 9004-34-6) Listed.
Magnesium carbonate (CAS 546-93-0) Listed.
Manganese (CAS 7439-96-5) Listed.
Mica (CAS 12001-26-2) Listed.
Titanium dioxide (CAS 13463-67-7) Listed.
US. New Jersey Worker and Community Right-to-Know Act
Aluminum oxide (CAS 1344-28-1)
Calcium carbonate (CAS 1317-65-3)
Cellulose (CAS 9004-34-6)
Magnesium carbonate (CAS 546-93-0)
Manganese (CAS 7439-96-5)
Mica (CAS 12001-26-2)
Titanium dioxide (CAS 13463-67-7)
US. Pennsylvania Worker and Community Right-to-Know Law
Aluminum oxide (CAS 1344-28-1)
Calcium carbonate (CAS 1317-65-3)
Cellulose (CAS 9004-34-6)
Manganese (CAS 7439-96-5)
Mica (CAS 12001-26-2)
Titanium dioxide (CAS 13463-67-7)

16. Other Information


Further information HMIS® is a registered trade and service mark of the NPCA.
A HMIS® Health rating including an * indicates a chronic hazard.
HMIS® ratings Health: 2*
Flammability: 0
Physical hazard: 0

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NFPA Ratings

0
2 0

Disclaimer The information in the sheet was written based on the best knowledge and experience currently
available.

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918578 Version #: 01 Revision date: - Issue date: 25-March-2014 10 / 10

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