Assignment 4: Solutions

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Assignment 4: Solutions Page |1

Q1
From (41) in summary for Week 4,

=− ⇒ =−

Given that ( − ) =

⇒ = + ⇒ = ⟹ =− =−
Assignment 4: Solutions Page |2

Q2
From (42) in summary for Week 4,

= + −

At constant T, for one mole

= −

Given that ( − ) =

⇒ = + ⇒ = ⇒ = − = + −

⇒ = ⇒∆ = ( − ) = 38.7 × 10 × (11 − 1) × 10
= 38.7 J
Assignment 4: Solutions Page |3

Q3
From (42) in summary for Week 4,

= −

At constant T,

=−

Given that ( − ) =

⇒ = + ⇒ = ⇒ =− =−

11
⇒ ∆ = − ln = −8.314 ln = −19.93 J mol K
1
Assignment 4: Solutions Page |4

Q4
From the given diagram
= 210 = 400 kJ kg

∆ = 210 − 400 = −190 kJ kg


Assignment 4: Solutions Page |5

Q5
The vapor coming out is saturated. From the saturated steam tables at 1 bar
 = 372.78
 = = 2675.4 kJ kg
 = = 7.3598 kJ kg K

Since the process is isentropic,


 = ⇒ = 7.3598 kJ kg K
In addition, it is given that,
 = 20

We look superheated steam tables for inlet temperature and enthalpy; the conditions
known are and as above.
 At = 20 and T = 723.15 K, = 7.2859 kJ kg K
 At = 20 and T = 748.15 K, = 7.3602kJ kg K

Thus, 723.15 < < 748.15 . Linear interpolation gives = 748.01

 At = 20 and T = 723.15 K, = 3357.8 kJ kg


 At = 20 and T = 748.15 K, = 3412.5 kJ kg
Linear interpolation gives
 At = 20 and = 748.01 , = 3412.21 kJ kg

Applying first law,


= ∆ = 10 × (3412.21 − 2675.4) = 7368.1 kJ s

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