CPCI CuringPrecastGuide EnglishRevMay2016 02
CPCI CuringPrecastGuide EnglishRevMay2016 02
CPCI CuringPrecastGuide EnglishRevMay2016 02
TECHNICAL GUIDE
Acknowledgements: CPCI wishes to thank the contributions to this paper by Mel Marshall,
Mel C Marshall Industrial Consultants Inc.
DISCLAIMER: Substantial effort has been made to ensure that all data and information in this
publication is accurate. CPCI cannot accept responsibility of any errors or oversights in the use of
material or in the preparation of engineering plans. The designer must recognize that no design
guide can substitute for experienced engineering judgment. This publication is intended for use by
professional personnel competent to evaluate the significance and limitations of its contents and
able to accept responsibility for the application of the material it contains. Users are encouraged to
offer comments to CPCI on the content and suggestions for improvement. Questions concerning
the source and derivation of any material in the design guide should be directed to CPCI.
Background. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 4
Concluding Remarks. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 19
References. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 19
Proper curing of concrete is critical to ensuring a product that is strong, watertight, and durable.
Curing is the chemical reaction (referred to as hydration) that occurs between the cementitious
materials and water, to form a Calcium Silicate Hydrate (CSH) gel, or the “glue” that binds all of
the ingredients together. In order to achieve complete hydration, it is imperative that moisture
not evaporate from the product, and that the product be in a heated environment. This paper
discusses the curing cycle for precast concrete cured in controlled environments, with
special emphasis on: (1) the allowable maximum curing temperature to avoid delayed
ettringite formation (DEF) and (2) the duration of curing required for high performance
concrete.
Background
There are essentially three basic curing methods, all of which are designed to keep the concrete
product moist:
1. One method is to maintain the presence of mixing water in the product while it hardens.
This can be achieved by ponding, fogging or spraying, and wet coverings such as wet
burlap.
3. One of the most common methods, used at precast plants, is accelerated curing where
strength gain is accelerated by the use of live steam, radiant heat or heated beds. The
use of commercial accelerating admixtures is also commonly used by some precast
manufacturers.
Live low-pressure steam curing, in tandem with tarping or covering (See Figure 1) is a common
method because it has the advantage of providing the heat necessary to accelerate the hydration
process, while also ensuring the retention of moisture in the product. In order to be effective, it is
necessary to follow a proper curing cycle.
1. Preset (or Pre-heating) – this is the initial set of the concrete. Preset allows the product a period of time to
commence hydration, and is an important part of the cycle. Subjecting the product to higher temperatures
before the product has begun hydration can result in thermal shock, and cracking.
2. Ramping – this is the period during which the product is raised from the preset temperature to the
curing target temperature, and must be done at a controlled rate of between 10°C to 20°C per hour.
The minimum temperature of 10°C/hour is required to rapidly activate the hydration process, while the
maximum temperature of 20°C/hour is necessary to prevent thermally shocking the product.
3. Holding Period – the product is held at the target curing temperature (60°C to 70°C) until the desired
concrete strength is developed.
4. Cooling Period – the product temperature is cooled at a maximum rate of 15°C/hr and the internal
temperature is monitored until the concrete temperature is not more than 20°C above the ambient
temperature. The product may be stripped, handled and placed outdoors during this period.
Idealized Accelerated Curing Cycle
• 1) Pre-steaming
• 2) Ramping
• 3) Holding
• 4) Cooling
In general, the higher the curing temperature, the faster the desired concrete strength is achieved. Precasters
typically achieve 28 day strengths at stripping times of 16 hours or less, depending on the concrete mix design.
This curing cycle enables them to reuse their forms on a 24 hour cycle.
There is a limit, however, on what the maximum temperature can be, to prevent Delayed Ettringite Formation
(DEF), and damage to the product. The maximum curing temperature that is generally acknowledged by most
authorities is 70°C, for products that are exposed to damp or continuously wet conditions in their service life.
During the late 1990s, DEF (a form of internal sulfate attack) was a major concern throughout Europe,
especially in relation to the production of structural elements such as girders. Many manufacturers were
curing their products at very high temperatures in excess of 70°C, and as high as 90°C, in order to “double
pour” their sections within a 24 hour period. At the same time, however, the cements contained a relatively
high percentage of sulfates. As a result, products that were exposed to a moist environment experienced
deleterious cracking, after only a few years. Upon investigation, this was determined to be a result of DEF.
Although ettringite is a normal product of early hydration of Portland cement, curing at too high a
temperature stops the formation of ettringite during the early hydration process. If the concrete product is
later exposed to water, or wet conditions at ambient temperature, ettringite slowly forms and grows in the
matrix, leading to a deleterious expansion of the concrete and destructive cracking, known as DEF.
In 1996, RILEM (Reunion Internationale des Laboratoires d’Essais et de Recherches sur les Materiaux et les
Constructions) established TC-ISA, a technical committee to study field problems, with regards to DEF and
cracked concrete1. Frequently, RILEM establishes technical committees (TCs) to investigate specific problems
with construction materials. Typically, the TCs have a maximum life span of four years, however, this committee
continued its work until they were disbanded in 2002.
Consensus was reached that internal sulfate attack had not been an issue until the early 1990s. It was in the
1990s that cement manufacturers increased the sulfate content of clinkers or cements, and increased the
fineness of their cements (Blaine surface area) in response to the increased demand for accelerated early
strength development. Committee members believed that this, combined with excessively high curing
temperatures, was the principal cause of DEF. While some of the researchers believed a maximum curing
temperature of 65°C should be recommended, others acknowledged a maximum of 70°C2.
Today, a maximum curing temperature of 70°C is commonly accepted around the world3,4,5,6,7,8 while some
authorities permit up to 77°C if Supplemental Cementitious Materials, such as Fly Ash, Ground Granulated
Blast Furnace Slag, or Silica Fume are added to the concrete or blended into the cement.
The American Concrete Institute (ACI)9 defines DEF as a form of sulfate attack by which mature hardened
concrete is damaged by internal expansion during exposure to cyclic wetting and drying in service and caused
by the late formation of ettringite, not because of excessive sulfate; not likely to occur unless the concrete has
been exposed to temperatures during curing of 158°F (70°C) or greater and less likely to occur in concrete
made with pozzolan or slag cement.
For concrete products exposed to infrequent wetting, and those that are continually dry for their service lives,
a maximum curing temperature of 82°C has been shown to be effective in ensuring long-term durability.
The round-robin testing compared the effects of three different curing regimes (air curing after 16 hour
accelerated curing, air curing after 72 hours moist curing, and air curing after 168 hours moist curing) on the
compressive strength and rapid chloride penetration properties of precast concrete of samples produced by
nine permanent precast concrete plants. The project’s goal was to investigate the effects of the accelerated
curing regimes on a variety of different concrete mixes particular to the plants, rather than using one standard
mix for all of the plants. Each of the nine permanent precast concrete plants participating in the round-robin
therefore used a mix design that was commonly used in their daily production for its clients. NRCC reviewed
the historical performance data for each plant and verified that the compressive strength values measured in
the test program were consistent with those typically measured at each plant, indicating that the mixes used in
the research project were typical of those produced by the companies.
Compressive strength and rapid Table 1. Performance Requirements for High Performance C-1 and C-XL
chloride penetration (RCP) tests Concrete According to CSA A23.1-09
were carried out on specific CSA
A23.1 C-1 and C-XL samples *
produced in the controlled
environments of the plants. Two
plants produced C-1 samples
while 7 produced C-XL samples,
all based on their own standard
mixes. Samples were tested at 28
and/or 56 days of age according
to the requirements of CSA
A23.1-09 (See Table 1). *At the time of this study the age of testing for RCP was 56 days.
CSA A23.1-14 now permits RCP to be achieved within 91days.
All of the plants produced
samples that met the criteria of CSA A23.1 in terms of compressive strength and RCP for all curing
regimes. More importantly, the samples that were air cured after 16 hour accelerated curing were
statistically the same as the 168 hour moist cured samples at a 0.957 statistical significance for
compressive strength and 0.95 for RCP.
A minimum of twenty-two compression testing and two air void samples were cast in standard 100 mm x 200
mm cylindrical moulds at most plants. Three 650 mm x 500 mm x 150 mm slabs were cast at each plant for use
in coring samples for rapid chloride tests. The samples reached maximum internal temperatures between 46
and 56oC during the casting process, meeting the CSA A23.4-09 maximum temperature requirement of 60oC
for damp conditions. A maximum temperature of 70oC is proposed for CSA A23.4-15.
The test cores were obtained from the slab samples cast at the plants from at least 50 mm from an edge of the
slab using a water cooled diamond core bit and were taken through the full depth of the slab. In the case of
the tests according to ASTM C1202, three cores had a 10 mm surface removed from each sample. The next 50
mm of sample was then tested and the results averaged. In the case of the samples for CSA S413, 10 mm was
removed from the top and bottom surfaces of two cores and 30 mm from the middle, resulting in 50 mm thick
top and bottom samples from each core, for a total of 4 tests per curing condition and age.
Figure 6 . Effects of curing regime on ASTM C1202 rapid chloride penetration results for C-1 mixes
Figure 7. Effects of curing regime on rapid chloride penetration according to ASTM C1202 at 56 days age for
C-XL mixes
RCP testing was also conducted according to CSA S413. CSA S413 requires separate measurements of top
and bottom sections of the slab. The results from these tests are therefore presented in Tables 6 through 9. In
all cases, the RCP results meet the required performance with samples air cured after heating, and in
all cases the top and bottom cores for the air cured after heating were statistically the same as the 168
hour moist cured samples, at a 0.95 probability of acceptance.
Table 6. CSA S413 rapid chloride penetration results for C-1 mixes (top of slab)
Table 7. CSA S413 rapid chloride penetration results for C-1 mixes (bottom of slab)
Table 9. CSA S413 rapid chloride penetration results for C-XL mixes at 56 days age (bottom of slab)
Table 10. Matched pair T-test results for 56 day old C-XL samples
*Note: All T-test values in the above table compare the air cured after heating and the 72 hour moist cure samples to the
168 hour moist cured samples. If the calculated T value is less than 1.943, then the data set being tested is considered
to have no differences from the control data set at a 0.95 probability of acceptance. The T value of 2.09 corresponds
to a probability of acceptance of 0.957 (ie. +/-2.02 standard deviations from the norm) which is the typical standard of
control for concrete testing.
In 2015, CPCI commissioned research by the University of Toronto12 to further investigate the durability of
accelerated cured high performance concretes, specifically the effect on the surface absorption of chlorides.
Of particular interest was the examination of the outer 10 to 20 mm of concrete cover, and its resistance to
chloride penetration by de-icing salts.
Five precast concrete slabs (275mm x 375mm x 100mm in size) were cast at a precast plant and the mix used
was a 60 MPa C-XL concrete mixture, which was then subjected to varying curing regimes. ASTM C1585 rate
of absorption tests were conducted on the formed face, and surfaces 10 and 20mm from the formed face (see
Figure 8). Instead of using water for this test, a 2.8M NaCl solution was used. The purpose was to determine
whether the differences in curing regimes affected the surface absorption relative to absorption of the interior
of each concrete slab, and also to see if the depth of near surface chloride penetration was affected. The test
specimens were exposed to salt water absorption for a total of 8 days and the depth of chloride penetration
was determined on split surfaces using silver nitrate spray.
Figure 8. Schematic showing the location of the tested surface of the rate of absorption tests
on 100 mm diameter cores in the 100 mm thick slabs
The values given in Table 11 show the rate of absorption results and the average depth of chloride penetration
after the 8-day test. The initial rate of absorption is of most interest in terms of relating to chloride ingress from
salt splash, with lower initial rates of absorption being better. In all curing regime scenarios, the rate of the
absorption of the formed surface (0 mm) is higher than further in (10 and 20 mm). This is likely in large part due
to the formed surface having a paste layer, while the 10 and 20 mm depth tests were on saw cut surfaces. The
results in all cases are very similar and, from Table 12, it can be seen that the initial rates of absorption at the
surface relative to 20 mm inside the slab are no worse for the high-temperature cured slab with no additional
moist curing than for the slabs that received additional moist curing. The depth of chloride penetration after
absorption from the formed surfaces was only 0.3 to 1.7 mm deeper than from surfaces at 10 or 20 mm depth.
Six days of additional moist curing after the accelerated curing regime did not reduce the depth of chloride
penetration relative to the accelerated cured slab with no additional moist curing.
Table 12. Ratio of Initial Rate of absorption values at the Formed surface to 20 mm below
In addition to the ASTM C1585 tests, the Nordtest NT492 (AASHTO TP64) rapid migration test13 was
conducted on a slice of each concrete slab with the face exposed to sodium chloride in the test being the one
perpendicular to the cured face, as shown in Figure 9. This approach was used by Hooton et al14 and by Ha15 to
demonstrate the impact of curing on the chloride resistance and service life of concrete.
(2) T
he impact of placing one concrete slab immediately after accelerated curing at one day of age to
low-temperature (2-4oC) storage (simulating cold outdoor temperatures) had no impact on initial rates
of surface absorption and did not have any bigger impact than the depth-dependent chloride diffusion
tests on the outer few millimetres below the cast and formed surfaces.
(3) Relative to any of the specimens that were accelerated cured, 7 days of ambient temperature moist
curing resulted in a better (lower) average chloride diffusion and better (higher) cylinder strengths.
However, for the same relative comparison, 7 days of ambient temperature most curing had no net
positive effect on either the rapid chloride permeability when measured in accordance to ASTM C1012,
or the initial rate of absorption, when measured in accordance with ASTM C1585, or chloride penetration
after 8 days of absorption. Finally, for the same comparison, the bulk resistivity of the ambient
temperature moist cured specimens showed significantly lower results than the accelerated cured
specimens, but for this test “lower” is a “worse” condition.
The accelerated curing scenarios therefore closely mirror what was done in the NRCC research10 previously
described in this report.
The report went on to say that “Concrete mixtures containing 8% Silica Fume and 25% slag appear to
have good potential for use in precast operations employing accelerated curing. They combine high early
strength with superior chloride penetration resistance and are easier to place and finish than concretes
that contain 8% SF alone.” It should also be noted that the NRCC research10 study in this report utilized
C-XL mixes with either silica fume contents of between 5-8%, 25% blast furnace slag content and/or fly ash
contents of 8-9%.
Another final interesting outcome of the study16 was the relation of rapid chloride penetration testing
(ASTM C1202) to bulk diffusion. This report found a high correlation between the two, of r2 equal to 0.973.
Chloride migration testing was also conducted and also related well.
References
1. International RILEM TC 186-ISA Workshop on Internal Sulfate Attack and Delayed Ettringite Formation, 4-6 September
2002, Villars, Switzerland INTERNAL SULFATE ATTACK-POINTS OF AGREEMENT AND DISAGREEMENT Jan Skalny
2. International RILEM TC 186-ISA Workshop on Internal Sulfate Attack and Delayed Ettringite Formation, 4-6 September
2002, Villars, Switzerland Summary of Discussions During Workshop
3. US Department of Transportation, Federal Highway Administration, HPC Bridge Views – Issue 47, Jan/Feb 2008
Thermal Mass Issues in High Performance Concrete, John Gaida, CTL Group, http://www.hpcbridgeviews.com/
directory3.asp
4. US Department of Transportation, Federal Highway Administration, HPC Bridge Views – Issue 47, Jan/Feb 2008, Mass
Concrete Provisions in Texas, Kevin R. Pruski and Ralph Browne, Texas Department of Transportation, http://www.
hpcbridgeviews.com/directory3.asp
5. Center for Transportation Research The University of Texas at Austin, Preventing Alkali-Silica Reaction and Delayed
Ettringite Formation in New Concrete, Project Summary Report 0-4085-S, March 2006, http://www.utexas.edu/research/
ctr/pdf_reports/0_4085_S.pdf
6. Portland Cement Association, PCA, Ettringite Formation and the Performance of Concrete, IS417, Portland Cement
Association, 2001, http://www.cement.org/tech/faq_DEF.asp
7. Florida Department of Transportation, Determination of the Maximum Placement and Curing Temperatures in Mass
Concrete to Avoid Durability Problems and DEF, University of Florida 2003 Report, Chinietal.http://www.dot.state.fl.us/
research-center/Completed_Proj/Summary_SMO/FDOT_BC354_29_rpta.pdf
8. Cement and Concrete Research 31, 2001, The semiquantitative dertermination and morphology of ettringite in pastes
containing expansive agent cured in elevated temperature, Tsinghua University, Beijing
9. American Concrete Institute ACI CT-13, ACI Concrete Terminology, (2013), Farmington Hills, MI, 48331, U.S.A.
10. Makar, J.M., Effect of Curing Conditions on the Performance of Accelerated Curing Precast Concrete, 2014, Report
A1-000435-2, National Research Council Canada: Ottawa, ON
11. Downing, D. and Clark, J., Statistics The Easy Way, 1997, pp. 205-6, Barron’s: Hauppauge, New York.
12. R. D. Hooton, Effects of Different Accelerated and Moist Curing Periods on Chloride Penetration Resistance of Precast
Concrete Elements, Canadian Precast/Prestressed Concrete Institute, 2015
13. Nordtest NT Build 492, Chloride Migration Coefficient From Non-Steady-State Migration Experiments, Nordtest, P.O.
Box 116 FIN–02151 Espoo, Finland, 1999.
14. Hooton, R.D., Geiker, M.R. and Bentz, E.C., “Effects of Curing on Chloride Ingress and Implications for Service Life”,
ACI Materials Journal, Vol. 99, No. 2, 2002, pp. 201-206.
15. Ha, My Phuong, “Quantification of Curing Effects on Chloride Ingress,” MASc Thesis, University of Toronto, 2003.
16. R.D. Hooton, M.P. Titherington, Chloride resistance of high performance concretes subjected to accelerated curing,
2004, Cement and Concrete Research 34 (2004) 1561–1567: www.sciencedirect.com
www.cpci.ca