Optical Filters

Construction of Optical Filters

Turan Erdogan, PhD (CTO and Co-founder)

Semrock, A Unit of IDEX Corporation

May 31, 2011

www.semrock.com
Multiple interfaces lead to interference

Multiple-path Constructive Destructive

Interference Interference Interference
Properties of reflection and The waves reflected off of the The waves reflected off of the
transmission are determined successive interfaces add up successive interfaces add up
by the interference of many in phase, thus yielding a large out of phase, thus causing the
partially reflected light waves total reflection light to be transmitted

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Different wavelengths interfere differently

Oil Slick

Interference leads to a
wavelength dependence
For a given thickness, only light of the right
wavelength interferes constructively. Leads
to colorful thin-film effects, like rings on an
oil slick or colors in a soap bubble. Soap Bubble
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Many “quarter-wave” layers → strong reflection

“Quarter-wave stack”
is a basic building block for thin-film filters;
made up of alternating layers of high- and
low-index material, each one quarter of an
optical wavelength in thickness; light at the Dielectric laser mirrors are typically
particular wavelength is strongly reflected. made with a quarter-wave stack

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Spectrum from a “quarter-wave stack”

• As an increasing number of high (H) and low (L) index layers are added
(in pairs), the transmission decreases (or reflection increases) over a
region called the “stopband”

The layers are one quarter-wave nH = 2.1 nair = 1.0

thick at a wavelength λ0 = 550 nm nL = 1.46 nsubstrate = 1.52

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Spectrum from a “quarter-wave stack”

• For many quarter-wave layers, large high-frequency “ripple” occurs in

the transmitting regions outside the stopband
• At shorter wavelengths, “harmonic stopbands” show up – for a pure
quarter-wave stack, only odd harmonics exist (λ0/3, λ0/5, …)

The layers are one quarter-wave nH = 2.1 nair = 1.0

thick at a wavelength λ0 = 550 nm nL = 1.46 nsubstrate = 1.52
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Stopband harmonics

• It is important to understand where the stopband harmonics show up,

because they can not always be eliminated completely, and they often
get in the way of transmitting light where you want it to transmit
 e.g., it is difficult to make a multi-photon emitter that both blocks light past
1000 nm (for a Ti:Sapphire laser) and transmits light at very short visible
wavelengths (near 400 nm)

2  n − nL 
x= arcsin H 
π  H
n + n L 

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Edge filter

• By optimizing the layer structure using non-quarter-wave thick layers,

the ripple outside the stopband can be greatly reduced on one side
 Reduce ripple on the long-wavelength side for a long-wave-pass (LWP)
edge filter (example shown below)
 Reduce ripple on the short-wavelength side for a short-wave-pass (SWP)
edge filter

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Edge filters for Raman spectroscopy

• The Raman “finger print” is measured by a spectrometer, but high-

performance filters are needed to stop undesired source light from
reaching the sample, and to prevent scattered laser light from
overwhelming the measurement system

Laser transmitting filter Laser blocking filter

Laser light
Filter transmission
Raman signal

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Long Wave Pass edge filter (RazorEdge®)

• Typical spectra for 532 nm RazorEdge filter

• Note that that theoretical spectrum can be very accurately realized by
the actual measured filter spectrum

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Notch filters (StopLine® U- and S-Grade)

• Stopbands (usually higher harmonics) are the basis for notch filters
• Notch filters effectively eliminate a narrow band of wavelengths (e.g., a
laser line) while transmitting all other wavelengths as much as possible

 Deep notch (OD > 6)

 Narrow bandwidth (< 4% of the laser wavelength)
 High transmission outside the notch (> 95%)
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Multi-notch filters (StopLine®)

• Filters can also be made with low ripple around more than one notch
• Complex, non-quarter-wave thick layers are required to make these
sophisticated filters with notches that occur at non-harmonically related
wavelengths
405 / 488 / 561-568 nm Triple-notch Filter

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New StopLine® “E-Grade” notch filters

• Semrock’s new StopLine® E-Grade notch filters utilized a brand new

design approach that offers an ultra-wide passband region that extends
from < 350 nm to > 1600 nm!

Typical
measured
data for the
532nm filter
is shown.

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“Fabry-Perot” (narrow bandpass) filter

• Two quarter-wave stacks combined with a “spacer” layer between them

(an integer number of half wavelengths thick) form what is called a
“Fabry-Perot cavity”
• At the center of the stopband λ0, the light constructively interferes in
transmission over a very narrow bandwidth

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Multi-cavity Fabry-Perot filter

• Increasing the number of cavities increases the steepness of the

passband edges and flattens the top of the passband while the
bandwidth remains constant
• By adding more quarter-wave layers at the appropriate places, the top
of the passband can be made even more flat (not shown here)

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Multi-cavity Fabry-Perot filter example (MaxLine®)

• This 488 nm filter also has “extended blocking” at wavelengths outside of

the stopband to ensure that all unwanted laser noise is eliminated
< 2 nm wide, yet > 90% transmission

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Diode laser “clean-up filter” (MaxDiode™)

• Diode laser wavelengths vary from laser-to-laser, with temperature, and

with the lifetime of the laser – this multi-cavity Fabry-Perot filter with
many cavities achieves very high transmission over a very flat (low-
ripple) passband region

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Bandpass filter by combining LWP-SWP

• For incoherent light, the combination of two edge filters – an LWP

(long-wave-pass) and an SWP (short-wave-pass) – “looks like” a single-
coating bandpass filter*

18 *See “Combining filters for incoherent light” below

Bandpass Fluorescence Filters (BrightLine®)

• Example GFP-3035B filter set overlaid on GFP spectra

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Thin-film filter manufacturing – monitoring

• Precise narrowband filters are made from quarter-wave layers using

“turning-point” optical monitoring

Switch materials at
well-defined points
on the curve of
transmission vs. time

Self-correcting process!

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Thin-film filter manufacturing – monitoring

• Non quarter waves offer exceptional flexibility for more difficult spectral
profiles, but optical monitoring is also more difficult

Successful optical
monitoring demands
more sophisticated
algorithms to achieve
high total filter thickness

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Thin-film filter manufacturing – deposition

• Two main approaches for manufacturing optical thin-film filters for high-
performance fluorescence instrumentation and microscopes today:

 Thermal / electron-beam evaporation

• Traditional approach; has been around for decades

 Ion-assisted Ion-Beam Sputtering (IBS)

• The new technology; adapted from recent developments in thin-film
technology engineered for telecom applications

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Deposition by evaporation (electron beam)

• “Traditional approach” – special form of thermal evaporation

• Thickness/number of layers limited to
about 10 – 20 layers (w/ no optical
monitoring), or 10’s (< 100) of layers
(w/ optical monitoring)
• Therefore large index contrast needed
just to achieve steep filter edges
• As a result, most common materials
used are Zinc Sulfide (ZnS; n = 2.35)
and Sodium Aluminum Fluoride
(“cryolite” or Na3AlF6; n = 1.35)
• These are “soft” coating materials
• Other aspects of filter spectra are still limited by insufficient layers (like
steep edge for a 45° dichroic beamsplitter)
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Ion-assisted ion-beam sputtering (IBS)

• Originally developed for coating

precise ferrite thin films on magnetic
disk drives and extremely low-loss
mirrors for ring-laser gyro applications
• Then adapted for extremely high-
performance optical filters for
Telecom/WDM in the late 1990’s
• Based on hard refractory oxide
materials like silica (SiO2; n = 1.45),
tantala (Ta2O5; n = 2.1), and niobia
(Nb2O5; n = 2.3) – as hard as the
glass substrates on which they are
coated
• Demonstrated ability to coat many
100’s of layers with extremely high
precision
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Comparison of coating approaches

Electron-beam / Thermal Ion-assisted

Evaporation Ion-beam Sputtering
Physical Vapor Deposition Energetic Physical Vapor Deposition
Deposition
Variable deposition rates Extremely stable deposition rates
Process
Variable spatial uniformity Controllable spatial uniformity

Soft coatings Hard, dense coatings

Low durability Very high durability

Hygroscopic (absorb moisture) Impervious to humidity

Resulting Thin
Appreciable temperature shifting Very low temperature shifting
Films
Some scattering Very low scattering

Some absorption Very low absorption

Low film stress Reproducible film stress

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Comparison of coating approaches

• Differences in film density are readily apparent (AFM data)

E-beam Evaporated Ion-Beam Sputtered

Soft Coating Hard Coating

Data from: Optical Morphology: Just How Smooth Is That Surface? Photonics Spectra, June 1998

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IBS advantage – very repeatable process

• The inherent stability of the IBS process enables an incredibly high

degree of batch-to-batch reproducibility

• Microscope exciter filter • Small-animal-imaging emitter filter

• 4 different batches • 20 different batches
• Different machines / different times • Different machines / different times

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IBS advantage – durability and longevity

• Proven reliability even in harsh (e.g., aqueous/solvent) environments

• Will not “burn out” under prolonged, intense optical irradiation from
bright fluorescence lamps or lasers (high “laser damage threshold”)
• All filters (even dichroics) can be handled/cleaned like any glass optics
Environmental
Standard / Procedure Test Description
Durability Test

Humidity MIL-STD-810F (507.4) Aggravated Humidity (> 10 x 24 hr cycles)

High Temperature MIL-STD-810F (501.4) Induced Hot (> 7 x 24 hr cycles)

Low Temperature MIL-STD-810F (502.4) Cold (C2) (24 hr cycles)

Physical
Standard / Procedure Test Description
Durability Test

Adhesion MIL-C-48497A (4.5.3.1) “Tape Test”

Humidity MIL-C-48497A (4.5.3.2) Damp Heat

Moderate Abrasion MIL-C-48497A (4.5.3.3) “Cheesecloth Test”

Solubility/Cleanability MIL-C-48497A (4.5.4.2) Acetone and Alcohol Immersion Environmental test lab
Water Solubility MIL-C-48497A (4.5.5.3) Distilled Water Immersion

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IBS advantage – durability and longevity

• Filter spectra measured before & after an aggressive 10 24-hour

cycles of Aggravated Humidity testing according to MIL-STD-810F

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Simpler construction (e.g., BrightLine® filters)

• Semrock’s durable coatings are as hard as the glass substrate,

permitting a simple one-piece filter construction*

BrightLine® Conventional
Exciter or Emitter Exciter or Emitter

Hard Soft

(Drawings not to scale)

• Fewer interfaces to reflect or scatter light → highest throughput

• No adhesive to optically damage, degrade or autofluoresce → most reliable
• All optical surfaces may even be cleaned with acetone → very durable

* US Patent 6,809,859 and pending

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Optical durability – Semrock filters don’t “burn out”!

• Two filters exposed to 15 Watts from a Xe arc lamp over central 15 mm for first
24 hours; then to 2.5 W (reproduces back port of a fluorescence microscope)

Competitor Premium DAPI Exciter Semrock DAPI Exciter

After < 300 hrs After > 1000 hrs

Side 1 Side 1

“Burn”

Crack Side 2 Side 2

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Optical durability – Semrock filters don’t “burn out”!

• Two filters exposed to 6 Watts of power from a Xenon arc lamp (with diameter to
reproduce back port of a fluorescence microscope) for 5 days

Competitor premium Semrock BrightLine®

soft-coated GFP exciter filter hard-coated FITC exciter filter

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Optical durability – Semrock filters don’t “burn out”!

• Different filters exposed to 6 Watts of power from a Xenon arc lamp (with
diameter to reproduce back port of a fluorescence microscope) for 5 days

Change in Transmission Change in Edge Position

Soft-coated filters degrade! Soft-coated filters shift!
100 1.0%

Semrock FITC A
90 0.8%
Semrock DAPI B
Other Texas Red A
80 0.6% Other GFP A

Relative Edge Wavelength Shift (%)

70 0.4%
Average Transmission (%)

60 0.2%

50 0.0%

40 -0.2%

30 -0.4%

20 Semrock FITC A -0.6%

Other Texas Red A
10 Other GFP A -0.8%

0 -1.0%
0 20 40 60 80 100 120 0 20 40 60 80 100 120
Exposure Time (hrs) Exposure Time (hrs)

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 Thank You!

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