SAFETY DATA SHEET

Product Trade Name: ALDACIDE® G ANTIMICROBIAL

Revision Date: 18-Apr-2018 Revision Number: 3

1. Identification
1.1. Product Identifier
Product Trade Name: ALDACIDE® G ANTIMICROBIAL
Synonyms None
Chemical Family Aldehyde
Internal ID Code HB003462

1.2 Recommended use and restrictions on use

Application Biocide
Uses advised against No information available

1.3 Manufacturer's Name and Contact Details

Manufacturer/Supplier
Baroid Fluid Services
Product Service Line of Halliburton Energy Services, Inc.
P.O. Box 1675
Houston, TX 77251
Telephone: (281) 871-4000

Halliburton Energy Services, Inc.

645 - 7th Ave SW Suite 1800
Calgary, AB
T2P 4G8
Canada

Prepared By Chemical Stewardship

Telephone: 1-281-871-6107
e-mail: [email protected]

1.4. Emergency telephone number

Emergency Telephone Number 1-866-519-4752 or 1-760-476-3962
Global Incident Response Access Code: 334305
Contract Number: 14012

2. Hazard Identification
2.1 Classification of the substance or mixture

Acute Oral Toxicity Category 4 - H302

Acute inhalation toxicity - vapor Category 2 - H331
Skin Corrosion / Irritation Category 1 B - H314
Serious Eye Damage/Irritation Category 1 - H318
Respiratory Sensitization Category 1 - H334
Skin Sensitization Category 1 - H317
Reproductive Toxicity Category 1B - H360
Specific Target Organ Toxicity - (Single Exposure) Category 3 - H335
Acute Aquatic Toxicity Category 1 - H400
Chronic Aquatic Toxicity Category 3 - H412

2.2. Label Elements

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Hazard Pictograms

Signal Word: Danger

Hazard Statements H302 - Harmful if swallowed

H314 - Causes severe skin burns and eye damage
H317 - May cause an allergic skin reaction
H318 - Causes serious eye damage
H331 - Toxic if inhaled
H334 - May cause allergy or asthma symptoms or breathing difficulties if inhaled
H335 - May cause respiratory irritation
H360 - May damage fertility or the unborn child
H400 - Very toxic to aquatic life
H412 - Harmful to aquatic life with long lasting effects

Precautionary Statements

Prevention P201 - Obtain special instructions before use

P202 - Do not handle until all safety precautions have been read and understood
P260 - Do not breathe dust/fume/gas/mist/vapors/spray
P264 - Wash face, hands and any exposed skin thoroughly after handling
P270 - Do not eat, drink or smoke when using this product
P271 - Use only outdoors or in a well-ventilated area
P272 - Contaminated work clothing should not be allowed out of the workplace
P273 - Avoid release to the environment
P280 - Wear protective gloves/protective clothing/eye protection/face protection
P284 -[In case of inadequate ventilation] wear respiratory protection.
Response P301 + P312 - IF SWALLOWED: Call a POISON CENTER or doctor/physician if
you feel unwell
P330 - Rinse mouth
P303 + P361 + P353 - IF ON SKIN (or hair): Take off immediately all
contaminated clothing. Rinse skin with water [or shower].
P363 - Wash contaminated clothing before reuse
P304 + P340 - IF INHALED: Remove victim to fresh air and keep at rest in a
position comfortable for breathing
P310 - Immediately call a POISON CENTER or doctor/physician
P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several
minutes. Remove contact lenses, if present and easy to do. Continue rinsing
P391 - Collect spillage
Storage P403 + P233 - Store in a well-ventilated place. Keep container tightly closed
P405 - Store locked up
Disposal P501 - Dispose of contents/container in accordance with
local/regional/national/international regulations

2.3 Other hazards which do not result in classification

None known

3. Composition/information on Ingredients

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Substances CAS Number PERCENT GHS Classification - HMIRA Registry Filing Date Decision
(w/w) Canada Number Granted Date
Glutaraldehyde 111-30-8 10 - 30% Acute Tox. 3 (H301) Not applicable Not Not
Acute Tox. 2 (H330) applicable applicable
Skin Corr. 1B (H314)
Eye Corr. 1 (H318)
Resp. Sens. 1 (H334)
Skin Sens. 1 (H317)
STOT SE 3 (H335)
Aquatic Acute 1 (H400)
Aquatic Chronic 2 (H411)
Methanol 67-56-1 0.1 - 1% Acute Tox. 3 (H301) Not applicable Not Not
Acute Tox. 3 (H311) applicable applicable
Acute Tox. 3 (H331)
Repr. 1B (H360)
STOT SE 1 (H370)
Flam. Liq. 2 (H225)

The exact percentage (concentration) of the composition has been withheld as proprietary.

4. First aid measures

4.1. Description of first aid measures
Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory
irritation develops or if breathing becomes difficult.
Eyes Immediately flush eyes with large amounts of water for at least 30 minutes. Seek
prompt medical attention.
Skin In case of contact, immediately flush skin with plenty of soap and water for at least
30 minutes and remove contaminated clothing, shoes and leather goods
immediately. Get medical attention immediately.
Ingestion Do NOT induce vomiting. Give nothing by mouth. Obtain immediate medical
attention.

4.2 Most important symptoms/effects, acute and delayed

Causes severe eye irritation which may damage tissue. Causes severe skin irritation with tissue destruction. May
cause allergic skin reaction. May cause allergic respiratory reaction. May cause respiratory irritation. Harmful if
swallowed. Toxic if inhaled. Potential reproductive hazard. May cause birth defects.

4.3. Indication of any immediate medical attention and special treatment needed
Notes to Physician Probable mucosal damage may contraindicate the use of gastric lavage. No specific
antidote. Treat symptomatically.

5. Fire-fighting measures
5.1. Extinguishing media
Suitable Extinguishing Media
Water fog, carbon dioxide, foam, dry chemical.
Extinguishing media which must not be used for safety reasons
None known.

5.2 Specific hazards arising from the substance or mixture

Special exposure hazards in a fire
Decomposition in fire may produce harmful gases.

5.3 Special protective equipment and precautions for fire-fighters

Special protective equipment for firefighters
Full protective clothing and approved self-contained breathing apparatus required for fire fighting personnel.

6. Accidental release measures

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6.1. Personal precautions, protective equipment and emergency procedures

Use appropriate protective equipment. Ensure adequate ventilation. Avoid breathing vapors. Avoid contact with skin,
eyes and clothing. Evacuate all persons from the area. Use only competent persons for cleanup.
See Section 8 for additional information

6.2. Environmental precautions

Prevent from entering sewers, waterways, or low areas.

6.3. Methods and material for containment and cleaning up

Isolate spill and stop leak where safe. Contain spill with sand or other inert materials. Scoop up and remove.

7. Handling and Storage

7.1. Precautions for safe handling
Handling Precautions
Use appropriate protective equipment. Ensure adequate ventilation. Avoid breathing vapors. Avoid breathing mist.
Avoid contact with eyes, skin, or clothing. Wash hands after use. Launder contaminated clothing before reuse.
Hygiene Measures
Handle in accordance with good industrial hygiene and safety practice.

7.2. Conditions for safe storage, including any incompatibilities

Storage Information
Store away from acids. Store away from alkalis. Store in a well ventilated area. Keep container closed when not in
use. Store locked up. Product has a shelf life of 36 months.

8. Exposure Controls/Personal Protection

8.1 Occupational Exposure Limits
Substances CAS Number OSHA PEL-TWA ACGIH TLV-TWA
Glutaraldehyde 111-30-8 Not applicable Not applicable
Methanol 67-56-1 TWA: 200 ppm TWA: 200 ppm
TWA: 260 mg/m3 STEL: 250 ppm

8.2 Appropriate engineering controls

Engineering Controls Use in a well ventilated area. Local exhaust ventilation should be used in areas
without good cross ventilation. If vapors are strong enough to be irritating to the
nose or eyes, the TLV is probably being exceeded and special ventilation or
respiratory protection maybe required.

8.3 Individual protection measures, such as personal protective equipment

Personal Protective Equipment If engineering controls and work practices cannot prevent excessive exposures,
the selection and proper use of personal protective equipment should be
determined by an industrial hygienist or other qualified professional based on the
specific application of this product.
Respiratory Protection If engineering controls and work practices cannot keep exposure below
occupational exposure limits or if exposure is unknown, wear a NIOSH certified,
European Standard EN 149, AS/NZS 1715:2009, or equivalent respirator when
using this product. Selection of and instruction on using all personal protective
equipment, including respirators, should be performed by an Industrial Hygienist or
other qualified professional.
Organic vapor respirator.

Hand Protection Use gloves which are suitable for the chemicals present in this product as well as
other environmental factors in the workplace.
Skin Protection Wear impervious protective clothing, including boots, gloves, lab coat, apron, rain

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jacket, pants or coverall, as appropriate, to prevent skin contact.
Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.
Other Precautions Eyewash fountains and safety showers must be easily accessible.

9. Physical and Chemical Properties

9.1. Information on basic physical and chemical properties
Physical State: Liquid Color Clear light yellow
Odor: Sharp Odor No information available
Threshold:

Property Values
Remarks/ - Method
pH: 3.1-4.5
Freezing Point / Range (-5) - (-10) °C / 14 - 23 °F
Melting Point / Range No data available
Boiling Point / Range 100.5 °C / 213 °F
Flash Point No data available
Flammability (solid, gas) No data available
Upper flammability limit No data available
Lower flammability limit No data available
Evaporation rate 0.9
Vapor Pressure 0.2 mmHg
Vapor Density 0.8
Specific Gravity 1.064
Water Solubility Soluble in water
Solubility in other solvents No data available
Partition coefficient: n-octanol/water -0.333
Autoignition Temperature > 275 °C / > 527 °F
Decomposition Temperature No data available
Viscosity No data available
Explosive Properties No information available
Oxidizing Properties No information available

9.2. Other information

VOC Content (%) No data available

10. Stability and Reactivity

10.1. Reactivity
Not expected to be reactive.

10.2. Chemical stability

Stable

10.3. Possibility of hazardous reactions

Will Not Occur

10.4. Conditions to avoid

Keep away from heat, sparks and flame.

10.5. Incompatible materials

Strong acids. Strong alkalis.

10.6. Hazardous decomposition products

Carbon monoxide and carbon dioxide.

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11. Toxicological Information
11.1 Information on likely routes of exposure
Principle Route of Exposure Eye or skin contact, inhalation; Ingestion.

11.2 Symptoms related to the physical, chemical and toxicological characteristics

Acute Toxicity
Inhalation Toxic if inhaled. Causes severe respiratory irritation. May cause allergic
respiratory reaction. Inhalation of vapors may result in skin sensitization.
Eye Contact Causes severe eye irritation which may damage tissue.
Skin Contact Causes severe burns. May cause an allergic skin reaction.
Ingestion Harmful if swallowed. Causes burns of the mouth, throat and stomach.

Chronic Effects/Carcinogenicity Prolonged or repeated exposure can cause delayed kidney damage. Prolonged or
repeated exposure may cause reproductive system damage. Prolonged or
repeated exposure may cause embryo and fetus toxicity.

11.3 Toxicity data

Toxicology data for the components

Substances CAS Number LD50 Oral LD50 Dermal LC50 Inhalation
Glutaraldehyde 111-30-8 50 mg/kg (Guinea Pig) 560 µL/kg (Rabbit) 0.28-0.5 mg/L (Rat) 4h
Methanol 67-56-1 300 mg/kg-bw (human) 1000 mg/kg-bw (human) 10 mg/L (human, vapor, 4h)
< 790 to 13,000 mg/kg (rat) 17,100 mg/kg (rabbit)

Substances CAS Number Skin corrosion/irritation

Glutaraldehyde 111-30-8 Causes severe skin irritation with tissue destruction. (Rabbit)
Methanol 67-56-1 Non-irritating to the skin (Rabbit)

Substances CAS Number Serious eye damage/irritation

Glutaraldehyde 111-30-8 Causes severe eye irritation which may damage tissue. (Rabbit)
Methanol 67-56-1 Non-irritating to the eye (Rabbit)

Substances CAS Number Skin Sensitization

Glutaraldehyde 111-30-8 Skin sensitizer in guinea pig.
Methanol 67-56-1 Did not cause sensitization on laboratory animals (guinea pig)

Substances CAS Number Respiratory Sensitization

Glutaraldehyde 111-30-8 May cause sensitization by inhalation
Methanol 67-56-1 No information available

Substances CAS Number Mutagenic Effects

Glutaraldehyde 111-30-8 In vivo tests did not show mutagenic effects.
Methanol 67-56-1 The weight of evidence from available in vitro and in vivo studies indicates that this substance is not
expected to be mutagenic.

Substances CAS Number Carcinogenic Effects

Glutaraldehyde 111-30-8 Did not show carcinogenic effects in animal experiments
Methanol 67-56-1 No data of sufficient quality are available.

Substances CAS Number Reproductive toxicity

Glutaraldehyde 111-30-8 Not a confirmed teratogen or embryotoxin.
Methanol 67-56-1 Experiments have shown reproductive toxicity effects on laboratory animals

Substances CAS Number STOT - single exposure

Glutaraldehyde 111-30-8 No information available
Methanol 67-56-1 May cause disorder and damage to the Central Nervous System (CNS)

Substances CAS Number STOT - repeated exposure

Glutaraldehyde 111-30-8 May cause disorder and damage to the Kidney
Methanol 67-56-1 No data of sufficient quality are available.

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Substances CAS Number Aspiration hazard
Glutaraldehyde 111-30-8 Not applicable
Methanol 67-56-1 No information available

12. Ecological Information

12.1. Toxicity
Ecotoxicity effects
Very toxic to aquatic life. Harmful to aquatic life with long lasting effects.
Product Ecotoxicity Data
No data available

Substance Ecotoxicity Data

Substances CAS Number Toxicity to Algae Toxicity to Fish Toxicity to Toxicity to Invertebrates
Microorganisms
Glutaraldehyde 111-30-8 EC50(72h): 0.61 mg/L LC50(96h): 10 mg/L EC50 (17h) 6.65 mg/L EC50(48h): 0.35 mg/L
(Desmodesmus (Lepomis macrochirus) (Pseudomonas putida) (Daphnia magna)
subspicatus) NOEC(97d): 1.6 mg/L EC50(48h): 0.7 mg/L
EC50(72h): 0.5 mg/L (Oncorhynchus mykiss) (Acartia tonsa)
(Skeletonema costatum) LC50(96h): 3.5 mg/L NOEC(21d): 0.13 mg/L
(Oncorhynchus mykiss) (Daphnia magna)
LC50(96h): 60 mg/L EC50(48h): 0.1 mg/L
(Scophthalmus maximus) (Acartia tonsa)
Methanol 67-56-1 EC50 (96 h) =22000 mg/L LC50(96 h)=15400 mg/L No information available NOEC(21 d)=208 mg/L
(Pseudokirchnerella (Lepomis macrochirus) (Daphnia magna)
subcapitata) EC50 (200h)=14536 mg/L EC50 (48h)=22200 mg/L
NOEC (8 d) =8000 mg/L (Oryzias latipes) (Daphnia obtuse)
(Scenedesmus
quadricauda)

12.2. Persistence and degradability

Readily biodegradable
Substances CAS Number Persistence and Degradability
Glutaraldehyde 111-30-8 Readily biodegradable (75% @ 28d)
Methanol 67-56-1 Readily biodegradable (95% @ 20d)

12.3. Bioaccumulative potential

Does not bioaccumulate.
Substances CAS Number Log Pow
Glutaraldehyde 111-30-8 -0.36
Methanol 67-56-1 Not Bioaccumulative; BCF=1

12.4. Mobility in soil

Substances CAS Number Mobility

Glutaraldehyde 111-30-8 Potential for mobility in soil is high (Koc between 50 and
150). Given its very low Henry'sconstant (3.3E-08
atm*m3/mole; 25 °C Measured), volatilization from natural
bodies of water or moist soil is not expected to be an
important fate process.
Methanol 67-56-1 No information available

12.5 Other adverse effects

No information available

13. Disposal Considerations

13.1. Waste treatment methods
Disposal methods Disposal should be made in accordance with federal, state, and local regulations.
Contaminated Packaging Follow all applicable national or local regulations.

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14. Transport Information

Canadian TDG
UN Number UN3265
UN proper shipping name: Corrosive Liquid, Acidic, Organic, N.O.S. (Contains Glutaraldehyde)
Transport Hazard Class(es): 8
Packing Group: II
Environmental Hazards: Marine Pollutant

US DOT
UN Number UN3265
UN proper shipping name: Corrosive Liquid, Acidic, Organic, N.O.S. (Contains Glutaraldehyde)
Transport Hazard Class(es): 8
Packing Group: II
Environmental Hazards: Marine Pollutant
NAERG: NAERG 153

IMDG/IMO
UN Number UN3265
UN proper shipping name: Corrosive Liquid, Acidic, Organic, N.O.S. (Contains Glutaraldehyde)
Transport Hazard Class(es): 8
Packing Group: II
Environmental Hazards: Marine Pollutant
EMS: EmS F-A, S-B

IATA/ICAO
UN Number UN3265
UN proper shipping name: Corrosive Liquid, Acidic, Organic, N.O.S. (Contains Glutaraldehyde)
Transport Hazard Class(es): 8
Packing Group: II
Environmental Hazards: Marine Pollutant

Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code Not applicable
Special Precautions for User None

15. Regulatory Information

Canadian Regulations
Canadian Domestic Substances All components listed on inventory or are exempt.
List (DSL)

US Regulations
US TSCA Inventory All components listed on inventory or are exempt.

TSCA Significant New Use Rules - S5A2

Substances CAS Number TSCA Significant New Use Rules - S5A2
Glutaraldehyde 111-30-8 Not applicable
Methanol 67-56-1 Not applicable

EPA SARA Title III Extremely Hazardous Substances

Substances CAS Number EPA SARA Title III Extremely Hazardous
Substances
Glutaraldehyde 111-30-8 Not applicable
Methanol 67-56-1 Not applicable

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EPA SARA (311,312) Hazard Class
Acute Health Hazard
Chronic Health Hazard

EPA SARA (313) Chemicals

Substances CAS Number Toxic Release Inventory (TRI) - Toxic Release Inventory (TRI) -
Group I Group II
Glutaraldehyde 111-30-8 Not applicable Not applicable
Methanol 67-56-1 1.0% Not applicable

EPA CERCLA/Superfund Reportable Spill Quantity

Substances CAS Number CERCLA RQ
Glutaraldehyde 111-30-8 Not applicable
Methanol 67-56-1 5000 lb
2270 kg

EPA RCRA Hazardous Waste Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as defined by the US EPA.
Federal Insecticide, Fungicide and Rodenticide Act:
Label in accordance with Federal Insecticide, Fungicide, and Rodenticide Act (FIFRA) requirements.
FIFRA Information
This chemical is a pesticide product registered by the Environmental Protection Agency and is subject to certain
labeling requirements under federal pesticide law. These requirements differ from the classification criteria and hazard
information required for safety data sheets, and for workplace labels of non-pesticide chemicals. Following is the
hazard information as required on the pesticide label:
Signal Word: DANGER
CORROSIVE
Hazard Statements Causes irreversible eye damage.
Causes skin irritation.
Harmful if inhaled.
Harmful if swallowed.
Harmful if absorbed through skin.
Prolonged or frequently repeated skin contact may cause allergic reactions in
some individuals.
Causes asthmatic signs and symptoms in hyper-reactive individuals.
This pesticide is toxic to fish.

NFPA Ratings: Health 3, Flammability 1, Reactivity 0

HMIS Ratings: Health 3, Flammability 1, Physical Hazard 0 , PPE: J

16. Other information

Preparation Information
Prepared By Chemical Stewardship
Telephone: 1-281-871-6107
e-mail: [email protected]

Revision Date: 18-Apr-2018

Reason for Revision SDS sections updated:

2

Additional information
For additional information on the use of this product, contact your local Halliburton representative.

For questions about the Safety Data Sheet for this or other Halliburton products, contact Chemical Stewardship at
1-580-251-4335.

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Key or legend to abbreviations and acronyms used in the safety data sheet
bw–bodywei ght
CAS–Chemi calAbst ractsSer vi
ce
EC50–Ef fectiveConcent ration50%
ErC50–Ef fectiveConcent rationgrowt
hrate50%
LC50–Let halConcent r
ati
on50%
LD50–Let halDose50%
LL50–Let halLoadi ng50%
mg/ kg–mi lli
gram/ kilogram
mg/ L–mi ll
igram/ li
ter
NIOSH–Nat i
onalI nstitut
ef orOccupationalSaf
etyandHeal
th
NTP–Nat i
onalTox i
cologyPr ogram
OEL–Occupat ionalEx posur eLimit
PEL–Per mi ssibleEx posur eLi mit
ppm –par tspermi l
li
on
STEL–Shor tTer m Ex posur eLi mit
TWA–Ti me- Wei ghtedAver age
UN–Uni tedNat ions
h - hour
mg/m3 - milligram/cubic meter
mm - millimeter
mmHg - millimeter mercury
w/w - weight/weight
d - day

Key literature references and sources for data

www.ChemADVISOR.com/
NZ CCID

Disclaimer Statement
This information is furnished without warranty, expressed or implied, as to accuracy or completeness. The
information is obtained from various sources including the manufacturer and other third party sources. The
information may not be valid under all conditions nor if this material is used in combination with other materials or in
any process. Final determination of suitability of any material is the sole responsibility of the user.

End of Safety Data Sheet

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