Adsorption of Acetic Acid With Activated Carbon PDF

Jeff Yee
Hayden Robbins
Mohammed Al Hashim
Adsorption of Acetic Acid with Activated Carbon

Experiment 6
Objective
To study the effects of activated carbon in adsorption processes and to

determine the maximum amount of adsorption (Qmax).
Introduction
Sorption refers to the action of either absorption or adsorption. It is the effect of

gases or liquids being incorporated into a material of a different state and adhering to
the surface of another molecule.
Sorption processes are very important in the fate and transport of contaminants
in the environment and also in the removal of contaminant, usually with the use of
reactors, for the following removal purposes:
● Removal of color from dye mill wastewater

● Removal of surface activate reagents from water
● Removal of total organic carbon from industrial wastewater
● Removal of taste or odor constituents, or both, from the potable water
Absorption is the incorporation of a substance in one state into another of a
different state (e.g. liquids being absorbed by a solid or gases being absorbed by a
liquid). Adsorption is the physical adherence or bonding of ions and molecules onto the
surface of another molecule or in another word adsorption is a surface phenomenon in
which the rate and the extent of adsorption are functions of the surface area of the
solids used.
Activated carbon is a generally made from a wood product or coal by heating to

temperatures between 300-1000℃ in one of a variety of possible gaseous atm osphere
such as CO2, air or water vapor, and then by rapid quenching in the air or water.
Activated carbon is a material with an exceptionally high surface area of approximately
500 m2 in 1 gram due to a high degree of microporosity. Sufficient activation for useful
applications may come solely from the high surface area, though often further chemical
treatment is used to enhance the absorbing properties of the material.
In this experiment Langmuir Isotherm plot will be used to estimate the maximum
amount of adsorption (Qmax).
Langmuir Isotherm relates the coverage or adsorption of molecules on a solid

surface to gas pressure or concentration of a medium above the solid surface at a fixed
temperature. Langmuir Isotherm assumes that a single adsorbate binds to a single site
of the adsorbent, and that all surface sites on the adsorbent have the same affinity for
the adsorbate.
Langmuir Isotherm equation was developed by Irving Langmuir in 1916 and it states
that:
𝑏𝑏𝑏𝑏
Langmuir 𝑞𝑞 = 𝑄𝑄𝑚𝑚𝑚𝑚𝑚𝑚 × 1+𝑏𝑏𝑏𝑏
Where When C is the concentration of contaminant in the liquid after adsorption (molar
or mg/l)
q is the mass of sorbed molecules per mass of sorbent (mole or mg per gram sorbent)
b = Langmuir equilibrium constant
Qmax=maximum adsorbed amount, mol/g
In order to calculate the amount adsorbed, q, the equation below can be used:
(𝐶𝐶𝑜𝑜 −𝐶𝐶)𝑉𝑉
q= 𝑚𝑚
where,
q = amount adsorbed, mmol/g of activated sludge carbon, mol/g
Co = aqueous concentration before adsorption, mol/L
C = aqueous concentration after adsorption, mol/L
m = weight of activated carbon, g
V = volume of sample, L
Figure 1 below show the Langmuir Isotherm plot (which can be later used to estimate
qmax or Ƭmax)
In the above graph;
● Region I represents the free adsorbent surface. In this region, adsorption

increase with increase in the concentration of aqueous solution after adsorption.
● Region II indicates that the most of the adsorption surfaces are full. In this region,
adsorption increased non-linearly with increase in the concentration of aqueous
solution.
● Region III indicates that all the adsorption surfaces are full. In this region, rate of
adsorption neither decrease nor increase with increase in the concentration of
aqueous solution.
Reagents
● Acetic acid solution with concentration of 1N.

● Activated carbon
● Aqueous sodium hydroxide solution (0.1N)
● Phenolphthalein indicator
Procedures
1. Dilute 1N acetic acid to 0.8, 0.4, 0.2, 0.1, 0.05 and 0.025 N. The final volume of
each concentration is 100 ml.
2. Transfer about 50.00 ml of different concentrations of diluted acetic acid solution
into a clean 250 ml Erlenmeyer flask. Prepare a series of each solution and
name one series, set I.
3. Transfer different volume (ml) of different concentrations of diluted acetic acid
solution into a clean 250 ml Erlenmeyer flask. Prepare a series of each solution
and name one series, set II.
4. Measure 1.0000 g activated carbon and transfer to set I of solutions. Stoppers
the flasks and place them in the shaker, shaking for 1.5 hours at 150 rpm.
5. For set II, measure the indicated volumes (Vo) of each sample solution and dilute
the rest with DI water to 50 ml in a clean, labeled Erlenmeyer flask.
6. Titrate the prepared solutions in step 3 against NaOH solution (0.1N) in order to
detect the precise concentration of acetic acid solution in each flask (Co). Make
sure to add three drops of the phenolphthalein indicator before you start the
titration. As you reach the end point the color of the colorless solution will turn
pale pink.
7. Record the volume of the NaOH solution use (V) at the end point in the provide
table.
8. Filter the solutions in set I and transfer them to clean, labeled 250 ml Erlenmeyer
flasks.
9. Follow step 3 and 4 above in order to detect the precise concentration of acetic
acid solution in each flask (C).
Results
Table 1: Dilution of acetic acid
Initial Volume of Target Volume of Volume of

concentration target acetic concentration initial acetic water added
of acetic acid acid (mL) of acetic acid acid required (mL)
(N) (N) (mL)
1.00 100.00 0.80 80.00 20.00
1.00 100.00 0.40 40.00 60.00
1.00 100.00 0.20 20.00 80.00
1.00 100.00 0.10 10.00 90.00
1.00 100.00 0.05 5.00 95.00
1.00 100.00 0.025 2.50 97.50
Table 2: Acetic acid concentration before adsorption
Standard NAOH titrant concentration 0.1 N
Labeled Volume of Initial read Final read of Volume of Actual

acetic acid acetic acid of NaOH NaOH titrant NaOH titrant concentration
concentration used (mL) titrant (mL) (mL) used (mL) of acetic acid
(N) - in flask (Co; N)
0.8 5.00 12.31 34.52 22.21 0.4442
0.4 5.00 33.72 44.90 11.18 0.2236
0.2 5.00 44.99 50.02 5.03 0.1006
0.1 10.00 39.62 44.99 5.37 0.0537
0.05 10.00 36.61 39.62 3.01 0.0301
0.025 15.00 34.52 36.61 2.09 0.0139

Table 3: Acetic acid concentration after adsorption
Standard NAOH titrant concentration 0.1 N
Labeled Volume of Initial read Final read of Volume of Actual

acetic acid acetic acid of NaOH NaOH titrant NaOH titrant concentration
concentration used (mL) titrant (mL) (mL) used (mL) of acetic acid
(N) - in flask (C; N)
0.8 5.00 22.80 43.50 20.70 0.414
0.4 5.00 16.40 25.80 9.40 0.188
0.2 5.00 18.20 22.80 4.60 0.092
0.1 10.00 14.00 18.20 4.20 0.042
0.05 10.00 14.20 16.40 2.20 0.022
0.025 20.00 13.10 14.20 1.10 0.0055
Table 4: Adsorption of acetic acid using activated carbon
Remark: molar concentration and normal concentration of acetic acid are the same
Diluted acetic Vo (mL) Co (mol/l) C (mol/l) Amount of Q (mol/g)

acid Volume of Actual Actual activated
concentration acetic acid concentration concentratio carbon
(N) in a/c flask of acetic acid n of acetic used (g)
before acid after
adsorption adsorption
0.8 50.00 0.4442 0.414 1.0000 0.00151
0.4 50.00 0.2236 0.188 1.0038 0.00177
0.2 50.00 0.1006 0.092 1.0006 0.04567
0.1 50.00 0.0537 0.042 1.0008 0.00058
0.05 50.00 0.0301 0.022 1.0013 0.00041
0.025 50.00 0.0139 0.0055 1.0049 0.00042

Sample Calculations
Table 1: Dilution of Acetic Acid:

Volume of Acetic Acid (1.00 N) needed:
𝑀𝑀 𝑉𝑉 𝑀𝑀 𝑉𝑉0.8𝑁𝑁
𝑉𝑉2 = 𝑀𝑀1 𝑉𝑉1 𝑉𝑉1.00𝑁𝑁 = 0.80𝑁𝑁 = (0.80N)(100mL)/1.00N = 80.00 mL
2 2 𝑀𝑀 1.00𝑁𝑁
Volume of DI Water needed:

𝑉𝑉𝐷𝐷𝐷𝐷 = 𝑉𝑉𝑇𝑇𝑇𝑇𝑇𝑇𝑇𝑇𝑇𝑇 − 𝑉𝑉0.80𝑁𝑁 = 100.00 mL - 80.00 mL = 20.00 mL
Table 2: Acetic Acid Concentration before Adsorption

Final Volume of NaOH titrant used:
𝑉𝑉𝑁𝑁𝑁𝑁𝑁𝑁𝑁𝑁 = 𝑉𝑉𝑓𝑓 − 𝑉𝑉𝑖𝑖 = 34.52 mL - 12.31 mL = 22.21 mL
Actual Concentration of Acetic Acid:

(𝑉𝑉 )∗(𝐶𝐶𝑁𝑁𝑁𝑁𝑁𝑁𝑁𝑁 22.21𝑚𝑚𝑚𝑚 ∗ 0.1𝑁𝑁
C0 = 𝑁𝑁𝑁𝑁𝑁𝑁𝑁𝑁 = = 0.4442 N
𝑉𝑉 𝐶𝐶𝐶𝐶3𝐶𝐶𝐶𝐶𝐶𝐶𝐶𝐶 5.00 𝑚𝑚𝑚𝑚
Table 3: Acetic Acid Concentration after Adsorption:

Final Volume of NaOH titrant used:
𝑉𝑉𝑁𝑁𝑁𝑁𝑁𝑁𝑁𝑁 = 𝑉𝑉𝑓𝑓 − 𝑉𝑉𝑖𝑖 = 43.50 mL - 22.80 mL = 20.70 mL
Actual Concentration of Acetic Acid:

(𝑉𝑉 )∗(𝐶𝐶𝑁𝑁𝑁𝑁𝑁𝑁𝑁𝑁 20.70𝑚𝑚𝑚𝑚 ∗ 0.1𝑁𝑁
C0 = 𝑁𝑁𝑁𝑁𝑁𝑁𝑁𝑁 = 5.00 𝑚𝑚𝑚𝑚 = 0.414 N
𝑉𝑉 𝐶𝐶𝐶𝐶3𝐶𝐶𝐶𝐶𝐶𝐶𝐶𝐶
Table 4: Adsorption of Acetic Acid Using Activated Carbon:

Amount of Adsorption:
(𝐶𝐶0 −𝐶𝐶)𝑉𝑉 (0.442𝑚𝑚𝑚𝑚𝑚𝑚/𝐿𝐿 − 0.414𝑚𝑚𝑚𝑚𝑚𝑚/𝐿𝐿)(50.00𝑚𝑚𝑚𝑚 ∗ 1𝐿𝐿/1000𝑚𝑚𝑚𝑚)
q = 𝑚𝑚 = = 0.00151 mol/g
𝐴𝐴𝐴𝐴 1.0000𝑔𝑔
Graph
Estimated Qmax (from graph) = 0.000285 mol/g
Figure 1: Amount of Adsorption (Q) vs. Actual Acetic Acid Concentration Before
Adsorption (C0).
Discussion
Adsorption is observed because an adsorbent solid is mixed with a liquid solution

that contains dissolved substances; this acts as an adsorbate. The activated charcoal
removes a part of the acetic acid once it is agitated, and therefore decreases the
amount of concentration of acetic acid in the solution. The acetic acid adsorbed
increases with the concentration of the adsorbate. Activated carbon filtration effectively
removes certain organic (carbon containing) compounds in water. When observing the
formula for acetic acid (CH3COOH), the numerous amounts of carbon are apparent,
making it easier for the activated carbon to remove the contaminants. The isotherm
observed from the acetic removal using activated carbon was the Langmuir model.
Because the graph produced from the experimental data obtained in this lab resembles
that of the Langmuir model, it can be noted that this lab followed this specific adsorption
isotherm. The graph illustrated in Figure 1 reveals that the maximum amount of
adsorption (Qmax) for this lab was 0.000285 mol/g. Referring to the shape of Figure 1,
region I behaves linearly due to the rapid increase of how much acetic acid is adsorbed
while having a relatively free adsorbent surface. Once the surface fills with the
adsorbate, the amount of acetic acid adsorbed increases, while the rate of adsorption
decrease (as observed in region II). Over time, the adsorbent surface becomes full and
the amount of adsorbed remains constant, regardless of increasing the concentration
(region III). If you reflect this situation graphically, a parabolic pattern is obtained and
Qmax is shown as a constant line. The increase of acetic acid concentration will increase
the amount of adsorption occurring at equilibrium until a limiting value is reached (Qmax).
When the removal of other contaminants is necessary, the maximum amount adsorbed
with change. The contaminants that are more easily adsorbed by the activated carbon
will be removed in larger amounts compared to those that are less well absorbed. This
is due to the fact that adsorption isotherms are characterized by their ability to remove a
specific contaminant, thus the Qmax value would change based on the desired
contaminant that needs to be removed.
Rapid adsorption would create a graph where region I would be decrease in size,
due to the decreased time of the free adsorbent surface. Because adsorption increases
with the increase in the concentration of the aqueous solution after adsorption, region I
would reflect a shorter period of this linear increase. Region II would reflect a smaller
section where the adsorption surfaces are full, because the contaminant is more easily
absorbed by the activated carbon. Although this is a non-linear increase, a smaller
curve would represent this rapid adsorption. Taking these predictions into consideration,
equilibrium would be reached at a fairly lower rate which would create a lower Qmax, and
therefore a decrease in the value where the graph appears to be constant. A higher
Qmax is favored over a lower Qmax in environmental engineering, due efficiently removing
a larger number of contaminants. If the threshold for absorbing contaminants is
increased, it will take the adsorption sites on the activated carbon to become fuller of
contaminants, which will reduce the contaminants in the water by using less materials.
Some errors that occurred during this experiment caused one pair of data
(0.4442,0.00151) to be thrown out to obtain Qmax graphically. This error can be
attributed to human error in the dilution of CH3COOH and over-titration.
Conclusion
This lab consisted of studying the effects of activated carbon in adsorption

processes. In this process, the adsorbent was activated carbon, while the adsorbate
was acetic acid. The adsorption effects of activated carbon were measured by variably
diluting the acetic acid. The maximum amount of adsorption (Qmax) observed graphically
was 0.000285 g/mol.

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Jeff Yee

Adsorption of Acetic Acid with Activated Carbon

To study the effects of activated carbon in adsorption processes and to

Sorption refers to the action of either absorption or adsorption. It is the effect of

● Removal of color from dye mill wastewater

Activated carbon is a generally made from a wood product or coal by heating to

Langmuir Isotherm relates the coverage or adsorption of molecules on a solid

● Region I represents the free adsorbent surface. In this region, adsorption

● Acetic acid solution with concentration of 1N.

Table 1: Dilution of acetic acid

Initial Volume of Target Volume of Volume of

1.00 100.00 0.80 80.00 20.00

1.00 100.00 0.40 40.00 60.00

1.00 100.00 0.20 20.00 80.00

1.00 100.00 0.10 10.00 90.00

1.00 100.00 0.05 5.00 95.00

1.00 100.00 0.025 2.50 97.50

Table 2: Acetic acid concentration before adsorption

Standard NAOH titrant concentration 0.1 N

Labeled Volume of Initial read Final read of Volume of Actual

0.8 5.00 12.31 34.52 22.21 0.4442

0.4 5.00 33.72 44.90 11.18 0.2236

0.2 5.00 44.99 50.02 5.03 0.1006

0.1 10.00 39.62 44.99 5.37 0.0537

0.05 10.00 36.61 39.62 3.01 0.0301

0.025 15.00 34.52 36.61 2.09 0.0139

Standard NAOH titrant concentration 0.1 N

Labeled Volume of Initial read Final read of Volume of Actual

0.8 5.00 22.80 43.50 20.70 0.414

0.4 5.00 16.40 25.80 9.40 0.188

0.2 5.00 18.20 22.80 4.60 0.092

0.1 10.00 14.00 18.20 4.20 0.042

0.05 10.00 14.20 16.40 2.20 0.022

0.025 20.00 13.10 14.20 1.10 0.0055

Table 4: Adsorption of acetic acid using activated carbon

Diluted acetic Vo (mL) Co (mol/l) C (mol/l) Amount of Q (mol/g)

0.8 50.00 0.4442 0.414 1.0000 0.00151

0.4 50.00 0.2236 0.188 1.0038 0.00177

0.2 50.00 0.1006 0.092 1.0006 0.04567

0.1 50.00 0.0537 0.042 1.0008 0.00058

0.05 50.00 0.0301 0.022 1.0013 0.00041

0.025 50.00 0.0139 0.0055 1.0049 0.00042

Table 1: Dilution of Acetic Acid:

Volume of DI Water needed:

Table 2: Acetic Acid Concentration before Adsorption

Actual Concentration of Acetic Acid:

Table 3: Acetic Acid Concentration after Adsorption:

Actual Concentration of Acetic Acid:

Table 4: Adsorption of Acetic Acid Using Activated Carbon:

Estimated Qmax (from graph) = 0.000285 mol/g

Adsorption is observed because an adsorbent solid is mixed with a liquid solution

This lab consisted of studying the effects of activated carbon in adsorption

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