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Ciência & Tecnologia dos Materiais 29 (2017) e198–e203

Special Issue “Materiais 2015”

Foamed bitumen: an alternative way of producing asphalt mixtures

Liliana Abreua, *, Joel Oliveirab, Hugo Silvab, Catarina Silvaa, Daniela Palhac, Paulo Fonsecac
a
Department of Civil Engineering (DEC), University of Minho, Guimarães 4800-058, Portugal
b
Centre for Territory, Environment and Construction (CTAC), University of Minho, Guimarães 4800-058, Portugal
c
Elevogroup, MonteAdriano Engenharia e Construção, Porto 4250-311, Portugal

Abstract
With the constant need to improve and make the production of asphalt mixtures more sustainable, new production techniques have
been developed, the implementation of which implies the correct knowledge of their performance. One of the most promising
asphalt production techniques is the use of foamed bitumen. However, it is essential to understand how this binder will behave
when subjected to the expansion process. The loss of volume of the foamed bitumen could be translated by a decay curve, which
allows to determine the ideal temperature and water content added to the bitumen in order to assure adequate conditions to the mix
the bitumen with the aggregates. On the present study, a conventional 160/220 pen grade bitumen was tested by using different
temperatures and water contents, and it was concluded that the optimum temperature for the production of foamed bitumen (with
the studied bitumen) is 150ºC, which corresponds to a viscosity of 0.1 Pa.s. The water content mostly influence the half-life of the
bitumen foam, resulting in quicker volume reductions for higher water contents.
© 2017
© 2017 Portuguese
Portuguese Society
Society of
of Materials
Materials (SPM).
(SPM). Published
Published by
by Elsevier
Elsevier España,
España,S.L.U.. All rights
S.L.U. All rights reserved.
reserved.
Keywords: Warm mix asphalt; foamed bitumen; asphalt mixtures; bitumen foaming characteristics.

1. Introduction * incorporate reclaimed asphalt materials. The need to

mitigate the influence of the production in the ageing
The asphalt pavement industry has been more of bitumen results in the use of different heating
concerned with the environment in the last years. The temperatures of the aggregates and reclaimed
need to mitigate the negative impact of the road materials [1,2].
construction on the environment has resulted in a high The utilization of high temperatures to the production
number of new techniques that reduce the adverse and application of new asphalt mixtures also cause a
effects of the production of asphalt mixtures. high level of GHG emissions. For that reason, the
The asphalt mixtures comprise about 95% of mineral industry has been developing techniques to reduce the
aggregates and 5% of bitumen. Due to its viscoelastic production temperatures of the mixtures. This type of
nature, bitumen presents a liquid form when heated up mixtures are normally classified as half-warm or warm
to temperatures around 150ºC and a solid form at mix asphalts. The classification of half-warm mixtures
ambient temperatures. Thus, the production of asphalt is given to mixtures produced between 70 and 100ºC,
mixtures has traditionally been made using high and the warm mixtures are produced between 100 and
temperatures to be able to work with the bitumen. 140ºC [3].
These temperatures are even higher when the mixtures A significant number of advantages can be associated
to the use of warm mix asphalt (WMA) in a global
perspective, i.e., without differentiating between the
techniques applied. The reduction of production
*
Corresponding author. temperature reduces the gas emissions and the energy
E-mail address: [email protected] (L. Abreu)

© 2017 Portuguese Society of Materials (SPM). Published by Elsevier España, S.L.U. All rights reserved.
http://dx.doi.org/10.1016/j.ctmat.2016.07.004
 Liliana Abreu et al. / Ciência & Tecnologia dos Materiais 29 (2017) e198–e203 e199

consumption, while improving the working conditions is the time measured between the moment that the
[4]. Associated to those main advantages, others can foamed bitumen reaches its maximum volume and the
be mentioned, namely, the cost reduction associated to moment it reaches half of that value. Jenkins [8] also
the lower energy consumption, the increase on the mentions the foam index (FI) as a characteristic that
transport distances due to the lower compaction should be used to choose the ideal conditions for the
temperatures [5], and could also extend the paving expansion process. The FI is obtained by applying a
windows [6], with the mixtures being applied in theoretical expression to the decay curve, and
conditions worse than those of hot mix asphalts calculating the area of the graph between the decay
(HMA). curve and a lower limit associated with the adequate
WMA mixtures can be produced by different viscosity of the bitumen to be mixed with the
techniques, using organic or chemical additives or aggregates. In terms of the decay curve (DC), this is
foaming processes [7]. The latter can be obtained by the representation of the evolution of the ER as a
water-containing technologies or by water-based function of the elapsed time.
technologies [6]. Water-containing technologies are The expansion characteristics of the bitumen is
obtained by incorporating additives which include influenced by different parameters. Some studies
water in their composition, while, in the water-based mention that a softer bitumen, combined with high
technologies, the water is injected into the hot bitumen temperatures, have better results than a harder bitumen
in small quantities and immediately added to the [9]. However, other study mentions that the viscosity
aggregates in the asphalt mixing chamber [4]. This is one of the most important parameters, i.e., different
process is normally more technically complex and bitumen foamed at equiviscous temperatures will have
requires a relatively large financial investment for identical characteristics [10].
plant modifications. For the present study, only one bitumen was analysed,
To the production of foamed bitumen by direct but with different water contents and temperatures, in
injection of water, the air and the water are injected in order to understand the influence of that type of
the bitumen as show in Fig. 1. variables on the bitumen decay curve.

2. Materials and Methods

The material used in this study was essentially a

160/220 pen grade bitumen. This bitumen has been
chosen taking into account the literature review that
mentions that softer bitumens have generally better
foaming results.
To the production of foamed bitumen, a Wirtgen WLB
Fig. 1. Schematic procedure of producing foamed bitumen (adapted 10 S machine was used. This equipment has been
from [11]). developed to a laboratory scale with the objective of
making the analysis of FB characteristics in small
Jenkins [8] mentioned that the foamed bitumen scale possible, but it is similar to the equipments used
process is analogous to a baker beating an egg, which in normal scale [11]. In order to reduce the number of
is viscous, into foam of low viscosity before mixing it variable under study, the air pressure was maintained
with flour. The beaten egg increases in volume, which with the default value (5.5 bar; 550 kPa), the
is necessary in order to evenly distribute it among the temperature of all components of the machine were
flour and produce a mix of acceptable quality and adjusted to the same temperature of the bitumen and a
consistency. Similarly, the foamed bitumen increases nozzle with 2 mm of diameter (capable of injecting
in volume, facilitating a good bitumen distribution 50 g of bitumen per second) was selected.
over the aggregates.
The two basic characteristics of foamed bitumen are 2.1. Basic characteristics
the maximum expansion ratio (ERmax) and the half-
life (HL). The expansion ratio (ER) is the ratio Regarding the basic characteristics of the bitumen,
between the volume of the bitumen in a specific time penetration (EN 1426) [12], softening point (EN 1427)
and the initial volume; the ERmax is the maximum [13] and dynamic viscosity (EN 13302) [14] tests were
value of the ER, immediately after injection. The HL carried out. To complete the analysis of the bitumen,
e200 Liliana Abreu et al. / Ciência & Tecnologia dos Materiais 29 (2017) e198–e203

its rheological properties have been tested (EN 14770) The dynamic viscosity of the bitumen (Fig. 3) is
[15] with the Dynamic Shear Rheometer (DSR), for a important to determine the adequate temperature for
temperature range between 19 and 88ºC. testing the expansion characteristics. For that study, it
was decided to use the temperature at which the
2.2. Expansion characteristics bitumen presents a viscosity of 0.1 Pa.s at the
intermediate temperature tested (150ºC).
The expansion characteristics of foamed bitumen are
essential to define the optimum combination of 100000

Dynamic Viscosity (Pa.s)

parameters that influence the foam stability during the 10000
mixing process. For a good characterization of the 1000
expansion properties, two parameters have to be
100
determined, namely, the maximum expansion ratio
10
(ERmax) and the half-life (HL).
In this study, the foam index (FI) values have also 1
been calculated, using the equation developed by 0.1
Jenkins [8], and the decay curves (DC) were presented 0.01
to understand how the process of expansion decay 0 50 100 150 200
changes with variations on the temperature (140, 150 Temperature (°C)
and 160ºC) and on the water content (between 2 and Fig. 3. Dynamic viscosity of the bitumen 160/220.
5% of water by mass of bitumen).
Taking the results of dynamic viscosity into
3. Results and Discussion consideration, the temperatures used to analyse the
bitumen expansion characteristics were 140, 150 and
3.1. Basic characteristics 160ºC as previously mentioned.

The results obtained for the basic characteristics of the 3.2. Expansion characteristics
bitumen (Table 1), in terms of penetration and
softening point, were in accordance with the reference Analysing the results of bitumen foaming tests,
values for that type of bitumen. namely ERmax and HL, with different water contents
(Fig. 4), it could be concluded that a higher
Table 1. Penetration and softening point of the bitumen 160/220. temperature did not result in better results in terms of
Binder Penetration (0.1 mm) Softening Point (ºC) the expansion ratio (ER), and the results show that the
Bit. 160/220 173.3 38.4
temperature associated with the reference viscosity
value (0.1 Pa.s) conducted to the best combination of
expansion characteristics for the studied bitumen.
In terms of rheology, the results for complex modulus
and phase angle are presented in Fig. 2. The higher
performance grade (PG) limit obtained for this 140 °C 150 °C 160 °C
30 60
bitumen was 52ºC.
25 50
1000 90
20 40
HL (seconds)
ERmax

100 80
15 30
Phase Angle (°)
G*(kPa)

10 70
10 20
1 60
5 10
0.1 50

0.01 40
0 0
10 30 50 70 90 1% 2% 3% 4% 5% 6%
Temperature (°C) Water content
Fig. 2. Complex modulus (continuous line) and Phase Angle Fig. 4. Essential expansion characteristics of the bitumen (filled
(dashed line) of the bitumen 160/220. markers - maximum expansion ratio, unfilled markers – half-life).
 Liliana Abreu et al. / Ciência & Tecnologia dos Materiais 29 (2017) e198–e203 e201

As previously mentioned, a third parameter can be fitting of the three curves (Fig. 6). For that fitting, the
used to analyse the best combination of these two Origin software was used through the DoseResp
characteristics and their relationship. Thus, the FI has function for the category Growth/Sigmoidal. The
been calculated for all the combinations obtained and selection of that function is based on the good fitting
the results are presented in Table 2. obtained to all the results analysed.

Table 2. FI values obtained for different temperatures and water 35

contents using the 160/220 pen bitumen.
30
Temperature Water content (%)
(ºC) 25
2 3 4 5

ER
140 585.54 553.21 590.20 572.52 20
150 687.19 739.76 635.55 611.12
15
160 395.66 444.09 459.30 457.91
10
With the results presented above it is possible to say 5
that the best results were obtained for the temperature
of 150ºC and 3% water content. Whatever the FI 0
0 20 40 60 80
values obtained for the studied bitumen, they are much Time (seconds)
higher than the values mentioned by Jenkins [8] as
desirable to be used in mixtures with reclaimed asphalt Fig. 6. Fitting made with the Origin software.
pavements and in half-warm asphalt mixtures (180
sec). In terms of ERmax, all values obtained also After this first analysis, where the function that
respect the desirable value mentioned by the author, describes the DC to all the parameters were obtained,
but the same did not happen to the HL, where the and in order to understand how the temperature and
desirable value is 13 seconds, which was not respected the water content change the foaming characteristics
in any test carried out at 160ºC and in the tests carried of the bitumen, the DC of the foamed bitumen
out with the water contents of 4 and 5% at 150ºC. produced at 150ºC with 3 % water was compared with
The decay curves (DC) of the bitumen for a given that of the foamed bitumen produced at the same
temperature and water content have been obtained for temperature but with 5% of water (Fig. 7) and with the
a numerical analyses of three different test repetitions. foamed bitumen produced at 140ºC and with the same
These have been performed due to the uncertainty of water content (Fig. 8).
the results obtained in each foamed bitumen injection.
Thus, three injections were carried out for each 35
5%
combination of parameters (Fig. 5). 30 3%

35 25
ER

30 20

25 15

10
ER

20
5
15
0
10 0 20 40 60 80

5 Time (seconds)
0 Fig. 7. Decay curves of the foamed bitumen produced at 150ºC with
0 20 40 60 80 different water contents.
Time (seconds)
The results obtained for different water contents show
Fig. 5. Decay curves obtained in three repetitions of the expansion
tests (150ºC and 3% water content). that the higher the percentage of water the quicker the
FB volume decreases, which originates worse results
The proximity showed in the DCs give the possibility in terms of HL. In terms of the ERmax, the results
to convert these three curves in a unique curve using a were very similar, as previously presented in Fig. 4.
e202 Liliana Abreu et al. / Ciência & Tecnologia dos Materiais 29 (2017) e198–e203

35 Acknowledgements
140
30 150
This work was funded by FEDER funds through the
25 Operational Programme for Competitiveness Factors –
COMPETE, given to the project “Energy Efficiency
ER

20

15
and Environmental Design of Bituminous Mixtures to
Reduce Emissions of Greenhouse Gases” (QREN-SI
10
090528), of the company ELEVO Group, which was
5 carried out in cooperation with the University of
0 Minho. Thanks are also due to the Foundation for
0 20 40 60 80 Science and Technology (FCT) for funding allocated
Time (seconds) through the PhD Scholarship SFRH/BD/85448/2012,
Fig. 8. Decay curves of the foamed bitumen produced with 3% and to the companies GALP and ELEVO Group., who
water using different temperatures. provided the binder and the reclaimed asphalt used in
this study.
In terms of temperature used in the production of
foamed bitumen, it is clear that a small variation on
the temperature can change the behaviour of the DC in References
a significant way. According to the results presented
in Fig. 8, it can be concluded that even though the [1] L.P.F. Abreu, J.R.M. Oliveira, H.M.R.D. Silva, P.V.
volume decrease with time is slower for the Fonseca, Constr. Build. Mater. 84 (2015) 230.
temperature of 140ºC than that observed for the [2] D. Palha, P. Fonseca, L.P.F. Abreu, J.R.M. Oliveira,
H.M.R.D. Silva, Proceedings of 2nd International
temperature of 150ºC, the maximum expansion was Conference - WASTES: solutions, treatments, opportunities,
significantly lower for the temperature of 140ºC. This Braga, Portugal, September 11-13, 2013.
may compromise the operation of adequately mixing [3] EAPA - European Asphalt Pavement Association, The
the foamed bitumen with the aggregates. use of warm mix asphalt, Brussels, Belgium, 2010.
[4] M. Zaumanis, V. Haritonovs, G. Brencis, J. Smirnovs,
4. Conclusions Constr. Sci. 13 (2012) 6.
[5] J. D’Angelo, E. Harm, J. Bartoszek, G. Baumgardner,
M. Corrigan, J. Cowsert, T. Harman, M. Jamshidi, W.
The use of foamed bitumen to produce new asphalt Jones, D. Newcomb, B. Prowell, R. Sines, B. Yeaton,
mixtures imply a complex analysis of the behaviour of Warm-Mix Asphalt: European Practice, Federal Highway
the bitumen when subjected to the expansion process. Administration, Washington, D.C., USA, 2008.
With this study, which took into consideration only [6] M.C. Rubio, G. Martínez, L. Baena, F. Moreno, J.
the results of one bitumen type (160/220 pen grade), it Cleaner Prod. 24 (2012) 76.
[7] A. Ali, A. Abbas, M. Nazzal, A. Alhasan, A. Roy, D.
was possible to conclude that there is an ideal
Powers, Constr. Build. Mater. 48 (2013) 1058.
temperature (or viscosity) to produce foamed bitumen. [8] K.J. Jenkins, PhD thesis, Faculty of Engineering,
The temperature corresponding to a viscosity of University of Stellenbosch, Stellenbosch, South Africa,
0.1 Pa.s conducted to the best results, regarding the 2000.
foaming characteristics of the studied bitumen, which [9] S. Sunarjono, PhD thesis, School of Civil Engineering -
contradicts the idea that higher temperatures always Nottingham Transportation Engineering Centre, University
of Nottingham, UK, 2008.
lead to better foaming results, as mentioned in part of
[10] M. Namutebi, Licentiate thesis, Division of Highway
the literature on this subject. and Railway Engineering, School of Architecture and the
Regarding the influence of the water content on the Built Environment - Royal Institute of Technology,
foaming characteristics, it was concluded that it affects Stockholm, Sweden, 2011.
mostly the HL. For the tests carried out at the same [11] Wirtgen, Suitability test procedures of foam bitumen
temperature, the DC showed quicker reductions in the using Wirtgen WLB 10 S, Germany, 2008.
ER for the tests carried out with higher water contents. [12] CEN, EN 1426:2007 - Bitumen and bituminous
binders. Determination of needle penetration, European
The present study highlights the importance of Committee for Standardization, Brussels, Belgium, 2007.
adequately understanding the foamed bitumen [13] CEN, EN 1427:2007 - Bitumen and bituminous
expansion process, prior to the mix design stage, in binders. Determination of the softening point. Ring and Ball
order to assure the production of quality asphalt method, European Committee for Standardization, Brussels,
mixtures when foamed bitumen is used. However, this Belgium, 2007.
study shall also be carried out for other bitumens.
 Liliana Abreu et al. / Ciência & Tecnologia dos Materiais 29 (2017) e198–e203 e203

[14] CEN, EN 13302:2010 - Bitumen and bituminous [15] CEN, EN 14770:2005 - Methods of test for petroleum
binders. Determination of dynamic viscosity of bituminous and its products. Bitumen and bituminous binders.
binder using a rotating spindle apparatus, European Determination of complex shear modulus and phase angle.
Committee for Standardization, Brussels, Belgium, 2010. Dynamic Shear Rheometer (DSR), European Committee for
Standardization, Brussels, Belgium, 2005.